WQ0024508_Monitoring - 03-2022_20220428

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DWR - NonDischarge Monitoring Report Submittal
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NORTH CAROLINA
E Mranmenlcl Quaffly
Monitoring Report Submittal
..............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Permit Number#* WQ0024508
Name of Facility:* Carolina Research Center WWTF
Month:* March Year:* 2022
Report Information
Type* Upload Document*
NDMR, NDAR-1, NDAR-2, NDMLR Smithers Carolina_March.pdf 2.62MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2,NDMLR,GW-59).
Confirmation Email Address:* [e-mail]
Name of Submitter:* Jessica Mize
Signature:
jrddLuz,4
Date of submittal: 4/28/2022
This will be filled in automatically
Initial Review
.............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Reviewer: Gerald,Wanda

Is the project number correct?* WQ0024508
Is the monitoring report accepted?* Yes No
Regional Office* Winston-Salem
Accepted Date: 5/10/2022

FORM:NDMR 05-16 NON-DISCHARGE MONITORING REPORT(NDMR) Page of
Permit No.: WQ0024508 I Facility Name: Carolina Research Center WWTF I County: Alamance I Month: March I Year: 2022
PPI: 001 I Flow Measuring Point: 0 Influent O Effluent 0 No flow generated I Parameter Monitoring Point: 0 Influent El Effluent 0 Groundwater Lowering 0 Surface Water
Parameter Code -* , .50050 00310 00940 ; 50060 .-;31616 .' 00610 00625 00620 00600 00400 00665 70300 00530
w w
> 111 : .
fl
c c . 2g .. ° c 0 To m�•, <cE G o -po ftig P 0oaj OF v O N _ m__. pQ: m r H ® t tL O Z F...a: c.., ; z = c .
n
24hr hrs GPD mglL mg/L. mg/L #/100 mL mg/L mg/I mglL mgtL su mg1L mg/L mg/L
1 11:26 0.25 •.536 0.96
2 536 7.15
3 494.
4 494
5 494.
6 . .494:`;
7 - ..494' -
8 10:44 0.25 494. ' 1.58
9 494 „,.
10 494 7
11 494 +
12 : .869 i-- -
13 --,869--2-r; • ,-.-:rr.
14 869
15 12:11 0.25 .869..: >2.20
16 869 ;
17 869. • 6.81
18 ,.869--u;
19 i 630-P'-s :. w.:
20 .630. ..
21 _ .630'�
22 11:55 0.25 -,_630 3.9 44.8 >2.20 2420 63.1 86.1 <0.040 86.2 15.9 398 30.3
23 •..630 6.76
,i.-E •
_
24 r 630 ,
.....,. . ,
25 ,:, :630 .
26 • ' 363 1.. ._ .
27 363 , .,: •
28 363
29 11:38 0.25 ,363---' .. >2.20
30 a 363 , .
31 •P•I..363- • ,
n
Average: ;; 587_€' 3.90 44.80 0.51 2,420.00 63.10 86.10 _i 0.00 86.20:_ 15.90 398.00 30.30:;` .
Daily Maximum: - -869--.• 3.90 `44.80 1.58 2,420.00 63.10 86.10 ! 0.04 86.20, 7.15 15.90 398.00 30.30
Daily Minimum: - -363- 3.90 44.80 0.96 2,420.00 63.10 86.10'` 0.04 86.20 . 6.76 15.90 398.00 30.30
Sampling Type: -•Estimate., Grab • Grab Grab Grab Grab Grab Grab .:.Grab: Grab Grab Grab Grab
Monthly Limit: •=-2,000'- -
Daily Limit:
Sample Frequency: Monthly." 3 X Year 3 X Year: Per Event 3 X Year 3 X Year 3 X Year 3 X Year 3X Year Per Event 3 X Year` 3 X Year 3 X Year

FORM:NDMR 05-16 NON-DISCHARGE MONITORING REPORT(NDMR) Page of
� I
Sampling Person(s) Certified Laboratories
Name: Glenn Price Name: Pace Analytical Services
Name: Name:
Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? l .ompUant 0 Non-Compliant
If the facility is non-compliant,please explain in the space below the reason(s)the facility was not in compliance. Provide in your explanation the date(s)of the non-compliance and describe the corrective
action(s)taken.Attach additional sheets if necessary.
Operator in Responsible Charge(ORC)Certification Permittee Certification
ORC: Glenn Price Permittee: Gus Zieske
Certification No.: 987931/20771 Signing Official: Ron Alcom
Grade: II Phone Number: 336-996-2841 Signing Official's Title: Manager,Avian and Wildlife Toxicology
Has the ORC changed since the previous NDMR? ❑Yes O No Phone Number. 336-376-0141 Permit Expiration: 8/31/2021
rAbAz grA z 7 z Z
Signature Date Signature Date
By this signature,I certify that this report is accurrate and complete to the best of my knowledge. I certify,under penally of law,that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that at qualified personnel property gathered and evaluated the Information
submitted.Based on my Inquiry of the person or persons who manage the system,or those persons directly responsible for
gathering the Information,the Information submitted Is,to the best of my knowledge and belief,true,accurate,and complete.I am
aware that there are significant penalties for submitting false information,Including the possibility of fans and Imprisonment for
knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
information Processing Unit
1617 Mail Service Center
Raleigh,North Carolina 27699-1617

FORM:NDAR-1 05-16 NON-DISCHARGE APPLICATION REPORT(NDAR-1) Page of
Permit No.: WQ0024508 , Facility Name: Carolina Research Center WWTF ` County: Alamance I Month: March Year: 2022
Did irrigation occurField Name: .2 Field Name: 3 Field Name: 4 Field Name: 5
Area(acres) 0 3 Area(acres): 0.3 • Area(acres) 0.5 • Area(acres): 0.3
at this facility? Cover Crop: Cover Crop: Cover Crop: Cover Crop:
❑YES ❑NO Hourly Rate(in): ;> 0.3 Hourly Rate(in): 0.3 Hourly Rate(in): 0.3 Hourly Rate(in): 0.3
Annual Rate(in): 42.9 ..; Annual Rate(in): 42.9 Annual Rate(in): 42.9 Annual Rate(in): 42.9
Weather Freeboard Field Irrigated? ❑YES p NO Field Irrigated? 0 YES p Na Field Irrigated? D YES p NO Field irrigated? 0 YES 0 NO
e m c m m
0 ` ` 0) -� e m - e , > E ?' 'C E m e 8 S. C T C E E . e d - :Y� C ..� e- c EE . e d Y` C 7 5. C
ro E,ro •- v E 7.:0 7 — E ro •- =a E � '0 7 — E r o E 7IS � — E ro v E 7 0
rJIH
ro ^
°F in ft ft gal. +min in in gal min in in gal min in In gal min in in
1
2 C 73 0 2.6
3
4
5
6
7
8
9
10 CI 45 0 2.6
11
12
13
14
15
16
17 CI 55 0 2.6
18 •
19
20
21
22
23 CI 61 0 2.6 2,000 25 0.25 0.25
24 CI 72 0 2.6 1,600 20 0.20 0.20
25
26
27
28
29
30
31
Monthly Loading: 0 / 0.00 i 0 'V 0.00 % 0 !/ 0.00 '� 3,600 % 0.44
12 Month Floating Total(in): 2.12 / 2.12 2.33 / 2.37���y��.

FORM:NDAR-1 05-16 NON-DISCHARGE APPLICATION REPORT(NDAR-1) Page of
Did the application rates exceed the limits in Attachment B of your permit? Rranpliant ❑Non{ompfiant
Were adequate measures taken to prevent effluent ponding in or runoff from the sites? git‘mpllant ❑Non-Compliant
Was a suitable vegetative cover maintained on all sites as specified in your permit? iid'Compiiant ❑Non-compliant
Were all setbacks listed in your permit maintained for every application to each permitted site? 1941pliant ❑Non-Compliant
Were all freeboards maintained in accordance with the specified freeboard heights in your permit? uu npliant 0 Non-Compliant
if the facility is non-compliant,please explain in the space below the reason(s)the facility was not in compliance. Provide in your explanation the date(s)of the non-compliance and describe the corrective
action(s)taken.Attach additional sheets If necessary.
Operator In Responsible Charge(ORC)Certification Permittee Certification
ORC: Glenn Price Permittee: Gus Zieske
Certification No.: 987931/20771 Signing Official: Ron Alcorn
Grade: II Phone Number: 336-996-2741 Signing Officials Title: Manager,Avian and Wildlife Toxicology
Has the ORC changed since the previous NDAR-1? ❑res ❑No Phone Number. 336-376-0141 Permit Exp.: 8/31/21
110 2— sX2 Zt
Signature Date Signature Date
By this signature,I certify that this report is ac currate and complete to the best of my knowledge. I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted.Based on my
inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the Information,the
information submitted is,to the best of my knowledge and bermf,true,accurate,and complete.I am aware that there are significant
penalties for submitting false information,including the possibility of fines and Imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh,North Carolina 27699-1617

FORM:NDAR-1 05-16 NON-DISCHARGE APPLICATION REPORT(NDAR-1) Page of
Permit No.: WQ0024508 J Facility Name: Carolina Research Center WWTF J County: Alamance I Month: March Year: 2022
Field,Name: 6 Field Name: 7 Field Name Field Name:
Did irrigation occur
Area(acres): . 0.9 Area(acres): 0.3 Area(acres): Area(acres):
at this facility? Cover Crop: Cover Crop: Cover Crop: Cover Crop:
0 YES CI NO Hourly Rate(in): 0.3 Hourly Rate(in): 0.3 Hourly Rate(in): Hourly Rate(in):
Annual Rate(in): 42.9 Annual Rate(in): 42.9 Annual Rate(in): Annual Rate(in):
Weather Freeboard Field Irrigated? O YES ❑NO Field Irrigated? 0 YES D NO Field Irrigated? ❑YES 0 No Field Irrigated? 0 YES 0 NO
m c m m
-0 ° 0 a .c 0 /3 0 E CO 0 'a a a► E c� 0 c E cs m a 'c CO E 0)
9, i
ii
H
E 0 . .0 ,N AC 3 ` C n
o o0. E � 'tai •E' c1 E o Cl, I- ,O 0 g Z <0 H ',_ G 0 rp—1 2 = 0 0'0. i= •C A 0 •i 3: 0 O 0. i= •C O a g = 0
°F in ft ft gal min in in gal min in in gal min in in gal min in in
1
2 C 73 0 2.6 2,000 25 0.08 0.08
3
4
5
6 ,
7
10 Cl 45 0 2.6 3,600-" 45 ` 0.15 0.15;.
11
12
13
14
15
16
17 Cl 55 0 2.6 4,800 .• 60 0.20 :: 0.20.
18
19 r,:
20
v 21 " '`
•
22
23 Cl 61 0 2.6
24 Cl 72 0 2.6
25 .
26
-.f ,13_.
26
29
30
31
Monthly Loading: . .10,400 % 0.43 0 V 0.00 % 0 % 0.00 0 ! 0.00
12 Month Floating Total(in): 2.04 J 1.97 i / 4

