WQ0040672_Monitoring - 03-2022_20220421

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DWR - NonDischarge Monitoring Report Submittal
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NORTH CAROLINA
Enrlranmenlel QHaflly
Monitoring Report Submittal
..............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Permit Number#* WQ0040672
Name of Facility:* Stevens Towing-Riverbulk Terminal WWTF
Month:* March Year:* 2022
Report Information
Type* Upload Document*
Revised-GW-59 GW-59 Signed.pdf 6.55MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2,NDMLR,GW-59).
Confirmation Email Address:* [e-mail]
Name of Submitter:* Kevin Robert Gagnon
Signature:
Ci Rafe-tt
Date of submittal: 4/21/2022
This will be filled in automatically
Initial Review
.............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Reviewer: Gerald,Wanda

Is the project number correct?* WQ0040672
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Accepted Date: 4/25/2022

SUBMIT FORM ON YELLOW PAPER ONLY
Margoriginal DEPARTMENT OF ENVIRONMENTAL QUALITY i DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: con INFORMATION PROCESSING UNIT
--and 1 cop to-:
�
COMPLIANCE REPORT FORM _ �� 1617 MAIL SERVICE CENTER,RALEIGH,NC27699.1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 12/31/2024
Facility Name: Stevens Towing-Riverbulk Terminal Non-Discharge WQ0040672 UIC
Permit Name (if different): NPDES Other
Facility Address: Edenton,NC 27932 TYPE OF PERMITTED OPERATION BEING MONITORED
Edenton.NC 27932 County Chowan El Lagoon ❑Remediation: Infiltration Gallery
0 Spray Field El Remediation:
Contact Person: Simon Rich,Ill Telephone#: [phone] El Rotary Distributor ❑Land Application of Sludge
Well Location/Site Name:MW-1 No.of wells to be sampled: 3 El Water Source Heat Pump ❑Other:
(From Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-i Date sample collected: 3/15/2022 FIELD ANALYSES: WAS
Well Depth: 15 bgs ft. Well Diameter: 2 in. pH 00400: units Temp.00010: 4.1 °C DRY at
time of
Depth to Water Level 82546: 13.45 ft.below measuring point Screened Interval: 9 ft. to 15 ft. Spec. Cond.00094: µMhos sampling,
Measuring Point is 2•95 ft. above land surface Relative M.P. Elevation: 23.92 ft. Odor 00085: none check
Volume of water pumped/bailed before sampling: 5 gallons Appearance clear/yellowish here:
Samples for metals were collected unfiltered: Li YES El NO and field acidified: Eil YES ❑NO
LABORATORY INFORMATION
Date sample analyzed:4/5/2022 Laboratory Name: Environmental Chemists,Inc. Certification No, 20-45107
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 <0.02 mg/L Pb-Lead 01051 <0.01 ug/L
Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO3)as N 00620 1.53 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 0.44 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 67 mg/L Al-Aluminum 01105 mg/L
pH(Lab)00403 units Ba-Barium 01007 0.055 ug/L
TOC o0680 11.6 mg/L Ca-Calcium o0916 mg/L
Chloride 00940 <5 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total oio34 .020 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? If Yes(1) ❑ No(0)
Specific Conductance 00095 µMhos K- Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 <0.02 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3 as N.Ammonia Nitrogen,Total) Mn-Manganese 01055 0.045 ug/L , method#
TKN as N 00625 1.53 mg/L Ni-Nickel 01067 <0.01 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory.-I am aware that there are significant,penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations.
Kay.t, Geork 1/4,114.t...kir I, 0 re.eost
4/18/2022
Permittee(or Authorized Aame and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.05-02-2017

SUBMIT FORM ON YELLOW PAPER ONLY
Mail original DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
aTi I copy to:
COMPLIANCE REPORT FORM �� --_ 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 12/31/2024
Facility Name: Stevens Towing-Riverbulk Terminal Non-Discharge WQ0040672 UIC
Permit Name(if different): NPDES Other
Facility Address: Edenton,NC 27932 TYPE OF PERMITTED OPERATION BEING MONITORED
Edenton.NC 27932 County Chowan ❑ Lagoon ❑Remediation: Infiltration Gallery
❑• Spray Field 0 Remediation:
Contact Person: Simon Rich, III Telephone#: [phone] ❑ Rotary Distributor ❑Land Application of Sludge
Well Location/Site Name:MW-3 No.of wells to be sampled: 3 El Water Source Heat Pump ❑Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-3 Date sample collected: 3/15/2022 FIELD ANALYSES: WAS
Well Depth: 25 bgs ft. Well Diameter: 2 in. pH 00400: 5.96 units Temp.00010 4.1 Sc DRY at
Depth to Water Level 82546: 19.66 ft.below measuring point Screened Interval: 17 ft. to 25 ft. Spec. Cond.00094: µ time ofMhos sampling,
Measuring Point is 3.23 ft. above land surface Relative M.P. Elevation: 42.94 ft. Odor 00085: none check
Volume of water pumped/bailed before sampling: 5 gallons Appearance yellowish here:
Samples for metals were collected unfiltered: 0 YES El NO and field acidified: [YES ❑NO
LABORATORY INFORMATION
Date sample analyzed:4/5/2022 Laboratory Name: Environmental Chemists,Inc. Certification No. 20-45107
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 <0.02 mg/L Pb-Lead 01051 <0.01 ug/L
Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO3)as N 00620 1.11 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 0.53 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 244 mg/L Al-Aluminum 01105 mglL
pH (Lab)00403 units Ba-Barium 01007 0.068 ug/L
TOO 0068o 10.8 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 <5 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 0.022 ug/L
Grease and Oils 00552 mg/L Cu -Copper 01042 mg/L ORGANICS:(by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? El Yes(1) El No(0)
Specific Conductance o0095 µMhos K-Potassium 00937 mg/L VOC 7873 , method# SM 6200E
Total Ammonia 00610 <0.02 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen,NH3as N.Ammonia Nitrogen,Total) Mn-Manganese 01055 0.115 ug/L , method#
TKN as N 00625 1.11 mg/L Ni-Nickel 01067 0.013 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory.I amaware that there are significant enalties for submittin false. information,including'the possibilityof fines and imprisonment for knowingviolations.
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Kev fh. G ae7 v. INIA..rk wr4c1.' D fer,47st' ��....-, 4_. 4/18/2022
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.05-02-2017

SUBMIT FORM ON YELLOW PAPER ONLY
I original DEPARTMENT OF ENVIRONMENTAL QUALITY•DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: �= - Q
COMPLIANCE REPORT FORM
` 1617 MAIL SERVICE CENTER,RALEIGH,NC- INFORMATION 7699-1617 UNPhone:919-807.6306
�� �` ���
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date:_12/31/2024
Facility Name: Stevens Towing-Riverbulk Terminal Non-Discharge WQ0040672 UIC
Permit Name(if different): NPDES Other
Facility Address: Edenton,NC 27932 TYPE OF PERMITTED OPERATION BEING MONITORED
Edenton.NC 27932 County Chowan ❑ Lagoon ❑ Remediation: Infiltration Gallery
El Spray Field ❑ Remediation:
Contact Person: Simon Rich,Ill Telephone#: [phone] ❑ Rotary Distributor ❑Land Application of Sludge
Well Location/Site Name:MW-4 No.of wells to be sampled: 3 El Water Source Heat Pump ❑Other:
(from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-4 Date sample collected: 3/15/2022 FIELD ANALYSES: WAS
Well Depth: 17 bgs ft. Well Diameter: 2 in. pH 00400: 6.87 units Temp.0o010: 4.1 °C DRY at
time of
Depth to Water Level 82546: 14.27 ft. below measuring point Screened Interval: 11 ft. to 17 ft. Spec.Cond.00094: µMhos sampling,
Measuring Point is 3.12 ft.above land surface Relative M.P. Elevation: 23.98 ft. Odor 00085: none check
Volume of water pumped/bailed before sampling: 5 gallons Appearance clear here:
Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: IN YES ❑NO
LABORATORY INFORMATION
Date sample analyzed:12/2/2021 Laboratory Name: Environmental Chemists,Inc. Certification No. 20-45107
PARAMETERS NOTE:Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N o0s15 <0.02 mg/L Pb-Lead 01051 <Q,01 ug/L
Coliform: MF Fecal 31616 <1 /100mL Nitrate(NO3)as N o0620 0.03 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 <0.04 mg/L
(Note. Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 161 mg/L Al-Aluminum 01105 mg/L
pH(Lab)00403 units Ba-Barium 01007 0.043 ug/L
TOC oos8o 25.1 mg/L Ca-Calcium 00916 mg/L
Chloride 00940 13 mg/L Cd-Cadmium 01027 ug/L
Arsenic o1002 ug/L Chromium:Total 01034 <0.01 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS: (by GC,GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? ❑■ Yes(1) ❑ No(0)
Specific Conductance 00095 µMhos K-Potassium 00937 mg/L VOC 7873 , method# SM 62008
Total Ammonia o0610 <0.2 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen;NH,as N.Ammonia Nitrogen,Total) Mn- Manganese 01055 0.032 ug/L , method#
TKN as N 00625 0.03 mg/L Ni-Nickel 01067 <0.01 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
I certifythat,to the best of knowledge andbelief,the information in this report is true,accurate,landcom complete,and that the laboratoryanalytical data wasproduced using approved methods of analysis bya
rnY 9 [? R . Yt PP Y
DWR-certified laboratory, I am aware that there are significant enalties for submittin false information,includin the possibility of fines and-imprisonment for knowin violations,..
Ke ink.\ G ,e, , t,/,‘,,- .,, rA-er 0r crc.l-or- 4 y 4/18/2022
Permittee(or Authorized Agent Name and Title-Please print or type I Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev,05-02-2017

