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HomeMy WebLinkAboutNCG030145_DMR_20210603Semi-annual Stormwater Discharge Monitoring Report for North Carolina Division of Water Z77,z neral Permit No. NCG030000 Date submitted CERTIFICATE OF COVERAGENO. NCG030145 SAMPLE COLLECTION YEAR: 2021 FACILITY NAME: Newton Instruments i ,t �CSMPLE PERIOD ❑ Jan -June ❑ July -Dec COUNTY: Granville ,;�ECE V or ®Monthly' May 2021 PERSON COLLECTING SAMPLES: Geoffrey Murphrey DISCHARGING TO CLASS ❑ORW ®HQW ❑Trout ❑PNA LABORATORY: : Pace Analytical Lab Cert. ##: 40 jum 14 NZ ❑Zero -flow ❑Water Supply ❑SA Comments on sample collection or analysis: Monthly samplifflq7RAL FILES ❑Other JWR SECTION PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 34 Part A: Stormwater Benchmarks and Monitoring Results ❑ No discharge this period?' pH' Non -Polar Outfall No. Date Sample 24-hour rainfall Total Suspended Standard Copper Lead Zinc O&G/ Total Total Toxic Collected' amount, Solids Petroleum Organics' (mo/dd/yr) Inches' units Hydrocarbons Benchmarks - - 100 mg/L 6.0 — 9.0 0.007 mg/L 0.03 mg/L 0.067 mg/L 15 mg/L 1 mg/L 001 05/12/21 0.2 15.2 mg/L 7.2 0.0056 mg/L <0.005 mg/L 0.0171 rrg/L 8.4 mg/L Not Detected ' Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. 2For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here. 3The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. a See General Permit, Table 3 identifying the especially sensitive receiving water classifications where the more protective benchmark applies. 5Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11; for semiconductor manufacture use the definition as found in 40 CFR 469.12; for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray tube manufacture use the definition found in 40 CFR 469.31). Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO monitoring may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement: "Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics (TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or Permit Date: 11/1/2017-10/31/2022 SWU-245, last revised 10/25/2012 Page 1 of 3 stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the solvent management plan included in the Stormwater Pollution Prevention Plan." Name (Print name) Title (Print title) (Signature) (Date) Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or others imi I a r non -numerical format. When results are below the applicable limits, they must be reported in the format, "<XX mg/L', where XX is the numerical value of the detection limit, reporting limit, etc. in mg/L. Note: if you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text. Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging> 55 gal of new oil per month. ❑ No discharge this period?' Outfall No. Date Sample Collected' (mo/dd/yr) 24-hour rainfall amount, Inches3 Non -polar O&G/TPH by EPA 1664 (SGT-HEM) Total Suspended Solids pH Benchmarks =__> - 15 mg/L 100 mg/L or 50 mg/L* 6.0 — 9.0 SU Footnotes from Part A also apply to this Part B * See General Permit text, Table 5, identifying the especially sensitive receiving water classifications where the more protective benchmark applies. Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text. Permit Date: 11/1/2017-10/31/2022 SWU-245, last revised 10/25/2012 Page 2 of 3 FOR PART A AND PART B MONITORING RESULTS: A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL?YES ® No ❑ IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE?YES ® NO ❑ REGIONAL OFFICE CONTACT" NAME: John Holley Mail an original and one copy of this DMR, including all "No Discharge" reportsLwithin 30 days of receipt of the lab results for at end of monitoring period in the case of "No Discharge" reports] to: Division of Water Quality Attn: DWQ Central Files 1517 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." (Signature o (Date) Permit Date: 11/1/2017-10/31/2022 SWU-245, last revised 10/25/2012 Page 3 of 3 ace Analytical www.pacelabs.com May 28, 2021 Mr. Pete Dressel Piedmont Geologic 6003 Chapel Hill Road Suite 109 Raleigh, NC 27607 RE: Project: Newton Instruments/ 2112 Pace Project No.: 92538713 Dear Mr. Dressel: Pace Analytical Services, LLC 9800 KinceyAve- Suite 100 Huntersville, NC 28078 (704 )875-90 92 Enciosed are the analytical results for sample(s) received by the laboratory on May 13, 2021. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNIINELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Eden Revision 1 - This report replaces the May 26, 2021 report This report was reissued on May 28, 2021 to update collectors name per client's request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Tyriek Hooks tyriek-hooks@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Jonathan Murphrey, Piedmont Geologic REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, L.L.C. Page 1 of 30 aceAnalytical www,pacelabs.com r E Project: Newton Instruments 12112 Pace Project No.: 92538713 Pace Analytical Services, LLG 9800 Kincey Ave. Suite 100 Huntersville, NC 26078 (704 )878-9092 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 Pace Analytical Services Eden 205 East Meadow Road Suite A, Eden, NC 27288 North Carolina Drinking Water Certification #: 37738 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia[VELAP Certification M 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiafVELAP Certification #: 460222 North Carolina Wastewater Certification #: 633 VirginiaNELAP Certification #: 460025 REPORT OF LABORATORY ANALYSIS This report shah not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 30 Pace Analytical Services, LLC 3 aceAnalytrcal 9844 untey Ave, Suite 144 Hurstersville, NC 26078 www.pacelabs.com (704)875-9092 SAMPLE SUMMARY Project: Newton Instruments 12112 Pace Project No.: 92538713 Lab ID Sample ID Matrix pate Collected pate Received 92538713001 Outfall-001 Water 0511212110:05 05/13/2115:18 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 30 _ ?ceAnalytical_' www.pacelabs.cam SAMPLE ANAL.YTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (704)875-9092 Project: Pace Project No.: Newton Instruments ! 