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HomeMy WebLinkAboutNC0003760_Wasteload Allocation_19830419NPDES DOCUMENT !;CANNIN`: COVER SHEET NPDES Permit: NC0003760 DuPont Kinston facility Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Engineering Alternatives (EAA) Correspondence Owner Name Change Approval Instream Assessment (67b) Speculative Limits Environmental Assessment (EA) Document Date: April 19, 1983 Thin document is printed on reuse paper - ignore any content on the rezrerise side Yecomm,e 1,14t/(i)-2S aY-C Cfrook? _ --Pe «C ilf 6).1 Pvp0n ami geac,4/re bsed .g71 e51//cudpeclo4ri'✓16rL1Ge_ /,['S doco,p-tikai vim,/zp-isj ,a/Anll rk 1)-) /,191)±5 Alori-4r-cle 1) r) l6s s vnB)/ 1 `-b `7iyi y. s4614,5 G sv, ood /icb s44,/ M The. U i 5c�%�CcCr-l.e. � j�Y'i �✓.' � �� �7 `lce G-HB'N • DISCHARGER RECEIVING STREAM WASTEFLOW ! SEG NO !REACH 1 LEG MI 1 ! 1 1 1 1 0+001 ! 1 ! 1 1 0+101 I 1 1 . 1 1 0.201 i 1 1 1 1 0.301 l 1 1 1 1 0,401 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0+501 1 1 0.601 1 1 0.701 1 1 0.801 1 1 0+901 1 I 1.001 1 1 1.101 1 1 1.201 1 1 1.301 1 1 1+401 1 1 1+501 1 1 1+601 1 1 1.701 i 1 1 1 1 1.801 - - 1-- -1 1 1 1 1 1 1 1 1 1 1 1 1 1 .. 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2.001 1 1 2+101 1 1 2+201 1 1 2+301 1 1 2+401 1 1 2.501 1 1 2.601 1 1 2+701 1 1 2+801 1 1 2+901 1 1 3.001 1 1 3.101 1 1 3.201 1 1 3+301 1 1 3+40! 1 1 .3+501 1 1 3.601 1 1 3.701 1 1 3+801 1 1 34901 1 1 4.001 1 1 4+101 1 1 4.201 1 1 4.30E 1 1 4.401 1 1 4.50E r! ' 4.501 2 1 4.701 2 1 4+901 2 1 5.101 5;301 2 1 5.501 KINSTON F`EACHTREE i NORTHSIDE' DUPONT MEUSE RIVER 6. 7 5, 4.7 5 7 3. 6 M G ID TIC 1 CBOD 1 ORGN 1 NH3i! 1 0+001 0+001 0.001 0+001 0+04 1 0.001 0+001 0.001 0.071 0+001 0.001 0.001 0+111 0+001 0.001 0+001 0.141 0+001 0.001 0.001 0.181 0+001 0.001 0.001 0.211 0.001 0.001 0.001 0+251 0.001 0.001 '0.001 0.281 0.001 0.001 0.001 0.311 0.001 0.001. 0.001 0.351 0.001 0.001 0.001 0.381 0+001 0+001 0+001 0.421 0.001 0+001 0.001 0.451 0.001 0+001 0+001 ,0.481 0+001 0.001 0+001 0.521 0.001 0+001 0+001 0.551 0+001 0+001 0+001 0.581 0.001 0+001 0+001 0.621 0+001 0.001 0+001 0+651- 0+00 i 0-+-001 0+681 0+001 0.001 0+001 0+711 0.001 04001 0+001 0.75i 0.001 0+001 0+001 0.781 0.001 0+001 0+001 0.811 0.001 0+001 0.001 0+841 0+001 0+001 0+001 0.871 0+001 0.001 0.001 0.901 0.001 0.001 0.001 0.941 0.001 0.001 0.001 0+971 0+001 0+001 0+001 1+001 0+001 0+001 0+001 1+031 0+001 0.001 0.001 1.061 0.001 0+001 0.001 1+091 0.001 0+001 0.001 1+121 0.001 0+001 0.001 1.151 0+001 0.001 0.001 1.181 0.001 0.001 0.001 1+211 0.001 0.001 0.001 1+241 0+001 0.001 0+001 1+271 0.001 0.001 0.001 1.301 0.001 0+001 0+001 1.331 0.001 0.001 0.001 1.361 0.001 0.001 0+001 1+391 0+001 0+001 0+001 1+421 0.•001 0+001 0.001 1.451 0+001 0+001 0.001 1+401 0+001 0+001 0+001 1+461 0+001 0+001 0+001 1+511 0+001 0+001 0.001 1.571 0+001 0.001 0+001 1+631 0.001 0.001 0.001 1.681 0+001 04001 0+001 NO3 1 FLOW 1 CS I 0+001220+4612604.3! 0.001220+5112529.91 0.001220.5712457.6i 0.001220+6212387.41 0+00122046712319+21 0+001220.7212252.91 0;001220+7 7 12188+61 0 + 00 1 220 + 83 1 2126 .. 1.1 0.001220.8812065.31 0.001220+9312006.31 0+001220.9811949.01 0.0 1 221 + 03 1 1893 t 1 0.001221.0911839.31 0.001221+1411786+71 0.001221+1911735.71 0+001221+2411686..11 0+001221+2911638+01 0+001221.3511591.2.1 0+001221+4011545.81 0+0010;00i::.21+4-5i 15i 1.-.6i 04001221+5011458.71 0+001221.551 1417+1 1 0.0012_'1+6111376+61 0.001221.6611337.31 0+001221.7111299.11 0+001221+7611262+01 0.001221.8111226.01 0+001221+8r11191.01 0+001221+9211157+01 0+001221.9711124.01 0.001222.0211091.91 0+001222+0711060.71 0+001222.1311030.51 0+ 00 1 222 4 18 1 1001 .:1. 1 0.001222.231 972+51 0.001222+281 944.71 0+001222.331 917.81 0+001222+39! 891461 0.001222.441 866.21 0.001222.491 841.51 0.001222+541 817.5i 0. 00 1 222 .59 1 794.11 0.001222.651 771.5E 0+001222.701 749.51 0.001222.751 728.1.1 0+001222.80i 707.31 0.001 0.001 0.001 0.001 0.001 0+OO1 230 230 230 230 230 230 . 16 1 2284 + :i. 1 .2712159.21 .3712041.11 .4811929+51 +5811824+01 . 68 1 1724.3 1 1 ! +., + , V t .t. + ■ , t .. , + ,•• ' 1 1 2 1 5.901 1.791 0.001 0.001 I 1 1 . IT 6:101 1.851 0.001 0.001 I 1 1 2' 1 6.301 1+ 90 1 0.001 0.001 1 1 I 2 ▪ 1 6+501 1.951 0.001 0.00! 1 1 2 1 6+70 ! 2.001 0.001 0+001 1 1 2' 1 6.901 2.061 0.001 0.001 1 1 2 I 7.101 2. 11 1 0.00 1 0.001 I 1 1 2 1 7.30t 2.. 16 1 0+001 0.001 1 1 1 2 1 7.501 2+21 1 0.001 0.001 1 1 • 1 7.701 2i261 0+001 0+001 1 I L. 1 7.901 2.31! 0.001 0.00! 1 1 I 2 1 8+ 10 1 2.361 0.001 0.001 1 1 I `? 1 «30! 2.411 0.00! 0+00I 1 1 1 8.501 2.451 0.001 0.001 1 1 2 1 8.701 2+50 1 0.001 0.001 1 1 I 2 1 8.901 2.551 0.001 '-?+OV I I 1 1 2 1 9.101 2.601 0.001 0.001 ! 1 1 2 1 9.301 2.641 0.001 0.001 1 1 1 2 1 9.501 2.691 0.001 0.001 I 1 1 2 I 9.701 2.731 0.001 0.001 1 1 2 1 9.901 2.781 0.001 0.001 1 I 2 110.101 2.821 0.001 0.00i I 1. 1 '1 110+301 2.871 0+001 0.001 1 1 1 2 110.501 2.911 0.001 0.001 I 1 I 3 I 10.501 2.841 0.001 0.001 t 1 1 3 1 10 + 70 1 2.891 0.001 0.001 I 1 I 3 1 10+90 1 2.931 0.001 0.001 1 1 1 3, 1 11.101 2.971 0.001 0+001 I 1 I 3 1 11.301 3.021 0.001 0.001 1 1 I 1 11.501 3.061 0.001 0.001 1 l 3 1 11.701 3.101 0.001 0.001 1 11 3 1 11+901 3.141 0+001 0.001 I 1 1 3 I 12.101 3+181 0.001 0.001 1 1 I 3 1 12.301 3.221 0.00 ! 0.001 1 1 1 3 1 12.501 3.261 0.001 0.001 I 1 1 3 112.701 3.301 0.001 0.001 I 1 1 3 1 12.901 3.341 0.001 0+001 1 I 3 1 13.101 3.381 0.00i 0.001 1 I 1 13+301 3.421 0.001 0.001 1 1 3 I 13.501 3.461 0.001 0.001 1 1 3 113+701 3.501 0.001 0.001 ! 1 1 3 113.901 3.541 0+001 0.001 1 1 ,:, 1 14 + 10 1 3+ 57 I 0.001 0.001 1 1 1 .3 1 14.301 3. 61 1 0.001 0.001 I 1 1 3 1 14.501 3.651 0.00E 0.001 I 1 1 3 1 14.701 3.681 0.001 0.001 1 I 3 1 14.9901 3+721 0.001 0.001 1. I :s 1 15.101 3.751 0.001 0.001 1 1 3 1 15+30! 3+791 0.001 0.001 1 1 11 3 1 15.501 3,821 0.001 0.001 i 1 1 I 0.001 0.001 - 0 ---0 i--_-- t 001 2 ! 1 1 0. 10 1 0.091 0.001 0.001 2 1 1 1 0.201 0. 17 1 0.001 0.001 I 2 1 1 1 0.301 0.261 0.001 0.001 2 1 1 I 0.401 0.341 0.001 0.001 1 2 1 1 1 0+50! 0.42! 0.001 0.001 1 2' 1 1 1 0.601 0.501 0+001 0.001 2' 1 1 I 0.701 0+ 58! 0+001 0♦00! 1 2 1 1 1 0.801 0.661 0.001 0.001 1 2 1 1 1 0.901 0+741 0.001 0.001 1 2 I 1 1 1.00i 0.821 0.001 0.001 I 2 1 1 I 1.101 0.891 0.001 0.001 1 2 1 1 1 1+201 0.971 0.001 0.001 I 2 1 1 1 1.301 1.041 0.001 0+001 2 1 1 1 1.401 1.1.21 0.001 0+001 1 1 1:.50! 