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HomeMy WebLinkAboutNC0026042_Wasteload Allocation_19930426NPDES DOCUMENT SCANNING% COVER SHEET NC0026042 Robersonville WWTP NPDES Permit: Document Type: Permit Issuance f Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Correspondence Speculative Limits Instream Assessment (67b) Environmental Assessment (EA) Permit History Document Date: April 26, 1993 This document is printed an reuse paper - ignore any content on the re -sr -erne side rok Ink ,. NPDES WASTE LOAD ALLOCATION PERMIT NO.: NC0026042 PERMIT FEE NAME: FACILITY NAME: Town of Robersonville Robersonville Wastewater Treatment Facility Facility Status: Existing Permit Status: Renewal Major Minor Pipe No.: 001 Design Capacity: 1.8 MGD Domestic (% of Flow): 20 % Industrial (% of Flow): 80 % Comments: RECEIVING STREAM: Flat swamp Class: C-Swamp NSW Sub -Basin: 03-03-06 Reference USGS Quad: E30NW (please attach) County: Martin Regional Office: Washington Regional Office Previous Exp. Date: 12/31/92 Treatment Plant Class: class IV Classification changes within three miles: No change within three miles. Requested by: Prepared by ,rwaa,,,., Reviewed by: � --,(ICl/Y rJ - o,� 6.5 (s(a) PLATTED Randy Kepler iR Date: 2/2/93 Date: 4/2z f q3 Date: q/I-3 9.3 Modeler Date Rec. # 5Prvo Z(4\c13 -13z5 Drainage Area (mi2 ) J e3 Avg. Streamflow (cfs): I 7Q10 (cfs) 6, Z7 Winter 7Q10 (cfs) 6.73 30Q2 (cfs) Toxicity Limits: IWC t u % Acute/Chronic' , FA: Instream Monitoring: Parameters Tt',rvi PEtzhTu.'L - D. 0 . r cn t- 65 L t F C(rvDKCT, 1 ry Location AT- l.t +sr loo/ u►lsT+zt 4 Location 'l74;wNl7rzeAen AT SR Go( Upstream Downstream y Effluent Characteristics Summer Winter BOD5 (mg/1) 5 5 NH3-N (mg/1) Z 2- D.O. (mg/1) L TSS (mg/1) - F. Col. (/100 ml) 2o0 Zoo pH (SU) 6. _ 1 6 _� CovPea (ktfi/ MoNIIlea_ —___---- ,.tvN t7eR. 64vOt.T MuN 1 Tv-(Z L1aID (itricU/I) ' 1N �G_(44).2--- - Mre.Nc-lviL- MDNI 'rv2 iV wI1TV1z- MONI r- Mef a y { : 1/L.) kapgtDe (rL 4):_ luvnlsTom c Ni T o/z. Comments: ;t od.6 5t-11.u4 Cw•1-r2ol,5 nn1 Nur2u r 1-,MITs Mhy (Lu:2e rN Tim 4uror C FCC a Ttj 15 (roT PART t A590u i- lont Facility Name: NPDES No.: Type of Waste: Facility Status: Permit Status: Receiving Stream: Stream Classification: Subbasin: County: Regional Office: Requestor: Date of Request: Topo Quad: FACT SHEET FOR WASTELOAD ALLOCATION Request # Robersonville WWTP NC0026042 20% dom/ 80% ind Existing Renewal Flat Swamp'Fi C-Sw, NSW 030306 Martin WaRO R. Kepler 2/2/93 E3ONW RECEIVED WASHINGTON OFFICE 73 aii 1 4 1993 Stream Characteristic: USGS # Date: Drainage Area (mi2): Summer 7Q10 (cfs): Winter 7Q10 (cfs): Average Flow (cfs): 30Q2 (cfs): IWC (%): D.EM. 18 0.27 0.73 18 91% Wasteload Allocation Summary (approach taken, correspondence with region, EPA, etc.) A Level C study was performed for this facility. Anoxic conditions were predicted even at 5/2 due to wastewater and natural swamp conditions; 5/2 limits were recommended to minimize impacts. The model included the Eagle Snacks discharge downstream. No