WI0500499_Other Correspondence_20120706

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Appendix C
Material Safety Data Sheets
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Material Safety Data Sheet
SECTION I - PRODUCT IDENTIFICATION
Product name: All Molasses
Manufacturer's Name:
Emergency phone number:
Crosby Molasses Company Limited
327 Rothesay Ave., P.O. Box 2240
Saint John, N.B. Canada
E2L 3V4
Chemical Name & Synonyms:
Chemical family:
[phone]
Inverted syrup from the juice of sugar cane.
Sugars
SECTION 11 - HAZARDOUS INGREDIENTS
None
WHMIS RATING Rating: 0 = None - - - 4 = Extreme
Health 0 Flammability 1 Reactivity 0
Product is generally considered safe for human consumption. (GRAS)
SECTION III - PHYSICAL DATA
Physical state Viscous liquid
Vapour pressure Not determined
pH 5.1
Evaporation rate Not determined
Freezing point Less than minus 18 C
Odours & Appearance: Fruity sweet,
brown, clear viscous liquid.
Vapour density Not applicable
Specific gravity 1.4
Boiling point 107 C
Solubility in water Highly soluble
SECTION IV - FIRE & EXPLOSION HAZARD DATA
Flammability
Means of extinction
Flashpoint
Flammable limits
Will bum only under conditions of extreme heat.
Water
Not determined
Not determined
Special fire fighting procedures
Unusual fire 7 explosion hazards
Auto -ignition temperature 60 C
Use NIOH approved self-contained breathing apparatus
Material may spontaneously decompose at temperatures
over 60 C.
7/16/2004 MSDS Molasses July 2004

SECTION 5 - REACTIVITY DATA
Product is stable
Incompatibility with other substances None
Conditions to avoid Heat over 60 C. Keep container vented, too allow
release of co2 produced by natural yeast in product.
SECTION 6 - TOXICOLOGICAL PROPERTIES
None
SECTION 7 - PREVENTIVE MEASURES
Storage Keep container vented, to allow release of co2 produced by natural yeast in product.
Personal protective equipment Not required
Product is generally considered as safe for human consumption. (GRAS)
SECTION 8 - SPILL OR LEAK PROCEDURES
Wash with hot water. If large quantities are to be flushed into drains follow local regulations.
SECTION 9 - PREPARATION DATE OF MSDS
Prepared by Susan Ans WHMIS coordinator
Phone # 1 - 506 - 634 - 7515
Date July 14, 2004
molmsds.xls disc safety 1
7/16/2004 MSDS Molasses July 2004

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ACC# 60240
Material Safety Data Sheet
Eosin Y
Section 1 - Chemical Product and Company Identification
MSDS Name: Eosin Y
Catalog Numbers: BP2419-100, BP2419-25, E511-100, E511-25, NC9215708, NC9412829,
NC9607248
Synonyms: Acid Red 87; Bromoeosine; Disodium Eosine; Eosine Yellowish; Tetrabromfluorescein, CI
45380.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NO 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
CAS#
Chemical Name
Percent
EINECS/ELINCS
17372-87-1
ACID RED 87
100
241-409-6
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: red to brown solid.
Caution! May cause eye and skin irritation. May cause respiratory and digestive tract irritation.
The toxicological properties of this material have not been fully investigated.
Target Organs: No data found.
Potential Health Effects
Eye: May cause eye irritation. This product contains an anionic dye. Similar dyes have not caused
injury to the cornea or conjunctiva in documented exposure cases with human or rabbit eyes.
Skin: May cause skin irritation.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological
properties of this substance have not been fully investigated.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance
have not been fully investigated.
Chronic: No information found.
Section 4 - First Aid Measures
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Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Get medical aid.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Get medical aid if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid
immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: The use of sodium chloride as antidotal treatment for bromine salt ove rdose
should be made only by qualified medical personnel (Medical Toxi cology, 1988).
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure -demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol -resistant
foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Sweep up, then place into a suitable container for disposal. Avoid generating dusty
conditions.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse.
Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with skin
and eyes. Keep container tightly closed. Avoid ingestion and inhalation.
Storage: Store in a cool, dry, well -ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
CAI/V.7YI W I.IIIIIco
Chemical Name
ACGIH
NIOSH
OSHA - Final PELs
ACID RED 87
none listed
none listed
none listed
OSHA Vacated PELs: ACID RED 87: No OSHA Vacated PELs are listed for this chemical.
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Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's
eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are
exceeded or if irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
Physical State: Solid
Appearance: red to brown
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not applicable.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:Not available.
Molecular Formula:C20H8Br405.2Na
Molecular Weight:693.65
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, incompatible materials.
Incompatibilities with Other Materials: Strong oxidizers.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
RTECS#:
CAS# 17372-87-1: LM5850000
LD50/LC50:
CAS# 17372-87-1:
Oral, mouse: LD50 = 2344 mg/kg;
Carcinogenicity:
CAS# 17372-87-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information available.
Teratogenicity: No information available.
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Reproductive Effects: No information available.
Mutagenicity: Please refer to RTECS# LM5850000 for specific information.
Neurotoxicity: No information available.
Other Studies:
Section 12 - Ecological Information
Ecotoxicity: No data available. No information available.
Environmental: No information reported.
Physical: No information available.
Other: No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous
waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts.261.3
Additionally, waste generators must consult state and local hazardous waste regulations to ensure
complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
US DOT
Canada TDG
Shipping Name:
Please contact Fisher Scientific for
shipping information
No information available.
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 17372-87-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
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SARA Codes
CAS # 17372-87-1: immediate.
Section 313 No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 17372-87-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
Califomia No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 17372-87-1: 1
Canada - DSL/NDSL
CAS# 17372-87-1 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
MSDS Creation Date: 12/12/1997
Revision #7 Date: 2/18/2008
The information above is believed to be accurate and represents the best information currently available to us. However, we make
no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no
liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their
particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or
any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.
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Material Safety Data Sheet
Rhodamine B
ACC# 95508
Section 1 - Chemical Product and Company Identification
MSDS Name: Rhodamine B
Catalog Numbers: AC132310000, AC132311000, AC132315000
Synonyms: Basic Violet 10; C.I. 45170; FD 4C Red No. 19
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
CAS#
Chemical Name
Percent
EINECS/ELINCS
81-88-9
Rhodamine B
ca 100
201-383-9
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Appearance: violet crystals or powder.
Warning! Causes respiratory tract irritation. Causes eye and skin irritation. May cause digestive tract
irritation. This substance has caused adverse reproductive and fetal effects in animals.
Target Organs: No data found.
Potential Health Effects
Eye: Causes eye irritation. This product contains a cationic dye. Similar dyes have caused permanent
injury to the cornea and conjunctiva in documented exposure cases with human or rabbit eyes. May cause
chemical conjunctivitis.
Skin: Causes skin irritation.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological
properties of this substance have not been fully investigated.
Inhalation: Causes respiratory tract irritation. The toxicological properties of this substance have not
been fully investigated. Can produce delayed pulmonary edema.
Chronic: Effects may be delayed. Adverse reproductive effects have been reported in animals.
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper
and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
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Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure -demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic
gases may be generated by thermal decomposition or combustion.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills
immediately, observing precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
Section 7 - Handling and Storage
Handling: Wash thoroughly after handling. Minimize dust generation and accumulation. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Wash clothing before reuse.
Storage: Store in a tightly closed container. Store in a cool, dry, well -ventilated area away from
incompatible substances.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Chemical Name
ACGIH
NIOSH
OSHA - Final PELs
Rhodamine B
none listed
none listed
none fisted
OSHA Vacated PELs: Rhodamine B: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and
face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2
requirements or European Standard EN 149 must be followed whenever workplace conditions warrant
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respirator use.
Section 9 - Physical and Chemical Properties
Physical State: Crystals or Powder
Appearance: violet
Odor: Strong
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not available.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:210 deg C dec
Decomposition Temperature:> 210 deg C
Solubility: soluble
Specific Gravity/Density:>1.0
Molecular Formula:C28H31CIN203
Molecular Weight:478.68
Section 10 - Stability and Reactivity
Chemical Stability: Stable at room temperature in closed containers under normal storage and handling
conditions.
Conditions to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating
and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
RTECS#:
CAS# 81-88-9: BP3675000
LD50/LCSO:
CAS# 81-88-9:
Oral, mouse: LDS() = 887 mg/kg;
Carcinogenicity:
CAS# 81-88-9:
• ACGIH: Not listed.
• California: carcinogen, Initial date 7/1/90
• NTP: Not listed.
• IARC: Not listed.
Epidemiology: IARC Group 3: Suspected animal carcinogenic substance of potential relevance to
humans.
Teratogenicity: Toxic dose, rat = 3870 mg/kg.
Reproductive Effects: Adverse reproductive effects have occurred in experimental animals.
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Mutagenicity: Mutagenic effects have occurred in experimental animals.
Neurotoxicity: No information available.
Other Studies:
Section 12 - Ecological Information
No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous
waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally,
waste generators must consult state and local hazardous waste regulations to ensure complete and
accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
US DOT
Canada TDG
Shipping Name:
Please contact Fisher Scientific for shipping
information
No information available.
Hazard Class:
UN Number:
Packing Group:
Section 15 - Regulatory Information
US FEDERAL
TSCA
CAS# 81-88-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals In this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals In this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals In this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals In this product have a TPQ.
SARA Codes
CAS # 81-88-9: acute, chronic.
Section 313
This material contains Rhodamine B (CAS# 81-88-9, ca 100%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
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This material does not contain any Class 1 Ozone depletors. -
This material does not contain any Class 2 Ozone-depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are listed as Priority Pollutants under the CWA.
None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 81-88-9 can be found on the following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
California Prop 65
The following statement(s) is(are) made in order to comply with the California Safe Drinking
Water Act:
WARNING: This product contains Rhodamine B, a chemical known to the state of California to cause
cancer.
California No Significant Risk Level: None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 36/37 Wear suitable protective clothing and gloves.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 81-88-9: 2
Canada - DSL/NDSL
CAS# 81-88-9 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2A, D2B.
Canadian Ingredient Disclosure List
CAS# 81-88-9 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
MSDS Creation Date: 9/02/1997
Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best information currently available to us. However, we make no
warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting
from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no
event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental,
consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.
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