1.1 % 00l 0 O i I 1.601 1+261 0.001 0.001 1 1 1 1.701 1.331 0.001 0.001 I 1 1 1.80! 1.401 0.001 0.001 1 1 I 1.901 1.47i 0.001 0.001 I 1 1 2.001 1 .'54 1 0+001 0.001 I 1 1 2..101 1.601 0.001 0.001 1 1 1 2.201 1.671 0.001 0+001 1 2 1 1 1 2.301 1.741 0.001 0.001 1 1 I 2.401 1.R01 0.001 0.001 1 2 I 1 I 2.501 1.871 0.001 0.001 1 1 1 0.001 3.541 0.001 0.001 1 I 1 I 0.501 3.641 0.001 0.00! 1 3 I 1 i 1.001 3.731 0,001 0.001 1 3 1 1 1 1.501 3.821 0.001 0.001 1 "3 1 1 I 2.001 3+901 0.001 0.001 1 .3 1 1 1 2. 50 1 3.991 0.001 0.001 1 •3 1 1 1 3.001 4,071 0.001 0.001 I a 1 1 1 3.501 4.151 0.001 0.001 I 3; 1 1 1 4.001 4.231 0,001 0.001 1 3 I 1 1 4.501 4.311 0.001 0+001 I 3 1 1 I 5+001 4.381 0.001 0+00! 1 3 I 1 1 5.501 4+46! 0.001 0.001 ! _ 1 1 .1 6.001 4.531 0.001 0.001 1 3 1 1 1 6.501 4.601 0.001 0.001 i 3 1 1 1 7+001 4.671 0.001 0.00! 1 3 1 1 1 7.501 4+731 0.001 0.001 I 1 1 8.001 4+80! 0+001 0.001 1 1 1 8.501 4+861 0.001 0.001 1 1 I 9.001 4.921 0.001 0+001 1 1 1 9.501 4, '99 ! 0.001 0.001 1 1. 110.001 5.041 0.001 0.001 2 I 1. r rJr r.? 1 1 0-1 0.001 0.001 0+00! 0.001 0+001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.00! 0.001 0.00! 0.001 0.001 0.001 0.001 0.00i 0.001 0.001 0.00! 0.001 0.001 0.001 0.001 0.001 O .001 0.001 0.001 0.001 0+001 0.001 0.001 0.001 0+001 0.001 O .001 0.001 0.001 0.001 O .001 ,0.l0.f11 0.001 0.001 O .001 0.001 0.001 0.001 0.001 0.001 0.001 0.00i 0.001 0.001 0.001 0.001 0.001 0.001230.8911540.91 0+001231.0011456.71 0.001231.1011377.11 0+001231.=2011301.81 0.001 '2 31 + 3 1 1 1230 .7 ! 0.00 1 231 .4.1. 1 1163+4 1 0.001231.5211099.91 0+001 231.621 103 +81 0.001 31.721 987.01 0.001231.831 929.31 0.001231.931 878.51 0+001232.041 830.51 0.001232+141 785+21 0.00 1232.241 742.31 0.001232;35i 701.81 0 : 00 1 232 . 45 1 663.51 0.001232.561 627.31 0.00 1 2. 2.66 1 593.11 0. 00 1 232. 76 1 560.71 32 530.11 0. 00 1 232 . 97 1 501.21 0.001233.081 473.91 0.0001233.181 448.11 0.001233.28i 423+61 0.001 238.861 647.41 0.00 1238 .9971 612+91 0.001239.071 580.21 0.001239.181 549+31 0.001239.28i 520.01 0+001239.381 492.31 0.001239.491 466.1.1 0.001239.591 441+31 0.001239.701 417.81 0.001239.801 395.61 0.001 '39.901 374.51 0.001240+011 354.61 0. 00 1 240. 11 1 335.81 0 . 00 1 240 . 22 1 317.91 0.00 1 240.32 1 301.01 0.00 1 240.42 1 285.01 0. 00 1 '40 + 53 1 269.91 0 . 00 1 240 . 63 1 255.61 0+001'40.741 242+01 0 . 00 1 240. 84 1 229.21 0.001240.941 217.01 0.001 41,051 205.51 0 + 00 1 241 . 15 1 194.6i 0 .00 1 24, 1 . 26 1 184.31 0.001241.36 1 174.61 0. 00 1 241 .46 1 165.31 - is + l_-! -0 E - _ 9 . 1 '0 1- -• 0f .1- c 0 ! 0.001 39.151 281 +8 1 0.001 39.201 262.21 0.001 39..26i 243. i 0.001 39.311 2 6+ 9 1 0.00! 39.361 211.11 0.001 39.411 196.51 0.001 39.461 182.9i 0.001 39.521 170.21 0.001 39+571 158.41 0.001 39.621 147.5i 0,001 39.671 1.37.41 0+00! 39.72! 127+91 0.001 39.781 1 1.9 +'. 1 0.00! 39.831 111.+01 0.001 0+00i 0.001 0+001 0.001 0.001 0.00! 0.001 0+001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0+001 0.001 0.00! 0.00! 0.001 0.001 0.001 0+001 0+001 0.001 01 0.001 7!.931 96.41 0.001 39.981 89.91 0.00i 40.041 83.81 v.00 1 40.091 78.2 1 0.001 40+141 72+91 0+00! 40+19 1 68.11 0.001 40.241 63.51 0.001 40.301 59+31 0.001 40.351 55.41 0.001 40.401 51.131 0.00 1 281 . 86 i 143,11 0.001282.121 130.81 0.001282.381 114.91 0.001282.641 100.8! 0 . 00 1 282 . 9'0 1 88 + 6 1 0+001283.161 77.8E 0.001283.421 68.4! 0.00 1 283. 68 ! 60.11 0.001283.941 52.91 0. 00 1 '284 . 20 1 46.51 0+001284.461 41.01 0.00 1 284. 7 "2 1 36. 1 1 0.001284.981 31.8E 0.001 2.2 85.4 i 28. 1 1 0.00 1 285.50 1 24. 8 1 0. 0 0 12.8 5 .7 6 i 21.91 0+ 0 0 1 2 8 6 . 0 i 1 19.41 0.001286+281 17.21 0+00 1 286.54 1 15+31 0 , 00 1 286 + 80 1 13.61 00 Iv; P rt- 4ssCs d 1 tZ w CrrsY DIVISION OF ENVIRONMENTAL MANAGEMENT April 27, 1983 MEMORANDUM TO: Steve Tedder, Supervisor Technical Services Unit FROM: Forrest R. Westall, Head Operations Branch SUBJECT: Disinfection Requirements for the Lower Neuse River Near the Kinston Area Attached for your review is a memorandum from the Washington Regional Office concerning this subject. I would ask that the observations from the Washington Regional Office be reviewed in relation to the evaluation performed by Randy for disinfection requirements in the Neuse River near the Kinston area. In the case of the Kinston Northside plant, it appears that monitoring data prior to disinfection will be necessary in order to evaluate whether disinfection at this facility can be discontinued. Following your review of this information, please provide a brief summary of the results of your review. If you have any questions concerning this request, please let me know. Attachment lit1,7•i WATER QUALITY OPERATIONS. BRANCH MEMORANDUM TO: Lee Fleming, Jr., Chief Water Quality Section 60164,1.Tt A".3 DIVISION OF ENVIRONMENTAL MANAGEMENT THROUGH: Jim Mulligan, Regional Supervisor Washington Regional Office FROM: Roger K. Thorpe, legion 1 Engineer Water Quality Section-WaRO SUBJECT: Disinfection Requirements for the Lower Neuse River Near the Kinston Area April 19, 1983 a Per your request, I have reviewed the letter from DuPont and the assessment made by Technical Services. In the case of DuPont's discharge, I believe that water quality standards in the Neuse River can be maintained without disinfection. As stated in Mr. Long's letter, only about 5% of the influent flow to the waste treatment plant is domes- tic flow. This coupled with the dilution ratio of approximately 36 to 1 should prevent violations of the fecal coliform standard in the Neuse River. Mr. Long related by telephone conversation on April 15, 1983, that he had sampled the effluent prior to chlorination from both of the final clarifiers that week and obtained F.C. concentrations of 50/100 ml and 200/100 ml. CMSD discharges to Contentnea Creek. The dilution ratio is approximately 11.6 to 1. Without disinfection, I feel that the coliform concentrations in the effluent may be high enough to contravene water quality standards in Contentnea Creek during low flow conditions. I could not recommend removing the disinfection requirement on the facility without first obtaining data which shows that the fecal coliform concentrations in the effluent without disinfection are consistently at or below the 20,000/100 ml range. In the case of Kinston's Northside plant, I could not recommend removing the disinfection requirement