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HomeMy WebLinkAboutNC0024911_Groundwater Monitoring Report January 2022_20220217�Q ok SEW&940' /N9 Metropolitan Sewerage District ey � OF BUNCOMBE COUNTY, NORTH CAROLINA � � x ysf.. �cPQa COUNTY, February 17, 2022 FEB 2 2 ZU[L Division of water Resources Water Quality Regional Operations Information Processing Unit Asheville Regional Office 1617 Mail Service Center Raleigh, NC 27699-1617 Information Processing Unit: Please find attached Groundwater Quality monitoring reports for January 2022from Metropolitan Sewerage District of Buncombe County (MSD). These monitoring report forms have additional identification on the well ID line, MW-05, MW-06R, MW-07 and MW-08R, for ease and reference. Monitoring Well-05 exceeded allowable limits for pH. Monitoring Well-0611 exceeded allowable limits for pH, manganese, and iron..Monitoring Well-07 exceeded allowable limits for pH. Monitoring Well-0811 exceeded allowable limits for manganese and iron. Please do hesitate to contact me at 828-225-8224 with questions regarding the attached reports. Sincerely, Roger Edwards Director of Operations & Pretreatment MSD of Buncombe County -Protecting Our Natural Resources- 2028 RIVERSIDE DRIVE, ASHEVILLE, NORTH CAROLINA28804 TELEPHONE: (828)254-9646 FAX: (828)254-3299 WEBSITE: www,msdbc.org GW-59A COMPLIANCE REPORT FORM Permit # NCO024911 (Submit one each nuns toring period with GIV-59 forms.) I Enter date monitoring results were due. L02/28/2022_) Will this monitoring report (GW-59 and GW-59A) YES be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question f or 2 is "YES" list in the space provided below the well identification number(a) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES( NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Ojecefor guidance. 4 Are any monitored constituents equal to or above the established standards? YES /NO If the answer to question 4 is "NO" skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below. MW-05 MW-06R MW-07 MW-08R pH 5.7 pH 5.17 pH 6.1 Mn 12,300 ug/L Mn 9,780 ug/L Fe 9,200 ug/L Fe 32,300 ug/L 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO'; skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). MW-05 pH Mn Fe MW46R pH Mn Fe MW-07 pH Mn Fe MOM pH Mn Fe 112120 5.9 533 ugr- 524 ugr- 112/20 6.3 10,000 ugr- 43,000 ug/L 112120 6.2 125 ug/L 627 ug/L 1/2120 11,700 uglL 18,800 ug/L 6/8/20 5.6 618120 5.5 7,880 ugr- 1,820 ugL 618120 5.9 308 ug/L 447 uglL 618120 19,700 ug/L 70,700 uglL 10/23/20 5.4 10/23/20 5.2 9,3W ugL 5,410 uglL 1DI23120 5.9 831 uglL 10/23/20 14,800 ugL 61,600 ug/L 1/16121 5.6 1115121 5.3 8,510ugr. 1,250 ugh 111 S121 6.0 334 ug/L 1/15121 20.1004L 69,000 ug/L 6124/21 5.4 6124/21 5.4 9,980 uglL 5,360 ug/1 6124121 5.9 176 ug/L 6124121 15,000 ugL 50,700 ugA- 1011/21 5.5 1011121 5.2 6,690 ugr- 1,080 ug/L 1011/21 5.8 740ug/L 1011/21 11,000 ug/L 37,600 ug/L Are the monitoring wells listed in section 5 located at or beyond the review boundary? YE NO If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES I NO groundwater quality problem? If the answer to question 7 is "YES', describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surroundina this facility. Failure to do so may subject the permittee to a Notice of Violation. fines, and/orpenalties. 8 The person completing this portion (GW-59A) of the monitoring report should sign below and submit this form with G W-59 forms for required wells to the address provided at the top of the current GW-59 form. 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E � g 0 � N i L) li U� 3 3 aceAnapicalm www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7175 February 07, 2022 Mr. Roger Edwards Metropolitan Sewerage District 2028 Riverside Drive Asheville, NC 28804 RE: Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Dear Mr. Edwards: Enclosed are the analytical results for sample(s) received by the laboratory between January 24, 2022 and January 25, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Eden If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures cc: Ms. Shannon Bergeron, Metropolitan Sewerage District Mr. John Gosnell, Metropolitan Sewerage District Ms. Sheila Kilby, MSD of Buncombe County Mr. Chad Ledford, Metropolitan Sewerage District Mr. Dwayne Martin, Metropolitan Sewerage District Patrick Smith, MSD of Buncombe County, NC Mr. Alan Taylor, Metropolitan Sewerage District REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC d 2225 Riverside Dr. aceAnalytical Asheville, NC 28804 % ww.pacelabsxom (828)254-7176 CERTIFICATIONS Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 South Carolina Certification #: 99006001 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Drinking Water Cart. M 99006003 North Carolina Drinking Water Certification M 37706 Florida/NELAP Certification M E87627 North Carolina Field Services Certification #: 5342 Kentucky UST Certification #: 84 North Carolina Wastewater Certification M 12 Louisiana DoH Drinking Water #: LA029 South Carolina Laboratory ID: 99006 VirginiaNELAP Certification M 460221 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, INC 28804 South Carolina Laboratory ID: 99030 Florida/NELAP Certification M B87648 South Carolina Certification M 99030001 North Carolina Drinking Water Certification M 37712 VirginiaNELAP Certification M 460222 North Carolina Wastewater Certification #: 40 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Wastewater Certification M 633 North Carolina Drinking Water Certification #: 37738 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnalXical wW.pacelabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: January 2022 Monitoring Wells Pace Project No.: ,92584078 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92584078001 MW-08R EPA 350A Rev 2.01993 SRS 1 PASI-E EPA 353.2 Rev 2.0 1993 SRS i PASI-E EPA 200.7 Rev 4.41994 CBV 10 PASI-A EPA 245.1 Rev 3.01994 DBB1 1 PASI-A SM 254OC-2015 MAB2 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 531OB-2014 MDW 1 PASI-A 92584078002 MW-07 EPA 350.1 Rev 2.01993 SRS 1 PASI-E EPA 353.2 Rev 2.0 1993 SRS 1 PASI-E EPA 200.7 Rev 4A 1994 CBV 10 PASI-A EPA 245.1 Rev 3.01994 DBB1 1 PASI-A SM 2540C-2015 ZMC 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 531OB-2014 MDW 1 PASI-A 92584380001 MW-05 EPA 350.1 Rev 2.01993 AMI 1 PASI-E EPA 353.2 Rev 2.01993 SRS 1 PASI-E EPA 200.7 Rev 4.4 1994 CBV 10 PASI-A EPA 245.1 Rev 3.01994 DBB1 1 PASI-A SM 254OC-2015 ZMC 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 531OB-2014 MDW 1 PASI-A 92584380002 MW-06R EPA 350.1 Rev 2.01993 AMI 1 PASI-E EPA 353.2 Rev 2.0 1993 SRS 1 PASI-E EPA 200.7 Rev 4.4 1994 CBV 10 PASI-A EPA 245.1 Rev 3.01994 DB131 1 PASI-A SM 254OC-2015 ZMC 1 PASI-A EPA 300.0 Rev 2.1 1993 JCM 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 531OB-2014 MDW 1 PASI-A PASI-A = Pace Analytical Services -Asheville PASI-C = Pace Analytical Services - Charlotte PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnalytical ww .pacolabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-08R Lab ID: 92684078001 Collected: 01/24/22 14:30 Received: 01/24/22 15:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 0.39 mg/L 0.10 1 01/27/2216:53 7664-41-7 353.2 NO2/NO3 unpres EDN Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Nitrate ND mg/L 0.040 1 01/25/22 13:51 14797-55-8 Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 02/07/22 16:04 Collected By S.Warlick 1 02/07/22 16:04 Collected Date 1124/22 1 02/07/22 16:04 Collected Time 14:30 1 02/07/22 16:04 pH 6.9 Sid. Units 1 02/07/22 16:04 Temperature 16.1 deg C 1 02/07/22 16:04 Static Water Level 10.59 feet 1 02/07/22 16:04 Specific Conductance 416.2 umhos/cm 1 02/07/22 16:04 Odor None 1 02/07/22 16:04 Detected Appearance Clear 1 02/07/22 16:04 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 0112512200:41 02/02/2214:05 7440-38-2 Barium 36.3 ug/L 5.0 1 01/2612200:41 02/0212214:05 7440-39-3 Cadmium ND ug/L 1.0 1 01/25/22 00:41 02/02/2214:05 7440-43-9 Chromium ND ug/L 5.0 1 01/25/22 00:41 02/0212214:06 7440-47-3 Iron 32300 ug/L 50.0 1 01/25/22 00:41 02/02/2214:05 7439-89-6 Lead ND ug/L 5.0 1 01/25/22 00:41 02/02/22 14:05 7439-92-1 Manganese 9780 ug/L 5.0 1 01/25/22 00:41 02/02/2214:05 7439-96-5 Selenium ND ug/L 10.0 1 01/25/22 00:41 02/02/2214:05 7782-49-2 Silver ND ug/L 5.0 1 01/25/22 00:41 02102/2214:05 7440-22-4 Sodium 24500 ug/L 5000 1 01/26/22 00:41 02/02/22 14:05 7440.23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 01/28/2216:25 02/01/2212:35 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 211 mg/L 25.0 1 01/25/22 11:55 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 37.9 mg/L 1.0 1 01/26/22 02:50 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, L-C. aceAnalytical ww pacalabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 fat@/_1Will9LOCI 0EMU] 0k Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-08R Lab ID: 92584078001 Collected: 01/24/22 14:30 Received: 01/24/22 15:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 19.7 mg/L 1.0 1 0112812219:26 16887-00-E 6310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 1.9 mg/L 1.0 1 02/01/22 00:54 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical ww,v.pacolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-07 Lab ID: 92584078002 Collected: 01/24/22 12:35 Received: 01/24/2215:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia ND mg/L 0.10 1 01/27/2216:54 7664-41-7 353.2 NO2/NO3 unpres EDN Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Nitrate 1.0 mg/L 0.040 1 01/26/22 13:50 14797-55-8 Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 02/07/22 16:09 Collected By S.Warlick 1 02/07/22 16:09 Collected Date 1124/22 1 02/07/22 16:09 Collected Time 12:35 1 02/07/22 16:09 pH 6.1 Std. Units 1 02/07/22 16:09 Temperature 11.5 deg C 1 02/07/22 16:09 Static Water Level 11.30 feet 1 02/07/22 16:09 Specific Conductance 317.4 umhos/cm 1 02/07/22 16:09 Odor None 1 02/07/22 16:09 Detected Appearance Clear 1 02/07/22 16:09 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic NO ug/L 10.0 1 01/25/22 00:41 02/02/22 14:08 7440-38-2 Barium 31.8 ug/L 5.0 1 01/2512200:41 02/02/22 14:08 7440-39-3 Cadmium ND ug/L 1.0 1 01/25/22 00:41 02/02/22 14:08 7440-43-9 Chromium ND ug/L 5.0 1 01/25/22 00:41 02/02/22 14:08 7440.47-3 Iron 150 ug/L 50.0 1 01/25/22 00:41 02/0212214:08 7439-89-6 Lead ND ug/L 5.0 1 01/25/22 00:41 02/02/22 14:08 7439-92-1 Manganese 46.7 ug/L 5.0 1 01/25/22 00:41 02/02/22 14:08 7439-96-5 Selenium ND ug/L 10.0 1 01/25/22 00:41 02/02/22 14:08 7782-49-2 Silver ND ug/L 5.0 1 01/25/22 00:41 02/0212214:08 7440-22-4 Sodium 9160 ug/L 5000 1 01/26/22 00:41 02/02/22 14:08 7440-23-5 246.1 Mercury Analytical Method: EPA 245A Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 01/28/2216:25 02/01/2212:43 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 254OC-2015 Pace Analytical Services -Asheville Total Dissolved Solids 211 mg/L 25.0 1 01/26/22 15:18 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 86.9 mg/L 1.0 1 01/26/2203:31 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. ZeAnalydcal' www.pacslabsxam Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-07 Lab ID: 92684078002 Collected: 01/24/2212:35 Received: 01/24/22 15:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 6.7 mg/L 1.0 1 01/28/2219:27 16887-00-6 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services - Asheville Total Organic Carbon 1.1 mg/L 1.0 1 02/01/22 01:12 7440-44-0 Date: 02/07/2022 04:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Without the written consent of Pace Analytical Services, LLC. aceAnalytical e ul .pacelabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-05 Lab ID: 92584380001 Collected: 01/25/22 09:00 Received: 01/25/22 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia EDN Nitrogen, Ammonia 353.2 NO2/NO3 unpres EDN Nitrogen, Nitrate Monitoring Well Data Performed by Collected By Collected Date Collected Time pH Temperature Static Water Level Specific Conductance Odor Appearance 200.7 MET ICP Arsenic Barium Cadmium Chromium Iron Lead Manganese Selenium Silver Sodium 245.1 Mercury Mercury 2640C Total Dissolved Solids Total Dissolved Solids 300.0 IC Anions 28 Days Sulfate Date: 02/07/2022 04:11 PM Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden NO mg/L 0.10 1 Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden ND mg/L 0.040 1 Analytical Method: Pace Analytical Services - Charlotte Pace 1 S.Warlick 1 1125/22 1 09:00 1 5.7 Std. Units 1 5.4 deg C 1 18.19 feel 1 32.4 umhos/cm 1 None 1 Detected Clear 1 01/31/22 16:24 7664-41-7 01 /26/22 17:57 14797-55-8 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 02/07/22 16:08 Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville NO ug/L 10.0 1 01/26/2214:30 01/31/2212:29 7440-38-2 13.3 ug/L 5.0 1 01/26/2214:30 01/31/2212:29 7440-39-3 ND ug/L 1.0 1 01/26/2214:30 01/31/2212:29 7440-43-9 ND ug/L 5.0 1 01/26/2214:30 01/31/2212:29 7440-47-3 217 ug/L 50.0 1 01/26/2214:30 01/31/2212:29 7439-89-6 ND ug/L 5.0 1 01/26/2214:30 01/31/2212:29 7439-92-1 32.6 ug/L 5.0 1 01/26/2214:30 01/31/2212:29 7439-96-5 ND ug/L 10.0 1 01/26/2214:30 01/31/2212:29 7782-49-2 ND ug/L 5.0 1 01/26/2214:30 01/31/2212:29 7440-22-4 NO ug/L 5000 1 01/26/2214:30 01/3112212:29 7440-23-5 Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Pace Analytical Services -Asheville ND ug/L 0.20 1 01/28/2216:25 02/01/2212:48 7439-97-6 Analytical Method: SM 254OC-2015 Pace Analytical Services - Asheville 33.0 mg/L 25.0 1 01127/2215:31 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 4.1 mg/L 1.0 1 01/27/2203:09 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. aceAnalj6cal www.pacelabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-05 Parameters Lab ID: 92684380001 Collected: 01/25/2209:00 Results Units Report Limit DF Received: 01/25/2214:35 Matrix: Water Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 1,3 mg/L 1.0 1 01/28/2219:31 16887-00-6 6310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon NO mg/L 1.0 1 02/01/22 01:31 7440-44-0 Date: 02/07/2022 04:11 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. (�;ZeAnalyficalo %ww.pacelabsxam ANALYTICAL RESULTS Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-06R Lab ID: 92684380002 Collected: 01/25/22 13:50 Received: 01/25/22 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 350.1 Ammonia EDN Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Ammonia 0.14 mg/L 0.10 1 01131/2216:26 7664-41-7 353.2 NO2/NO3 unpres EDN Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Eden Nitrogen, Nitrate ND mg/L 0.040 1 01/26/22 18:01 14797-55-8 Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 02/07/22 16:05 Collected By S.Warlick 1 02/07/22 16:06 Collected Dale 1125122 1 02/07/22 16:05 Collected Time 13:60 1 02/07/22 16:05 pH 5.7 Std. Units 1 02/07/22 16:05 Temperature 17.0 deg C 1 02/07/22 16:05 Static Water Level 10.41 feet 1 02/07/22 16:05 Specific Conductance 269.3 umhos/cm 1 02/07/22 16:05 Odor None 1 02/07/22 16:05 Detected Appearance Clear 1 02/07/22 16:05 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 01/26/2214:30 01/31/2212:32 7440-38-2 Barium 65.6 ug/L 5.0 1 01126/2214:30 01/31/2212:32 7440-39-3 Cadmium NO ug/L 1.0 1 01/26/2214:30 01/31/2212:32 7440-43-9 Chromium ND ug/L 5.0 1 01/26/2214:30 0113112212:32 7440-47-3 Iron 9200 ug/L 50.0 1 01/26/2214:30 01/31/2212:32 7439-89-6 Lead ND ug/L 5.0 1 01126/2214:30 01/31/2212:32 7439-92-1 Manganese 12300 ug/L 25.0 5 01/26/2214:30 02/01/2214:28 7439-96-5 Selenium ND ug/L 10.0 1 01/26/2214:30 01/31/2212:32 7782-49.2 Silver ND ug/L 5.0 1 01/26/2214:30 01/31/2212:32 7440-22-4 Sodium 17100 ug/L 5000 1 01/26/2214:30 01/31/2212:32 7440-23-5 245.1 Mercury Analytical Method: EPA 245.1 Rev 3,0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 01/28/2216:25 02/01/2212:50 7439-97-6 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 171 mg/L 25.0 1 01/27/22 15:34 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville Sulfate 88.3 mg/L 1.0 1 01/27/2203:23 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. 5OAnalytical e www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Sample: MW-06R Lab ID: 92584380002 Collected: 01/25/22 13:50 Received: 01/25/22 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4600 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 9.5 mg/L 1.0 1 01/28/2219:31 16887-00-6 5310B TOC Analytical Method: SM 5310B-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 02/01/22 01:46 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. d aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 674376 QC Batch Method: EPA 350.1 Rev 2.0 1993 Associated Lab Samples: 92584078001, 92584078002 METHOD BLANK: 3529757 Associated Lab Samples: 92584078001, 92584078002 Parameter Units Nitrogen, Ammonia mg/L QUALITY CONTROL DATA Analysis Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EDN Laboratory: Pace Analytical Services - Eden Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 0.10 01/27/2216A4 LABORATORY CONTROL SAMPLE: 3529758 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.2 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3529759 3529760 MS MSD 92584412001 Spike Spike MS MSD MS MSD % Rec Parameter Units -- Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.39 5 5 5.6 5.6 105 104 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3529761 3529762 MS MSD 92584582002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Ammonia mg/L 2.5 5 5 7.9 7.9 108 108 90-110 0 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical e www.pacelabsxom Pace Analytical Services, LLC 2225 Riverside Dr, Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 674908 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Balch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia, EON Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92584380001, 92584380002 METHOD BLANK: 3532572 Matrix: Water Associated Lab Samples: 92684380001, 92584380002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L NO 0.10 01131/2216:14 LABORATORY CONTROL SAMPLE: 3532573 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.3 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532574 3532575 MS MSD 92584366001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.76 5 5 5.9 5.8 103 102 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3532576 3532577 MS MSD 92584370001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.64 5 5 6.1 5.9 109 105 90-110 3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. ?Mnalytical e www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 673694 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Balch Method: EPA 353,2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92584078001, 92584078002 METHOD BLANK: 3526349 Matrix: Water Associated Lab Samples: 92584078001, 92584078002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 01/25/22 13:34 LABORATORY CONTROL SAMPLE: 3526360 Spike LCS LCS % Rae Parameter Units Cone. Result % Rae Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.4 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3526351 MS 92584029001 Spike Parameter Units Result Cone. Nitrogen, Nitrate mg/L 8.5 1.5 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3526639 MS 92583136015 Spike Parameter Units Result Cone. Nitrogen, Nitrate mg/L ND 1.5 3526352 MSD Spike MS MSD MS MSD % Rae Cone. Result Result %Rec %Rec Limits RPD 1.5 9.6 9.6 75 76 90.110 0 3526640 MSD Spike MS MSD MS MSD % Rae Cone. Result Result %Rec %Rec Limits RPD 1.5 1.4 1.4 93 92 90-110 1 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. Qual oval aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 2BB04 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 674062 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. EDN Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92684380001, 92584380002 METHOD BLANK: 3528139 Matrix: Water Associated Lab Samples: 92584380001, 92584380002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L NO 0.040 01/26/22 16:40 LABORATORY CONTROL SAMPLE: 3528140 Spike LCS LCS % Rae Parameter Units Cone. Result %Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3528141 3528142 MS MSD 92584296001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rae % Rae Limits RPD Qual Nitrogen, Nitrate mg/L 0.96 1.5 1.5 2.4 2.4 98 97 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3628420 3528421 MS MSD 92584380001 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Nitrate mg/L ND 1.5 1.5 1.6 1.5 104 102 90-110 2 Results presented on this page are in the units Intl tested by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, I.I.C. ZeAnai(Xical www.pacelebs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 674516 Analysis Method: EPA 245.1 Rev 3.0 1994 QC Batch Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92684078001, 92584078002, 92584380001. 92684380002 METHOD BLANK: 3530518 Matrix: Water Associated Lab Samples: 92584078001, 92584078002, 92584380001, 92584380002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L NO 0.20 02/01/2212:26 LABORATORY CONTROL SAMPLE: 3530519 Parameter Units Mercury ug/L Spike LCS LCS % Rae Cone. Result %Rec Limits 2.5 2.4 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3530520 MS MSD 92584078001 Spike Spike Parameter Units Result Cone, Cone. Mercury ug/L NO 2.5 2.5 3530521 Qualifiers MS MSD MS MSD %Rec Result Result % Rae % Rec Limits RPD Qual 2.2 2.3 90 91 70-130 1 Results presented on this page are In the units Intl tested by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical e www.pacslabsxom Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 673564 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584078001, 92584078002 METHOD BLANK: 3625679 Matrix: Water Associated Lab Samples: 92584078001, 92584078002 Parameter Units Arsenic ug/L Barium ug/L Cadmium ug/L Chromium ug/L Iron ug/L Lead ug/L Manganese ug/L Selenium ug/L Silver ug/L Sodium ug/L Blank Result Reporting Limit Analyzed NO 10.0 02/02/22 13:12 NO 5.0 02/02/22 13:12 NO 1.0 02/02/22 13:12 ND 5.0 02/02/22 13:12 ND 50.0 02/02/22 13:12 ND 5.0 02102/2213:12 ND 5.0 02/02/22 13:12 ND 10.0 02/02/22 13:12 NO 5.0 02/02/22 13:12 ND 5000 02/02/22 13:12 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 3525680 Units Spike Conc. LCS Result LCS % Rec % Rao Limits Arsenic ug/L 500 479 96 85-115 Barium ug/L 500 483 97 85-115 Cadmium ug/L 500 485 97 85-115 Chromium ug/L 500 490 98 85-115 Iron ug/L 5000 4990 100 85.115 Lead ug/L 500 486 97 86.115 Manganese ug/L 500 492 98 85-115 Selenium ug/L 500 468 94 85-115 Silver ug/L 250 241 96 85-115 Sodium ug/L 5000 4940J 99 85-115 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3526681 3525682 MS MSD 92583564003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Arsenic ug/L NO 500 500 476 489 95 97 70-130 3 Barium ug/L 47.1 500 500 506 517 92 94 70-130 2 Cadmium ug/L ND 500 500 465 476 93 95 70-130 2 Chromium ug/L ND 500 500 474 483 94 96 70.130 2 Iron ug/L 1860 5000 5000 6600 6710 95 97 70-130 2 Lead ug/L ND 500 500 463 475 93 95 70-130 3 Manganese ug/L 76.8 500 500 541 555 93 96 70-130 3 Selenium ug/L NO 500 500 484 497 97 99 70-130 3 Results presented on this page are in the units Ind lcated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical www.pacetabs.com Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3525681 3525682 MS MSD 92583564003 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conic, Conc. Result Result %Rec %Rec Limits RPD Qua[ Silver ug/L ND 250 250 233 238 93 95 70-130 2 Sodium ug/L 39700 5000 5000 43300 44000 72 86 70-130 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical www.pacolabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 673980 QC Batch Method: EPA 2007 Rev 4.4 1994 Associated Lab Samples: 92584380001, 92564380002 METHOD BLANK: 3527529 Associated Lab Samples: 92584380001, 92584380002 Parameter Units Arsenic ug/L Barium ug/L Cadmium ug/L Chromium ug/L Iron ug/L Lead ug/L Manganese ug/L Selenium ug/L Silver ug/L Sodium ug/L QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: Matrix: Water EPA 200.7 Rev 4.4 1994 200.7 MET Pace Analytical Services -Asheville Blank Result Reporting Limit Analyzed NO 10.0 01/31/22 12:22 ND 5.0 01/31/22 12:22 NO 1.0 01/31/22 12:22 NO 5.0 01/31/22 12:22 NO 50.0 01/31/22 12:22 ND 5.0 01/31/22 12:22 ND 5.0 01/31/22 12:22 NO 10.0 01/31/22 12:22 ND 5.0 01131/2212:22 NO 5000 01/3112212:22 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 3527530 Units Spike Conc. LCS Result LCS %Rec %Rec Limits Arsenic ug/L 500 488 98 85-115 Barium ug/L 500 475 95 85-115 Cadmium ug/L 500 496 99 85-115 Chromium ug/L 500 504 101 85-115 Iron ug/L 5000 5000 100 85-115 Lead ug/L 500 492 98 85-115 Manganese ug/L 500 502 100 85-115 Selenium ug/L 500 480 96 85-115 Silver ug/L 250 247 99 85-115 Sodium ug/L 5000 4780J 96 85.115 Qualifiers MATRIX SPIKE 8, MATRIX SPIKE DUPLICATE: 3627531 3527532 MS MSD 92584070001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L NO 500 500 497 500 99 99 70-130 1 Barium ug/L 10.3 500 500 488 493 96 96 70-130 1 Cadmium ug/L NO 500 500 489 490 98 98 70-130 0 Chromium ug/L ND 500 500 489 489 98 98 70.130 0 Iron ug/L 347 5000 5000 5370 5390 100 101 70-130 0 Lead ug/L ND 500 500 479 481 96 96 70-130 0 Manganese ug/L 21.5 500 500 511 513 98 98 70-130 0 Selenium ug/L ND 500 500 513 513 103 103 70-130 0 Results presented on this page are in the units Intl tested by the "Units' column except where an alternate unit is presented to Ue right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical e www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527531 3527532 MS MSD 92584070001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Silver ug/L ND 250 250 242 242 97 97 70-130 0 Sodium ug/L ND 5000 5000 5320 5340 96 97 70-130 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527533 MS 92584274005 Spike Parameter Units Result Cone. Arsenic ug/L ND 500 Barium ug/L 61.0 500 Cadmium ug/L ND 500 Chromium ug/L ND 500 Iron ug/L 879 5000 Lead ug/L ND 500 Manganese ug/L 75.6 500 Selenium ug/L ND 500 Silver ug/L ND 250 Sodium ug/L 138000 5000 3527534 MSD Spike MS MSD MS MSD % Rec Cone. Result Result % Rae % Rae Limits RPD Qual 500 521 526 103 104 70-130 1 500 554 566 99 101 70-130 2 500 493 501 98 100 70-130 2 500 500 510 99 101 70-130 2 5000 5560 5650 94 95 70-130 2 500 492 501 98 100 70-130 2 500 572 582 99 101 70-130 2 500 471 482 94 96 70-130 2 250 254 257 101 103 70-130 2 5000 142000 147000 81 168 70-130 3 E,M1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02107/202204:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalydcal e www.paealabs.pom Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 26804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92684078 QC Batch: 673555 Analysis Method: SM 254OC-2015 QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584078001 METHOD BLANK: 3525645 Associated Lab Samples: 92584078001 Parameter Units Total Dissolved Solids mg/L LABORATORY CONTROL SAMPLE: 3525646 Parameter Units Total Dissolved Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 01/25/2211:52 Spike LCS LCS % Rao Conc. Result % Rec Limits Qualifiers 250 244 98 90-110 SAMPLE DUPLICATE: 3525647 92583977001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 207 211 2 SAMPLE DUPLICATE: 3525648 92583977011 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 926 938 1 Results presented on this page are In the units Intl icated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02107/202204:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical e www.pacelebs.com Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 673844 Analysis Method: SM 254OC-2015 QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584078002 METHOD BLANK: 3527088 Matrix: Water Associated Lab Samples: 92584078002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L NO 25.0 01/26/22 15:17 LABORATORY CONTROL SAMPLE: 3527089 Spike LCS LIDS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Dissolved Solids mg/L 250 252 101 90-110 SAMPLE DUPLICATE: 3527090 92584233001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 29400 27900 5 SAMPLE DUPLICATE: 3527091 92584200008 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 508 478 6 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalXical e www.pacalabsxom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 674137 Analysis Method: SM 2540C-2015 QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584380001 METHOD BLANK: 3528505 Associated Lab Samples: 92584380001 Parameter Units Total Dissolved Solids mg/L LABORATORY CONTROL SAMPLE: 3528506 Parameter Units Total Dissolved Solids mg/L SAMPLE DUPLICATE: 3528507 Parameter Units Total Dissolved Solids mg/L SAMPLE DUPLICATE: 3528508 Parameter Total Dissolved Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 01127/2215:28 Spike LCS LCS % Rao Conic. Result % Rec Limits Qualifiers 250 260 104 90-110 92584367010 Dup Result Result RPD Qualifiers 139 137 1 92684401004 Dup Units Result Result mg/L 1800 1830 RPD Qualifiers 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. ;76Analj4icale` (� www.pacelabs.com QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 674138 Analysis Method: SM 254OC-2015 QC Batch Method: SM 254OC-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584380002 METHOD BLANK: 3528509 Associated Lab Samples: 92584380002 Parameter Units Total Dissolved Solids mg/L LABORATORY CONTROL SAMPLE: 3528510 Parameter Units Total Dissolved Solids mg/L Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 01/27/2215:34 Spike LCS LCS % Rae Cone. Result %Rec Limits Qualifiers 250 258 103 90-110 SAMPLE DUPLICATE: 3528511 92584472001 Dup Parameter Units Result Result Total Dissolved Solids mg/L 37.0 37.0 SAMPLE DUPLICATE: 3528512 92584472010 Dup Parameter Units Result Result Total Dissolved Solids mg/L 98.0 97.0 RPD Qualifiers 0 RPD Qualifiers 1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the wrigen consent of Pace Analytical Services, LLC. aceAnalytical wWw.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 673556 QC Batch Method: EPA 300.0 Rev 2.1 1993 Associated Lab Samples: 92584078001, 92584078002 METHOD BLANK: 3525649 Associated Lab Samples: 92584078001, 92584078002 Parameter Sulfate Units mg/L QUALITY CONTROL DATA Analysis Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 1.0 01/25/22 21:01 LABORATORY CONTROL SAMPLE: 3525650 Spike LCS LCS % Rao Parameter Units Conc. Result %Rec Limits Qualifiers Sulfate mg/L 50 51.3 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3525651 3525662 MS MSD 92583957002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rao Limits RPD Qual Sulfate mg/L 50.2 50 50 89.5 89.3 79 78 90-110 0 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3525653 3525654 MS MSD 92583967003 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 344 50 50 92.4 91.3 -504 -506 90-110 1 M1 Results presented on this page are in the units Ind lcated by the "Units" column except whore an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. m aceAnalytical www.pacolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 673906 QC Batch Method: EPA 300.0 Rev 2.1 1993 Associated Lab Samples: 92584380001, 92684380002 METHOD BLANK: 3527222 Associated Lab Samples: 92584380001, 92584380002 Parameter Units Sulfate mg/L QUALITY CONTROL DATA Analysis Method: Analysis Description: Laboratory: Matrix: Water EPA 300.0 Rev 2.1 1993 300.0 IC Anions Pace Analytical Services -Asheville Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 01/27/22 00:49 LABORATORY CONTROL SAMPLE: 3527223 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Sulfate mg/L 50 50.4 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527224 3527225 MS MSD 92583953015 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Cone. Result Result %Rec %Rec Limits RPD Qual Sulfate mg/L 265 50 50 305 308 81 86 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3527226 3527227 MS MSD 92684200005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Cone. Result Result %Rec %Rec Limits RPD Qual Sulfate mg/L 45.2 50 50 94.9 96.6 99 103 90-110 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical e Www,pacelabs.cam Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 674713 Analysis Method: SM 4500-CI-E-2011 QC Balch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584078001, 92584078002, 92584380001, 92584380002 METHOD BLANK: 3531420 Matrix: Water Associated Lab Samples: 92584078001, 92584078002, 92584380001, 92584380002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 01/28/2219:21 LABORATORY CONTROL SAMPLE: Parameter 3531421 Units Spike Cone. LCS Result LCS % Rec % Rae Limits Qualifiers Chloride mg/L 20 20.7 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3531422 3531423 MS MSD 92583740002 Spike Spike MS MSD MS MSD % Rae Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Chloride mg/L 57.4 10 10 68.8 70.8 114 134 90-110 3 M1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. aceAnalytical www.pacelabs.ccm Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: January 2022 Monitoring Wells Pace Project No.: 92584078 QC Batch: 675015 Analysis Method: SM 531OB-2014 QC Balch Method: SM 5310B-2014 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92584078001,92584078002,92584380001,92584380002 METHOD BLANK: 3533221 Matrix: Water Associated Lab Samples: 92584078001, 92584078002, 92584380001, 92584380002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L NO 1.0 01/31/2221:00 LABORATORY CONTROL SAMPLE: 3533222 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.6 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3533223 3533224 MS MSD 92583040001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Total Organic Carbon mg/L NO 25 25 24.9 25.2 100 101 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3633225 3533226 MS MSD 92584704001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Total Organic Carbon mg/L 1.2 25 25 25.8 26.1 98 99 90-110 1 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04: 11 PM without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 2225 Riverside Dr. aceAnalytical a Asheville, NC 28804 wr w.pacelabsxom (828)254-7176 QUALIFIERS Project: January 2022 Monitoring Wells Pace Project No.: 92684078 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL- Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte Is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS E Analyte concentration exceeded the calibration range. The reported result is estimated. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/07/2022 04:11 PM without the written consent of Pace Analytical Services, LLC. m ace Analytical wrw.pacelabsxam Pace Analytical services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: January 2022 Monitoring Wells Pace Project No.: 92584078 Lab ID 92584078001 92584078002 92684330001 92684380002 92584078001 92584078002 92584380001 92584380002 92584078001 92584078002 92584380001 92584380002 92584078001 92584078002 92584380001 92684380002 92584078001 92684078002 92584380001 92584380002 92684078001 92584078002 92584380001 92584380002 92684078001 92584078002 92684380001 92584380002 92584078001 92584078002 92584380001 92684380002 92584078001 92584078002 92584380001 92584380002 Sample ID MW-08R MW-07 MW-05 MW-06R MW-08R M W-07 MW-05 MW-06R MW-08R MW-07 MW-05 MW-06R MW-08R MW-07 MW-05 MW-06R MW-08R MW-07 MW-05 MW-06R MW-08R hnPIrEIM MW-05 MW-06R MW-08R MW-07 MW-05 MW-06R MW-08R MW-07 MW-05 MW-06R MW-08R MW-07 MW-05 MW-06R Dale: 02/07/2022 04:11 PM QC Batch Method EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 350.1 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 353.2 Rev 2.0 1993 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994 EPA 245.1 Rev 3.01994 EPA 245.1 Rev 3.01994 EPA 245.1 Rev 3.0 1994 EPA 245.1 Rev 3.0 1994 SM 2540C-2015 SM 2540C-2015 SM 2540C-2015 SM 2540C-2015 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 EPA 300.0 Rev 2.1 1993 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 4500-CI-E-2011 SM 5310B-2014 SM 5310B-2014 SM 5310B-2014 SM 531OB-2014 QC Batch Analytical Method 674375 674375 674908 674908 673694 673694 674062 674062 Analytical Batch 673564 EPA 200.7 Rev 4.4 1994 673574 673564 EPA 200.7 Rev 4.4 1994 673574 673980 EPA 200.7 Rev 4.4 1994 674123 673980 EPA 200.7 Rev 4.4 1994 674123 674516 EPA 245.1 Rev 3.0 1994 674853 674516 EPA 245.1 Rev 3.0 1994 674853 674516 EPA 245.1 Rev 3.0 1994 674853 674516 EPA 246.1 Rev 3.0 1994 674853 673555 673844 674137 674138 673556 673556 673906 673906 674713 674713 674713 674713 675015 675015 675015 675015 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. laboratorY re lving samples:' avttle Eden[] Greenwood❑ Htintersville❑ RelelghQ MechnicsvilleQ AtlantaQ KernersvllleQ Ash ClPehtName! ProjectNt r WO# : 92584078 O'`i-x 1I258407IIitI ll1lll111 Cqurier: gfedFx ❑UPS ❑U$PS ❑Client �( ❑other._ 8268407 ❑Commerclal Pace CustedY Seal Present? Dyes ONO Seals Intact? Dyes IINo M u ' Date/Initials Person Ex3ntiningtontents: _t.t-.LL(-2 Parking staterial: ❑Bubble Wrap DBubble Bags VJNona ❑ Other Thermometer. �y('7 Vwet (]slue iR Goa to: �30,1j� Type of ice; \ r Correction Factor: Cooler Temp: Add/Subtract (T) Cooler Tem.P Corrected ('C): _ \, USDA Regulated Soil (r/JN/A, wafer sample) or SC maPR s Did samP lesoriginate In aquaftntineeunewithfa the United States: CA, NY, Correct Containers Used7 Sample Labels MagchCOC? Seals COMM 64TS/5AMPt`c OISCREPANCY I]ha CJN/A 16. Elmo ON/A I9. Biological Tissue Frozen? Dyes ONO [/N/A ❑Note Tempshould be above freezing to VC xamples out of temp aberia. samples on ice, coaling Process hasbegun ME 01.7, H field Data Required? Oyes QNo Date/lime: ----- Person contacted: __--. ��/—i//{/—/� — `� V r _ .— Date: I v`tl _ r�! Project Manager SCURF Review: _ Date! project Manager SftfReview: ___- tchl eck rnark top half of box If PH and/or dechlorination is Project It verl lied and within the acceptance range for preservation sa"Ales. Exee ptlons: VOA, Catltorm, TOC, ©Iland Grease, OR0/8015 (watefl OO.C, Ulfg r*B ottom half of box Is to list nUrnber of bottles W0# : 92584078-- PM: UP Due Date: 02/07/22 CLIENT: 93-MSD a a 2 v o V v g S Q �' z U 0 6 tt 4 P Z •t .'2 A Z '^ d a 'n C O[I lh 'Y O O U Q T p S d C O `r a 4 nl V \ v ? m O 1 v p ry /•� S ? p 6 C Q d H S z O •.� 'C. r� E rtgLL _ v a `g p (g, w 5q yG u O 4 a E E E E E E E o y qE b E E E F.E a a S •� uuE�i p n J Z V u 0 O E nl Q a m O G ti t7 t°1a > > n N m ¢ > O — l s — 6 - Z 8 L0 — — 12 u - - - Samples Time preservation Amount or Ptesxrvative Loth added pH Adjustment Log for Preserved Samplc lD Type of Preserva[ive pit upon receipt Date preservation adjusted adjusted ..r;�...., 1til fomt will ha serrt[othe North Carolina DENNR Cxrtiriw[ion OfRtn ti.x. Note: whenxver There isa aiscrepancy mreama r.oar,�.,.,.,•,�•_•.....:......._• Out of hold, incorroa pre ervatlYe, out of temp, incorrect containers, . Bd 3 S&$n7�. 'u o m a v m m n w ro ITEM# $ m A a& ? S n n Cy o qz y 0 N o 0 b n as RaF4e ^f F;y F F a n 9 9 9 n ' 0 0 m �o a 8 li MATRIXCOGE (saevalbcodnsiolefQ Cr SAMPLETYPE (G=GRAB C=COMP) ' D mg F OV C m b RI Te m Z O — m 9 9 SAMPLE TEMP AT COLLECTION Diny C U0 bid /OF CONTAINERS 9 9 9 ➢n O D j N 2 2 2� Unpresenmd 2 A d O 0 H2804 a # 3 IINO3 m HCI c w m WON Ne2S203 oN a < i� s Methanol J4, vti -..• Omer Cj Analyses Test YIN �: Minnie %1 : 8 ammonia -oni Chloride, Sblfale m N Nilmte q. 4� TDS TOC s S: r3 3 r3 y � b EMPinC 'r N � E ResitlualCMorino (YIN) @ @ R 5 Received onIce y (Y/N) (Y oy Sealed �1J O Coolar YIN O O Semplss Inlact (J J (YIN) 2 S m m N u cn � � •-. •-• �i n n m v n n A nn 51 ... g g 't.. S m � o o = a �' �• • r � � I� N � � a v n O % S� v ro n S •-. � S$ S. S �• � f N 410 D� nw p y a ?F c ' 3 3 •Sl 3 n. a J o o °£ noz � •• iD �, � 0 C W J N N ° .Z .� O 6 7 r '� R C N o N '•J C n. d p_ y p G A A � o, n et b 3. m '35 '��. a a 3 2 c 2 z H m � V n 3 P o w 3,m 3 p4 n co.. �q 3d � 01 Po /y� W fqq. Y'M rpNp ryYry IHYd CO° N M " N 'YO '0 'YO p� N V]yj a ryY. t°f b o KPP KPP �pgp 1-•o gN10N Gd GpHI�NN !+j R 5 H •• •• n Y �. .1 0 p Y d 10 F N n a LT C. 3 M 0 2 Z n y P ng n n 9 3 ° 3 w iJ iYK RN 00 N 'q Pal P' �n ° m 3 3 =° !: !: 3v a dN p1m m 1.0 P d�° �n µMae pYpj��n �° GS x Y n n""° �wn 6'I pry H F.nq 14H 2 3TAg6o.3 fJ($�k ° ovt !? O� � � 1, 5 5 Q+5�55555555 �? I0 �v � rPrr ii$r0�a� n Z a ^In Document Name: Document Revised: November 15, 2021, Sample Condition Upon Receipt ($CUR) Page 2 of 2 Document No.: Issuing Authority: IA;a1ceAndlytal, .;F- f-CAR-CS•033-Rev.08 Pape Carolinas Quality OHiee 'Chet k mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation sampl es. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bot-tom half of box is to list number of bottles Project# WO# ; 9258 80 PM: UP Due Date: 02/08/22 CLIENT: 83—MSD Z v D Y Z E Z V N V Z Ni n 4 Dy N V V ? Z I Q Q V _- j4 v £ i V Y Z _ Q Y Z y v o. O O n n `Z" b e' N n v yryO� Q e rOAvO1 v a r Y E X z C 0 It O E./E� y E E E E o v e d a� E E E. E s A E E N r�E �p(E, y NEry yob vE1 QQ 0o 4 E J V i lit J N N V M V V t� s� Ni C od m am m m m- m a,¢ C ¢ 6 Q Q > > > uoi N m Q o 3 — pH Adjustment Log for Preserved Samples Samplel0 rypeof Preservative pH upon receipt Date preservation adjusted Time preservation Amount of preservative totes adjusted added Note: whenever there is a discrepancy affecting North Carolina compaancet samples, a copy or inn corm wn. oe sent m me NOW, Cu.m,na 0. HNn Cailn,L aflur 0 Our of hold, ,ncorrect preservative, out of temp, incorrect containers. Document Name: —. .----____ Document Issued: Geld Data Shea Pa e 1 of.- _. F nrCiln,ll iCd/ � Document Nmnber; Isstimg Auutority: P-CA&FLD•001-rev.01 Pace Hunlersville Qu'llity Office l �•� Field Data Sheet Client: mS V — Location: _� L t' � t �(��G_ ProjectNanw/N: M w_S_ Name and Afiliation (Sanlpler(s):---- `> _NIV 1_. 1� c i, v Name and Afiliation (Inspector):_,-. ..... _ Well Information Well ID:—h&-tr! "" O4 (�---- \n Well Diameter:._ 'total Well Depth:_L!-y A rA ft Static Water Ileight of Water Column:_Sp_,_J_�_ft Well Locked: yws 0 Construction: C Steel Stainless Steel 4lultiNactor':_� _(_�' _p(tadnu/rzlzx0,1:1xzasl Casing, Volume:_? LI—gnllons Cal.3 Volumes: / ('� gallons Purge Information �,., - i /cYl/ , n ` _L Date Purged: �_....../.ZL`../___�� Start Time:-_� � BhlisEl:� ��?-_PurgeRate:- 00hi J Purging tetirod:__ r -- �L) ���.i1_� _---fatal Volume Puged: � (t� / .-- gallons Sampling Information Date Collected:/ 1�/ `'_._.-fimeCollected: {_..... alp m t Sampling Equipment lJsecL_+.f,-i lnstrumentlD:_'�_)�.i._LU Baltic type Preservation Field Measurements/Observations Sample pi[(s.u.):._..tz_-i�l.____—__1'ime:_L Specific Loud. (uS)�:` _\[i I��_ Time:.- i i 3U _ ReDox (mV): �._1-1,a_'? -_._-- Time: Odor: —------ ' _—_—.. --- Time:_. U i Analysis Required 'I'urbidily (ntu);-- �..._'..1� Time: uLq? --- Digs Oxy (mg/1.):__�>.-__... "fine: -- Res. Cl (mg/[.)or(pg/L):------ Other: Other:.-- f't9 Appearance: GeneraUtNeather Observat ons � , Sampler Signature/Date asauu ¢uumi that Time (s.u.) Sec. Cond. P ReDox(mV) Turbidity (ntu) Diss Oxy.JolumepH (mg/L)is movedotherPurged (us) (P Ci G. , i i Us'Scz Documont < Aacv/Wlyfradl Field Data Sheet Face Issuing Field Data Sheet l Client: AM-9 -- Location: Name and Afiliation --- ____. Well Information l'VellID:_(1?_(� ---- Well Locked: YNS t Well Diameter:-___.�___ Cmnstruction: {V Sled StainlessSteel Total Well Depth:4�_—____._It MultiPactor*:D,1.6,� _//(^((tarn,=/I2)2x3.Llx7a81 Static Water LeveL•`1 Q,_it Casing Volume: _ e_lj_�L..._ gallons I eight of tinder Column:__L.'ft C'al.3 Volumes: l-1- -- gallons Purge Information_ Date Pin ged -) .-._ _ / -/ z 2 _ .. Start'I nne._ 1.z1.�, ..._._ Finish _�'Z' g __Purge Rnte: ~Z ��..WIG 9 (Uw Z' (rt Purging ----Total Volume Purged: wiQ�% gallons Sampling Informl!at on (i C, Q W z �A rr min II Sampling EquipmentUsed:_J' F15F�G�'tG Inshuu)entlfk._ 1._� U t' 6QI_.� V� Bottle Type Field MeasuremeWs Observations preservation Sample `I'ennp (°C): _...�.1..t__JI _._.__'finredi ? _ Specific Cond. (uS):.�a_� 7.1 �..._...._- Time: ReDox (Ul l rvalue): Odor: Analysis Required 3h Turbidity (ntu): _7. 1._......._7 i ...—.--- 1'inte: ___..._______._.. Diss Oxy (img/L): �)_t. 7_._._._,11111c:,_12 3 Res. CI(mg/L)or(pg/L,) Other: Other.-_ 1 G7.A.___ti_L_'fime: _ Appearance: Ceneral/Weather Observations (0 ---_— SamplerSignature/Date.: _.. •��ldl___.-.�.(.(�(� . _...._/..__ `_l�? �,� .�, �-__--...-__.. _----- _.-... Ua611haetnn Tne! Time Purged PH (s,a) Spec. Cond. (US) ReDox (mV) Turbidity (ntu) Diss Oxy. (mg/L) a Temp. (C) Volume Removed Other 12 i 2 D 1 2 "zit Nio P G 3. 0? ., l e —16 Q I I� 'z, ' n) Q IQ!' o 17T7) I � z t_ , � 3 , I \ , � t q09 Document Nine: Docu�nteot Issued: 1 f Field Data Shm-t PaLe l of �_. Document Numbec Issuuig Authority: -P+tc[aln;)fyGcdl F•CAtt•Fj D001 mv.01 Pace t{utttersviliu Quality Office Field Data Sheet Client: +__.____ Location:"rg \� (/,�_,�,t 1'1%i. _ Praject Nante/#:- Name and Afiliation(Santpler(s):---'_�_"y-�_�------- Name and Afiliation (inspector):----_l-f_� Well Information. Well ID: . u / IVN — Well Diameter: Total Well Depth; iL-1,12 ft static Water Level: 6 1 � . ---ft Height ofWater Colunim- --a,_ L-ft Well Locked; YI?S0 Construction: GVC Steel Stauliessacel Multi Factor': �f�6_'-(+(Radius/11)2x3.idx7.aSl Casing Volume; gallons Cal.3 Volumes: + $L•_gallons puree Information Date Purgerl:_l.._...-./-.Z.._�?_/_ 'G StmtTinge:_ 3d Finish: _.1A Purga purgingbletltod: JP..(a-._�9-_j_LG------- TotalVolumePurged: 11 00---gallons Sampling Information Date T me Collected:1C no-._ am pm Sampling Equipment Used:_(',�122.VnII;L lnstnunent1L): L 1�j�Lj �1 1T f�laJ- £�WC�_ Itottle'l'ype Preservation Field Measurements/Observations Sample Ternp (oQ: _fi 1-_ �1 ..—,'l'ime:o Cl CC -- Sample pl-I(s.u.):._.."l'nge:A0� 2.17 _- Specific Cond. (us): 3 t " _ Time; I_DiJO -- ReDox (mV):..._._�_� g +. ...... _...... Time: b d (f ReDox (Eli value):.._Ai Odor: .-1�1 �_�— Time: ltlu O Analysis Required Turbidity:-.. Time: '(>00 ( ntu)- _.� DissOxy(mg/1):4,�.__..__--_Tit»e:_ odd Res. CI (ngg/L)or(pg/L), Tinge:_.-"'.�.__-__ Other:. w r� _--� U 'rime: _q 00 e Other: _.._ . _�rin,e:'-'.�'-• .._- Appearance: 4 �p r ._-.._IIhne;__lA-00 General/Weather Observations Sampler Signature/Date:-,._`�uyl—�l/..(1aL/JL_._� � �_L�_—...-----_----------- Stabilization Test Time Purged PH (s.u.) Spec. Cond. (uS) ReDox (mV) Turbidity (ntu) Diss Oxy, (mg/t) o Temp. (C1 Volume Removed Other Bolq � t ">z 3 'lhF, ra t t Q fi t j2bd oqq� rz .h"1ii i,w Document Name: Document Issued: April 6, 2015 RL'fiitfl8iyll(k'if9 Field Data Sheet Page 2 of ?Y_ _y Document Number: Issueing Authority: F-CAR-FLO-001.rev.011 Pace Huntersville Quality Office client: LocatIOW � k , tTS�_ �r Project: ---JIA 2 J Well ID: 61 v —0 � Stabilizattlon Test Time Purged pH (s,u.) Spec, Cond, (US) ReDox (mV) Turbidity (ntu) Diss Oxy, (mg/L) u Temp. (C) Volume Removed Other __. Document Name: "� Document Issued: Field Data Sh.�t I Pagel off„ PnCe/In.tlyLC,7l Document Number. fssubrg Authority: F•CAR-FT.D•001,rev.01 face 1111atersvilte Quality Office Field Data Sheet Client: 5 ----- Location:. ?�-1(G ,y�_---- Project Name/Lt: - Name and Affiliation (Samplcr(s):___`?�_'Al- P-tr'. P Name and Afiliation (Inspector):-------_�-------..---.__-- Well Information Well ID: } Yi Well Diameter: Total Well Depth: -1 210 ft Static Water Level:_ I' 1 -_ft Height of Waiercolunut: -L— j_Jt Well lucked: Ym 'L) Construction: V Steel StahllessSteel Multi Factor*:o1,_LL f•ptadius/12)2x3.14x7ag1 Casing VOhtmel _� gallons Cal.L allons Cal. 3 Volumes: Payee Information ` }_ f Date PurgerL,..(.__._../._/. StartTime:-_t- Finish: 10.t_._PrngeRatc: Purging hfctlwd:_,_p_LQ�.};' �•�('4.�, j (�.__.—._._._Total Vohune Purged: gallons Sam olfng Infornation Date Collected: _�._/?_�'/ 1' "1'inneCblfected: 3 5�L-=. — am k Sampling Equipment Used-: -F d f ID:- 2_ Bottle'rype Preservation Field Measurements/Observations Sannplc'Pemp (°C):U.— S,ar nple Ptl (s.u.): 5 z1----. l'iale: Specific Conti. (6):'J. Cl �3 Tinte:__IaLi� ReDox (mV): _� �d.i_.t..�Time: ReDox (Till value):�Li--t---- Odor: ___ 0 _._-.__— Ceneral/Weather Observations Analysis Required 'turbidity (ata): -_. Time: Diss Oxy (mg/L): 11 h,_....._.'f'ime:._ 1�'r ri V Res. Cl Other:..- I ran p 'rime:_ sa j .� Other. 'Pine: -_--.___---- i\ppearancu: S. w iff rl r _ Sam tler Si nature Date: Stabilization Test Time pH (s,u•) Spec. Cond. ReDox (mV) Turbidity Diss Oxy. Temp. (°C) Volume Other Purged (us) (ntu) (mg/L) Removed 3 y ti6'314