FORM:NDAR-1 05-16 NON-DISCHARGE APPLICATION REPORT(NDAR-1) Page of
Did the application rates exceed the limits in Attachment B of your permit? DY6tplitint 0 Noncompliant
Were adequate measures taken to prevent effluent ponding in or runoff from the sites? R'Cotrtptiant ❑Non.compliant
Was a suitable vegetative cover maintained on all sites as specified in your permit? ,pliant 0 Non-Compliant
Were all setbacks listed in your permit maintained for every application to each permitted site? taipliant 0 Non-Compliant
Were all freeboards maintained in accordance with the specified freeboard heights in your permit? Q4pliant 0 Non-Compliant
If the facility is non-compliant,please explain in the space below the reason(s)the facility was not in compliance. Provide in your explanation the date(s)of the non-compliance and describe the corrective
action(s)taken.Attach additional sheets if necessary.
Operator in Responsible Charge(ORC)Certification Permittee Certification
ORC: Glenn Price Permittee: Gus Zieske
Certification No.: 987931/20771 Signing Official: Ron Alcom
Grade: II Phone Number: 336-996-2741 Signing Officials Title: Manager,Avian and Wildlife Toxicology
Has the ORC changed since the previous NDAR-1? ❑Yes ❑No Phone Number: 336-376-0141 Permit Exp.: 8/31/21
�ibfzZ if—
Signature Date Signature Date
By this signature.I certify that this report Is accuaale and complete to the best of my knowledge. I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that all qualified personnel property gathered and evaluated the Information submitted.Based on my
Nulty of the person or persons who manage the system,or those persons dsecUy responsible for gathering the information,the
information submttted Is,to the best of my knowledge and belief,true,accurate,and complete.I am aware that there are significant
penalties for submitting false Information,Including the possibility of fines and imprisonment for knowing violations.
Mall Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh,North Carolina 27699-1617

FORM:NDMLR 05-16 NON-DISCHARGE MASS LOADING REPORT(NDMLR) Page of
Permit No.: WQ0024508 Facility Name: Carolina Research Center WWTF County: Alamance Month: March Year: 2022
Field Name: 2 'Field Name: 3 Field Name: 4 Field Name: 5 Field Name: 6
Area(acres): 0.3 Area(acres): 0.3 _ Area(acres): 0.5 Area(acres): 0.3 Area(acres): 0.9
Cover Crop: ,Cover Crop, '"°' ' Cover Crop: Cover Crop: Cover Crop:
Load Type: PAN Load Type: PAN Load Type: PAN Load Type: PAN Load Type: PAN
Field Loaded? 0 YES 0 NO Field Loaded? 0 YES D No Field Loaded? 0 YES D NO Field Loaded? 0 YES 0 NO' Field Loaded? D YES 0 Na
c e e e e
Z 2 z d G Z m z o z g Z o z g z o z m
15
m S 0., "A a ,o ' CO E'm , 0. i°.. a .o eo- Ed eL a -o " o co Em o...m. a. .. CI ` E .
a1,: a - 1a
m E . is E'r 03 E E . o t o: E 2 w -a o
03 2 Z. �C Z o Th.,,,-1 ='o. ' orV �, o .. ...7 �.. 2 e. W C t o pJ OIo. toC �` o ;5J 2 o. An , _1
a 0 a. `m c c -.I E - o 0 E. v e � Ez o a ;a u c _, Ea o a. E 0 � ..r Ea Z. a i9 u eJ Ed
o 0 t) o- a o 'g CUa > Q Q c ° Un. > 4 c cia > a a c Uo.
S0 t) U C1 U
Month gal mg/L lbs/ac Ibslac gal mg/L lbs/ac lbs/ac gal mg/L Ibslac lbs/ac gal mg/L lbs/ac lbs/ac gal mg/L Ibs/ac Ibs/ac
April 0 64.1 0.0 0.0 0 64.1 ;0.0 0.0 0 64.1 0.0 0.0 2,000 64.1 3.6 3.6 6,800 64.1 4.0 4.0
May 5,600 64.1 10.0 10.0 0 I:. 64.1 . r.0.0 0.0 ;" 7,200 64.1 7.7 7.7 2,000 .64.1 3.6 7.1 ;, 0 64.1 0.0 4.0
June 0 64.1 0.0 10.0 6,000 " 64.1 10.7 10.7 3,600 64.1 3.8 11.5 0 64.1 0.0 7.1 4,000 64.1 2.4 6.4
July 0 66.8 0.0 10.0 0 66.8 0.0 10.7 0 66.8 0.0 11.5 2,000 " 66.8 3.7 10.8 10,400 66.8 6.4 12.9
August 4,000 66.8 7.4 17.4 0 66.8 '0.0; 10.7 10,000 66.8 11.1 22.7 4,000 66.8 7.4 18.3_ 0 66.8 0.0 12.9
September 2,000 66.8 3.7 21.1 5,200. 66.8 9.7 ' 20.3 0 66.8 0.0 22.7 0 66.8 0.0 18.3 3,600 66.8 2.2 15.1
October 0 66.8 0.0 21.1 0 .; 66.8 , 0.0 20.3 0 66.8 0.0 22.7 3,600 66.8 6.7 25,0 10,800 66.8 6.7 21.8
November 0 65.1 0.0 21.1 0 65.1 0.0'. 20.3 6,000 65.1 6.5 29.2 2,000 •65.1 ' 3.6 28.6 0 65.1 0.0 21.8
December 0 65.1 0.0 21.1 1,.. ..0" r,65.1 '-0 0,rr .;20.3_ 4,800 65.1 5.2 34.4 0`' ..:. =65.1 0.0 28.6x 0 65.1 0.0 21.8
January 5,600 65.1 10.1 31.3 -4,000 ' 65.1'... 7 2' `27.6";' 0 65.1 0.0 34.4 ' .0 65.1 0.0 '28.6 0 65.1 0.0 21.8
February 0 65.1 0.0 31.3 2,000 ! '65.1 ;-3 6;. -' 81.2;: 0 65.1 0.0 34.4 0 65.1 , 0.0 ' 28.6 3,600 65.1 2.2 23.9
March 0 38.5 0.0 31.3 s:0 38.5 " 0.0 ;. 31.2! 0 38.5 0.0 34.4 3,600 " 68.5 _.,6.9 35.4 10,400 38.5 3.7 27.6
12 Month Floating PAN Load 31.3 31.2 34.4 35.4 27.6
Ibslac/yr):
Annual PAN Load Limit 159 159 159 159 159
(Ibslac/yr): A

