Riverbend Steam Station (12)

,t I _i!
Page 31 of 38
Analytical Laboratory
Please print or type in the unshaded areas
EPA ID Number (copy from item I of Form 1)
Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
Form
2F
NPDES
United States Environmental Protection Agency
Washington, DC 20460
N M Application for Permit to Discharge Storm Water
1K7LM Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average 28 6 hours per application, including time for reviewing instructions, searching existing data
sources, gathering and maintaining the data needed, and completing and reviewing the collection of information Send comments regarding the burden estimate,
any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to Chief,
Information Policy Branch, PM-223, U S Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Management and Budget Washington, DC 20503
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water
A Outfall Number
list
B Latitude
C Longitude
D Receiving Water
name
SW 002
II. Improvements
A Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or
operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, std ulations, court orders, and grant or loan conditions
1 Identification of Conditions,
Agreements, Etc
2 Affected Outfalls
3 Brief Description of Project
4 Final
Com liance Date
number
source of discharge
a reg
b prol
B You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges)
you now have under way or which you plan Indicate whether each program is now under way or planned, and indicate your actual or planned
schedules for construction
III. Site Drainage Ma
Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a
topographic map Is unavailable) depicting the facility including each of its intake and discharge structures, the drainage area of each storm
water outfall, paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff,
materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied, each of its hazardous
waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous
waste under 40 CFR 262 34), each well where fluids from the facility are injected underground, springs, and other surface water bodies which
receive stone water discharges from the facility
EPA Form 3510 -2F (Rev 1 -92) Page 1 of 3 Continued on Page 2

1 Y
Page 32 of 38
Analytical Laboratory
Continued from the Front
IV. Narrative Description of Pollutant Sources
A For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and budding roofs) drained
to the outfall, and an estimate of the total surface area drained by the outfall
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Number
(provide units
(provide units
Number
(provide units
(provide units
SWO02
B Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present materials management
practices employed to minimize contact by these materials with storm water runoff, materials loading and access areas, and the location,
manner, and frequency in which pesticides, herbicides, sod conditioners, and fertilizers are applied
C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in
storm water runoff, and a description of the treatment the storm water receives, including the schedule and type of maintenance for
control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge
Outfall
List Codes from
Number
Treatment
Table 2F -1
SW0O2
V. Non Stormwater Discharges
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C
or Form 2E application for the outfall
Name of Official Title (type or punt)
Signature
Date Signed
B provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test
VI. Significant Leaks or Spills
Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three
ears, including the approximate date and location of the spill or leak, and the type and amount of material released
EPA Form 3510 -2F (Rev 1 -92) Page 2 of 3 Continued on Page 3

4 �t
r �
i
Page 33 of 38
Analytical Laboratory
EPA ID Number (copy from Item I of Form 1)
Continued from Page 2
VII. Discharge Information
&B,C, & D See instruction before proceeding Complete one set of tables for each outfall Annotate the outfall number in the space provided
Tables Vu -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2
E Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F-4, a substance or a component of a
substance which you currently use or manufacture as an intermediate or final product or byproduct?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
VIII. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation to your discharge within the last 3 years?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
IX. Contact analysis Information
Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm?
® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X)
analyzed by, each such laboratory or firm below
A Name
B Address
C Area Code & Phone No
D Pollutants Analyzed
Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease)
Huntersville, NC 28078 Organic
Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176
Asheville, NC 28804 Wet chemistry &
metals
X. Certification
1 certify under penalty of law that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the Information submitted Based on my Inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the Information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations y
A Name & Official Title (type or punt)
B Area Code and Phone No
C Signature
D Date Signed
EPA Form 3510 -2F (Rev 1 -92) Page 3 of 3

r
EPA ID Number (copy from Item /of Form 1)
Page 34 of 38
Analytical Laboratory
Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
Al. Discharge Information Continued from page 3 of Form 2F
Part A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outfall See
instructions for additional details
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
And
Grab Sample
Grab Sample
Storm
CAS Number
Taken During
Flow - weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Oil & Grease
27 6 mg/L.
N/A
13 8 mg /L
2
Biological Oxygen
5 2 mg /L
1
Demand BOD5
Chemical Oxygen
49 0 mg/L.
1
Demand COD
Total Suspended
67 7 mg/L.
40 4 mg /L
2
Solids TSS
Total
2 24 mg/L
1
Nitrogen
Total
0 12 mg /L
1
Phosphorus
pH
Minimum
I Maximum
I Minimum
I Maximum
Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES
permit for its process wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall
See the instructions for additional details and re wrements
Maximum Values
Average Values
Number
Pollutant
include units)
include units
Of
And
Storm
Grab Sample
Grab Sample
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Bromide (24959 -67 -9)
Chlorine, Total
residual
Ammonia (as N)
0 90 mg /L
0 55 mg /L
2
Chloride
5 8 mg /L
2 9 mg/L.
2
Color
180 units
90 units
2
Fluoride (16984 -48 -8)
Nitrate - Nitrite (as N)
1 0 mg/L.
0 97 mg /L
2
Radioactivity, alpha
< 1 1 t 0 7
1
total
Ci /L
Radioactivity, beta
4 8± 1 2
1
total
Ci /L
Radioactivity, radium
total
Radioactivity, radium
226 total
Sulfate (as SO4)
20 7 mg /L
19 0 mg /L
2
(14808 -79 -8
Sulfite (as S03)
14265 -45 -3)
Aluminum, Total
1 58 mg /L
1
7429 -90-5
Barium, Total
0 0517 mg/L.
1
7440 -39-3
Boron, Total (7440-
0 0915 mg /L
1
42 -8
Cobalt, Total (7440-
<0 005 mg /L
1
48-4
Iron, Total (7439 -89 -6)
5 79 mg /L
1
Magnesium, Total
3 52 mg /L
1
7439 -95-4
Magnesium,
Dissolved
Molybdenum, Total
7439 -98 -7
EPA Form 3510 -21F (Rev 1 -92) Page VII -1 Contmue on Reverse

Page 35 of 38
Analytical Laboratory
Manganese, Total
0 117 mg /L
1
7439 -96 -5
Tin, Total
<0 005 mg /L
1
7440 -31 -5
Titanium, Total
0 0813 mg /L
1
7440 -32 -6
Antimony, Total
7440 -36 -0
Arsenic, Total
<0 005 mg /L
1
7440 -38 -2
Beryllium, Total
7440 -41 -7
Cadmium, Total
0 0012 mg /L
1
7440 -43 -9
Chromium, Total
<0 005 mg /L
1
7440 -47 -3
Copper, Total
0 0333 mg /L
1
7440 -50 -8
Lead, Total
7439 -92 -1
Mercury, Total
<0 020 ug /L
1
7439 -97 -6
Nickel, Total
<0 005 mg /L
1
7440 -02 -0
Selenium, Total
0 0562 mg /L
1
7782 -49 -2
Silver, Total
<0 005 mg /L
1
7440 -22-4
Thallium, Total
7440 -28 -0
Zinc, Total
0 486 mg /L
1
7440 -66 -6
EPA Form 3510 -2F (Rev 1 -92) Page VII -1 Continue on Reverse

