Riverbend Steam Station (9)

\l
l�
I
I
Page 29 of 46
Analytical Laboratory
Please print or type in the unshaded areas I
EPA ID Number (copy from item l of Form 1)
Form Approved OMB No 2040 -0086
I Approval expires 5 -31 -92
Form
2F
NPDES
United States Environmental Protection Agency
Washington, DC 20460
Application for Permit to Discharge Storm Water
Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average 286 hours per application, including lane for reviewing instructions, searching existing data
sources, gathering and maintaining the data needed, and completing and reviewing the colledwn of information Send comments regarding the burden estimate,
any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to Chief,
Information Policy Branch, PM -223, U S Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Mana and Budget, Washington, DC 20503
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water
A Outfall Number
list
B Latitude
C Longitude
D Receiving Water
name
SW 001
II. Improvements
A Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or
operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, sti ulations, court orders, and grant or loan conditions
1 Identification of Conditions,
Agreements, Etc
2 Affected Outfalls
3 Brief Description of Project
4 Final
Compliance Date
number
source of discharge
a req
b proj
B You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges)
you now have under way or which you plan Indicate whether each program is now under way or planned, and indicate your actual or planned
schedules for construction
III. Site Drainage Ma
Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall (s) covered in the application if a
topographic map Is unavailable) depicting the facility including each of its intake and discharge structures, the drainage area of each storm
water outfall, paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff,
materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied, each of its hazardous
waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous
waste under 40 CFR 262 34), each well where fluids from the facility are injected underground, springs, and other surface water bodies which
receive storm water discharges from the facility
EPA Form 3510 -2F (Rev 1 -92) Page 1 of 3
Continued on Page 2

Page 30 of 46
Analytical Laboratory
r....s,n,.eA f n N.n C—f
IV. Narrative Description of Pollutant Sources
A For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and building roofs) drained
to the outfall, and an estimate of the total surface area drained by the outfall
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Number
(provide units
(provide units
Number
I (provide units
(provide units
SW001
B Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present materials management
practices employed to minimize contact by these materials with storm water runoff, materials loading and access areas, and the location,
manner, and frequency in which pesticides, herbicides, sod conditioners, and fertilizers are applied
C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in
storm water runoff, and a description of the treatment the storm water receives, including the schedule and type of maintenance for
control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge
Outfall
List Codes from
Number
Treatment
Table 217-1
SW001
V. Non Stormwater Dischar es
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C
or Form 2E application for the outfall
Name of Official Title (type or punt)
Signature
Date Signed
B provide a description of the method used, the date of any testing, and the onsite drainage points that were direct) observed during a test
A. Significant Leaks or Spills
Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three
ears, including the approximate date and location of the spill or leak, and the type and amount of material released
EPA Form 3510 -2F (Rev 1 -92) Page 2 of 3 Continued on Page 3

,_ _ _
Page 31 of 46
Analytical Laboratory
EPA ID Number (copy from Item I of Form 1)
Continued from Page 2
Al. Discharge Information
A,B,C, & D See instruction before proceeding Complete one set of tables for each outfall Annotate the outfall number in the space provided
Tables Vu -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2
E Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 217-4, a substance or a component of a
substance which you currently use or manufacture as an intermediate or final product or byproduct'?
❑ Yes (list all such pollutants below) ❑ No (go to Section 1X)
VIII. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation to your discharge within the last 3 years?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
IX. Contact analysis Information
Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm?
® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X)
analyzed by, each such laborato ry or rrnn below
A Name
B Address
C Area Code & Phone No
D Pollutants Analyzed
Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 - 875 -9092 Oil &Grease/
Huntersville, NC 28078 Organic
Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176
Asheville, NC 28804 Wet chemistry &
metals
X. Certification
I certify under penalty of law that this document and all attachments were prepared under my direction or
supervision In accordance with a system designed to assure that qualified personnel'properly gather and evaluate
the Information submitted Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information submitted Is, to the best of my knowledge and
belief, true, accurate, and complete I am aware that there are significant penalties for submitting false information,
including the possibility of fine and imprisonment for knowing violations
A Name & Official Title (type or print)
B Area Code and Phone No
C Signature
D Date Signed
EPA Form 3510 -2F (Rev 1 -92) Page 3 of 3

I Page 32 of 46
Analytical Laboratory
EPA ID Number (copy from Item I of Form 1) Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
VII. Discharge Information Continued from page 3 of Form 2F
Part A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outfall See
instructions for additional details
Maximum Values
Average Values
Number
Pollutant
include units
Include units
Of
And
Grab Sample
Grab Sample
Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Minutes
Composite
First 30
Minutes
Composite
Sampled
Sources of Pollutants
Oil & Grease
< 5 0 mg /L
N/A
1
Biological Oxygen
13 0 mg /L
1
Demand BOD5
Chemical Oxygen
< 25 0 mg /L
1
Demand COD
Total Suspended
29 3 mg/L.
1
Solids TSS
Total
3 9 mg /L
1
Nitrogen
Total
0 53 mg /L
1
Phosphorus
pH
Minimum
Maximum
Minimum
Maximum
Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES
permit for its process wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall
See the instructions for additional details and re uirements
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
And
Storm
Grab Sample
Grab Sample
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Bromide (24959 -67 -9)
Chlorine, Total
residual
Ammonia (as N)
1 7 mg /L
1
Chloride
Color
Fluoride (16984 -48 -8)
Nitrate - Nitrite (as N)
1 5 mg /L
1
Radioactivity, alpha
total
Radioactivity, beta
total
Radioactivity, radium
total
Radioactivity, radium
226 total
Sulfate (as SO4)
14808 -79-8
Sulfite (as SO,)
14265 -45 -3
Aluminum, Total
0 915 mg /L
1
7429 -90 -5
Barium Total
0 0339 mg /L
1
7440 -39 -3
Boron, Total (7440-
0 0795 mg /L
1
42 -8
Cobalt, Total (7440-
<0 005 mg /L
1
48 -4
Iron, Total (7439 -89-6)
2 00 mg /L
1
Magnesium, Total
1 7 mg /L
1
439 -95-4
Magnesium,
Dissolved
Molybdenum, Total
7439 -98 -7
Manganese, Total
0 0784 mg /L
1
7439 -96 -5
EPA Form 3510 -2F (Rev 1 -92) Page VII -1 Continue on Reverse

Page 33 of 46
Analytical Laboratory
Tin, Total
<0 005 mg /L
1
7440 -31 -5
Titanium, Total
0 0256 mg /L
1
7440 -32 -6
Antimony, Total
7440 -36 -0
Arsenic, Total
0 0054 mg /L
1
7440 -38 -2
Beryllium, Total
7440 -41 -7
Cadmium, Total
0 0013 mg /L
1
7440 -43 -9
Chromium, Total
<0 005 mg /L
1
7440 -47 -3
Copper, Total
0 0684 mg /L
1
440 -50 -8
Lead, Total
7439 -92 -1
Mercury, Total
<0 200 ug /L
1
7439 -97 -6
Nickel, Total
0 007 mg /L
1
7440 -02 -0
Selenium, Total
0 062 mg /L
1
7782 -49 -2)
Silver, Total
<0 005 mg /L
1
7440 -22-4
Thallium, Total
7440 -28 -0)
Zinc, Total
0 863 mg /L
1
7440 -66-6)
EPA Form 3510 -2F (Rev 1 -92) Page VII -I Continue on Reverse

Page 34 of 46
Analytical Laboratory
Cnnfinuart frnm tha Frnnt
Part C - List each pollutant shown in Tables 2F -2, 2F -3, and 2F-4 that you know or have reason to believe is present See the instructions for
additional details and requirements Com fete one table for each outfall
Pollutant
And
CAS Number
(if available)
Maximum Values
include units
Average Values
include units
Number
Of
Storm
Events
Sampled
Sources of Pollutants
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Grab Sample
Taken During
First 30
Minutes
Flow- weighted
Composite
Cyanide, Total
57 -12 -5
Phenols, Total
<0 010 mg/L
1
Surfactants (MBAs)
Total Dissolved Solids
Total Organic Carbon
Total Kleldahl
Nitrogen TKN
2 4 mg /L
1
Fecal Coliforrn
< 1 0 CFU/
100mL
1
Part D - Provide data for the storm events which resulted in the maximum values for the flow weighted coin osite sample_
1
Date of
Storm
Event
2
Duration
of Storm Event
(in minutes)
3
Total rainfall
during storm event
(in inches)
4
Number of hours between
beginning of storm measured
and end of previous
measurable rain event
5
Total flow from
rain event
(gallons or specify units)
7 Provide a description of the method of flow measurement or estimate
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

Page 35 of 46
Analytical Laboratory
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

Page 36 of 46
Analytical Laboratory
Please print or type in the unshaded areas
EPA ID Number (copy from item f of Form 1)
Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
Form
2F
NPDES
United States Environmental Protection Agency
Washington, DC 20460
Application for Permit to Discharge Storm Water
Discharges Associated with Industrial Activity
Paperwork Reduction Act Notice
Public reporting burden for this application is estimated to average 28 6 hours per application, including time for reviewing instructions, searching existing data
sources, gathering and maintaining the data needed, and completing and reviewing the collection of information Send comments regarding the burden estimate,
any other aspect of this collection of information or suggestions for improving this form, including suggestions which may increase or reduce this burden to Chief,
Information Policy Branch, PM -223, U S Environmental Protection Agency, 401 M St, SW, Washington, DC 20460, or Director, Office of Information and Regulatory
Affairs, Office of Mana ement and B et W in n, DC 20503
I. Outfall Location
For each outfall, list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water
A Outfall Number
list
B Latitude
C Longitude
D Receiving Water
name
SW 003
I1.Improvements
A Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or
operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described
in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance
schedule letters, std ulatrons, court orders, and grant or loan conditions
1 Identification of Conditions,
Agreements, Etc
2 Affected Outfalls
3 Brief Description of Project
4 Final
Com liance Date
number
source of discharge
a req
b prol
B You may attach additional sheets describing any additional water pollution (or other environmental projects which may affect your discharges)
you now have under way or which you plan Indicate whether each program is now under way or planned, and indicate your actual or planned
schedules for construction
M. Site Drainage Map
Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a
topographic map Is unavailable) depicting the facility including each of its intake and discharge structures, the drainage area of each storm
water outfall, paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for
outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff,
materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied, each of its hazardous
waste treatment, storage or disposal units (including each are not required to have a RCRA permit which is used for accumulating hazardous
waste under 40 CFR 262 34), each well where fluids from the facility are injected underground, springs, and other surface water bodies which
receive storm water discharges from the facility
EPA Form 3510 -2F (Rev 1 -92) Page 1 of 3 Continued on Page 2

Page 37 of 46
Analytical Laboratory
Cnnhnnarl hnm tho Frnnt
IV. Narrative Description of Pollutant Sources
A For each outfall, provide an estimate of the area (include units) of impervious surfaces (including paved areas and budding roofs) drained
to the outfall, and an estimate of the total surface area drained b the outfall
Outfall
Area of Impervious Surface
Total Area Drained
Outfall
Area of Impervious Surface
Total Area Drained
Number
(provide units
(provide units
Number
(provide units
(provide units
SW003
B Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed
in a manner to allow exposure to storm water, method of treatment, storage, or disposal, past and present materials management
practices employed to minimize contact by these materials with storm water runoff, materials loading and access areas, and the location,
manner, and frequency in which pesticides, herbicides, soil conditioners, and fertilizers are applied
C For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in
storm water runoff, and a description of the treatment the storm water receives, including the schedule and type of maintenance for
control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge
Outfall
List Codes from
Number
Treatment
Table 2F -1
SW003
V. Non Stormwater Dischar es
A I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of
nonstormwater discharges, and that all nonstormwater discharges from these outfall(s) are identified in either an accompanying Form 2C
or Form 2E application for the outfall
Name of Official Title (type or pent)
Signature
Date Signed
B provide a description of the method used, the date of any testing, and the onsite drainage points that were irectly observed during a test
VI. Significant Leaks or spills
Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three
ears, including the approximate date and location of the spill or leak, and the type and amount of material released
EPA Form 3510 -2F (Rev 1 -92) Page 2 of 3 Continued on Page 3

EPA ID Number (copy from Item I of Form 1)
Continued from Page 2
Page 38 of 46
Analytical Laboratory
VII. Discharge Information
A,B,C, & D See instruction before proceeding Complete one set of tables for each outfall Annotate the outfall number in the space provided
Tables Vu -A, VII -B, and VII -C are included on separate sheets numbered VII -1 and VII -2
E Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F -2, 2F -3, or 2F4, a substance or a component of a
substance which you currently use or manufacture as an intermediate or final product or byproduct?
❑ Yes (list all such pollutants below) ❑ No (go to Section 1X)
Vill. Biological Toxicity Testing Data
Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or
on a receiving water in relation to your discharge within the last 3 years?
❑ Yes (list all such pollutants below) ❑ No (go to Section IX)
IX. Contact analysis Information
Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm?
® Yes (list the name, address, and telephone number of, and pollutants ❑ No (go to Section X)
analyzed by, each such laboratory or firm below
A Name
B Address
C Area Code & Phone No
D Pollutants Analyzed
Pace Analytical Services, Inc 9800 Kincey Ave Suite 100 704 -875 -9092 Oil &Grease/
Huntersville, NC 28078 Organic
Pace Analytical Services, Inc 2225 Riverside Dr 828 - 254 -7176
Asheville, NC 28804 Wet chemistry &
metals
X. Certification
I certify under penalty of law that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the Information submitted Based on my inquiry of the person or persons who manage the system or those persons
directly responsible for gathering the information, the information submitted /s, to the best of my knowledge and
belief, true, accurate, and complete 1 am aware that there are significant penalties for submitting false Information,
Including the possibility of fine and imprisonment for knowing violations
A Name & Official Title (type or pnnt)
B Area Code and Phone No
C Signature
D Date Signed
EPA Form 3510 -2F (Rev 1 -92) Page 3 of 3

Page 39 of 46
Analytical Laboratory
EPA ID Number (copy from Item I of Form 1) Form Approved OMB No 2040 -0086
Approval expires 5 -31 -92
VII. Discharge Information Continued from page 3 of Form 2F
Part A - You must provide the results of at least one analysis for every pollutant in this table Complete one table for each outfall See
instructions for additional details
Maximum Values
Average Values
Number
Pollutant
include units
include units
Of
And
Grab Sample
Grab Sample
Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(If available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Oil & Grease
< 5 0 mg /L
N/A
1
Biological Oxygen
72 9 mg /L
54 9 mg /L
2
Demand BODS
Chemical Oxygen
233 mg /L
58 0 mg /L
2
Demand COD
Total Suspended
151 mg /L
1
Solids SS
Total
8 9 mg/L
2 28 mg /L
2
Nitrogen
Total
1 6 mg /L
0 16 mg /L
2
Phosphorus
pH
Minimum
Maximum
Minimum
Maximum
Part B - List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES
permit for its process wastewater (if the facility is operating under an existing NPDES permit) Complete one table for each outfall
See the instructions for additional details and re uirements
Maximum Values
Average Values
Number
Pollutant
include units
(include units )
Of
And
Grab Sample
Grab Sample
Storm
CAS Number
Taken During
Flow- weighted
Taken During
Flow- weighted
Events
(if available)
First 30
Composite
First 30
Composite
Sampled
Minutes
Minutes
Sources of Pollutants
Bromide (24959 -67 -9)
Chlorine, Total
residual
Ammonia (as N)
0 80 mg /L
0 25 mg /L
2
Chloride
Color
Fluoride (16984 -48 -8)
Nitrate - Nitrite (as N)
1 2 mg /L
0 78 mg /I
2
Radioactivity, alpha
total
Radioactivity, beta
total
Radioactivity, radium
total
Radioactivity, radium
226 total
Sulfate (as SO4)
14808 -79 -8)
Sulfite (as SO3)
14265 -45 -3
Aluminum, Total
0 753 mg /L
0 897 mg /L
2
(7429 -90 -5
Barium, Total
0 115 mg /L
0 0222 mg /L
2
7440 -39 -3
Boron, Total (7440-
0 072 mg /L
<0 050 mg /L
2
42 -8
Cobalt, Total (7440-
<0 005 mg /L
<0 005 mg /L
2
48-4
Iron, Total (7439 -89 -6)
21 2 mg /L
0 999 mg /L
2
Magnesium, Total
9 57 mg /L
0 934 mg /L
2
7439 -95-4
Magnesium,
Dissolved
Molybdenum, Total
7439 -98 -7
Manganese, Total
1 38 mg/L
0 0792 mg /L
2
7439 -96 -5
EPA Form 3510 -2F (Rev 1 -92) Page VII -I Continue on Reverse

Page 40 of 46
Analytical Laboratory
Tin, Total
<0 005 mg /L
<0 005 mg /L
2
7440 -31 -5
Titanium, Total
0 0299 mg /L
0 0403 mg /L
2
7440 -32 -6
Antimony, Total
7440 -36 -0
Arsenic, Total
0 005 mg /L
<0 005 mg /L
2
7440 -38 -2
Beryllium, Total
7440 -41 -7
Cadmium, Total
<0 001 mg /L
<0 001 mg /L
2
7440 -43 -9
Chromium, Total
<0 005 mg /L
<0 005 mg /L
2
7440 -47 -3
Copper, Total
0 0533 mg /L
0 0182 mglL
2
7440 -50 -8
Lead, Total
7439 -92 -1
Mercury, Total
<0 200 ug /L
<0 200 ug /L
2
7439 -97-6
Nickel, Total
0 0068 mg /L
<0 005 mg /L
2
7440 -02 -0
Selenium, Total
<0 010 mg /L
<0 010 mg /L
2
7782 -49 -2
Silver, Total
<0 005 mg /L
<0 005 mg /L
2
7440 -22 -4
Thallium, Total
7440 -28 -0
Zinc, Total
2 29 mg /L
0 758 mgiL
2
7440 -66 -6)
EPA Form 3510 -2F (Rev 1 -92) Page VII -I Continue on Reverse

Page 41 of 46
Analytical Laboratory
intinued from the Front
Part C - List each pollutant shown in Tables 217-2, 2F -3, and 2F-4 that you know or have reason to believe is present See the instructions for
additional details and requirements Com fete one table for each outfall
Maximum Values Average Values Number
Pollutant include units include units Of
And Grab Sample Grab Sample Storm
CAS Number Taken During Flow- weighted Taken During Flow- weighted Events
(if available) First 30 Composite First 30 Composite Sampled
Minutes Minutes Sources of Pollutants
Cyanide, Total
57 -12 -5
Phenols, Total 0 045 mg /L 1
Total Kleldahl 7 7 mg /L 1 5 mg /L 2
Nitrogen KN
Fecal Coliform 100 CFU /100 1
mL
7 Provide a description of the method of flow measurement or estimate
EPA Form 3510 -2F (Rev 1 -92) Page VII -2
Part D -
Provide data for the storm events which resulted in the maximum values for the flow weighted com osrte sample
1
2
3
4
5
Number of hours between
Date of
Duration
Total rainfall
beginning of storm measured
Total flow from
Storm
of Storm Event
during storm event
and end of previous
rain event
Event
(in minutes)
(in inches)
measurable rain event
(gallons or specify units)
7 Provide a description of the method of flow measurement or estimate
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

I'
Page 42 of 46
I Analytical Laboratory
EPA Form 3510 -2F (Rev 1 -92) Page VII -2

OUTFALL
SAMPLE
SAMPLE
ANALYSES
SAMPLED
COLLECTION DATE
TYPE
SW001
June 23, 2008
Grab
EPA 1664A
EPA 200 7
EPA 245 1
EPA 350 1
EPA 3512
EPA 353 2
EPA 365 1
EPA 420 4
SM2540D
SM 52106
SM 5220D
SM 9222D
SW003
June 23, 2008
Grab
EPA 1664A
EPA 200 7
EPA 245 1
EPA 350 1
EPA 3512
EPA 353 2
EPA 365 1
EPA 420 4
SM2540D
SM 52106
SM 5220D
SM 9222D
SW003
June 23, 2008
Composite
SM 52106

Duke Analytical Laboratory
IIVEnergy. H13339 Hagers Ferry Road
untersville, NC 28078 -7929
Rev 07 -09 -07 McGuire Nuclear Complex — MG03A2
Phone 704 - 875 -5245 Fax [phone]
Job Summary Report
Job Number: 08 -JUN -0400
Project Name:
Customer Name:
Copy To:
Customer Address:
Riverbend Stormwater (6/23)
Brandy Starnes
Steve Jones,
Riverbend Steam Station
Lab Contact: Mary Ann Ogle
Lab Contact Phone: [phone]
Report Authorized By:
(Printed Name)
MARY ANN OGLE
Page 1 of 46
Analytical Laboratory
Report Authorized By:
(Signature) Date lo 4l )h 1'
Data Package
This data package includes analytical results that are applicable only to the samples
described in this narrative. An estimation of the uncertainty of measurement for the
results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory Please contact the
Analytical Laboratory with any questions. The order of individual sections within this
report is as follows:
Job Summary Report
Analytical Laboratory Certificate of Analysts
Analytical Laboratory QC Reports (if applicable)
Sub - contracted Laboratory Results
Customer Specific Data Sheets, Reports & Documentation (tf applicable)
Customer Database Entries
Test Case Narratives
Chain of Custody (COQ

r
i
i
MERL Duke
' Energy®
i
R— 07 -09 -07
1
Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, NC 28078 -7929
McGuire Nuclear Complex — MG03A2
Phone 704 - 875 -5245 Fax 704 - 875 -5038
Job Summary Report
Certification
The Analytical Laboratory holds the following Certifications
New York State Department of Health Cert f cation # 11717(NELAC)
North Carolina Department of Health & Human Services Certification # 37804
South Carolina (DHEC) Laboratory ID # 99005
North Carolina (DENR) Certification 9 248
Analytical results listed in this report may not be certified by the authorities referenced above
Contact the Analytical Laboratory for definitive information about the certification status of
specific methods The results meet all requirements of NELAC except where deviations are
noted in this report
Data Flags
Any analytical tests or individual analytes within a test flagged with an "X" or a "1" indicate a
deviation from the method quality system or quality control requirement
Calculations
All results are reported on a wet weight basis unless otherwise noted
Sample ID's & Descriptions:
Page 2 of 46
Analytical Laboratory
Collection
Sample
Sample ID
Plant /Station
Date
Collected By
Description
- -
--- - - - - --
28017343
------- - - - - --
FOSSIL
---- - - - - --
6/23/2008
------ - - - - --
B STARNES
----- - - --
SWO01 (GRAB)
RIVERBEND
28017347
FOSSIL
6/23/2008
B STARNES
SWO03 (GRAB)
RIVERBEND
28017348
FOSSIL
6/23/2008
B STARNES
SWO03 (COMP )
RIVERBEND
-----------------
3 TOTAL SAMPLES

Duke
r.OwEnergy@
Rev 07 -03 -07
Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, NC 28078 -7929
McGuire Nuclear Complex — MG03A2
Phone 704 - 875 -5245 Fax 704 - 875 -5038
Job Summary Report
Validation of Analytical Data Package
COC and pdf report are in agreement with sample totals
i and analyses (compliance programs and procedures)
ii) All results are less than the laboratory reporting limits
iii) All laboratory QA/QC requirements are acceptable.
1V) NPDES and TCLP results are below permit or regulatory
limits respectively
It iv) above is No, document below:
Permit
Variable Result I Limit Notes
Page 3 of 46
Analytical Laboratory
Yes
1` No
1 Yes
Fi-I No
j� Yes
r No
r Yes
ENo
V)
Components of the Job Summary Report arranged in order
r Yes lr No
stipulated on page one
Indicate components included:
j,7
Job Summary Report
r—
Customer Specific Data Sheets, Reports &
Documentation cif applicable)
Analytical Laboratory Certificate of
Analysis
ry
Customer Database Entries
Analytical Laboratory QC Report
(if applicable)
1
Test Case Narratives
j-"
Sub - contracted Laboratory Results
r'
Chain of Custody
vi) Notes and Additional Information
This is a partial report for SW 003 and SW 001 The other reports for this outfall are 08 -JUL -0641 and 08-
JUN -0400 SW 001 had a quality control failure for BOD on the grab sample The value must be flagged when
reporting to the state The oxygen depeletion was <2 0 The BOD results are considered questionable
The following parameters contained quality control failures for matrix spike recovery, but the spike was not
performed on this sample ammonia The following parameters contained quality control failures for duplicate
relative percent difference, the quality control was not performed on this sample mercury and TKN These quality
control failures should be documented when reporting result, but these results are still considered valid
Mary Ann Ogle
Duke Energy Analytical Lab
NPDES Contact Office 704- 875 -5274 Cell 704 - 280 -7956

aeeAnalydcal
www pacefebs =n
July 09, 2008
Mr Jay Perkins
Duke Energy
13339 Hagers Ferry Road
Bldg 7405 MG30A2
Huntersville, NC 28078
RE Project 08- JUN -0400
Pace Project No 9221945
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
Page 4 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kmcey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Dear Mr Perkins,
Enclosed are the analytical results for sample(s) received by the laboratory on June 23, 2008 The
results relate only to the samples included in this report Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted All
Microbiological analyses were performed at the laboratory where the samples were received
If you have any questions concerning this report, please feel free to contact me
Sincerely,
Kevin Herring
kevin herring @pace) abs com
Project Manager
Enclosures
cc Accounts Payable DPEHS, Duke Energy Carolinas, LLC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 1 of 24

Page 5 of 46
REPORT OF LABORATORY ANALYSIS Page 2 of 24
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc
Analytical Laboratory
a
Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytical
2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacelabscom
Asheville, NC 28804 Huntersville, NC 28078
i
[phone] (704)875 -9092
CERTIFICATIONS
Project 08- JUN -0400
Pace Project No 9221945
Charlotte Certification IDs
Flonda /NELAP Certification Number E87627
North Carolina Field Services Certification Number 5342
Kansas Certification Number E -10364
South Carolina Certification Number 990060001
Louisiana /LELAP Certification Number 04034
South Carolina Bioassay Certification Number 990060003
North Carolina Drinking Water Certification Number 37706
Tennessee Certification Number 04010
North Carolina Wastewater Certification Number 12
Virginia Certification Number 00213
Asheville Certification IDs
Florida /NELAP Certification Number E87648
Pennsylvania Certification Number 68 -03578
Louisiana/LELAP Certification Number 03095
South Carolina Certification Number 99030001
New Jersey Certification Number NC011
South Carolina Bioassay Certification Number 99030002
North Carolina Drinking Water Certlfcabon Number 37712
Tennessee Certification Number 2980
North Carolina Wastewater Certification Number 40
Virginia Certification Number 00072
North Carolina Bioassay Certification Number 9
Eden Certification IDs
North Carolina Drinking Water Certification Number 37738
North Carolina Wastewater Certification Number 633
Virginia Drinking Water Certification Number 00424
REPORT OF LABORATORY ANALYSIS Page 2 of 24
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc

1
I
aceAnalytical
wwwpacalaba.com
t
Project 08- JUN -0400
Pace Project No 9221945
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
SAMPLE SUMMARY
Lab ID
Sample ID
Matrix
Date Collected
Date Received
9221945001
28017343
Water
06/23/08 08 30
06/23/08 11 45
9221945002
28017347
Water
06/23/08 08 40
06/23/08 11 45
9221945003
28017348
Water
06/23/08 08 40
06/23/08 11 45
Page 6 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Hunterswlle, NC 28078
(704)875 -9092
REPORT OF LABORATORY ANALYSIS Page 3 of 24
This report shall not be reproduced, except to full,
without the written consent of Pace Analytical Services, Inc
4

i
i
i
G
aceAnalytical
� �wrw pacelabs.com
Project 08- JUN -0400
Pace Project No 9221945
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)254 -7176
SAMPLE ANALYTE COUNT
Page 7 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville NC 28078
(704)875 -9092
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
9221945001
28017343
EPA 1664A
DNP
1
EPA 200 7
JMW
17
EPA 245 1
EWS
1
EPA 350 1
SAJ
1
EPA 351 2
SAJ
1
EPA 353 2
JDA
1
EPA 3651
DMN
1
EPA 420 4
JDA
1
SM 2540D
SER
1
SM 52108
JDA
1
SM 5220D
MJR
1
SM 9222D
CLW
1
9221945002
28017347
EPA 1664A
DNP
1
EPA 200 7
JMW
17
EPA 245 1
EWS
1
EPA 3501
SAJ
1
EPA 351 2
SAJ
1
EPA 353 2
JDA
1
EPA 3651
DMN
1
EPA 420 4
JDA
1
SM 2540D
SER
1
SM 52108
JDA
1
SM 5220D
MJR
1
SM 9222D
CLW
1
9221945003
28017348
SM 52108
JDA
1
REPORT OF LABORATORY ANALYSIS Page 4 of 24
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc
V ��

1�
I
i
i
,- aceAnalytical
ivwwpacalab&mn
Project 08- JUN -0400
Pace Project No 9221945
Sample 28017343
Parameters
HEM, Oil and Grease
Oil and Grease
200 7 MET ICP
Aluminum
Arsenic
Barium
Boron
Cadmium
Chromium
Cobalt
Copper
Iron
Magnesium
Manganese
Nickel
Selenium
Silver
Tin
Titanium
Zinc
MBIO 9222D Fecal Coliform CHT
Fecal Coliforms
245 1 Mercury
Mercury
2540D Total Suspended Solids
Total Suspended Solids
5210B BOO, Low Level
BOD, 5 day
350 1 Ammonia
Nitrogen, Ammonia
3512 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353 2 Nitrogen, N021NO3 pros
Nitrogen, NO2 plus NO3
3651 Phosphorus, Total
Phosphorus
Date 07109/2008 03 30 PM
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7176
ANALYTICAL RESULTS
Page 8 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Klncey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Lab ID. 9221945001 Collected 06/23/08 08 30 Received 06/23/08 11 45 Matrix Water
Report
Results Units Limit MOIL OF Prepared Analyzed CAS No Qual
Analytical Method EPA 1664A
ND mg /L
50
1 1
1
06/30/08 12 19
Analytical Method EPA 200 7 Preparation Method EPA 200 7
915 ug /L
100
250
1
06/25/08 1140
06/27/08 20 02 7429 -90 -5
54 ug /L
50
27
1
06/25/08 1140
06/27/08 20 02 7440 -38 -2
339 ug /L
50
020
1
06/25/08 1140
06/27/08 20 02 7440 -39 -3
795 ug /L
500
47
1
06/25/08 1140
06/27/08 20 02 7440 -42 -8
13 ug /L
10
050
1
06/25/08 1140
06/27/08 20 02 7440 -43 -9
ND ug /L
50
040
1
06/25/08 11 40
06/27/08 20 02 7440 -47 -3
ND ug /L
50
060
1
06/25/0811 40
06/27/08 20 02 7440 -48 -4
684 ug /L
50
030
1
06/2510811 40
06/27/08 20 02 7440 -50 -8
2000 ug /L
500
140
1
06/25/0811 40
06/27/08 20 02 7439 -89-6
1700 ug /L
100
30
1
06/25/0811 40
06/27/08 20 02 7439 -954
784 ug /L
50
030
1
06/25/0811 40
06/27/08 20 02 7439 -96 -5
70 ug /L
50
17
1
06/25/0811 40
06/27/08 20 02 7440 -02 -0
620 ug /L
100
38
1
06/2510811 40
06/27/08 20 02 7782 -49 -2
ND ug /L
50
010
1
06/25/08 11 40
06127/08 20 02 7440 -22 -4
ND ug /L
50
1 8
1
06/25/0811 40
06/27/08 20 02 7440 -31 -5
256 ug/L
50
010
1
06/2510811 40
06/27108 20 02 7440 -32 -6
863 ug /L
100
040
1
06/25/0811 40
06/27108 20 02 7440 -66 -6
Analytical Method SM 9222D
NO CFU 1100 mL
10
1
06/23/08 13 46
Analytical Method EPA 2451
Preparation Method EPA 245 1
NO ug /L
020
020
1
06/25/08 16 00
06/27/08 15 09 7439 -97-6
Analytical Method SM 2540D
29 3 mg /L
33
1
06/29/08 17 25
Analytical Method SM 5210B
13 0 mg /L
20
1
06/25/08 07 30
06/30/08 07 30
Analytical Method EPA 350 1
17 mg /L
010
010
1
07/01/08 14 41 7764 -41 -7
Analytical Method EPA 351 2
2 4 mg /L
050
050
1
07/03/08 15 28 7727 -37 -9
Analytical Method EPA 353 2
15 mg /L
010
010
1
07105/08 09 04
Analytical Method EPA 365 1
0 53 mg /L
010
010
1
07101/08 10 48 7723 -14 -0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
f 666
B2
Page 5 of 24

