NCG030694_2021 DMR_20210623

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
Via Online Portal & 2nd Day FedEx
June 23, 2021
North Carolina Department of Environmental Quality
Division of Energy, Mineral and Land Resources
450 West Hanes Mill Road, Suite 300
Winston-Salem, North Carolina 27105
Re: DMR September 2021 — NCG030694 — LLFIex, LLC
Oracle Flexible Packaging, Inc. (Former)
1300 Cunningham Avenue
Winston-Salem, Forsyth County
H&H Proiect No. L L F-007
Dear Madam/Sir:
On behalf of LLFIex, LLC (LLFIex), Hart & Hickman, PC (H&H) is submitting the enclosed semi-
annual stormwater Discharge Monitoring Report (DMR) for the site referenced above in
accordance with the industrial stormwater permit (NCG030694). Please note there are benchmark
value metal exceedances in Stormwater Discharge Outfall (SDO) samples SDO-003, SDO-004,
and SDO-005. Copper was detected found above the benchmark of 0.010 mg/L for SDO-003
(0.0245 mg/L), SDO-004 (0.0150 mg/L) and SDO-005 (0.0162 mg/L). Zinc was detected above
the benchmark of 0.126 mg/L for SDO-003 (0.131 mg/L). Historically, the Former Cunningham
Plant outfalls have exceeded the benchmarks of zinc and copper.
In 2014, DEQ performed an inspection to assess compliance with the NPDES general stormwater
permit to evaluate the drainage of the facility's five SDOs. The SDOs were found to be in excellent
condition and concluded in a letter dated June 5, 2014 that offsite sources have opportunities to
contaminate samples taken from outfalls 1, 2, 4 and 5. Considering the 2014 NC DEQ letter, the
only metal exceedance requiring a tiered response is zinc in SDO-003.
Because prior results detected no exceedances in SDO-003 above the benchmark for zinc, a Tier
One response will be documented in the Stormwater Pollution Prevention Plan (SPPP) in
accordance with the industrial stormwater permit (NCG030694). This response will identify
potential causes and feasible actions to prevent exceedances in the future. The response will also
list monitoring and inspection details such as the date and value of the benchmark exceedance, the
inspection date, selected actions, and the date the selected actions are implemented.
Additionally, a stormwater management inspection will be conducted to evaluate whether
conditions can be improved to prevent exceedances in the future.
2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd, Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919.847.4241 main

June 23, 2021
Page 2
Should you have any questions or need any additional information, please feel free to contact us.
Sincerely,
Hart & Hickman, PC
XOO
/ ' "mil
Matt Bramblett, PE
Principal
Enclosures
Me
Gregory Kanellis, PE
Project Manager
CC: Mr. Jason Caple, LLFlex (PDF via email)
Ms. Mary Katherine Stukes, Moore & Van Allen (PDF via email)
hart hickman
httpS:11h2rihlCk.ShkYepo�gl.CAmIS�t¢Slmasterfiles-]lshared dpcumenFs/2aa-m25t¢r proj¢ct0flex, lie (11i)NF-007 swppp monitoring 2020-20211dmrslane 20211202106 dmr SMARTEN ENVIpONMENTAL SOLUTIONS
cover letter.dom

