NC0024911_Groundwater Monitoring Report June 2019_20190729

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Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Information Processing Unit:
Metropolitan S
e District
OF BUNCOMBE COUNTY, NORTH CAROLINA
July 29, 2019
RECEIVED
AUG 0 1 2019
Infom%oWn Procrsamg Unk
DWQ/BOG
Please find attached the Groundwater Quality Monitoring Reports for June 2019 from The Metropolitan
Sewerage District of Buncombe County (MSD). These monitoring report forms have additional
identification on the Well ID line, MW-05, MW-06, MW-07, MW-08, for ease of reference.
Monitoring Well 05 exceeding allowable limits for manganese and pH. Monitoring Well 06 exceeding
allowable limits for manganese, iron and pH. Monitoring Well 07 exceeded allowable limits for
manganese, iron and pH. Monitoring Well 08 exceeded allowable limits for manganese, iron and pH.
Please do not hesitate to contact me at 828-225-8224 with questions regarding the attached reports.
Sincerely,
Roger Edwards
Director of Treatment
MSD of Buncombe County
Water Quality Regional Operations
Asheville Regional Office
-Protecting Our Natural Resources-
2028 RIVERSIDE DRIVE, ASHEVILLE, NORTH CAROLINA28804 TELEPHONE: [phone] FAX: [phone] WEEISITE: www.msdbc.org

GW-59A COMPLIANCE REPORT FORM Permit # NCO024911
(Submit one each monitoring period with GIV-59 forms.)
I
Enter date monitoring results were due. L07/3112019_) Will this monitoring report (GW-59 and GW-59A)
YES
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
INO
IF the answer to question 1 or 2 is 'YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YEA
NO
identification plate, area overgrown, etc.)? Ifthe ansiver is "Yes", contact the Regional Oriceforguidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
MW-05 MW-06 MW-07 MW-08
pH5.8 pH5.8 pH5.8 pH5.8
Manganese 482 ug/L Manganese 14100 ug/L Manganese 14400 ug/L Manganese 6820 ug/L
Iron 7480 ug/L Iron 1730 ug/L Iron 8660 ug/L
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
O
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is WO; skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES; describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may b
required to determine the impact the waste disoosal system is having at the review and compliance
boundaries surrounding this facility, Failure to do so may subiect the permittee to a Notice f Violation.
fines. and/or penalties.
g
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW��-59A) is true and complete to the best of my knowledge.
ign ure of Permittee (or Authorized Agent) ate
[fate
GW-59A 12/8/2003

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aceAnalXical
wrw.pacelabs.cwn
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
July 03, 2019
Mr. Roger Edwards
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
RE: Project: MWs 6/12/19
Pace Project No.: 92432959
Dear Mr. Edwards:
Enclosed are the analytical results for sample(s) received by the laboratory on June 13, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Yly, �I � �
ton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Shannon Bergeron, Metropolitan Sewerage District
Ryan Dyson, MSD of Buncombe County, NC
Mr. Chad Ledford, Metropolitan Sewerage District
Ms. Cassandra McKnight, MSD of Buncombe County
Mr. Alan Taylor, Metropolitan Sewerage District
Water Quality Regional Operations
Asheville Regional Office
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, L-C.
Page 1 of 23

Pace Analytical Services, LLC
e 2225 Riverside Dr.
aceAna/ytica/ Asheville, NC 28804
wxwpacelabs.wm [phone]
CERTIFICATIONS
Project: MWs 6/12/19
Pace Project No.: 92432959
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Missouri Certification #: 236
Alaska DEC- CS/UST/LUST
Montana Certification M Carl 0074
Alabama Certification M 41320
Nebraska Certification: NE-OS-28-14
Arizona Certification# AZO819
New Hampshire Certification #: 2958
Colorado Certification: FL NELAC Reciprocity
New Jersey Certification M FL022
Connecticut Certification M PH-0216
New York Certification #: 11608
Delaware Certification: FL NELAC Reciprocity
North Carolina Environmental Certificate M 667
Florida Certification M E83079
North Carolina Certification M 12710
Georgia Certification #: 955
North Dakota Certification #: R-216
Guam Certification: FL NELAC Reciprocity
Oklahoma Certification #: D9947
Hawaii Certification: FL NELAC Reciprocity
Pennsylvania Certification #: 68-00547
Illinois Certification #: 200068
Puerto Rico Certification #: FLO1264
Indiana Certification: FL NELAC Reciprocity
South Carolina Certification: #96042001
Kansas Certification #: E-10383
Tennessee Certification M TN02974
Kentucky Certification #: 90050
Texas Certification: FL NELAC Reciprocity
Louisiana Certification M FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Virginia Environmental Certification #: 460165
Maryland Certification: #346
West Virginia Certification #: 9962C
Michigan Certification M 9911
Wisconsin Certification M 399079670
Mississippi Certification: FL NELAC Reciprocity
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification M 99006001
Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification M E87627
North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84
North Carolina Field Services Certification M 5342 VirginiaNELAP Certification M 460221
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification M E87648
Massachusetts Certification M M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification M 99030001
VirginiaNELAP Certification M 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 23