WQ0040672
I Enter date monitoring results were due. ) Will this monitoring report(GW-59 and GW-59A) YLS
be submitted after the established due dale?
Was any required information missing on the GW-59 report forms? YES
r IF the answer to question 1 Qf 2 is "YES", list in the space provided below the well identification number(s)and
explain the problems encountered in obtaining the required information,
3Are an Of the monitor wells in need of repair or maintenance(damaged easing.unlocked or missing eap,missing YES tNciO)
identification plate,area overgrown,etc.)?If the answer is 'Yes",contact the Regional Office for stildonee.
L .
4 Are any monitored constituents equal to or above the established standards? YES
the answer to question 4 is'WO", skip to section 8.
If the answer to question 4 is"YES"list the affected wells individually wall constituent(s)and concentration(s)
exceeding standards in the space provided below:
5 For the constituents identified in question 4 above,hati xcdre'iuy for the YESVD)
:me constituent(s)in the same well(s)in the last two years?
If the answer to question 5 is"NO",skip to section 8.
If the answer to question 5 is"YES",list in the space provided below, each well with constituent(s)exceeding
standards, concentration(s)reported,and sample collection date for each occurrence(for the last two years).
4--
) 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? 'YES NO
' if the answer is"YES",a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE.If the answer is"NO", monitoring wells may be Improperly
located;contact the Regional Office.
7 is the permittee implementing previously approved actions required by the Division involving this YES NO
groundwater quality problem?
-1-) —
If the answer to question 7 is "YES", describe those actions in the space provided below
if the answer to question 7 ie"NO",contact Me Regional Office$,vithin PO days;an evaluation may be
required to determine the fauna the waste die,•- system if haying at the ravlew and Coinglience
boundaries surrounding thIsfecliltv, Feliqre_to do so inevigOject the permittee to a Notice of Violation,
fines,aiadior oenaMes,
8 The person completing this portion(GW-59A)of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
404*
J6' " 1_1 I gi GC.
Signature of Permittee(or Authorized Agent) Date

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ANALYTICAL&CONSULTING CHEMISTS infiva environmentaIchernists,corn
Quible &Associates Date of Report: Apr 05, 2022
PO Box 870 Manteo Report#: 22M-516
Kitty Hawk NC 27946 Report#: 2022-04795
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing MW
1 ,
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-11516 Site: MW-1 3/15/2022 11:10 AM Water Client
Test Method Results Date Analyzed
Lead EPA 200.7,Rev 4.4,1994 <0.01 mg/L 03/23/2022
Manganese EPA 200.7,Rev 4.4,1994 0.045 mg/L 03/23/2022
Nickel EPA 200.7,Rev 4.4,1994 <0.01 mg/L 03/23/2022
Barium EPA 200.7,Rev.4.4,1994 0.055 mg/L 03/23/2022
Chromium EPA 200.7,Rev.4 4,1994 0.020 mg/L 03/23/2022
Ammonia Nitrogen EPA 350 1,Rev 2 0,1993 < 0.2 mg/L 03/18/2022
Total Dissolved Solids (TDS) SM 2540 C-2015 67 mg/L 03/17/2022
Total Phosphorus SM 4500 P(F-11)-2011 0.44 mg/L 03/23/2022
Total Organic Carbon (TOC) SM 5310 B-2014 11.6 mg/L 03/17/2022
Chloride SM4500 CI E 2011 < 5 mg/L 03/18/2022
Nitrate Nitrogen (Cale)
Nitrate+Nitrite-Nitrogen EPA 353 2,Rev 2 0,1993 1.53 mg/L 03/21/2022
Nitrate Nitrogen Subtraction Method 1.53 mg/L 04/04/2022
Lab ID Sample ID: M-775 Collect Date/Time Matrix Sampled by
22-11517 Site: MW-1 3/15/2022 11:10 AM Water Client
Test Method Results Date Analyzed
Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 03/16/2022
Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 03/15/2022
Report#::2022-04795 Page 1 of 3

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ANALYTICAL&CONSULTING CHEMISTS 010a erwironmentalchemists.corn
Quible&Associates Date of Report: Apr 05, 2022
PO Box 870 Manteo Report#: 22M-516
Kitty Hawk NC 27946 Report#: 2022-04795
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing MW
Lab ID Sample ID: Collect DatefTime Matrix Sampled by
22-11518 Site: MW-3 3/15/2022 10:40 AM Water Client
Test Method Results Date Analyzed
Lead EPA 200.7,Rev 4.4,1994 <0.01 mg/L 03/23/2022
Manganese EPA 200.7,Rev 4.4,1994 0.115 mg/L 03/23/2022
Nickel EPA 200.7,Rev 4.4,1994 0.013 mg/L 03/23/2022
Barium EPA 200.7,Rev.4.4,1994 0.068 mg/L 03/23/2022
Chromium EPA 200.7,Rev.4.4,1994 0.022 mg/L 03/23/2022
Ammonia Nitrogen EPA 350.1,Rev.2.0,1993 < 0.2 mg/L 03/18/2022
Total Dissolved Solids (TDS) SM 2540 C-2015 244 mg/L 03/17/2022
Total Phosphorus SM 4500 P(F-H)-2011 0.53 mg/L 03/23/2022
Total Organic Carbon (TOC) SM 5310 B-2014 10.8 mg/L 03/17/2022
Chloride SM4500 CI E-2011 < 5 mg/L 03/18/2022
Nitrate Nitrogen (Calc)
Nitrate+Nitrite-Nitrogen EPA 353.2,Rev.2.0,1993 1.11 mg/L 03/21/2022
Nitrate Nitrogen Subtraction Method 1.11 mg/L 04/04/2022
Lab ID Sample ID: M-776 Collect Date/Time Matrix Sampled by
22-11519 Site: MW-3 3/15/2022 10:40 AM Water Client
Test Method Results Date Analyzed
Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 03/16/2022
Fecal Coliform SM 9222 0-2015 MF <1 Colonies/100mL 03/15/2022
Report#,.2022-04795 Page 2 of 3

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ANALYTICAL&CONSULTING CHEMISTS innfo(aa ennvironmentaichean ists.conna
Quible &Associates Date of Report: Apr 05, 2022
PO Box 870 Manteo Report#: 22M-516
Kitty Hawk NC 27946 Report#: 2022-04795
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing MW
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-11520 Site: MW-4 3/15/2022 11:45 AM Water Client
Test Method Results Date Analyzed
Lead EPA 200.7,Rev 4.4,1994 <0.01 mg/L 03/23/2022
Manganese EPA 200.7,Rev 4.4,1994 0.032 mg/L 03/23/2022
Nickel EPA 200.7,Rev 4.4,1994 <0.01 mg/L 03/23/2022
Barium EPA 200.7,Rev.4.4,1994 0.043 mg/L 03/23/2022
Chromium EPA 200.7,Rev.4.4,1994 <0.01 mg/L 03/23/2022
Ammonia Nitrogen EPA 350.1,Rev.2.0,1993 < 0.2 mg/L 03/18/2022
Total Dissolved Solids (TDS) SM 2540 C-2015 161 mg/L 03/17/2022
Total Phosphorus SM 4500 P(F-H)-2011 < 0.04 mg/L 03/23/2022
Total Organic Carbon (TOC) SM 5310 B-2014 25.1 mg/L 03/17/2022
Chloride SM4500 CI E-2011 13 mg/L 03/18/2022
Nitrate Nitrogen (Calc)
Nitrate+Nitrite-Nitrogen EPA 353.2,Rev.2.0,1993 0.03 mg/L 03/21/2022
Nitrate Nitrogen Subtraction Method 0.03 mg/L 04/04/2022
Lab ID Sample ID: M-777 Collect Date/Time Matrix Sampled by
22-11521 Site: MW-4 3/15/2022 11:45 AM Water Client
Test Method Results Date Analyzed
Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 03/16/2022
Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 03/15/2022
Comment'
,
ommen
Reviewed by , ,°/ / .4;., ......-
Report#::2022-04795 Page 3 of 3

