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HomeMy WebLinkAboutNC0037834_Wasteload Allocation_19940602NPDES DOCUMENT SCANNING COVER SKEET NC0037834 Archie Elledge WWTP NPDES Permit: Document Type: Permit Issuance Wasteload Allocation ) Authorization to Construct (AtC) Permit Modification Complete File - Historical Engineering Alternatives (EAA) Correspondence Owner Name Change Instream Assessment (67b) Speculative Limits Environmental Assessment (EA) Document Date: June 2, 1994 This document is printed cm reuse paper - ignore any content on the reverse aside NPDES WASTE LOAD ALLOCATION PERMIT NO.: NC0037834 PERMITTEE NAME: FACILITY NAME: City of Winston-Salem Archie Elledge WWTP Facility Status: Existing Permit Status: Renewal Major Minor Pipe No.: 001 Design Capacity: 30.0 MGD Domestic (% of Flow): 77.6 % Industrial (% of Flow): 22.4 % Comments: SIU info submitted to pretreatment 1/27/94 by W-S. City requesting Cadmium limit be dropped. See cover letter attached. RECEIVING STREAM: Salem Creek Class: C Sub -Basin: 03-07-04 Reference USGS Quad: C 17 SE County: Forsyth Regional Office: Winston-Salem Regional Office (please attach) Previous Exp. Date: 12/31/94 Treatment Plant Class: Class IV Classification changes within three miles: none rrer ..*zr 71 lima' Requested b, : Gre: Nizic10 , 3/15/94 Prepared �y: .limilmon�ri - Reviewe,r by: �_ vr/ -3F0.1)u.:. grip LQ/I / ' Modeler Date Rec. # ,l(la 3//' /f>G 7799 2 Drainage Area (mi ) LQ ,) Avg. Streamflow (cfs): (�5 7Q10 (cfs) l' Winter 7Q10 (cfs) (3 30Q2 (cfs) ) 9 Toxicity Limits: IWC .7U % Acut Instream Monitoring: Parameters aO, -fempevi fu r? re co I eel, frm CZYldachvl k Upstream '1 (i 3t fe) Location Downstream 3 Locatio (nkke;3kern) Effluent Characteristics Summer Winter BOD5 (mg/1) al NH3-N (mg/1) / . ) CI D.O. (mg/1) e9.5 62.5 TSS (mg/1) ,CIii SO F. Col. (/100 ml) 'cOo until l�l6r lch/ ate; 10I311g4 roco Lv L I IDI91 cJ 4r ' 1,I3 94 pH (SU) (0--ej 12 -.q i PC. LAANS) TP (rY lam') ►'Y)orr tt,,- 1'Y)OYl, }L r j'Y)cn, I-c.- Yr DYI, tur TN (rr I K) Ccv1 m ru,QJ1? 1 Moat toy 0, u(A 1Li -v r,,,n, iv{ l�c , •.,,,.1 ,,'(., Cu ar c.d C `e) Cc9 pe r ( A9) CL I LP ickc) rrv' n t h7Y J L rytA4 NV:. inr' 7,0c, l st) Y1ilcn,i-t.' VYI'ric' L€rr , cu.rren+l�{ I-hckK Y iL.. late t O -Wt c '�,,e{v , U(bC Ctelu4ll.1 e►rrl- ecael mof bI •`itUr-Ir 1 Comments: (r u\ v ec)lxn rn, l' 1-a=r-.u,'1 hCD noted much color ir7 el( lueo Cc i lelfer tc pertniP 6hacld it arrr) 4c C4I, Curren i`-t € amosncn color and rraii deve recce,v,r Strearn. a tar cl zvd, Facility Name: NPDES No.: Type of Waste: Facility Status: Permit Status: Receiving Stream: Stream Classification: Subbasin: County: Regional Office: Requestor: Date of Request: Topo Quad: FACT SHEET FOR WASTELOAD ALLOCATION Request # City of Winston-Salem Archie Elledge WWTP NC0037834 77.7% Domestic/22.4% Industrial Existing Renewal Salem Creek C 030704 Forsyth WS G. Nizich 3/ 16/94 C17SE RECEIVED N.C. Dept. of EHNI APR 14 1994 Winston-Salem 7789 Regional Office Stream Characteristic: USGS # Date: Drainage Area (mi2): Summer 7Q10 (cfs): Winter 7Q10 (cfs): Average Flow (cfs): 30Q2 (cfs): IWC (%): 02115857 1988 67.3 15 18 65 19 75.6 Wasteload Allocation Summary (approach taken, correspondence with region, EPA, etc.) Permit renewed with existing limits for conventional parameters. Current permit has 1000 fecal , and toxicity monitoring only since facility could not meet both WET and fecal coliform due to short chlorine contact time. This monitoring renewed until 12/31 of this year (expiration date of current permit), and 200 fecal limit and WET limit begin on 1/1/95. Special Schedule Requirements and additional comments from Reviewers: 71//S /, e/c./TY'S ."r/°GocoA, T Nos ,9 T,2Gire,.,Ddu. s / 1DC 4S or Co 4_ o e.a / T — TNI s /1 t. s u 4-TS / ,.J A 44 A' CAA 7 I C oc f,? o ,`1 Tx/ . 4,S t..e".4 foi.a/ T 'To 7 .4' YA D/P/l✓ ,Q vet 64- 8. % „7/4-e ). 6J5/20 6)O4 O L./XL. TO SEE LOLO.F Ii A7G4 L, 1, rs Otil 2?./E Asc.✓4,C6E. GlPST..2 ri `F Adoc.,NST,[ddH 1-142 n.1, To.t /AJC, o/ Coco/& A//G 7uI41/e/r/ l9ocxL.d sEd�f 44 V Avr4GEoc(S. ..