aceAnalyiical
wnw.pace/abs..
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project: MWs 6/12/19
Pace Project No.: 92432959
Lab ID
Sample ID
Method
Analysts
Analytts
Reported
Laboratory
92432959001
MW-05
EPA 200.7 Rev 4.41994
DS
10
PASI-A
EPA 245.1 Rev 3.0 1994
JMW1
1
PASI-A
SM 254OC-2011
MJP
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
1
PASI-A
EPA 350,1 Rev 2.0 1993
GC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
SM 4500-CI-E-2011
NAL
1
PASI-A
SM 5310B
SA1
1
PASI-0
92432959002
MW-06
EPA 200.7 Rev 4.4 1994
DS, SH1
10
PASI-A
EPA 245.1 Rev 3.0 1994
JMW1
1
PASI-A
SM 254OC-2011
MJP
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
1
PASI-A
EPA 350.1 Rev 2.0 1993
GC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
SM 4500-CI-E-2011
NAL
1
PASI-A
SM 5310B
SA1
1
PASI-O
92432959003
M W-07
EPA 200.7 Rev 4.4 1994
DS
10
PASI-A
EPA 245.1 Rev 3.0 1994
JMW1
1
PASI-A
SM 2540C-2011
MJP
i
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
1
PASI-A
EPA 350.1 Rev 2.0 1993
GC
1
PASI-A
EPA 353.2 Rev 2.01993
KDF1
1
PASI-A
SM 4500-CI-E-2011
NAL
1
PASI-A
SM 5310B
SA1
1
PASI-O
92432959004
MW-08
EPA 200.7 Rev 4.41994
DS
10
PASI-A
EPA 245.1 Rev 3.0 1994
JMW1
1
PASI-A
SM 254OC-2011
MJP
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
1
PASI-A
EPA 350.1 Rev 2.01993
GC
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
SM 4500-CI-E-2011
NAL
1
PASI-A
SM 5310B
SA1
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC,
Page 3 of 23

.WeAnalytical
wwwpacefabs.c
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MWs 6/12/19
Pace Project No.: 92432959
Sample: MW-05 Lab ID: 92432959001 Collected: 06/12/1914:15 Received: 06/1311911:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
5310B TOC
Total Organic Carbon
Date: 07/03/2019 05:20 PM
Analytical Method:
Mark
1
06/25/19 14:33
Swann
6112/19
1
06/25/19 14:33
14:15
1
06/25/19 14:33
5.8 Std. Units
0.10
1
06/25/19 14:33
15.8 deg C
0.50
1
06/25/19 14:33
15.77 feet
1
06/25/19 14:33
42 umhos/cm
1.0
1
06125/1914:33
No odor
1
06/25/19 14:33
Clear
1
06/25/19 14:33
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA
200.7 Rev 4.4 1994
ND ug/L
10.0
1
06/22/19 00:46
06/24/19 04:24
7440-38-2
17.3 ug/L
5.0
1
06/22/19 00:46
06/24/19 04:24
7440-39-3
ND ug/L
1.0
1
06/22/19 00:46
06/24/19 04:24
7440-43-9
ND ug/L
5.0
1
06/22/19 00:46
06/24/19 04:24
7440-47-3
206 ug/L
50.0
1
06/22/19 00:46
06/24/19 04:24
7439-89-6
ND ug/L
5.0
1
06/22/19 00:46
06/24/19 04:24
7439-92-1
482 ug/L
5.0
1
06/22/19 00:46
06/24/19 04:24
7439-96-5
ND ug/L
10.0
1
06/22/19 00:46
06/24/19 04:24
7782-49-2
ND ug/L
5.0
1
06/22/19 00:46
06/24/19 04:24
7440-22-4
ND ug/L
5000
1
06/22/19 00:46
06/24/19 04:24
7440-23-5
Analytical Method: EPA 245.1 Rev 3.0
1994 Preparation
Method: EPA
245.1 Rev 3.0 1994
ND ug/L
0.20
1
06/17/19 15:39
06/18/19 09:53
7439-97-6
Analytical Method: SM 254OC-2011
37.0 mg/L
25.0
1
06/1811913:18
Analytical Method: EPA 300.0 Rev 2.1
1993
4.0 mg/L
1.0
1
06/15/1917:35
14808-79-8
Analytical Method: EPA 350.1 Rev 2.0
1993
ND mg/L
0.10
1
06/2011921:30
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0
1993
0.056 mg/L
0.040
1
06/13/1915:19
14797-55-8
Analytical Method: SM 4500-CI-E-2011
1.0 mg/L
1.0
1
06/1911913:57
16887-00-6
Analytical Method: SM 5310B
ND mg/L
1.0
1
07/02/19 21:35
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
D6
Page 4 of 23