Environmental Chemist, Inc" Wilmington, NC Lab#94
GGOZ Windmill Way
Wilmington, NC 28405
Sample Receipt Checklist 910393.0233
Client: Date: � L- Report Number:_ 2022- (_
Receipt ofsample: E HEMP/ckup [] Client Delivery [] /UPS)( FedEx [] Other00YES [] NO N/A 1 VVerecustody seabpresent o /th cooler?
0 YES 0 NO NIA 2. If custody seals were present, were they intact/unbroken?
Original temperature upon receipt C Corrected temperature upon receipt C
How temperature taken: E3 Temperature Blank JV Against Bottles
IR Gun ID:Thomas Traceable S/N: 210835468 IR Gun Correction Factor*C: 0.0
0 YES 11 NO 3. If temperature of cooler exceeded 6'C, was Project Mgr./QA notified?
Jr4 YES 11 NO 4. Were proper custody procedures (relinquished/received) followed?
YES 0 NO 6. Were samples ID's listed on sample containers?
YES 11 NO 7. Were collection date and time listed on the COC?
YES El NO Were tests to be performed listed on the COC?
YES 0 NO 9. Did samples arrive in proper containers for each test?
res YES 0 NO ' 10. Did samples arrive in good condition for each test?
11. Was adequate sample volume available?
YES ID NO 12. Were samples recei'ved within proper holding time for requested tests?
YES 0 N 13. Were acid preserved samples received at a pH of<2?
ED] YES 0 NO 14. Were cyanide samples received at a pH >12?
YES 0 NO 15. Were sulfide samples received at a pH>9?
YES 11 NO 16. Were NH3/TKN/Phenol received at a chlorine residual of<0.5 m/L?
YES El NO 17. Were Sulfide/Cyanide received at a chlorine residual of<0.5 m/L?
YES El NO .18. Were orthophosphate samples filtered in the field within 15 minutes?
TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet.
Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet.
Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace)
Sample(s) were received incorrectly preserved and were adjusted accordingly
by adding (circle one): H2SO4 HNO3 HCI NaOH
Time of preservation: If more than one preservative is needed, notate in comments below
Note:Notify customer service immediately for incorrectly preserved samples.Obtain a new sample or
notify the state lab if directed to analyzed by the customer.Who was notified,date and time:
Volatiles Sample(s)
were received with headspace
COMMENTS:
DO[. ClA.O02 Rev 1

dmill Way
on,NC
fi m ENVIRONMENTAL CHEMISTS, INC o��EIn910�92-0223IIFAx9t10�92-n4zali
Analytical&Consulting Chemists
NCDENR:DWQ CERTIFICATION#94 NCDHHS:DLS CERTIFICATION#37729 [e-mail]
COLLECTION AND CHAIN OF CUSTODY
Client: Quible and Associates PROJECT NAME: Stevens Towing-Edenton, NC REPORT NO: I kO
ADDRESS: Post Office Drawer 870 Permit:WQ0040672 PO NO: 22.—y ZI-' S
Kitty Hawk,NC 27966 REPORT TO: Brian Rubino, P.G. PHONE/FAX:
COPY TO: Simon Rich/Stevens Towing email: [e-mail]
Sampled By: SAMPLE TYPE:I=Influent,E=Effluent,W=Well,ST=Stream,SO=Soil,SL=Sludge, Other:
Collection d y m _ d PRESERVATION
L a a cc7 c ®w
Sample Identification ®F E o` c `o ��0 E ca* z U o o ® ANALYSIS REQUESTED
Date Time Temp o LI " ' " z Z = ci
i I 1,110Ae, c
MW: SO Vt. l G G X Chloride, NO2,TDS
j
Depth to water: , ® G G C�"' 1��1� X <'Z NH3,NO3,P
C P
Gallons Bailed: S G G X `2 Ba,Cr,Pb,Mn,Ni
C P
HLfield)S G G X Fecal Coliform
, C P
'color: CI i 1,4eque:0-,, G G X . TOC
C P
odor: G G X VOC's(November)
I C P
G G
C P
G G
Total of 3 wells(1,3,4)due in March,July and November.
Kit Transfer ( Relinquished By: Date/Time Received By: Date/Time
2�. y` e ',re') e r i pas
Temperature when Received: 4-. i Accepted: Re-'icte : Resample R uested:
Delivered By: Received B — Date: -6 Xte, 22- Time: 12-00
Comments: TURNAROUND:

_-_,-A---Xle--::7:i-A,.:---.,_. 6602 Windmill VVay Wilmington,NC 28405
vemn_rocrierry ENVIRONMENTAL CHEMISTS, INC OFFICE:910-392-0223 FAX [phone]
NCDENR:DWQ CERTIFICATION#94 NCDHHS:DLS CERTIFICATION#37729 [e-mail]
Analytical&Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
Client:Quible and Associates PROJECT NAME:Stevens Towing-Edenton,NC REPORT NO: 2-2-1'{.51 ka
ADDRESS: Post Office Drawer 870 Permit:WQ0040672 PO NO: Z2 -L-1-- -9 5
Kitty Hawk, NC 27966 REPORT TO: Brian Rubino, P.G. PHONE/FAX:
COPY TO:Simon Rich/Stevens Towing email:brubino©quible.com
Sampled By: SAMPLE TYPE: I=Influent,E=Effluent,W=Well,ST=Stream,SO=Soil,SL=Sludge,Other:
Collection 2
s PRESERVATION
' aa it
..
Sample Identification t gL., il. a - .iiiis t,' cog 1 ., 3 a 6 2 5 ANALYSIS REQUESTED
0 ga_ i5E 5c1 ,E
. 2 2 111 g
Date i Time Temp a
C
MW: On- G G till tio x Chloride,NO2,TDS
_
C P
, ,
Depth to water fq,w(is .
G G 4..)5 x 2-1 NH3,NO3,P
C P
i 5
Gallons Bailed: G G 61 X -te Ba,Cr,Pb,Mn,N1
C P
pH(field) , 1 fa G G X Fecal Coliform
-
C ' P
color: \lel,tt)../iStA- G G X TOC
C P
odor Vlore, G G X VOC's(November)
_ _ 0--_
C P
G G
C P
G G ,
Total of 3 wells(1,3,4)due in March,July and November.
i S Transfer Relinquished By: _ ate!Time Received By: DatelTime
- ------- ! i ,
1 A CI ' I ' _...._ fl ' kil / 77.— I. C C -
s„C ' lieribi_ I,
.,.
• • 141 .
2.- - C r . n i / 4,-- _ --
4
a .
Temperature when Received: F3 (..._ Accepted. L''' -cted: Resample Requested:
Delivered By: Received By: 6 4 Date: Time: 12-00
Comments: TUR AR ND:

------ ------= -a------=__ 6602 VVindmill Way Wilmington,NC 28405
lotild-r0Cheiti, ENVIRON ENTAL CHE ISTS INC OFFICE:910-392-0223 FAX [phone]
NCDENR:DWQ CERTIFICATION#94 NCDHI-IS:DLS CERTIFICATION#37729 [e-mail]
Analytical&Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
,,--
Client:Quible and Associates PROJECT NAME: Stevens Towing-Edenton, NC REPORT NO: 272 , I -.
ADDRESS: Post Office Drawer 870 Permit:WQ0040672 PO NO: Z2--1-1-+9
Kitty Hawk, NC 27966 REPORT TO: Brian Rubino,P.G. PHONE/FAX:
COPY TO: Simon Rich/Stevens Towing email:brubin•qiquible.com ,
Sampled By: SAMPLE TYPE:I=Influent, E=Effluent,W=Well,ST=Stream,SO=Soil,SL=Sludge,Other:
Collection 2 .- . PRESERVATION
8 e 0 LTJ. eD , J12 ,__ — —J — m
Sample Identification Eg: 1:2. `2E it; 8 s, 1913 z V , g 8 g 0 5 ANALYSIS REQUESTED
i)i- g ro 8 9.... cf, E 1 2 2 ?
Date Time Temp 0 _
" - 1:45- C C'
mw: Z071.- G KTT) X Chloride, NO2,TDS
P Depth to water: 114.z G G IS \S X ".---/ 2 NH3,NO3,P
(co:en C P
k'r
Gallons Bailed: Z vei) G G X sCIP Ba.Cr,Pb,Mn,Ni
C P
pH(fleld): 511--- G G X Fecal Colifoml
- .
C P
loolor Cleci, v i G G X TOC
C P
odor: itdirle„, G H X VOC's (November)
- ,
C
G G
1 C P
G G
Total of 3 wells(1,3,4)due in March,July and November,
mr0 c_ Transfer--T ( i Relinquished By: Date/Time Received By: DatelTIme
1
1. -S 4 g" kit," , iy ?-z.... v5-0.fot C:1 ok-
2g „
Temperature when Received: ., Accepted: Re t d: Resample quested:
Delivered By: Received By: . Date:a t 22—.Time: 11_DC)
Comments: TURNAR UND:

ovolviv11101110:11-0001,100000111111111111111111111111111111111111,111,11,0000111
147,4, ,1111,vir •1111, ,1111,mm,11111111 mm..... 1111 H Id 11,..i 1111.... :11 11,11,...,1 mm s In.
''''' '11111111111111111111111111 11111111000000.0
011111!!!1111111600001111010 1,11,01111111„,00111111111111111;1.1,111iP 00 1 111111111111111 111111111111111111111110111111
66021Windmill ay, ilmaington,NC 2840'3 6 910 392 021111211311 MI..41D * 910 392 4424 Fax
11111A10 11111111111111 ,01,111111,0011 11
ofifil 0000lv00000 ull
$11111111 111100 11101111111111111111111111111111111111111111111111101
11 olovill,1111111111111
00001000;00, 11111111111:1000 710 Bowsertown Road,Manteo,NC 2/954 6 252.473.5702 Lab/Fax
255 A ilmingion Highway,Jacksonville,NC 28540 0 910 347.5843 Lab/Fax
violoolv1111111111111111111111111111111111111111111,11111111111JIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII0IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII ,m
ANALYTICALCONSULTING CHEMISTS
lrii info a erwironmentaIchemists.corn
Quible &Associates Date of Report: Apr 05, 2022
PO Box 870 Manteo Report#: 22M-516
Kitty Hawk NC 27946 Report#: 2022-04794
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-11514 Site: PPI -001 Effluent 3/15/2022 11:22 AM Water Client
Test Method Results Date Analyzed
Ammonia Nitrogen EPA 350.1,Rev.2.0,1993 < 0.2 mg/L 03/18/2022
Total Dissolved Solids (TDS) SM 2540 C-2015 95 mg/L 03/17/2022
Total Phosphorus SM 4500 P(F-H)-2011 0.67 mg/L 03/23/2022
Chloride SM4500 CI E-2011 < 5 mg/L 03/18/2022
Nitrate Nitrogen (Calc)
Nitrate Nitrogen Subtraction Method <0.02 mg/L 04/04/2022
Total Nitrogen (Calc)
Total Kjeldahl Nitrogen (TKN) EPA 351.2,Rev.2.0,1993 0.7 mg/L 03/23/2022
Nitrate+Nitrite-Nitrogen EPA 353.2,Rev.2.0,1993 <0.02 mg/L 03/21/2022
Total Nitrogen Total Nitrogen 0.7 mg/L 04/04/2022
Lab ID Sample ID: M-774 Collect Date/Time Matrix Sampled by
22-11515 Site: PPI -001 Effluent 3/15/2022 11:22 AM Water Client
Test Method Results Date Analyzed
, ..,„..._ .......______ ,..,
Fecal Coliform Idexx Colilert-18 <1 MPN/100m1 03/15/2022
Residue Suspended (TSS) SM 2540 D-2015 25.3 mg/L 03/17/2022
pH SM 4500 H B-2011 7.4 units 03/15/2022
Result estimated. Analyzed out of 15 minutes hold time.
Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 03/16/2022
BOD SM 5210 B-2016 13 mg/L 03/17/2022
Comment:
(/ t,
Reviewed by:
,),,,
/
Report#::2022-04794 Page 1 of 1

Environmental Chemist, Inc., Wilmington, NC Lab#94
6GO2 Windmill Way
Wilmington, NC I8405
Sample Receipt Checklist 910.392.0223
~`~�' \ `
C1ient ._^| Q-Je��s \/)��1 y-�� Date� ��\ \ L- Report Number ����-
�� ` _
Receipt ofsample: E�AEM Pickup [] Client Delivery[]
^/ '
Fe`d Ex [ O ther ]U YES O NO A
] YES [ NO . �cus�dy seals p�sento the ^""/er?� N/A 12. If custody seals were present, were they inta ct/un broken?
Original temperature upon receipt . ^ . -C � rectedtemperature uponreceipt How temperature taken: 0Temperature Blank �� Against at Bottles ~[
IR Gun ID:Thomas Traceable S/N: 210835468 /RGun [o�`--
tionFactor`C' OO
[] YES NO 3. If temperature of cooler exceeded 6'C, was Project n~. YES NOcusto notified?
.�� YES NO VVeresannp/e /D's |iste on the CO'�procedures `--�--''``^'``"/ '""»w�u'
YES CYES 0 NO 6. Were samples ID's listed on sample containers?
El NO 7. Were collection date and time listed on the COC?e'v;
YES
El NO
YES 0 NO 9. Did samples arrive in proper containers for each test?
�0n YES 0 NO 10. Did samples arrive in good condition for� ` -S 0 Q -- test?—
samp
vollinie available?
YES JE3 NO 112. Were samples received within proper holding time for requested tests?
YES 11 NO 13. Were acid preserved samples received at a pH of<2?
YES 0 No 14. Were cyanide samples received at a pH >12?
YES 0 NO 15. Were sulfide samples received at a pH >9?
YES 0 NO 16. Were NH3/TKN/Phenol received at a chlorine residual of<0.5 m/L?
YES ,0 NO 17. Were Sulfide/Cyanide received at a chlorine residual of<0.5 m/L?
YES 1:1 NO 18. Were orthophosphate samples filtered in the field within 15 minutes?
TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet.
Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet.
Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace)
Sample(s) were received incorrectly preserved and were adjusted accordingly
by adding (circle one): H2SO4 HNO3 HCI NaOH
Time of preservation: If more than one
preservative is needed, notate in comments below
Note:Notify customer service immediately for incorrectly preserved sampbs.Obtainamew sample or
In"u.vu/co a n � � cacaou/re �utuana4oedbythecosmewhnwasnnbf��dateandbme:
Vo/atUesSannp/e(s)` ' were received with headspace A
COMMENTS/

.-_-_--- --f----- -'----,-- --. 6602 Windmill Way Wilmington,NC 28405
I • 0 TAL I T # I OFFICE:910-392-0223 FAX [phone]
NCDENR:DWQ CERTIFICATION#94 NCDHHS:DLS CERTIFICATION#37729 infot/environmentalchem ists.com
Analytical&Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
Client: Quible and Associates PROJECT NAME: Steven's Towing/Edenton REPORT NO: 11-14 Si Lo
ADDRESS: Post Office Drawer 870 CONTACT NAME: Brian Rubino,P.G. PO NO: 2.2 - LI
Kitty Hawk,NC 27966 REPORT TO: PHONEJFAX:
COPY TO: email:
Sampled By: SAMPLE TYPE:I=Influent,E= Effluent,W=Well,ST=Stream,SO=Soil,SL=Sludge, Other:
Collection .e - , PRESERVATION
— de
Sid
Sample Identification 1.,14 E129 lilt Ill -11 I' ' 3 8 6 9- "6 ANALYSIS REQUESTED
Date Time Temp cc, 8 (39--- 2 Fi E '4 F ig
_
3,/i51 -lk!7-Ziew's C ( )
PPI 001-MU-IF Effluent 7077.- .,-) G 14--nq x BOD,TSS, NO2,pH
C P ,
_
61/1 ,July,Sept.,November G G /OS 16114 X 2-zet4 NH3,Total N(calc),Total P
. _
C P
pH(field): 1 35 G G X Fecal Coliform
C P
G G
— - - _
C P
PPI 001-WWTF Effluent G G X TDS, Chloride
C P
(p:3- July, November G G
- . ..
C P
G G
C P
G G
Transfer Relinquished By: Date/Time - eived By: Date/Time
1.7-N 'TP 1,1 14 3 „...1"-- P 3AS- 7 2- i..Z r 1 c-c , — 0.1°
(IA.5 's
2. rd,,t("Y5 7,5 a4 ct..........., ._ d___ .4-{,i1--, 44-4-,
, 0 gici&
Temperature when Received: '-i•-•V 6. Accepted: •-•"--- - -jected: Resample Requ-sted:
Delivered By: U(2 S Received By ": •\i'4•(-Y1/"1/4---(29—d1/4.-- Date: 1 - 2-7- Time: i 2-00 r
Comments: TU A-OUND: