WQ0000430_Residual Annual Report 2021_20220216

Non -Discharge Branch Upload/Submittal Form
NORTH CAROLINA
EnvironmentalQuul1ty
Version 2 - Revised June 23, 2020
Initial Review
Reviewer
Thornburg, Nathaniel D
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?*
Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2021
Permit Number (IR) * WQ0000430
Applicant/Permittee City of Cherryville
Email Notifications
Does this need review by the hydrogeologist? * 0 Yes OO No
Regional Office
CO Reviewer
Admin Reviewer
Mooresville

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name*
Lysa Finnerty
Email Address*
[e-mail]
Project Information
Application/Document Type *
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
14105376150
O Modification - Minor
O Renewal
O GW-59, NDMR, NDMLR, NDAR-1,
NDAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deg.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type: *
Permit Number:*
Applicant/Permittee Address *
Facility Name*
Wastewater Irrigation
Other Wastewater
Closed -Loop Recycle
Single -Family Residence Wastewater
Irrigation
WQ0000430
Has Current Existing permit number
435 Williams Court, Ste 100, Baltimore, MD 21220
City of Cherryville Class B Residuals Program
Please provide comments/notes on your current submittal below.
2021 Annual Report for City of Cherryville, NC.
High -Rate Infiltration
Reclaimed Water
Residuals
Other
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here. *
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
Cherryville NC 2021 Annual Report FINAL.pdf 6.77MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order and
made payable to the North Carolina Department of Environmental Quality (NCDEQ).
I also confirm that the uploaded document is a single PDF with all parts of the
application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
lyaa„ff./0u0
Submission Date 2/16/2022

435 Williams Court, Suite 100
Baltimore, MD 21220
wwwsynagro.com
SYNAGRO
FEBRUARY 16, 2022
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2021 Annual Report for Permit No. WQ0000430
Dear NCDEQ:
Synagro is submitting one electronic copy of the above referenced report on behalf of the City
of Cherryville, NC.
If you have any questions or need additional information, please do not hesitate to contact Larry
Wright at [phone] or Alex Fox at [phone].
Sincerely,
De't ic& Sfiiva't 25
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: Larry Wright, City of Cherryville
Alex Fox, Synagro
YOUR PARTNER FORA CLEANER, GREENER WORLD

CITY OF CHERRYVILLE, NC
RESIDUALS LAND APPLICATION PROGRAM
Permit No. WQ0000430
2021 ANNUAL REPORT

City of Cherryville, NC
Residuals Land Application Program
2021 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms and
Residuals Analyses
3. Annual Land Application Field Summary Forms
4. TCLP Analysis
5. Pathogen ReductionNector Attraction Reduction
6. Soil pH & Lime Application Records
7. Soil Analyses

SECTION 1

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit ##: W00000430 County Gaston Year 2021
Facility Name (as shown on permit) City of Cherryville WWTP NPDES No. NC0044440
Land Application Operator Svnagro Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. if NO, skip Part A, and Part 13 and proceed to Part C. Also, if residuals were generated but not land applied,
please attach an explanation on how the residuals were handled.
Part A —Residuals Application Summary:
Total number of application fields in the permit: 8
Total number of fields utilized for land application during the year: 3
Total amount of dry tons applied during the year for all application sites: 60.68
Total number of acres utilized for land application during the year:45.7
Part 13— Annual Compliance Statement:
Facility was compliant during calendar year 2021 with all conditions of the land application permit (including but not limited to items
1-13 below) issued by the Division of Water Quality X YES NO.
If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached,
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5, All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503
regulated facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9, All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C — Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations."
Larry Wright, Plant ORC & Plant Supervisor
ermittee Name and Title (type or print)
Sig na e of Pr . arer* Date
(if diffe ent frohi Permittee)
Signegns ireofPer r e• Date
2/9/2022
Sig uLandA tier Date
(if different fr Permittee an. Preparer)
*Preparer is defined in 40 CFR Part 503,9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 1/1/2021 - 12/31/2021
CHERRYVILLE, NC
CHERRYVILLE, NC LIQUID
MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS
November 2021 446,400.00 G 60.68 D 55.04
TOTAL 446,400.00 G 60.68 D 55.04
Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards
Report Date: 1/29/2022 1:07:47 PM

SECTION 2

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - S
WO Permit Number: WQ0000430 Laboratory:
Facility Name: CHERRYVILLE, NC PACE ANALYTICAL
Residual Source WO # or
NPDES#: NC0044440
WWTP Name: CHERRYVILLE
Residual Analysis Data
Product Type LIQ
Sample or Composite Date 10/05/21
Parameter (mg/kg dry weight) Ceiling Conc.
Limit
Percent Solids (%) NA 3.26
Arsenic 75 <2.5
Cadmium 85 0.69
Copper 4300 240
Chromium NA 16
Lead 840 14
Mercury 57 1.1
Molybdenum 75 <4.9
Nickel 420 14
Selenium 100 <4
Zinc 7500 290
Total Phosphorus NA 30000
TKN NA 41000
Ammonia -Nitrogen NA 7800
Nitrate and Nitrite NA 99
For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified
personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the
possibi ity of fines and imprisonment-fer-kQowing violations."
nature of Pr parer*
2- 9--2v2_2.
Date
eparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF {1212006)
Printed: 1/29/2022 11:53;40 AM For: 2008 01

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WO permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
WQ0000430
CHERRYVILLE, NC
NC0044440
CHERRYVILLE
Residual Analysis Data
Product Type
Sample or Composite Date
Parameters (mg/kg dry weight)
Aluminium
Calcium
Magnesium
pH (s.u.)
Potassium
Sodium
PAN
SAR (Ratio)
LIQ
10/05/21
15000
4800
1400
7.20
1800
1800
13959
0.9406
Laboratory:
PACE ANALYTICAL
"1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified
personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations!
nature of P
Preparer is defin-d in 40 CFR t1 503.9(r) and 15 A NCAC 2T.1102(28)
Printed: 1/29/202211:54:52 AM For : 2008 01
2-9--20Z2-
Date
DENR FORM RSSF-8 (12/2006)

PaceAnalytical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Cherryville
Lot Number:WJ05059
Date Completed:10/19/2021
10/21/2021 11:11 AM
Approved and released by:
Project Manager II: Lucas Odom
A413
ANSI Wong Board
ACCREDITED
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel: [phone] Fax: [phone] www.pacelabs.com
Page 1 of 16

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653
NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: WJ05059
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low percent solids, the initial sample amount used for the following sample was deviated 3X
greater from the standard procedure: WJ05059-001. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
The method blank for prep batch 18139 contained total phosphorus greater than the method acceptance
criteria. The associated sample contained detections for this analyte at concentrations greater than 10X
the value found in the method blank; therefore sample results are not impacted. The data has been
reported.
Pace Analytical Services, LLC (formerly ShealyEnvironmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 16

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Synagro
Lot Number: WJ05059
Sample Number Sample ID
Matrix Date Sampled Date Received
001 Cherryville Solid 10/05/2021 1020 10/05/2021
002 C 1 Solid 10/05/2021 1020 10/05/2021
003 C 2 Solid 10/05/2021 1020 10/05/2021
004 C 3 Solid 10/05/2021 1020 10/05/2021
005 C 4 Solid 10/05/2021 1020 10/05/2021
006 C 5 Solid 10/05/2021 1020 10/05/2021
007 C 6 Solid 10/05/2021 1020 10/05/2021
008 C 7 Solid 10/05/2021 1020 10/05/2021
(8 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 16

Inorganic non-metals
Client:Synagro
Description: Cherryville
Date Sampled:10/05/2021 1020
Date Received:10/05/2021
Laboratory ID:WJ05059-001
Matrix: Solid
% Solids: 3.26 10/05/2021 2221
Run Prep Method
1 350.1
1
1
1
1
1 351.4
Analytical Method
(Ammonia - N ) 350.1
(Nitrate - N ) 9056A
(Nitrite - N ) 9056A
(Phosphorus) 365.1
(Soil pH meas) 9045D
(TKN) 351.2
Dilution
10
10
10
25
1
2
Analysis Date Analyst
10/07/2021 1949 DAK
10/13/2021 1320 AMR
10/13/2021 1320 AMR
10/11/2021 1527 DMA
10/10/2021 1702 NBW
10/07/2021 1626 DMA
Prep Date Batch
18067
18772
18775
10/08/2021 1101 18139
18286
10/07/2021 0928 17903
Parameter
CAS
Number
Analytical
Method
Result Q LOQ
DL
Units Run
Ammonia - N (gas diffusion)
Nitrate - N (soluble)
Nitrite - N (soluble)
Phosphorus
Soil pH measured in water @ 18.4 ° C
TKN
7723-14-0
350.1
9056A
9056A
365.1
9045D
351.2
7800
99
ND
30000
7.2
41000
310
J 150
61
B 3800
160
31
31
770
3100 1500
mg/kg 1
mg/kg 1
mg/kg 1
mg/kg 1
su 1
mg/kg 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 16

CVAA
Client:Synagro Laboratory ID:WJ05059-001
Description: Cherryville Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 3.26 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1 7471B
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
7471B 1 10/13/2021 1411 CMS2 10/12/2021 1313 17959
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Mercury
7439-97-6
7471B 1.1 J 2.2 0.53 mg/kg 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 16

ICP-AES
Client:Synagro Laboratory ID:WJ05059-001
Description: Cherryville Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 3.26 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1 3050B
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
6010D 1 10/07/2021 1421 JMH 10/07/2021 0320 17835
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7429-90-5 6010D 15000 200 74 mg/kg 1
7440-38-2 6010D ND 7.4 2.5 mg/kg 1
7440-43-9 6010D 0.69 J 2.5 0.62 mg/kg 1
7440-70-2 6010D 4800 2500 310 mg/kg 1
7440-47-3 6010D 16 4.9 1.2 mg/kg 1
7440-50-8 6010D 240 4.9 2.2 mg/kg 1
7439-89-6 6010D 10000 49 22 mg/kg 1
7439-92-1 6010D 14 4.9 2.2 mg/kg 1
7439-95-4 6010D 1400 J 2500 310 mg/kg 1
7439-96-5 6010D 230 7.4 2.9 mg/kg 1
7439-98-7 6010D ND 20 4.9 mg/kg 1
7440-02-0 6010D 14 J 20 5.2 mg/kg 1
7440-09-7 6010D 1800 J 2500 310 mg/kg 1
7782-49-2 6010D ND 9.9 4.0 mg/kg 1
7440-23-5 6010D 1600 J 2500 310 mg/kg 1
7440-66-6 6010D 290 25 6.2 mg/kg 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 16

Inorganic non-metals
Client:Synagro Laboratory ID:WJ05059-002
Description: C 1 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 5.84 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 34237 * 20
col/g 1
Footnote(s): *Fecal Coliform (MF) - results estimated
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 16

Inorganic non-metals
Client:Synagro Laboratory ID:WJ05059-003
Description: C 2 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 4.32 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <23167 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 16

Inorganic non-metals
Client:Synagro Laboratory ID:WJ05059-004
Description: C 3 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 5.15 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <19420 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 16

Inorganic non-metals
Client:Synagro Laboratory ID:WJ05059-005
Description: C 4 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 6.04 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <16552 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 16

Inorganic non-metals
Client:Synagro Laboratory ID:WJ05059-006
Description: C 5 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 4.94 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <20254 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 16

Inorganic non-metals
Client:Synagro Laboratory ID:WJ05059-007
Description: C 6 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 3.39 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <29458 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 16

Inorganic non-metals
Client:Synagro Laboratory ID:WJ05059-008
Description: C 7 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 6.56 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <15233 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 16

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 16

9i Jo gI aged
o - 0,)
(1)
co
o 3.
13 a)
o —
5'
0
CD 2
cp 0
.....,
O 3'
o
SP,
E
3
,F)
cp
O CD
s) ▪ rri
-4 - G.
N.) ,
0
• D
-4 - --
(0 (1)
0 c,
0 s,
-110
• P
x
ix;
0
-4
co
woo.sqepoedwimm
ace Ararylicao
&elm A
C3a1
•33'
CHAIN-017--[;USTODY AnaiyticE1 gerwaM, Document
Jr CUSnTdr n I 1-..61 . :ekoart liakl; FT1L1I 1441...unild:rd znalzi*
ZIA213rP S%-atian
nguanki1 '111:114117fIrithr[ iferfi!en !rile far]:
2B4 RumRL.
IVICakkAale,
C n I c
''•tt, bun: orever
rxEnpint EynnAro
Addre
Rhone! c
41cE4.4.41 tr Dzi
gojti i, ra1ccvsyli1c.NIU...W.2.e
FLrLt Gfillf 1,15,;
Fr.jr1 Taw CAer way..
Froicti.
4
frrcroana,
SAMPLE ID
t )
S....fliar4PAJE,TEIEUNE,JE
VAIN,
u
3L
CAT_LECT.ED
I:444TE "NE
444
P'44p4
R4A1*.mr
1.444.7.•44.t
[-WTI:CM
.040411A4
P1574
TIiE
P. Fro-0)
PrascrvdtiC5.
g 13
z
•
f :-$.,12.7:2,Z15111:(ClitiA L CtOrIliM; r , -t, .09ig'76.-.14cp..4 ,,,i,-L,i_63Y,E ,,'i ---:•6-:,:ir,v-,
._ Irio-r-P II :Sig
A,Y.e--1.411 i cf/ri if tf
srAMF,17*!4:0e Nu....ftkIrquad,'
R '1= r P*, g - •
▪ NE S Gita.KP WATER
usr r FCRA
t6i1:41.vvationl
Ann liCg:.FilZered
F
E
-E
117. .5•FNK 5.k2 ViA•14
.7.7HFP
IMMO
WJ0509
Fro FE1 ,
74.
x
X X
ski6-iwz
UNAFLE cunt -Huila
Pecild-'1e- aisx--„• /
-40 S
M.74%T.1113 SAMPLErt I I7A74 %E.4.44.41
411,,ca 11.1a4CEINTIr
Ltui
.r-ALL-L-.Z4AL.'04,611.04.‘44-Kilf
PACE ANALYTICAL SERVICES, LLC

PACE ANALYTICAL SERVICES, LLC
Samples Rcccrpt CIi dcIiht (SRO jM1=0(1I8C-I5)
IssuL•ta Author:4; Pace ENV - 4l<+C'CL
Simple Receipt Checklist (SRC')
tvlicrm S '' ' Cr,+uicr [ns.ected byIdate: JRG2 r I0.4J5,202E [_ci! 4t; A'Ji:SI151
k'lcEns of receipt: Puce •Client UPS fedF:x • °titer - —
Yes El No 1. Weat custody ht3ILs present on the caale --
Yea No PPM 2, lrcustodly seals'. ere resent, were they i]ttpst and nnhrakert7
pH Strip II: C=[o,inStrip [7I'm -
Tested by:TM" --
Original ternpyruturc upon receipt r' Derivrj (Corrected)temperature upon receipt %S�FIid Sri -Cup ID.,
I /_ 1 s,+ N! /NA Cc NA /NAi oc+ NA »JA oc.'
Mc#hod: ETEmperaturc Blank LiEainst Bottles IR Ciun ]l7: '' JR Gun Correction Rector: _
Method ofOualcnt: El. wet Ice 111 Jce Packs ❑ 1Dry Ice ❑ None
7171 Ye El No DNA 3_ If tamper [I pre of any cjc I:r exceeded 6.0cC, www Project Manager `arti rice
�k.
No
17Y LI No
7 'f_ No
rerYea
❑✓ 'Yes
li
❑ No
No
No
❑ No
d
Yes
▪ N
Yes
Ys r
El Yes
—Yes
Yea L No
Pik was Netilled Uyr_ p1 nc / entail /'Lace -to -fact (circle ane j_
N.A'4. ]s com,I erciai cau_ier's puc:kings[ip or:Ached to this form?
Revised: 9 j29P020
Page 1 of 1
21-t926
DC
I5. 4Jere proper r_USt,dy procedures (reiittgc. s]tcd'reeeived) fol/owei.17
6. Were sample IDe listed on the CDC?
Were: stampie ED41i k t1 on ail s mpie cunteinors'f
Was collection data & tirne listed on the COC)
9_ Was colicetian date &. 'Lillie listed on all sourp le ounteincrs7
Ditl all conta111er ]abet information I(, drite, time) agree whir the i OC?
I i_ Were texts *o he performed listed on the COG?
8,
[2- Did al: sxrnple arrive i„ ;he piper cor•miners fur Inch test andlor in gcet/ eondition
(Unbroken. ]ids an, etc_)?
I. Was acleCtrirIs sample woiume avaifible?
11. Were all surnple.3 received will lin Y2 the holding time or 43 hours, whichever conies first?
15. Were any samples cr,utainRestuissinglcxcess fcirelcone) samples Not listed on COC7
Li. Nal [/J NA ]6. For VOA and RSX...l75 samples, were bubbles present ›"lee -size (' 'or 6:nm in diamictot)
u� zny of the VOA vials'
i� No ' INA I.!. Were all DRC froetalsinucri Ent samples meet i v d t r a pI'l off 2?
+! NA 18, Were all cv nide vrrnpl s receivvci at a pH > 12 and sulfide sem leg received at a pH - 9?
o ,-,,.—NA
19. 'ere all applicable N I-is.7101 y'nnic A. p enol 5, hetiO3_3 (‹ 0,5rnWL) stlfnp[c . free firUN
✓ em,dua.l chlorine?
❑No iN{A
*In ( NO
20. Were client remarkslrtmnosts{i_e, rcqucatcd,Iilntiolts, Marty/SO designations, etc___)
t oCCcc#ly trloRN ri bctl trcrn Qto caC lulu the comment section in L]M s,'
2 I , Was lc maple number listed ors th y cor_lainer lalxl? If � Quote 14
Sample Preservation (Mi.;st be Gymplcted t(rr cry sainple(s) incorrectly preserved or with headspace.)
ISanlpIc(s) N0
were received incorrectly presc;rved and were adjusted accordingly
in z;uunpre receiving with NIA mL ofclrale one: ] I2SSO4 HNO3, HCI, NaOH using SR iu NA
Time of pnescrvsttion N - . Irrnore than one p eteryativc is needed, p[eaae aotC in the comments below,
ItSapi7p" (s) were receiver) with hobbles >6 rim :r. diameter,
tiA-nplcs(s) NINwere received wltl: TRC "} 0.S tneL (If t1.9 is fro) and were
adjusted aoqurd[ng[y rnsirnplcromivirgwith sod[um thic.LJile. (Naz5203)with Shealy ID: to
SR bun labels applied by: JEti,2 Data: L011292021
Comments;
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 16

Sodium Absorption Ratio Calculation (SAR)
Product Code Product Name
Sample Date Report Range Ratio
2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 10/5/2021 1/1/2021 - 12/31/2021 0.9406
Na mg/I = (Na mg/kg x % Solids) = 100 = (1600 x 3.2600) = 100 = 52.16
Ca mg/I = (Ca mg/kg x % Solids) = 100 = (4800 x 3.2600) = 100 = 156.48
Mg mg/I = (mg mg/kg x % Solids) = 100 = (1400 x 3.2600) = 100 = 45.64
Na meq = Na mg/I = Molec.Wgt.Na = 52.16 = 23 = 2.26783
Ca meq = Ca mg/I = Molec.Wgt.Ca = 156.48 = 20 = 7.824
Mg meq = Mg mg/I = Molec.Wgt.Mg = 45.64 = 12 = 3.80333
SAR = Na meq = SqrRoot[0.5 x (Ca meq + Mg meq)] = 2.26783 = SqrRoot[0.5(7.824+3.80333)] = 0.940556

SECTION 3

FACILITY NAME: CHERRYVILLE, ND
LAND OWNER: CALVIN WEHUNT
OPERATOR: CALVIN WEHUNT
CROP 1 NAME: RYE (RY)
RESIDUAL SOURCE(S)', " Sea list at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
WO PERMIT #: W 00000430
ANNUAL DRY TONS APPLIED: 93.71
PREDOMINANT SOIL SERIES: CECIL
CROP 1 MAX, PAN: 116
FIELD#: NC-LT-00107-0-0003-
51TE ft; NC LT 00107
GROP2 NAME:
ACRES UTILIZED; 17.0
ACRES PERMITTED: 17.0
CATION EXCHANGE CAPACITY 4NON-503):
CROP 2 MAX. PAN:
Page: 1
Gallons (G)
Slta
Name of Crop Type
or Cubic Yards (Y)
Cond.
Precip
Volati-
Mineral-
Ammonia
Nitrate
PAN Applied
Receiving Residual
Dale or
or Wet Tons (W)
%
Resld9al
Dry, Wel,
Past 24 Hrs.
Application
Illation
ization
TKN
Nitrogen
and Nitrite
(Ibsfacre)
Application
Month
Amount
UOM
Solids
Dry TorsfAc
Source
Moist
Inches
Method"
Rate
Rote•"
mg14
mg/kg
mgfkg
Crop 1
Crop
Crop2
11115/2021
111,600.00
(0)
3.260
0.092
CHL
DRY
"0-<112"
SUR
0.5
0.30
41,000.00
7,000.00
99,00
24,915
RY
11/1712021
136,400,00
(0)
3.260
1.091
CHL
DRY
"0-<112"
SUR
0.5
0.30
41,000,00
7,800.00
99.00
30.461
RY
Nov-21
248,000.00
(G)
Total
1.983
Annual Ibslacro Applied
AS
000
00
0,003
CU
CR
0.052
0.003
P8 HG
0.066 0.004
MO
NI
SE
ZN
0.019
0.056
0.016
1.150
Total
P
118.069
55.366 0.000
Lima Applied
Date
Lbs&Ac
Cumulative Ibslacra Applied
[Permit PAN Limit (Ibslacre) ��...Mµ 18t Crop
[Federal C.P L.R.(Ibs/sere)"" 36.6 ' 34.9 1,939.0T '' 7 267.9
0.050
0.024
9,013 1.263 0.336 0.022 0.088 I 0 629
"58 1 8.410
CHL = CHERRYVILLE, NC LIQUID
"I certify, ender penalty of law, Iho1 Ih' document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant ?sniff f sub ' ' informalion, including the passibilily of fines and imprisanm"cnl for knowing violations."
7i Jnl"'zZ
SI NATURE OF LAND APPLIER DATE
i 116
15.0 I , ._..'. 375.D
NR - Not Reported or Not Required
Application Method: SUR - Surface, INJ - Injection, SURIN • Incorporation
Volatilization Rale: Surface 0.5, Injeclion/lncorporation 1.0
Printed: 112912022
Mineralization Rates: Compost 0.1, Anaerobically digesled-0.2, Aerobically digested-0.3, Raw Sludge-0.4
.... C.P.L.R. :Cumulative Pollutant Loading Rate
""" See Site pH & Lime Application Records Section of Report
DEM FORM FSF 412/2006)

FACILITY NAME: CHERRYVILLE, NC
LAND OWNER: CALVIN WEHUNT
OPERATOR: CALVIN WEHUNT
CROP i NAME: RYE (HY)
RESIDUAL SOURCE(S(: ` See 116t al bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
WO PERMIT #: W00000430 FIELD/1: NC-LT-00107-0-0004-
ANNUAL DRY TONS APPLIED: 10.01 SITE #: NC LT 00107
PREDOMINANT SOIL SERIES: RION
CROP 1 MAX. PAN: 84
CROP 2 NAME:
ACRES UTILIZED: 10.9
ACRES PERMITTED: 10.9
CATION EXCHANGE CAPACITY (NON-503):
CROP 2 MAX. PAN:
Page: 1
Dale or
Month
Gallons (G)
or Cubic Yards (Y)
or Wet Tans (W)
%
Solids
Dry TonslAc
Residual
Source
Sile
Cord.
Dry, Wet,
moist
Precip
Past 24 His,
Inches
Application
Method'
Volati-
Ilzation
Rate"
Mineral-
izotion
Rate"""
TKN
mgfkg
Ammonia
Nitrogen
mglkg
Nitrate
and Nitrite
mg/kg
PAN Applied
(thsleere}
Name of Crop Type
Receiving Residual
Application
Amount
UOM
Crap 1
Crop 2
Crop 1
Crop 2
11/18/2021
Nov-21
117,800.00
117,800.00
(G)
(G)
3.280
1,468
CHL
DRY
"0-[112'
SUR
0.5
0.30
41,000,00
7,800.00
09.00
41.018
RY
otal 1,469
Annual lbslacre Applied
AS
CD
CU
CR
PB
HG
MO
Ni
SE
Total
41.016 0.000
ZN
0.007
0,002
0.705
0.047
0.041
0,003
0.014
0.041
0.012
P
0,852
[Cumulative Ibsisere Applied
'Permit PAN Limit (les/acre)
�ederal C.P.L.R. {Ibslacre}`"" 33.8 34.8 1 1.339.0 E 267.9 15,4 375.0 69.0
CHL= CHERRYVILLF, NC LIQUID
"I certify, under penalty of law, that this a meat was prepared under my direction or supervision in accordance with a syslem designed to assure that qualified personnel properly gathered and evaluated die information submitted, I am
aware Owl Iliere are significant ponaltielor bmiti se rformation, including the possibility of fines and imprisonment for knowing violations."
SIGNATURE OF LAND APPLIER
0,071
0.015
88.150
3.572 T 0.351
0,280 ' J 0.006
0.064
0.248 _.� 0.076
5.143
84
Lime Applied
Date Lbs/Ao
ilk
1 sl Crop'
DATE
2,500,0
NR = Not Reported or Not Required ".. Mineralization Rates: Compost-0.1, Anaeroblcally dlgested-0.2, Aerobically digested-0,3, Raw Sludge-0.4
Application Method: SUR - Surface, INJ - Infection, SURIN - Incorporation •'•" C.P-L.R.: Cumulative Pollutant Loading Rate
Voiatllizallon Rate: Surface 0.5, Injection/Incorporation 1.0 ""•'" See Site pH & Lime Application Records Section of Report
Printed; 1/20/2022
DENR FORM ESE (1212006)

FACILITY NAME: CHERRYVILLE, NC
LAND OWNER: CALVIN WEHUNT
OPERATOR: CALVIN WEHUNT
CROP 1 NAME: RYE (RY)
RESIDUAL SOURCEIS): I` See Ilst at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
WQ PERMIT #: WO0000430
ANNUAL DRY TONS APPLIED: 10.96
PREDOMINANT SOIL SERIES: CECIL
CROP 1 MAX, PAN: 116
FIELD#: NC-LT-00107-0-0005-
SITE N: NC LT 00107
CROP 2 NAME:
ACRES UTILIZED: 17.8
ACRES PERMITTED: 17.8
CATION EXCHANGE CAPACITY (NON503):
CROP 2 MAX. PAN:
Page: 1
Dale or
Month
Gallons
or Cubic Yards
or Wet Tons
(G)
(Y)
(W)
UOM
%
Solids
Dry Tons&Ac
Residual
Source
Site
Cond.
Dry, Wet,
Moist
Prscip
Pest 24 Hrs.
Inches
Application
Method`
Volatl-
lizatlon
Rate""
Mineral-
Infirm
Rale"'
TKN
mg/kg
Ammonia
Nitrogen
mg/kg
Nitrate
end Nitrite
rnglkg
PAN/Applied
Palouse)
Name of Crop Type
Receiving Residual
Application
Amount
Crop 1
Crop 2
Crop 1
Crop 2
11/18/2021
11/19,2021
Nov-21
18,600.00
52,000,06
60,800.00
(G)
(0)
(G)
3.260
3,260
0.142
0,474
CHL
CHL
DRY
DRY
'0-<112'
"0-e112'
SUR
SUR
0.5
0.5
0.30
0.30
41,000.00
41,000.00
7,800.00
7,890.00
99.00
99,00
3.966
13.219
RY
RY
nnual ibslacre Applied
Total
0.616
AS
0.993
CD
CU
e0.001
0,295
Total
17.185 0.000
CR
PS
HG
MO
0,020
0.017
0.001
0,006
NI SE
0.017 0.005
ZN
Imo Applied
0.357
Date
LbsfAc
Cumulative Ibslacre Applied
0003
c3A01 I 0.295
0.0207— 0.017
0.001
0.006
0.017 I 0.005 0.357
Permit PAN Limit (ibslacre) 1s1 Crop!
116
Federal C.P.L.R. (Ibsfacro)""
36.6 1 34.8 I 1,339,0 I -'.. ,/ 267.915.0
375.0
0
CHL = CHERRYVILLE, NC LIQUID
"I certify, under penally of law, that this donumenl was prepared under my direction or supervision in accordance with a system designed 10 assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penal f fgjrsubmittin f 'nformotion, including the possibility of tines and imprisonment for knowing violations,"
SIGNATURE OF LAND APPLI ER DATE
NR = Not Reported or Not Required "" Mineralization Rates: Compost-0.1, Anaeroblcally digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4
` Application Method: SUR - Surface, INJ - Infection, SURIN - Inoerporatlon '... C.P.L.R.: Cumulative Pollutant Loading Rate
Volatilization Rate: Surface 0.5, Injection/Incorporation 1,0 """ See Site pH & Lime Application Records Section of Report
Printed: 1129/2022
DENR FORM FSF (12/2006)

SECTION 4

it
5uMMI
EkWIRONMENTAL TECHNOLOIaiES, INC
ArralyUcal Laboralorfas
November 09, 2021
Alex Fox
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL:
FAX:
RE: Cherryville- REVISED REPORT
Dear Alex Fox:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
Order No.: 21100540
Summit Environmental Technologies, Inc. received 1 sample(s) on 10/7/2021 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
y77..�t/cRa4--
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas
E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada OH009232020-1, New
Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma
2019-155, Oregon OH200001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah OH009232020-12,
Virginia VELAP 10381, West Virginia 9957C
Page 1 of 35

it
SUMMI T Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNO LOGES, INC. Cuyahoga Falls, Ohio 44223
4rraly0cal Laboralorlas TEL: [phone] FAX. [phone]
Website: http://www.settek.com
Case Narrative
WO#: 21100540
Date: 11/9/2021
CLIENT: Synagro
Project: Cherryville- REVISED REPORT
WorkOrder Narrative:
21100540: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
21100540-OO1A TCLP-VOC-MSTR Possible low bias for Carbon tetrachloride and
Trichloroethene due to low recoveries in CCV. Compounds demonstrate adequate instrument sensitivity
in the DETL. P: RPD between confirmation column is greater than 40%.
Analytical Sequence QC Notes:
LCS-52476 SVOC-BNA TCLP(8270): LCS-52476 exceeded calibration range for surrogate 2,4,6-
Tribromophenol. Detection should be considered an estimated concentration. Recovery was within
acceptance criteria.
CCV VOC-MSTR NPW(8260): CCV exhibits low recoveries for Carbon tetrachloride and
Revision vl
Page 2 of 35

it
SUMMI T Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNO LOGES, INC. Cuyahoga Falls, Ohio 44223
4rraly0cal Laboralorlas TEL: [phone] FAX. [phone]
Website: http://www.settek.com
Case Narrative
WO#: 21100540
Date: 11/9/2021
CLIENT: Synagro
Project: Cherryville- REVISED REPORT
Trichloroethene. Associated results may be biased low. Compounds demonstrate adequate instrument
sensitivity in the DETL.
LCS-52471 TCLP-VOC-MSTR TCLP(8260): Possible low bias for Carbon tetrachloride and
Trichloroethene due to low recoveries in CCV. Compounds demonstrate adequate instrument sensitivity
in the DETL.
MB-52471 TCLP-VOC-MSTR TCLP(8260): Possible low bias for Carbon tetrachloride and
Trichloroethene due to low recoveries in CCV. Compounds demonstrate adequate instrument sensitivity
in the DETL.
LCS SVOC-Herb NPW(8321): LCS-R134819 exhibits high recovery for Dalapon. All associated
samples are not selected to report for this analyte.
21100540-001ams/amsd TCLP-SVOC-CPEST(8081B): P: RPD between confirmation column is
greater than 40%.
LCS-52502 TCLP-SVOC-CPEST(8081B): P: RPD between confirmation column is greater than 40%.
MB-52502 TCLP-SVOC-CPEST(8081B): P: RPD between confirmation column is greater than 40%.
REVISED REPORT 11/9/21: CORRECTED TCLP PESTICIDE REPORTING LIMITS
Revision vl
Page 3 of 35

it
Summit Environmental Technologies, In
3310 Win
EkiwIRON M @Ni'AL TECHN❑ LOGiES, INC Cuyahoga Falls, Ohio 442
4rralytiical Laboralorlas TEL: [phone] FAX. [phone]
Website: http://www.settek.co
Summit
Qualifiers and Acronyms
WO#: 21100540
Date: 11/9/2021
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25% difference.
C The result has been confirmed by GC/MS.
X The result was not confirmed when GC/MS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low (-) or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low (-) or high (+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low (-) or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low (-) or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
QC
MB
LCS
LCSD
QCS
DUP
MS
MSD
RPD
ICV
ICB
CCV
CCB
RLC
DF
Not Detected
Quality Control
Method Blank
Laboratory Control Sample
Laboratory Control Sample Duplicate
Quality Control Sample
Duplicate
Matrix Spike
Matrix Spike Duplicate
Relative Percent Different
Initial Calibration Verification
Initial Calibration Blank
Continuing Calibration Verification
Continuing Calibration Blank
Reporting Limit Check
Dilution Factor
RL
MDL
LOD
LOQ
PQL
CRQL
PL
RegLvl
MCL
MinCL
RA
RE
TIC
RT
CF
RF
Reporting Limit
Method Detection Limit
Level of Detection
Level of Quantitation
Practical Quantitation Limit
Contract Required Quantitation Limit
Permit Limit
Regulatory Limit
Maximum Contamination Limit
Minimum Compound Limit
Reanalysis
Reextraction
Tentatively Identified Compound
Retention Time
Calibration Factor
Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Revision vl
Page 4 of 35

it
SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNQ Wolfs, IFIC, Cuyahoga Falls, Ohio 44223
4rraly0cal Laboralorfas TEL: [phone] FAX [phone]
Website: http://www.settek.com
Workorder
Sample Summary
WO#: 21100540
09-Nov-21
CLIENT: Synagro
Project: Cherryville- REVISED REPORT
Lab SamplelD Client Sample ID
21100540-001 Cherryville
Tag No Date Collected Date Received Matrix
10/5/2021 10:45:00 AM 10/7/2021 10:15:00 AM Sludge
Page 5 of 35

it
SUMMI
EHWIRON M E:N1AL TECHNO LOCIES, INC
Arra ytical Laboraloriag TEL: [phone] FAX. [phone]
Website: http://www.settek.com
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
DATES REPORT
WO#: 21100540
09 Nov 21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
Sample ID
Client Sample ID
Collection Date Matrix
Test Name Leachate Date
Prep Date
Analysis Date
21100540-OO1A Cheiryville
10/5/2021 10:45:00 AM Sludge Ignitability of Solids (SW-846: 1030)
pH (SW9045D)
Reactive Cyanide (9014/7.3.3.2)-Solid
Reactive Sulfide (9034)/7.3.4.2
TCLP Herbicides by EPA 8321B
TCLP Mercury Analysis (SW1311/74710/11/2021 3:00:00 PM
TCLP Metals Analysis (SW1311/6010 10/11/2021 3:00:00 PM
TCLP Pesticides Analysis (SW1311/8(10/11/2021 3:00:00 PM
TCLP Pesticides Analysis (SW1311/8(10/11/2021 3:00:00 PM
TCLP Semi-Volatiles Analysis 10/11/2021 3:00:00 PM
(SW1311/8270)
TCLP Volatiles Analysis
10/12/2021 9:45:00 AM
10/13/2021 9:30:00 AM
10/13/2021 9:55:00 AM
10/13/2021 9:55:00 AM
10/12/2021 8:25:00 AM
10/12/2021 3:17:04 PM
10/14/2021 1:46:39 PM
10/11/2021 2:41:00 PM
10/11/2021 2:41:00 PM
10/13/2021 6:52:00 PM
10/12/2021 4:11:00 PM
10/13/2021 3:11:00 PM
10/15/2021 3:56:00 AM
10/15/2021 3:56:00 AM
10/12/2021 9:36:00 PM
10/11/2021 3:00:00 PM 10/12/2021 6:36:00 PM
Revision vl
Page 6 of 35

il
5uMMI
ENVIRONMENTAL TECHNOLOGIES, ItlC
4rraly0cal Laboralorfas TEL: [phone] FAX.. [phone]
Website: http://wni'.settek.com
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
Analytical Report
(base report)
WO#: 21100540
Date Reported: 11/9/2021
CLIENT:
Matrix:
Lab ID:
Project:
Synagro
SLUDGE
21100540-001A
Cherryville- REVISED REPORT
Client Sample ID Cherryville
Tag Number:
Collection Date: 10/5/2021 10:45:00 AM
Analyses Result
RL Qual Units
DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury
ND 0.00200 mg/L
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As)
TCLP Barium(Ba)
TCLP Cadmium(Cd)
TCLP Chromium(Cr)
TCLP Lead(Pb)
TCLP Selenium(Se)
TCLP Silver(Ag)
ND
ND
ND
ND
ND
ND
ND
0.500
5.00
0.100
0.200
0.500
0.0500
0.500
SW7470A SW7470A Analyst: JEB
1
SW6010
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene
2,4, 5-Trichlorophenol
2,4, 6-Trichl orophenol
2,4-Dinitrotoluene
Cresols, Total
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
Surr: 2-Fluorophenol
Surr: Phenol-d6
Surr: Nitrobenzene-d5
Surr: 2,4,6-Tribromophenol
Surr: 2-Fluorobiphenyl
Surr: p-Terphenyl-d14
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
59.2
65.5
50.0
77.8
51.4
87.7
0.200 mg/L
0.500 mg/L
0.500 mg/L
0.100 mg/L
10.0 mg/L
0.0400 mg/L
0.100 mg/L
0.200 mg/L
0.200 mg/L
0.500 mg/L
0.500 mg/L
10 - 157 %Rec
10 - 169 %Rec
32.1 - 130 %Rec
45.4 - 166 %Rec
35.7 - 130 %Rec
70 - 145 %Rec
10/12/2021 4:11:00 PM
SW3010A Analyst: MSK
10/13/2021 3:11:00 PM
10/13/2021 3:11:00 PM
10/13/2021 3:11:00 PM
10/13/2021 3:11:00 PM
10/13/2021 3:11:00 PM
10/13/2021 3:11:00 PM
10/13/2021 3:11:00 PM
SW3510C Analyst: SFG
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
2 10/12/2021 9:36:00 PM
Qualifiers:
B
H
MC
ND
P
R
Analyte detected in the associated Method Blank
Holding times for preparation or analysis exceeded
Value is below Minimum Compound Limit.
Not Detected
Second column confirmation exceeds
RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
OG1
PL Permit Limit
RL Reporting Detection Limit
Revision vl
Page 7 of 35

il
5uMMI
ENVIRONMENTAL TECHNOLOGIES, ItlC
4rrafy0caf Laboralorfas TEL: [phone] FAX.. [phone]
Website: http://wni'.settek.com
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
Analytical Report
(base report)
WO#: 21100540
Date Reported: 11/9/2021
CLIENT:
Matrix:
Lab ID:
Project:
Synagro
SLUDGE
21100540-001A
Cherryville- REVISED REPORT
Client Sample ID Cherryville
Tag Number:
Collection Date: 10/5/2021 10:45:00 AM
Analyses Result
RL Qual Units
DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081
TCLP PESTICIDES ANALYSIS (SW1311/8081)
Chlordane, total
Toxaphene
Endrin
gamma-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surr: TCMX
Surr: DCB
TCLP HERBICIDES BY EPA 8321 B
2,4-D
2,4,5-TP
Surr: 2,4-Dichlorophenylacetic aci
ND
ND
ND
ND
ND
ND
ND
73.5
106
ND
ND
96.8
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene
1,2-Dichloroethane
MEK
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surr: 4-B rom ofl uorobenzene
Surr: Dibromofluoromethane
Surr: Toluene-d8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
93.4
94.3
101
0.0250
0.0500
0.00500
0.00500
0.00500
0.00500
0.00500
10- 119
10- 119
0.500
0.500
70 - 130
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%Rec
Pm %Rec
mg/L
mg/L
%Rec
0.250 mg/L
0.250 mg/L
5.00 mg/L
0.250 mg/L
0.250 QC- mg/L
2.50 mg/L
0.250 mg/L
0.250 mg/L
0.250 QC- mg/L
0.100 mg/L
70 - 130 %Rec
70 - 130 %Rec
70 - 130 %Rec
S W 8321
SW8260
SW3510C Analyst: CSS
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
10 10/15/2021 3:56:00 AM
Analyst: RIS
50 10/13/2021 6:52:00 PM
50 10/13/2021 6:52:00 PM
50 10/13/2021 6:52:00 PM
SW1311 M Analyst: SLV
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
50 10/12/2021 6:36:00 PM
Qualifiers:
B
H
MC
ND
P
R
Analyte detected in the associated Method Blank
Holding times for preparation or analysis exceeded
Value is below Minimum Compound Limit.
Not Detected
Second column confirmation exceeds
RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
OG1
PL Permit Limit
RL Reporting Detection Limit
Revision vl
Page 8 of 35

il
SUMMI Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNOLOMES, IFtC Cuyahoga Falls, Ohio 44223
4rraly0cai Laboralories TEL: [phone] FAX. [phone]
Website: http://wni'.settek.com
Analytical Report
(base report)
WO#: 21100540
Date Reported: 11/9/2021
CLIENT: Synagro
Matrix: SLUDGE
Lab ID: 21100540-001A
Project: Cherryville- REVISED REPORT
Client Sample ID Cherryville
Tag Number:
Collection Date: 10/5/2021 10:45:00 AM
Analyses
Result RL Qual Units DF Date Analyzed
RCI
SW9014 Analyst: MS
REACTIVE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive ND 0.481 mg/Kg 1 10/11/2021 2:41:00 PM
IGNITABILITY OF SOLIDS (SW-846: 1030) SW1030 Analyst: ALT
Ignitability non-flammable mm/sec 1 10/12/2021 3:17:04 PM
RCI SW9045D Analyst: ALT
PH (SW9045D)
pH 7.2 s.u.@19.0C 1 10/14/2021 1:46:39 PM
RCI SW9034 Analyst: MS
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive 30.0 25.0 mg/Kg 1 10/11/2021 2:41:00 PM
Qualifiers:
B Analyte detected in the associated Method Blank E Value above quantitation range
H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response
MC Value is below Minimum Compound Limit. N Tentatively identified compounds
ND Not Detected OG1
P Second column confirmation exceeds PL Permit Limit Revision v1
R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 9 of 35

it
SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHNOLOGIES, i Cuyahoga Falls, Ohio 44223
4rraly0cal Laboralorlas TEL: [phone] FAX [phone]
Website: http://www.settek.com
Accreditation Program
Analytes Report
WO#: 21100540
09 Nov 21
Client: Synagro State: NW
Project: Cherryville- REVISED REPORT Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte Status
21100540-001 A
Sludge Ignitability of Solids (SW-846: 1030) Ignitability A
Sludge pH (SW9045D) Hydrogen Ion (pH) A
Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U
Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U
Sludge TCLP Herbicides by EPA 8321B 2,4,5-TP A
Sludge TCLP Herbicides by EPA 8321B 2,4-D A
Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A
Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A
Sludge TCLP Metals Analysis (SW1311/6010) Barium A
Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A
Sludge TCLP Metals Analysis (SW1311/6010) Chromium A
Sludge TCLP Metals Analysis (SW1311/6010) Lead A
Sludge TCLP Metals Analysis (SW1311/6010) Selenium A
Sludge TCLP Metals Analysis (SW1311/6010) Silver A
Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A
Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A
Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A
Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A
Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A
Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A
Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A
Key Key
NC WW SCM A Accredited NC WW SCM U Unavailable
Version #3
Page 10 of 35

it
Summit Environmental Technologies, Inc.
3310 Win St.
ENVIRONMENTAL TECHN❑ LOGIES, INC Cuyahoga Falls, Ohio 44223
4rraly0cal Laboralorlas TEL: [phone] FAX [phone]
Website: http://www.settek.com
Accreditation Program
Analytes Report
WO#: 21100540
09 Nov 21
Client: Synagro
Project: Cherryville- REVISED REPORT
State: NW
Program Name: NC_WW_SCM
Sample ID
Matrix
Test Name
Analyte Status
21100540-001 A
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
Sludge TCLP Volatiles Analysis
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
A
A
A
A
A
A
A
A
A
A
Key
NC WW SCM A Accredited
Key
NC WW SCM U Unavailable
Version #3
Page 11 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52471
Sample ID: 21100457-001AMS SampType: MS
Client ID: BatchQC Batch ID: 52471
Analyte
TestCode: TCLP-VOC-M Units: mg/L
TestNo: SW8260 SW1311M
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/12/2021
%REC LowLimit HighLimit RPD Ref Val
RunNo: 134779
Seq No: 3559327
%RPD RPDLimit Qual
1,1-Dichloroethene
1,2-Dichloroethane
MEK
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surr: 4-B rom ofl u oro be nze ne
Surr: Dibromofluoromethane
Surr: Toluene-d8
0.959 0.250 1.00 0 95.9
0.859 0.250 1.00 0 85.9
ND 5.00 5.00 0 92.3
1.03 0.250 1.00 0 103
0.722 0.250 1.00 0 72.2
ND 2.50 1.00 0 97.9
0.935 0.250 1.00 0 93.5
0.864 0.250 1.00 0 86.4
0.810 0.250 1.00 0 81.0
0.906 0.100 1.00 0.0680 83.9
2450 2500 97.8
2390 2500 95.8
2500 2500 100
13.6
55.7
65.3
49.2
26.7
33.7
48.5
19.2
38.4
27.3
91.7
75.5
94.1
202
138
118
145
156
159
145
191
167
161
109
118
105
QC-
QC -
Sample ID: 21100457-001AMSD SampType: MSD
Client ID: BatchQC Batch ID: 52471
Analyte
Result
TestCode: TCLP-VOC-M Units: mg/L
TestNo: SW8260 SW1311M
Prep Date:
Analysis Date: 10/12/2021
PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
RunNo: 134779
Seq No: 3559328
%RPD RPDLimit Qual
1,1-Dichloroethene
1,2-Dichloroethane
MEK
Benzene
1.01
0.887
ND
1.09
0.250
0.250
5.00
0.250
1.00
1.00
5.00
1.00
0
0
0
0
101 13.6 202 0.959 4.93 25
88.7 55.7 138 0.859 3.21 25
92.4 65.3 118 0 0 25
109 49.2 145 1.03 5.48 25
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 12 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52471
Sample ID: 21100457-001AMSD SampType: MSD
Client ID: BatchQC Batch ID: 52471
Analyte
TestCode: TCLP-VOC-M Units: mg/L
TestNo: SW8260 SW1311M
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/12/2021
RunNo: 134779
Seq No: 3559328
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surr: 4-B rom ofl u oro be nze ne
Surr: Dibromofluoromethane
Surr: Toluene-d8
0.750
ND
0.954
0.910
0.848
0.946
2470
2410
2510
0.250
2.50
0.250
0.250
0.250
0.100
1.00
1.00
1.00
1.00
1.00
1.00
2500
2500
2500
0
0
0
0
0
0.0680
75.0
101
95.4
91.0
84.9
87.8
98.9
96.6
100
26.7
33.7
48.5
19.2
38.4
27.3
91.7
75.5
94.1
156
159
145
191
167
161
109
118
105
0.722
0
0.935
0.864
0.810
0.906
3.74
0
2.01
5.13
4.70
4.26
0
0
0
25 QC-
25
25
25
25 QC-
25
25
25
25
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 13 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52471
Sample ID: LCS-52471
Client ID: LCSS
Analyte
SampType: LCS
TestCode: TCLP-VOC-M Units: mg/L
Batch ID: 52471 TestNo: SW8260 SW1311M
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/12/2021
RunNo: 134779
Seq No: 3559324
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene
1,2-Dichloroethane
MEK
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surr: 4-B rom ofl u oro be nze ne
Surr: Dibromofluoromethane
Surr: Toluene-d8
0.989
0.838
ND
1.03
0.734
ND
0.923
0.895
0.806
0.881
2490
2410
2480
0.250
0.250
5.00
0.250
0.250
2.50
0.250
0.250
0.250
0.100
1.00
1.00
5.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2500
2500
2500
0 98.9
0 83.8
0 87.6
0 103
0 73.4
0 98.5
0 92.3
0 89.4
0 80.6
0 88.1
99.6
96.5
99.3
64.7
70
55.1
70
70
70
70
70
62.8
67.1
70
70
70
136
130
149
130
130
130
130
134
160
130
130
130
130
QC-
QC -
Sample ID: MB-52471
Client ID: PBS
Analyte
SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L
Batch ID: 52471 TestNo: SW8260 SW1311M
Result PQL SPK value SPK Ref Val
Prep Date: 10/11/2021
Analysis Date: 10/12/2021
RunNo: 134779
Seq No: 3559326
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene
1,2-Dichloroethane
MEK
Benzene
ND
ND
ND
ND
0.250
0.250
5.00
0.250
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 14 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52471
Sample ID: MB-52471
Client ID: PBS
Analyte
SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L
Batch ID: 52471 TestNo: SW8260 SW1311M
Result PQL SPK value SPK Ref Val
Prep Date: 10/11/2021
Analysis Date: 10/12/2021
RunNo: 134779
Seq No: 3559326
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surr: 4-B rom ofl u oro be nze ne
Surr: Dibromofluoromethane
Surr: Toluene-d8
ND
ND
ND
ND
ND
ND
2340
2340
2520
0.250
2.50
0.250
0.250
0.250
0.100
2500
2500
2500
93.6
93.6
101
70
70
70
130
130
130
QC-
QC -
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 15 of 35

5uMMI
EWWIR6NME 4TALTECHNOLOCKS, I IC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52476
Sample ID: 21100385-004AMS SampType: MS TestCode: SVOC-BNA T Units: mg/L
Client ID: BatchQC Batch ID: 52476
Analyte
Result
TestNo: SW8270 SW3510C
PQL SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/14/2021
RunNo: 134823
Seq No: 3560733
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene
2,4, 5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dinitrotoluene
o-Cresol
Cresols, Total
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
Surr: 2-Fluorophenol
Surr: Phenol-d6
Surr: Nitrobenzene-d5
Surr: 2,4,6-Tribromophenol
Surr: 2-Fluorobiphenyl
Surr: p-Terphenyl-d14
0.239 0.200 0.8000
ND 0.500 0.8000
ND 0.500 0.8000
0.265 0.100 0.8000
ND 0.500 0.8000
ND 10.0 1.600
0.230 0.0400 0.8000
0.259 0.100 0.8000
0.216 0.200 0.8000
0.294 0.200 0.8000
ND 0.500 0.8000
ND 0.500 0.8000
0.842 2.000
0.764 2.000
0.554 2.000
0.804 2.000
0.534 2.000
0.840 2.000
0 29.8
0 39.6
0 40.1
0 33.1
0 34.5
0 33.6
0 28.8
0 32.4
0 27.0
0 36.8
0 43.0
0 10.8
42.1
38.2
27.7
40.2
26.7
42.0
38.3
43.9
37.5
52.1
25.1
10
36.2
57.1
30.4
34
24.1
10
10
10
16.8
32.5
34
60.8
130
157
159
151
143
184
130
139
130
140
171
130
135
161
150
179
133
163
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 16 of 35

5uMMI
EWWIR6NME 4TALTECHNOLOCKS, I IC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52476
Sample ID: 21100385-004AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L
Client ID: BatchQC Batch ID: 52476
Analyte
Result
TestNo: SW8270 SW3510C
PQL SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/14/2021
RunNo: 134823
Seq No: 3560734
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene
2,4, 5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dinitrotoluene
o-Cresol
Cresols, Total
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
Surr: 2-Fluorophenol
Surr: Phenol-d6
Surr: Nitrobenzene-d5
Surr: 2,4,6-Tribromophenol
Surr: 2-Fluorobiphenyl
Surr: p-Terphenyl-d14
0.236 0.200 0.8000
ND 0.500 0.8000
ND 0.500 0.8000
0.266 0.100 0.8000
ND 0.500 0.8000
ND 10.0 1.600
0.207 0.0400 0.8000
0.268 0.100 0.8000
0.209 0.200 0.8000
0.311 0.200 0.8000
ND 0.500 0.8000
ND 0.500 0.8000
0.847 2.000
0.794 2.000
0.568 2.000
0.797 2.000
0.501 2.000
0.846 2.000
0
0
0
0
0
0
0
0
0
0
0
0
29.5
38.3
39.8
33.2
36.0
37.1
25.8
33.5
26.1
38.9
41.0
11.2
42.4
39.7
28.4
39.8
25.1
42.3
38.3
43.9
37.5
52.1
25.1
10
36.2
57.1
30.4
34
24.1
10
10
10
16.8
32.5
34
60.8
130
157
159
151
143
184
130
139
130
140
171
130
135
161
150
179
133
163
0.2388
0
0
0.2648
0
0
0.2304
0.2592
0.2164
0.2944
0
0
1.18
0
0
0.302
0
0
10.8
3.34
3.57
5.55
0
0
0
0
0
0
0
0
30
30
30
30
30
30
30
30
30
30
30
30
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 17 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52476
Sample ID: MB-52476
Client ID: PBS
Analyte
SampType: MBLK TestCode: SVOC-BNA T Units: mg/L
Batch ID: 52476 TestNo: SW8270 SW3510C
Result PQL SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/12/2021
RunNo: 134769
Seq No: 3559069
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene
2,4, 5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dinitrotoluene
o-Cresol
Cresols, Total
Hexachloro-1, 3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
Surr: 2-Fluorophenol
Surr: Phenol-d6
Surr: Nitrobenzene-d5
Surr: 2,4,6-Tribromophenol
Surr: 2-Fluorobiphenyl
Surr: p-Terphenyl-d14
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.89
1.95
1.52
1.93
1.35
1.93
0.100
0.250
0.250
0.0500
0.250
5.00
0.0200
0.0500
0.100
0.100
0.250
0.250
2.000
2.000
2.000
2.000
2.000
2.000
94.4
97.6
75.8
96.5
67.6
96.3
10
10
16.8
32.5
34
60.8
135
161
150
179
133
163
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 18 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52476
Sample ID: LCS-52476
Client ID: LCSS
Analyte
SampType: LCS TestCode: SVOC-BNA T Units: mg/L
Batch ID: 52476 TestNo: SW8270 SW3510C
Result PQL SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/12/2021
RunNo: 134769
Seq No: 3559070
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene
2,4, 5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dinitrotoluene
o-Cresol
Cresols, Total
Hexachloro-1, 3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Pyridine
Surr: 2-Fluorophenol
Surr: Phenol-d6
Surr: Nitrobenzene-d5
Surr: 2,4,6-Tribromophenol
Surr: 2-Fluorobiphenyl
Surr: p-Terphenyl-d14
0.577
0.713
0.708
0.763
0.711
ND
0.584
0.733
0.526
0.661
0.684
ND
1.84
1.86
1.50
2.04
1.29
1.72
0.100 0.8000
0.250 0.8000
0.250 0.8000
0.0500 0.8000
0.250 0.8000
5.00 1.600
0.0200 0.8000
0.0500 0.8000
0.100 0.8000
0.100 0.8000
0.250 0.8000
0.250 0.8000
2.000
2.000
2.000
2.000
2.000
2.000
0 72.2
0 89.2
0 88.6
0 95.4
0 88.9
0 89.8
0 73.0
0 91.6
0 65.7
0 82.6
0 85.5
0 27.4
92.2
93.0
75.2
102
64.7
86.0
46
62.5
57.9
69.4
55.9
57.9
38.3
69.1
36.3
52.1
60.9
10
10
10
16.8
32.5
34
60.8
130
131
136
132
130
111
130
130
130
130
133
130
135
161
150
179
133
163
m
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 19 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52480
Sample ID: MB-52480
Client ID: PBS
Analyte
SampType: MBLK
Batch ID: 52480
TestCode: HG_TCLP(74 Units: PPM
TestNo: SW7470A SW7470A
Result PQL SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/12/2021
RunNo: 134715
Seq No: 3557954
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury
ND
0.00200
Sample ID: LCS-52480
Client ID: LCSS
Analyte
SampType: LCS
Batch ID: 52480
TestCode: HG_TCLP(74 Units: PPM
TestNo: SW7470A SW7470A
Result PQL SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/12/2021
RunNo: 134715
SeqNo: 3557955
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury
0.00359
0.00200
0.00400
0
89.8
80
120
Sample ID: 21100448-006AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM
Client ID: BatchQC Batch ID: 52480
Analyte
Result
TestNo: SW7470A SW7470A
PQL
SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/12/2021
RunNo: 134715
Seq No: 3557970
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury
0.00415
0.00200
0.00400
0
104
75
125
Sample ID: 21100448-006AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM
Client ID: BatchQC Batch ID: 52480
Analyte
Result
TestNo: SW7470A SW7470A
PQL
SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/12/2021
RunNo: 134715
Seq No: 3557971
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury
0.00412
0.00200
0.00400
0
103
75
125
0.00415
0.726
20
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision v1
Page 20 of 35

5uMMI
EWWIR6NME 4TALTECHNOLOCKS, I IC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52480
Sample ID: 21100448-006AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM
Client ID: BatchQC Batch ID: 52480
Analyte
TestNo: SW7470A SW7470A
Result PQL SPK value SPK Ref Val
Prep Date: 10/12/2021
Analysis Date: 10/12/2021
RunNo: 134715
Seq No: 3557971
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 21 of 35

5uMMI
E WIRONMI:NTAL TECHNOL4
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52502
Sample ID: 21100540-001ams
Client ID: Cherryville
Analyte
SampType: MS
TestCode: TCLP-SVOC- Units: mg/L
Batch ID: 52502 TestNo: SW8081 SW3510C
Result PQL SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/15/2021
RunNo: 134943
Seq No: 3565138
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Chlordane, total
Endrin
gamma-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surr: TCMX
Surr: DCB
ND
0.0115
0.00871
0.0106
0.0110
0.0141
14.9
21.1
0.0250
0.00500
0.00500
0.00500
0.00500
0.00500
0.0200
0.0100
0.0100
0.0100
0.0100
0.0100
20.00
20.00
0
0
0
0
0
0
109
115
87.1
106
110
141
74.6
105
70 130
10 224
10 192
10 197
10 208
10 251
10 157
10 194
P
P
P
P
P
P
Pm
Sample ID: 21100540-001amsd SampType: MSD
Client ID: Cherryville Batch ID: 52502
Analyte
TestCode: TCLP-SVOC- Units: mg/L
TestNo: SW8081 SW3510C
Result PQL
SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/15/2021
RunNo: 134943
Seq No: 3565139
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Chlordane, total
Endrin
gamma-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surr: TCMX
Surr: DCB
ND
0.0112
0.00858
0.0107
0.0107
0.0141
14.5
20.5
0.0250
0.00500
0.00500
0.00500
0.00500
0.00500
0.0200
0.0100
0.0100
0.0100
0.0100
0.0100
20.00
20.00
0
0
0
0
0
0
107
112
85.8
107
107
141
72.3
103
70
10
10
10
10
10
10
10
130
224
192
197
208
251
157
194
0
0.0115
0.00871
0.0106
0.0110
0.0141
0
2.32
1.50
0.424
2.12
0.152
0
0
30 P
30 P
30 P
30 P
30 P
30 P
Pm
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 22 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52502
Sample ID: LCS-52502
Client ID: LCSS
Analyte
SampType: LCS
TestCode: TCLP-SVOC- Units: mg/L
Batch ID: 52502 TestNo: SW8081 SW3510C
Result PQL SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/14/2021
RunNo: 134943
Seq No: 3565142
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Chlordane, total
Endrin
gamma-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surr: TCMX
Surr: DCB
0.0184
0.0106
0.00785
0.0103
0.00973
0.0137
12.4
17.5
0.00250
0.000500
0.000500
0.000500
0.000500
0.000500
0.0200
0.0100
0.0100
0.0100
0.0100
0.0100
20.00
20.00
0
0
0
0
0
0
92.2
106
78.5
103
97.3
137
61.9
87.6
70 130
10 130
10 130
10 130
10 130
10 178
10 130
10 130
P
P
P
P
P
P
P
Pm
Sample ID: MB-52502
Client ID: PBS
Analyte
SampType: MBLK
Batch ID: 52502
TestCode: TCLP-SVOC- Units: mg/L
TestNo: SW8081 SW3510C
Result PQL
SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/14/2021
RunNo: 134943
Seq No: 3565143
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Chlordane, total
Toxaphene
Endrin
gamma-BHC
Heptachlor
Heptachlor epoxide
Methoxychlor
Surr: TCMX
Surr: DCB
ND
ND
ND
ND
ND
ND
ND
12.5
17.9
0.00250
0.00500
0.000500
0.000500
0.000500
0.000500
0.000500
20.00 62.4
20.00 89.4
10
10
119
119
P
Pm
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision v1
Page 23 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52502
Sample ID: MB-52502
Client ID: PBS
Analyte
SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L
Batch ID: 52502 TestNo: SW8081 SW3510C
Result PQL SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/14/2021
RunNo: 134943
Seq No: 3565143
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 24 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52513
Sample ID: 21100530-001AMS SampType: MS
TestCode: MTL-TCLP-7( Units: mg/L
Client ID: BatchQC Batch ID: 52513 TestNo: SW6010 SW3010A
Analyte
Result PQL SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/13/2021
RunNo: 134771
Seq No: 3559537
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As)
TCLP Barium(Ba)
TCLP Cadmium(Cd)
TCLP Chromium(Cr)
TCLP Lead(Pb)
TCLP Selenium(Se)
TCLP Silver(Ag)
1.91 0.500 2.000 0.01320 94.7
ND 5.00 2.000 0.1339 104
1.96 0.100 2.000 0 98.1
2.11 0.200 2.000 0.1309 99.1
1.97 0.500 2.000 0.01070 98.1
2.13 0.0500 2.000 0.02200 105
2.28 0.500 2.000 0.002340 114
70 130
70 130
70 130
70 130
70 130
70 130
70 130
Sample ID: 21100530-001AMSD SampType: MSD TestCode: MTL-TCLP-7( Units: mg/L
Client ID: BatchQC Batch ID: 52513
Analyte
TestNo: SW6010 SW3010A
Result PQL
SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/13/2021
RunNo: 134771
Seq No: 3559538
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As)
TCLP Barium(Ba)
TCLP Cadmium(Cd)
TCLP Chromium(Cr)
TCLP Lead(Pb)
TCLP Selenium(Se)
TCLP Silver(Ag)
1.89 0.500 2.000 0.01320 94.0
ND 5.00 2.000 0.1339 104
1.92 0.100 2.000 0 96.2
2.08 0.200 2.000 0.1309 97.4
1.94 0.500 2.000 0.01070 96.3
2.11 0.0500 2.000 0.02200 105
2.25 0.500 2.000 0.002340 112
70
70
70
70
70
70
70
130
130
130
130
130
130
130
1.908
0
1.962
2.112
1.973
2.125
2.281
0.731
0
1.88
1.59
1.81
0.519
1.47
20
20
20
20
20
20
20
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 25 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, IhNC
4rlafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: 52513
Sample ID: MB-52513
Client ID: PBS
Analyte
SampType: MBLK TestCode: MtI-TCLP-7(6 Units: mg/L
Batch ID: 52513 TestNo: SW6010 SW3010A
Result PQL SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/13/2021
RunNo: 134771
Seq No: 3559517
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As)
TCLP Barium(Ba)
TCLP Cadmium(Cd)
TCLP Chromium(Cr)
TCLP Lead(Pb)
TCLP Selenium(Se)
TCLP Silver(Ag)
ND
ND
ND
ND
ND
ND
ND
0.500
5.00
0.100
0.200
0.500
0.0500
0.500
Sample ID: LCS-52513
Client ID: LCSS
Analyte
SampType: LCS
Batch ID: 52513
Result
TestCode: MtI-TCLP-7(6 Units: mg/L
TestNo: SW6010 SW3010A
PQL
SPK value SPK Ref Val
Prep Date: 10/13/2021
Analysis Date: 10/13/2021
RunNo: 134771
Seq No: 3559518
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As)
TCLP Barium(Ba)
TCLP Cadmium(Cd)
TCLP Chromium(Cr)
TCLP Lead(Pb)
TCLP Selenium(Se)
TCLP Silver(Ag)
1.92
ND
2.14
2.16
2.09
2.04
2.29
0.500
5.00
0.100
0.200
0.500
0.0500
0.500
2.000
2.000
2.000
2.000
2.000
2.000
2.000
0 95.8
0 110
0 107
0 108
0 105
0 102
0 114
80 120
80 120
80 120
80 120
80 120
80 120
80 120
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 26 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, IhNC
4riafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: R134656
Sample ID: 21100267-015AMS SampType: MS
Client ID: BatchQC Batch ID: R134656
Analyte
TestCode: Sulfide,React Units: mg/Kg
TestNo: SW9034
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134656
Seq No: 3556196
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sulfide, Reactive
3270
25.0
3560
0
91.9
80
120
W
Sample ID: 21100267-015AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg
Client ID: BatchQC Batch ID: R134656
Analyte
TestNo: SW9034
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134656
Seq No: 3556197
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sulfide, Reactive
3390
25.0
3560
0
95.2
80
120
3270
3.60
30 W
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 27 of 35

5uMMI
ENVIRONMENTAL TECHNOLOCKS, INC
4riafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Proj ect:
Synagro
Cherryville- REVISED REPORT
BatchlD: R134656
Sample ID: MB-R134656
Client ID: PBW
Analyte
SampType: MBLK
Batch ID: R134656
TestCode: Sulfide,React Units: mg/L
TestNo: SW9034
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134656
Seq No: 3556184
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sulfide, Reactive
ND
25.0
Sample ID: LCS-R134656
Client ID: LCSW
Analyte
SampType: LCS
Batch ID: R134656
TestCode: Sulfide,React Units: mg/L
TestNo: SW9034
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134656
Seq No: 3556185
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Sulfide, Reactive
3370
25.0
3560
0
94.7
85
115
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 28 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: R134670
Sample ID: 21100267-015AMS SampType: MS
Client ID: BatchQC Batch ID: R134670
Analyte
TestCode: Cyanide,Rea Units: mg/Kg
TestNo: SW9014
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134670
Seq No: 3557140
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cyanide, Reactive
9.48
0.495
10.00
0
94.8
75
125
Sample ID: 21100267-015AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg
Client ID: BatchQC Batch ID: R134670
Analyte
TestNo: SW9014
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134670
Seq No: 3557141
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cyanide, Reactive
9.81
0.500
10.00
0
98.1
75
125
9.479
3.40
10
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 29 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: R134670
Sample ID: MB
Client ID: PBW
Analyte
SampType: MBLK
Batch ID: R134670
TestCode: Cyanide,Rea Units: mg/L
TestNo: SW9014
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134670
Seq No: 3556458
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cyanide, Reactive
ND
0.490
Sample ID: LCS
Client ID: LCSW
Analyte
SampType: LCS
Batch ID: R134670
TestCode: Cyanide,Rea Units: mg/L
TestNo: SW9014
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134670
SeqNo: 3556459
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cyanide, Reactive
10.6
0.495
10.00
0
106
85
115
Sample ID: RLCheck
Client ID: BatchQC
Analyte
SampType: RLC
Batch ID: R134670
Result
TestCode: Cyanide,Rea Units: mg/L
TestNo: SW9014
PQL
SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/11/2021
RunNo: 134670
Seq No: 3556461
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Cyanide, Reactive
ND
0.495
0.5000
0
0
50
150
Qualifiers: B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 30 of 35

5uMMI
ENVIRONMENTAL TECHNOLOCKS, INC
4riafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: R134711
Sample ID: LCS-R134711 SampType: LCS
Client ID: LCSS
Analyte
TestCode: Ignitability_S Units: mm/sec
Batch ID: R134711 TestNo: SW1030
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/12/2021
RunNo: 134711
Seq No: 3557455
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability
7.19
7.240
0
99.3
70
130
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 31 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, IhNC
4riafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: R134828
Sample ID: 21100540-001ADUP SampType: DUP
Client ID: Cherryville Batch ID: R134828
Analyte
TestCode: pH_S(9045D) Units: s.u.@19.3C
TestNo: SW9045D
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/14/2021
RunNo: 134828
Seq No: 3560897
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
pH
7.2
0
0
0
0
7.2
0.1
10
Sample ID: LCS-R134828
Client ID: LCSS
Analyte
SampType: LCS
Batch ID: R134828
TestCode: pH_S(9045D) Units: s.u.@21.7C
TestNo: SW9045D
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/14/2021
RunNo: 134828
Seq No: 3560900
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
pH
7.0
7.0
0
101
90
110
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 32 of 35

5uMMI
EWWIR6NMENTALTECHNOLOCKS, S, IIC
4rrafy 0caI Laboratories
Summit Environmental Technologies, Inc.
3310Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX. [phone]
Website: http://www.settek.com
QC SUMMARY REPORT
WO#: 21100540
09-Nov-21
Client:
Project:
Synagro
Cherryville- REVISED REPORT
BatchlD: R134828
Sample ID: LCS-R134828 SampType: LCS
Client ID: LCSW
Analyte
TestCode: pH_NPW(450 Units: s.u.@21.5C
Batch ID: R134828 TestNo: SW9045D
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/14/2021
RunNo: 134828
Seq No: 3560879
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
pH
7.0
7.0
0
100
98.6
101.4
Sample ID: 21100544-001ADUP SampType: DUP
Client ID: BatchQC Batch ID: R134828
Analyte
TestCode: pH_NPW(450 Units: s.u.@20.2C
TestNo: SW9045D
Result PQL SPK value SPK Ref Val
Prep Date:
Analysis Date: 10/14/2021
RunNo: 134828
Seq No: 3560881
%REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
pH
7.7
7.7
0.4
5 H
Qualifiers:
B
ND
PL
Analyte detected in the associated Method Blank
Analyte detected below quantitation limits
Not Detected
Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
OG1
R RPD outside accepted recovery limits
H
MC
P
RL
Holding times for preparation or anal}
Value is below Minimum Compound
Second column confirmation exceeds
Reporting Detection Limit
Revision vl
Page 33 of 35

5£ 40 17£ abed
DC-ACOC331L Rev. 42
al l IT
lMVtj4pat p#laiT'AL TI MM 1OLOGtl LS INC
3310 Win Ssrn+,
[ar pelh, Ohl* .114221
dGly-AT eed49
i
CI.i. l Name
Syrragr i
Client Sarr, Addrtae
284 Boger Rd
MocksvIlle„ NC 27026
'city Starr Zip
CUM., Phao-e---
336-7034681
Cd"n❑ P.+saa
Alex Fex
rfai SSI Or-LP:and
Repnrr Ta
Alex Fox
Analysis Request 1 Cb. 1 of Custody
Rcihr TO Terms and Conditions : w+r+,rsetlek.cosl
(Nene Manlier
C4ipit Bevan Addnaa
elox[r syrtagr'o.aom
Simper@a3' aninl,vame yrnd lierSitr, r4
rrt.r: Akx Fox
Alex Fax
For Day Celt. rewllr so b. r. arced rn scat. by
mla
:lahic. a..pplY �Y 4
lY Semple Palnt m
ID
F
rr� li
o$/
I
Zip 1 �, q S
ID GA g
A3 - i
."1 l'' ' : I ! . 72c ac 4
E3 g
L w�
i IL x 0
_ii' r1111111111
igIUIII:I1.
111.1.1111.1.1111111.111111.1.11111 111
Dote 1.11111:1111..11.
NDten 1 Comments:
1SET
WO
NO_:
ELi6utfve Dale' 1'it L12D'a
Page I of I
Fae $umrndi Enrbamearal Test!. es, [°ic, tut Daly
Analytical Parameters and Methods Requested
r 1
l OnoredlhlLnn Rrnid YSrneals:
❑Dpin EPA Ph. Cu
Drinking Wncer Campininee
❑ d,htr Compliance ctjrt Sinic)'PrpgrtmI
Ohio IAP
Sm®pk Lie:atii rtinn
Relinquished try:
Alex Fox
DAIS
COI leeled
Three
CiICesehil
b�. I0•-IC
Time
IM:=APIA1,1
NMI
��,,��rr Sum.;. by: Date OI
Y�AgintilMEMEINLIPA
E
ti
CI
Da �l
Rush Donn
Wet be appr:.... by Lab hlarager
SL.';':'lebt volume provided to sun QC
CS
Special Compkin
Coh 9+ YES L N
Dno DM.ELTED
Page 1 of 1

it
SUMMI T Summit Environmental Technologies, Inc.
3310 Win St.
Ek1VI#tONMENTALTECHNOLOGIES, IF# Cuyahoga Falls, Ohio 44223
Arrafytical Laboralarios TEL: [phone] FAX. [phone]
Website: http://www.settek.com
Sample Log -In Check List
Client Name: SYN-NC-27028
Work Order Number: 21100540
RcptNo: 1
4,104,
Logged by: Jacqueline Rasile 10/7/2021 10:15:00 AM
Completed By: Jacqueline Rasile 10/8/2021 1:43:46 PM
Reviewed By: Jennifer Woolf 10/8/2021 3:18:43 PM
rrr,.va,.11-
Chain of Custody
1. Is Chain of Custody complete?
2. How was the sample delivered?
Lop In
3. Coolers are present?
Yes ❑d
FedEx
Yes ❑d
4. Shipping container/cooler in good condition? Yes d❑
Custody seals intact on shipping container/cooler? Yes ❑
No. Seal Date: Signed By:
5. Was an attempt made to cool the samples? Yes ❑d
6. Were all samples received at a temperature of >0° C to 6.0°C
No ❑ Not Present ❑
No ❑ NA ❑
No ❑
No ❑
No ❑
Yes ❑d No ❑
7. Sample(s) in proper container(s)? Yes ❑d No ❑
8. Sufficient sample volume for indicated test(s)? Yes ❑d No ❑
g. Are samples (except VOA and ONG) properly preserved? Yes ❑d No ❑
10. Was preservative added to bottles? Yes ❑ No ❑d
Not Present V
NA ❑
NA ❑
NA ❑
11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials V
12. Were any sample containers received broken? Yes ❑ No ❑d
13. Does paperwork match bottle labels? Yes ❑d No ❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody? Yes ❑d No
15. Is it clear what analyses were requested? Yes ❑d No
16. Were all holding times able to be met?
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order?
Yes ❑d No
Yes ❑
No ❑
NA V
Person Notified:
By Whom:
Regarding:
Client Instructions:
Date:
Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
18. Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
Seal Intact
Seal No
Seal Date
Signed By
1
5.7
Good
Not Present
Page 35 of 35

SECTION 5

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Cherryville WQ Permit Number: WQ0000430
WWTP Name: City of Cherryville WWTP NPDES Number: NC0044440
Monitoring Period: From Jan 1, 2021 To Dec 31, 2021
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt, 1/A (time/temp) Alt. 2B (Alk Treatment)
Alt. 4/D (No Prior Test)
Alt. 3/C (Prior Testing)
Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment
Beta Ray � Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class 11 only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
Alt. 5/Process to Further Reduce Pathogens
If anplicable to alternative performed (Gass A or Clas B) [•
Thermophilic
Parameter
Allowable Level in Sludge
s comp cte t to Following monitoring
Pathogen Density
Minimum Geo. Mean Maximum Units
uata:
No. of
Excee-
dances
Frequency
of
Analysis
Sample
Type
Analytical
Technique
Fecal
Coliform
2x10 to the 6e1
power per gram
of total solids
MPN
CFU
15233
21 770
34237
MPN/g
0
Annual
Grab
SM922I C
E-2006
CFU/g
1000 MPN per gram of
total solids (dry weight)
MPN/g
Salmonella
bacteria (in
lieu of fecal
coliform)
3 MPN per 4 grams total
solids (dry weight)
Vector Attraction Reduction
Option/Alt. 1
(VS reduction)
Option/Alt. 5
(14-Day Aerobic)
Option/Alt. 9
(Injection)
(40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed:
0ption/Alt. 2
(40-day bench)
Option/Alt. 6
(Alk Stabilization)
Option/Alt, 10
(Incorporation)
Option/Alt. 3 Option/Alt. 4
(30-day bench) X (Spec, 02 uptake)
Option/Alt. 7
(Drying — Stable)
Option/Alt. 8
(Drying — Unstable)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement m 40 CFR 503.33/15A NCAC 02T,1107 have been met."
"I certify, under penalty oflaw, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
been met. 1 am aware that there are significant penalties for false certification including fine and imprisonment,"
Larry Wright, Plant ORC & Plant Superintendent
P parer Name an e o print)
Signature
f Prepar
2 -9.262 .
Land Applier Name and Title (if applicable) (type or print)
Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

PaceAnalytical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Alex Fox
Project Name: Cherryville
Lot Number:WJ05059
Date Completed:10/19/2021
10/21/2021 11:11 AM
Approved and released by:
Project Manager II: Lucas Odom
A413
ANSI Wong Board
ACCREDITED
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel: [phone] Fax: [phone] www.pacelabs.com
Page 1 of 16

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653
NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: WJ05059
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low percent solids, the initial sample amount used for the following sample was deviated 3X
greater from the standard procedure: WJ05059-001. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
The method blank for prep batch 18139 contained total phosphorus greater than the method acceptance
criteria. The associated sample contained detections for this analyte at concentrations greater than 10X
the value found in the method blank; therefore sample results are not impacted. The data has been
reported.
Pace Analytical Services, LLC (formerly ShealyEnvironmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 16

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Synagro
Lot Number: WJ05059
Sample Number Sample ID
Matrix Date Sampled Date Received
001 Cherryville Solid 10/05/2021 1020 10/05/2021
002 C 1 Solid 10/05/2021 1020 10/05/2021
003 C 2 Solid 10/05/2021 1020 10/05/2021
004 C 3 Solid 10/05/2021 1020 10/05/2021
005 C 4 Solid 10/05/2021 1020 10/05/2021
006 C 5 Solid 10/05/2021 1020 10/05/2021
007 C 6 Solid 10/05/2021 1020 10/05/2021
008 C 7 Solid 10/05/2021 1020 10/05/2021
(8 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 16

Inorganic non-metals
Client: Synagro
Description: Cherryville
Date Sampled:10/05/2021 1020
Date Received:10/05/2021
Laboratory ID: WJ05059-001
Matrix: Solid
% Solids: 3.26 10/05/2021 2221
Run Prep Method
1 350.1
1
1
1
1
1 351.4
Analytical Method
(Ammonia - N) 350.1
(Nitrate - N ) 9056A
(Nitrite - N ) 9056A
(Phosphorus) 365.1
(Soil pH meas) 9045D
(TKN) 351.2
Dilution
10
10
10
25
1
2
Analysis Date Analyst
10/07/2021 1949 DAK
10/13/2021 1320 AMR
10/13/2021 1320 AMR
10/11/20211527 DMA
10/10/20211702 NBW
10/07/2021 1626 DMA
Prep Date Batch
18067
18772
18775
10/08/2021 1101 18139
18286
10/07/2021 0928 17903
Parameter
CAS Analytical
Number Method
Result Q LOQ
DL
Units Run
Ammonia - N (gas diffusion)
Nitrate - N (soluble)
Nitrite - N (soluble)
Phosphorus
Soil pH measured in water @ 18.4 ° C
TKN
7723-14-0
350.1 7800 310 160
9056A 99 J 150 31
9056A ND 61 31
365.1 30000 B 3800 770
9045D 7.2
351.2 41000 3100 1500
mg/kg 1
mg/kg 1
mg/kg 1
mg/kg 1
su 1
mg/kg 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40%
W = Reported on wet weight basis
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 16

CVAA
Client: Synagro Laboratory ID: WJ05059-001
Description: Cherryville Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 3.26 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1 7471B
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
7471B 1 10/13/2021 1411 CMS2 10/12/2021 1313 17959
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Mercury
7439-97-6
7471B 1.1 J 2.2 0.53 mg/kg 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5of16

ICP-AES
Client: Synagro Laboratory ID: WJ05059-001
Description: Cherryville Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 3.26 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method
1 3050B
Analytical Method Dilution Analysis Date Analyst Prep Date Batch
6010D 1 10/07/20211421 JMH 10/07/2021 0320 17835
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7429-90-5 6010D 15000 200 74 mg/kg 1
7440-38-2 6010D ND 7.4 2.5 mg/kg 1
7440-43-9 6010D 0.69 J 2.5 0.62 mg/kg 1
7440-70-2 6010D 4800 2500 310 mg/kg 1
7440-47-3 6010D 16 4.9 1.2 mg/kg 1
7440-50-8 6010D 240 4.9 2.2 mg/kg 1
7439-89-6 6010D 10000 49 22 mg/kg 1
7439-92-1 6010D 14 4.9 2.2 mg/kg 1
7439-95-4 6010D 1400 J 2500 310 mg/kg 1
7439-96-5 6010D 230 7.4 2.9 mg/kg 1
7439-98-7 6010D ND 20 4.9 mg/kg 1
7440-02-0 6010D 14 J 20 5.2 mg/kg 1
7440-09-7 6010D 1800 J 2500 310 mg/kg 1
7782-49-2 6010D ND 9.9 4.0 mg/kg 1
7440-23-5 6010D 1600 J 2500 310 mg/kg 1
7440-66-6 6010D 290 25 6.2 mg/kg 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 16

Inorganic non-metals
Client: Synagro Laboratory ID: WJ05059-002
Description: C 1 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 5.84 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 34237 * 20
col/g 1
Footnote(s): *Fecal Coliform (MF) - results estimated
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank
N = Recovery is out of criteria
W = Reported on wet weight basis
E = Quantitation of compound exceeded the calibration range DL = Detection Limit
P = The RPD between two GC columns exceeds 40%
J = Estimated result < LOQ and > DL
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 16

Inorganic non-metals
Client: Synagro Laboratory ID: WJ05059-003
Description: C 2 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 4.32 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <23167 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 16

Inorganic non-metals
Client: Synagro Laboratory ID: WJ05059-004
Description: C 3 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 5.15 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <19420 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 16

Inorganic non-metals
Client: Synagro Laboratory ID: WJ05059-005
Description: C 4 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 6.04 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <16552 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 16

Inorganic non-metals
Client: Synagro Laboratory ID: WJ05059-006
Description: C 5 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 4.94 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <20254 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 16

Inorganic non-metals
Client: Synagro Laboratory ID: WJ05059-007
Description: C 6 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 3.39 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <29458 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 16

Inorganic non-metals
Client: Synagro Laboratory ID: WJ05059-008
Description: C 7 Matrix: Solid
Date Sampled:10/05/2021 1020 % Solids: 6.56 10/05/2021 2221
Date Received:10/05/2021
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Fecal Colifo) SM 9222 D-2006 1 10/07/2021 0001 NBW 10/05/2021 2301
Parameter
CAS Analytical
Number Method Result Q LOQ DL Units Run
Fecal Coliform-MF
SM 9222 D-2006 <15233 20
col/g 1
LOQ = Limit of Quantitation
ND = Not detected at or above the DL
H = Out of holding time
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
W = Reported on wet weight basis
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 16

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 16

gi Jo gI aRed
o
cv
01 0
=
.=
4.0
-0
0
z
(7,3'
cD (f)
0
5"
o
E
cc,
3
cr. `.<
15 (A
o
N.)
rn
<
rs.)
0
0 0
4., a
4.0 (,)
4ka z
5.
o
<1)
0
-n 5
3)2
0)
<ID
woo.sqepoed.mNuA
at49Araryticao-
&elm A
C3a1lifimathre
PIT aVnwro
2B4 Bum R.
VICO:SA.31r,
CHAIN-017--[;1JSTODY AnaiyticE] gerwilM, Document
Jr 571;A:7:: GudL7rI 1-"AL .1([11 . :ekoart liakl; FT1LI 1.....uniiv:rd ['Tana,.
Ztt2i3r St-atm,
nguanki1 '112:110:41TM&M iferfi!en
id it- 4
Can "im
ErIV!
Rhone! .541 C
tr
FLroto-...railf F.15,;
''•tt-•LL
bun: oreter
rxElany. EynnAro
Al/rem-
gOjti i, ralccvsylilc.NIU...W.2.e
Fr.jr-t Taw CAer way..
F
be.Wick! r..111.1krriana,
SAMPLE ID
)
S....fliar4P,IdE,TEIEU107_11E
r
u
3L
CAT_LECT.ED
DATE TlidE
444
PI:pe
Rwm.rm
Per .7:apt
Ilarbirt
7LiE
44.
P. F rah V,
PrascivdtiC5.
g 13
z
4.....------1-0":1•Vtitsciou ceeflum 7- 4.7 -t .09.g'7.5:L.V,P...1
_ .k_ io-r—P 11:5"g
444Y.--1.411''4Vt%g-2--. if =147^ if tf
NPDES Glta:KrYNATER
7' usr r FcR4-4
t6ibli.vv403-.1
r-.DFINK
r 7.7 HFP
4.P
F
(1 .1
-E
MUM
WJ0509
4am3Ert%1,L, ..••• • • •
X
X X
srArAe,17*!4:0t
UNAFLE Cunt -Huila
,V47-Nj ira
•F`RINT P•rrir t.07"-S
M.71%T.F113 SAMPLErt I 17.474 %.E.I.41 to .45.I
ILWECD.Trlig
4-41
011 IS101Aa1S 1V011A7VNV A0Vd

PACE ANALYTICAL SERVICES, LLC
CJi rkT $Ynaga
I141:r,nS 4f reCoipf;
5.1rnples Reeerpt Cheddirit (sRici M:
rOcIL c-1s) Revised.:
IssuLla Author:14; Race ENY - UlaCCL Page 1 of 1
Simple Receipt Checklist (SRC')
Cooler Ins.eH
cted byIdtre: JRG2 • . .:5,2o2r
Puce •Client UPS • fedr,x • °titer
Yes El No 1. Were custody riL i s present on the cooled -
Y
Yea Nn PPM 2, If custodtv.seai }+ere resent, were they iitl i t and rrtltrc.krn?
H Stri II+: �+•; M.k
R P C=t[4rine Strip 117� Tested by:TM" --
Original ternpyruturc upon receipt / DelFre j (Corrected) temperature upon receipt %S�FIid Sri -Cup ID.,
13. I s,+ NA 1 NA cc NA ++NAB c UA Yp o
Method: ETErripefaturc Blank EEainst Bottles IR Gun 117: '' JR Gun Correction Fraetor:
Mellrod oi'c olcnt: El. wet Ice 111 Jce Pack; ❑ 1D❑ None
71Yes El No DNA3_ IftemperuIIire ofany cjcI:rExceeded 6.0cC,was Project Manager `antiflee
�k.
No
I7YesLI No
7 'f_� No
rierY
❑ Nei
EJ� Yc No
I❑YL JNO
Tvex QN
Yet 7No
❑✓ 'Yes
li
❑ No
d
Yes
▪ N
dYes
Ys r
El Yes
—Yes
Yea u 1 0
Pik was Netilled Uy_ p}tonc / entail / face -to -fact (circle one)_
1*r.A' 4. ]s th.2 col:tmerl:iai eau_ Jews puc:Ccing s [i p or:ached to this teat?
DC
I5. Wire roper r_„st,dy procedures (relittgr s]tcd'reoeived) fol[owed7
6. Were sample IDe Iistad on the CDC?
Were stampie MDs lick 1 on a31 s mp:e containers?
$. Was collection date & tirne listed an the COC]
9_ Was col/notion date &. tii'Lc listed an al l sourp le eontaincrs7
IR Did all container ]abet information OD, date, tine) agree will' the f OC?
1 i_ Were texts to lie performed listed on the COG?
[2_ Did al: sample arrive iaa he pipercorm iaersfur each test andlorin gccxlcondition
(Unbroken. ]ids an, et .)?
I. Was aclequire sample volume available?
I+I. Were all strop.ie.3 received will !: the holding titne or 43 hours, whichever conies first?
15. Were any samples cr,utainResiuissinglcxcess (circle one) samples Not listed on COC7
[I' Nol VI NA ] fr. per VOA and RSX...175 samples, were Nibbles present ›"reaa-sizei° (' Yor 6:nm in diameter)
ui 2'ly 1.21 the VOA vials'?
i� No ',DNA I.!. Were all DRC ftnetalsinucri Ent samples feet i v d akr a pI.] off 2? .
+! NA 18, Were all cyanide v'rnples received at a pH > 12 and sulfide sent les received at a pH - 9?
3c �NA ]9. 'ere all applicable NII3.11(Nicynnic wp enol 5, ]f?i63_3 (‹ 0,5mWL) stlrip[cs free n
UP
rciidua.l chlorine?
No iNA
1•12! ( NO
20. Were client rcmarkxlrtquosts{J_e, rcqucatcdalilntioiu, MSfi4481)designations, etc___)
toCCcc#ly ttlptlyr i bed trcrn (he caC lulu the comment section in 1.,1M '?
2 I, Was l 1 mu ate number listed on th y eor_tairter l&lxl? If � Quote 41
Sample Preservation (Mi.;st be Grmplcted for ary sample(s) incorrectly preserved or with headspace.)
rSaa1lpIc(s)
were' ecr=ivad inc .rrectlly preserved and were adjusted accordingly
is riuiiip ? receiving with NIA mL ot•clrale one: ] I2SS04, HNO3, HCI, NaOH using SR 'a N
Time of presct-wittion N _ . Irmore than one preterraativc is needed, pieaae aotc. in the comments below,
ItSatiip (s) were received with bubbles >6 rt±ri :r. diameter.
'iA-nplcs(s) N — were received wit!: TCtC: "} 0.5 rtieL (If t1.9 is fro) and were
adjusted aneording[y in simple remivirg with 5ix11Lin this. LJi'rlr (Naz5203) with Shealy ID: NA
SR bare ode labels applied by: JRG2
Cvtnmenrs;
•
])ate LOM92.121
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 16

Analytical Results
Synagro
284 Boger Rd.
Mocksville, NC 27028
Receive Date: 10/05/2021
Reported: 11 / 12/2021
For: Cherryville
Comments:
Sample Number Parameter Sample ID Result
it
STATESVILLE
16, ANALYTICAL
Unit Method Analyzed Analyst
211005-64-01
30 Day Benchscale Cherryville 11.8
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
EPA625-R-92/0
10/05/2021 MD
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 5

Condition of Receipt
Sample Number 211005-64-01 Temp on Arrival: 3.0
Parameter Schedule:
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 5

Client: .ilr��
STAT ES V I L L E
ANALYTICAL
122 Court Street • P.O. Ilex 228
Statesville, NC 28687
(70418724697
Chain of
Custody Record
Address:
Contact Person:
Phone #
�� %�I
FAX#
f -
PO k
Requisitioned by:
(Time Dale)
Customer
Sam le IDN
Lab -ID IIParameter,requestedrtK
Time Sampled
(Grab Only)
Dale Sampled
(Grab Only)
Maki*
analysisp
shnq�
W
wa
Relinquished by:
Time 2.1a
am, pm Date 0/ 1-02
am. pm Date IC/ 5/
am, pm Date /
am, pm Date I/__
( Sampled by: it.x. r
Received by:
NCI Time ! (13Q
2f
Transported by: 1
Relinquished by:
Time
Time
Holding times met:
Received by:
Compliance work: i
Non-compliance work:
Composite Sampling #1:
Time begin am,
pm Date ��—
pm Date —J_J_
#21
Time end
am,
Lab Comments:
Samples Transported On Ice:
Initials:
Composite Sampling
Time begin am,
pm Date _/_/_
pm Date _/_/_
Time end
am,
PO Box 228 • Statesville, NC 28687 • 704/872/4697

STATESVILLE
ANALYTICAL
Analytical Results
Synagro
284 Boger Rd.
Mocksville, NC 27028
Entered: 10/5/21
Reported: 11/12/21
Sample ID: 211005-64-01
For: CHERRYVILLE
PARAMETER: Vector Attraction Reduction/Aerobically Digested Sludge (30day)
Total Solids
Volatile Solids % Volatile Solids
Week 1
Week 2
Week 3
Week 4
Week 5
Week 6
0.64 0.34 0.5313
0.70 0.37 0.5286
0.67 0.34 0.5075
0.65 0.34 0.5231
0.64 0.33 0.5156
0.60 0.30 0.5000
Volatile Solids Reduction: 0.5313 - 0.5000 X 100 = 11.8
0.5313 - (0.5313 x 0.5000)
Respectfully submitted,
Melissa Myers
Statesville Analytical, Inc.
NC WW Cert.# 440NC
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 4 of 5

30 Day Bench Worksheet
Sample ID # 211005-64-01
WEEK 1
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
0.62
0.33
2
0.66
0.34
3
0.64
0.34
Average:
0.64
0.34
0.5313
WEEK 2
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
0.67
0.36
2
0.70
0.37
3
0.72
0.39
Average:
0.70
0.37
0.5286
WEEK 3
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
0.67
0.34
2
0.66
0.34
3
0.67
0.35
Average:
0.67
0.34
0.5075
WEEK 4
Samples
Total Solids
Volatile Solids
%• Volatile Fraction
1
0.68
0.35
2
0.63
0.33
3
0.63
0.33
Average:
0.65
0.34
0.5231
WEEK 5
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
0.65
0.33
2
0.66
0.34
3
0.62
0.31
Average:
0.64
0.33
0.5156
WEEK 6
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
0.58
0.29
2
0.61
0.30
3
0.62
0.32
Average:
0.60
0.30
0.5000
Van Kleeck Reduction: 0.5313 - 0.5000 X 100 = %
0.5313 - (0.5313 X 0.5000)
Final Result: 11.8%
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 5 of 5

SECTION 6

Agricultural Lime Application Log
Year: 2021
Project:
Cherryville
Field
Soil
Lime Requirement
Tons/Acre
Date Applied
(state -county -site -field)
pH
(from soil analysis)
Applied(CCE Eq.)
LT-107-3
5.2
0.0T/Ac
0.0T/Ac
LT-107-4
5.7
0.0T/Ac
0.0T/Ac
LT-107-5
5.8
0.0T/Ac
0.0T/Ac

SECTION 7

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-SL020265
Sampled:
% li ra
r cil ` . Predictive
,, Asa,
. ''.-Cr Soil Report Mehlich-3 Extraction
'x ;: iit.;',"'. Links to Helpful Information
Client:
Client ID:
Calvin (John) Wehunt
2385 Norman Parker
Cherryville, NC 28021
Sampled County Lincoln
324632
Advisor: Alex Fox
Synagro
284 Boger Rd
Mocksville, NC 27028
Advisor ID: 501947
11/19/2021 Received: 11/24/2021 Completed: 01/24/2022 Farm: Lt-107
Sample ID: 3
Lime History:
Recommendations: Lime
Nutrients (lb/acre)
More
Information
Note: 3
Crop (tons/acre) N P2O5
1 -Corn, silage 1.0 180-220 30
2 - 0.0
K2O
130
Mg S
0 0
Mn Zn
0 0
Cu B
0 0
Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg%
0.36 0.97 4.7 61 1.8 5.2 58 33 39 19
S-I
70
Mn-I
26
Soil Class:
Mn-A11 Mn-Al2
33
Mineral
Zn-I Zn-AI
47 47
Cu-I Na ESP SS -I NO3-N
96 0.1 2
Sample ID: 4
Lime History:
Recommendations: Lime
Nutrients (lb/acre)
More
Information
Note: 3
Crop (tons/acre) N P2O5
1 -Corn, silage 0.4 180-220 0
2 - 0.0
K2O
140
Mg S
0 0
Mn Zn
0 0
Cu B
0 0
Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg%
0.51 1.13 4.4 73 1.2 5.7 135 29 54 16
S-I
31
Mn-I
137
Soil Class:
Mn-A11 Mn-Al2
99
Mineral
Zn-I Zn-AI
116 116
Cu-I Na ESP SS -I NO3-N
157 0.0
North Carolina
rr
Ts [u (rusk Funii C4 nmissioli
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY22-SL020265
Calvin (John) Wehunt
Page 2 of 3
Sample ID: 5
Lime History:
Recommendations: Lime
Nutrients (Ib/acre)
More
Information
Note: 3
Crop (tons/acre) N P2O5
1 -Corn, silage 0.3 180-220 80
2 - 0.0
K2O
160
Mg S
0 0
Mn Zn
0 0
Cu
0
B
0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
HM% W/V CEC BS% Ac pH P-I K-I Ca% Mg%
0.46 1.12 3.9 73 1.0 5.8 28 23 50 21
S-I
37
Mn-I
89
Soil Class:
Mn-AI1 Mn-Al2
70
Mineral
Zn-I Zn-AI
40 40
Cu-I
57
Na
0.0
ESP SS -I NO3-N

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY22-SL020265
Calvin (John) Wehunt Page 3 of 3
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Lime
Report Abbreviations
Ac exchangeable acidity
B boron
BS% % CEC occupied by basic cations
Ca% % CEC occupied by calcium
CEC cation exchange capacity
Cu-I copper index
ESP exchangeable sodium percent
HM% percent humic matter
K-I potassium index
K20 potash
Mg% % CEC occupied by magnesium
MIN mineral soil class
Mn manganese
Mn-All Mn availability index for crop 1
Mn-Al2 Mn-availability index for crop 2
Mn-I manganese index
M-0 mineral -organic soil class
N nitrogen
Na sodium
NO3-N nitrate nitrogen
ORG organic soil class
pH current soil pH
P-I phosphorus index
P205 phosphate
S-I sulfur index
SS -I soluble salt index
W/V weight per volume
Zn-AI zinc availability index
Zn-I zinc index
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at one
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Fertilizer
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be > 50. If they
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear
only on reports for greenhouse soil or problem samples.
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
ncagr.gov/agronomi/pubs.htm.
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find
the exact fertilizer grade recommended on the report, visit www.ncagr.caov/agronomi/obpart4.htmistind information that
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.
Test Results
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-A11, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinely
indicate levels fertility Visit www.ncagr.gov/agronomi/uyrst.htm
available)] of plant nutrients or other measurement.