1 - -
i
I
aceAnalytical
j wwwpacelabic=
Project 08- JUN -0400
Pace Project No 9221945
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville, NC 28804
(828)254 -7178
ANALYTICAL RESULTS
Page 9 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800KinceyAve Swte100
Huntersville, NC 28078
(704)8759092
Sample 28017343
Lab ID 9221945001 Collected
06/23108 08 30
Received 06/23/08 11 45 Matrix Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No Qua]
420 4 Phenolics, Total
Analytical Method EPA 420 4
Phenol
ND mg /L 0 010
0 010 1
06130/08 13 12 108 -95 -2
52200 COD
Analytical Method SM 5220D
Chemical Oxygen Demand
ND mg /L 25 0
25 0 1
06/26/08 11 39
Date 07/0912008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 6 of 24
This report shall not be reproduced, except in full,
without the written consent of ryPace Analytical Services, Inc
�LIJCld�,=

Page 10 of 46
Analytical Laboratory
® Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytical 2225 Riverside Dr 9800 Kincey Ave Sude 100
wwwpacefaftcom Asheville, NC 28804 Huntersville, NC 28078
(828)254 -7176 (704)875 -9092
Project 08- JUN -0400
Pace Project No 9221945
Sample 28017347
Parameters
HEM, Oil and Grease
Oil and Grease
200 7 MET ICP
Aluminum
Arsenic
Barium
Boron
Cadmium
Chromium
Cobalt
Copper
Iron
Magnesium
Manganese
Nickel
Selenium
Silver
Tin
Titanium
Zinc
MBIO 9222D Fecal Coliform CHT
Fecal Coliforms
2451 Mercury
Mercury
25400 Total Suspended Solids
Total Suspended Solids
52108 BOD, Low Level
BOD, 5 day
350 1 Ammonia
Nitrogen, Ammonia
351 2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353 2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
3651 Phosphorus, Total
Phosphorus
ANALYTICAL RESULTS
Lab ID 9221945002 Collected 06/23/08 08 40 Received 06/23108 11 45 Matrix Water
Report
Results Units Limit MDL DF Prepared Analyzed CAS No
Analytical Method EPA 1664A
ND mg /L
50
1 1
1
06/30/08 12 20
Analytical Method EPA 200 7 Preparation Method
EPA 200 7
753 ug/L
100
250
1
06/25/0811 40
06/27/08 20 05 7429 -90-5
50 ug /L
50
27
1
06/25/0811 40
06/27/08 20 05 7440 -38 -2
115 ug /L
50
020
1
06/25/08 1140
06/27/08 20 05 7440 -39 -3
722 ug /L
500
47
1
06/25/0811 40
06/27/08 20 05 7440 -42 -8
ND ug /L
1 0
050
1
06/25/0811 40
06/27/08 20 05 7440 -43 -9
ND ug /L
50
040
1
06/25/0811 40
06/27/08 20 05 7440 -47 -3
ND ug /L
50
060
1
06/25/0811 40
06127/08 20 05 7440 -48 -4
533 ug /L
50
030
1
06/25/0811 40
06/27/08 20 05 7440 -50 -8
21200 ug /L
500
140
1
06/25/0811 40
06/27/08 20 05 7439 -89 -6
9570 ug /L
100
30
1
06/25/0811 40
06/27/08 20 05 7439 -95 -4
1380 ug /L
50
030
1
06125/0811 40
06/27/08 20 05 7439 -96 -5
68 ug /L
50
1 7
1
06/25/0811 40
06/27/08 20 05 7440 -02 -0
ND ug /L
100
38
1
06/2510811 40
06/27/08 20 05 7782 -49 -2
ND ug /L
50
010
1
06/25/0811 40
06/27/08 20 05 7440 -22 -4
ND ug /L
50
1 8
1
06/2510811 40
06/27/08 20 05 7440 -31 -5
299 ug /L
50
010
1
06/25/08 1140
06/27/08 20 05 7440 -32 -6
2290 ug /L
100
040
1
06/25/08 1140
06/27/08 20 05 7440 -66 -6
Analytical Method SM 9222D
100 CFU /100 mL
1 0
1
06/23/08 13 46
Analytical Method EPA 245 1
Preparation Method EPA 245 1
ND ug /L
020
020
1
06/25/08 16 00
06/27/08 15 17 7439 -97 -6
Analytical Method SM 2540D
151 mg /L
67
1
06/29/08 17 25
Analytical Method SM 5210B
72 9 mg /L
20
1
06/25/08 07 30
06/30/08 07 30
Analytical Method EPA 350 1
080 mg /L
010
010
1
07/01/08 14 42 7764 -41 -7
Analytical Method EPA 3512
7 7 mg /L
050
050
1
07/03/08 15 30 7727 -37 -9
Analytical Method EPA 353 2
1 2 mg /L
010
010
1
07/05/08 09 04
Analytical Method EPA 365 1
16 mg /L
010
010
1
07/01/08 10 48 7723 -14 -0
u1
Qual
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 7 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

t
r
I
r aceAnalytical e
www pacelebsc=
I ,
Project 08- JUN -0400
Pace Project No 9221945
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
I_T:T_Wf7 ISM R;Z : &V1RV
Page 11 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kmcey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Sample 28017347
Lab ID 9221945002 Collected
06/23/08 08 40
Received 06/23/08 11 45 Matrix Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No Qual
420 4 Phenolics, Total
Analytical Method EPA 420 4
Phenol
0 045 mg /L 0 010
0 010 1
06/30/08 13 12 108 -95 -2
5220D COD
Analytical Method SM 52200
Chemical Oxygen Demand
233 mg /L 250
250 1
06/26108 1139
Date 07/0912008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 8 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

Page 12 of 46
Analytical Laboratory
® Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalyt cal 2225 Riverside Dr 9800 Kincey Ave Suite 100
� wrvwpacaJabs.com Asheville, NC 28804 Huntersville, NC 28078
(826)254 -7176 (704)8759092
ANALYTICAL RESULTS
Project 08- JUN -0400
Pace Project No 9221945
Sample 28017348 Lab ID 9221945003 Collected 06/23/08 08 40 Received 06123/08 11 45 Matrix Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No Qual
52108 BOD, Low Level Analyhcal Method SM 5210B
BOD, 5 day 54 9 mg /L 20 1 06/25/08 07 30 06/30/08 07 30
i
I
Date 07/09/2008 03 30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc
Page 9 of 24

Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 10 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
M�
Page 13 of 46
(
Analytical Laboratory
e
Pace Analytical Services, Inc
Pace Analytical Services, Inc
aceAnalytical
2225 Riverside Or
9800 KinceyAve Suite 100
wwwpacelabs.com
Asheville, NC 28804
Huntersville, NC 28078
(828)254 -7176
(704)875 -9092
QUALITY CONTROL DATA
Project 08- JUN -0400
Pace Project No 9221945
QC Batch MBCH /1652
Analysis Method SM 9222D
QC Batch Method SM 9222D
Analysis Description 9222D MBIO Fecal Coliform - CHT
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 132486
Associated Lab Samples 9221945001, 9221945002
Blank Reporting
Parameter Units
Result Limit Qualifiers
Fecal Coliforms CFU /100 mL
ND 10
SAMPLE DUPLICATE 132487
9221945001 Dup Max
Parameter Units
Result Result RPD RPD
Qualifiers
Fecal Coliforms CFU /100 mL
ND NO 0 20
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 10 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
M�

Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 11 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
Page 14 of 46
Analytical Laboratory
I e
Pace Analytical Services, Inc
Pace Analytical Services, Inc
aceAnalytical
2225 Riverside Or
9800 Kincey Ave Suite 100
I! wwwpacefaMcan
Asheville, NC 28804
Huntersville NC 28078
(828)254 -7176
(704)875 -9092
QUALITY CONTROL DATA
Project 08-JUN -0400
Pace Project No 9221945
QC Batch WET 14435
Analysis Method
SM 5210B
QC Batch Method SM 5210B
Analysis Description
52108 BOD, Low Level
Associated Lab Samples 9221945001, 9221945002,
9221945003
METHOD BLANK 132528
Associated Lab Samples 9221945001,
9221945002,
9221945003
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
BOD, 5 day
mg /L
ND
20
LABORATORY CONTROL SAMPLE
132529
Spike LOS
LOS % Rec
Parameter
Units
Conc Result
% Rec Limits
Qualifiers
BOD, 5 day
mg /L
198 211
107 84 -115
SAMPLE DUPLICATE 132530
9221990001 Dup
Max
Parameter
Units
Result Result
RPD RPD
Qualifiers
BOD, 5 day
mg /L
31
31 0
20
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 11 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

QUALITY CONTROL DATA
Protect 08- JUN -0400
Page 15 of 46
Analytical Laboratory
Pace Protect No 9221945
®
Pace Analytical Services, Inc
Pace Analytical Services, Inc
aceAnalytical
2225 Riverside Dr
9800 Kincey Ave Suite 100
EPA 245 1
Asheville, NC 28804
Huntersville, NC 28078
wwwpacelaft=n
Analysis Description
245 1 Mercury
(828)254 -7176
(704)875 -9092
QUALITY CONTROL DATA
Protect 08- JUN -0400
Pace Protect No 9221945
QC Batch MERP /1556
Analysis Method
EPA 245 1
QC Batch Method EPA 245 1
Analysis Description
245 1 Mercury
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 132539
Associated Lab Samples 9221945001,
9221945002
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Mercury
ug /L
ND 020
LABORATORY CONTROL SAMPLE
132540
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Mercury
ug /L
2 5 27
109
85 -115
MATRIX SPIKE SAMPLE
132541
9221970001 Spike
M5
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Mercury
ug/L
24 2 5
4 3
76 70 -130
SAMPLE DUPLICATE 132542
9221970002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Mercury
ug /L
ND ND
a1177µ,
„
120 RT
Date 0710912008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 12 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

Page 16 of 46
Analytical Laboratory
0 Pace Analytical Services, Inc Pace Analytical Services, Inc
I,/ aceAnalytical 2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacelabs=M Asheville, NC 28804 Huntersvilie, NC 28078
(828)254 -7176 (704)8759092
QUALITY CONTROL DATA
Project 08-JUN-0400
Pace Project No 9221945
QC Batch MPRP /2580 Analysis Method EPA 200 7
QC Batch Method EPA 200 7 Analysis Description 200 7 MET
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 132549
Associated Lab Samples
Parameter
9221945001, 9221945002
Units
Blank
Result
Reporting
Limit Qualifiers
Aluminum
ug /L
ND
100
Arsenic
ug /L
ND
50
Banum
ug /L
ND
50
Boron
ug /L
ND
500
Cadmium
ug /L
ND
10
Chromium
ug /L
ND
50
Cobalt
ug /L
ND
50
Copper
ug /L
ND
50
Iron
ug /L
ND
500
Magnesium
ug /L
ND
100
Manganese
ug /L
ND
50
Nickel
ug /L
ND
50
Selenium
ug /L
ND
100
Silver
ug /L
ND
50
Tin
ug /L
ND
50
Titanium
ug /L
ND
50
Zinc
ug/L
ND
100
LABORATORY CONTROL SAMPLE
Parameter
132550
Units
Spike
Conc
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Aluminum
ug/L
5000
4610
92
85 -115
Arsenic
ug/L
500
481
96
85 -115
Banum
ug /L
500
466
93
85 -115
Boron
ug /L
500
478
96
85 -115
Cadmium
ug /L
500
477
95
85 -115
Chromium
ug /L
500
483
97
85 -115
Cobalt
ug /L
500
474
95
85 -115
Copper
ug /L
500
474
95
85 -115
Iron
ug /L
5000
4780
96
85 -115
Magnesium
ug /L
5000
4750
95
85 -115
Manganese
ug /L
500
481
96
85 -115
Nickel
ug /L
500
478
96
85 -115
Selenium
ug /L
500
462
92
85 -115
Silver
ug /L
250
243
97
85 -115
Tin
ug /L
500
483
97
85 -115
Titanium
ug /L
500
483
97
85 -115
Zinc
ug /L
500
470
94
85 -115
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 13 of 24
This report shall not be reproduced, except In full
without the written consent of Pace Analytical Services, Inc
Q�,ce e
JC.HI\�

Page 17 of 46
Analytical Laboratory
I
®
Pace Analytical 5 Rivers de Dr Pace 9800 K Analytical
AS ervSuite Inc
aceAnalybscem Asheville, NC 28804 Huntersville NC 28078
w�vwpacelabscom
(828)254 -7176 (704)875 -9092
i
QUALITY CONTROL DATA
Project 08- JUN -0400
Pace Project No 9221945
Units
9221925001
Result
Dup
Result
RPD
Max
RPD Qualifiers
Aluminum
MATRIX SPIKE SAMPLE
132551
47000
1
20
Arsenic
ug /L
225
197
9221909014
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Aluminum
ug/L
NO
5000
4730
93
70 -130
Arsenic
ug /L
NO
500
468
93
70 -130
Barium
ug /L
ND
500
389
77
70 -130
Boron
ug /L
825
500
523
88
70 -130
Cadmium
ug /L
NO
500
407
81
70 -130
Chromium
ug /L
NO
500
425
85
70 -130
Cobalt
ug /L
NO
500
398
80
70 -130
Copper
ug /L
11 3
500
453
88
70 -130
Iron
ug /L
256
5000
4270
80
70 -130
Magnesium
ug /L
3840
5000
7610
75
70 -130
Manganese
ug /L
85
500
413
81
70 -130
Nickel
ug /L
NO
500
402
80
70 -130
Selenium
ug /L
104
500
467
91
70 -130
Silver
ug /L
NO
250
226
90
70 -130
Tin
ug /L
NO
500
418
83
70 -130
Titanium
ug /L
NO
500
421
84
70 -130
Zinc
ug /L
363
500
476
88
70 -130
SAMPLE DUPLICATE 132552
Parameter
Units
9221925001
Result
Dup
Result
RPD
Max
RPD Qualifiers
Aluminum
ug /L
46500
47000
1
20
Arsenic
ug /L
225
197
13
20
Barium
ug/L
526
536
2
20
Boron
ug /L
56 0
544
3
20
Cadmium
ug /L
104
11 1
7
20
Chromium
ug /L
553
560
1
20
Cobalt
ug /L
NO
NO
0
20
Copper
ug /L
1550
1590
2
20
Iron
ug /L
228000
249000
9
20
Magnesium
ug /L
27200
27500
1
20
Manganese
ug/L
2760
2790
1
20
Nickel
ug /L
398
404
1
20
Selenium
ug/L
315
301
5
20
Silver
ug /L
NO
2 6J
3
20
Tin
ug/L
285
289
1
20
Titanium
ug/L
3350
3380
7
20
Zinc
ug /L
268000
290000
8
20
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 14 of 24
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc

aceAnalytical
w,sw pxelab&=
Project 08- JUN -0400
Pace Project No 9221945
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
QC Batch WETA/2944 Analysis Method SM 5220D
QC Batch Method SM 5220D Analysis Description 52200 COD
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 132909
Associated Lab Samples 9221945001, 9221945002
Blank Reporting
Parameter Units Result Limit Qualifiers
Chemical Oxygen Demand mg /L ND 250
Page 18 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersvilie, NC 28078
(704)875 -9092
LABORATORY CONTROL SAMPLE
132910
9221381001
Dup
Max
Parameter Units
Result
Spike LCS
RPD RPD Qualifiers
LCS
% Rec
ND
j52 ;20 °R1
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Max
Chemical Oxygen Demand
mg /L
750
760
101
90 -110
11900
8 20
MATRIX SPIKE SAMPLE
132911
9221755001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits
Qualifiers
Chemical Oxygen Demand
mg /L
2040
750
5220
; 1424
_ 757125,M0'
Ay
L�
MATRIX SPIKE SAMPLE
132914
9221804002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits
Qualifiers
Chemical Oxygen Demand
mg /L
115
750
904
105
75 -125
SAMPLE DUPLICATE 132912
9221381001
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
Chemical Oxygen Demand mg /L
ND
ND
j52 ;20 °R1
SAMPLE DUPLICATE 132913
9221804001
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
Chemical Oxygen Demand mg /L
12800
11900
8 20
Date 07/09/2008 03 30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of tPace Analytical Services, Inc
�lJeki�
Page 15 of 24

QUALITY CONTROL DATA
Project 08- JUN -0400
Page 19 of 46
Analytical Laboratory
Pace Analytical Services, Inc
Pace Analytical Services, Inc
®
1,-.,Pa"ce Analytical
2225 Riverside Or
9800 Kincey Ave Suite 100
QC Batch Method SM 2540D
Asheville, NC 28804
Huntersville NC 28078
wwa!pacelabs.com
Associated Lab Samples 9221945001,
9221945002
(828)254 -7176
(704)875 -9092
QUALITY CONTROL DATA
Project 08- JUN -0400
Pace Project No 9221945
QC Batch WET 14484
Analysis Method
SM 2540D
QC Batch Method SM 2540D
Analysis Description
2540D Total Suspended Solids
Associated Lab Samples 9221945001,
9221945002
METHOD BLANK 134338
Associated Lab Samples 9221945001,
9221945002
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Total Suspended Solids
mg /L
ND
10
LABORATORY CONTROL SAMPLE
134339
Spike LCS
LCS % Rec
Parameter
Units
Conc Result
% Rec Limits Qualifiers
Total Suspended Solids
mg /L
250 264
106 80 -120
SAMPLE DUPLICATE 134341
9222027001 Dup
Max
Parameter
Units
Result Result
RPD RPD Qualifiers
Total Suspended Solids
mg /L
940
980 4 20
SAMPLE DUPLICATE 134410
9222029002 Dup
Max
Parameter
Units
Result Result
RPD RPD Qualifiers
Total Suspended Solids
mg /L
ND
ND 200; ; ` =�t �� "°,20,
7
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 16 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services Inc
" Sv
ffielk

{
i
/ aceftlytical e
j wwwpacefaftcw
I ,
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Page 20 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875 -9092
Project 08- JUN -0400
Pace Project No 9221945
QC Batch WETA/2975
Analysis Method
EPA 420 4
QC Batch Method EPA 420 4
Analysis Description
420 4 Phenolics
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 134431
Associated Lab Samples 9221945001,
9221945002
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Phenol
mg /L
ND 0 010
LABORATORY CONTROL SAMPLE
134432
Spike LCS
LCS
% Rec
Parameter
Units
Cone Result
% Rec
Limits
Qualifiers
Phenol
mg /L
25 024
96
90 -110
MATRIX SPIKE SAMPLE
134433
9221843006 Spike
MS
MS
% Rec
Parameter
Units
Result Cone
Result
% Rec
Limits Qualifiers
Phenol
mg /L
021 25
047
104
90 -110
SAMPLE DUPLICATE 134434
9221925001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Phenol
mg /L
ND ND 47:;;,
=;_" ,_ { 20,R1
�Jv
o� Io`l
i` t0,
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 17 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc

Page 21 of 46
Analytical Laboratory
A111*7 ® Pace Analytical Services, Inc Pace Analytical Services, Inc
124 aceAnalytical 2225 Riverside Dr 9800 Kincey Ave Suite 100
wwwpacefab&com Asheville, NC 28804 Hunterswlle, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project 08- JUN -0400
Pace Project No 9221945
QC Batch GCSV /3150 Analysis Method EPA 1664A
QC Batch Method EPA 1664A Analysis Description 1664 HEM, Oil and Grease
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 134471
Associated Lab Samples 9221945001, 9221945002
Blank Reporting
Parameter Units Result Limit Qualifiers
Oil and Grease mg /L ND 50
LABORATORY CONTROL SAMPLE & LCSD 134472 134473
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc Result Result % Rec % Rec Limits RPD RPD Qualifiers
Oil and Grease mg /L 40 395 387 99 97 78 -114 2 30
Date 07/09/2008 03 30 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc
:CLL�_
Page 18 of 24

i
Page 22 of 46
Analytical Laboratory
® Pace Analytical Services, Inc Pace Analytical Services, Inc
!( aceAnalytical 2225 Riverside Or 9800 Kincey Ave Suite 100
f Asheville NC 28804 Huntersville, NC 28078
wwwpacelaeacom
(828)254 -7176 (704)875 -9092
QUALITY CONTROL DATA
Project 08- JUN -0400
Pace Project No 9221945
QC Batch WETA/2976
Analysis Method EPA
365 1
QC Batch Method EPA 365 1
Analysis Description 3651 Phosphorus, Total
Associated Lab Samples 9221945001,
9221945002
METHOD BLANK 134637
Associated Lab Samples 9221945001, 9221945002
Blank Reporting
Parameter
Units
Result Limit
Qualifiers
Phosphorus
mg /L
NO 010
LABORATORY CONTROL SAMPLE
134638
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Phosphorus
mg /L
1 11
107
90 -110
MATRIX SPIKE SAMPLE
134639
9222315001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Phosphorus
mg /L
77 1
8 8
110 90 -110
MATRIX SPIKE SAMPLE
134647
9222090001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc
Result
% Rec
Limits Qualifiers
Phosphorus
mg /L
3 9 1
4 8
97 90 -110
SAMPLE DUPLICATE 134640
9222315002 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Phosphorus
mg /L
0 50 048
3
20
SAMPLE DUPLICATE 134648
9222112001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Phosphorus
mg /L
025 022
13
20
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 19 of 24
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services, Inc

f
/ �aceAnalytical
wwwpacatab&mn
Pace Analytical Services, Inc
2225 Riverside Or
Asheville, NC 28804
(828)254 -7176
QUALITY CONTROL DATA
Page 23 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)8759092
Project 08- JUN -0400
Pace Project No 9221945
QC Batch WETA/2979
Analysis Method EPA 350 1
QC Batch Method EPA 350 1
Analysis Description 350
1 Ammonia
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 134684
Associated Lab Samples 9221945001, 9221945002
Blank
Reporting
Parameter
Units
Result
Limit
Qualifiers
Nitrogen, Ammonia
mg /L
NO
010
LABORATORY CONTROL SAMPLE
134685
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Nitrogen, Ammonia
mg /L
5
51
102
90 -110
MATRIX SPIKE SAMPLE
134686
9221937001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg /L
094
5
7 0
421 �90�110 "M0;
MATRIX SPIKE SAMPLE
134689
9221967005
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg /L
367
500
368
SAMPLE DUPLICATE 134687
9221945001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg /L
1 7
1 6
3
20
SAMPLE DUPLICATE 134688
9221967004
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Ammonia
mg /L
192
196
2
20
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 20 of 24
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc
`IlJ-GILI,�

I
aceAnalytical
wwwp"labs.c=
QUALITY CONTROL DATA
Project 08- JUN -0400
Page 24 of 46
Analytical Laboratory
Pace Analytical Services, Inc
Pace Analytical Services, Inc
2225 Riverside Dr
9800 Kincey Ave Suite 100
Asheville, NC 28804
Huntersville, NC 28078
(828)254 -7176
(704)875 -9092
QUALITY CONTROL DATA
Project 08- JUN -0400
Pace Project No 9221945
QC Batch WETA/2980
Analysis Method
EPA 351 2
QC Batch Method EPA 3512
Analysis Description
351 2 TKN
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 135028
Associated Lab Samples 9221945001, 9221945002
Blank
Reporting
Parameter
Units
Result
Limit
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
ND
050
LABORATORY CONTROL SAMPLE
135029
Spike LCS
LCS
% Rec
Parameter
Units
Conc Result
% Rec
Limits
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
5
52
104
90 -110
MATRIX SPIKE SAMPLE
135030
9222267008
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
2 7
5 7 3
92
90 -110
MATRIX SPIKE SAMPLE
135032
9221945001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc
Result
% Rec
Limits Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
24
5 6 8
90
90 -110
SAMPLE DUPLICATE 135031
9222267009
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
27
22
SAMPLE DUPLICATE 135033
9221945002
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, Kjeldahl, Total
mg /L
77
57 29,
m'f ` 20"R1
Date 07109/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 21 of 24
This report shall not be reproduced, except in full
without the written consent of Pace Analytical Services, Inc

Page 25 of 46
Analytical Laboratory
Pace Analytical Services, Inc Pace Analytical Services, Inc
aceAnalytical ® 2225 Riverside Dr 9800 Kincey Ave Suite 100
i Asheville, NC 28804 Huntersville, NC 28078
wwwpacela6xcom
� (828)254 -7176 (704)8759092
QUALITY CONTROL DATA
Project 08- JUN -0400
Pace Project No 9221945
QC Batch WETA/2997
Analysis Method
EPA 353 2
QC Batch Method EPA 353 2
Analysis Description
353 2 Nitrate + Nitrite,
preserved
Associated Lab Samples 9221945001, 9221945002
METHOD BLANK 136274
Associated Lab Samples 9221945001,
9221945002
Blank
Reporting
Parameter
Units
Result
Limit
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND
010
LABORATORY CONTROL SAMPLE
136275
Spike LCS
LCS
% Rec
Parameter
Units
Cone Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
5
50
101
90 -110
MATRIX SPIKE SAMPLE
136276
9222267009
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone
Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg/L.
ND
5 4 9
98 75 -125
MATRIX SPIKE SAMPLE
136278
9221945002
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone
Result
% Rec
Limits
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
12
5 5 5
86 75 -125
SAMPLE DUPLICATE 136277
9222267010
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
ND
ND
0)-0 S
SAMPLE DUPLICATE 136279
9222177003
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Nitrogen, NO2 plus NO3
mg /L
6 9
69 1
20
Date 07/0912008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 22 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
L�GIQ�.

aceAnalytical
wwwpaaslaMcom
QUALIFIERS
Project 08- JUN -0400
Pace Project No 9221945
DEFINITIONS
Pace Analytical Services, Inc
2225 Riverside Dr
Asheville NC 28804
(828)254 -7176
Page 26 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kincey Ave Suite 100
Huntersville NC 28078
(704)875 -9092
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content
ND - Not Detected at or above adjusted reporting limit
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MOIL -Adjusted Method Detection Limit
S - Surrogate
1,2- Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable
Pace Analytical is NELAP accredited Contact your Pace PM for the current list of accredited analytes
ANALYTE QUALIFIERS
B2 Oxygen usage is less than 2 0 for all dilutions set The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample
MO Matrix spike recovery was outside laboratory control limits
R1 RPD value was outside control limits
R3 RPD value was outside control limits due to uncertainty of values at or near the PRL
u1 Results based upon colony counts outside acceptable range
Date 07/09/2008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 23 of 24
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc
�, A

o Pace Analytical Services, Inc
f a Analytical 2225 Riverside Dr
wwwpaWabscom Asheville NC 28804
(828)254 -7176
I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project 08- JUN -0400
Pace Project No 9221945
Page 27 of 46
Analytical Laboratory
Pace Analytical Services, Inc
9800 Kmcey Ave Suite 100
Huntersville NC 28078
(704)875 -9092
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
9221945001
28017343
SM 9222D
MBCH /1652
9221945002
28017347
SM 9222D
MBCH /1652
9221945001
28017343
SM 5210B
WET/4435
SM 5210B
9221945002
28017347
SM 52108
WET /4435
SM 5210B
9221945003
28017348
SM 5210B
WET/4435
SM 5210B
9221945001
28017343
EPA 245 1
MERP /1556
EPA 2451
9221945002
28017347
EPA 2451
MERP 11556
EPA 2451
9221945001
28017343
EPA 200 7
MPRP /2580
EPA 200 7
9221945002
28017347
EPA 200 7
MPRP 12580
EPA 200 7
9221945001
28017343
SM 52200
WETA/2944
9221945002
28017347
SM 5220D
WETA/2944
9221945001
28017343
SM 2540D
WET/4484
9221945002
28017347
SM 2540D
WET14484
9221945001
28017343
EPA 420 4
WETA12975
9221945002
28017347
EPA 4204
WETA/2975
9221945001
28017343
EPA 1664A
GCSV /3150
9221945002
28017347
EPA 1664A
GCSV /3150
9221945001
28017343
EPA 3651
WETA12976
9221945002
28017347
EPA 365 1
WETA/2976
9221945001
28017343
EPA 3501
WETA/2979
9221945002
28017347
EPA 350 1
WETA12979
9221945001
28017343
EPA 351 2
WETA12980
9221945002
28017347
EPA 351 2
WETA/2980
9221945001
28017343
EPA 353 2
WETA/2997
9221945002
28017347
EPA 353 2
WETA12997
Analytical
Batch
WET/4499
WET/4499
WET /4499
MERC /1558
MERC /1558
ICP/2462
ICP12462
Date 07/0912008 03 30 PM REPORT OF LABORATORY ANALYSIS Page 24 of 24
This report shall not be reproduced except in full,
without the written consent of Pace Analytical Services Inc
.lhe of Wt

Page 28 of 46
Analytical Laboratory
!' �! /�ceAralytical'
Client Name 1�L,►�,� Project #
Courier ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial Pace Other Option M'
Pro v'DuesDate NIA
Custody Seal on Cooler /Box Present yes ❑ no Seals Intact yes ❑ no »� NA
Packing Material ❑ Bubble Wrap (Bubble Bags [I None ❑Other
Thermometer Used T060 r Type of Ice et Blue None OX.,m1 les on ice, cooling process has begun
Cooler Temperature
Temp should be above freezing to 6 °C
�'� f Date and [nit i of erson examining
Biological Tissue is Frozen Yes N
contents G
Co mments
Chain of Custody Present
Yes ONo
ON /A
1
Chain of Custody Filled Out
36yes ONo
ON /A
2
Chain of Custody Relinquished
Yes ONo
❑N /A
3
Sampler Name & Signature on COC
Yes ONo
ON /A
4
Samples Arnved within Hold Time
Yes ONo
ON /A
5
Short Hold Time Analysis ( <72hr)
Yes ONo
ON /A
6
Rush Turn Around Time Requested
OYes ONo
ON /A
7
Suffictent Volume
❑Yes ko
❑N /A
8 W%d Nb� �o iv°Ga (Q la r ..V %.1, v--S
Correct Containers Used
-Pace Containers Used
OYes XNo
❑Yes No
ON /A
C3 N/A
g f,,, ?l Ae -vo %S 25-c' /11 /3c-
sv�lb °_ 2 rOL6«"
Containers Intact
kes ONo
ON /A
10
Filtered volume received for Dissolved tests
OYes ONo
N/A
11
Sample Labels match COC Yes ONo ❑N/A
- Includes date /time /ID /Analysis Matrix
12
All containers needing preservation have been checked
All containers needing preservation are found to be in
compliance with EPA recommendation
exceptions VOA, coliform TOC, O &G, WI -DRO (water)
Yes ONO
Yes ONo
//
❑Yes ONo
C1 N/A
C1 N/A
13
Initial when completed
Samples checked for dechlorination
Yes ❑No
ON /A
14
Headspace in VOA Vials ( >6mm)
OYes ONo
ON /A
15
Trip Blank Present
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased) N/A
OYes ONo
OYes ONo
AN /A
�N/A
15
Client Notification/ Resolution Field Data Required*7 Y / N / N/A
Person Contacted Aoq AA-ti Date/Time G Z3 o 131&
Comments/ Resolution
Project Manager Review
Date 6,
Note Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( i e out of hold, incorrect preservative, out of temp incorrect containers)

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Analytical Laboratory
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' Page 44 of 46
Analytical Laboratory
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Page 45 of 46
Analytical Laboratory
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1'
I Page 46 of 46
Analytical Laboratory
t
1
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9800 Kincey Ave, Suite 100
aceAnalytical a, Huntersville, NC 28078
i
wwwpacelabs.com (704)875 -9092
i,
! SAMPLE ACKNOWLEDGEMENT
Samples Submitted By Duke Energy Pace Protect Manager Kevin Herring
Client Project ID 08- JUN -0400 Phone [phone]
Client PO# ISW01 0000000341 kevin hernng @pacelabs com
Pace Analytical Project ID 9221945
Samples Received. June 23, 2008
Estimated Completion July 08, 2008
Please contact your project manager if you recognize any discrepancy in this form or have any questions about your protect
Thank you for choosing Pace Analytical Services, Inc
Page 1 of 1
Pace Analytical
Datefrime
Customer Sample ID
Lab ID
Matrix
Collected
Method
28017343
9221945001
Water
06/23/08 08 30
200 7 MET ICP
Aluminum, Arsenic, Barium, Boron, Cadmium,
Chromium, Cobalt, Copper, Iron, Magnesium,
Manganese, Nickel, Silver, Zinc, Titanium, Tin,
Selenium
245 1 Mercury
2540D Total Suspended Solids
350 I Ammonia
351 2 Total Kjeldahl Nitrogen
353 2 Nitrogen, NO2/NO3 pres
365 l Phosphorus, Total
420 4 Phenolics, Total
5210B BOD, Low Level
5220D COD
HEM, Oil and Grease .
MBIO 9222D Fecal Coliform CHT
28017347
9221945002
Water
06/23/08 08 40
200 7 MET ICP
Aluminum, Arsenic, Barium, Boron, Cadmium,
Chromium, Cobalt, Copper, Iron, Magnesium,
Manganese, Nickel, Silver, Zinc, Titanium, Tin,
Selenium
245 1 Mercury
2540D Total Suspended Solids
350 1 Ammonia
351 2 Total• Kjeldahl Nitrogen
353 2 Nitrogen, NO2/NO3 pres
365 I Phosphorus, Total
420 4 Phenolics, Total
5210B BOD, Low Level
5220D COD
HEM, Oil and Grease
MBIO 9222D Fecal Cohform CHT
28017348
9221945003
Water
0623/08 08 40
5210B BOD, Low Level v
Please contact your project manager if you recognize any discrepancy in this form or have any questions about your protect
Thank you for choosing Pace Analytical Services, Inc
Page 1 of 1