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HomeMy WebLinkAboutNC0024911_Groundwater Monitoring Report January 2019_20190205o \,LPN SEWFgq�� s Q- 9 CCO,yB�e��i,I,POP F COUNTY. NOP"O Metropolitan Sewerage istrict OF BUNCOMBE COUNTY, NORTH CAROLINA February 5, 2019 J ^' z 0 �- N O h Division of Water Resources LL Cq L w Information Processing Unit m 1617 Mail Service Center Raleigh, NC 276994617 0 k Information Processing Unit: Please find attached Groundwater Quality monitoring reports for January 2019 from Metropolitan Sewerage District of Buncombe County (MSD). These monitoring report forms have additional identification on the well ID line, MW-1R, MW-2R, MW-3 and MW-4, for ease and reference. Monitoring Well-1R exceeded allowable limits for iron and pH. Monitoring Well-213 exceeded allowable limits for pH and manganese. Monitoring Well-3 exceeded allowable limits for pH. The down gradient Monitoring Well-4 exceeded allowable limits for ammonia, iron, and manganese. The MSD is in communication with the Asheville Regional Operations section regarding these sample results and groundwater standards. Please do hesitate to contact Roger Edwards at 828-225-8224 with questions regarding the attached reports. Sincerely Peter C. Weed Director of Treatment MSD of Buncombe County -Protecting Our Natural Resources- FEB 19 P019 .-,•,�n���;�±Ions 2028 RIVERSIDE DRIVE, ASHEVILLE, NORTH CAROLINA 28804 TELEPHONE: (828)254-9646 FAX: (828)254-3299 WE13SITE: www.msdbc.org GW-59A COMPLIANCE REPORT FORM Permit # NCO024911 (Submit one each monitoring period with GW-59 forms.) 1 Enter date monitoring results were due. (_02128/19_) Will this monitoring report (GW-59 and GW-59A) Y be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YESd NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? Ifthe answer is "Yes", contact the Regional Officefor guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section B. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: MW-1R MW-2 MW-3 MW-4 Iron 438 pH 6.3 pH 5.6 Iron 30,200 pH 6.0 Manganese 86.3 Manganese 6,560 Ammonia 2.2 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is WO; skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). MWAR Fecal PH Iron Manganese MW-2R off Manganese MW-3 Fecal off Iron MW4 Ammonia off Manaanese Iron 10/24/17 370 5.6 10/24/17 6.4 10/24/17 5.3 10124/17 1.7 6.4 10/31/17 2 1113/17 2.3 10/22/17 44 10/31/16 2.8 1122/18 5,9 1/22/18 5.5 1/22/8 1.5 6/181 8 34 5.7 611N18 6.3 6/18/18 2.0 5.5 6/18H8 1.7 10/08/18 367 62.4 10/08/18 6.2 1100 1010818 5.5 466 10/08/18 1.9 6A 2340 2510 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES O If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. This is being discussed by the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? if the answer to question 7 is "YES" describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be reauired to determine the impact the waste disposal system is havina at the review and compliance boundaries surrounding this facility, Failure to do so may subject the permittee to a Notice of Violation, fines. and/or penalties, This is being discussed by the Regional Office. 8 The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form. 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Q Z> E E o `a O z 3 z ti rn O r Q 7 d O g J z '6 a o �° $ � w=� m E m O QQ 0 U o m d Q-'O Q m v m c p _ m J - n Q °' N m m o E mQmQ m m C� U LL LL O. LL U zi N 2i ❑ > N J 0 6 e m O O C O E U Q 0 r N w N K ElWnalXicalo wwwpa.labs... Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 January 22, 2019 Mr. Roger Edwards Metropolitan Sewerage District RE: Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 Dear Mr. Edwards: Enclosed are the analytical results for sample(s) received by the laboratory on January 07, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, � .