WI0700012_Monitoring (Report)_20060202

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. - Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
Well Locations/Site Name: Tank Farm
County: Beaufort
1
Bm
Telephone: [phone]
No. of Wells to be Sampled
18
Well Identification Number (from Permit):
Well Depth: 48.00 ft. Well Diamter:
CIW-7
Screened Interval: 31.00 ft. to 45.25 ft.
4 inch
Depth to Water Level: N/A ft. below measuring point.
Measuring Point is NIA ft above land surface.
For Groundwater Treatment
Systems Check One:
X Influent (98)
Effluent (99)
GALLONS of water pumped/bailed before sampling: N/A
Field Analysis: pH 6.9 , Specific Conductance 583 uMhos
Temp. 17.5 oC, Odor NONE Appearance: CLEAR
DEPARTMENT OF,ENVIRONMENT & NATURAL RESOURCES
WATER QUALITY DIVISION, GROUNDWATER SECTION
1636'.MAIL SERVICE CENTER
RALEIGH NC 27f99-1636 Rhone: [phone].
PERMIT ft: WI0700012
Non -Discharge
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field - - X Remediation : Rotary Distributor Land Application of Sludge
EXPIRATION DATE:
UIC X
01/15/08
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 1/24/06
Date sample analyzed: 1/24/06 to 1/25/06
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
. PARAMETERS: (Samples for metals were collected unfiltered Yes
COD
N/A mg/I
Coliform: MF Fecal
Coliform: MF Total
N/A /100m1'
<1.0 /100m1
(Note: Use MPN method for highly turbid samples)
- Dissolved Solids: Total N/A mg/1
pH (when analyzed) N/A units
TOC N/A mg
Chloride N/A mg/1
Arsenic N/A mg/1
Grease and Oils N/A mg/1
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKN as N
N/A mg/I
N/A mg/I
N/A uMhos
N/A mg/I
N/A mg/I
n/a
No and field acidified Yes n/a No )
Nitrite (NO2 as N) N/A mg/I
Nitrate (NO3 as N)
Phosphorus: Total as P
Orthophosphate
Al - Aluminum
Ba - Barium
Ca - Calcium
Cd- Cadmium
Chromium: Total
Cu - Copper
Fe - Iron
Hg - Mercury
K- Potassium
Mg - Magnesium
Mn - Manganese
Ni - Nickel N/A ug/I
N/A mg/I Pb - Lead
N/A mg/I Zn - Zinc
N/A mg/1 Ammonia Nitrogen
N/A ugA
N/A ug/I
N/A ugA
N/A ugA
N/A ug/I
N/A ug/I
N/A _ ug/I
N/A ugA
Other (Specify Compounds and Concentration Units)
Fluoride
MIRK
Ag - Silver
Se- Selenium
Sodium
N/A
N/A
N/A
N/A
N/A
N/A ug/I Organics: (GC, GC/MS, HPLC)
N/A ug/I (Specify test method #. Attach lab report)
N/A ug/I Report attached? Yes (1) No X
N/A ugA VOC : method#
N/A ug/I
: method#
: method#
ug/I
mg/I
ug/I
ug/I
ug/I
ugA
(2)
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 03/2000
Ross
Smith) - Mgcfar,
vironmental Affairs
Per ttee (of PutlSor' d Pffent me and Title - Please type or print
Signet re of Pettnittee (or Authorized Agent)
ig
(Date)

GROUNDWATER QUALITY MONITORING:
COMPLIANCE: -REPORTING FORM
FACILITY INFORMATION
Facilty Name: PCS PHOSPHATE CO., INC. -Aurora Division
Permit Name (if different):
Facility Addresss: P.O. Box 48
Aurora, NC 27806
Contact Person: Jack H. Taylor, Jr.
County: Beaufort
Telephone: [phone]
Well Locations/Site Name: Tank Farm No. of Wells to be Sampled
18
Well Identification Number (from Permit): MWTF1-CR
Well Depth: 42.00 ft. Well Diamter: 2 inch
Screened Interval: 38.70 ft. to 40.70 ft.
Depth to Water Level: 10.32 ft. below measuring point.
Measuring Point is 3.95 ft above land surface.
MILILITERS of water pumped/bailed before sampling:
Field Analysis: pH 6.8 , Specific Conductance 645 uMhos
Temp. 20.3 oC, Odor NONE Appearance:
For Groundwater Treatment
Systems Check One:
X Influent (98)
Effluent (99)
2100
CLEAR
Mail Original
to:
EP(QRTMENT CF ENVIRONMENT & NATURAI. RESOURCES
W. TER QUALITYDMSION, GROUN3WATER SECTION
636 MAIL SERVICECENTER.
RAEI YGHkNC 91 2769636 " Ph one-[phone]
PERMIT #: WI0700012 EXPIRATION DATE:
01/15/08
Non -Discharge UIC X
NPDES
TYPE OF PERMITTED OPERATION BEING MONITORED
Lagoon Remediation: Infiltration Gallery
Spray Field X Remediation :
Rotary Distributor Land Application of Sludge
Other
Note: Values should reflect dissolved and
colloidal concentrations
Date sample collected: 1/19/06
Date sample analyzed: 1/19/08 to 1/20/06
Laboratory Name: PCS PHOSPHATE and ENVIRONMENT 1
Certification No(s) 330 10
PARAMETERS: (Samples for metals were collected unfiltered Yes n/a
COD N/A mgA Nitrite (NO2 as N)
Coliform: MF Fecal N/A /100m1 Nitrate (NO3 as N)
Coliform: MF Total <1.0 /100m1 Phosphorus: Total as P
(Note: Use MPN method for highly turbid samples) Orthophosphate
Dissolved Solids: Total N/A mg/I Al - Aluminum
pH (when analyzed) N/A units Ba - Barium
TOC N/A mg/I Ca - Calcium
Chloride
Arsenic
Grease and Oils
Phenol
Sulfate
Specific Conductance
Total Ammonia
TKNasN
N/A mgA Cd- Cadmium
No and field acidified
N/A
N/A
N/A
N/A
N/A
N/A mgA Chromium: Total
N/A mg/I Cu - Copper
N/A mg/I Fe - Iron
N/A mg/I Hg - Mercury
N/A uMhos K- Potassium
N/A mg/I Mg - Magnesium
N/A mg/I Mn - Manganese
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
mg/I
mg/I
mgA
mg/1
ugA
ug/I
ugA
ugh
ugh
ugh
ug/I
ugA
ugA
ug/I
ugA
Ni - Nickel
Pb - Lead
Zn - Zinc
Yes n/a No )
NIA
N/A
N/A
Ammonia Nitrogen
Other (Specify Compounds and Concentration Units)
Fluoride
MIBK
Ag - Silver
Se- Selenium
Sodium
N/A
N/A
N/A
N/A
N/A
Organics: (GC, GC/MS, HPLC)
(Specify test method #. Attach lab report.)
Report attached? Yes (1) No X
VOC : method#
method#
. method#
ugA
ug/I
ug/I
ug/I
mg/I
ug/I
ugA
ugA
ug/I
(2)
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced
using approved methods of analysis by a North Carolina DWQ (formerly DEM) certified laboratory. I am aware that there are significant penalties for submitting
false information, including the possibility of fines and imprisonment for knowing violations.
NOTE:
GW-59 Rev 03/2000
Ros mI
Peyfnittee (ef
Signal re of P
na
Env'ronmental Affairs
and Title - Please type or pr)nt
imittee (or Authorized Agent)
B
(Date)

PCS Phosphate Co., Inc. - Tank Farm Remediation System Quarterly Monitoring
Date: /-5- O(o
Time:
Tech:
Xtg
System Gauge Pressures
SWW-1
Zmy,:l9 416 diia
SWW-7
" aCWW-1
"
CWW-7
it .7
file: 12-07-02
pc: TLB
Ref amp
PoIrd aml
SS Rd
mam
Ditch
12.91
78/
Barge Stip
Water Level
Control Tank
1G MSL
10.69
jNoP
/•//
Sand Layer Pelzometers Level Indicators
• Well ID
TOC
Elevation
MSC
WC
Ste Wtr
Level'
Level
Relative To
- MSL Ft.
WeII ID
TOC
Elevation
MSL'
TOC
Ste Wtr
level'
Level
Relative To
MSL Ft.
Spz-1
10A7
J. 8o
6 2
cpz-,
10.S,
Ms'
/0. 99
Aeo
- 0. / 9
spz-2
1121
7 9re
.t • a 9
Cpz-2
1025
Spz3
11.87
._ (0 3
6'.0? V
Cpz-3
11.12
9 / ?
r77 00
Spz-4
11A5
.
6.3g
is / 3
CPW
9.65
/0O.5
- l0
Sex-511A5
8.87
o .5g
MWTF-1A•
14.35
y:+//4/oj
/- pn
Spz6
1123
9 4,--a•D8
MWTF-1B•
14.36
7 . 90
,`9//5l--
9 si
Spa-7
11.59
98O
- '%/
/''//
WT,C•
MF
14.44
9os/
3790
Spz-a
1157
a /oO -
7. 99
MwTF-2A
14.05
/. e
%&✓/
Spz-9
11.01
780./0V'/
MWtF-2B
14.02
/O. 4/7...5s/
Spz-10
_ 12.16
f•/A-
a'• /29
MWTF-2C
14.08
/9..
-�•e
SPW
9.95
7S3
a. aMWTF3A
1221
£ 48
g63
MWTF3B
12.18
9 70
o7.Y8
MWTF-3C
12.19
kg- /()
-O.9/ -
Sand Layer And Croatan Formation Withdrawal Wells
Well ID
TOC
Elevation
MSL'
Max Ste
Wtr
Level FL
Pump
Activation Depth
Rel MSL
Max Level
Relative To
MSL Ft..
Control
Point
MSL'
Is Well
Pumping?
mesa po-
Comments
SWW-1
10.70
g5/
6'
..-3c9y
+1'to+2'
yf4
CWW-1
10.60
6...34/
9'
/Olo
-2'to-1'
4
SWW-2
9.99
p..//l
6'
c2, //
+1 'to+2'
ynj
CWW-2
1023
.5.78
9'
':9.44
-2'to-1'
y5
S1NW3
9.97
7 99
6'
/ y%
+1'to+2'
yef
CWW3
9.95
6..9
9'
vj. DV
-2'to-1'
Gfe5
SwW-4
10.73
7• %/D
6'
/,%l4
+1'to+2'
e?
CWW-4
10.73
.6-6
9'
-'9, 7/7/
-2'to-1'
Vt.?
SWW-5
10.60
'73
6'
/, 6.1
+1. to+2'
ye?
CWW-5
10.74
al,99
- 9'
c'. 0/
-2 'to-1'
// el
SWW-6
10.66
78
6'
//s/ .8/
+1 'to+2'
ye'y
CWW6
9.92
%69
9'
- /4 9/
-2'to-1'
9e5
W SW-7
10.70
7012
9'
/029
+1' to+2'
7"5
cww-7
9.95
6./9
9'
-or•g/
-2'to-1'
6,es
Revised 729/02
•
• Riser length added to TOC elevation 124/97
D.\Data%Fonns\Well Fam\Tank Farm Remed Welisads

SPZ
SPZ-1 `®
cPZ.1
CUT —OFT WALL
sWw.l CPZ-2 � r ASPHALT ROAD eWn/s
ens
CWw-1 SWW4- CwWJ
co-1
clW-1
OFFICE
1
SPZ-2 0
MWTF4
CLUSTER
/ ORADIAGE DITCH
S.P.A
PLANT
0
0
MWTF4
CLUSTER
SPZ-5
0
.M..•., .M...ea•er i
CPw SPW cvrwa
\\ sww4
WITHDRAWAL WL
FLOW TOTRl
AND CONTROL VALVES
005
CPZ-3 X
SPZ-9 .4
PIPERACK SPILL CONTAINMENT PAD
S.P.A
PLANT
WATER LEVEL
CONTROL TANK
MWIF-1
CLUSTER
cm-410Oi
002
004
/1
-r.- _ .r_-_
T
SPZ-10
_J
I. art.
ICI
II ILI ND
'YM11111 bt tic IOI. 111
•
•
•
()
rM/uW u•
........11.1. , .... •.IIII.•.•AI *III
• n...I.I.....IY...n..IIIMIIURAI WI. I I
intl. ......r l l ..r Al.11. rSrI . I I AN 1.111
. . • . ',SUM •AIIF I/Vll
LOCATION PLAN FOR TANK FAIIM
AREA REMEDIAL ACTION SYS I I M
WELLS AND PIEZOMETI 11'.
FIGURE 1

PCS PHOSPHATE - TANK FARM REMEDIAL ACTION PLAN
QUARTERLY OPERATIONAL AND MAINTENANCE REPORT FOR
THE INJECTION AND WITHDRAWAL WATER WELLS
November 2005 — January 2006
The Tank Farm Remediation System consists of a series of seven- (7) injection water wells located on the
south side of the Tank Farm Area and a series of fourteen (14) withdrawal water wells located on the north
side of the Tank Farm Area.
Injection Water Well System
The injection water well system operated with the DPW Water - Ultraviolet Light Disinfection system
during the period.
Daily operational data are collected by the Shipping Department and reported to the Environmental Affairs
Department. The total monthly and quarterly volumes of water injected as well as the month end water
level in the Water Level Control Tank are:
DPW WATER
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
TANK
LEVEL
FEET, MSL
Nov
895,292
0
895,292
20.7
15.0
Dec
962,394
0
962,394
21.6
15.0
Jan
707,074
0
707,074
19.6
15.0
TOTALS
2,564,760
0
2,564,760
\\aurdata2\users\AUR1DDW\Reports\2006\Quarterly\TFRAS Report First Quarter 2006.doc
3

Withdrawal Well System
The withdrawal water well pumps are monitored daily by the area Maintenance Department and
preventative maintenance work is performed as needed. The total monthly and quarterly withdrawal water
volumes for the period are:
SAND
FORMATION
GALLONS
CROATAN
FORMATION
GALLONS
TOTAL
GALLONS
AVERAGE
GPM
Nov
257,915
84,868
342,784
7.9
Dec
357,876
93,620
451,496
10.5
Jan
333,661
100,221
433,882
9.7
TOTALS
949,452
278,709
1,228,161
Some additional short periods of planned downtime for preventative maintenance, pipe header cleaning,
and troubleshooting on individual pumps in the fourteen well system were experienced. Details of these
activities are:
Confined Sand Formation Withdrawal Well (SWW) Pumps
SWW-1: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed
lines. On 12/19 Replaced pumps.
SWW-2: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed
lines. On 1/3 replaced counter. On 1/13 replaced counter. On 1/18 adjusted counter.
SWW-3: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed
lines.
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
SWW-4: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed lines. On 12/5,
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed out pumps and
lines. On 11/29 replaced counter.
SWW-5: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed lines. On 12/5,
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed out pumps and
lines.
\\aurdata2\users\AUR1DDW\Reports\2006\Quarterly\TFRAS Report First Quarter 2006.doc
4

SWW-6: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed lines. On 12/5,
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed out pumps and
lines.
SWW-7: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed lines. On 12/5,
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed out pumps and
lines. On 1/19 replaced counter.
Croatan Formation Withdrawal Well (CWW) Pumps
CWW-1: On 11/2, 11/8, 11/16 and 11/30 flushed out
12/15, 12/20 and 12/27 flushed out pumps and lines.
lines.
CWW-2: On 11/2, 11/8, 11/16 and 11/30 flushed out
12/15, 12/20 and 12/27 flushed out pumps and lines.
lines.
pumps. On 11/16 and 11/30 flushed
On 1/11, 1/17, 1/24 and 1/30 flushed
pumps. On 11/16 and 11/30 flushed
On 1/11, 1/17, 1/24 and 1/30 flushed
CWW-3: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed
lines. On 11/28 replaced counter. On 1/6 replaced pump.
CWW-4: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed
lines. On 1/10 replaced lines.
CWW-5: On 11/2, 11/8, 11/16 and 11/30 flushed out pumps. On 11/16 and 11/30 flushed
12/15, 12/20 and 12/27 flushed out pumps and lines. On 1/11, 1/17, 1/24 and 1/30 flushed
lines. On 12/12 replaced counter.
CWW-6: On 11/2, 11/8, 11/16 and 11/30 flushed out
12/15, 12/20 and 12/27 flushed out pumps and lines.
lines.
CWW-7: On 11/2, 11/8, 11/16 and 11/30 flushed out
12/15, 12/20 and 12/27 flushed out pumps and lines.
lines. On 1/9 replaced pump and lines.
pumps. On 11/16 and 11/30 flushed
On 1/11, 1/17, 1/24 and 1/30 flushed
pumps. On 11/16 and 11/30 flushed
On 1/11, 1/17, 1/24 and 1/30 flushed
\\aurdata2\users\AUR1DDW\Reports\2006\Quarterly\TFRAS Report First Quarter 2006.doc
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
lines. On 12/5,
out pumps and
5

PCS
Phosphate AURORA
PCS PHOSPHATE COMPANY, INC.
P.O. BOX 48, AURORA, NC U.S.A. 27806
February 2, 2006
EVAN O. KANE
GROUND WATER
DENR
1636 MAIL SERVICE CENTER
RALEIGH, NC 27699-1636
CERTIFIED MAIL
Subject: Underground Injection Control Program
Quarterly Groundwater Monitoring Report
November 2005 — January 2006
Injection Well Permit #WI0700012
Tank Farm Remedial Action System
Beaufort Co.
Dear Evan:
Please find the subject groundwater monitoring report attached. This includes the sampling and reporting
requirements of the above referenced permit, Part V, Section B 1 as well as the reporting requirements of
the overall Tank Farm Remedial Action Plan. Enclosed are: a) Form GW-59 for injection well CIW7 and
monitor well MWTF I CR, b) piezometer level monitoring field sheet, and c) the summary operational and
maintenance report.
Please do not hesitate to contact me at [phone] if you have any questions regarding this
information.
Sincerely,
A kitAttii2 GJ4,-174
D. Daniel Winstead III
Environmental Engineer
PCS Phosphate
Attachments

pc: Annalee Harris — Aquifer Protection DWQ, WaRO (w/ attachments)
R. M. Smith/12-07-02 (w/ attachments)
T. S. Ingra - Ardaman & Assoc. (w/attachments)
R. A. Allen (w/ attachments)
W. A. Schimming (w/ attachments)
Two Copies — Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina, 27699
Attn: Information Management
E-Mail:
M. I). Johnson
Nubia Guzman
R. B. Lee
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2