Riverbend Steam Station (11)

J
Page 31 of 47
Analytical Laboratory
Please print or type in the unshaded areas I
EPA ID Number (copy from item / of Form 1)
Form Approved OMB No 2040 -0086
I Approval expires 5 -31 -92
Form
2F
NPDES
United States Environmental Protection Agency
Washington, DC 20460
OmPA Application for Permit to Discharge Storm Water
Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average 286 hours per application, including time for reviewing instructions, searching existing data
sources, gathering and maintaining the data needed, and completing and reviewing the collection of information Send commends regarding the burden estimate,
any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to Chief,
Information Policy Branch, PM -223, U S Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Management and Budget Washington, DC 205M
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water
A Outfall Number
list
B Latitude
C Longitude
D Receiving Water
name
SW 002
H. Improvements
A Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or
operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, sti ulations, court orders, and grant or loan conditions
1 Identification of Conditions,
Agreements, Etc
2 Affected Outfalls
3 Brief Description of Project
4 Final
Com liance Date
number
source of discharge
a req
b proj
B You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges)
you now have under way or which you plan Indicate whether each program is now under way or planned, and indicate your actual or planned
schedules for construction
III. Site Drainage Ma
Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a
topographic map Is unavailable) depicting the facility including each of its intake and discharge structures, the drainage area of each storm
water outfall, paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff,
materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied, each of its hazardous
waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous
waste under 40 CFR 262 34), each well where fluids from the facility are injected underground, springs, and other surface water bodies which
receive storm water discharges from the facility
EPA Form 3510 -2F (Rev 1 -92) Page 1 of 3 Continued on Page 2

.e .?
Page 32 of 47
Analytical Laboratory
rnntlnuEd from the Front
IV. Narrative Description of Pollutant Sources
A For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and budding roofs) drained
to the outfall, and an estimate of the total surface area drained by the outfall
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
- Total Area Drained
Number
(provide units
(provide units
Number
(provide units
(provide units
SW002
B Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present materials management
practices employed to minimize contact by these materials with storm water runoff, materials loading and access areas, and the location,
manner, and frequency in which pesticides, herbicides, sod conditioners, and fertilizers are applied
C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in
storm water runoff, and a description of the treatment the storm water receives, including the schedule and type of maintenance for
control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge
Outfall
List Codes from
Number
Treatment
Table 2F -1
SW002
V. Non Stormwater Discharges
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C
or Form 2E application for the outfall
Name of Official Title (type orpnnt)
Signature
Date Signed
B provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test
VI. Significant Leaks or Spills
Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three
ears, including the approximate date and location of the spill or leak, and the type and amount of material released
EPA Form 3510 -2F (Rev 1 -92) Page 2 of 3 Continued on Page 3

EPA ID Number (copy from Item I of Form 1)
Continued from Page 2
Page 33 of 47
Analytical Laboratory
Al. Discharge Information
A,B,C, & D See instruction before proceeding Complete one set of tables for each outfall Annotate the outfall number in the space provided
Tables Vu -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2
E Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F-4, a substance or a component of a
substance which you currently use or manufacture as an intermediate or final product or byproduct?
❑ Yes (list all such pollutants below) ❑ No (go to Section /X)
VIII. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation to your discharge within the last 3 years?
❑ Yes (list all such pollutants below) ❑ No (go to Section /X)
IX. Contact analysis Information
Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? -
® Yes (list the name, address, and telephone number of and pollutants ❑ No (go to Section X)
analyzed by, each such laboratory or firm below
A Name
B Address
C Area Code & Phone No
D Pollutants Analyzed
Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease)
Huntersville, NC 28078 Organic
Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176
Asheville, NC 28804 Wet chemistry &
metals
X. Certification
l certify under penalty of law that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations
A Name & Official Title (type or pnnt)
B Area Code and Phone No
C Signature
D Date Signed
EPA Form 3510 -2F (Rev 1 -92) Page 3 of 3

Page 34 of 47
Analytical Laboratory
EPA ID Number (copy from Item I of Form 1) Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
VII. Discharge Information Continued from page 3 of Form 2F
Part A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outfall See
instructions for additional details
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
And
Grab Sample
Grab Sample
Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Oil & Grease
< 5 0 mg /L
N/A
1
Biological Oxygen
Demand BOD5
Chemical Oxygen
Demand COD
Total Suspended
13 1 mg /L
1
Solids TSS
Total
1 0 mg /L
1
Nitrogen
Total
Phosphorus
pH
I Minimum
Maximum
Minimum
Maximum
Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES
permit for its process wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall
See the instructions for additional details and re uirements
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
And
Storm
Grab Sample
Grab Sample
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Bromide (24959 -67 -9)
Chlorine, Total
residual
Ammonia (as N)
0 90 mg /L
1
Chloride
< 5 0 mg /L
1
Color
< 5 0 units
1
Fluoride (16984 -48 -8)
Nitrate - Nitrite (as N)
1 0 mg /L
1
Radioactivity, alpha
total
Radioactivity, beta
total
Radioactivity, radium
total
Radioactivity, radium
226 total
Sulfate (as SO4)
17 3 mg /L
1
14808 -79 -8
Sulfite (as SOs)
(14265 -45 -3
Aluminum, Total
7429 -90 -5
Banum, Total
7440 -39 -3
Boron, Total (7440-
42-8
Cobalt, Total (7440-
48-4
Iron, Total (7439 -89-6)
Magnesium, Total
7439 -95-4)
Magnesium,
Dissolved
Molybdenum, Total
7439 -98 -7
EPA Form 3510 -2F (Rev 1 -92) Page VII -1 Continue on Reverse

Page 35 of 47
Analytical Laboratory
Manganese, Total
7439 -96 -5
Tin, Total
7440 -31 -5
Titanium, Total
7440 -32 -6
Antimony, Total
7440 -36 -0
Arsenic, Total
7440 -38 -2
Beryllium, Total
7440 -41 -7
Cadmium, Total
7440 -43 -9
Chromium, Total
7440 -47 -3
Copper, Total
7440 -50 -8
Lead, Total
7439 -92 -1
Mercury, Total
7439 -97 -6
Nickel, Total
7440 -02 -0
Selenium, Total
7782 -49 -2
Silver, Total
7440 -22 -4
Thallium, Total
7440 -28 -0
Zinc, Total
7440 -66 -6
EPA Form 3510 -2F (Rev 1 -92) Page VII -I Contmue on Reverse

Wi f f
'ontinued from the Front
Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F-4 that you know or have reason to believ
additional details and requirements Com fete
one table for each outfall
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
And
Grab Sample
Grab Sample
Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Phenols, Total
Fecal Colifonn
Part D -
1
Date of
Storm
Event
Duration
of Storm Event
(in minutes)
storm eve_nt(s) which resulted in the
3
Total rainfall
during storm event
(in inches)
I I
7 Provide a description of the method of flow measurement or estimate
EPA Form 3510 -2F (Rev 1 -92) Page VII -2
4
Number of hours between
beginning of storm measured
and end of previous
measurable rain event
Page 36 of 47
Analytical Laboratory
is present Seethe i
Sources of Pollutants
5
Total flow from
rain event
(gallons or specify units)

K
Page 37 of 47
Analytical Laboratory
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

�f
Page 38 of 47
Analytical Laboratory
Instructions - Form 2F
Application for Permit to Discharge Storm Water
Associated with Industrial Activity -
Who Must File Form 2F
Form 2F must completed by operators of facilities which discharge storm water associated with Industrial activity
or by operators of storm water discharges that EPA is evaluating for designation of a significant contributor of
pollutants to waters of the United States, or as contributing to a violation of water quality standard
Operators of discharges which are composed entirely of storm water must complete Form 2F (EPA Form 3510 -
2F) in conjunction with Form 1 (EPA From 3510 -1)
Operators of discharges of storm water which are combined with process wastewater (process wastewater Is
water that comes into direct contact with or results from the production or use of any raw material, intermediate
product, finished product, byproduct, waste product, or wastewater) must complete and submit Form 2F, Form
1, and Form 2C (EPA Form 3510 -2C)
Operators of discharges of storm water which are combined with nonprocess wastewater (nonprocess
wastewater Includes noncontact cooling water and sanitary wastes which are not regulated by effluent
guidelines or a new source performance standard, except discharges by educational, medical, or commercial
chemical laboratories) must complete Form 1, Form 2F, and Form 2E (EPA Form 3510 -2E)
Operators of new sources or new discharges of storm water associated with industrial activity which will be
combined with other nonstormwater new sources or new discharges must submit Form 1, Form 2F, and Form
2D (EPA Form 3510 -2D)
Where to File Applications
The application forms should be sent to the EPA Regional Office which covers the State in which the facility is
located Form 2F must be used only when applying for permits in State where the NPDES permits program is
administered by EPA For facilities located in States which are approved to administer the NPDES permits
program, the State environmental agency should be contacted for proper permit application forms and
Instructions
Information on whether a particular program is administered by EPA or by a State agency can be obtained from
your EPA Regional Office Form 1, Table 1 of the "General Instructions" lists the addresses of EPA Regional
Offices and the States within the jurisdiction of each Office
Completeness
Your application will not be considered complete unless you answer every question on this form and on Form 1
If an item does not apply to you, enter "NA" (for not applicable) to show that you considered the question
Public Availability of Submitted Information
You may not claim as confidential any information required by this form or Form 1, or Form 2C you may claim as
confidential, but claims for information which are effluent data will be denied
If you do not assert a claim of confidentiality at the time of submitting the information, EPA may make the
information public without further notice to you Claims of confidentiality will be handled in accordance with
EPA's business confidentiality regulations at 40 CFR Part 2
Definitions
All significant terms used in these instructions and In the form are defined in the glossary found in the General
Instructions which accompany Form 1
EPA ID Number
Fill in your EPA Identification Number at the top of each odd - numbered page of Form 2F You may copy this
number directly from item 1 of Form 1
EPA Form 3510 -2F (Rev 1 -92) Page I -1

Page 39 of 47
Analytical Laboratory
Please print or type in the unshaded areas
EPA ID Number (copy from item 1 of Form 1)
Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
Form
2F
NPDES
United States Environmental Protection Agency
Washington, DC 20460
WIM EPA Application for Permit to Discharge Storm Water
Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average 28 6 hours per application, including time for reviewing instructions, searching existing data
sources, gathenng and maintaining the data needed, and completing and reviewing the collection of information Send comments regarding the burden estimate,
any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to Chief,
Information Policy Branch, PM -223, U S Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Management and Budget, Washington, DC 20503
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water
A Outfall Number
list
B Latitude
C Longitude
D Receiving Water
name
SW 003
II. Improvements
A Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or
operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, sti ulations, court orders, and grant or loan conditions
1 Identification of Conditions,
Agreements, Etc
2 Affected Outfalls
3 Brief Description of Project
4 Final
Com liance Date
number
source of discharge
a req
b proj
B You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges)
you now have under way or which you plan Indicate whether each program is now under way or planned, and indicate your actual or planned
schedules for construction
III. Site Drainage Ma
Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a
topographic map Is unavailable) depicting the facility including each of its intake and discharge structures, the drainage area of each storm
water outfall, paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in stone water runoff,
materials loading and access areas; areas where pesticides, herbicides, soil conditioners and fertilizers are applied, each of its hazardous
waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous
waste under 40 CFR 262 34), each well where fluids from the facility are infected underground, springs, and other surface water bodies which
receive storm water discharges from the facility
EPA Form 3510 -21F (Rev 1 -92) Page 1 of 3 Continued on Page 2

i
Page 40 of 47
Analytical Laboratory
Continued from the Front
IV. Narrative Description of Pollutant Sources
A For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and budding roofs) drained
to the outfall, and an estimate of the total surface area drained by the outfall
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Number
(provide units
(provide units
Number
(provide units
(provide units)
SW003
B Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present materials management
practices employed to minimize contact by these materials with storm water runoff, materials loading and access areas, and the location,
manner, and frequency in which pesticides, herbicides, soil conditioners and fertilizers are applied
C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in
storm water runoff, and a description of the treatment the storm water receives, including the schedule and type of maintenance for
control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge
Outfall
List Codes from
Number
Treatment
Table 217-1
SW003
V. Non Stormwater Dischar es
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C
or Form 2E application for the outfall
Name of Official Title (type or print)
Signature
Date Signed
B provide a description of the method used, the date of any testing, and the onsite drainage points that were directly observed during a test
VI. Significant Leaks or Spills
Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three
ears, including the approximate date and location of the spill or leak, and the type and amount of material released
EPA Form 3510 -2F (Rev 1 -92) Page 2 of 3 Continued on Page 3

.I
Page 41 of 47
Analytical Laboratory
EPA ID Number (copy from Item I of Form 1)
Continued from Page 2
Al. Discharge Information
A,B,C, & D See instruction before proceeding Complete one set of tables for each outfall Annotate the outfall number in the space provided
Tables Vu -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2
E Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F-4, a substance or a component of a
substance which you currently use or manufacture as an intermediate or final product or byproduct?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
VIII. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation to your discharge within the last 3 years?
❑ Yes (list aft such pollutants below) ❑ No (go to Section lX(l
IX. Contact analysis Information
Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm?
® Yes (list the name, address, and telephone number of and pollutants ❑ No (go to Section )(1
analyzed by, each such laborato ry or firm below
A Name
B Address
C Area Code & Phone No
D Pollutants Analyzed
Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 - 875 -9092 Oil &Grease/
Huntersville, NC 28078 Organic
Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176
Asheville, NC 28804 Wet chemistry &
metals
X. Certification
l certify under penalty of law that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete I am aware that there are significant penalties fob submitting false information,
including the possibility of fine and imprisonment for knowing violations
A Name & Official Title (type or punt)
B Area Code and Phone No
C Signature
D Date Signed
EPA Form 3510 -2F (Rev 1 -92) Page 3 of 3

.1 ° 1
EPA ID Number (copy from Item I of Form 1)
Page 42 of 47
Analytical Laboratory
Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
Al. Discharge Information Continued from page 3 of Form 2F
Part A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outfall See
instructions for additional details '
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
Grab Sample
Grab Sample
And
Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Oil & Grease
< 5 0 mg /L
N/A
1
Biological Oxygen
72 9 mg /L
54 9 mg /L
2
Demand BODS
Chemical Oxygen
233 mg /L
104 mg /L
81 mg /L
3
Demand COD
Total Suspended
151 mg /L
8 1 mg /L
2
Solids TSS
Total
8 9 mg /L
2 6 mg /L
2 44 mg /L
3
Nitrogen
Total
1 6 mg /L
0 20 mg /L
0 18 mg /L
3
Phosphorus
pH
Minimum
I Maximum
I Minimum
Maximum
Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES
permit for its process wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall
See the instructions for additional details and re uirements
Maximum Values
Average Values
Number
Pollutant
include units
include units)
Of
Grab Sample
Grab Sample
And
Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Bromide (24959 -67 -9)
Chlorine, Total
residual
Ammonia (as N)
0 80 mg /L
0 27 mg /L
0 026 mg /L
3
Chloride
< 5 0 mg /L
1
Color
40 0 units
1
Fluoride (16984 -48 -8)
Nitrate - Nitrite (as N)
1 2 mg/L
1 3 mg /l
1 04 mg /L
3
Radioactivity, alpha
total
Radioactivity, beta
total
Radioactivity, radium
total
Radioactivity, radium
226 total
Sulfate (as SO.)
10 3 mg /L
1
14808 -79 -8
Sulfite (as SOz)
(14265 -45 -3)
Aluminum, Total
0 753 mg /L
0 897 mg /L
0 631 mg /L
3
7429 -90 -5
Barium, Total
0 115 mg /L
0 0226 mglL
0 0224 mg /L
3
7440 -39 -3
Boron, Total (7440-
0 072 mg /L
<0 050 mg /L
<0 050 mg /L
3
42 -8
Cobalt, Total (7440-
<0 005 mg/L
<0 005 mg /L
<0 005 mg /L
3
48-4
Iron, Total (7439 -89-6)
21 2 mg /L
0 999 mg /L
0 723 mg /L
3
Magnesium, Total
9 57 mg /L
1 21 mg /L
1 07 mg /L
3
7439 -95 -4
Magnesium,
Dissolved
Molybdenum, Total
7439 -98 -7
Manganese, Total
1 38 mg /L
0 0792 mg /L
0 0604 mg /L
3
7439 -96 -5
EPA Form 3510 -21F (Rev 1 -92) Page VII -1 Continue on Reverse

Page 43 of 47
Analytical Laboratory
Tin, Total
<0 005 mg /L
<0 005 mg /L
<0 005 mg /L
3
7440 -31 -5
Titanium, Total
0 0299 mg /L
0 0403 mg /L
0 0267 mg /L
3
7440 -32 -6
Antimony, Total
7440 -36 -0
Arsenic, Total
0 005 mg /L
<0 005 mg /L
<0 005 mg/l.
3
7440 -38 -2
Beryllium, Total
7440 -41 -7
Cadmium, Total
<0 001 mg /L
<0 001 mg /L
<0 001 mg /L
3
7440 -43 -9
Chromium, Total
<0 005 mg /L
<0 005 mg /L
<0 005 mg /L
3
7440 -47 -3
Copper, Total
0 0533 mg /L
0 0182 mg /L
0 0167 mg /L
3
7440 -50 -8
Lead, Total
7439 -92 -1
Mercury, Total
<0 200 ug /L
<0 200 ug /L
<0 200 ug /L
3
7439 -97 -6
Nickel, Total
0 0068 mg/L.
<0 005 mg /L
<0 005 mg /L
3
7440 -02 -0
Selenium, Total
<0 010 mg /L
<0 010 mg/L.
<0 010 mg /L
3
7782 -49 -2
Silver, Total
<0 005 mg /L
<0 005 mg /L
<0 005 mg /L
3
7440 -22 -4
Thallium, Total
7440 -28 -0
Zinc, Total
2 29 mg /L
0 758 mg /L
0 753 mg /L
3
7440 -66 -6)
EPA Form 3510 -2F (Rev 1 -92) Page VII -1 Continue on Reverse

Page 44 of 47
Analytical Laboratory
Continued from the Front
Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F-4 that you know or have reason to believe is present See the instructions for
additional details and requirements Com fete one table for each outfall
Pollutant
And
CAS Number
(if available)
Maximum Values
include units
Average Values
(include units)
Number
Of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Cyanide, Total
57 -12 -5
Phenols, Total
0 045 mg /L
1
Surfactants (MBAs)
Total Dissolved Solids
Total Organic Carbon
Total Kleldahl
TKN
7 7 mg /L
1 5 mg /L
1 4 mg /L
3
-Nitrogen
Fecal Coliform
100 CFU /100
mL
1
Part D - Provide data for the storm events which resulted in the maximum values for the flow weighted com osite sample
1
Date of
Storm
Event
2
Duration
of Storm Event
(in minutes
( )
3
Total rainfall
during storm event
(�n inches)
4
Number of hours between
beginning of storm measured
and end of previous
measurable rain event
5
Total flow from
rain event
(gallons or specify units)
7 Provide a description of the method of flow measurement or estimate
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

Page 45 of 47
Analytical Laboratory
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

OUTFALL
SAMPLED
SAMPLE
COLLECTION DATE
SAMPLE
TYPE
ANALYSES
SW002
July 29, 2008
Grab
ASTM D516 -90
EPA 1664A
EPA 350 1
EPA 353 2
SM 2120B
SM2540D
SM 4500 -CI -E
SW003
July 29, 2008
Composite
ASTM D516 -90
EPA 200 7
EPA 245 1
EPA 350 1
EPA 3512
EPA 353 2
EPA 365 1
SM 2120B
S M 2540 D
SM 4500 -CI -E
SM 5220D

mh Duke .Analytical Laboratory
PER 13339 ille, N Ferry Road
Huntersville, NC 28078 -7929
Rev 07 -09 -07 McGuire Nuclear Complex — MG03A2
Phone [phone] Fax 704 - 875 -5038
Job Summary Report
Job Number: 08 -JUL -0641
Project Name:
Customer Name:
Copy To:
Customer Address:
Rlverbend Stormwater (7/29)
Brandy Starnes
Steve Jones,
Rlverbend Steam Station
Lab Contact: Mary Ann Ogle
Lab Contact Phone: 704 - 875 -5274
Report Authorized By:
(Printed Name)
MARY ANN OGLE
Page 1 of 47
Analytical Laboratory
Report Authorized By:
(Signature) CAV_'�� G Date 1041210%
Data Package
This data package includes analytical results that are applicable only to the samples
described In this narrative An estimation of the uncertainty of measurement for the
results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory Please contact the
Analytical Laboratory with any questions. The order of Individual sections within this
report is as follows-
Job Summary Report
Analytical Laboratory Certificate ofAnalysis
Analytical Laboratory QC Reports (if applicable)
Sub - contracted Laboratory Results
Customer Specific Data Sheets, Reports & Documentation (if applicable)
Customer Database Entries
Test Case Narratives
Chain of Custody (COQ

,4
Page 2 of 47
Analytical Laboratory
Duke Analytical Laboratory
Energy® 13339 ille Ferry Road
Huntersville, NC 28078 -7929
iA- 07 -09 -07 McGuire Nuclear Complex— MG03A2
Phone 704 - 875 -5245 Fax 704 - 875 -5038
I
Job Summary Report
Certification
The Analytical Laboratory holds the following Certifications
Netiv York State Department of Health Cert fcation # 11717(2VELAC)
North Carolina Department of Health & Human Services Certification # 37804
South Carolina (DHEC) Laboratory ID # 99005 -
North Carolina (DENR) Certification # 248
Analytical results listed in this report may not be certified by the authorities referenced above
Contact the Analytical Laboratory for definitive information about the certification status of
specific methods The results meet all requirements ofNELAC except where deviations are
noted in this report
Data Flags
Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a
deviation from the method quality system or quality control requirement
Calculations
All results are reported on a wet weight basis unless otherwise noted
Sample ID's & Descrintions:
Collection
Sample
Sample ID Plant /Station
--- - - - - -- ------- - - - - --
Date Collected By
- --- - - - - -- ------
Description
28021487 FOSSIL
- - - - --
7/29/2008 B STARNES
----- - - - - --
SWO02 (GRAB)
RIVERBEND
28021488 FOSSIL
7/29/2008 B STARNES
SWO03 (COMP)
RIVERBEND
-----------------
3 TOTAL SAMPLES

f
I
Page 3 of 47
Analytical Laboratory
Duke Analytical Laboratory
®Energy ® H 13339 Ferry Road
untersvilleille, NC 28078 -7929
Rev 07 -09 -07 McGuire Nuclear Complex — MG03A2 ,
Phone 704 - 875 -5245 Fax 704 - 875 -5038
Job Summary Report
Validation of Analytical Data Package
COC and pdf report are in agreement with sample totals
0
1✓ Yes
" No
and analyses (compliance programs and procedures).
Job Summary Report
ii) All results are less than the laboratory reporting limits.
1" Yes
,No
iii) All laboratory QA/QC requirements are acceptable
Documentation (if applicable)
Fr '
NPDES and TCLP results are below permit or regulatory
iv
r Yes
No
limits respectively
Analytical Laboratory QC Report
(-
li iv) above is No, document below
Permit
Variable Result Llmlt Notes
Components of the Job Summary Report arranged in order
V) stipulated on page one r Yes f No
Indicate components included
)v
Job Summary Report
Customer Specific Data Sheets, Reports &
Documentation (if applicable)
Analytical Laboratory Certificate of
Analysis
Customer Database Entries
Analytical Laboratory QC Report
(-
Test Case Narratives
(if applicable)
Sub - contracted Laboratory Results
j,7
Chain of Custody
vi) Notes and Additional Information
This is a partial report for SW 002 and SW 003 The other reports for this outfall are 08 -JUL -0149 and 08-
JUN -0400
The following parameters contained quality control failures for matrix spike recovery, but the spike was not
performed on this sample TP The following parameters contained quality control failures for duplicate relative
percent difference, the quality control was not performed on this sample metals These quality control failures
should be documented when reporting result, but these results are still considered valid
Mary Ann Ogle
Duke Energy Analytical Lab
NPDES Contact Office 704 - 875 -5274 Cell 704 - 280 -7956
NA--Not applicable

aceAnalytical
wwwpecelabs.com
r
August 13, 2008
Mr Jay Perkins
Duke Energy
13339 Hagers Ferry Road
Bldg 7405 MG30A2
Huntersvdle, NC 28078
RE Project 08 -JUL -0641
Pace Project No 9224413
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
Page 4 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersvdle NC 28078
Dear Mr Perkins
Enclosed are the analytical results for sample(s) received by the laboratory on July 30, 2008 The
results relate only to the samples included in this report Results reported herein conform to the
most current NELAC standards, where applicable, unless otherw Ise narrated in the body of the
report
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersvdle laboratory unless otherwise footnoted All
Microbiological analyses were performed at the laboratory where the samples were received
If you have any questions concerning this report, please feel free to contact me
Sincerely,
Renee Spencer for
Kevin Herring
kevin herring @pacel abs com
Project Manager
Enclosures
cc Accounts Payable DPEHS, Duke Energy Carolinas, LLC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
(704)875 -9092
Page 1 of 23

I
I
aceAnalytical e
mm pacelabs corn
Project 08 -JUL -0641
Pace Project No 9224413
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
CERTIFICATIONS
Page 5 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Charlotte Certification IDs
Connecticut Certification Number PH -0104
North Carolina Field Services Certification Number 5342
Pennsylvania Certification Number 68 -00784
North Carolina Wastewater Certification Number 12
West Virginia Certification Number 357
North Carolina Drinking Water Certification Number 37706
Virginia Certification Number 00213
Louisiana/LELAP Certification Number 04034
Tennessee Certification Number 04010
Kentucky UST Certification Number 84
South Carolina Bioassay Certification Number 990060003
New Jersey Certification Number NC012
South Carolina Certification Number 990060001
Flonda/NELAP Certification Number E87627
Asheville Certification IDs
Connecticut Certification Number PH -0106
Massachusetts Certification Number M -NC030
West Virginia Certification Number 356
Virginia Certification Number 00072
Tennessee Certification Number 2980
South Carolina Bioassay Certification Number 99030002
South Carolina Certification Number 99030001
Eden Certification IDs
Virginia Drinking Water Certification Number 00424
North Carolina Wastewater Certification Number 633
Pennsylvania Certification Number 68 -03578
North Carolina Bioassay Certification Number 9
North Carolina Wastewater Certification Number 40
North Carolina Drinking Water Certification Number 37712
New Jersey Certification Number NC011
Louisiana /LELAP Certification Number 03095
Flonda/NELAP Certification Number E87648
North Carolina Drinking Water Certification Number 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 2 of 23

i
1
Page 6 of 47
Analytical Laboratory
1
I®
Pace Analytical Services, Inc
Pace Analytical Services, Inc
aceAnalytical
2225 Riverside Dr
9800 Kincey Ave Suite '100
wwwpacerab&cam
Asheville, NC 28804
Huntersville NC 28078
(828)254 -7176
(704)875 -9092
t
SAMPLE SUMMARY
Project 08 -JUL -0641
Pace Project No 9224413
Lab ID Sample ID
Matrix Date Collected
Date Received
9224413001 SWO02
Water 07/29/08 12 20
07/30/08 11 39
9224413002 SWO03
Water 07/29/08 12 30
07/30/08 11 39
REPORT OF LABORATORY ANALYSIS Page 3 of 23
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc
ice•,
°�ec

Page 7 of 47
Analytical Laboratory
e Pace Analytical Services, Inc Pace Analytical Services, Inc
,.f aeeAnalytical 2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacelabs.com
Asheville, NC 28804 Hunterswlle NC 28078
(828)254 -7176 [phone]
Project
08 -JUL -0641
Pace Protect No
9224413
SAP
1
Lab ID
Sample ID
9224413001
SWO02
9224413002 SWO03
SAMPLE ANALYTE COUNT
Method
Analysts
Analytes
Reported
ASTM D516 -90
SAP
1
EPA 1664A
DNP
1
EPA 350 1
RAB
1
EPA 353 2
JDA
1
SM 2120B
SAJ
1
SM 2540D
RAB
1
SM 4500 -CI -E
SAP
1
ASTM D516 -90
SAP
1
EPA 200 7
EWS
17
EPA 245 1
SHB
1
EPA 350 1
RAB
1
EPA 351 2
JDA
1
EPA 353 2
JDA
1
EPA 365 1
SER
1
SM 21206
SAJ
1
SM 2540D
RAB
1
SM 4500 -CI -E
SAP
1
SM 5220D
DMN
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 4 of 23

i Page 8 of 47
Analytical Laboratory
e Pace Analytical Services, Inc Pace Analytical Services, Inc
/ aceAnalytical 2225 Riverside Dr 9800 Kincey Ave Suite 100
lwwwpawfabscan Asheville, NC 28804 Huntersville, NC 28078
(828)254 -7176 (704)875 -9092
ANALYTICAL RESULTS
Project 08-JUL -0641
Pace Project No 9224413
Sample SWO02
Lab ID 9224413001 Collected
07/29/08 12 20
Received 07130108 11 39 Matrix Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed CAS No Qual
HEM, Oil and Grease
Analytical Method EPA 1664A
Oil and Grease
ND mg /L 50
1 1
1
07/31/08 09 55
21208 W Apparent Color
Analytical Method SM 21208
Apparent Color
ND units 50
1
07/31/08 09 43
2540D Total Suspended Solids
Analytical Method SM 2540D
Total Suspended Solids
13 1 mg /L 22
1
07131/08 22 45
350 1 Ammonia
Analytical Method EPA 350 1
Nitrogen, Ammonia
0 90 mg /L 010
010
1
08/06/08 20 32 7764 -41 -7
353 2 Nitrogen, N021NO3 pres
Analytical Method EPA 353 2
Nitrogen, NO2 plus NO3
10 mg /L 010
010
1
08103/08 13 15
4500 Chloride
Analytical Method SM 4500 -CI -E
Chloride
ND mg /L 50
50
1
08/04/08 16 06 16887 -00 -6
ASTM D516 -90 Sulfate Water
Analytical Method ASTM D516 -90
Sulfate
17 3 mg /L 50
50
1
08/07/08 17 55 14808 -79 -8
Date 08/13/2008 1010 AM REPORT OF LABORATORY ANALYSIS Page 5 of 23
This report shall not be reproduced except in full
without the written consent of Pace Analytical Services, Inc

Page 9 of 47
Analytical Laboratory
Pace Analytical Services, Inc Pace Analytical Services, Inc
i
�MAnalAcal" 2225 Riverside Or 9800 Kincey Ave Suite 100
r wwwpace1a6s.cem
Asheville, NC 28804 Huntersville, NC 28078
(828)254 -7176 (704)875 -9092
ANALYTICAL RESULTS
Project 08 -JUL -0641
Pace Project No 9224413
Sample SWO03
Lab ID. 9224413002 Collected
07/29/08 12 30
Received 07/30/08 1139 Matrix Water
Report
Parameters
Results Units Limit
MDL
OF
Prepared
Analyzed CAS No Qual
200 7 MET ICP
Analytical Method EPA 200 7 Preparation Method EPA 200 7
Aluminum
366 ug /L
100
25 0
1
08/04/08 10 10
08/11/08 16 04 7429 -90 -5
Arsenic
NO ug /L
5 0
2 7
1
08/04108 10 10
08111108 16 04 7440 -38 -2
Barium
226 ug /L
5 0
020
1
08/04/08 10 10
08/11/08 16 04 7440 -39 -3
Boron
NO ug /L
500
4 7
1
08104/08 10 10
08/11/08 16 04 7440 -42 -8
Cadmium
NO ug /L
10
0 50
1
08/04/08 10 10
08/11/08 16 04 7440 -43 -9
Chromium
NO ug /L
5 0
040
1
08/04/08 10 10
08/11/08 16 04 7440 -47 -3
Cobalt
NO ug /L
5 0
060
1
08104108 10 10
08/11/08 16 04 7440 -48 -4
Copper
153 ug /L
5 0
030
1
08/04/08 10 10
08/11/08 16 04 7440 -50 -8
Iron
447 ug /L
500
140
1
08104/08 10 10
08/11/08 16 04 7439 -89 -6
Magnesium
1210 ug /L
100
3 0
1
08/04/08 10 10
08/11/08 16 04 7439 -95 -4
Manganese
07 ug /L
50
030
1
08/04/08 10 10
08/11/08 16 04 7439 -96 -5
Nickel
NO ug /L
50
17
1
08/04/08 10 10
08/11/08 16 04 7440 -02 -0
Selenium
NO ug /L
100
38
1
08/04108 10 10
08/11/08 16 04 7782 -49 -2
Silver
NO ug /L
50
010
1
08/04/08 10 10
08/11/08 16 04 7440 -22 -4
Tin
NO ug /L
50
1 8
1
08/04/08 10 10
08/11/08 16 04 7440 -31 -5
Titanium
132 ug /L
50
010
1
08/04/08 10 10
08/11/08 16 04 7440 -32 -6
Zinc
748 ug /L
100
040
1
08/04108 10 10
08/11/08 16 04 7440 -66 -6
245 1 Mercury
Analytical Method EPA 245 1
Preparation Method EPA 245 1
Mercury
NO ug /L
020
020
1
08/04/08 12 30
08/06/08 10 12 7439 -97 -6
21208 W Apparent Color
Analytical Method SM 2120B
Apparent Color
40 0 units
50
1
07/31/08 09 43
25400 Total Suspended Solids
Analytical Method SM 2540D
Total Suspended Solids
8 1 mg /L
21
1
07/31/08 22 46
350 1 Ammonia
Analytical Method EPA 350 1
Nitrogen, Ammonia
0 27 mg /L
010
010
1
08/06/08 20 33 7764 -41 -7
351 2 Total Kjeldahl Nitrogen
Analytical Method EPA 3512
Nitrogen, Kjeldahl, Total
13 mg /L
050
050
1
08/12/08 11 11 7727 -37 -9
353 2 Nitrogen, NO2/NO3 pres
Analytical Method EPA 353 2
Nitrogen, NO2 plus NO3
13 mg /L
010
010
1
08/09108 13 56
3651 Phosphorus, Total
Analytical Method EPA 365 1
Phosphorus
0 20 mg /L
010
010
1
08/08/08 17 54 7723 -14 -0
4500 Chloride
Analytical Method SM 4500 -CI -E
Chloride
NO mg /L
50
50
1
08/04108 16 06 16887 -00 -6
5220D COD
Analytical Method SM 5220D
Chemical Oxygen Demand
104 mg /L
250
250
1
08/08/08 20 05
Date 08/1312008 1010 AM REPORT OF LABORATORY ANALYSIS Page 6 of 23
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc

Page 10 of 47
Analytical Laboratory
o
wwwpacelabacom Pace Analytical Services, Inc Pace Analytical Services, Inc
�aceAnalytical 2225 Riverside Or 9800 KnceyAve Suite 100
Asheville, NC 28804 Huntersvdle, NC 28078
(828)2547178 (704)875 -9092
ANALYTICAL RESULTS
Project 08 -JUL -0641
Pace Project No 9224413
Sample SWO03 Lab ID 9224413002 Collected 07/29/08 12 30 Received 07/30/08 11 39 Matrix Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No Qual
ASTM D516 -90 Sulfate Water Analytical Method ASTM D516 -90
Sulfate 10 3 mg /L 5 0 5 0 1 08/07/08 17 55 14808 -79 -8
Date 08/13/200810 10 AM REPORT OF LABORATORY ANALYSIS Page 7 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
�� 66

I
)
C
;aceAnalytIcal
iMwpacelabs com
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch WET /4880
QC Batch Method SM 2120B
Associated Lab Samples 9224413001, 9224413002
METHOD BLANK 146985
Associated Lab Samples 9224413001, 9224413002
Parameter Units
Apparent Color units
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Analysis Method SM 2120B
Analysis Description 2120B Color
Blank Reporting
Result Limit Qualifiers
ND 50
Page 11 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
SAMPLE DUPLICATE 146986
9224413001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Apparent Color units NO ND 0 20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 8 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

aceAnalytical
wwwpacelebscan
I
I
Project 08 -JUL -0641
Pace Project No 9224413
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
QC Batch GCSV /3368 Analysis Method EPA 1664A
QC Batch Method EPA 1664A Analysis Description 1664 HEM, Oil and Grease
Associated Lab Samples 9224413001
METHOD BLANK 147077
Associated Lab Samples 9224413001
Blank Reporting
Parameter Units Result Limit Qualifiers
Oil and Grease mg /L ND 50
Page 12 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE & LCSD 147078 147079
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc Result Result % Rec % Rec Limits RPD RPD Qualifiers
Oil and Grease mg /L 40 375 377 94 94 78 -114 5 30
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
r
without the written consent of Pace Analytical Services, Inc
A "o'
Page 9 of 23

Page 13 of 47
Analytical Laboratory
e Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytical 2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacalabsccm Asheville. NC 28804 Huntersville NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch WET /4902 Analysis Method SM 2540D
QC Batch Method SM 2540D Analysts Description 2540D Total Suspended Solids
Associated Lab Samples 9224413001, 9224413002
METHOD BLANK 147617
Associated Lab Samples 9224413001, 9224413002
Blank Reporting
Parameter Units Result Limit Qualifiers
Total Suspended Solids mg /L ND 10
LABORATORY CONTROL SAMPLE 147618
Parameter Units
Total Suspended Solids mg /L
SAMPLE DUPLICATE 147619
Parameter Units
Total Suspended Solids mg /L
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
250 262 105 80 -120
9224329003 Dup Max
Result Result RPD RPD Qualifiers
142 144 1 20
Date 08/13/2008 1010 AM REPORT OF LABORATORY ANALYSIS Page 10 of 23
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc
Yll_IGiG���

Page 14 of 47
Analytical Laboratory
Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytical ® 2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacelab&cam Asheville, NC 28804 Huntersvllle, NC 28078
i (828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch WETA/3198
Analysis Method
EPA 353 2
QC Batch Method EPA 353 2
Analysis Description
353 2 Nitrate + Nitrite,
preserved
Associated Lab Samples 9224413001
METHOD BLANK 148319
Associated Lab Samples 9224413001
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND
010
LABORATORY CONTROL SAMPLE
148320
Spike LCS
LCS
% Rec
Parameter
Units
Cone Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
5 51
102
90 -110
MATRIX SPIKE SAMPLE
148321
9224499001 Spike
MS
MS
% Rec
Parameter
Units
Result Cone
Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND
5 52
105
75 -125
MATRIX SPIKE SAMPLE
148323
9224500006 Spike
MS
MS
% Rec
Parameter
Units
Result Cone
Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
022
5 58
112
75 -125
SAMPLE DUPLICATE 148322
9224499002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND
ND 0
20
SAMPLE DUPLICATE 148324
9224373002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND
ND 0
20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 11 of 23
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc
s`iAea

i
I
�aceAnalytical'
i
WW pacefabs com
Project 08 -JUL -0641
Pace Project No 9224413
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
QC Batch MPRP /2771 Analysis Method EPA 200 7
QC Batch Method EPA 200 7 Analysis Description 200 7 MET
Associated Lab Samples 9224413002
METHOD BLANK 148418
Associated Lab Samples 9224413002
Parameter
Units
Aluminum
ug /L
Arsenic
ug /L
Barium
ug /L
Boron
ug /L
Cadmium
ug /L
Chromium
ug /L
Cobalt
ug /L
Copper
ug /L
Iron
ug /L
Magnesium
ug /L
Manganese
ug /L
Nickel
ug /L
Selenium
ug /L
Silver
ug /L
Tin
ug /L
Titanium
ug /L
Zinc
ug /L
LABORATORY CONTROL SAMPLE
148419
Parameter
Units
Aluminum
ug /L
Arsenic
ug/L
Barium
ug /L
Boron
ug /L
Cadmium
ug /L
Chromium
ug /L
Cobalt
ug /L
Copper
ug /L
Iron
ug /L
Magnesium
ug /L
Manganese
ug /L
Nickel
ug /L
Selenium
ug /L
Silver
ug /L
Tin
ug /L
Titanium
ug/L
Zinc
ug /L
Page 15 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Swte 100
Hunterswlle NC 28078
(704)875 -9092
Blank
Reporting
Result
Limit
Qualifiers
NO
100
NO
50
NO
so
NO
500
ND
10
NO
50
NO
50
NO
50
NO
500
NO
100
NO
50
NO
50
ND
100
NO
50
NO
50
NO
50
NO
100
Spike
LCS
LCS
% Rec
Conc
Result
% Rec
Limits Qualifiers
5000
4600
92
85 -115
500
466
93
85 -115
500
470
94
85 -115
500
480
96
85 -115
500
452
90
85 -115
500
464
93
85 -115
500
469
94
85 -115
500
480
96
85 -115
5000
4830
97
85 -115
5000
4660
93
85 -115
500
462
92
85 -115
500
456
91
85 -115
500
462
92
85 -115
250
235
94
85 -115
500
459
92
85 -115
500
476
95
85 -115
500
456
91
85 -115
Date 08/1312008 1010 AM REPORT OF LABORATORY ANALYSIS Page 12 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

Page 16 of 47
Analytical Laboratory
® Pace Analytical Services, Inc Pace Analytical Services, Inc
�
. aceAnalytfcal 2225 Riverside Or 9800 Kincey Ave Suite 100
iwiwpacalabs.ccm Asheville NC 28804 Huntersville NC 28078
r (828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -JUL -0641
Units
9224415001
Result
Dup
Result
Max
RPD RPD Qualifiers
Aluminum
ug /L
Pace Project No 9224413
905
2 20
Arsenic
ug /L
NO
NO
MATRIX SPIKE SAMPLE
148420
ug/L
41 4
405
2 ` _ 20
Boron
ug /L
511
9224413002
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone
Result
% Rec
Limits Qualifiers
Aluminum
ug /L
366
5000
5200
97
70 -130
Arsenic
ug /L
NO
500
471
94
70 -130
Barium
ug /L
226
500
483
92
70 -130
Boron
ug /L
NO
500
500
93
70 -130
Cadmium
ug /L
NO
500
450
90
70 -130
Chromium
ug /L
NO
500
461
92
70 -130
Cobalt
ug /L
NO
500
465
93
70 -130
Copper
ug /L
153
500
493
96
70 -130
Iron
ug /L
447
5000
5250
96
70 -130
Magnesium
ug /L
1210
5000
5820
92
70 -130
Manganese
ug /L
41 7
500
492
90
70 -130
Nickel
ug /L
NO
500
455
91
70 -130
Selenium
ug /L
NO
500
470
93
70 -130
Silver
ug /L
NO
250
234
94
70 -130
Tin
ug /L
NO
500
458
92
70 -130
Titanium
ug /L
132
500
484
94
70 -130
Zinc
ug /L
748
500
1210
93
70 -130
SAMPLE DUPLICATE 148421
Parameter
Units
9224415001
Result
Dup
Result
Max
RPD RPD Qualifiers
Aluminum
ug /L
925
905
2 20
Arsenic
ug /L
NO
NO
1131 .4 20' R3 1
Barium
ug/L
41 4
405
2 ` _ 20
Boron
ug /L
511
48J
6 20
Cadmium
ug /L
NO
NO
0 20
Chromium
ug /L
NO
NO
0 20
Cobalt
ug /L
56
61
8 20
Copper
ug /L
NO
12J
12 20
Iron
ug /L
946
933
1 20
Magnesium
ug /L
1270
1240
2 20
Manganese
ug/L
413
406
2 20
Nickel
ug /L
514
506
2 20
Selenium
ug /L
NO
NO
200, = - 20 R3
Silver
ug/L
NO
NO
-69- _,, _ '20,R3`
Tin
ug /L
NO
NO
148 y _20 R3,
Titanium
ug /L
NO
52J
19 20
Zinc
ug /L
802
764
5 20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 13 of 23
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc

i Page 17 of 47
Analytical Laboratory
e Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytical 2225 Riverside Dr 9800 Kmcey Ave Suite 100
wwwpacelabs cam Asheville NC 28804 Huntersville NC 28078
(828)254 -7176 (704)875 -9092
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch MERP /1624
QC Batch Method EPA 245 1
Associated Lab Samples 9224413002
METHOD BLANK 148450
Associated Lab Samples 9224413002
Parameter Units
Mercury ug /L
LABORATORY CONTROL SAMPLE 148451
Parameter Units
Mercury ug /L
QUALITY CONTROL DATA
Analysis Method EPA 245 1
Analysis Description 245 1 Mercury
Blank Reporting
Result Limit Qualifiers
ND 020
Spike LCS LCS % Rec
Cone Result % Rec Limits Qualifiers
25 25 102 85 -115
MATRIX SPIKE SAMPLE 148452
9223856007 Spike MS MS % Rec
Parameter Units Result Cone Result % Rec Limits Qualifiers
Mercury ug /L NO 25 2 0 77 70 -130
SAMPLE DUPLICATE 148453
Parameter
Mercury
9224516001 Dup Max
Units Result Result RPD RPD Qualifiers
ug /L ND ND 16 20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 14 of 23
This report shall not be reproduced except in full,
without the written consent of �Pace Analytical Services, Inc

I
I
11r aceAnalydcal e
—pacelab&com
Project 08 -JUL -0641
Pace Project No 9224413
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch WETA13200 Analysis Method SM 4500 -CI -E
QC Batch Method SM 4500 -CI -E Analysis Description 4500 Chloride
Associated Lab Samples 9224413001, 9224413002
METHOD BLANK 148478
Associated Lab Samples 9224413001, 9224413002
Blank Reporting
Parameter Units Result Limit Qualifiers
Chloride mg /L ND 50
LABORATORY CONTROL SAMPLE
148479
Parameter
Units
Chloride
mg /L
MATRIX SPIKE SAMPLE
148480
Parameter
Units
Chloride
mg /L
SAMPLE DUPLICATE 148481
Parameter
Units
Chloride
mg /L
Page 18 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville NC 28078
(704)8759092
Spike LCS LCS % Rec
Conc Result % Rec Limits Qualifiers
20 203 101 90 -110
9224054001 Spike MS MS % Rec
Result Conc Result % Rec Limits Qualifiers
138 20 316 89 75 -125
9224054002 Dup Max
Result Result RPD RPD Qualifiers
164 166 9 20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 15 of 23

Page 19 of 47
f Analytical Laboratory
ii a Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytica! 2225 Riverside Dr 9800 Kincey Ave Swte 100
wwwpacefabscam Asheville, NC 28804 Hunterswlle, NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch WETA/3207 Analysis Method EPA 365 1
QC Batch Method EPA 365 1 Analysis Description 365 1 Phosphorus, Total
Associated Lab Samples 9224413002
METHOD BLANK 148728
148732
Associated Lab Samples 9224413002
9224586017
Spike
MS
MS
Blank Reporting
Parameter
Units
Result
Parameter
Units
Result Limit
Qualifiers
Phosphorus
mg /L
Phosphorus
mg /L
ND 010
»88, , v 90µ110: MO_
SAMPLE DUPLICATE 148731
LABORATORY CONTROL SAMPLE
148729
Spike LCS
LCS
% Rec
Max
Parameter
Units
Cone Result
% Rec
Limits
Qualifiers
Phosphorus
mg /L
1 092
92
90 -110
NO
146
20
MATRIX SPIKE SAMPLE
148730
SAMPLE DUPLICATE 148733
9224586007 Spike
MS
MS
% Rec
Parameter
Units
Result Cone
Result
% Rec
Limits Qualifiers
Phosphorus
mg /L
ND 1
083
78'.
-d -- 90 -110 MO,
MATRIX SPIKE SAMPLE
148732
9224586017
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone
Result
% Rec
Limits Qualifiers
Phosphorus
mg /L
0 31
1
1 2
»88, , v 90µ110: MO_
SAMPLE DUPLICATE 148731
9224586008
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Phosphorus
mg /L
ND
NO
146
20
SAMPLE DUPLICATE 148733
9224586018
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Phosphorus
mg /L
043
039
10
20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 16 of 23
This report shall not be reproduced, except in full,
without the written consent of Pars Analytical Services, Inc

I
Page 20 of 47
Analytical Laboratory / ® Pace Analytical Services, Inc Pace Analytical Services, Inc
f , . aceAnalytical 2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacetabscom Asheville. NC 28804 Huntersville, NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -JUL -0641
149964
Pace Project No 9224413
QC Batch WETA/3215
Analysis Method
EPA 3501
QC Batch Method EPA 350 1
Analysis Description
350 1 Ammonia
Associated Lab Samples 9224413001, 9224413002
MS
METHOD BLANK 149962
Parameter
Units
Associated Lab Samples 9224413001, 9224413002
Conc
Result
% Rec
Blank Reporbng
Limits Qualifiers
Parameter Units
Result Limit
Qualifiers
Nitrogen, Ammonia mg /L
ND 010
93
90 -110
LABORATORY CONTROL SAMPLE 149963
149966
Spike LCS
LCS % Rec
Parameter Units
Conc Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg /L
5 51
103 90 -110
MATRIX SPIKE SAMPLE
149964
9224836001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg /L
019
5
4 8
93
90 -110
MATRIX SPIKE SAMPLE
149966
9224482001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg /L
ND
5
4 9
99
90 -110
SAMPLE DUPLICATE 149965
9224411001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg /L
ND
ND
5
20
SAMPLE DUPLICATE 149967
9224598001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg /L
037
037
1
20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 17 of 23
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc

Page 21 of 47
I Analytical Laboratory
e Pace Analytical Services, Inc Pace Analytical Services, Inc
.' aceAnalydcal 2225 Riverside Dr 9800 Kmcey Ave Suite 100
wwwpacefa6scom Asheville, NC 28804 Huntersville NC 28078
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch WETA13222
Analysis Method ASTM D516 -90
QC Batch Method ASTM D516 -90
Analysis Description ASTM D516 -90 Sulfate
Water
Associated Lab Samples 9224413001, 9224413002
METHOD BLANK 150030
Associated Lab Samples 9224413001, 9224413002
Blank Reporting
Parameter
Units
Result Limit Qualifiers
Sulfate
mg /L
ND 50
LABORATORY CONTROL SAMPLE
150031
Spike LCS LCS
% Rec
Parameter
Units
Conc Result % Rec
Limits
Qualifiers
Sulfate
mg /L
20 190 95
90 -110
MATRIX SPIKE SAMPLE
150032
9224836001 Spike MS
MS
% Rec
Parameter
Units
Result Conc Result
% Rec
Limits Qualifiers
Sulfate
mg /L
ND 20 197
90 75 -125
SAMPLE DUPLICATE 150033
9224776003 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Sulfate
mg /L
11 9 120 4
20
SAMPLE DUPLICATE 150571
9224928002 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Sulfate
mg /L
337 339 7
20
Date 08/13/2008 10 10 AM
REPORT OF LABORATORY ANALYSIS
Page 18 of 23
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc
h66

aceAnalytical
www pacelabs com
Project 08-JUL -0641
Pace Project No 9224413
QC Batch WETA/3236
QC Batch Method SM 52200
Associated Lab Samples 9224413002
METHOD BLANK 151412
Associated Lab Samples 9224413002
Parameter Units
Chemical Oxygen Demand mg /L
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Analysis Method SM 5220D
Analysis Description 5220D COD
Blank Reporting
Result Limit Qualifiers
ND 250
Page 22 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersville NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE
151413
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Chemical Oxygen Demand ,
mg /L
750
758
101
90 -110
MATRIX SPIKE SAMPLE
151414
9224345001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand
mg /L
129
750
853
97 75 -125
MATRIX SPIKE SAMPLE
151416
9224940001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Chemical Oxygen Demand
mg /L
8180
6000
13300
85 75 -125
SAMPLE DUPLICATE 151415
9224355001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Chemical Oxygen Demand
mg /L
ND
ND
0
20
SAMPLE DUPLICATE 151417
9224942002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Chemical Oxygen Demand
mg /L
375
364
3
20
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 19 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

i4
I
I
f 4nalytical
r� wmApacefabs.ccm
r
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Page 23 of 47
Analytical Laboratory
Pace Analytical Services, Inc
98001(inceyAve Suite 100
Huntersville NC 28078
[phone]
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch WETA13239
Analysis Method
EPA 353 2
QC Batch Method EPA 353 2
Analysis Description
353 2 Nitrate + Nitrite,
preserved
Associated Lab Samples 9224413002
METHOD BLANK 151542
Associated Lab Samples 9224413002
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND 010
LABORATORY CONTROL SAMPLE
151543
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
5 54
107
90 -110
MATRIX SPIKE SAMPLE
151544
9224740001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
NO
5 5 3
106
75 -125
MATRIX SPIKE SAMPLE
151546
9224740011 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND
5 56
112
75 -125
SAMPLE DUPLICATE 151545
9224740002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
NO
ND 0
20
SAMPLE DUPLICATE 151547
9224413002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
1 3
1 3 0
20
Date 08113/2008 10 10 AM
REPORT OF LABORATORY ANALYSIS
Page 20 of 23
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

I
, aceAnalytical
I
� wwwpaceJabs com
Project 08 -JUL -0641
Pace Project No 9224413
QC Batch WETA/3244
QC Batch Method EPA 351 2
Associated Lab Samples 9224413002
METHOD BLANK 151749
Associated Lab Samples 9224413002
Parameter Units
Nitrogen, Kjeldahl, Total mg /L
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Analysis Method EPA 351 2
Analysis Description 3512 TKN
Blank Reporting
Result Limit Qualifiers
ND 050
Page 24 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE
151750
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
5
45
91
90 -110
MATRIX SPIKE SAMPLE
151751
9224601005
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
375
5
534
318, „',A,90-1101W,
5/A 0*
5
MATRIX SPIKE SAMPLE
151754
9224740010
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
ND
5
51
94 90 -110
SAMPLE DUPLICATE 151752
9224601006
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
383
403
5
20
SAMPLE DUPLICATE 151753
9224740009
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
094
057
49
20
Date 08/13/2008 10 10 AM
REPORT OF LABORATORY ANALYSIS
Page 21 of 23
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc
J L�IC�.IGL�=

I
�aceAnalytical'
r wwwpacelab&c=
QUALIFIERS
Project 08 -JUL -0641
Pace Project No 9224413
DEFINITIONS
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
Page 25 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 KinceyAve Suite 100
Huntersville, NC 28078
(704)875 -9092
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content
ND - Not Detected at or above adjusted reporting limit
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL - Adjusted Method Detection Limit
S - Surrogate
1,2- Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable
Pace Analytical is NELAP accredited Contact your Pace PM for the current list of accredited analytes
ANALYTE QUALIFIERS
MO Matrix spike recovery was outside laboratory control limits
R3 RPD value was outside control limits due to uncertainty of values at or near the PRL
Date 08/13/2008 10 10 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc
Page 22 of 23

e
Pace Analytical Services, Inc
aceAnalytical
2225 Riverside Dr
wwwpacelabscow
Asheville NC 28804
SWO02
(828)254 -7176
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project 08 -JUL -0641
Pace Project No 9224413
Page 26 of 47
Analytical Laboratory
Pace Analytical Services, Inc
9800 KlnceyAve Suite 100
Huntersville NC 28078
(704)875 -9092
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
9224413001
SWO02
SM 2120B
WET 14880
9224413002
SWO03
SM 2120B
WET /4880
9224413001
SWO02
EPA 1664A
GCSV/3368
9224413001
SWO02
SM 2540D
WET /4902
9224413002
SWO03
SM 2540D
WET /4902
9224413001
SWO02
EPA 353 2
WETA/3198
9224413002
SWO03
EPA 200 7
MPRP /2771
EPA 200 7
9224413002
SWO03
EPA 245 1
MERP /1624
EPA 245 1
9224413001
SWO02
SM 4500 -CI -E
WETA/3200
9224413002
SWO03
SM 4500 -CI -E
WETA/3200
9224413002
SWO03
EPA 365 1
WETA/3207
9224413001
SWO02
EPA 350 1
WETA/3215
9224413002
SWO03
EPA 350 1
WETA/3215
9224413001
SWO02
ASTM D516 -90
WETA13222
9224413002
SWO03
ASTM D516 -90
WETA/3222
9224413002
SWO03
SM 5220D
WETA/3236
9224413002
SWO03
EPA 353 2
WETA/3239
9224413002
SWO03
EPA 351 2
WETA13244
Analytical
Batch
ICP/2636
MERC /1623
Date 08/13/2008 10 10 AM REPORT OF LABORATORY ANALYSIS Page 23 of 23
This report shall not be reproduced except in full
without the written consent of Pace Analytical Services, Inc

i -
Page 27 of 47
Analytical Laboratory
,j_�,d�aceAra�yfical' Client Name 1) U-L RSU3 j— Project # yea LfLi(3
f ,
Courier ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial
XT
Pace Other
Prt`
Custody eal on Cooler /Box Present es ❑ tom( Pr© due ©ate, Nf�
Y Y eats intact yes /�� no x .�y
r� r, �,
P�Qrr'�Nm�� fit!
Packing Material ❑ Bubble Wrap �bble Bags one ❑Other
Thermometer Used T060� _ Type o Ice a/et Blue None mples on ice, cooling process has begun
�p
Cooler Temperature �i
Temp should be above freezing to 6'C
Biological Tissue is Frozen Yes No NIA
9
Comments
Date and Initi of er x ng
contents
Chain of Custody Present
-2�Ve-s ONO
❑NIA
1
Chain of Custody Filled Out
E5?e-s ONO
❑N /A
2
Chain of Custody Relinquished
4R'fes ONO
❑NIA
3
Sampler Name & Signature on COC
Ares ONO
❑N /A
4
Samples Arrived within Hold Time
-e4es ONO
❑N /A
5
Short Hold Time Analysis ( <72hr)
❑Yes .Qmo
❑N /A
6
Rush Turn Around Time Requested
CaYes -090
ON /A
7
Sufficient Volume
o
ON /A
8 _ n
Correct Containers Used
-Pace Containers Used
❑Yes -&7o
OYes_2NO
❑NIA
❑NIA
g
Containers Intact
ErY—es ONO
ON /A
10
Filtered volume received for Dissolved tests
❑Yes ONO
CIWA
11
Sample Labels match COC es 0 N ❑N /A
- Includes date /time /ID /Analysis Matrix %-�
12
All containers needing preservation have been checked
All containers needing preservation are found to be in
compliance with EPA recommendation
exceptions VOA, coliform TOC, 0 &G, WI -DRO (water)
P*es ONO
ICY s ONO
❑Yes ONO
❑N!A
❑NIA
13
Initial when completed
Samples checked for dechlonnatlon
,fires ONO
❑NIA
14
Headspace in VOA Vials ( >6mm)
❑Yes ONO AEhWA
15
Trip Blank Present
Trip Blank Custody Seals Present
Pace Tnp Blank Lot # (If purchased) N/A
Oyes ONO
❑Yes ONO
6++/A
p N/A
16
Client Notification/ Resolution Field Data Required? Y / N / N/A
Person Contacted Date/Time
Comments/ Resolution
Project Manager Review "I Date. X13
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( i e out of hold, incorrect preservative, out of temp, incorrect containers)

/ aceAnalytical'
/
Page 28 of 47
Analytical Laboratory
Client Name U1, P at3� Project # yea ��(3
Courier ❑ Fed Ex UPS ❑ a
� ❑ ❑ USPS Client (�❑ commercial Pace Other
Custody eal on Cooler /Box Present es ❑ Prod, ?�Due
Y Y ;olcel", eats mtact yes �no Packing Material ❑ Bubble Wrap �bble Bags one ❑Other
Thermometer Used T060r Type Blue None mpies on ice, cooling process has begun
Cooler Temperature �wf `"� 'J
Temp should be above freezing to 6'C
Biological Tissue Is Frozen Yes No N/A
Comments
Date and init� of er x I ng
contents
Chain of Custody Present
-2r-es ONo
❑N/A
1
Chain of Custody Filled Out
EM—es ONo
❑N /A
2
Chain of Custody Relinquished
$Yes ONo
ON/A
3
Sampler Name & Signature on COC
Yes ONo
ON /A
14
Samples Arrived within Hold Time
-E '?es ONo
ON /A
5
Short Hold Time Analysis ( <72hr)
OYes .Q"o
ON /A
6
Rush Turn Around Time Requested
Yes .ego
ON /A
7
Sufficient Volume
94,
❑N /A
8 I n
Correct Containers Used
-Pace Containers Used
1­71 Yes .&Rci
OYes ,IlNo
ON /A
❑N/A
g
Containers Intact
ErYes ONo
❑N /A
10
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Oyes ONo
C;NM
11
Sample Labels match COC 459es- ONo ON /A
- Includes date /time /ID /Analysis Matrix
12
All containers needing preservation have been checked
All containers needing preservation are found to be in
compliance with EPA recommendation
exceptions VOA, coliform TOC 0 &G WI ORO (water)
❑No
�s ONo
❑Yes ONo
❑N /A
❑N /A
13
Initial when completed
Samples checked for dechlorination
_ "s ONo
❑NIA
14
Headspace In VOA Vials ( >6mm)
OYes ONo AaMA
15
Trip Blank Present
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased) N/A
OYes ONo
OYes ONo
&N A
❑N /A
16
Client Notification/ Resolution Field Data Required? Y / N / N/A
Person Contacted Date/Time
Comments/ Resolution
f
Project Manager Review
Date q► 3
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( i e out of hold incorrect preservative, out of temp, incorrect containers)

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