<' o _ Lord Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Ms. Shannon Bergeron, Metropolitan Sewerage District Ryan Dyson, MSD of Buncombe County, NC Ms. Sheila Kilby, Metropolitan Sewerage District Mr. Chad Ledford, Metropolitan Sewerage District Cassandra McKnight, MSD of Buncombe County, NC Mr. Alan Taylor, Metropolitan Sewerage District REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. viceAnalytical w vpaaelabs.ccm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Monitoring Wells 117/18 Pace Project No.: 92413019 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification #: 40 Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001 Massachusetts Certification #: M-NC030 VirginiaNELAP Certification #: 460222 North Carolina Drinking Water Certification #: 37712 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. ceAnalytical wvnvpecelabsmm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Pace Project No.: Monitoring Wells 1/7/18 92413019 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92413019001 MW-1R EPA 200.7 Rev 4.4 1994 DS 10 PASI-A EPA 245.1 Rev 3.0 1994 RDT 1 PASI-A SM 2540C-2011 MJP 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.01993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 GC i PASI-A SM 531OB-2011 ECH 1 PASI-A 92413019002 MW-2R EPA 200.7 Rev 4.41994 DS 10 PASI-A EPA 245.1 Rev 3.0 1994 RDT 1 PASI-A SM 2540C-2011 MJP 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 5310B-2011 ECH 1 PASI-A 92413019003 MW-3 EPA 200.7 Rev 4.4 1994 DS 10 PASI-A EPA 245.1 Rev 3.01994 RDT 1 PASI-A SM 2540C-2011 MJP 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 531 OB-2011 ECH 1 PASI-A 92413019004 MW-4 EPA 200.7 Rev 4.41994 DS 10 PASI-A EPA 245.1 Rev 3.01994 RDT 1 PASI-A SM 2540C-2011 MJP 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 GC 1 PASI-A SM 5310B-2011 ECH 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. ace Analytical xxw.paie/abs.cvm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 Sample: MW-1R Lab ID: 92413019001 Collected: 01/07/1912:00 Received: 01107/1915:55 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Mark 1 01/22/19 09:43 Swann Collected Date 1/7/19 1 01/22/19 09:43 Collected Time 12:00 1 01/22/19 09:43 pH 6.0 Std. Units 0.10 1 01/22/19 09:43 Temperature 11.4 deg C 0.50 1 01/22/19 09:43 Static Water Level 6.37 feet 1 01/22/19 09:43 Specific Conductance 62 umhos/cm 1.0 1 01/22/19 09:43 Odor No odor 1 01/22/19 09:43 Appearance Clear 1 01/22/19 09:43 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Arsenic ND ug/L 10.0 1 01/08/19 01:30 01/08/19 19:42 7440-38-2 Barium 13.6 ug/L 5.0 1 01/08/19 01:30 01/08/19 19:42 7440-39-3 Cadmium ND ug/L 1.0 1 01/08/19 01:30 01/08/19 19:42 7440-43-9 Chromium ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:42 7440-47-3 Iron 438 ug/L 50.0 1 01/08/19 01:30 01/08/19 19:42 7439-89-6 Lead ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:42 7439-92-1 Manganese 16.8 ug/L _ 5.0 1 01/08/19 01:30 01/08/19 19:42 7439-96-5 Selenium ND ug/L 10.0 1 01/08/19 01:30 01/08/19 19:42 7782-49-2 Silver ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:42 7440-22-4 Sodium ND ug/L 5000 1 01/08/19 01:30 01/08/19 19:42 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Mercury ND ug/L 0.20 1 01/08/19 20:26 01/09/19 12:07 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solids 57.0 mg/L 25.0 1 01/09/19 10:22 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 8.0 mg/L 1.0 1 01/08/1918:49 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia ND mg/L 0.10 1 01/10/19 14:14 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 0.21 mg/L 0.020 1 01108/1903:13 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 2.3 mg/L 1.0 1 01/08/1920:58 16887-00-6 5310E TOC Analytical Method: SM 531OB-2011 Total Organic Carbon ND mg/L 1.0 1 01/10/19 05:10 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM - without the written consent of Pace Analytical Services, LLC. ,aceAnaVical w vpacelabs.crom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 Sample: MW-2R Lab ID: 92413019002 Collected: 01/07/1914:00 Received: 01/07/1915:55 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Mark 1 01/22/19 09:44 Swann Collected Date 1/7/19 1 01/22/19 09:44 Collected Time 13:57 1 01/22/19 09:44 pH 6.3 Sid. Units 0.10 1 01/22/19 09:44 Temperature 17.1 deg C 0.50 1 01/22/19 09:44 Static Water Level 5.81 feet 1 01/22/19 09:44 Specific Conductance 461 umhos/cm 1.0 1 01122/1909:44 Odor No odor 1 01/22/19 09:44 Appearance Clear 1 01/22/19 09:44 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Arsenic ND ug/L 10.0 1 01/08/19 01:30 01/08/19 19:45 7440-38-2 Barium 71.5 ug/L 5.0 1 01/08/19 01:30 01/08/19 19:45 7440-39-3 Cadmium NO ug/L 1.0 1 01/08/19 01:30 01/08/19 19:45 7440-43-9 Chromium ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:45 7440-47-3 Iron NO ug/L 50.0 1 01/08/19 01:30 01/08/19 19:45 7439-89-6 Lead NO ug/L 5.0 1 01/08/19 01:30 01/0811919:45 7439-92-1 Manganese 86.3 ug/L 5.0 1 01/08/19 01:30 01/08/19 19:45 7439-96-5 Selenium NO ug/L 10.0 1 01/08/19 01:30 01/08/19 19:45 7782-49-2 Silver NO ug/L 5.0 1 01/08M901:30 01/08/19 19:45 7440.22-4 Sodium 16800 ug/L 5000 1 01/08/19 01:30 01/08/19 19:45 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Mercury ND ug/L 0.20 1 01/08/1920:26 01/09/1912:09 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Total Dissolved Solids 301 mg/L 25.0 1 01/09/19 10:22 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 98.2 mg/L 2.0 2 01/09/19 02:17 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia NO mg/L 0.10 1 01/11/1912:23 7664-41-7 353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 4.7 mg/L 0.040 2 01108/1903:33 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 9.7 mg/L 1.0 1 01/08/1921:01 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Total Organic Carbon NO mg/L 1.0 1 01/10/19 06:00 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: O1/22/2019 09:54 AM without the written consent of Pace Analytical Services, LLC. aceAnaiXical o www.paielabs.cam Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells 117/18 Pace Project No.: 92413019 Sample: MW-3 Lab ID: 92413019003 Collected: 01/07/19 13:25 Received: 01/07/19 15:55 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Mark 1 01/22/19 09:45 Swann Collected Date 117119 1 01/22/19 09:45 Collected Time 13:26 1 01/22/19 09:45 pH 5.6 Std. Units 0.10 1 01/22/19 09:45 Temperature 15.0 deg C 0.50 1 01/22/19 09:45 Static Water Level 60.09 feet 1 01/22/19 09:45 Specific Conductance 48 umhos/cm 1.0 1 01/22/19 09:45 Odor No odor 1 01/22/19 09:45 Appearance Clear 1 01/22/19 09:45 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Arsenic ND ug/L 10.0 1 01/0811901:30 01/08/19 19:48 7440-38-2 Barium 38.3 ug/L 5.0 1 01/08/19 01:30 01/08/19 19:48 7440-39-3 Cadmium ND ug/L 1.0 1 01/0811901:30 01/08/19 19:48 7440-43-9 Chromium ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:48 7440-47-3 Iron 207 ug/L 50.0 1 01/08/19 01:30 01/08/19 19:48 7439-89-6 Lead ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:48 7439-92-1 Manganese 5.1 ug/L 5.0 1 01/08/19 01:30 01/08/19 19:48 7439-96-5 Selenium ND ug/L 10.0 1 01/08/19 01:30 01/0811919:48 7782-49-2 Silver ND ug/L 5.0 1 01/08/19 01:30 01108/1919:48 7440-22-4 Sodium ND ug/L 5000 1 01/08/19 01:30 01/08/19 19:48 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Mercury ND ug/L 0.20 1 01/08/19 20:26 01/09/19 12:12 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Total Dissolved Solids 44.0 mg/L 25.0 1 01/09/19 10:22 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate ND mg/L 1.0 1 01108/1919:20 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia ND mg/L 0.10 1 01/11/19 12:24 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 3.4 mg/L 0.040 2 01/0811903:31 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 2.4 mg/L 1.0 1 01/08/1921:02 16887-00-6 5310E TOC Analytical Method: SM 531OB-2011 Total Organic Carbon ND mg/L 1.0 1 01/10/19 06:11 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, -LC. aceAnalytical w w.pamfaba.mm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 Sample: MW-4 Lab ID: 92413019004 Collected: 01/07/1915:25 Received: 01/07/19 15:55 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Collected By Mark 1 01/22/19 09:53 Swann Collected Date 117/19 1 01/22/19 09:53 Collected Time 15:21 1 01/22/19 09:53 pH 6.6 Std. Units 0.10 1 01/22/19 09:53 Temperature 18.2 deg 0.50 1 01122/1909:53 Static Water Level 9.06 feet 1 01/22/19 09:53 Specific Conductance 753 umhos/cm 1.0 1 01/22/19 09:53 Odor No odor 1 01/22/19 09:53 Appearance Clear 1 01/22M9 09:53 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Arsenic ND ug/L 10.0 1 01/08/19 01:30 01/08/19 19:52 7440-38-2 Barium 93.3 ug/L 5.0 1 01/08/19 01:30 01/08/19 19:52 7440-39-3 Cadmium ND ug/L 1.0 1 01/08/19 01:30 01/08/19 19:62 7440-43-9 Chromium ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:52 7440-47-3 Iron 30200 ug/L 50.0 1 01/08/19 01:30 01/08/19 19:52 7439-89-6 Lead ND ug/L 6.0 1 01/0811901:30 01108/1919:52 7439-92-1 Manganese 6560 ug/L 5.0 1 01/08/19 01:30 01/08/19 19:52 7439-96-5 Selenium ND ug/L 10.0 1 01/0811901:30 01/08/19 19:52 7782-49-2 Silver ND ug/L 5.0 1 01/08/19 01:30 01/08/19 19:52 7440-22-4 Sodium - 21400 ug/L 5000 1 01108/1901:30 01/08/19 19:52 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Mercury ND ug/L 0.20 1 01/08/1920:26 01/09/1912:14 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Total Dissolved Solids 482 mg/L 25.0 1 01/09/19 10:22 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 188 mg/L 4.0 4 01/09/19 02:32 14808-79-8 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Nitrogen, Ammonia 2.2 mg/L 0.10 1 01/11/1912:26 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate ND mg/L 0.020 1 01/08/1903:21 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 10.0 mg/L 1.0 1 01/08/1921:03 16887-00-6 5310B TOC Analytical Method: SM 531OB-2011 Total Organic Carbon 2.3 mg/L 1.0 1 01/10/19 06:22 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical wmvpaie/abs.com Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451293 Analysis Method: EPA 245.1 Rev 3.0 1994 QC Batch Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury Associated Lab Samples: 92413019001,92413019002,92413019003,92413019004 METHOD BLANK: 2468063 Matrix: Water Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 01109/1911:05 LABORATORY CONTROL SAMPLE: 2468064 Spike LCS 1-CS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 103 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2468065 2468066 MS MSD 92412916001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L ND 2.5 2.5 2.3 2.5 91 101 70-130 11 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2468067 2468068 MS MSD 92413007006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L ND 2.5 2.5 1.9 2.1 76 84 70-130 9 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical wwwpacelabs.com Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451165 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 METHOD BLANK: 2467556 Matrix: Water Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Arsenic ug/L NO 10.0 01/08/19 18:24 Barium ug/L NO 5.0 01/08/1918:24 Cadmium ug/L NO 1.0 01/08/1918:24 Chromium ug/L NO 5.0 01/08/1918:24 Iron ug/L NO 50.0 01/08/1918:24 Lead ug/L NO 5.0 01/08/1918:24 Manganese ug/L NO 5.0 01/08/1918:24 Selenium ug/L NO 10.0 01/08/1918:24 Silver ug/L NO 5.0 01/0811918:24 Sodium ug/L NO 5000 01/08/1918:24 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2467557 Units Spike Cone. LIDS Result LCS % Rec % Rec Limits Arsenic ug/L 500 450 90 85-115 Barium ug/L 500 529 106 85-115 Cadmium ug/L 500 480 96 85-115 Chromium ug/L 500 507 101 85-115 Iron ug/L 5000 4930 99 85-115 Lead ug/L 500 466 93 85-115 Manganese ug/L 500 486 97 85-115 Selenium ug/L 500 455 91 85-115 Silver ug/L 250 252 101 85-115 Sodium ug/L 5000 5080 102 85-115 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467558 2467559 MS MSD 92412938001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L NO 500 500 450 455 90 91 70-130 1 Barium ug/L 0.034 500 500 551 548 103 103 70-130 1 mg/L Cadmium ug/L NO 500 500 477 478 95 96 70-130 0 Chromium ug/L NO 500 500 495 496 99 99 70-130 0 Iron ug/L 1.9 5000 5000 6970 6960 101 101 70-130 0 mg/L Lead ug/L NO 500 500 456 458 91 91 70-130 0 Manganese ug/L 0.28 500 500 762 758 96 95 70-130 0 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate un It is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, LLC. ,aceAnalytical www.paielabs;mm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467658 2467559 MS MSD 92412938001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Selenium ug/L ND 500 500 468 467 94 93 70-130 0 Silver ug/L ND 250 250 248 246 99 98 70-130 1 Sodium ug/L ND 5000 5000 10100 9950 104 101 70-130 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467560 2467561 MS MSD 92412967001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 500 500 446 444 89 89 70-130 0 Barium ug/L 17.6 500 600 628 524 102 101 70-130 1 Cadmium ug/L ND 500 500 473 475 95 95 70-130 0 Chromium ug/L ND 500 500 496 495 99 99 70-130 0 Iron ug/L 0.096 5000 5000 4900 4870 96 96 70-130 1 mg/L Lead ug/L ND 500 500 455 454 91 90 70-130 0 Manganese ug/L 91.0 500 500 566 562 95 94 70-130 1 Selenium ug/L ND 500 500 466 461 93 92 70-130 1 Silver ug/L ND 250 250 248 248 99 99 70-130 0 Sodium ug/L 9060 5000 5000 14000 13800 99 95 70-130 1 Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, LLC. aceAnalytical wNw.pecelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451438 Analysis Method: SM 254OC-2011 QC Batch Method: SM 254OC-2011 Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 METHOD BLANK: 2468626 Matrix: Water Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/1- ND 25.0 01/09/19 10:21 LABORATORY CONTROL SAMPLE: 2468627 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 251 252 101 90-110 SAMPLE DUPLICATE: 2468628 92413007003 Cup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/1- 72.0 63.0 13 D6 SAMPLE DUPLICATE: 2468629 92413030001 Dup Parameter Units Result Result RPD Qualifers Total Dissolved Solids mg/L 134 139 4 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, LLC. , .ace Analytical® wmvpace/abs.mm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451155 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 METHOD BLANK: 2467530 Matrix: Water Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L ND 1.0 01/08/1911:19 LABORATORY CONTROL SAMPLE: 2467531 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Sulfate mg/L 50 52.3 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467532 2467533 MS MSD 92412916001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 1900 50 50 2060 2070 313 332 90-110 0 M6 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467534 2467535 MS MSD 92413007007 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 4.0 50 50 55.8 56.4 104 105 90-110 1 Results presented on this page are in the units Indicated by the "units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, L-C. aceAnalytical w wpacefabs.oam Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451682 