violations of limits are indicated on the compliance system. Instream data pulled in 6/92 indicate low D.O.'s upstream and higher D.O.'s appx. 3.5 miles downstream. (Summer 1992 data does not indicate D.O.'s under 5 mg/1). Robersonville is not part of the Tar Pam Basin Assoc. If they expand, they will be subject to nutrient limits. The facility should be warned that "more stringent controls on nutrient inputs may be required in the future" even if the facility does not expand. Pretreatment information indicates that the facility is implementing a program. The facility had a meeting with TSB 6/92 asking for relaxation of their limits (small tax base and major SIU [Perdue] was pressuring the Town to lower costs); TSB denied request for relaxation of limits due to the predicted anoxic conditions on Flat Swamp. Special Schedule Requirements and additional comments from Reviewers: Recommended by: /rwa�.. 'I . �(%l �,ve�- Date: '7 � 3 Reviewed by Instream Assessment: Regional Supervisor: , , _ /�L _ ,�:..� Date: Permits & Engineering: Date:4 Z443____ Date: 4 /g13 RETURN TO TECHNICAL SERVICES BY: MAY 1 1 1993 2 CONVENTIONAL PARAMETERS Existing Limits: Monthly Average Summer Winter Wasteflow (MGD): 1.8 1.8 BOD5 (mg/1): 5 5 NH3N (mg/1): 2 2 DO (mg/1): 6 6 TSS (mg/1): 30 30 Fecal Col. (/100 ml): 1000 1000 pH (SU): 6-9 6-9 Residual Chlorine (14/1): Oil & Grease (mg/1): TP (mg/1): TN (mg/1): Recommended Limits: Monthly Average Summer Winter WQ or EL Wasteflow (MGD): 1.8 1.8 BOD5 (mg/1): 5 5 NH3N (mg/1): 2 2 DO (mg/1): 6 6 TSS (mg/1): 30 30 Fecal Col. (/100 ml): 200 200 pH (SU): 6-9 6-9 Residual Chlorine (1.tg/1): Oil & Grease (mg/1): TP (mg/1): TN (mg/1): Hoc) ou rt cLe Crnc ) me-v+-L- ✓ ti,uck r4-e t. j� Limits Changes Due To: Parameter(s) Affected Change in 7Q10 data Change in stream classification Relocation of discharge Change in wasteflow Other (onsite toxicity study, interaction, etc.) Instream data New regulations/standards/procedures Fecal coliform New facility information (explanation of any modifications to past modeling analysis including new flows, rates, field data, interacting discharges) (See page 4 for miscellaneous and special conditions, if applicable) 3 Type of Toxicity Test: Existing Limit: Recommended Limit: Monitoring Schedule: Existing Limits COD (mg/): Cadmium (ug/l): Chromium (ug/1): Copper (ug/1): Nickel (ug/l): Lead (ug/1): Zinc (ug/1): Cyanide (ug/1): Phenols (ug/l): Mercury (ug/1): Silver (ug/1): Recommended Limits COD (mg/): Cadmium (ug/1): Chromium (ug/1): Copper (ug/1): Nickel (ug/1): Lead (ug/l): Zinc (ug/1): Cyanide (ug/l): Phenols (ug/l): Mercury (ug/1): Silver (ug/l): TOXICS/METALS Chronic Chronic Quarterly P/F at 91% Chronic Quarterly P/F at �% (�i 0 7o) Feb, May, Aug, Nov Limits Changes Due To: New pretreatment information Daily Max. Daily Max. monitor monitor monitor monitor WQ or EL C sop PDR. ktATe Rs) Parameter(s) Affected Based on "domestic/uncontrollable" pretreatment information (elevated values) C., Failing toxicity test Other (onsite toxicity study, interaction, etc.) _X Parameter(s) are water quality limited. For some parameters, the available load capacity of the immediate receiving water will be consumed. This may affect future water quality based effluent limitations for additional dischargers within this portion of the watershed. OR No parameters are water quality limited, but this discharge may affect future allocations. 4 INSTREAM MONITORING REQUIREMENTS Upstream Location: at least 100 ft upstream Downstream Location: downstream at SR 1506 Parameters: temperature, D.O., Fecal coliform, conductivity Special instream monitoring locations or monitoring frequencies: MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS Adequacy of Existing Treatment Has the facility demonstrated the ability to meet the proposed new limits with existing treatment facilities? Yes No If no, which parameters cannot be met? Would a "phasing in" of the new limits be appropriate? Yes No If yes, please provide a schedule (and basis for that schedule) with the regional office recommendations: If no, why not? Special Instructions or Conditions Wasteload sent to EPA? (Major) N (Y or N) (If yes, then attach schematic, toxics spreadsheet, copy of model, or, if not modeled, then old assumptions that were made, and description of how it fits into basinwide plan) Additional Information attached? N (Y or N) If yes, explain with attachments. Facility Name RBePsoN\11 [.t.E Vil,ITP Permit # COOZ(o0 Z Pipe CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in: 1.) The North Carolina Ccriodaphnia chronic effluent bioassay Procedure - Revised *September 1989) or subsequent versions.procedure Carolina Chronic Bioassay The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is q n % (defined as treatment two in the North Carolina guermonitoring using this procedure to establish compliancewith ture he document). mit conditThe ion. holder first test will b performedafter thirty days from the effective date of this permit during the months of will be A . Effluent sampling for this testis shall be permitted final e `i uent discharge below all treatment processes g performed at the NPDES All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well all dose/response data Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet begin immediately until such time that a single test is passed. Upspecified nep s ng, thilimits; monthly test requirementwill revert to quarterly in the months specified above. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. 7Q10 0-"'7 cfs Permitted Flow I. MGD IWC Basin & Sub -basin _ 030 3o to (T-4,eo 6� Receiving Stream _ Fti r SwamP Chic County Recommended by: ,. 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'tf ''- `! 4f..• ! . 7.9!