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HomeMy WebLinkAboutNC0024911_Permit (Modification)_20080115NPDES DOCUMENT :MCANNINO COVER SHEET NPDES Permit: NC0024911 MSD Buncombe County WWTP Document Type: Permit Issuance Wasteload Allocation Authorization to Construct (AtC) Permit Modification `) — P3""" a iIJ-•l YI,Y.Ch— '- wrMw•.rkuu.. •" Complete File - Historical Engineering Alternatives (EAA) Staff Report Instream Assessment (67b) Speculative Limits Environmental Assessment (EA) Document Date: January 15, 1y4' ► ` 1 7009 This document is printed on reuse paper - ignore any content on the reizerse side Michael F. Easley, Governor State of North Carolina William G. Ross, Jr., Secretary Department of Environment and Natural Resources Coleen H. Sullins, Director Division of Water Quality January 15, 2008 Mr. Tom Hartye MSD of Buncombe County 2028 Riverside Drive Asheville, North Carolina 28804 Subject: Issuance of NPDES Permit NC0024911 French Broad River WRF Buncombe County Dear Mr. Hartye: As a result of the Consent Agreement and Settlement between MSD of Buncombe County and the Division, we are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 15, 2007 (or as subsequently amended). This final permit contains the following significant changes as a result of the settlement agreement: > A 2-yr compliance schedule has been placed in effect for the 22 ug/L daily maximum cyanide limit. This limit will take effect on February 1, 2010. The Division will review the cyanide limit, upon request, after twelve months of data have been collected. The review will take into account the most recent 24 months of DMR data. ➢ MSD will complete a study of its wastewater collection system and treatment plant to determine the source(s) of the cyanide previously detected in the wastewater effluent. In designing and implementing this study, MSD will solicit the assistance of staff in DWQ's laboratory certification section and/or their counterparts in EPA region IV, conceming procedures for sampling and preservation of samples. Additionally, as part of the settlement agreement, MSD may work with DWQ staff to develop a site -specific limit for cyanide. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, the Coastal Area Management Act or any other Federal or Local governmental permit that may be required. If you have any questions concerning this permit, please contact Toya Fields at telephone number (919) 733-5083, extension 551. Sincerely, Coleen H. Sullins cc: Central Files Asheville Regional Office/Surface Water Protection NPDES Unit PERCS Unit Aquatic Toxicology Marshall Hyatt, EPA Region IV 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Telephone (919) 733-7015 FAX (919) 733-0719 512 N. Salisbury Street, Raleigh, North Carolina 27604 On the Internet at http://h2o.enr.state.nc.us/ An Equal Opportunity/Affirmative Action Employer NorthCarolina ,Naturally Permit NC0024911 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, the Metropolitan Sewerage-- District of Buncombe County is hereby authorized to discharge wastewater from a facility located at the French Broad River WRF NC Highway 251 North of Asheville Buncombe County to receiving waters designated as French Broad River in the French Broad River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV -hereof. This permit shall become effective February 1, 2008. This permit and authorization to discharge shall expire at midnight on December 31, 2010. Signed this day January 15, 2008. oleen H. Sullins, Director Division of Water Quality By Authority of the Environmental Management Commission Permit NC0024911 SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no Longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. The Metropolitan Sewerage District of Buncombe County is hereby authorized to: 1. Continue to operate an existing 40 MGD wastewater treatment system consisting of a Rotating Biological Contactor (RBC) system with the following components: • Two mechanical bar screens • Three aerated grit chambers with grease removal • Three influent pumps with capacity of 35 MGD each. ♦ Instrumental flow measurement • Seven 250-micron primary microscreens (currently not in service) • Eighteen 27-micron secondary microscreens ♦ lst, 2nd, and 3rd stage RBCs (150 total) • Three intermediate pumps • Four intermediate clarifier cells • Effluent chlorination (sodium hypochlorite) • Two gravity sludge thickeners • Four gravity belt thickeners (currently not in service) • Two anaerobic digesters (currently not in service) • Two 2.5-meter belt filter presses • Fluidized bed incinerator • Alkaline stabilization facility • 2 MW back-up generator (diesel) • Two 450 KW gas generators • Three 850 KW hydro turbines • 17-acre ash storage lagoon The facility is located north of Asheville at the MSD Buncombe County WRF on NC Highway 251 in Buncombe County; 2. Discharge from said treatment works at the location specified on the attached map into the French Broad River, classified B waters in the French Broad Basin. NC00024911- MSD Buncombe County Latitude: Longitude: Ouad #: Stream Class: Receiving Stream: permitted Flow; 35°39'02" 82°35'54" ESNE/Weaverville B French Broad River 40.0 MGD Sub -Basin: 04-03-02 Metropolitan Sewerage District of Buncombe County NC0024911 MSD - Buncombe WWTP Permit NC0024911 A. (1.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge from outfall 001.. Such'discharges shall be limited and monitored by the Permittee as specified below: LIMITS MONITORING REQUIREMENTS EFFLUENT CHARACTERISTICS Monthly Average ' Weekly Average Daily Maximum Measurement : ; ` Frequency > Sample Type Sample Location' Flow 40 MGD Continuous Recording ' I or E CBOD, 5-day (20°C)2 25.0 mg/L 40.0 mg/L Daily Composite I & E Total Suspended Solids2 30.0 mg/L 45.0 mg/L Daily Composite I & E NH3 as N Daily Composite E Dissolved Oxygen3 Daily Grab E, U & D Fecal Coliform (geometric mean) 200/100 nil 400/100 ml Daily Grab E, U & D Total Residual Chlorines 28 pg/L Daily Grab E Temperature (°C) Daily Grab E, U & D Total Nitrogen (NO2+NO3+TIN) Quarterly Composite E Total Phosphorus Quarterly Composite E Conductivity Daily Grab E, U & D Cyanide4 22 }ig/L Weekly Grab E Total Copper 2/Month Composite E Total Zinc 2/Month Composite E Total Silver 2/Month Composite E pH Between 6.0 and 9.0 s.u. Daily Grab E Chronic Toxicity6 Quarterly Composite E Annual Pollutant Scan7 Annual Grab E Footnotes: 1. I= Influent, E= Effluent, U= Upstream at dam discharge to fish ladder adjacent to intake flume to the hydroelectric plant (Location is approximately 2700 feet upstream of the hydroelectric plant). D = Downstream at Ledges Park. Upstream and downstream samples shall be grab samples. Stream samples shall be collected three times per week during June, July, August and September then once per week in the remaining months of the year. 2. The monthly average effluent CBOD5 and Total Suspended Solids concentrations shall not exceed 15% of the respective influent value (85% removal). 3. The daily average dissolved oxygen effluent concentration shall not be less than 5.0mg/L. 4. See special condition A(3). 5. TRC limit takes effect May 1, 2008. Limit and monitoring requirement only apply if chlorine is used for disinfection. 6. Whole effluent toxicity will be monitored using the Pass/Fail Chronic Toxicity test with Ceriodaphnia at 12%. Samples shall be taken in February, May, August & November; see A. (2.). 7. See special condition A(7). There shall be no discharge of floating solids or visible foam in other than trace amounts Permit NC0024911 t A. (2.) CHRONIC TOXICITY PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 12%. The permit holder shall perform at a minimum, Quarterly monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, • or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The tests will be performed during the months of February, May, August and November. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised - February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value. Additionally, DWQ Form AT-3 (original) is to be sent to the following address: Attention: North Carolina Division of Water Quality Environmental Sciences Section 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Section no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for -disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Section at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re- opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. Permit NC0024911 A. (3) CYANIDE SPECIAL CONDITION The cyanide limit shall take effect February 1, 2010, two years after the effective date of this final permit, however the weekly monitoring requirement applies as of the effective date of this final permit. The quantitation limit for cyanide shall be 10 pg/L (10 ppb). Levels reported at less than 10 pg/L shall be considered zero for compliance purposes. The Division will review the cyanide limit, upon request, after twelve months of data have been collected. The review will take into account the most recent 24 months of DMR data. During the two-year period before the cyanide limit takes effect, MSD shall complete a study of its wastewater collection system and treatment facility to determine the source(s) of cyanide previously detected in the WWTP effluent. During this same period, MSD may choose to develop and propose (with the cooperation of DWQ staff) a site -specific limit for cyanide. At the conclusion of the two-year period, one of the following will occur: (a) The daily maximum cyanide limit specified in Section A(1) will take effect, or; (b) A site -specific daily maximum cyanide limit, as developed by MSD and subject to DWQ approval, will take effect, or; (c) The cyanide limit will be removed from this permit based on a review of 24 months of data demonstrating no reasonable potential for the discharge to cause an exceedance of cyanide water quality standards. A. (4.) PRETREATMENT MONITORING CLARIFICATION Ground Water remediation sites discharging to MSD Buncombe WRF with locally issued permits shall be considered as Non -Significant Industrial Users and shall have no specific requirements for parameter limits or monitoring frequency if they do not discharge more than 25,000 gallons of industrial process wastewater per day, they do not discharge more than 5 % of the Maximum Allowable Headworks Loading (MARL) of any pollutant to the MSD Buncombe WRF, they are not a 40 CFR regulated Categorical Industry, or they do not in the opinion of the Director of MSD Buncombe have the potential to upset or interfere with the operation of the WRF. The Director of MSD WRF shall enforce the Sewer Use Ordinance, permit, limit, monitor, and inspect all dischargers to his WRF as needed to assure proper operation and compliance with all NPDES effluent limits including Whole Effluent A. (5.) GROUNDWATER REQUIREMENTS I. Monitoring Requirements a: The existing monitoring wells MW 1, MW2, MW3, and MW4 shall be sampled three times per year for the following parameters: ➢ Arsenic > Barium ➢ TOC > Chlorides > Chromium > Fecal coliform ➢ Lead > Mercury > Nitrogen, Ammonia Total (as N) Nitrogen, Nitrate Total (as N) pH Silver TDS Volatile Organic Compounds (Sample annually in the last quarterly sampling month only) Water level The measurement of water level and then pH must be taker prior to sampling the remaining parameters. The depth to water in each well shall be measured from the surveyed point on the top of the casing. The measuring points (top of well casing) of all monitoring wells shall be surveyed to provide the relative elevation of the measuring point for each well. b. Analyses of the required parameters must be conducted by a laboratory certified by the DWQ Laboratory Certification Unit for those analyses. c. Volatile Organic Compounds (VOCs). Samples collected for VOCs must be analyzed using one of the following methods: Permit NC0024911 Standard Method 6230D Standard Method 6210D EPA Method 8021, Low Concentration EPA Method 8260, Low Concentration Another method, with prior approval by the Aquifer Protection Section Chief Any method used to analyze VOCs must include, at a minimum, all constituents listed in Table VIII of Standard Method 6230D. Any method used must provide a Practical Quantitation Limit (PQL) of 0.5 ug/L or less, which must be supported by laboratory proficiency studies as required by the DWQ Laboratory Certification Unit. Any constituents detected above the Method Detection Limit (MDL) but below the PQL of 0.5 ug/L must be qualified (estimated) and reported. d. The Division may require additional groundwater monitoring it deems necessary to determine compliance with Groundwater Quality Standards and other applicable laws and regulations. II. Reporting Requirements a. The Permittee shall prepare groundwater monitoring reports for each sampling period using current versions of Form GW-59 (Groundwater Quality Monitoring: Compliance Report Form) and Form GW-59A (Compliance Report Form) and shall include copies of the laboratory report(s) with each report. b. The Permittee shall submit three (3) copies of its reports to the following address, postmarked no later than the 28th day of the month following the sampling period: Division of Water Quality Attn: Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 c. Copies of current forms may be downloaded from the Division of Water Quality website at http://h2o.enr.state.nc.us/aps/gnu/forms.htm or requested from the address above. III. Applicable Boundaries a. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in 15A NCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary for the disposal system individually permitted prior to December 30, 1983 is established at either 500 feet from the waste disposal area, or at the property boundary, whichever is closest to the waste disposal area. An exceedance of Groundwater Quality Standards at or beyond the Compliance Boundary is subject to remedial action according to 15A NCAC 2L .0106(d) (2). b. The REVIEW BOUNDARY is established around the disposal system midway between the Compliance Boundary and the perimeter of the waste disposal area. Any exceedance of standards at the Review Boundary shall require action in accordance with 15A NCAC 2L .0106(d)(1). A. (6.) ASH STORAGE LAGOON MSD Buncombe is permitted to operate a 17-acre lagoon for the purpose of storing incinerator ash. Effluent from this lagoon is sent to the head of the plant for treatment. No other materials may be stored in the lagoon without prior Division notification. Permit NC00249 11 A. (7.) EFFLUENT POLLUTANT SCAN The permittee shall perform an annual effluent pollutant scan for all parameters listed in the table below (in accordance with 40 CFR Part 136). The annual effluent pollutant scan samples shall represent seasonal (summer, winter, fall, spring) variations over the 5-year permit cycle. Unless otherwise indicated, metals shall be analyzed as "total recoverable." Additionally, the method detection level and the minimum level shall be the most sensitive as provided by the appropriate analytical procedure. Ammonia (as N) Chlorine (total residual, TRC) Dissolved oxygen Nitrate/Nitrite Total Kjeldahl nitrogen Oil and grease Total Phosphorus Total dissolved solids Hardness Antimony Arsenic Beryllium Cadmium Chromium Copper Lead Mercury Nickel Selenium Silver Thallium Zinc Cyanide Total phenolic compounds Volatile organic compounds: Acrolein Acrylonitrile Benzene Bromoform Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane 2-chloroethylvinyl ether Chloroform Dichlorobromomethane 1, 1 -dichloroethane 1,2-dichloroethane Trans-1, 2-dichl oroethylen e 1,1-dichloroethylene 1,2-dichloropropane 1, 3-dichloropropylene Ethylbenzene Methyl bromide Methyl chloride Methylene chloride 1,1,2,2-tetrachloroethane Tetrachloroethylene • Toluene 1,1,1-trichloroethane 1,1,2-trichloroethane Trichloroethylene Vinyl chloride Acid -extractable compounds: P-chloro-m-cresol 2-chlorophenol 2,4-dichlorophenol 2,4-dimethylphenol 4,6-dinitro-o-cresol 2,4-dinitrophenol 2-nitrophenol 4-nitrophenol Pentachlorophenol Phenol 2,4,6-trichlorophenol Base -neutral compounds: Acenaphthene Acenaphthylene Anthracene Benzidine Benzo(a)anthracene Benzo(a)pyrene 3,4 benzofluoranthene Benzo(ghi)perylene Benzo(k)fluoranthene Bis (2-chloroethoxy) methane Bis (2-chloroethyl) ether Bis (2-chloroisopropyl) ether Bis (2-ethylhexyl) phthalate 4-bromophenyl phenyl ether Butyl benzyl phthalate 2-chloronaphthalene 4-chlorophenyI phenyl ether Chrysene Di-n-butyl phthalate Di-n-octyl phthalate Dibenzo(a,h)anthracene 1,2-dichlorobenzene 1,3-dichlorobenzene 1,4-dichlorobenzene 3,3-dichlorobenzidine Diethyl phthalate Dimethyl phthalate 2,4-dinitrotoluene 2,6-dinitrotoluene 1,2-diphenylhydrazine Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclo-pentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone Naphthalene Nitrobenzene N-nitrosodi-n-propylamine N-nitrosodimethylamine N-nitrosodiphenylamine Phenanthrene Pyrene 1,2,4-trichlorobenzene Test results shall be reported to the Division in DWQ Form- DMR-PPA1 or in a form approved by the Director, within 90 days of sampling. A copy of the report shall be submitted to Central Files to the following address: Division of Water Quality, Water Quality Section, 1617 Mail Service Center, Raleigh, North Carolina 27699-1617. STATE OF NORTH CAROLINA COUNTY OF BUNCOMBE IN THE OFFICE OF ADMINISTRATIVE HEARINGS 06 EHR 2061 Metropolitan Sewerage District of Buncombe County, Petitioner, NC Department of Environment and Natural Resources, Division of Water Quality, Respondent. CONSENT AGREEMENT AND SETTLEMENT The petitioner, Metropolitan Sewerage District of Buncombe County ("MSD"), and the respondent, North Carolina Department of Environment and Natural Resources, Division of Water Quality ("DWQ"), hereby enter into this Consent Agreement and Settlement ("Agreement") in order to resolve matters in controversy between them pursuant to N.C.G.S. § 150B-31(b). This above -captioned matter arose out of the 27 September 2006 renewal by the respondent of NPDES Permit NC0024911 ("the permit") , held by the petitioner. The permit authorizes the petitioner to operate a 40 MGD wastewater treatment system at its Water Reclamation Facility, and to discharge treated wastewater from that facility into the French Broad River at a specified location. The permit includes effluent limitations and monitoring conditions for various parameters and constituents of concern, including Cyanide. The renewal permit included a daily maximum effluent limit of 22 micrograms per liter (ug/1) and requires weekly monitoring for Cyanide. This limit was to take effect 1 May 2008, to allow the petitioner an opportunity to conduct a study and determine the source of high readings previously reported for this parameter. MSD commenced the above -captioned contested case to challenge the cyanide limit. The parties subsequently engaged in settlement negotiations and developed a draft amended permit which is agreeable to both. Therefore, without any trial of fact or law in the above - styled matter, THE PARTIES AGREE THAT: 1. The daily maximum effluent limit for c anide (22 ug/1) will remain in the subject permit, but will not take effect until two (2) years following full execution of this Agreement. 2. During the same two (2) - year period, MSD will complete a study of its wastewater collection system and treatment facility to determine the source(s) of the cyanide previously detected in the treatment plant effluent. The study would include, but not be limited to, consideration of the waste stream coming from the incinerator scrubber water, and instream analyses for cyanide, upstream and downstream in the receiving waters, -nd in the flume. In designing and implementing this study, MSD will solicit the -2- assistance of staff in DWQ's laboratory certification section and/or their counterparts in EPA Region IV, concerning procedures for sampling and preservation of samples. 3. During the same two (2) - year period, MSD reserves the right, pursuant to 15A N.C. Admin. Code 2B .0211, to work with appropriate staff in DWQ to develop a site -specific limit for cyanide, and will submit to DWQ the results of its study, along with any other relevant information, in attempting to develop such a limit. DWQ will consider any such request, review the supporting data submitted, and act upon it as required and/or allowed by law. 4. MSD reserves the right to request, at the conclusion of the same two (2) - year period, that DWQ remove from its permit the effluent limit for cyanide. Any such request shall be supported by a minimum of twenty-four (24) consecutive months of data which MSD contends demonstrates that the permitted facility and discharge V/ have no reasonable potential for causing an exceedance of water quality standards for cyanide. DWQ agrees to consider any such request, review the supporting data submitted, and act upon it as required and/or allowed by law. 5. Within ten (10) days following full execution of this Agreement, and subject to its terms and conditions, the respondent, DWQ, agrees to issue to the petitioner, MSD, an amended renewal permit containing the same terms and conditions as the draft permit -3- developed and agreed to by the parties. A copy of the draft is attached to this Agreement, marked "Exhibit A," and incorporated by reference herein. 6. By execution of this Agreement, and subject to its terms and conditions, MSD accepts and agrees not to challenge the terms and conditions of the amended renewal permit, Exhibit A hereto. 7. MSD explicitly waives its right to a contested case hearing in this matter and additionally agrees to withdraw its petition for contested case hearing previously filed with the Office of Administrative Hearings in the above -captioned matter. Petitioner shall file a notice of withdrawal of request for contested case hearing within ten (10) days following full execution of this Agreement. FOR THE PETITIONER: METROPOLITAN SEWERAGE DISTRICT OF BUNCOMBE COUNTY Date: ROBERTS & STEVENS, P.A. Attorneys for the Petitioner William Clarke P.O. Box 7647 Asheville NC 28802 Date: -4- FOR THE RESPONDENT: NC DENR, DIVISION OF WATER QUALITY Susan Wilson, Supervisor Western NPDES Program Date: ROY COOPER Attorney General Sueanna P. Sumpter Assistant Attorney General NC Department of Justice 42 N. French Broad Avenue Asheville NC 28801 Date: FW: MSP / NPDES Subject: FW: MSD / NPDES From: "Sumpter, Sueanna" <WOssumpt@ncdoj.gov> Date: 'rue, 28 Aug 2007 09:16:26 -0400 To: "Toya Fields" <toya.fields@ncmail.net>, "Susan Wilson" <susan.a.wilson@ncmail.net> CC: "Roger Edwards" <Roger.Edwards@ncmail.net> What do you think? He is essentially suggesting that we leave the existing permit term as it is. Sueanna From: Billy Clarke [mailto:BClarke@roberts-stevens.com] Sent: Monday, August 27, 2007 4:35 PM To: Sumpter, Sueanna Subject: MSD / NPDES FOR SETTLEMENT PURPOSES ONLY have spoken with the client. Client is agreeable with no cyanide limit in permit for a period of two years from effective date of Settlement Agreement. With respect to item 4. in my letter, the permit now reads, in paragraph A. 3, that the Division will review the cyanide limit, upon request, after twelve months of data have been collected. MSD wanted that provision clarified to read that if there were twelve months of data showing no exceedances, there would be no limit in the permit. I understand the state does not want that and suggested two years. I would suggest we just leave the language as is. That way, the Division can review the data and do as it sees fit. also understand you will contact OAH to see if we are on a calendar. Thanks for your help. William Clarke Roberts & Stevens, PA Post Office Box 7647 Asheville, N.C. 28802 Suite 1100 BB & T Building One West Pack Square, 28801 (828) 258-6919 (Voice) (828) 210-6526 (Fax) ************************************************************************** This message has been scanned for viruses by Roberts & Stevens, P.A. NOTICE: This message is intended only for the designated recipient(s). It may contain confidential or proprietary information and may be subject to the attorney -client privilege or other confidentiality protections. Any review, copying, printing, disclosure, distribution, or any other use by any other person or entity is strictly prohibited. If you are not a designated recipient, or believe you have received this email in error, please reply to the sender and delete the copy you received. Thank you. ************************************************************************** 1 of 1 8/28/2007 3:50 PM Re:, MSD .v. DENR, DWQ (OAH 06 EHR 2061) (NPDES Permit # ... r Subject: Re: MSD v. DENR, DWQ (OAH 06 EHR 2061) (NPDES Permit # NC0024911) From: Toya Fields <toya.fields@ncmail.net> Date: Mon, 27 Aug 2007 15:41:08 -0400 To: "Sumpter, Sueanna" <WOssumpt@ncdoj.gov> CC: Susan Wilson <susan.a.wilson@ncmail.net>, Roger Edwards <Roger.Edwards@ncmail.net> Thanks Sueanna, My only comment is that the data wouldn't necessarily have to show all non -detects So for the last part, instead of /"Typically, DWQ requires 2 years of non -detects before agreeing to consider removal of a limit. Accordingly, any settlement condition would have to provide for 24, rather than 12, consecutive months of non -detects before the cyanide limit would be removed from the permit."/ I'd put something like " Typically, when considering the removal of a permit limit, DWQ reviews two years of data. DWQ then performs an analysis to determine whether the discharge could be expected to contravene water quality standards. If not, then the limit is removed. Accordingly, any settlement condition would have to provide for 24, rather than 12, months of data that does not demonstrate "reasonable potential" to cause an exceedance of cyanide water quality standards". I know its wordier but MSD will know what we mean. Susan is out today, back tomorrow. She might have more thoughts. Toya Sumpter, Sueanna wrote: I have attached for your review a response to MSD's counteroffer. Please take a look at it and let me know if it correctly states your position. Thanks. Sueanna Toya Fields - toya.fields@ncmail.net Environmental Engineer I Western NPDES Program Division of Water Quality Tel: 919-733-5083 x 551 Fax: 919-733-0719 1 of 1 8/28/2007 3:50 PM MSD Buncombe Counter offer (7/2/2007) DWQ offers the following to MSD Buncombe (based on further review of the CN standard and criteria) 1) A compliance schedule of 2 years to meet the CN limit (2 years from date of final settlement agreement). Ef- 2) Commitment to evaluate sampling and preservation of samples for CN testing (solicit expertise of NC Lab Certification and/or EPA R4 Lab personnel) 3) Develop site -specific criteria per 15A NCAC 2B .0211(3)(1)(vi) for CN (acute). Based on information obtained from NC's water quality standards contact (Connie Brower), the site specific value for CN (acute) could be 46 µg/1 (for non - trout waters). This value will need to be confirmed by MSD. The 22 µg/1 CN daily max limit will remain in the permit until the approval of a site -specific criterion. As stated in (1) above, DWQ will allow a 2-year compliance schedule prior to implementation of this limit for CN. 4) Drop proposal to perform instream CN monitoring (DWQ does not consider this to be value-added since the proposed limit is based on an acute criteria). WI. IhibkP AitIA'ij 101 Oa(1� /xo(7 /41;D guNC4Wbb (e‘i-cur tio"tr os.-t;73 1/27�,6 46' At9P ((( 7f 7O) /Ica L Fat cf 1/S /g QS,6 69P re. Got / - C{jru Py.4nlcc 1 ►i /11-11/ L, (Al 7 S %e 5P&—i hhc Dp7-7Ok. i To ; Malec PP/20\l'•� > 6A Aite-rgo rho Q LC�' gc O"TLiN 5 A t1CAc 2 z r1 (s)a)Cv2,7 ICA,C74.-0 ST1 r:/4- 642e %we-4- 7 -120, �� 7 G,j ,i,7', 4> 5 c. r)955 r ¢moo 140 Gar iviP/i C11J ' C°/ DRAFT NORTH CAROLINA FRESHWATER AQUATIC LIFE STANDARD FOR CYANIDE (AS FREE) c Introduction 1i S c..) AS , LL OG IL CO n I°197-- I1,9� .) The Clean Water Act requires states to review their water quality standards and classifications every three years and make any changes that are necessary to improve ) -- water quality protection. The following review of the current cyanide standard for freshwaters was conducted as part of the 1997-1999 Triennial Review. This review incorporates EPA and literature data and proposes to revise the current freshwater standard to address trout and non -trout waters. Similar recalculations have been conducted in other states'. North Carolina's current cyanide standard for freshwaters is 5.0 ug/1 and is implemented as total cyanide. This standard is based on EPA's 1976 "Red Book"2. In 1985, EPA published a new standard for cyanide of 5.2 ug/1 as free cyanide3. North Carolina did not adopt this change as it was based on an acute/chronic ratio that incorporated a wide range of ratios. There were five ratios used in the calculation. Four of those ratios ranged from 8.8 to 13. A ratio of 68 was also used from Asellus communis, a pollution tolerant species. If this value is not used, then the final chronic value is 5.1 ug free cyanide/1 which is nearly the same as the Red Book value of 5.0 ug •cyanide/1. — i NoLerwueA- c zs v 1 cb.. 40 4 o CF o2 13 (c j`cec� Ca'i� 5 The recent review of the literature and EPA's databases provided no new toxicity data that met EPA's criteria for acceptable data4. However, the standard was recalculated for trout and non -trout waters, as trout are the most sensitive species tested to date. This document explains that recalculation and proposes modification of the current cyanide standard. Background Cyanides are used extensively in the manufacture of synthetic fabrics and plastics, in electroplating baths and metal mining operations, as pesticidal agents and intermediates in agricultural chemical production, and in predator control devices. Anthropogenic sources of cyanide in the environment include certain industrial processes, laboratories, fumigation operations, cyanogenic drugs, fires, cigarette smoking and chemical warfare. Cyanide occurs in water as hydrocyanic acid (HCN), the cyanide ion (CN), simple cyanides, metallocyanide complexes, and as simple chain and complex ring organic compounds5. Some of the metallocyanide complexes such as Zn(CN)2 are easily Sawyer, B., D.R Zenz, C. Lue-Hing, D.T. Lordi, and R. Hill. 1998. Realistic Limits for Water Toxics. Water Environment & Technology. 6:57-60. 2 EPA. 1976. Quality Criteria for Water. pp 65-69. 3 50 FR 30784, July 29, 1985 4 EPA. 1985a. Guidelines for Deriving Numerical National Water Quality Criteria for the Protection of Aquatic Organisms and Their Uses. 98 pp. 5 EPA. 1985b. Ambient Water Quality Criteria for Cyanide — 1984. EPA 440/5-84-028. DRAFT degradable, while others such as iron and cobalt complexes are moderately degradable. Copper and nickel complexes are intermediate between the zinc and iron complexes. "Free cyanide" is the sum of the cyanide present as HCN and as CN-. The relative concentrations of these two forms of cyanide depend mainly on pH and temperature. When pH is below 8 and temperature is below 25°C, at least 94 percent of the free cyanide exists as HCN. When pH or temperature or both are higher, a greater percentage of free cyanide exists as CN". At pH 7, about 99% of the free cyanide is in the form of HCN, whereas at pH 9.3 HCN composes 50%. Free cyanide is the primary toxic agent, regardless of its origin. Cyanides are readily absorbed through inhalation, ingestion, or skin contact and are readily distributed throughout the body via blood. All available evidence suggests that cyanides are not mutagenic, teratogenic, nor carcinogenic6. Moreover, there are no reports of cyanide bioaccumulating or cycling in living organisms, probably owing to its rapid detoxification. Cyanide seldom persists in surface waters and soils due to complexation or sedimentation, microbial metabolism, and loss from volatilization. More data are needed on cyanide distribution and transformation in the atmosphere to fully understand the fate of atmospheric cyanide. Some complex cyanides, especially the hexacyanoferrate complexes (iron complexes) are subject to photolysis over a wide range of wave -lengths of light and liberate free cyanides in the process. The dynamics of the process are fairly well understood and allow a degree of prediction of conversion rates under ideal conditions. However, in complex systems where photolytic synthesis of free cyanides is influenced by turbulent mixing over depth with varying light intensities, and where competing removal processes occur, the prediction of resulting free cyanide levels is problematic. Criteria Development Aquatic Toxicity In the EPA's criteria documents, the tests reported indicated that invertebrates were considerably more resistant than fishes, but Daphnia sp. and Gammarus pseudolimnaeus were comparable to fishes in sensitivity. The only consideration with this apparent difference in sensitivity is that most of the invertebrate tests were static and the test concentrations were not measured. On the other hand, many of the fish tests were flow - through tests in which free cyanide concentrations were measured. Certain life history stages and species of fish appear to be more sensitive to acute effects of cyanide than others. Embryos, sac fry, and warmwater species tended to be the most resistant. Free cyanide concentrations from about 50 to 200 ug/1 eventually were 6 Eisler, R. 1991. Cyanide Hazards to Fish, Wildlife and Invertebrates: A Synoptic Review. US Fish and Wildlife Service, Biological Report 85(1.23). Contaminant Hazard Reviews Report 23. Hartung, R. 1990. Differential Toxicity of Forms of Cyanide. The Aluminum Association, Inc. Washington, DC. 8 EPA. 1985b. Ibid. 05/18/06 2 DRAFT fatal to juveniles of most of the sensitive fish species, with concentrations slightly above 200 ug/1 being rapidly fatal to most juvenile fish. According to the review by Eisler9 in 1991, fish were the most sensitive aquatic organisms tested under controlled conditions. Nonlethal effects, including reduced swimming performance and inhibited reproduction, were observed in the range of 5.0-7.2 ug free cyanide/1 for bluegills. This data was not included in the EPA's 1984 criteria document because of low spawning success in the controls and no concentration effect relationship was observed. Instead, the EPA's chronic value for bluegill was based on long-term survival. Based on reduced long-term survival in an early life -stage test with the bluegill and reduced reproduction by the brook trout and fathead minnow in partial and full life -cycle tests, the chronic values of 13.57, 7.849 and 16.39 ug free cyanide/1 were used by the EPA. Chronic values are also available for two freshwater invertebrates, the isopod, Asellus communis, with a chronic value of 34.06 ug free cyanide/1 and the amphipod, Gammarus pseudolimnaeus, with a chronic value of 18.33 ug free cyanide/1. Acute Toxicity 1 S117_.O No additional data were added to the existing cyanide toxicity database found in EPA's 1985 Cyanide standards document10. Trout Waters EPA guidance requires that the FAV be compared to each of the species mean acute value (SMAV) to insure that all the SMAVs are below the FAV. It was found that rainbow trout (Oncorhynchus mykiss) with a SMAV of 44.73 ug free cyanide/1 was more sensitive than the FAV to cyanide. Therefore, the rainbow trout SMAV was used as the FAV. The acute standard for cyanide to protect trout waters is 44.73 divided by 2 or 22.36 ug free cyanide/1. Non -Trout Waters The surface water quality standard for non -trout waters was derived by removing the trout SMAV from the calculation. The species removed were Oncorhynchus mykiss, Salmo salar, and Salvelinus fontinalis. This action resulted in there being thirteen genus mean acute values. Following EPA guidance it was confirmed that eight different were still represented in the data. The acute standard based on this analysis is e cyanide/1 (FAV of 91.6 divided by 2). A review of literature was conducted ne if there were data that indicated other species were as sensitive as trout. No such species were found. 9 Eisler. 1991 Ibid. 1° EPA. 1985b. Ibid. 05/18/06 3 DRAFT Table 1. Species Reference GMAV, SMAV and ACR for Free Cyanide RANK GMAV SPECIES SMAV ACR 1 63.45 Oncorhynchus mykiss 44.73 Salmo salar 90.00 2 85.80 Salvelinus fontinalis 85.80 10.59 3 92.64 Perca flavescens 92.64 4 99.28 Lepomis macrochirus 99.28 7.316 5 102 Pomoxis nigromaculatus 102 6 102 Micropterus salmoides 102 7 123.6 Daphnia magna 160 Daphnia pulex 95.55 8 125.1 Pimephales promelas 125.1 7.633 9 147 Poecilia reticulata 147 10 167 Gammarus pseudolimnaeus 167 9.111 11 318 Carassius auratus 318 12 426 Pteronarcys dorsata • 426 ' 13 432 Physa heterostropha 432 14 2326 Asellus communis 2326 68.29 15 2490 Tanytarsus dissimilis 2490 Key: GMAV=genus mean acute value, SMAV=species mean acute value, ACR=acute to chronic ratio. All values are as free cyanide and in ug/1. Chronic Toxicity Trout Waters In EPA's calculation of the cyanide standard, an acute to chronic ratio (ACR) of 8.57 was used. This ratio is based on the geometric mean of the ACRs for brook trout, fathead minnows, bluegill sunfish and the amphipod, Gammarus pseudolimnaeus. The chronic standard for trout waters was determined by taking the FAV of 44.73 ug free cyanide/1 and dividing by the ACR of 8.57. This resulted in a chronic aquatic life standard of 5.2 ug free cyanide/1. Non -Trout Waters For non -trout waters, the ACR was calculated as the geometric mean of the species ACRs for fathead minnows, bluegill sunfish, and the amphipod, Gammarus pseudolimnaeus. To determine the final chronic standard for non -trout waters, the FAV of 91.6 ug free cyanide/1 was divided by 7.98, the non -trout ACR. The final chronic aquatic life standard for non -trout waters is 11..5 ug free cyanide/1. This value is below the concentration at which reduced long-term survival in bluegill early life -stage tests occurred (13.57 ug free cyanide/1). 05/18/06 4 DRAFT Proposed Standard For free cyanide, the surface water quality standards to protect freshwater aquatic life as derived using EPA guidance are 12 ug free cyanide/1 for non -trout waters and 5 ug free cyanide/1 for trout waters. 05/18/06 5 • JQHI{ s. srC 't14 _.IAP C 1if• iu.vilAMs G�ML: rr.• t.01►1/41 • roilt4 w. liweola ..prApc DUpd!r Sll♦<iAYI. t{. �ILL�w1It LaOKL 4;piciim.i a. a$ftDgE.ca, JP -ti^11110i11t Rolm[ *mood A�KioAY :P• :MVTCMIN• JAO* ON a, . b1w,1ILTON bTtvicPA Mw11K c AUR YI . .i4Q6iitt. ldi ,O OA*NY MRINTOPMGR, % . CAM►ARLL • Twit♦.Ri1ou • Sueanna_Sumpter Assistant Attorney General NC Department of Justice . 42 North French Broad Aye Asheville, NC 28801 Re; Metropolitan Sewerage District v, DEAR. DWQ / 06 EHR 2061, STEVENS D64T ■uiLDINC DNL WEST •AQK 3oUANL &Tit 1100 eobO. POSY OrPICi QOa .7647 A6NEv1LLE. NoRTN CAROLINA 8AdQ2 TKLcPNONE .OQei a11i•66a0 PAC21MR 1 10=d1 aD0•p•ss WooltobefilliNIPPAIIILDOM Wraer'x Dirt-CUP/tone NP, . /12S/258-6919 Wratrr'x Otrrc(Fu'. i nfr. A28,)UI•6526. Writer's E-molt. briarkc1 .roberrx-srevans tom May ;t, 2007.. 002. DAVQL. LIth.I $i CVNrWIA .5.• QAAor r. •wCI4 aOT r "J CN''ttMP. rA. 14 !RAMCes• DuNot% KLPiNeTM t♦. IUNY • DCNNI$ .. MA71r1N. JR. PETL.f1 0• MCOUtas itevii4 P. KOPP AtBP.CCA'•tOKNsitON K. OrAN 5MAf LLY. 11 or COtir6it L,N00N NOAKRts ousg.1Ea 1.. •C1iapIC rpaNlt P. GRAN/0 (iewo•te e%1 • For Settlement Purposes Only Via Facsimile- 251-6338 (4LNosARDT Dear Sueanna: Thank you, Susan Wilson and Keith Haynes for meeting .with me, Tom Hartye, John Kiviniemi, Dennis Lance; Monty Payne and Gary McGill at MSD on April 16, 2007 to discuss . the cyanide issue and the MSD•NPDES Permit. I believe the meeting was'inforznative'and pToduetivc. 1 am writing to follow up on the.matters we discussed. • As we indicated at the:meeting, MSD's preference would be that this permitincludesno limit for cyanide during this permit cycle. MSD believes the additional time is justified based on the limited amount of data used by DLNR in determining that a.cyanide limit should be required. for the MSD water reclamation facility ("WRF")• As we also discussed, MSD is in the midst of an exten&ive. study focused on_ a source or sources of cyanide in its wastewater collection system ' or•WRF: Although cyanide: appears sporadically in the treatment planteffluent, no source has been identi fied. Cyanide has .never been detected in the plant influent, and MSD's industrial .Monitoring has detected only one minor pretreatment permit exceedance for cyanide in the last .several years. Regular concentrations of cyanide are present in the small volume of wastewater from jibe scrubber for the incinerator, however, that wastestrearn is pumped to the head of the plant for treatment, and•samples taken from the headworks after mixing have not detected any cyanide. MSD believes it will need•at least three more years to identify the source or sources of -cyanide:or to determine aim presence is duel() analytical interference. MSD's task is especially .complex -given the relationship between chlorine .and cyanide and the fact that.MSD. will be ,required to "dechlorinat&' •residual chlorine in. its, effluent next year. Obviously, MSD hopes that b0'd LS:171 LOOZ 9Z unf 8££9-LSZ-8Z8:Xe3 331330 t<ti N39 11V wJuuJ • the result of its study will be identification of the source or sources of cynanidC or the analytical phenomenoncausing it to "appear,` wth appropriate action -ensuing. .Should that not be the case, be willingto accr pt:a limit for cyanide although MSD. does not believe.22 t2 um In he I�STa. would g appropriate .- appropriate limit. Should MSD-and NCDENR,corno to ant o cagreement am � the bas basis fQ the 22 u�� limit, thc future that a limit is needed, MSD wouldsttlto .its discharge and the significant die of particularly considering the site .specific issues related the receiving scream Additionally, if a source or sources of cyanide are identified, MSD must d 1 pit eve o .an effective management strategy for controlling these sources to ensure that the ac y , - can mcet its limit. Based onour discussions at the meeting, MSD would propose the following: have an additional three years to study- the cyanide .issue beginning on the MSD would on 1. date.of resolution of. this Contested. Case• MSD would submit semian.nUai,reports..to D Q the: results .of the study: completion of the study, MSD and DW.Q would meet to determine:1) whether a- Z. Upon p what that lima should be, and 3) the steps needed limit should be .imposed for e.ymilide; 2) if so. to address' and properly manage the. source(s)= identified. 3. MSD would expand its "study" to include treatment or other management of the waste stream coming from the incinerator scrubber water. My other source(s) identified fordeftnsovelY would: would also be considered appropriate treatment management.1 The:study include instream analysesfor cyanide, including upstream and downstream sampling in the river and in :the flume. Thanks again for the meeting. Please let me know if you have questions. 1 look. forward to hearing from You. Sincerely, RC)BERTS & STEVENS, PA itliam''Claykc WC/sh cc.: Mr. Tom NIartye (via e-mail:.thartye®msdbc.org) Mr. John Kiveniemi (via e-mail:-sewerman@msdbe,org). Mr. Gary McGill (via e-mail; garym@mcgillengineers.com) KAS S39725.-1 50 'd LS:01 L00Z 9Z unf 8££9-1SZ-8Z8:xe3 33I330 A N3J lib► uo(7 /10o 4iticeis, . / I'- gifi- % AN1w P/N-1 41 ci /vo . u,K r -r %wT /F UM. r r" /411 7) A,/G O 0f./ M elW14firdAdy ©1 J 7193L6,- ��C' cl �5/o•v �mr/7' a T /-f4&-o5' y'Jo u.eco ©G CAN bG pg wrfi- Iomp ,) i ev .-ram A✓ al) (444 , r coo- ter 44er 11,1 At tr ,¢,.', T!7 77,46 /fi r C te.w B ''Li" 1144-s cr.11,'I' ,9WL V(N 5r"49 —7 _ jtit1445, it64-Li /V.v,2,444 Cm / ?-6i trE Sr- /kir 6 v C/tt- r/f (,V1 NL4ti!7"j SP.1,. c' S.OD61+7I G /^1S (ootgiuf 64'9 194-49 cS f set., r 50Yi►7gLE3 FeiL414 tr" 6147, 43 /1-7-e) C W ou u) 66 g w; C� a e' r b•a) ‘411, %k ,kW -roes. — ? 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(1971,4.-4% 661(9 c.," kfrz&) 6441(6-A / cI ►ci/ -r PitPitt= IZi vC2 S636_.) 5,44.,,#figg, H7)0 .01 1-47 wr PI (Pr Al 62.1 off (At t / 5- -ter 12,EfQ CO Ire; /2) ( I P 874 0 (At/ p�ci/ bncc. /")* , 7-0- rbj((cr7' prfi nrioce i1if /•��v �� 7�5��cry/ cti) 151' Go44 1"ro t94,'Le-ry /.may cTti , 74w CAI 1141:5ra*' trt,r7 CeA/ 5.2E72,,M-7 Ve) /917,4-n-i47,6; 0' 4,,f1;0is . Gs�i ot14I cc dab c r, r c.c(N were — ems© ,Jp „G 5 i N%7-( ,1z yr A.71 e.76, Re: FW:,MSD v. DWQ (OAH 06 EHR 2061)(NPDES Permi... Subject: Re: FW: MSD v. DWQ (OAH 06 EHR 2061)(NPDES Permit NC0024911) From: Susan Wilson <susan.a.wilson@ncmail.net> Date: Thu, 12 Apr 2007 16:04:26 -0400 To: "Sumpter, Sueanna" <WOssumpt@ncdoj.gov> CC: Toya Fields <toya.fields@ncmail.net> Good timing in that our standards person walked into my office right after I hung up the phone with you. How about this: DWQ is required to protect the Best Usage of Waters (which includes protection of aquatic life on a short term or long term basis). For MSD - the French Broad River is "B" [ref. 15A NCAC 2B .0219 (2); then, 2B .0211]. Protection of aquatic life includes protection for acute impacts (short term) and chronic impacts (long term) - ref. 15A 2B .0202 (1) and (1)(a). EPA's numeric water quality criteria and subsequent versions are adopted via (1)(a). Final Acute Value (FAV) = Criteria Maximum Concentration (CMC) = acute criteria. The acute criteria (freshwater CMC) is 22 ug/1 (via EPA's water quality criteria publication). So, DWQ implemented the EPA's acute value for CN to protect aquatic life from short term impacts (and subsequently protect the best usage of the waters). This was the more stringent value (i.e., in this the case the acute criteria was more stringent that the chronic standard - so DWQ implemented the acute criteria) . The EPA criteria is linked below (scroll to Cyanide): http: / /www.epa.gov/waterscience / criteria/wqcriteria.html Hope this helps - that's the best way I know of to answer it. We'll plan to see you at 10 am on Monday (at MSD Buncombe). If you have directions - let us know. Not sure where that is. Susan Sumpter, Sueanna wrote: Thank you again for your help. Sueanna Original Message From: Toya Fields [mailto:toya.fields@ncmail.net] Sent: Wednesday, January 17, 2007 6:14 PM To: Sumpter, Sueanna Subject: Re: MSD v. DWQ (OAH 06 EHR 2061)(NPDES Permit NC0024911) Hi Sueanna, I have some additional information about our water quality standards to help with a response to the folks at MSD. They have requested that we implement a cyanide limit of 43 ug/L based on a freshwater quality standard of 5 ug/L and a dilution factor. That would be consistent with our methodology for developing permit limits based on our chronic water quality standards. However, in the case of cyanide, EPA has not only recommended a chronic criteria of 5.2 ug/L, but also an acute criteria of 22 ug/L. We have adopted these acute 1 of 2 4/12/2007 4:05 PM Re: FW: MSD v. DWQ (OAH 06 EHR 2061)(NPDES Permi... criteria in our administrative code 15A NCAC 022 .0202 (1)(2). Acute criteria represent a maximum short-term exposure. Therefore, while we do allow a dilution factor when calculating limits based on chronic (long-term) exposure, we do not when acute criteria also apply. I couldn't find any procedural documents, but I did speak with Susan about this and she felt that the definition of "acute toxicity" that is listed in our rules supports our interpretation (lethality or other harmful effects due to short-term exposure) . Chrnni r, i-n,r; define( Let me Thanks Toya Sumptez I hac indic mattE immed an ap Thank Suean Susan A. Wi Supervisor, 1 (919) 733 - 1617 Mail St Raleigh, NC: 0 e W ATF-roc, North Carolina Department of Environment and Natural Resources Division of Water Quality (919) 733-5083 (a) 1617 Mail Service Center Raleigh, NC Fax: (919) 733-0719 2 of 2 4/12/2007 4:05 PM 11/09/2006 15:12 FAX 8282586999 ROBERTS-STEVENS Zoo' ROBERTS & STEVENS, P.A. ONE PACK SQUARE, SUITE 1100 (28801) POST OFFICE BOX 7647 ASHEVILLE, NORTH CAROLINA 28802 SENDER'S DIRECT LINE: (828) 258-6919 SENDER'S DIRECT FAX: (828) 210-6526 FACSIMILE TRANSMISSION COVER SHEET TOTAL NUMBER OF PAGES INCLUDING THIS COVER SHEET: (35 ) To: Office of Administrative Hearings 919/733-3478 cc: Mr. Alan Klimek 919/733-0719 From: Billy Clarke Date: November 9, 2006 Rc: Metropolitan Sewerage District of Buncombe County / Contested Case with NC Department of Environment and Natural Resources, Division of Water Quality Facsimile Operator: Sarah Hayden NOTICE: The information contained in this facsimile message is attorney privileged and confidential information intended only for the use of the individual or entity oanied above. If the reader of this message is not the intended recipient, you arc hereby notified that any dissemination, distribution or copy of this communication is strictly prohibited. If you have received this communication in error, please immediately notify us by telephone and return the original message to us at the above address via U.S. Postal Service. R&S 510954-1 11/09/2006 15:12 FAX 8282586999 ROBERTS-STEVENS j002 JOHN = r.TrVEN6 JAMES W WILLIAMS CARL W LOFTIN JOHN W MASON MARC AuOOw SHERYL H. WILLIAMS WILLIAM CLARKE vINCtNT 0 CHILORESS JR. MARJORIE ROWE MANN GREGORY 0 HUTCHINS JACKSON D. HAMILTON WATT 5. STEVENS MARK C. KUROYS JACOUELINC O. GRANT CHRICTOPNCR Z. CAMPBELL PATSY ORISON ROBERTS STEVENS ATTORNEYS AT Law DOar Ou.LOING ONE WEST PACK SQUARE. STE 1100 20001 POST OFFICE Box 76.117 ASHEVILLE. NORTH CAROLINA 28802 TCLCOHONE 10201 202-G00O FACSIMILE 18281 256 6955 uM1w.rl bertl.storel*S.eem Writer's Direct Phone No.: 828/258-6919 Writer's Direct Facsimile: 828/210-6526 Writer's E-mail: bclarkecrobcrts-stcvens.com November 9, 2006 Office of Administrative Hearings Clerk's Office 6714 Mail Service Center Raleigh, NC 27699-6714 OAVIO l ENOLISH CYNTHIA S GRADY P LACHICOTTC %ACH' ZEMP JR. KENNETH R HUNT DENNIS L MARTIN. JR I'CTCRf 0 MGCNIRC KEVIN P KOPP RE©ECCA JOHNSTON REINHARDT K. OCAN &HATLEY. 11 or COUN&CL LANOON Q0008? WALTER L CURRIe FRANK P. GRAHAM 17.►y • 20031 Via Facsimile: 919/733-3478 & US Mail Re: Metropolitan Sewerage District of Buncombe County / Contested Case with NC Department of Environment and Natural Resources, Division of Water Quality Dear Sir or Madam: Enclosed please find a Petition for Contested Case we are filing on behalf of the Metropolitan Sewerage District of Buncombe County. The original petition and 3 copies are being placed in the mail today. Copies of the Petition are being served on Alan Klimek, the Director of the Division of Water Quality, and Mary Penny Thompson, General Counsel to the Department of Environment and Natural Resources. Please return two file stamped copy to us in the envelope provided. Your cooperation and assistance are appreciated. Sincerely, ROBERTS & STEVENS, PA WC/sh Enclosures cc: Mr. Alan Klimek Ms. Mary Penny Thompson Mr. Tom Hartye, P.E. General Manager, MSD Mr. John Kivenimi, MSD R&S 510948-I 11/09/2006 15:13 FAX 8282586999 ROBERTS-STEVENS Z 003 STATE OF NORTH CAROLINA COUNTY OF BUNCOMBE METROPOLITAN SEWERAGE DISTRICT OF BUNCOMBE COUNTY PETITIONER, v. DIVISION OF WATER QUALITY, NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RESPONDENT. IN THE OFFICE OF ADMINISTRATIVE HEARINGS 06-EHR- PETITION FOR CONTESTED CASE NOW COMES the Metropolitan Sewerage District of Buncombe County ("MSD"), by and through counsel, and Petitions the Office of Administrative Hearings ("OAH") for a Contested Case Hearing on the matters set forth herein. In support of this Petition, MSD would show unto OAH the following: 1. MSD is a Metropolitan Sewerage District organized under Chapter 153 of the North Carolina General Statutes, now recodified as Article 5 of Chapter 162A, 2. MSD is comprised of all the incorporated municipalities in Buncombe County and certain unincorporated portions of Buncombe County. 3. MSD owns and operates, pursuant to an existing National Pollutant Discharge Elimination System ("NPDES") Permit (the "Existing Permit"), a Water Reclamation Facility (the "WRF") which collects, treats and discharges approximately 20 million gallons per day to the French Broad River. 4. The North Carolina Division of Water Quality ("DWQ") implements the NPDES program in North Carolina and issues NPDES Permits to MSD and other municipal and industrial dischargers. 5. By letter dated September 27, 2006, DWQ renewed NPDES Permit NC0024911 to MSD (the "Renewed Permit"). A copy of the letter and the proposed permit are attached hereto and incorporated herein by reference as Exhibit A. 6. By letter dated October 12, 2006, DWQ made corrections to NPDES Permit NC0024911. A copy of the letter is attached hereto and incorporated herein by reference as Exhibit B. R&tS 508727-1 11/09/2006 15:13 FAX 8282586999 ROBERTS-STEVENS 2004 7. The Renewed Permit includes an effluent limit for cyanide (Cn) of 22 micrograms per liter (parts per billion) effective May 1, 2008 and a requirement that MSD analyze its effluent weekly for the presence of Cn. 8. MSD samples the influent to its treatment plant on a periodic basis. MSD has never detected Cn in its influent. 9. MSD samples the effluent discharge from the WRF on a daily basis. At least twice a month, the effluent sample is analyzed for Cn. Over the last four years, there were limited/episodic detections of Cn with only a few high values and no apparent pattern. 10. There are a limited number of users of the MSD Sewerage System who use Cn in their processes. The amount of Cn these users are allowed to discharge is regulated by permits issued by MSD. Compliance with these permits is regulated by industrial self -monitoring and by the MSD Industrial Waste Section. All dischargers of Cn have been in compliance with the limits in their permits for the relevant period. 11. MSD has developed and is implementing an eighteen month study to attempt to locate the source of the Cn. MSD began the study in August, 2006 and will report the study results to DWQ, 12. MSD does not believe there is sufficient evidence or basis to include a Cn limit in the Renewed Permit. 13. MSD does not believe there is sufficient evidence or reasonable basis to include a limit of 22 parts per billion for Cn in the Renewed Permit. The limit is based on DWQ's inputting of the highest Cn data points from 2003 — 2005 in the Reasonable Potential Model resulting in an extraordinarily stringent standard. This standard also ignores any mixing/dilution of the effluent from the WRF. 14. Effluent from the WRF goes first into the hydroelectric flume where it undergoes significant mixing prior to entering the French Broad River. MSD is precluded by the US Fish and Wildlife Service from considering the water in the flume as water of the river. 15. MSD objects to the weekly monitoring requirement in the Renewed Permit as it will impose additional collection, monitoring and reporting costs, 16. Inclusion of the limit in the Renewed Permit would impose a significant hardship on MSD in the form of additional monitoring, analysis and reporting. The proposed standard is unnecessarily stringent and so close to the practical quantization limit that there is a significant possibility of non-compliance based on laboratory error and imperfections in analytical instruments. Non compliance with the proposed limit could result in fines and penalties and other issues related to long term non compliance. R&S 508727-1 11/09/2006 15:13 FAX 8282586999 ROBERTS-STEVENS O005 17. MSD believes DWQ acted erroneously, arbitrarily and capriciously and exceeded its authority under the law in issuing the Renewed Permit with the Cn limit of 22 micrograms per liter and the increased monitoring and analysis requirement for Cn. WHERERFORE, MSD respectfully requests the Office of Administrative Hearing that 1, This matter be assigned to an Administrative Law Judge for a Contested Case Hearing. 2. That the Renewed Permit be issued without the Cn limit and the increased monitoring requirement for Cn. 3. That MSD be allowed to proceed with its eighteen month study to determine, if possible, the source of the Cn in its effluent, 4. That the parties be allowed to proceed with discovery in this matter This the day of November, 2006. ROBERTS & STEVENS, P.A. WILLIAM CL Attorneys for Petitioner P.O. Box 7647 Asheville, NC 28802 (828) 252-6600 NC State Bar No. 10278 R&S 5Q8727- I 11/09/2006 15:13 FAX 8282586999 ROBERTS-STEVENS v Z 006 CERTIFICATE OF SERVICE The undersigned hereby certifies that a true copy of the foregoing Petition for Contested Case was served upon the Respondents and/or persons indicated below in this contested case by facsimile and/or electronic mail to the number and/or e-mail address indicated below and by placing a copy thereof in the United States Mail, postage prepaid, addressed as follows: Mr. Alan Klimeck, P.E. Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Facsimile: 919/733-0719 This the ay of November, 2006. Ms. Mary Penny Thompson General Counsel 1601 Mail Service Center Raleigh, NC 27699-1601 E-mail: mary.p.thompson@ncmail.net William Clarke Attorney for Petitioner R&S 508727-1 State of Worth Carolina Department of Justice ROY COOPER 42 North French Broad Avenue Attorney General Asheville, NC 28801 -- MEMORANDUM -- TO: Susan Wilson Supervisor, Western NPDES Group DENR/DWQ FROM: Sueanna P. Sumpter Assistant Attorney General DATE: 27 December 2007 SUBJECT: MSD v. DENR/DWQ OAH file no. 06 EHR 2061 NPDES permit no. NC0024911 JAN 22008 �F F I�iR �._n •:u ..�ii Western Office Phone: (828) 251-6083 Fax: (828) 251-6338 ATTORNEY -CLIENT COMMUNICATION Privileged and Not Public Record I am enclosing for your signature two originals and one copy of the Consent Agreement and Settlement we previously negotiated with MSD. Please return both originals to me in the enclosed self- addressed envelope. The enclosed copy is for your records. I will later forward a fully -executed copy, along with a copy of the petitioner's notice of withdrawal to you for your file. Please note that we will need to issue the revised permit upon full execution of the agreement. MSD has requested that this be sent directly to Tom Hartye. Thanks, and please call me if you have any questions about this matter. SPS Enclosures STATE OF NORTH CAROLINA =( BAN 2 ay IN THE OFFICE OF ADMINISTRATIVE HEARINGS COUNTY OF BUNCOMBE 06 EHR 2061 Metropolitan Sewerage District of Buncombe County, Petitioner, NC Department of Environment and Natural Resources, Division of Water Quality, Respondent. CONSENT AGREEMENT AND SETTLEMENT The petitioner, Metropolitan Sewerage District of Buncombe County ("MSD"), and the respondent, North Carolina Department of Environment and Natural Resources, Division of Water Quality ("DWQ"), hereby enter into this Consent Agreement and Settlement ("Agreement") in order to resolve matters in controversy between them pursuant to N.C.G.S. § 150B-31(b). This above -captioned matter arose out of the 27 September 2006 renewal by the respondent of NPDES Permit NC0024911 ("the permit"), held by the petitioner. The permit authorizes the petitioner to operate a 40 MGD wastewater treatment system at its Water Reclamation Facility, and to discharge treated wastewater from that facility into the French Broad River at a specified location. The permit includes effluent limitations and monitoring conditions for various parameters and constituents of concern, including Cyanide. The renewal permit included a daily maximum effluent limit of 22 micrograms per liter (ug/1) and requires weekly monitoring for Cyanide. This limit was to take effect 1 May 2008, to allow the petitioner an opportunity to conduct a study and determine the source of high readings previously reported for this parameter. MSD commenced the above -captioned contested case to challenge the cyanide limit. The parties subsequently engaged in settlement negotiations and developed a draft amended permit which is agreeable to both. Therefore, without any trial of fact or law in the above - styled matter, THE PARTIES AGREE THAT: 1. The daily maximum effluent limit for cyanide (22 ug/1) will remain in the subject permit, but will not take effect until two (2) years following full execution of this Agreement. 2. During the same two (2) - year period, MSD will complete a study of its wastewater collection system and treatment facility to determine the source(s) of the cyanide previously detected in the treatment plant effluent. The study would include, but not be limited to, consideration of the waste stream coming from the incinerator scrubber water. In designing and implementing this study, MSD will solicit the assistance of staff in DWQ's laboratory certification section and/or their counterparts in EPA Region IV, -2- concerning procedures for sampling and preservation of samples. 3. During the same two (2) - year period, MSD reserves the right, pursuant to 15A N.C. Admin. Code 2B .0211, to work with appropriate staff in DWQ to develop a site -specific limit for cyanide, and will submit to DWQ the results of its study, along with any other relevant information, in attempting to develop such a limit. DWQ will consider any such request, review the supporting data submitted, and act upon it as required and/or allowed by law. 4. MSD reserves the right to request, at the conclusion of the same two (2) - year period, that DWQ remove from its permit the effluent limit for cyanide. Any such request shall be supported by a minimum of twenty-four (24) consecutive months of data which MSD contends demonstrates that the permitted facility and discharge have no reasonable potential for causing an exceedance of water quality standards for cyanide. DWQ agrees to consider any such request, review the supporting data submitted, and act upon it as required and/or allowed by law. 5. The parties understand and agree that, at the expiration of the two-year period following full execution of this Agreement, one of the following will occur in accordance with the preceding paragraphs: (a) the daily maximum cyanide limit specified in paragraph one (1) , above, will take effect; or (b) a site -specific daily maximum cyanide limit will be developed for petitioner's -3- facility as provided in paragraph three (3) , above, and that limit will take effect; or (c) the cyanide limit will be removed from petitioner's permit due to a sufficient showing by the petitioner as described in paragraph four (4), above, that the permitted facility and discharge have no reasonable potential for causing an exceedance of water quality standards for cyanide. 6. Within ten (10) days following full execution of this Agreement, and subject to its terms and conditions, the respondent, DWQ, agrees to issue to the petitioner, MSD, an amended renewal permit containing the same terms and conditions as the draft permit developed and agreed to by the parties. A copy of the draft is attached to this Agreement, marked "Exhibit A," and incorporated by reference herein. 7. By execution of this Agreement, and subject to its terms and conditions, MSD accepts and agrees not to challenge the terms and conditions of the amended renewal permit, Exhibit A hereto. 8. MSD explicitly waives its right to a contested case hearing in this matter and additionally agrees to withdraw its petition for contested case hearing previously filed with the Office of Administrative Hearings in the above -captioned matter. Petitioner shall file a notice of withdrawal of request for contested case hearing within ten (10) days following full execution of this Agreement. -4- FOR THE PETITIONER: METROPOLITAN SEWERAGE DISTRICT OF BUNCOMBE COUNTY / 2 ar/o ROBERTS & STEVENS, Attorpeys for William Clarke P.O. Box 7647 Asheville NC 28802 Date: /t-' /7/07 P.A. itioner FOR THE RESPONDENT: NC DENR, DIVISION OF WATER QUALITY ©i ;, �s N c77 Susan Wilson, Supervisor Western NPDES Program Date: ROY COOPER Attorney General Sueanna P. Sumpter Assistant Attorney General NC Department of Justice 42 N. French Broad Avenue Asheville NC 28801 Date: