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HomeMy WebLinkAboutNCG030390_DMR_20210222QEERLESS B L O W E R S Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, N.C. 27699-1617 Sir or Madam: P.O. Box 187 172 South Andrews Ave. Not Springs, NC 28743 828-622-7500 3b3`1d A R0 RECEIVED MAR 15 Z02i CENTRAL FILES DWR oECTION Enclosed is analysis for a recent storm water event. We have two outfalls, one flows to the French Broad River and the other to Spring Creek. The event took place on 2/22/21, samples were collected after 1 hour and 30 minutes of rain that produced .3 inches of rain in that period of time. Both outfalls are from roof and parking lot drains and there are no manufacturing or storage activity outside of the building. kr, -1, 4�zla�al� Don Wallin Materials/Maintenance Director Pace Analytical Services, LLC acemalxiaal 2225 Riverside Asheville, NC 28804 WmPacelabsx0m (826)254-7176 March 03, 2021 Mr. Donald Wallin MMC, Peerless Blowers 172 South Andrews Avenue Hot Springs, NC 28743 RECEIVED MAR 15 2021 RE: Project: Peerless Stormwater ­CI'q I R L RL a Pace Project No.: 92523505 C3VVn SEECTION Dear Mr. Wallin: Enclosed are the analytical results for sample(s) received by the laboratory on February 23, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton Iorri. patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 IeIV IQOcal 1rnflRp�di6s<.COIG Project: Peerless Stormwater Pace Project No.: 92523505 Paco Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification * 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification M 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Flodda/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, I.I.C. Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Page 2 of 23 CeAnaly bl trw��ehC�am SAMPLE ANALYTE COUNT Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92523505001 OUTFALL #1 EPA 1664B TEG 1 PASI-C EPA 200.7 Rev 4.4 1994 KQ 3 PASI-A EPA 625.1 PKS 59 PASI-C EPA624.1 PM1 37 PASI-C SM 254OD-2011 RED 1 PASI-A 92623505002 OUTFALL #2 EPA 1664E TEG 1 PASI-C EPA 200.7 Rev 4.41994 KO 3 PASI-A EPA 625.1 PKS 59 PASI-C EPA624.1 PM1 37 PASI-C SM 254OD-2011 RED 1 PASI-A PASI-A= Pace Analytical Services -Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 lceftVical a trMkp��btfi0tn ANALYTICAL RESULTS Project: Peerless Stormwater Pace Analytical Services, LLC 2226 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Project No.: 92523505 Sample: OUTFALL #1 Lab ID: 92523505001 Collected: 02/22/21 11:30 Received: 02/23/21 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT HEM, TPH Analytical Method: EPA 1664B Pace Analytical Services - Charlotte Total Petroleum Hydrocarbons ND mg/L 5.0 1 03/03/21 09:40 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4A 1994 Pace Analytical Services -Asheville Copper 5.8 ug/L 5.0 1 02/2612102:07 02128/2120:28 7440-50-8 Lead ND ug/L 5.0 1 02126/2102:07 0212812120:28 7439-92-1 Zinc 16.4 ug/L 10.0 1 02126/2102:07 02/28/2120:28 7440-66-6 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 83-32-9 Acenaphthylene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 208-96-8 Anthracene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 120-12-7 Benzidine ND ug/L 50.0 1 0212612107:54 02/26/2121:43 92-87-5 IL Benzo(a)anthracene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 0212612107:54 02/26/2121:43 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 02/26/21 07:54 02/26/2121:43 205-99-2 Benzo(g,h,i)perylene ND uglL 5.0 1 02/2612107:54 02/26/2121:43 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 207-08-9 4-Bromophenytphenyl ether ND ug/L 5.0 1 02126/21 07:64 02126/2121:43 101-55-3 Butylbenzytphthalate ND ug/L 5.0 1 02/26/2107:54 02/2612121:43 85-68-7 4-Chloro-3-methytphenol ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02126/2107:54 02/26/2121:43 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 0212612107:54 02/26/2121:43 91-58-7 2-Chlorophenol ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 0212612107:54 02/26/2121:43 7005-72-3 Chrysene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 0212612107:54.02/26/2121.43_53-70-3 _ 3,3'-Dichlorobenzidine ND ug/L 10.0 1 02/2612107:64 02126/2121:43 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 02126/2107:54 02126/2121:43 120-83-2 Diethylphthalate ND ug/L 5.0 1 02126/2107:54 02/2612121:43 84-66-2 2,4-Dimethytphenol ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 105-67-9 Dimethytphthalate ND ug/L 5.0 1 02/26/2107:54 02/2612121:43 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 02/26/2107:54 02/2612121:43 84-74-2 4,6-Dir itro-2-methytphenol ND ug/L 10.0 1 0212612107:54 02/2612121:43 534-52-1 2,4-Dir itrophenol ND ug/L 50.0 1 02/26/21 07:54 02/2612121:43 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 02/26/2107:54 02/2612121:43 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 02/26/2107:54 02/2612121:43 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 02/26/2107:54 02126/2121:43 117-84-0 1,2-Diphenythydrazine ND ug/L 5.0 1 02126/2107:54 02126/2121:43 122-66-7 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 02126/2107:54 02126/2121:43 117-81-7 Fiuoranthene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 206-44-0 Fluorene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 02126/2107:64 02126/2121:43 87-68-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, I.I.C. Page 4 of 23 IeAlbc?tCt?1 armpaalths.= ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #1 Parameters Lab ID: 92523505001 Collected: 02122/21 11:30 Results Units Report Limit DF Received: 02/23121 12:00 Matrix: Water Prepared Analyzed CAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Hexachlorobenzene ND ug/L 5.0 1 02/26/2107:54 02/2612121:43 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 02/2612107:54 02/26/2121:43 77-47-4 Hexachloroethane ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 193-39-5 Isophorone ND ug/L 10.0 1 02/26/2107:54 02/2612121:43 78-59-1 Naphthalene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 91-20-3 Nitrobenzene ND ug/L 5.0 1 02/26/21 07:54 02/26/2121:43 98-95-3 2-Nitrophenol ND ug/L 5.0 1 02/26/21 07:54 0212612121:43 88-75-5 4-Nitrophenol ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 100-02-7 N-Nitrosodimethylamine ND ug/L 6.0 1 02/26/2107:54 02/26/2121!43 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 02/2612107:54 02/26/2121:43 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 02/26/2107:54 02/26/2121:43 86-30-6 Pentachloropheno) ND ug/L 10.0 1 02/2612107:54 02126/2121:43 87-86-5 Phenanthrene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 85-01-8 Phenol ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 108-95-2 Pyrene ND ug/L 5.0 1 02/26/2107:54 02/26/2121:43 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 02126/2107:54 02/26/2121:43 120-82-1 2,4,6-Tdchlorophenol ND ug/L 10.0 1 02126/2107:54 02/26/2121:43 88-06-2 Surrogates Nitrobenzene-d5 (S) 76 % 10-120 1 02/26/21 07:54 02/26/21 21:43 4165-60-0 2-Fluorobiphenyl (S) 58 % 15-120 1 02126/2107:54 02/26/21 21:43 321-60-8 Terphenyl-d14 (S) ill % 11-131 1 02126/2107:54 02/26/2121:43 1718-51-0 Phenol-d6 (S) 39 % 10-120 1 =26/21 07:54 02/26/2121:43 13127-88-3 2-Fluorophenol (S) 51 % 10-120 1 02126/2107:54 02/2612121:43 367-12-4 2,4,6-Tribmmophenol (S) 85 % 10-137 1 02/26/21 07:54 02/26/21 21.43 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA624.1 Pace Analytical Services - Charlotte Acrolein NO ug/L 5.0 1 02124/2120:23 107-02-8 Acrylonitrile NO ug/L 5.0 1 0212412120:23 107-13-1 Benzene NO ug/L 1.0 1 0212412120:23 71-43-2 Bromodichloromethane ND ug/L 2.0 1 02/2412120:23 75-27-4 Bromoform NO ug/L 2.0 1 02/24/2120:23 75-25-2 Bromomethane NO ug/L 2.0 1 02/2412120:23 74-83-9 Carbon tetrachloride NO ug/L 2.0 1 02/24/2120:23 56-23-5 Chlorobenzene ND ug/L 2.0 1 02/24/2120,23 108-90-7 Chloroethane ND ug/L 2.0 1 02124/2120:23 75-00-3 2-Chioroethylvinyl ether ND ug/L 5.0 1 02124/2120:23 110-76-8 Chloroform ND ug/L 2.0 1 0212412120:23 67-66-3 Chloromethane ND ug/L 2.0 1 02124/2120:23 74-87-3 RI Dibromochloromethane ND ug/L 2.0 1 02/24/2120:23 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:23 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 02124/2120:23 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 02124/2120:23 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 0212412120:23 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 0212412120:23 107-06-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 23 lCeAnaocalo w mr paedahu m ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2226 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #1 Lab ID: 92623505001 Collected: 02122/21 11:30 Received: 02/23/21 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Acroleln 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Methylene Chloride 1,1,2, 2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Tdchloroethane 1,1,2-Trichloroethane Trichlorcethene Trichlorofluoromethane Vinyl chloride Surrogates 4-Bromofluorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 2540D Total Suspended Solids Total Suspended Solids Sample: OUTFALL #2 Parameters 1664 SGT HEM, TPH Total Petroleum Hydrocarbons 200.7 MET ICP Copper Lead Zinc 625 RVE Acenaphthene Acenaphthylene Anthracene Date: 03/03/2021 03:40 PM Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte ND ug/L 2.0 1 02124/2120:23 75-35-4 ND ug/L 2.0 1 02/24/2120:23 156-59-2 ND ug/L 2.0 1 02/24/2120:23 156-60-5 ND ug/L 2.0 1 02124/2120:23 78-87-5 ND ug/L 2.0 1 02124/2120:23 10061-01-5 ND ug/L 2.,0 1 02124/2120:23 10061-02-6 ND ug/L 1.0 1 02/24/2120:23 100-41-4 ND ug/L 2.0 1 02124/2120:23 75-09-2 ND ug/L 2.0 1 02/24/2120:23 79-34-5 ND ug/L 2.0 1 02/24/2120:23 127-18-4 ND ug/L 1.0 1 02/24/2120:23 108-88-3 ND ug/L 2.0 1 02/24/2120:23 71-55-6 ND ug/L 2.0 1 02/24/2120:23 79-00-5 ND ug/L 2.0 1 02/24/2120:23 79-01-6 ND ug/L 2.0 1 02/24/2120:23 75-69-4 ND