WQ0019753_Residual Annual Report 2021_20220301

Initial Review
Reviewer
Thornburg, Nathaniel D
Is this submittal an application? (Excluding additional information.)*
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number (IR) * WQ0019753
ApplicantlPermittee Town of Madison
Email Notifications
Does this need review by the hydrogeologist?* Yes • No
Regional Office Winston-Salem
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Name* Denise Harrison
Email Address*
[e-mail]
Project Information
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
336-978-0042
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
hftps://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type: * Wastewater Irrigation
Other Wastewater
Closed -Loop Recycle
Single -Family Residence Wastewater
Irrigation
Permit Number: * WQ0019753
Has Current Existing permit number
Applicant/Permittee Address* Madison, NC
Facility Name* Town of Madison Class A Residuals Program
Please provide comments/notes on your current submittal below.
Town of Madison Class A WTP 2021 Land Application Annual Report
High -Rate Infiltration
Reclaimed Water
Residuals
Other
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2021 Class A WTP Annual Report-WO0019753-Town of
5.25MB
Madison.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality (NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 3/1/2022

2021 ANNUAL REPORT
LAND APPLICATION PROGRAM
TOWN OF MADISON
PERMIT #WQ0019753
Compiled By:
Bio-Green Services, Inc.
383 Potts Road
Advance, NC 27006
February 2022

March 1, 2022
NCDENR-DWR
512 N Salisbury St
9114 Floor, Office #942X
Raleigh, NC 27604
Attention: Information Processing Unit
Reference: 2021 LAND APPLICATION ANNUAL REPORT
TOWN OF MADISON
Permit No. WQ0019753
Non -Discharge Compliance Unit:
Bio-Green Services, Inc. (Bio-Green) is submitting all monitoring and reporting
requirements as specified in the above referenced permit. Bio-Green compiled this
report using data gathered during the compliance year by Bio-Green and The Town of
Cleveland. This data includes:
I Annual Residual Sampling Summary Form
Form RSSF
II DMSDF
III Lab Sheets (Analytical Data)
If there is any further information required or questions regarding this annual report,
please do not hesitate to contact Bio-Green for further assistance.
Sincerely,
/fag O4rIi##
Ray Gambill
NC Land Application/Residuals Operator

Bio-green Services, Inc.
377 Potts Road
Advance, NC 27006
336-940-4544
NC PERMIT # WQ0019753
LAND APPLIERS:
Bio-Green Services, Inc.
383 Potts Road
Advance, North Carolina 27006
2021 Town of Madison
Total Dry Tons 299.92
2021 Town of Madison

Total Metric Tons 272.027
TABLE OF CONTENTS
SECTION NO. TITLE
I Annual Residual Sampling Summary Form
Form RSSF
II DMSDF
III Lab Sheets (Analytical Data)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM

butitA, Waits
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0019753
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analysis Data
Town of Madison
02-79-030
Town of Madison WWTP
Laboratory: 1) Pace Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
(mg/kg)a
Sample or Composite
Date
1114/2I
Percent Solids (%)
NA
9.9
Arsenic
75
0
Cadmium
85
0
Copper
4,300
0
Chromium
NA
58
Lead
840
0
Mercury
57
0
Molybdenum
75
0
Nickel
420
0
Selenium
100
0
Zinc
7,500
55.5
Total Phosphorus
NA
625
TKN
NA
2570
Ammonia -Nitrogen
NA
0
Nitrate and Nitrite
NA
0
For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
3/1/2022
Date
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0019753
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Town of Madison
02-79-030
Town of Madison WWTP
Residual Analysis Data
Laboratory: 1) Pace Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Sample or Composite
Date
11 /4/21
Aluminum
0
Calcium
0 _
Magnesium
0
pH
6.7
Potassium
0
Sodium
0
SAR
0
PAN
1.028
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
3/1/2022
cutitn., gaits
Signature of Preparer
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM RSSF - B (12/2006)

DMSDF

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0019753 FACILITY NAME:
PHONE: [phone] COUNTY:
Town of Madison
Rockingham
OPERATOR:
Bio-Green Services, Inc.
FACILITY TYPE (please check one): 0 Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
❑ Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? Yes El No ❑ —► If No skip parts A, B, C and certify form below
Part A*:
Part B*:
Month
Sources s include NPDES # if
() (
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
February
March
April
May
June
July
August
September
October
Town of Madison 02-79-030
96.602
96,602
B Neil
96.602
Fertilizer
November
Town of Madison 02-79-030
19.196
19.196
B Neil
19.196
Fertilizer
December
Total from FORM DMSDF (sup)
0
184.122
184.122
184.122
Totals:
Annual
(dry tons):
0
299.92
299.92
299.92
Amendment(s) used:
_
Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form
DMSDF (Supp)I
art C:
Facility was compliant during the past calendar year with all conditions of the land application permit
(including but not limited to items 1-3 below) issued by the Division of Water Resources:
❑ Yes
❑ No ► If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
3/1/2022
q4s
Signature of Permittee
Date Signature of Preparer**
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM DMSDF (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT #: WQ19753 FACILITY NAME:
Town of Madison
PHONE: [phone] COUNTY: Rockingham OPERATOR: Bio-Green Services, Inc.
FACILITY TYPE (please check one): 0 Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
❑ Distribution and Marketing (complete Parts A, and B
Part A*:
Part B*:
Month
Sources(s) (include
a licable
pp
NPDES # if
)
Volume
(dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry
tons)
Intended use(s)
November
Town of Madison 02-79-030
184.122
184.122
A Fulp
184.122
Furtilizer
Totals:
Annual (dry tons):
0
184.122
184.122
184.122
Amendment(s) used:
Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF
(supp)): Total Number of Form
DMSDF (Supp)I
I
DENR FORM DMSDF (Supp) (12/2006)

LAB SHEETS

TOWN OF MADISON LAND APPLICATION PROGRAM
Residual Type:
pH 6.7
RESIDUALS ANALYSIS
Wastewater Treatment Plant
Date Sampled: 11/4/2021
Permit No. WQ0019753
Mineralization rate 0.30
9.9 % Solids
Parameter
%
PPM (mq/kq)(% *10,0001
Lbs/DryTon (Mq/Kq * 0.002)
PAN Surface
514
1.028
PAN Injection
TKN
2570
5.14
Ammonia Nitrogen (Am)
0
0
Nitrate Nitrogen (Nin)
0
0
Organic Nitrogen (Orn)
0
0
Total Phosphorus (P)
625
1.25
Total Phosphate (P205)
0
0
Estimated Avail. P205
0
0
Total Potassium (K)
0
0
Total Potash (K20)
0
0
Arsenic (As)
0
0
Cadmium (Cd)
0
0
Chromium (Cr)
58
0.116
Copper (Cu)
0
0
Lead (Pb)
0
0
Mercury (Hg)
0
0
Molybdenum (Mo)
0
0
Nickel (Ni)
0
0
Selenium (Se)
0
0
Zinc (Zn)
55.5
0.111
Aluminum (Al)
0
0
Calcium (Ca)
0
0
Iron (Fe)
0
0
Sodium (Na)
0
0
Sulfur (S)
0
0
Magnesium (Mg)
0.002
Manganese (Mn)
0
0
Pace Analytical 92570767
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N)+ Ammonia N + Nitrate N +Nitrate N - % PAN
Surface Application
(Mineralization Rate)(TKN-Ammonia N)+ (0.5) (Ammonia N) + Nitrate N +Nitrate N - % PAN
Note: Constituents N.D. (Not Detected) or < direction limits are listed as detection limits for calculation purposes.
1000 gallon loads 0.424 PAN
0.002

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December 02, 2021
Kevin Yates
Town of Madison
120 N. Market Street
Madison, NC 27025
RE: Project: SLUDGE BEDS
Pace Project No.: 92570767
Dear Kevin Yates:
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on November 04, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses were subcontracted outside of the Pace Network. The test report from the external subcontractor is
attached to this report in its entirety.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Terri Page for
Jessica L Mabe
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Kevin Yates, Town Of Madison
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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CERTIFICATIONS
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water#: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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SAMPLE ANALYTE COUNT
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Lab ID Sample ID
Method
Analytes
Analysts Reported Laboratory
92670767001 SLUDGE BEDS
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
EPA 6010D JOR 10 PASI-A
EPA7471B DBB1 1 PASI-A
SM 2540G-2011 KDF 1 PASI-C
SW-846 KDF 1 PASI-C
EPA 9045D SMK 1 PASI-A
None EWS 1 PASI-A
EPA 350.1 Rev 2.0 1993 Mod. NGP 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 MFO 3 PASI-A
EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC,
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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: EPA 6010D
Description: 6010 MET ICP
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for EPA 6010D by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050B with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 658133
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92570843003
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3449632)
• Antimony
• Iron
• MSD (Lab ID: 3449633)
• Antimony
• Iron
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: EPA 7471 B
Description: 7471 Mercury
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for EPA 7471 B by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 B with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 658504
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92565968002
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3451346)
• Mercury
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: SM 2540G-2011
Description: 2540G Total Percent Solids
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for SM 2540G-2011 by Pace Analytical Services Charlotte. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 26

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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - SuiteA
Eden, NC 27288
[phone]
Method: EPA 9045D
Description: 9045 pH Soil
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for EPA 9045D by Pace Analytical Services Asheville. All samples were received in acceptable condition with
any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of
this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
H3: Sample was received or analysis requested beyond the recognized method holding time.
• SLUDGE BEDS (Lab ID; 92570767001)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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PROJECT NARRATIVE
Project: SLUDGE BEGS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: None
Description: Plant Available Nitrogen
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for None by Pace Analytical Services Asheville. All samples were received in acceptable condition with any
exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this
report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below,
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 26

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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: EPA 350.1 Rev 2.0 1993 Mod.
Description: 350.1 Ammonia
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for EPA 350.1 Rev 2.0 1993 Mod. by Pace Analytical Services Asheville. All samples were received in
acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR)
attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 350.1 Rev 2.0 1993 Mod. with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 659397
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92569953001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 3455877)
• Nitrogen, Ammonia
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: EPA 351.2 Rev 2.01993
Description: 351.2 Total Kjeldahl Nitrogen
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for EPA 351.2 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 351.2 Rev 2.0 1993 with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 658862
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92569953001
MI: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 3453108)
• Nitrogen, Kjeldahl, Total
R1: RPD value was outside control limits.
• MSD (Lab ID: 3453109)
• Nitrogen, Kjeldahl, Total
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: EPA 353.2 Rev 2.0 1993
Description: 353.2 Nitrogen, NO2/NO3
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for EPA 353.2 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions rioted below.
H1: Analysis conducted outside the EPA method holding time.
• SLUDGE BEDS (Lab ID: 92570767001)
H2: Extraction or preparation conducted outside EPA method holding lime.
• SLUDGE BEDS (Lab ID: 92570767001)
Sample Preparation:
The samples were prepared in accordance with EPA 353.2 Rev 2.0 1993 with any exceptions rioted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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PROJECT NARRATIVE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Method: EPA 365.1 Rev 2.0 1993
Description: 365.1 Phosphorus, Total
Client: Town of Madison
Date: December 02, 2021
General Information:
1 sample was analyzed for EPA 365.1 Rev 2.0 1993 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 365.1 Rev 2.0 1993 with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 659612
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92570767001
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MSD (Lab ID: 3456869)
• Phosphorus
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample: SLUDGE BEDS Lab ID: 92570767001 Collected: 11/04/21 11:30 Received: 11/04/21 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3050B
Pace Analytical Services -Asheville
Antimony ND mg/kg 20,3 1 11/08/21 09:10 11/09/21 21:13 7440-36-0
Arsenic ND mg/kg 20.3 1 11/08/21 09:10 11/09/21 21:13 7440-38-2
Cadmium ND mg/kg 0.81 1 11/08/21 09:10 11/09/21 21:13 7440-43-9
Chromium 58.0 mg/kg 4.1 1 11/08/21 09:10 11/09/21 21:13 7440-47-3
Copper ND mg/kg 40.6 1 11/08/21 09:10 11/09/21 21:13 7440-50-8
Iron 29100 mg/kg 406 1 11/08/21 09:10 11/09/21 21:13 7439-89-6
Molybdenum ND mg/kg 40.6 1 11/08/21 09:10 11/09/21 21:13 7439-98-7
Selenium ND mg/kg 8.1 1 11/08/21 09:10 11/09/21 21:13 7782-49-2
Sodium ND mg/kg 4060 1 11/08/21 09:10 11/09/21 21:13 7440-23-5
Zinc 55.5 mg/kg 8.1 1 11/08/21 09:10 11/09/21 21:13 7440-66-6
7471 Mercury
Mercury
Analytical Method: EPA 74718 Preparation Method: EPA 74718
Pace Analytical Services - Asheville
ND mg/kg 0.049 1 11/09/21 16:28 11/10/21 14:32 7439-97-6
2540G Total Percent Solids Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids 9.9 % 0.10 1 11/10/21 17:50
Percent Moisture Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture 90.1 % 0.10 1 11/10/21 17:40 N2
9045 pH Soil Analytical Method: EPA 9045D
Pace Analytical Services -Asheville
pH at 25 Degrees C 6.7 Std. Units 0.10 1 11/16/21 21:21 H3
Plant Available Nitrogen Analytical Method: None
Pace Analytical Services -Asheville
Plant Available Nitrogen 771 mg/kg 1 11/19/21 15:31 N2
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Mod. Preparation Method: EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services -Asheville
Nitrogen, Ammonia ND mg/kg 98.8 1 11/12/21 09:25 11/12/21 11:30 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.01993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total 2570 mg/kg 438 1 11/10/21 19:16 11/11/21 05:00 7727-37-9
353.2 Nitrogen, NO21NO3 Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3 ND mg/kg 39.6 1 11/09/21 22:29 11/10/21 00:16 H1,H2
Nitrogen, Nitrate ND mg/kg 39.6 1 11/09/21 22:29 11/10/21 00:16 14797-55-8
Nitrogen. Nitrite ND mg/kg 39.6 1 11/09/21 22:29 11/10/21 00:16 14797-65-0 H1,H2
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample: SLUDGE BEDS Lab ID: 92570767001 Collected: 11/04/21 11:30 Received: 11/04/21 14:32 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
365.1 Phosphorus, Total
Phosphorus
Date: 12/02/2021 09:22 AM
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
625 mg/kg
48.4 5 11/13/21 01:11 11/15/21 18:13 7723-14-0 M1
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QC Batch: 658504 Analysis Method: EPA7471B
QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92570767001
METHOD BLANK: 3451344 Matrix: Solid
Associated Lab Samples: 92570767001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/kg ND 0.0036 11/10/21 13:37
LABORATORY CONTROL SAMPLE: 3451345
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg 0.05 0.055 109 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3451346 3451347
MS MSD
92565968002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury
mg/kg 0.014 0.072 0.072 0.11 0.094 135 113 75-125 15 H1,M1
Results presented on this page are In the units indicated by the "Units" column except where an aitemate unit Is presented to the right of the result.
Date: 12/02/2021 09:22AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - SuiteA
Eden, NC 27288
[phone]
QC Batch: 658133 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050E Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92570767001
METHOD BLANK: 3449630 Matrix: Solid
Associated Lab Samples: 92570767001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony mg/kg ND 2.5 11/09/21 20:34
Arsenic mg/kg ND 2.5 11/09/21 20:34
Cadmium mg/kg ND 0.10 11/09/21 20:34
Chromium mg/kg ND 0.50 11/09/21 20:34
Copper mg/kg ND 5.0 11/09/21 20:34
Iron mg/kg ND 50.0 11/09/21 20:34
Molybdenum mg/kg ND 5.0 11/09/21 20:34
Selenium mg/kg ND 1.0 11/09/21 20:34
Sodium mg/kg ND 500 11/09/21 20:34
Zinc mg/kg ND 1.0 11/09/21 20:34
LABORATORY CONTROL SAMPLE: 3449631
Parameter
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
Antimony mg/kg 50 46.2 92 80-120
Arsenic mg/kg 50 44.9 90 80-120
Cadmium mg/kg 50 47.2 94 80-120
Chromium mg/kg 50 47.3 95 80-120
Copper mg/kg 50 48.3 97 80-120
Iron mg/kg 500 467 93 80-120
Molybdenum mg/kg 50 50.3 101 80-120
Selenium mg/kg 50 40.1 80 80-120
Sodium mg/kg 500 463J 93 80-120
Zinc mg/kg 50 46.1 92 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3449632 3449633
MS MSD
92570843003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Antimony mg/kg ND 60.4 58.2 17.3 16.6 28 28 75-125 4 M1
Arsenic mg/kg 3.2 60.4 58.2 53.1 55.4 83 90 75-125 4
Cadmium mg/kg ND 60.4 58.2 56.1 57.8 93 99 75-125 3
Chromium mg/kg 10.9 60.4 58.2 67.4 70.4 94 102 75-125 4
Copper mg/kg ND 60.4 58.2 61.7 64.8 97 106 75-125 5
Iron mg/kg 12900 604 582 12000 10300 -154 -443 75-125 15 M1
Molybdenum mg/kg ND 60.4 58.2 53.6 53.7 87 91 75-125 0
Selenium mg/kg ND 60.4 58.2 45.1 46.2 75 79 75-125 3
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3449632 3449633
MS MSD
92570843003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sodium mg/kg ND 604 582 567J 571J 92 96 75-125
Zinc mg/kg 3.7 60.4 58.2 59.1 61.6 92 99 75-125 4
Results presented on thls page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QC Batch: 658950 Analysis Method: SW-846
QC Batch Method: SW-846 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92570767001
SAMPLE DUPLICATE: 3453866
92570767001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture
90.1
89.5 1 N2
SAMPLE DUPLICATE: 3453867
92571546002 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture
%
96.7
96.7 0 N2
Results presented on thls page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QC Batch: 660163 Analysis Method: EPA 9045D
QC Batch Method: EPA 9045D Analysis Description 9045 pH
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92570767001
SAMPLE DUPLICATE: 3459109
92569977002 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C
Std. Units 7.6 7.6 1 H3
SAMPLE DUPLICATE: 3459110
92571574002 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C
Std. Units 7.8 7.9 1 H3
Results presented on this page are In the units Indicated by the "Units" column except where an altemate unit Is presented to the right of the result.
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QC Batch: 659397 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92570767001
METHOD BLANK: 3455874 Matrix: Solid
Associated Lab Samples: 92570767001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/kg ND 10.2 11/12/21 11:19
LABORATORY CONTROL SAMPLE: 3455875
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/kg 510 525 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3455876 3455877
MS MSD
92569953001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia
mg/kg 6410 2440 2340 8780 8430 97 86 90-110 4 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QC Batch: 658862 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92570767001
METHOD BLANK: 3453106 Matrix: Solid
Associated Lab Samples: 92570767001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg ND 50.0 11/11/21 04:54
LABORATORY CONTROL SAMPLE: 3453107
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/kg 1000 1020 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3453108 3453109
MS MSD
92569953001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 34700 4070 4070 49200 38600 356 97 90-110 24 M1,R1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 12/02/2021 09:22 AM
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QC Batch: 658637 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92570767001
METHOD BLANK: 3452243 Matrix: Solid
Associated Lab Samples: 92570767001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/kg ND 4.0 11/10/21 00:13
Nitrogen, Nitrite mg/kg ND 4.0 11/10/21 00:13
Nitrogen, NO2 plus NO3 mg/kg ND 4.0 11/10/21 00:13
LABORATORY CONTROL SAMPLE: 3452244
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 15.2 101 90-110
Nitrogen, Nitrite mg/kg 10 10.3 103 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 25.6 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3452245 3452246
MS MSD
92571531001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/kg ND 33.6 33.6 36.3 36.4 108 108 90-110 0
Nitrogen, Nitrite mg/kg ND 22.5 22.5 23.4 23.2 104 104 90-110 1
Nitrogen, NO2 plus NO3 mg/kg ND 56 56 59.7 59.7 103 103 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE BEDS
Pace Project No.: 92570767
Paco Analytical Services, LLC
205 East Meadow Road - SuiteA
Eden, NC 27288
[phone]
QC Batch: 659612 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.01993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92570767001
METHOD BLANK: 3456866 Matrix: Solid
Associated Lab Samples: 92570767001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/kg ND 0.76 11/15/21 18:11
LABORATORY CONTROL SAMPLE: 3456867
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/kg 48.1 49.9 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3456868 3456869
MS MSD
92570767001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus
mg/kg 625 484 475 1060 1030 91 85 90-110 4 M1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 12/02/2021 09:22 AM
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
H1 Analysis conducted outside the EPA method holding time.
H2 Extraction or preparation conducted outside EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
R1 RPD value was outside control limits.
Date: 12/02/2021 09:22 AM
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: SLUDGE BEDS
Pace Project No.: 92570767
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Lab ID
Sample ID QC Batch Method
Analytical
QC Batch Analytical Method Batch
92570767001 SLUDGE BEDS EPA3050B 658133 EPA6010D 658213
92570767001 SLUDGE BEDS EPA7471B 658504 EPA7471B 658616
92570767001 SLUDGE BEDS SM 2540G-2011 659203
92570767001 SLUDGE BEDS SW-846 658950
92570767001 SLUDGE BEDS EPA 9045D 660163
92570767001 SLUDGE BEDS None 661278
92570767001 SLUDGE BEDS EPA 350.1 Rev 2.0 1993 659397 EPA 350.1 Rev 2.0 1993 659471
Mod. Mod.
92570767001 SLUDGE BEDS EPA 351.2 Rev 2.0 1993 658862 EPA 351.2 Rev 2.0 1993 659003
92570767001 SLUDGE BEDS EPA 353.2 Rev 2.0 1993 658637 EPA 353.2 Rev 2.0 1993 658638
92570767001 SLUDGE BEDS EPA 365.1 Rev 2.0 1993 659612 EPA 365.1 Rev 2,0 1993 659728
Date: 12/02/2021 09:22 AM
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without the written consent of Pace Analytical Services, LLC. Page 25 of 26

Pace Analytical"
Company:
c,[it/tsU,....3
Address:
CHAIN -OF -CUSTODY Analytical Request Document
Chain -of -Custody is a LEGAL DOCUMENT- Complete all relevent fields
Billing Information:
Report To:
Email To:
LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or
"WO#:92570767
ALL SHADEDi
Container Preservative Type
*1101111
P Y I
�I 1 III
Copy To:
Site Collection Info/Address:
Customer Project Name/Number:
Phone:
Email:
Colle ed By (print): ff r
PIALY
Coll By (signa
Sample Dispo I:
I I Dispose as appropriate 1 ] Return
( I Archive:
I Hold:
State:
/
Site/Facility ID ft:
Purchase Order It:
Quote tt:
naround Date Required:
Rush:
County/City: Time Zone Collected:
[ ]PT[ ]MT[ ]CT [ JET
I ] Same Day [ ] Next Day
[ J 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day
(Expedite Charges Apply)
Compliance Monitoring?
[ J Yes 1 ] No
DW PWS ID II:
DW Location Code:
Immediately Packed on Ice:
I I Yes [ I No
Field Filtered (if applicable):
1 ] Yes [ ] No
Analysis:
' Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (8), Vapor (V), Other (OT)
Customer Sample ID
r5) (Ake_ae etc
Matrix'
Comp /
Grab
Collected (or
Composite Start)
Composite End
Date
11-4101
Time
Date
Time
Res
CI
ft of
Ctns
92570767
" P eserva ive Types: (1) nitric acid, (2) sulfuric acid, wr „y, ,,, ,,, ,,"• •.
(6) methanol, (7) sodium blsulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate,
(C) ammonium hydroxide, (0) TSP, (U) Unpreserved, (0) O1J)er
Ana yses
745
J
2
‘c
0
4
3
ci
2
Lab Profile/Line:
Lab Sample Receipt Checklist:
Custody Seals Present/Intact Y N
Custody Signatures Present N
Collector Signature Present (v N
Bottles intact
Correct Bottles
Sufficient Volume
Samples Received on ice
VOA - lieadspace Acceptable
USDA Regulated Soils y.
Samples in Holding Time
Residual Chl uePve,rsen 4J1 N
Cl Strips: i'�&b eldn.tg Ira. "1"..
Sample pH Acceptable
pH Strips:
Sulfide Present
Lead Acetate Strips:
LAB USE ONLY:
Lab Sample # / Comments:
NA
NA
NA
NA
Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used:
Relinquished by/Company: (Signature)
G77-
Rs�- •she y/C mpany: (Signature)
s.
ReUquished by/Company: (Signature)
0
Iv
-
Wet Blue Dry None
Packing Material Used:
Radchem sample(s) screened (<500 cpm): Y
Date/Time:
Date/Time:
'Z\
ad by orr�p
N
y: (Signature}
Received by/Company: (Signature)
SHORT HOLDS PRESENT (<72 hours): Y N N/A)
Lab Tracking }^^ /+
`1 -`•
Samples received via:
FEDEX UPS Client Courier/ Pace Courie
Date/Time:
\\-y-Z\ 1(3Z
MTJNsta.ussegEie
Table ff:
Date/Time:
Date/Time:
Received by/Company: (Signature)
Date/Time:
Acctnum:
Template:
Prelogin• 4 ! I
PB:
Cooler 1 Temp Upon Receipt:
Cooler 1 Therm Corr. Factor:
Cooler 1 Corrected Temp:
Comments:
Lab Sample Temperature Info:
Temp Blan -Re cL Y N
Therm IDt�i c
oC
oC
oC
Trip Blank Received: Y N NA
HCL McOH TSP Other
Non Conformance(s):
YES / NO
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