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92413019001 METHOD BLANK: 2469792 Associated Lab Samples: 92413019001 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 2469793 Parameter Units Nitrogen, Ammonia mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 01/10/1913:19 Spike LCS LCS % Rae Cone. Result % Rae Limits Qualifiers 5 5.0 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2469794 MS 92413121001 Spike Parameter Units Result Cone. Nitrogen, Ammonia mg/L ND 5 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2469796 MS 92413174001 Spike Parameter Units Result Cone. Nitrogen, Ammonia mg/L ND 5 2469795 MSD Spike MS MSD MS MSD % Rae Cone. Result Result a% Rec % Rae Limits RPD Qual 5 6.3 5.3 104 104 90-110 0 2469797 MSD Spike MS MSD MS MSD % Rae Cone. Result Result e% Rae % Rae Limits RPD 5 5.2 5.2 103 103 90-110 0 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, L-C. Qual ,aceAnalytical / v ..➢ecalsba.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451918 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Associated Lab Samples: 92413019002, 92413019003, 92413019004 METHOD BLANK: 2471060 Matrix: Water Associated Lab Samples: 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 01/11/1911:56 LABORATORY CONTROL SAMPLE: 2471061 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.1 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2471062 2471063 MS MSD 92413308002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 3.4 5 5 8.5 8.5 101 101 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2471064 2471065 MS MSD 92413333001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 2.4 5 5 7.4 7.4 101 100 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, I.I.C. aceAnalyiical e www.pacelabe.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NO 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451169 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 METHOD BLANK: 2467571 Matrix: Water Associated Lab Samples: 92413019001. 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 01/08/19 03:09 LABORATORY CONTROL SAMPLE: 2467572 Spike LCS LCS % Rec Parameter Units Cone. Result %Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.4 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467573 2467574 MS MSD 92413019001 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone, Result Result % Rae % Rae Limits RPD Qual Nitrogen, Nitrate mg/L 0.21 1.5 1.6 2.0 2.0 119 120 90-110 1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, L-C. aceAnalytical wnwpacelabs.mm Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 QC Batch: 451345 Analysis Method: SM 4500-CI-E-2011 QC Balch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 METHOD BLANK: 2468349 Matrix: Water Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L NO 1.0 01/08/1920:41 LABORATORY CONTROL SAMPLE: 2468350 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chloride mg/L 20 19.0 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2468351 2468352 MS MSD 92412576004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone, Cone. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 15.0 10 10 25.8 25.8 108 108 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2468353 2468354 MS MSD 92413019001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 2.3 10 10 12.3 12.4 100 100 90-110 0 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical services, LLC. ace Analytical wewpacelabe.com Pace Analytical Services, LLC 2225 Riverside Or, Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Monitoring Wells 1/7118 Pace Project No.: 92413019 QC Batch: 451510 Analysis Method: SM 531OB-2011 QC Batch Method: SM 531OB-2011 Analysis Description: 5310B TOC Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 METHOD BLANK: 2469020 Matrix: Water Associated Lab Samples: 92413019001, 92413019002, 92413019003, 92413019004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 01/10/19 01:10 LABORATORY CONTROL SAMPLE: 2469021 Spike LCS LCS % Rae Parameter Units Cone. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 23.7 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2469022 2469023 MS MSD 92413030013 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result % Rec % Rae Limits RPD Qual Total Organic Carbon mg/L 0.54J 25 25 24.1 24.2 94 95 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2469024 2469025 MS MSD 92412988002 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual Total Organic Carbon mg/L ND 25 25 23.3 23.4 93 93 90-110 0 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date; 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, L-C. aceAnalytrcal® w.uw.pacelabs.wm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: Monitoring Wells 1/7118 Pace Project No.: 92413019 DEFINITIONS DF - Dilution Factor, If reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte Is a combined concentration. Pace Analytical Is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST -A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/22/2019 09:54 AM without the written consent of Pace Analytical Services, LLC. aC Analytical o wwwp.cerabs=. Pace Analytical Services, LLC 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Monitoring Wells 1/7/18 Pace Project No.: 92413019 Lab ID 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 92413019001 92413019002 92413019003 92413019004 Sample ID MWAR MW-2R M W-3 M W-4 MWAR MW-2R M W-3 M W-4 M W-1 R MW-2R M W-3 MW-4 M W-1 R MW-2R MW-3 M W-4 M W-1 R M W-2R M W-3 M W-4 M W-1 R MW-2R M W-3 M W-4 M W-1 R MW-2R M W-3 MW-4 M W-1 R MW-2R M W-3 M W-4 M W-1 R M W-2R M W-3 M W-4 Data: O1/22/2019 09:54 AM QC Batch Method EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 245.1 Rev 3.0 1994 EPA 245.1 Rev 3.0 1994 EPA 245.1 Rev 3.0 1994 EPA 245.1 Rev 3.0 1994 SM 2540C-2011 SM 2540C-2011 SM 2540C-2011 SM 2540C-2011 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 5310B-2011 SM 5310B-2011 SM 5310B-2011 SM 5310B-2011 QC Batch 451165 451165 451165 451165 451293 451293 451293 451293 451438 451438 451438 451438 451155 451155 451155 451155 451682 451918 451918 451918 451169 451169 451169 451169 451346 451345 451345 451345 451510 451510 451510 451510 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 245.1 Rev 3.0 1994 EPA 245.1 Rev 3.0 1994 EPA 245.1 Rev 3.0 1994 EPA 245.1 Rev 3.0 1994 Analytical Batch 451178 451178 451178 451178 451359 451359 451359 451359 tj p w w J d, U A w N ITEM # A m 3 O A m w » n 10 0 0 @ '3 y 2 vy in m = C\r 0 C y1 Z O 3 e.- Q V J m t m 3 ) � N C s HP�o.c y,ro >� O v v1, nA�S� m K rl 4 v V A 0 p n A F N g a e :S ti a B'0 2 2 y� 1 OIn 3 i 3 O m v N MATRIXCODE (see valid codes to left) Z SAMPLE TYPE (G=GRAB C=COMP) ~ o rlz� In od y D T_ y o ym oy l N 3 r O m ml m r N A A i m t __ s a R 1 '� ;✓ > m p 3 D .� .P m 8 m Z 0 ad Q G m A z p "p SAMPLE TEMP AT COLLECTION m o y S # OF CONTAINERS $ s R 3 4Lnin V d p Unpreserved m H,SO, u z o^ n p HNO3 CDm B 3 — '— HCI m NaOH m 0 NaiS103 y \ m 9 Methanol Other D t � r jAnalysis Test j v/ N J 3 D N �'-a Sitr✓O A )( '� r✓28tu." 0'o � O n o m r s o to k< '� T, o ,✓ Cam— a . a m c LL Jo. d y 1 In y k T ti Ny ✓ '^ y y n -mi o D In jolt. m m p i In A G) 2 Z 9 T s O Z 0 _ Temp in°C O Residual Chlorine (Y/N) � y In N Received on Ice (Y/N) al N.) •-� v is is n V JV^ O o W Custody Sealed Cooler (Y/N) O q C3 Q © o O w P ,_ o w m x W N) y z CG Samples Intact w c y (V/N) I7 In .m � m L✓------------ N w- c O J 1 9 M — J a 3 n 0 N C � a N ( n v h "a J � � N • ^, i O it � a N y O V p fJ U l• I W CD CD O D 3 m o• m CA EL { ® n 3