FORM:NDMLR 05-16 NON-DISCHARGE MASS LOADING REPORT(NDMLR) Page of
Did the mass loading rates exceed the limits in Attachment B of your permit? giempliant ❑Non-Compliant:
If the facility is non-compliant,please explain in the space below the reason(s)the facility was not in compliance. Provide in your explanation the date(s)of the non-compliance and describe the corrective
action(s)taken.Attach additional sheets if necessary.
Operator In Responsible Charge(ORC)Certification Permittee Certification
ORC: Glenn Price Permittee: Gus Zieske
Certification Number: 987931/20771 Signing Official: Ron Alcom
Grade: II Phone Number: 336-996-2741 Signing Official's Title: Manager,Avian and Wildlife Toxicology
Has the ORC changed since the previous NDMLR? ❑Yes ID No Phone No.: 336-376-0141 Permit Exp.: 8/31/21
44z_ 111 4-27-22.
Signature Date Signature Date
By this signature,I certify that this report is accurrate and complete to the best of my knowledge. I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that ail qualified personnel properly gathered and evaluated the
information submitted.Based on my Inquiry of the person or persons who manage the system,or those persons directly
responsible for gathering the information,the Information submitted is,to the best of my knowledge and belief,We,
accurate,and complete.I am aware that there are significant penalties for submitting false information,Including the
possibility of fines and imprisonment for knowing violations.
Mall Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mall Service Center
Raleigh,North Carolina 27699-1617

FORM:NDMLR 05-16 NON-DISCHARGE MASS LOADING REPORT(NDMLR) Page of
Permit No.: WQ0024508 Facility Name: Carolina Research Center WWTF County: Alamance Month: March Year: 2022
Field Name: 7 Field Name: Field Name: Field Name: , Field Name:
'.-
Area(acres): 0.3 - Area(acres): Area(acres): Area(acres): Area(acres):
Cover Crop: Cover Crop: Cover Crop: Cover Crop: Cover Crop:
Load Type: PAN Load Type: Load Type:
Load Type: - Load Type:
Field Loaded? DYES i NO Field Loaded? DYES 0 NO Field Loaded? 0 YES 0 NO Field Loaded? DYES 0 NO Field Loaded? 0 YES 0 NO
z g z c 12 c -a c -0
a = a 0 o 1 ) 0 ,isi 0 o co 0
0 no a. 4, 0. .?'. 0 0 lo o . .,,j .2 0 "C &1 .1 .....7!: CD 13 o '..g ,j 7t: CD 13 0 7:',. 3 .2
.9.' E .9'. 0 ,..1- >,3:1 isi 0 E .2 13 col E .2 to 1-, . ii, E .2 E ja: 0 1 E .2 ri, 1
a 1 I I) 5 m l j -ea mg co 20- 2c 2% oo 2o. oc Z-ft oo ...... 1. . = z .
4.) i 4 s: .2. § t g -1 i> .2. <1- .1
> 0 0 . a, . 0 . 0 0 0 o 0 0 o 0 0
4 o 2 c.) 2 u 2 u 2 o
Month gal mglL lbs/ac lbs/ac : gal mg/L, lbs/ac lbs/ac gal mg!L lbs/ac lbs/ac gal mg/L lbs/ac lbs/ac gal mg(L lbs/ac lbs/ac
April 0 64.1 0.0 0.0 -- -- - ,
May 0 64.1 0.0 0.0
June 6,000 64.1 10.7 10.7 ---- ,
July 0 68.8 0.0 10.7 -
"
August 0 66.8 0.0 10.7
September 4,000 66.8 7.4 18.1
October 0 66.8 0.0 18.1 - -
November 0 65.1 0.0 18.1
December 0 65.1 0.0 18.1
January 0 65.1 0.0 18.1
February 0 65.1 0.0 18.1
March 0 38.5 0.0 18.1
12 Month Floating PAN Load
18.1 r 0.0 , 0.0 vr
o.. 0.0
lbs/ac/yr):
Annual PAN Load Limit
159
• •
..
" . , - •