aceAnalXical
w vpacelaes..
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MWs 6/12119
Pace Project No.: 92432959
Sample: MW-06 Lab ID: 92432959002 Collected: 06/12/1916:00 Received: 06/13/19 11:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
5310B TOC
Total Organic Carbon
Date: 07/03/2019 05:20 PM
Analytical Method:
Mark
1
06/25/19 14:35
Swann
6112119
1
06/25/19 14:35
16:00
1
06/25/19 14:35
5.8 Std. Units
0.10
1
06/25/19 14:35
21.4 deg C
0.50
1
06/25/19 14:35
9.02 feet
1
06/25/19 14:35
309 umhos/cm
1.0
1
06/25/19 14:35
No odor
1
06/25/19 14:35
Clear
1
06/25/19 14:35
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA
200.7 Rev 4.4 1994
ND ug/L
10.0
1
06/22/19 00:46
06/24/19 04:28
7440-38-2
66.1 ug/L
5.0
1
06122/19 00:46
06/24/19 04:28
7440-39-3
ND ug/L
1.0
1
06/22/19 00:46
06/24/19 04:28
7440-43-9
ND ug/L
5.0
1
06/22/19 00:46
06/24/19 04:28
7440-47-3
7480 ug/L
50.0
1
06/22/19 00:46
06/24/19 04:28
7439-89-6
ND ug/L
5.0
1
06/22/19 00:46
06/24/19 04:28
7439-92-1
14100 ug/L
25.0
5
06/22/19 00:46
06/25/19 13:13
7439-96-5
ND ug/L
10.0
1
06/22/19 00:46
06/24/19 04:28
7782-49-2
ND ug/L
5.0
1
06/22/19 00:46
06/24/19 04:28
7440-22-4
14500 ug/L
5000
1
06/22/19 00:46
06/24/19 04:28
7440-23-5
Analytical Method: EPA 245.1 Rev 3.0
1994 Preparation
Method: EPA
245.1 Rev 3.0 1994
ND ug/L
0.20
1
06/17/1915:39
06/18/1910:00
7439-97-6
Analytical Method: SM 254OC-2011
172 mg/L
25.0
1
06/18/1913:19
Analytical Method: EPA 300.0 Rev 2.1
1993
62.3 mg/L
1.0
1
06/15/1917:49
14808-79-8
Analytical Method: EPA 350.1 Rev 2.0
1993
0.19 mg/L
0.10
1
06/20/1921:31
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0
1993
ND mg/L
0.040
1
06/13/1915:20
14797-55-8
Analytical Method: SM 4500-CI-E-2011
11.0 mg/L
1.0
1
06/19/1913:57
16887-00-6
Analytical Method: SM 5310B
1.6 mg/L
1.0
1
07/02/19 22:18
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 23

.ace Analytical
www.pacalabs.com
1
ANALYTICAL RESULTS
Project: MWs 6/12/19
Pace Project No.: 92432959
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-07 Lab ID: 92432959003 Collected: 06/13/1914:25 Received: 06/13/1916:01 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
5310E TOC
Total Organic Carbon
Date: 07/03/2019 05:20 PM
Analytical Method:
Mark
1
06/25/19 14:55
Swann
6113/19
1
06/25/19 14:55
14:25
1
06/25/19 14:55
5.8 Bid. Units
0.10
1
06/26/19 14:55
25.3 deg C
0.50
1
06/25/19 14:55
10.15 feet
1
06/25/19 14:55
448 umhos/cm
1.0
1
06/25/19 14:55
No odor
1
06/25/19 14:55
Clear
1
06/25/19 14:55
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA
200.7 Rev 4.4 1994
ND ug/L
10.0
1
06/22/19 00:46
06/23/19 02:39
7440-38-2
43.6 ug/L
5.0
1
06/22/19 00:46
06/23/19 02:39
7440-39-3
NO ug/L
1.0
1
06/22/19 00:46
06/23/19 02:39
7440-43-9
NO ug/L
5.0
1
06/22/19 00:46
06/23/19 02:39
7440-47-3
1730 ug/L
50.0
1
06/22/19 00:46
06/23/19 02:39
7439-89-6
ND ug/L
6.0
1
06/22/19 00:46
06/23/19 02:39
7439-92-1
14400 ug/L
25.0
5
06/22/19 00:46
06/24/19 19:30
7439-96-5
ND ug/L
10.0
1
06122/19 00:46
06/23/19 02:39
7782-49-2
ND ug/L
5.0
1
06/22/19 00:46
06/23/19 02:39
7440-22-4
15300 ug/L
5000
1
06/22/19 00:46
06/24/19 00:57
7440-23-5
Analytical Method: EPA 245.1 Rev 3.0
1994 Preparation
Method: EPA
245.1 Rev 3.0 1994
NO ug/L
0.20
1
06/17/19 15:39
06/18/19 10:02
7439-97-6
Analytical Method: SM 254OC-2011
307 mg/L
25.0
1
06/19/19 03:17
Analytical Method: EPA 300.0 Rev 2.1
1993
149 mg/L
3.0
3
06/15/19 22:07
14808-79-8
Analytical Method: EPA 350.1 Rev 2.0
1993
0.16 mg/L
0.10
1
06/20/1921:37
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0
1993
0.48 mg/L
0.040
1
06/14/1910:26
14797-55-8
Analytical Method: SM 4500-CI-E-2011
12.0 mg/L
1.0
1
06/19/1913:58
16887-00-6
Analytical Method: SM 5310B
1.4 mg/L
1.0
1
07/02/19 23:47
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, -I-C.
Page 6 of 23

aceAnalytical
w vpaaefabs.san
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MWs 6/12119
Pace Project No.: 92432959
Sample: MW-08 Lab [D: 92432959004 Collected: 06/13/19 15:35 Received: 06/13/19 16:01 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
Monitoring Well Data
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
4500 Chloride
Chloride
5310B TOC
Total Organic Carbon
Date: 07/03/2019 05:20 PM
Analytical Method:
Mark
1
06/25/19 14:57
Swann
6113/19
1
06/26/19 14:57
15:35
1
06/25/19 14:57
5.8 Std. Units
0.10
1
06/25/19 14:57
24.3 deg C
0.50
1
06/25/19 14:57
9.77 feet
1
06/25/19 14:57
380 umhos/cm
1.0
1
06/25/19 14:57
No odor
1
06/25/19 14:57
Clear
1
06/25/19 14:57
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation Method: EPA
200.7 Rev 4.4 1994
ND ug/L
10.0
1
06/22/19 00:46
06/23/19 02:42
7440-38-2
103 ug/L
5.0
1
06/22/19 00:46
06/23/19 02:42
7440-39-3
NO ug/L
1.0
1
06/22/19 00:46
06/23/19 02:42
7440-43-9
ND ug/L
5.0
1
06/22/19 00:46
06/23/19 02:42
7440-47-3
8660 ug/L
50.0
1
06/22/19 00:46
06/23/19 02:42
7439-89-6
NO ug/L
5.0
1
06/22/19 00:46
06/23/19 02:42
7439-92-1
6820 ug/L -
5.0
1
06/22/19 00:46
06/23/19 02:42
7439-96-5
ND ug/L
10.0
1
06/22/19 00:46
06/23/19 02:42
7782-49-2
NO ug/L
5.0
1
06/22/19 00:46
06/23/19 02:42
7440-22-4
16800 ug/L
5000
1
06/22/19 00:46
06/24/19 01:01
7440-23-5
Analytical Method: EPA 245.1 Rev 3.0
1994 Preparation
Method: EPA
245.1 Rev 3.0 1994
NO ug/L
0.20
1
06/17/1915:39
06/18/1910:05
7439-97-6
Analytical Method: SM 254OC-2011
250 mg/L
25.0
1
06/19/19 03:17
Analytical Method: EPA 300.0 Rev 2.1
1993
94.5 mg/L
1.0
1
06/15/1919:13
14808-79-8
Analytical Method: EPA 350.1 Rev 2.0
1993
0.23 mg/L
0.10
1
06/20/19 21:38
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0
1993
2.7 mg/L
0.040
1
06/14/1910:32
14797-55-8
Analytical Method: SM 4500-CI-E-2011
18.2 mg/L
1.0
1
06/19/1914:01
16887-00-6
Analytical Method: SM 5310B
4.3 mg/L
1.0
1
07/03/19 00:05
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLD.
Page 7 of 23

WMnalytical
www.pacelabs.cnm
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 481574
Analysis Method: EPA 245.1 Rev 3.0 1994
QC Batch Method: EPA 245.1 Rev 3.0 1994
Analysis Description: 245.1 Mercury
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
METHOD BLANK: 2604578
Matrix: Water
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ug/L
ND 0.20
06/18/1909:15
LABORATORY CONTROL SAMPLE: 2604579
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits
Qualifiers
Mercury ug/L
2.5 2.3
91 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2604580 2604581
MS MSD
92429344001
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Mercury ug/L ND
2.5 2.5 2.0
2.0 78
77
70-130 0 111
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2604582 2604583
MS MSD
92432959001
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec
% Rec
Limits RPD Qua]
Mercury ug/L ND
2.5 2.5 2.5
2.5 101
99
70-130 2
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 23

(�I�aoiqAnalj4icalo
waw.paielobs.com
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 482508 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92432959001, 92432959002
METHOD BLANK: 2608860
Associated Lab Samples: 92432959001, 92432959002
Parameter
Units
Arsenic
ug/L
Barium
ug/L
Cadmium
ug/L
Chromium
ug/L
Iron
ug/L
Lead
ug/L
Manganese
ug/L
Selenium
ug/L
Silver
ug/L
Sodium
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
10.0
06/24/1919:36
ND
5.0
06/24/1919:36
ND
1.0
06/24/1919:36
ND
5.0
06/24/1919:36
ND
50.0
06/24/1919:36
ND
5.0
06/24/1919:36
ND
5.0
06/24/1919:36
ND
10.0
06/24/1919:36
ND
5.0
0612411919:36
ND
5000
06/24/1919:36
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2608851
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits
Arsenic
ug/L
500
462
92
85-115
Barium
ug/L
500
524
105
85-115
Cadmium
ug/L
500
494
99
85-115
Chromium
ug/L
500
521
104
85-115
Iron
ug/L
5000
4830
97
85-115
Lead
ug/L
500
475
95
85-115
Manganese
ug/L
500
478
96
85-115
Selenium
ug/L
500
477
95
85-115
Silver
ug/L
250
254
102
85-115
Sodium
ug/L
5000
4830J
97
85-115
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2608852
2608853
MS
MSD
92432889001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
478
481
95
96
70-130
1
Barium
ug/L
6.2
500
500
524
533
104
105
70-130
2
Cadmium
ug/L
ND
500
500
508
514
101
103
70-130
1
Chromium
ug/L
ND
500
500
521
529
104
106
70-130
2
Iron
ug/L
NO
5000
5000
4770
4880
95
98
70-130
2
Lead
ug/L
ND
500
500
480
488
96
97
70-130
2
Manganese
ug/L
ND
500
500
476
486
95
97
70-130
2
Selenium
ug/L
ND
500
500
520
529
104
106
70-130
2
Silver
ug/L
ND
250
250
257
259
103
104
70-130
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 23

aceAnalytical®
wwxpacalabs.cnm
QUALITY CONTROL DATA
Project: MWs 6/12119
Pace Project No.: 92432959
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MA FRIX SPIKE & MATRIX SPIKE DUPLICATE: 2608852 2608853
MS MSD
92432889001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD Qua[
Sodium ug/L ND 5000 5000 9050 9140 96 98 70-130 1
]vIAI KIA JPIKE & MATRIX SPIKE DUPLICATE:
2608854
MS
92433959007
Spike
Parameter
Units
Result
Conc.
Arsenic
ug/L
ND
500
Barium
ug/L
ND
500
Cadmium
ug/L
ND
500
Chromium
ug/L
ND
500
Iron
ug/L
ND
5000
Lead
ug/L
ND
500
Manganese
ug/L
ND
500
Selenium
ug/L
ND
500
Silver
- ug/L
ND
250
Sodium
ug/L
62200
5000
2608855
MSD
Spike
MS
MSD
MS
MSD
% Rae
Conc.
Result
Result
% Rae
% Rec
Limits
RPD
500
486
483
97
96
70-130
1
500
523
527
104
105
70-130
1
500
506
506
101
101
70-130
0
600
523
630
105
106
70-130
1
5000
4820
4850
96
97
70-130
0
500
478
478
95
95
70-130
0
500
476
477
95
95
70-130
0
500
510
508
102
102
70-130
0
250
258
258
103
103
70-130
0
5000
67000
68400
94
122
70-130
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, L-C.
Qual
Page 10 of 23

ZaceAnalytical®
...pacolabs.oan
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
We oalcn: 4dZtiy9 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92432959003, 92432959004
METHOD BLANK: 2609749 Matrix: Water
Associated Lab Samples: 92432959003, 92432959004
Parameter
Units
Arsenic
ug/L
Barium
ug/L
Cadmium
ug/L
Chromium
ug/L
Iron
ug/L
Lead
ug/L
Manganese
ug/L
Selenium
ug/L
Silver
ug/L
Sodium
ug/L
Blank
Result
Reporting
Limit
Analyzed
NO
10.0
06/23/19 01:54
ND
5.0
06/23/19 01:54
ND
1.0
06/2311901:54
NO
5.0
06/23/19 01:54
ND
50.0
06/23/19 01:54
NO
5.0
06/23/19 01:54
ND
5.0
06/23/19 01:54
NO
10.0
06/23/19 01:54
ND
5.0
06/23/19 01:54
NO
5000
06/24/19 00:36
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2609750
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Arsenic
ug/L
500
454
91
85-115
Barium
ug/L
500
484
97
85-116
Cadmium
ug/L
500
477
95
85-115
Chromium
ug/L
500
486
97
85-115
Iron
ug/L
5000
4880
98
85-115
Lead
ug/L
500
472
94
85-115
Manganese
ug/L
500
481
96
85-115
Selenium
ug/L
500
473
95
85-115
Silver
ug/L
250
246
99
85-115
Sodium
ug/L
5000
4790J
96
85-115
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2609751
2609752
MS
MSD
92432800001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
499
502
99
99
70-130
0
Barium
ug/L
32.3
500
500
530
535
100
101
70-130
1
Cadmium
ug/L
NO
500
500
481
487
96
97
70-130
1
Chromium
ug/L
NO
500
500
498
504
99
100
70-130
1
Iron
ug/L
4320
5000
5000
9180
9410
97
102
70-130
2
Lead
ug/L
9.6
500
500
488
494
96
97
70-130
1
Manganese
ug/L
644
500
500
1140
1150
100
102
70-130
1
Selenium
ug/L
ND
500
500
538
541
108
108
70-130
1
Silver
ug/L
NO
250
250
259
262
104
105
70-130
1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 23

ace Analytical
www.pace/aba.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2609751 2609752
MS MSD
92432800001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Dual
Sodium ug/L 323000 5000 5000 336000 336000 254 252 70-130 0 E
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2609753
MS
92432972001 Spike
Parameter Units Result Cone.
MSD
Spike
Cone.
2609764
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
NO
500
500
473
465
94
93
70-130
2
Barium
ug/L
10.9
500
500
506
499
99
98
70-130
1
Cadmium
ug/L
ND
500
500
489
479
98
96
70-130
2
Chromium
ug/L
NO
500
500
496
487
99
97
70-130
2
Iron
ug/L
269
5000
5000
5210
5120
99
97
70-130
2
Lead
ug/L
NO
600
500
482
473
96
95
70-130
2
Manganese
ug/L
6.3
500
500
497
488
98
96
70-130
2
Selenium
ug/L
ND
600
500
526
515
105
103
70-130
2
Silver
ug/L
NO
250
250
254
250
101
100
70-130
1
Sodium
ug/L
NO
5000
5000
5830
5730
99
97
70-130
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 23

aceAnalytical
v...pacelabs.00m
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 481769
Analysis Method: SM 254OC-2011
QC Batch Method: SM 2540C-2011
Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92432959001, 92432959002
METHOD BLANK: 2605361
Matrix: Water
Associated Lab Samples: 92432959001, 92432959002
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND 25.0 06/18/19 13:16
LABORATORY CONTROL SAMPLE:
2605362
Spike LCS 1-CS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 250 100 90-110
SAMPLE DUPLICATE: 2605363
92432663040 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
490 494 1
SAMPLE DUPLICATE: 2605364
92432959001 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
37.0 34.0 8 D6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, L-C. Page 13 of 23

•aceAnalyfical
xvnvpacelabs.com
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 481966
Analysis Method: SM 254OC-2011
QC Batch Method: SM 2540C-2011
Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92432959003, 92432959004
METHOD BLANK: 2606270
Matrix: Water
Associated Lab Samples: 92432959003, 92432959004
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND 25.0 06/19/19 03:15
LABORATORY CONTROL SAMPLE:
2606271
Spike LCS LIDS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 264 105 90-110
SAMPLE DUPLICATE: 2606272
92433085004 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
76.0 76.0 0
SAMPLE DUPLICATE: 2606273
92433165004 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
561 555 1
Results presented on this page are In the units Intl icated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, L-C. Page 14 of 23

aceAnalytical
..pace/abs.com
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 481352 Analysis Method: EPA
300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
METHOD BLANK: 2603669 Matrix: Water
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
Blank Reporting
Parameter Units Result Limit
Analyzed Qualifiers
Sulfate mg/L ND 1.0
06/15/1912:41
LABORATORY CONTROL SAMPLE: 2603670
Spike LCS
LCS % Rec
Parameter Units Cone. Result
% Rec Limits Qualifiers
Sulfate mg/L 50 52.9
106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2603671 2603672
MS MSD
92433166001 Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result Cone. Cone. Result
Result e/ Rec % Rec
Limits RPD Qua[
Sulfate mg/L <0.50 50 50 55.0
54.9 109 109
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2603673 2603674
MS MSD
92432935006 Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qua]
Sulfate mg/L 6.2 50 50 57.9
59.5 103 106
90-110 3
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the wrttten consent of Pace Analytical Services, L-C.
Page 15 of 23

•aceAnalytical
..pe.fabecom
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 482425 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
METHOD BLANK: 2608510 Matrix: Water
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
Blank Reporting
Parameter Units Result Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/L NO 0.10
06/2011921:00
LABORATORY CONTROL SAMPLE: 2608511
Spike LCS
LCS % Rec
Parameter Units Cone. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 - 4.7
93 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2608512 2608513
MS MOD
92432874001 Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L 0.96 5 5 5.6
5.7 93 94
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2608514 2608515
MS MSD
92432887002 Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L 15.7 5 5 20.1
20.1 88 88
90-110 0 Mt
p1�M,
AUG 05 2019
Water Quality Regional Operations
Asheville Regional Office
Results presented on this page are In the units indicated by the "Units" column except where an alternate un It is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, -LC.
Page 16 of 23

aceAnalytical
www.pacelabs son
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 481000
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92432959001, 92432959002
METHOD BLANK: 2601901
Matrix: Water
Associated Lab Samples: 92432959001, 92432959002
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.040 06/13/19 15:11
LABORATORY CONTROL SAMPLE: 2601902
Spike LCS 1-CS % Rae
Parameter Units
Conc. Result % Rae Limits Qualifiers
Nitrogen, Nitrate mg/L
1.5 1.5 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2601903
2601904
MS MSD
92432934002
Spike Spike MS MSD MS MSD % Rae
Parameter Units Result
Cone. Cone. Result Result % Rae % Rae Limits RPD Qua]
Nitrogen, Nitrate mg/L 0.22
1.6 1.5 1.7 1.7 98 99 90-110 1
Results presented on this page are in the units Indicated by the "units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 23

aceAnalXical
x ww.pa.labeoem
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 481132
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92432959003, 92432959004
METHOD BLANK: 2602653
Matrix: Water
Associated Lab Samples: 92432959003. 92432959004
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.040 06/14/19 10:24
LABORATORY CONTROL SAMPLE: 2602654
Spike LCS LCS % Rec
Parameter Units
Cone. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
1.5 1.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2602655 2602656
MS MSD
92432959003
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Cone. Cone. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.48
1.5 1.5 1.9 1.9 95 95 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, L-C.
Page 18 of 23

aceAnalyiical®
wrtwpae,1abs...
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 481983 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500
Chloride
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
METHOD BLANK: 2606306 Matrix: Water
Associated Lab Samples: 92432959001, 92432959002, 92432959003, 92432959004
Blank Reporting
Parameter Units Result Limit
Analyzed
Qualifiers
Chloride mg/L ND 1.0
06/19/1913:39
LABORATORY CONTROL SAMPLE: 2606307
Spike LCS
LCS % Rec
Parameter Units Cone. Result
% Rec Limits
Qualifiers
Chloride mg/L 20 20.6
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2606308 2606309
MS MSD
92433233001 Spike Spike MS
MSD MS
MSD % Rec
Parameter Units Result Cone. Cone. Result
Result %Rec
%Rec Limits RPD Qual
Chloride mg/L 11.1 10 10 21.2
21.2 101
101 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2606310 2606311
MS MSD
92433233002 Spike Spike MS
MSD MS
MSD % Rec
Parameter Units Result Cone. Cone. Result
Result % Rec
% Rec Limits RPD Qual
Chloride mg/L 7.4 10 10 18.0
17.8 106
104 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 23

