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HomeMy WebLinkAboutNC0003760_Permit (Issuance)_20060921NPDES DOCUMENT SCANNING COVER SHEET NPDES Permit: NC0003760 DuPont Kinston facility Document Type: /Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Engineering Alternatives (EAA) Correspondence Owner Name Change Technical Correction Instream Assessment (67b) Speculative Limits Environmental Assessment (EA) Document Date: September 21, 2006 This; document its printed on reuse paper - ignore any content on the reirertse slide 2TTP \14AT' Michael F. Easley 4F"'A Governor 7 NCDENR William G. Ross, Jr., Secretary r North Carolina Department of Environment and Natural Resources '< Alan W. Klimek, P.E., Director Division of Water Quality September 21, 2006 Mr. Tom Caudle, Vice President Unifi-Kinston LLC 4693 Hwy 11 North Kinston, North Carolina 28502-0800 Subject: Issuance of NPDES Permit NC0003760 Unifi-Kinston LLC Lenoir County Dear Mr. Caudle: Division personnel have reviewed and approved your application for renewal of the subject permit. Accordingly, we are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated May 9, 1994 (or as subsequently amended). This final permit includes no major changes from the draft permit sent to you on July 19, 2006. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699-6714). Unless such demand is made, this decision shall be final and binding. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, the Coastal Area Management Act or any other Federal or Local governmental permit that may be required. If you have any questions concerning this permit, please contact Sergei Chernikov at telephone number (919) 733-5083, extension 594. cc: NPDES Files Washington Regional Office / Surface Water Protection Aquatic Toxicology Unit Mr. Roosevelt Childress, EPA Region IV N. C. Division of Water Quality / NPDES Unit 1617 Mail Service Center, Raleigh, NC 27699-1617 Internet: h2o.enr.state.nc.us Sincerely, Phone: (919) 733-5083 fax: (919) 733-0719 DENR Customer Service Center: 1 800 623-7748 Permit No. NC0003760 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWA 1'ER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, UNIFI-KINSTON LLC is hereby authorized to discharge wastewater from a facility located at Unifi-Kinston LLC 4693 Hwy 11 North Lenoir County to receiving waters designated as Neuse River in the Neuse River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, and IV hereof. The permit shall become effective, November 1, 2006. This permit and the authorization to discharge shall expire at midnight on December 31, 2007. Signed this day September 21, 2006. Alan W. Klimek, P.E., Director Division of Water Quality By Authority of the Environmental Management Commission r Permit No. NC0003760' SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. UNIFI-KINSTON LLC is hereby authorized to: 1. Continue to operate the existing 3.6 MGD wastewater treatment facility located on NC Highway 11, northeast of Kinston, in Lenoir County; and consisting of: • influent catch basin with "Muffin Monster" solids grinder, • two (2) - one million gallon retention ponds; • one (1) - 3.6 million gallon aeration basin with two (2) 45HP aerators and thirteen (13) 25HP floating aerators, • two (2) - 90 ft. diameter secondary clarifiers, • two (2) sludge return lift stations, • chlorine contact basin (operation optional), • effluent flow measurement with recorder, • six (6) sand drying beds; and 2. Discharge from said treatment facility through an effluent diffuser into the Neuse River (Outfall 001), and discharge into an unnamed tributary to the Neuse River (Outfall 002) and into Beaverdam Branch (Outfall 003), all of which are Class C NSW waters in the Neuse River Basin, at the locations specified on the attached map. 3. Discharge stormwater into an unnamed tributary to Beaverdam Branch (Outfall 004), and discharge stormwater into an unnamed tributary to the Neuse River (Outfall 005), and discharge stormwater into an unnamed tributary to the Neuse River (Outfall 006), all of which are Class C NSW waters in the Neuse River Basin, at the locations specified on the attached map. •44r- VICINITY MAP N SCALE 1:24,000 (1" = 2000') Discharge Point Outfall 001 Lat. 35° 19' 29" Long. 77° 27' 56" Unifi Kinston, LLC NC0003760 Wastewater Treatment Plant Receiving Stream: Stream Classification: River Basin: Sub -Basin #: Neuse River C NSW Neuse 03-04-05 Ill r A Permit No. NC0003760 A.(1.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - OUTFALL 001 During the period beginning on the effective date of this permit and lasting until expiration, the Permittee shall be authorized to discharge treated process and sanitary wastewaters, remediated groundwater, treated steam condensate, treated landfill leachate, stormwater, and non -contact cooling water from Outfall 001 subject to the effluent limitations and monitoring requirements below and in Condition A.(2.) of this permit: EFFLUENT CHARACTERISTICS EFFLUENT LIMITATIONS MONITORING REQUIREMENTS Parameter Units Parameter Code Monthly Daily Average Maximum Measurement Frequency Sample Type Sample Location (1) Flow MGD 50050 3.6 Continuous Recording E Total Monthly Flow MG Monitor & Report Monthly Calculated E BOD, 5-day, 20°C lb/day 00310 193.8 497.3 Weekly Composite E Total Suspended Solids lb/day 00530 337.1 1,057.9 Weekly Composite E TKN mg/L 00625 Monitor & Report Weekly Composite E NO2-N + NO3-N mg/L 00630 Monitor & Report Weekly Composite E TN (2) mg/L 00600 Monitor & Report Weekly Composite E TN Load (3) Ib/mo Ib/yr Monitor & Report 35,193 Monthly Annually Calculated Calculated E E Total Phosphorus (4) mg/L 00655 2.0 (quarterly average) Weekly Composite E pH S.U. 00400 Shall be within the range of 6.0 to 9.0 standard units at all times Weekly Grab E Fecal Coliform (geometric mean) #/100 mL 31616 Weekly Grab E, U, D (5) Temperature °C 00o10 Weekly Grab E, U, D (5) Dissolved Oxygen mg/L 00300 See Footnote (6) Weekly Grab S1, U, D (5) NH3-N mg/L 00610 Monthly Composite E Chronic Toxicity P/F TGP3B See Footnote (7) Quarterly Composite E There shall be no discharge of floating solids or visible foam in other than trace amounts. Footnotes: 1) Sample locations: I - Influent, E - Effluent, S1 - Chlorine contact chamber or other approved location, U - Upstream, 100 yard above outfall, D - Downstream,1 mile below outfall. 2) For a given wastewater sample, TN = TKN + NO3-N + NO2-N, where TN is Total Nitrogen, TKN is Total Kjeldahl Nitrogen, and NO3-N and NO2-N are Nitrate and Nitrite Nitrogen, respectively. 3) TN Load is the mass quantity of TN discharged in a given period of time. See Special Condition A.(4.), Calculation of Total Nitrogen Loads. The annual TN Load limit shall become effective with the calendar year beginning on January 1, 2003. Compliance with the limit shall be determined in accordance with Special Condition A.(5.) of this permit, Annual Limits for Total Nitrogen. 4) The quarterly average for total phosphorus shall be the average of composite samples collected weekly during the calendar quarter Qanuary-March, April -June, July -September, October -December). 5) Stream samples shall be taken three times per week during the months of June, July, August and September, and once per week during the remaining months of the year. 6) The daily average dissolved oxygen effluent concentration shall not be less than 2.5 mg/L at the sampling point. 7) Chronic Toxicity (Ceriodaphnia) P/F at 1.9%; January, April, July, and October; see Condition A.(7.), Chronic Toxicity Permit Limit. Part I, Page 1 of 21 Permit No. NC0003760'� A.(2.) ADDITIONAL EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - Outfall 001 During the period beginning on the effective date of this permit and lasting until expiration, the Permittee shall be authorized to discharge treated process and sanitary wastewaters, remediated groundwater, and non -contact cooling water from Outfall 001 subject to the effluent limitations and monitoring requirements below and in Condition A.(1.) of this permit: PARAMETER EFFLUENT LIMITATIONS MONITORING REQUIREMENTS Monthly Average (Ibs/day) Daily Maximum (Ibs/day) Daily Maximum (ug/L) Measurement Frequency (2) Sample Type Sample Location (1) Bis(2-ethylhexyl) phthalate 0.868 2.352 Quarterly Grab E Di-n-butyl phthalate 0.228 0.481 Quarterly Grab E Methyl Chloride 0.725 1.602 Quarterly Grab E Acenaphthene 0.185 0.497 Annually Grab E Acenaphthylene 0.185 0.497 Annually Grab E Acrylonitrile 0.809 2.040 Annually Grab E Anthracene 0.185 0.497 Annually Grab E Benzene 0.312 1.147 Annually Grab E Carbon Tetrachloride 0.152 0.320 Annually Grab E Chlorobenzene 0.126 0.236 Annually Grab E Chloroethane 0.877 2.260 Annually Grab E Chloroform 0.177 0.388 Annually Grab E 2-Chlorophenol 0.261 0.826 Annually Grab E 1,2-Dichlorobenzene 0.649 1.374 Annually Grab E 1,3-Dichlorobenzene 0.261 0.371 Annually Grab E . 1,4-Dichlorobenzene 0.126 0.236 Annually Grab E 1,1-Dichloroethane 0.185 0.497 Annually Grab E 1,2-Dichloroethane 0.573 1.779 Annually Grab E 1,1-Dichloroethylene 0.135 0.211 Annually Grab E 1,2-trans-Dichloroethylene 0.177 0.455 Annually Grab E 2,4-Dichlorophenol 0.329 0.944 Annually Grab E 1,2-Dichloropropane 1.290 1.939 Annually Grab E 1,3-Dichloropropylene 0.245 0.371 Annually Grab E Diethyl phthalate 0.683 1.712 Annually Grab E 2,4-Dimethylphenol 0.152 0.304 Annually Grab E Dimethyl phthalate 0.160 0.396 Annually Grab E 4,6-Dinitro-o-cresol 0.658 2.336 Annually Grab E 2,4-Dinitrophenol 0.599 1.037 Annually Grab E 2,4-Dinitrotoluene 0.953 2.403 Annually Grab E 2,6-Dinitrotoluene 2.150 5.405 Annually Grab E Ethylbenzene 0.270 0.911 Annually Grab E Fluoranthene 0.211 0.573 Annually Grab E Fluorene 0.185 0.497 Annually Grab E Hexachlorobenzene 0.2097 Annually Grab E Hexachlorobutadiene 0.169 0.413 Annually Grab E Hexachloroethane 0.177 0.455 Annually Grab E Methylene Chloride 0.337 0.750 Annually Grab E Naphthalene 0.185 0.497 Annually Grab E Nitrobenzene 0.228 0.573 Annually Grab E 2-Nitrophenol 0.346 0.582 Annually Grab E 4-Nitrophenol 0.607 1.046 Annually Grab E Phenanthrene 0.185 0.497 Annually Grab E Phenol 0.126 0.219 Annually Grab E Pyrene 0.211 0.565 Annually Grab E Part I, Page 2 of 21 Permit No. NC0003760 PARAMETER EFFLUENT LIMITATIONS MONITORING REQUIREMENTS Monthly Average (Ibslday) Daily Maximum (Ibslday) Daily Maximum (ug/L) Measurement Frequency Sample Type Sample Location (1) Tetrachloroethylene 0.185 0.472 Annually Grab E Toluene 0.219 0.675 Annually Grab E Total Chromium 9.359 23.356 Annually Grab E Total Copper 362.1 Annually Grab E Total Cyanide 3.541 258.7 Annually Grab E Total Lead 2.698 5.818 Annually Grab E Total Nickel 14.250 33.558 Annually Grab E Total Zinc 8.853 22.007 Annually Grab E 1,2,4-Trichlorobenzene 0.573 1.180 Annually Grab E 1,1,1-Trichloroethane 0.177 0.455 Annually Grab E 1,1,2-Trichloroethane 0.177 0.455 Annually Grab E Trichloroethylene 0.177 0.455 Annually Grab E Vinyl Chloride 0.877 2.260 Annually Grab E Total PAHs (2) 8.44 (3) Annually Calculated E Benzo(a)anthracene 0.185 Annually Grab E 3,4-Benzofluoranthene 0.194 0.514 Annually Grab E Benzo(k)fluoranthene 0.185 Annually Grab E Benzo(a)pyrene 0.194 Annually Grab E . Chrysene Annually Grab E Dibenz(a,h)anthracene Annually Grab E Indeno(1,2,3-ed)pyrene Annually Grab E Footnotes: 1) Sample location: E - Effluent 2) In the event that the analysis for any of these parameters equals or exceeds its Practical Quantitation Limit, the monitoring frequency for that parameter shall immediately increase to once per quarter. When 12 consecutive quarterly samples using appropriate laboratory methods do not detect the parameter, the monitoring frequency for that parameter shall immediately return to once per year. Also see Footnote (3). 3) Total PAHs are comprised of Benzo(a)anthracene, Benzo(a)pyrene, 3,4-Benzofluoranthene, Benzo(k)fluoranthene, Chrysene, Dibenz (a,h) anthracene, and Indeno (1,2,3-ed) pyrene. The sum of concentrations of these parameters shall not exceed the stated Total PAH limit. In the event that the monitoring frequency for any of these parameters changes per Footnote (2), the change shall apply to all of the Total PAH parameters. Part I, Page 3 of 21 Permit No. NC0003760' A.(3.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - Outfall 002 During the period beginning on the effective date of this permit and lasting until expiration, the Permittee shall be authorized to discharge non -contact cooling water, steam condensate, and stormwater runoff from Outfall 002 subject to the following effluent limitations and monitoring requirements: EFFLUENT CHARACTERISTICS_ EFFLUENT LIMITATIONS MONITORING REQUIREMENTS Parameter Units Parameter Code Monthly Daily Average Maximum Measurement Frequency Sample Type Sample � Location") Flow MGD sooso Monthly Instantaneous E pH S.U. 0040o Shall be within the range of 6.0 to 9.0 standard units at all times Weekly Grab E Temperature °C wow See Footnote (2) Monthly Grab E Total Residual Chlorine ug/L 50060 17.0 (3) Monthly Grab E Total Cadmium ug/L 01027 2.0 Monthly Composite E Total Chromium ug/L 01034 50.0 Monthly Composite E Total Copper ug/L 01042 Monthly Composite E Total Lead ug/L own 25.0 Monthly Composite E Total Mercury ug/L 71900 0.012 Monthly Composite E Total Nickel ug/L 01067 88.0 Monthly Composite E Total Selenium ug/L 01147 5.0 Monthly Composite E Total Silver ug/L o1077 Monthly Composite E Total Zinc ug/L 01092 Monthly Composite E Total Nitrogen mg/L 00600 Quarterly Composite E Total Phosphorus mg/L 00655 2.0 (quarterly average) (4) Quarterly Composite E There shall be no discharge of floating solids or visible foam in other than trace amounts. There shall be no addition of chromium, zinc, or copper to the cooling water systems except as components of pre -approved biocidal compounds. See Condition A.(8.). Footnotes: 1) Sample location: E - Effluent. 2) The temperature of the effluent shall not cause an increase in the temperature of the receiving stream of more than 2.8 °C nor at any time cause the ambient water temperature to exceed 32 °C. 3) The effluent limitation for Total Residual Chlorine shall become effective January 1, 2004. 4) The quarterly average for total phosphorus shall be the average of composite samples collected during the calendar quarter (January -March, April -June, July -September, October -December). Part I, Page 4 of 21 Permit No. NC0003760 A.(4.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - Outfall 003 During the period beginning on the effective date of this permit and lasting until expiration, the Permittee shall be authorized to discharge non -contact cooling water, steam condensate, and stormwater from Outfall 003 subject to the following effluent limitations and monitoring requirements: EFFLUENT CHARACTERISTICS EFFLUENT LIMITATIONS MONITORING REQUIREMENTS Parameter Units Parameter Code Monthly Daily Average Maximum Measurement Frequency Sample Type Sample Location (1) Flow MGD sooso Monthly Instantaneous E pH S.U. 00400 Shall be within the range of 6.0 to 9.0 standard units at all times Weekly Grab E Temperature °C wow See Footnote (2) Monthly Grab E Total Residual Chlorine ug/L 50060 17.0 (3) Monthly Grab E Cadmium ug/L 01027 2.0 Monthly Composite E Chromium - ug/L o1034 Monthly Composite E Copper ug/L 01042 Monthly Composite E Lead ug/L oiosi 25.0 Monthly Composite E Mercury ug/L 71900 0.012 Monthly Composite E Nickel ug/L 01067 88.0 Monthly Composite E Selenium ug/L 01147 5.0 Monthly Composite E Silver ug/L Dion Monthly Composite E Zinc ug/L 01092 Monthly Composite E Total Nitrogen mg/L 00600 Quarterly Composite E Total Phosphorus mg/L 00655 2.0 (quarterly average) (4) Quarterly Composite E There shall be no discharge of floating solids or visible foam in other than trace amounts. There shall be no addition of chromium, zinc, or copper to the cooling water systems except as components of pre -approved biocidal compounds. See Condition A.(8.). Footnotes: 1) Sample location: E - Effluent. 2) The temperature of the effluent shall not cause an increase in the temperature of the receiving stream of more than 2.8 °C nor at any time cause the ambient water temperature to exceed 32 °C. 3) The effluent limitation for Total Residual Chlorine shall become effective January 1, 2004. 4) The quarterly average for total phosphorus shall be the average of composite samples collected during the calendar quarter Ganuary-March, April -June, July -September, October -December). Part I, Page 5 of 21 Permit No. NC0003760' A.(5.) CALCULATION OF TOTAL NITROGEN LOADS (a.) The Permittee shall calculate monthly and annual TN Loads as follows: (1.) Monthly TN Load (lb/mo) = TN x TMF x 8.34 where: (h) TN — the average Total Nitrogen concentration (mg/L) of the composite samples collected during the month TMF — the Total Monthly Flow of wastewater discharged during the month (MG/mo) 8.34 — conversion factor, from (mg/L x MG) to pounds (ii.) Annual TN Load (lb/yr) = Sum of the 12 Monthly TN Loads for the calendar year The Permittee shall report monthly Total Nitrogen results (mg/L and lb/mo) in the discharge monitoring report for that month and shall report each year's annual results (lb/yr) in the December report for that year. A.