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Home My WebLink AboutNCG030314_2022 DMR_20220302 (3)aceAnalytical www.paeelabs.enm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 February 22, 2022 Kelly McIntosh Specail Metals 1401 Burris Road Newton, NC 28658 RE: Project: Storm Water Pace Project No.: 92586920 Dear Kelly McIntosh: Enclosed are the analytical results for sample(s) received by the laboratory on February 08, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Sara Poulson sara.poulson@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Larry Stephens, Special Metals REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 16 aceAnalytical www.pacelabs.cem Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Storm Water Pace Project No.: 92586920 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water#: LA029 Virginia/VELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 16 aceAnalytical www.pacelabs.cem Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Pace Project No.: Storm Water 92586920 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92586920001 WEST 001 EPA 1664B ICO 1 PASI-C EPA 200.7 Rev 4.4 1994 CBV 2 PASI-A EPA 200.8 Rev 5.4 JOR 1 PASI-A SM 254OD-2015 ZMC 1 PASI-A SM 4500-H+B-2011 YEG 1 PASI-A SM 5220D-2011 JP1 1 PASI-A 92586920002 SOUTH 002 EPA 1664B ICO 1 PASI-C EPA 200.7 Rev 4.4 1994 CBV 2 PASI-A EPA 200.8 Rev 5.4 JOR 1 PASI-A SM 2540D-2015 ZMC 1 PASI-A SM 4500-H+B-2011 YEG 1 PASI-A SM 5220D-2011 JP1 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 16 aceAnalytical www.pacelabs.cem Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Storm Water Pace Project No.: 92586920 Sample: WEST 001 Lab ID: 92586920001 Collected: 02/03/22 17:00 Received: 02/08/22 09:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 02/10/22 09:28 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper ND mg/L 0.0050 1 02/17/22 02:31 02/21/22 22:47 7440-50-8 Lead ND mg/L 0.0050 1 02/17/22 02:31 02/21/22 22:47 7439-92-1 200.8 MET ICPMS Analytical Method: EPA200.8 Rev 5.4 Preparation Method: EPA200.8 Rev 5.4 Pace Analytical Services - Asheville Zinc 0.17 mg/L 0.010 1 02/16/22 11:37 02/17/22 05:50 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Asheville Total Suspended Solids 3.7 mg/L 2.5 1 02/09/22 16:22 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B-2011 Pace Analytical Services - Asheville pH at 25 Degrees C 5.4 Std. Units 0.10 1 02/11/22 12:58 H3 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services - Asheville Chemical Oxygen Demand ND mg/L 25.0 1 02/17/22 02:42 02/17/22 06:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 16 aceAnalytical www.pacelabs.cem Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: Storm Water Pace Project No.: 92586920 Sample: SOUTH 002 Lab ID: 92586920002 Collected: 02/03/22 18:05 Received: 02/08/22 09:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.2 1 02/10/22 09:28 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper ND mg/L 0.0050 1 02/17/22 02:31 02/21/22 22:50 7440-50-8 Lead ND mg/L 0.0050 1 02/17/22 02:31 02/21/22 22:50 7439-92-1 200.8 MET ICPMS Analytical Method: EPA200.8 Rev 5.4 Preparation Method: EPA200.8 Rev 5.4 Pace Analytical Services - Asheville Zinc 0.027 mg/L 0.010 1 02/16/22 11:37 02/17/22 05:54 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 254OD-2015 Pace Analytical Services - Asheville Total Suspended Solids 18.1 mg/L 2.5 1 02/09/22 16:22 4500H+ pH, Electrometric Analytical Method: SM 4500-H+B-2011 Pace Analytical Services - Asheville pH at 25 Degrees C 5.8 Std. Units 0.10 1 02/11/22 13:02 H3 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services - Asheville Chemical Oxygen Demand ND mg/L 25.0 1 02/17/22 02:42 02/17/22 06:04 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 16 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Storm Water Pace Project No.: 92586920 QC Batch: 677165 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92586920001, 92586920002 METHOD BLANK: 3544163 Matrix: Water Associated Lab Samples: 92586920001, 92586920002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 5.0 02/10/22 09:28 LABORATORY CONTROL SAMPLE: 3544164 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 20 15.1 76 64-132 MATRIX SPIKE SAMPLE: 3544165 92586763001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L ND 19.6 16.4 76 64-132 SAMPLE DUPLICATE: 3544166 92586932002 Dup Parameter Units Result Result RPD Qualifiers Total Petroleum Hydrocarbons mg/L ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 16 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Storm Water Pace Project No.: 92586920 QC Batch: 678797 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92586920001, 92586920002 METHOD BLANK: 3552170 Matrix: Water Associated Lab Samples: 92586920001, 92586920002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg/L ND 0.0050 02/21/22 21:24 Lead mg/L ND 0.0050 02/21/22 21:24 LABORATORY CONTROL SAMPLE: 3552171 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Copper mg/L 0.5 0.51 102 85-115 Lead mg/L 0.5 0.50 99 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3552174 3552175 MS MSD 92586855001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper mg/L ND 0.5 0.5 0.51 0.51 101 101 70-130 0 Lead mg/L ND 0.5 0.5 0.48 0.48 96 96 70-130 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3552178 3552179 MS MSD 92587021001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper mg/L <5.0 0.5 0.5 0.53 0.52 104 103 70-130 1 ug/L Lead mg/L <5.0 0.5 0.5 0.48 0.47 97 95 70-130 2 ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 16 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Storm Water Pace Project No.: 92586920 QC Batch: 678627 Analysis Method: EPA 200.8 Rev 5.4 QC Batch Method: EPA 200.8 Rev 5.4 Analysis Description: 200.8 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92586920001, 92586920002 METHOD BLANK: 3551290 Matrix: Water Associated Lab Samples: 92586920001, 92586920002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Zinc mg/L ND 0.010 02/17/22 05:19 LABORATORY CONTROL SAMPLE: 3551291 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Zinc mg/L 0.05 0.047 94 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3551292 3551293 MS MSD 92582064004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Zinc mg/L 100 0.05 0.05 0.15 0.17 93 148 70-130 17 M1 ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3551294 3551295 MS MSD 92587541006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Zinc mg/L 95.2 0.05 0.05 0.16 0.16 132 120 70-130 4 M1 ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 16 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Storm Water Pace Project No.: 92586920 QC Batch: 676896 Analysis Method: SM 2540D-2015 QC Batch Method: SM 254OD-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92586920001, 92586920002 METHOD BLANK: 3542926 Matrix: Water Associated Lab Samples: 92586920001, 92586920002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 02/09/22 16:16 LABORATORY CONTROL SAMPLE: 3542927 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 246 98 90-110 SAMPLE DUPLICATE: 3544145 92586766002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 472 480 2 H3 SAMPLE DUPLICATE: 3544146 92586769002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 609 666 9 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 16 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Storm Water Pace Project No.: 92586920 QC Batch: 677503 Analysis Method: SM 4500-H+B-2011 QC Batch Method: SM 4500-H+B-2011 Analysis Description: 4500H+B pH Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92586920001, 92586920002 SAMPLE DUPLICATE: 3545994 92586980001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 6.8 6.7 1 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 16 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Storm Water Pace Project No.: 92586920 QC Batch: 678892 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92586920001, 92586920002 METHOD BLANK: 3552737 Matrix: Water Associated Lab Samples: 92586920001, 92586920002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand mg/L ND 25.0 02/17/22 06:01 LABORATORY CONTROL SAMPLE: 3552738 Spike 1-CS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Chemical Oxygen Demand mg/L 750 751 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3552739 3552740 MS MSD 92586823001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 83.3 100 100 192 188 109 104 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3552741 3552742 MS MSD 92586845002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 36.9 100 100 139 148 102 111 90-110 6 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 16 aceAnalytical www.pacelabs.cem Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: Storm Water Pace Project No.: 92586920 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/22/2022 11:47 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 16 aceAnalytical www.pacelabs.cem Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Storm Water 92586920 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92586920001 WEST 001 EPA 1664B 677165 92586920002 SOUTH 002 EPA 1664B 677165 92586920001 WEST 001 EPA 200.7 Rev 4.4 1994 678797 EPA 200.7 Rev 4.4 1994 678902 92586920002 SOUTH 002 EPA 200.7 Rev 4.4 1994 678797 EPA 200.7 Rev 4.4 1994 678902 92586920001 WEST 001 EPA 200.8 Rev 5.4 678627 EPA 200.8 Rev 5.4 678790 92586920002 SOUTH 002 EPA 200.8 Rev 5.4 678627 EPA 200.8 Rev 5.4 678790 92586920001 WEST 001 SM 254OD-2015 676896 92586920002 SOUTH 002 SM 254OD-2015 676896 92586920001 WEST 001 SM 4500-H+B-2011 677503 92586920002 SOUTH 002 SM 4500-H+B-2011 677503 92586920001 WEST 001 SM 5220D-2011 678892 SM 5220D-2011 678914 92586920002 SOUTH 002 SM 5220D-2011 678892 SM 5220D-2011 678914 Date: 02/22/2022 11:47 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 16 Document Name: Document Revised: November 15, 2021 a aceAnalytical Sample Condition Upon Receipt (SOUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.08 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑% Raleigh[] Mechanicsville[] Atlanta❑ Kernersville❑ Sample Condition Client Name: Receipt Project WO11.92586920 Upon �: { ,. Courier: ❑Fed Ex ❑UPS CUSPS [:]Client111111111 III I 11111111111 ❑ Commercial ❑Pace ❑Other: 925861320 Custody Seal Present? ❑Yes ONO Seals Intact? []Yes ❑No Date/initials Person Examining Contents: i Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer:. ❑ Wet []Blue ❑None []Yes []NO []N/A ElIR Gun ID. � �Jc) . ZJ Type of Ice: Correction Factor: Cooler Temp: j Add/Subtract (°C) Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process Coolet�empEorrected {'Cj. a u USDA Regulated Sol (Ej N/A, water. sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (theck maps)? Did samples originate from a foreign source {internationaliy, I�Yes i`iNa �i„d �o W-1i � 4 D—� ai..,,') I-lvo� t—inl,. Comments/Discrepancy: Chain of Custody Present? []Yes ONO ❑N/A 1. Samples Arrived within Hofd Time? ❑Yes []NO []N/A 2. Short Hold Time Analysis (<72 hr.)? ❑Yes ❑Na N/A 3. Rush Turn Around Time Requested? []Yes ❑No ❑NJA 4. Sufficient Volume? ❑Yes ❑No ❑NJA S. Correct Containers Used? -Pace Containers Used? QYes Des ❑No []No ❑N/A ❑NJA 6. Containers Intact? ❑Yes [I No N/A 7. Dissolved analysis: Samples Feld Filtered? ❑Yes ❑X( ❑N/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: ❑Yes i ❑Na ❑N/A 9. Headspace in VbA vials (�,5.6mm)? []Yes ❑No -1V%A 10, Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes (]Yes []NO ❑No ❑N/A []WA— COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Datefnme: Date: Date: Field Data Required? Des ❑No Page 14 of 16 Document Name: le Candltlon Upon Recell Document No.: P-CAR•CS-033•Rev.09 *Check mark top half of box If pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, ORO/Bois (water) ROC, LLHg **Bottom half of box is to list number of bottles Document Revised: November 15, 2021 t (SCUR) Page 2 of 2 Issuing Authority: Pace Carolinas.Quality Office Project q f 0# : 92586924 PM: SC Due bale: 02/22/22 CLIENT: 83-SPMETALS a ,: z z z z '" Z o. Z z Z N (V G N d v a 'a v y ei! arq s 7 v in a)v, �, V Z z a - A b v H N a 3 a m v H y a ? z ai ;� z z u 2 u d : w v m u '^ S d vp " w A N n a n a 0 0 ¢ s O L n p v O ? vi �^ a u v ^� n ti c e c a ^ Z l7 a c 2 E , a, $ o a a c c n V y V V u ` L X ¢ m c « y 4 d Z ] j u L E l.7 2 rn y n } " A - T N ar a as a E a` a o Z 2 ar `w a a N s ,� a E E E ¢ q q ¢ ` m v E c a a a. a a a E a E ¢ ry D 0 0 O a a ' a q E o W ° '' o. J E J .4 E J E N ° J J E E a J E ur N N pppE vEi a N vEi '„N4 uEi a N p' (m� E G ryrye N a O E O O " ,N-1 ,-1 'i ,..� F O _ � Y Y .T.r .�k. N N EE a M ry N a m v a N .� M ,i rn i m m or a . a 0.s e, s d rL d t7 lH 0 L7 l7 l7 l7 a t.7 l7 0 M CMm m m m m m in3 a ¢ a ¢ ¢ a o > > o 4n m a > a 1 IX I.- \J\ 3 f N. I N\ I 6 . E N\N I 7 N I \\\\J' N\N \� I -\\\N N\N N\\J 10 \\N\ 11 \NN\ 12 pH Adjustment Log for Preserved Samples Sample ID Type of preservative pH upon receipt Date preservation adjusted Time preservitlan adjusted Amount of PreSerVatlVe added Lot k Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be rent to the North Carolina DEHNR Certification 4fflce (I.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 15 of 16 0 0 R b m Z D n R N 0 o Is i o tp 00 y s to A u N j ITEM # n v a Q S 2 v T o a m T S m w O z [] i. w N m m = N O m N N ^. G) 0m m T o o o m O v m m o 1 N o 0 40 N o 0 N o N N o O a [� D 01 3 Ch C 0 lu b C N O 3 o n � v vl' D �� m n m m rn a Q CL n O 3 c v x v N m p axe m s z m N N �n n 0 a F A o � 0 0 a m m m -IOD Oln4 On T N c m A 9 3 Q v m D � MATRIX CODE (see valid codes lu left) a f° o c O C) O O O SAMPLE TYPE (G=GRAB C=COMP) +` m N lfl 1 N N N N I o �7 0 W N IQ N N N N N N ri g J + h �.� { m v 7 bT m m rn cn rn u, m p, N rA a v r a b v O 0 O C1 5 R m D K K m Q r z D 2 R -+ Q Ny N N N N N N m c w D z N IQ R m � rn m N N N N N N N -1 m m a N o T y z :l" �^,} rn v, os m m zz 0 n m N O 0 O 0 (�St 3 a O (O» 0 fJ —{ m 7 Z o r a L1 m K O m A A c m m co SAMPLE TEMP AT COLLLCTION "C n y \ po �I N # OF CONTAINERS v v 'O D C] b m v N a 0p /�� a ` ` 'C C -a tlnpreserded n n m y N v �- n' oou m N o X x H2SO4 (Sulfuric) m n Z 0 r 0 x x HNO3 (Nilric) v m � v n x X HCI � p C7 l7 n p 0 NaOH fa Na2S203 y a1 m m Methanal p z „z„} v < Olher `n v Analyses Test YIN a m r pH o < /D C6 -ni a f- _j x x Melals - Cu, Pb, Zn c m a x x R , 2m CD TSS. COD p- (n C N N Oil and Grease by 1664 H m N n 4i a C rto Z. D m N n Y m " CD m r- S r-t C a a n m z` y R R� n rD m TEMP in C o Residual Chlorine (YIN) r CID Received on Ice N a c n (YIN) u—St a y Q Sealed Caofer _ zv � (, q Y!N 2 ` N Samp€es S } (YIN) Page 16 of 16