.aceAnalyiical
wan:pacelabs.00m
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 550762
Analysis Method: SM
5310B
QC Balch Method: SM 5310B
Analysis Description: 5310B TOC
Associated Lab Samples: 92432959001
METHOD BLANK: 2986779
Matrix: Water
Associated Lab Samples: 92432959001
Blank Reporting
Parameter Units
Result Limit
Analyzed
Qualifiers
Total Organic Carbon mg/L
ND 1.0
07/02/19 14:23
LABORATORY CONTROL SAMPLE: 2986780
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits
Qualifiers
Total Organic Carbon mg/L
20 19.6
98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986781 2986782
MS MSD
20110000001
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result %Rec
%Rec
Limits RPD Qual
Total Organic Carbon mg/L 2.3
20 20 22.2
22.3 99
100
80-120 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986783 2986784
MS MSD
35476968003
Spike Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Total Organic Carbon mg/L 8.1
20 20 28.4
28.3 101
101
80-120 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 23

aceAnalytical
wmvpa.1abs.00m
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MWs 6/12/19
Pace Project No.: 92432959
QC Batch: 550763 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: 5310B TOC
Associated Lab Samples: 92432959002, 92432959003, 92432959004
METHOD BLANK: 2986791 Matrix: Water
Associated Lab Samples: 92432959002, 92432959003, 92432959004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 07/02/19 21:47
LABORATORY CONTROL SAMPLE: 2986792
Spike 1-CS LCS % Rae
Parameter Units Cone. Result % Rae Limits Qualifiers
Total Organic Carbon mg/1- 20 19.3 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986793
2986794
MS
MSD
92432959002 Spike
Spike
MS
MSD MS MSD % Rae
Parameter Units Result Cone.
Cone.
Result
Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 1.6 20
20
20.7
20.6 96 95 80-120 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2986795 2986796
MS MSD
2620193009 Spike Spike MS MSD MS MSD % Rae
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 2.9 20 20 22.0 22.1 95 96 80-120 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 23

Pace Analytical Services, LLC
® 2225 Riverside Dr.
aceAnalytica/ Asheville, NC 28804
wmvpawlbs.w.
(828)2547176
QUALIFIERS
Project: MWs 6/12/19
Pace Project No.: 92432959
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H1 Analysis conducted outside the EPA method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/03/2019 05:20 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 23

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
MWs 6/12/19
92432959
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92432959001
MW-05
92432959002
MW-06
92432959003
MW-07
92432959004
1AW-08
92432959001
MW-05
EPA 200.7 Rev 4.4 1994
482508
EPA 200.7 Rev 4.4 1994
482712
92432959002
MW-06
EPA 200.7 Rev 4.4 1994
482508
EPA 200.7 Rev 4.4 1994
482712
92432959003
M W-07
EPA 200.7 Rev 4.4 1994
482699
EPA 200.7 Rev 4.4 1994
482713
92432959004
MW-08
EPA 200.7 Rev 4.4 1994
482699
EPA 200.7 Rev 4.4 1994
482713
92432959001
MW-05
EPA 245.1 Rev 3.0 1994
481574
EPA 245.1 Rev 3.0 1994
481595
92432959002
MW-06
EPA 245.1 Rev 3.0 1994
481574
EPA 245.1 Rev 3.0 1994
481595
92432959003
MW-07
EPA 245.1 Rev 3.0 1994
481574
EPA 245.1 Rev 3.0 1994
481595
92432959004
MW-08
EPA 245.1 Rev 3.0 1994
481574
EPA 245.1 Rev 3.0 1994
481595
92432959001
MW-05
SM 2540C-2011
481769
92432959002
MW-06
SM 254OC-2011
481769
92432959003
MW-07
SM 254OC-2011
481966
92432959004
MW-08
SM 254OC-2011
481966
92432959001
MW-05
EPA 300.0 Rev 2.1 1993
481352
92432959002
MW-06
EPA 300.0 Rev 2.1 1993
481352
92432959003
M W-07
EPA 300.0 Rev 2.1 1993
481352
92432959004
MW-08
EPA 300.0 Rev 2.1 1993
481352
92432959001
MW-05
EPA 350.1 Rev 2.0 1993
482425
92432959002
M W-06
EPA 350.1 Rev 2.0 1993
482425
92432959003
M W-07
EPA 350.1 Rev 2.0 1993
482425
92432959004
MW-08
EPA 350.1 Rev 2.0 1993
482425
92432959001
M W-05
EPA 353.2 Rev 2.0 1993
481000
92432959002
MW-06
EPA 353.2 Rev 2.0 1993
481000
92432959003
MW-07
EPA 353.2 Rev 2.0 1993
481132
92432959004
MW-08
EPA 353.2 Rev 2.0 1993
481132
92432959001
MW-05
SM 4500-CI-E-2011
481983
92432959002
MW-06
SM 4500-CI-E-2011
481983
92432959003
MW-07
SM 4500-CI-E-2011
481983
92432959004
MW-08
SM 4500-CI-E-2011
481983
92432959001
MW-05
SM 5310B
550762
92432959002
MW-06
SM 5310B
550763
92432959003
MW-07
SM 5310B
550763
92432959004
MW-08
SM 53108
550763
Date: 07/03/2019 05:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 23