(6.) ANNUAL LIMITS FOR TOTAL NITROGEN (a.) Total Nitrogen (TN) allocations and TN Load limits for NPDES dischargers in the Neuse River basin are annual limits and are applied for the calendar year. (b.) For any given calendar year, the Permittee shall be in compliance with the annual TN Load limit in this Permit if: (i.) the Permittee's annual TN Load is less than or equal to said limit, or (ii.) the Permittee is a Co-Permittee Member of a compliance association. (c.) The TN Load limit in this Permit (if any) may be modified as the result of allowable changes in the Permittee's TN allocation. (i.) Allowable changes include those resulting from purchase of TN allocation from the Wetlands Restoration Fund; purchase, sale, trade, or lease of allocation between the Permittee and other dischargers; regionalization; and other transactions approved by the Division. (ii.) The Permittee may request a modification of the TN Load limit in this Permit to reflect allowable changes in its TN allocation. Upon receipt of timely and proper application, the Division will modify the permit as appropriate and in accordance with state and federal program requirements. (iii.) Changes in TN limits become effective on January 1 of the year following permit modification. The Division must receive application no later than August 31 for changes proposed for the following calendar year. (iv.) Application shall be sent to: NCDWQ / NPDES Unit Attn: Neuse River Basin Coordinator Mail Service Center Raleigh, NC 27699-1617 (d.) If the Permittee is a member and co-permittee of an approved compliance association, its TN discharge during that year is governed by that association's group NPDES permit and the TN limits therein. (i.) The Permittee shall be considered a Co-Permittee Member for any given calendar year in which it is identified as such in Appendix A of the association's group NPDES permit. Part I, Page 6 of 21 a ` Permit No. NC0003760 (ii.) Association roster(s) and members' TN allocations will be updated annually and in accordance with state and federal program requirements. (iii.) If the Permittee intends to join or leave a compliance association, the Division must be notified of the proposed action in accordance with the procedures defined in the association's NPDES permit. (A) Upon receipt of timely and proper notification, the Division will modify the permit as appropriate and in accordance with state and federal program requirements. (B) Membership changes in a compliance association become effective on January 1 of the year following modification of the association's permit. (e.) The TN monitoring and reporting requirements in this Permit remain in effect until expiration of this Permit and are not affected by the Permittee's membership in a compliance association. A.(7.) CHRONIC TOXICITY PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 1.9%. The permit holder shall perform at a minimum, quarterly monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The tests will be performed during the months of January, April, July, and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised - February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value. Additionally, DWQ Form AT-3 (original) is to be sent to the following address: Attention: North Carolina Division of Water Quality Environmental Sciences Branch 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Branch no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test Part I, Page 7 of 21 Permit No. NC0003760' • form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re- opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. A.(8.) BIOCIDES The Permittee shall not use any biocides in its cooling systems except those approved by the Division of Water Quality in conjunction with the permit application. The Permittee shall notify the Director in writing not later than ninety (90) days prior to planned use of any additional biocide which may be toxic to aquatic life, other than those previously reported to the Division. Such notification shall include submittal of a completed Biocide Worksheet Form 101 and a map locating the discharge point and receiving stream. A.(9.) INSTREAM MONITORING Instream monitoring requirements in this NPDES permit shall be provisionally waived so long as the Permittee remains a member of the Lower Neuse Basin Association and the Association continues to function as approved by the Division and the Environmental Management Commission. If the Permittee does not participate in the Association or if the Association ceases to function, the instream monitoring requirements in this permit become effective immediately; and the Division may reopen this permit by administrative letter to establish additional instream monitoring requirements it deems necessary to adequately characterize the effects of the discharges on water quality in the receiving stream. A. (10.) NON -DETECTION REPORTING AND DETERMINATION OF COMPLIANCE When pursuant to this permit a pollutant analysis is conducted using an approved analytical protocol with the appropriate minimum detection level and a result of "non -detectable" or "below quantitation limit" is obtained, the Permittee shall record that result as reported. For the purpose of determining compliance with a permit limit for the pollutant, the numerical value of that individual analytical result shall be zero. Part I, Page 8 of 21 Permit No. NC0003760 A.(11.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - Outfall 004 During the period beginning on the effective date of this permit and lasting until expiration, the Permittee shall be authorized to discharge stormwater from Outfall 004 subject to the following monitoring requirements. All analytical monitoring shall be performed during a representative storm event. Discharge Characteristics Units Measurement Frequency Sample Type Sample Location Benchmark Values Total rainfall inches Semi-annual - - - Oil & grease mg/L Semi-annual Grab SDO* 30 BOD5 mg/L Semi-annual Grab SDO 30 COD mg/L Semi-annual Grab SDO 120 Total suspended solids mg/L Semi-annual Grab SDO 100 Total nitrogen mg/L Semi-annual Grab SDO 30 Total phosphorus mg/L Semi-annual Grab SDO 2 pH Standard units Semi-annual Grab SDO 6 - 9 Copper ug/L Semi-annual Grab SDO 7.3 Lead ug/L Semi-annual Grab SDO 33.8 Silver ug/L Semi-annual Grab SDO 1.1 Zinc ug/L Semi-annual Grab SDO 67 *Stormwater discharge outfall Semi-annual monitoring means once in the months of April - June, and once in the months of September - November. The Permittee shall compare monitoring results to the benchmark values above. The benchmark values are not permit limits, but shall be used by the Permittee to trigger an investigation of the sources of any benchmark exceedances and an evaluation of the effectiveness of any site BMPs. The Permittee shall update the SPPP to document the exceedences, the investigation, the evaluation, and any resulting actions to address stormwater contamination. Part I, Page 9 of 21 Permit No. NC0003760 A.(12.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - Outfall 005 During the period beginning on the effective date of this permit and lasting until expiration, the Permittee shall be authorized to discharge stormwater from Outfall 005 subject to the following effluent limitations and monitoring requirements. All analytical monitoring shall be performed during a representative storm event. Discharge Characteristics Units Measurement Frequency Sample Type Sample Location Benchmark Values Total rainfall inches Semi-annual - - - Oil & grease mg/L Semi-annual Grab SDO* 30 BOD5 mg/L Semi-annual Grab SDO 30 COD mg/ L Semi-annual Grab SDO 120 Total suspended solids mg/L Semi-annual Grab SDO 100 Total nitrogen mg/L Semi-annual Grab SDO 30 Total phosphorus mg/L Semi-annual Grab SDO 2 pH Standard units Semi-annual Grab SDO 6 - 9 Copper ug/L Semi-annual Grab SDO 7.3 Lead ug/L Semi-annual Grab SDO 33.8 Silver ug/L Semi-annual Grab SDO 1.1 Zinc ug/L Semi-annual Grab SDO 67 * Stormwater discharge outfall Semi-annual monitoring means once in the months of April - June, and once in the months of September - November. The Permittee shall compare monitoring results to the benchmark values above. The benchmark values are not permit limits, but shall be used by the Permittee to trigger an investigation of the sources of any benchmark exceedances and an evaluation of the effectiveness of any site BMPs. The Permittee shall update the SPPP to document the exceedences, the investigation, the evaluation, and any resulting actions to address stormwater contamination. Part I, Page 10 of 21 e Permit No. NC0003760 A.(13.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - Outfall 006 During the period beginning on the effective date of this permit and lasting until expiration, the Permittee shall be authorized to discharge stormwater from Outfall 006 subject to the following effluent limitations and monitoring requirements. All analytical monitoring shall be performed during a representative storm event. Discharge Characteristics Units Measurement Frequency Sample Type Sample Location Benchmark Values Total rainfall inches Semi-annual - - - Oil & grease mg/L Semi-annual Grab SDO* 30 BOD5 mg/L Semi-annual Grab SDO 30 COD mg/L Semi-annual Grab SDO 120 Total suspended solids mg/L Semi-annual Grab SDO 100 Total nitrogen mg/L Semi-annual Grab SDO 30 Total phosphorus mg/L Semi-annual Grab SDO 2 pH Standard units Semi-annual Grab SDO 6 - 9 Copper ug/L Semi-annual Grab SDO 7.3 Lead ug/L Semi-annual Grab SDO 33.8 Silver ug/L Semi-annual Grab SDO 1.1 Zinc ug/L Semi-annual Grab SDO 67 1,1-biphenyl ug/L Semi-annual Grab SDO 2-methylphenol ug/L Semi-annual Grab SDO 4-methylphenol ug/L Semi-annual Grab SDO Dibenzofuran ug/L Semi-annual Grab SDO *Stormwater discharge outfall Semi-annual monitoring means once in the months of April - June, and once in the months of September - November. The Permittee shall compare monitoring results to the benchmark values above. The benchmark values are not permit limits, but shall be used by the Permittee to trigger an investigation of the sources of any benchmark exceedances and an evaluation of the effectiveness of any site BMPs. The Permittee shall update the SPPP to document the exceedences, the investigation, the evaluation, and any resulting actions to address stormwater contamination. Part I, Page 11 of 21 Permit No. NC00037,60 J. NEW A.(14.) QUALITATIVE STORMWATER MONITORING Qualitative monitoring requires a visual inspection of each stormwater outfall (Outfalls 004, 005, 006) regardless of representative outfall status and shall be performed as specified below. Qualitative monitoring is for the purpose of evaluating the effectiveness of the Stormwater Pollution Prevention Plan (SPPP) and assessing new sources of stormwater pollution. No analytical tests are required. The Permittee shall conduct qualitative monitoring during a stormwater discharge, but not necessarily during a stormwater discharge resulting from a representative storm event. In the event an atypical condition is noted at a stormwater discharge outfall, the Permittee shall document the suspected cause of the condition and any actions taken in response to the discovery. This documentation shall be maintained with the Stormwater Pollution Prevention Plan. All qualitative monitoring will be performed twice per year, once in the spring (April - June) and once in the fall (September - November). Qualitative Monitoring Requirements Discharge Characteristics , , Frequency, Monitoring., Location' Color Semi-annually SDO Odor Semi-annually SDO Clarity Semi-annually SDO Floating Solids Semi-annually SDO Suspended Solids Semi-annually SDO Foam Semi-annually SDO Oil Sheen Semi-annually SDO Erosion in the outfall vicinity Semi-annually SDO Sedimentation in the outfall vicinity Semi-annually SDO Trash or other obvious indicators of stormwater pollution Semi -Annually SDO Part I, Page 12 of 21 Permit No. NC0003760 A.(15.) STORMWATER POLLUTION PREVENTION PLAN The Permittee shall develop a Stormwater Pollution Prevention Plan, hereinafter referred to as the Plan. The Plan shall be considered public information. The Plan shall include, at a minimum, the following items: 1. Site Plan. The site plan shall provide a description of the physical facility and the potential pollutant sources that may be expected to contribute to contamination of stormwater discharges. The site plan shall contain the following: (a) A general location map (USGS quadrangle map or comparable map), showing the facility's location in relation to transportation routes and surface waters, the name of the receiving waters to which the stormwater outfalls discharge, or if the discharge is to a municipal separate storm sewer system, the name of the municipality, and the ultimate receiving waters, and accurate latitude and longitude of the points of discharge. (b) A narrative description of storage practices, loading and unloading activities, outdoor process areas, dust or particulate generating or control processes, and waste disposal practices. (c) A site map drawn to scale with the location of industrial activities (including storage of materials, disposal areas, process areas, and loading and unloading areas), site property boundaries, drainage structures, drainage area boundaries, total area for each outfall, activities occurring in each drainage area, building locations, existing BMPs, impervious surfaces, and the percentage of each drainage area that is impervious. For each outfall, a narrative description of the potential pollutants that could be expected to be present in the stormwater discharge. (d) A list of significant spills or leaks of pollutants that have occurred at the facility during the three previous years and any corrective actions taken to mitigate spill impacts. (e) Certification that the stormwater outfalls have been evaluated for the presence of non- stormwater discharges. The certification statement must be signed in accordance with the requirements found in Part III, Standard Conditions, Section B, Paragraph 3. 2. Stormwater Management Plan. The stormwater management plan shall contain a narrative description of the materials management practices employed which control or minimize the exposure of significant materials to stormwater, including structural and nonstructural measures. The stormwater management plan, at a minimum, shall incorporate the following: (a) Feasibility Study. A review of the technical and economic feasibility of changing the methods of operations and/ or storage practices to eliminate or reduce exposure of materials and processes to stormwater. Wherever practical, the Permittee shall prevent exposure of all storage areas, material handling operations, and manufacturing or fueling operations. In areas where elimination of exposure is not practical, the stormwater management plan shall document the feasibility of diverting the stormwater runoff away from areas of potential contamination. (b) Secondary Containment Schedule. A schedule to provide secondary containment for bulk storage of liquid materials, storage of Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) water priority chemicals, and storage of hazardous substances to prevent leaks and spills from contaminating stormwater runoff. Part I, Page 13 of 21 Permit No. NC0003760 If the secondary containment devices are connected directly to stormwater conveyance systems, the connection shall be controlled by manually activated valves or other similar devices (which shall be secured with a locking mechanism) and any stormwater that accumulates in the containment area shall be at a minimum visually observed for color, foam, outfall staining, visible sheens, and dry weather flow, prior to release of the accumulated stormwater. Accumulated stormwater shall be released if found to be uncontaminated by the material stored within the containment area. Records documenting the individual making the observation, the description of the accumulated stormwater, and the date and time of the release shall be kept for a period of five years. (c) BMP Summary. A narrative description shall be provided of Best Management Practices (BMPs) to be considered such as, but not limited to, oil and grease separation, debris control, vegetative filter strips, infiltration, and stormwater detention or retention, where necessary. The need for structural BMPs shall be based on the assessment of potential of sources to contribute significant quantities of pollutants to stormwater discharges and data collected through monitoring of stormwater discharges. 3. Spill Prevention and Response Plan. The Spill Prevention and Response Plan (SPRP) shall incorporate an assessment of potential pollutant sources based on a materials inventory of the facility. Facility personnel (or team) responsible for implementing the SPRP shall be identified. A responsible person shall be on -site at all times during facility operations that have the potential, to contaminate stormwater runoff through spills or exposure of materials associated with the facility operations. The SPRP must be site stormwater specific. Therefore, a SPCC plan may be a component of the SPRP, but may not be sufficient to completely address the stormwater aspects of the SPRP. The common elements of the SPCC with the SPRP may be incorporated by reference into the SPRP. 4. Preventative Maintenance and Good Housekeeping Program. A preventative maintenance program shall be developed and implemented. The program shall document schedules of inspections and maintenance activities of stormwater control systems, plant equipment, and plant systems. Inspection of material handling areas and regular cleaning schedules of these areas shall be incorporated into the program. 5. Employee Training. Training schedules shall be developed and training provided at a minimum on an annual basis on stormwater protection principles, proper spill response and cleanup procedures, and preventative maintenance activities for all personnel involved in any of the facility's operations that have the potential to contaminate stormwater runoff. Facility personnel (or team) responsible for implementing the training shall be identified. 6. Responsible Party. The Stormwater Pollution Prevention Plan shall identify the specific position(s) or person(s) responsible for the overall coordination, development, implementation, and revision to the Plan. Responsibilities for all components of the Plan shall be documented and position assignments provided. 7. Plan Amendment. The permittee shall amend the Plan whenever there is a change in design, construction, operation, or maintenance that has a significant effect on the potential for the discharge of pollutants to surface waters. The Stormwater Pollution Prevention Plan shall be reviewed and updated on an annual basis. The Director may notify the Permittee when the Plan does not meet one or more of the minimum requirements of the permit. Within 30 days of such notice, the Permittee shall submit a time Part I, Page 14 of 21 Permit No. NC0003760 schedule to the Director for modifying the Plan to meet minimum requirements. The Permittee shall provide certification in writing to the Director that the changes have been made. 8. Facility Inspection Program. The Permittee must inspect all stormwater systems on at least a quarterly schedule, once in the periods of January -March; April - June; July - September; and October - December. The inspection and any subsequent maintenance activities performed shall be documented, recording date and time of inspection, individual(s) making the inspection, and a narrative description of the facility's stormwater control systems, plant equipment, and plant systems. Records of these inspections shall be incorporated into the Stormwater Pollution Prevention Plan. 9. Implementation. The Permittee shall document all monitoring, measurements, inspections, maintenance activities, and training provided to employees, a log of the sampling data, and a record of actions taken to implement BMPs. Such documentation shaII be kept on -site for a period of five years and made available to the Director or his authorized representative immediately upon request. BOILERPLATE ADDITIONS TO THE WASTEWATER PERMIT (Sergei, we may already have these parts in your Standard Conditions, General Conditions, etc. wastewater boilerplate. I've included them here in case we don't.) PART III. A. COMPLIANCE AND LIABILITY 1. Compliance Schedule The permittee shall comply with Limitations and Controls specified for stormwater discharges in accordance with the following schedule: Existing Facilities: The Stormwater Pollution Prevention Plan shall be developed and implemented within 12 months of the effective date of the initial permit and updated thereafter on an annual basis. Secondary containment shall be accomplished within 12 months of the effective date of the initial permit issuance. 4. Civil and Criminal Liability Except as provided in Part III, Section C of this permit regarding bypassing of stormwater control facilities, nothing in this individual permit shall be construed to relieve the permittee from any responsibilities, liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3, 143-215.6A, 143-215.6B, 143-215.6C or Section 309 of the Federal Act, 33 USC 1319. Furthermore, the permittee is responsible for consequential damages, such as fish kills, even though the responsibility for effective compliance may be temporarily suspended. Part I, Page 15 of 21 Permit No. NC0003770 Part III. B. GENERAL CONDITIONS 3. Signatory Requirements (This section is specifically referenced in my stormwater pollution prevention plan write-up above, in New A.(15.) 1.(e). - either way, may I ask you to check the reference in A.(15.) to be sure it ties to your correct boilerplate section?) All applications, reports, or information submitted to the Director shall be signed and certified. a. All applications to be covered under this individual permit shall be signed as follows: (1) For a corporation: by a responsible corporate officer. For the purpose of this Section, a responsible corporate officer means: (a) a president, secretary, treasurer or vice president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the corporation, or (b) the manager of one or more manufacturing production or operating facilities employing more than 250 persons or having gross annual sales or expenditures exceeding 25 million (in second quarter 1980 dollars), if authority to sign documents has been assigned or delegated to the manager in accordance with corporate procedures. (2) For a partnership or sole proprietorship: by a general partner or the proprietor, respectively; or (3) For a municipality, state, federal, or other public agency: by either a principal executive officer or ranking elected official. b. All reports required by the individual permit and other information requested by the Director shall be signed by a person described above or by a duly authorized representative of that person. A person is a duly authorized representative only if: (1) The authorization is made in writing by a person described above; (2) The authorization specified either an individual or a position having responsibility for the overall operation of the regulated facility or activity, such as the position of plant manager, operator of a well or well field, superintendent, a position of equivalent responsibility, or an individual or position having overall responsibility for environmental matters for the company. (A duly authorized representative may thus be either a named individual or any individual occupying a named position.); and (3) The written authorization is submitted to the Director. c. Any person signing a document under paragraphs a. or b. of this section shall make the following certification: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Part I, Page 16 of 21 Permit No. NC0003760 III. C. OPERATION AND MAINTENANCE OF POLLUTION CONTROLS 3. Bypassing of Stormwater Control Facilities Bypass is prohibited and the Director may take enforcement action against a permittee for bypass unless: a. Bypass was unavoidable to prevent loss of life, personal injury or severe property damage; and b. There were no feasible alternatives to the bypass, such as the use of auxiliary control facilities, retention of stormwater or maintenance during normal periods of equipment downtime or dry weather. This condition is not satisfied if adequate backup controls should have been installed in the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal periods of equipment downtime or preventive maintenance; and c. The permittee submitted notices as required under, Part III, Section E of this permit. If the Director determines that it will meet the three conditions listed above, the Director may approve an anticipated bypass after considering its adverse effects. III.D. MONITORING AND RECORDS 1. Representative Sampling Samples collected and measurements taken, as required herein, shall be characteristic of the volume and nature of the permitted discharge. Analytical sampling shall be performed during a representative storm event. Samples shall be taken on a day and time that is characteristic of the discharge. All samples shall be taken before the discharge joins or is diluted by any other waste stream, body of water, or substance. Monitoring points as specified in this permit shall not be changed without notification to and approval of the Director. 5. Representative Outfall If a facility has multiple discharge locations with substantially identical stormwater discharges that are required to be sampled, the permittee may petition the Director for representative outfall status. If it is established that the stormwater discharges are substantially identical and the permittee is granted representative outfall status, then sampling requirements may be performed at a reduced number of outfalls. 6. Records Retention Visual monitoring shall be documented and records maintained at the facility along with the Stormwater Pollution Prevention Plan. Copies of analytical monitoring results shall also be maintained on -site. The permittee shall retain records of all monitoring information, including all calibration and maintenance records and all original strip chart recordings for continuous monitoring instrumentation, and copies of all reports required by this individual permit for a period of at least 5 years from the date of the sample, measurement, report or application. This period may be extended by request of the Director at any time. Part I, Page 17 of 21 Permit No. NC0003760 7. Inspection and Entry The permittee shall allow the Director, or an authorized representative (including an authorized contractor acting as a representative of the Director), or in the case of a facility which discharges through a municipal separate storm sewer system, an authorized representative of a municipal operator or the separate storm sewer system receiving the discharge, upon the presentation of credentials and other documents as may be required by law, to; a. Enter upon the permittee's premises where a regulated facility or activity is located or conducted, or where records must be kept under the conditions of this individual permit; b. Have access to and copy, at reasonable times, any records that must be kept under the conditions of this individual permit; c. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment), practices, or operations regulated or required under this individual permit; and d. Sample or monitor at reasonable times, for the purposes of assuring individual permit compliance or as otherwise authorized by the Clean Water Act, any substances or parameters at any location. III. E. REPORTING REQUIREMENTS 4. Non-Stormwater Discharges If the storm event monitored in accordance with this individual permit coincides with a non- stormwater discharge, the permittee shall separately monitor all parameters as required under the non-stormwater discharge permit and provide this information with the stormwater discharge monitoring report. VI. DEFINITIONS 3. Allowable Non-Stormwater Discharges Non-stormwater discharges which shall be allowed in the stormwater conveyance system are: (a) All other discharges that are authorized by a non-stormwater NPDES permit. (b) Uncontaminated groundwater, foundation drains, air -conditioner condensate without added chemicals, springs, discharges of uncontaminated potable water, waterline and fire hydrant flushings, water from footing drains, flows from riparian habitats and wetlands. (c) Discharges resulting from fire -fighting or fire -fighting training. 4. Best Management Practices (BMPs) Measures or practices used to reduce the amount of pollution entering surface waters. BMPs may take the form of a process, activity, or physical structure. Part I, Page 18 of 21 • Permit No. NC0003760 5. Bypass A bypass is the known diversion of stormwater from any portion of a stormwater control facility including the collection system, which is not a designed or established operating mode for the facility. 6. Bulk Storage of Liquid Products Liquid raw materials, manufactured products, waste materials or by-products with a single above ground storage container having a capacity of greater than 660 gallons or with multiple above ground storage containers located in close proximity to each other having a total combined storage capacity of greater than 1,320 gallons. 14. Municipal Separate Storm Sewer System A stormwater collection system within an incorporated area of local self-government such as a city or town. 17. Point Source Discharge of Stormwater Any discernible, confined and discrete conveyance including, but not specifically limited to, any pipe, ditch, channel, tunnel, conduit, well, or discrete fissure from which stormwater is or may be discharged to waters of the state. 18. Representative Storm Event A storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. For example, if it rains for 2 hours without producing any collectable discharge, and then stops, a sample may be collected if a rain producing a discharge begins again within the next 10 hours. 19. Representative Outfall Status When it is established that the discharge of stormwater runoff from a single outfall is representative of the discharges at multiple outfalls, the DWQ may grant representative outfall status. Representative outfall status allows the permittee to perform analytical monitoring at a reduced number of outfalls. 20. Rinse Water Discharge The discharge of rinse water from equipment cleaning areas associated with industrial activity. Rinse waters from vehicle and equipment cleaning areas are process wastewaters and do not include washwaters utilizing any type of detergent or cleaning agent. 21. Secondary Containment Spill containment for the contents of the single largest tank within the containment structure plus sufficient freeboard to allow for the 25-year, 24-hour storm event. 22. Section 313 Water Priority Chemical Part I, Page 19 of 21 Permit No. NC0003760 A chemical or chemical category which: a. Is listed in 40 CFR 372.65 pursuant to Section 313 of Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986, also titled the Emergency Planning and Community Right -to -Know Act of 1986; b. Is present at or above threshold levels at a facility subject to SARA title III, Section 313 reporting requirements; and c. That meet at least one of the following criteria: (1) Is listed in Appendix D of 40 CFR part 122 on either Table II (organic priority pollutants), Table III (certain metals, cyanides, and phenols) or Table IV (certain toxic pollutants and hazardous substances); (2) Is listed as a hazardous substance pursuant to section 311(b)(2)(A) of the CWA at 40 CFR 116.4; or (3) Is a pollutant for which EPA has published acute or chronic water quality criteria. 24. Significant Materials Includes, but is not limited to: raw materials; fuels; materials such as solvents, detergents, and plastic pellets; finished materials such as metallic products; raw materials used in food processing or production; hazardous substances designated under section 101(14) of CERCLA; any chemical the facility is required to report pursuant to section 313 of Title III of SARA; fertilizers; pesticides; and waste products such as ashes, slag and sludge that have the potential to be released with stormwater discharges. 25. Significant Spills Includes, but is not limited to: releases of oil or hazardous substances in excess of reportable quantities under section 311 of the Clean Water Act (Ref: 40 CFR 110.10 and CFR 117.21) or section 102 of CERCLA (Ref: 40 CFR 302.4). 26. Stormwater Runoff The flow of water which results from precipitation and which occurs immediately following rainfall or as a result of snowmelt. 27. Stormwater Associated with Industrial Activity The discharge from any point source which is used for collecting and conveying stormwater and which is directly related to manufacturing, processing or raw material storage areas at an industrial site. Facilities considered to be engaged in "industrial activities" include those activities defined in 40 CFR 122.26(b)(14). The term does not include discharges from facilities or activities excluded from the NPDES program. 28. Stormwater Pollution Prevention Plan Part I, Page 20 of 21 Permit No. NC0003760 A comprehensive site -specific plan which details measures and practices to reduce stormwater pollution and is based on an evaluation of the pollution potential of the site. 29. Ten Year Design Storm The maximum 24 hour precipitation event expected to be equaled or exceeded on the average once in ten years. Design storm information can be found in the State of North Carolina Erosion and Sediment Control Planning and Design Manual. 32. Toxic Pollutant Any pollutant listed as toxic under Section 307(a)(1) of the Clean Water Act. 34. Vehicle Maintenance Activity Vehicle rehabilitation, mechanical repairs, painting, fueling, lubrication, vehicle cleaning operations, or airport deicing operations. 35. Visible Sedimentation Solid particulate matter, both mineral and organic, that has been or is being transported by water, air, gravity, or ice from its site of origin which can be seen with the unaided eye. 36. 25-year, 24 hour storm event The maximum 24-hour precipitation event expected to be equaled or exceeded, on the average, once in 25 years. Part I, Page 21 of 21 A 67 I • NCDENR NORTH CAROLINA DPARTM Kr or ENVIRONMCNr AND Na RAL RESOURCES Fact Sheet - NPDES Permit Unifi Kinston, LLC NPDES No. NC0003760 FACILITY INFORMATION RECEIVING STREAM Facility Name: Permit Flow (MGD): Facility Class: Facility Status: Permit Status: County: Regional Office: Kinston Dacron® Plant 3.6 IV Biological Existing Existing/Major Modification Lenoir Washington USGS Topo Quad: F29SW (Grifton, NC) Receiving Streams: Subbasin: Index No.: Stream Class: 303(d) Listed: Use Support: Drainage Area (mi2): Summer 7Q10 (cfs) Winter 7Q10 (cfs): 30Q2 (cfs): Average Flow (cfs): IWC (%): Neuse River, etc. 030405 C NSW Y (TMDL completed) 2,552 283.1 291.6 1,514 1.9 SUMMARY Unifi submitted their request for modification of their permit on 12/01/2005. The modification required significant input from Stormwater Unit, which caused significant delay in processing the request. Comments from Stormwater Unit were received on 05/25/2006. PROPOSED CHANGES 1. Stormwater was added to Outfall 001 and Outfall 003 as a permitted discharge. 2. Steam Condensate was added to Outfall 001 as a permitted discharge. 3. Outfall 002 was relocated to a location downstream in order to incorporate the potential additional stormwater runoff over the C8&D and Ash Landfills New outfall coordinates are: Lat. 350 19' 26", Long. 770 08' 56" 4. Stormwater Outfalls 004 (Lat. 350 20' 09", Long. 770 28' 51"), 005 (Lat. 350 19' 59", Long. 770 28' 10"), and 006 (Lat. 350 19' 35", Long. 770 28' 18") were added to the permit. 5. Low -flow leachate from Old Landfill (SWMU3), Original Ash Landfill and New Ash Landfill was permitted to be treated at WWTP and subsequently discharged through Outfall 001. Total estimated flow from these sources is 0.15 gpm. Leachate Source and Description - Sample Location 9 The two inter -connected leachate collection areas, collectively identified as Sample Location 9, consists of the Boil Out Neutralization Chamber (SWMU 23) which is an in -ground concrete sump and chamber constructed from reinforced concrete. The sump is in close proximity to an earthen lined open ditch formerly used as a process wastewater discharge channel (SWMU 12). It is our understanding that the source of the leachate largely originates from a formerly utilized residue landfill and associated burning FACT SHEET - NPDES PERMIT E.I. DuPont de Nemours & Co., Inc. FINAL NPDES No. NC0003760 pits identified as SWMU 7 that is situated approximately 1200 ft due west of Sample Location 9. SWMU 7 is comprised of a series of four capped trenches, or pits, and an adjacent 1.5 acre capped landfill. SWMU 7 is currently listed in the Facility's RCRA Part B Permit Renewal Application which was most recently filed with the NCDENR Division of Waste Management on August 31, 2005. Some leachate may also be collected from SWMU 1, located approximately 1625 ft west of Sample Location 9, which consists of four or five capped glycol pits formerly operated on -Site; however, this potential source of leachate is believed to be a minor contributor, if at all, to the small amount of leachate collected at Sample Location 9. PROPOSED SCHEDULE FOR PERMIT ISSUANCE Draft Permit to Public Notice: 7 / 05 / 06 (est.) Permit Scheduled to Issue: 8/28/06 (est.) STATE CONTACT If you have any questions on any of the above information or on the attached permit, please contact Sergei Chernikov at (919) 733-5038, extension 594. REGIONAL OFFICE COMMENT: NAME: DATE: EPA COMMENT: Name: Date: -2- imap://sergei.chernikov%40dwq.denr.ncmail.net@cros.ncmail.net:143/... Subject: Draft Permit Review From: John Giorgino <john.giorgino@ncmail.net> Date: Wed, 23 Aug 2006 13:35:22 -0400 To: sergei chernikov <sergei.chernikov@ncmail.net> Hi Sergei, I have reviewed NC0003760 Unifi-Kinston LLC, and have no comments. Thanks for forwarding it. -John John Giorgino Environmental Biologist North Carolina Division of Water Quality Environmental Sciences Section Aquatic Toxicology Unit Mailing Address: 1621 MSC Raleigh, NC 27699-1621 Office: 919 733-2136 Fax: 919 733-9959 1 of 1 9/11/2006 3:49 PM J�\StiD ST,��S Ark YW REGION 4 ��% Q ATLANTA FEDERAL CENTER 02 61 FORSYTH STREET 19.4C prt01 ATLANTA, GEORGIA 30303-8960 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY AUG 0 7 axe Sergei Chernikov, Ph.D North Carolina Department of Environment and Natural Resources Division of Water Quality NPDES Unit 1617 Mail Service Center Raleigh, NC 27699-1617 SUBJ: Draft NPDES Permit Modification Unifi-Kinston LLC Permit No. NC0003760 Dear Dr. Chernikov: In accordance with the EPA/NCDENR MOA, we have completed review of the draft permit modification referenced above and have no comments. We request that we be afforded an additional review opportunity only if significant changes are made to the draft permit modification prior to issuance or if significant comments objecting to the permit modification are received. Otherwise, please send us one copy of the final modified permit when issued. Sincerely, Marshall Hyatt, Environmental Scientist Permits, Grants, and Technical Assistance Branch Water Management Division E C L5 AUG 9 2006 DENR - WATER DUALITY POINT SOURCE BRANCH Internet Address (URL) • http://www.epa.gov Recycled/Recyclable • Printed with Vegetable O1 Based Inks on Recycled Paper (Minimum 30% Postconsumer) imap://sergei.chemikov%40dwq. denr.ncmail.net@cros.ncmail.net:143/... Subject: 37006 Response to Request for Additional Information From: "Vincent, Jay" <jvincent@craworld.com> Date: Thu, 27 Jul 2006 13:33:58 -0400 To: "Sergei Chernikov" <sergei.chernikov@ncmail.net> CC: "Filing" <Filing@craworld.com>, "Horn, Shawn" <shorn@craworld.com>, "Proctor, James - Kinston" <ProctoJR@unifi-inc.com>, <chris.petry@invista.com> Sergei...here is the response to the remaining question (#2) presented in your email dated June 26, 2006. A brief description for the source of the leachate that is being collected at the two leachate collection areas, designated as Sample location 9, and which is described in our letter dated November 9, 2005 is provided as follows. Leachate Source and Description - Sample Location 9 The two inter -connected leachate collection areas, collectively identified as Sample Location 9, consists of the Boil Out Neutralization Chamber (SWMU 23) which is an in -ground concrete sump and chamber constructed from reinforced concrete. The sump is in close proximity to an earthen lined open ditch formerly used as a process wastewater discharge channel (SWMU 12). It is our understanding that the source of the leachate largely originates from a formerly utilized residue landfill and associated buming pits identified as SWMU 7 that is situated approximately 1200 ft due west of Sample Location 9. SWMU 7 is comprised of a series of four capped trenches, or pits, and an adjacent 1.5 acre capped landfill. SWMU 7 is currently listed in the Facility's RCRA Part B Permit Renewal Application which was most recently filed with the NCDENR Division of Waste Management on August 31, 2005. Some leachate may also be collected from SWMU 1, located approximately 1625 ft west of Sample Location 9, which consists of four or five capped glycol pits formerly operated on -Site; however, this potential source of leachate is believed to be a minor contributor, if at all, to the small amount of leachate collected at Sample Location 9. Please feel free to call if you have any additional questions. Best Regards, Jay T. Vincent Conestoga Rovers & Associates 4215-1 Stuart Andrew Blvd. Charlotte, NC 28217 (704) 676-0502 (Office) (704) 676-0704 (Fax) (704) 650-5733 (Mobile) Email: jvincent(,cr aworld.com Web: www.craworld.com An Equal Employment Opportunity Employer 1 of 1 7/27/2006 1:37 PM NORTH CAROLINA WAYNE COUNTY. --Tnc;;vith— the Clerk of Court. Dila to Storms facilities, we will not hone AFFIDAVIT OF PUBLICATION Before the undersigned, a Notary Public of said County and State, duly commissioned, qualified, and authorized by law to administer oaths, personally appeared • Teresa Bozeman who being first duly sworn, deposes and says: that he (she) is Legal Clerk (Publisher, or other officer or employee authorized to make affidavit) of WAYNE PRINTING COMPANY, INC., engaged in the publication of a newspaper known as GOLDSBORO NEWS-ARGUS, published, issued, and entered as second class mail in the city of Goldsboro in said County and State; that he (she) is authorized to make this affidavit and sworn statement; that the notice or other legal advertisement, a true copy of which is attached hereto, was published in GOLDSBORO NEWS-ARGUS on the following dates: July 24, 2006 and that the said newspaper in which such notice, paper, document, or Iegal advertisement was published was, at the time of each, and every such publication, a newspaper meeting all of the requirements and qualifications of Section 1-597 of the General Statutes of North Carolina and was a qualified newspaper within the meaning of Section 1-597 of the General Statutes of North Carolina. This 29 day of August i0. (Signature of person m Sworn to and subscribed before me, this 3t My Commission expires: Notary Public 10 q 10 davit) 29th 06 20 day of 20 06. :stori K' CLIPPING OF LEGAL ADVERTISEMENT ATTACHED HERE .UBLIC NOTECE •,.\ ,- ,. ST';.PATE OF-NORTHCAROVA':' -TwIRONMEtmLtir� �:;.: t •• : MANAGEMENT f ,'.; , • ,•COMMIssrohU[iPDES UNIT • ' .1817 MAIL Aetna canal 'RALEIGH, NC 899-1817.: (cacti oRtinagmir,r),Tor,,,:- rreCvneW .Ew wtheaRbasis�AfihaorPRngMJhosaff 'NI; 14321, eubrc (aw 92-5OO and other Iawtri( xdardsrarrd regulatiaaa,tho' North-Caroir'na' Environmental . Management Commtssion?...... • ; to issue a Nattonai'toiild=,, - iacharge. Elimination SW. taro (NPDES) wastewater Pm= Iistede etowpermft to•the'person(s) from ` effective:dfi?days e ubitsb date %notice: P ' tin, ccfp�eatsregaldfag the proposed permit vwiil beat= c d..lm :logs after.th8 rifs,iv1s oboe, lit cornmeveed irk% a the id dafa,re:conseied to thO Rna4 deterlirl a r e:;, r9arding they ' ,proposed:pe it« s;Dt . r jo(;the C vfplon of�Wa e a uaua tlaneardetde to IIrol. ' . 1 perPAlmit oul8 Divpta'iore n ee.,' ce(ve prop frcant,degree' l .Cpples;of the drpiiiiiic aftpetiriitand other'supporirng informal bn'on fIfaoosed.io determine cgpdi. tions present hi tie draft peinit{ a►e available upon request aiW payment of the costs of rpp ruesls l o ,. the xx� :addressroQuality at 'Pofnt=Sbit rc�� n h ati(9 733'5Q 3t e ' x;pgston:ro cap ttl IneWtroe� �4(PDES. pe - mIt:Hunt . e(l(linach'ed cdis mmmayiur �:al�, aorsor� . o(! Water R'uatity at St21N,:Balls bYPIS.tteek tifilktiq 27604 nilatbetileen : ' «is.aa&oriIA Cr -;bss .'-ce. , r ngermmCa00376pMrat wa_ ter.to tht�e- e.... Nertee'tiiver; (:the permfb is being jm , , ed to in- clude ;the; discharge of sto waterand tow -flow lands leachate. This discharge may • affect;fcsture discharges 'in this portion of the river basin. Legal d828', July 24, 2006 • imap://sergei.chernikov%40dwq.denr.ncmail.net@cros.ncmail.net:143/... Subject: 37006 Information Request - Lat/Long From: "Vincent, Jay" <jvincent@craworld.com> Date: Fri, 30 Jun 2006 17:38:19 -0400 To: "Sergei Chernikov" <sergei.chernikov@ncmail.net> Sergei...here are the lat/long coordinates for the proposed relocation of Outfall 2: 35° 19.266' N 077°8.861'W I will get back with you shortly regarding the other question as soon as I can get the requested information together. Thanks, J Jay T. Vincent Project Manager Conestoga Rovers & Associates 4215-1 Stuart Andrew Blvd. Charlotte, NC 28217 (704) 676-0502 (Office) (704) 676-0704 (Fax) (704) 650-5733 (Mobile) Email: jvincent@acraworld.com Web: www.craworld.com An Equal Employment Opportunity Employer 1 of 1 7/3/2006 8:50 AM Una permitiacrolein issues Subject: Unifi permit/acrolein issues From: Ed Warren Jr <Ed.Warren-jr@ncmail.net> Date: Thu, 02 Feb 2006 16:09:12 -0500 To: Gil Vinzani <Gil.Vinzani@ncmail.net> Reference the Fact Sheet we were discussing on the phone. Though I could not find it while we were on the phone, I had previously read on page 1, last paragraph, the reference to "In 1999, DuPont modified one of its production lines did not require modifications to the permit," and had inferred that this statement was in reference to the new production line that used acrolein and that they notified us of the change. (on the phone with you, I paraphrased this as saying I though there was some reference to acrolein in the fact sheet, evidently because I was surmising from this statement that we would have known what the process chemicals were). If they notified us of the acrolein line and it was an accurate representation of what they were doing, then our fact sheet statement, "that the process change did not require modifications to the permit," indicates we do not need to consider the issue I brought up about would we have increased monitoring and other parameters analyzed for. 1 of 1 2/2/2006 4:51 PM NCDENR DIVISION OF WATER QUALITY WASHINGTON REGIONAL OFFICE WASHINGTON, N.C. 27889 Phone: 252-946-6481 FAX: 252-946-9215 v:azar),To: 4:1 FAX NO. -733- o?/ FROM: (,J)4grfe,._, DATE: NO. OF PAGES (INCLUDING COVER): 1 J COMMENTS: �� ` — Loti6e 0AS. nzerf,7),„) aitt,aS' fet.s.-6;01 -Ixre4.*G10‘14) /7/11. 943 Washington Square Mali, Washington, NC 27889 NorthCaro ina 77aturally I0 'd ZZ:9I 90, Z clad STZ6-9b6-ZSZ: xed 0ddf/OP10 • uiviri, isms Kinston, L1 C P. O. Box 800 Highway 11 North NC 28502-0800 RECEIVEEJ JAN C / 2006 DWQ.WARO Mr. Al Hodge Regional Director DWQ State of North Carolina Dept of Enviromment and Natural Resources Dear Mr. Hodge, James Proctor Environrocntai Specialist Unifi Kinston, LLC Phone: (252) 522-6443 Kinston, Fax: (252) 522-6236 Cell: (252) 883-9220 Pager. (877)-515-8660 E-mail: proctoJR©unifi.com January 27, 2006 SUBJECT: Notification! Requirements; NPDES Permit NC0003760 This purpose of this letter is follow up to the phone can between you and Sergio Macieisa 1-27-06, and to comply with the requirements of part 3 section C of the NPDES permit # NC0003760. Unifi has reason to believe that an activity occurred which resulted in the discharge of acrolein at a concentration ccceeding 200 ug/1. Testing for the OCPSF was completed on an effluent sample from outfall 001 collected on December 21,2005. Environment 1 Inc. ran the scans needed for the 4 compounds to be reported. Environment 1 Inc. ran all compounds on the sett and reported all compounds. Acrolein had a detection of 273 ug/1. Test results from 2002,2003,and early 2005 indicated acrolein concentrations below the laboratory detection limit at 100 ug/l. Please note that there have been no violations ions of the effluent limitation for chronic toxicity. Unifi has =eluded that the source is DuPont's 3G2 process that operates on the Unifi Kinston site as a tenant that existed prior to Unifi Kinstoa's acquisition of the site in September 2004. The 3G2 process began operation in May of 2000. Unifi has been unable to find doc unemation indicating that DuPont notified the DWQ about the new manufactining process. DuPont provided Unif with a copy of a report "BIOLOGICAL TREATABILITX STUDY TO ASSESS TIE IMPACTS OF TREATMENT OF N-125 (3GT) WASTEWATER IN KINSTON'S WASTEWATER TREATMENT PLANT', DuPont Engineering March 27,1998. A copy of the report is attached to this letter. DuPont intends to expand the 3GT manufacturing facilities. Unifi is investigating the potential impact to the WWI? operations. Unifi requests assistance from DWQ to determine the requirements to update our current NPDES peanut for the effluent of the 3C2 process and the future expansion plans for 3G3. If 1 can be of airy more assistance on this subject I can be contacted at 252-522-6443 Sincerely, James Proctor 4//ge STZ6-9b6-ZSZ: XeJ Mdf1i0M0 '3AN.23'2006 13:18 t0803 P.002 CL: fpI /T 4 :4:y( DUPONT ENGINEERING EnvIrunmesrai as rrec ss Darcz), March 27, 1998 to 'ro: ' CATRY BABOWTCZ- N2545-1 BOB JENKINS - N8545-2 RON NORRIS - N8545-3 RON WINK ER - N5410 FROM; BOB KISSELL - N5436A -.� WAVERLY SMITH - N5428 C: Jerry Baik y-DAC-Kinston Mike Cr ei1-ENGR-charlotnc Mark Haase-ENGR-N5438 Cad King I" .N EN2/333 Ian Kneib-DAC-Kinston Marge Ventura-ENGR-Olaagow CIS, BG368, W&WM BIOLOGICAL TRI"ATABILITY STUDY TO ASSESS THE IMPACTS OF TREATMiENT OF N-125 WASTEWATER IN KINSTON'S WASTEWATER TREATMENT PLANT A biological wearability study was conducted by Engineering at the Glasgow Wastewater Lab to assess the potential impacts of treating wastes from the N125 process in Kinston's existing wastewater ncasnievt system. Pilot runs for the N125 process were conducted at Kinston, and generated wastes anticipated to be typical of full-scale operations. Representative samples of these wastes were collected for use w conducting this treatability study_ This material was fed to test units in conjunction with samples of the current influent to Kinston's wastewater treatment plant The results of the mcatability study showed that a microorganism population taken frcno the Aston site's wastewater treatment plant was able to treat wastes from N125 pilot runs in combination with other site wastewater with )3o observed adverse effects under all conditions tested. Nearly identical resulta ware obtained for COD and BOD removal in the control unit (Unit 1), which received t' feed consisting aoiely of tate wastewater treatment plant influent, and the two test units (Units 2 and 3), which received site wastewater with varying amounts of wastewater from N125 pilot Hans added, COD and BOD MnayaiAPROIcd big t run Unit 3 during pbase.2 o(t sttudy when the N125 wastewater was added at twice the pxvjected els, and in Units 2 and-3 in phase 3 when acrolein and alkyl alcohol were added in twcxvasing amounts. No difference in total phosphorus removal was observed between the control unit and test units, though no signfflcRnt removal occurnxl in any of the units. Feed and effluent TKN and nitrate concentrations indicate significant nitrification occurred in each of the units throughout the study, with the exception of *Period of apparent ixtbiition in Unit 1. Biomass production autos appeared to be minimal in all of the mks. Grim the relatively short duration of the study, no attempt to determine yield coefficients was £0 'd ZZ:9t 90, Z cl ad SRZ6-9b6-ZSz:XeJ o�dm�oma 'JAN.23'2006 13:19 t0803 P.003 . =adc. SLasdgo votnrxae index osnd x000 eettLing velocity dou.a indicwu.Q ham Lac scitlsas *C3 of • fiat the biosobOds in the teat units did not differ significantly from chose of the control unit biosolids.' Effluent samples collected from each of the test units during phases 1 and 2 of the study were tested for • acme find chronic toxicity to CeriodapIuiiadubia. The samples were diluted to several concentrations using moderately hard reconstituted water for the testing. Them were no effects observed for arty of the unit effluents at even the 100% effluent concentration, indicating no acute or chronic toxicity to the test species. Overall„ the study proceeded well with very positive results. Indications are that the N125 wastes can be treated in the site's wastewater trea :neat system without impacting the facility's ability to treat other sire wastes. Results from phase 2 of the study suggest that this is true at up to twice the projected flows of • N125 wastewater. Phase 3 of the study sbowed no major short terra impacts of introduction of acrr leis and allyl alcohol, compounds identified as being of potential concern, at concentuations much higher than would be expected in Cbe site's wastewater treatment plant influent. The two compounds were biodegraded or otherwise transformed to below detection levels in the test unit effluent scrams. The full report descr iibing the methodology, results and conclusions is attached. LWS A1ch Ku ep-doc b0 'd £Z:91 90. Z sad SRZ6-9b6-ZSZ: xe3 O?JUP1/01110 Mitlarateniliatitl .K. -. f '3AN.23'2006 13:19 #0803 P-004 BIOLOGICAL TREATABXLfTY STUDY TO ASSESS TBE IMPACTS OF TREATMENT OF N-125 WASTEWATER IN KINSTON'S WASTEWATER TREATMENT PLANT don The purpose of this treatabiliry study was to assess the potential impacts of treating wastes fxona the N125 process in Kinston's existing wastewater treatment system. Pilot runs for the N125 prnccss weft conducted et Kinston, and generated wastes anticipated ro be typical of full .scale operations. Representative samples of these wastes were collected for use in conducting this wearability study. This material was fed to test units in conjunction with samples of the current influent to KIDStpn s wastewater treatment plant. - The following key perforcmmu a criteria were monitored during the study to allow the assessment of impacts to be made: the ability to maintain high COD/BOD removal - effluent concentrations of constituents of concern - system response to batch/cyclic exposure to the test streams - system capabilities for handling slugs of above -average concentrations of constituents of concern - phosphorus removal end effluent concentrations biomass production rates and the settleability of the biosolids -effluent toxicity. Metkoctsisei The original scope of work for the study is included as Attachment 1; minor revisions west made to this plan during the course of the study, After receipt at the WWI,, sampling, andcharacterization, a sample of biomass forts IGaston's wwtp was divided among three 7.SL Eckeofelder continuous flow units. During au initial stabilization period, the prehusinary test units were fed Kinston wwtp influent. After this stabilization period, the biomass from the three writs was combined and then redistributed. The vomits wute agitated and aerated with supplied air, and maintaincui at an average tetuperatwre of-20°C. A combination of sludge age (--30 days) and food -to -microorganism (F/M) ratio (0.07-0.15) was used to control the mixed liquor volatile suspended solids (MLVSS) concentrations in the units through solids wasting as needed. The following gives the approximate flow and COD content of the Kinston wwtp influent (see attached) and N125 waste states; Flow COD err 'Gaston influent 1000 -380 ' -' —N125 -wastes 150 -? These flaws were scaled down to the test unit volumes to give hydraulic reteztrion times (HR'r) and compositions comparable to those projected for the full scale plant. Feed recipes for the control and two test units were generated accordingly (see Attachment i for details). Feed *fixtures were made up daily SO'd 9O, Z aaj STZ6-976-ZSZ: X2J 08d(1i01'la -JAN.23'2006 13:19 00803 P.005 utilizing samples of wwtp influent and N-125 waste supplied by the site. Each of the waste samples used by me tan were sampled and analyzed for a number of pacatneters for characterization pYuposes. Results of this characterization work are summarized in Attachment 2_ Throughout the test, the feed to the control unit (Unit 1) remained unmodified site wwtp influent. The feeds to the two test units (Unit 2 and Unit 3) were varied during the various phases of the testing to allow'information to be collected for different potential impacts. During phase 1 (9/5 - 10/12197), the test units were fed mixtures of wwtp influent and N-125 wastewater (vacuum jet barwe)T overflow wager). Addition of the jet hotwell water to Unit 2 was ramped to the projected levels over the course of a week, while it was started immediately at this level in Unit 3. About midway through phase I, fire jet hotwell water feed, to Unit 3 was cycled off fora week and then back on again- Deering phase 2 (10/13 - 10/2S/97), the. feeds to Units 1 and 2 remained the same as in phase I while the rurnount of jet hvtwell water fed to Unit 3 was doubled. In phase 3 (10/29- 11/2 7), the jet botwell water fed to Unit 3 was xetux i od to projected Levels avd iocrozsing amounts (1-10 ppm) of e,crolejn and afyl alcohol were added to the feeds to Units 2 and 3, zespectiveIy. Finally, during phase 4 (I 1/23 12/4/97) the addition of ac roleia and ally! alcohol was discontinued and the test units received projected levels of jet botwell water slung with wwtp influent. Saxxi$es of the influent to each of the reactors, the effluent from each of the reactors„ and from the reactors themselves were taken routinely doing the swtdy. The samples were analyzed for a number of different parameters. The complete set of results hum the sampling and analysts inn, as well as visual observations of the units, is included as Attachment 3. Pictures of the overall test set-up, the control unit, and the two best units are given as Figures 1, 2, and 3, respectively. tS*udy Rermatis Gomel OvetalI, the testing proceeded relatively smoothly. No upsets occurred during the test period, and no operational problems were experienced. The slight changes in performance observed were largely the result of variability in the site.'a wwtp influent. No foaming or other problems were noted in the daily visual observations of the units. MLVSS levels (Figures 4, 5, and 6) were maintained in the range of 1000-2000 mg/L. In each of the reamers throughout the study, and were typically between 1000 and 1500 naglt.. Initially, solids were washed in an effort to achieve a sludge age of 3D days. With relatively low biomass production in each of the unite. MLVSS levels dropped to —1000 mg/L and wasting was discontinued. The F/M ratio (based on soluble COD and 143,VSS, fgJday COD)/rg MLVSSJ) for each unit is shown in Figure 7. These values varied over the course of the study, largely as the result of changes in Kinston wwtp influent drum samples. The F/M ratio averaged 0.11 in Units 1, 2. and 3. Specific oxygen ups rate (SOUR) data for the test units is given in Figure 8. The SOUK, or resphation rate, is the amount of oxygen used per unit mass of ni cnnorganisms as they degrade conatimerts in the wad stream. It provides a measure of biological activity. Values for the units ranged from Ic s than 1 mg OA Ml.VSS/hr in Units 2 and 3 near the start of the study to 16 tug Os/g MLVSs/l,r in Unit 3 at the start of phase 2. With the exception of Unit 2 in phase 3, no significant differences in SOUR were observed betweea, the ,control and test units. During phase 3, Unit 2 received iiocreasiug arodunis of acrolein added to its feed strcrun and bad an average SOUR somewhat higher than the other two units. The SOUR averaged 9.80 mg Oz/g MLVSS/hr in Unit 2 during phase 3 compared to 4.89 and 6.83 mg O,/g IVIi.VS5/hr in Units 1 and 3, respectively. 2 KinsRep.dvc 3127/98 90'd £Z=91 90, Z pad StZ6-9V6-ZSZ: red OddP1/0FI0 JAN,23'2006 13:19 #0803 P.006 I Each of the units was operared at a acrpoint of 7.3 utroughout the study, Despite the fog; ow me average pH of the feed to each of the units was -7.1, a small amount of acid addition was required to maintaib the sctpoint. Units 1 and 2 required axe average of 4.3 ttml, and Unit 3 an average of 3.3 mi of 1 N sulfuric acid per liter of influent flow. - COD and DOD Removal Soluble COD levels in the feed and effluent of each of the reactors axe given in Figures 9, 10, and 1.1. Despite the variable nature of the COD content of the feed streams. which were generally higher at the start of a new dnnn of wwtp influent and decreased over the time period die drum was in service, the efflueet COI) levels were consistcut!y low in each of the test units. In Unit 1, the COD of tie feed averaged 348 rng/t. over the course of the study; fn Units 2 and 3 it was slightly lower at 323 and 327 nog/L, respectively. This deflects the fact that the jet hotwelt water, had a low= COD content than the wwtp influent. Effluent COD averaged 20 mg/L for Unit 1., and 17 mg/L in both Unit 2 and Unit 3. Soluble COD removal efficiencies for the three units are shown in Figure 12. For all units, > 85% COD removal was observed throughout the test, with values typically 90% or greater. COD removal averaged .93% in Unoit 1 and 94% in Units 2 and 3. These values are consistent with the average COD removal • efficiency of 93% observed in the site's wwtp during approximately the same time period (g/1/97 - 12J31/97). Trends in the data for soluble 5-day biochemical oxygen demand (BOW were similar to that for COD. Figures 13, 14, and 15 show feed and effluent HOD, levels for the test units, and Figure 16 shows removal efficiencies. The effluent BODY levels for all three units were consistently very Low throughout the test, averaging less than 4 mg& for each. Over the coarse of the study, soluble BODY, was removed with an average of 97.7% efficiency in Unit 1., 97,8% efficiency in Unit 2, and. 97.9% in Unit 3.. Note; M deacribed above, the values for COD and BOD5 include only the soluble portion of these parameters. Susded solids present typically result in sorxze amount of COD and BODs. and as such would add to the values reported. Phosivinrus Resnoval . To Blow an assessment of the impacts on the ability of the Kinston biomasrs to rourove phosphorus, total phosphorus ioQ th.e feed and effluent of each unit was monitored. The results are presented in Figures 17, 18, and 19. The average effluent concentration was slightly below that of the fend for each unit, though no statistically aigniifrcent (at 95% confidence) phosphorus removal. occurred. On occasion, the effluent concentration exceeded that of the feed for each 'unit. 'These differences are likely within the accuracy of the sampling and analytic techniques, however. For the Kinston wwtp, bowever, the influent and effluent phosphorus data for 8/1/97 - 12/31/97 do show statistically significant removal taking plugs. The average influent and efficient phoaphonis concentrations for the she's treatment system were 2.35 hr►d O.g6 w L, respectively. This suggests drat the phosphorus removal mechanism experienced at the pla a was loot, captured by the tteatability study set-up and/or copditious. It should be noted that the total mid soluble phosphorus content of t1=c influent samples utilized in the study were 4.35 and 3.97 eng/L. both substantially higher thao the average plant influent value of 2.35 Rom.. 3 KiusRep.doc 3l2?/98....-...... LO d bZ 9T 90, Z qaj STZ6-9176-ZSZ XeJ 06df/0mQ JA4.23'2006 13:20 .:3803 P.007 Nitrogen $alance and Nitrification ' Concentrations of total kjcldahl (organic + ammonia) nitrogen (TKN) in the feed and effluent of each of the test units are shown in Figures 20, 21. and 22. Relative to soluble COD and BODs. feed TKN levels for each unit were more consistent from the start to the finish of a wwtp influent drum. as well as from drum to drum. The feed to Units land 2 averaged 18 mg/L of TKN, while that to Unit 3 averaged 20 mg/L.. Residual levels of TKN in the Effluent of Units 2 and 3 were low thriughout the test, averaging 2 mg/L in both cases. In Unit 1, however, effluent TKN Ievels were low initially but thenincreased to Levels nearly comparable to that of the feed before decreasing to relatively low concentrations once again near the end of the study. This fluctuadon in the effluent concentration can largely be attributed to chagges in nitrification tares in the unit, Though it is not a significant process in the operation of Kinston's full-scale wwtp, nitrification did play a amyor role in the nitrogen balance in the three test units. Figtucs 23, 74, and 25 show the feed and effluent levels of NO3, the end product of nitriftcation, for each of the test units. he data are reported as nitrogen. Nitrite avOJ, an intermediate product in the overall nitrification process, was else monitored in each unit's feed and effluent but wan found only et very tow concentrations. As can be seen, the • effluent NO, concentrations are generally much higher than the feed concentrations, indicative of nitrification occurring. The exception, to this is in Unit 1 during the period corresponding to the higher TKN effluent levels when feed and effluent NO;-N Levels were'essentially equivalent. It appears that the nitrification process Was inhibited during this time. The calve not 1 a readily apparent as parameters such as temperature and pH which can impact nitrification raves remained steady during this tune. The Phase in performance did seem to generally correlate with the change in influent drums which occurred on 10/10/97. On tb.e average, the increase in NO3 levels in the test units can account for -60% of the decrease in TIN levels. The remaining 5-7 mg/L of Tlel removed represent a relatively low amount of nitmgen 'utilization for the amount of soluble BOD3 removed. A typical ratio for utilization of nitrogen with the removal of BOD is 100:5 for BOD:nitrogen on a weight basis. The actual ratios observed were 100:2.3 in Unit I,100:3.0 in Unit 2, and 100:3.2 in Unit 3. Meso1jds Sesttleablllty Frame 26 gives the results of the sludge volume index (SVI) analyses nm on sales from the three units during the study. The SVI analysis provides a measure of how compactly the solids in a sludge settle within a prescribed time interval (30 minutes). Sludges with good settling characteristics typically have an SVI gf 1M0 mUg or less. As can be seen ill Figure 2b, all of the SVI data for the three mita are well above 100 fig. The data for each of the units largely tracked that of the others for much of die study. During the second ham of the study, however, the control unit (Unit 1) generally had higher results than either of the tesc units, In Figure 27, the zone settling velocity (;ASV) data for each of the unirs-are$Novvrs' AS 'data be-atpedid, the data show an inverse relationship with the MLSS concentration in each unit; the high esi ZSV values occur at the lowest MLSS concentrations and the lowest ZSV values at higher MLSS concentrations. This is as *result of the hindered ability of displaced water to pass through the sealing bulk solids layer in the zone seating regime as the solids content of that layer increases. The exception to this occurred in Unit 2 during phase 3 of the study, when relatively stable MLSS concealsations corresponded to inctRasing ZSV values, This is indicative of improving settling charactctistips. Unit 2 ZSV values began to approach hose in Unit 3 in phase 4 of the study when each of the units received the same feed. 4 KinsRep.doc 7196 80 'd VZ:91 90. Z clad STZ6-976-ZSZ:xed AN.,23' 2006 13.20 #0803 P.008 Another measure of the settling characteristics of the solids in Each of the units is effluent /Qtcl susPeocred solids CPS) levels. The effluent TSS concenaradons for each of the units, as mea5uzed in maples of the collected effluent, are shown in Figure 28. Each of the units performed relatively well throughout the study with effluent TSS values generally below 10 mg/L. The overall average effluent TSS concentration for Unit J. was 7.1 mg/1_, while Unit 2 averaged 7.8 mng/L and Unit 3 averaged 8.8 nsg/L_ .'xhe value for Unit 3 includes as outlier early in the study (9/12/97) of 90 mg/1, the average for Unit 3 excluding this Value was 6.5 rrig/L, Pilaw 3 Splldng Results As described previously in phase 3 of the study, increasing amounts (1-10 ppm) of nctvlein,and ally[ alcohol were added to the feeds to Units 2 and 3, respectively, with the jet hotwell water fed at projected levels. Near the end of this phase of the study, two samples each of the fced and efiloent to Units 2 and 3 wets collected and scot to Jackson Lab at Chambers Works for purge/trap QC/i IS and GCJFID analyses for the api]acd constituents. As a result of previous analytical difficulties, one see of samples for each stream were pH adjusted for preservation of the samples while the other was not, The results of the analyses are gives[ in Table I. 'While significant Ievels of acrolein and allyl alcohol were fowad in the feed samples, all effluent results were below detection limits indicating tr/noval of the compounds by degradation, stripping, or transformation, Tablet: A.crolein and Aliyl Alcohol Analytical Results for Phase 3 �.. Sample Acrolcin (PPm9— AUy1 Alcohol (ppm) Unit 2 — -.� 1 Feed ---_�. - - §- Effluent Food E ad1usred < 0.3 5-3- Effluent (pH adjusted) < 0.3 - ---- Unit 3 - Feed —`- — . 5.5 Effluent �` _ _ < 0.3 Feed (pH arlatia d 5.1 Effluent (pH adiva _ _ < 0.3 Effluent Aquatic Toxicity Effluent samples were collected and composited for each of the units during phases 1 and 2 of thestudy for the purpose of aquatic toxicity testing. The samples were shipped to the ASci Corporation's Duluth Environ ental Testing Division where they were evaluated for the prescuce of acute and ehronlc oaxiciky to Cerrodaphnia dab. The test was conducted according to EPA's mannal "Short' Tenn Methods for Estimating the Chronic 'Toxicity of Effluents and Receiving Waters to Freshwater ", Third Edifroa), in a way that also allowed determination of aerate toxicity, The test endpoints were survival and reproduction. The effluent samples were tested at concentrations of 100%, 50%, 25%, 12.5%, 6.25%, and 1.9% with moderatrely hard reconstituted water used as the diluent. The results of the testing are swnmatized below. There were no survival or reproduction effects observed for any of the oxaples at die A0% cffluenf cor3ccntration. The samples thus ex:hibired no acute or chioniic toxicity to Cerfodaphrba dublac. ICmsRe 4qc 3/27/98 5 60 'd SZ r 91 90, Z anti STZ6-9176-ZSZtXed Oddm/Oma • ` JAN..23'2006 13:20 • #0803 P.009 Table 2: Surnznary of Aquatic Toxicity Testing Results Tent Endyoint Unit 1 Effluent Unit 2 Effluent Unit 3 ...--- Effluent Acute Way • > 100% > i 0O% > I00% rS, mva1 NOEC 100% 100% 100% Survival LOEC� - __ - RDrodacaion NOEC 100% WO% 100% Reproduction LOEC - - _ Cote:10 ms, The results of the dreatability study showed that a microorganism population taken from the Kinston she's wastewater treatment plant was able to treat wastes from N 1.25 pilot runs in combination with other site wastewater with no observed adverse effects under all conditions rested, Nearly identical results were obtained for COD and BOD removal, ire the control wont, (Unit 1) which received a feed consisting solely of site wastewater treatment plant influent, and the two test units (Units 2 and 3) which received site wastewater with varying amounts of wastewater from N125 pilot runs added. For all of the units, average soluble COD removal efficiencies of 93-94% and soluble BOD removal efficiencies of 97+% were observed. COD and BOA removal remained at these levels is Unit 3 during phase 2 of the stay when the N125 wastewater was added at twice the projected levels, and in Units 2 and 3 in phase 3 when ac,lein and allyl aicamounts. obol were added in increasing Effluent soluble COD everaged 2A melt or lees in each of 'the tibias, and efliuent soluble BOD Ie:s6 than , 4 nug%1.. No dsl�ra�eiucer in performance of the units was observed whether the N125 wastewater was sIowiy tamped to projected levels or introduced immediately at those IeveLs, or when the N125 wastewater feed was cycled off and on again. Phosphorus removal is an imporraut capability of the Kinston wastewater treatment systeni and thus the mat onus were monitored to determine if this ability was affected by the introductiou of the N125 wastes. No difference in total phosphorus removal was observed between the control nail and test units. No significant removal occarred in any of the units. Though not cuxreody a critical process in Kinston's l teattoeut. System, the importance of nitrification in the overall nitrogen balance for each of the units *n the study should be noted. Feed and effluent TKN and nitrate conccmoratiorts indicate significant nitrification occurred in each of the units throughout the study, with the exception of a pato' od of apparent i>otbibitran in Unit 1. Biomass production rates appeared to be minimal in all of the units. With no solids wastung through mZch of the study, )1+ LVSS levels remained relatively stable. Given the relatively short duration of the study, no attempt to determine yield coefficients was made. Sludge volume index and zotre settling velocity data indicated that the settling g characteristics of the biosolids in the test units did not differ significantly frown those of the control twit biosolids. Effluent sapplrs collected fzom each of the test units during phases 1 and 2 of the study were tested for 3F41.1spil manic to ucity to. Ccriodaphnia dr!bra., The. k+lunpko were ailut i to sat . .... .e�cal�oiorAcezitt?�tiopa using modorat'ly hard oaconstuutcd water' for the testing, hear wcm go effects observed for any of the unit effluents at even the 100% effluent concentration, indicating no acute or chronic toxicity to the test species. lrtnsRcp40c 3J27/9g 6 0I 'd SZ:91 90. Z aa3 SIZ6-9b6-ZSZ: xed - 06dri'cma .JAN_23'2006 13:21 #0803 P.010 :Overall, the study procccdcd well wish very pQSItXYe results. Indications are that the Nl2S w* to can be Ercaton ua me airs-s ...wan -water cmerrnent system without impacting the facility's ability to treat other site wtsates. Results from phase 2 of the study suggest that dais is true ar up to twice the projected flows of N125 wastewater. Phase 3 of the study showed no major short term impacts of introduction of acrolein and ,alkyl alcohol, compounds identified as being of potential concern, Ea cancel/IX-Atom much higher than world be expected in the site's wastewater treatment plant influent_ The two compounds were biodegraded or otherwise trans -formed to below detection levels in the test unit effluent smarms. d o_ iVdEtne>l This azasability study was set up, operated, and monitored at the Wastewater Lab at Glass Marge Venn h d.primary responsibility for these activities. Other lab assisted wham condtrctieig the study and/or personnel following: assisted in performing analyses in support of it include the following: Dennis Azcilla !Crystal Coles Mcri Laughlin David Swift Ken Branner Chuck Miller Diane Nabb Annemarie Mitchell A,dditionai guidance and study oversight were provided by Bob KisseJl and Mike Gel] of the Environmental & Process Safety section of Engineering. Jerry Bailey and Ian Rveib provided guidance from the site's perspective, and coordinated collection and shi.pnaent of samplcs from the site. gehttPd Sys Prior to this flow -through treatability study, a two-phase electrolytic ze apitometry study was conductEngineering's Wastewater Lab for the Kinston Plant to assess the potential inhrlhhory,, toxic, and s biodegradability properties of ac olein and allyl alcohol with rrspect to the site's biomass and went system. The report for this study is available upon request. Kin:Rep.dac 3/ '7/9g 7 IT'd 9Z:9T 90. Z qa.d STZ6-9b6-ZSZ:xed 0ddf9i0f9a November 9, 2005 Reference No. 37006 NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Division of Water Quality NPDES Section 512 N. Salisbury Street Raleigh, North Carolina 27604 Attn: Mr. Sergei Chernikov Re: Resubmittal of Application for Modification of NPDES Permit # NC0003760 Unifi Kinston LLC Post Office Box 800 Kinston, North Carolina 28502 Lenoir County Unifi Kinston LLC (Unifi) is submitting this application for certain modifications of the existing NPDES Permit issued for the Kinston Facility on March 10, 2003 (NPDES Permit # NC0003760). This application provides follow-up documentation to the original Application for Permit Modification which was submitted by INVISTA S.a.r.l. on September 28, 2004. As you are aware, Unifi subsequently purchased the facility after the original request for modification was submitted. EPA Forms 1 and 2 F are attached pursuant to previous discussions with North Carolina Department of Environment and Natural Resources (NCDENR) staff including Mr. Tom Belnick - NPDES Permitting Unit - and Mr. Bradley Bennett and Mr. Ken Pickle - Stormwater Permitting Unit. Forms 2C and 3, are not required for this submittal as directed by NCDENR personnel pursuant to 15A NCAC 02H.0105(a). Based on our discussions, Unifi understands that the permit modifications, it is seeking at this time, are considered minor modifications. Unifi is providing representative analytical data for the additional stormwater outfall locations referenced in this application as Outfalls 004, 005, and 006. Pursuant to recent discussions with Mr. Ken Pickle of Stormwater Permitting Unit and Mf.Sergei Cherrulcov of the NPDES Unit, the analytical dataset includes the specific samplir ; requirements set forth in previous communications and memoranda issued by NCDENR concerning this permit modification We have attached Table 1 and Figure 1, which present the analytical results and locations of samples taken during June 2005 for the additional stormwater outfall locations addressed by this permit modification request. November 09, 2005 2 - Reference No. 37006 Table 1 also contains stormwater outfall sampling data from the original permit modification request. In order to establish baseline monitoring data for the stormwater at the locations addressed by this permit modification request, the facility conducted a sampling effort in September 2004. As noted in the original application for modification, not all of the September 2004 samples represented valid data due to a lack of spacing between rainfall events and some quality control issues. Accordingly, the 2004 data should be viewed only as qualitative data that may not represent actual conditions. The request for modification of the existing NPDES permit includes the following components: 1) Modification of the existing permit to include stormwater discharge at Outfalls 001 and 003. At present, the facility's NPDES permit does not specifically provide for stormwater discharge to these outlets. The facility recently conducted a facility stormwater evaluation that identified the potential for small volumes of stormwater to enter these outfalls. Outfall 001 receives small volumes of stormwater that enters a grated process drain near a chemical tank farm in a on to small flows within the area of tTie WWTP at the southern end of Basin A. Similarly, Outfall 003 includes amage from asin as w as flows from the parking lot and common entrance area. 0 ow for minor stormwater discharges to the existing outlets. 2) Re-desi tion of the dischar : e ' oint for Outfall 002 to a location downstream of the currentl desi ted Outfall 002, in order to incorpo . - e potential additional stormwater runoff over the C&D and Ash Landfills. As you are aware, these two landfills have undergone soil cap construction. Both -the C&D and Ash Landfills have recentclosure-cedification by NCDENR. The downstream relocation of Outfall 002 would also require moving the current sampling location to the new Outfall 002 discharge point. These changes will allow the facility to incorporate potential stormwater flows from these areas into its existing sampling program. 3) Addition of Outfalls 004, 005, and 006 to provide for stormwater discharge at these locations. The areas that each of these outfalls will dram of stormwater are more fully described in Part IV-B of the enclosed Form 2F and the Form 2F Additional Information. The potential discharges at these locations are expected to consist of stormwater only. 4) Addition of low -flow leachate from three collection areas to the industrial wastewater ,treatment plant WifflriardNalarges to Outfall 001. Two of the leachate collection areas, iden ' e as p e Location 9, are located within Basin B and discharge -to -the IWWTP. Basin C also contains a leachate collection area id ntifi as Sami lP Inc lion 0, which sts of o r rconnected collection ps. This area appears to collect lea ate om the on and the newer Ash Landfill. The original Ash Landfill was dosed during the mid 1970s and was formerly used for disposal of ash November 09, 2005 3 Reference No. 37006 generated from the coal-fired powerhouse boilers. The new Ash Landfill is a completely separate landfill that was recently capped as part of the permitted closure process. Analytical data for Sampling Locations 9 and 10 are included in Table 3. This data was obtained during the September, 2004 sampling event. The locations for these two sampling points are also depicted in Figure 1. In preparation for closure of the C&D Landfill and new Ash Landfill, the facility previously requested approval to route the resulting leachate of less than 5 gallons per minute (gpm) to its IWWTP for treatment and disposal. As noted in the Department's conditional approval letter, dated November 13, 2003, the low flow associated with dewatering operations is considered minor pending characterization of the leachate. The facility requests inclusion of the three other leachate collection source flows described above, with each having n estimated flow of apgroCimateely 0.05 gpm, in the approved discharge through Outfall 001 following collection and onsite treatment at the IWWTP. Finally, please note that the facility is modifying some of its steam condensate lines to discharge condensate into either the process wastewater line, which is treated by the IWWTP and discharged via Outfall 001, or to Outfalls 002 and 003, where untreated steam condensate is currently permitted to discharge. Unifi's understanding of the authorized discharge for Outfall 001 is that it includes all wastewaters generated by the facility's industrial operations, including boiler blowdown and steam condensate, as long as the wastewaters are treated at the IWWTP prior to discharge via Outfall 001. Unifi requests confirmation of its understanding of the permit, or a permit modification to specifically authorize dischar 001, if necessary. Unifi intends to proceed with a project to pipe the steam con ensate to Outfall or to Outfalls 002 and/or 003 in the near future, based on its understanding of the current permit's authorizations. Please direct any questions or information requests to the following: Conestoga -Rovers & Associates Attn: Mr. Jay Vincent 4215-I Stuart Andrew Boulevard Charlotte, NC 28217 (704) 676-0502 November 09, 2005 Best Regards, \.:„J, )-1,,,,, Vanish Green Plant Manager Unifi Kinston LLC (252) 522-6233 - 4 Reference No. 37006 Enclosed: Form 1; Form 2-F; Form 2-F Additional Information; Tables 1, 2, & 3; and Figures 1,2,&3 Cc: Mr. Ken Pickle, North Carolina Department of Environment and Natural Resources, Stormwater Permitting Unit fi FORM 2F ADDITIONAL INFORMATION UNIFI KINSTON LLC ITEM II A The site has significant soil and groundwater contamination issues from past operating and waste disposal activities that occurred while the Site was owned and operated by DuPont. DuPont is completing investigations and corrective actions under a RCRA Part-B permit, EPA ID Number: NCD003190386. The environmental condition of the Site has been evaluated through several successive phases of environmental investigations and corrective actions beginning in the 1980s and continuing through the present time. Contaminants indicated during the investigations include the following pollutants from Tables 2F-2 and 2F-3: Barium, Manganese, Arsenic, Chromium, Lead, Mercury, Benzene, Chloroform, Methylene Chloride, Trichloroethylene, Anthracene, Benzo(a)anthracene, Benzo(a)pyrene, Benzo(k)fluoranthene, Dibenzo(a,h)anthracene, Chrysene, Fluroanthene, Fluorene, Phenanthrene, and Pyrene. ITEM IV B Aboveground storage tanks (ASTs) are utilized at the Site for the storage of a variety of significant materials including petroleum products, raw materials, and chemicals utilized in conjunction with manufacturing. The majority of raw materials and other chemicals associated with the manufacturing processes are stored in ASTs located within an aboveground tank farm provided with secondary spill containment and a concrete base. In addition, ASTs are used to store petroleum products which also have secondary containment. A current list of AST tanks and other storage devices that contain significant materials that could potentially allow exposure to stormwater is provided in Table 2. The facility uses No. 6 fuel oil, No. 2 fuel oil (diesel), gasoline, kerosene, various other types of lubricating and hydraulic oils, cottonseed based finishing oils, and other raw materials. The new and used oils are stored at the facility in ASTs, and/or are used in electrical equipment, process, or operating equipment. Figure 3 shows the facility layout, and provides the locations of each of the oil and chemical storage areas. Please note that Figure 3 contains storage and industrial areas that are not exposed to stormwater. Table 2 contains a list of storage and industrial areas that have currently been identified for potential exposure to stormwater. Fuel oil No. 6 is contained in a 1,000,000-gallon capacity AST (#300) in the Powerhouse Area. Fuel oil No. 6 is pumped into two 12,000-gallon ASTs (#298 & #299) and into two 3,500-gallon ASTs (#257 & #258) for storage. Fuel oil No. 6 is also pumped through heaters for use in boilers, vaporizers, and the Factory Engine Room. Fuel oil No.6 is received at the facility by truck at a transfer station located to the northwest of Tank 300, and is either pumped into storage or directly to the boilers and Factory Engine Room. A 940-gallon AST is used as an oil/water separator for Tank 300. Fuel oil No. 2 (Diesel) is received at the facility by truck at a transfer station located northeast of Tank 3, a 130,000-gallon AST. Diesel is stored for use at the facility in several ASTs including the following: • 270-gallon emergency fire pump AST (#293) • two new 550-gallon Detroit emergency fire pump ASTs • 400-gallon emergency generator AST (#290) • 300-gallon AST (A); • two 550-gallon vehicle refill tanks (#285 & #286) • 6,000-gallon yarn side furnace AST (#23); and • 130,000-gallon new vaporizers alternate fuel AST (#308). Gasoline (#282 & #283) and kerosene (#284) are stored at the vehicle refill station in 550- gallon ASTs. Four oil -filled transformers, two 6,265-gallon (#1 & #2) and two 10,505-gallon (#3 & #4) are in use at the facility; however, these transformers are owned and maintained by Carolina Power & Light Company. The following facility -owned and maintained substations are also in use: two 1,030-gallon (12A & 12B); one 375-gallon (RR), and two 1,285-gallon (TT & UU). Lubricating and hydraulic oils are in use in the two outside Factory Engine Room (FER) air compressors (Area 22) with each having a volume of 150 gallons. New and waste finish oils are stored at the facility in both the industrial area and tank farm area. Industrial finish oil is stored in a 10,000-gallon AST (Tank 223). Waste finish oil is also contained in a 4,000-gallon capacity AST and is treated in a 6,500-gallon waste finish oil separator in the tank farm area. Finish oil is stored in a 10,000-gallon AST (L- 525), an 8,000-gallon AST (L-357) and an 8,000-gallon AST (K7164) within the tank farm. Raw materials and other chemicals associated with manufacturing processes are also stored within the tank farm and industrial area. These materials include ethylene glycol; 1,3 propanediol; triethylene glycol; methanol; and dimethyl terephthalate (powder). Pesticides, herbicides, soil conditioners, and fertilizers are not applied at the Site except for the limited use of Parmitol and Roundup in landscaping activities. The Kinston facility has two former landfills that have undergone soil cap construction and have recently received approval for closure by the NCDENR Division of Waste Management - Solid Waste Section. The two former landfills are commonly referred to as the new Ash Landfill and the C&D Landfill. The new Ash Landfill primarily contains ash and residue from the coal fired boiler operations conducted at the facility powerhouse. The C&D Landfill was predominately used for the disposal of construction and other debris. A third landfill, the original Ash Landfill, is located adjacent to and due east of the new Ash Landfill and was closed during the mid 1970's. It is considered to be a separate solid waste management unit of the facility. ITEM IV C Structural Controls The facility uses a variety of structural control measures to prevent and minimize exposure of significant materials to stormwater runoff or discharge. Table 2 provides information regarding these structural measures in minimizing exposure to the proposed stormwater outlets in this application for modification. In addition, the facility has constructed a 1 million gallon containment pond upstream of Outfall 002 to prevent the release of significant materials to surface waters in the event of a catastrophic spill or as a result of water released to combat a major fire incident. Table 2 provides a summary of discharge or drainage controls such as secondary containment around containers and other structures. Potential spills occurring at most oil containing or process chemical ASTs, would be contained in their respective secondary containment areas. Accumulated liquids in the secondary containment areas are visually inspected for the presence of oil prior to releasing the contents either onto the ground surface or into the process sewer. Only valves of manual, open -and -closed design are in use at the facility for the drainage of diked areas. If oil is present in a secondary containment area, the accumulated oils would be removed, treated, and disposed. The hazardous waste area located at the Site is currently undergoing closure by Dupont. The hazardous waste area contains grated drains that discharge into sumps with no drainage or other conveyances in order to prevent access to stormwater. The sumps are visually inspected and the contents are tested for various parameters prior to removing water or other liquids. The Plant wastewater going to the wastewater treatment facility is monitored constantly by two total organic carbon analyzers. Alarms and diversion facilities are online to direct any chemicals or oil detected to an emergency retention pond to prevent releases of significant materials from reaching the Neuse River. Drainage waters are treated continuously in one treatment unit. No pump transfer is necessary, as the lift pump is installed permanently. The wastewater plant has recently experienced a substantial reduction in flow which currently ranges between approximately 450,000 to 600,000 gallons/ day. Nonstructural Controls The Site employs a variety of nonstructural measures and Best Management Practices (BMPs) to prevent or minimize potential exposure to stormwater runoff including the use of: 1) Materials management practices including chemical tracking and inventory control; 2) SPCC Plan implementation and updates; 3) Implementation of a Hazard Communication Program; 4) Training programs, including written procedures, for the transfer, management, and disposal of significant materials; 5) Operator -attended transfers of petroleum products and other significant materials; 6) Trained emergency response personnel and written response procedures; and 7) Inspection, testing, and recordkeeping practices for AST's and other storage devices including oil containing equipment and secondary containment. Based on the types and quantities of materials used and stored at the Site, the Kinston facility is subject to Emergency Planning and Community Right -to -Know Act (EPCRA) requirements. The facility has a system in place for tracking chemicals on Site through use of a chemical inventory. Chemical spills are addressed by the Site emergency response team in accordance with the Site Chemical Emergency Response Plan. The Site has also implemented a Spill Prevention, Control and Countermeasures (SPCC) Plan. In addition, the plant has a Hazard Communication program that describes the systems used to review and manage chemicals on the Site. Hazard communication training is conducted on an annual basis by Unifi personnel. Hazard labeling is conducted for the bulk storage containers at the Site. In the event of a release, the facility has trained personnel and equipment available to contain and clean-up minor volumes of oil. On -site equipment and materials include spill kits, shovels, and sorbent materials (booms, pads, etc.) that may be used to dike, contain, and remove minor releases. i The managers of oil storage areas are responsible for properly instructing their personnel in the operation and maintenance of equipment to prevent the discharge of oil, and applicable pollution control laws, rules, and regulations. At a minimum, training is conducted annually or whenever new spill regulations are promulgated, existing operating systems are modified, personnel responsibilities change, or the SPCC Plan is amended. Attendance rosters and other training records will be maintained in the main office for a period no less than three years. In case of a larger release, specific response procedures have been developed. As part of these procedures, internal and external resources (contractors) have been identified to assist facility personnel. These contractors have the capabilities to provide emergency response, industrial power vacuuming, building decontamination, excavation, earthmoving, and waste transportation and disposal services. Oil storage tanks and other storage devices including secondary containment are regularly inspected, maintained, and tested for integrity. ASTs containing oil, chemicals, and raw materials are subjected to quarterly inspections as detailed on the Quarterly Fuel Oil Storage Tank Inspection Report and other documents. Quarterly inspections include observations for tank, valve, and line conditions; blank and locked out valve use; dike or wall conditions; operation of level indicators; leak or spill evidence; overhead pipe and support conditions; and availability of sorbent material. Above ground oil tanks are also subjected to periodic integrity testing, which includes observations for leaks, and inspection of bolts, washer gaskets, welds, seam rivets, and piping where practicable. Visual observations also include an inspection of the footings for signs of settling. Each oil storage container is also evaluated during the semi-annual dike inspection for evidence of corrosion or deterioration. All above ground valves and pipelines are regularly examined by operating personnel at which time the general conditions of items such as flange joints, expansion joints, valve glands and bodies, catch pans, pipeline supports, locking of valves, and metal surfaces are assessed. In addition periodic pressure testing for pipes in areas where facility drainage is such that a failure might lead to a spill event is performed if warranted. Tank truck transfer lines and liquid level sensing devices are also tested regularly. All inspections and test results are recorded as to dates, time, results, and corrective maintenance. Any defective item is promptly corrected. All oil storage dikes are inspected semi-annually in accordance with the Kinston Plant Dike Inspection Checklist. Semi-annual inspections include visually assessing the integrity of the walls, floor, seals, pumps, pipelines, and related appurtenances. The position of each drain valve is confirmed to be in the closed position. Each oil storage container is also evaluated during the semi-annual inspection for evidence of corrosion or deterioration. All outdoor tank dikes, with the exception of the main No. 6 fuel oil dike, must be drained of rainwater periodically. Water will not be collected to a level that personnel safety is jeopardized when entering a dike. Prior to draining a dike, the liquid will be visually inspected for the presence of oil. If no oil or sheen is apparent, the dike may be drained. If oil or sheen is present, the plant Environmental Group will be contacted for instructions. Records of inspections and tests are kept with the SPCC Plan for a period of 3 years. The main No. 6 fuel oil tank (Tank 300) has an earthen dike, so any rainwater that enters the dike percolates into the soil. Any spill or leakage is manually removed from the diked area. Facility -owned transformers are observed during work shifts by Power House operations personnel. Observations of the transformers include corrosion, staining or leaking. These inspection records are kept with the SPCC Plan. The five facility -owned transformers are subjected to annual tests by an external contractor, and are overhauled every 5 years. The utility -owned oil -containing transformers and load tap changers are inspected every 5 years by Carolina Power and Light (Progress Energy) substation maintenance crews. Inspections include looking for oil leaks, checking oil levels and testing the oil as needed. Maintenance is performed on the load tap changer by the substation maintenance crew every 3 years or 100,000 operations, whichever comes first. Maintenance activities include checking oil levels, checking for leaks, and oil replacement. Maintenance is performed on oil and gas circuit breakers once every six months, or less as determined by other factors. Maintenance activities include removing and replacing the oil from the breakers. Solid wastes generated at the Site are segregated and stored primarily in bulk form in dumpsters, open -top lugger boxes, drums, and tanks. Solid waste, currently temporarily managed on Site, consists of the wastewater treatment plant sludge, which is thin spread on the Site to dry, in accordance with the Site NPDES permit, prior to transportation and disposal at the Waste Industries, Inc. landfill in Bertie County, North Carolina. The remaining solid wastes are all transported off Site for disposal. The Site is a Small Quantity Generator (SQG) of hazardous waste. It has been assigned EPA ID #NCD 003 190 386. There is little hazardous waste generated from the production processes. Most of the generated waste consists of fluorescent light bulbs and miscellaneous wastes from maintenance, cleaning of vessels, decommissioning activities, and laboratory operations. All hazardous wastes are packaged, labeled, and transported off Site using manifests with third party licensed hazardous waste transporters. The Site has a number of oil storage and satellite accumulation areas and one 90-day hazardous waste accumulation area that is maintained in a secure location away from the Site production areas. Treatment Processes The facility also conducts a variety of treatment processes as part of manufacturing operations including wastewater treatment at the industrial wastewater treatment plant (IWWTP) that discharges to Outfall 001. The IWWTP is authorized to discharge treated process and sanitary wastewaters, remediated groundwater, leachate, and non -contact cooling water from Outfall 001. Various treatment processes performed at the plant are listed in the following table. TREATMENT PROCESSES Ammonia Stripping 1-A Coagulation 2-D Flocculation 1-G Dechlorination 2-E Gas -Phase Separation 1-K Ion Exchange 24 Reverse Osmosis (Hyperfiltration) 1-S Activated Sludge 3-A Slow Sand Filtration 1-V Aerated Lagoons 3-B Carbon Adsorption 2-A Anaerobic Treatment 3-C Chemical Precipitation 2-C Nitrification-Denitrification 3-D ITEM VIIB The following table contains information regarding the constituents for which the NPDES permit contains effluent limits for the discharges at Outfalls 001, 002, and 003. Constituents for which effluent limits (L) or monitoring requirements (M) are established by the NPDES permit are also indicated. OUTFALL 001 Flow L 2,4-Dinitrophenol L BOD, 5-day, 20 C L 2,4-Dinitrotoluene L Total Suspended Solids L 2,6-Dinitrotoluene L TN Load L Ethylbenzene L Total Phosphorus L Fluoranthene L PH L Fluorene L Dissolved Oxygen L Hexachlorobenzene L Chronic Toxicity L Hexachlorobutadiene L Bis(2-ethylhexyl) phthalate L Hexachloroethane L Di-n.-butyl phthalate L Methylene Chloride L Methyl Chloride L Naphthalene L Acenaphthene L Nitrobenzene L Acenaphthylene L 2-Nitrophenol L Acrylonitrile L 4- Nitrophenol L Anthracene L Phenanthrene L Benzene L Phenol L Carbon Tetrachloride L Pyrene L Chlorobenzene L Tetrachlorethylene L Chloroethane L Toluene L Chloroform L Total Chromium L 2-Chlorophenol L Total Copper L 1,2-Dichlorobenzene L Total Cyanide L 1,3-Dichlorobenzene L Total Lead L 1,4- Dichlorobenzene L Total Nickel L 1,1-Dichloroethane L Total Zinc L 1,2- Dichloroethane L 1,2,4-Trichlorobenzene L 1,1-Dichloroethylene L 1,1,1-Trichloroethane L 1,2-trans-Dichloroethylene L 1,1,2-Trichloroethane L 2,4-Dichlorophenol L Trichloroethylene L 1,2-Dichloropropane L Vinyl Chloride L 1,3-Dichloropropylene L Total PAHs L Diethyl phthalate L Benzo(a)anthracene L 2,4-Dimethylphenol L 3,4-Benzofluoranthene L Dimethyl phthalate L Benzo(k)fluoranthene L 4,6-Dinitro-o-cresol L Benzo(a)pyrene L Total Monthly Flow M Temperature M TKN M NH3-N M Nitrate -Nitrite Nitrogen M Chrysene M Total Nitrogen M Dibenz(a,h)anthracene M Fecal Coliform M Indeno(1,2,3-ed) pyrene M OUTFALL 002 Flow Total Mercury L PH L Total Nickel L Temperature L Total Selenium L Total Residual Chlorine L Total Silver M Total Cadmium L Total Zinc M Total Chromium L Total Nitrogen M Total Copper M Total Phosphorus L Total Lead L OUTFALL 003 Flow Total Mercury L PH L Total Nickel L Temperature L Total Selenium L Total Residual Chlorine L Total Silver M Total Cadmium L Total Zinc M Total Chromium L Total Nitrogen M Total Copper M Total Phosphorus L Total Lead L TABLE2 Page 1 of 12 v UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or (gal) Chemical ID Type of Containment Valves or Drains present? Are they or can they be locked? Direction of Potential Spill? MAIN STORAGE TANK (6027) 1 300 1,000,000 #6 Fuel Oil Earth Dike - with sump Y Release to ground surface after test S or E POWER HOUSE NORTH DAY TANK (6025) 2 298 12,000 #6 Fuel Oil Concrete Block Dike Y Release to ground surface after test S POWER HOUSE SOUTH DAY TANK (6026) 2 299 12,000 #6 Fuel Oil Concrete Block Dike Y Release to ground surface after test S POWER HOUSE TANK - USED AS 0/W SEPARATOR FOR MAIN TANK 18 940 # 6 Fuel & Water Concrete Block Dike Y Y Released to ground surface after test S FACTORY ENGINE ROOM WEST DAY TANK (6001) 6 257 3,500 #6 Fuel Oil Concrete Block Dike Sump pump, test, release to process sewer Sump pump to SW sewer FACTORY ENGINE ROOM EAST DAY TANK (6002) 6 258 3,500 #6 Fuel Oil Concrete Block Dike Sump pump, test, release to process sewer I Sump pump to SW sewer EMERGENCY FIRE PUMP (6021) 4 293 270 Diesel Fuel Double Walled Steel Tank N A spill or leak would consist primarily of fuel and be disposed of accordingly S NEW DETROIT EMERGENCY FIRE PUMPS NORTH TANK (NEW) 17 550 Diesel Fuel Concrete (inside building) N A spill or leak would consist primarily of fuel and be disposed of accordingly W inside bldg on concrete floor SOUTH TANK (NEW) 17 550 Diesel Fuel Concrete (inside building) N A spill or leak would consist primarily of fuel and be disposed of accordingly W inside bldg on concrete floor EMERGENCY GENERATOR (6019) 7 290 400 i Diesel Fuel Stainless Steel Dike Y N Release to ground surface after test S CRA 37006 Final Rewbmittal 77 10-1406xls TABLE 2 Page 2 of 12 • UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or (gal) Chemical ID Type of Containment Valves or Drains present? Are they or can they be Iocked? Direction of Potential Spill? VEHICLE AND MAINTENANCE REFILL STATION NORTH TANK 1 (6016) 11 285 550 Diesel Fuel Concrete Block Dike N Dike content inspected, then either released to process sewer or pumped into drums S to ditched storm sewer drain. Gravel overburden. SOUTH TANK 1 (6017) 11 286 550 Diesel Fuel Concrete Block Dike N Dike content inspected, then either released to process sewer or pumped into drums S to ditched storm sewer drain. Gravel overburden. VEHICLE REFILL STATION (6015) 11 284 550 Kerosene Concrete Block Dike N Dike content inspected, then either released to process sewer or pumped into drums S to ditched storm sewer drain. Gravel overburden. NORTH TANK 2 (6013) 11 282 550 Gasoline Concrete Block Dike N Dike content inspected, then either released to process sewer or pumped into drums S to ditched storm sewer drain. Gravel overburden. SOUTH TANK 2 (6014) 11 283 550 Gasoline Concrete Block Dike N Dike content inspected, then either released to process sewer or pumped into drums S to ditched storm sewer drain. Gravel overburden. TRANSFER STATIONS - LOADING AND UNLOADING AREAS VEHICLE REFILL STATION Loading and Unloading Area 11 NA Gasoline Diesel Kerosene None (not practicable due to locational constraints) N S to ditched storm sewer drain. Gravel overburden. EMERGENCY FIRE PUMP (6021) Loading and Unloading Area 4 NA Diesel Fuel None Release during fueling to go to retention pond in Basin D. Procedure developed to assure valve at retention pond is closed prior to transfer operations N A spill or leak would consist primarily of fuel and be disposed of accordingly S NORTH/SOUTH TANK (NEW DETROIT) Loading and Unloading Area 17 NA Diesel Fuel None N Procedure in place to assure that potential spill drains into process sewer or retention pond S RRA 37006 Final Rcsubmittal 721040-05.xls TABLE 2 • Page 3 of 12 UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or ID (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be locked? Direction of Potential Spill? FUEL OIL NO. 6 TRANSFER STATION 8 NA #6 Fuel Oil Paved Unloading Ramp - with sump N Pumped to process sewer after inspection SW FUEL OIL NO. 2 TRANSFER STATION 14 NA #2 Fuel Oil None (not practicable due to locational constraints) N SW FINISHING OIL TRANSFER STATION 23 NA Cottonseed Oil None N N DOWTHERM UNLOADING AREA - Tank truck 43 AOC 103C NA Dowtherm Dike Y Spills would collect in sump connected to process sewer S DOWTHERM UNLOADING AREA - Railcar station 44 AOC 103D NA Dowtherm Sump Y Pump to process sewer. Dowtherm loading and unloading area not in service S NEW VAPORIZERS ALTERNATE FUEL Loading and Unloading Area 3 NA #2 Fuel Oil None. Concrete Pad (not practicable due to locational constraints) N NW Drain to SW sewer ADDITIONAL TANKS & on. CONTAINING EQUIPMENT YARN SIDE FURNACE (4002) - OIL RESERVOIR 5 23 6,000 #2 Fuel Oil Concrete Dike Y N (gate valve) Drain to ground surface E or S on gravel overburden NEW VAPORIZERS ALTERNATE FUEL TANK (NEW) 3 308 130,000 #2 Fuel Oil Concrete Dike _ Visually inspect then discharge to ground surface NW Drain to SW sewer TANK A (STAPLE SHIPPING) 13 A 532 #2 Fuel Oil Concrete N Released to ground surface after testing NE FER AIR COMPRESSOR - OIL RESERVOIR 22 14 150 Lubricating None N W: External storage above gravel overburden FER AIR COMPRESSOR - OIL RESERVOIR 22 16 150 Lubricating . None N W: External storage above gravel overburden OIL -FILLED TRANSFORMERS CP&L BANK NO. 1 24 1 6,265 SAE 15 ,Non - detergent None Concrete Drip Pad N N or W Ditched CRA 37006 Final Rcwbmittal 7210-10-06.xb TABLE 2 Page 4 of 12 • 0 UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP AIternate tank Volume Type of Oil or ID # (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be locked? • Direction of Potential Spill? CP&L BANK NO. 2 24 2 6,265 SAE 15 ,Non - detergent None Concrete Drip Pad N N or W Ditched CP&L BANK NO. 3 24 3 10,505 SAE 15 ,Non - detergent None Concrete Drip Pad N N or W Ditched CP&L BANK NO. 4 24 4 10,505 SAE 15 ,Non - detergent None Concrete Drip Pad N N or W Ditched SUBSTATION 12A 25 12A 1,030 SAE 15 ,Non - detergent None Concrete Drip Pad N S or E SUBSTATION 12B 25 12B 1,030 SAE 15 ,Non - detergent None Concrete Drip Pad N S or E SUBSTATION RR 26 Idetergent RR 375 SAE 15 ,Non - None Concrete Drip Pad N S or E SUBSTATION TT 26 TT 1,285 SAE 15 ,Non - detergent None Concrete Drip Pad N S or E SUBSTATION UU 26 UU 1,285 SAE 15 ,Non - detergent None Concrete Drip Pad N S or E OTHER STORAGE >55 GALLON CAPACITY. INCLUDE DRUMS, MOBILE CONTAINERS, ETC. DUPONT HAZARDOUS WASTE STORAGE AREA Note: Currently undergoing closure as of 09/01/05 15 —5500 max Used Oil I Grated troughs feed into concrete lift pad with sump N DRAIN Valve sump and trough collection must be pumped out Gated and Locked Facility NW UNIFI a 90 DAY ACCUMULATION AREA 30 —8250 max Varies Material stored in drums and placed on spill spill pallets located inside building on sealed concrete floor N NW L-525 (TANK FARM 10) 31 10 10,000 Finish Oil (cottonseed oil) Combination concrete wall and earthen banks; clay and rock floor tank on concrete pad Y Dike content discharged to process sewer N L-357 (TANK FARM 12) 31 8,000 Finish Oil Concrete wall; clay and rock floor tank on concrete pad Y Dike content discharged to process sewer N WASTE FINISH (TANK FARM 50) 31 4,000 Waste