Page 36 of 38
Analytical Laboratory
Continued from the Front
Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F -4 that you know or have reason to believe is present See the instructions for
additional details and requirements Com fete one table for each outfall
Pollutant
And
CAS Number
(if available)
Maximum Values
include units
Average Values
Include units
Number
Of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Cyanide, Total
(57 -12 -5)
Phenols, Total
<0 010 mg /L
1
Surfactants (MBAs)
Total Dissolved Solids
Total Organic Carbon
Total Kleldahl
Nitrogen TKN
1 3 mg/L
1
Fecal Coliform
Part D - Provide data for the storm events which resulted in the maximum values for the flow weighted com osite sample
1
Date of
Storm
Event
2
Duration
of Storm Event
(in minutes)
3
Total rainfall
during storm event
(in Inches )
4
Number of hours between
beginning of storm measured
and end of previous
measurable rain event
5
Total flow from
rain event
(gallons or specify units)
7 Provide a description of the method of flow measurement or estimate
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

Page 37 of 38
Analytical Laboratory
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

OUTFALL
SAMPLED
SAMPLE
COLLECTION DATE
SAMPLE
TYPE
ANALYSES
SW002
Sep 10, 2008
Grab
ASTM D516 -90
EPA 1664A
EPA 200 7
EPA 245 1
EPA 350 1
EPA 3512
EPA 353 2
EPA 365 1
EPA 420 4
SM 21206
SM2540D
SM 4500 -CI -E
SM 52106
SM 5220D

mft Duke Analytical Laboratory
VEnergy. H 13339 Ferry Road
untersvilleille, NC 28078 -7929
Rev 07 -03-07 McGuire Nuclear Complex — MG03A2
Phone 704 - 875 -5245 Fax 704 - 875 -5038
Job Summary Report
Job Number: I 08 -SEP -0240
Project Name:
Customer Name:
Copy To:
Customer Address:
Riverbend Storm Water
Brandy Starnes
Steve Jones, Greg Phillips
MG03A3
Lab Contact: Mary Ann Ogle
Lab Contact Phone: [phone]
Report Authorized By:
(Printed Name)
MARY ANN OGLE
Page 1 of 38
Analytical Laboratory
Report Authorized By:
(Signature) Date /o O Fj
Data Package
This data package includes analytical results that are applicable only to the samples
described In this narrative. An estimation of the uncertainty of measurement for the
results In the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory Please contact the
Analytical Laboratory with any questions The order of Individual sections within this
report is as follows.
Job Summary Report
Analytical Laboratory Certificate of Analysts -
Analytical Laboratory QC Reports (f applicable)
Sub - contracted Laboratory Results
Customer Specific Data Sheets, Reports & Documentation (f applicable)
Customer Database Entries
Test Case Narratives
Chain of Custody (COQ

Page 2 of 38
Analytical Laboratory
Duke Analytical Laboratory
10WEnergy. H13339 Ferry Road
untersvilleille, NC 28078 -7929
Rev 07 -0.9 -07 McGuire Nuclear Complex — MG03A2
Phone 704 - 875 -5245 Fax 704 - 875 -5038
Job Summary Report
Certification
The Analytical Laboratory holds the following Certifications
New York State Department of Health Certification # 11717(NELAC)
North Carolina Department of Health & Human Services Certification # 37804
South Carolina (DHEC) Laboratory ID # 99005
North Carolina (DENR) Certification # 248
Analytical results listed in this report may not be certified by the authorities referenced above
Contact the Analytical Laboratory for definitive information about the certification status of
specific methods The results meet all requirements of NELAC except where deviations are
noted in this report
Data Flags
Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a
deviation from the method quality system or quality control requirement
Calculations
All results are reported on a wet weight basis unless otherwise noted
Sample ID's & Descriptions:
Collection Sample
Sample ID Plant /Station Date Collected By Description
--- - - - - -- ------- - - - - -- ---- --- - -- ------ - - -- -- ----- - - -- --
28026404 FOSSIL 9/10/2008 B STARNES RI�IERBEND SWO02
-----------------
1 TOTAL SAMPLES

Page 3 of 38
Analytical Laboratory
Duke Analytical Laboratory
®Energy® 13339 Hagers Ferry Road
Huntersville, NC 28078 -7929
Rte, 07 -03-07 McGuire Nuclear Complex — MG03A2
Phone 704 - 875 -5245 Fax 704 - 875 -5038
Job Summary Report
Validation of Analytical Data Package -
COC and pdf report are in agreement with sample totals
i) and analyses (compliance programs and procedures)
r Yes
r No
ii) All results are less than the laboratory reporting limits.
(" Yes
F,' No
iii) All laboratory QA/QC requirements are acceptable
Yes
1` No
NPDES and TCLP results are below permit or regulatory
IV) limits respectively
r Yes
No
11 rv) above is No, document below
Permit
Variable Result I Limit Notes
Components of the Job Summary Report arranged in order
V) stipulated on page one [F No
Indicate components included.
vi) Notes and Additional Information
This is a partial report for SW 002 The other reports for this outfall are 08 -JUL -0641
The following parameters contained quality control failures for matrix spike recovery, but the spike was not
performed on this sample TP, phenols, sulfate, chloride The following parameters contained quality control
failures for duplicate relative percent difference, the quality control was not performed on this sample TSS These
quality control failures should be documented when reporting result, but these results are still considered valid
Mary Ann Ogle
Duke Energy Analytical Lab
NPDES Contact Office 704 - 875 -5274 Cell 704 - 280 -7956
of
Job Summary Report
r
Customer Specific Data Sheets, Reports &
Documentation (if applicable)
F
Analytical Laboratory Certificate of
Analysis
j
Customer Database Entries
F
Analytical Laboratory QC Report
(if applicable)
1-`
Test Case Narratives
f7
Sub - contracted Laboratory Results
r
Chain of Custody
vi) Notes and Additional Information
This is a partial report for SW 002 The other reports for this outfall are 08 -JUL -0641
The following parameters contained quality control failures for matrix spike recovery, but the spike was not
performed on this sample TP, phenols, sulfate, chloride The following parameters contained quality control
failures for duplicate relative percent difference, the quality control was not performed on this sample TSS These
quality control failures should be documented when reporting result, but these results are still considered valid
Mary Ann Ogle
Duke Energy Analytical Lab
NPDES Contact Office 704 - 875 -5274 Cell 704 - 280 -7956
of

/�aceAnalydcal'
wwwpacelabs cam
October 03, 2008
Mr Jay Perkins
Duke Energy
13339 Hagers Ferry Road
Bldg 7405 MG30A2
Huntersville, NC 28078
RE Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)254 -7178
Page 4 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Hunterswile NC 28078
(704)875 -9092
Dear Mr Perkins
Enclosed are the analytical results for sample(s) received by the laboratory on September 11, 2008
The results relate only to the samples included in this report Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersvllle laboratory unless otherwise footnoted All
Microbiological analyses were performed at the laboratory where the samples were received
If you have any questions concerning this report, please feel free to contact me
Sincerely,
-K s,-- -- Kevin Herring
kevin hernng @pacelabs corn
Project Manager
Enclosures
cc Accounts Payable DPEHS, Duke Energy Carolinas, LLC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc
Page 1 of 23

J aceAnalytical
vm w pacelabxcom
r
Project 08 -SEP -0240
Pace Project No 9227707
Charlotte Certification IDs
Connecticut Certification Number PH -0104
Pennsylvania Certification Number 68 -00784
West Virginia Certification Number 357
Virginia Certification Number 00213
Tennessee Certification Number 04010
South Carolina Drinking Water Cent Number 990060003
South Carolina Certification Number 990060001
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
CERTIFICATIONS
Page 5 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kmcey Ave Sude 100
Huntersville, NC 28078
(704)875 -9092
North Carolina Field Services Certificatron Number 5342
North Carolina Wastewater Certification Number 12
North Carolina Drinking Water Certification Number 37706
Louisiana /LELAP Certification Number 04034
Kentucky UST Certification Number 84
New Jersey Certification Number NC012
Florida /NELAP Certification Number E87627
Asheville Certification IDs
Connecticut Certification Number PH -0106
Pennsylvania Certification Number 68 -03578
Massachusetts Certification Number M -NC030
North Carolina Bioassay Certification Number 9
West Virginia Certification Number 356
North Carolina Wastewater Certification Number 40
Virginia Certification Number 00072
North Carolina Drinking Water Certification Number 37712
Tennessee Certification Number 2980
New Jersey Certification Number NC011
South Carolina Bioassay Certification Number 99030002
Louisiana /LELAP Certification Number 03095
South Carolina Certification Number 99030001
Flonda/NELAP Certification Number E87648
Eden Certification IDs
Virginia Drinking Water Certification Number 00424 North Carolina Drinking Water Certification Number 37738
North Carolina Wastewater Certification Number 633
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,
Page 2 of 23

I
I
i
i _ aceAnalytical
/ vrviwpaCOWScom
Project 08 -SEP -0240
Pace Project No 9227707
Lab ID Sample ID
9227707001 28026404 SW002
Pace Analytical Services, Inc
2225 Riverside Dc
Asheville, NC 28804
(828)254 -7176
SAMPLE SUMMARY
Matrix Date Collected Date Received
Water 09/10/08 16 00 09/11/08 14 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
xiL1Cd�=
Page 6 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersvdle, NC 28078
(704)8759092
Page 3 of 23

i
/�aceAnalXicale
vavwpacelabs.com
r
f
Project 08 -SEP -0240
Pace Project No 9227707
Lab ID Sample ID
9227707001 28026404 SWO02
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
SAMPLE ANALYTE COUNT
Method
ASTM D516 -90
EPA 1664A
EPA 200 7
EPA 245 1
EPA 350 1
EPA 351 2
EPA 353 2
EPA 365 1
EPA 420 4
SM 2120B
SM 2540D
SM 4500 -CI -E
SM 5210B
SM 5220D
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
fir/ .••,`e \._
Page 7 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
Page 4 of 23
Analytes
Analysts
Reported
SER
1
DNP
1
EWS
17
SHB
1
RAB
1
RAS
1
JDA
1
JDA
1
SER
1
RAS
1
SAJ
1
SER
1
SAJ
1
RAB
1
Page 4 of 23

_, aceAnalytical
vrvNipacelabscom
i
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)254 -7176
ANALYTICAL RESULTS
Page 8 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KnceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
Project 08 -SEP -0240
Pace Project No 9227707
Sample 28026404 SWO02
Lab ID 9227707001 Collected
09/10/08 16 00
Received 09/11/08 14 30 Matnx Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared
Analyzed
CAS No Qual
HEM, Oil and Grease
Analytical Method EPA 1664A
Oil and Grease
27 6 mg /L
5 0
11
1
09/22/08 10 52
200 7 MET ICP
Analytical Method EPA 200 7 Preparation Method
EPA 200 7
Aluminum
1580 ug /L
100
250
1
09/17/08 12 55
09/25/08 2211
7429 -90 -5
Arsenic
ND ug /L
5 0
27
1
09/17/08 12 55
09/25/08 2211
7440 -38 -2
Barium
517 ug /L
5 0
020
1
09/17/08 12 55
09/25/08 22 11
7440 -39 -3
Baron
91 5 ug /L
500
47
1
09/17/08 12 55
09/25108 22 11
7440 -42 -8
Cadmium
12 ug /L
1 0
050
1
09/17/08 12 55
09/25/08 22 11
7440 -43 -9
Chromium
ND ug /L
5 0
040
1
09/17/08 12 55
09/25/08 22 11
7440 -47 -3
Cobalt
ND ug /L
5 0
060
1
09/17/08 12 55
09/25/08 22 11
7440 -48 -4
Copper
333 ug /L
50
030
1
09/17/08 12 55
09/25/08 22 11
7440 -50 -8
Iron
5790 ug /L
Soo
140
1
09/17/08 12 55
09/25/08 22 11
7439 -89 -6
Magnesium
3520 ug /L
100
30
1
09/17/0812 55
09/25/08 22 11
7439 -95 -4
Manganese
117 ug /L
5 0
030
1
09/17/08 12 55
09/25/08 22 11
7439 -96 -5
Nickel
ND ug /L
50
1 7
1
09/17/08 12 55
09/25/08 22 11
7440 -02 -0
Selenium
56 2 ug /L
100
38
1
09117/08 12 55
09/25/08 22 11
7782 -49 -2
Silver
ND ug /L
5 0
010
1
09/17/08 12 55
09/25/08 22 11
7440 -22 -4
Tin
ND ug /L
5 0
18
1
09/17/08 12 55
09/25/08 22 11
7440 -31 -5
Titanium
81 3 ug /L
so
010
1
09117108 12 55
09/25108 22 11
7440 -32 -6
Zinc
486 ug /L
100
040
1
09/17/08 12 55
09/25/08 22 11
7440 -66-6
2451 Mercury
Analytical Method EPA 245 1
Preparation
Method EPA 245 1
Mercury
ND ug/L
020
020
1
09/29/08 18 10
09/30/08 09 48
7439 -97 -6
21208 W Apparent Color
Analytical Method SM 2120B
Apparent Color
180 units
50
1
09/11/08 22 50
2540D Total Suspended Solids
Analytical Method SM 2540D
Total Suspended Solids
67 7 mg /L
33
1
09/15/08 14 49
52108 BOO, Low Level
Analytical Method SM 52108
BOD, 5 day
5 2 mg /L
2 0
1
09/12/08 06 00
09/17/08 12 00
3501 Ammonia
Analytical Method EPA 350 1
Nitrogen, Ammonia
0 21 mg /L
010
010
1
09/17/08 20 30
7764 -41 -7
3512 Total Kjeldahl Nitrogen
Analytical Method EPA 351 2
Nitrogen, Kjeldahl, Total
13 mg /L
0 50
050
1
09/15/08 20 30
7727 -37 -9
353 2 Nitrogen, NO2/NO3 pres
Analytical Method EPA 353 2
Nitrogen, NO2 plus NO3
0 94 mg /L
010
010
1
09/20/08 12 26
3651 Phosphorus, Total
Analytical Method EPA 365 1
Phosphorus
012 mg /L
010
010
1
09/16/08 10 52
7723 -14-0
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 5 of 23
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc
"e

k
1�laceAnalytical'
mwirpaWabs com
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
ANALYTICAL RESULTS
Page 9 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
Sample 28026404 SWO02
Parameters
Lab ID 9227707001 Collected
Report
Results Units Limit
09/10/08 16 00
MDL DF
Received 09/11/08 14 30 Matrix Water
Prepared Analyzed CAS No Qual
420 4 Phenolics, Total
Analytical Method EPA 420 4
Phenol
NO mg /L 0 010
0 010
1
09117108 16 52 108 -95 -2
4500 Chloride
Analytical Method SM 4500 -CI -E
Chloride
5 8 mg /L so
50
1
09/16108 17 20 16887 -00 -6
5220D COD
Analytical Method SM 5220D
Chemical Oxygen Demand
49 0 mg /L 250
25 0
1
09/12/08 17 25
ASTM D516 -90 Sulfate Water
Analytical Method ASTM D516 -90
Sulfate
20 7 mg /L 5 0
50
1
09/16/08 13 56 14808 -79 -8
Date 10/03/2008 03 34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc.
�CJL1�.4.
Page 6 of 23

ii
I
_ ;alceAnalydcal'
wwwpace/ahsccm
i
f
i
Project 08 -SEP -0240
Pace Project No 9227707
QC Batch WET /5428
QC Batch Method SM 2120B
Associated Lab Samples 9227707001
METHOD BLANK 166940
Associated Lab Samples 9227707001
Parameter Units
Apparent Color units
SAMPLE DUPLICATE 166941
Parameter Units
Apparent Color units
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)2547176
QUALITY CONTROL DATA
Analysis Method SM 2120B
Analysis Description 21208 Color
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5 0 09/11/08 22 50
Page 10 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Hunterswlle NC 28078
(704)875 -9092
9227707001 Dup Max
Result Result RPD RPD Qualifiers
180 180 0 20
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 7 of 23
This report shall not be reproduced, except in full
without the written consent of PaceAnalyhcal Services, Inc,

`a
I
11;aCeAnalytical'
-71VffiWPaCe18bs coin
E
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
QC Batch WET /5431 Analysis Method SM 5210B
QC Batch Method SM 5210B Analysis Description 52106 BOD, Low Level
Associated Lab Samples 9227707001
METHOD BLANK 166948
Associated Lab Samples 9227707001
Parameter Units
BOD, 5 day mg /L
LABORATORY CONTROL SAMPLE 166949
Parameter Units
BOD, 5 day mg /L
Matnx Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2 0 09/17/08 12 00
Page 11 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
198 192 97 84 -115
SAMPLE DUPLICATE 166950
9227681001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
BOD, 5 day mg /L 6 9 6 5 5 20 62
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 8 of 23
This report shall not be reproduced, except in full,
without the wntten consent oof,�Pace Analytical Services, Inc

aceAnalytical
wwv+pacefabs com
I
QUALITY CONTROL DATA
Project 08 -SEP -0240
Page 12 of 38
Analytical Laboratory
Pace Analytical Services, Inc
Pace Analytical Services, Inc
2225 Riverside Dr
9800 Kincey Ave Sulte 100
Asheville, NC 28804
Huntersville, NC 28078
(828)254- 7176
(704)875 -9092
QUALITY CONTROL DATA
Project 08 -SEP -0240
167256
Pace Project No 9227707
QC Batch WETA/3453
Analysis Method
SM 5220D
QC Batch Method SM 5220D
Analysis Description
5220D COD
Associated Lab Samples 9227707001
MS
MS
METHOD BLANK 167254
Matrix Water
Parameter
Associated Lab Samples 9227707001
Units
Result
Cone
Blank Reporting
% Rec
Parameter Units
Result Limit
Analyzed Qualifiers
Chemical Oxygen Demand mg /L
NO 25 0 09/12/08 17 25
118
750
813
LABORATORY CONTROL SAMPLE 167255
93
75 -125
MATRIX SPIKE SAMPLE
Spike LCS
LCS % Rec
Parameter Units
Cone Result
% Rec Limits Qualifiers
Chemical Oxygen Demand mg /L
750 755
101 90 -110
MATRIX SPIKE SAMPLE
167256
9227080001
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand
mg /L
118
750
813
93
75 -125
MATRIX SPIKE SAMPLE
167258
9227647002
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand
mg /L
380
750
1100
96
75 -125
SAMPLE DUPLICATE 167257
9227094001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Chemical Oxygen Demand
mg /L
673
678
7
20
SAMPLE DUPLICATE 167259
9227662001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Chemical Oxygen Demand
mg /L
850
850
0
20
Date 1010312008 03 34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
a
Y /
C11
Page 9 of 23

i
_ aceAnalytical
j VmWocelabs.com
f
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7178
QUALITY CONTROL DATA
Project 08 -SEP -0240
Pace Project No 9227707
QC Batch WETA/3464 Analysis Method EPA 365 1
QC Batch Method EPA 365 1 Analysis Description 365 1 Phosphorus, Total
Associated Lab Samples 9227707001
Page 13 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
METHOD BLANK 167967
167971
Matrix Water
Associated Lab Samples 9227707001
II
9227680001
Spike
Blank Reporting
MS
% Rec
Parameter
Units
Result Limit
Analyzed
Qualifiers
Phosphorus
mg /L
ND 010
09/16/08 10 49
36
1
5 0
137
90 -110 MO
LABORATORY CONTROL SAMPLE
167968
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits Qualifiers
Phosphorus
mg /L
1 10
100
90 -110
Qualifiers
Phosphorus
mg /L
052
049
MATRIX SPIKE SAMPLE
167969
I SAMPLE DUPLICATE 167972
9227807001 Spike
MS
MS % Rec
Parameter
Units
Result Conc
Result
% Rec Limits Qualifiers
Phosphorus
mg /L
71 1
77
60 90 -110 MO
MATRIX SPIKE SAMPLE
167971
II
9227680001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Phosphorus
mg /L
36
1
5 0
137
90 -110 MO
SAMPLE DUPLICATE 167970
9227807002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Phosphorus
mg /L
052
049
5
20
I SAMPLE DUPLICATE 167972
9227707001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Phosphorus
i
I
mg /L
012
011
9
20
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 10 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
3'��4

acmnalytical
wwwpacelabs coin
i
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Page 14 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Hunterswlle, NC 28078
(704)8759092
QC Batch WET 15458
Analysis Method
SM 2540D
QC Batch Method SM 2540D
Analysis Description
2540D Total Suspended Solids
Associated Lab Samples 9227707001
METHOD BLANK 167976
Matrix Water
Associated Lab Samples 9227707001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Suspended Solids
mg /L
ND 1 0 09/15/08 14 39
LABORATORY CONTROL SAMPLE
167977
Spike LCS
LCS % Rec
Parameter
Units
Conc Result
% Rec Limits Qualifiers
Total Suspended Solids
mg /L
250 240
96 80 -120
SAMPLE DUPLICATE 167978
9227751001 Dup
Max
Parameter
Units
Result Result
RPD RPD Qualifiers
Total Suspended Solids
mg /L
11 7 160 31 20 R1
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 11 of 23
This report shall not be reproduced except in full
without the written consent of Pace Analytical Services, Inc