ug/L 2.0 1 02/24/2120:23 75-01-4 102 % 70-130 1 02/24121 20:23 460-00-4 98 % 70-130 1 02/24/2120:23 2037-26-5 92 % 70-130 1 02/24/2120:23 17060-07-0 Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville ND mg/L 2.5 1 02/25/2119:27 Lab ID: 92523605002 Collected: 02/22/21 11:20 Received: 02/23/21 12:00 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 1664E Pace Analytical Services - Charlotte ND mg/L 5.0 1 03/0312109:39 Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.41994 Pace Analytical Services -Asheville 6.1 ug/L 5.0 1 02/26/21 02:07 02128/21 20:31 7440-50-8 ND ug/L 5.0 1 02/26/2102:07 0212812120:31 7439-92-1 67.3 ug/L 10.0 1 02/26/21 02:07 02/28/21 20:31 7440-66-6 Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 83-32-9 ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 208-96-8 ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 120-12-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, I.I.C. Page 6 of 23 ceArraiytiri tfinr ptctltia t om ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #2 Parameters Lab ID: 92523505002 Results Units Collected: 02/22/21 11:20 Report Limit DF Received: 02/23/21 12:00 Matrix: Water Prepared Analyzed GAS No. Qual 626 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Pace Analytical Services - Charlotte Benzidine ND ug/L 50.0 1 02/26/2107:54 02/26/2122:11 92-87-5 IL Benzo(a)anthracene ND ug/L 5.0 1 02/26/21 07:54 02126/2122:11 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 02/26/2107:54 0212612122:11 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 02/26/2107:54 02126/2122:11 111-91-1 bis(2-Chloroethyn ether ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 91-58-7 2-Chlorophenol ND ug/L 5.0 1 02/26/2107:64 02/26/2122:11 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 02126/2107:54 02/26/2122:11 7005-72-3 Chrysene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 218-01-9 Dibenz(a,h)anthraoene ND ug/L 5.0 1 0212612107:54 0212612122:11 53-70-3 3,3'-Dichlorobenzidine ND ug/L 10.0 1 02/2612107:54 02/26/2122:11 91-94-1 2,4-Dichicrophenol ND ug/L 5.0 1 02/2612107:64 02/26/2122:11 120-83-2 Diethyiphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 02/26/2107:64 02/26/2122:11 105-07-9 Dimethylphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 02/26/2107:54 02/26/2122:11 534-52-1 2,4-Dinitrophenoi ND ug/L 50.0 1 02/2612107:54 02/2612122:11 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 0212612107:54 02/26/2122:11 121-14-2 2,6-Dinilrotoluene ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 117-84-0 1,2-Diphenylhydrazirle ND ug/L 5.0 1 02126/2107:54 02/26/2122:11 122-66-7 bis(2-Ethythexyl)phthalate ND ug/L 5.0 1 02t26/21 07:54 02/26W 22:11 117-81-7 Fluoranthene ND ug/L 5.0 1 02/26/2107:54 02/2612122:11 206-44-0 Fluorene ND ug/L 5.0 1 02/26/21 07:54 02/26/2122:11 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 02126/2107:54 02/26/2122:11 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 02/26/2107:54 02126/2122:11 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 02/26/2107:54 02/2612122:11 77-47-4 Hexachloroethane ND ug/L 5.0 1 02/2612107:54 02/26/2122:11 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 193-39-5 Isophorone ND ug/L 10.0 1 02/2612107:54 02126/2122:11 78-59-1 Naphthalene ND ug/L 5.0 1 02/26/2107:54 02/26/2122:11 91-20-3 Nitrobenzene ND ug/L 5.0 1 02/2612107:54 02126/2122:11 98-95-3 2-Nitrophenol ND ug/L 5.0 1 02126/2107:64 02126/2122:11 88-75-5 4-Nitrophenol ND ug/L 10.0 1 0212612107:54 02126/2122:11 100-02-7 N-Nitrosodimethylamine ND ug1L 5.0 1 02126/2107:54 0212612122:11 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 02/2612107:54 0212612122:11 621-64-7 N-Nitrosodiphenylamine ND ug1L 10.0 1 0212612107:54 0212612122:11 86-30-6 Pentachlorophenol ND ug/L 10.0 1 02126/2107:54 02/26/2122:11 87-86-5 Phenanthrene ND ug/L 5.0 1 0212612107:54 02/26/2122:11 85-01-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 23 Pace Analytical Services, LLC (,�,�� 2225 Riverside Dr. 16417AW Asheville, NC 28804 t Mpail" OfG (828)254-7176 ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Sample: OUTFALL #2 Lab ID: 92623606002 Collected: 02/22121 11:20 Received: 02/23/21 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA625.1 Preparation Method: EPA625.1 Pace Analytical Services - Charlotte Phenol ND ug/L 5.0 1 02/26/21 07:54 02/260 22:11 108-95-2 Pyrene NO ug/L 5.0 1 02/26/21 07:54 02/26/21 22:11 129-00-0 1,2,4-Trichlorobenzene NO ug/L 5.0 1 02126/2107:54 02/26/2122:11 120-82-1 2,4,6-Tdchlorophenol NO ug/L 10.0 1 02/26/2107:54 02/26/21 22:11 88-06-2 Surrogates Nitrobenzene-d5 (S) 68 % 10-120 1 02/26/21 07:54 02/26/21 22:11 4165-60-0 2-Fluorobiphenyl (S) 52 °% 15-120 1 02/26/21 07:54 02/26/21 22:11 321-60-8 Terphenyl-dl4 (8) 98 °% 11-131 1 02/26/21 07:54 02/26/21 22:11 1718-51-0 Phenol-d6 (S) 29 % 10-120 1 02/26/21 07:54 02126/21 22:11 13127-88-3 2-Fluorophenoi (S) 34 °% 10-120 1 02/26/21 07:54 02/26121 22:11 367-12-4 2,4,6-Tribromophenol (S) 54 °% 10-137 1 02/26/21 07:54 02/26/21 22:11 118-79-6 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Acrolein ND ug/L 5.0 1 02/24/2120:41 107-02-8 Acrylonitrile ND ug/L 5.0 1 02/24/2120:41 107-13-1 Benzene ND ug/L 1.0 1 02/24/2120:41 71-43-2 Bromodichloromethane ND ug/L 2.0 1 02/24/2120:41 75-27-4 Bromoform ND ug/L 2.0 1 02124/2120:41 75-25-2 Bromomethane ND ug/L 2.0 1 02/24/2120:41 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 02/24/2120:41 56-23-5 Chlorobenzene ND ug/L 2.0 1 02124/2120:41 108-90-7 Chloroethane ND ug/L 2.0 1 02/24/2120:41 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 02/24/2120:41 110-75-8 Chloroform ND ug/L 2.0 1 02/24/2120:41 67-66-3 Chloromethane ND ug/L 2.0 1 02/2412120:41 74-87-3 Dibromochloromethane ND ug/L 2.0 1 O2/24/2120:41 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:41 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:41 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 02/24/2120:41 108-46-7 1,1-Dichlorcethane ND ug/L 2.0 1 02/2412120:41 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 02/24/2120:41 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 02/24/2120:41 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 02/2412120:41 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 02/24/2120:41 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 02/2412120:41 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 02/24/2120:41 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 02/24/2120:41 10061-02-6 Ethylbenzene ND ug/L 1.0 1 02/24/2120:41 100-41-4 Methylene Chloride ND ug/L 2.0 1 02/24/2120:41 75-09-2 1,1,2,2-Tetrachloroethane NO ug/L 2.0 1 02/24/2120:41 79-34-5 Tetrachloroethene NO ug/L 2.0 1 02/24/2120:41 127-18-4 Toluene NO ug/L 1.0 1 02/24/2120:41 108-88-3 1,1,1-Tdchloroethane ND ug/L 2.0 1 02/24/2120:41 71-55-6 1,1,2-Tdchloroethane NO ug/L 2.0 1 02/24M 20:41 79-00-5 Trichloroethene NO ug/L 2.0 1 02/24/2120:41 79-01-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 23 Ieft6K�7 tnew.�alsiaeora ANALYTICAL RESULTS Project: Peerless Stormwater Pace Project No.: 92523505 Pace Analytical Services, LLC 2225 Riverside Or. Asheville, NC 28804 (828)254-7176 Sample: OUTFALL #2 Lab ID: 92523505002 Collected: 02/22/21 11:20 Received: 02/23/21 12:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Acrolein Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte Trichlorofluoromethane ND ug/L 2.0 1 02/24/2120:41 75-69-4 Vinyl chloride ND ug/L 2.0 1 02/24/21 20:41 75-01-4 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 02/24/21 20:41 460-00-4 Toluene-d8 (S) 97 % 70-130 1 02/24/21 20:41 2037-26-5 1,2-Dichloroethane-d4 (S) 90 % 70-130 1 02/24/21 20:41 17060-07-0 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Asheville Total Suspended Solids 32.6 mg/L 5.0 1 02/25/21 19:27 REPORT OF LABORATORY ANALYSIS This report shatl not be reproduced, except in full. Date: 03103/2021 03;40 PM without the written consent of Pace Analytical Services, I.L.C. Page 9 of 23 (�2ceAnayicale trine,�altttgeoto QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 QC Batch: 603708 Analysis Method: EPA 1664B QC Batch Method: EPA 1664E Analysis Description: 1664 SGT HEM, TPH Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3180620 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L NO 5.0 03/03/21 09:34 Pace Analytical Services, LLC 2226 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 3180621 Spike LCS LCS % Rae Parameter Units Cone. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg1L 20 17.3 86 64-132 MATRIX SPIKE SAMPLE: 3180622 35613802002 Spike MS MS % Rec Parameter Units Result Cone. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 5.OU 20 ND 4 64-132 M1 Results presented on this page are In the units Indicated by the "Units" coluum except where an alternate unit Is presented to the right of the resuh. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03103/2021 03:40 PM without the written consent of Pace Analytical Services, I.I.C. Page 10 of 23 aceA�alytical' tatrKfWdttttcaa Project: Peerless Stormwater Pace Project No.: 92523505 QC Batch: 602773 QC Batch Method: EPA 200.7 Rev 4.4 1994 Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3176232 Associated Lab Samples: 92523505001, 92523605002 Parameter Units Copper ug/L Lead ug/L Zinc ug/L QUALITY CONTROL DATA Analysis Method: EPA 200.7 Rev 4.41994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services - Asheville Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 5.0 0212812119:06 NO 5.0 02128/2119:06 ND 10.0 02/28/2119:06 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 LABORATORY CONTROL SAMPLE: 3176233 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Copper ug/L 500 522 104 85-115 Lead ug/L 500 500 100 85-115 Zinc ug/L Soo 497 99 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3176234 3176235 MS MSD 92523050001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper ug/L 14.8 500 500 539 532 105 104 70-130 1 Lead ug/L ND 500 500 492 491 98 98 70-130 0 Zinc ug/L 0.049 500 500 555 553 101 101 70-130 0 mg/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3176236 3176237 MS MSD 92523693001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua[ Copper ug/L 607 500 500 1140 1120 107 103 70-130 2 Lead ug/L ND 500 500 506 500 101 100 70-130 1 Zinc ug/L 27.1 500 500 531 526 101 100 70-130 1 Results presented on this page are In the units Indlcated by the "Units" column except where an alternate urtlt is presented to the right of the resutt. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 26)eAnaVical* (� tetrrLpaatrb>I.eant Project: Peerless Stormwater Pace Project No.: 92523505 QC Batch: 602248 QC Batch Method: EPA 624.1 Associated Lab Samples: 92523505001, 92523505002 QUALITY CONTROL DATA Analysis Method: EPA 624.1 Analysis Description: 624 MSV with Acrolein Laboratory: Pace Analytical Services - Charlotte METHOD BLANK: 3173190 Associated Lab Samples: 92523505001, 92523505002 Parameter Units Matra: Water Blank Reporting Result Limit Analyzed 1,1,1-Trichloroethane ug/L ND 2.0 02/24/2110:36 1,1,2,2-Tetrachloroethane ug/L ND 2.0 02/24/2110:36 1,1,2-Trichloroethane ug1L ND 2.0 02/24/2110:36 1,1-Dichloroethane ug/L ND 2.0 02/2412110:36 1,1-Dichloroethene ug/L ND 2.0 02124/2110:36 1,2-Dichlorobenzene ug/L ND 2.0 02/24/2110:36 1,2-Dichloroethane ug/L ND 2.0 02/2412l10:36 1,2-Dichloropropane ug/L ND 2.0 02/2412110:36 1,3-Dichlorobenzene ug/L ND 2.0 02/2412110:36 1,4-Dichlorobenzene ug/L ND 2.0 02/2412110:36 2-Chloroethylvinyl ether ug/L ND 5.0 02/24/21 10:36 Acrolein ug/L ND 5.0 02/24/2110:36 Acrylonitrile ug/L ND 5.0 02/2412110:36 Benzene ug/L ND 1.0 02/24/2110:36 Bromodichloromethane ug/L ND 2.0 02/24/2110:36 Bromoform ug/L ND 2.0 02/2412110:36 Bromomethane ug/L ND 2.0 02/24/2110:36 Carbon tetrachloride ug/L ND 2.0 02/24/2110:36 Chlorobenzene ug/L ND 2.0 02/24/2110:36 Chloroethane ug/L NO 2.0 02/24/2110:36 Chloroform ug/L ND 2.0 02/24/2110:36 Chioromethane ug/L ND 2..0 02/24/2110:36 cis-1,2-Dichloroethene ug/L ND 2.0 02/24/2110:36 cis-1,3-Dichloropropene ug/L ND 2.0 02/24/2110:36 Dibromochloromethane ug/L ND 2.0 02/24/2110:36 Ethylbenzene ug/L ND 1.0 02/24/2110:36 Methylene Chloride ug/L NO 2.0 02/24/2110:36 Tetrachloroethene ug1L NO 2.0 02124/2110:36 Toluene ug/L ND 1.0 02124/2110:36 trans-1,2-Dichloroethene ug/L ND 2.0 02/24/2110:36 trans-1,3-Dichloropropene ug/L ND 2.0 02/24/2110:36 Trichloroethene ug/L ND 2.0 02124/2110:36 Trichlorofluoromethane ug/L ND 2.0 02124/2110:36 Vinyl chloride ug/L ND 2.0 02/24/21 10:36 1,2-Dichloroethane-d4 (S) % 91 70-130 02/24/21 10:36 4-Bromofluorobenzene (S) % 98 70-130 02/24/21 10:36 Toluene-d8 (S) % 98 70-130 02/24/21 10:36 Qualifiers Pace Analytical Services, LLC 2226 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the resutL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 lceAn*ical" trttthhpt�elsee.h:oat QUALITY CONTROL DATA Project: Peerless Stormwater Pate Project No.: 92523505 LABORATORY CONTROL SAMPLE: Parameter 3173191 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1-Trichloroethane ug/L 20 18.3 92 70-130 1,1,2,2-Tetrachloroethane ug/L 20 20.6 103 70-130 1,1,2-Trichloroethane ug/L 20 20.2 101 70-130 1,1-Dichloroethane ug/L 20 18.9 94 70-130 1,1-Dichloroethene ug/L 20 19.9 100 70-132 1,2-Dichiorobenzene ug/L 20 22.9 115 70-130 1,2-Dichloroethane ug/L 20 16.8 84 70-130 1,2-Dichloropropane ug/L 20 19.9 99 70-130 1,3-Dichlorobenzene ug/L 20 22.0 110 70-130 1,4-Dichlorobenzene ug/L 20 23.1 115 70-130 2-Chloroethylvinyl ether ug/L 40 30.3 76 67-130 Acrolein ug/L 100 103 103 60-140 Acrylonitrile ug/L 100 98.1 98 70-130 Benzene ug/L 20 19.5 98 70-130 Bromodichloromethane ug/L 20 17.4 87 70-130 Bromoform ug/L 20 18.7 94 70-130 Bromomethane ug/L 20 26.1 130 30-177 Carbon tetrachloride ug/L 20 18.4 92 70-130 Chlorobenzene ug/L 20 20.8 104 70-130 Chioroethane ug/L 20 23.8 119 46-131 Chloroform ug/L 20 18.3 91 70-130 Chlotomethane ug/L 20 17.9 89 49-130 cis-1,2-Dichloroethene ug/L 20 18.8 94 70-130 cis-1,3-Dichloropropene ug/L 20 20.4 102 70-130 Dibromochloromethane ug/L 20 19.5 98 70-130 Ethylbenzene ug/L 20 20.4 102 70-130 Methylene Chloride ug/L 20 18.3 92 68-130 Tetrachloroethene ug/L 20 19.8 99 70-130 Toluene ug/L 20 19.5 97 70-130 trans-1,2-Dichloroethene ug/L 20 19.7 98 70-130 trans-1,3-Dichloropropene ug/L 20 19.2 96 70-130 Trichioroethene ug/L 20 19.8 99 70-130 Trichlorofluoromethane ug/L 20 20.4 102 61-130 Vinyl chloride ug/L 20 17.6 88 59-142 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 96 70-130 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 3173192 3173193 MS MSD 92523505001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1-Tdchioroethane ug/L ND 20 20 20.7 20.4 104 102 70-148 2 1,1,2,2-Tetrachloroethane ug/L ND 20 20 18.2 18.9 91 94 70-131 4 1,1,2-Tdchloroethane ug/L ND 20 20 20.6 19.6 103 98 70-136 5 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/0312021 03:40 PM without the written consent of Pace Analytical Services, I.L.C. Page 13 of 23 Ie�ttdfJJa cal tnnr,lieclak cats QUALITY CONTROL DATA Project: Peerless Stormwater Pate Project No.: 92523505 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3173192 3173193 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Parameter 92523505001 Units Result MS Spike Conc. MSD Spike Conc. MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD 1,1-Dichloroethane ug/L ND 20 20 20.4 19.2 102 96 71-143 6 1,1-Dichloroethane ug/L ND 20 20 22.0 21.1 110 105 70-158 4 1,2-Dichlorobenzene ug/L ND 20 20 20.7 20.3 104 101 70-133 2 1,2-Dichloroethane ug/L ND 20 20 18.4 17.5 92 88 72-137 5 1,2-Dichloropropane ug/L ND 20 20 20.4 19.9 102 99 70-138 3 1,3-Dichlorobenzene ug/L ND 20 20 20.6 20.0 103 100 75-133 3 1,4-Dichlorobenzene ug/L ND 20 20 20.8 20.1 104 100 70-133 4 2-Chloroethyivinyl ether ug/L ND 40 40 36.6 39.2 92 98 10-200 7 Acrolein ug/L ND 100 100 91.3 89.4 91 89 50-150 2 Acrylonitrile ug/L ND 100 100 89.6 89.8 90 90 68-140 0 Benzene ug/L ND 20 20 20.3 19.0 102 95 75-125 7 Bromodichioromethane ug/L ND 20 20 19.0 18.8 95 94 70-138 1 Bromoform ug/L ND 20 20 20.4 21.2 102 106 57-138 4 Bromomethane ug/L ND 20 20 15.0 14.6 75 73 10-200 3 Carbon tetrachloride ug/L ND 20 20 21.7 21.7 108 108 70-125 0 Chlorobenzene ug/L ND 20 20 20.5 21.2 102 106 82-137 4 Chloroethane ug/L ND 20 20 17.4 15.6 87 78 51-166 11 Chloroform ug/L ND 20 20 19.3 19.1 97 95 70-121 1 Chloromethane ug/L ND 20 20 10.6 17.7 53 89 24-161 51 R1 cis-1,2-Dichloroethene ug/L ND 20 20 19.4 18.3 97 91 67-148 6 cis-1,3-Dichloropropene ug/L ND 20 20 19.8 20.1 99 100 70-142 1 Dibromochloromethane ug/L ND 20 20 21.4 21.5 107 107 69-133 1 Ethylbenzene ug/L ND 20 20 20.7 20.8 104 104 75-134 0 Methylene Chloride ug/L ND 20 20 18.8 17.7 94 88 64-148 6 Tetrachicroethene ug/L ND 20 20 23.4 23.7 117 118 70-133 1 Toluene ug/L ND 20 20 20.4 19.8 102 99 75-134 3 trans-1,2-Dichloroethene ug/L ND 20 20 20.5 19.6 103 98 70-143 4 trans-1,3-Dichloropropene ug/L ND 20 20 20.3 19.0 102 95 70-138 7 Trichloroethene ug/L ND 20 20 21.9 21.7 110 108 75-138 1 Trichlorotluoromethane ug/L ND 20 20 18.9 19.9 95 100 61-154 5 Vinyl chloride ugJL ND 20 20 18.9 18.5 94 92 55-172 2 1,2-Dichloroethane-d4 (S) % 93 98 70-130 4-Bromofluorobenzene (S) % 91 97 70-130 Toluene-d8 (S) % 96 97 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. Qual REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, I.I.C. Page 14 of 23 1C8h*AM/" tnnrpacdmh= QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 QC Batch: 602808 Analysis Method: EPA 625.1 QC Batch Method: EPA 625.1 Analysis Description: 625 MSS Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3176312 Matrix: Water Associated Lab Samples: 92623505001, 92523505002 Parameter Units Blank Result Reporting Limit Analyzed 1,2,4-Tdchlorobenzene ug/L ND 5.0 02126/2111:10 1,2-Diphenylhydrazine ug/L NO 5.0 02/26/2111:10 2,4,6-Tdchlorophenol ug/L ND 10.0 02/2612111:10 2,4-Dichlorophenol ug/L ND 5.0 02126/2111:10 2,4-Dimethyiphenol ug/L ND 10.0 02/26/21 11:10 2,4-Dinitrophenol ug/L ND 50.0 02/2612111:10 2,4-Dinitrotoluene ug/L NO 5.0 02/26/21 11:10 2,60nitrotoluene ug/L ND 5.0 02/26/21 11:10 2-Chioronaphthalene ug/L ND 5.0 02/26/21 11:10 2-Chlorophenol uglL ND 5.0 02126/2111:10 2-Nitrophenol ug/L ND 5.0 02/2612111:10 3,3'-Dichlorobenzidine ug/L NO 10.0 02126/2111:10 4,6-Dlnitro-2-methylphenol ug/L ND 10.0 02/26/21 11:10 4-Bromophenylphenyl ether ug/L NO 5.0 02/26/21 11:10 4-Chloro-3-methylphenol ug/L ND 5.0 02/26/21 11:10 4-Chlorophenylphenyl ether ug/L ND 5.0 02/26/21 11:10 4-Nitrophenol ug/L ND 10.0 02/2612111:10 Acenaphthene ug/L ND 5.0 02/2612111:10 Acenaphthylene ug/L ND 5.0 02/26/21 11:10 Anthracene ug/L ND 5.0 02/26/21 11:10 Benzidine ug/L ND 50.0 02126/2111:10 Benzo(a)anthracene ug/L ND 5.0 02/26/21 11:10 Benzo(a)pyrene ug/L ND 5.0 02/26/21 11:10 Benzo(b)fluoranthene ug/L ND 5.0 02/26/21 11:10 Benzo(g,h,i)perylene ug/L ND 5.0 02126/2111:10 Benzo(k)tluoranthene ug/L ND 5.0 02/26/21 11:10 bis(2-Chloroethoxy)methane ug/L ND 10.0 02/26/21 11:10 bis(2-Chloroethyl) ether ug/L ND 5.0 02/26/21 11:10 bis(2-Ethylhexyl)phthalate ug/L ND 5.0 02/26/21 11:10 Butylbenzylphthalate ug/L ND 5.0 02/26/21 11:10 Chrysene ug/L ND 5.0 02/26/21 11:10 Di-n-butylphthalate ug/L ND 5.0 02/26/21 11:10 Di-n-octylphthalate ug/L ND 5.0 02/26/21 11:10 Dibenz(a,h)anthracene ug/L ND 5.0 02/26/21 11:10 Dlethylphthalate ug/L ND 5.0 02/26/21 11:10 Dimethylphthalate ug/L ND 5.0 02/26/21 11:10 Fluoranthene ug/L NO 5.0 02/26/21 11:10 Fluorene ug/L ND 5.0 02/26/21 11:10 Hexachloro-1,3-butadiene ug/L ND 5.0 02/26/21 11:10 Hexachlorobenzene ug/L ND 5.0 02/26/21 11:10 To Qualifiers Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Results presented on this page are In the units Indicated by the'UnIW column except where an alternate unit Is presented to the right of the resun. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 0310312021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 IC2225Q A,�_�j�m eilmlyt Project: Peerless Stormwater Pace Project No.: 92523505 QUALITY CONTROL DATA Pace Analytical Services, LLC Riverside Dr. Asheville, NC 28804 (828)254-7176 METHOD BLANK 3176312 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter units Result Limit Analyzed Qualifiers Hexachlorocyclopentadiene ug/L ND 10.0 02/26/2111:10 Hexachloroethane ug/L ND 5.0 02/26/2111:10 Indeno(1,2,3-cd)pyrene ug/L NO 5.0 02/2612111:10 Isophorone ug/L ND 10.0 02/26/2111:10 N-Nitroso-di-n-propylamine ug/L NO 5.0 02/26/2111:10 N-Nitrosodimethylamine ug/L ND 5.0 02/2612111:10 N-Nitrosodiphenylamine ug/L ND 10.0 02/26/2111:10 Naphthalene ug/L ND 5.0 02/26/2111:10 Nitrobenzene ug/L ND 5.0 02/26/2111:10 Pentachlorophenol ug/L ND 10.0 02/2612111:10 Phenanthrene ug/L ND 5.0 02/26/2111:10 Phenol ug/L ND 5.0 02/2612111:10 Pyrene ug/L ND 5.0 02126/2111:10 2,4,6-Tdbromophenol (S) % 95 10-137 02/26/2111:10 2-Fluorobiphenyl (S) % 77 15-120 02/26/21 11:10 2-Fluorophenoi (S) % 61 10-120 02/26/21 11:10 Nitrobenzene-d5 (S) % 94 10-120 02/26/21 11.10 Phenol-d6 (S) e% 46 10-120 02126/21 11:10 Terphenyl-d14 (S) % 138 11-131 02/26/2111:10 S3 LABORATORY CONTROL SAMPLE: 3176313 Spike LCS LCS °% Rec Parameter units Conc. Result % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/L 50 30.9 62 44-142 1,2-Diphenylhydrazine ug/L 50 49.9 100 25-150 2,4,6-Trichlorophenol ug1L 50 52.1 104 37-144 2,4-Dichiorophenol ug/L 50 49.8 100 1-191 2,4-Dimethyiphenol ug/L 50 51.9 104 32-119 2,4-Dinitrophenoi ug/L 250 320 128 1-181 2,4-Dinitrotoluene ug/L 50 46.1 92 39-139 2,6-Dinitrotoluene ug/L 50 60.3 121 50-158 2-Chloronaphthalene ug/L 50 35A 71 60-118 2-Chlorophenol ug/L 50 47.7 95 23-134 2-Nitrophenol ug/L 50 57.4 115 29-182 3,T-Dichlorobenzidine ug/L 100 115 115 1-262 4,6-Dinitro-2-methylphenol ug/L 100 138 138 1-181 4-Bromophenylphenyl ether ug/L 50 50.4 101 53-127 4-Chloro-3-methylphenol ug/L 100 103 103 22-147 4-Chlorophenylphenyl ether ug/L 50 42.2 84 25-158 4-Nitrophenol ug/L 250 151 60 1-132 Acenaphthene ug/L 50 39.5 79 47-145 Acenaphthylene ug/L 50 42.9 86 33-145 Anthracene ug/L 50 55.3 111 1-166 Benzidine ug/L 100 ND 11 10-1301L Results presented on this page are In the units Indicated by the "Unas" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/0312021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 23 CeArra cal wxpttcdibs t om QUALITY CONTROL DATA Project: Peerless Stormwater Pace Project No.: 92523505 LABORATORY CONTROL SAMPLE: Parameter 3176313 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Benzo(a)anthracene ug/L 50 59.2 118 33-143 Benzo(a)pyrene ug/L 50 60.2 120 17-163 Benzo(b)fluoranthene ug/L 50 59.9 120 24-159 Benzo(g,h,i)perylene ug/L 50 57.7 115 1-219 Benzo(k)ffuoranthene ug/L 50 57.9 116 11-162 bis(2-Chloroethoxy)rrtethane ug/L 50 50.6 101 33-184 bis(2-Chloroethyl) ether ug/L 50 53.0 106 12-158 bis(2-Ethylhexyl)phthalate ug/L 50 65.1 130 8-158 Butylbenzylphthalate ug/L 50 64.8 130 1-152 Chrysene ug/L 50 56.5 113 17-168 Di-n-butylphthalate ug/L 50 58.2 116 1-118 Di-n-octylphthalate ug/L 50 71.0 142 4-146 Dibenz(a,h)anthracene ug/L 50 59.6 119 1-227 Diethylphthalate ug/L 50 52.6 105 1-114 Dimethylphthalate ug/L 50 50.8 102 1-112 Fluoranthene ug/L 50 56.7 113 26-137 Fluorene ug/L 50 46.1 92 59-121 Hexachloro-1,3-butadiene ug/L 50 27.7 55 24-116 Hexachlorobenzene ug/L 50 48.4 97 1-152 Hexachlorocyclopentadlene ug/L 50 28.3 57 25-150 Hexachloroethane ug/L 50 31.2 62 40-113 Indeno(1,2,3-cd)pyrene ug/L 50 60.2 120 1-171 Isophorone ug/L 50 52.1 104 21-196 N-Ndroso-di-n-propylamine ug/L 50 53.9 108 1-230 N-Nitrosodimethylamine ug/L 50 39.9 80 25-150 N-Nitrosodiphenylamine ug/L 50 51.3 103 25-150 Naphthalene ug/L 50 36.8 74 21-133 Nitrobenzene ug/L 50 51.9 104 35-180 Pentachlorophencl ug/L 100 113 113 14-176 Phenanthrene ugiL 50 52.8 106 54-120 Phenol ug/L 50 30.2 60 5-112 Pyrene ug/L 50 55.7 111 52-115 2,4,6-Tribromophenol (S) % 109 10-137 2-Fluorobiphenyl (S) % 81 15-120 2-Fluorophenol (S) % 65 10-120 Nitrobenzene-d5 (S) % 100 10-120 Phenol-d6 (S) % 48 10-120 Terphenyl-d14 (S) % 119 11-131 Pace Ana"cai Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Qualifiers Results presented on this page are In the units Indicated by the "units" column except whore an alternate unit Is presented to the right of the reaut. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/0312021 03:40 PM without the written consent of Pace Analytical Services, I.I.C. Page 17 of 23 aceAffi cal wacpsedatasan QUALITY CONTROL DATA Project: Peerless Stormwater Paoe Project No.: 92523505 QC Batch: 602714 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92523505001, 92523505002 METHOD BLANK: 3176982 Matrix: Water Associated Lab Samples: 92523505001, 92523505002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 02125/21 19:22 Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)264-7176 LABORATORY CONTROL SAMPLE: 3175983 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 240 96 90-110 SAMPLE DUPLICATE: 3176179 92523421004 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 1530 1400 8 SAMPLE DUPLICATE: 3176180 92524022001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 5900 6000 2 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/03/2021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 Pace Analytical Services, LLC acetlytical m 2225 Riverside Dr. Asheville, NC 28804 trMI pcdtbsum (828)254-7176 QUALIFIERS Project: Peerless Stormwater Pace Project No.: 92523505 DEFINITIONS DF - Dilution Factor, If reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 Is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample. REPORT OF LABORATORY ANALYSIS This report shall not to reproduced, except in full, Date: 03/0312021 03:40 PM without the written consent of Pace Analytical Services, I.I.C. Page 19 of 23 IeAnaliftal'o (� 1a9nrpaatths.eam QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: Peerless Stormwater Pace Project No.: 92523505 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92523506001 OUTFALL #1 EPA 1664E 603708 92623606002 OUTFALL #2 EPA1664B 603708 92523506001 OUTFALL #1 EPA 200.7 Rev 4.41994 602773 EPA 200.7 Rev 4.41994 602805 92623606002 OUTFALL #2 EPA 200.7 Rev 4.41994 602773 EPA 200.7 Rev 4.41994 602805 92523505001 OUTFALL #1 EPA 625.1 602808 EPA 625.1 602884 92623506002 OUTFALL #2 EPA 625.1 602808 EPA 625.1 602884 92623505001 OUTFALL #1 EPA 624.1 602248 92623605002 OUTFALL #2 EPA 624.1 602248 92623505001 OUTFALL #1 SM 254OD-2011 602714 92523505002 OUTFALL #2 SM 264OD-2011 602714 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/0312021 03:40 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 23 0/1napical" Document Name: Sample Condition Upon Recelpt(SCUR) Document Revised: October 28, 2020 Page 1 of 2 Document No.: F-CAR-CS-033-Rev.07 Issuing Authority: Pace Carolinas Quality Office Laboratory rec.Oving samples: Asheville g Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] Atlanta[:] Kernersville❑ Client Name: 1 # ; 925235a5 ��� Project A w �� � C�c��osf �i�:..,�� 1- l tt11 Courier: ❑Fed Ex eaps ❑USPS ❑Client ❑ Commercial ❑Pace ❑Other 92623505 Custody Seal Present? ❑Yes �No Seals intact? ❑Yes 290 ,//'�� I ' Due/Initials Person Examining Contents; 0_1 ), Packing Material: ❑Bubble wrap �ubble Bags []None ❑ Other Thermometer IR Gun In: �� Wet ❑81ue Type of Ice; Correction Factor: Cooler Temp: Add/Subtract (T) CI) Cooler Temp Corrected V9 USDA Regulated Soil ( (El'Nl/A, water sample) Did samples origina in a quarantine zone within the United States: CA, NY, or SC (check maps)? n— ' Biological Tissue F ozen? []Yes ❑No �N/A []Non[! Temp should be above freezing to 6°C ❑Samples out of temp criteria. Samples on ice, cooling process has begun Old sa%!es originate from a foreign source (interne ' nally, includineHawail and Puerto Rico)? ❑Yes o Cam ments/Discrepa ncy: Chain of Custody Present? Res No ❑N/A 1. Samples Arrived within Hold Time? es ❑N ❑N/A 2. Short Hold Time Analysis <72 hr.)? Dyes N14. ❑N/A 3. Rush Turn Around Tlme Requested? Dyes No NIA 4. Sufficient Volume? (q�e3j No ❑NIA 5. Correct Containers Used? ❑Na ❑NIA 6. -Pace Containers Used? [:]No N/A Containers Intact? /es Oyes ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No /A 8. Sample Labels Match COC? Y []Noes No ❑NIA 9. ! LA, -includes Date/Time/ID/Analysis Matrlx: Heads ace in VOA Vials (>5.6mm)? ON '7 10. Trip Blank Present? !0yes No f4/�A Trip Blank Custod Seals Present? No COMMENTS/SAMPLE DISCREPANCY Lot ID ofspiit containers: CLIENT NOTIFICATION/RESOLUTION Field Data Required? (]Yes []NO Person contacted: Datefime: Project Manager SCURF Review: Date: z Project Manager SRF Review: Date: Page 21 of 23 o ;ZeAnaW,W Document Name: Sample Condition Upon Recel SCUR Docwrtent Revised: October 28, 2020 Page 2 of 2 Document No.: FCAR-CS-033-Rev.07 Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorinatlon is verified and within the acceptance range for preservation samples. Excepttors: VOA, Coliform, TOC, Oil and Grease, ORO/9015 (water) DOC, LLHg "Bottom half of box Is to list number of bottles 11 Projectg WV# * 92523505 PH: top Due Date: 03/05/21 CLIENT: 93-PEERLESS Q 4 U O d wa A mcq 9 A v +yr a b v V do 6r Z ~ 'i 2 a bp1 .� n C�J a m` vp r' s �" i e 0 C m j >> E E E E E E E v 0 5`r E E E E y E o E o 0 0 m m o m PH Adjustment Log for Preserved Samples Sample ID type of Preservative pH upon receipt Date preservation adjusted Time presemtion adjusted Amount of Preservative added tot S .r.... r�.....an .....�... a., u....w r•—pna AFHNR [arttrtcatlGfl Office (i.e. Note: whenever there is a aucrepancy arrecang muru, tar uu..o..,��.�r ��•, � �a..r.- - _....._ ._...- ---_ -- �----- Out of hold, incorrect preservative, out of temp, incorrect containers. Page 22 of 23 .A logo M PY mmmmmmmmmmmm mmmmmmmmmmmm mmmmmmmmmmmm mmmmmmmm M. mmmm MOMMOMMOMMOM MWOMMOMMOMME mmmmmmmmmmmm mmmmmmmmmmmm MEN E MRSIEF:; go Page 23 of 23