FORM:NDMLR 05-16 NON-DISCHARGE MASS LOADING REPORT(NDMLR) Page of
Did the mass loading rates exceed the limits in Attachment B of your permit? giempliant ❑Non-Compliant
If the facility Is non-compliant,please explain in the space below the reason(s)the facility was not in compliance. Provide in your explanation the date(s)of the non-compliance and describe the corrective
action(s)taken.Attach additional sheets if necessary.
Operator in Responsible Charge(ORC)Certification Permittee Certification
ORC: Glenn Price Permittee: Gus Zieske
Certification Number. 987931/20771 Signing Official: Ron Alcom
Grade: II Phone Number: 336-996-2741 Signing Official's Title: Manager,Avian and Wildlife Toxicology
Has the ORC changed since the previous NDMLR? ❑Yes No Phone No.: 336-376-0141 Permit Exp.: 8/31/21
%W.0�� Y 27-2Z
Signature Date Signature Date
By this signature,I certify that this report is accurrate and complete to the best of my knowledge. I certify,under penally of law,that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that at qualified personnel properly gathered and evaluated the
Information submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly
responsible for gathering the information,the information submitted Is,to the best of my knowledge and belief,true,
accurate,and complete.I am aware that there are significant penalties for submitting false information,including the
possibility of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mall Service Center
Raleigh,North Carolina 27699-1617

Pace Analytical Services,LLC
ac('P f7�] ,/r{r/' 9800 Kincey Ave. Suite 100
Aral `i aI Huntersville,NC 28078
www.pacelabs.cam
[phone]
April 05, 2022
Gus Zieske
Smithers Viscient
2900 Quakenbush Rd.
Snow Camp, NC 27349
RE: Project: Smithers-Carolina Research
Pace Project No: 92594692
Dear Gus Zieske:
Enclosed are the analytical results for sample(s)received by the laboratory on March 22,2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
• Pace Analytical Services-Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Stephanie Knott
[e-mail]
704-977-0981
Project Manager
Enclosures
cc: Ronald Alcorn
COW'
REPORT OF LABORATORY ANALYSIS
L NJ r This report shall not be reproduced,except in full.
� �.� without the written consent of Pace Analytical Services,LLC. Page 1 of 23
BORA'°

Pace Analytical Services,LLC
o 9800 KIncey Ave.aceAnalytical Huntersv lie,NC'28078
www.pacelabs.caa [phone]
I
CERTIFICATIONS
Project: Smithers-Carolina Research
Pace Project No.: 92594692
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
North Carolina Wastewater Certification#:40
Pace Analytical Services Eden
205 East Meadow Road Suite A,Eden,NC 27288 North Carolina Wastewater Certification#:633
North Carolina Drinking Water Certification#:37738 VirginiaNELAP Certification#:460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 23

Pace Analytical Services,LLC
aceAf lalytical a 9800 Kincey Ave. Suite 100
liuntersville,NC 28078
rI www.pacolaba.com [phone]
SAMPLE ANALYTE COUNT
Project: Smithers-Carolina Research
Pace Project No.: 92594692
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92594692001 MW-2 SM 2540C-2015 MWF 1 PASI-E
EPA 350.1 Rev 2.01993 AMI 1 PASI-E
EPA 353.2 Rev 2.0 1993 AMI 1 PASI-E
SM 9222D-2015 LRB 1 PASI-E
EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A
EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92594692002 MW-3 SM 2540C-2015 MWF 1 PASI-E
EPA 350.1 Rev 2.0 1993 AMI 1 PASI-E
EPA 353.2 Rev 2.0 1993 AMI 1 PASI-E
SM 9222D-2015 LRB 1 PASI-E
EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A
EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A
SM 5310B-2014 MDW 1 PASI-A
92594692003 Effluent SM 2540C-2015 MWF 1 PASI-E
SM 2540D-2015 AED 1 PASI-E
EPA 350.1 Rev 2.0 1993 AMI 1 PASI-E
EPA 353.2 Rev 2.01993 AMI 1 PASI-E
SM 5210B-2016 MWF 1 PASI-E
Colilert-18 LRB 1 PASI-E
None EWS 1 PASI-A
TKN+NO3+NO2 Calculation MAB2 1 PASI-A
EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
EPA 365.1 Rev 2.0 1993 KDF1 1 PASI-A
PASI-A=Pace Analytical Services-Asheville
PASI-E=Pace Analytical Services-Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 23

