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NCG030711_MONITORING REPORT_20200922
t Robert Bosch, LLC 1980 Indian Creek Lincolnton, North Carolina 28092 NCG030711 September 151h, 2020 Attn: DEMLR Division of Energy, Mineral & Land Resources 1612 Mail Service Center Raleigh, North Carolina 27699-1612 Dear Zahid Khan, RECE/VED La OENR-OEMI_R `viooresvilleunlify Sectio1� Regional C)ffice The Robert Bosch, LLC (Bosch) facility located at 1980 Indian Creek is currently in Tier 11 status for exceedances in Zinc (0.149 mg/1) at Outfall #3, Copper (0.0199 mg/L) at Outfall # 1, and pH at Outfalls # 1 and #3 (5.8). Therefore, Bosch is collecting samples and completing monthly analytical monitoring at Outfalls # 1 and #3 for all parameters as well as three (3) off -site locations (off -site locations #1,#2, and #3). Off -site location #1 is located up gradient and 0.3 miles to the north, off -site location #2 is located up gradient and 0.1 miles to the north, and off -site location #3 is located up gradient and 0.1 miles to the northeast of the facility. The results from monitoring these off -site locations have shown similar exceedances in Zinc (0.131 mg/1), Copper (0.0139 mg/1), and pH (5.2). Based on the determination that these exceedances are prevalent in the natural background monitoring, Bosch is requesting the release of tier two status and monthly analytical monitoring and to resume the semi-annual analytical and qualitative monitoring status. Analytical monitoring results and pH testing reports of the outfalls subject to tier two status as well as the off -site locations are provided as enclosures. For questions, please contact me at either (704) 691-8636 or at Kasev.Wattley(ao7,us.bosch.com. Sincerely, Kasey Wattley Health, Safety, & Environmental Coordinator Robert Bosch, LLC Enclosures; July 08, 2020 Results August 11, 2020 Results September 09, 2020 Results Stormwater pH Testing Report 8-3-2020 Stormwater pH Testing Report 8-31-2020 eiL 5-tormwater pH Testing Report Requestor: Owner: Document Document Revision PT -AC Number: Controller: Type: Date: Jordie Nicole Nicole Form July-27-2020 Promislow McQueen McQueen Facility Name: Robert Bosch Tool Corporation Permit Number: NCGO030711 Sample Location: 1980 Indian Creek Road, Lincointon, North Carolina, 28092 pH Meter: Dr. Meter pH-100 meter M-Date: 200206007 See Lct-HSE-WI-0016 for instruction on calibrating the pH meter and measuringow? Calibration BOSCH Invented for life Date: "�Analyst's Name: Jj c, i CAt PC - U I Y) I s � V, /11c, Meter Calibration Check Standard Buffer Buffers @ 250C Prepared Date Prepared Time Calibrated Time Temperature Actual pH pH Reading 6.86 25 A I i-v 2v Ate, czm '61, wyt 22 4.00 )�Cl 1 A 1` kx pH is based on temperature, check back of buffer packet for pH based on temperature. 9.18 If W-Y-, Check standard buffer reading must be within 0.1 S.U. r#j,1=. im I Analyst's Name: I ') � i & Q- V \ 0,m \- z) Sample Name Date Time Sampled Time Tested Temperature pH Reading [0.01 S.U.]* pH Reported [0.1 S.U.]** Clutfall 1 `3 -,T1 y) oco 2 il (0 Clutfall 2 -------- - - - Clutfall 3 <C3 :",k -, �CFy, � 5 2 '1 C- C, 5 Clutfall 4 Offsite 1 li, Offsite 2 Offsite 3 1 j 12-010 i')'i I -oC "1 1 W,0 'A \ko oji,, 4Z 3'C Ambient Rainwater �!)J- (A, 1A osf� 1 1-1 5 �6 *pH meter reading is to the hundredth decimal place **pH is reported to nearest tenth decimal place Will complete pH readings at Robert Bosch Tool Corporation and surrounding areas therefore do not need to complete post -analysis calibration verification because there will not be multiple sample sites. Data Qualifiers if applicable (anything that was different from sampling procedure): h CIA cX\ f N tics �W l i w," ` - - {� $ ` ., -. � `� f 1 aJ f Analyst's Signature �f Date t®rmwater pH Testing Report Requestor: Owner: Document Document Revision PT -AC Number: Controller: Type: Date: Jordie Nicole Nicole Form July-27-2020 Promislow McQueen McQueen BOSCH j Invented for life Facility Name: Robert Bosch Tool Corporation Permit Number: NCGO030711 „� f �.�z � Sample Location: 1980 Indian Creek Road Lincolnton North Carolina 28092 '1' pH Meter: Dr. Meter pH-100 meter M-Date: 200206007 (10 See Lct-HSE-WI-0016 for instruction on calibrating the pH meter and measuring puzp�y�?o iod,c� g Calibration cf. Date: Analyst's Name: r , Meter Calibration Check Standard Buffer Buffers @ 25°C Prepared Date Prepared Time Calibrated Time Temperature Actual pH pH Reading 6.86 i 121 i t "� 1,� ui, pH is based on temperature, check back of buffer packet for pH based on temperature. A "2:iI �' vs Check standard buffer reading must be within 0.1S.U. malill-TT-MUMI Analyst's Name: I jov-aov— �'- 'V- t-cr , , Sample Name Date Time Sampled p Time Time Temperature pH Reading [0.01 S.U.] * pH Reported [0.1 S.U.] ** Outfall1 , Outfall2 Outfall 3 OU2 ` ,. Outfall 4 _ Offsite 1 3 '.'} vriN `_ 1A om Offsite 2 C 4 i Offsite 3 t 3 t7 6 , `` 0 Rainwater tY� € F *pH meter reading is to the hundredth decimal place **pH is reported to nearest tenth decimal place I Stormwater pH Testing Report Requestor: Owner: Document Document Revision PT -AC Number: Controller: Type: Date: Jordie Nicole Nicole Form July-27-2020 Promislow McQueen McQueen BOSCH Invented for life Based on the ambient rainwater pH the benchmark range is r = CA `)(W P0 ' Will complete pH readings at Robert Bosch Tool Corporation and surrounding areas therefore do not need to complete post -analysis calibration verification because there will not be multiple sample sites. Data Qualifiers if applicable (anything that was different from sampling procedure): Analyst's Signature Date (�IaneAnalXica(' www.pacelab3.cem July 08, 2020 Glenn Magley Heritage Environmental 7901 W Morris St Indianapolis, IN 46231 RE: Project: RBTC STORMWATER Pace Project No.: 92484086 Dear Glenn Magley: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on June 30, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely,--� Taylor Ezell taylor.ezell@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pagel of 44 acmnalytical www.pacelabs.com Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 KinceyAve. Suite 1o0 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services Charlotte 9800 KinceyAve. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 44 aceAnalytical www,pecolabs.com SAMPLE ANALYTE COUNT Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92484086001 OUTFALL 1 EPA 1664E WAM 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C SMK 1 PASI-A 92484086002 OUTFALL 3 EPA 1664B WAM 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 JNS 1 PASI-A EPA 9040C SMK 1 PASI-A 92484086003 OFFSITE 1 EPA 1664E WAM 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624A SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C SMK 1 PASI-A 92484086004 OFFSITE 2 EPA 1664E WAM 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 2540D-2011 RED 1 PASI-A EPA 9040C SMK 1 PASI-A 92484086006 OFFSITE 3 EPA 1664B WAM 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C SMK 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 44 laneAnalj&al www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 1 Parameters Lab ID: 92484086001 Collected: 06/28/20 16:00 Results Units Report Limit DF Received: 06/30/20 12:40 Matrix: Water Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 07/02/20 10:03 608 PCB Pest RVE Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte Aldrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 309-00-2 alpha-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 319-84-6 beta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 319-85-7 delta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 58-89-9 Chlordane (Technical) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 57-74-9 alpha -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 5103-71-9 gamma -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 5103-74-2 4,4'-DDD ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 72-54-8 4,4'-DDE ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 72-55-9 4,4'-DDT ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 50-29-3 Dieldrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 60-57-1 Endosulfan I ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 959-98-8 Endosulfan II ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 33213-65-9 Endosulfan sulfate ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 1031-07-8 Endrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 72-20-8 Endrin aldehyde ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 7421-93-4 Heptachlor ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 76-44-8 Heptachlor epoxide ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:11 1024-57-3 PCB-1016 (Aroclor 1016) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 11096-82-5 L1 PCB, Total ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 1336-36-3 Toxaphene ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:11 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 70 % 10-130 1 07/02/20 20:12 07/07/20 17:11 877-09-8 Decachlorobiphenyl (S) 37 % 10-130 1 07/02/20 20:12 07/07/20 17:11 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper 6.3 ug/L 5.0 1 07/01/20 01:47 07/01/20 23:05 7440-50-8 Lead ND ug/L 5.0 1 07/01/20 01:47 07/01/20 23:05 7439-92-1 Zinc 89.8 ug/L 10.0 1 07/01/20 01:47 07/01/20 23:05 7440-66-6 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 44 aceAnalytical ", www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Project No.: 92484086 Sample: OUTFALL 1 Lab ID: 92484086001 Collected: 06/28120 16:00 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 208-96-8 Anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 91-58-7 2-Chlorophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 7005-72-3 Chrysene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 120-83-2 Diethylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 105-67-9 Dimethylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 07/01/20 11:25 07/02/20 21:43 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 07/01/20 11:26 07/02/20 21:43 117-81-7 Fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 206-44-0 Fluorene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 77-47-4 Hexachloroethane ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 193-39-5 Isophorone ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 78-59-1 Naphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 91-20-3 Nitrobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 98-95-3 2-Nitrophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 88-75-5 4-Nitrophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 108-60-1 Pentachlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 44 Pace Analytical Services, LLC laneAnalj&al ® 9800 KinceyAve. Suite 100 Huntersville, NC 28078 www.pacela6s.com (704)875-9092 ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Sample: OUTFALL 1 Lab ID: 92484086001 Collected: 06/28/20 16:00 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 85-01-8 Phenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 108-95-2 Pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 129-00-0 1,2,4-Trichoorobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 21:43 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 21:43 88-06-2 Surrogates Nitrobenzene-d5 (S) 69 % 10-120 1 07/01/20 11:25 07/02/20 21:43 4166-60-0 2-Fluorobiphenyl(S) 55 % 15-120 1 07/01/20 11:25 07/02/20 21:43 321-60-8 Terphenyl-d14 (S) 104 % 11-131 1 07/01/20 11:25 07/02/20 21:43 1718-51-0 Phenol-d6 (S) 37 % 10-120 1 07/01/20 11:25 07/02/20 21:43 13127-88-3 2-Fluorophenol (S) 41 % 10-120 1 07/01/20 11:25 07/02/20 21:43 367-12-4 2,4,6-Tribromophenol (S) 81 % 10-137 1 07/01/20 11:25 07/02/20 21:43 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 07/01/20 14:06 71-43-2 Bromodichloromethane ND ug/L 2.0 1 07/0112014:06 75-27-4 Bromoform ND ug/L 2.0 1 07/01/20 14:06 75-25-2 Bromomethane ND ug/L 2.0 1 07/01/20 14:06 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 07/01/20 14:06 56-23-5 Chlorobenzene ND ug/L 2.0 1 07/01/20 14:06 108-90-7 Chloroethane ND ug/L 2.0 1 07/01/20 14:06 75-00-3 Chloroform ND ug/L 2.0 1 07/01/20 14:06 67-66-3 Chloromethane ND ug/L 2.0 1 07/01/20 14:06 74-87-3 Dibromochloromethane ND ug/L 2.0 1 07/01/20 14:06 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 07/01/20 14:06 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 07/01/20 14:06 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 07/01/20 14:06 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 07/01/20 14:06 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 07/01/20 14:06 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 07/01/20 14:06 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 14:06 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 14:06 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 07/01/20 14:06 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 14:06 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 14:06 10061-02-6 Ethylbenzene ND ug/L 1.0 1 07/01/20 14:06 100-41-4 Methylene Chloride ND ug/L 2.0 1 07/01/20 14:06 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 07/01/20 14:06 79-34-5 Tetrachloroethene ND ug/L 2.0 1 07/01/20 14:06 127-18-4 Toluene ND ug/L 1.0 1 07/01/20 14:06 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 07/01/20 14:06 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 07/01/20 14:06 79-00-5 Trichloroethene ND ug/L 2.0 1 07/01/20 14:06 79-01-6 Trichloroiluoromethane ND ug/L 2.0 1 07/01/20 14:06 75-69-4 Vinyl chloride ND ug/L 2.0 1 07/01/20 14:06 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 44 (� aceAnalXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92484086 Sample: OUTFALL 1 Lab ID: 92484086001 Collected: 06/28/20 16:00 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 Toluene-d8 (S) 100 % 70-130 1 1,2-Dichloroethane-d4 (S) 92 % 70-130 1 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 2.5 mg/L 2.5 1 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 5.0 Sid. Units 0.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. 07/0112014:06 460-00-4 HS 07/01/2014:06 2037-26-5 07/01 /20 14:06 17060-07-0 07/01 /20 16:50 07/05/2013:34 H3 Page 7 of 44 aceAnalytical www.pacolabs.com I Project: RBTC STORMWATER Pace Project No.: 92484086 Sample: OUTFALL 3 Parameters 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 PCB Pest RVE Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) alpha -Chlordane gamma -Chlordane 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) PCB, Total Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 626 RVE Acenaphthene Date: 07/08/2020 08:47 AM Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Lab ID: 92484086002 Collected: 06/28/20 16:06 Received: 06/30/20 12:40 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Analytical Method: EPA 1664E Pace Analytical Services - Charlotte ND mg/L 5.0 1 07/02/2010:03 Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 309-00-2 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 319-84-6 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 319-85-7 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 319-86-8 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 58-89-9 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 57-74-9 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 5103-71-9 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 5103-74-2 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 72-54-8 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 72-55-9 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 50-29-3 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 60-57-1 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 959-98-8 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 33213-65-9 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 1031-07-8 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 72-20-8 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 7421-93-4 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 76-44-8 ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:26 1024-57-3 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 12674-11-2 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 11104-28-2 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 11141-16-5 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 53469-21-9 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 12672-29-6 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 11097-69-1 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 11096-82-5 L1 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 1336-36-3 ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:26 8001-35-2 30 % 10-130 1 07/02/20 20:12 07/07/20 17:26 877-09-8 18 % 10-130 1 07/02/20 20:12 07/07/20 17:26 2051-24-3 Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville 9.7 ug/L 5.0 1 07/01/20 01:47 07/01/20 23:14 7440-50-8 ND ug/L 5.0 1 07/01/20 01:47 07/01/20 23:14 7439-92-1 177 ug/L 10.0 1 07/01/20 01:47 07/01/20 23:14 7440-66-6 Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 83-32-9 H3 Qual REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 44 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Project No.: 92484086 Sample: OUTFALL 3 Lab ID: 92484086002 Collected: 06/28/20 16:06 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 208-96-8 H3 Anthracene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 120-12-7 H3 Benzo(a)anthracene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 56-55-3 H3 Benzo(a)pyrene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 50-32-8 H3 Benzo(b)fluoranthene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 205-99-2 H3 Benzo(g,h,i)perylene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 191-24-2 H3 Benzo(k)fluoranthene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 207-08-9 H3 4-Bromophenylphenyl ether ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 101-55-3 H3 Butylbenzylphthalate ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 85-68-7 H3 4-Chloro-3-methylphenol ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 59-50-7 H3 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 111-91-1 H3 bis(2-Chloroethyl) ether ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 111-44-4 H3 2-Chloronaphthalene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 91-58-7 H3 2-Chlorophenol ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 95-57-8 H3 4-Chlorophenylphenyl ether ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 7005-72-3 H3 Chrysene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 218-01-9 H3 Dibenz(a,h)anthracene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 53-70-3 H3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 91-94-1 H3 2,4-Dichlorophenol ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 120-83-2 H3 Diethylphthalate ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 84-66-2 H3 2,4-Dimethylphenol ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 105-67-9 H3 Dimethylphthalate ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 131-11-3 H3 Di-n-butylphthalate ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 84-74-2 H3 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 06/30/20 21:63 07/02/20 18:48 534-52-1 H3 2,4-Dinitrophenol ND ug/L 50.0 1 06/30/20 21:53 07/02/20 18:48 51-28-5 H3 2,4-Dinitrotoluene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 121-14-2 H3 2,6-Dinitrotoluene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 606-20-2 H3 Di-n-octylphthalate ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 117-84-0 H3 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 117-81-7 H3 Fluoranthene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 206-44-0 H3 Fluorene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 86-73-7 H3 Hexachloro-1,3-butadiene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 87-68-3 H3 Hexachlorobenzene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 118-74-1 H3 Hexachlorocyclopentadiene ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 77-47-4 H3 Hexachloroethane ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 67-72-1 H3 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 193-39-5 H3 Isophorone ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 78-59-1 H3 Naphthalene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 91-20-3 H3 Nitrobenzene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 98-95-3 H3 2-Nitrophenol ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 88-75-5 H3 4-Nitrophenol ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 100-02-7 H3 N-Nitrosodimethylamine ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 62-75-9 H3 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 621-64-7 H3 N-Nitrosodiphenylamine ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 86-30-6 H3 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 108-60-1 H3 Pentachlorophenol ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 87-86-5 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 44 acmnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 3 Parameters Lab ID: 92484086002 Collected: 06/28/20 16:06 Results Units Report Limit DF Received: 06/30/20 12:40 Matrix: Water Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 85-01-8 H3 Phenol ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 108-95-2 H3 Pyrene ND ug/L 5.0 1 06/30/20 21:53 07/02/20 18:48 129-00-0 H3 1,2,4-Trichlorobenzene ND ug/L 5.0 1 06/30/20 21:53 07/0212018:48 120-82-1 H3 2,4,6-Trichlorophenol ND ug/L 10.0 1 06/30/20 21:53 07/02/20 18:48 88-06-2 H3 Surrogates Nitrobenzene-d5 (S) 64 % 10-120 1 06/30/20 21:53 07/02/20 18:48 4165-60-0 2-Fluorobiphenyl (S) 58 % 15-120 1 06/30/20 21:53 07/02/20 18:48 321-60-8 Terphenyl-d14 (S) 75 % 11-131 1 06/30/20 21:53 07/02/20 18:48 1718-51-0 Phenol-d6 (S) 39 % 10-120 1 06/30/20 21:53 07/02/20 18:48 13127-88-3 2-Fluorophenol (S) 46 % 10-120 1 06/30/20 21:53 07/02/20 18:48 367-12-4 2,4,6-Tribromophenol (S) 85 % 10-137 1 06/30/20 21:53 07/02/20 18:48 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 07101/2014:24 71-43-2 Bromodichloromethane ND ug/L 2.0 1 07/01/20 14:24 75-27-4 Bromoform ND ug/L 2.0 1 07/01/20 14:24 75-25-2 Bromomethane ND ug/L 2.0 1 07/01/20 14:24 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 07/01/20 14:24 56-23-5 Chlorobenzene ND ug/L 2.0 1 07/01/20 14:24 108-90-7 Chloroethane ND ug/L 2.0 1 07/0112014:24 75-00-3 Chloroform ND ug/L 2.0 1 07/01/20 14:24 67-66-3 Chloromethane ND ug/L 2.0 1 07/0112014:24 74-87-3 Dibromochloromethane ND ug/L 2.0 1 07/01/20 14:24 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 07/01/20 14:24 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 07/01/20 14:24 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 07/01/20 14:24 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 07/01/20 14:24 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 07/01/20 14:24 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 07/01/20 14:24 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 14:24 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 14:24 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 07/01/20 14:24 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 14:24 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 14:24 10061-02-6 Ethylbenzene ND ug/L 1.0 1 07/01/20 14:24 100-41-4 Methylene Chloride ND ug/L 2.0 1 07/01/20 14:24 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 07/01/20 14:24 79-34-5 Tetrachloroethene ND ug/L 2.0 1 07/01/20 14:24 127-18-4 Toluene ND ug/L 1.0 1 07/01/20 14:24 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 07/01/20 14:24 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 07101/2014:24 79-00-5 Trichloroethene ND ug/L 2.0 1 07/01/20 14:24 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 07/01/20 14:24 75-69-4 Vinyl chloride ND ug/L 2.0 1 07/01/20 14:24 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 44 aceAna1j&a1 www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92484086 Sample: OUTFALL 3 Lab ID: 92484086002 Collected: 06/28/20 16:06 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 2540D Total Suspended Solids Total Suspended Solids 9040 pH pH at 25 Degrees C Date: 07/08/2020 08:47 AM Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte 99 % 70-130 1 07/01/2014:24 460-00-4 HS 100 % 70-130 1 07/01/2014:24 2037-26-5 92 % 70-130 1 07/01/2014:24 17060-07-0 Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville 4.3 mg/L 2.5 1 07/01/2016:51 Analytical Method: EPA 9040C Pace Analytical Services - Asheville 4.7 Std. Units 0.10 1 07/05/20 13:45 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 44 QD leAna1j4iea1 www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Sample: OFFSITE 1 Parameters Lab ID: 92484086003 Collected: 06/28/20 15:30 Results Units Report Limit DF Received: 06/30/20 12:40 Matrix: Water Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 07/06/20 08:40 608 PCB Pest RVE Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte Aldrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 309-00-2 alpha-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 319-84-6 beta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 319-85-7 delta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 58-89-9 Chlordane (Technical) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 57-74-9 alpha -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 5103-71-9 gamma -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 5103-74-2 4,4'-DDD ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 72-54-8 4,4'-DDE ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 72-55-9 4,4'-DDT ND ug/L 0,050 1 07/02/20 20:12 07/07/20 17:41 50-29-3 Dieldrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 60-57-1 Endosulfan I ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 959-98-8 Endosulfan II ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 33213-65-9 Endosulfan sulfate ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 1031-07-8 Endrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 72-20-8 Endrin aldehyde ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 7421-93-4 Heptachlor ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 76-44-8 Heptachlor epoxide ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:41 1024-57-3 PCB-1016 (Aroclor 1016) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 11096-82-5 L1 PCB, Total ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 1336-36-3 Toxaphene ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:41 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 87 % 10-130 1 07/02/20 20:12 07/07/20 17:41 877-09-8 Decachlorobiphenyl (S) 67 % 10-130 1 07/02/20 20:12 07/07/20 17:41 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper 6.9 ug/L 5.0 1 07/01/20 01:47 07/01/20 23:18 7440-50-8 Lead ND ug/L 5.0 1 07/01/20 01:47 07/01/20 23:18 7439-92-1 Zinc 63.9 ug/L 10.0 1 07/01/20 01:47 07/01/20 23:18 7440-66-6 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, I.I.C. Page 12 of 44 aceAna1j&a1 www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92484086 Sample: OFFSITE 1 Lab ID: 92484086003 Collected: 06/28/20 15:30 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 626.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 208-96-8 Anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 91-58-7 2-Chlorophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 7005-72-3 Chrysene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 120-83-2 Diethylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 105-67-9 Dimethylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 131-11-3 Di-n-butylphthalate ND ug/L 6.0 1 07/01/20 11:25 07/02/20 22:12 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 07/01/20 11:25 07/02/20 22:12 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 117-81-7 Fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 206-44-0 Fluorene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 77-47-4 Hexachloroethane ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 193-39-5 Isophorone ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 78-59-1 Naphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 91-20-3 Nitrobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 98-95-3 2-Nitrophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 88-75-5 4-Nitrophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 108-60-1 Pentachlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 44 lacmnalyticalv www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 7 Parameters Lab ID: 92484086003 Collected: 06/28/20 15:30 Results Units Report Limit DF Received: 06/30/20 12:40 Matrix: Water Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 85-01-8 Phenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 108-95-2 Pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:12 129-00-0 1,2,4-Trichoorobenzene ND ug/L 5.0 1 07101/2011:25 07/02/20 22:12 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:12 88-06-2 Surrogates Nitrobenzene-d5 (S) 74 % 10-120 1 07/01/20 11:25 07/02/20 22:12 4165-60-0 2-Fluorobiphenyl (S) 59 % 15-120 1 07/01/20 11:25 07/02/20 22:12 321-60-8 Terphenyl-d14 (S) 109 % 11-131 1 07/01/20 11:25 07/02/20 22:12 1718-51-0 Phenol-d6 (S) 44 % 10-120 1 07/01/20 11:25 07/02/20 22:12 13127-88-3 2-Fluorophenol (S) 47 % 10-120 1 07/01/20 11:25 07/02/20 22:12 367-12-4 2,4,6-Tribromophenol (S) 91 % 10-137 1 07/01/20 11:25 07/02/20 22:12 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 07/01/20 15:17 71-43-2 Bromodichloromethane ND ug/L 2.0 1 07/01/20 15:17 75-27-4 Bromoform ND ug/L 2.0 1 07/01/20 15:17 75-25-2 Bromomethane ND ug/L 2.0 1 07/01/20 15:17 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 07/01/20 15:17 56-23-5 Chlorobenzene ND ug/L 2.0 1 07101/2015:17 108-90-7 Chloroethane ND ug/L 2.0 1 07/01/20 15:17 75-00-3 Chloroform ND ug/L 2.0 1 07/01/20 15:17 67-66-3 Chloromethane ND ug/L 2.0 1 07/01/20 15:17 74-87-3 Dibromochioromethane ND ug/L 2.0 1 07/01/20 15:17 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 07/01/20 15:17 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 07/0112015:17 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 07/01/20 15:17 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 07101/2015:17 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 07/01/20 15:17 107-06-2 1,1-Dichioroethene ND ug/L 2.0 1 07/01/20 15:17 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 15:17 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 15:17 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 07101/2015:17 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 15:17 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 15:17 10061-02-6 Ethylbenzene ND ug/L 1.0 1 07/01/20 15:17 100-41-4 Methylene Chloride ND ug/L 2.0 1 07/01/20 15:17 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 07/01/20 15:17 79-34-5 Tetrachloroethene ND ug/L 2.0 1 07/01/20 15:17 127-18-4 Toluene ND ug/L 1.0 1 07/01/20 15:17 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 07/01/20 15:17 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 07/01/20 15:17 79-00-5 Trichloroethene ND ug/L 2.0 1 07/01/2016:17 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 07/01/20 15:17 75-69-4 Vinyl chloride ND ug/L 2.0 1 07/01/20 15:17 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, I.I.C. Page 14 of 44 lacieAnalyfical" www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 1 Lab ID: 92484086003 Collected: 06/28/20 15:30 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 Toluene-d8 (S) 100 % 70-130 1 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 48.8 mg/L 3.6 1 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 6.9 Std. Units 0.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. 07/01/2015:17 460-00-4 HS 07/01/2015:17 2037-26-5 07/01 /20 15:17 17060-07-0 07/01 /20 16:52 07/05/2013:56 H3 Page 15 of 44 Pace Analytical Services, LLC laneAnalyficalo 9800 KinceyAve. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Sample: OFFSITE 2 Lab ID: 92484086004 Collected: 06/28/20 15:39 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 07/06/20 08:40 608 PCB Pest RVE Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte Aldrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 309-00-2 alpha-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 319-84-6 beta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 319-85-7 delta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 58-89-9 Chlordane (Technical) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 57-74-9 alpha -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 6103-71-9 gamma -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 5103-74-2 4,4'-DDD ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 72-54-8 4,4'-DDE ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 72-55-9 4,4'-DDT ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 50-29-3 Dieldrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 60-57-1 Endosulfan I ND ug/L 0.050 1 07/02120 20:12 07/07/20 17:55 959-98-8 Endosulfan II ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:65 33213-66-9 Endosulfan sulfate ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 1031-07-8 Endrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 72-20-8 Endrin aldehyde ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 7421-93-4 Heptachlor ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 76-44-8 Heptachlor epoxide ND ug/L 0.050 1 07/02/20 20:12 07/07/20 17:55 1024-57-3 PCB-1016 (Aroclor 1016) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 11096-82-5 L1 PCB, Total ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 1336-36-3 Toxaphene ND ug/L 0.50 1 07/02/20 20:12 07/07/20 17:55 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 85 % 10-130 1 07/02/20 20:12 07/07/20 17:55 877-09-8 Decachlorobiphenyl (S) 62 % 10-130 1 07/02/20 20:12 07/07/20 17:55 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper 5.4 ug/L 5.0 1 07/01/20 01:47 07/01/20 23:21 7440-50-8 Lead ND ug/L 5.0 1 07/01/20 01:47 07/01/20 23:21 7439-92-1 Zinc 30.4 ug/L 10.0 1 07/01/20 01:47 07/01/20 23:21 7440-66-6 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 44 aceAnalytical www.pacelabs.cam I ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Project No.: 92484086 Sample: OFFSITE 2 Lab ID: 92484086004 Collected: 06/28/20 15:39 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 208-96-8 Anthracene ND ug/L 5.0 1 07101/2011:25 07/02/20 22:41 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 206-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 91-58-7 2-Chlorophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 7005-72-3 Chrysene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 120-83-2 Diethylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 105-67-9 Dimethylphthalate ND ug/L 6.0 1 07/01/20 11:25 07/02/20 22:41 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 07/01/20 11:25 07/02/20 22:41 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 117-81-7 Fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 206-44-0 Fluorene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 07/01/20 11:25 07102/2022:41 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 77-47-4 Hexachloroethane ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 193-39-5 Isophorone ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 78-59-1 Naphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 91-20-3 Nitrobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 98-95-3 2-Nitrophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 88-75-5 4-Nitrophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 108-60-1 Pentachlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 44 aceAnalytical e www.pscelabs,com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Sample: OFFSITE 2 Lab ID: 92484086004 Collected: 06/28/20 15:39 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 85-01-8 Phenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 108-95-2 Pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 22:41 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 22:41 88-06-2 Surrogates Nitrobenzene-d5 (S) 75 % 10-120 1 07/01/20 11:25 07/02/20 22:41 4165-60-0 2-Fluorobiphenyl (S) 60 % 15-120 1 07/01/20 11:25 07/02/20 22:41 321-60-8 Terphenyl-dl4 (S) 107 % 11-131 1 07/01/20 11:25 07/02/20 22:41 1718-51-0 Phenol-d6 (S) 46 % 10-120 1 07/01/20 11:25 07/02/20 22:41 13127-88-3 2-Fluorophenol (S) 56 % 10-120 1 07/01/20 11:25 07/02/20 22:41 367-12-4 2,4,6-Tribromophenol (S) 95 % 10-137 1 07/01/20 11:25 07/02/20 22:41 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 07/01/20 15:35 71-43-2 Bromodichloromethane ND ug/L 2.0 1 07/01/20 15:35 75-27-4 Bromoform ND ug/L 2.0 1 07/01/20 15:35 75-25-2 Bromomethane ND ug/L 2.0 1 07/01/20 15:35 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 07/01/20 15:35 56-23-5 Chiorobenzene ND ug/L 2.0 1 07/01/20 15:35 108-90-7 Chloroethane ND ug/L 2.0 1 07/01/20 15:35 75-00-3 Chloroform ND ug/L 2.0 1 07/01/20 15:35 67-66-3 Chloromethane ND ug/L 2.0 1 07/01/20 15:35 74-87-3 Dibromochioromethane ND ug/L 2.0 1 07/01/20 15:35 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 07/01/20 15:35 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 07/01/20 15:35 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 07/01/20 15:35 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 07/01/20 15:35 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 07/01/20 15:35 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 07/01/20 15:35 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 07101/2015:35 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 15:35 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 07/01/20 15:35 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 15:35 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 15:35 10061-02-6 Ethylbenzene ND ug/L 1.0 1 07/01/20 15:35 100-41-4 Methylene Chloride ND ug/L 2.0 1 07/01/20 15:35 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 07/01/20 15:35 79-34-5 Tetrachloroethene ND ug/L 2.0 1 07/01/20 15:35 127-18-4 Toluene ND ug/L 1.0 1 07/01/20 15:35 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 07/01/20 15:35 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 07/01/20 15:35 79-00-5 Trichloroethene ND ug/L 2.0 1 07/01/20 15:35 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 07/01/20 15:35 75-69-4 Vinyl chloride ND ug/L 2.0 1 07/01/20 15:35 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 44 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 2 Lab ID: 92484086004 Collected: 06/28/20 15:39 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 Toluene-d8 (S) 99 % 70-130 1 1,2-Dichloroethane-d4 (S) 92 % 70-130 1 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 40.4 mg/L 5.0 1 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 6.6 Std. Units 0.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. 07/01/2015:35 460-00-4 HS 07/01/2015:35 2037-26-5 07/01 /20 15:35 17060-07-0 07/01 /20 16:53 07/05/2014:02 H3 Page 19 of 44 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 3 lab ID: 92484086005 Collected: 06/28/20 15:49 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 07/06/20 08:40 608 PCB Pest FIVE Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte Aidrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 309-00-2 alpha-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 319-84-6 beta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 319-85-7 delta-BHC ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 58-89-9 Chlordane (Technical) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 57-74-9 alpha -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 5103-71-9 gamma -Chlordane ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 5103-74-2 4,4'-ODD ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 72-54-8 4,4'-DDE ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 72-55-9 4,4'-DDT ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 50-29-3 Dieldrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 60-57-1 Endosulfan I ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 959-98-8 Endosulfan II ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 33213-65-9 Endosulfan sulfate ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 1031-07-8 Endrin ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 72-20-8 Endrin aldehyde ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 7421-93-4 Heptachlor ND ug/L 0.060 1 07/02/20 20:12 07/07/20 18:10 76-44-8 Heptachlor epoxide ND ug/L 0.050 1 07/02/20 20:12 07/07/20 18:10 1024-57-3 PCB-1016 (Aroclor 1016) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 11096-82-5 L1 PCB, Total ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 1336-36-3 Toxaphene ND ug/L 0.50 1 07/02/20 20:12 07/07/20 18:10 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 82 % 10-130 1 07/02/20 20:12 07/07/20 18:10 877-09-8 Decachlorobiphenyl (S) 63 % 10-130 1 07/02/20 20:12 07/07/20 18:10 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper 6.6 ug/L 5.0 1 07/01/20 01:47 07/01/20 23:24 7440-50-8 Lead ND ug/L 5.0 1 07/01/20 01:47 07/01/20 23:24 7439-92-1 Zinc 51.9 ug/L 10.0 1 07/01/20 01:47 07/01/20 23:24 7440-66-6 626 RVE Analytical Method: EPA 626.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 44 aeeAnalydcal www.pecolobs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 3 Lab ID: 92484086005 Collected: 06/28/20 15:49 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 208-96-8 Anthracene ND ug/L 6.0 1 07/01/20 11:25 07/02/20 23:10 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 91-58-7 2-Chlorophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 7005-72-3 Chrysene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 07/01/2011:26 07/02/20 23:10 120-83-2 Diethylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 105-67-9 Dimethyiphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 07/01/20 11:25 07/02/20 23:10 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 117-81-7 Fluoranthene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 206-44-0 Fluorene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 77-47-4 Hexachloroethane ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 193-39-5 Isophorone ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 78-59-1 Naphthalene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 91-20-3 Nitrobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 98-95-3 2-Nitrophenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 88-75-5 4-Nitrophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 108-60-1 Pentachlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 44 aceftlytical www.pacelabs.com I ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 3 Lab ID: 92484086006 Collected: 06/28/20 15:49 Received: 06/30/20 12:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 85-01-8 Phenol ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 108-95-2 Pyrene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 129-00-0 1,2,4-Trichoorobenzene ND ug/L 5.0 1 07/01/20 11:25 07/02/20 23:10 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 07/01/20 11:25 07/02/20 23:10 88-06-2 Surrogates Nitrobenzene-d5 (S) 33 % 10-120 1 07/01/20 11:26 07/02/20 23:10 4165-60-0 2-Fluorobiphenyl (S) 26 % 15-120 1 07/01/20 11:25 07/02/20 23:10 321-60-8 Terphenyl-d14 (S) 73 % 11-131 1 07/01/20 11:25 07/02/20 23:10 1718-51-0 Phenol-d6 (S) 16 % 10-120 1 07/01/20 11:25 07/02/20 23:10 13127-88-3 2-Fluorophenol (S) 20 % 10-120 1 07/01/20 11:25 07/02/20 23:10 367-12-4 2,4,6-Tribromophenol (S) 39 % 10-137 1 07/01/20 11:25 07/02/20 23:10 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 07/01/20 15:53 71-43-2 Bromodichloromethane ND ug/L 2.0 1 07/01/20 15:53 75-27-4 Bromoform ND ug/L 2.0 1 07/01/20 15:53 75-25-2 Bromomethane ND ug/L 2.0 1 07/01/2016:53 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 07/01/20 15:53 56-23-5 Chlorobenzene ND ug/L 2.0 1 07/01/20 15:53 108-90-7 Chloroethane ND ug/L 2.0 1 07/01/20 15:53 75-00-3 Chloroform ND ug/L 2.0 1 07/01/20 15:53 67-66-3 Chloromethane ND ug/L 2.0 1 07/01/20 15:53 74-87-3 Dibromochloromethane ND ug/L 2.0 1 07/01/20 15:53 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 07/01/20 15:53 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 07/0112015:63 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 07/01/20 15:53 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 07/01/20 15:53 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 07/01/20 15:53 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 07/01/20 15:53 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 15:53 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 07/01/20 15:53 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 07/01/20 15:53 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 15:53 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 07/01/20 15:53 10061-02-6 Ethylbenzene ND ug/L 1.0 1 07/0112015:53 100-41-4 Methylene Chloride ND ug/L 2.0 1 07/01/20 15:53 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 07/01/20 15:53 79-34-5 Tetrachloroethene ND ug/L 2.0 1 07/01/20 15:53 127-18-4 Toluene ND ug/L 1.0 1 07/01/20 15:53 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 07/01/20 15:53 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 07/01/20 15:53 79-00-5 Trichloroethene ND ug/L 2.0 1 07/0112015:53 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 07/01/20 15:53 75-69-4 Vinyl chloride ND ug/L 2.0 1 07/01/20 15:53 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 44 lacieAnalyfica( www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 3 Parameters Lab ID: 92484086006 Collected: 06/28/20 15:49 Results Units Report Limit DF Received: 06/30/20 12:40 Matrix: Water Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 07/01/20 15:53 460-00-4 HS Toluene-d8 (S) 99 % 70-130 1 07/01/20 15:53 2037-26-5 1,2-Dichloroethane-d4 (S) 91 % 70-130 1 07/01/20 15:53 17060-07-0 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 15.1 mg/L 3.6 1 07/01/20 16:53 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 5.2 Std. Units 0.10 1 07/05/20 14:08 H3 Date: 07/08/2020 08:47 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 44 acmnalytical o, www.pacelabs.com i QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 550977 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92484086001, 92484086002 METHOD BLANK: 2928683 Matrix: Water Associated Lab Samples: 92484086001, 92484086002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L NO 5.0 07/02/20 10:03 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2928684 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 20 18.7 94 64-132 MATRIX SPIKE SAMPLE: 2928685 92483996001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L ND 20 22.9 108 64-132 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 44 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 551259 Analysis Method: EPA 1664B QC Batch Method: EPA 1664E Analysis Description: 1664 SGT-HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92484086003, 92484086004, 92484086005 METHOD BLANK: 2930301 Matrix: Water Associated Lab Samples: 92484086003, 92484086004, 92484086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 5.0 07/06/20 08:40 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2930302 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 20 16.4 82 64-132 MATRIX SPIKE SAMPLE: 2930303 92484258001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L ND 20 20.5 82 64-132 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 44 leAnaljftal www.pecolobs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 550616 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 METHOD BLANK: 2927216 Matrix: Water Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper ug/L ND 5.0 07/01/20 22:10 Lead ug/L NO 5.0 07/01/20 22:10 Zinc ug/L ND 10.0 07/01/20 22:10 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2927217 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper ug/L 500 518 104 85-115 Lead ug/L 600 514 103 85-115 Zinc ug/L 500 491 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927218 2927219 MS MSD 92483880001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper ug/L 9.8 500 500 556 533 109 105 70-130 4 Lead ug/L ND 500 500 527 508 105 102 70-130 4 Zinc ug/L 25.8 500 500 553 531 105 101 70-130 4 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927220 2927221 MS MSD 92484086001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper ug/L 6.3 500 500 543 556 107 110 70-130 2 Lead ug/L ND 500 500 545 567 108 111 70-130 2 Zinc ug/L 89.8 500 500 606 616 103 105 70-130 2 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 44 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 550758 Analysis Method: EPA 624.1 QC Batch Method: EPA 624.1 Analysis Description: 624 MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 METHOD BLANK: 2927800 Matrix: Water Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1-Trichloroethane ug/L ND 2.0 07/01/20 10:51 1,1,2,2-Tetrachloroethane ug/L ND 2.0 07/01/20 10:51 1,1,2-Trichloroethane ug/L ND 2.0 07/01/20 10:51 1,1-Dichloroethane ug/L ND 2.0 07/01/2010:61 1,1-Dichloroethene ug/L ND 2.0 07/01/20 10:51 1,2-Dichlorobenzene ug/L ND 2.0 07/01/20 10:51 1,2-Dichloroethane ug/L NO 2.0 07/01/20 10:51 1,2-Dichloropropane ug/L ND 2.0 07/01/20 10:51 1,3-Dichlorobenzene ug/L NO 2.0 07/01/20 10:51 1,4-Dichlorobenzene ug/L ND 2.0 07/01/20 10:51 Benzene ug/L ND 1.0 07/01/20 10:51 Bromodichioromethane ug/L ND 2.0 07/01/20 10:51 Bromoform ug/L ND 2.0 07/01/20 10:51 Bromomethane ug/L ND 2.0 07/01/20 10:51 Carbon tetrachloride ug/L ND 2.0 07/01/20 10:51 Chlorobenzene ug/L ND 2.0 07/01/20 10:51 Chloroethane ug/L ND 2.0 07/01/20 10:51 Chloroform ug/L ND 2.0 07/01/20 10:51 Chloromethane ug/L ND 2.0 07/01/20 10:51 cis-1,2-Dichloroethene ug/L ND 2.0 07/01/20 10:51 cis-1,3-Dichloropropene ug/L ND 2.0 07/01/20 10:51 Dibromochloromethane ug/L ND 2.0 07/01/20 10:51 Ethylbenzene ug/L ND 1.0 07/01/20 10:51 Methylene Chloride ug/L ND 2.0 07/01/20 10:51 Tetrachloroethene ug/L ND 2.0 07/01/20 10:51 Toluene ug/L ND 1.0 07/01/20 10:51 trans-1,2-Dichloroethene ug/L ND 2.0 07/01/20 10:51 trans- 1,3-Dichloropropene ug/L ND 2.0 07/01/20 10:51 Trichloroethene ug/L NO 2.0 07/01/20 10:51 Trichlorofluoromethane ug/L ND 2.0 07/01/20 10:51 Vinyl chloride ug/L ND 2.0 07/01/20 10:51 1,2-Dichloroethane-d4 (S) % 92 70-130 07/01/20 10:51 4-Bromofluorobenzene (S) % 98 70-130 07/01/20 10:51 Toluene-d8 (S) % 99 70-130 07/01/20 10:51 Qualifiers Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2927801 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1-Trichloroethane ug/L 20 19.0 95 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 44 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 LABORATORY CONTROL SAMPLE: 2927801 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers 1,1,2,2-Tetrachloroethane ug/L 20 20.0 100 60-140 1,1,2-Trichloroethane ug/L 20 20.4 102 70-130 1,1-Dichloroethane ug/L 20 17.9 89 70-130 1,1-Dichloroethene ug/L 20 18.1 91 50-150 1,2-Dichlorobenzene ug/L 20 21.8 109 65-135 1,2-Dichloroethane ug/L 20 18.0 90 49-155 1,2-Dichloropropane ug/L 20 19.0 95 35-165 1,3-Dichlorobenzene ug/L 20 21.5 108 70-130 1,4-Dichlorobenzene ug/L 20 21.6 108 65-135 Benzene ug/L 20 19.3 96 65-135 Bromodichloromethane ug/L 20 17.5 87 65-135 Bromoform ug/L 20 22.1 111 70-130 Bromomethane ug/L 20 12.5 62 15-185 Carbon tetrachloride ug/L 20 20.0 100 70-130 Chlorobenzene ug/L 20 21.0 105 65-135 Chloroethane ug/L 20 18.1 90 40-160 Chloroform ug/L 20 18.5 93 70-135 Chloromethane ug/L 20 12.8 64 1-205 cis-1,2-Dichloroethene ug/L 20 17.8 89 68-146 cis-1,3-Dichloropropene ug/L 20 20.5 103 25-175 Dibromochloromethane ug/L 20 21.9 109 70-135 Ethylbenzene ug/L 20 20.1 101 60-140 Methylene Chloride ug/L 20 14.1 71 60-140 Tetrachloroethene ug/L 20 21.5 107 70-130 Toluene ug/L 20 19.7 99 70-130 trans-1,2-Dichloroethene ug/L 20 17.6 88 70-130 trans-1,3-Dichloropropene ug/L 20 19.7 99 50-150 Trichloroethene ug/L 20 21.4 107 65-135 Trichlorofluoromethane ug/L 20 17.2 86 50-150 Vinyl chloride ug/L 20 14.5 72 5-195 1,2-Dichloroethane-d4 (S) % 91 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927802 2927803 MS MSD 92483368001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual 1,1,1-Trichloroethane ug/L ND 80 80 92.2 89.0 115 111 52-162 4 1,1,2,2-Tetrachloroethane ug/L NO 80 80 86.5 85.5 108 107 46-157 1 1,1,2-Trichloroethane ug/L ND 80 80 88.6 87.2 111 109 52-150 2 1,1-Dichloroethane ug/L ND 80 80 84.4 80.0 106 100 59-155 5 1,1-Dichloroethene ug/L ND 80 80 88.5 85.0 111 106 1-234 4 1,2-Dichlorobenzene ug/L ND 80 80 95.3 93.0 119 116 18-190 2 1,2-Dichloroethane ug/L ND 80 80 80.2 77.9 100 97 49-155 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 44 laneAnalytical@ www.pacolabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927802 MS 92483368001 Spike Parameter Units Result Conc. MSD Spike Conc. 2927803 MS Result MSD Result MS % Rea MSD % Rec % Rec Limits RPD Qual 1,2-Dichloropropane ug/L ND 80 80 87.7 83.4 110 104 1-210 5 1,3-Dichlorobenzene ug/L ND 80 80 96.8 95.9 121 120 59-156 1 1,4-Dichlorobenzene ug/L ND 80 80 96.7 95.8 121 120 18-190 1 Benzene ug/L ND 80 80 91.3 86.9 114 109 37-151 5 Bromodichioromethane ug/L ND 80 80 79.9 77.0 100 96 35-155 4 Bromoform ug/L ND 80 80 90.9 86.9 114 109 45-169 5 Bromomethane ug/L ND 80 80 34.2 29.6 43 37 1-242 14 Carbon tetrachloride ug/L ND 80 80 90.4 87.1 113 109 70-140 4 Chlorobenzene ug/L ND 80 80 96.9 94.7 121 118 37-160 2 Chloroethane ug/L ND 80 80 96.3 89.7 120 112 14-230 7 Chloroform ug/L ND 80 80 86.8 82.5 109 103 51-138 5 Chloromethane ug/L ND 80 80 59.8 57.7 75 72 1-273 4 cis-1,2-Dichloroethene ug/L ND 80 80 83.4 80.5 104 101 45-174 4 cis-1,3-Dichloropropene ug/L ND 80 80 67.1 63.4 84 79 1-227 6 Dibromochloromethane ug/L ND 80 80 94.7 92.2 118 115 53-149 3 Ethylbenzene ug/L ND 80 80 94.4 91.2 118 114 37-162 3 Methylene Chloride ug/L ND 80 80 66.8 63.0 83 79 1-221 6 Tetrachloroethene ug/L ND 80 80 101 99.1 126 124 64-148 2 Toluene ug/L ND 80 80 92.7 88.8 116 111 47-150 4 trans-1,2-Dichloroethene ug/L ND 80 80 85.1 80.5 106 101 54-156 6 trans-1,3-Dichloropropene ug/L ND 80 80 74.8 71.9 94 90 17-183 4 Trichioroethene ug/L ND 80 80 102 99.7 128 125 70-157 3 Trichlorofluoromethane ug/L ND 80 80 85.9 81.9 107 102 17-181 5 Vinyl chloride ug/L ND 80 80 73.1 69.3 91 87 1-251 5 1,2-Dichloroethane-d4 (S) % 88 86 70-130 4-Bromofluorobenzene (S) % 99 98 70-130 Toluene-d8 (S) % 96 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 44 aceAna1j4ka1 www.pecelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 550943 Analysis Method: EPA 608.3 QC Batch Method: EPA 608.3 Analysis Description: 608 PCB Pest Red Vol Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 METHOD BLANK: 2928583 Matrix: Water Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 Blank Reporting Parameter Units Result Limit Analyzed 4,4'-DDD ug/L NO 0.050 07/07/20 01:59 4,4'-DDE ug/L ND 0.050 07/07/20 01:59 4,4'-DDT ug/L ND 0.050 07/07/20 01:59 Aldrin ug/L ND 0.050 07/07/20 01:59 alpha-BHC ug/L ND 0.050 07/07/20 01:59 alpha -Chlordane ug/L ND 0.050 07/07/20 01:59 beta-BHC ug/L ND 0.050 07/07/20 01:59 Chlordane (Technical) ug/L NO 0.50 07/07/20 01:59 delta-BHC ug/L ND 0.050 07/07/20 01:59 Dieldrin ug/L ND 0.050 07/07/20 01:59 Endosulfan I ug/L ND 0.050 07/07/20 01:59 Endosulfan II ug/L ND 0.050 07/07/20 01:59 Endosulfan sulfate ug/L ND 0.050 07/07/20 01:59 Endrin ug/L ND 0.050 07/07/20 01:59 Endrin aldehyde ug/L ND 0.050 07/07/20 01:59 gamma-BHC (Lindane) ug/L ND 0.050 07/07/20 01:69 gamma -Chlordane ug/L NO 0.050 07/07/20 01:59 Heptachlor ug/L ND 0.050 07/07/20 01:59 Heptachlor epoxide ug/L ND 0.050 07/07/20 01:59 PCB-1016 (Aroclor 1016) ug/L ND 0.50 07/07/20 01:59 PCB-1221 (Aroclor 1221) ug/L ND 0.50 07/07/20 01:59 PCB-1232 (Aroclor 1232) ug/L ND 0.50 07/07/20 01:59 PCB-1242 (Aroclor 1242) ug/L ND 0.60 07/07/20 01:59 PCB-1248 (Aroclor 1248) ug/L ND 0.50 07/07/20 01:59 PCB-1254 (Aroclor 1254) ug/L ND 0.50 07/07/20 01:59 PCB-1260 (Aroclor 1260) ug/L ND 0.50 07/07/20 01:59 Toxaphene ug/L ND 0.50 07/07/20 01:59 Decachlorobiphenyl (S) % 86 10-130 07/07/20 01:69 Tetrachloro-m-xylene (S) % 61 10-130 07/07/20 01:59 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2928584 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 6.8 136 50-140 PCB-1260 (Aroclor 1260) ug/L 5 7.6 152 8-140 L1 Decachlorobiphenyl (S) % 73 10-130 Tetrachloro-m-xylene (S) % 67 10-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 44 (� aceAna1j&a1 www.pecelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 LABORATORY CONTROL SAMPLE: 2928585 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD ug/L 0.25 0.22 90 31-141 4,4'-DDE ug/L 0.25 0.19 75 30-145 4,4'-DDT ug/L 0.25 0.20 81 25-160 Aldrin ug/L 0.25 0.15 58 42-140 alpha-BHC ug/L 0.25 0.19 75 37-140 alpha -Chlordane ug/L 0.25 0.19 75 45-140 beta-BHC ug/L 0.25 0.23 92 17-147 delta-BHC ug/L 0.25 0.20 79 19-140 Dieldrin ug/L 0.25 0.21 83 36-146 Endosulfan I ug/L 0.25 0.20 82 45-153 Endosulfan 11 ug/L 0.25 0.23 93 1-202 Endosulfan sulfate ug/L 0.25 0.23 91 26-144 Endrin ug/L 0.25 0.21 83 30-147 Endrin aldehyde ug/L 0.25 0.19 74 50-148 gamma-BHC (Lindane) ug/L 0.25 0.19 77 32-140 gamma -Chlordane ug/L 0.25 0.20 78 45-140 Heptachlor ug/L 0.25 0.15 62 34-140 Heptachlor epoxide ug/L 0.25 0.19 77 37-142 Decachlorobiphenyl (S) % 86 10-130 Tetrachloro-m-xylene (S) % 74 10-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928586 2928587 MS MSD 92484324001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 4,4'-DDD ug/L ND 0.5 0.5 0.39 0.70 78 140 31-141 57 R1 4,4'-DDE ug/L ND 0.5 0.5 0.27 0.99 55 198 30-145 113 M1,R1 4,4'-DDT ug/L ND 0.5 0.5 0.16 0.28 31 55 25-160 56 R1 Aldrin ug/L ND 0.5 0.5 0.70 1.0 140 201 42-140 36 M1,R1 alpha-BHC ug/L ND 0.5 0.5 0.29 0.32 57 64 37-140 11 alpha -Chlordane ug/L ND 0.5 0.5 0.35 0.72 70 143 45-140 68 M1,R1 beta-BHC ug/L ND 0.5 0.5 0.48 0.72 96 144 17-147 40 delta-BHC ug/L NO 0.5 0.5 0.38 0.55 76 111 19-140 38 Dieldrin ug/L ND 0.5 0.5 0.31 1.0 63 203 36-146 105 M1,R1 Endosulfan I ug/L ND 0.5 0.5 0.97 1.5 195 295 45-153 41 M1,R1 Endosulfan II ug/L ND 0.5 0.5 0.57 0.84 113 168 1-202 39 Endosulfan sulfate ug/L ND 0.5 0.5 1.7 1.7 330 333 26-144 1 M1 Endrin ug/L ND 0.5 0.5 0.70 1.3 140 259 30-147 60 M1,R1 Endrin aldehyde ug/L ND 0.5 0.5 0.16 0.24 33 49 50-150 39 M1,R1 gamma-BHC (Lindane) ug/L ND 0.5 0.5 0.31 0.42 62 84 32-140 30 Heptachlor ug/L ND 0.5 0.5 0.20 0.37 39 74 34-140 62 R1 Heptachlor epoxide ug/L ND 0.5 0.5 1.6 1.7 310 340 37-142 9 M1 Decachlorobiphenyl (S) % 15 18 10-130 Tetrachloro-m-xylene (S) % 45 49 10-130 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 44 laneAnalj4icalo www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2928588 2928589 MS MSD 92484324001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rae % Rec Limits RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 10 10 28.5 41.7 285 417 50-140 38 M1,R1 PCB-1260 (Aroclor 1260) ug/L ND 10 10 9.1 11.9 91 119 8-140 26 Decachlorobiphenyl (S) % 11 18 10-130 Tetrachloro-m-xylene (S) % 39 62 10-130 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 44 aceAnalytical www.pacelabs.com Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 550592 QC Batch Method: EPA 625.1 QUALITY CONTROL DATA Analysis Method: EPA 625.1 Analysis Description: 625 MSS Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 METHOD BLANK: 2927153 Matrix: Water Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,2,4-Trichlorobenzene ug/L ND 5.0 07/01/20 15:06 2,2'-Oxybis(1-chloropropane) ug/L NO 5.0 07/01/20 15:06 2,4,6-Trichlorophenol ug/L NO 10.0 07/01/20 15:06 2,4-Dichlorophenol ug/L NO 6.0 07/01/20 15:06 2,4-Dimethylphenol ug/L NO 10.0 07/01/20 15:06 2,4-Dinitrophenol ug/L ND 50.0 07/01/20 15:06 2,4-Dinitrotoluene ug/L ND 5.0 07/01/20 15:06 2,6-Dinitrotoluene ug/L ND 5.0 07101/2015:06 2-Chloronaphthalene ug/L ND 5.0 07101/2015:06 2-Chlorophenol ug/L ND 5.0 07/01/20 15:06 2-Nitrophenol ug/L ND 5.0 07/01/20 15:06 3,3'-Dichlorobenzidine ug/L ND 10.0 07101/2015:06 4,6-Dinitro-2-methylphenol ug/L NO 10.0 07/01/20 15:06 4-Bromophenylphenyl ether ug/L ND 5.0 07/01/20 15:06 4-Chloro-3-methylphenol ug/L NO 5.0 07/01/20 15:06 4-Chlorophenylphenyl ether ug/L ND 5.0 07/01/20 15:06 4-Nitrophenol ug/L ND 10.0 07/01/20 15:06 Acenaphthene ug/L ND 5.0 07/01/20 15:06 Acenaphthylene ug/L ND 5.0 07/01/20 15:06 Anthracene ug/L ND 5.0 07/01/20 15:06 Benzo(a)anthracene ug/L ND 5.0 07101/2015:06 Benzo(a)pyrene ug/L NO 5.0 07/01/20 15:06 Benzo(b)fluoranthene ug/L NO 5.0 07/01/20 15:06 Benzo(g,h,i)perylene ug/L ND 5.0 07101/2015:06 Benzo(k)fluoranthene ug/L ND 5.0 07/01/2016:06 bis(2-Chloroethoxy)methane ug/L ND 10.0 07/01/20 15:06 bis(2-Chloroethyl) ether ug/L ND 5.0 07/01/20 15:06 bis(2-Ethylhexyl)phthalate ug/L ND 5.0 07/01/20 15:06 Butylbenzylphthalate ug/L ND 5.0 07/01/20 15:06 Chrysene ug/L NO 5.0 07/01/20 15:06 Di-n-butylphthalate ug/L NO 5.0 07/01/20 15:06 Di-n-octylphthalate ug/L NO 5.0 07/01/20 15:06 Dibenz(a,h)anthracene ug/L ND 5.0 07/01/20 15:06 Diethylphthalate ug/L ND 5.0 07/01/20 15:06 Dimethylphthalate ug/L ND 5.0 07/0112015:06 Fluoranthene ug/L NO 5.0 07/01/20 15:06 Fluorene ug/L ND 5.0 07/01/20 15:06 Hexachloro-1,3-butadiene ug/L NO 5.0 07/0112015:06 Hexachlorobenzene ug/L NO 5.0 07/01/20 15:06 Hexachlorocyclopentadiene ug/L ND 10.0 07/01/20 15:06 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 44 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 METHOD BLANK: 2927153 Matrix: Water Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 Blank Reporting Parameter Units Result Limit Analyzed Hexachloroethane ug/L ND 5.0 07/01/20 15:06 Indeno(1,2,3-cd)pyrene ug/L ND 5.0 07/01/20 15:06 Isophorone ug/L ND 10.0 07/0112015:06 N-Nitroso-di-n-propylamine ug/L NO 5.0 07/01/20 15:06 N-Nitrosodimethylamine ug/L NO 5.0 07/01/20 15:06 N-Nitrosodiphenylamine ug/L ND 10.0 07/01/20 15:06 Naphthalene ug/L ND 5.0 07/01/20 15:06 Nitrobenzene ug/L ND 5.0 07/01/20 15:06 Pentachlorophenol ug/L NO 10.0 07/01/20 15:06 Phenanthrene ug/L NO 5.0 07/01/20 15:06 Phenol ug/L NO 5.0 07/01/20 15:06 Pyrene ug/L ND 5.0 07/01/20 15:06 2,4,6-Tribromophenol (S) % 79 10-137 07/01/20 15:06 2-Fluorobiphenyl (S) % 78 15-120 07/01/20 15:06 2-Fluorophenol (S) % 66 10-120 07/01/20 15:06 Nitrobenzene -dB (S) % 79 10-120 07/01/20 15:06 Phenol-d6 (S) % 43 10-120 07/01/20 15:06 Terphenyl-d14 (S) % 109 11-131 07/01/20 15:06 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2927154 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4-Trichlorobenzene ug/L 50 34.8 70 44-142 2,2'-Oxybis(1-chloropropane) ug/L 50 37.5 75 36-166 2,4,6-Trichlorophenol ug/L 50 21.6 43 37-144 2,4-Dichlorophenol ug/L 50 30.2 60 1-191 2,4-Dimethylphenol ug/L 50 40.2 80 32-119 2,4-Dinitrophenol ug/L 250 29.9J 12 1-181 2,4-Dinitrotoluene ug/L 50 45.6 91 39-139 2,6-Dinitrotoluene ug/L 50 45.6 91 50-158 2-Chloronaphthalene ug/L 50 39.0 78 60-118 2-Chlorophenol ug/L 50 32.7 65 23-134 2-Nitrophenol ug/L 50 29.4 59 29-182 3,3'-Dichlorobenzidine ug/L 100 88.8 89 1-262 4,6-Dinitro-2-methylphenol ug/L 100 22.7 23 1-181 4-Bromophenylphenyl ether ug/L 50 43.1 86 53-127 4-Chloro-3-methylphenol ug/L 100 92.6 93 22-147 4-Chlorophenylphenyl ether ug/L 50 41.2 82 25-158 4-Nitrophenol ug/L 250 26.4 11 1-132 Acenaphthene ug/L 50 40.6 81 47-145 Acenaphthylene ug/L 50 42.1 84 33-145 Anthracene ug/L 50 43.8 88 1-166 Benzo(a)anthracene ug/L 50 44.5 89 33-143 Benzo(a)pyrene ug/L 50 45.0 90 17-163 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 44 (���a'ceAnalj&al www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 LABORATORY CONTROL SAMPLE: Parameter 2927154 Units Spike Cone. LCS Result LCS % Rec % Rec Limits Benzo(b)fluoranthene ug/L 50 45.4 91 24-169 Benzo(g,h,i)perylene ug/L 50 44.8 90 1-219 Benzo(k)fluoranthene ug/L 50 44.9 90 11-162 bis(2-Chloroethoxy)methane ug/L 50 38.0 76 33-184 bis(2-Chloroethyl) ether ug/L 50 42.3 85 12-158 bis(2-Ethylhexyl)phthalate ug/L 50 44.7 89 8-158 Butylbenzylphthalate ug/L 50 43.7 87 1-152 Chrysene ug/L 50 43.9 88 17-168 Di-n-butylphthalate ug/L 50 44.1 88 1-118 Di-n-octylphthalate ug/L 50 46.3 93 4-146 Dibenz(a,h)anthracene ug/L 50 46.6 93 1-227 Diethylphthalate ug/L 50 41.4 83 1-114 Dimethylphthalate ug/L 50 41.0 82 1-112 Fluoranthene ug/L 50 45.0 90 26-137 Fluorene ug/L 50 42.0 84 59-121 Hexachloro-1,3-butadiene ug/L 50 39.8 80 24-116 Hexachlorobenzene ug/L 50 44.5 89 1-152 Hexachlorocyclopentadiene ug/L 50 33.6 67 25-150 Hexachloroethane ug/L 50 38.9 78 40-113 Indeno(1,2,3-cd)pyrene ug/L 50 45.6 91 1-171 Isophorone ug/L 50 39.5 79 21-196 N-Nitroso-di-n-propylamine ug/L 50 44.1 88 1-230 N-Nitrosodimethylamine ug/L 50 35.7 71 25-150 N-Nitrosodiphenylamine ug/L 50 43.0 86 25-150 Naphthalene ug/L 50 39.6 79 21-133 Nitrobenzene ug/L 50 39.5 79 35-180 Pentachlorophenol ug/L 100 19.6 20 14-176 Phenanthrene ug/L 50 42.6 85 54-120 Phenol ug/L 50 20.6 41 5-112 Pyrene ug/L 50 42.3 85 52-115 2,4,6-Tribromophenol (S) % 66 10-137 2-Fluorobiphenyl (S) % 78 15-120 2-Fluorophenol (S) % 38 10-120 Nitrobenzene-d5 (S) % 78 10-120 Phenol-d6 (S) % 45 10-120 Terphenyl-d14 (S) % 96 11-131 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927155 MS MSD 35558666005 Spike Spike Parameter Units Result Cone. Cone. 1,2,4-Trichlorobenzene ug/L 1.6U 50 50 2,2'-Oxybis(1-chloropropane) ug/L 1.3U 50 50 2,4,6-Trichlorophenol ug/L 1.41.1 50 50 2,4-Dichlorophenol ug/L 1.51-1 50 50 2927156 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers MS MSD MS MSD % Rec Result Result % Rec % Rec Limits RPD Qual 45.0 44.6 90 89 44-142 1 44.0 40.5 88 81 36-166 8 52.6 49.1 105 98 37-144 7 60.6 48.8 101 98 1-191 4 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 35 of 44 aceAnalj&al www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927155 MS 35558666005 Spike Parameter Units Result Conc. MSD Spike Conc. 2927156 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 2,4-Dimethylphenol ug/L 1.5U 50 50 54.3 53.0 109 106 32-119 2 2,4-Dinitrophenol ug/L 7.3U 250 250 258 233 103 93 1-181 10 2,4-Dinitrotoluene ug/L 1.71-1 50 50 55.1 53.2 110 106 39-139 4 2,6-Dinitrotoluene ug/L 1.7U 50 50 53.6 51.3 107 103 50-158 4 2-Chloronaphthalene ug/L 1.41-1 50 50 46.6 45.5 93 91 60-118 2 2-Chlorophenol ug/L 1 AU 50 50 47.7 44.2 95 88 23-134 8 2-Nitrophenol ug/L 1.71-1 50 50 51.1 49.4 102 99 29-182 3 3,3'-Dichlorobenzidine ug/L 2.7U 100 100 108 107 108 107 1-262 1 4,6-Dinitro-2-methylphenol ug/L 4.5U 100 100 113 104 113 104 1-181 8 4-Bromophenylphenyl ether ug/L 1.21-1 50 50 50.3 50.1 101 100 53-127 0 4-Chloro-3-methylphenol ug/L 2.8U 100 100 113 101 113 101 22-147 11 4-Chlorophenylphenyl ether ug/L 1.51-1 50 50 51.4 47.5 103 95 25-158 8 4-Nitrophenol ug/L 9.41-1 250 250 145 129 58 51 1-132 12 Acenaphthene ug/L 1.41-1 50 50 49.2 46.6 98 93 47-145 5 Acenaphthylene ug/L 1.5U 50 50 50.0 48.5 100 97 33-145 3 Anthracene ug/L 1.61-1 50 50 50.9 50.5 102 101 1-166 1 Benzo(a)anthracene ug/L 1.51-1 50 50 52.1 50.4 104 101 33-143 3 Benzo(a)pyrene ug/L 1.8U 50 50 51.5 49.4 103 99 17-163 4 Benzo(b)fluoranthene ug/L 1.7U 50 50 54.2 48.4 108 97 24-159 11 Benzo(g,h,i)perylene ug/L 1.61-1 50 50 55.4 53.2 111 106 1-219 4 Benzo(k)fluoranthene ug/L 1.5U 50 50 54.1 47.8 108 96 11-162 12 bis(2-Chloroethoxy)methane ug/L 1.3U 50 50 47.9 47.0 96 94 33-184 2 bis(2-Chloroethyl) ether ug/L 1.7U 50 50 49.5 45.4 99 91 12-158 9 bis(2-Ethylhexyl)phthalate ug/L 2.01-1 50 50 52.9 50.4 106 101 8-158 5 Butylbenzylphthalate ug/L 1.91-1 50 50 53.7 51.5 107 103 1-152 4 Chrysene ug/L 1.4U 50 50 50.5 48.6 101 97 17-168 4 Di-n-butylphthalate ug/L 1.6U 50 50 51.5 50.8 103 102 1-118 1 Di-n-octylphthalate ug/L 2.21-1 50 50 55.8 54.0 112 108 4-146 3 Dibenz(a,h)anthracene ug/L 1.61-1 50 50 56.6 54.7 113 109 1-227 3 Diethylphthalate ug/L 1.61-1 50 50 47.6 45.7 95 91 1-114 4 Dimethylphthalate ug/L 1AU 50 50 46.8 44.9 94 90 1-112 4 Fluoranthene ug/L 1.61-1 50 50 52.0 52.2 104 104 26-137 0 Fluorene ug/L 1.41-1 50 50 52.7 48.1 105 96 59-121 9 Hexachloro-1,3-butadiene ug/L 1.61-1 50 50 44.1 44.4 88 89 24-116 1 Hexachlorobenzene ug/L 1.3U 50 50 51.6 51.2 103 102 1-152 1 Hexachlorocyclopentadiene ug/L 2.4U 50 50 35.0 36.3 70 73 25-150 4 Hexachloroethane ug/L 1.3U 50 50 43.5 44.3 87 89 40-113 2 Indeno(1,2,3-cd)pyrene ug/L 1.7U 50 50 55.0 53.4 110 107 1-171 3 Isophorone ug/L 1.31-1 50 50 52.3 50.0 105 100 21-196 4 N-Nitroso-di-n-propylamine ug/L 1.3U 50 50 53.5 50.3 107 101 1-230 6 N-Nitrosodimethylamine ug/L 1.8U 50 50 38.7 38.3 77 77 25-150 1 N-Nitrosodiphenylamine ug/L 1 AU 50 50 50.7 49.9 101 100 25-150 2 Naphthalene ug/L 1.6U 50 50 45.5 44.2 91 88 21-133 3 Nitrobenzene ug/L 1.51.1 50 50 50.9 48.8 102 98 35-180 4 Pentachlorophenol ug/L 2.8U 100 100 108 104 108 104 14-176 4 Phenanthrene ug/L 1 AU 50 50 49.1 48.1 98 96 54-120 2 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 36 of 44 (�IaneAnalj&al www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2927155 2927156 MS MSD 35558666005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phenol ug/L 1.5U 50 50 24.9 20.3 50 41 5-112 20 Pyrene ug/L 1.5U 50 50 52.2 49.5 104 99 52-115 5 2,4,6-Tribromophenol (S) % 130 126 10-137 2-Fluorobiphenyl (S) % 100 97 15-120 2-Fluorophenol (S) % 73 67 10-120 Nitrobenzene-d5 (S) % 109 106 10-120 PhenoW6(S) % 58 53 10-120 Terphenyl-d 14 (S) % 125 121 11-131 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 44 (�Iacmnalyfical QO www.pacolabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 550845 Analysis Method: SM 254OD-2011 QC Batch Method: SM 2540D-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 METHOD BLANK: 2928182 Matrix: Water Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 07/01/20 16:35 Pace Analytical Services, LLC 9800 Kincey Aver Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2928183 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 246 98 90-110 SAMPLE DUPLICATE: 2928290 92483687002 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 716 724 1 SAMPLE DUPLICATE: 2928291 92483925001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 2970 2970 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 38 of 44 aceAnalytieal www.pecolabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92484086 QC Batch: 551234 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92484086001, 92484086002, 92484086003, 92484086004, 92484086005 SAMPLE DUPLICATE: 2930240 92483386001 Dup Parameter Units Result Result RPD Qualifiers PH at 25 Degrees C Std. Units 7.6 7.5 0 H3 SAMPLE DUPLICATE: 2930241 Parameter PH at 25 Degrees C 92484086002 Units Result Std. Units 4.7 Dup Result RPD Qualifiers 4.7 0 H3 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 39 of 44 aceAnalj4ical www.pacelabs.com QUALIFIERS Project: RBTC STORMWATER Pace Project No.: 92484086 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA Method 8260, N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. HS Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter). L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 40 of 44 aceAnalytical' www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: RBTC STORMWATER 92484086 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92484086001 OUTFALL1 EPA1664B 550977 92484086002 OUTFALL 3 EPA 1664E 550977 92484086003 OFFSITE1 EPA1664B 551259 92484086004 OFFSITE 2 EPA1664B 551259 92484086005 OFFSITE 3 EPA1664B 551259 92484086001 OUTFALL 1 EPA 608.3 550943 EPA 608.3 551255 92484086002 OUTFALL 3 EPA 608.3 550943 EPA 608.3 551255 92484086003 OFFSITE 1 EPA 608.3 550943 EPA 608.3 551255 92484086004 OFFSITE 2 EPA 608.3 550943 EPA 608.3 551255 92484086005 OFFSITE 3 EPA 608.3 560943 EPA 608.3 551255 92484086001 OUTFALL 1 EPA 200.7 Rev 4.4 1994 550616 EPA 200.7 Rev 4.4 1994 550621 92484086002 OUTFALL 3 EPA 200.7 Rev 4.4 1994 550616 EPA 200.7 Rev 4.4 1994 650621 92484086003 OFFSITE 1 EPA 200.7 Rev 4.4 1994 550616 EPA 200.7 Rev 4.4 1994 550621 92484086004 OFFSITE 2 EPA 200.7 Rev 4.4 1994 550616 EPA 200.7 Rev 4.4 1994 550621 92484086006 OFFSITE 3 EPA 200.7 Rev 4.4 1994 550616 EPA 200.7 Rev 4.4 1994 550621 92484086001 OUTFALL 1 EPA 625.1 550592 EPA 625.1 550801 92484086002 OUTFALL 3 EPA 625.1 550592 EPA 625.1 550801 92484086003 OFFSITE 1 EPA 625.1 550592 EPA 625.1 550801 92484086004 OFFSITE 2 EPA 625.1 550592 EPA 625.1 550801 92484086005 OFFSITE 3 EPA 625.1 550592 EPA 625.1 650801 92484086001 OUTFALL 1 EPA 624.1 550758 92484086002 OUTFALL 3 EPA 624.1 550758 92484086003 OFFSITE 1 EPA 624.1 550758 92484086004 OFFSITE 2 EPA 624.1 550758 92484086006 OFFSITE 3 EPA 624.1 550758 92484086001 OUTFALL 1 SM 2540D-2011 550845 92484086002 OUTFALL 3 SM 2540D-2011 550845 92484086003 OFFSITE 1 SM 254OD-2011 550845 92484086004 OFFSITE 2 SM 2540D-2011 550845 92484086006 OFFSITE 3 SM 2540D-2011 550845 92484086001 OUTFALL1 EPA 9040C 551234 92484086002 OUTFALL 3 EPA 9040C 551234 92484086003 OFFSITE1 EPA 9040C 551234 92484086004 OFFSITE 2 EPA 9040C 551234 92484086006 OFFSITE 3 EPA 9040C 551234 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/08/2020 08:47 AM without the written consent of Pace Analytical Services, LLC. Page 41 of 44 Document Name: Document Revised: February 7, 2018 Analytical Sample Condition Upon Recet I(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS•033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden® GreenwoodEl Huntersville D"' Raleigh[) MechanicsvilleR .ff + Client Name: , Project #: Courier: ❑ ed� []UPS OUSPS ❑Elent ❑ Commercial Pace 00ther: Custody Seal Present? Des (No Seals Intact? ❑Yes (]No Date/initials Person Examining Contents ,? `f° Packing Material: []Bubble Wrap E]Bubble Bags ❑None ❑ Other Blological7issue fro en? Thermometer: ❑Yes []No C]N/A QiR Gun ID: 92TO61 Type of Ice: Owet ❑Blue QNone Cooler Temp (°C): r , �. /' Correction Factor: Add/Subtract ('C) +0,1 Temp should be above freezing to 6'C Cooler TempCorrected 'C / f r `' ( )•� r f ' �r �'I� � []samples out of temp criteria. Samples on Ice, cooling process has begun USDA Regulated Soil ( NIA, water sample) Did samples originate -in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source Untempiofiaily, mv— r1I. inri-iino wnuall and puerta llicol? r1Yes n/ No Comments/piscre ancy: Chain of Custody Present? Wires Na ❑N/A 1. Samples Arrived within Hold Time? (]fes QNO ON/A 2. Short Hold Time Analysis (<72 hr.)? Oyes l No ,. []N/A 3. Rush Turn Around Time Requested? (]Yes MN. ❑N/A 4. Sufficient Volume? DYes No ❑N/A S. Correct Containers Used? -Pace Containers Used? ,,=]9e;: ' oVes QNo ❑No QN/A EIN/A 6. Containers Intact? ©Yes CN-.—'o NJA 7. Dissolved analysis: Samples Field Filtered? OYes No QiV/A 8. -Includes Date/Time/ID/Anal sis matrix: Ves N N A 9. Heads ace in VOA Vials >5-6mm)? £=Yes ❑No- N/A p j 10.{m1' VL2 ' Trip Blank Present? Trip Blank Custody Seals Present? Dyes Yes • No ONO QN//A UN/A 11. COMMENTS/SAMPLE DISCREPANCY Field Data Required? Oyes []No Lot ID of spk containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time; Project Manager SCURF Review: date: Project Manager SRF Review: Date: Page 42 of 44 Document Name: Document: nevised: February 1, 2018 Sample Condillort on Recel tISCUR) Page 1 of 2 LI r?CBARIjII"ICBI Document No.: Issuing Authority: P-CAR-CS-033-Rev.06 Pace Carolinas Quality Office `Check mark top half of box if pH and/or dechlorination is Project verified and within the acceptance range for preservation samples. Exceptions: VOA, Collform, TOC, Oil and Grease, ORO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle M a N v Z N " m E m = 2 O Z S4 LE N m Pa O y o v w 3 w v c ' v E ;; a r^y _ Y u x u E N l9 a n O iEE d o m t7 a 2 rV x `a E °; w t7 a 2 O S 0 m L9 G a Z a r E n 6 ? U x QO o azi a 4 ,. 0 ro Z O _J 0 > z n C O J 0 q obi ; Q Op S M x 7 J 0 a O .Z,. " m h _ x R O > :ic m x ` n : u 3 ZLn a y r vt n vt m < a ?r ^ E w ti i yr x Z .-�+ ° E m Z c O a E E a Q Z c c .n E a z > �, a O u .o Q E N a c > a E rq m c > a E Lq N m v a > 6. E _0 C a C u M m a = A E m M Z i `-' ° 0 VW' m t 1 3j 6 9 10 li 12 pH Adjustment log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation _.adjusted Amount of Preservative -- adde lot N — . will be stet to the North Carolina DEHNR Certification Office (i.e. Note: Whenever there is a discrepancy affecting North carouna compnal— ,, wN r. Out of hold, Incorrect preservative, out of temp, Incorrect containers. Page 43 of 44 ITEM # 3 ° to A n L1 �yqq q � 9 M e a '.. agaEomv�Fg�y s f a d $$ $$ a m MATRIXCODE (see valid codas to left) SAMPLE TYPE (G=GRAB C=COMP) 0 mm � � � O m mom ae�rs�i OMMEMMOMMEN■��MMEMEMMOMEME .........■.■ MEN MENEM. MMMMWMMMMMMM ■���MMMO®®®© • WOMEN MUNBURME m���l M Bonn, ■��No M®a©FAMI•:MNI reair in c j"� Residual Chlorine (YIN) Received on Ice ti_y f (YM)...�� Custody Sealed Cooler' (YIN) Samples -"... L, Intact (Y/N) 'A _ � H c B� p a K n p A p N J A (J C v D K � < 3 m s ii re (7 w z o O o n C 7 Q r c �0 0 p® � O O D m N (4 03 N tl� Cr 0 3 � n O 3 03 n m O Page 44 of 44 aceAnalytical www.pacolabs.com September 09, 2020 Glenn Magley Heritage Environmental 7901 W Morris St Indianapolis, IN 46231 RE: Project: RBTC Stormwater Pace Project No.: 92493437 Dear Glenn Magley: Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on September 01, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNIINELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, J Bonnie Vang bonnie.vang@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 35 Pace Analytical Services, LLC aceAnalytical o 9800Hunte sv Ile, NC 28078 www.pacelabs.com (704)875-9092 CERTIFICATIONS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 35 aceAnalytical R www.pacelabs.com Project: RBTC Stormwater Pace Project No.: 92493437 Lab ID Sample ID 92493437001 Outfall 1 92493437002 Ouffall3 92493437003 Offsite 1 92493437004 Offsite 2 92493437005 Of isite 3 PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte SAMPLE ANALYTE COUNT Method EPA1664B EPA 200.7 Rev 4.4 1994 EPA 625.1 EPA 624.1 SM 254OD-2011 EPA 9040C EPA 1664B EPA 200.7 Rev 4.4 1994 EPA 625.1 EPA 624.1 SM 2540D-2011 EPA 9040C EPA 1664B EPA 200.7 Rev 4.4 1994 EPA 625.1 EPA 624.1 SM 254OD-2011 EPA 9040C EPA 1664E EPA 200.7 Rev 4.4 1994 EPA 625.1 EPA 624.1 SM 2540D-2011 EPA 9040C EPA 1664E EPA 200.7 Rev 4.4 1994 EPA 625.1 EPA 624.1 SM 254OD-2011 EPA 9040C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, L.L.C. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytes Analysts Reported Laboratory HH 1 PASI-C DS 3 PAST -A PKS 59 PASI-C SAS 38 PASI-C RED 1 PASI-A SMK 1 PASI-A HH 1 PASI-C DS 3 PASI-A PKS 59 PASI-C SAS 38 PASI-C RED 1 PASI-A SMK 1 PASI-A HH 1 PASI-C SH1 3 PASI-A PKS 59 PASI-C SAS 38 PASI-C RED 1 PASI-A SMK 1 PASI-A HH 1 PASI-C SH1 3 PASI-A PKS 59 PASI-C SAS 38 PASI-C RED 1 PASI-A SMK 1 PASI-A HH 1 PASI-C SH1 3 PASI-A PKS 59 PASI-C SAS 38 PASI-C RED 1 PASI-A SMK 1 PASI-A Page 3 of 35 leAnaljdical www,pacelabs.cem ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Outfall 1 Parameters Lab ID: 92493437001 Collected: 08/31/20 08:37 Received: 09/01/20 14:45 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 09/09/20 08:41 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:12 7440-50-8 Lead ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:12 7439-92-1 Zinc 56.8 ug/L 10.0 1 09/02/20 01:33 09/02/20 21:12 7440-66-6 BC 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 83-32-9 Acenaphthylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 208-96-8 Anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 120-12-7 Benzidine ND ug/L 50.0 1 09/04/20 07:09 09/04/20 16:28 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 101-55-3 Butyibenzylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 111-91-1 bis(2-Chloroethyi) ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 91-58-7 2-Chlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 95-57-8 4-Chiorophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 7005-72-3 Chrysene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 120-83-2 Diethylphtha late ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 105-67-9 Dimethylphtha late ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 09/04/20 07:09 09/04/20 16:28 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 122-66-7 L1 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 117-81-7 Fiuoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 206-44-0 Fluorene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 87-68-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, I.I.C. Page 4 of 35 aeeAnalytical www.pecolabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Project No.: 92493437 Sample: Outfall 1 Lab ID: 92493437001 Collected: 08/31/20 08:37 Received: 09/01/20 14:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Hexachlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 77-47-4 Hexachloroethane ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 193-39-5 Isophorone ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 78-59-1 Naphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 91-20-3 Nitrobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 98-95-3 2-Nitrophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 88-75-5 4-Nitrophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 86-30-6 Pentachlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 87-86-5 Phenanthrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 85-01-8 Phenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 108-95-2 Pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:28 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:28 88-06-2 Surrogates Nitrobenzene-d5 (S) 44 % 10-120 1 09/04/20 07:09 09/04/20 16:28 4165-60-0 1 g 2-Fluorobiphenyl (S) 19 % 15-120 1 09/04/20 07:09 09/04/20 16:28 321-60-8 Terphenyl-d14 (S) 101 % 11-131 1 09/04/20 07:09 09/04/20 16:28 1718-51-0 Phenol-d6 (S) 10 % 10-120 1 09/04/20 07:09 09/04/20 16:28 13127-88-3 2-Fluorophenol (S) 2 % 10-120 1 09/04/20 07:09 09/04/20 16:28 367-12-4 SO 2,4,6-Tribromophenol (S) 7 % 10-137 1 09/04/20 07:09 09/04/20 16:28 118-79-6 SO 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 09/03/20 18:01 107-02-8 Acrylonitrile ND ug/L 5.0 1 09/03/20 18:01 107-13-1 Benzene ND ug/L 1.0 1 09/03/20 18:01 71-43-2 Bromodichloromethane ND ug/L 2.0 1 09103/2018:01 75-27-4 Bromoform ND ug/L 2.0 1 09/03/20 18:01 75-25-2 Bromomethane ND ug/L 2.0 1 09/03/20 18:01 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 09/03/20 18:01 56-23-5 Chlorobenzene ND ug/L 2.0 1 09/03/20 18:01 108-90-7 Chloroethane ND ug/L 2.0 1 09/03/20 18:01 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 09/03/20 18:01 110-75-8 c3 Chloroform ND ug/L 2.0 1 09/03/20 18:01 67-66-3 Chloromethane ND ug/L 2.0 1 09/03/20 18:01 74-87-3 Dibromochloromethane ND ug/L 2.0 1 09/0312018:01 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:01 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:01 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:01 106-46-7 Dichlorodifluoromethane ND ug/L 2.0 1 09/03/20 18:01 75-71-8 1,1-Dichloroethane ND ug/L 2.0 1 09/03/20 18:01 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 35 Pace Analytical Services, LLC aceAnaiyticai ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Sample: Outfall 1 Lab ID: 92493437001 Collected: 08/31/20 08:37 Received: 09/01/20 14:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte 1,2-Dichloroethane ND ug/L 1,1-Dichloroethene ND ug/L trans-1,2-Dichloroethene ND ug/L 1,2-Dichloropropane ND ug/L cis-1,3-Dichloropropene ND ug/L trans-1,3-Dichloropropene ND ug/L Ethylbenzene ND ug/L Methylene Chloride ND ug/L Naphthalene ND ug/L 1,1,2,2-Tetrachioroethane ND ug/L Tetrachloroethene ND ug/L Toluene ND ug/L 1,1,1-Trichloroethane ND ug/L 1,1,2-Trichloroethane ND ug/L Trichloroethene ND ug/L Trichlorofluoromethane ND ug/L Vinyl chloride ND ug/L Surrogates 4-Bromofluorobenzene (S) 43 % Toluene-d8 (S) 96 % 1,2-Dichloroethane-d4 (S) 91 % 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services -Asheville Total Suspended Solids 2.7 mg/L 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 5.7 Sid. Units Date: 09/09/2020 03:20 PM 2.0 1 09/03/20 18:01 107-06-2 2.0 1 09/03/20 18:01 75-35-4 2.0 1 09/03/20 18:01 156-60-5 2.0 1 09/03/20 18:01 78-87-5 2.0 1 09/03/20 18:01 10061-01-5 2.0 1 09/03/20 18:01 10061-02-6 1.0 1 09/03/20 18:01 100-41-4 2.0 1 09/03/20 18:01 75-09-2 5.0 1 09/03/20 18:01 91-20-3 2.0 1 09/03/20 18:01 79-34-5 2.0 1 09/03/20 18:01 127-18-4 1.0 1 09/03/20 18:01 108-88-3 2.0 1 09/03/20 18:01 71-55-6 2.0 1 09/03/20 18:01 79-00-5 2.0 1 09/03/20 18:01 79-01-6 2.0 1 09/03/20 18:01 75-69-4 2.0 1 09/03/20 18:01 75-01-4 70-130 1 70-130 1 70-130 1 2.5 1 0.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 09/03/20 18:01 460-00-4 2g,HS 09/03/20 18:01 2037-26-5 09/03/20 18:01 17060-07-0 09/03/20 19:15 09/06/20 13:34 I:tc Page 6 of 36 laneAnalj4ical@ www.pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Outfall 3 Parameters Lab ID: 92493437002 Collected: 08/31/20 08:49 Results Units Report Limit DF Received: 09/01/20 14:45 Matrix: Water Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 4.9 1 09/09/20 08:41 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:16 7440-50-8 Lead ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:16 7439-92-1 Zinc 74.7 ug/L 10.0 1 09/02/20 01:33 09/02/20 21:16 7440-66-6 BC 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 83-32-9 Acenaphthylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 208-96-8 Anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 120-12-7 Benzidine ND ug/L 50.0 1 09/04/20 07:09 09/04/20 16:57 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:67 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 91-58-7 2-Chlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 7005-72-3 Chrysene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 120-83-2 Diethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:67 105-67-9 Dimethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 09/04/20 07:09 09/04/20 16:57 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 122-66-7 L1 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 117-81-7 Fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 206-44-0 Fluorene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 87-68-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 35 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Outfall 3 Parameters Lab ID: 92493437002 Collected: 08/31/20 08:49 Results Units Report Limit DF Received: 09/01/20 14:45 Matrix: Water Prepared Analyzed GAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Hexachlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 77-47-4 Hexachloroethane ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 193-39-5 Isophorone ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 78-59-1 Naphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 91-20-3 Nitrobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 98-95-3 2-Nitrophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 88-75-5 4-Nitrophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 100-02-7 N-Nitrosodimethylamine ND ug/L 6.0 1 09/04/20 07:09 09/04/20 16:57 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 86-30-6 Pentachlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 87-86-5 Phenanthrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 85-01-8 Phenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 108-95-2 Pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 129-00-0 1,2,4-Trichoorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 16:57 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 16:57 88-06-2 Surrogates Nitrobenzene-d5 (S) 52 % 10-120 1 09/04/20 07:09 09/04/20 16:57 4165-60-0 2-Fluorobiphenyl (S) 24 % 15-120 1 09/04/20 07:09 09/04/20 16:57 321-60-8 Terphenyl-d14 (S) 124 % 11-131 1 09/04/20 07:09 09/04/20 16:57 1718-51-0 Phenol-d6 (S) 39 % 10-120 1 09/04/20 07:09 09/04/20 16:57 13127-88-3 2-Fluorophenol (S) 54 % 10-120 1 09/04/20 07:09 09/04/20 16:57 367-12-4 2,4,6-Tribromophenol (S) 80 % 10-137 1 09/04/20 07:09 09/04/20 16:57 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 09/03/20 18:18 107-02-8 M1 Acrylonitrile ND ug/L 5.0 1 09/03/20 18:18 107-13-1 Benzene ND ug/L 1.0 1 09/03/20 18:18 71-43-2 Bromodichloromethane ND ug/L 2.0 1 09/03/20 18:18 75-27-4 Bromoform ND ug/L 2.0 1 09/03/20 18:18 75-25-2 Bromomethane ND ug/L 2.0 1 09/03/20 18:18 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 09/03/20 18:18 56-23-5 Chlorobenzene ND ug/L 2.0 1 09/03/20 18:18 108-90-7 Chloroethane ND ug/L 2.0 1 09/03/20 18:18 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 09/03/20 18:18 110-75-8 c3 Chloroform ND ug/L 2.0 1 09/03/20 18:18 67-66-3 Chloromethane ND ug/L 2.0 1 09/03/20 18:18 74-87-3 Dibromochloromethane ND ug/L 2.0 1 09/03/20 18:18 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:18 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:18 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 09/0312018:18 106-46-7 Dichlorodifluoromethane ND ug/L 2.0 1 09/03/20 18:18 75-71-8 1,1-Dich►oroethane ND ug/L 2.0 1 09/0312018:18 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 35 aceAnalytical www.pacolabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC Stormwater Pace Project No.: 92493437 Sample: Outfall 3 Lab ID: 92493437002 Collected: 08/31/20 08:49 Received: 09/01/20 14:45 Matrix: Water Parameters 624 Volatile Organics Acrolein 1,2-Dichloroethane 1,1-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Methylene Chloride Naphthalene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl chloride Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 2540D Total Suspended Solids Total Suspended Solids 9040 pH pH at 25 Degrees C Date: 09/09/2020 03:20 PM Results Units Report Limit DF Prepared Analyzed CAS No. Quaff Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 104 % 100 % 99 % Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville ND mg/L Analytical Method: EPA 9040C Pace Analytical Services - Asheville 4.7 Std. Units 2.0 1 09/03/20 18:18 107-06-2 2.0 1 09/03/20 18:18 75-35-4 2.0 1 09/03/20 18:18 156-60-5 2.0 1 09/03/20 18:18 78-87-5 2.0 1 09/03/20 18:18 10061-01-5 2.0 1 09/03/20 18:18 10061-02-6 1.0 1 09/03/20 18:18 100-41-4 2.0 1 09/03/20 18:18 75-09-2 5.0 1 09/0312018:18 91-20-3 2.0 1 09/03/20 18:18 79-34-5 2.0 1 09/03/20 18:18 127-18-4 1.0 1 09/03/20 18:18 108-88-3 2.0 1 09/03/20 18:18 71-55-6 2.0 1 09/03/20 18:18 79-00-5 2.0 1 09/03/20 18:18 79-01-6 2.0 1 09/03/20 18:18 75-69-4 2.0 1 09/03/20 18:18 75-01-4 70-130 1 70-130 1 70-130 1 2.5 1 0.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 09/03/20 18:18 460-00-4 HS 09/03/20 18:18 2037-26-5 09/03/20 18:18 17060-07-0 09/03/20 19:16 09/06/2013:40 H3 Page 9 of 35 acmnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (704)875-9092 Sample: Offsite 1 Parameters Lab ID: 92493437003 Collected: 08/31/20 09:00 Received: 09/01/20 14:45 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 4.9 1 09/09/20 08:42 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Copper ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:32 7440-50-8 Lead ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:32 7439-92-1 Zinc 32.4 ug/L 10.0 1 09/02/20 01:33 09/02/20 21:32 7440-66-6 BC 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 83-32-9 Acenaphthylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 208-96-8 Anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 120-12-7 Benzidine ND ug/L 50.0 1 09/04/20 07:09 09/04/20 17:27 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 91-58-7 2-Chlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 7005-72-3 Chrysene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 120-83-2 Diethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 105-67-9 Dimethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 09/04/20 07:09 09/04/20 17:27 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 122-66-7 L1 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 117-81-7 Fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 206-44-0 Fluorene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 87-68-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 35 leAnalyfical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Offsite 1 Parameters Lab ID: 92493437003 Collected: 08/31/20 09:00 Results Units Report Limit DF Received: 09/01/20 14:45 Matrix: Water Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Hexachlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 77-47-4 Hexachloroethane ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 193-39-5 Isophorone ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 78-59-1 Naphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 91-20-3 Nitrobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 98-95-3 2-Nitrophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 88-75-5 4-Nitrophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 86-30-6 Pentachlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 87-86-5 Phenanthrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 85-01-8 Phenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 108-95-2 Pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:27 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:27 88-06-2 Surrogates Nitrobenzene-d5 (S) 62 % 10-120 1 09/04/20 07:09 09/04/20 17:27 4165-60-0 2-Fluorobiphenyl (S) 34 % 15-120 1 09/04/20 07:09 09/04/20 17:27 321-60-8 Terphenyl-d14 (S) 124 % 11-131 1 09/04/20 07:09 09/04/20 17:27 1718-51-0 Phenol-d6 (S) 30 % 10-120 1 09/04/20 07:09 09/04/20 17:27 13127-88-3 2-Fluorophenol (S) 38 % 10-120 1 09/04/20 07:09 09/04/20 17:27 367-12-4 2,4,6-Tribromophenol (S) 77 % 10-137 1 09/04/20 07:09 09/04/20 17:27 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 09/03/20 18:36 107-02-8 Acrylonitrile ND ug/L 5.0 1 09/03/20 18:36 107-13-1 Benzene ND ug/L 1.0 1 09/03/20 18:36 71-43-2 Bromodichloromethane ND ug/L 2.0 1 09/03/20 18:36 75-27-4 Bromoform ND ug/L 2.0 1 09/03/20 18:36 75-25-2 Bromomethane ND ug/L 2.0 1 09/0312018:36 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 09/03/20 18:36 56-23-5 Chlorobenzene ND ug/L 2.0 1 09/03/20 18:36 108-90-7 Chloroethane ND ug/L 2.0 1 09/03/20 18:36 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 09/03/20 18:36 110-75-8 c3 Chloroform ND ug/L 2.0 1 09/03/20 18:36 67-66-3 Chloromethane ND ug/L 2.0 1 09/0312018:36 74-87-3 Dibromochloromethane ND ug/L 2.0 1 09103/2018:36 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:36 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:36 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 09/03/20 18:36 106-46-7 Dichlorodifluoromethane ND ug/L 2.0 1 09/03/20 18:36 75-71-8 1,1-Dichloroethane ND ug/L 2.0 1 09103/2018:36 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 35 (:�;a'neAnalXical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Offsite 1 Lab lD: 92493437003 Collected: 08/31/20 09:00 Received: 09/01/20 14:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Acrolein 1,2-Dichloroethane 1,1-Dichioroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1, 3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Methylene Chloride Naphthalene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichiorofluorometha ne Vinyl chloride Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 2640D Total Suspended Solids Total Suspended Solids 9040 pH pH at 25 Degrees C Date: 09/09/2020 03:20 PM Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 101 % 103 % 102 % Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville 7.0 mg/L Analytical Method: EPA 9040C Pace Analytical Services - Asheville 5.7 Std. Units 2.0 1 09/03/20 18:36 107-06-2 2.0 1 09/03/20 18:36 75-35-4 2.0 1 09/03/20 18:36 156-60-5 2.0 1 09/03/20 18:36 78-87-5 2.0 1 09/03/20 18:36 10061-01-5 2.0 1 09/03/20 18:36 10061-02-6 1.0 1 09/03/20 18:36 100-41-4 2.0 1 09/03/20 18:36 75-09-2 5.0 1 09/03/20 18:36 91-20-3 2.0 1 09/03/20 18:36 79-34-5 2.0 1 09/03/20 18:36 127-18-4 1.0 1 09/03/20 18:36 108-88-3 2.0 1 09/0312018:36 71-55-6 2.0 1 09/03/20 18:36 79-00-5 2.0 1 09/03/20 18:36 79-01-6 2.0 1 09/03/20 18:36 75-69-4 2.0 1 09/03/20 18:36 75-01-4 70-130 1 70-130 1 70-130 1 N&F111111111111il 0.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 09/03/20 18:36 460-00-4 09/03/20 18:36 2037-26-5 09/03/20 18:36 17060-07-0 09/03/20 19:16 09/06/2013:46 H3 Page 12 of 35 laneAnallj4icalo www.pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Offsite 2 Parameters Lab ID: 92493437004 Collected: 08/31/20 09:07 Results Units Report Limit DF Received: 09/01/20 14:46 Matrix: Water Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 4.8 1 09/09/20 08:43 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:35 7440-50-8 Lead ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:35 7439-92-1 Zinc 11.0 ug/L 10.0 1 09/02/20 01:33 09/02/20 21:35 7440-66-6 BC 625 RVE Analytical Method: EPA 626.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 83-32-9 Acenaphthylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 208-96-8 Anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 120-12-7 Benzidine ND ug/L 50.0 1 09/04/20 07:09 09/04/20 17:56 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 91-58-7 2-Chlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 7005-72-3 Chrysene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 120-83-2 Diethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 105-67-9 Dimethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 09/04/20 07:09 09/04/20 17:56 51-28-5 2,4-Dinitrotoluene ND ug/L &0 1 09/04/20 07:09 09/04/20 17:56 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 122-66-7 L1 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 117-81-7 Fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 206-44-0 Fluorene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 87-68-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 35 7 0 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC Stormwater Pace Project No.: 92493437 Sample: Offsite 2 Lab ID: 92493437004 Collected: 08/31/20 09:07 Received: 09/01/20 14:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Hexachlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 77-47-4 Hexachloroethane ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 193-39-5 Isophorone ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 78-59-1 Naphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 91-20-3 Nitrobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 98-95-3 2-Nitrophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 88-75-5 4-Nitrophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 86-30-6 Pentachlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 87-86-5 Phenanthrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 85-01-8 Phenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 108-95-2 Pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 17:56 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 17:56 88-06-2 Surrogates Nitrobenzene-d5 (S) 51 % 10-120 1 09/04/20 07:09 09/04/20 17:56 4165-60-0 2-Fluorobiphenyl (S) 22 % 15-120 1 09/04/20 07:09 09/04/20 17:56 321-60-8 Terphenyl-04 (S) 115 % 11-131 1 09/04/20 07:09 09/04/20 17:56 1718-51-0 Phenol-d6 (S) 37 % 10-120 1 09/04/20 07:09 09/04/20 17:56 13127-88-3 2-Fluorophenol (S) 46 % 10-120 1 09/04/20 07:09 09/04/20 17:56 367-12-4 2,4,6-Tribromophenol (S) 83 % 10-137 1 09/04/20 07:09 09/04/20 17:56 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 09/03/2018:54 107-02-8 Acrylonitrile ND ug/L 5.0 1 09/03/2018:64 107-13-1 Benzene ND ug/L 1.0 1 09/03/2018:54 71-43-2 Bromodichloromethane ND ug/L 2.0 1 09/03/2018:54 75-27-4 Bromoform ND ug/L 2.0 1 09/03/2018:54 75-25-2 Bromomethane ND ug/L 2.0 1 09/03/2018:64 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 09/03/20 18:54 56-23-5 Chlorobenzene ND ug/L 2.0 1 09/03/2018:54 108-90-7 Chloroethane ND ug/L 2.0 1 09/03/2018:54 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 09/03/20 18:54 110-75-8 c3 Chloroform ND ug/L 2.0 1 09103/2018:54 67-66-3 Chloromethane ND ug/L 2.0 1 09/03/2018:54 74-87-3 Dibromochloromethane ND ug/L 2.0 1 09/03/2018:54 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 09/03/2018:54 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 09/03/2018:54 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 09/03/2018:54 106-46-7 Dichlorodifluoromethane ND ug/L 2.0 1 09103/2018:54 75-71-8 1,1-Dichloroethane ND ug/L 2.0 1 09/03/2018:54 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 35 Pace Analytical Services, LLC (� ® 9800 Kincey Ave. Suite 100 IaneAnalyfica(Huntersville, NC 28078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Sample: Offsite 2 Lab ID: 92493437004 Collected: 08/31/20 09:07 Received: 09/01/20 14:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte 1,2-Dichloroethane ND ug/L 2.0 1 09/03/20 18:54 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 09/03/20 18:54 75-35-4 trans-1,2-Dichloroethene ND ug/L 2.0 1 09/03/20 18:54 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 09/03/20 18:54 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 09/03/20 18:54 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 09/0312018:54 10061-02-6 Ethylbenzene ND ug/L 1.0 1 09/03/20 18:54 100-41-4 Methylene Chloride ND ug/L 2.0 1 09/03/20 18:54 75-09-2 Naphthalene ND ug/L 5.0 1 09/03/20 18:54 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 09/03/20 18:54 79-34-5 Tetrachloroethene ND ug/L 2.0 1 09/03/20 18:54 127-18-4 Toluene ND ug/L 1.0 1 09/03/20 18:54 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 09/0312018:54 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 09/0312018:54 79-00-5 Trichloroethene ND ug/L 2.0 1 09/03/20 18:54 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 09/03/20 18:54 75-69-4 Vinyl chloride ND ug/L 2.0 1 09/03/20 18:54 75-01-4 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 09/03/20 18:54 460-00-4 HS Toluene-d8 (S) 101 % 70-130 1 09/03/20 18:54 2037-26-5 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 09/03/20 18:54 17060-07-0 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 10.1 mg/L 2.5 1 09/03/20 19:17 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 6.0 Std. Units 0.10 1 09/06/20 13:51 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 35 (:!;5'neAna1j6ca1 www.pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Offsite 3 Lab ID: 92493437005 Collected: 08/31/20 09:16 Received: 09/01/20 14:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 4.9 1 09/09/20 08:43 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:38 7440-50-8 Lead ND ug/L 5.0 1 09/02/20 01:33 09/02/20 21:38 7439-92-1 Zinc 42.1 ug/L 10.0 1 09/02/20 01:33 09/02/20 21:38 7440-66-6 BC 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 83-32-9 Acenaphthylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 208-96-8 Anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 120-12-7 Benzidine ND ug/L 50.0 1 09/04/20 07:09 09/04/20 18:26 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 91-58-7 2-Chlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 7005-72-3 Chrysene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 120-83-2 Diethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 105-67-9 Dimethylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 09/04/20 07:09 09/04/20 18:26 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 122-66-7 L1 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 117-81-7 Fluoranthene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 206-44-0 Fluorene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 87-68-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 35 (�IaceAnalyfical www,pacelabs.com ANALYTICAL RESULTS Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Offsite 3 Parameters Lab ID: 92493437006 Collected: 08/31/20 09:16 Results Units Report Limit DF Received: 09/01/20 14:45 Matrix: Water Prepared Analyzed CAS No. Quaff 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Hexachlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 77-47-4 Hexachloroethane ND ug/L 6.0 1 09/04/20 07:09 09/04/20 18:26 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 09/04/20 07:09 09104/2018:26 193-39-5 Isophorone ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 78-69-1 Naphthalene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 91-20-3 Nitrobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 98-95-3 2-Nitrophenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 88-75-5 4-Nitrophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 86-30-6 Pentachlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 87-86-5 Phenanthrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 85-01-8 Phenol ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 108-95-2 Pyrene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 09/04/20 07:09 09/04/20 18:26 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 09/04/20 07:09 09/04/20 18:26 88-06-2 Surrogates Nitrobenzene-d5 (S) 50 % 10-120 1 09/04/20 07:09 09/04/20 18:26 4165-60-0 2-Fluorobiphenyl (S) 22 % 15-120 1 09/04/20 07:09 09/04/20 18:26 321-60-8 Terphenyl-d14 (S) 96 % 11-131 1 09/04/20 07:09 09/04/20 18:26 1718-51-0 Phenol-d6 (S) 35 % 10-120 1 09/04/20 07:09 09/04/20 18:26 13127-88-3 2-Fluorophenol (S) 51 % 10-120 1 09/04/20 07:09 09/04/20 18:26 367-12-4 2,4,6-Tribromophenol (S) 57 % 10-137 1 09/04/20 07:09 09/04/20 18:26 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 09103/2019:12 107-02-8 Acrylonitrile ND ug/L 5.0 1 09/03/2019:12 107-13-1 Benzene ND ug/L 1.0 1 09103/2019:12 71-43-2 Bromodichloromethane ND ug/L 2.0 1 09/03/2019:12 75-27-4 Bromoform ND ug/L 2.0 1 09/03/2019:12 75-25-2 Bromomethane ND ug/L 2.0 1 09/03/2019:12 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 09/03/20 19:12 56-23-5 Chlorobenzene ND ug/L 2.0 1 09/03/2019:12 108-90-7 Chloroethane ND ug/L 2.0 1 09/03/2019:12 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 09/03/20 19:12 110-75-8 c3 Chloroform ND ug/L 2.0 1 09103/2019:12 67-66-3 Chloromethane ND ug/L 2.0 1 09/03/2019:12 74-87-3 Dibromochloromethane ND ug/L 2.0 1 09/03/2019:12 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 09/03/2019:12 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 09/03/2019:12 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 09/03/2019:12 106-46-7 Dichlorodifluoromethane ND ug/L 2.0 1 09/03/2019:12 75-71-8 1,1-Dichloroethane ND ug/L 2.0 1 09/03/2019:12 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 35 laaceAnalj4ical www.pacelabs.com Project: RBTC Stormwater Pace Project No.: 92493437 Sample: Offsite 3 Parameters 624 Volatile Organics Acrolein 1,2-Dichloroethane 1,1-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1, 3-Dichloropropene trans-1, 3-Dichloropropene Ethylbenzene Methylene Chloride Naphthalene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl chloride Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 2540D Total Suspended Solids Total Suspended Solids 9040 pH pH at 25 Degrees C Date: 09/09/2020 03:20 PM Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Lab ID: 92493437006 Collected: 08/31/20 09:16 Received: 09/01/20 14:45 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 102 % 101 % 101 % Analytical Method: SM 2540D-2011 Pace Analytical Services -Asheville 20.2 mg/L Analytical Method: EPA 9040C Pace Analytical Services - Asheville 6.1 Std. Units 2.0 1 09/03/20 19:12 107-06-2 2.0 1 09/03/20 19:12 75-35-4 2.0 1 09/03/20 19:12 156-60-5 2.0 1 09/03/20 19:12 78-87-5 2.0 1 09/03/20 19:12 10061-01-5 2.0 1 09/03/20 19:12 10061-02-6 1.0 1 09/03/20 19:12 100-41-4 2.0 1 09/03/20 19:12 75-09-2 5.0 1 09/03/20 19:12 91-20-3 2.0 1 09/03/20 19:12 79-34-5 2.0 1 09/03/20 19:12 127-18-4 1.0 1 09/03/20 19:12 108-88-3 2.0 1 09/03/20 19:12 71-55-6 2.0 1 09/03/20 19:12 79-00-5 2.0 1 09/0312019:12 79-01-6 2.0 1 09/03/20 19:12 75-69-4 2.0 1 09/03/20 19:12 75-01-4 70-130 1 09/03/20 19:12 460-00-4 70-130 1 09/0312019:12 2037-26-5 70-130 1 09/03/20 19:12 17060-07-0 5.0 1 09/03/20 19:17 0.10 1 09/06/20 13:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. HS H3 Page 18 of 35 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 QC Batch: 565178 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 METHOD BLANK: 2995378 Matrix: Water Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L NO 5.0 09/09/20 08:38 LABORATORY CONTROL SAMPLE: 2995379 Parameter Units Total Petroleum Hydrocarbons mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 20 14.0 70 64-132 MATRIX SPIKE SAMPLE: 2995380 92493352001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L ND 20 9.5 32 64-132 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 35 lacmnalj4ical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 QC Batch: 563902 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 METHOD BLANK: 2989407 Matrix: Water Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper ug/L ND 5.0 09/02/20 20:46 Lead ug/L NO 5.0 09/02/20 20:46 Zinc ug/L ND 10.0 09/02/20 20:46 BC Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2989408 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Copper ug/L 500 509 102 85-115 Lead ug/L 500 507 101 85-115 Zinc ug/L 500 497 99 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2989409 2989410 MS MSD 92493301001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper ug/L ND 500 500 530 545 105 108 70-130 3 Lead ug/L ND 500 500 504 514 100 102 70-130 2 Zinc ug/L 53.2 500 500 560 566 101 103 70-130 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2989411 2989412 MS MSD 92493072001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper ug/L ND 500 500 544 536 108 106 70-130 2 Lead ug/L ND 500 500 523 513 105 103 70-130 2 Zinc ug/L 0.42 500 500 949 932 107 103 70-130 2 mg/L Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, I.I.C. Page 20 of 35 aceAnalytical www.pacolabs.com Project: RBTC Stormwater Pace Project No.: 92493437 QC Batch: 563944 QC Batch Method: EPA 624.1 QUALITY CONTROL DATA Analysis Method: EPA 624.1 Analysis Description: 624 MSV with Acrolein Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 METHOD BLANK: 2989527 Matrix: Water Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1-Trichloroethane ug/L ND 2.0 09/03/20 17:25 1,1,2,2-Tetrachloroethane ug/L ND 2.0 09/03/20 17:25 1,1,2-Trichloroethane ug/L ND 2.0 09/03/20 17:25 1,1-Dichloroethane ug/L ND 2.0 09/03/20 17:25 1,1-Dichloroethene ug/L ND 2.0 09103/2017:25 1,2-Dichlorobenzene ug/L ND 2.0 09/03/20 17:25 1,2-Dichloroethane ug/L ND 2.0 09/03/20 17:25 1,2-Dichloropropane ug/L ND 2.0 09/03/20 17:25 1,3-Dichlorobenzene ug/L ND 2.0 09/03/20 17:25 1,4-Dichlorobenzene ug/L ND 2.0 09/03/20 17:25 2-Chloroethylvinyl ether ug/L ND 5.0 09/03/20 17:25 Acrolein ug/L ND 5.0 09/03/20 17:25 Acrylonitrile ug/L ND 5.0 09/03/2017:26 Benzene ug/L ND 1.0 09/0312017:25 Bromodichloromethane ug/L ND 2.0 09/03/20 17:25 Bromoform ug/L ND 2.0 09/03/20 17:25 Bromomethane ug/L ND 2.0 09/03/20 17:25 Carbon tetrachloride ug/L ND 2.0 09/03/20 17:25 Chlorobenzene ug/L NO 2.0 09/03/20 17:25 Chloroethane ug/L ND 2.0 09/03/20 17:25 Chloroform ug/L ND 2.0 09/03/20 17:25 Chloromethane ug/L ND 2.0 09/03/20 17:25 cis-1,3-Dichloropropene ug/L ND 2.0 09/03/20 17:25 Dibromochloromethane ug/L ND 2.0 09/03/20 17:25 Dichlorodifluoromethane ug/L ND 2.0 09/03/20 17:25 Ethylbenzene ug/L ND 1.0 09/03/20 17:25 Methylene Chloride ug/L ND 2.0 09/03/20 17:25 Naphthalene ug/L ND 5.0 09/03/20 17:25 Tetrachloroethene ug/L ND 2.0 09/0312017:25 Toluene ug/L ND 1.0 09/03/20 17:25 trans-1,2-Dichloroethene ug/L ND 2.0 09/03/20 17:25 trans-1,3-Dichloropropene ug/L ND 2.0 09/03/20 17:25 Trichloroethene ug/L ND 2.0 09/03/20 17:25 Trichiorofluoromethane ug/L ND 2.0 09/03/20 17:25 Vinyl chloride ug/L NO 2.0 09/03/20 17:25 1,2-Dichloroethane-d4 (S) % 103 70-130 09/03/20 17:25 4-Bromofluorobenzene (S) % 101 70-130 09/03/20 17:25 Toluene-d8 (S) % 100 70-130 09/03/20 17:25 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 35 aceAnalytical a www.pacelabs.com Project: RBTC Stormwater Pace Project No.: 92493437 QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2989528 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1-Trichloroethane ug/L 20 20.9 105 70-130 1,1,2,2-Tetrachloroethane ug/L 20 20.7 104 60-140 1,1,2-Trichloroethane ug/L 20 22.0 110 70-130 1,1-Dichloroethane ug/L 20 19.9 99 70-130 1,1-Dichloroethene ug/L 20 20.0 100 50-150 1,2-Dichlorobenzene ug/L 20 21.5 108 65-135 1,2-Dichloroethane ug/L 20 19.7 98 49-155 1,2-Dichloropropane ug/L 20 20.7 103 35-165 1,3-Dichlorobenzene ug/L 20 21.2 106 70-130 1,4-Dichlorobenzene ug/L 20 21.7 109 65-135 2-Chloroethylvinyl ether ug/L 40 42.2 106 1-225 Acrolein ug/L 100 102 102 60-140 Acrylonitrile ug/L 100 98.9 99 60-140 Benzene ug/L 20 20.8 104 65-135 Bromodichloromethane ug/L 20 19.5 98 65-135 Bromoform ug/L 20 22.2 111 70-130 Bromomethane ug/L 20 18.0 90 15-185 Carbon tetrachloride ug/L 20 21.4 107 70-130 Chlorobenzene ug/L 20 20.7 104 65-135 Chloroethane ug/L 20 17.0 85 40-160 Chloroform ug/L 20 20.3 101 70-135 Chloromethane ug/L 20 15.8 79 1-205 cis-1,3-Dichloropropene ug/L 20 22.4 112 25-175 Dibromochloromethane ug/L 20 22.6 113 70-135 Dichlorodifluoromethane ug/L 20 16.5 83 70-130 Ethylbenzene ug/L 20 20.4 102 60-140 Methylene Chloride ug/L 20 17.8 89 60-140 Naphthalene ug/L 20 22.0 110 70-130 Tetrachloroethene ug/L 20 20.6 103 70-130 Toluene ug/L 20 20.2 101 70-130 trans-1,2-Dichloroethene ug/L 20 20.4 102 70-130 trans-1,3-Dichloropropene ug/L 20 21.0 105 50-150 Trichloroethene ug/L 20 21.0 105 65-135 Trichlorofluoromethane ug/L 20 17.8 89 50-150 Vinyl chloride ug/L 20 17.1 86 5-195 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2989529 2989530 MS MSD 92493437002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1-Trichloroethane ug/L ND 20 20 20.9 23.5 105 118 52-162 12 H1 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.3 21.0 102 105 46-157 3 H1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 35 aceAnalytical QD www.pacelabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2989529 2989530 MS MSD 92493437002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,2-Trichloroethane ug/L ND 20 20 21.6 21.7 108 109 52-150 1 H1 1,1-Dichloroethane ug/L ND 20 20 23.0 23.9 115 120 59-155 4 H1 1,1-Dichloroethene ug/L ND 20 20 21.5 23.9 108 119 1-234 10 H1 1,2-Dichlorobenzene ug/L ND 20 20 19.1 20.8 95 104 18-190 9 H1 1,2-Dichloroethane ug/L ND 20 20 22.0 22.1 110 110 49-155 0 H1 1,2-Dichloropropane ug/L ND 20 20 22.4 23.1 112 116 1-210 3 H1 1,3-Dichlorobenzene ug/L ND 20 20 18.2 20.4 91 102 59-156 11 H1 1,4-Dichlorobenzene ug/L ND 20 20 17.9 20.7 89 103 18-190 14 H1 2-Chloroethylvinyl ether ug/L ND 40 40 43.4 45.8 109 114 1-306 5 H1 Acrolein ug/L ND 100 100 21.4 18.4 21 18 40-160 15 H1,M1 Acrylonitrile ug/L ND 100 100 114 115 114 115 40-160 1 H1 Benzene ug/L ND 20 20 20.8 23.0 104 115 37-151 10 H1 Bromodichloromethane ug/L ND 20 20 19.5 20.7 98 103 35-155 6 H1 Bromoform ug/L ND 20 20 19.4 20.8 97 104 45-169 7 H1 Bromomethane ug/L ND 20 20 27.0 28.4 135 142 1-242 5 H1 Carbon tetrachloride ug/L ND 20 20 17.5 21.4 88 107 70-140 20 H1 Chlorobenzene ug/L ND 20 20 18.6 22.0 93 110 37-160 17 H1 Chloroethane ug/L ND 20 20 21.3 22.0 106 110 14-230 3 H1 Chloroform ug/L ND 20 20 22.4 23.2 112 116 51-138 4 H1 Chloromethane ug/L ND 20 20 20.4 20.8 102 104 1-273 2 H1 cis-1,3-Dichloropropene ug/L ND 20 20 20.5 21.4 103 107 1-227 4 H1 Dibromochloromethane ug/L ND 20 20 20.9 22.6 104 113 53-149 8 H1 Dichlorodifluoromethane ug/L ND 20 20 14.7 16.3 73 82 70-130 11 H1 Ethylbenzene ug/L ND 20 20 17.2 21.4 86 107 37-162 22 H1 Methylene Chloride ug/L ND 20 20 20.4 21.1 102 106 1-221 4 H1 Naphthalene ug/L ND 20 20 20.4 20.9 102 104 70-130 2 H1 Tetrachloroethene ug/L ND 20 20 16.1 19.8 80 99 64-148 21 H1 Toluene ug/L ND 20 20 18.3 21.3 91 106 47-150 15 H1 trans-1,2-Dichloroethene ug/L ND 20 20 21.8 23.5 109 118 54-156 7 H1 trans-1,3-Dichloropropene ug/L ND 20 20 19.4 20.1 97 100 17-183 3 H1 Trichloroethene ug/L ND 20 20 19.5 23.2 98 116 70-157 17 H1 Trichlorofluoromethane ug/L ND 20 20 16.9 19.6 84 98 17-181 15 H1 Vinyl chloride ug/L ND 20 20 19.0 20.5 95 102 1-251 8 H1 1,2-Dichloroethane-d4 (S) % 103 99 70-130 4-Bromofluorobenzene (S) % 103 103 70-130 HS Toluene-d8 (S) % 98 99 70-130 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 35 aceAnalytical www.pecolabs.com Project: RBTC Stormwater Pace Project No.: 92493437 QC Batch: 564460 QUALITY CONTROL DATA Analysis Method: EPA 625.1 QC Batch Method: EPA 625.1 Analysis Description: 625 MSS Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 METHOD BLANK: 2992260 Matrix: Water Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 Blank Reporting Parameter Units Result Limit Analyzed 1,2,4-Trichlorobenzene ug/L ND 5.0 09/04/20 10:33 1,2-Diphenylhydrazine ug/L ND 5.0 09/04/20 10:33 2,4,6-Trichlorophenol ug/L NO 10.0 09/04/20 10:33 2,4-Dichlorophenol ug/L ND 5.0 09/04/20 10:33 2,4-Dimethylphenol ug/L ND 10.0 09/04/20 10:33 2,4-Dinitrophenol ug/L ND 50.0 09/04/20 10:33 2,4-Dinitrotoluene ug/L ND 5.0 09/04/20 10:33 2,6-Dinitrotoluene ug/L ND 5.0 09/04/20 10:33 2-Chloronaphthalene ug/L ND 5.0 09/04/20 10:33 2-Chlorophenol ug/L ND 5.0 09/04/20 10:33 2-Nitrophenol ug/L ND 5.0 09/04/20 10:33 3,3'-Dichlorobenzidine ug/L ND 10.0 09/04/20 10:33 4,6-Dinitro-2-methylphenol ug/L ND 10.0 09/04/20 10:33 4-Bromophenylphenyl ether ug/L ND 5.0 09/04/20 10:33 4-Chloro-3-methylphenol ug/L ND 5.0 09/04/20 10:33 4-Chlorophenylphenyl ether ug/L ND 5.0 09/04/20 10:33 4-Nitrophenol ug/L ND 10.0 09/04/20 10:33 Acenaphthene ug/L ND 5.0 09/04/20 10:33 Acenaphthylene ug/L ND 5.0 09/04/20 10:33 Anthracene ug/L ND 5.0 09/04/20 10:33 Benzidine ug/L ND 50.0 09/04/20 10:33 Benzo(a)anthracene ug/L ND 5.0 09/04/20 10:33 Benzo(a)pyrene ug/L ND 5.0 09/04/20 10:33 Benzo(b)fluoranthene ug/L ND 5.0 09/04/20 10:33 Benzo(g,h,i)perylene ug/L NO 5.0 09/04/20 10:33 Benzo(k)fluoranthene ug/L ND 5.0 09/04/20 10:33 bis(2-Chloroethoxy)methane ug/L ND 10.0 09/04/20 10:33 bis(2-Chloroethyl) ether ug/L ND 5.0 09/04/20 10:33 bis(2-Ethylhexyl)phthalate ug/L ND 5.0 09/04/20 10:33 Butylbenzylphthalate ug/L ND 5.0 09/04/20 10:33 Chrysene ug/L ND 5.0 09/04/20 10:33 Di-n-butylphthalate ug/L ND 5.0 09/04/20 10:33 Di-n-octylphthalate ug/L ND 5.0 09/04/20 10:33 Dibenz(a,h)anthracene ug/L ND 5.0 09/04/20 10:33 Diethylphthalate ug/L ND 5.0 09/04/20 10:33 Dimethylphthalate ug/L ND 5.0 09/04/20 10:33 Fluoranthene ug/L ND 5.0 09/04/20 10:33 Fluorene ug/L ND 5.0 09/04/20 10:33 Hexachloro-1,3-butadiene ug/L ND 5.0 09/0412010:33 Hexachlorobenzene ug/L ND 5.0 09/04/20 10:33 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 35 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 METHOD BLANK: 2992260 Matrix: Water Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Hexachlorocyclopentadiene ug/L ND 10.0 09/04/20 10:33 Hexachloroethane ug/L ND 5.0 09/04/20 10:33 Indeno(1,2,3-cd)pyrene ug/L ND 5.0 09/04/20 10:33 Isophorone ug/L ND 10.0 09/04/20 10:33 N-Nitroso-di-n-propylamine ug/L ND 5.0 09/04/20 10:33 N-Nitrosodimethylamine ug/L ND 5.0 09/04/20 10:33 N-Nitrosodiphenylamine ug/L ND 10.0 09/04/20 10:33 Naphthalene ug/L NO 5.0 09/04/20 10:33 Nitrobenzene ug/L ND 5.0 09/04/20 10:33 Pentachlorophenol ug/L ND 10.0 09/04/20 10:33 Phenanthrene ug/L ND 5.0 09/04/20 10:33 Phenol ug/L ND 5.0 09/04/20 10:33 Pyrene ug/L ND 5.0 09/04/20 10:33 2,4,6-Tribromophenol (S) % 90 10-137 09/04/20 10:33 2-Fluorobiphenyl (S) % 87 15-120 09/04/20 10:33 2-Fluorophenol (S) % 68 10-120 09/04/20 10:33 Nitrobenzene-d5 (S) % 102 10-120 09/04/20 10:33 Phenol-d6 (S) % 52 10-120 09/04/20 10:33 Terphenyl-d14 (S) % 129 11-131 09/04/20 10:33 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 2992261 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/L 50 37.6 75 44-142 1,2-Diphenylhydrazine ug/L 50 80.2 160 25-150 L1 2,4,6-Trichlorophenol ug/L 50 47.7 95 37-144 2,4-Dichlorophenol ug/L 50 50.7 101 1-191 2,4-Dimethylphenol ug/L 50 55.0 110 32-119 2,4-Dinitrophenol ug/L 250 288 115 1-181 2,4-Dinitrotoluene ug/L 50 56.8 114 39-139 2,6-Dinitrotoluene ug/L 50 58.0 116 50-158 2-Chloronaphthalene ug/L 50 46.3 93 60-118 2-Chlorophenol ug/L 50 49.8 100 23-134 2-Nitrophenol ug/L 50 52.6 105 29-182 3,3'-Dichlorobenzidine ug/L 100 105 105 1-262 4,6-Dinitro-2-methylphenol ug/L 100 112 112 1-181 4-Bromophenylphenyl ether ug/L 50 48.2 96 53-127 4-Chloro-3-methylphenol ug/L 100 107 107 22-147 4-Chlorophenylphenyl ether ug/L 50 45.5 91 25-158 4-Nitrophenol ug/L 250 180 72 1-132 Acenaphthene ug/L 50 47.9 96 47-145 Acenaphthylene ug/L 50 50.3 101 33-145 Anthracene ug/L 50 46.3 93 1-166 Benzidine ug/L 100 30.6J 31 10-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 35 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 LABORATORY CONTROL SAMPLE: Parameter 2992261 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Benzo(a)anthracene ug/L 50 51.6 103 33-143 Benzo(a)pyrene ug/L 50 52.5 105 17-163 Benzo(b)fluoranthene ug/L 50 56.3 113 24-159 Benzo(g,h,i)perylene ug/L 50 52.9 106 1-219 Benzo(k)fluoranthene ug/L 50 53.4 107 11-162 bis(2-Chloroethoxy)methane ug/L 50 52.1 104 33-184 bis(2-Chloroethyl) ether ug/L 50 51.3 103 12-158 bis(2-Ethylhexyl)phthalate ug/L 50 60.1 120 8-158 Butylbenzylphthalate ug/L 50 64.6 129 1-152 Chrysene ug/L 50 51.3 103 17-168 Di-n-butylphthalate ug/L 50 53.8 108 1-118 Di-n-octylphthalate ug/L 50 64.9 130 4-146 Dibenz(a,h)anthracene ug/L 50 53.7 107 1-227 Diethylphthaiate ug/L 50 54.2 108 1-114 Dimethylphthalate ug/L 50 52.0 104 1-112 Fluoranthene ug/L 50 50.3 101 26-137 Fluorene ug/L 50 49.3 99 59-121 Hexachloro-1,3-butadiene ug/L 50 32.0 64 24-116 Hexachlorobenzene ug/L 50 45.3 91 1-152 Hexachiorocyclopentadiene ug/L 50 34.9 70 25-150 Hexachloroethane ug/L 50 36.0 72 40-113 Indeno(1,2,3-cd)pyrene ug/L 50 53.0 106 1-171 Isophorone ug/L 50 53.9 108 21-196 N-Nitroso-di-n-propylamine ug/L 50 58.2 116 1-230 N-Nitrosodimethylamine ug/L 50 39.8 80 25-150 N-Nitrosodiphenylamine ug/L 50 51.9 104 25-150 Naphthalene ug/L 50 44.5 89 21-133 Nitrobenzene ug/L 50 50.6 101 35-180 Pentachlorophenol ug/L 100 101 101 14-176 Phenanthrene ug/L 50 49.9 100 54-120 Phenol ug/L 50 34.4 69 5-112 Pyrene ug/L 50 53.1 106 52-115 2,4,6-Tribromophenol (S) % 100 10-137 2-Fluorobiphenyl (S) % 91 15-120 2-Fluorophenol (S) % 72 10-120 Nitrobenzene-d5 (S) % 100 10-120 Phenol-d6 (S) % 62 10-120 Terphenyl-d14 (S) % 121 11-131 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)875-9092 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2992262 2992263 MS MSD 92482412025 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,2,4-Trichlorobenzene ug/L ND 50 50 39.0 37.5 78 75 44-142 4 1,2-Diphenylhydrazine ug/L ND 50 50 82.6 80.9 161 157 25-150 2 MO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 35 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersviile, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2992262 MS MSD 92482412025 Spike Spike Parameter Units Result Conc. Conc. 2992263 MS MSD MS MSD % Rec Result Result % Rec % Rec Limits RPD Qual 2,4,6-Trichlorophenol ug/L ND 50 50 45.4 43.3 91 87 37-144 5 2,4-Dichlorophenol ug/L ND 50 50 47.6 45.8 95 92 1-191 4 2,4-Dimethylphenol ug/L ND 50 50 54.4 52.0 102 97 32-119 5 2,4-Dinitrophenol ug/L ND 250 250 259 211 104 84 1-181 20 2,4-Dinitrotoluene ug/L ND 50 50 59.0 62.6 118 125 39-139 6 2,6-Dinitrotoluene ug/L ND 50 50 55.3 53.1 111 106 50-158 4 2-Chloronaphthalene ug/L ND 50 50 45.5 44.1 91 88 60-118 3 2-Chlorophenol ug/L ND 50 50 49.3 46.6 99 93 23-134 6 2-Nitrophenol ug/L ND 50 50 49.9 47.6 100 95 29-182 5 3,3'-Dichlorobenzidine ug/L ND 100 100 37.7 60.8 38 61 1-262 47 R1 4,6-Dinitro-2-methylphenol ug/L ND 100 100 107 96.2 107 96 1-181 10 4-Bromophenylphenyl ether ug/L ND 50 50 47.6 46.3 95 93 53-127 3 4-Chloro-3-methylphenol ug/L ND 100 100 141 137 141 137 22-147 3 4-Chlorophenylphenyl ether ug/L ND 50 50 44.3 43.0 89 86 25-158 3 4-Nitrophenol ug/L ND 250 250 197 175 79 70 1-132 12 Acenaphthene ug/L 131 50 50 121 154 -19 48 47-145 24 M1 Acenaphthylene ug/L ND 50 50 51.9 52.8 104 106 33-145 2 Anthracene ug/L ND 50 50 48.2 50.7 90 95 1-166 5 Benzidine ug/L ND 100 100 ND ND 0 0 10-130 M1 Benzo(a)anthracene ug/L ND 50 50 50.7 49.2 101 98 33-143 3 Benzo(a)pyrene ug/L ND 50 50 50.7 48.7 101 97 17-163 4 Benzo(b)fluoranthene ug/L ND 50 50 55.2 52.8 110 106 24-159 4 Benzo(g,h,i)perylene ug/L ND 50 50 50.2 47.7 100 95 1-219 5 Benzo(k)fluoranthene ug/L ND 50 50 50.9 47.9 102 96 11-162 6 bis(2-Chloroethoxy)methane ug/L ND 50 50 48.4 46.6 97 93 33-184 4 bis(2-Chloroethyl) ether ug/L ND 50 50 50.4 47.7 101 95 12-158 5 bis(2-Ethylhexyl)phthalate ug/L ND 50 50 61.2 59.3 122 119 8-158 3 Butylbenzylphthalate ug/L ND 50 50 63.1 61.0 126 122 1-152 3 Chrysene ug/L ND 50 50 50.0 48.8 100 98 17-168 2 Di-n-butylphthalate ug/L ND 50 50 54.7 51.5 109 103 1-118 6 Di-n-octylphthalate ug/L ND 50 50 66.8 65.4 134 131 4-146 2 Dibenz(a,h)anthracene ug/L ND 50 50 49.5 48.8 99 98 1-227 1 Diethylphthalate ug/L ND 50 50 52.2 49.8 104 100 1-114 5 Dimethylphthalate ug/L ND 50 50 48.2 46.6 96 93 1-112 3 Fluoranthene ug/L ND 50 50 51.4 52.5 99 101 26-137 2 Fluorene ug/L 62.2 50 50 85.0 110 46 96 59-121 26 M1 Hexachloro-1,3-butadiene ug/L ND 50 50 34.4 33.3 69 67 24-116 3 Hexachlorobenzene ug/L ND 50 50 47.0 45.3 94 91 1-152 4 Hexachlorocyclopentadiene ug/L ND 50 50 36.2 33.5 72 67 25-150 8 Hexachloroethane ug/L ND 50 50 38.9 36.3 78 73 40-113 7 Indeno(1,2,3-cd)pyrene ug/L ND 50 50 50.7 48.7 101 97 1-171 4 Isophorone ug/L ND 50 50 48.7 46.5 97 93 21-196 5 N-Nitroso-di-n-propylamine ug/L ND 50 50 54.8 51.4 110 103 1-230 6 N-Nitrosodimethylamine ug/L ND 50 50 43.1 40.6 86 81 25-150 6 N-Nitrosodiphenylamine ug/L ND 50 50 52.2 57.2 104 114 25-150 9 Naphthalene ug/L 1190 50 50 741 789 -899 -805 21-133 6 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 35 laneAnalyfical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2992262 2992263 MS MSD 92482412025 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrobenzene ug/L ND 50 50 47.1 45.5 94 91 35-180 4 Pentachlorophenol ug/L ND 100 100 103 95.3 103 95 14-176 8 Phenanthrene ug/L 24.6 50 50 66.2 88.8 83 128 54-120 29 M1 Phenol ug/L ND 50 50 43.1 39.8 86 80 5-112 8 Pyrene ug/L ND 50 50 54.1 54.7 104 106 52-115 1 2,4,6-Tribromophenol (S) % 99 94 10-137 2-Fluorobiphenyl (S) % 85 82 15-120 2-Fluorophenol (S) % 76 70 10-120 Nitrobenzene-d5 (S) % 89 85 10-120 Phenol-d6 (S) % 73 69 10-120 Terphenyl-d14(S) % 119 114 11-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 35 (�IaoeAnalyfical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 QC Batch: 564431 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 METHOD BLANK: 2992067 Matrix: Water Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 09/03/20 19:13 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2992068 Spike LCS LCS %Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 240 96 90-110 SAMPLE DUPLICATE: 2992069 Parameter Units Total Suspended Solids mg/L SAMPLE DUPLICATE: 2992245 Parameter Units Total Suspended Solids mg/L 92493457001 Dup Result Result RPD Qualifiers 280 236 17 92493471001 Dup Result Result RPD Qualifiers 5840 5890 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 35 acmnalytical www.pacolabs.com QUALITY CONTROL DATA Project: RBTC Stormwater Pace Project No.: 92493437 QC Batch: 564816 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92493437001, 92493437002, 92493437003, 92493437004, 92493437005 SAMPLE DUPLICATE: 2993984 92492996001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 7.2 7.3 1 H3 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2020 03:20 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 35 Pace Analytical Services, LLC 0 9800 Kincey Ave. Suite 100 aceAnalXical Huntersville, NC 28078 www.pacolabs.com (704)875-9092 QUALIFIERS Project: RBTC Stormwater Pace Project No.: 92493437 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS 1g Re -extraction conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time. 2g Run with more compliant surrogate recovery is out of hold. Sample was clean on both runs. BC The same analyte was detected in an associated blank at a concentration above 1/2 the reporting limit but below the laboratory reporting limit. H1 Analysis conducted outside the EPA method holding time. H3 Sample was received or analysis requested beyond the recognized method holding time. HS Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter). L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. c3 Analysis of 2-chloroethyl vinyl ether was performed from a sample that was field preserved to pH < 2 with HCI. Acid preservation is not allowed for this parameter by the test method or for NPDES compliance per 40CFR Part 136. Date: 09/09/2020 03:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 35 (� aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: RBTC Stormwater Pace Project No.: 92493437 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92493437001 Ouffall 1 EPA 1664E 565178 92493437002 Ouffall 3 EPA 1664E 565178 92493437003 Offsite 1 EPA 1664B 565178 92493437004 Offsite 2 EPA 1664B 565178 92493437005 Offsite 3 EPA 1664E 565178 92493437001 Ouffall 1 EPA 200.7 Rev 4.4 1994 563902 EPA 200.7 Rev 4.4 1994 563927 92493437002 Ouffall 3 EPA 200.7 Rev 4.4 1994 563902 EPA 200.7 Rev 4.4 1994 563927 92493437003 Offsite 1 EPA 200.7 Rev 4.4 1994 563902 EPA 200.7 Rev 4.4 1994 563927 92493437004 Offsite 2 EPA 200.7 Rev 4.4 1994 563902 EPA 200.7 Rev 4.4 1994 563927 92493437006 Offsite 3 EPA 200.7 Rev 4.4 1994 563902 EPA 200.7 Rev 4.4 1994 563927 92493437001 Ouffall 1 EPA 625.1 564460 EPA 625.1 564546 92493437002 Ouffall 3 EPA 625.1 564460 EPA 625.1 564546 92493437003 Offsite 1 EPA 625.1 564460 EPA 625.1 564546 92493437004 Offsite 2 EPA 625.1 564460 EPA 625.1 564546 92493437006 Offsite 3 EPA 625.1 564460 EPA 625.1 564546 92493437001 Ouffall 1 EPA 624.1 563944 92493437002 Ouffall 3 EPA 624.1 563944 92493437003 Offsite 1 EPA 624.1 563944 92493437004 Offsite 2 EPA 624.1 563944 92493437005 Offsite 3 EPA 624.1 563944 92493437001 Ouffall 1 SM 254OD-2011 564431 92493437002 Ouffall 3 SM 254OD-2011 564431 92493437003 Offsite 1 SM 254OD-2011 564431 92493437004 Offsite 2 SM 254OD-2011 564431 92493437005 Offsite 3 SM 254OD-2011 564431 92493437001 Ouffall 1 EPA 9040C 564816 92493437002 Ouffall 3 EPA 9040C 564816 92493437003 Offsite 1 EPA 9040C 564816 92493437004 Offsite 2 EPA 9040C 564816 92493437005 Offsite 3 EPA 9040C 564816 Date: 09/09/2020 03:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 35 Oocument Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SCUR) Pa e 1 of 2 IytlCal h Document No.: is Authority: n.9 a.,.. rsc Pace Carolinas Quality Office .".... -t— Gun ID: � 921Ufai Cooler Temp (`C): L -11 Correction Factor: Add/Subtract (`C) 0.0 Temp should be above freezing to 6`C Cooler Temp Corrected (`Cj: 2 ❑Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Wil ( N/A, water sample) Did samples originate in a arantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreignsource (internationally, IndudlnaHawali and Puerto RicoIco)?? [Yes ONO Chain of Custody Present? °' — .— I — Samples Arrived wfthin Hoid lime? Yes ONO NIA 2. Short Hold Time Analysis 02 hr.)? Oyes o ON/A 3. Rush Turn Around Time Requested? OY. IhN. N/A A. Sufficient Volume? %Yes (]No N/A S. Correct Containers Used? -Oyes ❑No QN/A 6. -Pace Containers Used? Yes ONo ON/A Containers Intact? es ONG N A 7. Dissolved analysis: Samples Field Filtered? OYes o N/A 8. Sample Labels Match COL? es No j]N/A 4• -includes0ate/Time/i0/Analysis Matrix: Headspace in VQA Vials >S-5mm)? es No N/A 10• Trip Blank Present? QYes ❑No JEJ�/A 11. Trio Blank Custody Seats Present? [Yes No /A COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Date/Time: Date: Date: Project Manager SRF Review: Field Data Required? Oyes ❑No Page 33 of 35 u FE a - aceAOalytical Document Name: Sample Condition Upon Recei t(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No.: F-CAR-CS-033-Rev.06 issuing Authority: Pace Carolinas Quality Office "Check mark top half of box If pH and/or dechlorination is Project # I verified and within the acceptance range for preservation samples. PM: EY Die Date: D9fA912C Exceptions: VOA, Coliform, TOC, Oil and Grease, DR0/801S (water) DOC, LLHg CZiENT: 92- fer, I ta,e "Bottom half of box is to list number of bottle $ j�fj -- a c a M J E Vf N O a m n c > u J E a N a m a c > u J E, Y? 101,1 � a m a n c O. ti 7 m u O +"� = a J E of lil m VnN O Z S a J E � N 2 �' m O z 3 N u o. J E %n .N-i N d -- NC_`Y O m z r a �! E N rNi m obi T� L E v y� LL G a a c ¢ : - r-1 t4 H ° u x Q °: - ry5f ei t7 H u Z Z �i c O E QJ E In N l H v n �i N 2 Q v -' ,r}i t9 H V = 2 G n E 0 VNN� M t9 Q Fzi E d J E N _ l7 H V O > J E O q inOat tb9 a z Ln A O > J E p q t� > I- ? a O > J E O �qj t9 7 O > J E O q t9 G z o ui N t0 � O > Y a > g v �. 7 J E N i'.+ a % Q z J E Ln N a vt r; vv x J E � z CL c E p O 6 9 o E O = ? z a c J E q �J C lr �g 2+7- 2 1 2- 3 4 NX\\� NNN 6 7 S 9 10 u 12 PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of preservative added Lot # ,.,:u hn �e�t rr, rho Nnrth raroiina DEHNR Certirution Office (i.e. Note: Whenever there is a discrepancy aueumg,w-u, emu,—". • - — - Out of hold, incorrect preservative, out of temp, incorrect containers. Page 35 of 35 (�IaceAnalXicaf' www.pacelabs.com August 11, 2020 Glenn Magley Heritage Environmental 7901 W Morris St Indianapolis, IN 46231 RE: Project: RBTC STORMWATER Pace Project No.: 92489086 Dear Glenn Magley: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on August 04, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NEIAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Bonnie Vang bonnie.vang@pacelabs.com (704)875-9092 Project Manager Enclosures P At REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 43 leAnalytical www.pacelabs.com Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersviile, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 43 leAnalyfical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92489086 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92489086001 OUTFALL 1 EPA 1664E JSG 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C ECH 1 PASI-A 92489086002 OUTFALL 3 EPA 1664B JSG 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C ECH 1 PASI-A 92489086003 OFFSITE 1 EPA 1664E JSG 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C ECH 1 PASI-A 92489086004 OFFSITE 2 EPA 1664B JSG 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PASI-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C ECH 1 PASI-A 92489086005 OFFSITE 3 EPA 1664B JSG 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A EPA 625.1 PKS 58 PAS►-C EPA 624.1 SAS 34 PASI-C SM 254OD-2011 RED 1 PASI-A EPA 9040C ECH 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 43 Pace Analytical Services, LLC laneAnalj4ical 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Sample: OUTFALL 1 Lab ID: 92489086001 Collected: 08/03/20 16:23 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 08/05/20 11:47 608 PCB Pest RVE Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte Aldrin ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 309-00-2 alpha-BHC ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 319-84-6 beta-BHC ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 319-85-7 delta-BHC ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 58-89-9 Chlordane (Technical) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 57-74-9 alpha -Chlordane ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 5103-71-9 gamma -Chlordane ND ug/L 0,050 1 08/07/20 09:41 08/10/20 16:05 5103-74-2 4,4'-DDD ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 72-54-8 4,4'-DDE ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 72-55-9 4,4'-DDT ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 50-29-3 Dieldrin ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 60-57-1 Endosulfan I ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 959-98-8 Endosulfan II ND ug/L 0.050 1 08/07/20 09:41 08/10120 16:05 33213-65-9 Endosulfan sulfate ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 1031-07-8 Endrin ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 72-20-8 Endrin aldehyde ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 7421-93-4 Heptachlor ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 76-44-8 Heptachlor epoxide ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:05 1024-57-3 PCB-1016 (Aroclor 1016) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.60 1 08/07/20 09:41 08/10/20 16:05 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 11096-82-5 PCB, Total ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 1336-36-3 Toxaphene ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:05 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 57 % 10-130 1 08/07/20 09:41 08/10/20 16:05 877-09-8 Decachlorobiphenyl (S) 59 % 10-130 1 08/07/20 09:41 08/10/20 16:05 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper ND ug/L 5.0 1 08/05/20 01:12 08/06/20 00:08 7440-50-8 Lead ND ug/L 5.0 1 08/05/20 01:12 08/06/20 00:08 7439-92-1 Zinc 62.6 ug/L 10.0 1 08/05/20 01:12 08/06/20 00:08 7440-66-6 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 43 aceAnalytical www.pecolobs.com i ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 1 lab ID: 92489086001 Collected: 08/03/20 16:23 Receiveo: Ufsiu4izu -n:zo wiatnx: vvdtul Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 208-96-8 Anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 91-58-7 2-Chlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 7005-72-3 Chrysene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 120-83-2 Diethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 105-67-9 Dimethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 08/06/20 13:26 08/06/20 20:43 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 117-81-7 Fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 206-44-0 Fluorene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 77-47-4 Hexachloroethane ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 193-39-5 Isophorone ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 78-59-1 Naphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 91-20-3 Nitrobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 98-95-3 2-Nitrophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 88-75-5 4-Nitrophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 62-76-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 108-60-1 Pentachlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 43 laneAnalyfical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 1 Parameters Lab ID: 92489086001 Collected: 08/03/20 16:23 Results Units Report Limit DF Received: 08/04/20 11:26 Matrix: Water Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 85-01-8 Phenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 108-95-2 Pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 129-00-0 1,2,4-Trichoorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 20:43 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 20:43 88-06-2 Surrogates Nitrobenzene-d5 (S) 38 % 10-120 1 08/06/20 13:26 08/06/20 20:43 4165-60-0 2-Fluorobiphenyl (S) 35 % 15-120 1 08/06/20 13:26 08/06/20 20:43 321-60-8 Terphenyl-d14 (S) 87 % 11-131 1 08/06/20 13:26 08/06/20 20:43 1718-51-0 Phenol-d6 (S) 21 % 10-120 1 08/06/20 13:26 08/06/20 20:43 13127-88-3 2-Fluorophenol (S) 27 % 10-120 1 08/06/20 13:26 08/06/20 20:43 367-12-4 2,4,6-Tribromophenol (S) 56 % 10-137 1 08/06/20 13:26 08/06/20 20:43 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 08/05/20 12:55 71-43-2 Bromodichloromethane ND ug/L 2.0 1 08/05/20 12:55 75-27-4 Bromoform ND ug/L 2.0 1 08/05/20 12:55 75-25-2 Bromomethane ND ug/L 2.0 1 08/05/20 12:55 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 08/05/20 12:55 56-23-5 Chlorobenzene ND ug/L 2.0 1 08/05/20 12:55 108-90-7 Chloroethane ND ug/L 2.0 1 08/05/20 12:55 75-00-3 Chloroform ND ug/L 2.0 1 08/0512012:55 67-66-3 Chloromethane ND ug/L 2.0 1 08/05/20 12:55 74-87-3 Dibromochloromethane ND ug/L 2.0 1 08/05/20 12:55 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 08/05/20 12:55 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 08/0512012:55 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 08/05/20 12:55 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 08/05/20 12:55 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 08/05/20 12:55 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 08/05/20 12:55 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 12:55 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 12:55 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 08/05/20 12:55 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 12:55 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 12:55 10061-02-6 Ethylbenzene ND ug/L 1.0 1 08/05/20 12:55 100-41-4 Methylene Chloride ND ug/L 2.0 1 08/05/20 12:65 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 08/05/20 12:55 79-34-5 Tetrachloroethene ND ug/L 2.0 1 08/05/20 12:55 127-18-4 Toluene ND ug/L 1.0 1 08/05/20 12:55 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 08/05/20 12:55 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 08/05/20 12:55 79-00-5 Trichloroethene ND ug/L 2.0 1 08105/2012:55 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 08/05/20 12:55 75-69-4 Vinyl chloride ND ug/L 2.0 1 08/05/20 12:55 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 43 IaceAnalyfica(�l www.pacelabs,com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 1 Lab ID: 92489086001 Collected: 08/03/20 16:23 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-eromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 2540D Total Suspended Solids Total Suspended Solids 9040 pH pH at 25 Degrees C Date: 08/11/2020 11:51 AM 98 % 70-130 1 08/05/2012:55 460-00-4 HS 100 % 70-130 1 08/05/2012:55 2037-26-5 101 % 70-130 1 08/05/2012:55 17060-07-0 Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville 8.6 mg/L 2.5 1 08/06/2018:32 Analytical Method: EPA 9040C Pace Analytical Services - Asheville 4.6 Std. Units 0.10 1 08/09/20 17:39 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 43 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 3 Lab ID: 92489086002 Collected: 08/03/20 16:35 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 608 PCB Pest RVE Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) alpha -Chlordane gamma -Chlordane 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan 1 Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) PCB, Total Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 RVE Acenaphthene Date: 08/11/2020 11:51 AM Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte 08/05/20 11:48 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 309-00-2 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 319-84-6 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 319-85-7 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 319-86-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 58-89-9 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 57-74-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 5103-71-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 5103-74-2 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 72-54-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 72-55-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 50-29-3 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 60-57-1 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 959-98-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 33213-65-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 1031-07-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 72-20-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 7421-93-4 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 76-44-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:19 1024-57-3 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 12674-11-2 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 11104-28-2 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 11141-16-5 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 53469-21-9 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 12672-29-6 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 11097-69-1 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 11096-82-5 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 1336-36-3 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:19 8001-35-2 20 % 10-130 1 08/07/20 09:41 08/10/20 16:19 877-09-8 29 % 10-130 1 08/07/20 09:41 08/10/20 16:19 2051-24-3 Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville 8.1 ug/L 5.0 1 08/05/20 01:12 08/06/20 00:11 7440-50-8 ND ug/L 5.0 1 08/05/20 01:12 08/06/20 00:11 7439-92-1 149 ug/L 10.0 1 08/05/20 01:12 08/06/20 00:11 7440-66-6 Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 43 aceAnalytical ' www.pacelabs.com I ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 KinceyAve. Suite too Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 3 Lab ID: 92489086002 Collected: 08/03/20 16:35 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 208-96-8 Anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 91-58-7 2-Chlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 7005-72-3 Chrysene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 120-83-2 Diethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 105-67-9 Dimethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 08/06/20 13:26 08/06/20 21:12 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 117-81-7 Fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 206-44-0 Fluorene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 77-47-4 Hexachloroethane ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 193-39-5 Isophorone ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 78-59-1 Naphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 91-20-3 Nitrobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 98-95-3 2-Nitrophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 88-75-5 4-Nitrophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 108-60-1 Pentachlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 43 lacmnalj4ical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 3 Lab iD: 92489086002 Collected: 08/03/20 16:35 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 85-01-8 Phenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 108-95-2 Pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:12 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:12 88-06-2 Surrogates Nitrobenzene-d5 (S) 67 % 10-120 1 08/06/20 13:26 08/06/20 21:12 4165-60-0 2-Fluorobiphenyl (S) 53 % 15-120 1 08/06/20 13:26 08/06/20 21:12 321-60-8 Terphenyl-04 (S) 112 % 11-131 1 08/06/20 13:26 08/06/20 21:12 1718-51-0 Phenol-d6 (S) 42 % 10-120 1 08/06/20 13:26 08/06/20 21:12 13127-88-3 2-Fluorophenol (S) 49 % 10-120 1 08/06/20 13:26 08/06/20 21:12 367-12-4 2,4,6-Tribromophenol (S) 105 % 10-137 1 08/06/20 13:26 08/06/20 21:12 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 08/05/20 14:06 71-43-2 Bromodichloromethane ND ug/L 2.0 1 08/05/20 14:06 75-27-4 Bromoform ND ug/L 2.0 1 08/05/20 14:06 75-25-2 Bromomethane ND ug/L 2.0 1 08/05/20 14:06 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 08/05/20 14:06 56-23-5 Chiorobenzene ND ug/L 2.0 1 08/05/20 14:06 108-90-7 Chloroethane ND ug/L 2.0 1 08/05/20 14:06 75-00-3 Chloroform ND ug/L 2.0 1 08/05/20 14:06 67-66-3 Chloromethane ND ug/L 2.0 1 08/05/20 14:06 74-87-3 Dibromochloromethane ND ug/L 2.0 1 0810512014:06 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:06 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:06 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:06 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 08/05/20 14:06 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 08/05/20 14:06 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 08/05/20 14:06 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 14:06 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 14:06 156-60-5 1,2-Dichioropropane ND ug/L 2.0 1 08/05/20 14:06 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 14:06 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 08/0512014:06 10061-02-6 Ethylbenzene ND ug/L 1.0 1 08/05/20 14:06 100-41-4 Methylene Chloride ND ug/L 2.0 1 08/05/20 14:06 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 08105/2014:06 79-34-5 Tetrachloroethene ND ug/L 2.0 1 08/05/20 14:06 127-18-4 Toluene ND ug/L 1.0 1 08105/2014:06 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 08/06/20 14:06 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 08/05/20 14:06 79-00-5 Trichloroethene ND ug/L 2.0 1 08/05/20 14:06 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 08/05/20 14:06 75-69-4 Vinyl chloride ND ug/L 2.0 1 08/05/20 14:06 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 43 aceAnalytical @, www.pacelabs.com I ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OUTFALL 3 Lab ID: 92489086002 Collected: 08/03/20 16:35 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 2640D Total Suspended Solids Total Suspended Solids 9040 pH pH at 25 Degrees C Date: 08/11/2020 11:51 AM 95 % 70-130 1 08/05/2014:06 460-00-4 HS 98 % 70-130 1 08/05/2014:06 2037-26-5 100 % 70-130 1 08/05/2014:06 17060-07-0 Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville 36.1 mg/L 8.2 1 08/06/2018:32 Analytical Method: EPA 9040C Pace Analytical Services - Asheville 4.9 Std. Units 0.10 1 08/09/20 17:45 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 43 aceAnalytical www.pecolobs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 1 Lab ID: 92489086003 Collected: 08/03/20 16:13 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons Analytical Method: EPA 1664B Pace Analytical Services - Charlotte ND mg/L 5.0 1 08/05/2011:48 608 PCB Pest RVE Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte Aldrin ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 309-00-2 alpha-BHC ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 319-84-6 beta-BHC ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 319-85-7 delta-BHC ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 58-89-9 Chlordane (Technical) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 57-74-9 alpha -Chlordane ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 5103-71-9 gamma -Chlordane ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 5103-74-2 4,4'-DDD ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 72-54-8 4,4'-DDE ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 72-55-9 4,4'-DDT ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 50-29-3 Dieldrin ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 60-57-1 Endosulfan I ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 959-98-8 Endosulfan II ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 33213-65-9 Endosulfan sulfate ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 1031-07-8 Endrin ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 72-20-8 Endrin aldehyde ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 7421-93-4 Heptachlor ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 76-44-8 Heptachlor epoxide ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:34 1024-57-3 PCB-1016 (Aroclor 1016) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 12674-11-2 PCB-1221 (Aroclor 1221) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 11104-28-2 PCB-1232 (Aroclor 1232) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 11141-16-5 PCB-1242 (Aroclor 1242) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 53469-21-9 PCB-1248 (Aroclor 1248) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 12672-29-6 PCB-1254 (Aroclor 1254) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 11097-69-1 PCB-1260 (Aroclor 1260) ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 11096-82-5 PCB, Total ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 1336-36-3 Toxaphene ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:34 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 61 % 10-130 1 08/07/20 09:41 08/10/20 16:34 877-09-8 Decachlorobiphenyl (S) 84 % 10-130 1 08/07/20 09:41 08/10/20 16:34 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper 6.3 ug/L 5.0 1 08/05/20 01:12 08/06/20 00:14 7440-50-8 Lead ND ug/L 5.0 1 08/05/20 01:12 08/06/20 00:14 7439-92-1 Zinc 27.2 ug/L 10.0 1 08/05/20 01:12 08/06/20 00:14 7440-66-6 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 43 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 1 Parameters Lab lD: 92489086003 Collected: 08/03/20 16:13 Results Units Report Limit DF Received: 08/04/20 11:26 Matrix: Water Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 208-96-8 Anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 91-58-7 2-Chlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 7005-72-3 Chrysene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 120-83-2 Diethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 105-67-9 Dimethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 08/06/20 13:26 08/06/20 21:41 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 117-81-7 Fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 206-44-0 Fluorene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 77-47-4 Hexachloroethane ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 193-39-5 Isophorone ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 78-59-1 Naphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 91-20-3 Nitrobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 98-95-3 2-Nitrophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 88-75-5 4-Nitrophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 108-60-1 Pentachlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 43 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Sample: OFFSITE 1 Parameters Lab ID: 92489086003 Collected: 08/03/20 16:13 Results Units Report Limit DF Received: 08/04/20 11:26 Matrix: Water Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 85-01-8 Phenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 108-95-2 Pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 21:41 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 21:41 88-06-2 Surrogates Nitrobenzene-d5 (S) 70 % 10-120 1 08/06/20 13:26 08/06/20 21:41 4165-60-0 2-Fluorobiphenyl (S) 53 % 15-120 1 08/06/20 13:26 08/06/20 21:41 321-60-8 Terphenyl-d14 (S) 119 % 11-131 1 08/06/20 13:26 08/06/20 21:41 1718-51-0 Phenol-d6 (S) 41 % 10-120 1 08/06/20 13:26 08/06/20 21:41 13127-88-3 2-Fluorophenol (S) 42 % 10-120 1 08/06/20 13:26 08/06/20 21:41 367-12-4 2,4,6-Tdbromophenol (S) 76 % 10-137 1 08/06/20 13:26 08/06/20 21:41 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 08/05/20 14:24 71-43-2 Bromodichioromethane ND ug/L 2.0 1 08/05/20 14:24 75-27-4 Bromoform ND ug/L 2.0 1 08/05/20 14:24 75-25-2 Bromomethane ND ug/L 2.0 1 08/05/20 14:24 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 08/05/20 14:24 56-23-5 Chlorobenzene ND ug/L 2.0 1 08/05/20 14:24 108-90-7 Chloroethane ND ug/L 2.0 1 08/05/20 14:24 75-00-3 Chloroform ND ug/L 2.0 1 08/05/20 14:24 67-66-3 Chloromethane ND ug/L 2.0 1 08/05/20 14:24 74-87-3 Dibromochloromethane ND ug/L 2.0 1 08/05/20 14:24 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:24 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:24 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:24 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 08/05/20 14:24 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 08/0512014:24 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 08/05/20 14:24 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 14:24 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 14:24 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 08/05/20 14:24 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 08/0512014:24 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 14:24 10061-02-6 Ethylbenzene ND ug/L 1.0 1 08/05/20 14:24 100-41-4 Methylene Chloride ND ug/L 2.0 1 08/05/20 14:24 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 08/05/20 14:24 79-34-5 Tetrachloroethene ND ug/L 2.0 1 08/05/20 14:24 127-18-4 Toluene ND ug/L 1.0 1 08/05/20 14:24 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 08/05/20 14:24 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 08/05/20 14:24 79-00-5 Trichloroethene ND ug/L 2.0 1 08/05/20 14:24 79-01-6 Trichiorofluoromethane ND ug/L 2.0 1 08105/2014:24 75-69-4 Vinyl chloride ND ug/L 2.0 1 08/05/20 14:24 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, I.I.C. Page 14 of 43 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92489086 Sample: OFFSITE 1 Lab ID: 92489086003 Collected: 08/03/20 16:13 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 08/05/20 14:24 460-00-4 HS Toluene-d8 (S) 99 % 70-130 1 08/05/20 14:24 2037-26-5 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 08/05/20 14:24 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids ND mg/L 3.0 1 08/06/20 18:32 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 5.5 Std. Units 0.10 1 08/09/20 17:33 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:61 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 43 aceAnalytieal www.pecolobs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 2 Lab ID: 92489086004 Collected: 08/03/20 15:48 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Total Petroleum Hydrocarbons 608 PCB Pest RVE Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) alpha -Chlordane gamma -Chlordane 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) PCB, Total Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyi (S) Analytical Method: EPA 1664B Pace Analytical Services - Charlotte ND mg/L 5.0 1 08/05/2011:47 Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte ND ug/L 0,050 1 08/07/20 09:41 08/10/20 16:49 309-00-2 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 319-84-6 0.062 ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 319-85-7 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 319-86-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 58-89-9 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 57-74-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 5103-71-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 5103-74-2 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 72-54-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 72-55-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 50-29-3 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 60-57-1 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 959-98-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 33213-65-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 1031-07-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 72-20-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 7421-93-4 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 76-44-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 16:49 1024-57-3 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 12674-11-2 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 11104-28-2 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 11141-16-5 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 53469-21-9 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 12672-29-6 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 11097-69-1 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 11096-82-5 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 1336-36-3 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 16:49 8001-35-2 45 % 10-130 1 08/07/20 09:41 08/10/20 16:49 877-09-8 53 % 10-130 1 08/07/20 09:41 08/10/20 16:49 2051-24-3 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Copper 9.1 ug/L 5.0 1 08/05/20 01:12 08/06/20 00:17 7440-50-8 Lead ND ug/L 5.0 1 08/05/20 01:12 08/06/20 00:17 7439-92-1 Zinc 131 ug/L 10.0 1 08/05/20 01:12 08/06/20 00:17 7440-66-6 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 43 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 2 Parameters Lab ID: 92489086004 Collected: 08/03/20 15:48 Results Units Report Limit DF Received: 08/04/20 11:26 Matrix: Water Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 208-96-8 Anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 91-58-7 2-Chlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 7005-72-3 Chrysene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 120-83-2 Diethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 105-67-9 Dimethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 08/06/20 13:26 08/06/20 22:10 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 117-81-7 Fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 206-44-0 Fluorene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 77-47-4 Hexachloroethane ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 08/06/20 13:26 08106/2022:10 193-39-5 Isophorone ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 78-59-1 Naphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 91-20-3 Nitrobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 98-95-3 2-Nitrophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 88-75-5 4-Nitrophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 108-60-1 Pentachlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 43 aceAnalytical o www.pacolabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 2 Lab ID: 92489086004 Collected: 08/03/20 15:48 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 85-01-8 Phenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 108-95-2 Pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:10 129-00-0 1,2,4-Trichoorobenzene ND ug/L 6.0 1 08/06/20 13:26 08/06/20 22:10 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:10 88-06-2 Surrogates Nitrobenzene-d5 (S) 40 % 10-120 1 08/06/20 13:26 08/06/20 22:10 4165-60-0 2-Fluorobiphenyl (S) 35 % 15-120 1 08/06/20 13:26 08/06/20 22:10 321-60-8 Terphenyl-dl4 (S) 84 % 11-131 1 08/06/20 13:26 08/06/20 22:10 1718-51-0 Phenol-d6 (S) 22 % 10-120 1 08/06/20 13:26 08/06/20 22:10 13127-88-3 2-Fluorophenol (S) 28 % 10-120 1 08/06/20 13:26 08/06/20 22:10 367-12-4 2,4,6-Tribromophenol (S) 72 % 10-137 1 08/06/20 13:26 08/06/20 22:10 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 08/0512014:42 71-43-2 Bromodichloromethane ND ug/L 2.0 1 08/05/20 14:42 75-27-4 Bromoform ND ug/L 2.0 1 08/05/20 14:42 75-25-2 Bromomethane ND ug/L 2.0 1 08/05/20 14:42 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 08/05/20 14:42 56-23-5 Chlorobenzene ND ug/L 2.0 1 08/05/20 14:42 108-90-7 Chloroethane ND ug/L 2.0 1 08/05/20 14:42 75-00-3 Chloroform ND ug/L 2.0 1 08/05/20 14:42 67-66-3 Chloromethane ND ug/L 2.0 1 08/05/20 14:42 74-87-3 Dibromochloromethane ND ug/L 2.0 1 08/05/20 14:42 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:42 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:42 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 08/05/20 14:42 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 08/05/20 14:42 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 08/05/20 14:42 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 08/0512014:42 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 14:42 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 08105/2014:42 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 08/05/20 14:42 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 14:42 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 14:42 10061-02-6 Ethylbenzene ND ug/L 1.0 1 08/05/20 14:42 100-41-4 Methylene Chloride ND ug/L 2.0 1 08/05/20 14:42 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 08/05/20 14:42 79-34-5 Tetrachloroethene ND ug/L 2.0 1 08/05/20 14:42 127-18-4 Toluene ND ug/L 1.0 1 08/05/20 14:42 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 08/05/20 14:42 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 08/05/20 14:42 79-00-5 Trichloroethene ND ug/L 2.0 1 08/05/20 14:42 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 08/05/20 14:42 75-69-4 Vinyl chloride ND ug/L 2.0 1 08/05/20 14:42 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 43 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 2 lab ID: 92489086004 Collected: 08/03/20 15:48 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) 88 % 70-130 1 08/05/20 14:42 460-00-4 HS Toluene-d8 (S) 98 % 70-130 1 08/05/20 14:42 2037-26-5 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 08/05/20 14:42 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 37.9 mg/L 6.6 1 08/06/20 18:32 D6 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 5.3 Std. Units 0.10 1 08/09/20 17:16 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 43 laneAnalj4ical www.pacelabs.com ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 3 Lab ID: 92489086005 Collected: 08/03/20 16:00 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 608 PCB Pest RVE Aidrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) alpha -Chlordane gamma -Chlordane 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieidrin Endosulfan I Endosulfan II Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1264) PCB-1260 (Aroclor 1260) PCB, Total Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 200.7 MET ICP Copper Lead Zinc 625 RVE Acenaphthene Date: 08/11/2020 11:51 AM Analytical Method: EPA 608.3 Preparation Method: EPA 608.3 Pace Analytical Services - Charlotte 08/05/20 11:49 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 309-00-2 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 319-84-6 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 319-85-7 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 319-86-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 58-89-9 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 57-74-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 5103-71-9 ND ug/L 0,050 1 08/07/20 09:41 08/10/20 17:03 5103-74-2 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 72-54-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 72-55-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 50-29-3 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 60-57-1 0.10 ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 959-98-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 33213-65-9 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 1031-07-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 72-20-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 7421-93-4 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 76-44-8 ND ug/L 0.050 1 08/07/20 09:41 08/10/20 17:03 1024-57-3 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 12674-11-2 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 11104-28-2 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 11141-16-5 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 53469-21-9 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 12672-29-6 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 11097-69-1 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 11096-82-5 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 1336-36-3 ND ug/L 0.50 1 08/07/20 09:41 08/10/20 17:03 8001-35-2 40 % 10-130 1 08/07/20 09:41 08/10/20 17:03 877-09-8 67 % 10-130 1 08/07/20 09:41 08/10/20 17:03 2051-24-3 Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville 13.9 ug/L 5.0 1 08/05/20 01:12 08/06/20 00:21 7440-50-8 ND ug/L 5.0 1 08/05/20 01:12 08/06/20 00:21 7439-92-1 120 ug/L 10.0 1 08/05/20 01:12 08/06/20 00:21 7440-66-6 Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 83-32-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 43 aceAnalytical www.pacolobs.com i ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: OFFSITE 3 Lab ID: 92489086005 Collected: 08/03/20 16:00 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 208-96-8 Anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 91-58-7 2-Chlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 7005-72-3 Chrysene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 120-83-2 Diethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 105-67-9 Dimethylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 08/06/20 13:26 08/06/20 22:40 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 606-20-2 Di-n-octylphthalate ND ug/L 6.0 1 08/06/20 13:26 08/06/20 22:40 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 117-81-7 Fluoranthene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 206-44-0 Fluorene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 77-47-4 Hexachloroethane ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 193-39-5 Isophorone ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 78-59-1 Naphthalene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 91-20-3 Nitrobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 98-95-3 2-Nitrophenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 88-75-5 4-Nitrophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 108-60-1 Pentachlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 87-86-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 43 Pace Analytical Services, LLC aceAnalj&al ® 9800 KinceyAve. Suite 100 www.pacelabs.com Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: RBTC STORMWATER Pace Project No.: 92489086 Sample: OFFSITE 3 Lab ID: 92489086005 Collected: 08/03/20 16:00 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Phenanthrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 85-01-8 Phenol ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 108-95-2 Pyrene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 08/06/20 13:26 08/06/20 22:40 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 08/06/20 13:26 08/06/20 22:40 88-06-2 Surrogates Nitrobenzene-d5 (S) 46 % 10-120 1 08/06/20 13:26 08/06/20 22:40 4165-60-0 2-Fluorobiphenyl (S) 36 % 15-120 1 08/06/20 13:26 08/06/20 22:40 321-60-8 Terphenyl-d14 (S) 103 % 11-131 1 08/06/20 13:26 08/06/20 22:40 1718-51-0 Phenol-d6 (S) 29 % 10-120 1 08/06/20 13:26 08/06/20 22:40 13127-88-3 2-Fluorophenol (S) 31 % 10-120 1 08/06/20 13:26 08/06/20 22:40 367-12-4 2,4,6-Tribromophenol (S) 74 % 10-137 1 08/06/20 13:26 08/06/20 22:40 118-79-6 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Benzene ND ug/L 1.0 1 08105/2015:00 71-43-2 Bromodichloromethane ND ug/L 2.0 1 08/05/20 15:00 75-27-4 Bromoform ND ug/L 2.0 1 08/05/2016:00 75-25-2 Bromomethane ND ug/L 2.0 1 08/05/20 15:00 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 08/05/20 15:00 56-23-5 Chlorobenzene ND ug/L 2.0 1 08/05/20 15:00 108-90-7 Chloroethane ND ug/L 2.0 1 08/05/20 15:00 75-00-3 Chloroform ND ug/L 2.0 1 08/05/20 15:00 67-66-3 Chloromethane ND ug/L 2.0 1 08/05/20 15:00 74-87-3 Dibromochloromethane ND ug/L 2.0 1 08/05/20 15:00 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 08/05/20 15:00 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 08/05/20 15:00 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 08/0512015:00 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 08/05/20 15:00 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 08/0512015:00 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 08/05/20 15:00 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 15:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 08/05/20 15:00 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 08/05/20 15:00 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 15:00 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 08/05/20 15:00 10061-02-6 Ethylbenzene ND ug/L 1.0 1 08/05/20 15:00 100-41-4 Methylene Chloride ND ug/L 2.0 1 08/05/20 15:00 75-09-2 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 08/05/20 15:00 79-34-5 Tetrachloroethene ND ug/L 2.0 1 08/05/20 15:00 127-18-4 Toluene ND ug/L 1.0 1 08/05/20 15:00 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 08/05/20 15:00 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 08/05/20 15:00 79-00-5 Trichloroethene ND ug/L 2.0 1 08/05/20 15:00 79-01-6 Trichlorofluoromethane ND ug/L 2.0 1 08105/2015:00 75-69-4 Vinyl chloride ND ug/L 2.0 1 08/05/20 15:00 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 43 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92489086 Sample: OFFSITE 3 Lab ID: 92489086006 Collected: 08/03/20 16:00 Received: 08/04/20 11:26 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 08/05/20 15:00 HS Toluene-d8 (S) 98 % 70-130 1 2 037-26- 08/05/20 15:00 037-26-5 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 08/05/20 15:00 17060 07-0 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 44.2 mg/L 4.2 1 08/06/20 18:32 9040 pH Analytical Method: EPA 9040C Pace Analytical Services - Asheville pH at 25 Degrees C 6.0 Std. Units 0.10 1 08/09/20 17:28 H3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 43 aceAnaljftal www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 QC Batch: 557971 Analysis Method: EPA 1664E QC Batch Method: EPA 1664E Analysis Description: 1664 SGT-HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2960944 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 20 17.4 87 64-132 MATRIX SPIKE SAMPLE: 2960945 92487793001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L NO 20 13.9 68 64-132 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 43 (�IaaeAnalyfical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 QC Batch: 557904 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 METHOD BLANK: 2960761 Matrix: Water Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper ug/L ND 5.0 08/05/20 20:31 Lead ug/L ND 5.0 08/05/20 20:31 Zinc ug/L ND 10.0 08/06/2012:40 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2960762 Spike LCS LCS °lo Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper ug/L 500 502 100 85-115 Lead ug/L 500 474 95 85-115 Zinc ug/L 500 454 91 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2960765 MS 92489056001 Spike Parameter Units Result Conc. Copper ug/L 0.0070 500 mg/L Lead ug/L ND 500 Zinc ug/L 0.054 500 mg/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2960767 MS 92488981001 Spike Parameter Units Result Conc. Copper ug/L 15.9 500 Lead ug/L NO 500 Zinc ug/L 81.1 500 2960766 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD Qual 500 534 548 105 108 70-130 3 500 487 501 97 100 70-130 3 500 511 527 91 95 70-130 3 2960768 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD Qual 500 647 530 106 103 70-130 3 500 503 494 100 98 70-130 2 500 560 554 96 95 70-130 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 43 laneAnalj4ical www.pacolabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 QC Batch: 558010 Analysis Method: EPA 624.1 QC Batch Method: EPA 624.1 Analysis Description: 624 MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 METHOD BLANK: 2961052 Matrix: Water Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1-Trichloroethane ug/L ND 2.0 08/05/20 11:44 1,1,2,2-Tetrachloroethane ug/L ND 2.0 08/05/20 11:44 1,1,2-Trichloroethane ug/L ND 2.0 08/05/20 11:44 1,1-Dichloroethane ug/L ND 2.0 08/05/20 11:44 1,1-Dichloroethene ug/L ND 2.0 08/05/20 11:44 1,2-Dichlorobenzene ug/L ND 2.0 08/05/20 11:44 1,2-Dichloroethane ug/L ND 2.0 08/05/20 11:44 1,2-Dichloropropane ug/L NO 2.0 08/05/20 11:44 1,3-Dichlorobenzene ug/L ND 2.0 08/05/20 11:44 1,4-Dichlorobenzene ug/L ND 2.0 08/05/20 11:44 Benzene ug/L ND 1.0 08/05/20 11:44 Bromodichloromethane ug/L ND 2.0 08/05/20 11:44 Bromoform ug/L ND 2.0 08/05/20 11:44 Bromomethane ug/L ND 2.0 08/05/20 11:44 Carbon tetrachloride ug/L ND 2.0 08/05/20 11:44 Chlorobenzene ug/L ND 2.0 08/05/20 11:44 Chloroethane ug/L ND 2.0 08/05/20 11:44 Chloroform ug/L ND 2.0 08/05/20 11:44 Chloromethane ug/L NO 2.0 08/05/20 11:44 cis-1,2-Dichloroethene ug/L ND 2.0 08/05/20 11:44 cis-1,3-Dichloropropene ug/L ND 2.0 08/05/20 11:44 Dibromochloromethane ug/L ND 2.0 08/05/20 11:44 Ethylbenzene ug/L ND 1.0 08/05/20 11:44 Methylene Chloride ug/L ND 2.0 08/05/20 11:44 Tetrachloroethene ug/L ND 2.0 08/05/20 11:44 Toluene ug/L ND 1.0 08/05/20 11:44 trans-1,2-Dichloroethene ug/L ND 2.0 08105/2011:44 trans-1,3-Dichloropropene ug/L ND 2.0 08/05/20 11:44 Trichloroethene ug/L ND 2.0 08/05/20 11:44 Trichlorofluoromethane ug/L ND 2.0 08/05/20 11:44 Vinyl chloride ug/L ND 2.0 08/05/20 11:44 1,2-Dichloroethane-d4 (S) % 95 70-130 08/05/20 11:44 4-Bromofluorobenzene (S) % 97 70-130 08/05/20 11:44 Toluene-d8 (S) % 100 70-130 08/05/20 11:44 LABORATORY CONTROL SAMPLE: 2961053 Qualifiers Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1-Trichloroethane ug/L 20 17.6 88 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 43 aceAnalj&ai'�) www.pacolobs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92489086 LABORATORY CONTROL SAMPLE: 2961053 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers 1,1,2,2-Tetrachloroethane ug/L 20 18.1 90 60-140 1,1,2-Trichloroethane ug/L 20 18.0 90 70-130 1,1-Dichloroethane ug/L 20 18.3 92 70-130 1,1-Dichloroethene ug/L 20 17.8 89 50-150 1,2-Dichlorobenzene ug/L 20 18.1 91 65-135 1,2-Dichloroethane ug/L 20 16.6 83 49-155 1,2-Dichloropropane ug/L 20 18.9 95 35-165 1,3-Dichlorobenzene ug/L 20 18.0 90 70-130 1,4-Dichlorobenzene ug/L 20 18.1 91 65-135 Benzene ug/L 20 18.4 92 65-135 Bromodichloromethane ug/L 20 15.4 77 65-135 Bromoform ug/L 20 16.4 82 70-130 Bromomethane ug/L 20 22.8 114 15-185 Carbon tetrachloride ug/L 20 16.4 82 70-130 Chlorobenzene ug/L 20 17.6 88 65-135 Chloroethane ug/L 20 15.5 78 40-160 Chloroform ug/L 20 18.5 92 70-135 Chloromethane ug/L 20 15.3 77 1-205 cis-1,2-Dichloroethene ug/L 20 18.1 91 68-146 cis-1,3-Dichloropropene ug/L 20 19.3 96 25-175 Dibromochloromethane ug/L 20 18.1 91 70-135 Ethylbenzene ug/L 20 17.5 87 60-140 Methylene Chloride ug/L 20 15.6 78 60-140 Tetrachloroethene ug/L 20 17.7 88 70-130 Toluene ug/L 20 17.8 89 70-130 trans-1,2-Dichloroethene ug/L 20 17.7 89 70-130 trans-1,3-Dichloropropene ug/L 20 17.7 88 50-150 Trichloroethene ug/L 20 17.8 89 65-135 Trichlorofluoromethane ug/L 20 15.2 76 50-150 Vinyl chloride ug/L 20 15.1 76 5-195 1,2-Dichloroethane-d4 (S) % 98 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2961054 2961055 MS MSD 92489086001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1-Trichloroethane ug/L NO 20 20 22.1 19.6 110 98 52-162 12 1,1,2,2-Tetrachloroethane ug/L ND 20 20 24.3 22.4 121 112 46-157 8 1,1,2-Trichloroethane ug/L ND 20 20 23.5 20.7 117 104 52-150 13 1,1-Dichloroethane ug/L ND 20 20 22.1 20.4 111 102 59-155 8 1,1-Dichloroethene ug/L NO 20 20 19.8 18.4 99 92 1-234 7 1,2-Dichlorobenzene ug/L ND 20 20 26.8 23.4 134 117 18-190 14 1,2-Dichloroethane ug/L ND 20 20 20.5 19.9 101 98 49-155 3 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 43 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2961054 MS 92489086001 Spike Parameter Units Result Cone. MSD Spike Cone. 2961055 MS Result MSD Result MS % Rec MSD % Rae % Rec Limits RPD Qua[ 1,2-Dichloropropane ug/L ND 20 20 22.8 21.6 114 108 1-210 6 1,3-Dichlorobenzene ug/L ND 20 20 27.1 23.9 136 120 59-156 13 1,4-Dichlorobenzene ug/L ND 20 20 26.5 23.4 132 117 18-190 13 Benzene ug/L ND 20 20 22.0 20.6 110 103 37-151 7 Bromodichloromethane ug/L ND 20 20 20.8 18.9 104 95 35-155 9 Bromoform ug/L ND 20 20 22.3 19.6 112 98 45-169 13 Bromomethane ug/L ND 20 20 14.3 13.8 69 66 1-242 3 Carbon tetrachloride ug/L ND 20 20 21.6 19.4 108 97 70-140 10 Chlorobenzene ug/L ND 20 20 24.4 21.7 122 108 37-160 12 Chloroethane ug/L ND 20 20 14.3 13.8 71 69 14-230 4 Chloroform ug/L ND 20 20 22.5 21.9 112 109 51-138 3 Chloromethane ug/L ND 20 20 7.6 6.8 38 34 1-273 11 cis-1,2-Dich[oroethene ug/L ND 20 20 22.7 20.7 113 104 45-174 9 cis-1,3-Dichloropropene ug/L ND 20 20 23.1 21.8 116 109 1-227 6 Dibromochloromethane ug/L ND 20 20 25.0 21.9 125 109 53-149 13 Ethylbenzene ug/L ND 20 20 24.2 21.9 121 109 37-162 10 Methylene Chloride ug/L ND 20 20 18.2 17.5 91 88 1-221 4 Tetrachloroethene ug/L ND 20 20 24.1 21.4 120 107 64-148 12 Toluene ug/L ND 20 20 22.9 20.4 114 102 47-150 12 trans-1,2-Dichloroethene ug/L ND 20 20 20.9 19.7 104 98 54-156 6 trans-1,3-Dichloropropene ug/L ND 20 20 22.2 20.7 111 103 17-183 7 Trichloroethene ug/L ND 20 20 22.6 20.6 113 103 70-157 9 Trichlorofluoromethane ug/L ND 20 20 15.7 13.9 78 69 17-181 12 Vinyl chloride ug/L ND 20 20 9.4 9.0 47 45 1-251 4 1,2-Dich[oroethane-d4 (S) % 101 102 70-130 4-Bromofluorobenzene (S) % 97 97 70-130 Toluene-d8 (S) % 97 98 70-130 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 43 aceAnalytical www.pacelabs.com t QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 QC Batch: 558541 Analysis Method: EPA 608.3 QC Batch Method: EPA 608.3 Analysis Description: 608 PCB Pest Red Vol Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 METHOD BLANK: 2963679 Matrix: Water Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 4,4'-DDD ug/L NO 0.050 08/10/2019:30 4,4'-DDE ug/L ND 0.050 08/10/20 19:30 4,4'-DDT ug/L ND 0.050 08/10/20 19:30 Aldrin ug/L NO 0.050 08/10/20 19:30 alpha-BHC ug/L ND 0.050 08/10/20 19:30 alpha -Chlordane ug/L ND 0.050 08110/2019:30 beta-BHC ug/L ND 0.050 08/10/20 19:30 Chlordane (Technical) ug/L ND 0.50 08/10/20 19:30 delta-BHC ug/L ND 0.050 08/10/20 19:30 Dieldrin ug/L ND 0.050 08/10/20 19:30 Endosulfan I ug/L ND 0.050 08/10/20 19:30 Endosulfan II ug/L ND 0.050 08/10/20 19:30 Endosulfan sulfate ug/L ND 0.050 08/10/20 19:30 Endrin ug/L ND 0.050 08/1012019:30 Endrin aldehyde ug/L ND 0.050 08/10/20 19:30 gamma-BHC (Lindane) ug/L ND 0.050 08/10/20 19:30 gamma -Chlordane ug/L ND 0.050 08/10/20 19:30 Heptachlor ug/L ND 0.050 08/10/20 19:30 Heptachlor epoxide ug/L ND 0.050 08/10/20 19:30 PCB-1016 (Aroclor 1016) ug/L ND 0.50 08/10/20 19:30 PCB-1221 (Aroclor 1221) ug/L ND 0.50 08/10/20 19:30 PCB-1232 (Aroclor 1232) ug/L ND 0.50 08/10/20 19:30 PCB-1242 (Aroclor 1242) ug/L NO 0.50 08/10/20 19:30 PCB-1248 (Aroclor 1248) ug/L ND 0.50 08/10/20 19:30 PCB-1254 (Aroclor 1254) ug/L ND 0.50 08/10/20 19:30 PCB-1260 (Aroclor 1260) ug/L ND 0.50 08/10/20 19:30 Toxaphene ug/L ND 0.50 08/10/20 19:30 Decachlorobiphenyl (S) % 100 10-130 08/10/20 19:30 Tetrachloro-m-xylene (S) % 74 10-130 08/10/20 19:30 LABORATORY CONTROL SAMPLE: 2963680 Parameter 4,4'-DDD 4,4'-DDE 4,4'-DDT Aldrin alpha-BHC alpha -Chlordane Spike LCS Units Conc. Result ug/L 0.25 0.26 ug/L 0.25 0.23 ug/L 0.25 0.28 ug/L 0.25 0.14 ug/L 0.25 0.19 ug/L 0.25 0.22 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LCS % Rec % Rec Limits Qualifiers 104 31-141 91 30-145 114 25-160 55 42-140 77 37-140 89 45-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08111 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 43 aceAnalytical www.pacelabs.cem Project: RBTC STORMWATER Pace Project No.: 92489086 LABORATORY CONTROL SAMPLE: 2963680 Parameter beta-BHC delta-BHC Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde gamma-BHC (Lindane) gamma -Chlordane Heptachlor Heptachlor epoxide Decachlorobiphenyl (S) Tetrachloro-m-xylene (S) QUALITY CONTROL DATA Units Spike Conc. LCS Result LCS % Rec % Rec Limits ug/L 0.25 0.28 112 17-147 ug/L 0.25 0.21 85 19-140 ug/L 0.25 0.24 97 36-146 ug/L 0.25 0.23 94 45-153 ug/L 0.25 0.25 102 1-202 ug/L 0.25 0.26 104 26-144 ug/L 0.25 0.25 99 30-147 ug/L 0.25 0.21 85 50-148 ug/L 0.25 0.20 81 32-140 ug/L 0.25 0.24 94 45-140 ug/L 0.25 0.16 64 34-140 ug/L 0.25 0.22 87 37-142 % 109 10-130 % 76 10-130 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Qualifiers LABORATORY CONTROL SAMPLE: 2963681 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 3.2 64 50-140 PCB-1260 (Aroclor 1260) ug/L 5 4.2 83 8-140 Decachlorobiphenyl (S) % 95 10-130 Tetrachloro-m-xylene (S) % 61 10-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2963682 MS 92488949001 Spike Parameter Units Result Cone. MSD Spike Conc. 2963683 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qua] 4,4'-DDD ug/L ND 0.25 0.25 0.21 0.18 86 72 31-141 18 4,4'-DDE ug/L ND 0.25 0.25 0.19 0.16 77 63 30-145 20 4,4'-DDT ug/L ND 0.25 0.25 0.24 0.20 96 78 25-160 20 Aldrin ug/L ND 0.25 0.25 0.13 0.11 53 43 42-140 22 alpha-BHC ug/L ND 0.25 0.25 0.15 0.12 61 50 37-140 20 alpha -Chlordane ug/L ND 0.25 0.25 0.20 0.16 79 66 45-140 18 beta-BHC ug/L NO 0.25 0.25 0.22 0.19 89 76 17-147 16 delta-BHC ug/L ND 0.25 0.25 0.18 0.15 71 60 19-140 18 Dieldrin ug/L ND 0.25 0.25 0.20 0.17 81 66 36-146 19 Endosulfan I ug/L ND 0.25 0.25 0.21 0.18 84 73 45-153 15 Endosulfan 11 ug/L ND 0.25 0.25 0.21 0.18 84 70 1-202 17 Endosulfan sulfate ug/L NO 0.25 0.26 0.22 0.19 88 75 26-144 15 Endrin ug/L ND 0.25 0.25 0.21 0.17 83 70 30-147 18 Endrin aldehyde ug/L ND 0.25 0.25 0.19 0.16 76 65 50-150 16 gamma-BHC (Lindane) ug/L ND 0.25 0.25 0.16 0.13 63 53 32-140 17 gamma -Chlordane ug/L ND 0.25 0.25 0.21 0.17 86 69 45-140 21 Heptachlor ug/L ND 0.25 0.25 0.15 0.12 58 48 34-140 20 Results presented on this page are in the units Indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 43 1aceAnalyfical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2963682 MS 92488949001 Spike Parameter Units Result Conc. Heptachlor epoxide ug/L ND 0.25 Decachlorobiphenyl (S) % Tetrachloro-m-xylene (S) % Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 2963683 MSD Spike MS MSD MS MSD % Rec Conc. Result Result % Rec % Rec Limits RPD Qual 0.25 0.18 0.15 73 61 37-142 18 110 88 10-130 64 48 10-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2963684 2963685 MS MSD 92488949001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual PCB-1016 (Aroclor 1016) ug/L ND 5 5 3.4 2.7 68 54 50-140 24 PCB-1260 (Aroclor 1260) ug/L ND 5 5 4.1 4.1 82 83 8-140 0 Decachlorobiphenyl (S) % 97 97 10-130 Tetrachloro-m-xylene (S) % 54 49 10-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08111 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 43 aceAnalj6cal www.pacolabs.com Project: RBTC STORMWATER Pace Project No.: 92489086 Stu tsaicn: 558232 QC Batch Method: EPA 626.1 QUALITY CONTROL DATA Analysis Method: EPA 625.1 Analysis Description: 625 MSS Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 METHOD BLANK: 2962242 Matrix: Water Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 Blank Reporting Parameter Units Result Limit Analyzed 1,2,4-Trichlorobenzene ug/L ND 5.0 08/06/20 16:47 2,2'-Oxybis(1-chloropropane) ug/L ND 5.0 08/06/20 16:47 2,4,6-Trichlorophenol ug/L ND 10.0 08/06/20 16:47 2,4-Dichlorophenol ug/L ND 5.0 08/06/20 16:47 2,4-Dimethylphenol ug/L ND 10.0 08/0612016:47 2,4-Dinitrophenol ug/L NO 50.0 08/06/20 16:47 2,4-Dinitrotoluene ug/L ND 5.0 08/06/20 16:47 2,6-Dinitrotoluene ug/L ND 5.0 08106/2016:47 2-Chloronaphthalene ug/L ND 5.0 08/06/20 16:47 2-Chlorophenol ug/L ND 5.0 08/06/20 16:47 2-Nitrophenol ug/L ND 5.0 08/06/20 16:47 3,3'-Dichlorobenzidine ug/L ND 10.0 08/06/20 16:47 4,6-Dinitro-2-methylphenol ug/L ND 10.0 08/06/20 16:47 4-Bromophenylphenyl ether ug/L ND 5.0 08/06/20 16:47 4-Chloro-3-methylphenol ug/L ND 5.0 08/06/20 16:47 4-Chlorophenylphenyl ether ug/L ND 5.0 08/06/20 16:47 4-Nitrophenol ug/L ND 10.0 08/06/20 16:47 Acenaphthene ug/L ND 5.0 08/06/20 16:47 Acenaphthylene ug/L ND 5.0 08/06/20 16:47 Anthracene ug/L ND 5.0 08/06/20 16:47 Benzo(a)anthracene ug/L ND 5.0 08/06/20 16:47 Benzo(a)pyrene ug/L ND 5.0 08/06/20 16:47 Benzo(b)fluoranthene ug/L ND 5.0 08/06/20 16:47 Benzo(g,h,i)perylene ug/L ND 5.0 08106/2016:47 Benzo(k)fluoranthene ug/L ND 5.0 08/06/20 16:47 bis(2-Chloroethoxy)methane ug/L ND 10.0 08/06/20 16:47 bis(2-Chloroethyl) ether ug/L ND 5.0 08/06/20 16:47 bis(2-Ethylhexyl)phthalate ug/L NO 5.0 08/06/20 16:47 Butylbenzylphthalate ug/L ND 5.0 08/06/20 16:47 Chrysene ug/L ND 5.0 08/06/20 16:47 Di-n-butylphthalate ug/L ND 5.0 08/06/20 16:47 Di-n-octylphthalate ug/L ND 5.0 08/06/20 16:47 Dibenz(a,h)anthracene ug/L ND 5.0 08/06/20 16:47 Diethylphthalate ug/L NO 5.0 08/06/20 16:47 Dimethylphtha late ug/L ND 5.0 08/06/20 16:47 Fluoranthene ug/L NO 5.0 08/06/20 16:47 Fluorene ug/L ND 5.0 08/06/20 16:47 Hexachloro-1,3-butadiene ug/L ND 5.0 08/06/20 16:47 Hexachlorobenzene ug/L ND 5.0 08/06/20 16:47 Hexachlorocyclopentadiene ug/L ND 10.0 08/06/20 16:47 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 43 Pace Analytical Services, LLC ® 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (:�a'ceAnalj&al www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 METHOD BLANK: 2962242 Matrix: Water Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Hexachloroethane ug/L NO 5.0 08/06/20 16:47 Indeno(1,2,3-cd)pyrene ug/L ND 5.0 08/0612016:47 Isophorone ug/L ND 10.0 08/06/20 16:47 N-Nitroso-di-n-propylamine ug/L ND 5.0 08/06/20 16:47 N-Nitrosodimethylamine ug/L NO 5.0 08/06/20 16:47 N-Nitrosodiphenylamine ug/L ND 10.0 08/06/20 16:47 Naphthalene ug/L NO 5.0 08/0612016:47 Nitrobenzene ug/L NO 5.0 08/06/20 16:47 Pentachlorophenol ug/L ND 10.0 08/06/20 16:47 Phenanthrene ug/L ND 5.0 08/06/20 16:47 Phenol ug/L ND 5.0 08/06/20 16:47 Pyrene ug/L NO 5.0 08/06/20 16:47 2,4,6-Tribromophenol (S) % 103 10-137 08/06/20 16:47 2-Fluorobiphenyl (S) % 97 15-120 08/06/20 16:47 2-Fluorophenol (S) % 71 10-120 08/06/20 16:47 Nitrobenzene-d5 (S) % 104 10-120 08/06/20 16:47 Phenol-d6 (S) % 55 10-120 08/06/20 16:47 Terphenyl-d14 (S) % 132 11-131 08/06/20 16:47 S3 LABORATORY CONTROL SAMPLE: 2962243 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/L 50 43.5 87 44-142 2,2'-Oxybis(1-chloropropane) ug/L 50 48.7 97 36-166 2,4,6-Trichlorophenol ug/L 50 62.4 105 37-144 2,4-Dichlorophenol ug/L 50 50.9 102 1-191 2,4-Dimethylphenol ug/L 50 53.1 106 32-119 2,4-Dinitrophenol ug/L 250 292 117 1-181 2,4-Dinitrotoluene ug/L 50 54.5 109 39-139 2,6-Dinitrotoluene ug/L 50 52.9 106 50-158 2-Chloronaphthalene ug/L 50 47.9 96 60-118 2-Chlorophenol ug/L 50 50.1 100 23-134 2-Nitrophenol ug/L 50 57.9 116 29-182 3,3'-Dichlorobenzidine ug/L 100 106 106 1-262 4,6-Dinitro-2-methylphenol ug/L 100 145 145 1-181 4-Bromophenylphenyl ether ug/L 50 50.4 101 53-127 4-Chloro-3-methylphenol ug/L 100 97.6 98 22-147 4-Chlorophenylphenyl ether ug/L 50 47.7 95 25-158 4-Nitrophenol ug/L 250 158 63 1-132 Acenaphthene ug/L 50 46.8 94 47-145 Acenaphthylene ug/L 50 47.6 95 33-145 Anthracene ug/L 50 44.7 89 1-166 Benzo(a)anthracene ug/L 50 49.9 100 33-143 Benzo(a)pyrene ug/L 50 50.4 101 17-163 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 43 aceAnalytieal www.pacolabs.com Project: RBTC STORMWATER Pace Project No.: 92489086 QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE: 2962243 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Benzo(b)fluoranthene ug/L 50 51.9 104 24-159 Benzo(g,h,i)perylene ug/L 50 50.1 100 1-219 Benzo(k)fluoranthene ug/L 50 61.5 103 11-162 bis(2-Chloroethoxy)methane ug/L 50 49.8 100 33-184 bis(2-Chloroethyl) ether ug/L 50 50.6 101 12-158 bis(2-Ethylhexyl)phthalate ug/L 50 55.5 111 8-158 Butylbenzylphtha late ug/L 50 55.4 111 1-152 Chrysene ug/L 50 50.4 101 17-168 Di-n-butylphthalate ug/L 50 53.2 106 1-118 Di-n-octylphthalate ug/L 50 56.4 113 4-146 Dibenz(a,h)anthracene ug/L 50 52.2 104 1-227 Diethylphthalate ug/L 50 48.4 97 1-114 Dimethylphthalate ug/L 50 48.2 96 1-112 Fluoranthene ug/L 50 50.5 101 26-137 Fluorene ug/L 50 47.2 94 59-121 Hexachloro-1,3-butadiene ug/L 50 42.1 84 24-116 Hexachlorobenzene ug/L 50 50.0 100 1-152 Hexachlorocyclopentadiene ug/L 50 46.2 92 25-150 Hexachloroethane ug/L 50 45.5 91 40-113 Indeno(1,2,3-cd)pyrene ug/L 50 50.5 101 1-171 Isophorone ug/L 50 47.1 94 21-196 N-Nitroso-di-n-propylamine ug/L 50 49.5 99 1-230 N-Nitrosodimethylamine ug/L 50 46.6 93 25-150 N-Nitrosodiphenylamine ug/L 50 49.6 99 25-150 Naphthalene ug/L 50 45.2 90 21-133 Nitrobenzene ug/L 50 50.9 102 35-180 Pentachlorophenol ug/L 100 97.3 97 14-176 Phenanthrene ug/L 50 48.9 98 54-120 Phenol ug/L 50 35.2 70 5-112 Pyrene ug/L 50 49.3 99 52-115 2,4,6-Tribromophenol (S) % 119 10-137 2-Fluorobiphenyl (S) % 104 15-120 2-Fluorophenol (S) % 80 10-120 Nitrobenzene-d5 (S) % 112 10-120 Phenol-d6 (S) % 65 10-120 Terphenyl-d14 (S) % 126 11-131 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2962244 2962245 MS MSD 92482412014 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual 1,2,4-Trichlorobenzene ug/L NO 50 50 43.6 45.0 87 90 44-142 3 2,2'-Oxybis(1-chloropropane) ug/L ND 50 50 47.5 47.5 95 95 36-166 0 2,4,6-Trichlorophenol ug/L NO 50 50 54.4 53.4 109 107 37-144 2 2,4-Dichlorophenol ug/L ND 50 50 51.4 52.9 103 106 1-191 3 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 43 (�IaoeAnalyfical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: RBTC STORMWATER Pace Project No.: 92489086 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2962244 2962245 MS MSD 92482412014 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Clual 2,4-Dimethylphenoi ug/L ND 50 50 53.1 55.1 106 110 32-119 4 2,4-Dinitrophenol ug/L ND 250 250 379 122 151 49 1-181 103 R1 2,4-Dinitrotoluene ug/L ND 50 50 57.4 56.8 115 114 39-139 1 2,6-Dinitrotoluene ug/L ND 50 50 54.5 55.0 109 110 50-158 1 2-Chloronaphthalene ug/L ND 50 50 49.6 49.7 99 99 60-118 0 2-Chlorophenol ug/L ND 50 50 47.4 49.2 95 98 23-134 4 2-Nitrophenol ug/L ND 50 50 57.4 59.1 115 118 29-182 3 3,3'-Dichlorobenzidine ug/L ND 100 100 108 109 108 109 1-262 1 4,6-Dinitro-2-methylphenol ug/L ND 100 100 149 121 149 121 1-181 20 4-Bromophenylphenyl ether ug/L ND 50 50 50.4 50.7 101 101 53-127 1 4-Chloro-3-methylphenol ug/L ND 100 100 97.7 102 98 102 22-147 4 4-Chlorophenylphenyl ether ug/L ND 50 50 48.9 49.5 98 99 25-158 1 4-Nitrophenol ug/L ND 250 250 155 123 62 49 1-132 23 Acenaphthene ug/L ND 50 50 48.1 48.2 96 96 47-145 0 Acenaphthylene ug/L ND 50 50 48.7 48.9 97 98 33-145 0 Anthracene ug/L ND 50 50 44.8 44.5 90 89 1-166 1 Benzo(a)anthracene ug/L ND 50 50 51.0 50.7 102 101 33-143 1 Benzo(a)pyrene ug/L ND 50 50 52.7 52.7 105 105 17-163 0 Benzo(b)fluoranthene ug/L ND 50 50 53.0 52.8 106 106 24-159 0 Benzo(g,h,i)perylene ug/L ND 50 50 52.5 52.4 105 105 1-219 0 Benzo(k)fluoranthene ug/L ND 50 50 53.8 54.0 108 108 11-162 0 bis(2-Chloroethoxy)methane ug/L ND 50 50 49.8 50.7 100 101 33-184 2 bis(2-Chloroethyl) ether ug/L ND 50 50 48.4 50.3 97 101 12-158 4 bis(2-Ethylhexyl)phthalate ug/L ND 50 50 56.7 56.1 113 112 8-158 1 Butylbenzylphthalate ug/L ND 50 50 56.3 56.4 113 113 1-152 0 Chrysene ug/L ND 50 50 52.0 51.6 104 103 17-168 1 Di-n-butylphthalate ug/L ND 50 50 65.3 54.4 111 109 1-118 2 Di-n-octylphthalate ug/L ND 50 50 58.2 57.9 116 116 4-146 0 Dibenz(a,h)anthracene ug/L ND 50 50 54.6 54.8 109 110 1-227 0 Diethylphthalate ug/L ND 50 50 50.2 50.5 100 101 1-114 1 Dimethylphthalate ug/L ND 50 50 49.0 49.5 98 99 1-112 1 Fluoranthene ug/L ND 50 50 51.8 51.0 104 102 26-137 2 Fluorene ug/L ND 50 50 48.8 48.8 98 98 59-121 0 Hexachloro-1,3-butadiene ug/L ND 50 50 40.6 41.8 81 84 24-116 3 Hexachlorobenzene ug/L ND 50 50 49.4 50.0 99 100 1-152 1 Hexachlorocyclopentadiene ug/L ND 50 50 47.4 46.9 95 94 25-150 1 Hexachloroethane ug/L ND 50 50 43.3 42.8 87 86 40-113 1 lndeno(1,2,3-cd)pyrene ug/L ND 50 50 52.7 52.9 105 106 1-171 0 Isophorone ug/L ND 50 50 47.5 48.2 95 96 21-196 1 N-Nitroso-di-n-propylamine ug/L ND 50 50 47.6 48.9 95 98 1-230 3 N-Nitrosodimethylamine ug/L ND 50 50 39.8 42.1 80 84 25-150 6 N-Nitrosodiphenylamine ug/L ND 50 50 49.7 49.8 99 100 25-150 0 Naphthalene ug/L ND 50 50 49.3 49.8 91 92 21-133 1 Nitrobenzene ug/L ND 50 50 50.3 52.1 101 104 35-180 4 Pentachlorophenol ug/L ND 100 100 92.4 83.9 92 84 14-176 10 Phenanthrene ug/L ND 50 50 48.9 48.9 98 98 54-120 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11/2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 35 of 43 aceAnalytical www.pecolobs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2962244 2962245 MS MSD 92482412014 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phenol ug/L ND 50 50 32.6 34.4 62 65 5-112 5 Pyrene ug/L ND 50 50 50.2 49.8 100 100 52-115 1 2,4,6-Tribromophenol (S) % 112 114 10-137 2-Fluorobiphenyl (S) % 100 100 15-120 2-Fluorophenol (S) % 69 73 10-120 Nitrobenzene-d5 (S) % 105 109 10-120 Phenol-d6 (S) % 54 58 10-120 Terphenyl-d14 (S) % 122 122 11-131 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 36 of 43 (�15&eAnalXical www.pacelabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 QC Batch: 558401 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 METHOD BLANK: 2963207 Matrix: Water Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 08/06/20 18:28 LABORATORY CONTROL SAMPLE: 2963208 Spike LCS LCS % Rec Units Conc. Result % Rec Limits mg/L 250 232 93 90-110 Parameter Total Suspended Solids SAMPLE DUPLICATE: 2963489 Parameter Total Suspended Solids SAMPLE DUPLICATE: 2963519 Parameter Total Suspended Solids 92489039001 Dup Units Result Result mg1L 163 148 92489086004 Dup Units Result Result mg/L 37.9 61.8 RPD Qualifiers 10 RPD Qualifiers 48 D6 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 43 aceAnalytical www.pacclabs.com QUALITY CONTROL DATA Project: RBTC STORMWATER Pace Project No.: 92489086 QC Batch: 558776 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92489086001, 92489086002, 92489086003, 92489086004, 92489086005 SAMPLE DUPLICATE: 2965204 92488685001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 5.7 5.7 0 H3 SAMPLE DUPLICATE: 2965205 92488716002 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 7.3 7.2 2 D6,1-13 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 38 of 43 aceAnalytical www.pacolabs.com QUALIFIERS Project: RBTC STORMWATER Pace Proiect No.: 92489086 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time: HS Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter). R1 RPD value was outside control limits. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample. Date: 08/11/2020 11:51 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 43 Pace Analytical Services, LLC +� v y� ® 9800 Kincey Ave. Suite 100 www.pacelabs.com CtGt, I IG�I Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: RBTC STORMWATER Pace Project No.: 92489086 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92489086001 OUTFALL I EPA 1664E 557971 92489086002 OUTFALL 3 EPA 1664B 557971 92489086003 OFFSITE 1 EPA 1664B 557971 92489086004 OFFSITE 2 EPA 1664E 557971 92489086005 OFFSITE 3 EPA 1664B 557971 92489086001 OUTFALL 1 EPA 608.3 558541 EPA 608.3 558826 92489086002 OUTFALL 3 EPA 608.3 558541 EPA 608.3 558826 92489086003 OFFSITE 1 EPA 608.3 558541 EPA 608.3 558826 92489086004 OFFSITE 2 EPA 608.3 558541 EPA 608.3 558826 92489086006 OFFSITE 3 EPA 608.3 558541 EPA 608.3 558826 92489086001 OUTFALL I EPA 200.7 Rev 4.4 1994 557904 EPA 200.7 Rev 4.4 1994 557921 92489086002 OUTFALL 3 EPA 200.7 Rev 4.4 1994 557904 EPA 200.7 Rev 4.4 1994 557921 92489086003 OFFSITE 1 EPA 200.7 Rev 4.4 1994 557904 EPA 200.7 Rev 4.4 1994 557921 92489086004 OFFSITE 2 EPA 200.7 Rev 4.4 1994 557904 EPA 200.7 Rev 4.4 1994 557921 92489086006 OFFSITE 3 EPA 200.7 Rev 4.4 1994 557904 EPA 200.7 Rev 4.4 1994 557921 92489086001 OUTFALL 1 EPA 625.1 558232 EPA 625.1 558418 92489086002 OUTFALL 3 EPA 625.1 558232 EPA 625.1 558418 92489086003 OFFSITE 1 EPA 625.1 558232 EPA 625.1 558418 92489086004 OFFSITE 2 EPA 625.1 558232 EPA 625.1 558418 92489086005 OFFSITE 3 EPA 625.1 558232 EPA 625.1 558418 92489086001 OUTFALL 1 EPA 624.1 558010 92489086002 OUTFALL 3 EPA 624.1 558010 92489086003 OFFSITE 1 EPA 624.1 558010 92489086004 OFFSITE 2 EPA 624.1 558010 92489086005 OFFSITE 3 EPA 624.1 558010 92489086001 OUTFALL 1 SM 2540D-2011 558401 92489086002 OUTFALL 3 SM 254OD-2011 558401 92489086003 OFFSITE I SM 254OD-2011 558401 92489086004 OFFSITE 2 SM 2540D-2011 558401 92489086006 OFFSITE 3 SM 254OD-2011 558401 92489086001 OUTFALLI EPA 9040C 558776 92489086002 OUTFALL 3 EPA 9040C 558776 92489086003 OFFSITE1 EPA 9040C 558776 92489086004 OFFSITE 2 EPA 9040C 558776 92489086006 OFFSITE 3 EPA 9040C 558776 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/11 /2020 11:51 AM without the written consent of Pace Analytical Services, LLC. Page 40 of 43 !;Z6Analytieal Document Name: Sample Condition Upon Recet t(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No.: Issuing Authority: /I F•CAR-CS-033•Rev.06 Pace Carolinas Quality Office Laboratory receiving satrapies: Asheville ❑ Eden❑ Greenwood ❑ Huntersvilie [ ] RaleighEl Mechanicsville❑ ° Client Name: i=I - t I' ail �[,�t fr�i��t „ Courier: ❑Fed Ex EJUP[:]USPS Client ❑ Commercial Pace []Other: 92489086 '"••^ Seai Present? i—lYes I fiNo Seals intact? i�Yes i�INo � - Date/Initials Person Examining contents: Packing Material: (]Bubble wrap []Bubble Bags ❑None ❑ Other Biological Tissug Frozen? c _' ` Thermometer: 92T061 Type of ice: Qwet 0Biue ❑None Oyes ❑No ❑N/A ❑IR Gun ID: Cooler Temp (°C): 1), 1 7 Correction Factor: Add/Subtract (°C) 0.0 Temp should be above freezing to 6°C Cooler Temp Corrected (°C): �� ampies out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil (] N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, P9.. _ _ r"1.. _. 1n.1u41noW-211 and Duprtn R1rn17I—iyps 171NO Comments/Discrepancy: Chain of Custody Present? MYes QNO N/A 1. Samples Arrived within Hold Time? jZlYe5 EINO N/A 2. Short "old Time Analysis 02 hr.)? " Yes No N/A 3. Rush Turn Around Time Requested? Yes ONO N/A 4. Sufficient Volume? yes [:]No N/A 5. Correct Containers Used? -Pace Containers Used? (Yes Yes ❑No ONo QN/A N/A 6. Containers Intact? Yes ❑No N A 7. Dissolved analysis: Samples Field Filtered? es ❑No N/A 8. Sample Labels Match COC? -includes Date/Time/ID/Analysis Matrix: MYes ❑No ®N/A 9. Headspace in VOA Vials (>5.6mm)? ves No J �J fA 10. Trip Blank Present? Trip Blank Custody Seals Present? OYes Yes ®No []No ❑N/A N/A 11. COMMENTS/SAMPLE DISCREPANCY i Held Date Required? QYes ❑No t{`'Cz'{ ` Z>J, # `tit r _ Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time: Date: Date: Page 41 of 43 Document Name: Document Revised: February 7, 2018 aceAnalytical� Sample Condition U on Recel t(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project # PH' 8V Due Date: 08/11/20 CLIENT: 92—Heritage t� 8 2 a u ��o a E v ® z ar °� a a E vci rT m i v °. a E 9 LN l0 4 a C N C w = Do r v °q O S in a E rn aa GO = Q S % a E o n al m QCL N V y E Yt m = 2 Zt7 N y E in m ,� 5 ° ° ° T� : a E u = r^y p, a a = is w a E 4 E O v x a E = S a O o E 2 z .EaO E ro l \ d o f+t z O J E ¢ o ? s O j E M $ Y1 ' 39 g & u m �~ vEi u ° o `� E X E ory E a E o 1 N\ r J7 a 3 � TV °i. %,.. 6 , 7 8 9 10 li NN 12 pH Adjustment Log for Preserved Samples rSampl.Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # •. ...Y. , O Y D41Cj diKi Y ,cuing ,vm ur t a wY,a LYmpuance onmpies, a Lupy ur toffs Torm will oe sent io the norm t.aronna uttitvn cenittcauon office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 42 of 43 ITEM # -:U -F. a —6 oo v) co ;7 0 ?q 6 i m lu r W C ti Ld 0 C !4 do MATRIXCODE (see valid codes to [on) 07 SAMPLE TYPE (G-GRAD CzCOMP) W� MY W r 41 0 5 Lo Zt A 0 z Z Z m 2 i 1 m m m 0 z m M M r m SAMPLE TEMPAT COLLECTION v v 0 > # OF CONTAINERS Unpreserved T v D m c H2804 z N HNO3 'U R Co HCI NaOH (D Na2S2O3 Methanol Other A Analyses Test,: TSS YIN RH ;XK pH m 2 Cu, Plb A Oil & Grease SGT Tro VOC TTO SVOC I —F t I TEMP in CiD Residual Chlorine (YIN) Received on Ice (Y/N) S" OM Custody Sealed Cooler Y/N ;L 1510, Samples Intact (YIN) -40 =r (D 0 > z -n 0 0 CL � C Si 0 0 ITI 0 > 0 C 9 M 0 (D to n 0 Cr 0 (D 8 ra 3 (D 'a M Page 43 of 43 STORM WATER DISCHARGE MONITORING TRACKING LOG BENCHMARK (mg/1): 100 6.0 - 9.0 0.010 0.075 0.126 15 1 Outfall SAMPLE DATE TSS PH Cu PB ZN O&G TTO 1 12/17/2019 9.4 5.1 0.0206 0.005 0.0364 < 5 < 0.05 2 12/17/2019 14.5 6.5 0.005 0.005 0.0115 < 5 3 12/17/20191 0.0025 4.8 o.o05j 0.0051 0.04771 < 51 < 0.05 4 12/17/20191 17.8 5.8 0.0051 0.005 0.0471 < 51 < 0.05 BENCHMARK (mg/I): 100 6.0-9.0 0.010 0.075 0.126 15 1 Outfall SAMPLE DATE TSS PH Cu PB ZN O&G TTO 1 5/18/2020 y< 1; ,�6: 5.8 0.0199 0.005 0. < 5 < 0.05 2 5/18/2020 17 7 0.0369 0.005 Z430,9 < 5 < 0.05 3 5/18/2020 4.2 5.8 0.0236 0.005 14 < 5 < 0.05 4 5/18/2020 11 6 0.0108 0.005 0.07511 < 5 < 0.05 Offsite 1 5/18/2020 4.5 6.5 < 0.005 < 0.005 0.0247 < 5 .<..0.05 BENCHMARK (mg/1): 100 6.0 - 9.0 0.010 0.075 0.126 15 1 Outfall SAMPLE DATE TSS PH CU PB ZN O&G TTO 1 6/28/2020 2.5 5 a0063 0.005 &0898 < 5 < 0.05 3 6/28/2020 4.3 4.7 0.0097 0.005 0.171 < 5 < 0.05 4 Offsite 1 6/28/2020 48.8 5.9 0.0069 0.005 0.0539 < 5 < 0.05 Offsite 2 6/28/2020 40.4 5.6 0.0054 0.005 0.0304 < 5 < 0.05 Offsite 3 6/28/2020 15.1 5.2 0.0066 0.005 0.65191 51 < 0.05 BENCHMARK (mg/1): 100 &0 - 9.0 0.010 0.075 0.126 15 1 Outfall SAMPLE DATE TSS PH Cu PB ZN O&G TTO 1 8/3/2020 8.5 6.9 <0.005 <0.005 0.052 < 5 < 0.05 3 8/3/2020 5.1 6.4 0.0081 < 0.005 0.149 < 5 < 0.05 4 Offsite 1 8/3/2020 < 3.0 7.2 0.0063 < 0.005 0.0272 < 5 < 0.05 Offsite 2 8/3/2020 37.9 7.1 0.0091 < 0.005 0.131 < 5 0.00062 Offsite 3 8/3/2020 44.21 7.21 120 j < 5 0.0001 Ambient 8/3/2020 6.5 BENCHMARK (mg/1): 100 --T- 5.8 - 9.0 0.010 0.075 0.126 15 1 Outfall SAMPLE DATE TSS PHICU PB ZN O&G TTO 1 8/31 /2020 2.7 6.61 < 0.005 < 0.005 0.0568 < 5 < 0.05 2 3 8/31 /2020 < 2.5 5.8 < 0.005 < 0.005 0.0747 < 5 < 0.05 4 Offsite 1 8/31 /2020 7 6.7 < 0.005 < 0.005 0.0324 < 5 < 0.05 Offsite 2 8/31/2020 10.1 6.9 < 0.005 < 0.005 &0110 < 5 < 0.05 Offsite 3 1 8/31/20201 20.21 71 < 0.005 < 0.0051 0.04211 < 5 < 0.05 Ambient 1 8/31/20201 1 5.8 ---------------- atit llow - ow 0 FELT ........... ........... I Receiving water is Indian Creek within the Catawba River Basin. Segment of Indian Creek adjacent to site is designated as Class WS-IV waters. This segment is listed in the 2018 Integrated Report 303(d) list of impaired waters as exceeding criteria for Fish Community (Nar, AL, FW). TIVIDI-s have not been established specific to Indian Creek within the Catawba River Basin. There is a state-wide TIVIDL for mercury, which does not impact monitoring for Robert Bosch Tool Corporation. FIGURE NUMBER: I LOCATION MAP REFERENCE: 2019 USGS Topographic Map, LincoInton West, NC Robert Bosch Tool Corporation PROJECT NUMBER: ENMO190155.00 1980 Indian Creek Road wEl SCALE: As Shown Lincolnton, NC 28092 FIGURE NUMBER: 2 REFERENCE: Lincoln County GIS, 2019 Aerial PROJECT NUMBER: ENMO 190155.00 SCALE: Approximate 1 inch = 400 feet SITE MAP Robert Bosch Tool Corporation 1980 Indian Creek Road Lincolnton, NC 28092 712