without first obtaining data which shows that the fecal coliform concentrations in the effluent without disinfection are consistently at or below the 50,000/100 ml range. If this information could be obtained, then in both the case of CMSD and Kinston Northside, I believe that monitoring should be required and a re -opener be included in the permit which would allow us to require disinfection when a certain concentration is reached. RKT / ekw DIVISION OF ENVIR0 4EQ TAL MANAGEMENT March 28, 1983 Hr. E. L. Long, Specialist Environmental Control E. I. du Pont de furs & fany Kinston Plant Kinston, North Carolina 28501 Dear 14r. Long: Thank you for your letter of January h, 1983 concerning chlorination of the wastewater effluent at the Kinston plant. Also, I appreciate the recent opportunity we had to discuss this issue in my office. As I indicated to you, the water quality program is taking a hard look at the issue of chlorination of treated wastewater. ly staff has been in communication with the Department of Human Resources and with the researchers at area universities on this important issue. It appears that some research effort may be directed toward the issue of wastewater chlorination during the coming year. It would be our intention to use that research effort to examine our existing requirements for disinfection. With specific reference to your request to reconsider disinfection at the Kinston facility, we have prepared a peal iminary analyses of the four plants discharging in this area of the Neuse River. Because this evaluation is very preliminary and could affect all concerned discharged, we need to carefully SWIM the results before a final determination is made. As a result, I am referring the preliminary determination to our regional office water quality staff In Washington and to the central water quality staff to determine if dropping disinfection requirements is in the best interest of water quality of the Meuse River. This evaluation will be completed by Ap i 1 22, 1983. At that time, we will notify you of the results of our determination. In reviewing our disinfection requirement, I think it is 'important to point out a few key things. our NPDIES vomit does not require chlorination of effluents but ratter requires an a b1e collform density. Certainly chlorination is the most widelyused meths of achieving this effluent quality. However. alternative disinfectimethods are available. If problems associated with chlorination are to be avoided, these other methods may need more consider- ation. Therefore, in addressing the issue of disinfection of waotewater discharges, it is necessary to consider this issue from the disinfection technology standpoint as well as from the public health aspect. Nr. E. L. Long Page 2 March 28„ 1983 I think you can appreciate our desire to trove carefU ly en this issue. If you have any questions concerning this natter, please let me knew. Sincerely yours. J R. W. Zee Fleming* Jr., Chief Voter Quality Section cc: Forrest UUestal1 1HuiIiga►n Steve Tedder Alan Klimek 414 / f - �,,.,( `L(j beet( DIVISION OF Ei VIROi IEUTAL MANAGEMENT March 25, 1933 ! EMORAN!)UM TO: Jim Mulligan, Regional Supervisor Wasnington Regional Office FROM: W. Lee Fleming, Jr., Chief Rater Quality Section SU3JECT: Disinfection Requirements for the Lower Neuse River dear the Kinston Area Attached for your review is information concerning this issue. Please review in consultation with the Technical Services Unit and provide comments concerning this no later than April 13. As you will note from the letter to ifir. E. L. Long, ge need to determine our position before April 22. Your assistance in this matter is appreciated. If you have any questions, please let re know. cc: Forrest testall Flan Klimek Steve Tedder DIVISION OF ENVIRONMENTAL MANAGEMENT March 22, 1983 MEMORANDUM TO: Forrest Westall, Head Operations Branch FROM: Randy Williams �, Technical Services �" U THRU: Steve Tedder 4),Xr SUBJECT: Disinfection Requirements DuPont - Kinston Plant Mr. E. L. Long of DuPont has requested that the company be allowed to discontinue the chlorination of its wastewater. This request was made on the basis that the "Kinston Plant tradewaste facility effluent does not require chlorination to protect public health" (see letter to Lee Fleming dated January 5, 1983) since there are no drinking water intakes or public beaches located downstream of this discharge. Further, only 5/ of the feed to the facility is of domestic origin. Thus, low counts of fecal coliform bacteria should be present in the plant's effluent even without chlorination. Kinston's Northside WWTP is located 4.5 miles below the city's Peachtree Plant and 6 miles upstream from DuPont. Contentnea MSD is located on Contentnea Creek 2.5 miles above the mouth of the creek, which is 5 miles below DuPont. Presently, only Kinston Peachtree is not required to disinfect its wastewaters, based on an analysis of fecal coliform data supplied by its consultant, L. E. Wooten, and recent self - monitoring data. The other three plants are required to meet an effluent limit of 1000/100 ml. The most recent data available on a yearly basis for both the Kinston Peachtree and Northside Plants is that from 1981. From Table 1, the average upstream fecal coliform value was 243/100 ml for that year while the average value downstream of the Peachtree Plant was 330/100 ml. This station corresponds to the upstream station for Northside. The average value of fecal coliform below the Northside Plant was 465/100 ml. From this data, it can be seen that the treatment plants exert little influence on the values of fecal coliform in the river. In fact, fecal coliform increases by over 25% between the stations above and below Northside, even though the plant was providing disinfection. Forrest Westall March 22, 1983 - page two - Recently, Kinston Peachtree's disinfection requirements were rescinded on the basis of the plant's past performance with respect to fecal coliform. At 7010 river flow, it was determined that an effluent concentration of 20,000/100 ml would protect. the standard if the mix time was instantaneous. If the mix time was 6 hours, 50,000/100 ml would protect the standard. Modeling shows that these values would also protect the river below North - side and DuPont if applied to those discharges. According to E. L. Long, 5% of DuPont's wastewater is domestic. Assuming a typical undisinfected wastewater concentration 'of 400,000/100 ml, a final effluent concentration of 20,0007100 ml could be expected. Thus, it appears that none of the discharges needs disinfection as long as these values can be maintained in the effluents. In summary, the fecal coliform levels in the Neuse near Kinston appears to be a function of upstream conditions. Treatment plants, as they are presently operated, exert little influence on these levels. If disinfection were tc be discontinued at those plants discharging directly to the river, little change in in -stream levels is expected, as long as 50,000/100 ml effluent limits are maintained. Let me know if you have any questions. RW:cs Attachment Table 1 Peachtree Northside 1981 Upstream Effluent Downstream = Upstream Effluent Downstream Jan 318 30000 438 438 <10 650 Feb 78 24000 139 114 <10 145 Mar 280 ......... 10000 .. _ 628-.._ , ,. _ .._.....:.-628 , <10 : __, ,. __.-1319- Apr 250 5000 190 190 <10 260 May 138 2000 193 193 <10 175 June 150 3000 140 162 <10 225 July ND ND ND:- 203 <10 180 Aug 100 4600 150 181 <10 185 Sept 173 100 240 5114 <10 318 Oct 700 3000 850 825 <10 1188 Average 243 9200 330 345 <10 . 465 f b I, • R.12003.K vwar .•v s• ESTUUSNED not E. I. DU PONT DE NEMOURS & COMPANY INCORPORATED KINSTON PLANT KINSTON, NORTH CAROLINA 28501 TEXTILE FIBERS DEPARTMENT Mr. Lee Fleming Chief, Water Quality. Section N. C. Dept. of Natural Resources and Community Development P. 0. Box 27687 Raleigh, N. C. 27611 414c 14%1 /([ .1 — 6_,YA r he aft0 -ikt) L 114 C� 3� >�j ,�Q►^ �� January 5, 1983 °)Y C(1/ '474° 4 Ali g WAY, Lrkt.4"71,;_- g'iejjrit� 4g. 4t Ao3 Dear Mr. Fleming: Ref.: Kinston Plant - Chlorination of Tradewaste Facility Effluent - NPDES Permit No. NC 0003760 It has come to my attention that chlorination of tradewaste effluents is a condition of receiving water flow and is not required in some wastewater treatment plants in North Carolina. The chlorination of wastewater effluents has become a matter of in- creasing concern in recent years because of the potential for adverse effects on aquatic life and human health from the chlorination of substances that can be present in the receiving waters. Environmental Science and Technology reviewed these concerns in a January, 1982 article, "The Chlorination Question" (Attach- ment 1'), and stated that "Because the discharge of chlorine into surface waters and the ocean damages aquatic organisms, some areas of the U.S. are seriously considering banning wastewater chlorination." Several years ago, the U.S. EPA removed the fecal coliform limitation from the Secondary Treatment Regulation after an EPA Task Force formed to review the use of chlorine concluded that: (a) the use of chlorine wastewatericy on disinfection and to situations where it is necessaryto should be limited exclusive use of chlorine for disinfection should not to be continued ealth, and , ( r the of aquatic life is of primary consideration.(�g where protec- tion e Attachment 1 to addressee only. (1) U.S. EPA, "Disinfection of Water --Task Force Report." MCD-21, No. EPA-430/9-75-012, Centralized Mailing Lists Services (8 FSS), Denver Federal Center, Denver, Colo. (1975). R • • Mr. Lee Fleming - 2 - January 5, 1983 More recently, the December, 1982 issue of "News", a publication of the Water Resources Research Institute, pointed out that 25 states have now re- vised its standard for chlorine disinfection in wastewater. In one state, studies showed the requirement was excessive and it had a negative effect on aquatic life. The article continues to point out only 88 of that state's 1600 treatment plants still require chlorination and this was because they were located within 20 miles of a drinking water plant or a swimming beach. Therefore, the need for fecal coliform limitations and resultant chlorination should be determined on a case -by -case basis. We believe that the Kinston Plant tradewaste facility effluent does not require chlorination to protect public health. As in the case of the state pointed out in "News", there are no drinking water intakes or swimming beaches below our plant. The clarified effluent comes from a well -operated biological treatment system and contains a low concentration of suspended solids. Only about 5% of the feed to that system is sanitary wastewater. Even at low river flow, the site dis- charge is less than 1% of the river flow. Therefore, we believe that the residual fecal coliform content of the effluent would not have a significant impact on the river. The Kinston Plant began chlorination about five years ago to maintain a fecal coliform bacteria count of less than 1,000 colonies per 100 ml as a permit requirement. The attached bacteria data (Attachment 2) of the Neuse River for the past three years during the traditional low flow months show our chlorinated tradewaste effluent has no effect on fecal coli- form count when upstream and downstream values are compared. Therefore, we question the continued need to chlorinate our effluent in light of the concerns that have arisen regarding possible detrimental effects of chlorination to aquatic life. We request that you and your staff perform the necessary river quality analytical evaluation in our area so as to relieve us of an unnecessary fecal coliform permit burden and enable us to cease chlorination. Your consideration of our request will be appreciated. ELL:gs M13/13 Attachments Sincerely, t E. L. Long, Spec'3aQist Environmental Con of ATTACHMENT 1 0 The chlorination question Highlights of the recent conference in California Water chlorination is both a bane and a benefit to man. Recognition of some of the health problems caused by chlorine in drinking water led to the first water chlorination conference in Oak Ridge, Tenn., in 1975. Since then, a conference has been held every two years. The last one took place in Pa- cific Grove, Calif., at the end of Oc- tober and was attended by about 200 persons. Seventy papers were pre- sented and 38 poster presentations were given. Why does there continue to be so much research in the area of water chlorination? One reason is that probably no other public health issue affects a larger proportion of the U.S. population. Another is that chlorine is used to disinfect not only potable water supplies, but the wastewater from sewage treatment plants. It is also added to the water circulating inside the cooling towers of electric power plants. In this way, lakes, streams, and oceans annually receive a great deal of chlorine, which undoubtedly affects aquatic ecosystems. Chlorine is also employed in food processing to control the growth of bacteria and other pathogens. Recognition that water chlorination causes health risks and harm to aquatic life has not led to its demise. Consulting ,engineer George White said that chlorine use is 20-40% greater than reported in 1975 and growing steadily, especially in the area of disinfection. The many applications of water chlorination and the fact that it pre- sents complex and demanding scien- tific problems have made it a subject for much research. A great deal has been learned in the past six years. Toxicological information relevant to drinking water disinfection was virtu- ally nonexistent prior to 1976. How- ever, according to James Fava of Ecological Analysts (Sparks, Md.) and William Davis (U.S. EPA), the basic questions regarding chlorination have not changed even though the experi- mental evidence about the chemistry of chlorination and its effects on man and aquatic life has expanded greatly. We are still asking, for instance, if chlorination is the best treatment method for drinking water. Would another disinfectant be safer for human health? Do we really need to disinfect wastewater from sewage treatment plants? Other disinfectants Alternative disinfectants that have been considered are chlorine dioxide, ozone, chloramines, UV irradiation, iodination, or some combination of these processes. The first three have been given the most attention. How- ever, as Richard Bull (U.S. EPA, Cincinnati) pointed out, all forms of disinfection commonly used alter the composition of trace organic chemicals because the efficacy of disinfectants "depends on their ability to alter or- ganic chemicals by either chemical or physical means." This does not mean that another disinfectant may never be found safer than chlorine. At present, not enough research has been done to assess the relative hazards ofthe vari- ous alternatives to chlorine. An advantage of chlorine dioxide (C102) is that it forms very few chlo- rinated products. But this is probably outweighed by many serious draw- backs. C1O2 produces chlorite (C102-), which presents an acute toxicological hazard. Bull stated at the conference that C102- has been shown to oxidize hemoglobin to the non- functional pigment methemoglobin; at lower levels it produces hemolytic anemia. It may also depress sperm production. In addition, C102 itself may possess activity as an antithyroid agent, though the mechanism for this is not yet understood. Chloramines also have associated hazards. A major concern is their mutagenic properties. Bull said that chloramine has been found to produce methemoglobinemia when present in water used for dialysis of patients with - chronic kidney failure. However, when animals are exposed to chloramine orally, this effect has not been ob- served. Ozone is an effective disinfectant and is used quite commonly in Europe. But it is expensive and must be used in combination with some other chemical because ozone leaves no residual to continue disinfection after water is distributed into the system. Conse- quently, a small amount of chlorine is usually added to the water after ozo- nation. Health effects of chlorination • What has been learned about the adverse health effects of chlorine and the nroductc it fnrmc9 Cnrnr a ,l,, Bean: One or two key chemical reactions may explain a great deal the toxicological effects of chlorine itself (technically a mixture of HOCI and OCl— depending on pH) have re- ceived almost no study —a major gap in the presently available research. There is only one long-term investi- gation of chlorine toxicity, an experi- ment by Druckery that indicates no harmful effects from drinking water containing 100 mg/L of chlorine pro- vided to rats over seven generations. Chlorinated water supplies do seem to present a hazard. At the conference Earle Nestmann (Canada Health and Welfare) reported on a study of the mutagenicity of 30 chlorinated water supplies in Canada. Out of four sam- ples taken from every water treatment plant, he found at least one sample from each to be mutagenic. He also reported that compared with other organics, trihalomethanes (THMs), the regulated byproducts of chlorina- tion in the U.S., did not seem to be well correlated with mutagenicity. The health effects of THMs have been studied in some detail. Chloro- form has been found to cause cancer in both mice and rats. The carcinoge- nicity of the other THMs has not been established definitely, but is being ex- amined in the national toxicology carcinogenesis bioassay program. Michael Pereira (U.S. EPA, Cin- cinnati) discussed his research con- cerning the ,mechanism by which THMs induce cancer. The object of his study was to determine whether they are initiators or promoters of cancer. If initiators, they would presumably act by a genetic mechanism; that is, they would act, through interaction with genetic material of the target cell and the effects would be irreversible. If promoters, the THMs would act through an epigenetic mechanism, and the effect would be reversible, i.e., the damage would stop once the promoter was removed unless it bad already caused an actual tumor. Clarifying this is important: if a carcinogen is an initiator, it is believed Fava: The basic questions regarding chlorination have not changed to have no threshold level below which it has zero effect; if it is a promoter, it is thought to have a threshold level. Therefore, such a study can aid in formulating models that help to define a level at which to regulate THMs. Pereira's results are preliminary but indicate that THMs are promoters of cancer. They appear to have "the weakest, if any, tumor -initiating ac- tivity." Besides THMs, chlorination also produces other byproducts. Their identification has been a relatively slow process. And all of them —there are a great many —have still not been iden- tified. The formation of chlorinated phe- nols has been known for many years. They show up in the chlorination of wastewaters. 2,4,6-Trichorophenol has been demonstrated to be a carcinogen in both mice and rats, and Jerry Exon of the University of Idaho has found some evidence for the fetotoxic effect of 2-chlorophenol at high doses in rats. Haloacetonitriles are also products of chlorination and a dichloroacetonitrile has been shown to be mutagenic in the Ames test. Preliminary data also in- dicate that this chemical is a tumor initiator. The formation of organic N-chloramines has been postulated and a model compound N-chloropip- eridene has been shown to be formed in aqueous solution. It has direct mu- tagenic activity. The treatment of wastewater is im- portant because advanced treatment is being studied as a potential source for replenishment of groundwater supplies. Martin Reinhard of Stanford University found wastewater samples only weakly mutagenic before disin- fection but strongly mutagenic after treatment with chlorine. He noted that bromination occurred during chlorin- ation and suspected a connection be- tween bromination and increased mutagenicity. In a poster session, general chair- man of the conference Robert Jolley Jolley: Bromochloramines are important halodmines in chlorinated seawater (Oak Ridge National Laboratory) reported on his study of the mutagen- . icity and chemical characterization of the nonvolatile organics in disinfected wastewater effluents. Chlorine was used as a disinfectant on some samples and ozone was used on others. In both cases, disinfection most often led to an increase in the number of mutagenic • materials. However, sometimes the reverse was true, i.e., the mutagenicity of a few samples was decreased by disinfection. This inconclusive evi- dence calls for a better understanding that new research might provide. In food processing, chlorine is ap- plied directly to some foods, such as fish and chicken, and indirectly to others because it is employed to sani- tize equipment. George Braude of the Food and Drug Administration pre- sented a paper about the lack of data concerning the effects of chlorination on foods. He said: "Very little infor- mation is available regarding the identity, exposure level, and potential toxicity of chlorinated or oxidized re- action products resulting from the use of chlorine -containing sanitizers in food processing." Population studies What epidemiological evidence do we have that chlorinated drinking water is causing increased cancer rates? Kenny Crump, Science Re- search Systems (Ruston, La.), stated that "although a causal relationship between chlorinated drinking water and cancer has not been established, . the evidence is to a considerable extent suggestive of such a relationship for rectal cancer and, to a lesser extent, bladder and colon cancer." He listed five case -control studies, conducted by different investigators using data from widely separated geographic areas of the U.S., which found in each case el- evations in cancer rates for one or more types of cancer. He said that although no single study is definitive, these in-; dependent finclinac TPlin rP i}iP ,w , bility that the increases arc clue to ei- ther chance or confounding factors." Some drawbacks of these studies are that. the measures of water quality were very crude and data to control for confounding factors was limited to those.previded by death certificates. Theresa Young described a matched -pair case -control study car- ried on in Iowa in which "only colon cancer mortality was found to be sig- nificantly greater among those exposed to chlorinated water." She indicated that an important weakness was the lack of individual 'water exposure histories. She also found that when THM levels were compared to cancer rates, no dose -related risk gradient was found, but that "when other variables indicative of organic contamination were considered, an interesting risk gradient emerged." According to this study, other contaminants present in chlorinated water may be more carci- nogenic than TH Ms. Future epidemiological studies may provide more definitive evidence. A large case -control study of bladder cancer, sponsored by the National Cancer Institute, is nearing completion in which interview data should provide much more extensive control for con- founding factors. In an epidemiology overview, Kenneth Cantor, National Cancer Institute, said that many brominated analogs of chlorinated compounds may have higher carcino- genicity and may play an important role as cancer agents. Cost -benefit analysis With such uncertainties about the actual contribution of water chlorin- ation to adverse health effects, it would seem impossible to do a cost -benefit analysis of the different methods of water treatment. One conference participant felt that such .analysis could lead to investment in alternative methods that would eventually prove less advantageous. In contrast, another participant, Talbot Page of the California Institute of Technology, said: "We .believe a cost -benefit approach offers a useful perspective to the problem of chemi- cals in.:.drinking water." -He claimed that cost -benefit analysis allows one to • organize research around areas where filling the gaps will have the most ef- fect on decision making. He pointed out that a "decision to postpone action, awaiting better in- formation, is just as much a decision as one to undertake action," and said that his analysis shows there would be a net benefit associated with installing granular activated carbon filters in fAT11P (111PC If 4...s F:l�a�. ..-.. •.....7 before chlorination, they remove the precursor substances that give rise to chlorination byproducts. Analytical measurements Previously, there was no quick method of measuring total residual halogens (HOBr, HOCI, NH2C1, and NHBr2) down to parts per billion lev- els, and operators of power plants said that a standard of 50 ppb residual halogen would be unrealistic because we -couldn'tmeasure it. At the con- ference, • James Carpenter, now with the Nuclear Regulatory Commission, reported a simple fluorometric method , that quickly measures total halogens with an accuracy of ± 0.1 ppb and distinguishes the different species by adjusting the pH. Harvey Sellner of the EPCO Company (Danbury, Conn.) described an amperometric technique of continuously monitoring total residual chlorine at levels in the region below 1 ppb. The chemistry of chlorination The reactions of chlorine with or- ganic materials in natural waters are extremely complex. In general, organic materials in natural waters (loosely referred to as humic substances) and other organic materials derived from natural sources are responsible for most of the observed reactions of chlorine with surface waters. Roger Bean of Battelle, Pacific Northwest Laboratories cleared up some of the confusion about chlorine chemistry by presenting a table called Low Level Chlorination of Natural Waters (see box). Before the conference, it was ] iabacetonitrile ' - p=:v ;formation - ,= ; t `Formation of -'{, 74 - onfiatoform:. : �� ' ;�orgariichalogens'vz- v T:- :.--;1 thane ��i : � � .7-::::'...., .i. Cfs z` E i-lalogenated phenol►'' +Vp -#ormation ',,, Low level chlorinati o natural waters (wheredoes =: ::::''..***the 'chlorine .• Process _Haloform .formation 0:5-5"sed .Organic oxidation to — • >�50=80 i1 -depotymerized r Other react! A rough estunatepl abeirrcer40t -used by each trievfloactio ,~ thought that approximately 80% of the chlorine was used to oxidize organic matter to CO2. However, George Helz of Stanford University reported ex- periments that suggest the figure is closer to 50%. He postulated that at- tack at certain labile amino acids in the peptide chains initiated a series of re- -actions resulting in CO2 production. Another reaction that requires a weak link in the peptide chain is the forma- tion of haloacetonitriles, reported by Theodore Bieber of Florida Atlantic University (Boca Raton, La.). • In the past, several scientists sug- gested that phenolic components in humic materials are the primary • sources of halofdrms from water chlorination. At this conference, Scott Boyce of the California Institute of Technology reported work with res- orcinol, a 13C-labeled phenolic com- pound, showing that the aromatic carbon atom between two meta-hy- droxy groups is the one incorporated into the haloform product: Barry Ol- iver (Canada Centre for Inland Wa- ters) reported that the amount of THMs produced from humic sub- stances can be correlated with in- creasing color if the primary THM producers in' a water sample are humics. Bean reported that .his own work suggested that phenols are important substrates in water chlorination reac- tions. He found more than 30 different halogenated phenols produced by the low level chlorination of power plant cooling waters. Jolley presented work showing that bromochloramines should be included along with monochloramine, dibro- mamine, and tribromoamine as im- portant haloamines in chlorinated seawater. Donald Johnson and coworkers of the University of North Carolina chlorinated natural aquatic humic material and analyzed the products. They found that except for chloroform and choral, all chlorinated components were carboxylic acids. Also, the ma- jority of the components contained chlorine; no chlorinated aromatics were present. The experiment revealed a great deal but did not tell how the total amount of other chlorinated or- ganics relates to the amount of chlo- roform nor whether any of them are present in actual drinking. water. Johnson said that "if it is shown that trihalomethanes are not the most abundant chloro derivatives of aquatic humic material which occur ubiqui- . tously, then health effects data on compounds such as di- and trichloro- acetic acid will be needed in order to • risks from the consumption of chlori- nated water." Although the reactions of chlorine are complex, Bean speculated "it is possible that only one or two key re- actions with a few key structural components will be required to explain the initiation of the reaction sequences involved." Obviously much work re- - mains to be done in this area before even the most important reactions of chlorine in natural environments can be reasonably understood. - Aquatic ecosystems Because the discharge of chlorine into surface waters and the ocean damages aquatic organisms, -some areas of the U.S. are seriously consid- ering banning wastewater chlorination. The EPA is now working on chlorine water quality criteria for the protection of aquatic life. It is anticipated that draft chlorine criteria will be com- pleted early-tbis year. Presently, many regulators and environmental man- agers feel sufficient research has been completed to identify the hazards of chlorination for aquatic life. This chlorination conference, how- ever, highlighted the fact that a great deal is still unknown. Richard Vand- erhorst of Battelle, Pacific Northwest Laboratories performed a study that examined the effects of low level chlorination on open microcosms in Puget Sound, Washington. He found statistically significant differences in the rates of growth; however, the • meaning of these findings is question- able because the "systems were dearly in agrowth phase and had not reached steady state at the experiment's con- clusion?' David Anderson of Envirotest (Redmond, Wash.) presented infor- mation to show that the interaction of chlorination with nickel resulted in increased accumulation of nickel in rainbow trout. His data show how important it is to evaluate the inter- action of chlorination with other chemicals known to have environ- mental effects. An overview of the effects of chlo- rine -produced oxidants and THMs on marine invertebrates was presented by Geoffrey Scott of Research Planning Institute (Meggett, S.C.). The mate- rials he reviewed showed that many of the effects are irreversible and that the juvenile stages of the organisms are more sensitive than the adult stages. Scott also presented information on the bioconcentration of bromoform in American oysters. Fava and Davis said.that the "inte- gration of marine biological research with identified technical needs could be one of the true progressive steps to achieve the benefits of chlorination while at -the same time helping to pro- tect sensitive environmental systems." An example is using marine organisms such as oysters to monitor for human pathogens in the effluent from waste treatment plants. Many investigators said that additional field experiments concerning the effects of chlorine on aquatic life are needed to confirm what has been learned in the laboratory. Fava and Davis pointed out the need for additional research when they said: "As the use of chlorine continues to grow, so does the potential for aquatic -.effects. Ignoring the problem is not the proper response front an intelligent society. Instead,'we need to be pre- pared to make educated technical de- cisions based on experimentally proven 1 facts —not on ignorance and unproven assumptions." The proceedings of the conference will be published this year by Ann Arbor Science (Mich.). The ' next f chlorination conference is scheduled for October 1983 in the Maryland - Virginia area. • --Bette Hileman ATTACHMENT 2 KINSTON PLANT BACTERIA ANALYSIS OF THE MEUSE RIVER (COLONIES/100 ML) MAY JUNE JULY AUG. SEPT. • 1980 - Upstream 1300 1100 700 500 850 - Downstream 1050 1000 600 550. 1050 • 1981 - Upstream - Downstream • 1982 - Upstream - Downstream /1s Misc.II12:5 300 1000 700 90b 1350 450 1200 800 800 1250 200 100 1150 350 200 400 150 1250 250 200 DIVISION OF ENVIRONMENTAL MANAGEMENT March 22, 1983 MEMORANDUM TO: Forrest Westall, Head Operations Branch FROM: Randy Williams Technical Services THRU: Steve Tedder Zit)1 SUBJECT: Disinfection Requirements DuPont - Kinston Plant Mr. E. L. Long of DuPont has requested that the company be allowed to discontinue the chlorination of its wastewater. This request was made on the basis that the "Kinston Plant tradewaste facility effluent does not require chlorination to protect public health" (see letter to Lee Fleming dated January 5, 1983) since there are no drinking water intakes or public beaches located downstream of this discharge. Further, only 5% of the feed to the facility is of domestic origin. Thus, low counts of fecal coliform bacteria should be present in the plant's effluent even without chlorination. Kinston's Northside WWTP is located 4.5 miles below the city's Peachtree Plant and 6 miles upstream from DuPont. Contentnea MSD is located on Contentnea Creek 2.5 miles above the mouth of the creek, which is 5 miles below DuPont. Presently, only Kinston Peachtree is not required to disinfect its wastewaters, based on an analysis of fecal coliform data supplied by its consultant, L. E. Wooten, and recent self - monitoring data. The other three plants are required to meet an effluent limit of 1000/100 ml. The most recent data available on a yearly basis for both the Kinston Peachtree and Northside Plants is that from 1981. From Table 1, the'average upstream fecal coliform value was 243/100 ml for that year while the average value downstream of the Peachtree Plant was 330/100 ml. This station corresponds to the upstream station for Northside. The average value of fecal coliform below the Northside Plant was 465/100 ml. From this data, it can be seen that the treatment plants exert little influence on the values of fecal coliform in the river. In fact, fecal coliform increases by over 25% between the stations above and below Northside, even though the plant was providing disinfection. • r Forrest Westall March 22, 1983 - page two - Recently, Kinston Peachtree's disinfection requirements were rescinded on the basis of the plant's past performance with respect to fecal coliform. At 7Q10 river flow, it was determined that an effluent concentration of 20,000/100 ml would protect the standard if the mix time was instantaneous. If the mix time was 6 hours, 50,000/100 ml would protect the standard. Modeling shows that these values would also protect the river below North - side and DuPont if applied to those discharges. According to E. L. bong, 5% of DuPont's wastewater is domestic. Assuming a typical undisinfected wastewater concentration of 400,000/100 ml, a final effluent concentration of 20,000/100 ml could be expected. Thus, it appears that non o± the discharges needs disinfection as long as these values can be maintained in the effluents. In summary, the fecal coliform levels in the Neuse near Kinston appears to be a function of upstream conditions. Treatment plants, as they are presently operated, exert little influence on these levels. If disinfection were tc be discontinued at those plants discharging directly to the river, little change in in -stream levels is expected, as long as 50,000/100 ml effluent limits are maintained. Let me know if you have any questions. RW:cs Attachment Table 1 Peachtree Northside 1981 Upstream Effluent Downstream = Upstream Effluent Downstream Jan 318 30000 438 438 <10 650 Feb 78 24000 139 114 <10 0 .145 Mar 280 10000 628 628 <10 1319 . Apr 250 5000 190 190 <10 260 May 138 2000 193 193 <10 175 June 150 3000 140 162 <10 225 July ND ND ND:: 203 <10 180 Aug 100 4600 150 181 <10 185 Sept 173 .100 240 5114 <10 318 Oct 700 3000 850 825 <10 1188 Average 243 9200 330 345 <10 465 JN�SEOST . 9 W Aft L �iT4C PROZ@'' UNITED STATES ENVIRONMENTAL PROTECTION AGENCY J A N 3 1983 REF: 4WM-FP REGION IV 345 COURTLAND STREET ATLANTA, GEORGIA 30365 Randy Williams Environmental Engineer NC Department of Natural Resources & Community Development Division of Environmental Management Post Office Box 27687 Raleigh, North Carolina 27611-7687 Dear Mr. Williams: Enclosed are five runs of EPA's DOM model of the Kinston/Neuse River system. Run 1 is a simulation of background conditions only with instream rates set as in the DEM allocation run. Run 2 is a simulation of background conditions with the same instream rates as in Run 1 except the reaeration rate was set at twice the temperature corrected deoxygeration rate. Conditions in Run 3 were set to be identical as in the DEM allocation run except the reaeration rate was determined as in Run 2. Conditions in Runs 4 and 5 were modified according to the State/EPA agreement concerning wasteload allocations. Reaeration rates were adjusted to equal twice the temperature corrected deoxygeration rates, and BOD inputs for dischargers were split into NBOD and CBOD. Background conditions were unchanged. The existing permit limitations for Dupont were used. After these changes were made, allocations for the Peachtree, Northside, and Contentnea Creek facilities were run. Please rail me at (404) 881-2156 if you have questions about the model outputs. Also, as we discussed on December 13, 1982 it may be fruitful to review the water quality data available for stations upstream of the northside discharge. Sincerely yours, ritz Wagener Environmental Engineer North Unit/Permits Section Facilities Performance Branch 6._°A_-_aovtx,L) c N 03 e AW,u2_ CcrK,�,.. 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