Finish Oil Earthen Clay & Rock Y Dike content discharged to process sewer N cRA 37006 Final Rcsubmittal T21040-05xds TABLE 2 so Page 5 of 12 UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or ID # (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be locked? (J Direction of Potential Spill? K-7164 (TANK FARM - FINISH OIL) 32 8,000 Finish Oil Concrete wall Cement floor Y Dike content inspected then discharged through valve to cement ditch to process sewer N INDUSTRIAL WASTE FINISH OIL TANK & SUMP 10 223 10,000 Waste Finish Oil Concrete Block Dike Y Dike content inspected then discharged through valve to cement ditch to process sewer E YARN FINISH 9 240 6,000 Finish Oil Gravel/Clay Dike Y Yarn finish pump used to pump to Oil Seperator and then to process sewer W WASTE FINISH OIL SEPARATOR 27 Shown on Map 6,500 Waste Finish Oil Concrete Dike - with sump N Pumped to process sewer after visual inspection N PCB STORAGE AREA 34 —220 max Light Oil /Tar Ballasts Spill Pallet Containment (interior storage) N Tested and pumped out to process sewer E TRUCK SHOP USED OIL STORAGE 29 —220 max Used Oil Spill Pallet Containment (interior storage) N Tested and pumped out to process sewer RECYCLING FINISHING OIL TANK TRUCK - SOUTH 35 6,600 Finishing Oil Concrete Dike. N Pumped to ground surface or process water after inspection S Toward storm drain Block mats in place during transfers DOWTHERM FER STORAGE TANK 36 4,500 Dowtherm Concrete Block Dike Sump Pumped to process sewer after test S TANK FARM STORAGE TANK 37 18,000 Dowtherm Dike Drain to process after test NW DOW COND REC NO. 1 38 8,000 Dowtherm Common Concrete Dike Y Plugged drain. Water pumped to process sewer S DOW COND REC NO. 2 38 8,000 Dowtherm Common Concrete Dike Process after test S DOW COND REC NO. 3 38 8,000 Dowtherm Common Concrete Dike Process after test S CRA 37006 Ftma! Rcsubmittal 1210.70-05xls TABLE 2 Page 6 of 12 d UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or ID # (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be locked? Direction of Potential Spill? DOW DRAIN TANK NO. 1 38 4,000 Dowtherm Common Concrete Dike Process after test S DOW DRAIN TANK NO. 2 38 4,000 Dowtherm Common Concrete Dike Process after test S DOW LOOP SEAL TANK 38 500 Dowtherm Common Concrete Dike Process after test S DIRTY DOW STORAGE TANK 39 9,000 Dowtherm Dike Process after test S WASTE DOWTHERM DRUM STORAGE AREA, VAPORIZERS 40 SWMU 59 440 Dowtherm None Direct drain to process sewer S WASTE DOWTHERM DRUM STORAGE AREA, RECLAMATION UNIT 41 SWMU 60 500 Dowtherm Dike Process after test S DOWTHERM VAPORIZERS 42 AOC 89 8 @ 1500 Dowtherm Common Concrete Dike Y Drain connected to process sewer. Discharge to process after visual inspection S ABOVE GROUND PIPING —300 gallons #6 Fuel Oil None N Spills would flow onto ground and gravel beneath Varies Y4/5 CP/SPIN DOWTHERM CONDENSATE RECEIVER (OUTDOOR) 19 3,500 gal Dowtherm & Water Concrete Dike Y Plugged Drain Water pumped to storm drain following inspection. Dowtherm pumped into drums E TPA1 DOWTHERM CONDENSATE RECEIVER (IN BUILDING WITH OPEN SIDES) 34 4,000 gal Dowtherm & Water Concrete Dike Y Plugged Drain Water pumped to storm drain following inspection. Dowtherm pumped into drums W TPA2 DOWTHERM CONDENSATE RECEIVER (IN BUILDING WITH OPEN SIDES) 34 4,000 gal Dowtherm & Water Concrete Dike (directly under 1st floor) Open sump -no drain. Water pumped to storm drain following inspection. Dowtherm is pumped from dike into drums W CRA 37006 Final Resubmittai 7210-10-05.4s TABLE 2 Page 7 of 12 • UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP AIternate tank Volume Type of Oil or ID (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be locked? Direction of Potential Spill? Y6 SPIN. LOW PRESSURE CONDENSATE RECEIVER (IN BUILDING) 33 4,000 gal Dowtherm & Water Shared Below Grade Level Concrete Dike No Drain. Contents must be pumped from dike into drums following inspection E Y7 Spin. LOW PRESSURE CONDENSATE RECEIVER (IN BUILDING) 33 4,000 gal Dowtherm & Water Shared Below Grade Level Concrete Dike No Drain. Contents must be pumped from dike into drums following inspection E Y6 HIGH PRESSURE CONDENSATE RECEIVER (OUTSIDE) 25 4,000 gal Dowtherm & Water Shared Concrete Dike Y Plugged drain Water pumped to storm drain following inspection. Dowtherm pumped into drums S or E Y7 HIGH PRESSURE CONDENSATE RECEIVER (OUTSIDE) 25 4,000 gal Dowtherm & Water Shared Concrete Dike Y Plugged Drain Water pumped to storm drain following inspection. Dowtherm pumped into drums S or E DOW RECEIVER 3G 45 85 Dowtherm Shared Dike Y Inside Bldg.to Process Sewer DOW VENT RECEIVER 45 85 Dowtherm Shared Dike Y Plugged drains and to process sewer DOW CONDENSATE RECEIVER 45 978 Dowtherm Dike Y Plugged drains and to process sewer DOW HIGH PRESSURE RECEIVER 45 370 Dowtherm Shared Dike Y Plugged drains and to process sewer DOW STORAGE TANK 45 587 Dowtherm None Y Plugged drains and to process sewer DOW BLOW OFF TANK 45 340 Dowtherm Dike Y Plugged drains and to process sewer DOW FLA REBOILER 45 314 Dowtherm Shared Dike Y Plugged drains and to process sewer QtA 37005 Fin! Rcwbmittal 771610-06.xts TABLE 2 Page 8 of 12 UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or ID # (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be locked? Direction of Potential Spill? 1 DOW FLA/LOOPSEAL REBOILER 45 61 Dowtherm None Y Plugged drains and to process sewer DOW FIN. REBOILER 45 132 Dowtherm Shared Dike Y Plugged drains and to process sewer MON. LINE DOW TANK 45 212 Dowtherm Shared Dike Y Plugged drains and to process sewer REACTOR DOW TANK 45 212 Dowtherm Shared Dike Y Plugged drains and to process sewer DOW TRANSFER LINE TANK 45 225 Dowtherm None N Plugged drains and to process sewer TL PANCAKE HEATER 45 68 Dowtherm None N Process sewer POL. PUMP DOW BOILER 45 267 Dowtherm None N Process sewer WASTE DOW DRUM (12' LEVEL) 45 55 Dowtherm Shared Dike Y Process sewer WASTE DOW DRUM (0' LEVEL) 45 55 Dowtherm Dike Y Inside Bldg.to Process Sewer WASTE DOW DRUM (24' LEVEL) 45 55 Dowtherm Shared Dike Y Inside Bldg.to Process Sewer DOW BOILER 1 TL 45 81 Dowtherm None Y Plugged drains and to process sewer DOW BOILER 2 45 82 Dowtherm None Y Plugged drains and to process sewer DOW BOILER 4 45 82 Dowtherm Dike Y Plugged drains and to process sewer DOW BOILER 5 45 82 Dowtherm Dike Y Plugged drains and to process sewer CRA 37016 Final Rewbmittal 1210.10-06xla TABLE 2 Page 9 of 12 r UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or ID (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be locked? ti Direction of Potential Spill? DOW BOILER 6 45 ' 75 Dowtherm None Y Plugged drains and to process sewer DOW BOILER 9 45 181 Dowtherm None Y Plugged drains and to process sewer DOW BOILER 10 45 75 Dowtherm None Y Plugged drains and to process sewer FLASH V/L RE -BOILER 45 113 Dowtherm None N Plugged drains and to process sewer LIQUID DOW CONDENSATE RETURN LINES - LOCATIONS INDICATED ON FIGURE 3 Y6/7 INSIDE TANK TO HEADER 20 35 Dowtherm None N Not defined Y6/7 OUTSIDE TANK TO HEADER 20 21 Dowtherm None N Not defined TPA1 TANK TO FACTORY ENGINE ROOM 34 931 Dowtherm None N Not defined TPA2 TANK TO HEADER 34 150 Dowtherm None N Not defined Y5 TANK TO FACTORY ENGINE ROOM 19 1,550 Dowtherm None N Not defined Y6/7 & TPA HEADER TO FACTORY ENGINE ROOM 20 1,761 Dowtherm None N Not defined TPA2 TO Y6/7 DOW JACKETED OLIGOMER LINE 20 517 Dowtherm None N Not defined RAW MATERIALS, WASTES, AND OTHER REGULATED CHEMICALS ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 10 3 65,000 Liquid Common Concrete Block Dike Tanks 1-8 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 10 7 150,000 Liquid Common Concrete Block Dike Tanks 1-8 Y Y N RA 37006 Final Rnubmittal 7210.10A6.xls TABLE 2 Page 10 of 12 4, .► UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or ID # (gal) Chemical Type of Containment Valves or Drains present? Are they or can they be Iocked? o d Direction of Potential Spill? ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 10 8 150,000 Liquid Common Concrete Block Dike Tanks 1-8 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 10 9 300 Liquid Common Concrete Block Dike Tanks 1-8 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 31 30 10,000 Liquid Common Concrete Block Dike Tanks 30-35 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 31 31 10,000 Liquid Common Concrete Block Dike Tanks 30-35 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 31 32 10,000 Liquid Common Concrete Block Dike Tanks 30-35 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 31 33 10,000 Liquid Common Concrete Block Dike Tanks 30-35 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 31 34 10,000 Liquid Common Concrete Block Dike Tanks 30-35 Y Y N ETHYLENE GLYCOL (EG) SOLUTION PREP TANK FARM 31 35 10,000 Liquid Common Concrete Block Dike Tanks 30-35 Y Y N ETHYLENE GLYCOL (EG) TPA FEED TANK 34 200 Liquid None Concrete Lift Pad N S ETHYLENE GLYCOL (EG) TPA FEED TANK 34 200 Liquid None Concrete Lift Pad N S 1,3 PROPANEDIOL (PDO) SOLUTION PREP TANK FARM 10 1 65,000 Liquid Common Concrete Block Dike Tanks 1-8 Y Y N 1,3 PROPANEDIOL (PDO) SOLUTION PREP TANK FARM 10 2 65,000 Liquid Common Concrete Block Dike Tanks 1-8 Y Y N 1,3 PROPANEDIOL (PDO) SOLUTION PREP TANK FARM 10 5 65,000 Liquid Common Concrete Block Dike Tanks 1-8 Y Y N 1,3 PROPANEDIOL (PDO) SOLUTION PREP TANK FARM 37 25 20,000 i Liquid Concrete Block Dike Y Y N CRA 37006 Final Resubmittal T21040-06.xIs TABLE 2 Page 11 of 12 UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or (gal) Chemical ID # Type of Containment Valves or Drains present? Are they or can they be locked? Direction of Potential Spill? 1,3 PROPANEDIOL (PDO) SOLUTION PREP TANK FARM 37 26 20,000 Liquid Concrete Block Dike Y Y N 1,3 PROPANEDIOL (PDO) SOLUTION PREP TANK FARM 46 62 500,000 Liquid None N N 1,3 PROPANEDIOL (PDO) 3 GT RECYCLE TANK 1 45 1,000 Liquid None N S 1,3 PROPANEDIOL (PDO) 3 GT RECYCLE TANK 2 45 1,000 Liquid None N S METHANOL SOLUTION PREP TANK FARM 44 20 33,000 Liquid Common Concrete Block Dike Tanks 20,23,24 Y Y N METHANOL SOLUTION PREP TANK FARM 44 23 170,000 Liquid Common Concrete Block Dike Tanks 20,23,24 Y Y N METHANOL SOLUTION PREP TANK FARM 44 24 170,000 Liquid Common Concrete Block Dike Tanks 20,23,24 Y Y N DIMETHYL TETRAPHTHALATE (DMT) SOLUTION PREP TANK FARM 46 61 500,000 Solid (powder) None N Heated @ 140 deg C Solidifies at Ambient Temperature. TERREPTHALIC ACID (TPA) TPA SILO 1 34 TPA 1 1,400,000 lbs Solid (powder) None N S/SW TERREPTHALIC ACID (TPA) TPA SILO 2 34 TPA 2 1,400,000 lbs Solid (powder) None N S/SW DIMETHYL TEREPHTHALATE (TPA) (DMT) TPA RAILCARS 34 200,000 lbs ea Solid (powder) None N S/SW TPA WASTEWATER SOLUTION PREP TANK FARM 9 21 33,000 Liquid Clay Walls & Gravel Overburden Y Y SW TPA WASTEWATER SOLUTION PREP TANK FARM 9 22 33,000 Liquid Clay Walls & Gravel Overburden Y Y SW TRIETHYLENE GLYCOL (TEG) SOLUTION PREP TANK FARM 31 40 8,000 Liquid Common Clay Wall and Gravel Floor. Tank on Concrete Pad. Y Y N CRA 37006 Final Resubmivai 121040- 0xis TABLE 2 Page 12 of 12 re UPDATED 09/20/05 Description (Tank No.) TYPES OF PRODUCTS STORED AND POTENTIAL STORAGE VOLUME UNIFI KINSTON LLC FACILITY MAP Alternate tank Volume Type of Oil or (gal) Chemical ID Type of Containment Valves or Drains present? Are they or can they be locked? Direction of Potential Spill? 31 41 8,000 Liquid Common Clay Wall and Gravel Floor. Tank on Concrete Pad. Y Y N TRIETHYLENE GLYCOL (TEG) SOLUTION PREP TANK FARM TRIETHYLENE GLYCOL (TEG) SOLUTION PREP TANK FARM 31 42 8,000 Liquid Common Clay Wall and Gravel Floor. Tank on Concrete Pad. Y Y N 32 43 8,000 Liquid Concrete Wall, Cement Floor Y Y N TRIETHHYLENE GLYCOL (TEG) SOLUTION PREP TANK FARM 19 10,000 Liquid Concrete Dike Y Y S DIETHYLENE GLYCOL Y4/5 HOLDING TANK ALUMINIM SULFATE SOLUTION PREP TANK FARM 27 275 Liquid Plastic Lined Dike with Grate N Flow to sump at 0/W Separator. Pumped to process or OW separator A-Z Waste Finishing Oil 27 8,500 Waste Finish Oil Concrete Dike Y Y S/SW SODIUM HYPCHLORITE Y4/Y5 PVC TANK 19 2000 Liquid PVC Dike Y Y S SODIUM HYPOCHLORITE Y6/Y7 PVC TANK 20 1,000 Liquid PVC Dike Y Y S SODIUM HYDROXIDE 40% Na0H, 10% KOH, 50% H2O Y4 SYNTHETIC TANK 19 500 Liquid None Concrete Floor N S SODIUM HYDROXIDE 40% Na0H, 10% KOH, 50% H2O TPA 34 8,000 Liquid Doublewalled Construction with Sight Glass N S TITANIUM DIOXIDE 3 GT SLURRY TANK 45 500 Liquid None N S CRA 37006 Flea! Reaubmitlal 721410-05.xv 1 TABLE 3 DETECTED COMPOUNDS FROM SEPTEMBER 2004 SURFACE WATER SAMPLING UNIFI KINSTON LLC, NORTH CAROLINA Analand Method Units Location 9 37006JRP9 Location 10 37006JRPIO Current Permit Limit Outfit!! Reference General Chemistry AMMONIA E350.I mg/L 0.929 12.5 NL TKN E351.2 mg/L 1.54 14.17 NL NO3-NO2 E353.2 mg/L NL PHOSPHORUS E365.4 mg/L 2.05 0.763 2 (QA) 002 CYANIDE SW9012 ug/L 2.3 J 258.7 001 Mania ALUMINUM SW6010B ug/L 247 146 1 NL ANTIMONY SW6010B ug/L 4 J 4.7 J NL ARSENIC SW6010B ug/L 37.8 19.6 NL BARIUM SW6010B ug/L 15.3 l 44.5 J NL CADMIUM SW6010B ug/L 0.43 l 0.39 J 2 002 CALCIUM SW6010B ug/L 11800 48300 NL CHROMIUM SW6010B ug/L 2.4 J 1.7 1 50 002 COBALT SW6010B ug/L 0.71 J 1.1 J NL COPPER SW6010B ug/L 1.9 1 6.2 362.1 001 IRON SW6010B ug/L 31000 18900 NL LEAD SW6010B ug/L 2.6 J 1.3 1 25 002 MAGNESIUM SW601013 ug/L 1700 l 5290 NL MANGANESE SW6010B ug/L 224 331 NL MERCURY SW7470A ug/L MA 001 NICKEL SW6010B ug/L 1.7 J 88 002 POTASSIUM SW601013 ug/L 1280 J 4500 J NL SELENIUM SW6010B ug/L 3.3 l 3.8 J 5 002 SODIUM SW6010B ug/L 8410 5690 NL VANADIUM SW6010B ug/L 1.4 1 1.2 J NL ZINC SW601013 ug/L 52.4 64.3 NL liLeCs 1,I'-BIPHENYL SW8270C ug/L NL 2-METHYLPHENOL SW8270C ug/L NL 4-METHYLPHENOL SW8270C ug/L NL PHENOL SW8270C ug/L MA 001 &ICE 1 • Estimated quantity, detected below reporting limit. NL - No Limit QA - Quarterly Average MA - Monthly Average Mass Loading (pounds per day) 001 - Permit limit for Outfall 001 002 • Permit limit for Outfalls 002 and 003 CRA 37006 Final Resubmtttal T3 10-10-05 fig I PROPOSED RELOCATION OF NPDES OUTFALL 002 PROPOSED OUTFALL 004 BAS PROPOSED OUTFALL 005 664 i' NPDES OUTFALL 001 SAMPLE LOCATION 9 SEPT. 2004 PROPOSED OUTFALL 006 SAMPLE LOCATION 10 SEPT. 2004 SCALE veaviuna+ I oruVASTATUS UNIFI KINSTON NC KINSTON, NORTH CAROLINA SAMPLING LOCATION MAP COI STOOA ROVERS A ASSOCIATES Pepe Woos: awe 37006-00 FCHER001 I figure 1 \. I ,f. } ''�•>. flr. Lsnuinct, ' - I(.. _ fi • ti G tr 4 V '- / f :/ .0. ms Clb � eW La1O rly 1 / • / N.C. r QUADRANGLE LOCATION 0 1000 2000ft SOURCE: USGS 7.5 MINUTE QUAD GRIFTON, N.C. figure 2 SITE LOCATION UNIFI KINSTON NC Kinston, North Carolina 37006-00(CHER0011GN-SP002 SEP 01/2005 Discharge Characteristics Rainfall duration Total rainfall O&G - N-Hexane Extractable BOD5 COD Total suspended solids Total organic nitrogen Total phosphorus pH - Lab pH - Field Fecal coliform Arsenic Cadmium Chromium Cobalt Copper Lead Mercury Nickel Selenium Silver Zinc Acetaldehyde Acrolein Allyl alcohol Formaldehyde Xylenes (total) 1,1-biphenyl 2-methylphenol 4-methylphenol bis (2-Ethylhexyl) phthalate Acetone 2-Butanone Toluene Caprolactam Dibenzofuran Phenol Units minutes inches mg/L mg/L mg/L mg/L mg/L mg/L Standard units Standard units (MF)/100 mL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L mg/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L TABLE 1 UNIFI KINSTON LLC NCDENR APPROVED PARAMETER LIST SAMPLING DATA FOR SDO-004, SDO-005, AND SDO-006 Current Permit Requirements Sei Jtember 2004 same liw; results Sample ictuai or Type (Dugan 001 Outfall 002 Outfall 003 Anticipated Limit GC GC GC GC GC GC GC GC GC Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals VOCs VOCs VOCs VOCs VOCs SVOCs SVOCs SVOCs SVOCs VOCs VOCs VOCs SVOCs SVOCs SVOCs 30 CO L 193.81b/dy L-MA 120 CO L 100 CO M M M M L L L 2.0 L-QA L L L 6.0to9.0 L L L 6.0 to 9.0 M 1,000/100 ml CO L L L L L Outfall 004 Dugan 005 Outfall 006 lulu 2005 sampling results Outfall 004 Outfall 005 Outfall 006 Trip Blank (VOC) 210 210 210 0.65 0.65 0.65 NA NA NA ND (5) ND (5) ND (5) NA NA NA NA ND (2) 5 J 19 J NA NA NA NA ND (10) 45.0 52.6 NA NA NA NA ND (4) 20 14 NA 2 B 2 B 420 NA ND (0.1) 1.33 2.33 0.09 B 0.9 3.0 NA 7.1J 6.7J 7.7J NA 7.3 6.9 7.0 NA 137 5400 310 NA 50 SW ND (10) 3.2 B ND (10) ND (10) ND (10) ND (10) NA L L 2.0 L-SW 0.33 B ND (5) ND (5) ND (5) ND (5) ND (5) NA L M 50 L-SW 1.1 B 6.2 1.9 B ND (10) 2.4 B ND (10) NA M M ND (5) 1.6 B ND (5) ND (50) ND (50) ND (50) NA M M 7.0 SW 11.2 2.6 B ND (5) ND (25U) ND (25U) ND (25U) NA L L 25 L-SW 17 ND (3) ND (3) 4.5 1.9 B ND (3) NA L L 0.012 L-SW ND (0.2) ND (0.2) ND (0.2) ND (0.20) ND (0.20) ND (0.20) NA L L 88 L-SW 2.7 B 2.9 B 1.6 B ND (40) 3.5 B 2.3 B NA L L 5.0 L-SW ND (5) ND (5) ND (5) ND (5) ND (5) ND (5) NA M M .06 SW ND (5) ND (5) ND (5) ND (10) ND (10) ND (10) NA M M 50 SW 197 8.4 B 5.2 B ND(66.4U) ND (59.3U) ND (20) NA M NA NA NA ND (5) ND (5) ND (5) NA M NA NA NA ND (20) ND (20) ND (20) ND (20) M NA NA NA ND (5) ND (5) ND (5) NA M NA NA NA 0.0038 J 0.0044 J 0.010 J NA M ND (0.5) ND (0.5) ND (0.5) ND (2) ND (2) ND (2) ND (2) M ND (10) ND (10) 66 ND (10) ND (10) 6.6 J NA M ND (10) ND (10) 21 ND (10) ND (10) 9.1 J NA M ND (10) ND (10) 18 ND (10) ND (10) 0.83 J,# NA 2.352lb/ dy L-DM NA NA NA ND (10U) ND (10U) ND (10U) NA NA NA NA ND (10) ND (10) 29 ND (10) NA NA NA ND (10) ND (10) 1.2 J ^ND (10) 0.2191b/ dy L-DM NA NA NA ND (1) ND (1) ND (1) 0.32 J NA NA NA ND (10) ND (10) 1.0 J NA NA NA NA ND (10) ND (10) 0.59 J NA 0.2191b/ dy L-DM NA NA NA ND (10) ND (10) 24 NA Notes: B - Below analytical reporting limit. Considered estimated concentration J - Below analytical reporting limit. Considered estimated concentration L - Current permit has established limit for parameter. M - Current permit has monitoring only requirement. NA - Parameter not analyzed. ND - Parameter not detected. # - This value represents a probable combination of 3-Methylphenol (m-cresol and 4-methylphenol (p-cresol SW - Surface Water Quality Standard CO - Cutoff Concentration (Typical) MA - Montly Average QA - Quarterly Average DM - Daily Maximum * - The toluene result for SDO-6 is qualified as non -detect because the associated trip blank yielded a toluene detection of 0.32 ug/L U - The analyte is non -detect with the associated value being the quantitation limit CRA 37006 Final Resubmittal T110.10-05.xls