2112 92538713 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92538713001 Outfall-001 SM 254OD-2011 LRB 1 PASI-E EPA 1664B TEG 1 PASI-C EPA 608.3 SEM 30 PASI-C EPA 200.7 Rev 4.4 1994 IDS 12 PASI-A EPA 245.1 Rev 3.0 1994 SOO 1 PASI-A EPA 625.1 PKS 62 PASI-C EPA624.1 SAS 31 PASI-C EPA420.4 Rev 1.0 1993 KDF1 1 PASI-A SM 4500-CN-E-2011 CJL 1 PASI-A PAS[ -A= Pace Analytical Services -Asheville PASI-C = Pace Analytical Services - Charlotte PASI-E = Pace Analytical Services - Eden REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 4 of 30 aceAnalytical srwr.pacelabs.cam ANALYTICAL RESULTS Project: Newton Instruments / 2112 Pace Project No.: 92538713 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Outfall-001 Lab ID: 92538713001 Collected: 05/12/21 10:05 Received: 05/13/21 15:18 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services - Eden Total Suspended Solids 15.2 mg/L 2.6 2.6 1 05/17121 09:08 Field Data Analytical Method: Pace Analytical Services - Charlotte Perforated by Piedmont 1 05/12/21 10:05 Geologic Collected By Geoffrey 1 05/12121 10:05 Murphrey Collected Date 06112/21 1 05/1221 10:05 Collected Time 10:05 1 0511221 10:05 pH 7.2 Std. Units 1 05/12/21 10:05 HEM, Oil and Grease Analytical Method: EPA 1664E Pace Analytical Services - Charlotte Oil and Grease 8.4 mg/L 4.9 1.1 1 05/2521 18:53 608 PCB Pest RVE Analytical Method: EPA608.3 Preparation Method: EPA608.3 Pace Analytical Services - Charlotte Aldrin ND ug/L 0.050 0.026 1 0&18/2106:25 05/212104:26 309-00-2 alpha-BHC ND ug/L 0.050 0.026 1 05/182106:25 05/212104:26 319-84-6 beta-BHC ND ug/L 0.050 0.022 1 05/182106:25 05/212104:26 319-85-7 delta-BHC ND ug/L 0.050 0,018 1 051182106:25 051212104:26 319-86-8 gamma-BHC (Lindane) ND ug/L 0.050 0.020 1 05/1821 06:25 05/2121 04:26 58-89-9 Chlordane (Technical) ND ug/L 0.50 0.21 1 0511M 106:25 05/2121 04:26 57-74-9 alpha -Chlordane ND ug/L 0.050 0.015 1 05/182106:25 051212104:26 5103-71-9 gamma -Chlordane ND ug/L 0.050 0.035 1 05/182106:25 051212104:26 5103-74-2 4.4'-DDD ND ug/L 0.050 0,012 1 05/182106:25 05/212104:26 72-54-8 4.4'-DOE ND ug/L 0.050 0.016 1 05/182106:25 05/212104:26 72-55-9 4.4'-DDT ND ug/L 0.050 0.048 1 05/182106:25 05/212104:26 50-29-3 Dieldrin ND ug/L 0.050 0.013 1 05/1821 06:25 0512121 04:26 60-57-1 Endosulfan I ND ug/L 0.050 0.014 1 05/1821 06:25 05/2121 04:26 959-98-8 Endosulfan 11 ND ug/L 0.050 0.017 1 05/1821 06:25 05121M 04:26 33213-65-9 Endosulfan sulfate ND ug/L 0.050 0.014 1 05/1821 06:25 0512121 04:26 1031-07-8 Endrin ND ug/L 0.050 0.014 1 05/1821 06:25 0512121 04:26 72-20-8 Endrin aldehyde ND ug/L 0.050 0.028 1 05/1821 06:25 05/2121 04:26 7421-93-4 Heptachlor ND ug/L 0.050 0.036 1 05/1821 06:25 0512121 04:26 76-44-8 Heptachlor epoxide ND ug/L 0.050 0.015 1 0&1821 06:25 0512121 04:26 1024-57-3 PCB-1016 (Aroclor 1016) ND ug/L 0.50 0.47 1 0511IM1 06:25 0512121 04:26 12674-11-2 PCB-1221 (Arodor 1221) ND ug/L 0.50 0.45 1 05/1821 06-.25 05/2121 04:26 11104-28-2 PCB-1232 (Arodor 1232) ND ug/L 0.50 0.36 1 05/1821 06:25 052121 04:26 11141-16-5 PCB-1242 (Arodor 1242) ND ug/L 0.50 0.26 1 05/1821 06:25 0512121 04:26 53469-21-9 PCB-1248 (Arodor 1248) NO ug/L 0.50 0.40 1 0511821 06:25 052121 04:26 12672-29-6 PCB-1254 (Arodor 1254) NO ug/L 0.50 0.25 1 05/1821 06:25 052121 04:26 11097-69-1 PCB-1260 (Arodor 1260) ND ug/L 0.50 0.42 1 0511821 06:25 0512121 04:26 11096-82-5 PCB, Total ND ug/L 0.50 0.50 1 05/1821 06:25 05/2121 04:26 1336-36-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/282021 10:52 AM without the written consent of Pace Analytical Services, LLC, Page 5 of 30 aceAnalytrcal www.pacolabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (7p4)875-9092 Project: Newton Instruments 12112 Pace Project No.. 92538713 Sample: Outfall-001 Lab ID: 92538713001 Collected: 05112/21 10:05 Received: 05/13/21 15:18 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Anaiyzed CAS No. Qual 608 PCB Pest RVE Analytical Method: EPA608.3 Preparation Method: EPA608.3 Pace Analytical Services - Charlotte Toxaphene ND ug/L 050 0.27 1 05/18/21 06:25 05/21/21 04:26 8001-35-2 Surrogates Tetrachloro-m-xylene (S) 113 % 10-154 1 05/18/21 06:25 05/21/21 04:26 877-09-8 Decachlorobiphenyl (S) 106 % 10-184 1 05/18/21 06:25 05/21/21 04:26 2051-24-3 200.7 MET ICP Analytical Method: EPA200 7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services - Asheville Antimony ND uglL 5.0 3.0 1 05/22/21 09:50 05/22/21 23:06 7440-36-0 Arsenic ND ug1L 10.0 4.7 1 05/22/21 09:50 05/22/21 23:06 7440-38-2 Beryllium Nil ug/L 1.0 0.70 1 0512212109:50 0512212123:06 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 0512212109:50 0512212123:06 7440-43-9 Chromium ND ug1L 5.0 3.7 1 05/22/21 09:50 05/22/21 23:06 744047-3 Copper 5.6 ug/L 5.0 4.3 1 05/22/21 09:50 05/22/21 2106 7440-50-8 Lead NO ug1L 5.0 4.5 1 05/22/21 09:50 05/22/21 23:06 7439-92-1 Nickel 3.5J ug/L 5.0 3.5 1 05/22/21 09:50 0512212123:06 7440-02-0 Selenium ND ug/L 10.0 4.7 1 05/22/21 09:50 0512212123:06 7782-49-2 Silver ND ug1L 5.0 2.5 1 05/2212109:50 05/22/21 23:06 7440-22-4 Thallium ND ug1L 10.0 8.1 1 0512212109:50 05/22/21 23:06 7440-28-0 Zinc 17-1 ug/L 10.0 9.5 1 05/22/21 09:50 05/22/21 23:06 7440-66-6 245.1 Mercury Analytical Method: EPA245 1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994 Pace Analytical Services -Asheville Mercury ND ug1L 0.20 0.12 t 05/24/2113:55 0512512113:01 7439-97-6 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA625.1 Pace Analytical Services - Charlotte Acenaphthene ND ug/L 5.0 2.0 1 05118/21 11:12 05119/2121:44 83-32-9 Acenaphthyiene ND ug/t_ 5.0 2.0 1 0511812111A2 0511912121:44 208-96-8 Anthracene ND ug1L 5.0 2 3 1 05/18/21 11:12 05/19/21 21:44 120-12-7 Benzidine ND ug1L 50.0 13.4 1 05/18/21 11:12 05/19/21 21:44 92-87-5 IL Benzo(a)anthracene ND ug1L 5.0 2.7 1 05/18/21 11:12 05/19/2121:44 56-55-3 Benzo(a)pyrene ND ug1L 5.0 2.8 1 05118/2111:12 05/19/2121:44 50-32-8 Benzo(b)fluoranthene ND ug1L 5.0 2.6 1 0511812111:12 05119/2121:44 205-99-2 Benzo(g.h,i)perylene ND ug1L 5.0 2.8 1 M1812111:12 0511912121:44 191-24-2 Benzo(k)fluoranthene ND ug1L 5.0 2.7 1 0511812111:12 05/19/2121:44 207-08-9 4-Bromophenylphenyl ether ND ug1L 5.0 1.8 1 05/18/21 11712 05/19/21 21:44 101-55-3 L1 Butyl benzylphtha late ND ugIL 5.0 3.1 1 M1812111:12 0511912121:44 85-68-7 L1 4-Chloro-3-methyl phenol ND ug1L 5.0 3.3 1 05/18/21 11:12 05119/2121:44 59-50-7 bis(2-Chloroethoxy)methane ND ug1L 10.0 1.8 1 0511812111:12 05119/2121:44 111-91.1 bis(2-Chloroethyl) ether ND ug/L 5.0 1.9 1 05/18/21 11:12 05/19/21 21:44 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1.7 1 05/18/21 11:12 05/19/21 21:44 91-58-7 2-Chlorophenol ND ug/L 5.0 1.2 1 05/18/21 11:12 05/19/21 21:44 95-57-8 4-Chlorophenylphenyl ether ND ug1L 5.0 2.0 1 05/18/21 11:12 05/19/21 21:44 7005-72-3 Chrysene ND ug1L 5.0 2.8 1 0511812111:12 0511912121:44 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 3.0 1 05/18/21 11:12 05/19/21 21:44 5370-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 30 1�;a'ceAnalytical www.pacelsbs.cam ANALYTICAL RESULTS Project: Newton Instruments / 2112 Pace Project No.: 92538713 Pace Analytical Services, LLC 9800 Kincey Ave_ Suite 100 Huntersviile. NC 28078 (704)875-9092 Sample: Outfall-001 Lab 1D: 92538713001 Collected: 05/12/21 10:05 Received: 05/13/21 15:18 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 625 RVE 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 3,3'-Dichlorobe nzidine 2,4-❑ichlorophenol Diethylphthalate 2,4-Dimethylphenol Dimethylphthalate Di-n-butylphthalate 4,6-Dinitro-2-methylptie nol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octylphth a late 1,2-Diphenylhydrazine bis(2-Ethylhexyl)phlhalate Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadiene Hexachloroethane Indeno(1,2,3-cd)pyrene Isophorone Naphthalene Nitrobenzene 2-Nitrophenol 4-Nitropheno! N-Nitrosodimethylamine N-Nitroso-di-n-propylamine N-Nitrosodiphenylamine Pentachlorophenol Phenanthrene Phenol Pyrene 1,2,4-Trichlorobenzene 2,4,6-Trichlorophenol Surrogates Nitrobenzene-d5 (S) 2-Fluorcbiphenyl(S) Terphenyl-d14 (S) Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) Analytical Method: FPA625.1 Preparation Method: EPA625.1 Pace Analytical Services - Charlotte ND ug/L 5.0 1.8 1 05/1812111:12 0511912121:44 95-50-1 ND ug/L 5.0 1.5 1 05118/2111:12 05/1912121:44 541-73-1 ND ug/L 5.0 1.7 1 0511812111:12 0511912121:44 106-46-7 ND ug1L 10.0 8.1 1 0511812111:12 05/19/21 21:44 91-94-1 ND ug/L 5.0 1.4 1 05/1812111:12 05/1912121:44 120-83-2 ND ug/L 5.0 2.0 1 05118/2111:12 0511912121:44 84-66-2 ND ug/L 10.0 1.7 1 05/1812111:12 0511912121:44 105-67-9 ND ug/L 5.0 2.1 1 05/18/21 11:12 0511912121:44 131-11-3 ND ug/L 5.0 2.2 1 05/18/21 11:12 05/19/21 21:44 84-74-2 ND ug/L 10.0 3.4 1 05/1812111:12 05/19/21 21:44 534-52-1 ND ug/L 50.0 25.0 1 05/18/21 11:12 05/19/21 21:44 51-28-5 ND ug1L 5.0 1.6 1 05/18/21 11:12 05/19/21 21:44 121-14-2 ND ug/L 5.0 1.7 1 05/18/21 11:12 05/19/21 21:44 606-20-2 ND ug/L 5.0 3.9 1 0511812111:12 05119/2121:44 117-84-0 ND ug/L 5.0 1.6 1 05/18/21 11:12 05/1912121:44 122-66-7 ND ug/L 5.0 3.7 1 05/18/21 11:12 05/19/21 21:44 117-81-7 ND ug/L 5.0 2.2 1 05/18/21 11:12 05/19/21 21:44 206-44-0 ND ug/L 5.0 2.1 1 05/18/21 11:12 0511912121:44 86-73-7 ND ug/L 5.0 1.8 1 05/113/21 11:12 05119/2121:44 87-68-3 ND ug/L 5.0 2.2 1 05/18/2111:12 0511912121:44 118-74-1 ND ug/L 10.0 1.6 1 05/18/21 11:12 05/19/21 21:44 77-47-4 ND ug/L 5.0 1.4 1 05/18/21 11:12 05/19/21 21:44 67-72-1 ND ug/L 5.0 2.9 1 05/18/21 11:12 05119/2121:44 193-39-5 ND ug/L 10.0 1.7 1 05/113/21 11:12 05119/2121:44 78-59-1 ND ug/L 5-0 2.1 1 05/18/21 11:12 05119/2121:44 91-20-3 ND ug/L 5.0 1.9 1 05/18/21 11:12 0511912121:44 98-95-3 ND ug/L 5.0 1.4 1 05/18/21 11:12 05/19/21 21:44 88-75-5 ND ug/L 10.0 6.6 1 05118/2111:12 05/19/2121:44 100-02-7 ND ug/L 5.0 1.9 1 05/18/21 11:12 05/19/21 21:44 62-75-9 ND ug/L 5.0 1.3 1 05/16/21 11:12 05/19/21 21:44 621-64-7 ND ug/L 10.0 3A 1 05/18/21 11:12 05/19/21 21:44 86-30-6 ND ug/L 10.0 3.8 1 05/18/21 11:12 05/19/21 21:44 87-86-5 ND ug/L 5.0 2.0 1 05/18/21 11:12 05/19/21 21:44 85-01-8 ND ug/L 5.0 1.4 1 05/1812111:12 05119/2121:44 108-95-2 ND ug/L 5.0 2.2 1 0511812111:12 05119/2121:44 129-00-0 ND ug/L 5.0 1.7 1 05/18/21 11:12 05/19/21 21:44 120-82-1 ND ug/L 10.0 1.6 1 05/18/21 11:12 05/19/21 21:44 88-06-2 103 % 10-120 1 05/18/21 11:12 05/19/21 21:44 4165-60-0 91 % 15-120 1 05118/2111:12 05/19/21 21:44 321-60-8 124 % 11-131 1 05/18/21 11:12 05/19/21 21:44 1718-51-0 58 % 10-120 1 05/1812111:12 0511912121:44 13127-88-3 70 % 10-120 1 05/18/21 11:12 05/19/21 21:44 367-12-4 119 % 10-137 1 05/1812111:12 05/19/21 21:44 118-79-6 REPORT OF LABORATORY ANALYSIS L1 L1 L1 L1 L1 L1 L1 L1 L1 L1 L1 This report shall not be reproduced, except in full, Date: 05128/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 30 aceAnalytical www.paculabs.com i i ANALYTICAL RESULTS Project: Newton Instruments 12112 Pace Project No.: 92538713 Pace Analytical Services, LLC 9800 Klncey Ave Suite 100 Huntersville, NC 28078 (704 )875-9092 Sample: Outfall-001 Lab ID: 92538713001 Collected: 05/12/21 10:05 Received: 05/13/21 15:18 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. (Dual 624 Volatile Organics Acrolein Acrolein Acrylonitrile Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethylvinyl ether Chloroform Chloromethane Dibromochiorometha ne 1,1-Dichloroethane 1,2-Dichloroethane trans- l,2-Dichloroethene 1.2-Dichloropropane cis-1,3-Dichloropro pene trans- l,3-Dichloropropene Ethylbenzene Methylene Chloride 1, 1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trlchloroethane 1,1,2-Tri ch loroetha ne Trichloroethene Vinyl chloride Surrogates 4-Bromoffuorobenzene (S) Toluene-d8 (S) 1,2-Dichloroethane-d4 (S) 420.4 Phenolics, Total Phenolics, Total Recoverable 450OCNE Cyanide, Total Cyanide Date: 05/28/2021 10:52 AM Analytical Method: EPA 624.1 Pace Analytical Services - Charlotte ND ug/L 5.0 3.6 1 05/14/21 14:59 107-02-8 ND ug/L 5.0 2.3 1 05/14/21 14:59 107-13-1 ND ug/L 1.0 0.42 1 05/14/21 14:59 71-43-2 ND ug/L 2.0 0.41 1 05/14/21 14:59 75-27-4 ND ug/L 2.0 0.59 1 05/14/21 14:59 75-25-2 ND ug/L 2.0 1.5 1 05/14/21 14:59 74-83-9 ND ug/L 2.0 0.47 1 05/14/21 14:59 56-23-5 ND ug/L 2.0 0.39 1 05/1412114:59 108-90-7 ND ug/L 2.0 0.71 1 05/14/21 14:59 75-00-3 ND ug/L 5.0 0.94 1 05/1412114;59 110-75-8 ND ug1L 2.0 0,49 1 05/14/21 14:59 67-66-3 ND ug/L 2.0 0.60 1 05/14/21 14:59 74-87-3 NO ug/L 2.0 0.39 1 D511412114:59 124-48-1 ND ug/L 2.0 0.47 1 05/14/21 14:59 75-34-3 ND ug/L 2.0 0.42 1 05/1412114:59 107-06-2 ND ug/L 2.0 0.48 1 05/14/21 14:59 156-60-5 ND ug/L 2.0 0.44 1 05114/2114:59 78-87-5 ND ug1L 2.0 0.35 1 05/14/21 14:59 10061-01-5 ND ug1L 2.0 0.34 1 05114/2114:59 10061-02-6 ND ug/L 1.0 0.35 1 05/14/21 14:59 100-41-4 ND ug/L 2.0 0.91 1 05/14/21 14:59 75-09-2 ND ug/t_ 2.0 0.30 1 05/14/21 14:59 79-34-5 ND ug1L 2.0 0.38 1 05/14/21 14:59 127-18-4 ND uglL 1.0 041 1 D5114121 14:59 108-88-3 ND uglL 2.0 0.43 1 05/14/21 14:59 71-55-6 ND uglL 2.0 0,38 1 05114/2114:59 79-00-5 ND uglL 2.0 0.41 1 05114/21 14:59 79-01-6 ND uglL 2.0 0.41 1 05/14/21 14:59 75-01-4 103 % 70-130 1 05/14/21 14:59 460-00-4 102 % 70-130 1 05/14/21 14:59 2037-26-5 98 % 70-130 1 05/14/21 14:59 17060-07-0 Analytical Method: EPA420.4 Rev 1.0 1993 Preparation Method: EPA420.4 Rev 1.0 1993 Pace Analytical Services - Asheville ND mg/L 0.020 0.0076 1 05/18/21 08:15 05/18/2112:57 64743-03-9 Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011 Pace Analytical Services - Asheville ND mg/L 0.0080 0.0060 1 05/19/21 21:32 06/20/21 20:26 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services. l Page 8 of 30 aceAnalXical www.pacelabs.com QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 QC Batch: 620784 Analysis Method: SM 2540D-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services - Eden Associated Lab Samples: 92538713001 Pace Analytical Services, LLG 9800 Kincey Ave. Suite 100 Huntersvilie. NC 28078 (704)875-9092 METHOD BLANK: 3266172 Matrix: Water Associated Lab Samples: 92538713001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 2.5 05/17121 09:00 LABORATORY CONTROL SAMPLE: 3266173 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 238 95 90-110 SAMPLE DUPLICATE: 3266174 92538710001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 150 155 3 25 SAMPLE DUPLICATE: 3266175 92538710002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Suspended Solids mg/L 1010 653 43 25 D6 Results presented on this page are in the units indlcated by the "units" column except whore an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services, LLG. Page 9 of 30 ZJce Analytical www.paculabs.com QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 QC Batch: 622846 Analysis Method: EPA 1664B QC Batch Method: EPA 1664E Analysis Description: 1664 HEM, Oil and Grease Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92538713001 METHOD BLANK: 3276679 Associated Lab Samples: 92538713001 Parameter Units Oil and Grease mg1L LABORATORY CONTROL SAMPLE: 3276680 Parameter Units Oil and Grease mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704 )875-9092 Matrix: Water Blank Reporting Result Limit MDL Analyzed Qualifiers ND 5.0 1.1 05/25/2118:50 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 40 31.3 78 78-114 MATRIX SPIKE SAMPLE: 3276681 35633068001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Oil and Grease mg/L 1.8J 39.2 35.9 87 78-114 SAMPLE DUPLICATE: 3276682 92539234002 Dup Parameter Units Result Result Oil and Grease mg1L 6.8 6.1 Max RPD RPD Qualifiers 11 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/2812021 10:52 AM without the written consent of Pace Analytical Services, LLC, Page 10 of 30 aceAnalyiica! www.pacelabs.com Project: Newton Instruments / 2112 Pace Project No.: 92538713 QC Batch: 622447 QC Batch Method: EPA 245.1 Rev 3.0 1994 Associated Lab Samples: 92538713001 METHOD BLANK: 3274974 Associated Lab Samples: 92538713001 Parameter Units Mercury ug/L LABORATORY CONTROL SAMPLE: 3274975 Parameter Units Mercury ug/L QUALITY CONTROL DATA Analysis Method: EPA 245.1 Rev 3.0 1994 Analysis Description: 245.1 Mercury Laboratory: Pace Analytical Services -Asheville Matrix: Water Blank Reporting Result Limit ND 0.20 Spike LCS Conc. Result 2.5 2.3 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 HuMersville, NC 28078 (704)875-9092 MDL Analyzed Qualifiers 0.12 05/25/2112:50 LCS % Rec % Rec Limits Qualifiers 92 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3274976 3274977 MS MSD 92538634001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2 3 2.3 93 93 70-130 0 20 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3274978 3274979 MS MSD 92538713001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conic. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2 5 2.3 2.4 92 94 70-130 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the resuM. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 30 _ ;a'ce Analytical4 www.pacelabsxant QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 QC Batch: 622085 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 2D0.7 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92538713001 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 METHOD BLANK: 3272875 Associated Lab Samples: 92538713001 Parameter Units Matrix: Water Blank Reporting Result Limit MDL Analyzed Qualifiers Antimony ug1L ND 5.0 3.0 05/2212121:39 Arsenic ug1L ND 10.0 4.7 0512212121:39 Beryllium ug1L ND 1.0 0.70 05122/2121:39 Cadmium ug1L ND 1.0 0.40 05122/2121:39 Chromium ug1L ND 5.0 3.7 05122/2121:39 Copper ug1L ND 5.0 4.3 0512212121:39 Lead ug1L ND 5.0 4.5 0512212121:39 Nickel ug1L ND 5.0 3.5 05/2212121:39 Selenium ug1L ND 10.0 4.7 05122/2121:39 Silver ug1L ND 5.0 2.5 05122/2121:39 Thallium ug1L ND 10.0 8.1 05122/2121:39 Zinc ug1L ND 10.0 9.5 05/22/2121:39 LABORATORY CONTROL SAMPLE: Parameter 3272876 Units Spike Cone. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug1L 500 474 95 85-115 Arsenic ug1L 500 478 96 85-115 Beryllium uglL 500 493 99 85-115 Cadmium ug1L 500 491 96 85-115 Chromium ug1L 500 484 97 85-115 Copper ug1L 500 490 98 85-115 Lead ug1L 500 480 96 85-115 Nickel ug1L 500 482 96 85-115 Selenium ug1L 5D0 466 93 85-115 Silver ug1L 250 242 97 85-115 Thallium ug1L 500 477 95 85-115 Zinc ug1L 500 478 96 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3272877 3272878 MS MSD 92538551001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Antimony uglL ND 500 500 476 483 95 96 70-130 1 20 Arsenic ug1L ND 500 500 479 484 95 96 70-130 1 20 Beryllium ug1L ND 500 500 488 496 98 99 70-130 2 20 Cadmium uglL ND 500 500 488 495 98 99 70-130 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result - REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05128/2021 10:52 AM without the written consent of Pace Analytical Services. LLC Page 12 of 30 aceAnalytical www.pacelabs.com r QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave Suite 100 Huntersvi1e. NC 28078 (704)875-9092 Project: Pace Project No.: Newton Instruments 12112 92538713 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3272877 3272878 MS MSD 92538551001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chromium ug/L 0.0052 500 500 497 503 98 100 70-130 1 20 mg/L Copper ug/L 0.015 500 500 510 516 99 100 70-130 1 20 mg/L Lead ug/L ND 500 500 479 485 95 96 70-130 1 20 Nickel ug/L ND 500 500 483 489 96 98 70-130 1 20 Selenium ug/L ND 500 500 485 492 97 98 70-130 1 20 Silver ug/L ND 250 250 242 244 97 98 70-130 1 20 Thallium ug/L ND 500 500 466 475 93 95 70-130 2 20 Zinc ug/L 0,073 500 500 565 571 98 100 70-130 1 20 mg/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3272879 MS 92538803002 Spike Parameter Units Result Conc. MSD Spike Conc. 3272880 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Antimony ug/L ND 500 500 469 472 94 94 70-130 1 20 Arsenic ug1L ND 500 500 470 468 94 93 70-130 0 20 Beryllium ug/L ND 500 500 483 483 97 97 70-130 0 20 Cadmium ug/L ND 500 500 476 478 95 96 70-130 1 20 Chromium ug/L ND 500 500 479 432 96 96 70-130 1 20 Copper ug/L ND 500 500 478 484 95 96 70-130 1 20 Lead uglL ND 500 500 467 471 93 94 70-130 1 20 Nickel ug/L ND 500 500 471 474 94 95 70-130 1 20 Selenium ug/L ND 500 500 481 486 96 97 70-130 1 20 Silver ug/L ND 250 250 235 237 94 95 70-130 1 20 Thallium ug/L ND 500 500 454 455 90 91 70-130 0 20 Zinc ug/L 16.3 500 500 502 504 97 98 70-130 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report sha11 not be reproduced, except in full, Date: 05128/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 30 aoAnaoicals fwww.pacelabs.com I QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 QC Batch: 620596 QC Batch Method: EPA 624 1 Associated Lab Samples: 92538713001 Analysis Method: Analysis Description: Laboratory: EPA624.1 624 MSV with Acrolein Pace Analytical Services - Charlotte METHOD BLANK: 3265338 Matrix: Water Associated Lab Samples- 92538713001 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,11-Trichloroethane ug1L NO 2.0 0.43 0511412114:06 1,1,2,2-Tetrachloroethane ug1L NO 2.0 0.30 0511412114:06 1,1,2-Trichloroethane ug1L ND 2.0 0.38 0511412114:06 1,1-Dichloroethane uglL ND 2.0 0.47 05/14/21 14:06 1,2-Dichloroethane ug1L ND 2.0 0.42 05114/2114:06 1.2-Dichloropropane uglL NO 2.0 0.44 05114/2114:06 2-Chloroethylvinyl ether uglL ND 5.0 0.94 05114/21 14:06 Acrolein uglL ND 5.0 3.6 05114/2114:06 Acrylonitdle ug1L ND 5.0 2.3 0511412114:06 Benzene uglL ND 1.0 0.42 05114/2114:06 BromOdiGhloromethane ug1L NO 2.0 0.41 05/14/21 14:06 Bromoform ug1L ND 2.0 0.59 05114/2114:06 Bromomethane uglL ND 2.0 1.5 05114/2114:06 Carbon tetrachloride ug1L ND 2.0 0.47 05/14/21 14:06 Chlorobenzene uglL ND 2.0 0.39 05/14/21 14:06 Chloroethane ug1L ND 2.0 0.71 05114/2114:06 Chloroform uglL ND 2.0 0.49 05/14/21 14:06 Chloromethane ug1L ND 2.0 0.60 05114/2114:06 cis-1,3-Dichloropropene ug1L ND 2.0 0.35 0511412114:06 Di b romochloro methane ug1L ND 2.0 0.39 05/14/21 14:06 Ethylbenzene uglL N❑ 1.0 0.35 05/14/21 14:06 Methylene Chloride uglL NO 2.0 0.91 05/14/21 14:06 Tetrachloroethene uglL ND 2 0 0.38 05/14/21 14:06 Toluene uglL ND 1.0 0.41 05/14/21 14:06 trans-12-Dichloroethene uglL ND 2.0 0.48 05/14/2114:06 trans- 1.3-Dichloropropene uglL ND 2.0 0.34 05/14/21 14:06 Trichloroethene uglL NO 2.0 0.41 05/14/21 14:06 Vinyl chloride uglL ND 2.0 0.41 05/14/21 14:06 1,2-Dichloroethane-d4 (S) % 98 70-130 05/14/21 14:06 4-Bromofluorobenzene (S) % 101 70-130 05/14/21 14:06 Toluene-d8 (S) % 98 70-130 05/14/21 14:06 LABORATORY CONTROL SAMPLE: 3265339 Pace Analytical Services, LLC 9600 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,11-Trichloroethane uglL 20 19.9 99 70-130 1,1,2,2-Tetrachloroethane uglL 20 19.1 96 70-130 1,1,2-Trichloroethane uglL 20 20.2 101 70-130 1,1-Dichloroethane uglL 20 19.4 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05128/2021 10:52 AM without the written consent of Pace Analytical Services. LLC Page 14 of 30 aceAnalytical " wwtrpacetatucom QUALITY CONTROL DATA Project: Newton Instruments / 2112 Pace Project No.: 92538713 LABORATORY CONTROL SAMPLE: 3265339 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2-Dichloroethane ug/L 20 19.3 96 70-130 1,2-Dichloropropane ug/L 20 20.2 101 70-130 2-Chloroethylvinyl ether ug/L 40 30.7 77 67-130 Acrolein ug/L 100 123 123 60-M Acrylonitrile ug/L 100 94.2 94 70-130 Benzene ug/L 20 20.6 103 70-130 Bromodichloromethane ug/L 20 18.9 95 70-130 Bromoform ug/L 20 18.9 94 70-130 Bromomethane ug/L 20 25.8 129 30-177 Carbon tetrachloride ug/L 20 21.8 109 70-130 Chlorobenzene ug/L 20 20.8 104 70-130 Chloroethane ug/L 20 19.1 95 46-131 Chloroform ug/L 20 20.1 101 70-130 Chloromethane ug/L 20 19.1 95 49-130 cis-1,3-Dichloropropene ug/L 20 18.9 95 70-130 Dibromochloromethane ug/L 20 19.7 99 70-130 Ethylbenzene ug/L 20 20.8 104 70-130 Methylene Chloride ug/L 20 19.1 96 68-130 Tetrachloroethene ug/L 20 20.8 104 70-130 Toluene ug/L 20 19.6 98 70-130 trans-1.2-Dichloroethene ug/L 20 20.2 101 70-130 trans-1,3-Dichloropropene ug/L 20 17.8 89 70-130 Tichloroethene ug/L 20 21.3 107 70-130 Vinyl chloride ug/L 20 18.7 93 59-142 1,2-Dichloroethane-d4 (S) % 94 70-130 4-Bromoftuorobenzene (S) % 99 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3265340 3265341 MS MSD 92538568001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Quai 1,1,1-Tdchloroethane ug/L ND 20 20 23.9 22.4 119 112 70-148 7 21 1,1,2,2-Tetrachloroethane ug/L ND 20 20 22.6 20.1 113 101 70-131 12 30 1,1,2-Tdchloroethane ug/L ND 20 20 23.1 21.6 116 108 70-136 7 27 1, 1 -DicHoroethane ug/L ND 20 20 22.9 21.7 114 108 71-143 5 30 1,2-Dichloroethane ug/L ND 20 20 22.0 21.3 110 106 72-137 3 29 1,2-Dichloropropane ug/L ND 20 20 23.9 22.2 120 111 70-138 8 30 2-Chtoroethylvinyl ether ug/L ND 40 40 34.0 32.5 85 81 10-200 5 32 Acrolein ug/L ND 100 100 65.8 76.0 66 76 50-150 14 30 Acrylonitdle ug/L ND 100 100 108 97.4 108 97 68-140 11 30 Benzene ug/L ND 20 20 24.3 22.7 121 114 75-125 6 30 Bromodichloromethane ug/L ND 20 20 23.1 21.1 115 106 70-138 9 30 Bromoform ug/L ND 20 20 22.5 20.0 112 100 57-138 12 25 Bromomethane ug/L ND 20 20 21.2 23.1 106 115 10-200 9 35 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 30 _ _ ?ceAnaVical' www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9B00 KinceyAve. Suite 100 Huntersville. NC 28078 (704)875-9092 Project: Newton Instruments 12112 Pace Project No.: 92538713 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3265340 3265341 MS MSD 92538568001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Carbon tetrachloride ug/L ND 20 20 25.8 24.4 129 122 70-125 6 26 M1 Chlorobenzene ug/L ND 20 20 24.7 22.3 124 111 82-137 10 29 Chloroethane ug/L ND 20 20 22.8 22.4 114 112 51-166 2 30 Chloroform ug/L ND 20 20 24.2 22.6 119 111 70-121 7 30 Chloromethane ug1L ND 20 20 20.3 19.0 101 95 24-161 6 30 cis- 1,3-Dichloropropene ug1L ND 20 20 22.0 20.3 110 101 70-142 8 30 Di b romochloro methane ug/L ND 20 20 24.1 21.4 121 107 69-133 12 30 Ethylbenzene ug/L ND 20 20 24.9 22.4 125 112 75-134 11 30 Methylene Chloride ug1L ND 20 20 21.6 20.0 108 100 64-148 8 30 Tetrachloroethene ug1L ND 20 20 25.0 22A 125 112 70-133 11 23 Toluene ug/t_ ND 20 20 23.7 22.1 117 109 75-134 7 22 trans- l.2-Dichloroethene ug1L ND 20 20 23.9 22.3 120 111 70-143 7 27 trans- 1,3-Dichloropropene ug1L ND 20 20 20.6 19.6 103 98 70-13B 5 30 Tfichloroethene ug1L ND 20 20 25.5 23.5 127 117 75-138 8 29 Vinyl chloride ug1L ND 20 20 22.6 21.0 113 105 55-172 7 30 1,2-❑ichloroethane-d4(S) % 97 93 70-130 4-Bromofluorobenzene (S) % 100 97 70-130 Toluene-0 (S) % 98 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the resutt. REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full. Date: 05/2812021 10:52 AM without the written consent of Pace Analytical Services, LLC Page 16 of 30 1�?ceAnalyfical www.pacelaKeom QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 620767 OC Batch Method: EPA608.3 Associated Lab Samples: 92538713001 Analysis Method: EPA608 3 Analysis Description 608 PCB Pest Red Vol Laboratory: Pace Analytical Services - Charlotte METHOD BLANK 3266119 Matrix: Water Associated Lab Samples: 92538713001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 4,4'-DDD ug/L ND 0.050 0.012 05/19/2116-53 4,4'-DOE ug/L ND 0.050 0.016 0511912116:53 4.4'-DDT ug/L ND 0.050 0.048 05/19/21 16:53 Aldrin ug/L ND O.D50 0.026 05/1912116:53 alpha-BHC ug/L ND 0,050 0.026 05/19/21 16:53 alpha -Chlordane ug/L ND 0.050 0.015 05/19/2116-53 beta-BHC ug/L ND 0.050 0.022 05/1912116:53 Chlordane (Technical) ug/L ND 0.50 0.21 05/19/21 16:53 delta-BHC ug/L ND 0.050 0.018 05/19/21 16:53 Dieldrin ug/L ND 0.050 0.013 05/1912116:53 Endosulfan I ug/L ND 0.050 0.014 05/19/21 16:53 Endosulfan II ug/L ND 0,050 0.017 05/19/21 16:53 Endosulfan sulfate ug/L ND 0,050 0.014 05/19/21 16:53 Endrin ug/L ND 0,050 0.014 05/1912116:53 Endrin aldehyde ug/L ND 0.050 0.028 05/19/21 16:53 gamma-BHC (Lindane) ug/L ND 0.050 0.020 05/19121 16:53 gamma -Chlordane ug/L ND 0,050 0.035 0511912116:53 Heptachlor ug/L ND 0.050 0.036 05/19/21 16:53 Heptachlor epoxide ug/L ND 0.050 0.015 05/19/21 16:53 PCB-1016 (Arodor 1016) ug/L ND 0.50 0.47 05/19121 16:53 PCB-1221 (Arodor 1221) ug/L ND 0,50 0.45 05/19/21 16:53 PCB-1232 (Arodor 1232) ug/L ND 0.50 0.36 05/19/21 16:53 PCB-1242 (Arodor 1242) ug/L ND 0.50 0.26 05/19/21 16:53 PCB-1248 (Arodor 1248) ug/L ND 0.50 0.40 05/19/21 16:53 PCB-1254 (Arodor 1254) ug/L ND 0.50 0.25 05/19121 16:53 PCB-1260 (Arodor 1260) ug/L ND 0.50 0.42 05/19/21 16:53 Toxaphene ug/L ND 0.50 0.27 0511912116:53 Decachlorobiphenyl IS) % B6 10-184 05/19/21 16:53 Tetrachloro-m-xylene (S) % 84 10-154 05/19/21 16:53 LABORATORY CONTROL SAMPLE: Parameter 3266120 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 4.4'-DDD ug/L 0,25 0.25 100 45-141 4,4'-DDE ug/L 0.25 0.22 87 37-141 4,4'-DDT ug/L 0,25 0.16 66 52-160 Aldrin ug/L 0,25 0.16 65 42-130 alpha-BHC ug/L 0.25 0.20 79 37-139 alpha -Chlordane ug/L 025 0.21 84 45-139 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Aralytical Services, LLC. Page 17 of 30 w aceAnaIXical www.pacelabs.com QUALITY CONTROL DATA Project: Newton Instruments/ 2112 Pace Project No.: 92538713 LABORATORY CONTROL SAMPLE: Parameter 3266120 Units Spike Conc. LCS Result beta-BHC ug/L 0.25 0.25 delta-BHC ug/L 0.25 0.22 Dieldrin ug/L 0.25 0.22 Endosulfan I ug/L 0.25 0.20 Endosulfan 11 ug/L 0.25 0.21 Endosulfan sulfate ug/L 0.25 0.22 Endrin uglL 0.25 0.23 Endrin aldehyde ug/L 0.25 0.17 gamma-BHC (Lindane) ug/L 0.25 0.20 gamma -Chlordane ug/L 0.25 0.22 Heptachlor ug/L 0.25 0.21 Heptachlor epoxide ug/L 0.25 0.21 Decachlorobiphenyl (S) % Tetrachloro-m-xylene (S) % LCS % Rec %u Rec Limits 100 39-147 87 39-140 86 40-146 79 45-145 85 47-153 88 48-144 90 41-147 67 45-146 82 42-140 88 45-140 83 34-135 85 39-142 93 10-184 82 10-154 Pace Analytical Services, LLC 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers LABORATORY CONTROL SAMPLE: 3266121 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 3.8 76 50-137 PCB-1260 (Aroclor 1260) ug/L 5 4.3 85 42-140 Decachlorobiphenyl (S) % 85 10-184 Tetrachloro-m-xylene (S) % 70 10-154 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3266122 3266123 MS MSD 92538041001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD ug1L ND 0.25 0.25 0.25 0.27 100 107 36-141 6 39 4,4'-DDF ug/L ND 0.25 0.25 0.17 0.17 68 69 31-145 1 35 4,4'-DDT ug/L ND 0.25 0.25 0.27 0.24 it() 96 25-160 13 42 Aidrin ug1L ND 0.25 0.25 0.25 0.24 99 96 42-140 3 35 aipha-BHC ug/L ND 0.25 0.25 0.18 0.18 71 71 37-140 0 36 alpha -Chlordane ug1L ND 0.25 0.25 0.19 0.20 76 79 45-140 3 35 beta-BHC ug/L ND 0.25 0.25 0.24 0.25 95 101 30-147 6 44 delta-BHC ug/L ND 0.25 0.25 0.16 0.18 66 73 32-140 10 52 Dieldrin ug/L ND 0.25 0.25 0.18 0.18 70 72 36-146 3 49 Endosulfan I ug/L ND 0.25 0.25 0.16 0.16 62 65 45-153 4 28 Endosulfan II ug/L ND 0.25 0.25 0.16 0.17 66 68 27-176 3 53 Endosulfan sulfate ug/L ND 0.25 0.25 0.16 D.15 62 61 31-144 2 38 Endrin ug/L ND 0.25 0.25 0.18 0.18 73 72 30-147 1 48 Endrin aldehyde ug/L ND 0.25 0.25 ND ND 11 6 16-177 30 M1 gamma-BHC (Lindane) ug/L ND 0.25 0.25 0.18 D.19 71 74 32-140 4 39 gamma -Chlordane ug1L ND 0.25 0.25 0.32 0.33 129 134 45-140 3 35 Heptachlor ug/L ND 0.25 0.25 0.17 0.23 66 91 34-140 31 43 Results presented on this page are in the units indicaled 4y the "units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services. LLC. Page 18 of 30 aceAnalXical WWw.pdtala63.cUm QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 3266122 3266123 MS MSD 92538041001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc Conc Result Result % Rec % Rec Limits RPD RPD Qual Heptachlor epoxide ug/L ND 0.25 0.25 0.18 0.19 71 75 37-142 5 26 Decachlorobiphenyl (S) % 64 67 10-184 Tetrachloro-m-xylene (S) % 68 71 10-154 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3266124 3266125 MS MSD 92538041001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PC8-1016 (Arodor 1016) ug/L ND 5 5 6.6 4.7 133 94 50.140 34 36 PCB-1260 (Arodor 1260) ug/L ND 5 5 3.8 3.5 76 70 42-140 8 38 Decachlorobiphenyl (S) % 101 70 10-184 Tetrachloro-m-xylene (S) % 84 71 10-154 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 05128/2021 10:52 AM without the written consent of Pace Analytical Services. LLC Page 19 of 30 acmnalytical www.pacelabs.com QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 QC Batch: 621048 Analysis Method: EPA625.1 QC Batch Method: EPA625.1 Analysis Description: 625 MSS Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92538713001 METHOD BLANK( 3267555 Matrix Water Associated Lab Samples: 92538713001 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,2,4-Trichlorobenzene ug/L NO 5.0 1.7 05118/2117:07 1,2-Dichlorabenzene ug/L NO 5.0 1.8 05/1812117:07 1,2-Diphenylhydrazine ug/L ND 5.0 1.6 05/1812117:07 1,3-Diohlorobenzene ug/L ND 5.0 1.6 D511812117.07 1,4-DicNorobenzene ug/L ND 5.0 1.7 0511812117:07 2.4.6-Trtchlorophenol ug/L ND 10.0 1.6 05/18/21 17:07 2,4-Dichlorophenol ug/L NO 5.0 1.4 0511812117:07 2.4-Dimethylphenol ug/L NO 10.0 1.7 0511812117:07 2,4-Di nitro phenol uglL NO 5D 0 26.0 05/18/21 17:07 2,4-Dinitrotoluene ug/L ND 5.0 1.6 05118/2117:07 2,6-Dinitrotoluene ug/L ND 5.0 1.7 05/1812117:07 2-Chloronaphihalene ug/L ND 5.0 1.7 05/18/21 17:07 2-Chlorophenol ug/L ND 5.0 1.2 0511812117:07 2-Nitrophenol ug/L ND 5.0 1.4 0511812117:07 3,3'-DichIorobenzidine ug/L ND 10.0 8.1 05/18/21 17:07 4,6-Dinitro-2-methy IphenaI ug/L ND 100 3A 05/18/21 17-07 4-Bromophenylphenyl ether ug/L ND 5.0 1.8 05118/21 17:07 4-Chloro-3-methylphenol ug/L NO 5.0 3.3 05/1812117:07 4-Chlorophenylphenyl ether ug/L ND 5.0 2.0 05/18/21 17:07 4-Nitrophenol ug/L ND 100 6.6 05118/21 17:07 Acenaphthene ug/L NO 5.0 2.0 05/18/21 17:07 Acenaphthylene ug/L ND 5.0 2.0 05/18/21 17:07 Anthracene ug/L ND 5.0 2.3 05/1812117:07 Benzidine ug/L NO 50.0 13.4 0511812117.07 Benzo(a)anthracene uglL ND 5.0 2.7 05118/2117:07 Benzo(a)pyrene ug/L ND 5.0 2.8 0511812117:07 Benzo(k)fluoranthene ug/L ND 5.0 2.6 05/1812l 17:07 Benzo(g.h.i)perylene ug/L ND 5.0 2.8 05/18/21 17:07 Benzo(k)fluoranthene ug/L ND 5.0 2.7 05118/2117:07 bis(2-Chloroethoxy)melhane ug/L NO 10.0 1.8 05/1812117:07 bis(2-Chloroethyl) ether ug/L NO 5 0 1.9 05/18/21 17:07 bi s(2-Ethylhexyl) phthal ate ug/L NO 5.0 3.7 05/1812117:07 Butyl benzylphthalate ug/L NO 5.0 3.1 05/1812117:07 Chrysene ug/L ND 5.0 2.8 0511812117:07 Di-n-butylphthalate ug/L ND 5.0 2.2 0511812117:07 Di-n-octylphth a late ug/L ND 5.0 3.9 05/18/21 17:07 Dibenz(a,h)anthracene ug/L ND 5.0 3.0 05/18/2117:07 Diethyl phthalate ug/L NO 5.0 2.0 0511812117:07 Dimethylphthalate ug/L NO 5.0 2.1 0511812117:07 Fluoranthene ug/L NO 5 0 2.2 05/18/21 17:07 Pace Analytical Services, LLC 9800 KinceyAve_ Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 05128/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 30 Pace Analytical Services, LLC aceAnalytical 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 www.pacelabsxom (704)875-9092 QUALITY CONTROL DATA Project: Newton Instruments / 2112 Pace Project No.: 92538713 METHOD BLANK: 3267555 Matrix: Water Associated Lab Samples: 92538713001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Fluorene ug/L ND 5.0 2.1 05/1812117:07 Hexachloro-1,3-butadiene ug/L ND 5.0 1.8 0511812117:07 Hexachlorobenzene ug/L ND 5.0 2.2 05118/2117:07 Hexachlorocyclopentadiene ug/L ND 10.0 1.6 05118/2117:07 Hexachloroethane ug/L ND 5.0 1.4 05118/2117:07 Indeno(1,2,3-cd)pyrene ug/L ND 5.0 2.9 05118/2117:07 Isophorone ug/L ND 10.0 1.7 05118/2117:07 N-Nitroso-di-n-propylamine ug/L ND 5.0 1.3 05/18/2117:07 N-Nitrosodimethylamine ug/L ND 5.0 1.9 05118/2117:07 N-Nitrosodiphenylamine ug/L ND 10.0 3.0 05/18/2117:07 Naphthalene ug/L ND 5.0 2.1 05/18/2117:07 Nitrobenzene ug/L ND 5.0 1.9 05/18/2117:07 Pentachlorophenol ug/L ND 10.0 3.8 05/18/2117:07 Phenanthrene ug/L ND 5.0 2.0 05/18/2117:07 Phenol ug/L ND 5.0 1.4 05/18/2117:07 Pyrene ug/L ND 5.0 2.2 05/1842117:07 2,4,6-Tdbromophenol (S) % 142 10-137 05/1821 17:07 S3 2-Fluorobiphenyl (S) % 107 15-120 0511821 17:07 2-Fluorophenol (S) % 94 10-120 05/1821 17:07 Nitrobenzene-d5 (S) % 119 10-120 0511821 17:07 Phenol-d6 (S) % 76 10-120 05/1821 17:07 Terphenyl-d14 (S) % 114 11-131 05/1821 17:07 LABORATORY CONTROL SAMPLE: 3267556 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2,4-Tdchlorobenzene ug/L 50 46.1 92 44-142 1,2-Dichlorobenzene ug/L 50 42.7 85 32-129 1,2-Diphenylhydrazine ug/L 50 64.9 130 25-150 1,3-Dichlorobenzene ug/L 50 41.5 83 1-172 1,4-Dichlorobenzene ug/L 50 42.6 85 20-124 2,4,6-Tdchlorophenol ug/L 50 74.5 149 37-144 L1 2,4-Dichlorophenol ug/L 50 74.0 148 1-191 2,4-Dimethylphenol ug/L 50 75.9 152 32-119 L1 2,4-Dinitrophenol ug/L 250 367 147 1-181 2,4-Dinitrotoluene ug/L 50 65.9 132 39-139 2,6-Dinitrotoluene ug/L 50 69.1 138 50-158 2-Chtoronaphthalene ug/L 50 57.8 116 60-118 2-Chlorophenol ug/L 50 65.7 131 23-134 2-Nitrophenol ug/L 50 76.0 152 29-182 3,3'-Dichtorobenzidine ug/L 100 139 139 1-262 4,6-Dinitro-2-methylphenol ug/L 100 153 153 1-181 4-Bromophenylphenyl ether ug/L 50 68.6 137 53-127 L1 4-Chloro-3-rttethylphenol ug/L 100 142 142 22-147 Results presented on this page are in the units Indicated by the "units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05128/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 30 aceAnaV cal www.paceiabs.com QUALITY CONTROL DATA Project: Newton instruments 12112 Pace Project No.: 92538713 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 3267556 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 4-Chlorophenylphenyl ether uglL 50 63.8 128 25-158 4-Nitrophenol uglL 250 247 99 1-132 Acenaphthene ug1L 50 63.0 126 47-145 Acenaphthylene ug1L 50 64.9 130 33-145 Anthracene ug1L 50 69.0 138 1-166 Benzidine ug1L 100 15.2J 15 10-130 Senzo(a)anthracene ug1L 50 70.9 142 33-143 Benzo(a)pyrene uglL 50 68.3 137 17-163 Benzo(b)fluoranthene uglL 50 66.8 134 24-159 Benzo(g,h,i)perylene ug1L 50 74.7 149 1-219 Benzo(k)fluoranthene ug1L 50 67.6 135 11-162 bis(2-Chloroethoxy)methane ug1L 50 64.8 130 33-184 bis(2-Chloroethyl) ether ug1L 50 65.6 131 12-158 bis(2-Ethylhexyl) phthal ate ug1L 50 80.1 160 8-158 L1 Butylbenzylphthalate ug1L 50 77.4 155 1-152 L1 Chrysene ug1L 50 68.7 137 17-168 Di-n-butylphthalate ug1L 50 73.0 146 1-118 L1 Di-n-octylphthalate ug1L 50 85.8 172 4-146 L1 Dibenz(a,h)anthracene ug1L 50 76.3 153 1-227 Diethyl phlhalate ug1L 50 64.1 128 1-114 L1 Dimethylphthalate ug1L 50 63.2 126 1-112 L1 Fluoranthene ug1L 50 71.3 143 26-137 L1 Fluorene ug1L 50 66.1 132 59-121 L1 Hexachloro-1,3-1)utadiene ug1L 50 41.1 82 24-116 Hexachlorobenzene ug1L 50 63.2 126 1-152 Hexachlorocyclopentadiene ug1L 50 41.6 83 25-150 Hexachloroethane ug1L 50 39.9 80 40-113 Indeno(1,2,3-cd)pyrene ug1L 50 75,6 151 1-171 Isophorone ug1L 50 61.0 122 21-196 N-Nitroso-di-n-propylamine ug1L 50 59.3 119 1-230 N-Nitrosodimethylamine ug1L 50 55.5 111 25-150 N-Nitrosodiphenylamine uglL 50 69.2 138 25-150 Naphthalene uglL 50 53.1 106 21-133 Nitrobenzene ug1L 50 62.6 125 35-180 Pentachlorophenol uglL 100 164 164 14-176 Phenanthrene ug1L 50 67.8 136 54-120 L1 Phenol ug1L 50 49.5 99 5-112 Pyrene ug11- 50 66.3 133 52-115 L1 2,4,5-Tribromophenol (S) % 142 10-137 SO 2-Fluorobiphenyl (S) % 106 15-120 2-Fluorophenol (S) % 96 10-120 Nitrobenzene-d5 (S) % 119 10-120 Phenol-d6 (S) % 78 10-120 Terphenyl-d14 (S) % 120 11-131 Resutts presented an this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 30 aceAnalytrcal - www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 KinceyAve, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Newton Instruments 12112 Pace Project No.: 92538713 MATRIX SPIKE & MATRIX SPIKE DUPLICATE. 3267557 3267558 MS MSD 35632710001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 12,4-Trichlorobenzene ug/L 8.6U 50 50 19.1J 15.8J 38 32 44-142 30 M1 1,2-Dichlorobenzene ug/L 9.01-1 50 50 18,4J 15.6J 37 31 32-129 30 M1 1,2-Diphenylhydrazine ug/L 8.01-1 50 50 23 9J 23.8J 48 48 25-150 30 1.3-Dichlorobenzene ug/L 8AU 50 50 16.9J 15.3J 34 31 1-172 30 1,4-Dichlorobenzene ug/L 8AU 50 50 18.11 15.13J 36 32 20-124 30 2,4,6-Trichlorophenol ug/L 7.81-1 50 50 27AJ 26.7J 54 53 37-144 30 2,4-Dichlorophenol uglL 7.OU 50 50 27.7 25.8 55 52 1-191 7 30 2.4-Dimethylphenol ug/L 8.51-1 50 50 27.8J 25.6J 56 51 32-119 30 2.4-Dinitrophenol ug/L 130U 250 250 ND NO 0 12 1-181 30 M1 2,4-Dinitrotoluene ug/L 8.1U 50 50 24.7J 24.OJ 49 48 39-139 30 2,6-Dinitrotoluene ug/L 8.6U 50 50 22.5J 23.3J 45 47 50-158 30 M1 2-Chloronaphthalene ug/L 8.6U 50 50 23 7J 21.OJ 47 42 60-118 30 M1 2-Chlorophenol ug/L 6.OU 50 50 25.6 23.1J 51 46 23-134 30 2-Nitrophenol ug/L 7.OU 50 50 29.0 24.21 58 48 29-182 30 3,3'-Dichlorobenzidine ug/L 40.6U 100 100 ND NO 16 20 1-262 30 4,6-Dinitro-2-methylphenol ug/L 17.OU 100 100 ND 21.OJ 16 21 1-181 30 4-Bromophenylphenyl ether ug/L 8.8U 50 50 24AJ 24.5J 49 49 53-127 30 MO 4-Chlaro-3-methylphenol ug/L 16 7U 100 100 49.4 50.8 49 51 22-147 3 30 4-Chlorophenylphenyl ether ug/L 10.0U 50 50 24.5J 23.6J 49 47 25-158 30 4-Nitrophenol ug/L 33.OU 250 250 77,8 82.3 31 33 1-132 6 30 Acenaphthene ug/L 10.0U 50 50 24.8J 22.7J 50 45 47-145 30 M1 Acenaphthylene ug/L 9.8U 50 50 25.0 22.8J 50 46 33-145 30 Anthracene ug/L 11.61-1 50 50 24 9J 25.7 50 51 1-166 30 Benzidine ug/L 67.OU 100 100 ND NO 0 0 10-130 30 M1 Benzo(a)anthracene ug]L 13AU 50 50 24.9J 26.2 50 52 33-143 30 Benzo(a)pyrene ug/L 13.9U 50 50 23AJ 25.5 46 51 17-163 30 Benzo(b)nuoranihene ug/L 13.OU 50 50 22.5J 24.7J 45 49 24-159 30 Benzo(g,h,i)perylene ug/L 14.2U 50 50 25.0 27.7 50 55 1-219 10 30 Benzo(k)Ruo(anthene ug/L 13.6U 50 50 22.8J 24.1J 46 48 11-162 30 bis(2- ug]L 9.1U 50 50 25AJ 22.2J 50 44 33-184 30 Chloroethoxy)methane bis(2-Chloroethyl) ether ugJL 9.61-11 50 50 27.7 24.3J 55 49 12-158 30 bis(2-Ethylhexyl) p hthal ate ug/L 18.6U 50 50 24.8J 25.6 50 51 8-158 30 Butyibenzylphthalate ug/L 15.7U 50 50 25.8 27.9 52 56 1-152 8 30 Chrysene ug/L 13.8U 50 50 23.7J 26.2 47 52 17-168 30 Di-n-butylphthalate ug/L 11.0U 50 50 22.7J 24.9J 45 50 1-118 30 Di-n-octylphthalate ug]L 19.6U 50 50 26.0 29.0 52 58 4-146 11 30 Dibenz(a,h)anthracene ug/L 14.81J 50 50 252 27.5 50 55 1.227 9 30 Diethyl phthalate ug/L 10.2U 50 50 23.OJ 23.7J 46 47 1-114 30 Dimethylphthalate ug/L 10.61-11 50 50 22.8J 22.5J 46 45 1-112 30 Fiuoranthene ug/L 11.0U 50 50 24 5J 26.1 49 52 26-137 30 Fluorene ug/L 10.41-1 50 50 25.0 24.2J 50 48 59-121 30 MO Hexachloro-1.3-butadiene ug/L 8.8U 50 50 17.3J 14.7J 35 29 24-116 30 Hexachlorobenzene ug/L 10.81-11 50 50 23.OJ 23.5J 46 47 1-152 30 Hexachlorocyclopentadiene ug/L 8 OU 50 50 11.5J 10.01 23 20 25-150 30 M1 Hexachloroethane ug/L 6.9U 50 50 16.6J 14.3J 33 29 40-113 30 M1 Results presented on this page are in the units indicated by the "Units- column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05128/2021 10:52 AM without the written consent of Pace Analytical Services, LLC, Page 23 of 30 aceAnalytfical www.pat:alabs.cam QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3267557 MS 35632710001 Spike Parameter Units Result Conc. MSD Spike Conc. Indeno(1,2,3-cd)pyrene ug/L 14.41-1 50 50 Isophorone ug/L 8.3U 50 50 N-Nitroso-di-n-propylamine ug/L 6.6U 50 50 N-Nitrosodimethylamine ug/L 9AU 50 50 N-Nitrasodiphenylamine ug/L 15.OU 50 50 Naphthalene ug/L 10AU 50 50 Nitrobenzene ug/L 9AU 50 50 Pentachlorophenol ug/L 18.8U 100 100 Phenanthrene ug/L 10.0U 50 50 Phenol ug/L 6.8U 50 50 Pyrene ug/L 11.0U 50 50 2,4,6-Tribromophenal(S) % 2-Fluorobiphenyl(S) % 2-Fluorophenol(S) % Nitrobenzene-d5 (S) % Phenol-d6 (S) % Terphenyl-d14 (S) % 3267558 MS Result 25.4 23.3J 24.2J 22.3J 23.6J 21.8J 27.4 34.9J 24.8J 20.11J 23AJ Pace Analytical Services, LLC 9800 Kincey Ave_ Suite 100 Huntersville, NC 28078 (704 )875-90 92 MSD MS MSD % Rec Max Result % Rec % Rec Limits RPD RPD Qual 27.7 51 55 1-171 9 30 20.1J 47 40 21-196 30 21.OJ 48 42 1-230 30 19.91 45 4D 25-150 30 24.2J 47 413 25-150 30 18.5J 44 37 21-133 30 24.3J 55 49 35-180 30 42.3J 35 42 14-176 30 26.1 50 52 54-120 30 MO 16.4J 40 33 5-112 30 25.OJ 47 50 52-115 30 MO 43 46 10-137 41 37 15-120 35 30 10-120 50 43 10-120 D3 29 25 10-120 38 42 11-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52AM without the written consent of Pace Analytical Services, LLC. Page 24 of 30 aceAnalytical www.paeelabs.com 1 Project: Newton Instruments / 2112 Pace Project No.: 92538713 QC Batch: 620922 QC Batch Method: EPA420.4 Rev 1.0 1993 Associated Lab Samples 92538713001 METHOD BLANK: 3267065 Associated Lab Samples: 92538713001 Parameter Units Phenolics. Total Recoverable mg/L QUALITY CONTROL DATA Analysis Method: EPA420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics Laboratory: Pace Analytical Services -Asheville Matrix: Water Blank Reporting Result Limit MDL Analyzed ND 0,020 0.0076 05/18/2112:27 Pace Analytical Services, t_LC 9800 Kincey Ave, Suite 100 Huntersville. NC 28078 (704)875-9092 Qualifiers LABORATORY CONTROL SAMPLE: 3267066 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenolics, Total Recoverable mg/L 0.05 0 051 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3267067 3267068 MS MSD 92538819001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec %fl Rec Limits RPD RPD Quail Phenolics, Total mg/L ND 0.05 0.05 0.050 0.057 68 83 90-110 14 10 M1,R1 Recoverable Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shalt not be reproduced, except in full. Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services. LLC, Page 25 of 30 aceAnaIXical" www.pacelabs.com QUALITY CONTROL DATA Project: Newton Instruments 12112 Pace Project No.: 92538713 QC Batch: 621281 Analysis Method: SM 4500-CN-E-2011 QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 450OCNE Cyanide, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92538713001 Pace Analytical Services, LLC 9800 Kinoey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 3269128 Matrix: Water Associated Lab Samples: 92538713001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cyanide mg/L ND 0.0080 0.0060 05/20/2120:05 LABORATORY CONTROL SAMPLE: 3269129 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Cyanide mg/L 0.1 0.10 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3269154 3269155 MS MSD 92539018004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide mg/L ND 0.1 0.1 0.10 0.10 102 101 80-120 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3269156 3269157 MS MSD 92539018011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide mg/L ND 0.1 0.1 0.088 0.091 88 91 80-120 3 10 Results presented on this page are to the units Indicated by the "Units" column except where an alternate unit is presented to the right of the resutt. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services, I.I.C. Page 26 of 30 1�;a'ceAnalytical' WWW.pacalabstam QUALIFIERS Project: Newton Instruments / 2112 Pace Project No.: 92538713 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704 )875-90 92 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. Aseparate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonilrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. D6 The precision between the sample and sample duplicate exceeded laboratory control limits IL This analyte exceeded secondary source verification criteria low for the initial Calibration. The reported results should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M0 Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/28/2021 10:52 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 30 1�;a'ceAnalXical' www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Newton Instruments 12112 92538713 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92538713001 Outfall-001 SM 2540D-2011 620784 92538713001 O utfal I-001 92538713001 Outfall-001 EPA 1664E 622846 92538713001 Outfall-001 EPA608.3 620767 EPA608.3 621019 92538713001 Outfall-001 EPA200.7 Rev 4.4 1994 622085 EPA200.7 Rev 4.4 1994 622302 92538713001 Outfall-001 EPA245.1 Rev 3.01994 622447 EPA245.1 Rev 3.01994 622486 92538713001 Outfall-001 EPA625.1 621048 EPA625A 621329 92538713001 Outfall-001 EPA 624.1 620596 92538713001 Outfall-001 EPA420.4 Rev 1.0 1993 620922 EPA420.4 Rev 1.0 1993 621042 92538713001 Outfall-001 SM 4500-CN-E-2011 621281 SM 4500-CN-E-2011 621609 Date: 05128/2021 10:52 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC, Page 28 of 30 z y, A N Sp 8 p, F i fL}.n! ,rqq�� '+�' '3; i.•_(.r Y. 'G.pQ�w � �1�r,,P '�• (�-. i } y�. '. di o,: Li �.:� ��'.•Z ' A vy E sr da 2 }p� aLB, _ o T?1, Apr p p •rN� ni W ..i {G .a{ �YiO iQlWraJ CLf�tll.tte Vill Y / mown N EMMI �` NOUN =o ..- 5 o NOUN v s v ��. S S � r �• � rx t�xr � ,,mot 1 F... E 909 A4 (O11) S90d + SGPIapsad 9Z9 A (CA) ASSW ort xa iPig, VVZ9 hg (011) s0OA Its Aq 000a0110 Al. W E v a v T 18 m Cr n E m_ ¢ffi F E} n c a3� m �S 3c a a t: � w eo Vf m �Z '� — �a FF••,, a C n$ LL C N Q V m z � x n C O m V z rn � E V Y lot,t°i E n` Ill 10 OEa3r 0. s A I a w V t�� ,� — U U 1 E_\ s"a Page 29 of 30 Name: �Oocument Revised: October 28, 2020 _- e • Ce f ens pane 2 of 2 _ Document No.: 'Check nhark top half of box If pH and/or dechlorinaton Is verified and within the acceptance range for preservation samples. Ee;egtfons: VOA,Coliform, MC, Oil and Grease, DRO/Bois (water) Doc, Wig Pace carounas Ouanty Office 1 Prole WO# : 92538713 PM: TIH Due Date: 05/27/21 CLIENT: 82—PIED GEOL 001 0.0011010001 MIMS OMM Ilk ON olIL400OLILILI ilk MONSOON MIS 0 a 0 0 am - M 0 M 0 10 M ON M 0 MmmMOam Lin NONNI M vollsmam son ELISE Mail all, me No HOMMORN� ►ii►i►►�iii►►ii■i1 WE= rrnanavu UNTO * a asaapanry a�.�.,6,•••-• �• _...-----•.�-. _...... out of hold, Incorrect preservatNe, out of tamp, rnccrract conurnem Page 30 of 30