¢ /8-94- Recommended by: Reviewed by Instream Assessme I c y/j `l Date: /2"-- Regional Supervisor: �,�. ?, �� Date: S Permits & Engineering: /,z , C�'v�l�.f Date: fr/q,7 � Date: i//7/q(1 c. acLuii RETURN TO TECHNICAL SERVICES BY: tact I y TrfY cvn se;,snne r) f- D Y' 515 /c4 2 $xisting Limits: Wasteflow (MGD): BOD5 (mg/1): NH3N (mg/1): DO (mg/1): TSS (mg/1): Fecal Co1. (/100 m1): pH (SU): Residual Chlorine (4/1): TP (mg/1): TN (mg/1): J ecomtnended Limits: Wasteflow (MGD): BOD5 (mg/1): NH3N (mgll): DO (mg/1): TSS (mg/1): Fecal Co1. (/100 ml): pH (SU): Residual Chlorine (µg/1): TP (mg/1): TN (mg/1): CONVENTIONAL PARAMETERS Monthly Average Summer Winter 30 30 21 30 1.2 9 6.5 6.5 30 30 1000 1000 6-9 6-9 Monitor Monitor Monitor Monitor Monitor Monitor Monthly Average December 31, 1994 Summer Winter 30 30 21 33' ', 1.2 9 6.5 6.5 30 30 1000 1000 6-9 6-9 Monitor Monitor Monitor Monitor Monitor Monitor until Monthly Average after December 31, 1994 Summer 30 1.2 6.5 30 200 6-9 Monitor Monitor Monitor Winter 30 30 9 6.5 30 200 6-9 Monitor Monitor Monitor WQ or EL WQ WQ WQ Limits Changes Due To: Parameter(s) Affected Change in 7Q10 data Change in stream classification Relocation of discharge Change in wasteflow Other (onsite toxicity study, interaction, etc.) Instream data New regulations/standards/procedures New facility information (explanation of any modifications to past modeling analysis including new flows, rates, field data, interacting discharges) (See page 4 for miscellaneous and special conditions, if applicable) 3 Type of Toxicity Test: Existing Limit Recommended Limit: Monitoring Schedule: existing Limits COD (mg/): Cadmium (ug/l): Chromium (ug/1): Copper (ug/1): Nickel (ug/l): Lead (ug/1): Zinc (ug/1): Cyanide (ug/l): Recommended Limits COD (mg/): Cadmium (ug/l): Chromium (ug/l): Copper (ug/1): Nickel (ug/1): Lead (ug/1): Zinc (ug/1): Cyanide (ug/l): Limits Changes Due To: New tox procedure for municipalities TOXICS/METALS Chronic Phase II Monitoring only (monthly summer, qrtrly winter, qrtrly prechlorination year round). Existing monitoring until Dec. 31,1994; Limit at 76% after 12/31/94 Jan, Apr, Jul, Oct for quarterly tests Weekly Avg Daily Max 2.6 66 Monitor 116 33 Monitor Monitor 10 264 464 45 Weekly Avg. Daily Max 2.6 10 Monitor in LTMP Monitor in NPDES Monitor in LTMP Monitor in LTMP Monitor in NPDES 6.6 26 (WQ/EL) WQ WQ Parameter(s) Affected Cr, Ni, Pb X Parameter(s) are water quality limited. For some parameters, the available load capacity of the immediate receiving water will be consumed. This may affect future water quality based effluent limitations for additional dischargers within this portion of the watershed. OR No parameters are water quality limited, but this discharge may affect future allocations. INSTREAM MONITORING REQUIREMENTS Upstream Location: Salem Ck at SR 1120 Downstream Location: 1. Salem Ck at SR 2991, 2.) Muddy Ck at SR 1493, 3.) Muddy Ck at SR 14S5 Parameters: DO, temperature, fecal coliform, conductivity Special instream monitoring locations or monitoring frequencies: MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS Adequacy of Existing Treatment Has the facility demonstrated the ability to meet the proposed new limits with existing treatment facilities? Yes No I - t1004f.c.IT D&s LT-,.4' SdoUGO ENA6L.e ff<aC J7 TD NL, .7 If no, which parameters cannot be met? d e AI Fec A'- 4d %oX / c ' T / GP'1 / 7-s . Would a "phasing in" of the new limits be appropriate? Yes - No ' If yes, please provide a schedule (and basis for that schedule) with the regional office recommendations: If no, why not? ,13Z- Ceprr,LX7-4D Z1 /2-3/-9'4-. Special Instructions or Conditions m is Ct.trrerd-iy wor*.ric on a_ r dnenf mode( of c� k lock- 1- c. Upon conclas+on of This m ma reopen J4-z perrnhf to inC<<.+Lte mA rier? hrmia ons, Wasteload sent to EPA? (Major) Y (Y or N) (If yes, then attach schematic, toxics spreadsheet, copy of model, or, if not modeled, then old assumptions that were made, and description of how it fits into basinwide plan) Additional Information attached? Y (Y or N) If yes, explain with attachments. Basic background info, toxics analysis notes • •-. z9nnirs IIl lay Facility Name Wtn&t - 1 eyy, IArthu Eli Permit # NC 3 -63/ Pipe # 001 CHRONIC TOXICITY PERMIT LIMIT (QRTRLY) (**Chronic Toxicity (Ceriodaphnia) ChV at 312.%,dcJr Aorivl 0c , See Part JIL , Condition .) The effluent discharge shall at no time exhibit 48 hour acute toxicity as lethality in an effluent concentration of 1 b % nor measure a quarterly arithmetic average chronic value less than this same percentage of waste. The: chronic value will be determined using the geometric mean of the highest concentration having no statistically detectable impairment of reproduction or survival and the lowest concentration that does have a statistically detectable impairment of reproduction or survival. The presence of 48 hour acute toxicity will be determined using Fisher's Exact Test at 48 hours from test initiation. Collection methods, exposure regimes, and further statistical methods are defined in: The North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure (July, 1991) or subsequent versions. The permit holder shall perform at a minimum, quarterly monitoring using these procedures to establish compliance with the permit condition. The first test will be performed after thirty days from issuance of this permit during the months of , !VOW 0& Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter measures 48 hour acute toxicity or a chronic value less than that specified above, then multiple concentration testing shall be performed, at a minimum, in each of the two following months. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code THP3B for the Chronic Value and TGA3B for the 48 hour Acute Toxicity measure (Pass/Fail). Additionally, DEM Form AT-3 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek.Road Raleigh, NC 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting (within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. Permitted Flow 3) MGD Basin & Sub-basin4' 7Q10 15 cfs Receiving Stream5ctlem Gait IWC '7C4 % County pprsyth Recommended by: � .. l� .v5t0Cwil Date: kikilq4 PIIQLR Version 7/91 Effecito. cA,,,chl ialai Iqq, 5 mpte,3 should be. k x4(e n }tenor FacilityNameWantrGh!°�n�fi � �jem j Archie giltaa Permit # I�Ct 3)g3(/ Pipe # C�1 CHRONIC TOXICITY MONITORING REQUIREMENT (QRTRLY) (**Chronic Toxicity (Ceriodaphnia) Monitoringi)Gtn,apr 304 Oc.# , See Part 211_, Condition1.) The permittee shall conduct chronic toxicity tests using test procedures outlined in: The ,North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure (July, 1991) or subsequent versions. The effluent concentration defined as the Instream Waste Concentration (IWC) shall be 7lv % . The chronic value for this analysis will be determined using the geometric mean of the highest concentration having no statistically detectable impairment of reproduction or survival and the lowest concentration that does have a statistically detectable impairment of reproduction or survival. The presence of 48 hour acute toxicity will be determined using Fisher's Exact Test at 48 hours from test initiation. Collection methods, exposure regimes, and further statistical methods are described by the document referenced above. The permit holder shall perform at a minimum, quarterly monitoring using these procedures to establish compliance with the permit condition. The first test will be performed after thirty days from issuance of this permit during the months ofJan, Apr ciu.I Oc Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter measures 48 hour acute toxicity or a chronic value less than that specified above, then multiple concentration testing shall be performed, at a minimum, in each of the two following months. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code THP3B for the Chronic Value and TGA3B for the 48 hour Acute Toxicity measure (Pass/Fail). Additionally, DEM Form AT-3 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, NC 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting (within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. Permitted Flow 30 MGD Basin & Sub -basin '1acWJ4 7Q10 15 cfs Receiving Stream Salem CreEr- IWC —70 % County Recommended by: C. &.)2(Zk Date: 441ulg4 PIIQMR Version 7/91 Gf ec we. urth l 12131194. Should be -6r aAmmer rnpv lf) ova (Aped- i4pr1 (fibber) Facility Name rtsil n e.rn 1Avrhie. filed Permit #M ca37g34 Pipe # DOI CHRONIC TOXICITY MONITORI G REQUIREMENT (MONTHLY) (**Chronic Toxicity (Ceriodaphnia) Monitoring, /gi-- Ctibber , See Part j, Condition C .) The permittee shall conduct chronic toxicity tests using test procedures outlined in: The North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure (July, 1991) or subsequent versions. The effluent concentration defined as the Instream Waste Concentration (IWC) shall be % . The chronic value for this analysis will be determined using the geometric mean of the highest concentration having no statistically detectable impairment of reproduction or survival and .the lowest concentration that does have a statistically detectable impairment of reproduction or survival. The presence of 48 hour acute toxicity will be determined using Fisher's Exact Test at 48 hours from test initiation. Collection methods, exposure regimes, and further statistical methods are described by the document referenced above: The permit holder shall perform at a minimum, monthly monitoring using these procedures to establish compliance with the permit condition. The first test will be performed after thirty days from issuance of this permit. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All tests performed under this requirement will be performed using the multiple concentration exposure of the above referenced protocol. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code THP3B for the Chronic Value and TGA3B for the 48 hour Acute Toxicity measure (Pass/Fail). Additionally, DEM Form AT-3 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, NC 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting (within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. Permitted Flow 30 MGD Basin & Sub -basin d014 7Q10 cfs Receiving Stream 5atenn (re.eX. IWC "Ito % County t & is i Recommended by: Rtil CAStattai Date: •0 * PIIMMR Version 7/91 frt.;e E11ed 11orp Salem CK 030704 Ct L QUP11.07e. model 1 cb p2Q-d5rntact 1( c -< Apnl 1991). /t rest.t.taz Matti c iciic Jrd eyiksb, Jc kry),1,S ctre rf /ash" permd reneJJ\2.l ictci re cc cIssfe d N/J3 Jun, / / my-/ fb prc J anaans-1- x crIi j. a d ipt. hin4 Arts (61.4.0524 ID C9, 5 mccl Q 11m 5 nx51,P). (6(05 tOas n do -fled s,nL2 laccGfj rde oc SO/5 Y-hvbujk, Major ma cahoh - 1 rmL r ;s pe Lrnh 1 ?Duld a_ very cla& prbi-echn Je it *eam_ 1 (made( flat rt tri 6NQ-e- ithcd Odua / /ern, f,5 c e cJd p►ol-ex!Wahl l } and ,Q511 f7 p eci' ). • 464C Aclue Oled ff score Sc�en�. Ck. Oho?:* AIlDUYIble YYkiAtS (Cp)(Q.tp) + (CA CIA)) (ed G2C1) C.Q:O Cid dandaAd to oc4p = 150,5 Qi 30Th6D CCC)(.6) Cu) kite, olaktede C e)(W.5) 440,5 (s15)(er.5 140.6 .75(Li1.6) 4Lg. s cis caul .u811 t964151,1 ct 3 Atli xt6(1 = 33 +ug (l so Cul. 6) Cu) Z 40S W .5(f / (cep, 5) CIA) '1co . 6 t 05 Nc261414 I5 462.5 = Lzi.5 c� — off. pier noieo txi (4) a.2 (w. s) v u ZIA flU ,Zq obinal �pto At:76 m et oa tc Arc. Copper .. Zinc are_ otdiast_ feud subs ahces So nt _ hfi,k, Will bt, a ass: W, thu)evec jx eat mods hilt& matt c2llwa&e have 1oQew obaselved o rrbiilari'n co && b2 /el/ a... NP S taumil raw Ihcu le'hn3 L.rm P d{a sate. Cc iah; de-- Duon3 pad ye ,., 1eot ha3her '/ho,t alleceable Mil i/mil NP talon- do13 fwe as 2nalcris . A.)l rk.ibn - &dem iArch,i a Ellett Saki& Ct 630704 fc�S 3LTYAN Gutted Mi12is ft*►t (qrl l - KI93 ird►'ecnn mon,fan'nd No vialafior►s 613.5ewecl. /qurne►ous -fecal CoIik►nit. uiofahoho (boFGi updreaht_ a- downstream). Cadn,;tm . C4i0 COoer Miler io perfra hwhat_ 021ed 212.2/94/ C' . a44. Cdtiti 9 l , ,f ead weer o►'� ,.�� ethionn . 3.1 I n,5 cOas r d ad i in. d uma .�,�� s e wet: NdthueI 4ezt o{ eraei CAI Cannot 'nee/ d, They ke r cs k Chi paz,r5 v. ChlariA4._ CztAid Wed ' ! wer a& ack'nos.i 'hat A tis ca,�ld be Jk cpeni� &eats e��e � file ra I S v e per Conutafxsac. 0- I'�10A- bF - CJ'CZdmiam /n efavenf kS ned - bi meat table_ d 1� ("a✓". are ,n fe/ins o/ b , /& e✓e/ dnypnj ' 4 bone tat d ocw s fcedi ke) I dD 412, some. - Ei slictdri do itdher oat 01 treith kcii pr -- wake eiecb to a3 so Co- OWL more CIc$P #1. perm0lee% itipefs iz,„„e4 h&i received a orani• 464 & Al)w4 on. ?re ven/ra.t. to inveslisale Cadnion. Sources. Nok21 CaAdt. of W •S end: ca/ed Secaera.i source,' were fottre e/'m1nafed �r reduced: 0 pktpin3 Ithaca,- a chemical no lortr added cloud keyed C'd Hat %ieveval n� lafilr/ies. Cnpa.f Woo ificdic� oaf a-Ani s . p 2t Idler on 31a4194 siathn6 441 callhatin5 is e W/ ckivi c abaypti _ w 4-his ap,5 mefa,Js mduce,z5 Ck d n um, _ MDblenl- macf now be. sots/ea'. attack co of lellef Ir, ,t oE& 114.. (eCec✓e 14, 'Talked 5fiakc. (A)eth - kQ iooc eld J II 1, k Cc( 4 all rnelals htlid3 .dvDp nu. he Peel5Th' montly fct (ir cL Chem. SIQci e ). _a ni 1- fk ,,t9 VO -chi", [)r tOba • - G2ftcf Citregdzia TOXICANT ANALYSIS Facility Name ^ Winston-Salem;A . Elledge NPDES # NC0037834 Ow (MGD) 30 7Q10s (cfs) ; 15 /WC (%) 7.5.61 Reeving Stream Salem Creek Stream Class C FINAL RESULTS Chromium Max. Pred Cw 39.2 Allowable Cw 66.1 Nickel Max. Pred Cw 112.5 Allowable Cw 116.4 Lead Max. Pred Cw 22.8 Allowable Cw 33.1 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 0 Max. Pred Cw 0 Allowable Cw 0.0 3/25194 PAGE 1 TOXICANT ANALYSIS - Winston Salem Archie Elledge WWTP Parameter = Chromium Parameter = Nickel Standard = �._.»._.�..�50 _ Standard = .»»�._.._»88iµg/1 n BDL=1/2DL Actual Data RESULTS n BDL=1RDL Actual Data RESULTS 1 11 11 Std Dev. 5.673685785 1 14 14 Std Dev. 9.796 2 11 11 Mean 13.67213115 2 13 13 Mean 20.11 3 13 13 C.V. 0.414981814 3 17 17 C.V. 0.487 4 14 14 4 15 15 5 28 28 5 22 22 6 25 25 Mult Factor = 1.4! 6 18 18 Mult Factor = 1.5 7 10 10 Max. Value 28 µg/I 7 14 14 Max. Value 75 8 15 15 Max. Pred Cw 39.2 µg/1 8 21 21 Max. Pred Cw 112.5 9 13 13 Allowable Cw 66.1 µg/1 9 13 13 Allowable Cw 116.4 10 19 19 10 29 29 11 12 12 11 16 16 12 15 15 12 16 16 13 15 15 13 9 9 14 28 28 14 21 21 15 28 28 15 22 22 16 17 17 16 18 18 17 15 15 17 15 15 18 15 15 18 12 12 19 18 18 19 33 33 20 23 23 20 17 17 21 16 16 21 20 20 22 16 16 22 17 17 23 11 11 23 21 21 24 9 9 24 20 20 25 11 11 25 17 17 26 9 9 26 23 23 27 7 7 27 46 46 28 8 8 28 75 75 29 10 10 29 48 48 30 10 10 30 21 21 31 7 7 31 24 24 32 3 3 32 17 17 33 6 6 33 18 18 34 15 15 34 18 18 35 14 14 35 14 14 36 14 14 36 23 23 37 14 14 37 17 17 38 11 11 38 19 19 39 13 13 39 21 21 40 10 10 40 17 17 41 10 10 41 20 20 42 6 6 42 14 14 43 9 9 43 16 16 44 8 8 44 13 13 45 11 11 45 20 20 46 16 16 46 15 15 47 8 8 47 21 21 48 15 15 48 17 17 49 21 21 49 16 16 50 18 18 50 16 16 51 12 12 51 11 11 52 10 10 52 14 14 53 9 9 53 10 10 54 10 10 54 22 22 55 11 11 55 14 14 56 11 11 56 18 18 57 11 11 57 28 28 58 13 13 58 15 15 59 16 16 59 18 18 60 23 23 60 27 27 61 27 27 61 22 22 62 62 25 25 63 63 24 24 3/25/94 PAGE ' TOXICANT ANALYSIS - Winston Salem Archie Elledge WWTP • 'ammeter = !Lead Standard = '._._.�.._ 25 lien n -`* BDL=1/2DL Actual Data RESULTS 1 12 12 Std Dev. 2.523 2 7 7 Mean 12.64 • 3 10 10 C.V. 0.2 4 10 10 `, 5 16 16 ' 6 14 14 Mult Factor = ! 1.21 1.4/1.• A 7 11 11 Max. Value 19 µell Pe 8 15 15 Max. Pred Cw 22.8 µell µell; 4 9 12 12 Allowable Cw 33.1 nil • 10 14 14 11 13 13 12 12 12 13 11 11 14 12 12 15 13 13 16 14 14 17 11 11 "• 18 8 8 19 12 1250 ii 20 10 10 y 21 12 12 22 12 12 23 13 13 2A 12 12 25 12 12 • 26 14 14 • 27 18 18 28 13 13 { 29 17 17 { 30 14 14 31 15 15 32 10 10 33 9 9 34 19 19 35 14 14 ty 36 13 13 ggi 37 12 12 38 13 13 f:: 39 r 15 15 40 13 13 41 14 14 42 8 8 •}{ 43 14 14 r 44 10 10 45 14 14 46 13 13 47 9 9 48 11 11 49 8 8 50 12 12 `• ' 51 11 11 52 14 14 53 10 10 54 15 15 •{"' 55 12 12 56 12 12 57 12 12 58 18 18 59 15 15 60 16 16 { " 61 16 16 62 63 3/25/34 PAGE -"O CITY OF \VINSTO\SALEM PUBLIC WORKS DEPARTMENT P.O. BOX 2511, WINSTON-SALEM, NORTH CAROLINA 27102 March 24, 1994 Mr. Dennis Ramsey North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management 512 North Salisbury Street Raleigh, NC 27604 Dear Mr. Ramsey: = hav-e. coPy. _Ts `ours ? / QUALITYSEC`lION OPERA T IONS BRANCH RECEIVED fAPR 5 TEHNICAL Si,WPORT BRANCH Winston-Salem has recently discovered an urfusual phenomenon which`` exerts a positive interference on the analyses of certain metals at the parts per billion level. This phenomenon also renders spike recovery tests, which are designed to detect such an inter- ference, ineffective. Due to the inability of standard quality control procedures to de- tect this problem, Winston-Salem has inadvertently reported some falsely high metals monitoring results. We have found this interference to significantly affect analyses in the parts per billion range for those heavy metals which absorb light at wavelengths less than 300 nanometers. Cadmium and Nickel analyses appear to be the most affected. Zinc and Lead are also affected, but to a lesser degree. In the case of Cadmium, we have determined that levels in the Elledge Plants effluent are approximately 72% lower than previ- ously reported. While there is no way to reanalyze past samples, we are confident that violations of the plant's effluent Cadmium limit have been reported when the true Cadmium concentration was probably well below the limit. We asked Perkin-Elmer, Corp., the manufacturer of our atomic ab- sorption unit, to explain this phenomenon. David Bass, an Appli- cations Chemist with the company, told us he has encountered this problem before. It is called "Background Attribution", an effect that causes an "across the board" increase in the absorbancy of every absorbing parameter in a sample. We understand that it is this type of total absorbancy increase that adversely impacts spike recovery analyses and prevents the detection of the inter- ference. We have requested a letter from Perkin-Elmer which will provide additional information on this subject. We will forward a copy of this letter to your office when it becomes available. Mr. Dennis Ramsey March 24, 1994 Page 2 Winston-Salem has already implemented laboratory procedures to compensate for this interference. We expect that future Discharge Monitoring Reports will exhibit a decrease in the concentrations of Cadmium and certain other heavy metals. Please feel free to contact me at 910/784-4700 if you have any questions or need additional information. Sincerely, 'Stanl a ebb Wastewater Operations Manager ,et& p A pc: Steve Mauney, Winston-Salem Regional Office Tom Griffin, Utilities Superintendent Barry Shearin, Utility Plants Engineer Lee Byerly, WTP Superintendent/Elledge/MMC Crystal Couch, IWC Supervisor Kathy Southern, Laboratory Supervisor David Bass, Applications Specialist, Perkin-Elmer It 0 PERKIN ELMER The Perkin-Elmer Corporation 3206 Tower Oaks Blvd P.O. Box 2280 Rockville. MD 20852-2280 Ms. Mary Bumgamer City of Winston-Salem Treatment Plant March 24, 1994 Dear Mary: am writing this response to your inquiry concerning background attribution in Flame AA and how to recognize and correct for it. One of the factors that make Atomic Absorption such a powerful analytical tool is that it is element specific where only copper atoms will absorb light from a copper lamp regardless of other metals in the sample. This is not the case in "background" or "nonspecific" absorption since the amount of attribution to the total signal is not related to the amount of analyte. The origin of background arises from the fact that not all of the sample matrix is 100% atomized. These undissociated matrix materials actually absorb the light from the source lamp and would be counted as absorbance by the instrument even though the they are not ground state atoms of the element that you are attempting to measure. Another common source for this problem is tiny particles(salts) that form in the flame when the aerosol liquid has been removed. Either scenario produces the same result: More absorbance is being measured than that produced solely from the analyte of interest which will always produce a high biased result if not corrected for. The three main criteria for evaluating the presence of a potential background problem are analytical wavelength less than 250 nm, dissolved solid content exceeds 0.5- 1 % and the actual analyte content is less than 1 mg/l(ppm). If your analytical conditions meet one of the above, then investigation of a potential background problem needs to be undertaken. My experience has shown this problem actually occuring up to 300 nm. One area of analysis that will typically not indicate this problem is in the use of outside control samples(read against the calibration curve) and in matrix spiking. Control samples are usually a mixture of pure metals in an acid medium generally at fairly low concentrations that do not produce this background effect when read against aqueous standards in the "AA" mode only. Matrix spikes typically produce the same percent recovery whether in "AA" or "AA-BG" mode because the background will be essentially the same in both the original sample and a spike of that sample so the final recovery is not affected despite the fact that Phone (301) 984-4700 Fax (301) 984-4813 PERKIN ELMER The Perkin-Elmer Corporation 3206 Tower Oaks Blvd P.O. Box 2280 Rockville, MD 20852-2280 the original result may be reported higher than actual due to a background problem. Modern instruments provide a readily accessible way of determining whether a background problem exists and how to correct for it. If you place the instrument in the "BG" mode and measure the absorbance of your samples, a positive result indicates that background absorption is occurring. To verify that the background correction system is functioning properly, run standards/samples in the "AA" mode then run in the "BG" mode. Rerun the same set in the "AA-BG" mode. The values obtained in the "AA-BG" mode should match those from the "AA" mode with the "BG" results subtracted from them. Normally, the analyst will analyze in the "AA-BG" mode since the reported values will automatically be corrected for non-specific absorption on the instrument display. I hope this information will answer your questions regarding flame analysis on your instrument. If you have any other questions do not hesitate to call me. Sincerely yours, L o d/1. David L. Bass Sr. AS Product Specialist Perkin-Elmer Corp. (301)-984-4730 Phone (301) 984-4700 Fax (301) 984-4813 CITY OF \VJNSTON-SALEM PUBLIC WORKS DEPARTMENT P.O. BOX 2511, WINSTON-SALEM, NORTH CAROLINA 27102 February 22, 1994 Ms. Coleen Sullins NPDES Permits and. Engineering Unit Division of Environmental Management P. O. Box 29535 Raleigh, NC 27626-0535 Dear Ms. Sullins: Three sets of the documents necessary to renew the NPDES permit for Winston-Salem's Archie Elledge Wastewater Treatment Plant are attached. The plant's current permit NC0037834, expires on Decem- ber 31, 1994. Winston-Salem re nests that DEM delete the current effluent limits for cadmium when -the new permit is issued. The plant consently fails to meet its weekly average limit because there is sufficient cadmium entering the plant from uncontrollable sources to cause a permit violation. More importantly, bioassay analyses of the plant's unchlorinated effluent have shown no evidence of toxicity. This suggests that the numerical limit is much too low. DEM instituted limits on certain heavy metals, such as cadmium, to comply with EPA's Aquatic Life Metals Criteria. The goal of these criteria is to prevent toxic effects on aquatic organisms result- ing from their exposure to heavy metals. Given this, it would be reasonable to expect the Elledge Plant's unchlorinated effluent to exhibit toxicity since it consistently violates the cadmium limit. Biomonitoring data on the plant's ef- fluent, however, shows conclusively that this is not the case. One explanation for this phenomenon, wherein a predicted metals toxicity in a discharge does not occur, is contained in an inter- nal memorandum from EPA's Office of Water to their Division Direc- tors. In this document EPA acknowledges that metals toxicity is sig- nificantly influenced by "site specific factors". These factors vary widely and EPA could not possibly compensate for all of them during the research used to derive the ambient metals .criteria. As a result, there are some discharges for which EPA's metals standards do not and should not apply. Ms. Coleen Sullins February 22, 1994 Page 2 Our data indicates that the Elledge Plant falls into this cat- egory. In that the biomonitoring provisions in the permit are ad- equate to detect and prevent toxicity from any source, Winston-Salem feels that the elimination of the cadmium limit will not endanger the receiving water. We also feel that we are being unfairly regulated in that we are required to meet a limit that is economically impossible to achieve and unnecessary to protect the environment. Thank you for your consideration in this matter and call me at 910/784-4700 if you or your staff need additional information. Sincerely, State ey.. B. Webb Wastewater Operations Manager pc: Barry Shearin, Utility Plants Engineer Lee Byerly, WTP Superintendent/Elledge/MMC Steve Rippey, Asst. WTP Superintendent/Elledge/MMC Crystal Couch, IWC Supervisor Larry Coble, DEM Winston-Salem Regional Office Attachment (s) It Archie Elledge Wastewater Treatment Plant FC CC FINAL CLARIFIERS (-WA s THICKENER NITRIFICATION ACT1vATED SLUOGE a. _ ........ _. 1 P EFFLUENT TO SALEM CREEK Discharge 1/ 001 LEGEND WASTEWATER FLOW - - SLUDGE FLOW p PUMPING STATION S C SLUDGE CONDITIONING C C CHLORINE CONTACT w .. .� ..� FC FLOOD CONTROL PUMP STATION 1 OPTIONAL SLUDGE WASTING 1 1 4 P PRIMARY CLARIFIERS SCHEMATIC FLOW DIAGRAM 1 V SCR. a GRIT REM. 1 1 SECONDARY DIGESTERS Lagoons Land Application AERATED LAGOONS GITY of WIYSTON SALEM PUBLIC WORKS DEPARTMENT P.O. BOX 2511, WINSTON-SALEM, NORTH CAROLINA 27102 t February 7, 1994 Mr. Preston Howard, Director Division of Environmental Management Post Office Box 29535 512 North Salisbury Street Raleigh, N. C. 27626-0535 .1 RE: Notice of Intent to Renew NPDES Permit Archie Elledge WWTP (NC0037834) Winston-Salem, North Carolina Dear Mr. Howard: 30.L. FEB 15 1994 1010.41.‘OF ENVIRO " 'ark MGMNT• FLi, This letter is to notify you that the City of Winston-Salem re- quests the renewal of the NPDES permit for our Archie Elledge Wastewater Treatment Plant. The plant's current permit expires on December 31, 1994. The renewal application, pertinent supporting documents and the processing fee will be submitted to DEM's Permits and Engineering section very shortly. Should you or your staff have questions or need additional infor- mation regarding this matter, please contact Mr. Stan Webb at 910/784-4700. Sincerely, P.W. w Assistant City Manager/Public Works pc: Barry Shearin, Utility Plants Engineer Stan Webb, Muddy Creek Plant Larry Coble, Winston-Salem Regional Office, D. E. M. Coleen Sullins, NPDES Permits Group 1t Attachment to NPDES Renewal Application Description of Sludge Disposal Program Archie Elledge WWTP Winston-Salem, North Carolina Residual sludges produced during the wastewater treatment process are anaerobically digested to a PSRP condition and disposed of by land application on to permitted agricultural lands. All sludges are applied at agronomic rates and the program is regulated by NCDEM via non -point discharge permit WQ0000094. The Muddy Creek Plant produces "1,770 dry tons of sludge annually. This material is applied as a liquid containing "5% solids. Ap- proximately 8.5 million gallons are land applied normally. The City of Winston-Salem disposes of sludges from its Muddy Creek and Archie Elledge Treatment plants under a single program. The City's land application program includes "8,738 acres of permitted farm land in the counties of Forsyth, Davie and Yadkin. At the present time the City land applies sludge on to "2,500 acres annu- ally. It cc: Permits and Engineering Technical Support Branch County Health Dept. Central Files WSRO SOC PRIORITY PROJECT: Yes No X To: Permits and Engineering Unit Water Quality Section Attention: (Greg Nizich) Date: April 15, 1994 NPDES STAFF REPORT AND RECOMMENDATION County Forsyth Permit No. NC0037834 PART I - GENERAL INFORMATION 1. Facility and Address: Archie Elledge WWTP Mailing Address: Facility Location: City of Winston-Salem 2801 Griffith Rd. PO Box 2511 W-S, NC Winston-Salem, NC 27102 2. Date of Investigation: March 8, 1994 3. Report Prepared by: Lee G. Spencer 4. Persons Contacted and Telephone Number: Stan Webb 784-4700 Steve Rippey and Frank Crump - (910)765-0165 5. Directions to Site: From WSRO take North Point/Silas Creek Pkwy. west to Hwy 158 west (Stratford Rd.). Turn west and proceed several traffic lights to Hanes Mall Blvd. Turn left and then immediately right onto Griffith Road. Proceed about one mile to the WWTP on the left. 6. Discharge Points(s), List for all discharge points: Latitude: 36°01'46" Longitude: 80°18'54" U.S.G.S. Quad No. C17SE U.S.G.S. Quad Name W-S West 7. Site size and expansion area consistent with application ? X Yes No If No, explain: Somewhat limited area. 8. Topography (relationship to flood plain included): The WWTP sets along and immediately adjacent to Salem Creek. Units are supposed to be designed with the flood plain in mind. 9. Location of nearest dwelling: Some houses, mobile homes and businesses are within 1000' of the treatment plant. 10. Receiving stream or affected surface waters: Salem Creek a. Classification: C b. River Basin and Subbasin No.: 03-07-04 c. Describe receiving stream features and pertinent downstream uses: Creek flows through mostly rural residential and agricultural areas from this point to its confluence with Muddy Creek and then into the Yadkin River. Part II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. a. Volume of Wastewater to be permitted: (Ultimate Design Capacity) 30.0 MGD b. What is the current permitted capacity of the Waste Water Treatment facility? 30.0 MGD c. Actual treatment capacity of the current facility (current design capacity)? 30.0 MGD based on past staff reports and permits. d. Date(s) and construction activities allowed by previous Authorizations to Construct issued in the previous two years. A to Cs issued May 11, 1992 and March 29, 1993. e. Please provide a description of existing or substantially constructed wastewater treatment facilities: Pretreatment lagoons; screening and grit removal units; primary clarifiers; high rate trickling filters; nitrification tanks; final clarifiers; chlorination with chlorine contact chamber; and flow measurement. Sludge handling facilities consisting of anaerobic digesters and sludge storage lagoons. f. Please provide a description of proposed wastewater treatment facilities: Upgrades and/or replacements of several existing units are in progress. The high rate trickling filters are to be replaced by large single stage nitrification tanks. Additional items to be added include odor control facilities, polymer feed systems, chemical feed systems, dechlorination equipment, an expanded chlorine contact chamber, and gravity sludge thickeners. g. Possible toxic impacts to surface waters: The application states that chlorinated hydrocarbons known to be present in the effluent include: Bromodichloromethane, bromoform, chloroform, and dibromochloromethane. However, letter accompanying NPDES Permit Staff Report Version 10/92 Page 2 application also states that bioassay analyses of the plant's unchlorinated effluent have shown no evidence of toxicity. New permit should require toxicity monitoring and limitation after chlorination and dechlorination. h. Pretreatment Program (POTWs only): Approved. 2. Residuals handling and utilization/disposal scheme: a. If residuals are being land applied, please specify DEM permit no. WQ0000094. b. Residuals stabilization: PSRP * PFRP Other 3. Treatment plant classification (attach completed rating sheet): Class IV 4. SIC Code(s): 4952 Primary 01 Secondary 02 Main Treatment Unit Code: 1 1 0 x 3 PART III - OTHER PERTINENT INFORMATION 1. Is this facility being constructed with Construction Grant Funds or are any public monies involved? Yes 2. Special monitoring or limitations (including toxicity) requests: The city has requested that the effluent limits for cadmium be deleted. They argue that analysis of unchlorinated effluent has shown no evidence of toxicity. With this in mind, this office would propose that the cadmium limits might be slightly increased, rather than eliminated. The increase could be correlated to the maximum value which the plant has consistently met since 1983, ie., 3'OToxicity monitoring and limitation should be imposed after chlorination and dechlorination. (The WWTP expansion includes a larger chlorine contact tank which was added in an effort to consistently pass toxicity tests.) 3. Important SOC, JOC or Compliance Schedule dates: N/A 4. Alternative Analysis Evaluation: N/A 5. Other Special Items: NPDES Permit Staff Report Version 10/92 Page 3 PART IV - EVALUATION AND RECOMMENDATIONS Winston-Salem appears to give above average attention to its wastewater treatment programs and systems. O&M program, pretreatment program and sludge management program are all generally outstanding. This facility's effluent, as well as several others in our region, has a tremendous amount of color in it. The dark color from this discharge is usually evident all the way to the Yadkin River. This office and the City of Winston-Salem have received complaints about the dark color. It would seem that this dark color would have to inhibit photometric/photosynthesis activity for several miles of watercourse. The aesthetic appearance alone is reason enough to correct the problem. This writer would like to see the color issue addressed and reasonable limits imposed. This office does not object to the reissuance of this permit along current Division guidelines. Signature of report preparer Date r///v Water Quality Regional pervisor NPDES Permit Staff Report Version 10/92 4?'5‘ Date Page 4