NCDEQ Division of Energy, Mineral and Land Resources
Stormwater Discharge Monitoring Report (DMR) Form for NCG030000
Metal Fabrication
Click here for instructions
Complete, sign, scan and submit the DMR via the Stormwater NPDES Permit Data Monitoring Report (DMR
I Upload form within
30 days of receiving sampling results. Mail the original, signed hard copy of the DMR to the appropriate DEMLR Regional Office.
Certificate of Coverage No. NCG03 0 6 9 4 Person Collecting Samples: Glenn Price (Pace Analytical)
Facility Name: Former Oracle200 Facility Laboratory Name: Pace Analytical
Facility County: Forsyth Laboratory Cert. No.: Asheville, NC(40), Eden, NC (633), Huntersville, NC (12)
Discharge during this period: ❑■ Yes ❑ No (if no, skip to signature and date)
Has your facility implemented mandatory Tier response actions for any benchmark exceedances? ❑■ Yes ❑ No
If so, which Tier (1, 11, or III)? 1
Analytical Monitoring Requirements for Outfalls with industrial Activities — Benchmarks in (Red)
Parameter
Parameter
Outfall01
Outfall02
Outfall 03
Outfall 04
Outfall 05
Code
N/A
Receiving Stream Class
C
C
C
C
C
N/A
Date Sample Collected MM/DD/YYYY
06/10/2021
06/10/2021
06/10/2021
06/10/2021
06/10/2021
46529
24-Hour Rainfall in inches
3.5
3.5
3.5
3.5
3.5
00552
Non -Polar Oil & Grease in mg/L (25)
<5
<5
<5
<5.7
<5.3
C0530
TSS in mg/L (100 or 50*)
10
8.9
11.2
32.3
51.4
00400
pH in standard units (6.0-9.0)
7.07
6.93
6.91
7.14
6.88
New Motor/Hydraulic Oil Usage in
NCOIL
gal/month
01119.
Copper, total recoverable in mg/L
0.008
0.0072
0.0245
0.0150
0.0162
(0.010 FW, 0.005 SW)
01051
Lead, total recoverable in mg/ L
<0.005
<0.005
0.0068
<0.005
<0.005
(0.075 FW, 0.220 SW)
01094
Zinc, total recoverable in mg/ L (0.126
0.0370
0.0363
0.131
0.0803
0.0823
FW, 0.095 SW)
78141
Total Toxic Organics (TTO) in mg/L(1)
* Outfalls to Outstanding Resource Waters (ORW), High Quality Waters (HQW), Trout Waters (Tr) and Primary Nursery Areas (PNA)
have a benchmark TSS limit of 50 mg/L. All other water classifications have a benchmark of 100 mg/L.
Notes (optional):
"I certify by my signature below, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for
gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations." f7
Signature o�ermittee gated Authorized Individual
Date
Page 27 of 27

acmnalytical
www.pacelabs cam
June 21, 2021
Greg Kanellis
Hart & Hickman
3921 Sunset Ridge Rd.
Suite 301
Raleigh, NC 27607
RE: Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Dear Greg Kanellis:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on June 11, 2021. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
• Pace Analytical Services - Kernersville, NC
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
�-
Kevin Godwin
[e-mail]
1(704)875-9092
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 27

aceAnalytical
www.pacelabs.com
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
LouisianalNELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirgintaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 KinceyAve. Suite IN
Huntersville, NC 28078
[phone]
Page 2 of 27

aceAnalytical
www.pacelabs.cnm
SAMPLE ANALYTE COUNT
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28DIB
[phone]
Analysts
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92543776001
Outfall SD01
SM 254OD-2011
LRB
1
PASI-E
EPA 9664E
CJM
1
PASI-C
EPA 200.7 Rev 4.4 1994
IDS
3
PASI-A
AF
4
PASI-KR
92543776002
Outfall SD02
SM 254OD-2011
LRB
1
PASI-E
EPA 1664B
CJM
1
PASI-C
EPA 200.7 Rev 4.4 1994
DS
3
PASI-A
AF
4
PASI-KR
92543776003
Outfall S1303
SM 25401)-2011
LRB
1
PASI-E
EPA 1664B
CJM
1
PASI-C
EPA 200.7 Rev 4.4 9994
IDS
3
PASI-A
AF
4
PASI-KR
92543776004
Outfall SD04
SM 254OD-2011
LRB
1
PASI-E
EPA 1664B
CJM
1
PASI-C
EPA 200.7 Rev 4.4 ;1994
IDS
3
PASI-A
AF
4
PASI-KR
92543776005
Outfall SD05
SM 254OD-2011
LRB
1
PASI-E
EPA 16646
CJM
1
PASI-C
EPA 200.7 Rev 4.4 9994
IDS
3
PASI-A
AF
4
PASI-KR
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
PASI-KR = Pace Analytical Services - Kernersville, NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 27

aoAnalj cal
wwwpacelabsxam
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Outfall SD01 Lab ID: 92543776001 Collected: 06/10/21 11:30 Received: 06/11/21 08:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
10 mg1L 3.8
1
06/14/21 09:50
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mglL 5.0
1
06/18/21 09:45
200.7 MET ICP
Analytical Method: EPA 200.7 Rev4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
8.0 ug1L 5.0
1
06/16/2116:12 06/18/21 02:19 7440-50-8
Lead
ND ug1L 5.0
1
06/16/2116:12 0611812102:19 7439-92-1
Zinc
37.0 ug1L 10.0
1
06/1612116:12 06/18/21 02:19 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
06/10/21 11:30
Collected By
Glenn
1
06A0121 11:30
Price
pH
7.07 Std. Units
1
06/10/21 11:30
Temperature
19 deg C
1
06/10/21 11:30
Date: 06/21/2021 08:42 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 27

(�IacleAnalytical"
www.paDelabs can
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services, LLC
9800 KinceyAve, Suite 100
Huntersville, NC 28078
[phone]
Sample: Outfall SD02 Lab ID: 92543776002 Collected: 06/10/21 11:21 Received: 06/11/21 08:11 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared
Analyzed CAS No.
25400 Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
8.9 mg/L 4.4
1
06/14/21 09:49
1664 SGT-HEM, TPH
Analytical Method: EPA 1664E
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg/L 5.0
1
06/16/21 08:25
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
Capper
7.2 ug/L 5.0
1
06/16/21 16:12
06/18/21 02:29 7440-50-8
Lead
ND ug/L 5.0
1
06116/2116:12
06/1812102:29 7439-92-1
Zinc
36.3 ug/L 10.0
1
06/16/21 16:12
06/18/21 02:29 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
06/10/21 11:21
Collected By
Glenn
1
06/10121 11:21
Price
pH
6.93 Std. Units
1
06/10/21 11:21
Temperature
20 deg C
1
06/10/21 11:21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21/2021 08:42 AM without the written consent of Pace Analytical Services, I-l.C.
Qual
Page 5 of 27

aceAnalytical
W".pecalahs.cota
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Sample: Outfall SD03 Lab ID: 92543778003 Collected: 06/10/21 11:09 Received: 06/11/21 08:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
11.2 mg1L 4.1
1
06/14/21 09:50
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg1L 5.0
1
06/16/21 08:25
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
Copper
24.5 ug/L 5.0
1
06/16/21 16:12 06/18/21 02:32 7440-50-8
Lead
6.8 ug/L 5.0
1
06/16/21 16:12 06/18/21 02:32 7439-92-1
Zinc
131 ug/L 10.0
1
06116/21 16:12 06/18/21 02:32 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
06/10/21 11:09
Collected By
Glenn
1
06/10/21 11:09
Price
pH
6.91 Std. Units
1
06/10/21 11:09
Temperature
19 deg C
1
06/10/21 11:09
Date: 06/21 /2021 08:42 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 27

aceAnaljftal
www.pacelabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, HC 28078
[phone]
Sample: Outfall SD04 Lab ID: 92543778004 Collected: 06/10/21 11:14 Received: 06/11/21 08:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
32.3 mg1L 4.5
1
061141211 09:50
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg1L 5.7
1
06/16/21 08:25
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
Copper
15.0 uglL 5.0
1
0611612116:12 06/18/21 02:35 7440-50-8
Lead
ND uglL 5.0
1
06/1612116:12 06/18/21 02:35 7439-92-1
Zinc
80.3 uglL 10.0
1
0611612116:12 06/18/21 02:35 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
06/10/21 11:14
Collected By
Glenn
1
06/10/21 11:14
Price
pH
7.14 Std. Units
1
06/10/21 11:14
Temperature
19 deg C
1
06/10/21 11:14
Date: 06/21/2021 08:42 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 27

aceAnalXical"
www.pacelabs.com
ANALYTICAL RESULTS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Outfall SD05 Lab ID: 92543776005 Collected: 06/10/21 11:01 Receiver[: 06/11/21 08:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2640D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
51.4 mg/L 5.8
1
06/14/21 09:49
1664 SGT-HEM, TPH
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
Total Petroleum Hydrocarbons
ND mg/L 5.3
1
06/16/21 08:25
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
Capper
16.2 ug/L 5.0
1
06/16121 16: 12 06/18/21 02:39 7440-50-8
Lead
ND ug/L 5.0
1
06/1612116:12 0611812102:39 7439-92-1
Zinc
82.3 ug/L 10.0
1
06/1612116:12 06/18/21 02:39 7440-66-6
Field Data Kernersville
Analytical Method:
Pace Analytical Services - Kernersville, NC
Performed by
Pace
1
06/10/21 11:01
Collected By
Glenn
1
06/10/21 11:01
Price
pH
8.88 Sid. Units
1
06/10/21 11:01
Temperature
21 deg C
1
06/10/21 11:01
Date: 06/21/2021 08:42 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 27

laceAnalyticale
wuuw.pecela5s.com
QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
QC Batch: 626820 Analysis Method: SM 2540D-2011
QC Hatch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92543776001, 92543776002, 92543776003, 92543776004, 92543776005
METHOD BLANK: 3295578 Matrix: Water
Associated Lab Samples: 92543776001, 92543776002, 92543776003, 92543776004, 92543776005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mglL ND 2.5 06/14/21 09:47
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
t704j875-9092
LABORATORY CONTROL SAMPLE: 3295579
Spike LCS LCS % Rec
Parameter Units Cone. Result % Pee Limits Qualifiers
Total Suspended Solids mg1L 250 228 91 90-110
SAMPLE DUPLICATE: 3295580
Parameter
Total Suspended Solids
SAMPLE DUPLICATE: 3295581
Parameter
Total Suspended Solids
Units
92543778001
Result
Dup
Result
mg1L
84.2
83.0
Units
92543717001
Result
Dup
Result
mg1L
283
295
RPD Qualifiers
1
RPD Qualifiers
4
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21 /2021 08:42 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 27

aceAnaij tical
wM.pacelabls.cem
QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
QC Batch: 627301 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92543776002, 92543776003, 92543776004, 92543776005
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 3297920
Matrix: Water
Associated Lab Samples: 92543776002, 92543776003, 92543776004, 92543776005
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Petroleum Hydrocarbons
mglL
ND 5.0
06/16/21 08:25
LABORATORY CONTROL SAMPLE:
3297921
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mg1L
20 19.9
100 64-132
MATRIX SPIKE SAMPLE:
Parameter
3297922
Units
35639764001
Result
Spike MS MS % Rec
Cone. Result % Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mglL
5.1U
19.8 ND 9 64-132
SAMPLE DUPLICATE: 3297923
92542516002
Dup
Parameter
Units
Result
Result RPD Qualifiers
Total Petroleum Hydrocarbons
mglL
63.9
54.2 16
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21/2021 08:42 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 27

aceAnalj cal o
www.pacelabs.cam
QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services, LLC
9800 Kincey Ave, Suite 100
Huntersville, NC 28078
[phone]
QC Balch: 627956
Analysis Method:
EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description:
1664 SGT-HEM, TPH
Laboratory:
Pace Analytical Services - Charlotte
Associated Lab Samples: 92543776001
METHOD BLANK: 3301078
Matrix: Water
Associated Lab Samples: 92543776001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Petroleum Hydrocarbons
mg1L
ND 5.0 06/18/21 09:45
LABORATORY CONTROL SAMPLE: 3301079
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mglL
20 16.4
82 64-132
MATRIX SPIKE SAMPLE: 3301080
92543823002 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Total Petroleum Hydrocarbons
mglL
21.4 19.6
26.9 28 64-132
SAMPLE DUPLICATE: 3301081
70176238001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Petroleum Hydrocarbons
mglL
12.9 10.4 22
Results presented on thls page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fall,
Late: 06/21/2021 08:42 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 27

laneAnalyfical"
wwwpacalabs.com
QUALITY CONTROL DATA
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
QC Batch: 627519
Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994
Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92543776001, 92543776002, 92543776003, 92543776004, 92543776005
METHOD BLANK: 3298986
Matrix: Water
Associated Lab Samples: 92543776001, 92543776002, 92543776003, 92543776004, 92543776005
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Copper ug1L
ND 5.0 06/18/2102:06
Lead ug1L
ND 5.0 06/18/2102:06
Zinc ug1L
ND 10.0 06/18/2102:06
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvilte, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
3298987
Spike
LCS LCS % Rec
Parameter
Units
Cone.
Result % Rec Limits Qualifiers
Copper
ug1L
500
518 104 85-115
Lead
uglL
500
493 99 85-115
Zinc
ug1L
500
473 95 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3298988
3298989
MS
MSD
92543776001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Cone.
Result
Result
% Rec
% Rec
Limits RPD Qual
Copper uglL
8.0
500
500
494
489
97
96
70-130 1
Lead uglL
ND
500
500
471
470
94
94
70-130 0
Zinc ug/L
37.0
500
500
500
558
93
104
70-130 11
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21/2021 08:42 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 27

larkaAnapical
www.pacalabs.coro
QUALIFIERS
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
a7:491I11Wilfrelkif-1
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvifle, NC 28078
[phone]
PQL - Practical Quantitation Limit.
RL- Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/21/2021 08:42 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 27

aceAna1j&al
www.pacelabs.cam
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Hart & Hickman Oracle 200
Pace Project No.: 92543776
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample IA
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92543776001
Outfall SD01
SM 254OD-2011
626820
92543776002
Outfall S1302
SM 254OD-2011
626820
92543776003
Outfall SD03
SM 2540D-2011
626820
92543776004
Outfall SD04
SM 2540D-2011
626820
92643776005
Outfall SD05
SM 2540D-2011
626820
92543776001
Outfall SD01
EPA 1664E
627956
92643776002
Outfall SD02
EPA 1664B
627301
92543776003
Outfall SD03
EPA 1664B
627301
92643776004
Outfall SD04
EPA1664B
627301
92543776005
Outfall SD05
EPA 1664B
627301
92543776001
Outfall SD01
EPA 200.7 Rev 4.4 1994
627519
EPA 200.7 Rev 4.4 1994
627649
92543776002
Outfall SD02
EPA 200.7 Rev 4.4 1994
627519
EPA 200.7 Rev 4.4 1994
627649
92543776003
Outfall SD03
EPA 200.7 Rev 4.4 1994
627519
EPA 200.7 Rev 4.4 1994
627649
92543776004
Outfall SD04
EPA 200.7 Rev 4.4 1994
627519
EPA 200.7 Rev 4.4 1994
627649
92543776005
Outfall SD05
EPA 200.7 Rev 4.4 1994
627519
EPA 200.7 Rev 4.4 1994
627649
92543776001
Outfall S1301
92543776002
Outfall SD02
92543778003
Outfall SD03
92543776004
Outfall SD04
92543776005
Outfall SD05
Date: 06/21 /2021 08:42 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 27

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Document No.: Issuing Authority:
F•CAR-L4-03•Rev.06 Pace CaraAnas Quallty Office
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pH Adjustment Log for Preserved Sartiples
Sample to rypeof Prwirvative pH upan racelpt bite presarrattan irdlutted Time prezerfiHan Amount of Preservative
adjumd added
Note: Whanaver there is a discrepancl affecting North Carolina compliance samples, a Copy at this farm will W rent to the North Carafina DEHNR CertUicitlon
Out of hold, incorrect pre servalive, out of temp, incorrect containarf,
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Page 16 of 27