-. • • /1��rd 9/. r.l • River Mill MHP / Uniprop (NEW FLOWS) Residual Chlorine 7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) UPS BACKGROUND LEVEL (UG/L) IWC (%) Allowable Concentration (ug/I) Fecal Limit (based on 331 : 1) Ammonia as NH3 (summer) 0.27 7010 (CFS) 1.8 DESIGN FLOW (MGD) 2.79 DESIGN FLOW (CFS) 17.0 STREAM STD (MG/L) 0 UPS BACKGROUND LEVEL (MG/L) 91.18 IWC (%) 18.65 Allowable Concentration (mg/l) 200 mg/I Ammonia as NH3 (winter) 7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) UPS BACKGROUND LEVEL (MG/L) IWC (%) Allowable Concentration (mg/I) 0.27 1.8 2.79 1.0 0.22 91.18 1.08 0.47 1.8 2.79 1.8 0.22 85.58 2.07 f-hCIi,(r'1 AL- /k Nfls sr2JA4e,Jr 1\11-13-!i LikiT4N9 t v 13-IJ/ CUoIC.E Ow, 06 NC0056499 4/6/93 W}IOI.G EPIC' TC)X(CITY TE.SfING 0(SELP-NIOM"rOR1NCi SUNI\9ARYMon, Feb I.S. I993 FACILITY REQUIREMENT YETI( JAN I1•:Il MAR APR MAY JUN 1111, AttG SEP OCT NOV. DFC RIVIJ( HIIN Lrn!.TI'I ES PERM (1II( I.IM:JIYt;.1(:11All) 09 --- -•• .-. --- ... ..- ... .,. NC0060291 Begin:I✓01/89 Frequency:Q P/F A JAN Alit JUL. OCI' NonCanp: 90 N1 N1 N1 141 r4"i FAIL Ni -•- PASS LATE PASS »• County: BRUNSWICK Region: WIRO Subbasin: CPF17 91 PASSSIG - -- LATE bt FAIL FAIL FAIL PASS NR FAIL LATE PF:0.025 Special 92 PASS ••- - PASS --- --- FAIL PASS -• PASS -- -- 7Q10:0.09 RVC(%):30.06 order. 93 ROADSIDE TRUCK PLAN-11f)l PERM CI IR LIM:10% Y 89 hA PASS Ni - - Ni PASS PASS PASS -- N00032867 121cpn:12/17/87 Frequency: Q P/F OCT IAN APR JUL NonComp: 90 PASS -- -- PASS - - bt - -• PASS - FAIL County: CLI.NIJ.AND Region: MRO Suhlnsiit: Cr1305 91 WI PASS LATE PASS Ni Ni PASS -- -• PF:0.01 - Special 92 PASS -- PASS •» -- PASS - FAIL.FAIL PASS 7QI0:0.20 DVC(%):10.10 Oren 93 ROBBINS WWI? PERM CHRJAC LIM:I8%/ FTHD 241IR LC50 NC0062855 Dcpn:12/01/91 Frequency: Q PM A JAN APR JUL ocr NonComp: County:MOORE Region: FRO SobbasimCPF10 PF: 1.0 Special 7QI0:15.9 BVq%):8.9 Order: 89 -- 90 -- 91 PASS 92 P.NONEI 93 PASS.PASS 35.41,FAIL PASS.>1001 -- PASS PASS.>1001 -- PASS PASS.79.0I - ROBERSONVILLE WWTP PERM CHR LIM:91 % 89 PI5' NONE' NONE' NONE' NONE' NONE' NONE' NONE' 27.4' `. E' >90 NONE' N00026042 Begin:01/01/88 Frequency: Q P/F FEB MAY AUG NOV NonComp: 90 -- PASS -- - bt -- PASS N3 bt PASS FAIL FAIL County:MARTIN Region: WARO Suhbasin:TAR06 91 PASS PASS PASS -- -- PASS -- -- FAIL PASS PF: 1.80 Specie 92 -- PASS -- LATE/FAIL PASS PASS PASS -- 7Q10:0.27 IWq%):91.18 - - - - - RO➢ESON CO. SCHOOLS PERM CHR LIM:99%. 89 -- - N00034100 Begin: I0/01/90 Frequency: Q P/F A FEB MAY AUG NOV NonComp: 90 -• -- County: ROBESON Region: FRO Subbasin: LUM5I 91 N I PASS PF:0.006 Special SOC: 1113/92.9/1/95TOXREQ WAIVED. 92 H -- 7Q10:0.0 IWq%):100 Order 93 NR Not N3 ROCKINGHAM COMMUNITY COLLEGE PERM 0IR LIM:99% (GRAD) 89 -. -- _. NC0046337 Begin: 12/01/90 Frequency. Q P/F A JAN APR JUL OCT NonComp: 90 -- -. -- -.- -. _. _. _- -- _- -. County:ROCKINGHAM Region:WSRO Subbasin:ROA03 91 FAIL N1 Nt FAIL FAIL FAIL FAIL FAIL FAIL N1 FAIL FAIL PF:0.03 Special 92 FAIL PASS PASS FAIL FAIL FAIL FAIL 64.0,FAIL FAIL FAIL FAIL 7910: 0.0 IWq%):100 Omer 93 FAIL ROCKINGHAM WWTP PERM CHR LIM:28% 89 - - -- -- -- - -- NC0020427 Begin:09/01/90 Frequency: Q P/F A FEB MAY AUG NOV NonComp: 90 -- -- FAIL PASS PASS PASS PASS -• PASS - County:RICHMOND Region: FRO Subbasin: YAD16 91 -- PASS - - PASS -- -- FAIL PASS PASS PF:6.0000 