J
i
{ {{ /IceAnalytIcal'
{ wwwpacelabs com
II /
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Project 08 -SEP -0240
Pace Project No 9227707
QC Batch WETA/3473 Analysis Method EPA 3512
QC Batch Method EPA 351 2 Analysis Description 351 2 TKN
Associated Lab Samples 9227707001
METHOD BLANK 168200
Associated Lab Samples 9227707001
Parameter Units
Nitrogen, Kjeldahl, Total mg /L
Matnx Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0 50 09/15/08 20 30
Page 15 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE 168201
Spike LCS LCS % Rec -
Parameter Units Conc Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg /L 5 49 98 90 -110
MATRIX SPIKE SAMPLE
168202
9227643002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
17
5
5 3
71
90 -110 MO .
MATRIX SPIKE SAMPLE
168204
9227643012
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
14
5
6 8
108
90 -110
SAMPLE DUPLICATE 168203
9227643003
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
0 86
072
18
20
SAMPLE DUPLICATE 168205
9227677001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen, Kjeldahl, Total mg /L 1 3 1 5 15 20
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 12 of 23
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc

I
Page 16 of 38
Analytical Laboratory
Aar I
m Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytical 2225 Riverside Or 9800 Kmcey Ave Suite 100
vivnvpacelab =M Asheville, NC 28804 Huntersville, NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -SEP -0240
Pace Project No 9227707
QC Batch WETA/3475
Analysis Method EPA 420 4
QC Batch Method EPA 420 4
Analysis Description 420
4 Phenolics
a
Associated Lab Samples 9227707001
METHOD BLANK 168285
Matrix Water
Associated Lab Samples 9227707001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Phenol
mg /L
ND 0 010
09/17/08 16 44
LABORATORY CONTROL SAMPLE
168286
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits Qualifiers
Phenol
mg /L
25 026
105
90 -110
MATRIX SPIKE SAMPLE
168287
9227048002 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Phenol
mg /L
ND 25
NO
0
90 -110 M1
MATRIX SPIKE SAMPLE
168289
9227666003 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Phenol
mg /L
ND 25
ND
1
90 -110 M1
SAMPLE DUPLICATE 168288
9227047003 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Phenol
mg /L
ND ND
20
SAMPLE DUPLICATE 168290
9227700001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Phenol
mg /L
ND 0 012
20
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 13 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

aceAnalylical
wwwpacelabs ccm
1 r'
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 2880$
(828)254 -7176
QUALITY CONTROL DATA
QC Batch WETA/3476 Analysis Method ASTM D516 -90
QC Batch Method ASTM D516 -90 Analysis Description ASTM D516 -90 Sulfate Water
Associated Lab Samples 9227707001
METHOD BLANK 168291
Associated Lab Samples 9227707001
Parameter Units
Sulfate
mg /L
LABORATORY CONTROL SAMPLE
Parameter
168292
Units
Sulfate
mg /L
MATRIX SPIKE SAMPLE
Parameter
168293
Units
Sulfate
mg /L
MATRIX SPIKE SAMPLE
Parameter
168295
Units
Sulfate
mg /L
SAMPLE DUPLICATE 168294
Parameter
Units
Sulfate
mg /L
SAMPLE DUPLICATE 168296
Parameter
Units
Sulfate
mg /L
Date 10/03/2008 03 34 PM
Page 17 of 38
Analytical Laboratory
Paco Analyticai Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 5 0 09/16/08 13 51
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
20 195 97 90 -110
9227649005 Spike MS MS % Rec
Result Conc Result % Rec Limits Qualifiers
109 20 105 -19 75 -125 MO
9227708006 Spike MS MS % Rec
Result Conc Result % Rec Limits Qualifiers
ND 20 ND 4 75 -125 MO
9227785001 Dup Max
Result Result RPD RPD Qualifiers
161 160 9 20
9227708007 Dup
Result Result RPD
NO ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc
Max
RPD Qualifiers
20
Page 14 of 23

1aC6Analytical'
vnvw pacetabs com
r
i
Project 08 -SEP -0240
Pace Project No 9227707
QC Batch WETA/3477
QC Batch Method SM 4500 -CI -E
Associated Lab Samples 9227707001
METHOD BLANK 168297
Associated Lab Samples 9227707001
Parameter Units
Chloride mg /L
LABORATORY CONTROL SAMPLE
Parameter
168298
Units
Chloride
mg /L
MATRIX SPIKE SAMPLE
Parameter
168299
Units
Chloride
mg /L
MATRIX SPIKE SAMPLE
Parameter
168301
Units
Chloride
mg/L
SAMPLE DUPLICATE 168300
Parameter
Units
Chloride
mg /L
SAMPLE DUPLICATE 168302
Parameter
Units
Chloride
mg /L
Date 10/03/2008 03 34 PM
1
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Analysis Method SM 4500 -CI -E
Analysis Description 4500 Chloride
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5 0 09/16/08 17 20
Page 18 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
20 210 105 90 -110
9227527001 Spike MS MS % Rec
Result Conc Result % RPc Limits Qualifiers
2300 20 4260 9830 75 -125 M1
9227708008 Spike MS MS % Rec
Result Conc Result % Rec Limits Qualifiers
ND 20 ND 2 75 -125 M1
9227527002 Dup Max
Result Result RPD RPD Qualifiers
9390 8840 6 20
9227708009 Dup Max
Result Result RPD RPD Qualifiers
ND ND 20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of �Pace Analytical Services Inc
y J1�dtflti.,.
Page 15 of 23

I -
i
I
I
_ 7&eAnalyticale
wwwpacelabs corn
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc.
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
QC Batch MPRP /3024 Analysis Method EPA 200 7
QC Batch Method EPA 200 7 Analysis Description 200 7 MET
Associated Lab Samples 9227707001
Page 19 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersville NC 28078
(704)875 -9092
METHOD BLANK 168952
Matrix Water
Associated Lab Samples 9227707001
Blank
Reporting
Parameter
Units Result
Limit
Analyzed
Qualifiers
Aluminum
ug /L
ND
100
09/25/08 20 49
Arsenic
ug /L
ND
50
09/25108 20 49
Banum
ug /L
NO
5 0
09/25/08 20 49
Boron
ug /L
NO
500
09/25/08 20 49
Cadmium
ug /L
ND
10
09/25/08 20 49
Chromium
ug /L
ND
50
09/25/08 20 49
Cobalt
ug /L
ND
5 0
09/25/08 20 49
Copper
ug /L
NO
5 0
09/25/08 20 49
Iron
ug /L
NO
50 0
09/25/08 20 49
Magnesium
ug /L
ND
100
09/25/08 20 49
Manganese
ug /L
ND
50
09/25/08 20 49
Nickel
ug /L
ND
50
09/25/08 20 49
Selenium
ug /L
NO
100
09/25/08 20 49
Silver
ug /L
NO
50
09/25108 20 49
Tin
ug /L
NO
50
09/25/08 20 49
Titanium
ug /L
NO
50
09/25/08 20 49
Zinc
ug /L
ND
100
09/25108 20 49
LABORATORY CONTROL SAMPLE
168953
Spike
LCS
LCS %
Rec
Parameter
Units Conc
Result
% Rec Limits Qualifiers
Aluminum
ug /L
5000
5080
102
85 -115
Arsenic
ug /L
500
538
108
85 -115
Banum
ug /L
500
510
102
85 -115
Boron
ug /L
500
522
104
85 -115
Cadmium
ug /L
500
523
105
85 -115
Chromium
ug /L
500
528
106
85 -115
Cobalt
ug /L
500
511
102
85 -115
Copper
ug /L
500
515
103
85 -115
Iron
ug /L
5000
5180
104
85 -115
Magnesium
ug /L
5000
5140
103
85 -115
Manganese
ug /L
500
526
105
85 -115
Nickel
ug /L
500
523
105
85 -115
Selenium
ug /L
500
552
110
85 -115
Silver
ug /L
250
251
100
85 -115
Tin
ug/L
500
515
103
85 -115
Titanium
ug /L
500
520
104
85 -115
Zinc
ug /L
500
536
107
85 -115
Date 10103/2008 03 34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full,
without the written consent of Pace Analytical
Seances, Inc
Page 16 of 23

