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HomeMy WebLinkAboutWI0400198_Monitoring (Report)_20210804 p ARCADIS Designrnaturaland&Consultancy fo built assets Mr. Michael Rogers Arcadis U.S.,Inc. UIC Program Manager 111-D Sanders Lane NCDEQ— DWR Bluefield,VA 24605 1636 Mail Service Center Tel 276 322 3879 Raleigh, North Carolina 27699 Fax 276 322 3946 www.arcadis.com Subject: 1st Semi-Annual Groundwater Monitoring Report—2021 Former BP Facility#24163 381 Knollwood Street ENVIRONMENT Winston-Salem, North Carolina 27103 Incident Number: 6400 (Closed) Date: Risk Classification: Low (No Further Action) June 25, 2021 Dear Mr. Rogers: Contact: On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina is submitting the Hardik Patel attached 1st Semi-Annual Groundwater Monitoring Report—2021 for the above referenced site. Phone: Please contact me at (919) 328-5605 with any questions or concerns related to the Report or this incident number. 919.328.5605 Sincerely, Arcadis G&M of North Carolina, Inc. Email: Hardik.Patel@arcadis.com INAS "A'/4 Our ref: Hardik Patel 30013560 AFS Project Manager (GP16BPNA.NC10) Copies: File— BP #24163 ARCADIS !)esign&Consultancy for naturaland Built assets Atlantic Richfield Company c/o BP Products North America, Inc. 1ST SEMI-ANNUAL MONITORING REPORT - 2021 Former BP Facility #24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina NCDEQ Incident #6400 (Closed) Injection Permit #WI0400198 June 2021 1st Semi-Annual Monitoring Report-2021 1ST SEMI-ANNUAL MONITORING REPORT - 2021 Prepared for: Atlantic Richfield Company c/o BP Products North America, Inc. Mr. Kyle Christie—Project Manager Pa/AS 1919 Mariposa Lane Fullerton,CA 92833 Hardik Patel Tel 714.815.8971 AFS Project Manager Prepared by: Arcadis G&M of North Carolina, Inc. 5420 Wade Park Blvd. Suite 350 Raleigh, North Carolina 27607 Tel 919.854.1282 ■ •17.t Fax 919.854.5448 C. Scott Bostian, P.- tEAL North Carolina f E. o. 2 www.arcadis-us.com Senior Engineer �� .'� tt‘ea„ Environmental Our Ref.: -04 30013560 Date: June 10,2021 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged, confidential and exempt from disclosure under applicable law. Any dissemination, distribution or copying of this document is strictly prohibited. arcadis.com ES-1 1st Semi-Annual Monitoring Report- 2021 1st Semi-Annual Monitoring Report—2021 Former BP Facility#24163 381 Knollwood St Winston-Salem, Forsyth County, North Carolina Latitude 36°5' 25.94"N Longitude 80° 17' 11.79"W (Reference Figure 1) Groundwater Incident#: 6400 (Closed) Risk Classification: Low(No Further Action) Reason for Risk Classification: Dissolved-phase Sulfate concentrations above groundwater quality standards (2L) Land Use Category: Industrial/Commercial Source of Release: Former gasoline UST system(s) Date of Release Discovery: 1983 Estimated Quantity of Release: Unknown Cause of Release: Former UST System Responsible Party Atlantic Richfield Company c/o BP Products North America, Inc. Attn: Kyle Christie 1919 Mariposa Lane Fullerton, CA 92833 (714)815-8971 Property Owner Mr. Charles Sherren Thruway Shopping Center, LLC. 7501 Wisconsin Ave., Suite 1500 Bethesda, Maryland, 20814 (301)986-2925 ext.215 ,:r I, �- 44V1 a Professional Engineer for Arcadis G&M of North Carolina, Inc., do cerli,that tft- • ''A ion contained in this report is correct and accurate to the best of my knowledge. Arc dis g� N. -'f . a=rolina, Inc. is licensed to practice geology and engineering in North Carolina. T i cer�gn nt, nbers of the company are C-155 (geology)and C-1869 (engineering). PE f iti;o, t,!vX,-,0",-:4.r.!. ,.:.f A' arcadis.com ES-2 1st Semi-Annual Monitoring Report- 2021 CONTENTS 1.0 Site History and Characterization 5 2.0 Groundwater Monitoring 6 2.1 Groundwater Gauging 6 2.2 Groundwater Sampling 6 2.3 Groundwater Analytical Results 7 3.0 Site Remediation 7 3.1 Remediation Activities to Date 7 4.0 Conclusions and Recommendations 8 TABLES Table 1. Monitoring Well Construction Data Table 2. Groundwater Elevation Data Table 3. Summary of Groundwater Analytical Data FIGURES Figure 1. Site Location Map Figure 2. Site Map Figure 3. Potentiometric Surface Map—April 2, 2021 Figure 4. Groundwater Analytical Data—August 2018—April 2021 Figure 5. Sulfate Isoconcentration Map—April 2, 2021 APPENDICES A—Historical Groundwater Elevation Data B— Laboratory Analytical Report and Chain-of-Custody Record—April 21, 2021 C— Historical Groundwater Analytical Data arcadis.com ES-3 1st Semi-Annual Monitoring Report- 2021 EXECUTIVE SUMMARY On behalf of Atlantic Richfield Company(ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina, Inc. (Arcadis) personnel performed the semi-annual groundwater sampling of groundwater monitoring wells associated with Former BP Facility#24163 located at 381 Knollwood Street, in Winston-Salem, Forsyth County, North Carolina (the Site)on April 2, 2021. All groundwater monitoring activities were conducted in response to the final project evaluation requirement specified in Part VII, Item 5 of the Renewal Issuance of Injection Permit WI0400198 from the North Carolina Department of Environmental Quality(NCDEQ) Division of Water Quality—Aquifer Protection Section in April 2013. On April 2, 2021, Arcadis completed a semi-annual groundwater monitoring and sampling event at the Site. Two (2)groundwater monitoring wells (MW-8R and MW-6)were gauged to determine the depth to water(DTW). DTW ranged from 12.16 feet below top of casing (btoc) in groundwater monitoring well MW- 8R to 9.55 feet btoc in groundwater monitoring well MW-6. The historical groundwater flow direction for the Site is towards the southeast. On April 2, 2021, groundwater samples were collected from groundwater monitoring wells MW-8R and MW-6. The maximum concentrations of selected dissolved-phase COCs found during the April 2021 sampling events are summarized in the table below: Maximum Groundwater Concentrations (April 2, 2021) Chemical of Monitoring Well Concentration North Carolina Concern ID (mg/L) Groundwater (COC) Quality(2L) Standards Sulfate MW-8R 306 250 Note:Concentration in Bold exceeds the applicable North Carolina GCL Standard mg/L: milligrams per liter Dissolved phase sulfate concentrations decreased compared to historical groundwater analytical data. Dissolved phase sulfate was detected above the applicable North Carolina Groundwater Quality(2L) Standard at groundwater monitoring well MW-8R only. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for November 2021. Groundwater monitoring wells MW-8R and MW-6 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-8R and MW-6 for analysis of sulfate by Standard Method 9056A. A Semi-Annual Groundwater Monitoring Report documenting the proposed activities for 2021 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com ES-4 1st Semi-Annual Monitoring Report- 2021 1 .0 SITE HISTORY AND CHARACTERIZATION Former BP Facility#24163 is located at 381 Knollwood Street, Winston-Salem, Forsyth County, North Carolina (the Site). The Site is currently owned by Thruway Shopping Center, LLC. and serves as a parking lot adjacent to surrounding retail stores. The site property is approximately 0.5 acres, covered by asphalt and concrete, and was formerly developed as a retail fueling station which housed gasoline, diesel, waste oil, and kerosene Underground Storage Tanks (USTs). A site location map is presented as Figure 1 and a site map is shown as Figure 2. The North Carolina Department of Environmental Quality (NCDEQ) issued groundwater incident number 6400 due to a subsurface release of gasoline that occurred on or before September 14, 1983 from a ruptured product line associated with the UST system. The quantity of the release remains unknown. One (1) 10,000-gallon steel gasoline UST, three (3) 6,000-gallon steel gasoline USTs, and one (1) 10,000-gallon steel diesel UST were removed from the site in 1990. Three (3) 10,000-gallon gasoline USTs, one (1) 10,000-gallon diesel UST, and one (1) 550-gallon waste oil UST were subsequently installed at the site and the site was purchased by M. M. Fowler, Inc. in January 1994 and continued operation until 2004. The remaining five USTs were removed before 2005 and the site was razed. Site geology and hydrogeology include surficial deposits immediately underlying the site are described generally as sandy silts that grade upward to clayey silts and silty clays. Bedrock beneath the site is mapped as a strongly foliated biotite gneiss and schist. The maximum depth of investigation at the site has been approximately 55 feet below ground surface (bgs); bedrock has not been encountered during site investigation work. Historically, the range for shallow groundwater beneath the site is approximately 11 to 14 feet bgs, and groundwater flow direction is toward the southeast with an apparent horizontal gradient of approximately 0.012 feet per foot(ft/ft). The calculated groundwater seepage velocity for shallow groundwater beneath the site is approximately 2.8 feet per year. Two activated sodium persulfate injections were performed at the Site on June 4—9, 2012 and June 3— 6, 2013 under Underground Injection Control (UIC) Permit#W10400198 which was issued by the NCDEQ Division of Water Quality on August 9, 2011. Approximately 11,237-gallons of sodium persulfate and 6,826-gallons of sodium persulfate were injected at the Site on June 4—9, 2012 and June 3—6, 2013, respectively. The NCDEQ Risk Classification for this site was reduced to "Low" on January 23, 2015 after issuing a request for Notice of Residual Petroleum (NORP). The NORP was recorded with the Forsyth County Register of Deeds on March 18, 2015 and imposed the following perpetual restriction on the Site property: • Groundwater: Groundwater from the site is prohibited from use as a water supply. Water supply wells of any kind shall not be installed or operated on the site. No Further Action (NFA)status was granted for the subject incident number by the NCDEQ on April 28, 2015. In accordance with UIC Permit#WI0400198, dissolved-phase concentrations of sulfate are being monitored on a semi-annual basis at the Site. Closure of UIC Permit#WI0400198 will be requested once arcadis.com 5 1st Semi-Annual Monitoring Report- 2021 dissolved-phase sulfate concentrations are no longer detected above the North Carolina Groundwater Quality (2L) Standards. 2.0 GROUNDWATER MONITORING 2.1 Groundwater Gauging On April 2, 2021, Arcadis G&M of North Carolina, Inc. (Arcadis) personnel gauged groundwater monitoring wells MW-8R and MW-6. Groundwater monitoring well MW-19 was paved over and presumed destroyed when Arcadis arrived on site. Arcadis contacted NCDEQ and got approval to sample MW-6 in lieu of MW-19. Gauging was conducted with a water interface probe (IP) prior to purging and sampling to determine DTB and DTW. The IP and attached tape, marked in 0.01-foot increments, were properly decontaminated before each use with Alconox soap and rinsed with distilled water. The DTW was measured from the marked survey point on the top of well casing (TOC). All measurements were recorded to the nearest 0.01-foot increment. The DTW ranged from 12.16 btoc in groundwater monitoring well MW-8R to 9.55 feet btoc in groundwater monitoring well MW-6. Groundwater monitoring well construction details are included in Table 1. Current groundwater elevations are summarized in Table 2. Historical groundwater gauging data is provided in Appendix A. A potentiometric surface map depicting historical groundwater flow direction is provided as Figure 3. 2.2 Groundwater Sampling On April 2, 2021, groundwater monitoring wells MW-8R and MW-6 were purged of stagnant water to prepare for groundwater sampling. Prior to purging, the amount of water to be removed was calculated using the following formula: 3.1415 x r2 x (TD-DTW)x 7.481 = gallons of water(1 well volume) Where: r= radius of well (in feet) TD =total depth of well (in feet) DTW= depth to water(in feet) In order to ensure that the water in the wells after purging is representative of the water in the aquifer, a minimum of three well volumes were removed. Groundwater samples obtained from the groundwater monitoring well were collected from disposable polyethylene bailers using new nylon rope. Groundwater samples were placed in laboratory supplied containers and shipped on wet ice to TestAmerica Inc. in Pensacola, Florida, for analysis of Sulfate (SO4) by Standard Method 9056A. Groundwater samples submitted for sulfate analysis were collected in 250-milliliter plastic bottles. The laboratory analytical report and chain-of-custody record for the April 2, 2021 groundwater sampling event is included as Appendix B. arcadis.com 6 1st Semi-Annual Monitoring Report- 2021 2.3 Groundwater Analytical Results Groundwater analytical data from the April 2, 2021 groundwater sampling event indicated the following: • Dissolved-phase concentrations of sulfate were detected in concentrations exceeding the applicable North Carolina 2L Standard of 250 milligrams per liter(mg/L) in groundwater monitoring well MW-8R (306 mg/L). Current groundwater analytical results are presented in Table 3. Historical groundwater analytical data can be found in Appendix C. A dissolved phase concentration map is presented as Figure 4. A sulfate isoconcentration map depicting the dissolved-phase extent of sulfate exceeding the applicable 2L groundwater quality standard is presented in Figure 5. 3.0 SITE REMEDIATION 3.1 Remediation Activities to Date Summarized in the table below is a chronology of remediation activities performed at the site to date: Date Activity September 14, 1983 Subsurface release of gasoline from a ruptured product line associated with the UST system December 1990 UST systems associated with release removed; 500 tons of contaminated soil removed during UST closure 1992 Vacuum Extraction System Installed 1992 - 1994 Vacuum Extraction System Operation 1994 -2011 Monitoring of site June 4—9, 2012 Activated Sodium Persulfate (ASP) injection event. Approximately 11,237-gallons of sodium persulfate injected. June 3—6, 2013 ASP injection event. Approximately 6,826-gallons of sodium persulfate injected. 2013 - Present Monitored Natural Attenuation arcadis.com 7 1st Semi-Annual Monitoring Report- 2021 4.0 CONCLUSIONS & RECOMMENDATIONS Dissolved-phase sulfate was detected above the applicable 2L groundwater quality standard for sulfate of 250 mg/L in only groundwater monitoring well MW-8R on April 2, 2021. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for September 2021. Groundwater monitoring wells MW-8R and MW-6 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-8R and MW-6 for analysis of sulfate by Standard Method 9056A. A Semi-Annual Groundwater Monitoring Report documenting the proposed activities for 2021 will be submitted to the NCDEQ for review and approval within 45- days of receipt of the laboratory analytical report. arcadis.com 8 Tables Table 1 A ARCJ�D I S Design 8 Consultancy Monitoring Well Construction Data for natural and Former BP Service Station No.24163 built assets 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well TOC Total Well Screen Avg Screen Well Status Type Elevation Depth Diameter(inches) Interval Elevation MW-3 In Use Type II 99.03 20 2 NA - NA NA MW-5 Abandoned Type II 99.39 25.5 4 10.5 - 25.5 81.4 MW-5R In Use Type II NS 20 2 10 - 20 NA MW-6 In Use Type II 98.68 25.5 4 10.5 - 25.5 80.7 MW-6i In Use Type III 99.26 55 2 50 - 55 46.8 MW-8 Abandoned Type II 97.84 24 6 NA - NA NA MW-8R In Use Type II NS 20 2 10 - 20 NA MW-14 In Use Type II 100.44 22 4 7 - 22 85.9 MW-15 In Use Type II 99.91 22 4 7 - 22 85.4 MW-16 In Use Type II 97.42 25 2 10 - 25 79.9 MW-17 In Use Type II 100.00 22 4 7 - 22 85.5 MW-18 In Use Type II NS 20 2 10 - 20 NA MW-19 Destroyed(6) Type II NS 20 2 10 - 20 NA Notes: 1. Reported in feet below grade 2. Measured in feet relative to site datum 3. Conestoga Rover and Associates,a former consultant for this Site, previously reported that no reference was found to the following wells: MW-1, MW-9,MW-10,MW-11,MW-12 or MW-13.These wells are presumed to be abandoned. 4. Monitoring wells MW-5 and MW-8 were abandoned on 5/19/2010 and replaced with monitoring wells MW-5R and MW-8R the same day. 5. Monitoring wells MW-18 and MW-19 were installated on October 25,2011. 6. Monitoring well MW-19 was paved over and presumed destroyed on 3/25/2020. NA=Not Applicable/Available NS=Not Surveyed TOC=Top of Casing Page 1 of 1 Table 2 JR�IJ I ,Mnsultancy Groundwater Elevation Data for natural and Former BP Service Station No.24163 built assets 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina "1121111Date TOC Depth to Depth to LNAPL Corrected Groundwater Groundwater Measured Elevation LNAPL btoc) Thickness Elevation MW-8R 4/2/2021 NS ND 12.16 0.00 NM MW-6 4/2/2021 98.68 ND 9.55 0.00 89.13 Notes: 1. Measured in feet relative to site datum 2. Corr.GW Elev.=(ref.point elevation)-(depth to groundwater)+(LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 LNAPL=Light non-aqueous phase liquid ND=Not Detected NM=Not Measured NS=Not Surveyed TOC=Top of casing btoc=below top of casing Page 1 of 1 Table 3 Summary of Groundwater Analytical Data j R 2l DIS Desnaral ignu&Consultancy Former BP Service Station No. 24163 built 381 Knollwood Street Winston-Salem, Forsyth County, NC Sample ID MW-8R MW-6 Date Sampled 4/2/2021 4/2/2021 Units mg/L mg/L Sulfate 306 24.0 Notes: mg/L-milligrams per liter BOLD text indicates exceendance of NC groundwater standard 2L for sulfate(250 mg/L). Page 1 of 1 FIGURES w fr\ L V I/-.,, ���� o� �� 1 3 �" m ROBS �� V� H �Jw Y� !�`? �� �j \ 1 ��� �' Buena °�pli0�� ,_ _ � O _, RO v OS! 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' L ' �` t o o m \\© m �KEECN — �° Z .,..,..,.,.,_ wzo � C z wHo , 2 ♦, o - it �. ]$CIA r F„ 1 �, ato room/1 1 v ip,, w - REFERENCE: BASE MAP USGS 7.5.MIN.TOPO.QUAD.,WINSTON-SALEM WEST, NC,2016. oFa o, i 0 2000' 4000' oLL.. w ATLANTIC RICHFIELD COMPANY N m aZ Approximate Scale: 1 in.=2000 ft. CIO BP PRODUCTS NORTH AMERICA, INC. Z 5 w s a Hw a FORMER BP STATION 24163 S-a N 381 KNOLLWOOD ST.,WINSTON-SALEM, NORTH CAROLINA o g- o K '8 1st SEMI-ANNUAL MONITORING REPORT-2021 c�go aE j u i oo w o • AREA Ism N LOCATION SITE LOCATION MAP O E a 1x m N U ,� FIGURE AARCADIS 1 ""a " NORTH CAROLINA w w F / O MH. O a LEGEND: H U 2 •UP ,UP /Si, — — — PROPERTY LINE o •UP O. ONCRETE + ABANDONED GROUNDWATER MONITORING WELL W 0 DESTROYED-PAVED OVER E CTRIC GRASS PARKING M:TER FORMER PRODUCT LINE OCB CATCH BASIN oW [0-M 17 ` O M.H. MAN HOLE a ® E AREA LIGHT • U.P. UTILITY POLE F.H. FIRE HYDRANT ` ASPHALT TRASH ❑T TELEPHONE o PARKING ENCLOSURE t',I LARGE MANHOLE COVER MW-3 METAL ` GROUNDWATER MONITORING WELL SHED vZ a O I�JJ I I METAL SHED I III I \ Q Ct I FORMER GASOLINE FORMER '^ UST AREA I C BP SERVICE LL V+ I STATION g NOTE: "a 0 4_ MW-18 CONCRETE O °PAD C ". 1. MONITORING WELL LOCATIONS ARE APPROXIMATE. ( * 2. THE SITE IS A VACANT PARKING LOT.ALL SITE FEATURES EXCEPT 0 PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE CHARACTERISTICS. _1MW-5 MW-5R MW-14 a F.H. 1— FORMER PUMP O S<�iI/ MW-16 i, O $ ISLAND(TYP) I ` O FORMER oc71Z MW-6i 4- MW-8R�Iam CANOPY 4"I T PARKING iMW-19r z • o= b — O▪P RM LaiI FIER I — ` r LVI L DIESEL UST I o AREA S MW-6 o w L__ ► IP FORMER PUMP ^„o I ri, ,n P I ISLAND(TYP) ,g CONCRETE M.; FORMER o z° TANK SOLD Ia a a 0 0 0 0 FORMER 30' 60 Uo m�= • 0 0 o CANOPY I milgam= I 2 Q - GRAPHIC SCALE I ° m FORMER .0 N ( ) VENT RISERS 00 ATLANTIC RICHFIELD COMPANY w aC/O BP PRODUCTS NORTH AMERICA, INC. ao .oap� FORMER BP STATION 24163 _ 381 KNOLLWOOD ST.,WINSTON-SALEM, NORTH CAROLINA 1st SEMI-ANNUAL MONITORING REPORT-2021 o ° O. `� FORMER w°o O mMW-15 VENT RISERS oak 0 SITE MAP Ora E o sm O MH. Y� r 2 a FIGURE 0 AARCADIS I 2 U U0<Q w U W r / F o M H. O a a e LEGEND: 3 F- w • P UP iS4q�O — — — PROPERTY LINE •UP I + ABANDONED GROUNDWATER MONITORING WELL = ONCRETE W * DESTROYED-PAVED OVER co m GRASS 00 MLERRIC P FORMER PRODUCT LINE IARKING C.B. O CATCH BASIN o [ MW17 ` O M.H. MAN HOLE Q T AREA LIGHT a I • U.P. UTILITY POLE F.H. FIRE HYDRANT E. 8 ASPHALT TRASH ❑i TELEPHONE o PARKING ENCLOSURE r_, W ` L__J LARGE MANHOLE COVER MW-3 SH DL ' + GROUNDWATER MONITORING WELL o ZQ (89.13) GROUNDWATER ELEVATION W I METAL SHED (NSVD) NOT SURVEYED TO VERTICAL DATUM LU I I L \ HISTORICAL DEPICTED GROUNDWATER FLOW(FT Co Ct I I AMSL)DIRECTION I FORMER GASOLINE FORMER FT AMSL FEET ABOVE MEAN SEA LEVEL LT '^ UST AREA I C BP SERVICE V/ STATION N I NOTE: -- MW-18 CONCRETE o O l PAD C 1. MONITORING WELL LOCATIONS ARE APPROXIMATE. 0 0 (° •4 2. THE SITE IS A VACANT PARKING LOT.ALL SITE FEATURES EXCEPT 0 PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE ° C CHARACTERISTICS. J MW-5 i,MW-5R MW-14 ,,S< 3. MW-19 WAS UNABLE TO LOCATE, HENCE NOT GAUGED. a` F.H. lMW_8 T FORMER PUMP 44,6 IN MW-16 O I ISLAND(TYP) ` o *MW-8R CANOPY FORMER 71 Z MW-6i 111 �lll(NSVD)) L° a PARKING �oI _ Jz� I -ol I _ IIIO U if V FORMER — `f MW-19 DIESEL UST I z L _ AREA -. MW-6 o S �I` (89.13) P I IP Q I FORMER PUMP O ^ ^ P I ISLAND(TYP) I iCONCRETE am FORMER 0,s a TANK HOLD AI'. a Q a o 0 0 o FORMER 0 30 60' 0 a �. o J 0 CANOPY I I °m GRAPHIC SCALE c'E I I 2a ❑ — o m FORMER 2 m m VENT RISERS ATLANTIC RICHFIELD COMPANY J C/O BP PRODUCTS NORTH AMERICA, INC. s E FORMER BP STATION 24163 ° 0��'� 381 KNOLLWOOD ST.,WINSTON-SALEM, NORTH CAROLINA a s'`A 1st SEMI-ANNUAL MONITORING REPORT-2021 o' �° ���o FORMER m \ VENT RISERS POTENTIOMETRIC SURFACE MAP 5o APRIL 02, 2021 O'2a E O M.H. °Lm sr }z 2 FIGURE UUQ ARCADIS I 3 w w 0 H d / O M H. wH ciI 'iii' UP O. LEGEND: H A No • ONCRETE .) — — — PROPERTY LINE o GRASS ELCTRIC + ABANDONED GROUNDWATER MONITORING WELL a PARKING M TER w I 0 DESTROYED-PAVED OVER [ MW17 FORMER PRODUCT LINE Q C.B.O CATCH BASIN O M.H. MAN HOLE I AREA LIGHT w ASPHALT TRASHTh- • U.P. UTILITY POLE > PARKING ENCLOSURE F.H. FIRE HYDRANT N ` MW-3 METAL 1- TELEPHONE >:-) SHED 7 g �o LARGE MANHOLE COVER U W I / I METAL SHED \ + GROUNDWATER MONITORING WELL !+/ I L mg/L MILLIGRAMS PER LITER az I FORMER GASOLINE I FORMER ` NS NOT SAMPLED a '^ I UST AREA I C BP SERVICE V/ I J STATION LL LEGEND 0 MW-18 CONCRETE Abbreviation Constituent 2 L 0 PAD C SO4 Sulfate 250 2 40. C 0 0('''' • C� 9 MW-5R C MW-144_ �M�W-5 ,S� NOTE: d , F.H. rMW-8 FORMER PUMP I O �tO 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L o MW-16 0 I ISLAND(TYP) r ` MW-8R FORMER Z MW-6i.- I /—CANOPY 2. VALUES IN BOLD EXCEED NORTH CAROLINA 2L STANDARDS. I� S PARKING I I Z a I MW-19— _ J� o2 — a O o --� IIF�II FORMER I— - `rr L I,,j •�I DIESEL UST n - L AREA Z MW-6 OW =I� P N ' P P P FORMER PUMP O P P ISLAND(TYP) a� � n hi I M I I CONCRETE d FORMER o a MW-8R TANK HOLD I �■ G�� o 0 0 o P Ih 0 30' 60' a = Date 8/20/2018 3/15/2019 10/8/2019 3/25/2020 9/1/2020 4/2/2021 FORMER o m g Sulfate 436 60 475 450 442 306 CANOPY I milla w Y I ❑ �J I GRAPHIC SCALE 2 G _ o 0 m N FORMER m m ( VENT RISERS ATLANTIC RICHFIELD COMPANY Lal C/O BP PRODUCTS NORTH AMERICA, INC. s a . FORMER BP STATION 24163 ° 'pOo 381 KNOLLWOOD ST.,WINSTON-SALEM, NORTH CAROLINA a s o MW-6 �� MW-19 1st SEMI-ANNUAL MONITORING REPORT-2021 00 z$ Date 3/25/2020 9/1/2020 4/2/2021 �\, FORMER Date 8/20/2018 3/15/2019 10/8/2019 3/25/2020 9/1/2020 „o A. MW-15 VENT RISERS rgr Sulfate 25.2 38.6 24.0 Sulfate 806 1,150 783 NS NS GROUNDWATER ANALYTICAL DATA o E° AUGUST 2018 -APRIL 2021 O M L H. m yr }z FIGURE UUQ ARCADIS I 4 w w r F / O MH O a a s 3 w 2 U.P. •u.R /844vo d •UP O. _ ONCRETE 0 r0# w GRASS EL CTRIC IARKING M:TER LEGEND: L. Mi-17 PROPERTY LINE o U ` Q ABANDONED GROUNDWATER MONITORING WELL a I 0 DESTROYED-PAVED OVER FORMER PRODUCT LINE C.B. 8 ASPHALT TRASH Q CATCH BASIN w PARKING ENCLOSURE M.H. ` O MAN HOLE MW-3 METAL 1- AREA LIGHT SHED v o �o • U.P. UTILITY POLE I METAL SHED F.H. W I I \ � FIRE HYDRANT L TELEPHONE Z0 I LARGE MANHOLE COVER 6 I FORMER GASOLINE FORMER ` LT UST AREA I C BP SERVICE 4- GROUNDWATER MONITORING WELL o I J STATION 0 -45- MW-18 CONCRETE (306) SULFATE CONCENTRATION(mg/L) 0 0 PAD C 0. 250 ESTIMATED SULFATE CONCENTRATION CONTOUR 0 a. .` 2L STANDARD(mg/L) O (mg/L) MILLIGRAMS PER LITER _4. MW-5R C MW-144- -I F H MW 8 — InMW-5 FORMER PUMP i IC) /S<9LO NOTE: MW-16 , O SLAND(TYP) % 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L FORMER Z ` (�W-gR CANOPY 2. SHADED VALUES EXCEED NORTH CAROLINA 2L STANDARDS. MW-6i ` (306) V- s PARKING zI _ J z I _ IT* I''� , ' p3 I FORMER I — ` � .MW-19 DIESEL UST I z _ AREA_ M4/. o (24.0) P I P Q I FORMER PUMP O ^ ^ P I ISLAND(TYP) I iCONCRETE am FORMER 0,s a TANK HOLD I a Q a o 0 0 o FORMER 0 30 60' J a i i, f o CANOPY I 1� °m GRAPHIC SCALE c'E I I 2< ❑ — 0 , FORMER m m r VENT RISERS ATLANTIC RICHFIELD COMPANY N C/O BP PRODUCTS NORTH AMERICA, INC. s m FORMER BP STATION 24163 ° .000. �0'� 381 KNOLLWOOD ST.,WINSTON-SALEM, NORTH CAROLINA a s N 1st SEMI-ANNUAL MONITORING REPORT-2021 o' C, ��� FORMER v o O m• - VENT RISERS SULFATE ISOCONCENTRATION MAP °io Ea APRIL 02, 2021 �L m OM.H. yr }z E FIGURE UUQ AARCADIS I 5 APPENDIX A Historical Groundwater Elevation Data Appendix A Historical Groundwater Elevation Data A i (�^ R i DIS for natural and Former BP Service Station No.24163 built 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation(1)(2) * 06/24/93 ND 13.89 0.00 85.14 * 08/23/94 ND 14.36 0.00 84.67 * 03/21/95 ND 13.58 0.00 85.45 * 08/05/96 ND 13.54 0.00 85.49 * 11/17/98 ND 14.09 0.00 84.94 * 06/19/01 ND 14.11 0.00 84.92 * 09/12/01 ND 14.41 0.00 84.62 * 12/27/01 ND 14.51 0.00 84.52 * 03/05/02 ND 14.29 0.00 84.74 05/13/03 ND 14.35 0.00 84.68 12/09/03 ND 13.63 0.00 85.40 03/23/06 ND 13.64 0.00 85.39 05/08/07 ND 13.40 0.00 85.63 05/14/08 ND 13.42 0.00 85.61 05/28/09 ND 13.31 0.00 85.72 05/27/10 ND 13.07 0.00 85.96 MW-3 10/31/11 99.03 ND 13.87 0.00 85.16 05/22/12 ND 13.55 0.00 85.48 06/14/12 ND 13.53 0.00 85.50 07/09/12 ND 13.98 0.00 85.05 08/14/12 ND 14.24 0.00 84.79 09/19/12 ND 14.08 0.00 84.95 12/05/12 ND 14.42 0.00 84.61 02/26/13 ND 13.55 0.00 85.48 05/31/13 ND 13.58 0.00 85.45 08/28/13 ND 13.57 0.00 85.46 11/07/13 ND 14.30 0.00 84.73 02/27/14 ND 13.28 0.00 85.75 06/02/14 ND 13.34 0.00 85.69 10/16/14 ND 14.18 0.00 84.85 04/23/15 ND 13.54 0.00 85.49 04/28/16 ND 13.51 0.00 85.52 09/19/16 ND 13.92 0.00 85.11 03/03/17 ND NM 0.00 NM 06/24/93 ND 13.51 0.00 85.88 08/23/94 ND 13.82 0.00 85.57 03/21/95 ND 13.71 0.00 85.68 08/05/96 ND 13.54 0.00 85.85 11/17/98 ND 14.08 0.00 85.31 _ 06/19/01 NM NM NM NM 09/12/01 ND 14.46 0.00 84.93 MW-5 12/27/01 99.39 14.51 15.07 0.56 84.73 03/05/02 14.45 14.88 0.43 84.82 _ 05/12/03 NM NM NM NM 12/09/03_ 13.18 13.60 0.42 86.10 _ 03/23/06 ND 13.67 0.00 85.72 05/08/07- ND 13.45 0.00 85.94 05/14/08 _ ND 13.51 0.00 85.88 05/28/09 ND 13.39 0.00 86.00 Page 1 of 5 Appendix A Historical Groundwater Elevation Data A i (�^ R i DIS for natural and Former BP Service Station No.24163 built 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation(1)(2) 05/27/10 ND 13.70 0.00 NM _ 10/31/11 ND 13.97 0.00 NM 05/22/12 ND 13.66 0.00 NM 06/14/12 ND 13.73 0.00 NM 07/09/12 ND 14.18 0.00 NM 08/14/12 ND 14.45 0.00 NM 09/19/12 ND 14.35 0.00 NM 12/05/12 ND 14.68 0.00 NM 02/26/13 ND 13.89 0.00 NM 05/31/13 ND 13.77 0.00 NM 08/28/13 ND 13.83 0.00 NM MW-5R 11/07/13 NS ND 14.53 0.00 NM 02/27/14 ND 13.39 0.00 NM 06/02/14 ND 13.47 0.00 NM 10/16/14 ND 14.32 0.00 NM 04/23/15 ND 13.69 0.00 NM 10/13/15 ND 14.19 0.00 NM 04/28/16 ND 13.61 0.00 NM 09/19/16 ND 13.99 0.00 NM 03/03/17 ND 14.01 0.00 NM 09/20/17 ND 13.67 1.00 NM 03/01/18 ND 13.62 0.00 NM 08/20/18 ND 13.61 0.00 NM _ * 06/24/93 ND 12.31 0.00 86.37 * 08/23/94 ND 12.61 0.00 86.07 * 03/21/95 ND 13.15 0.00 85.53 * 08/05/96 ND 12.39 0.00 86.29 * 11/17/98 ND 13.16 0.00 85.52 * 06/19/01 NM NM NM NM * 09/12/01 ND 13.51 0.00 85.17 * 12/27/01 ND 13.61 0.00 85.07 * 03/05/02 ND 11.02 0.00 87.66 05/12/03 ND 11.10 0.00 87.58 MW-6 12/09/03 98.68 ND 13.49 0.00 85.19 03/23/06 ND 11.79 0.00 86.89 05/08/07 ND 12.50 0.00 86.18 05/14/08 ND 12.16 0.00 86.52 05/28/09 ND 10.64 0.00 88.04 05/27/10 ND 11.84 0.00 86.84 10/31/11 ND 12.95 0.00 85.73 06/02/14 ND 12.38 0.00 86.30 03/25/20 ND 11.50 0.00 87.18 09/01/20 ND 11.80 0.00 86.88 04/02/21 ND 9.55 0.00 89.13 _ 06/24/93 ND NM 0.00 NM 08/23/94 ND NM 0.00 NM 03/21/95 ND 14.75 0.00 84.51 08/05/96 ND 14.13 0.00 85.13 11/17/98 ND 14.09 0.00 85.17 06/19/01 ND 18.07 0.00 81.19 09/12/01 ND 16.60 0.00 82.66 12/27/01 ND 14.61 0.00 84.65 _ 03/05/02 ND 14.96 0.00 84.30 _ MW-6i 05/12/03 99.26 ND 15.17 0.00 84.09 12/09/03 ND 13.55 0.00 85.71 03/23/06 ND 13.55 0.00 85.71 05/08/07 ND 12.93 0.00 86.33 05/14/08 ND 13.22 0.00 86.04 05/28/09 ND 13.39 0.00 85.87 05/27/10 ND 13.23 0.00 86.03 10/31/11 ND 13.90 0.00 85.36 06/02/14 ND 13.35 0.00 85.91 04/28/16 ND 13.55 0.00 85.71 Page 2 of 5 Appendix A Historical Groundwater Elevation Data A i (�^ R i DIS for natural and Former BP Service Station No.24163 built 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation(1)(2) * 08/23/94 ND 12.14 0.00 85.70 _ * 03/21/95 ND 12.02 0.00 85.82 * 08/05/96 ND 11.99 0.00 85.85 * 11/17/98 1 ND 12.53 0.00 85.31 * 06/19/01 NM NM NM NM * 09/12/01 ND 12.67 0.00 85.17 * MW-8 12/27/01 97.84 14.47 15.03 0.56 83.26 • 03/05/02 I 12.42 12.60 0.18 85.38 05/12/03 NM_ NM NM NM 12/09/03 13.32 13.56 0.24 84.47 03/23/06 ND 12.15 0.00 85.69 05/08/07 ND 11.90 0.00 85.94 05/14/08 I ND 11.95 0.00 85.89 05/28/09 ND 11.70 0.00 86.14 _ 05/27/10 ND 12.97 0.00 NM 10/31/11 ND 13.34 0.00 NM 05/22/12 ND 13.69 0.00 NM 06/14/12 ND 14.94 0.00 NM 07/09/12 ND 14.08 0.00 NM 08/14/12 ND 14.29 0.00 NM 09/19/12 ND 14.08 0.00 NM 12/05/12 ND 14.53 0.00 NM 02/26/13 ND 13.80 0.00 NM 05/31/13 ND 13.61 0.00 NM 08/28/13 ND 13.74 0.00 NM 11/07/13 ND 14.42 0.00 NM 02/27/14 ND 13.33 0.00 NM MW-8R 06/02/14 NS ND 13.34 0.00 NM 10/16/14 ND 14.18 0.00 NM 04/23/15 I ND 13.57 0.00 NM 10/13/15 ND 14.08 0.00 NM 04/28/16 ND 13.53 0.00 NM 09/19/16 ND 13.91 0.00 NM 03/03/17 ND 13.92 0.00 NM 09/20/17 ND 13.61 0.00 NM 03/01/18 ND 13.63 0.00 NM 08/20/18 ND 13.52 0.00 NM 03/15/19 ND 13.35 0.00 NM 10/08/19 ND 13.54 0.00 NM 03/25/20 ND 12.59 0.00 NM 09/01/20 ND 12.72 0.00 NM 04/02/21 I ND 12.16 0.00 NM 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 13.55 0.00 86.89 08/05/96 ND 13.64 0.00 86.80 11/17/98 ND 14.26 0.00 86.18 06/19/01 ND 14.55 0.00 85.89 09/12/01 ND 14.81 0.00 85.63 12/27/01 ND 14.85 0.00 85.59 03/05/02 ND 14.64 0.00 85.80 MW-14 05/12/03 100.44 ND 13.41 0.00 87.03 12/09/03 ND 13.51 0.00 86.93 03/23/06 ND 13.82 0.00 86.62 05/08/07 ND 13.54 0.00 86.90 _ 05/14/08 ND 13.64 0.00 86.80 _ 05/28/09 ND 13.47 0.00 86.97 05/27/10 ND 13.00 0.00 87.44 10/13/11 _ ND 14.14 0.00 86.30 06/02/14 ND 13.42 0.00 87.02 04/28/16 ND 13.65 0.00 86.79 Page 3 of 5 Appendix A Historical Groundwater Elevation Data A i (�^ R i DIS for natural and Former BP Service Station No.24163 built 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation(1)(2) 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.83 0.00 87.08 08/05/96 ND 12.77 0.00 87.14 11/17/98 ND 13.58 0.00 86.33 06/19/01 ND 13.80 0.00 86.11 09/12/01 ND 14.18 0.00 85.73 12/27/01 ND 14.29 0.00 85.62 03/05/02 ND 13.98 0.00 85.93 MW-it 05/12/03 99.91 NM 12.75 NM 87.16 12/09/03 ND 12.89 0.00 87.02 03/23/06 ND 13.14 0.00 86.77 05/08/07 ND 12.90 0.00 87.01 05/14/08 ND 13.12 0.00 86.79 05/28/09 ND 12.90 0.00 87.01 05/27/10 ND 12.25 0.00 87.66 10/31/11 ND 13.61 0.00 86.30 06/02/14 ND 12.82 0.00 87.09 10/16/14 ND 13.91 0.00 86.00 04/28/16 ND 13.15 0.00 86.76 _ 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.06 0.00 85.36 08/05/96 ND 12.09 0.00 85.33 _ 11/17/98 ND 12.60 0.00 84.82 _ 06/19/01 ND 12.74 0.00 84.68 _ 09/12/01 ND 12.98 0.00 84.44 _ 12/27/01 NM NM NM NM 03/05/02 ND 12.83 0.00 84.59 _ MW-16 05/12/03 97.42 NM NM NM NM 12/09/03 ND 12.13 0.00 85.29 _ 03/23/06 ND 12.18 0.00 85.24 05/08/07 NM NM NM NM 05/14/08 ND 12.03 0.00 85.39 _ 05/28/09 ND 11.96 0.00 85.46 _ 05/27/10 ND 11.69 0.00 85.73 _ 10/31/11 ND 12.45 0.00 84.97 _ 11/07/13 ND 12.88 0.00 84.54 06/02/14 ND 11.97 0.00 85.45 _ 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 14.42 0.00 85.58 08/05/96 ND 14.46 0.00 85.54 11/17/98 ND 14.91 0.00 85.09 _ 06/19/01 ND 15.03 0.00 84.97 _ 09/12/01 ND 15.28 0.00 84.72 12/27/01 ND 15.37 0.00 84.63 _ 03/05/02 ND 15.15 0.00 84.85 MW-17 05/12/03 100.00 NM 14.15 NM 85.85 12/09/03 ND 14.50 0.00 85.50 03/23/06 ND 14.45 0.00 85.55 05/08/07 ND 14.22 0.00 85.78 05/14/08 ND 14.22 0.00 85.78 05/28/09 ND 14.12 0.00 85.88 05/27/10 ND 13.90 0.00 86.10 10/31/11 ND 14.72 0.00 85.28 06/02/14 ND 14.14 0.00 85.86 04/28/16 ND 14.36 0.00 I 85.64 Page 4 of 5 Appendix A Historical Groundwater Elevation Data A i (�^ R i DIS for natural and Former BP Service Station No.24163 built 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation(1)(2) 10/31/11 ND 13.95 0.00 NM 05/22/12 ND 14.10 0.00 NM 06/14/12 ND 13.61 0.00 NM 07/09/12 ND 14.05 0.00 NM 08/14/12 ND 14.43 0.00 NM 09/19/12 ND 14.34 0.00 NM 12/05/12 ND 14.62 0.00 NM 02/26/13 ND 14.67 0.00 NM 05/31/13 ND 14.57 0.00 NM 08/28/13 ND 14.33 0.00 NM MW-18 11/07/13 NS ND 14.51 0.00 NM 02/27/14 ND 13.76 0.00 NM 06/02/14 ND 13.55 0.00 NM 10/16/14 ND 14.37 0.00 NM 04/23/15 ND 13.84 0.00 NM 10/13/15 ND 14.81 0.00 NM 04/28/16 ND 13.62 0.00 NM 09/19/16 ND 14.04 0.00 NM 03/03/17 ND 14.08 0.00 NM 09/20/17 ND 13.21 0.00 NM 03/01/18 ND 13.60 0.00 NM 08/20/18 ND 13.42 0.00 NM - 10/31/11 ND 13.75 0.00 NM 05/22/12 ND 13.37 0.00 NM 06/14/12 ND 13.39 0.00 NM 07/09/12 ND 13.89 0.00 NM 08/14/12 ND 14.13 0.00 NM 09/19/12 ND 14.02 0.00 NM 12/05/12 ND 14.39 0.00 NM 02/26/13 ND 13.62 0.00 NM 05/31/13 ND 13.47 0.00 NM 08/28/13 ND 13.56 0.00 NM 11/07/13 ND 14.25 0.00 NM 02/27/14 ND 13.17 0.00 NM MW-19 06/02/14 NS ND 13.14 0.00 NM 10/16/14 ND 14.03 0.00 NM 04/23/15 ND 13.46 0.00 NM 10/13/15 ND 14.01 0.00 NM 04/28/16 ND 13.38 0.00 NM 09/19/16 ND 13.75 0.00 NM 03/03/17 ND 13.79 0.00 NM 09/20/17 ND 13.48 0.00 NM 03/01/18 ND 13.42 0.00 NM 08/20/18 ND 13.38 0.00 NM 03/15/19 ND 12.22 0.00 NM 10/08/19 ND 13.27 i 0.00 NM 03/25/20 Paved Over-Destroyed(4) Notes: 1. Measured in feet relative to site datum 2. Corr.GW Elev.=(ref.point elevation)-(depth to groundwater)+(LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 4. MW-19 was paved over and presumed destroyed on 3/25/2020. -Prior to URS'work at this Site,monitoring well MW-3 has previously been reported as MW-2,monitoring well MW- 6 has previously been reported as MW-8,and monitoring well MW-8 has previously been reported as MW-6. LNAPL=Light non-aqueous phase liquid ND=Not detected NM=Not measured NS=Not Surveyed TOC=Top of casing btoc=below top of casing -During the May 2003 sampling event LNAPL was observed in MW-5. Depth to groundwater and thickness of LNAPL were not measured. Page 5 of 5 APPENDIX B Laboratory Analytical Report and Chain-of-Custody Record — April 21, 2021 El ti% eurofins • Environment Testing America ANALYTICAL REPORT Eurofins TestAmerica, Pensacola dm 3355 McLemore Drive Pensacola, FL 32514 Tel: (850)474-1001 ::.,,. _w. Laboratory Job ID: 400-201649-1 Client Project/Site: BP 24163 r: ARCADIS U.S., Inc. 5420 Wade Park Boulevard Milk, Suite 350 Raleigh, North Carolina 27607 r- '` Attn: Hardik Patel Y2 > Authorized for release by: 4/21/2021 11:15:41 AM Leah Klingensmith, Senior Project Manager (615)301-5038 Leah.Klingensmith@Eurofinset.com LINKS rRe►►iew your project results through NrTota Access A r Have a Question? Lim Ask T e The test results in this report meet all 2003 NELAC, 2009 TNI, and 2016 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced Ex e r t except in full,and with written approval from the laboratory.For questions please contact the G�° Project Manager at the e-mail address or telephone number listed on this page. Ar This report has been electronically signed and authorized by the signatory.Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Visit us at: www.Burofinsus.COmlEnv Results relate only to the items tested and the sample(s)as received by the laboratory. Client:ARCADIS U.S., Inc. Laboratory Job ID:400-201649-1 Project/Site: BP 24163 Table of Contents Cover Page 1 Table of Contents 2 Sample Summary 3 Case Narrative 4 Definitions 5 Client Sample Results 6 QC Sample Results 8 QC Association 10 Chronicle 11 Method Summary 13 Certification Summary 14 Chain of Custody 15 Receipt Checklists 16 Eurofins TestAmerica, Pensacola Page 2 of 16 4/21/2021 Sample Summary Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Lab Sample ID Client Sample ID Matrix Collected Received Asset ID 400-201649-1 MW-6-040221 Water 04/02/21 11:30 04/07/21 09:40 400-201649-2 MW-8R-040221 Water 04/02/21 10:05 04/07/21 09:40 Eurofins TestAmerica, Pensacola Page 3 of 16 4/21/2021 Case Narrative Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Job ID: 400-201649-1 Laboratory: Eurofins TestAmerica, Pensacola 4 Narrative Job Narrative 400-201649-1 Comments No additional comments. Receipt The samples were received on 4/7/2021 9:40 AM. Unless otherwise noted below,the samples arrived in good condition, and where required, properly preserved and on ice. The temperature of the cooler at receipt was 0.7°C. HPLC/IC No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. Eurofins TestAmerica, Pensacola Page 4 of 16 4/21/2021 Definitions/Glossary Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. tt Listed under the"D"column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CFU Colony Forming Unit CNF Contains No Free Liquid DER Duplicate Error Ratio(normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit(DoD/DOE) DL,RA,RE, IN Indicates a Dilution,Re-analysis,Re-extraction,or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration(Radiochemistry) EDL Estimated Detection Limit(Dioxin) LOD Limit of Detection(DoD/DOE) LOQ Limit of Quantitation(DoD/DOE) MCL EPA recommended"Maximum Contaminant Level" MDA Minimum Detectable Activity(Radiochemistry) MDC Minimum Detectable Concentration(Radiochemistry) MDL Method Detection Limit ML Minimum Level(Dioxin) MPN Most Probable Number MQL Method Quantitation Limit NC Not Calculated ND Not Detected at the reporting limit(or MDL or EDL if shown) NEG Negative/Absent POS Positive/Present PQL Practical Quantitation Limit PRES Presumptive QC Quality Control RER Relative Error Ratio(Radiochemistry) RL Reporting Limit or Requested Limit(Radiochemistry) RPD Relative Percent Difference,a measure of the relative difference between two points TEF Toxicity Equivalent Factor(Dioxin) TEQ Toxicity Equivalent Quotient(Dioxin) TNTC Too Numerous To Count Eurofins TestAmerica, Pensacola Page 5 of 16 4/21/2021 Client Sample Results Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Client Sample ID: MW-6-040221 Lab Sample ID: 400-201649-1 Date Collected: 04/02/21 11:30 Matrix: Water Date Received: 04/07/21 09:40 Method: 9056-Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 24.0 1.00 mg/L 04/19/21 17:58 1 6 Eurofins TestAmerica, Pensacola Page 6 of 16 4/21/2021 Client Sample Results Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Client Sample ID: MW-8R-040221 Lab Sample ID: 400-201649-2 Date Collected: 04/02/21 10:05 Matrix: Water Date Received: 04/07/21 09:40 Method: 9056-Anions, Ion Chromatography Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate 306 10.0 mg/L 04/21/21 03:28 10 6 Eurofins TestAmerica, Pensacola Page 7 of 16 4/21/2021 QC Sample Results Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Method: 9056 - Anions, Ion Chromatography Lab Sample ID: MB 400-528204/4 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 528204 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate ND 1.00 mg/L 04/19/21 16:19 1 Lab Sample ID: LCS 400-528204/6 Client Sample ID: Lab Control Sample ITI Matrix: Water Prep Type: Total/NA Analysis Batch: 528204 Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 10.0 9.919 mg/L 99 90-110 Lab Sample ID: LCSD 400-528204/7 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 528204 Spike LCSD LCSD %Rec. RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 9.817 mg/L 98 90-110 1 15 Lab Sample ID: MRL 400-528204/5 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 528204 Spike MRL MRL %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 1.00 ND mg/L 87 50-150 Lab Sample ID: 400-201649-1 MS Client Sample ID: MW-6-040221 Matrix: Water Prep Type: Total/NA Analysis Batch: 528204 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 24.0 10.0 34.96 mg/L 110 80-120 Lab Sample ID: 400-201649-1 MSD Client Sample ID: MW-6-040221 Matrix: Water Prep Type: Total/NA Analysis Batch: 528204 Sample Sample Spike MSD MSD %Rec. RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 24.0 10.0 35.36 mg/L 114 80-120 1 20 Lab Sample ID: MB 400-528453/4 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 528453 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate ND 1.00 mg/L 04/20/21 16:43 1 Lab Sample ID: LCS 400-528453/6 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 528453 Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 10.0 9.926 mg/L 99 90-110 Eurofins TestAmerica, Pensacola Page 8 of 16 4/21/2021 QC Sample Results Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Method: 9056 - Anions, Ion Chromatography Lab Sample ID: LCSD 400-528453/7 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 528453 Spike LCSD LCSD %Rec. RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 9.918 mg/L 99 90-110 0 15 Lab Sample ID: MRL 400-528453/5 Client Sample ID: Lab Control Sample ri Matrix: Water Prep Type: Total/NA Analysis Batch: 528453 Spike MRL MRL %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 1.00 ND mg/L 88 50-150 Lab Sample ID: 400-201733-D-1 MS Client Sample ID: Matrix Spike Matrix: Water Prep Type: Total/NA Analysis Batch: 528453 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 10.1 10.0 20.60 mg/L 105 80-120 Lab Sample ID: 400-201733-D-1 MSD Client Sample ID: Matrix Spike Duplicate Matrix: Water Prep Type: Total/NA Analysis Batch: 528453 Sample Sample Spike MSD MSD %Rec. RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.1 10.0 20.54 mg/L 104 80-120 0 20 Eurofins TestAmerica, Pensacola Page 9 of 16 4/21/2021 QC Association Summary Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 HPLC/IC Analysis Batch: 528204 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 400-201649-1 MW-6-040221 Total/NA Water 9056 MB 400-528204/4 Method Blank Total/NA Water 9056 LCS 400-528204/6 Lab Control Sample Total/NA Water 9056 LCSD 400-528204/7 Lab Control Sample Dup Total/NA Water 9056 MRL 400-528204/5 Lab Control Sample Total/NA Water 9056 400-201649-1 MS MW-6-040221 Total/NA Water 9056 400-201649-1 MSD MW-6-040221 Total/NA Water 9056 8 Analysis Batch: 528453 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 400-201649-2 MW-8R-040221 Total/NA Water 9056 MB 400-528453/4 Method Blank Total/NA Water 9056 LCS 400-528453/6 Lab Control Sample Total/NA Water 9056 LCSD 400-528453/7 Lab Control Sample Dup Total/NA Water 9056 MRL 400-528453/5 Lab Control Sample Total/NA Water 9056 400-201733-D-1 MS Matrix Spike Total/NA Water 9056 400-201733-D-1 MSD Matrix Spike Duplicate Total/NA Water 9056 Eurofins TestAmerica, Pensacola Page 10 of 16 4/21/2021 Lab Chronicle Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Client Sample ID: MW-6-040221 Lab Sample ID: 400-201649-1 Date Collected: 04/02/21 11:30 Matrix: Water Date Received: 04/07/21 09:40 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528204 04/19/21 17:58 TAJ TAL PEN Client Sample ID: MW-8R-040221 Lab Sample ID: 400-201649-2 Date Collected: 04/02/21 10:05 Matrix: Water Date Received: 04/07/21 09:40 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 10 528453 04/21/21 03:28 TAJ TAL PEN 9 Client Sample ID: Method Blank Lab Sample ID: MB 400-528204/4 Date Collected: N/A Matrix: Water Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528204 04/19/21 16:19 TAJ TAL PEN Client Sample ID: Method Blank Lab Sample ID: MB 400-528453/4 Date Collected: N/A Matrix: Water Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528453 04/20/21 16:43 TAJ TAL PEN Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-528204/6 Date Collected: N/A Matrix: Water Date Received: N/A F Batch Batch Dil Initial Final Batch Prepared LPrep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528204 04/19/21 17:09 TAJ TAL PEN Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-528453/6 Date Collected: N/A Matrix: Water Date Received: N/A rBatch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528453 04/20/21 17:32 TAJ TAL PEN Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-528204/7 Date Collected: N/A Matrix: Water Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528204 04/19/21 17:33 TAJ TAL PEN Eurofins TestAmerica, Pensacola Page 11 of 16 4/21/2021 Lab Chronicle Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-528453/7 Date Collected: N/A Matrix: Water Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528453 04/20/21 17:57 TAJ TAL PEN Client Sample ID: Lab Control Sample Lab Sample ID: MRL 400-528204/5 Date Collected: N/A Matrix: Water Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528204 04/19/21 16:44 TAJ TAL PEN 9 Client Sample ID: Lab Control Sample Lab Sample ID: MRL 400-528453/5 Date Collected: N/A Matrix: Water Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528453 04/20/21 17:08 TAJ TAL PEN Client Sample ID: MW-6-040221 Lab Sample ID: 400-201649-1 MS Date Collected: 04/02/21 11:30 Matrix: Water Date Received: 04/07/21 09:40 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528204 04/19/21 18:23 TAJ TAL PEN Client Sample ID: MW-6-040221 Lab Sample ID: 400-201649-1 MSD Date Collected: 04/02/21 11:30 Matrix: Water Date Received: 04/07/21 09:40 F Batch Batch Dil Initial Final Batch Prepared LPrep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528204 04/19/21 18:48 TAJ TAL PEN Client Sample ID: Matrix Spike Lab Sample ID: 400-201733-D-1 MS Date Collected: N/A Matrix: Water Date Received: N/A rBatch Batch Oil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528453 04/20/21 18:47 TAJ TAL PEN Client Sample ID: Matrix Spike Duplicate Lab Sample ID: 400-201733-D-1 MSD Date Collected: N/A Matrix: Water Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056 1 528453 04/20/21 19:12 TAJ TAL PEN Laboratory References: TAL PEN=Eurofins TestAmerica, Pensacola,3355 McLemore Drive, Pensacola, FL 32514,TEL(850)474-1001 Eurofins TestAmerica, Pensacola Page 12 of 16 4/21/2021 Method Summary Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Method Method Description Protocol Laboratory 9056 Anions, Ion Chromatography SW846 TAL PEN Protocol References: SW846="Test Methods For Evaluating Solid Waste, Physical/Chemical Methods",Third Edition,November 1986 And Its Updates. Laboratory References: TAL PEN=Eurofins TestAmerica,Pensacola,3355 McLemore Drive, Pensacola,FL 32514,TEL(850)474-1001 10 Eurofins TestAmerica, Pensacola Page 13 of 16 4/21/2021 Accreditation/Certification Summary Client: ARCADIS U.S., Inc. Job ID: 400-201649-1 Project/Site: BP 24163 Laboratory: Eurofins TestAmerica, Pensacola Unless otherwise noted,all analytes for this laboratory were covered under each accreditation/certification below. Authority Program Identification Number Expiration Date North Carolina(WW/SW) State 314 12-31-21 The following analytes are included in this report,but the laboratory is not certified by the governing authority. This list may include analytes for which the agency does not offer certification. Analysis Method Prep Method Matrix Analyte 9056 Water Sulfate m Eurofins TestAmerica, Pensacola Page 14 of 16 4/21/2021 m • m m o ~ m y " a ° Z I '_N Eu O v O 2 Q o c va - A v 2 2;m(9 a26 o - o _a'p vo <=r c E - IZaZ z zip-a` ao u G E E W Q N- of 2 Z 0 a 0cc v)H 7> N E U U U > ._ v v in C. C ch V a ZC. Q Y A I 22 a f.k- `- O m Qu -. L.rO 2 v<F,Sro Q 1. Qm G lO ✓ UZ' N p N U NZZ§ EmEpp .. p oo s ` - t ff a a am0owLL0x_ , _, o a 01•.r d sJaU!elUoa)o lagwnN Lew' y o I NIQ S.LI N 1-1 N o o 1ommzO b Jn d v NE i a a t U V Na`o I iHHIiiI;d In o o m -OHWdONO 9S06 Z I- c � .m cvCC U E m (ON 3 seA)OS WJS W 41(04-144/1�0.........a am 0) _ E Y (oN JO seA)a!dweg parai!!j Pla!N�' LL a 0, _E 2 N = a y q 11111111s a a a O o E E E 0 0 0 �+ m U U U O <, U Z �. d E I) L.) A E r r om Na cz n Ui 73 LY Tv d" .6 A c iI 0 o N r cii O V m 9 O , _ � C c d a ill v �0 d ni 1 4 ,,," d 'v,A m m ii oii a 1 - E V'E E o a 2 _Nan E N N A a o o o oa o rn 1 m m u) `a o r o a d a`c (n �+ 0 0 0 0 ti 0 Li `c CO >. C N ld n co y I C co 5 Ws N O t d a0 co O 22 \ E O N• O M is c m u r a a > > z To o u v O n d @ �' '.c 1 1 m .. r H N O w , N f` d ) S Z N Ct a n a CO N C ov � �a N m o ' �� 3 m ca , s r v> r,. o .+ o Y r.0 L a(O a Z a). XI p Y w m o Q co N C V mQ � O)NN Y V N a' = Z o .5 .a N G O d - U °)o N .- o N ` J E `� _ o_ 3 c') N L v m o R o V 2 m U ° E m a- _v co a) E m d w U W r a a Qol UQ a�n o nZ a W r o_CO u) (n 0 W a a a Page 15 of 16 4/21/2021 Login Sample Receipt Checklist Client:ARCADIS U.S., Inc. Job Number:400-201649-1 Login Number: 201649 List Source: Eurofins TestAmerica, Pensacola List Number: 1 Creator: Whitley,Adrian Question Answer Comment Radioactivity wasn't checked or is</=background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. N/A Sample custody seals, if present, are intact. N/A The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True 0.7°C IR7 COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time(excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol.for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is N/A <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins TestAmerica, Pensacola Page 16 of 16 4/21/2021 APPENDIX C Historical Groundwater Analytical Data Appendix C �^ Historical Groundwater Analytical Summary j R f.\DIS D sran&Cons ltancy Former BP Service Station No.24163 built assets 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina 1 - I Carbon Well Sample Date Benzene Ethylbenzene Toluene Xylenes(Total) MTBE Sulfate Dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE - NC 2L 1 600 600 500 20 250 NE - Units: pg/I pg/I pg/I pg/I pg/I mg/I mg/I 5/13/2003 8.5 0.98 J 0.61 J 1.7 J 8_ -- -- 12/9/2003 47.4 14.3 1.9 8.1 r 37.3 -- -- 3/23/2006 4.5 J <0.5 <0.5 UJ <1 UJ 5.5 -- -- 5/8/2007 40.4 3.7 1.4 2 J 13.1 -- -- 5/14/2008 4.3 J <0.8 <0.7 <0.8 14 -- -- 5/28/2009 5.4 0.44 J 0.14 J 0.49 J 5.6 -- -- 5/27/2010 0.44 J <0.11 0.3 J <0.32 4.8 -- -- _ 10/31/2011 5.5 0.76 <0.17 U 0.38 J 19.1 8.4 405 _ 5/22/2012 <0.43 U <0.2 <0.2 <0.52 4.6 15.3 378 _ 6/14/2012 12.1 6.7 0.72 4.7 15.4 6.6 J 344 _ 7/9/2012 2.2 1.6 2.6 3 14.7 9.9 393 _ MW-3 8/14/2012 2 2.1 <0.13 0.4 J 17.9 3.6 303 _ 9/19/2012 2.7 0.66 <0.13 0.33 J 19.8 2.8 459 _ 12/5/2012 11.3 1.2 0.43 J 1.1 J 19.3 0.78 J 377 _ 2/26/2013 0.23 J <0.1 <0.1 <0.22 5.4 32.6 338 _ 5/31/2013 0.32 J <0.1 <0.1 <0.22 10.5 17.9 334 _ 8/28/2013 3.6 0.53 0.12 J 0.31 J 10.3 21.9 457 11/7/2013 4.3 0.27 J 0.13 J <0.22 10 21.7 536 _ 2/27/2014 <0.1 <0.1 <0.1 <0.2 1.3 42.2 198 _ 6/3/2014 0.48 J 0.15 J <0.1 <0.2 3.1 -- -- _ 10/16/2014 -- -- -- -- -- 18.0 372 4/23/2015 -- -- -- -- -- 22.8 296 _ 9/19/2016 21.3 -- 3/23/2006 11,700 2,440 32,000 13,500 16,100 -- -- 3/23/2006(1) 11,000 2,370 30,700 13,200 15,400 -- -- 5/8/2007 I. 7,410 1,590 21,100 8,920 8,830 -- I -- _ MW-5 5/8/2007 i1i g 7,400 1,680 20,100 9,290 9,360 -- -- - 5/14/2008 10,000 2,100 29,000 12,000 18,000 -- -- - 5/14/2008I1) 10,000 2,100 30,000 12,000 18,000 -- -- 5/28/2009 7,390 2,330 25,700 13,400 6,920 -- -- 5/28/2009(1) 6,510 2,240 22,100 12,900 6,510 - _ -- - 5/27/2010 6,610 2,810 24,300 J 15,700 4,330 -- -- 5/27/2010(1) 6,090 2,380 30,100 J 13,300 4,250 -- -- 10/31/2011 7,960 2,660 28,000 13,800 3,830 <1 <5 10/31/2011(1) III 8,360 2,870 24,600 14,800 4,070 -- -- 5/22/2012 IL 7,980 3,470 32,200 19,200 3,820 <5 179 6/15/2012(2) 244 227 1,190 1,120 36.9 6,070 1,820 7/9/2012 336 J 481 J 2,010 J 2,400 J 48.4 J 6,470 2,620 MW-5R 8/14/2012 201 283 1,050 1,300 48.5 14,700 4,190 9/19/2012 158 181 650 _883 114 19,000 3,280 12/5/2012 754 505 2,220 2,380 1,160 13,600 1,840 2/26/2013 1,360 878 3,520 3,940 1,660 8,520 1,530 5/31/2013 1,410 1,380 5,930 6,220 1,150 J 4,680 1,560 8/28/2013 165 178 489 1,380 417 13,900 1,590 11/7/2013 214 131 331 969 651 14,400 1,570 2/27/2014 142 177 328 1,060 240 2,990 807 6/2/2014 256 436 1040 2520 519 J -- -- 10/16/2014 -- -- -- -- -- 9,950 1,390 4/23/2015 -- -- -- -- -- 5,980 1,510 10/13/2015 -- -- -- -- -- 5,790 -- 4/28/2016 -- -- -- -- -- 2,980 -- MW-SR 9/19/2016 -- -- -- _ -- -- 2,880 3/3/2017 _ -- -- -- - -- 3,570 -- - 9/20/2017 - - 1,060 -- 3/1/2018 163 -- _ 8/20/2018 147 Page 1 of 4 Appendix C �^ Historical Groundwater Analytical Summary j R f.\DIS D sran&Cons ltancy Former BP Service Station No.24163 built assets 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina Carbon Well Sample Date Benzene Ethylbenzene Toluene Xylenes(Total) MTBE Sulfate Dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE - NC 2L 1 600 600 500 20 250 NE _ Units: pg/I pg/I pg/I pg/I pg/I mg/I mg/I _ 5/12/2003 <0.5 0.52 J <0.5 <1 -- --3 12/9/2003 2.3 0.64 J 1.1 3.6 17.6 -- -- 12/9/2003 2.4 0.68 J 1.1 3.8 18 _ -- -- 3/23/2006 0.76 J 0.59 J 3.6 2.8 J 1.1 -- -- 5/8/2007 <0.5 <0.5 <0.5 <1 <0.5 -- -- 5/14/2008 <0.5 <0.8 <0.7 <0.8 <0.5 -- -- MW-6 5/28/2009 <0.06 <0.05 <0.06 <0.14 0.17 J -- -- 5/27/2010 <0.11 0.13 J 0.38 J 0.46 J <0.12 -- -- 10/31/2011 8.7 J 11.7 J 27.5 J 132 J <0.26 UJ 131 2,130 6/2/2014 17.6 J 59.4 J 31.6 J 99.4 J 783 J -- -- 3/25/2020 -- -- -- -- -- 25.2 -- 9/1/2020 -- -- -- _ -- -- 38.6 -- 4/2/2021 -- -- -- -- -- 24.0 -- 5/12/2003 <0.5 <0.5 <0.5 1.1 J <0.5 -- -- 12/9/2003 <2.5 <2.5 <2.5 <5 <2.5 -- -- 3/23/2006 49.7 18.9 48.7 443 3,560 -- -- 5/8/2007 <25 <25 <25 <50 6,910 -- -- MW-61 5/14/2008 5.2 J <2 <1.8 <2 3,400 -- -- 5/28/2009 2.5_ <0.05 <0.06 <0.14 1,150 -- -- 5/27/2010 1.6 J <1.1 <1.1 <3.2 492 -- -- 10/31/2011 0.41 J <0.36 <0.32 <0.75 122 <1 76.1 6/2/2014 <0.1 <0.1 <0.1 <0.2 3.3 -- -- 3/23/2006 671 1,340 1,230 8,100 124 -- -- MW 8 5/8/2007 1,160 799 196 2,990 _ 1,440 -- -- 5/14/2008 600 1,800 700 3,000 190 -- -- 5/28/2009 1,390 2,050 357 3,310 1,560 -- -- _ 5/27/2010 Mr 8,570 2,870 31,700 15,700 6,260 -- -- 10/31/2011 r 8,000 3,180 32,100 17,200 3,170 <1 <5 5/22/2012 8,270 4 3,360 1 36,400 J 17,800 3,920 <5 119 6/15/2012(2) 726 47 J 760 242 J 96.3 J 4,760 22,200 7/9/2012 4,540 J 1,870 J 17,100 J 10,800 J 1,530 J 6,570 4,500 8/14/2012 4,370 1,610 19,300 8,780 2,000 7,010 1,560 9/19/2012 4,780 1,800 20,900 10,400 2,600 6,700 1,100 _ 12/5/2012 7,760 2,440 31,900 13,800 4,560 2,410 635 2/26/2013 7,310 2,480 30,500 13,400 4,530 959 590 - 5/31/2013 6,540 A 3,040 i 30,500 12,500 4,200 439 437 8/28/2013 1,600 628 5,390 3,990 1,380 4,770 703 11/7/2013 1,130 329 2,440 1,830 1,770 7,460 766 _ 2/27/2014 1,020 603 3,200 3,430 1,190 7,670 940 _ 6/2/2014 1,360 J 680 J 3,510 J 3,330 J 2,110 J -- -- _ MW-8R 6/2/2014(1) 1,540 556 J 3,650 2,630 J 2,640 J -- -- 10/16/2014 3,310 883 9,070 4,990 3,910 3,560 842 _ 4/23/2015 -- -- -- _ -- 2,050 812 _ 10/13/2015 -- -- -- -- 1,600 -- 4/29/2016 -- -- -- _ -- -- 1,640 -- 9/19/2016 _ -- 1,330 -- 3/3/2017 -- -- -- _ -- -- 1,720 -- 9/20/2017 -- -- -- _ -- -- 797 -- 3/1/2018 -- -- -- _ -- -- 677 8/20/2018 -- 436 -- 3/15/2019 -- -- -- -- -- 60 -- 10/8/2019 -- 475 -- 3/25/2020 -- -- -- -- -- 450 -- I 9/1/2020 -- -- -- -- -- 442 -- I 4/2/2021 -- -- -- -- -- 306 -- 5/12/2003 <0.5 _ <0.5 <0.5 <1 0.52 J -- -- 12/9/2003 <0.5 <0.5 <0.5 <1 5.9 -- -- 3/23/2006 <0.5 <0.5 <0.5 <1 <0.5 -- _ - 5/8/2007 <0.5 <0.5 <0.5 _ <1 <0.5 -- - MW-14 5/14/2008 <0.5 <0.8 <0.7 <0.8 <0.5 -- - 5/28/2009 <0.06 <0.05 0.077 J <0.14 <0.06 -- - 5/27/2010 <0.11 <0.11 <0.11 <0.32 <0.12 -- -- 10/31/2011 <0.13 <0.15 <0.42U <0.3 <0.13 43.2 <5 6/3/2014 <0.1 <0.1 <0.1 <0.2 <0.1 -- - Page 2 of 4 Appendix C �^ Historical Groundwater Analytical Summary j R f.\DIS D sran&Cons ltancy Former BP Service Station No.24163 built assets 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina Carbon Well Sample Date Benzene Ethylbenzene Toluene Xylenes(Total) MTBE Sulfate Dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE - NC 2L 1 600 600 500 20 250 NE - Units: pg/I pg/I pg/I pg/I pg/I mg/I mg/I _ 3/23/2006 0.63 J 2.1 <0.5 18.6 _ 1.6 -- -- 5/8/2007 <0.5 <0.5 <0.5 2.2 J <0.5 -- -- 5/14/2008 <0.5 <0.8 <0.7 3.7 J <0.5 -- - M W-15 5/27/2010 <0.11 <0.11 <0.11 <0.32 <0.12 -- - 10/31/2011 <0.13 <0.15 <0.13 <0.3 <0.13 <1 <5 6/3/2014 <0.1 <0.1 <0.1 <0.2 <0.1 -- - 10/16/2014 <0.1 <0.1 <0.1 <0.2 <0.1 -- -- 3/23/2006 <2.5 90.8 15.8 836 2.8 J -- -- 5/14/2008 <0.5 160 15 1,600 4.1 J -- -- MW-16 5/27/2010 3.6 54.7 J 5.1 525 J 1.3 -- -- 10/31/2011 <0.65 17.2 <1.4 U 321 <0.65 194 <5 11/7/2013 -- -- -- -- -- 55.4 <5 6/3/2014 <0.1 25 0.92 417 J <0.1 -- -- 5/13/2003 57.7 <0.5 <0.5 <1 69 -- -- 5/13/2003 40.8 <0.5 <0.5 <1 63.3 -- -- 12/9/2003 6.6 0.65 J <0.5 <1 80.6 -- -- 3/23/2006 1 <0.5 <0.5 <1 58.9 -- -- M W-17 5/8/2007 <0.5 <0.5 <0.5 <1 17.4 -- -- 5/14/2008 3.7 J <0.8 <0.7 <0.8 19 -- -- _ 5/28/2009 7 <0.05 0.076 J <0.14 14.5 -- -- _ 5/27/2010 5.7 <0.11 <0.11 <0.32_ 12.4 -- -- _ 10/31/2011 0.51 0.16 J <0.81 U 0.57 J 8.9 <1 422 6/3/2014 <0.1 <0.1 <0.1 <0.2 4.1 -- -- - 10/31/2011 3,140 998 11,100 8,950 1,140 8.2 446 _ 5/22/2012 2,280 2,790 18,200 12,000 789 <5 307 6/15/2012(2) 373 910 4,800 3,910 114 10,600 3,410 7/9/2012 1,730 J 2,170 J 15,000 J 9,750 J 676 J 2,300 835 8/14/2012 3,020 2,990 24,400 12,800 1,090 758 580 9/19/2012 3,190 3,090 22,600 14,000 1,240 322 542 12/5/2012 3,370 2,970 20,100 12,800 1,380 32 436 2/26/2013 2,510 2,970 10,100 8,690 1,140 13.8 500 5/31/2013 2,780 3,070 8,210 5,740 1,000 83.3 475 8/28/2013 182 368 1 730 1,660 139 7,850 2,230 MW-18 11/7/2013 1,140 727 4,910 3,250 694 2,640 1,370 2/27/2014 16.6 109 20.2 _ 45.8 18.5 4,310 1,270 6/2/2014 26.2 J 125 J 37.5 J 31.6 J 37.4 J -- -- 10/16/2014 359 388 244 138 364 1,540 513 4/23/2015 -- -- - -- -- 780 1,100 10/13/2015 -- -- -- -- -- 516 -- 4/29/2016 -- 79.4 -- 9/19/2016 -- -- -- -- -- 377 -- 3/3/2017 -- 295 -- 9/20/2017 -- -- -- -- -- 257 - 3/1/2018 -- -- -- -- -- 253 - 8/20/2018 -- -- -- -- -- 173 -- Page 3 of 4 Appendix C �^ Historical Groundwater Analytical Summary j R f.\DIS r0fran&Consultancy Former BP Service Station No.24163 built assets 381 Knollwood Street Winston-Salem,Forsyth County,North Carolina II Carbon Well Sample Date Benzene Ethylbenzene Toluene Xylenes(Total) MTBE Sulfate Dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE NC 2L 1 600 600 500 20 250 NE Units: pg/I pg/I pg/I pg/I pg/I mg/I mg/I 10/31/2011 2,390 1,380 8,790 7,040 5,160 3.7 425 5/22/2012 2,700 1,560 14,200 7,940 4,880 <5 310 6/15/2012(2) 4,020 1,440 18,200 7,940 3,290 1,090 6,520 7/9/2012 5,130 2,910 30,400 J 16,300 5,330 232 991 8/14/2012 2,420 1,650 14,200 8,370 4,090 469 1,080 9/19/2012 2,090 1,630 12,900 8,640 3,960 260 690 12/5/2012 2,320 1,810 15,200 10,400 4,010 58.8 588 2/26/2013 2,210 1,110 10,600 6,990 3,890 169 503 5/31/2013 1,830 894 8,820 5,250 3,120 1,530 606 8/28/2013 2,710 J 1,190 J 13,100 7,420 J 3,240 J 2,660 525 11/7/2013 2,020 984 9,850 _ 5,620 2,260 2,890 255 2/27/2014 2,550 1,400 10,900 _ 7,880 3,320 2,790 322 MW-19 6/2/2014 2,370 1,260 11,900 _ 7,260 2,830 -- -- 10/16/2014 -- -- -- _ -- -- 2,340 632 4/23/2015 -- -- -- _ -- -- 2,540 514 10/13/2015 -- -- -- _ -- -- 1,960 - 4/28/2016 -- -- - _ -- -- 1,780 - 9/19/2016 -- -- -- _ -- -- 1,270 - 3/3/2017 -- -- -- _ -- -- 941 - 9/20/2017 -- -- -- _ -- -- 1,020 - 3/1/2018 -- -- -- -- -- 745 - 8/20/2018 -- -- - -- -- 806 -- 3/15/2019 -- 1,150 -- 10/8/2019 -- -- -- -- -- 783 I -- 3/25/2020 Paved Over-Destroyed Notes: (1(Field duplicate (2)Alkalinity,sulfate,and carbon dioxide samples were collected 6/14/2012 and volatile organic analysis samples were collected 6/15/12. -"-Not sampled or analyzed <-Not detected at the specified detection limit pg/I-Micrograms per Liter GCL-Gross Contamination Level 2L-North Carolina Groundwater Quality(2L)Standard J-Estimated value mg/I-Milligrams per Liter MTBE-Methyl ten-Butyl Ether NE-Not established U-Not present above the associated level;blank contamination exists UJ-Not detected and the detection limit is estimated BOLD text indicates 2L exceedance Bold cell with green highlight indicates GCL exceedence Activated sodium persulfate injections were performed at the site from June 4,2012,to June 9,2012,and from June 3,2013,to June 6,2013. Page 4 of 4 i RCAD I S Design&Consultancy for natural and built assets Arcadis U.S., Inc. 111-D Sanders Lane Bluefield, Virginia 24605 Tel 276 322 3879 Fax 276 322 3946 www.arcadis.com