Pace Analytical Services,LLC
m 9800 Kincey Ave.aceAnalytfical Huntersvllle.C'28078
www.pacelabs.ecm [phone]
I
ANALYTICAL RESULTS
Project Smithers-Carolina Research
Pace Project No.: 92594692
Sample: MW-2 Lab ID: 92594692001 Collected: 03/22/22 11:00 Received: 03/22/22 13:45 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Eden
Total Dissolved Solids 54.0 mg/L 25.0 1 03/28/22 09:12
350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia ND mg1L 0.10 1 03/28/22 14:06 7664-41-7
353.2 NO21NO3 unpres EDN Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Nitrate 0.93 mg/L 0.040 1 03/22/22 14:46 14797-55-8
MBIO 9222D Fecal Coliform EDN Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Eden
Fecal Coliforms 480 CFU/100 mL 1.0 1 03/22/22 14:30 03/23/22 13:49
300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Rev 2.1 1993
Pace Analytical Services-Asheville
Chloride 3.1 mg/L 1.0 1 03/24/22 23:21 16887-00-6 M1
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 1.3 mg/L 0.050 1 03/31/22 18:49 04/01/22 09:53 7723-14-0
5310B TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon ND mg/L 1.0 1 03/24/22 20:07 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services.LLC. Page 4 of 23

Pace Analytical Services,LLC
aceAnalytical 9800 KirtceyAve. Sidle 700
Huntersville,NC 28078
www parolabs.cain [phone]
ANALYTICAL RESULTS
Project Smithers-Carolina Research
Pace Project No.: 92594692
Sample: MW-3 Lab ID: 92594692002 Collected: 03/22/22 10:30 Received: 03/22/22 13:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Eden
Total Dissolved Solids 63.0 mg/L 25.0 1 03/28/22 09:12
350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia ND mg/L 0.10 1 03/28/22 14:07 7664-41-7
353.2 NO2M03 unpres EDN Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Nitrate 0.056 mg/L 0.040 1 03/22/22 14:49 14797-55-8
MBIO 9222D Fecal Coliform EDN Analytical Method:SM 9222D-2015 Preparation Method:SM 9222D-2015
Pace Analytical Services-Eden
Fecal Coliforms ND CFU/100 mL 1.0 1 03/22/22 14:30 03/23/22 13:49
300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Rev 2.1 1993
Pace Analytical Services-Asheville
Chloride 4.6 mg/L 1.0 1 03/25/22 00:07 16887-00-6
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 0.13 mg/L 0.050 1 03/31/22 18:49 04/01/22 09:54 7723-14-0
5310E TOC Analytical Method:SM 5310B-2014
Pace Analytical Services-Asheville
Total Organic Carbon ND mg/L 1.0 1 03/24/22 20:56 7440 14 0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 23

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacolabs.com
[phone]
1
ANALYTICAL RESULTS
Project: Smithers-Carolina Research
Pace Project No.: 92594692
Sample: Effluent Lab ID: 92594692003 Collected: 03/22/22 11:20 Received: 03/22/22 13:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Eden
Total Dissolved Solids 398 mg/L 25.0 1 03/28/22 09:13
2540D Total Suspended Solids Analytical Method:SM 2540D-2015
Pace Analytical Services-Eden
Total Suspended Solids 30.3 mg/L 7.6 1 03/23/22 12:33
350.1 Ammonia EDN Analytical Method:EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Ammonia 63.1 mg/L 1.0 10 03/28/22 15:19 7664-41-7
353.2 N021NO3 unpres EDN Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Eden
Nitrogen,Nitrate ND mg/L 0.040 1 03/22/22 14:50 14797-55-8
5210B BOD,5 day EDN Analytical Method:SM 5210B-2016 Preparation Method:SM 5210B-2016
Pace Analytical Services-Eden
BOD,5 day 3.9 mg/L 2.0 1 03/23/22 10:47 03/28/22 10:53
Colilert-18 Fecal Coliform EDN Analytical Method:Colilert-18 Preparation Method:Colilert-18
Pace Analytical Services-Eden
Fecal Colifonns 2420 MPN/100mL 1.0 1 03/22/22 14:26 03/23/22 09:33 El
Plant Available Nitrogen Analytical Method:None
Pace Analytical Services-Asheville
Plant Available Nitrogen 38.5 mg/L 1 04/05/22 16:48 N2
Total Nitrogen Calculation Analytical Method:TKN+NO3+NO2 Calculation
Pace Analytical Services-Asheville
Total Nitrogen 86.2 mg/L 0.040 1 04/04/22 12:07
300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Rev 2.1 1993
Pace Analytical Services-Asheville
Chloride 44.8 mg/L 1.0 1 03/25/22 00:23 16887-00-6
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Rev 2.0 1993 Preparation Method:EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Kjeldahl,Total 86.1 mg/L 5.0 10 03/28/22 18:07 03/29/22 05:54 7727-37-9
353.2 Nitrogen,N021NO3 pres. Analytical Method:EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,NO2 plus NO3 0.045 mg/L 0.040 1 03/28/22 12:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full.
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 23

Pace Analytical Services,LLC
aceAnalytical m 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
wrw.pacelabs.com [phone]
I
ANALYTICAL RESULTS
Project: Smithers-Carolina Research
Pace Project No.: 92594692
Sample: Effluent Lab ID: 92594692003 Collected: 03/22/22 11:20 Received: 03/22/22 13:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 15.9 mg/L 0.50 10 03/31/22 18:49 04/01/22 09:54 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 23

Pace Analytical Services,LLC
aceAnalytical co 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
I
QUALITY CONTROL DATA
Project: Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 687584 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92594692001,92594692002,92594692003
METHOD BLANK: 3594068 Matrix: Water
Associated Lab Samples: 92594692001,92594692002,92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 03/28/22 09:12
LABORATORY CONTROL SAMPLE: 3594069
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 236 94 90-110
SAMPLE DUPLICATE: 3594070
92594918001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 1010 914 10
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 23

Pace Analytical Services,LLC
_ aceAnalytical® 9800 Kincey Ave. Suite 100
Hunlersville,NC 28078
wwrr.pacetabs.com
[phone]
1
QUALITY CONTROL DATA
Project Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 686683 Analysis Method: SM 2540D-2015
QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92594692003
METHOD BLANK: 3589798 Matrix: Water
Associated Lab Samples: 92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 03/23/22 12:30
LABORATORY CONTROL SAMPLE: 3589799
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Suspended Solids mg/L 250 230 92 90-110
SAMPLE DUPLICATE: 3589800
92594705002 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids rng/L 45.2 52.5 15
SAMPLE DUPLICATE: 3589801
92594736001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 66.9 65.7 2
Results presented on thls page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 23

Pace Analytical Services,LLC
a
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 687553 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia,EDN
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92594692001,92594692002,92594692003
METHOD BLANK: 3593946 Matrix: Water
Associated Lab Samples: 92594692001,92594692002,92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 03/28/22 13:53
LABORATORY CONTROL SAMPLE: 3593947
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.0 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3593948 3593949
MS MSD
92594591001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.1 5.1 102 102 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3593950 3593951
MS MSD
92594668001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.0 5.0 101 101 90-110 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 23

Pace Analytical Services,LLC
aceAnalytical m 9800 Kincey Ave. Suite 100
Huntersville,NC 28D78
www.pacelabs.com
[phone]
I
QUALITY CONTROL DATA
Project: Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 686417 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite,Unpres.EDN
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92594692001,92594692002,92594692003
METHOD BLANK: 3588649 Matrix: Water
Associated Lab Samples: 92594692001,92594692002,92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Nitrate mg/L ND 0.040 03/22/22 13:44
LABORATORY CONTROL SAMPLE: 3588650
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Nitrate mg/L 1.5 1.5 103 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3588651 3588652
MS MSD
92594434001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Nitrate mg/L 0.27 1.5 1.5 1.8 1.8 102 102 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3588899 3588900
MS MSD
92594692001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result °Ae Rec %Rec Limits RPD Qual
Nitrogen,Nitrate mg/L 0.93 1.5 1.5 2.5 2.5 103 105 90-110 1
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full.
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services.LLC. Page 11 of 23

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.ptcMobs.com
[phone]
I
QUALITY CONTROL DATA
Project: Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 686613 Analysis Method: SM 5210B-2016
QC Batch Method: SM 5210B-2016 Analysis Description: 5210E BOO,5 day Final EDN
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92594692003
METHOD BLANK: 3589542 Matrix: Water
Associated Lab Samples: 92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
BOD,5 day mg/L ND 2.0 03/28/22 10:03
LABORATORY CONTROL SAMPLE: 3589543
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
BOD,5 day mg/L 198 183 93 84.6-115
SAMPLE DUPLICATE: 3589545
92594705002 Dup
Parameter Units Result Result RPD Qualifiers
BOD,5 day mg/L 124 126 1
Results presented on this page are In the units Indicated by the'Units"column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 23

Pace Analytical Services,LLC
aceAnalytical ea 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabulafl
[phone]
I
QUALITY CONTROL DATA
Project Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 686472 Analysis Method: SM 9222D-2015
QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF)-EDN
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92594692001,92594692002
METHOD BLANK: 3588926 Matrix: Water
Associated Lab Samples: 92594692001,92594692002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 03/23/22 13:49
METHOD BLANK: 3588928 Matrix: Water
Associated Lab Samples: 92594692001,92594692002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 03/23/22 13:49
METHOD BLANK: 3588929 Matrix: Water
Associated Lab Samples: 92594692001,92594692002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Cotiforms CFU/100 mL ND 1.0 03/23/22 13:49
SAMPLE DUPLICATE: 3588927
92594707003 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Cotiforms CFU/100 mL 236 216 9
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 23

Pace Analytical Services,LLC
aceAnalytical m 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelaba.coia [phone]
QUALITY CONTROL DATA
Project: Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 686467 Analysis Method: Colilert-18
QC Batch Method: Colilert-18 Analysis Description: Colilert-18 Fecal Coliform EDN
Laboratory: Pace Analytical Services-Eden
Associated Lab Samples: 92594692003
SAMPLE DUPLICATE: 3588919
92594705001 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms MPN/100mL ND ND
Results presented on this page are In the units indicated by the'Units"column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 23

Pace Analytical Services,LLC
aceAnalytical m 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.com
[phone]
I
QUALITY CONTROL DATA
Project: Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 687138 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92594692001,92594692002,92594692003
METHOD BLANK: 3592080 Matrix: Water
Associated Lab Samples: 92594692001,92594692002,92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 03/24/22 19:14
LABORATORY CONTROL SAMPLE: 3592081
Spike LCS LCS °A°Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Chloride mg/L 50 49.5 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3592084 3592085
MS MSD
92594692001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chloride mglL 3.1 50 50 59.7 59.7 113 113 90-110 0 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3592095 3592096
MS MSD
92594680003 Spike Spike MS MSD MS MSD °A)Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Chloride mg/L 28.5 50 50 85.2 84.4 113 112 90-110 1 M1
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 23