aC Analytical
wwvi pacelab$ com
i
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
MATRIX SPIKE & MATRIX SPIKE DUPLICATE 168954
9227672001
Parameter Units Result
MS
Spike
Conc
MSD
Spike
Conc
Aluminum
ug /L
328
5000
5000
Arsenic
ug /L
ND
500
500
Banum
ug/L
ND
500
500
Boron
ug /L
850
500
500
Cadmium
ug /L
ND
500
500
Chromium
ug /L
630
500
500
Cobalt
ug /L
ND
500
500
Copper
ug /L
ND
500
500
Iron
ug /L
ND
5000
5000
Magnesium
ug /L
ND
5000
5000
Manganese
ug /L
ND
500
500
Nickel
ug /L
ND
500
500
Selenium
ug /L
ND
500
500
Silver
ug /L
ND
250
250
Tin
ug /L
ND
500
500
Titanium
ug /L
ND
500
500
Zinc
ug /L
394
500
500
Page 20 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
168955
Units
9227673001
Result
Dup
Result
RPD
Max
RPD
Aluminum
MS
MSD
MS
MSD
% Rec
Arsenic
Max
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
5800
5890
109
111
70 -130
2
20
550
563
110
113
70 -130
2
20
533
540
106
108
70 -130
1
20
609
622
105
107
70 -130
2
20
536
540
107
108
70 -130
7
20
1210
1220
116
118
70 -130
8
20
525
530
105
106
70 -130
9
20
551
561
110
112
70 -130
2
20
5370
5420
107
108
70 -130
9
20
5410
5460
107
108
70 -130
9
20
542
547
108
109
70 -130
9
20
541
545
108
109
70 -130
7
20
562
573
112
114
70 -130
2
20
262
267
105
107
70 -130
2
20
535
540
107
108
70 -130
9
20
537
543
107 -
109
70 -130
1
20
594
603
111
113
70 -130
2
20
SAMPLE DUPLICATE 168956
Parameter
Units
9227673001
Result
Dup
Result
RPD
Max
RPD
Aluminum
ug/L
969
991
2
20
Arsenic
ug /L
ND
ND
20
Barium
ug /L
235
239
2
20
Boron
ug/L
3110
3170
2
20
Cadmium
ug /L
ND
ND
20
Chromium
ug/L
202
200
1
20
Cobalt
ug/L
102
102
0
20
Copper
ug /L
268
281
5
20
Iron
ug /L
1050
1080
3
20
Magnesium
ug /L
998
1030
3
20
Manganese
ug /L
176
180
2
20
Nickel
ug /L
128
130
2
20
Selenium
ug /L
ND
ND
20
Silver
ug /L
ND
ND
20
Tin
ug /L
ND
4 8J
20
Titanium
ug /L
199
203
2
20
Zinc
ug /L
502
523
4
20
Date 10103/2008 03 34 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services Inc
Qualifiers
Page 17 of 23

/7,ilaceAnalytIcal o
vmwpacdabs com
I
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
QC Batch WETA/3486 Analysis Method EPA 3501
QC Batch Method EPA 350 1 Analysis Description 350 1 Ammonia
Associated Lab Samples 9227707001
METHOD BLANK 169416 Matrix Water
Associated Lab Samples 9227707001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg /L ND 0 10 09/17/08 20 30
Page 21 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersviile, NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE
169417
9227654001
Dup
Max
Spike LCS
LCS
% Rec
RPD Qualifiers
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Nitrogen, Ammonia
mg /L
5 53
106
90 -110
Max
Parameter Units
Result
Result RPD
RPD Qualifiers
Nitrogen, Ammonia mg /L
ND
MATRIX SPIKE SAMPLE
169418
9227651001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg /L
029 5
54
103
90 -110
MATRIX SPIKE SAMPLE
169420
ILJ-
9227910002 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg /L
ND 5
57
0 114
90 -110 MO
SAMPLE DUPLICATE 169419
9227654001
Dup
Max
Parameter Units
Result
Result RPD
RPD Qualifiers
Nitrogen, Ammonia mg /L
NO
ND
20
I
SAMPLE DUPLICATE - 169421
9227910003
Dup
Max
Parameter Units
Result
Result RPD
RPD Qualifiers
Nitrogen, Ammonia mg /L
ND
ND
20
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 18 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Ina

ff
aceAnalXical
wwwpacelabsccm
r
QUALITY CONTROL DATA
Project 08 -SEP -0240
Page 22 of 38
Analytical Laboratory
Pace Analytical Services, Inc
Pace Analytical Services, Inc
2225 Riverside Dr
9800 KinceyAve Suite 100
Asheville NC 28804
Huntersville, NC 28078
(828)254 -7176
(704)875 -9092
QUALITY CONTROL DATA
Project 08 -SEP -0240
Pace Project No 9227707
QC Batch WETA13511
Analysis Method EPA 353 2
QC Batch Method EPA 353 2
Analysis Description 353
2 Nitrate + Nitrite,
preserved
Associated Lab Samples 9227707001
METHOD BLANK 170839
Matrix Water
Associated Lab Samples 9227707001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND 0 10
09/20/08 12 26
LABORATORY CONTROL SAMPLE
170840
Spike LCS
LCS
% Rec
Parameter
Units
Cone Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
5 50
99
90 -110
MATRIX SPIKE SAMPLE
170841
9227680001 Spike
MS
MS
% Rec
Parameter
Units
Result Cone
Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
167 5
244
153
75 -125 MO 0`
7
MATRIX SPIKE SAMPLE
170843
9227910009 Spike
MS
MS
% Rec
Parameter
Units
Result Cone
Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND 5
51
102
75 -125
SAMPLE DUPLICATE 170842
9227707001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
0 94 0 94
0
20
SAMPLE DUPLICATE 170844
9227910010 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND ND
20
Date 10/03/2008 03 34 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc
Page 19 of 23