Document Name:
Document Revised: February 7, 2018
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
aCBf�Ctdlj/f(CB��
Document No.:
- Issuing Authority:
r
F-CAR-CS-033-Rev.06
Pace Carolinas quality Office
Laboratory receiving samples:
❑ Huntersville ❑ Raleigh[]
Asheville X Eden[_ Greenwood
Client Name: - L /-� WNO# ; 9,2432959
/ il'TY7P0}, l Gty1C'WPfLcI, 4/i5¢I^tC# f
Courier: Fed Ex ❑UPS ❑USPS ❑Client III II II II F II II�III III
❑ Commercial Pace ❑Other._ 924132959 !!
Custody Seal Present? ❑Yes KNo Seals Intact? ❑Yes ONo
Date/Initials Person Examining Contents;
Packing Material: []Bubble Wrap PrBubble Bags ❑None ❑ Other Biological Tissue
��� Frozen?
Thermometer: Wet ❑Blue ❑None ❑Yes ❑No ZN/A
`r'� / Type of ice: )
SIR Gun ID: iY
Cooler Temp (°C): — A ... Correction Factor: Add/Subtract ('C) _0
//tt Temp should be above freezing to 6°C
Cooler Temp Corrected (°C): t 0 ❑Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Soil (IV N/A, water sample) -
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally,
r-tvo° 141m„ - includine Hawaii and Puerto Rico)? []Yes IMNo
Comments/Discrepancy:
Chain of Custody Present?
Wyss
❑No
❑N/A
1.
Samples Arrived within Hold Time?
AYes
❑No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
Myes
[-]No
❑N/A
3.
Rush Turn Around Time Requested?
[]Yes
No
❑N/A
4.
Sufficient Volume?
JaYes
[]No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
®Yes
Yes
❑No
❑No
[]N/A
❑N/A
6.
Containers Intact?
IMYes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
Elmo
MN/A
8.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
yAoYes
1
❑No
❑N/A
9.
Headspace in VOAVials(>5-6mm)?
[-]Yes
No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
Dyes
WNo
XNG
❑N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: - Date/Time: _
Project Manager SCURF Review: ✓i`��'_
Project Manager SRF Review: J
Field Data Required? tdlI es []NO
Date: �11
Date:
r

Document Name:
Document Revised: February 7, 2018
a
��ceAnaljdical
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
F-CAR-CS-033-Rev.06
Issuing Authority:
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project#t WO# 0 92495
PPE: UP Due Date: 06/27/19
CLIENT: 93—FISD
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Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot N
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.

ITEM #
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75
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S♦/

Document Name: Document Revised: February 7, 2
Condition Upon Receipt(SCUR) Page 1 of 2
Document No.: Issuing Authority:
rornnnac nnality Office
Laboratory receiving samples:
Asheville Q Eden❑ Greenwood ❑ Huntersville❑ Raleigh❑ Mechanicsville❑
r Client Name: - W®# : 924032959
(�
Elm
� .'� � 1 Project PM: LJP Due Date: 06/27/19
Courier: Fed Ex ❑UPS ❑USPS ❑Client
❑Commercial ,Pace ❑Other:_ CLIENT: 93—PISD
Custody Seal Present? ❑Yes �o Seals Intact? ❑Yes ONo
' ,,__..,,�� Date/Initials Person Examining Contents;
Packing Material: []Bubble wrap Bubble Bags ❑None ❑ Other Biological Tissue Frozen?
❑Yes [:]No [PN/A
Thermometey � -2 tl�6 Type of Ice: [ Net ❑Blue ❑None
IR Gun ID: �j j�
Cooler Temp (°C): 5� 7 fJ 7Correction Factor: Add/Subtract (°C) D, Temp should be above freezing to VC
Cooler Temp Corrected(°C): ! (]Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Sail (JN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
_A. Puerto Ricol?rlYes ❑No
❑Yes LINO
,,.,.,w...e .._.. _.
Comments/Discrepancy:
1.
Chain of Custody Present?. Yes ❑No ❑N/A
Samples Arrived within Hold Time?
Yes
[]No
❑N/A
2.
Short Hold Time Analysis(02 hr.)?
Yes
❑No
[]N/A
3.
4.
Rush Turn Around Time Requested? ❑Yes No ❑N/A
Sufficient Volume?
lYes,
❑No
❑N/A
5.
Correct Containers Used?
Yes
❑No
❑N/A
6.
-Pace Containers Used?
Yes
❑No
❑N/A
Containers intact?
I jyes
❑,/No
❑N/A
7.
Dissolved analysis: Samples Field Filtered? ElvesGIN
-
❑N/A
8.
Sample Labels Match COC?
3Yes
❑No
❑N/A
9.
,r,,,f
YF� /
-Includes Date/Time/ID/Analysis
Matrix:
_
Headspace in VOA Vials (>5-6mm)?
❑Yes
No
. ❑N/A
10.
Trip Blank Present?
[-]Yes
IdNo
❑N/A
11.
Trip Blank Custody Seals Present?
Dyes
❑No
/A
COMMENTS/SAMPLE DISCREPANCY
Lot
CLIENT
Field Data Required? LjYes„'JNo
Person contacted: Date/Time: _
r�
1 l
Project Manager SCURF Review: Date: I
Project Manager SRF Review: Date: l

Document Name:
Document No.:
TO
page 1 of 2
Issuing Authority:
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLH9
**Bottom half of box is to list number of bottle
Project # : 92432959
pM: L.lp Due Date: D6/27/flu
CLIENT: 93-1`10
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pH Adjustment Log for Preserved $aples
pH upon receipt Date preservation adjusted Tlme preeua6on Amount
adhted
Note; Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form vhhe senttothe
Out of hold, incorrect preservative, out of temp, incorrect containers.
added
Loth
tl.e.

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