Special 92 -- PASS PASS -- PASS - PASS 7910: 23.4 IWq%):28.4 Orden 93 ROCKWELL SOUTH WWTP PERM CHR L1M:99%, 70%0>0.2 MGD Y 89 FAIL FAIL FAIL bt bt,FAIL FAIL FAIL FAIL FAIL F.17ChV FAIL PASS NO3021768 Begin:09/01/90 Frequency. Q P/F A MAR JUN SEP DEC NonComp: 90 F,28ChV FAIL bt FAIL FAIL FAIL FAIL FAIL PASS PASS FAIL LATE County:ROWAN Region:MRO Sc -6sin:YAD04 91 PASS PASS PASS -- - 83.2 83.2 -- >99 -- -- 83.2 PE:0.20 Special SOC: 4/8/91-10/31/93 OR EXPAN-OW MONNT Q 92 - - >99.0 - >419.0 -- >99.0 -- 37.5 7Q10:0.00 IWq%):100.00 Order (99%,70,61,23,8) 93 ROCKY MOUNT REGIONAL WWI? PERM CHR LIM:21 % Y 89 PASS - PASS PASS - NA bt -- LATE PASS - MR NC0030317 Begin: I I/0I/88 Frequency. Q P/F JAN APR JUL OCr NonComp: 90 PASS - -- PASS - FAIL -• NR PASS County:EDGECOMBE RegioreRRO SubbasireTAR02 91 PASS - -- PASS - PASS - - PASS - PF: 14.0 Special 92 PASS - PASS - PASS PASS 7Q10:83.00 1Wq%):20.73 Otter 93 ROSE HILL WWTP PERM CHR LIM:99% 89 - - -- N3 - FAIL FAIL - - NR NC0056863 Begim07/01/89 Frequary:QP/F JAN APR JUL OCT NonComp: 90 FAIL - -- FAIL - -- FAIL - - PASS County:DUPLIN RegionWSRO SnbbasimCPF22 91 FAIL - PASS - bl PASS - PASS PF:0.45 Special 92 PASS PASS -- FAIL -• - PASS 7QICt 0.00 IWq%):100.00 Order: 93 PASS 0 2 consecutive failures = significant noncompliance Y Pre 1989 Data Available PE R.M = Permit Requirement LET Letter --Target Frequency = Monitoring frequency: Q- Quarterly: M- Monthly: BM- Illnwuthly: SA-Scrnlannnnlly; A- Annually:OWI)- Only when discharging; D. DIscurdhured monitoring requirement: IS. Conducting independent study Benin=First month required 7Q10=Receiving stream low flow criterion (cfs) A =quarterly monitoring increases to monthly upon single failure Months that testing must occur - ex. JAN,APRJUL,OCI NonComp =Current Compliance Requirement PP=Perrdtied flow (MGD) IWC%= Instream waste concentration P/F = Pass/Fall chronic test AC = Acute CHR =Chronic Data Notation: f- Fathead Minnow: • - Cedodaolmia so.: my - Mvsid shrimp: ChV - Chronic value: P - Mortality of stated lerantaste at highest concentration: at - Performed by DEM Act Tox Grotto: bt - Bad test Reporting Notation: - = Data not required; NA - Not reported; ( ) . Beginning of Quarier Facility Activity Status: I - Inactive, N - Newly Issucd(To construct): 11- Active but not discharging SIG = ORC signature needed 4 Page 1 Note for Dana Folley From: Dana Folley Date: Wed, Mar 31, 1993 2:07 PM Subject: RE: To: Susan Wilson Susan - About Oxford, I have some additional data of Oxford's influent and effluent for 5 of the six pollutants for you to use. Please call me when you get back and I'll bring it over. In general, after you redo the numbers using the additional data, Julia and I recommend you revise the limits/monitoring requirements for these pollutants following the interim APAM policy. Please talk to Carla about what this policy is. Carla has a version that she gave to Julia; Julia gave her an alternative policy back, now they both will be discussing these versions with their respective staffs and then getting back to discuss a final interim policy. I have copies of both of these policies if you need them. We in pretreatment went over the two this morning and we like our version best for a variety of reasons that Julia will brief Carla on soon. Julia and I recommend you use our version for these parameters for Oxford. About Robersonville, I have misplaced your sheets so I looked at my PIRF - I assume the parameters were CU, ZN, and HG. In general, we recommend you proceed with the limits/ monitoring requirements as you have determined as this is how everyone else has been treated. When we come up with our new policy, we will revise Robersonville's permit then. From: Susan Wilson on Wed, Mar 24, 1993 10:10 AM To: Dana Folley 1) What's the status on Oxford ? 2) Have you spoken with Julia about possible Hg limit and Cu,Zn monitoring for Robersonville? thanks! 03/03/93 ver 3.1 T O X I C S R E V I E W . Facility: robersonville NPDES Permit No.: nc0026042 Status (E, P, or M) : e Permitted Flow: 1.8 mgd Actual Average Flow: 1.0876 mgd Subbasin: '030306 Receiving Stream: flat swp crk I PRETREATMENT DATA I----EFLLUENT DATA ---- Stream Classification: c-sw,nsw I ACTUAL PERMITTEDI 7Q10: 0.27 cfs I Ind. + Ind. + 1 FREQUENCY IWC: 91.18 % 1 Domestic PERMITTED Domestic 1 OBSERVED of Chronic Stn'd / Bkg 1 Removal Domestic Act.Ind. Total Industrial Total 1 Eflluent Criteria Pollutant AL Conc. 1 Eff. Load Load Load Load Load 1 Conc. Violations (ug/1) (ug/1) 1 it (#/d) (#/d) (#/d) (#/d) (#/d) 1 (ug/1) (#vio/#sam) Cadmium S 2.0 1 0% 1 I Chromium S 50.0 1 0% 1 1 I Copper AL 7.0 1 86% 0.0677 0.0000 0.0677 1 1 N Nickel S 88.0 1 0% 1 1 P Lead S 25.0 1 0% 1 1 U Zinc AL 50.0 1 79% 0.1354 0.0000 0.1354 1 1 T Cyanide S 5.0 1 0% 1 I Mercury S 0.012 1 60% 0.0003 0.0000 0.0003 I 1 S Silver AL 0.06 1 0% I I E Selenium S 5.00 1 0% 1 1 C Arsenic S 50.00 1 0% 1 1 T Phenols S NA 1 0% 1 1 I NH3-N C 1 0% 1 1 O T.R.Chlor.AL 17.0 1 0% 1 1 N ALLOWABLE PRDCT'D PRDCT'D PRDCT'D MONITOR/LIMIT I--ADTN'L RECMMDTN'S-- Effluent Effluent Effluent Instream 1 Recomm'd Conc. using using Conc. Based on Based on Based on 1 FREQUENCY INSTREAM I Allowable CHRONIC ACTUAL PERMIT using ACTUAL PERMITTED OBSERVED 1 Eff. Mon. Monitor. Pollutant 1 Load Criteria Influent Influent OBSERVED Influent Influent Effluent 1 based on Recomm'd ? (#/d) (ug/1) (ug/1) (ug/1) (ug/1) Loading Loading Data 1 OBSERVED (YES/NO) Cadmium S 1 0.02 2.194 0.000 0.000 0.00 1 1 A Chromium S 1 0.53 54.839 0.000 0.000 0.00 1 1 N Copper AL 1 0.53 7.677 1.044 0.000 0.00 Monitor 1 1 A Nickel S 1 0.93 96.516 0.000 0.000 0.00 1 1 L Lead S 1 0.26 27.419 0.000 0.000 0.00 1 1 Y Zinc AL 1 2.51 54.839 3.133 0.000 0.00 Monitor 1 1 S Cyanide S 1 0.05 5.484 0.000 0.000 0.00 1 1 I Mercury S 1 0.00 0.013 0.013 ✓ 0.000 0.00 Limit 1 1 S Silver AL 1 0.00 0.066 0.000 0.000 0.00 1 Selenium S 1 0.05 5.484 0.000 0.000 0.00 1 1 R Arsenic S 1 0.53 54.839 0.000 0.000 0.00 1 1 E Phenols S 1 0.000 0.000 0.000 0.00 1 1 S NH3-N C 1 0.000 0.00 1 1 U T.R.Chlor.AL 1 18.645 0.00 1 I L I I I T I I S