i
i
aceAnalytical
wwwPacelabscom
I
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)2547176
QUALITY CONTROL DATA
Project 08 -SEP -0240
Pace Project No 9227707
QC Batch GCSV/3754 Analysis Method EPA 1664A
QC Batch Method EPA 1664A Analysis Description 1664 HEM, Oil and Grease
Associated Lab Samples 9227707001
METHOD BLANK 171008
Associated Lab Samples 9227707001
Parameter Units
Oil and Grease mg /L
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5 0 09/22/08 10 44
Page 23 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KlnceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE
171009
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Oil and Grease
mg /L
40 360
90
78 -114
MATRIX SPIKE SAMPLE
171010
5018622003 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Oil and Grease
mg /L
67 426
490
99
78 -114
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 20 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

i
I
f
I
aceAnalytical e
I wwwparelabs com
Project 08 -SEP -0240
Pace Project No 9227707
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)2547178
QUALITY CONTROL DATA
QC Batch MERP /1725 Analysis Method EPA 2451
QC Batch Method EPA 245 1 Analysis Description 245 1 Mercury
Associated Lab Samples 9227707001
METHOD BLANK 174972
Associated Lab Samples 9227707001
Parameter
Units
Mercury
ug /L
LABORATORY CONTROL SAMPLE
Parameter
174973
Units
Mercury
ug /L
MATRIX SPIKE SAMPLE
Parameter
174974
Units
Mercury
ug /L
SAMPLE DUPLICATE 174975
Parameter
Units
Mercury
ug /L
Matrix Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0 20 09/30/08 09 43
Page 24 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Hunterswlle, NC 28078
(704)875 -9092
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
25 24 98 85 -115
9227707001 Spike MS MS % Rec
Result Conc Result % Rec Limits Qualifiers
ND 25 25 97 70 -130
9228780004 Dup
Result Result RPD
ND ND
Max
RPD Qualifiers
20
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 21 of 23
This report shall not be reproduced, except in full,
without the wntten consent of Pace Analytical Services, Inc

Page 25 of 38
Analytical Laboratory
Pace Analytical Services, Inc Pace Analytical Services, Inc
laceAnalytical"
2225 Riverside Or 9800 KlnceyAve Suite 100
vnnvpacelabscom
Asheville, NC 28804 Huntersville, NC 28078
(828)254- 7176 (704)675 -9092
QUALIFIERS
Project 08 -SEP -0240
Pace Project No 9227707
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content
ND - Not Detected at or above adjusted reporting limit
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL -Adjusted Method Detection Limit
S - Surrogate
1,2- Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable
Pace Analytical is NELAP accredited Contact your Pace PM for the current list of accredited analytes
ANALYTE QUALIFIERS
B2 Oxygen usage is less than 2 0 for all dilutions set The reported value is an estimated less than value and Is calculated
for the dilution using the most amount of sample
MO Matrix spike recovery was outside laboratory control limits
M1 Matrix spike recovery exceeded QC limits Batch accepted based on laboratory control sample (LCS) recovery
R1 RPD value was outside control limits
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 22 of 23
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc

aceAnalytical0
YMW(lacelabac0a7
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Page 26 of 38
Analytical Laboratory
Pace Analytical Services, Inc
9800 KlnceyAve Swte 100
Huntersvrlle NC 28078
(704)875 -9092
Project
08 -SEP -0240
Pace Project No
9227707
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
9227707001
28026404 SW002
SM 2120B
WET/5428
9227707001
28026404 SW002
SM 5210B
WET/5431
SM 5210B
WET/5439
9227707001
28026404 SW002
SM 5220D
WETA/3453
9227707001
28026404 SW002
EPA 365 1
WETA/3464
9227707001
28026404 SW002
SM 2540D
WET/5458
9227707001
28026404 SW002
EPA 351 2
WETA/3473
9227707001
28026404 SW002
EPA 420 4
WETA/3475
9227707001
28026404 SW002
ASTM D516 -90
WETA/3476
9227707001
28026404 SW002
SM 4500 -CI -E
WETA/3477
9227707001
28026404 SW002
EPA 200 7
MPRP /3024
EPA 200 7
ICP/2855
9227707001
28026404 SW002
EPA 350 1
WETA/3486
9227707001
28026404 SW002
EPA 353 2
WETA/3511
9227707001
28026404 SW002
EPA 1664A
GCSV /3754
9227707001
28026404 SW002
EPA 245 1
MERP /1725
EPA 2451
MERC /1721
Date 10/03/2008 03 34 PM REPORT OF LABORATORY ANALYSIS Page 23 of 23
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Servlces, Inc

Florida Radiochemistry Services, Inc.
Sample Login
Client: Pace Anaylical services Date / Time Work order 0
Received
09115/08 09 :48 0809085
Client Contact: Kevin Herring
Client P.O. CHS 04599
Project I.D. 28026404
Lab Sample I.D. Client Sample I.D. Sample Analysis
Date/Time Requested
080908301 28028404 SWO02 09/10/0816:00 Gross Alpha I Beta
Analysis Results
" Bross Alpha <4.1 Dross Beta 4.8
Error +/- 0.7 Error +1- 1.2
MDL 1.1 MDL 1.6
EPA Method 900.0 EPA Method 900.0
Prep Date 09/16/08 Prep Date 09116/08
Prep Time 06:40 Prep Time 00:40
Analysis Data 09/17/06 Analysis Date 09/17/08
Analysis Time 10:30 Analysis Time 10:30
Analyst MJN Analyst MJN
Units pCill Units pCi /l
Page 27 of 38
Analytical Laboratory

• A M
I�
f
E
I
Page 28 of 38
Analytical Laboratory
999 Florida Radiochemistry Services, Inc.
QA Pape
Analyte Sample # Date
Sample Amount
Spike
Spike /Dup
Spike
Spike Dup
Analyzed
Result Spiked
Result
Result
% Rec.
% Rpd
Gross Alpha 0809084 -02 09/17108
0.2 10.2
10.4
10.9
102
4.7
Grose Bets 0809084 -02 09/17/08
0.6 16.7
17.1
16.7
109
8.6
Quality
Control Limits
% RPD
% Rec.
Gross Alpha 23.6
62421
Gross Beta 16.7
80 -116

1
i
Page 29 of 38
Analytical Laboratory
• • • a
aceAnalytxaf
Client Name._,�k Project #
Courier ❑ Fed Ex ❑ UPS ❑ USPS u,
❑ Client ❑ Commercial 0 Pace Other tOpftgnaL;� +, °��v
Custody Seal on Cooler /Box Present yes no S � ❑
(� ❑ Seals intact yes no
Packing Material ❑ Bubble Wrap []Bubble Bags ZfNone ❑Other
Thermometer Used T060 Type of Ice v0 Blue None C Samples on ice, cooling process has begun
Cooler Temperature Biological Tissue is Frozen. Yes No N/A Date and In s pe examining
Temp should be above freezing to 6 °C contents
Comments
Chain of Custody Present
j;iYes 0 N
ON /A
1
Chain of Custody Filled Out
-QYes ONO
❑N /A
2
Chain of Custody Relinquished
.BYes ONO
❑N /A
3
Sampler Name & Signature on COC
Byes ONO
❑N /A
4
Samples Arrived within Hold Time
fires ONo
ON /A
5
Short Hold Time Analysis ( <72hr)
fames ONO
❑N /A
6 It
Rush Turn Around Time Requested
OYes ZNo
ON /A 7
Sufficient Volume
❑Yes No
❑N /A g
Correct Containers Used
❑Yes 2 o
❑N /A 9014
-Pace Containers Used
Oyes .CJNo
ON /A QN-YJ I LX- .
�6 901 114 ,
Containers Intact
Oes ONO
❑N /A 10
Filtered volume received for Dissolved tests
❑Yes ONo
/A 11
Sample Labels match COC
OYes,21No
ON /A 12 �W� S
- Includes date/time/ID/Analysis Matrix
All containers needing preservation have been checked
iQYes ONO
❑NIA 13
All containers needing preservation are found to be in
compliance with EPA recommendation
tomes ONo
ON /A
exceptions VOA, conform TOC, 0 &G WI DRO (water)
❑Yes ONO
Initial when completed
Samples checked for dechlorination
�'res ONO
❑N /A 14
Headspace in VOA Vials ( >6mm)
❑Yes ONO
� t5
Trip Blank Present
Oyes ONo -2fgTA 16
Trip Blank Custody Seals Present
❑Yes ONo (,7WX
Pace Trip Blank Lot l# (if purchased) N/A
Client Notification/ Resolution Field Data Required? Y / N / NIA
Person Contacted Date/Time
Comments/ Resolution
Project Manager Review
Date R
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( i e out of hold, incorrect preservative, out of temp, incorrect containers)
0,

0 0
r
D •
N,
co
:. m
O Q -
-o
0
Lr 7
O a CD
3X
(D 0
a -a
N Q
a
m m
(
0
3(D
fl.
O
I
1111110
a
f1
�
o
v0
u
v
s
Q
O
R
a
0
�s
°
v
e
fly
Customer, Important. please
Indicate desired turnaround
p 3 a $
A
e
a
0.
0 0
r
D •
N,
co
:. m
O Q -
-o
0
Lr 7
O a CD
3X
(D 0
a -a
N Q
a
m m
(
0
3(D
fl.
O
I
1111110
i
�a I
�a
Page 30 of 38
Analytical Laboratory
a i ,
D
,
00 I
N �,ll 3' �
L F
S I S 0 1
oa 1 a i
r 1
1 gr
A 1
jig
1 si
1�9 =O yl
r
r s
G
-'C
,N
.O
�v
r • (1 �P 1 OM
o
D
' ;
a 1
Comp .1 3 �� O �+ i v
Grab ..r. r O W Z
1� s,
NH3. NO3-M02 r ' D
� � 1
1
color
"s l ;-n
raa
;
eao
' l r
9 ,
301. CI In � � c a r 1
-- -'
ebaaal� �. S O
TKK ir. Coo C $ v
:: a : e s m
Cr.NkAaalr,Lr.tta
0 CIO
tohl Be a o I^
la
�liiff s Z IN
S n
gamYm Us � r
on
Total 0 Contains v -,,�'L
f1
�
N
0
0
°
v
9
i
�a I
�a
Page 30 of 38
Analytical Laboratory
a i ,
D
,
00 I
N �,ll 3' �
L F
S I S 0 1
oa 1 a i
r 1
1 gr
A 1
jig
1 si
1�9 =O yl
r
r s
G
-'C
,N
.O
�v
r • (1 �P 1 OM
o
D
' ;
a 1
Comp .1 3 �� O �+ i v
Grab ..r. r O W Z
1� s,
NH3. NO3-M02 r ' D
� � 1
1
color
"s l ;-n
raa
;
eao
' l r
9 ,
301. CI In � � c a r 1
-- -'
ebaaal� �. S O
TKK ir. Coo C $ v
:: a : e s m
Cr.NkAaalr,Lr.tta
0 CIO
tohl Be a o I^
la
�liiff s Z IN
S n
gamYm Us � r
on
Total 0 Contains v -,,�'L

f T
O
d
Customer to complete appmpnate columns to rigt
Page 38 of 38
Analytical Laboratory
d
'R
0
N
c
�
S
c
N
S
C
S
a
G
m
a
D
Is
Is N'
Or m l
N
I 3 I
I r1 d I
d v l
J
O
m
O
m
Q O•
d
O
al
O i l
1
3
3
3
a 3
-
m
m
m
p4 m
-j
� 0
,e
A
m�r•'9
O
t
ID
I
a
O
n
n
n
n
�
�
0
0
m
a
m
m
a
x
a
O
9
m
m
N
G.
m
CL
001
M
y
O
s
a
n
3
m
3
m
3
$
3
0 N
O
m
m
\m
m
O
7 0f s
i}
F
S
3
.D
O
N
1
I g l
Customer, Important please
Indicate desired turnaround
(7 ; v A M
D Er co O O a
n� 2 m
0
0
C
d
v O
Q.
O
d
Customer to complete appmpnate columns to rigt
Page 38 of 38
Analytical Laboratory
o
a A
M
<
Y
C
D
Is
Is N'
Or m l
N
I 3 I
I r1 d I
d v l
J
I
O i l
1
1COP)
I0
CU
j
I m 3 C
' 3 o y t(D '
I
-
-
-
-
----
-j
� 0
,e
A
m�r•'9
O
t
ID
I
I
t0 0, O I
�
O
m
N
G.
001
M
y
O
I
a
iu
n
3
�(°
0 N
O
7 0f s
i}
F
3
.D
O
N
1
I g l
m
a/
C m
00 :0
O
v
N
N
1 1
of
m
O
r�
v
4C
�
UH
m
X
Im 3" it
� ✓
2
f.,
NH3, NO3 NO2
p
re
Q
� I
I° uVri2al
ml
o�'�:0e�
I D
O1�
O Q
1
S y
A
CD
A
w
t o u w g m l
'm ar�
N
a
°
2
O
C
a O I
"sd
Fecal Conform
m
o
+ir
t''
v
xo
N
n
I
'_3 A
CO
O
j
I p l
s
D
p r
O� O
3
z
Q
w
<y I ^
A A m D
M
o
a A
M
<
Y
C
i
I
1COP)
I0
m
� 0
ya
I
t
ID
I
�
c
a
iu
n
3
�(°
In
v
3
m
a/
C m
00 :0
m
10
A li
c
'"C'
r�
v
4C
�
Z
� I Z
X
� ✓
2
NH3, NO3 NO2
p
re
N°
O
I D
O1�
Fecal Conform
m
o
+ir
xo
f
I O C)
0 ;a
F C Y I
' n
w
<y I ^
A A m D
M
color
la
8
.
i F1 I m
r_
v 0
V
Op
TSS /
1
0�
A
I I 'n
V i IO I0
Boo
r9
°oo
n
c
I 0 M I
I '
soa, Cl
m �
N
a
ZRIA Sat
N
u
c
in
.O
O
�
=
2
TKN, TP, COD
a
O
Z
T
D
r "O
o 2Ip
S, G, d,CO Se,
20
� . n�i,J
As, SIf Zn, Hg
N
o
Z
N CO
,
m
,Q
a
—'
W
o
—
TRadium
S=
=
Beta
9
T
Ada
k
I
o+Z N
0 1
228
in
Z
Total # Containersa