Pace Analytical Services,LLC
aceAnalytical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacsIaEuom [phone]
I
QUALITY CONTROL DATA
Project Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 687669 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92594692003
METHOD BLANK: 3594512 Matrix: Water
Associated Lab Samples: 92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total mg/L ND 0.50 03/29/22 05:07
LABORATORY CONTROL SAMPLE: 3594513
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 9.9 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3594514 3594515
MS MSD
92595031001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mglL 27.6 10 10 39.4 41.3 117 136 90-110 5 M1
Results presented on this page are In the units Indicated by the"Unite column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 23

Pace Analytical Services,LLC
aceAnalytical m 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacsiabs.com
[phone]
QUALITY CONTROL DATA
Project Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 687574 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.01993 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92594692003
METHOD BLANK: 3594022 Matrix: Water
Associated Lab Samples: 92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.040 03/28/22 12:29
LABORATORY CONTROL SAMPLE: 3594023
Spike LCS LCS 9'o Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.4 97 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3594024 3594025
MS MSD
92595442006 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 1.1 2.5 2.5 3.4 3.4 91 92 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3594026 3594027
MS MSD
92595442007 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 2.1 2.5 2.5 4.4 4.4 92 92 90-110 0
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 23

Pace Analytical Services,LLC
aceAnalyical® 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.cem [phone]
I
QUALITY CONTROL DATA
Project: Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 688560 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92594692001,92594692002,92594692003
METHOD BLANK: 3598331 Matrix: Water
Associated Lab Samples: 92594692001,92594692002,92594692003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 04/01/22 09:42
LABORATORY CONTROL SAMPLE: 3598332
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3598333 3598334
MS MSD
92595889001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 0.22 2.5 2.5 2.9 2.9 108 107 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3598335 3598336
MS MSD
92595889004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 0.31 2.5 2.5 3.0 3.0 107 106 90-110 1
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 23

Pace Analytical Services,LLC
aceAnalytical
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacelabs.cc m [phone]
I
QUALITY CONTROL DATA
Project Smithers-Carolina Research
Pace Project No.: 92594692
QC Batch: 687057 Analysis Method: SM 5310B-2014
QC Batch Method: SM 5310B-2014 Analysis Description: 5310B TOC
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92594692001,92594692002
METHOD BLANK: 3591518 Matrix: Water
Associated Lab Samples: 92594692001,92594692002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 03/24/22 15:25
LABORATORY CONTROL SAMPLE: 3591519
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Organic Carbon mglL 25 23.8 95 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3591520 3591521
MS MSD
92595110001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Total Organic Carbon mg/L 11.7 25 25 34.9 35.1 93 94 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3591522 3591523
MS MSD
92594692001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Total Organic Carbon mglL ND 25 25 23.9 24.1 94 95 90-110 1
Results presented on this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 23

Pace Analytical Services,LLC
aceAnalytical a 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.pacolabs.com
[phone]
I
QUALIFIERS
Project: Smithers-Carolina Research
Pace Project No.: 92594692
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation LimiL
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
El Reported value should be considered a minimum estimate since it is the maximum reportable number for this method
based on the sample volume used.The true value is likely greater than the value reported.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply.A
complete list of accreditations/certifications is available upon request.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 23

Pace Analytical Services,LLC
aceAnalytical e 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
www.patolabs.com
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project Smithers-Carolina Research
Pace Project No.: 92594692
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92594692001 MW-2 SM 2540C-2015 687584
92594692002 MW-3 SM 2540C-2015 687584
92594692003 Effluent SM 2540C-2015 687584
92594692003 Effluent SM 2540D-2015 686683
92594692001 MW-2 EPA 350.1 Rev 2.0 1993 687553
92594692002 MW-3 EPA 350.1 Rev 2.0 1993 687553
92594692003 Effluent EPA 350.1 Rev 2.0 1993 687553
92594692001 MW-2 EPA 353.2 Rev 2.0 1993 686417
92594692002 MW-3 EPA 353.2 Rev 2.0 1993 686417
92594692003 Effluent EPA 353.2 Rev 2.0 1993 686417
92594692003 Effluent SM 5210B-2016 686613 SM 5210B-2016 686714
92594692001 MW-2 SM 9222D-2015 686472 SM 9222D-2015 686473
92594692002 MW-3 SM 9222D-2015 686472 SM 9222D-2015 686473
92594692003 Effluent Cotilert-18 686467 Colilert-18 686470
92594692003 Effluent None 689567
92594692003 Effluent TKN+NO3+NO2 689202
Calculation
92594692001 MW-2 EPA 300.0 Rev 2.1 1993 687138
92594692002 MW-3 EPA 300.0 Rev 2.1 1993 687138
92594692003 Effluent EPA 300.0 Rev 2.1 1993 687138
92594692003 Effluent EPA 351.2 Rev 2.0 1993 687669 EPA 351.2 Rev 2.0 1993 687803
92594692003 Effluent EPA 353.2 Rev 2.0 1993 687574
92594692001 MW-2 EPA 365.1 Rev 2.0 1993 688560 EPA 365.1 Rev 2.0 1993 688730
92594692002 MW-3 EPA 365.1 Rev 2.0 1993 688560 EPA 365.1 Rev 2.0 1993 688730
92594692003 Effluent EPA 365.1 Rev 2.0 1993 688560 EPA 365.1 Rev 2.0 1993 688730
92594692001 MW-2 SM 5310B-2014 687057
92594692002 MW-3 SM 5310E-2014 687057
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/05/2022 05:06 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 23

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