NC0003298_Monitoring Report_20141106

NPDES DOCUMENT SCANNi1N. COVER SHEET
Permit:
NC0003298
Riegelwood Paper Mill
NPDES
Document Type:
Permit Issuance
Wasteload Allocation
Authorization to Construct (AtC)
Permit Modification
Speculative Limits
Monitoring Report
Instream Assessment (67B)
Environmental Assessment (EA)
Permit
History
Document Date:
November 6, 2014
This document int printed on le exasse paper - ig►riore any
content on the rezreriae nide

INTERNATIONAL
November 6, 2014
PAPER
Certified Mail: 7012 3460 0003 4822 4550
Mr. Jay Sauber
Chief, Environmental Sciences Section
NC DENR Division of Water Quality
1621 Mail Service Center
Raleigh, NC 27699-1621
n COPY
RIEGELWOOD MILL
JOHN L. RIEGEL ROAD
RIEGELWOOD, NC 28456
RECEIVED/DENR/DWR
NOV 1 2 2014
Water Quality
Permitting Section
SUBJECT: Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the
International Paper Company Mill at Riegelwood, NC — 2014 Report
NPDES Permit No. NC0003298
Dear Mr. Sauber:
Please find enclosed the 2014 annual report for fish tissue dioxin monitoring conducted on the Cape
Fear River in the vicinity of International Paper's Riegelwood Mill.
If you have questions or need additional information, please call me at 910/362-4621.
Edward Kreul
Environmental, Health, Safety & Sustainability Manager
Enclosure
cc: James H. Gregson, Surface Water Protection Supervisor
NC DENR — Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405
Tom Belnick, NPDES Unit Supervisor
NC DENR Division of Water Quality
1617 Mail Service Center
Raleigh, NC 27699-1617
eeh
S:\Groups\Environmental\Wastewater\Fish Tissue\2014\Annual Fish Tissue Dioxin Report -2014.docx

J. Sauber
November 6, 2014
Page 2of2
Dr. Ken Rudo
NC DHHS, Division of Public Health
1931 Mail Service Center
Raleigh, NC 27699-1931
eeh
S:\Groups\Environmental\Wastewater\Fish Tissue12014\Annual Fish Tissue Dioxin Report -20 14.docx

DIOXIN MONITORING STUDY OF FISH TISSUE
FROM THE CAPE FEAR RIVER IN THE VICINITY OF
THE INTERNATIONAL PAPER COMPANY MILL
AT RIEGELWOOD, NORTH CAROLINA
2014 REPORT
Prepared for
International Paper Company
Riegelwood Mill
John L. Riegel Road
Riegelwood, North Carolina 28456
Prepared by
CZR Incorporated
4709 College Acres Drive, Suite 2
Wilmington, North Carolina 28403
November 2014
RECEIVED/DENRJDWR
NOV 1 2 2014
Water Quality
Permitting Section
1

/1
DIOXIN MONITORING STUDY OF FISH TISSUE RECEIVEDIDENR/DWR
FROM THE CAPE FEAR RIVER IN THE VICINITY OF NOV 2 2014
THE INTERNATIONAL PAPER COMPANY MILL1
AT RIEGELWOOD, NORTH CAROLINA Water Quality
ogN Permitting Section
TABLE OF CONTENTS
Page
raN TABLE OF CONTENTS ii
LIST OF TABLES
LIST OF FIGURES iii
`` LIST OF APPENDICES iii
1.0 INTRODUCTION 1
tok-
2.0 METHODS 2
rair 2.1 Sampling Stations 2
2.2 Species Selection 8
2.3 Sample Collection Methodology 8
2.4 Sample Preparation and Shipment 11
2.5 Chemical Analysis 12
3.0 RESULTS AND DISCUSSION 13
3.1 Fish Collection 13
, 3.2 Tissue Analyses 13
tots
f",
041
REFERENCES 22
ii

Sample ID: Comp#2 Site 1 Bluegill TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_002
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
QC Batch No.: 12595
Date Collected: 25-Aug-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 07-Oct-2014 19:20
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
(0.059)
0.059
(0.059)
(0.059)
(0.059)
12378-PeCDD
(0.0478)
0.0478
(0.0239)
(0.0478)
(0.0478)
123478-HxCDD
(0.0376)
0.0376
(0.00376)
(0.00376)
(0.00376)
123678-HxCDD
[0.0764]
J
0.0415
[0.00764]
[0.00764]
[0.00764]
123789-HxCDD
[0.0995]
J B
0.0406
[0.00995]
[0.00995]
[0.00995]
1234678-HpCDD
0.105
J B
0.0556
0.00105
0.00105
0.00105
OCDD
0.357
J B
0.113
0.000357
0.0000357
0.000107
2378-TCDF
[0.0609]
J
0.0373
[0.00609]
[0.00609]
[0.00609]
12378-PeCDF
(0.0352)
0.0352
(0.00176)
(0.00176)
(0.00106)
23478-PeCDF
(0.0397)
0.0397
(0.0199)
(0.0199)
(0.0119)
123478-HxCDF
(0.035)
0.035
(0.0035)
(0.0035)
(0.0035)
123678-HxCDF
(0.0309)
0.0309
(0.00309)
(0.00309)
(0.00309)
234678-HxCDF
(0.0305)
0.0305
(0.00305)
(0.00305)
(0.00305)
123789-HxCDF
(0.0418)
0.0418
(0.00418)
(0.00418)
(0.00418)
1234678-HpCDF
0.0503
J B
0.0296
0.000503
0.000503
0.000503
1234789-HpCDF
(0.0477)
0.0477
(0.000477)
(0.000477)
(0.000477)
OCDF
(0.106)
0.106
(0.000106)
(0.0000106)
(0.0000318)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.00191
0.00159
0.00166
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.0692
0.0808
0.0766
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.137
0.16
0.151
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
SGS
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.0256
0.0869
0.148
0.0253
0.0985
0.172
0.0253
0.0943
0.163
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 196-361-QRH
SGS Environmental Services - D/F 2014 Rev. 4.31

Sample ID: Comp#2 Site 1 Bluegill Method 1613B
Client Data
Sample Data
Laboratory Data
Name: CZR Incorporated
Matrix:
Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
Weight/Volume: 10.03 g
Lab Sample ID A7174_12595_DF_002
Date Extracted: 02-Oct-2014
Date Collected: 25-Aug-2014
% Lipid: 0.281
QC Batch No: 12595
Date Analyzed: 07-Oct-2014
Split: -
Dilution: -
Time Analyzed: 19:20:11
Analyte
Conc. (pglg)
DL (pg/g)
EMPC (pg/g)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD
ND
0.059
ES 2378-TCDD
87.2
12378-PeCDD
ND
0.0478
ES 12378-PeCDD
89.4
123478-HxCDD
ND
0.0376
ES 123478-HxCDD
89.9
123678-HxCDD
EMPC
0.0764
J
ES 123678-HxCDD
80.6
123789-HxCDD
EMPC
0.0995
J B
ES 123789-HxCDD
84
1234678-HpCDD
0.105
J B
ES 1234678-HpCDD
78.7
OCDD
0.357
J B
ES OCDD
63.9
2378-TCDF
EMPC
0.0609
J
ES 2378-TCDF
89.8
12378-PeCDF
ND
0.0352
ES 12378-PeCDF
94.4
23478-PeCDF
ND
0.0397
ES 23478-PeCDF
85.6
123478-HxCDF
ND
0.035
ES 123478-HxCDF
82.2
123678-HxCDF
ND
0.0309
ES 123678-HxCDF
83
234678-HxCDF
ND
0.0305
ES 234678-HxCDF
91.7
123789-HxCDF
ND
0.0418
ES 123789-HxCDF
82.3
1234678-HpCDF
0.0503
J B
ES 1234678-HpCDF
78.7
1234789-HpCDF
ND
0.0477
ES 1234789-HpCDF
81.3
OCDF
ND
0.106
ES OCDF
60
Totals
'Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
97.2
Total TCDD
ND
0.059
ND
CS 12347-PeCDD
99.1
Total PeCDD
ND
0.0478
ND
CS 12346-PeCDF
99.2
Total HxCDD
ND
0.176
CS 123469-HxCDF
89.8
Total HpCDD
0.105
0.204
CS 1234689-HpCDF
88.2
AS 1368-TCDD
87.8
Total TCDF
ND
0.122
AS 1368-TCDF
87.9
Total PeCDF
0.0788
0.0788
Total HxCDF
ND
0.0341
ND
Total HpCDF
0.0503
0.0503
Total PCDD/Fs
0.591
0.989
WHO-2005 TEQs
TEQ: ND=0
0.00166
0.0253
5500 Business Drive
TEQ: ND=DU2
TEQ: ND=DL
0.0766
0.152
0.0754
0.151
0.0943
0.163
SGS1
Wilmington, NC 28405, USA
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 196-361-QRH
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 09:59 Analyst: AC

Sample ID: Comp#1 Site 1 Bluegill TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_001
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
QC Batch No.: 12595
Date Collected: 25-Aug-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 07-Oct-2014 18:26
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
(0.0453)
0.0453
(0.0453)
(0.0453)
(0.0453)
12378-PeCDD
(0.0606)
0.0606
(0.0303)
(0.0606)
(0.0606)
123478-HxCDD
[0.114]
J
0.0448
[0.0114]
[0.0114]
[0.0114]
123678-HxCDD
(0.0486)
0.0486
(0.00486)
(0.00486)
(0.00486)
123789-HxCDD
0.141
J B
0.0461
0.0141
0.0141
0.0141
1234678-HpCDD
[0.204]
J B
0.061
[0.00204]
[0.00204]
[0.00204]
OCDD
1.52
J B
0.121
0.00152
0.000152
0.000457
2378-TCDF
(0.03)
0.03
(0.003)
(0.003)
(0.003)
12378-PeCDF
(0.0405)
0.0405
(0.00203)
(0.00203)
(0.00122)
23478-PeCDF
(0.0427)
0.0427
(0.0214)
(0.0214)
(0.0128)
123478-HxCDF
(0.0397)
0.0397
(0.00397)
(0.00397)
(0.00397)
123678-HxCDF
(0.0406)
0.0406
(0.00406)
(0.00406)
(0.00406)
234678-HxCDF
(0.0378)
0.0378
(0.00378)
(0.00378)
(0.00378)
123789-HxCDF
(0.0516)
0.0516
(0.00516)
(0.00516)
(0.00516)
1234678-HpCDF
[0.0531]
J B
0.026
[0.000531]
[0.000531]
[0.000531]
1234789-HpCDF
(0.0405)
0.0405
(0.000405)
(0.000405)
(0.000405)
OCDF
0.178
J B
0.121
0.000178
0.0000178
0.0000534
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.0158
0.0143
0.0146
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.0806
0.0942
0.0899
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.145
0.174
0.165
www.us.sgs.com
EMPC = 0, < J-Ievel = 0
0
0
0
SGS
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.0298
0.0919
0.154
0.0283
0.106
0.183
0.0286
0.101
0.174
I
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 131-371-SPZ
SGS Environmental Services - D/F 2014 Rev. 4.31
(((((((((((((((((f ((((((((((((((((( ((((( r 4 f

C C C C C C C C CC C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C
Sample ID: Comp#1 Site 1 Bluegill Method 1613B
Client Data
CZR Incorporated
2014 Annual Fish Project
25-Aug-2014
Sample Data
Tissue
10.03 g
0.268
-
Laboratory Data
Date Received: 30-Sep-2014
Date Extracted: 02-Oct-2014
Date Analyzed: 07-Oct-2014
Time Analyzed: 18:26:54
Name:
Project ID:
Date Collected:
Matrix:
WeightNolume:
% Lipid:
Split:
Lab Project ID: A7174
Lab Sample ID A7174_12595_DF_001
QC Batch No: 12595
Dilution: -
Analyte
Conc. (pg/g)
DL (pg/g)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
ND
ND
EMPC
ND
0.141
EMPC
1.52
ND
ND
ND
ND
ND
ND
ND
EMPC
ND
0.178
0.0453
0.0606
0.0486
0.03
0.0405
0.0427
0.0397
0.0406
0.0378
0.0516
0.0405
0.114
0.204
0.0531
J
J B
J B
J B
J B
J B
ES 2378-TCDD
ES 12378-PeCDD
ES 123478-HxCDD
ES 123678-HxCDD
ES 123789-HxCDD
ES 1234678-HpCDD
ES OCDD
ES 2378-TCDF
ES 12378-PeCDF
ES 23478-PeCDF
ES 123478-HxCDF
ES 123678-HxCDF
ES 234678-HxCDF
ES 123789-HxCDF
ES 1234678-HpCDF
ES 1234789-HpCDF
ES OCDF
79.2
76.5
79.7
70
73
72.2
58
81
79.1
73.6
73.3
72.8
81.5
73.2
73.2
74.1
54.1
Totals
Standard
CS/AS Recoveries
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
0.141
0.24
ND
ND
ND
ND
0.0453
0.0606
0.03
0.0415
0.042
ND
ND
0.256
0.443
ND
ND
ND
0.103
CS 37CI-2378-TCDD
CS 12347-PeCDD
CS 12346-PeCDF
CS 123469-HxCDF
CS 1234689-HpCDF
AS 1368-TCDD
AS 1368-TCDF
99.1
94.7
94.3
92.2
95.7
90.3
89.2
Total PCDD/Fs
2.08
2.5
WHO-2005 TEQs
TEQ: ND=O
TEQ: ND=DL/2
TEQ: ND=DL
0.0146
0.0899
0.165
0.0776
0.155
0.0286
0.101
0.174
SGS1
5500 Business Drive
Wilmington, NC 28405, USA
www.us.sgs.com
[phone]; Toll -Free 866 846-8290
Tel:
Checkcode: 131-371-SPZ
SGS Environmental Services - DIF 2014 Rev. 4.31
Report Created: 09-Oct-2014 09:58 Analyst: AC

)))))))))))))))))))))))))))))))))))))))))))
100
90 -
80 -
70
60
u
cc 50
40
30 -
0
Mean Recoveries of Clean -Up Standards (N=14)
Project ID: 2014 Annual Fish Project
A7174
O"1'
Mean Std. Dev.

) ) ) ) ) ) ) 1 ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ))))) ))) ) ) )
90
80 .,.
70 •
60
50 \ \
Mean Recoveries of Extraction Standards (N=14)
Project ID: 2014 Annual Fish Project
A7174
oti
cc
0
40
30
20
10 \ \ \
ti°C1- 9,
4
Mean Std. Dev.
N.

) ) ) )) ) ) ) )) )) ) ) ) ) ) )) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) )
Totals Total PCDD/Fs (ND=0; EMPC=0)
Project ID: 2014 Annual Fish ProjecrotalPCDD/Fs(ND=O;EMPC=EMPC)
A7174
25
20
15 A
10
5
1/
o
N Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC)
Q p1
19
ene
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0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
WHO-2005-TEQ
Project ID: 2014 Annual Fish Project
A7174
M 11
i
i
i
0
0
yr cQ•
OJ0, a�` o 0, OJey.
e C c
e
oat`ac C �� C �Q Q��\ P 5" C.°fie
0 0
4\e `oF G �QA
0
�yph �Je�\\
ND=0; EMPC=0
ND=0; EMPC=EMPC
ND=DL/2; EMPC=O
• ND=DL/2; EMPC=EMPC
ND=DL; EMPC=EMPC
NJ,��J OQ'Ca o Ca
cb¢°ti�i°
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n)4 FySO Q� A. ° (o sti4~
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�`o
co of

A7174 - Totals
Project ID: 2014 Annual Fish Project
Sample Summary SG! Method 1613B
Part 2
Method
Comp#1
Comp#2
Comp#3
Comp#4
Site 1
Comp#5
Comp#6
Comp#7
Comp#8 8
p2
Comp#9
Comp#10
Comp#11
CSitep#312
Comp#13
Analyte
Blank
A7174 1259
Site 1
Bluegill
Site 1
Bluegill
Site 1 Blue
Catfish
Common
Cam
Site 2
Bluegill
Site 2
Blueglll
Site 2 Blue
Catfish
Common
Cara
Site 3
Blueglll
Site 3
Blueglll
Site 3 Blue
Catfish
Common
earn
Site 1 Blue
Catfish
pglg
p919
Pglg
Pglg
pg/g
Pglg
Pglg
P9lg
P919
P9ig
Pglg
Pglg
NY!
Pg/9
Totals
TCDDs
0
0
0
0.0888
0.537
0
0
0.0759
0
0
0
0
0.227
0.18
PeCDDs
0
0
0
0.131
0.243
0
0
0
0.147
0
0
0
0
0
HpCDDs
0
0.141
0
0.0965
1.35
0.128
0
0.285
0.449
0.127
0
0.545
0.775
1
HpCDDs
0.139
0.24
0.105
0.773
3.15
0.351
0.167
0.801
1.26
0.109
0.167
0.924
1.79
1.57
QCDD
0.846
1.52
0.357
2.51
15.8
1.27
0.584
1.95
4.85
0.422
0.582
2.23
6.4
5.55
TCDFs
0
0
0
0.0797
0.363
0
0
0
0.127
0
0
0
0.101
0.18
PeCDFs
0
0
0.0788
0.165
0.445
0
0.0607
0
0.108
0
0
0.0709
0.112
0.381
HxCDFs
0
0
0
0
0.343
0
0
0.071
0.136
0
0.0664
0.0425
0
0.114
HpCDDs
0
0
0.0503
0
0
0.0509
0
0
0.0803
0
0
0.0561
0.114
0.293
OCDF
0.182
0.178
0
0
0
0.181
0
0.336
0
0
0
0
0
0
Total PCDDIFs (ND=0; EMPC-0)
1.17
2.08
0.591
3.85
22.2
1.98
0.812
3.52
7.17
0.658
0.816
3.86
9.52
9.27
Total PCDDIFs (NDsO; EMPC-EMPC)
1.51
2.5
0.989
4.6
23.2
1.98
0.964
4.37
7.58
0.738
1.15
4.03
10.3
10.1
Total PCDDWFs (2378•X ND-DL; EMPC■EMPC)
2.09
2.98
1.5
4.98
23.4
2.52
1.74
4.41
7.96
1.42
1.92
4.53
10.7
10.4
Total 23785 (ND-0; EMPC-0)
1.17
1.84
0.513
3.71
21.1
1.86
0.751
3.37
6.94
0.658
0.816
3.67
9.09
8.87
Total 2378s (ND-0.5; EMPC-0)
1.51
2.15
0.828
4.04
21.3
2.13
1.2
3.62
7.2
1.03
1.26
3.98
9.38
9.03
Total 2378s (ND-1; EMPC■0)
1.86
2.45
1.14
4.37
21.5
2.4
1.65
3.88
7.45
1.41
1.71
4.3
9.66
9.19
Total 2378s (1,1134; EMPC-1)
1.41
2.21
0.749
4.23
21.5
1.86
0.903
4.22
7.22
0.738
1.02
3.84
9.5
9.05
Total 2378s (ND40.5; EMPC-1)
1.7
2.45
1
4.41
21.6
2.13
1.29
4.24
7.41
1.08
1.4
4.09
9.7
9.18
Total 2378s (ND-1; EMPC.1)
1.99
2.69
1.26
4.6
21.7
2.4
1.68
4.26
7.6
1.42
1.79
4.34
9.9
9.31
Checkcode
920-465-YCD
131-371-SPZ
196-361-QRH
107-824-WZP
128-860-B13K
906-864-PJY
232-687-RSH
675-218-0FW
446.588-ZCJ
727-826-GTX
264-816-QSX
723-046-SJC
730-995-LMN
877-284-LYV
Lab ID
1411_12595_DF_$0$
67174_12506_0F_001
57174 12596_DF_002
A7/74 12596_0F 003
A7/7412596_OF_OO4
A7174_12506_0F_006_A7174
12595_0f 006
A7174_12596 OF 007
A7174_12596-0F006
A7174_12595 OF_009
A7174_12595 OF 010
A7174 12595_DF 011
A7174 12506_DF 012
A7174_12506_DF_013
=DL
(J=EMPC

A7174 - Others
Project ID: 2014 Annual Fish Project
Sample Summary
Part 3
GS1
Method 1613B
Analyte
Method
Blank
A7174_1259
S
pglg
Comp#1
Site 1
Bluegill
pgig
Comp#2
Site 1
Bluegill
pg/g
Comp#3
Site 1 Blue
Catfish
pglg
Comp#4
Site 1
Common
Cam
pglg
Comp#5
Site 2
Bluegill
pg/g
Comp#6
Site 2
Bluegill
pglg
Comp#7
Site 2 Blue
Catfish
pglg
Comp#8
Site 2
Common
Cam
pglg
Comp#9
Site 3
Bluegill
pglg
Comp#10
Site 3
Bluegill
pglg
Comp#11
Site 3 Blue
Catfish
p9l9
Comp#12
Site 3
Common
Cam
pglg
Comp#13
Site 1 Blue
Catfish
pglg
Other PCDD/Fs (NDsO, EMPC■O)
Other TCDD
0
0
0
0
0.384
0
0
0
0
0
0
0
0.227
0.0824
Other PeCDD
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Other HxCDD
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Otter HpCDD
0
0.24
0
0
0
0.125
0
0.146
0.15
0
0
0.153
0.0984
0
Other TCDF
0
0
0
0.0797
0.143
0
0
0
0
0
0
0
0.101
0.0846
Other PeCDF
0
0
0.0788
0.0508
0.21
0
0.0607
0
0
0
0
0
0
0.231
Other HxCDF
0
0
0
0
0.343
0
0
0
0.0729
0
0
0.0425
0
0
Otter HpCDF
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Other PCDDIF5 (ND=0, EMPCsEMPC)
Other TCDD
0
0
0
0
0.384
0
0
0
0.0697
0
0
0
0.227
0.0824
Other PeCDD
0
0
0
0
0
0
0
0
0
0
0
0
0
0.0671
Other HxCDD
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Other HpCDD
0.1
0.24
0.0993
0.144
0.155
0.125
0
0.146
0.15
0
0.129
0.153
0.0984
0.17
Other TCDF
0
0
0.0613
0.0797
0.22
0
0
0
0
0
0
0
0.101
0.25
Other PeCDF
0
0
0.0788
0.0971
0.44
0
0.0607
0
0
0
0
0
0.146
0.274
Otter HxCDF
0
0
0
0
0.343
0
0
0
0.0729
0
0
0.0425
0.124
0.176
Other HpCDF
0
0.0504
0
0.0582
0.111
0
0
0
0.0679
0
0
0
0.0725
0.0634
Checkcode
920-465-YCD
131-371-SPZ
196.361-QRH
107-824-WZP
128-860-BBK
906-864-PJY
232.687-RSH
675-218-QFW
446-588-ZCJ
727-826-GTX
264-816.0SX
723-046-SJC
730-995-LMN
877-284-LW
Lab ID
M01.12$95_DF_SOS
A7174_12596_0F 001
A7174_12505DF 002
A7174_1259 OF_003
A7171_12595 OF_004
A7174_12596_0F005
A7174 12595,0E 006
A7174 12595 OF_007
A7174_12595_0f_C06
A7174_12595_DF_009
A7174_12595Of 010
A7174_12595 Df 011
A7174_ 12595,0E 012
117174_12595_DF 013
(I=DL
[ ] EMPC

A7174 - TEQ
Project ID: 2014 Annual Fish Project
Sample Summary
1
SGPart
Method 1613B
Analyte
Method
Blank
A7174_1259
5
P919
Comp#1
Site 1
Bluegill
P9/9
Comp#2
Site 1
Bluegili
P9l9
Comp#3
Site 1 Blue
Catfish
pg/g
Camp#4
Site 1
Common
ram
pg/g
Comp#5
Site 2
Bluegitl
pg/g
Comp#6
Site 2
Bluegill
pg/g
Comp#7
Site 2 Blue
Catfish
pg/g
Comp#8
Site 2
Common
('arn
pg/g
Comp#9
Site 3
Blueglll
pg/g
Comp#10
Site 3
Bluegili
149
Comp#11
Site 3 Blue
Catfish
pg/g
Comp#12
Site 3
Common
Corn
pg/g
Comp#13
Site 1 Blue
Catfish
pg/g
2,3,7,8-TCDD
(0.0496)
(0.0453)
(0.059)
0.0888
0.153
(0.0597)
(0.0518)
0.0759
[0.0932]
(0.0612)
(0.0613)
[0.0597]
[0.0813]
0.0972
1,2.3,7.8-PeCDD
(0.0619)
(0.0606)
(0.0478)
0.131
0.243
(0.0642)
(0.068)
[0.0936]
0.147
(0.0688)
(0.093)
[0.109]
[0.112]
[0.181]
1,2,3,4,7.8•11XCDD
(0.0576)
[0.114]
(0.0376)
0.0965
0.271
(0.0431)
(0.0495)
(0.0838]
0.153
(0.0512)
(0.06)
(0.0672)
0.127
0.182
1.2,3,6.7.8•HxCDD
(0.0658)
(0.0486)
[0.0764]
[0.211]
0.706
(0.0461)
[0.0611]
0.285
0.296
(0.0608)
[0.065]
0.298
0.412
0.487
1,2,3.7,8,9-HxCDD
10.176]
0.141
[0.0995]
[0.155]
0.372
0.128
[0.0911]
[0.206]
[0.182]
0.127
[0.135]
0.247
0.236
0.33
1,2,3.4.6,7.8-HpCDD
0.139
[0.204]
0.105
0.773
3.15
0.226
0.167
0.656
1.11
0.109
0.167
0.771
1.69
1.57
OCDD
0.846
1.52
0.357
2.51
15.8
1.27
0.584
1.95
4.85
0.422
0.582
2.23
6.4
5.55
2,3,7,8-TCDF
(0.0455)
(0.03)
[0.0609]
[0.042]
0.22
(0.0409)
(0.0348)
(0.0354)
0.127
(0.046)
(0.0474)
(0.0464)
[0.179]
0.0955
1.2,3,7,8-PeCDF
(0.0366)
(0.0405)
(0.0352)
(0.0375)
(0.0378)
(0.0295)
(0.0358)
[0.0459]
(0.0393)
(0.0367)
(0.0465)
(0.0368)
(0.0377)
(0.0389)
2,3,4,7.8-PeCDF
(0.042)
(0.0427)
(0.0397)
0.114
0.234
(0.0369)
(0.0413)
[0.0825]
0.108
(0.0428)
(0.0542)
0.0709
0.112
0.15
1,2,3,4.7.8-HxCDF
(0.0411)
(0.0397)
(0.035)
(0.0388)
[0.0652]
(0.037)
(0.0306)
[0.0473]
(0.0485)
(0.04)
(0.0389)
(0.036)
(0.039)
(0.0333)
1,2,3,6,7,8-HxCDF
(0.0401)
(0.0406)
(0.0309)
(0.04)
[0.0575]
(0.0365)
(0.0284)
[0.0502]
(0.0481)
(0.0363)
(0.0398)
(0.0342)
(0.0384)
0.0535
2.3.4,6.7.8•HxCOF
(0.0356)
(0.0378)
(0.0305)
[0.035]
[0.103]
(0.0357)
(0.0317)
[0.0572]
0.0626
[0.0465]
0.0664
(0.0296)
[0.0422]
0.0608
1,2.3,7.8.9•HxCDF
(0.0524)
(0.0516)
(0.0418)
(0.0448)
(0.0333)
(0.0518)
(0.0419)
0.071
(0.0644)
(0.0476)
(0.0566)
(0.0447)
(0.0501)
(0.0419)
12,3,4,6,7.8•HpCDF
[0.0661]
[0.0531]
0.0503
[0.0681]
[0.151]
0.0509
(0.054)
[0.105]
0.0803
(0.0333]
(0.0489)
0.0561
0.114
0.293
1,2,3,4,7,8,9•HpCDF
(0.0576)
(0.0405)
(0.0477)
(0.0457)
(0.0501)
(0.0579)
(0.0924)
[0.0834]
(0.0571)
(0.0495)
(0.0751)
(0.064)
(0.0524)
(0.0489)
OCDF
0.182
0.178
(0.106)
(0.166)
(0.104)
0.181
(0.219)
0.336
(0.128)
(0.14)
(0.155)
(0.144)
(0.176)
(0.0942)
WHO.2005 TEQ (N1:0-0; EMPC-O)
0.0017
0.0146
0.00166
0.272
0.66
0.0161
0.00185
0.119
0.257
0.014
0.00849
0.0847
0.131
0.283
WHO.2005 TEQ (ND=0; EMPC.EMPC)
0.02
0.0286
0.0253
0.317
0.684
0.0161
0.0171
0.285
0.368
0.0189
0.0285
0.253
0.346
0.465
WHO-2005 TEQ (ND=DLJ2; EMPC=0)
0.085
0.0899
0.0766
0.292
0.667
0.0988
0.086
0.171
0.301
0.102
0.113
0.161
0.193
0.32
WHO.2005 TEQ (N0=0L12; EMPC.EMPC)
0.0998
0.101
0.0943
0.324
0.687
0.0988
0.0953
0.287
0.377
0.105
0.127
0.267
0.354
0.469
WHO-2005 TEQ (NO=DL; EMPC.EMPC)
0.18
0.174
0.163
0.331
0.689
0.182
0.174
0.288
0.386
0.192
0.226
0.281
0.361
0.474
Checkcode
920-465-YCD
131-371-SPZ
196-361•QRH
107-824-WZP
128-860-BBK
906-864-PJY
232-687-RSH
675-218-QFW
446.588-ZCJ
727-826-GTX
264-816-QSX
723-046-SJC
730-995-LMN
877.284-LW
Lab ID
1481_12595_DF SOS
A7174_12596 OF 001
A717/ 12595_OF_000
A7174_ 12505_DF_003
A7174_12506_DF_004
A7174 12585_DF O05
A7174_ 12595 ON
A7174 12595_DF 007
A7174_12505_DF_00e
117174_125%OF_009
A7174_12595_DF_OtO
A7174 12595_DF 011
A7174_ 1256S_OF 012
A7174 12595_OF 013
()=DL
( -EMPC

SGS CERTIFICATIONS
Arkansas
88-0682
California (ELAP)
Interim ELAP Cert #2914
CLIA
34D1013708
Connecticut
PH-0258
USDA Soil Permit
P330-14-00135
DoD
2726.01
Florida (Primary NELAP)
E87634
ISO 17025/IEC
2726.01
Louisiana
4115
Maine
#2014020
Massachusetts
M-NC919
Minnesota (Primary NELAP For Method 23)
Lab #037-999-459 Cert #688823
New Jersey
NC100
New York
11685
North Carolina DWR
481
North Dakota
R-197
Oregon
NC200002
Pennsylvania
68-03675
South Carolina
Lab #99029 Cert #99029002
Texas
T104704260-13-5
US Coast Guard
16714/159.317/SGS
Virginia
Lab #460214 Cert #3006
Washington
C913
West Virginia
293
Rev. 04-Sep-2014
Page 5 of 5

SG-41
APPENDIX A: GENERAL DATA QUALIFIERS / DATA ATTRIBUTES
r
rseN
(Iwt
rit1
erig
ex)
/1
B
The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the
sample.
C
Two or more congeners co -elute. In EDDs, C denotes the lowest IUPAC congener in a co -elution group and
additional co-eluters for the group are shown with the number of the lowest IUPAC co-eluter.
E
The reported concentration exceeds the calibration range (upper point of the calibration curve) and is an estimated
value.
EMPC
Represents an Estimated Maximum Possible Concentration. EMPCs arise in cases where the signal/noise ratio is
not sufficient for peak identification (the determined ion -abundance ratio is outside the allowed theoretical range),
or where there is a co -eluting interference.
H/h
If the standard recovery is below the method or SOP specified value "H" is assigned. If the obtained value is less
than half the specified value "h" is assigned.
J
Indicates that an analyte has a concentration below the reporting limit (lowest point of the calibration curve) and is
an estimated value.
ND
Indicates a non -detect.
NR or R
Indicates a value that is not reportable.
1
PR
Due to interference, the associated congener is poorly resolved.
QI
Indicates the presence of a quantitative interference.
SI
Denotes "Single Ion Mode" and is utilized for PCBs where the secondary ion trace has a significantly elevated
noise level due to background PFK. Responses for such peaks are calculated using an EMPC approach based
solely on the primary ion area(s) and may be considered estimates.
U
The analyte was not detected. The estimated detection limit (EDL) may be reported for this analyte.
V
The labeled standard recovery was found to be outside of the method control limits.
esbs
Page 3 of 5

SG$
APPENDIX B: DRBC/TMDL SPECIFIC DATA QUALIFIERS / DATA ATTRIBUTES
J
The reported result is an estimate. The value is Tess than the minimum calibration level but greater than the
estimated detection limit (EDL).
U
The analyte was not detected in the sample at the estimated detection limit (EDL).
E
The reported concentration is an estimate. The value exceeds the upper calibration range (upper point of the
calibration curve).
D
Dilution Data. Result was obtained from the analysis of a dilution.
B
Analyte found in the sample and associated method blank.
C
Co -eluting congener
Cxx
Co -elutes with the indicated congener, data is reported under the lowest IUPAC congener. `Xx' denotes the
IUPAC number with the lowest numerical designated congener.
NR
Analyte is not reportable because of problems in sample preparation or analysis.
V
Labeled standard recovery is not within method control limits.
X
Results from re-injection/repeat/second-column analysis.
EMPC
Estimated maximum possible concentration. Indicates that a peak is identified but did not meet the method
specified ion -abundance ratio.
APPENDIX C: LAB IDENTIFIERS
AR
Indicates use of the archived portion of the sample extract.
CU
Indicates a sample that required additional clean-up prior to MS injection/processing.
D
Indicates a dilution of the sample extract. The number that follows the "D" indicates the dilution factor.
DE
Indicates a dilution performed with the addition of ES (extraction standard) solution.
DUP
Designation for a duplicate sample.
MS
Designation for a matrix spike.
MSD
Designation for a matrix spike duplicate.
RJ
Indicates a reinjection of the sample extract.
S
Indicates a sample split. The number that follows the "S" indicates the split factor.
Page 4 of 5

sG$
rot)
10 OCTOBER 2014
(;ik
)
tiwN
f Dear Sam;
tot)
f'1
i
SAM COOPER
CZR INCORPORATED
Suite 2,
4709 College Acres Dr.
Wilmington, NC 28403
t. 910 392 9253
e. scooDer(a�czr-inc.com
SUBJECT: CERTIFICATE OF RESULTS
Attached to this narrative are the analytical results for sample(s) submitted for the determination of polychlorinated dibenzo-p-
dioxins and polychlorinated dibenzofurans. The insert below summarizes information about the project. If applicable, QC
annotations below highlight specific analytical observations and assessments made during the sample handling and data
interpretation phases.
Results reported relate only to the items tested.
PROJECT INFORMATION SUMMARY (When applicable, see QC Annotations for details)
Client Project
IP, 2014 Annual Fish Project
SGS Project #
A7174
Analytical Protocol(s)
Method 1613B
No. Samples Submitted
13 fish composites
Additional QC Sample(s)
0
No. Laboratory Method Blanks
1
No. OPRs / Batch CS3
1
Date Received
30-Sep-14
Condition Received
good
Temperature upon Receipt (°C)
-6
Extraction within Holding Time
yes
Analysis within Holding Time
yes
SGS Environmental Services
5500 Business Drive Wilmington, NC 28405 [phone] I [phone] www.sgs.com
Member of the SGS Group (SGS SA)

SG$
QC ANNOTATIONS:
1. Please see Appendices attached for data qualifier/attribute and lab identifier descriptions which may be contained
in the project.
SGS remains committed to serving you in the most effective manner. Should you have any questions or need additional
information and technical support, please do not hesitate to contact us.
The management and staff of SGS welcomes customer feedback, both positive and negative, as we continually improve our
services. Please visit our web site at www.sgs.com/ultratrace and click on the 'Email Us' Zink or go to our survey here. Thank you
for choosing SGS.
All services are rendered in accordance with the applicable SGS General Conditions of Service accessible
via: http://www.sgs.com/terms and conditions.htm.
Sincerely,
Amy J. Boehm
Senior Project Manager
Page 2 of 5

) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) )
ngcncr data (pg/g and TEF TEQ) by sample analyzed for 2014 study. Sec Figure 2-1 for sampling station locations in the Cape Fear River Values for TEFs arc WHO mammalian factors from Van den Berg et al.. 2006.
Composite
1
2
3
4
5
6
7
8
9
Station
1
1
1
1
2
2
2
2
3 __
BG
Species
WIR).
lit,
BG
BC
CC
BG __
BG
BC
CC
_
SGS
Lab
111.
St is
SGS
SGS
SGS
SGS
SGS
SGS
SGS
Units
pg/g
11:Q
pg/g
TEQ
pgl8
TEQ
pg/g
TEQ
pg/g
TEQ
p8/8
TEQ
pglg
TEQ
pg/g
TEQ
p8/8
TEQ
TCDD
0.00
2.3.7,8-TCDD
1.0
ND(0.05)
0.00
ND(0.06)
0.00
0.09
0.09
0.15
0.1 i
ND(0.06)
0.00
ND(0.05)
0.00
0.08
0.08
EMPC(0.09)
0.09
ND(0.06)
PcCDD
0.00
1,2,3,7,8-PcCDD
ND(0.06)
0.00
ND(0.05)
0.00
0.13
0.13
0.24
0.2.1
ND(0.06)
0.00
ND(0.07)
0.00
EMPC(0.09)
0.09
0.15
0.15
ND(0.07)
HxCDD
0.00
1,2,3,4,7,8-11xCDD
0.1
EMPC(0.1I)
0.01
ND(0.04)
0.00
0.10
0.01
0.27
0.03
ND(0.04)
0.00
ND(0.05)
0.00
EMPC(0.08)
0.01
0.15
0.02
ND(0.05)
1,2,3,6,7,8-HxC➢D
0.1
ND(0.05)
0.00
EMPC(0.08)
0.01
EMPC(0.21)
0.02
0.71
0.07
ND(0.05)
0.00
EMPC(0.06)
0.01
0.29
0.03
0.30
0.03
ND(0.06)
0.00
0.01
1,2,3,7,8,9-HxCDD
0.1
0.14
0.01
EMPC(0.10)
0.01
EMPC(0.16)
0.02
0.37
0.04
0.13
0.01
EMPC(0.09)
0.01
EMPC(0.21)
0.02
EMPC(0.18)
0.02
0.13
HpCDD
1.2,3,4,6,7,8-HpCDD
0.01
EMPC(0.20)
0.00
0.11
0.00
0.77
0.01
3.15
0.03
0.23
0.00
0.17
0.00
0.66
0.01
1.11
0.01
0.11
0.00
OCDD
0.0003
1.52
0.00
0.36
0.00
2.51
0.00
15.80
0.00
1.27
0.00
0.58
0.00
1.95
0.00
4.85
0.00
0.42
0.00
TCDF
2,3,7,8-TCDF
0.1
ND(0.03)
0.00
EMPC(0.06)
0.01
EMPC(0.04)
0.00
0.22
0.02
ND(0.04)
0.00
ND(0.03)
0.00
ND(0.04)
0.00
0.13
0.01
ND(0.05)
0.00
PCCDF
1,2,3,7,8-PcCDF
0.03
ND(0.04)
0.00
ND(0.04)
0.00
ND(0.04)
0.00
ND(0.04)
0.00
ND(0.03)
0.00
ND(0.04)
0.00
EMPC(0.05)
0.00
ND(0.04)
0.00
ND(0.04)
0.00
2,3.4,7,8-PcCDF
0.3
ND(0.04)
0.00
ND(0.04)
0.00
0.11
0.03
0.23
0.07
ND(0.04)
0.00
ND(0.04)
0.00
EMPC(0.08)
0.02
0.11
0.03
ND(0.04)
0.00
HxCDF
1,2,3,4,7,8-HxCDF
0.1
ND(0.04)
0.00
ND(0.04)
0.00
ND(0.04)
0.00
EMPC(0.07)
0.01
ND(0.04)
0.00
ND(0.03)
0.00
EMPC(0.05)
0.01
ND(0.05)
0.00
ND(0.04)
0.00
1,2,3,6,7,8-HxCDF
0.1
ND(0.04)
0.00
ND(0.03)
0.00
ND(0.04)
0.00
EMPC(0.06)
0.01
ND(0.04)
0.00
ND(0.03)
0.00
EMPC(0.05)
0.01
ND(0.05)
0.00
ND(0.04)
0.00
1,2,3,7,8,9-HxCDF
0.1
ND(0.04)
0.00
ND(0.03)
0.00
EMPC(0.04)
0.00
EMPC(0J0)
0.01
ND(0.04)
0.00
ND(0.03)
0.00
EMPC(0.06)
0.01
0.06
0.01
EMPC(0.05)
0.01
2,3,4,6,7,8-HxCDF
0,1
ND(0.05)
0,00
ND(0.04)
0.00
ND(0.05)
0.00
ND(0.03)
0.00
ND(0.05)
0.00
ND(0.04)
0.00
0.07
0.01
ND(0.06)
0.00
ND(0.05)
0.00
HpCDF
I,2.3,4,6,7,8-HpCDF
0.01
EMPC(0.05)
0.00
0.05
0.00
EMPC(0.07)
0.00
EMPC(0.15)
0.00
0.05
0.00
ND(0.05)
0.00
EMPC(0.11)
0.00
0.08
0.00
EMPC(0.03)
0.00
1.2.3,4,7,8,9-HpCDF
0.01
ND(0.04)
0.00
ND(0.05)
0.00
ND(0.05)
0.00
ND(0.05)
0.00
ND(0.06)
0.00
ND(0.09)
0.00
EMPC(0.08)
0.00
ND(0.06)
0.00
N13(0.05)
0.00
OCDF
0.0003
0.18
0.00
ND(0.11)
0.00
ND(0.17)
0.00
ND(0.10)
0.00
0.18
0.00
ND(0.22)
0.00
0.34
0.00
ND(0.13)
0.00
ND(0.14)
0.00
TOTAL TEO (EMPC =0)
0.01
0.00
0.27
0.66
0.01
0.00
0.12
0.26
0.01
TOTAL TEQ(EMPC=EMPC)
0.02
0.03
031
0.68
0.01
0.02
0.29
0.37
0.02
Legend/Notes: (BC) blue catfish; BG) bluegill sunfish; (CC) common carp; ND(Detcclion Limi ) indicates compound not detected; EMPC(Estitma cd Maximum Possible Concentration) indicates estimated maximum value due to ton ratio failure; Total TEQs cx
Maximum possible Concentrations per EPA Method 1613B.

Table DI. (concluded)
Composite
Location
Species
Lab
WHO-
TEF
10
11
12
13
3
BG
SGS
3
BC
SGS
3
CC
SGS
3
BC - replicate
SGS
Units
pg/g
TEQ
pg/g
TEQ
pg/g
TEQ
pg/g
TEQ
TCDD
2,3,7.8-TCDD
1.0
ND(0.06)
0.00
EMPC(0.06)
0.06
EMPC(0.08)
0.08
0.10
0.10
PeCDD
1,2,3,7,8-PeCDD
1.0
ND(0.09)
0.00
EMPC(0.II)
0.11
EMPC(0.II)
0.11
EMPC(0.18)
0.18
HxCDD
1,2,3,4,7,8-HxCDD
0.1
ND(0.06)
0.00
N13(0.07)
0.00
0.13
0.01
0.18
0.02
I,2,3,6,7,8-HxCDD
0.1
EMPC(0.07)
0.01
0.30
0.03
0.41
0.04
0.49
0.05
1,2,3,7,8,9-HxCDD
0.1
EMPC(0.14)
0.01
0.25
0.03
0.24
0.02
0.33
0.03
HpCDD
1,2,3,4,6,7,8-11pCDD
0.01
0.17
0.00
0.77
0.00
1.69
0.02
1.57
0.02
OCDD
0.0003
0.58
0.00
2.23
0.00
6.40
0.00
5.55
0.00
TCDF
2,3,7,8-TCDF
0.1
ND(0.05)
0.00
ND(0.05)
0.00
EMPC(0.18)
0.02
0.10
0.01
PcCDF
1,2,3.7,8-PcCDF
0.03
ND(0.05)
0.00
ND(0.04)
0.00
ND(0.04)
0.00
ND(0.04)
0.00
2,3,4.7,8-PcCDF
0.3
ND(0.05)
0.00
0.08
0.02
0.11
0.03
0.15
0.05
HxCDF
I,2,3.4.7.8-HxCDF
0.1
ND(0.04)
0.00
ND(0.04)
0.00
ND(0.04)
0.00
ND(0.03)
0.00
1,2,3.6,7,8-HxCDF
0.1
ND(0.04)
0.00
ND(0.03)
0.00
ND(0.04)
0.00
0.05
0.00
1,2,3,7,8,9-HxCDF
0.1
0.07
0.01
ND(0.03)
0.00
EMPC(0.04)
0.00
0.06
0.00
2,3,4,6,7,8-HxCDF
0.1
ND(0.06)
0.00
ND(0.04)
0.00
ND(0.05)
0.00
ND(0.04)
0.00
HpCDF
1,2,3,4,6,7,8-HpCDF
0.01
ND(0.05)
0.00
0.06
0.00
EMPC(0.1I)
0.00
0.29
0.00
1,2,3,4,7.8,9-HpCDF
0.01
ND(0.08)
0.00
ND(0.06)
0.00
ND(0.05)
0.00
ND(0.05)
0.00
OCDF
0.0003
ND(0.I6)
0.00
ND(0.14)
0.00
ND(0.18)
0.00
ND(0.09)
0.00
TOTAL TEQ (EMPC = 0)
0.01
0.08
0.13
0.28
TOTAL TEQ (EMPC = EMPC)
0.03
0.25
0.34
0.46
Legend/Notes: (BC) blue catfish; (BG) btucgill sunfish; (CC) common carp; ND(Dctection Limit) indicates compound not detected; EMPC(Estima cd Maximum Possible Concentration) indicates estimated maximum valuc due to ion ratio failure; Total TEQs exclude Estimatcd
Maximum possible Concentrations per EPA Mcthod 1613B.

APPENDIX D
TOTAL TEQ (WHO TEFS) / SGS LEVEL II ANALYTICAL LAB REPORTS

C Z R 4709 COLLEGE ACRES DRIVE
SUITE 2
A", INC ORPORATED WILMINGTON, NORTH CAROLINA 28403-1725
Ow ENVIRONMENTAL CONSULTANTS TEL[phone]
FAX [phone]
CHAIN OF CUSTODY [e-mail]
TO: SGS Environmental Services FROM: Sam Cooper
Attn: Amy Boehm CZR Incorporated, Suite 2
5500 Business Drive 4709 College Acres Drive
os► Wilmington, NC 28405 Wilmington, NC 28403
- [e-mail]
DATE: 30 September 2014
RE: International Paper Company, Inc., 2014 Annual Fish Project (IP PO# S066133589 to SGS)
TESTS: Analysis of fish tissues for percent lipid (extraction) and 2, 3, 7, 8 TCDD (Dioxin), 2, 3, 7, 8, TCDF
(Furan) with full screen of congeners (Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans)
via EPA Method 1613B.
oak ENCLOSED ITEMS:
Thirteen (13) frozen composite fish tissue (fillets) samples, each fillet wrapped in aluminum foil (dull side toward
fish) and enclosed in labeled "zip -lock" plastic bags. Composites are identified below.
SAMPLE ID #
Composite # Site Species (number of fish fillets)
1 1 Bluegill (10 "A" fillets)
2 1 Bluegill (10 "A" fillets)
3 1 Blue Catfish (10 "A" fillets)
4 1 Common Carp (9 "A" fillets)
5 2 Bluegill (10 "A" fillets)
6 2 Bluegill (10 "A" fillets)
or% 7 2 Blue Catfish (10 "A" fillets)
8 2 Common Carp (2 "A" fillets)
9 3 Bluegill (10 "A" fillets)
r► 10 3 Bluegill (10 "A" fillets)
1 1 3 Blue Catfish ( fillets} 7 V;I,IrkS-SL
12 3 Common Carp (5 "A" fillets) 1 °c'r L0 I t
," 13 1 Blue Catfish - replicate (10 "B" fillets)
/► COMMENTS:
- Send one digital version and two hard copies of the report to Sam Cooper/CZR at the above address. We
also request permission to include the report as an appendix to CZR's report summarizing the 2014
�► collection efforts and results.
- Forward the invoice to International Paper -Riegelwood, Shared Services, P.O. Box 792, Milford, OH
45150
■►, - A detailed fish composite data table is also enclosed.
2 ?/ �/yam
Relinquished by: b�
ate/time
9%/iq i�;o
Received by: Date/time
(c)o
CZR CP# 1340.22
2151 Alternate Al A South • SUITE 2000 • JUPITER, FLORIDA 33477-3902
TEL [phone] • FAX [phone] • [e-mail] • www.CZRINC.com

APPENDIX C
LETTER OF TRANSMITTAL/CHAIN OF CUSTODY

RENEW
North Carolina Division of Marine Fisheries
Proof of Purchase
: Scientific or Educational Collection Permit : Permit Number 707778
KIermit Number : 707778
PffiRermit Year : 2014
NC Residency :
Qualifying Product :
Sales Outlet : DMF Morehead City Office
Terminal Number : SEBAY
1'Nffective Date/rime : 01/01/2014 00:00 Fee : 0.00
Expiration Date/rime : 12/31/2014 23:59 Status : Active
ssue Date/rime : 12/10/2013 I10:17 Status Date : 12/10/2013
PuNtriction Type :
pne;STRICT TO
art Time:
mments:
regicsstriction Type :
.STRICT TO
ate:
..trt Time: End Time:
mments: _
._.striction Type : Gear Code :
esKSTRICT TO Gear Quantity :
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
tot)
t tme :
'trt Time:
„komments:
. friction Type :
STRICT TO
End Time:
e:
f .art Time: End Time:
,mments: UNNAMED TRIBUTARIES TO DURHAM CREEK,BEAUFORT COUNTY, NC
-
..striction Type : Gear Code : Species Group : Water Body :
,STRICT TO Gear Quantity : Species Quantity : 0210020000-WELCH
CREEK
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Species Group :
Species Quantity
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0528000000-PAMLICO
RIVER
Water Body :
0528010000-LONG
CREEK
Water Body :
0528350000-DURHAM
CREEK
Water Body :
Species Group :
Species Quantity :
Species Size :
Species Units :
tot\ Gear Units : Species Size :
Species Units :
. atne :
'rt Time:
Lomments:
'"striction Type :
ASTRICT TO
End Time:
Gear Code : Species Group :
Gear Quantity : Species Quantity :
Gear Units : Species Size :
ist.ne : Species Units :
,art Time: End Time:
imments:
eakstriction Type : Gear Code : Species Group : Water Body :
/STRICT TO Gear Quantity : Species Quantity : 1900000000-CAPE
" FEAR RIVER
Gear Units : Species Size :
OK1ne : Species Units :
.,part Time: End Time:
riwpmments_ _
..cstriction Type : Gear Code : Species Group : Water Boy :
*ESTRICT TO Gear Quantity : Species Quantity : 1201020204-WHITEHU
RST CREEK
Gear Units : Species Size :
j ime : Species Units :
art Time: End Time:
Aomments:
Water Body :
0210000000-ROANOKE
RIVER
";1
DMF Morehead City Office, 3441 Arendell St., PO Box 769, Morehead City NC., 28557-0769
SUEANN BAY

North Carolina Division of Marine Fisheries
Proof of Purchase
RENEW : Scientific or Educational Collection Permit : Permit Number 707778
Permit Number : 707778 NC Residency : Sales Outlet : DMF Morehead City Office
Permit Year : 2014 Qualifying Product : Terminal Number : SEBAY
Effective Dateffime : 01/01/2014 00:00
Expiration Date/Time : 12/31/2014 23:59 Status : Active
Issue Date/Time : 12/10/2013 10:17 Status Date : 12/10/2013
Fee : 0.00
Request To Sell?
Issued By:
Authorized to Sell?
Issued Date:
DMF Morehead City Office, 344 I Arendell St., PO Box 769, Morehead City NC., 28557-0769
elk
of•4
f^
es4
t
04
elk
/,
004.
elk
orN
ON
0.4
Pie
0114
014+
014
Oft
00‘
tok
SIJEANN BAY

(1181
rii4ne
.art Time:
,mments:
_.,striction Type :
,STRICT TO
tme :
/14N.rt Time:
L:otnments:
fit‘striction Type
. STRICT TO
Inc :
*art Time:
mmments:
riiiistrietion Type :
..STRICT TO
folk1
one :
.,tart Time:
,imments:
North Carolina Division of Marine Fisheries
Proof of Purchase
RENEW : Scientific or Educational Collection Permit : Permit Number 707778
oLikttermit Number : 707778 NC Residency :
)01,cermit Year : 2014 Qualifying Product :
)ffective DatefTime : 01/01/2014 00:00
:;xpiration Date/Time : 12/31/2014 23:59 Status : Active
e4issue Date/ Time : 12/10/2013 10:17
Status Date : 12/10/2013
Sales Outlet : DMF Morehead City Office
Terminal Number : SEBAY
Fee :
0.00
*striction Type :
::STRICT TO
i..mc:
/"4trt Time:
End Time:
(comments: GEARS OR METHODS: ELECTROFISHING; GILL NETS; FYKE
1 TRAPS
incstriction Type : Gear Code :
iibtSTRICT TO Gear Quantity :
I� Gear Units :
,ze :
$tart Time: End Time:
r�mments: SPECIES: ALL EXCEPT THOSE LISTED AS
striction Type : Gear Code :
STRICT TO Gear Quantity :
Gear Units :
Vie•
...art Time: End Time:
Gear Code :
Gear Quantity :
Gear Units :
lmments:
I.cstriction Type :
I11CSTRICT TO
Gear Code :
Gear Quantity :
Gear Units :
tart Time: End Time:
mments: WATER BODY: PCSI PROJECT AREA II
,gstriction Type : Gear Code :
.STRICT TO Gear Quantity :
Gear Units .
End Time:
End Time:
End Time:
End Time:
•.estriction Type :
STRICT TO
cm1
,,Rime
'art Time:
,omments:
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
NETS; TROT LINES; DIP NETS; TRAWL; SEINE; HOOK AND LINE; FISH
Species Group : Water Body :
Species Quantity :
Species Size :
Species Units :
ENDANGERED OR THREATENED.
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Sizc :
Species Units
Water Body :
0200000000-ALBEMAR
LE SOUND
Water Body :
Water Body :
0535301000-SCOTT
CREEK
Water Body :
0528070201-BAILEY
CREEK
Water Body :
0528370000-SOUTH
CREEK
Water Body :
0528370100-TOOLEY
CREEK
Water Body :
0528360000-HUDDLES
GUT
lakt
DMF Morehead City Office, 3441 Arendell St., PO Box 769, Morehead City NC., 28557-0769
SUEANN BAY

North Carolina Division of Marine Fisheries
Proof of Purchase
RENEW : Scientific or Educational Collection Permit : Permit Number 707778
Permit Number : 707778 NC Residency :
Permit Year : 2014 Qualifying Product :
Effective Date/Time : 01/01/2014 00:00
Expiration Date/Time : 12/31/2014 23:59 Status : Active
Issue Date/Time : 12/10/2013 10:17 Status Date : 12/10/2013
Sales Outlet : DMF Morehead City Office
Terminal Number : SEBAY
Fee : 0.00
Restriction Type :
RESTRICT TO
Time :
Start Time:
Comments:
Restriction Type :
RESTRICT TO
Time :
Start Time:
Comments:
Restriction Type :
RESTRICT TO
Time :
Start Time:
Comments:
Restriction Type .
RESTRICT TO
Time :
Start Time:
Comments:
Rcstriction Type :
RESTRICT TO
End Time:
End Time:
End Time:
End Timc:
Time :
Start Time: End Time:
Comments:
Gcar Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0528370300-JACKS
CREEK
Water Body :
0528370201-DRINKWA
TER CREEK
Species Group : Water Body :
Species Quantity : 0528370200-JACOBS
CREEK
Species Size :
Species Units :
Species Group : Water Body :
Species Quantity : 0528350400-PORTER
CREEK
Species Size :
Species Units :
Species Group : Water Body :
Species Quantity : 0528063302-SCOTT
CREEK
Species Size :
Species Units :
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 0528370900-LITTLE
CREEK
Gear Units : Species Size : f'mt'N
Time : Species Units :
Start Timc: End Timc: r*"'�
Comments:
Restriction Type : Gear Code : Species Group : Water Body : elb
RESTRICT TO Gear Quantity : Species Quantity : 0528410101-DUCK
CREEK !46\
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments:
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 0205010000-MUDDY e41."
CREEK
Gear Units . Species Size :
Time : Species Units
Start Time: End Time:
Comments: ella
Rcstriction Type Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity ; Species Quantity : 0208000000-CHOWAN rib,
RIVER
Gear Units : Species Size : elarN
Time : Species Units :
Start Time: End Time: timb
Comments:
e'N
DMF Morehead City Office, 3441 Arendell St., PO Box 769, Morehead City NC., 28557-0769 SUEANN BAY

many of the remaining fields as you can. The report is due within 15 days of the expiration of this permit. Your user name is (first initial and last name)
and the default password is 1"Aqu@tics0l ".
The first time you log in you will be prompted to change your password and enter security questions. Once in the PAWS system click on the "+" before
the Fisheries to view and click on the aquatics database fink. Next add a new submission, then you will be able to click on the add/edit link to begin
entering site data. Inside the data entry pages you can cursor over the green question marks for detailed information about a particular field.
For some data entry boxes, we have provided specific examples of how we would like the data entered. Help documents are available online and
additional questions can be sent to Ryan Heise ([e-mail]).
This permit/license is non -transferable and expires at midnight on the above specified expiration date.
ISSUED BY:
411.04,9
TITLE:
Permits Supervisor
14-ES00022

North Carolina Division of Marine Fisheries
Proof of Purchase
RENEW : Scientific or Educational Collection Permit : Permit Number 707778
Permit Number : 707778 NC Residency :
Permit Year : 2014 Qualifying Product :
Effective Date/Time : 01/01/2014 00:00
Expiration Date/Time : 12/31/2014 23:59 Status : Active
Issue Date/Time : 12/10/2013 10:17 Status Date : 12/10/2013
Sales Outlet : DMF Morchcad City Office
Terminal Number : SEBAY
Fee :
0.00
Permit Holder : 730069 CZR, INC.
Business Type:
Physical Address : 4709 COLLEGE ACRES DRIVE,
Mailing Address :
SUITE 2,
WILMINGTON, NC, 28403
United States
County : New Hanover
County :
Race :
Eyes :
Weight :
Gender : Date of Birth :
Hair :
Height :
ft.
Inches
Home Phone : [phone] Primary Residence : NC
Prior Names :
Business Phone : [phone] Secondary Residence :
Fax: [phone]
Ids :
E-Mail : [e-mail]
Business Agent : 730085 COOPER, SAMUEL
Physical Address : 5425 ANDOVER ROAD,
Mailing Address :
WILMINGTON, NC, 28403
United States
County : New Hanover
County :
Race : Caucasian
Eyes : Brown
Weight :
160
Gender : Male Date of Birth 03/12/1963
Hair : Brown
Height :
5 ft.
10 Inches
Home Phone : [phone] Primary Residence : NC
Prior Names :
Business Phone : [phone] Secondary Residence :
Fax : [phone]
Ids :
E-Mail :
Contact Information
Contact Person I Contact Person DOB
Contact Person Telephone #
SAMUEL COOPER 03/12/1963
[phone]
Purpose of Collection
Research
I
Teaching Specimens
! Educational Display (Aquariums)
j
1 X
Other (specify) SECTION 401 WQC MONITORING & DIOXIN SCANS
Collectors
ParticipantId Name
DOB
Contact
Phone
_
JULIA K. BERGER
02/02/1951
(910)
392-9253
SHERRY BANNER
07/21/1943
(910)
392-9253
LORRIE LALIBERTE BOSWELL
06/29/1981
(910)
392-9253
RANDALL PULLEY
02/02/1978
(910)
392-9253
ALEXANDER CRAIG
10/11/1983
(910)
392-9253
JASON HALL
06/05/1973
(910)
392-9253
MICHAEL NEAL
03/27/1997
(910)
392-9253
CHELSEA MCDOUGALL
07/03/1987
(910)
392-9253
NICHOLAS TUDOR
06/23/1989
(910)
392-9253
SEAN FARRELL
08/12/1990
(910)
392-9253
AMANDA JOHNSON
05/02/1986
(910)
392-9253
JOEY POWERS
03/27/1983
(910)
392-9253
ZACH GILSTRAP
10/07/1986
(910)
392-9253
Restriction Information
(4"rats
t
ftN
fftN
etiN
r"1
tut)
/41*‘
ell")
DMF Morehead City Office, 3441 Arendt!! St., PO Box 769, Morchcad City NC., 28557-0769
SUEANN BAY

NORM Scientific Fish Collecting License
cam...
AUTHORITY
STATUIES
113-261, 113-262, & 113-272.4
`uN+s
North Carolina Wildlife Resources Commission
Division of Inland Fisheries
Phone: [phone] MSC 1721
Fax: [phone] Raleigh, NC 27699-1721
PERMITTEE/LICENSEE
PERMIT NUMBER
14-SFC00004
SAMUEL COOPER
CZR, INC
EFFECTIVE
EXPIRES
4709 COLLEGE
ACRES DRIVE
03/07/2014
12/31/2014
SUITE 2
WILMINGTON,
NC 28403
Conditions and Authorizations: Print Date: 03/07/2014
The above licensee is authorized to collect the species/organisms by the sampling methods as listed below without
restriction to season, size, or creel limits unless otherwise specified under Special Conditions. These species/organisms
may be collected in the River Basins/Counties listed below. Sampling in Collection -Sensitive Waters is not authorized
under this license unless specified under Special Conditions or allowed through a Commission -issued Endangered Species
Permit. For a current list of Collection -Sensitive Waters, see www.ncwildlife.org/Licensing/fishcollection.aspx. The take or
possession of federally or state listed endangered, threatened, or special concern species is not authorized under this
license except in conjunction with a valid Endangered Species Permit. The licensee is required to comply with all
requirements and laws specified by the U.S. Fish and Wildlife Service and National Marine Fisheries Service as they
pertain to federally -listed species. For a current list of federally or state listed endangered, threatened, or special concern
species, see www.ncwildlife.org/Licensing/fishcollection.aspx.
SPECIES/ORGANISMS:
Amblyopsidae; Amiidae; A
Cottidae; Cyprinidae; Elass
Petromyzontidae; Poeciliida
RIVER BASINS/COUNTIES
nguillidae; Aphredoderidae; Atherinopsidae; Catostomidae; Centrarchidae; Clupeidae;
omatidae; Esocidae; Fundulidae; Ictaluridae; Lepisosteidae; Moronidae; Percidae;
e; Salmonidae; Umbridae
CAPE FEAR - Bladen, Brunswick, Columbus, Pender
ROANOKE - Bertie, Martin, Washington
TAR-PAMLICO - Beaufort
SAMPLING METHOD:
Electrofishing, Boat; Net, Di
ASSISTANTS:
p; Net, Fyke; Net, Gill; Seines; Traps; Trawls; Hook and Line
SHERRY BANNER, JULIA BERGER, ALEXANDER CRAIG, RANDALL PULLEY, JASON HALL, LORRIE LALIBERTE
BOSWELL, MICHAEL NEAL, NICHOLAS TUDOR, AMANDA JOHNSON, SEAN FARRELL, ZACH GILSTRAP, JOEY
POWERS
SPECIAL CONDITIONS:
This permitllicens
ISSUED BY:
is non -transferable and expires at midnight on the above specified expiration date.
a7,e/cf'
TITLE:
Chief
14-SFC00004

c
Phone: [phone]
Fax: [phone]
Endangered Species Permit
North Carolina Wildlife Resources Commission
Division of Wildlife Management
MSC 1722
Raleigh, NC 27699-1722
AUTHORITY
STATUTES
GS 113-331-113-337
RULES
1 SA NCAC 101.0001 - .0005
PERMITTEEIUCENSEE
SAMUEL COOPER
CZR, INC
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NC 28403
D
CIIflE
LDEC 1 8 2013
Type of Permit:
Possession, Survey, Take
Species Authorized:
-Fish, Freshwater
0�-Yl i... — rested '
Wilmington, NC
PERMIT NUMBER
14-ES00022
EFFECTIVE
01101/2014
EXPIRES
12/31/2014
COUNTY
DISTRICT
Location Where Authorized Activity May Be Conducted:
STATEWIDE
Conditions and Authorizations:
State -listed Species Only
Print Date: 12/13/2013
Authorized for incidental take of state -listed fish species while conducting fish collection activities as a designated agent of the NC Wildlife Resources
Commission.
All mortalities must be reported to this office (919)-707-0050 within twenty-four (24) hours; a written report describing the mortality event must be
submitted within five (5) work days to: Division of Wldtife Management/Permits, 1722 Mall Service Center, Raleigh, NC 27699-1722; and all mortalities
must be included in the annual report.
All activities must be supervised ON -SITE by the permittee, or by an authorized subpermittee as designated by the permit holder. All individuals
conducting activities under this permit must carry a copy of this permit and a letter of authorization while engaged in permitted activities.
Authorized subpermittees: Julia Berger, Sherry Banner, Lorrle Laliberte, Randall Pulley, Alexander Craig, Daniel Moore, Michael Neal, Nicholas
Tudor, Amanda Johnson, Sean Farrell, Chelsea McDougall, Anne Dowling, Tyler Peacock, and Jason Hall
All specimens must be retained in the possession of the permittee unless lawfully transferred, released, or destroyed.
A fish collection license is also required from the North Carolina Wildlife Resources Commission, Division of Inland Fisheries.
Possession and transportation of dead specimens is permitted only as authorized by this permit.
Unless specifically authorized by this permit, collected voucher specimens must be deposited in the North Carolina Museum of Natural Sciences,
Raleigh.
Issuance of this permit does not constitute permission to conduct these activities on any public or private lands; Such permission must be obtained
separately from the appropriate landowner or land manager before beginning these authorized activities. This permit, neither directly nor by
implication, grants right of trespass.
The validity of this permit is conditioned upon strict observance of all applicable local, state, and federal law.
A requested amendment to this permit must be submitted in writing by the permittee any time the permittee name, contact Information, species,
location, or permit conditions change.
Failure to meet any of the conditions specified herein constitutes just cause for revocation of the permit or denial of renewal.
All activity conducted under an Endangered Species Collection Permit must be reported to the NC Wildlife Resources Commission via an online data
entry web site to meet the reporting requirements (https://ncpaws.org/paws/). Some fields are required and are marked with an asterisk, but fill in as
This permit/license is non -transferable and expires at midnight on the above specified expiration date.
ISSUED BY:
TITLE:
Permits Supervisor
14-ES00022

APPENDIX B
NORTH CAROLINA SCIENTIFIC COLLECTION PERMITS

Monitoring Strategy for International Paper Company at Riegelwood, North Carolina
Composite Sample Guidance
All fish samples will be composited to maximize the number of sampled individuals and the
potential of sampling contaminated fish. Composite samples will consist of single species,
ideally represented by a maximum of ten individual fish. Composites will be prepared by
combining fillet fish tissue from similar sized individual fish, with a preference for larger fish.
Individual length and weight (metric) will be recorded for each fish and the average weight
and length for composites will be calculated. Whole fish tissue analysis is not required.
Fillets will be prepared by leaving skin on and removing scales for most species, with the
exception of catfish which will be skinned. Individual fish will be identified to species. A
sufficient quantity of each (un-extracted) composite sample will be retained and archived
(frozen) for a period of three months following submission of the final report.
Sample Collections Total laboratory samples to be analyzed = 13 (12 samples and one
duplicate)
Sampling Site 1 - Cape Fear River in the vicinity of SR 1730 Bladen County
Four composite samples will be analyzed for dioxin at this station:
- one composite sample for largemouth bass with sunfish as fallback species,
- one composite sample for bluegill with other sunfish as fallback species
(redbreast, redear, etc.),
- one composite sample for catfish (flatheads, channels, blue, other) or carp,
-one composite sample for catfish (flatheads, channels, blue, other) with
other edible finfish as fallback species.
Sampling Site 2 - Cape Fear River in the vicinity of Bryant Mill Creek
Four composite samples will be analyzed for dioxin at this station:
- one composite sample for largemouth bass with sunfish as fallback species,
- one composite sample for bluegill with other sunfish as fallback species
(redbreast, redear, etc.),
- one composite sample for catfish (flatheads, channels, blue, other) or carp,
-one composite sample for catfish (flatheads, channels, blue, other) with
other edible finfish as fallback species.
Sampling Site 3 - Cape Fear River in the vicinity of confluence with Black River
A-1

Four composite samples will be analyzed for dioxin at this station:
-one composite sample for largemouth bass with sunfish as fallback species,
-one composite sample for bluegill with other sunfish as fallback species
(redbreast, redear, etc.),
-one composite sample for catfish (flatheads, channels, blue, other) or carp,
-one composite sample for catfish (flatheads, channels, blue, other) with
other edible finfish as fallback species.
Laboratory Analysis and Reporting Procedures
Samples will be analyzed for Dioxin and Furans in accordance with analytical protocols set
out in Appendix C of USEPA/Paper Industry Cooperative Dioxin Screening Study (EPA
440/1-88-025, March 1988) or other equivalent analytical protocol approved by EPA.
Analysis will include the determination of concentrations of 2,3,7,8 TCDD and 2,3,7,8
TCDF. Dioxin analysis will be performed using high resolution Mass Spectrometry as
required by EPA Methods 624, 625, 8290, 1613 or other approved methods.
Required Analysis of Dioxins and Furans
Matrix Compound Quantitative Limits
Fish 2,3,7,8 TCDD 1 part per trillion
Fish 2,3,7,8 TCDF 1 part per trillion
Results will be reported in ppt with a minimum quantitative limit of 1 ppt. Where the
compound is detected at concentrations less than the minimum quantitative limit, an
estimate of the concentration will be given. If a compound is not detected it will be so
noted.
Reports
A monitoring report will be submitted that will include:
- sampling locations shown on copies of topographical maps (1:2400);
-analytical methods and procedures with name of laboratory;
-individual specimen description (species, length, weight, condition);
- composite descriptions (species, average length, average weight);
- All results will be reported as 2,3,7,8 TCDD and 2,3,7,8 TCDF in parts per trillion
(PO -
Monitoring reports (with results) will be sent in triplicate and directed to:
Mr. Steve Tedder
Chief, Water Quality Section
Division of Environmental Management
PO Box 27687
Raleigh, North Carolina 27611
A-2

APPENDIX A
DIOXIN MONITORING STRATEGY

Van den Berg, M. et al. 1998. Toxic Equivalency Factors (TEFs) for PCBs, PCDDs,
PCDFs for Humans and Wildlife. Environmental Health Perspectives 106: 775-792.
Van den Berg, M. et al. 2006. The 2005 World Health Organization Reevalua
tion of
Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin -Like
Compounds. Toxicological Sciences 93(2): 223-241.
24

CZR Incorporated. 2006. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2007. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2008. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2009. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2010. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2011. Dioxin Monitoring Study of Fish Tissue from the Cape
Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2012. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2013. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
EA Engineering, Science, and Technology, Inc. 1992. Dioxin Monitoring Study of Fish
Tissue from the Vicinity of Federal Paper Board Company's Riegelwood Mill.
Prepared for Federal Paper Board Company, Inc., EA Engineering, Science, and
Technology, Inc., Smyrna, Georgia. Report No. 12347.01.
National Council for Air and Stream Improvement (NCASI). 1991. A critical review of the
literature on the bioaccumulation of 2,3,7,8-tetrachlorodibenzo-p-dioxin and furan in
fish. NCASI Tech. Bull. No. 610.
NCDENR. 2013. Standard Operating Procedures Fish Tissue Assessments. North
Carolina Department of Environmental and Natural Resources. Division of Water
Resources, Environmental Sciences Section, Intensive Survey Branch. Version 1.2.
Taylor, K., and K. M. Rudo. 1990. Risk Assessment of Dioxin Contaminated Fish.
Division of Epidemiology, NC Department of Environment, Health, and Natural
Resources. Raleigh, North Carolina.
23

REFERENCES
CZR Incorporated. 1993. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina.
CZR Incorporated. 1994. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina.
CZR Incorporated. 1995. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina.
CZR Incorporated. 1996. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 1997. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 1998. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 1999. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2000. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2001. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2002. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2003. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2004. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2005. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
22

Table 3-4. Summary of analytical results from fish tissue composites collected in the Cape Fear River near the International Paper Company Mill at
Riegelwood, NC, during 2014. Detailed case narratives of the laboratory results are found in Appendix D.
Year
2,3,7,8-TCDD average concentration (ppt)
Station 1
Station 2 Station 3
Gamefish Bottom feeder Gamefish Bottom feeder Gamefish Bottom feeder
1992 0.09 _ 0.15 0.38 2.09 0.35 1.15
1993 0.09a 0.16 0.17b 0.59 0.33 0.38
1994 0.08 ND 0.32 0.2 0.22 0.42
1995 ND ND ND 0.2113 ND ND
1996 ND ND ND 0.37b ND 0.12
1997 ND 0.17b 0.20a 0.25a ND 0.06b
1998 ND ND ND ND ND 0.31
1999 ND 0.05b 0.08b 0.17b ND 0.31b
2000 ND ND` 0.18b ND 0.09b ND
2001 ND ND` 0.11b 0.19b 0.11b 0.08b
2002 ND 0.26b ND 0.29b ND ND
iv 2003 ND ND ND 0.05b ND 0.63
2004 ND 0.25b ND 0.14 0.26 0.1
2005 0.23 0.34a 0.12 0.43 0.20 0.26a
2006 0.07b 0.22a ND 0.24a ND 0.36a
2007 ND 0.33a ND 0.15a ND 0.07b
2008 ND 0.42a ND 0.11 ND 0.33a
2009 0.42 0.70 0.32 1.13 0.56b 0.49
2010 ND 0.30b ND 0.29b 0.14b 0.12b
2011 ND 0.10b ND 0.42 ND ND
2012 ND 0.18b ND 0.52a ND 0.11b
2013 ND 0.11b ND 0.18a ND 0.19a
2014 ND 0.12 ND 0.09a ND 0.07b
*1992 data were obtained from EA Report No. 12347.01 (EA Engineering, Science, and Technology, Inc., 1992).
ND = Not detected; detection limits were not used in calculating average concentrations of 2,3,7,8-TCDD.
aValues represent average of dioxin concentrations and estimated concentrations.
"Values represent average of estimated concentrations.
`Estimated concentration found in replicate.

LIST OF TABLES
Table Page
2-1 Water quality parameters measured in Cape Fear River sampling during
2014 fish collections in association with International Paper, Riegelwood, NC .... 7
2-2 Collection dates, techniques, effort, and fish captured in Cape Fear River fish
collections during 2014 in association with International Paper, Riegelwood,
NC 9
3-1 Summary of 2014 fish composites retained from three Cape Fear River
stations in the vicinity of the International Paper Company Mill at Riegelwood,
NC 15
3-2 Fish composite data for three Cape Fear River stations in the vicinity of the
International Paper Company Mill at Riegelwood, NC, collected during 2014....19
3-3 Summary of analytical results from fish tissue composites collected in the
Cape Fear River near the International Paper Company Mill at Riegelwood,
NC, during 2014 20
3-4 Comparison of dioxin (2,3,7,8-TCDD) concentrations among gamefish and
bottom feeder composites from the Cape Fear River from 1992 to 2014 21
LIST OF FIGURES
Figure Page
2-1 Sampling Stations — Sites of Fish Collection on the Cape Fear River near
Riegelwood, NC 3
2-2 Sampling Station 1 -- Site of Fish Collection on the Cape Fear River near
Riegelwood, NC 4
2-3 Sampling Station 2 -- Site of Fish Collection on the Cape Fear River near
Riegelwood, NC 5
2-4 Sampling Station 3 -- Site of Fish Collection on the Cape Fear River near
Riegelwood, NC 6
LIST OF APPENDICES
APPENDIX A: DIOXIN MONITORING STRATEGY
APPENDIX B: NORTH CAROLINA SCIENTIFIC COLLECTION PERMITS
APPENDIX C: LETTER OF TRANSMITTAL/CHAIN OF CUSTODY
APPENDIX D: TOTAL TEQ (WHO TEFS) / SGS LEVEL II ANALYTICAL LAB REPORTS
iii

f*
Aft
1.0 INTRODUCTION
International Paper Company's (International Paper) NPDES permit (No.
NC0003298) for the Riegelwood mill requires the collection and analysis of fish tissue for
the presence of dioxins and furans. The mill is located along the Cape Fear River near
Riegelwood, Columbus County, North Carolina. The dioxin monitoring program is
administered by the North Carolina Division of Water Resources (DWR), formerly the
Division of Water Quality. International Paper contracted CZR Incorporated (CZR) to
collect fish samples during 2014. To maintain report consistency, the format and style of
this report are similar to CZR Incorporated's past monitoring reports (1993 through 2013
Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the
Federal Paper Board's Mill at Riegelwood, North Carolina) which were modeled and
derived from the September 1992 report (EA Report No. 12347.01) titled "Dioxin Monitoring
est'► Study of Fish Tissue from the Cape Fear River in the Vicinity of Federal Paper's
Riegelwood, North Carolina Mill" prepared by EA Engineering, Science, and Technology,
Inc.
e
Monitoring protocols were established in September 1990 to comply with the Special
Order by Consent (SOC) EMC WQ No. 84-30 AD II effective 12 July 1990. The protocols
comply with both the NPDES permit and the SOC. The following sections discuss sampling
stations, sample collection techniques, sample preparation, and analytical results.
rn\
rst

2.0 METHODS
2.1 Sampling Stations
Fish collections occurred in the sampling areas established from previous studies
(EA Engineering, Science, and Technology, Inc., 1992). Sampling stations were originally
selected as required by the current NPDES permit and SOC. North Carolina's current
DWR fish tissue dioxin monitoring strategy for the Riegelwood mill is provided in Appendix
A. One station was located upstream of the mill's discharge and the remaining stations
were located downstream of the mill (Figure 2-1).
Station 1 is approximately 11 miles upstream of Lock & Dam No. 1 in the vicinity of
Elwell's Ferry (SR 1730). This station is a control site located approximately 20 miles
upstream of the mill outfall and separated from the mill by a physical barrier, Lock & Dam
No. 1 (Figure 2-2). Station 2 is approximately 2 miles downstream of the mill discharge
near Green Bank Landing (Figure 2-3). Station 3 is approximately 13 miles downstream of
the mill discharge near the confluence of the Cape Fear River and the Black River (Figure
2-4).
Generally, fish habitat was sparse and varied among the three sampling stations.
The available fish habitat consisted of inundated tree roots, aquatic macrophytes,
overhanging riparian vegetation, snags, and fallen timber. Physicochemical measurements
taken in conjunction with fish collections at each sampling station are found in Table 2-1.
2

LEGEND
SAMPLING STATION
SITE OF PAPER MILL
SOURCE:
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NAD83 FEET, 1:24000—SCALE, USGSTopoTile018.SID
0
20,000
40,000
SCALE IN FEET
SAMPLING STATIONS
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
SCALE: AS SHOWN
DATE: 12/09/08
APPROVED BY:
DRAWN BY: TLJ
FILE: 1340-KEY
ZR
INCORPORATED
ENVIRONMENTAL CONSULTANTS
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROUNA 28403
TEL [phone]
FAX [phone]
CP#1 340
FIGURE 2-1
3

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LEGEND
SAMPLING STATION 1
/
SAMPLING STATION ,
\
V
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
0 2,000 4,000
SCALE: AS SHOWN
APPROVED BY:
DRAWN BY: TLJ
DATE: 12/09/08
FILE: 1340—SP1
KA
'-•• '• %
fl 47D9 COLLEGE ACRESUDRIIVE
CPE1340
SOURCE: SCALE IN FEET
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NAD83 FEET, 1:24000-SCALE, USGSTopoTile018.SID
v L
...: INCORPORATED
ENVIRONMENTAL CONSULTANTS
WILMINGTON. NORTH CAROUNA 28403
TEL [phone]
FAX [phone]
FIGURE 2-2

)))))))))))))))))))))))))))))))))))))))))))
LEGEND
SAMPLING STATION
SOURCE:
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NAD83 FEET. 1:24000—SCALE, USGSTopoTile018.SID
0
2,000
4,000
SCALE IN FEET
SAMPLING STATION 2
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
SCALE: AS SHOWN
DATE: 12/09/08
APPROVED BY:
DRAWN BY: TLJ
FILE: 1340-SP1
±�M
ZR
INCORPORATED
ENVIRONMENTAL CONSULTANTS
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROUNA 28403
TEL [phone]
FAX [phone]
CP#1340
FIGURE 2-3

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LEGEND
SAMPLING STATION
SOURCE:
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NANO FEET, 1:24000—SCALE, USGSTopoTile018.SID
O 2,000
4,000
SCALE IN FEET
SAMPLING STATION 3
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
SCALE: AS SHOWN
DATE: 1 2/09/08
APPROVED BY:
DRAWN BY: TLJ
FILE: 1340-SP1
ZR
INCORPORATED
ENV I RONA! NTAL CONSULTANTS
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON. NORTH CAROLINA 28403
TEL [phone]
FAX [phone]
CP#1 340
FIGURE 2-4

Table 2-1. Water quality parameters measured in Cape Fear River sampling during 2014 fish collections in association with
International Paper, Riegelwood, NC.
Sampling
Station
1
1
1
2
2
2
2
2
2
3
3
3
3
3
Date
25=Aug-14
26-Aug-14
27-Aug-14
26-Aug-14
27-Aug-14
9-Sept-14
10-Sept-14
22-Sept-14
23-Sept-14
8-Sept-14
9-Sept-14
10-Sept-14
22-Sept-14
23-Sept-14
Temp DO
Time (°C) DO% (mg/L) Cond(µS)
1755 28.3 59.4 4.64 116.7
1220 27.7 61.1 4.83 119.6
0955 27.4 56.0 4.40 125.2
1630 27.6 61.8 4.86 137.9
1445 28.7 69.9 5.41 147.8
0930 27.9 70.5 5.53 297.7
1020 27.3 64.4 5.14 206.7
1830 24.7 74.3 6.20 107.7
0950 24.4 78.1 6.24 168.8
1830 28.1 61.9 4.82 263.3
1315 27.6 65.4 5.13 246.8
1345 28.0 72.2 5.65 195.0
1800 24.7 59.5 4.92 132.5
1420 23.4 57.3 4.89 106.4
SpCond(µS)
109.8
111.4
119.6
130.2
138.5
281.4
197.5
108.2
170.4
249.0
234.3
184.8
133.2
109.7
Salinity(psu)
0.05
0.05
0.06
0.06
0.06
0.13
0.09
0.05
0.08
0.12
0.11
0.09
0.06
0.05
Secchi(in) pH
32.50 5.53
27.50 5.99
26.00 6.39
38.00 5.81
23.50 6.21
36.00 6.14
21.50 5.95
30.00 5.50
30.25 5.82
29.50 6.13
37.00 6.01
37.00 6.01
31.50 5.62
26.50 5.26

2.2 Species Selection
The goal of the fish collection effort was to obtain four composite samples at each
sampling location with each sample consisting of ten individuals of the same species and of
similar length and weight. Larger (adult) specimens were given preference. Composites at
each station were composed of gamefish and bottom feeding species fillets. Target
species listed in the state's dioxin strategy include:
• one composite sample for largemouth bass with sunfish (bluegill, redbreast,
etc.) as fallback species;
• one composite sample for bluegill with other sunfish (redbreast, redear, etc.)
as fallback species;
• one composite sample for catfish (order of preference being flathead,
channel, blue, and others) or carp;
• one composite sample for catfish (order of preference being flathead,
channel, blue, or others with fallback species as edible finfish).
2.3 Sample Collection Methodology
Various active and passive methods of fish collection were used to obtain target
species. Fish were collected under scientific fish collecting Permit Number SECP-707778
(North Carolina Division of Marine Fisheries) and License Number 14-SFC00004 (North
Carolina Wildlife Resources Commission) (Appendix B). Gill nets (flounder nets; 5.50-inch
mesh x 20 mesh x 50 or 100 yards and 5.75-inch mesh x 15 mesh x 50 or 100 yards), trot
lines, and hook and line fishing were used to collect fish. Descriptions of effort and gear
types used are given in Table 2-2.
8

Table 2-2. Collection dates, techniques, effort, and fish captured in Cape Fear River fish collections during 2014 in association with International Paper,
Riegelwood, NC. See Figures 1 through 3 for site/station locations.
Sampling
Station Date Gear Level of Effort Catch
1 25 August 2014 Hook & line 1.00 hour 9 bluegill
1 26 August 2014 Hook & line 1.00 hour 5 bluegill, 1 pumpkinseed
Trot line 2 lines — 50 hooks 1 flathead catfish
Gill net 8 nets overnight — 450 yards 14 blue catfish, 6 common carp, 1 flathead catfish
1 26 August 2014 Hook & line 1.00 hour 7 bluegill
Gill net 5 nets overnight — 300 yds 9 blue catfish, 3 common carp
2 26 August 2014 Hook & line 0.75 hour 3 bluegill
2 27 August 2014 Hook & line 0.50 hour 0 fish
(0 Trot line 2 lines — 50 hooks 1 blue catfish
Gill net 4 nets overnight — 200 yards 5 blue catfish, 2 flathead catfish, lcommon carp
2 9 September 2014 Hook & line 1.00 hour 2 bluegill, 1 largemouth bass
Trot line 2 lines — 50 hooks 1 blue catfish
Gill net 3 nets overnight — 150 yards 3 blue catfish, 1 largemouth bass
2 10 September 2014 Hook & line 0.50 hour 1 bluegill
Trot line 1 line — 25 hooks 0 fish
Gill net 4 nets overnight — 200 yards 2 blue catfish
2 22 September 2014 Hook & line 2 hooks — 0.75 hour 3 bluegill, 1 blue catfish
2 23 September 2014 Hook & line 2 hooks — 1.00 hour 19 bluegill
Trot line 2 lines — 50 hooks 0 fish
Gill net 4 nets overnight — 200 yards 1 common carp

Table 2-2. (Concluded).
Sampling
Station Date Gear Level of Effort Catch
3 8 September 2014 Hook & line 0.50 hour 2 bluegill
3 9 September 2014 Hook & line 0.75 hour 3 bluegill
Trot line 2 lines — 50 hooks 4 blue catfish
Gill net 5 nets overnight — 300 yards 3 common carp, 1 blue catfish
3 10 September 2014 Hook & line 1.00 hour 6 bluegill
Trot line 2 lines — 50 hooks 1 blue catfish
Gill net 5 nets overnight — 300 yards 4 blue catfish, 1 common carp
3 22 September 2014 Hook & line 2 lines — 0.50 hour 0 fish
3 23 September 2014 Hook & line 2 lines — 2.50 hour 9 bluegill, 1 pumpkinseed, 1 channel catfish
Trot line 1 line — 25 hooks 0 fish
o Gill net 6 nets overnight — 350 yards 1 blue catfish, 1 flathead catfish, 1 common carp

(PR)
ese,\
(A) 2.4 Sample Preparation and Shipment
rA
`A) Collected fish were descaled or skinned, filleted, and preserved by CZR. SGS
Environmental Services (2714 Exchange Dr., Wilmington, North Carolina 28405) was
rlk\
prevent cross -contamination between stations and composites, all equipment used to
(A) handle fish (excluding nets) was solvent rinsed with pesticide -grade acetone and hexane
and when applicable, wrapped with aluminum foil (e.g., measuring boards and scale pans)
which was changed between composites. Fish from different stations were held in
separate coolers and disposable latex gloves were worn and frequently changed when
responsible for final sample preparation (i.e., homogenization) and chemical analysis. To
handling fish during each phase of sample preparation.
(A) As fish were collected, they were placed on wet ice until processing. Fish were
filleted with knives on cutting boards wrapped with aluminum foil (dull side up). Cutting
board wraps were changed and fillet knives were solvent rinsed between composites. Fillet
samples consisted of flesh from both sides of each specimen, including the skin (for
gamefish) but not the scales. Catfish and carp specimens were skinned. Samples were
wrapped in aluminum foil (dull side toward the fish) to shield it from light and were labeled
with sample location, species, and date of collection. All labeled samples making up a
(A) single composite were placed in individual plastic "zip -lock" bags, then all composite
sample bags were sealed inside a larger bag for each station. Samples were frozen to
await delivery to the laboratory for analysis.
On 30 September 2014, the frozen samples were hand -delivered to SGS
Environmental Services in Wilmington, North Carolina, in coolers packed with ice. A copy
(A, of the letter of transmittal/chain of custody that accompanied samples is included in
Appendix C.
r
11

2.5 Chemical Analysis
SGS Environmental Services performed the chemical extraction and analyses in
`a• accordance with EPA Method 1613B using high -resolution chromatography/high-resolution
mass spectrometry for detecting the presence of 2,3,7,8- tetrachlorodibenzo-p-dioxin
(TCDD) and 2,3,7,8-tetrachlorinatedibenzofuran (TCDF). Additionally, analyses of all 17 of
the dioxin and furan congeners that are substituted with chlorine at the 2,3,7, and 8
positions were performed.
All summary results were reported as 2,3,7,8-TCDD; 2,3,7,8-TCDF; and dioxin
toxicity equivalents (TEQs). TEQs were calculated using 17 of the 2,3,7,8-chlorine
substituted dioxin and furan congeners using the 2005 World Health Organization (WHO)
toxicity equivalent factors (TEFs) for mammals (Total TEQ WHO TEFs) (Van den Berg et
al., 2006). Congener concentrations reported as non -detect were entered as zero in the
calculation of all TEQ values. Congeners reported as estimated maximum possible
concentrations (EMPC) were not included in calculations of total TEQs. Total extractable
lipid content was also determined for each composite sample. A composite sample of blue
catfish from Station 1 was designated for duplicate laboratory analysis. A quantity sufficient
for re -extraction of each composite sample (where available) was retained and will be held
frozen for a period of 30 days at the lab following the analysis. Duplicate samples will be
held at CZR for three months following the completion of this report.
rst
osit
/112` 12
olwaN

3.0 RESULTS AND DISCUSSION
3.1 Fish Collection
A summary description of the 2014 fish composites is found in Table 3-1. Gamefish
and bottom feeder target species were collected from each of the three stations. Gamefish
or water -column feeding species submitted for analysis included bluegill (Lepomis
macrochirus) from Stations 1, 2, and 3. Bottom feeder species submitted for analysis
included blue catfish (IctaIurus furcatus) and common carp (Cyprinus carpio) from Stations
1, 2, and 3. Sample composites with calculated average total fish lengths and weights are
found in Table 3-2.
3.2 Tissue Analyses
Dioxin (TCDD) concentrations (all reported in parts per trillion — ppt) in 2014 were
detected in 7; of 13 composite samples, none exceeding 0.15 ppt (Table 3-3). The highest
concentration of dioxin detected was 0.15 ppt found in common carp composite number 4
(composite of 9 individuals) at Station 1. The next highest concentration detected was 0.10
ppt found in blue catfish replicate composite number 13 (composite of 10 individuals), also
located at Station 1. Detected dioxin concentrations from Station 1 ranged from 0.09 ppt to
0.15 ppt. Station 2 dioxin ranged from 0.08 ppt to an estimated maximum possible
concentration of 0.09 ppt, while Station 3 dioxin ranged from an estimated maximum
possible concentration of 0.06 ppt to 0.10 ppt.
Furan (TCDF) concentrations (all reported in parts per trillion — ppt) in 2014 were
detected in 5 of 13 composite samples, none exceeding 0.25 ppt (Table 3-3). The highest
concentration of furan detected was 0.22 ppt found in common carp composite number 4
(composite of 9 individuals) at Station 1. The next highest concentration detected was an
estimated maximum possible concentration of 0.18 ppt found in common carp composite
number 12 (composite of 5 individuals), located at Station 3. Detected furan concentrations
from Station 1 ranged from an estimated maximum possible concentration of 0.04 ppt to
0.22 ppt. Furan concentrations were only detected in common carp composite number 8
from Station 2, with a concentration of 0.13 ppt. Detected furan concentrations from
13

Station 3 ranged from 0.10 ppt to an estimated maximum possible concentration of 0.18
ppt. Concentrations of furan were not detected in bluegill composites from all three
sampling stations.
All analytical results for fish tissue composites collected and submitted during 2014
are summarized in Table 3-3. Percent lipid contents ranged from 0.26 (bluegill at Station 3)
to 3.03 (common carp from Station 1). Reported TEQs for 2,3,7,8-TCDD/F only are all
rstN below 0.20 ppt. Data for individual congeners (Total TEQ, WHO TEFs) and laboratory data
reports provided by SGS Environmental Services are included in Appendix D.
The State of North Carolina currently uses a dioxin and furan concentration of 4.00
ppt in issuing an advisory (NCDENR 2013). Total dioxin and furan concentrations below
this amount are considered acceptable by the State of North Carolina. Total TEQ values
for all 17 congeners (using WHO TEFs) in 2014 range from 0.00 ppt in bluegill composites
number 2 and 6 (both composites of 10 individuals) at Stations 1 and 2, respectively, to
0.66 ppt in common carp composite number 4 at Station 1 (Table 3-3). Total TEQ values
for all fish composite samples collected and submitted in 2014 are well below the state
advisory level of 4.00 ppt. Average dioxin concentrations (TCDD) from game and bottom
feeding fish in the vicinity of the Riegelwood Mill have remained relatively low during the
course of annual sampling periods over the last twenty-three years and do not display any
increasing trends in TCDD concentration (Table 3-4).
14

Table 3-1. Summary of 2014 fish composites retained from three Cape Fear River stations in
the vicinity of the International Paper Company Mill at Riegelwood, North Carolina.
Station Composite Species Length (mm) Weight (g) Fillet A (g) Ka
1 1 Bluegill 160 66 13 1.61
ilit 1 1 Bluegill 150 70 14 2.07
1 1 Bluegill 150 70 15 2.07
`at\ 1 1 Bluegill 150 73 15 2.16
rst, 1 1 Bluegill 150 75 15 2.22
1 1 Bluegill 148 75 16 2.31
1 1 Bluegill 158 80 17 2.03
1 1 Bluegill 160 83 17 2.03
1 1 Bluegill 152 84 16 2.39
1 1 Bluegill 155 85 17 2.28
1 2 Bluegill 155 92 19 2.47
r 1 2 Bluegill 165 93 19 2.07
1 2 Bluegill 170 100 25 2.04
1 2 Bluegill 170 108 25 2.20
tAN 1 2 Bluegill 165 118 26 2.63
1 2 Bluegill 183 120 27 1.96
1 2 Bluegill 170 130 30 2.65
tit) 1 2 Bluegill 180 142 32 2.43
r 1 2 Bluegill 205 190 35 2.21
1 2 Bluegill 200 197 35 2.46
1 3 Blue catfish 580 2,500 380 1.28
1 3 Blue catfish 615 2,650 575 1.14
1 3 Blue catfish 610 2,675 430 1.18
1 3 Blue catfish 595 2,675 385 1.27
1 3 Blue catfish 620 2,700 360 1.13
1 3 Blue catfish 610 2,700 380 1.19
1 3 Blue catfish 655 2,850 370 1.01
1 3 Blue catfish 640 3,375 410 1.29
1 3 Blue catfish 680 3,650 470 1.16
1 3 Blue catfish 660 3,750 460 1.30
rArN
1 4 Common carp 650 3,250 300 1.18
iat
1 4 Common carp 590 3,300 510 1.61
1 4 Common carp 610 3,400 380 1.50
1 4 Common carp 640 3,500 460 1.34
1 4 Common carp 620 3,550 450 1.49
1 4 Common carp 630 3,700 415 1.48
riik 1 4 Common carp 650 3,750 360 1.37
1 4 Common carp 640 3,800 420 1.45
fik 1 4 Common carp 680 4,750 590 1.51
1 Bluegill 140 60 12 2.19
15

Table 3-1. (continued).
Station Composite Species
Length
(mm)
Weight (g) Fillet A (g) Ka
1 Blue catfish 530 1,600 235 1.07
1 Blue catfish 540 1,800 285 1.14
1 Blue catfish 550 1,800 290 1.08
1 Blue catfish 570 2,000 280 1.08
1 Blue catfish 570 2,100 295 1.13
1 Blue catfish 580 2,200 350 1.13
1 Blue catfish 610 2,250 315 0.99
1 Blue catfish 590 2,300 350 1.12
1 Blue catfish 620 2,300 300 0.97
1 Blue catfish 700 4,000 615 1.17
1 Blue catfish 700 4,450 635 1.30
1 Blue catfish 730 4,500 710 1.16
1 Blue catfish 750 6,135 875 1.45
1 Flathead catfish 495 1,100 165 0.91
1 Flathead catfish 600 2,850 300 1.32
1 Pumpkinseed 183 120 30 1.96
2 5 Bluegill 151 60 16 1.74
2 5 Bluegill 149 60 14 1.81
2 5 Bluegill 147 62 14 1.95
2 5 Bluegill 151 63 16 1.83
2 5 Bluegill 152 65 16 1.85
2 5 Bluegill 148 70 18 2.16
2 5 Bluegill 158 77 18 1.95
2 5 Bluegill 162 83 20 1.95
2 5 Bluegill 163 83 20 1.92
2 5 Bluegill 173 97 20 1.87
2 6 Bluegill 167 100 20 2.15
2 6 Bluegill 181 122 22 2.06
2 6 Bluegill 182 124 24 2.06
2 6 Bluegill 175 125 20 2.33
2 6 Bluegill 189 138 28 2.04
2 6 Bluegill 192 152 30 2.15
2 6 Bluegill 195 154 30 2.08
2 6 Bluegill 200 160 39 2.00
2 6 Bluegill 219 200 34 1.90
2 6 Bluegill 216 218 48 2.16
2 7 Blue catfish 535 1,325 233 0.87
2 7 Blue catfish 565 1,800 350 1.00
2 7 Blue catfish 561 1,850 290 1.05
2 7 Blue catfish 569 1,950 315 1.06
2 7 Blue catfish 607 2,300 362 1.03
2 7 Blue catfish 624 2,425 363 1.00
2 7 Blue catfish 670 3,075 415 1.02
2 7 Blue catfish 664 3,550 480 1.21
2 7 Blue catfish 680 3,600 495 1.14
2 7 Blue catfish 693 3,600 540 1.08
16

Table 3-1. (continued)
Station Composite Species
Length
(mm)
Weight (g) Fillet A (g) Ka
2 8 Common carp 520 2,150 230 1.53
2 8 Common carp 620 2,400 175 1.01
2 Bluegill 118 34 10 2.07
rx\ 2 Bluegill 124 38 8 1.99
r 2 Bluegill 124 39 8 2.05
2 Bluegill 130 41 10 1.87
2 Bluegill 135 47 10 1.91
rst\ 2 Bluegill 133 49 12 2.08
2 Bluegill 159 58 16 1.44
2 Bluegill 144 59 16 1.98
tlfe
1114*
2 Blue catfish 382 450 64 0.81
2 Blue catfish 479 950 155 0.86
rmit\ 2 Flathead catfish 591 2,300 265 1.11
2 Flathead catfish 690 4,650 540 1.42
2 Largemouth bass 277 322 73 1.52
2 Largemouth bass 469 1,550 255 1.50
3 9 Bluegill 129 41 10 1.91
1 3 9 Bluegill 145 57 12 1.87
" 3 9 Bluegill 144 57 11 1.91
3 9 Bluegill 150 62 17 1.84
r" 3 9 Bluegill 155 63 18 1.69
" 3 9 Bluegill 153 65 16 1.81
3 9 Bluegill 161 81 12 1.94
" 3 9 Bluegill 170 82 20 1.67
tatN 3 9 Bluegill 178 91 18 1.61
3 9 Bluegill 172 92 20 1.81
" 3 10 Bluegill 186 95 18 1.48
" 3 10 Bluegill 180 98 18 1.68
3 10 Bluegill 173 109 22 2.11
3 10 Bluegill 188 124 21 1.87
rfic1 3 10 Bluegill 187 141 28 2.16
3 10 Bluegill 193 150 25 2.09
3 10 Bluegill 192 152 30 2.15
3 10 Bluegill 193 157 25 2.18
3 10 Bluegill 202 170 32 2.06
3 10 Bluegill 197 176 28 2.30
" 3 11 Blue catfish 604 2,150 364 0.98
3 11 Blue catfish 601 2,175 345 1.00
3 11 Blue catfish 563 2,200 340 1.23
" 3 11 Blue catfish 633 2,650 390 1.04
3 11 Blue catfish 658 3,025 470 1.06
3 11 Blue catfish 636 3,200 500 1.24
3 11 Blue catfish 666 3,650 460 1.24
,�, 17

EPP\
Table 3-1. (concluded).
Station Composite Species Length Weight (g) Fillet A (g) Ka
3 12 Common carp 603 2,900 422 1.32
3 12 Common carp 579 3,050 460 1.57
3 12 Common carp 591 3,100 492 1.50
3 12 Common carp 638 3,900 388 1.50
" 3 12 Common carp 670 4,150 550 1.38
etzt
3 Blue catfish 384 500 90 0.88
3 Blue catfish 435 675 123 0.82
eilk 3 Blue catfish 449 800 110 0.88
elk\ 3 Blue catfish 462 900 162 0.91
3 Channel catfish 435 600 110 0.73
3 Flathead catfish 631 3,175 346 1.26
3 Pumpkinseed 199 143 28 1.81
aFulton-type condition factor - (weight(g)/length(mm)3)*100000
elit
r41k1
fatN
ellit
rit
/014 18

Table 3-2. Fish composite data for three Cape Fear River stations in the vicinity of the International Paper
Company Mill lat Riegelwood, North Carolina, collected during 2014.
Station CompositenumberTypea Species
Number in
composite
Average
length
(mm)
Average
weight (g)
Average
fillet
weight (g)
1 1 G Bluegill 10 153.3 76.1 15.5
1 2 G Bluegill 10 176.3 129.0 27.3
1 3 B Blue catfish 10 626.5 2,953.0 422.0b
1 4 B Common carp 9 634.0 3,667.0 432.0
2 5 G Bluegill 10 155.4 72.0 17.2
2 6 G Bluegill 10 191.6 149.3 29.5
2 7 B Blue catfish 10 616.8 2,548.0 384.3
2 8 B Common carp 2 570.0 2,275.0 203.0
3 9 G Bluegill 10 155.7 69.1 15.4
3 110 G Bluegill 10 189.1 137.2 24.7
3 11 B Blue catfish 7 623.0 2,721.0 409.9
3 12 B Common carp 5 616.0 3,420.0 462.0
aG = Gamefish/water-column feeder; B = Bottom feeder.
bReplicate samples submitted.
19

0
Table 3-3. Summary of analytical results from fish tissue composites collected in the Cape Fear River near the International Paper Company
Mill at Riegelwood, North Carolina, during 2014. Detailed case narratives of the laboratory results are found in Appendix D.
Station
1
1
1
1
1
2
2
2
2
3
3
3
3
Notes:
a
b
c
d
e
f
S
Species Composite (#)
Bluegill (1)
Bluegill (2)
Blue catfish (3)
Common carp (4)
Blue catfish (13)g
Bluegill (5)
Bluegill (6)h
Blue catfish (7)
Common carp (8)
Bluegill (9)
Bluegill (10)
Blue catfish (11)
Common carp (12)
Percent
lipid
0.27
0.28
1.49
3.03
1.99
0.30
0.54
1.46
0.84
0.26
0.42
1.79
1.47
2,3,7,8-TCDD (ppt)
Concentration
NDd
NDd
0.09
0.15
0.10
NDd
NDd
0.08
0.09e
NDd
NDd
0.06e
0.08e
Percent
recovery?
79.2
87.2
83.7
74.0
91.1
82.2
82.9
91.7
83.2
79.7
89.4
85.0
84.9
2,3,7,8-TCDF (ppt)
Concentration
NDd
0.06e
0.04e
0.22
0.10
NDd
NDd
NDd
0.13
NDd
NDd
NDd
0.18e
2,3,7,8-
TCDD/F
Percent WHO TEQ
recovery? (ppt)b
81.0 0.00
89.8 0.01
85.8 0.09
74.2 0.17
93.3 0.11
81.8 0.00
84.4 0.00
92.7 0.08
88.3 0.10
84.1 0.00
89.9 0.00
86.4 0.06
86.6 0.10
Total TEQ
WHO TEFs
(PPt)c
0.01
0.00f
0.27
0.66
0.28
0.01
0.00f
0.12
0.26
0.01
0.01
0.08
0.13
± 5% statistical variability.
Includes Estimated Maximum Possible Concentrations due to ion ratio failure.
Toxic Equivalent (Total TEQ WHO TEFs) excludes Estimated Maximum Possible Concentrations per EPA Method 1613B.
Not detected.
Estimated Maximum Possible Concentration.
Analyte not displayed on table was detected, but Total TEQ (WHO TEFs) remains less than 0.00 ppt.
Duplicate sample.

Sample ID: Comp#3 Site 1 Blue Catfish
Client Data
Name:
Project ID:
Date Collected:
Analyte
CZR Incorporated
2014 Annual Fish Project
26-Aug-2014
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Conc. (pglg)
0.0888-
0.131
0.0965
EMPC
EMPC
0.773
2.51
EMPC
ND
0.114
ND
ND
EMPC
ND
EMPC
ND
ND
Sample Data
Matrix: Tissue
Weight/Volume: 10.01 g
% Lipid: 1.49
Split:
DL (pglg)
0.0375
0.0388
0.04
0.0448
0.0457
0.166
EMPC (pg/g)
0.211
0.155
0.042
0.035
0.0681
Laboratory Data
Lab Project ID: A7174
Lab Sample ID A7174_12595_DF_003
QC Batch No: 12595
Dilution:
Qualifiers
J
J
J
J
JB
JB
JB
J
J
J
JB
Standard
ES 2378-TCDD
ES 12378-PeCDD
ES 123478-HxCDD
ES 123678-HxCDD
ES 123789-HxCDD
ES 1234678-HpCDD
ES OCDD
ES 2378-TCDF
ES 12378-PeCDF
ES 23478-PeCDF
ES 123478-HxCDF
ES 123678-HxCDF
ES 234678-HxCDF
ES 123789-HxCDF
ES 1234678-HpCDF
ES 1234789-HpCDF
ES OCDF
Method 1613B
Date Received:
Date Extracted:
Date Analyzed:
Time Analyzed:
ES Recoveries
83.7
81.9
84.7
74.9
76.2
70.7
49.3
85.8
89.1
78.4
78.7
78.4
88
82.6
70.8
76.7
50.8
30-Sep-2014
02-Oct-2014
07-Oct-2014
20:13:27
Qualifiers
Totals
Standard
CS/AS Recoveries
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
0.0888
0.131
0.0965
0.773
0.0797
0.165
ND
ND
0.0888
0.131
0.462
0.916
0.122
0.211
0.035
0.126
CS 37CI-2378-TCDD
CS 12347-PeCDD
CS 12346-PeCDF
CS 123469-HxCDF
CS 1234689-HpCDF
AS 1368-TCDD
AS 1368-TCDF
Total PCDD/Fs
3.85
4.6
WHO-2005 TEQs
TEQ: ND=0
TEQ: ND=DU2
TEQ: ND=DL
0.272
0.292
0.311
0.101
0.202
0.317
0.324
0.331
95.5
95.3
93
89.8
87.8
85.2
89
SGS1
5500 Business Drive
Wilmington, NC 28405, USA
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 107-824-WZP
SGS Environmental Services - DIF 2014 Rev. 4.31
Report Created: 09-Oct-2014 09:59 Analyst: AC

Sample ID: Comp#3 Site 1 Blue Catfish TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_003
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.01 g
QC Batch No.: 12595
Date Collected: 26-Aug-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 07-Oct-2014 20:13
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
0.0888
J
0.0576
0.0888
0.0888
0.0888
12378-PeCDD
0.131
J
0.0834
0.0656
0.131
0.131
123478-HxCDD
0.0965
J
0.0801
0.00965
0.00965
0.00965
123678-HxCDD
[0.211]
J
0.0841
[0.0211]
[0.0211]
[0.0211]
123789-HxCDD
[0.155]
J B
0.0876
[0.0155]
[0.0155]
[0.0155]
1234678-HpCDD
0.773
J B
0.0797
0.00773
0.00773
0.00773
OCDD
2.51
J B
0.15
0.00251
0.000251
0.000754
2378-TCDF
[0.042]
J
0.039
[0.0042]
[0.0042]
[0.0042]
12378-PeCDF
(0.0375)
0.0375
(0.00188)
(0.00188)
(0.00113)
23478-PeCDF
0.114
J
0.0444
0.0569
0.0569
0.0341
123478-HxCDF
(0.0388)
0.0388
(0.00388)
(0.00388)
(0.00388)
123678-HxCDF
(0.04)
0.04
(0.004)
(0.004)
(0.004)
234678-HxCDF
[0.035]
J
0.0334
[0.0035]
[0.0035]
[0.0035]
123789-HxCDF
(0.0448)
0.0448
(0.00448)
(0.00448)
(0.00448)
1234678-HpCDF
[0.0681]
J B
0.0347
[0.000681]
[0.000681]
[0.000681]
1234789-HpCDF
(0.0457)
0.0457
(0.000457)
(0.000457)
(0.000457)
OCDF
(0.166)
0.166
(0.000166)
(0.0000166)
(0.0000498)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.231
0.294
0.272
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.251
0.314
0.292
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.271
0.334
0.311
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
EMPC = EMPC, ND = 0
0.276
0.339
0.317
EMPC = EMPC, ND = DL / 2
0.284
0.347
0.324
EMPC = EMPC, ND = DL
0.291
0.354
0.331
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 107-824-WZP
SGS Environmental Services - D/F 2014 Rev. 4.31
))))))))))))))))))))))))))) )) 3 ) ) ) ) ) ) )

Sample ID: Comp#4 Site 1 Common Carp Method 1613B
Client Data
Sample Data
Laboratory Data
Name: CZR Incorporated
Matrix:
Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
Lab Sample ID A7174_12595_DF_004
Date Extracted: 02-Oct-2014
Date Collected: 26-Aug-2014
% Lipid: 3.03
QC Batch No: 12595
Date Analyzed: 07-Oct-2014
Split: -
Dilution: -
Time Analyzed: 21:06:45
Analyte
Conc. (pglg)
DL (pglg)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD- - -
0.153
J
ES 2378-TCDD
74
12378-PeCDD
0.243
J
ES 12378-PeCDD
77.3
123478-HxCDD
0.271
J
ES 123478-HxCDD
79.7
123678-HxCDD
0.706
J
ES 123678-HxCDD
71.9
123789-HxCDD
0.372
J B
ES 123789-HxCDD
73.1
1234678-HpCDD
3.15
ES 1234678-HpCDD
71.3
OCDD
15.8
ES OCDD
55.4
2378-TCDF
0.22
J
ES 2378-TCDF
74.2
12378-PeCDF
ND
0.0378
ES 12378-PeCDF
78.4
23478-PeCDF
0.234
J
ES 23478-PeCDF
72.4
123478-HxCDF
EMPC
0.0652
J
ES 123478-HxCDF
72.5
123678-HxCDF
EMPC
0.0575
J
ES 123678-HxCDF
73.6
234678-HxCDF
EMPC
0.103
J
ES 234678-HxCDF
80.9
123789-HxCDF
ND
0.0333
ES 123789-HxCDF
70.4
1234678-HpCDF
EMPC
0.151
J B
ES 1234678-HpCDF
71.6
1234789-HpCDF
ND
0.0501
ES 1234789-HpCDF
72.6
OCDF
ND
0.104
ES OCDF
51.1
Totals
!Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
87.8
Total TCDD
0.537
0.537
CS 12347-PeCDD
91.7
Total PeCDD
0.243
0.243
CS 12346-PeCDF
86.9
Total HxCDD
1.35
1.35
CS 123469-HxCDF
86.2
Total HpCDD
3.15
3.3
CS 1234689-HpCDF
85.9
AS 1368-TCDD
80.8
Total TCDF
0.363
0.441
AS 1368-TCDF
80.3
Total PeCDF
0.445
0.674
Total HxCDF
0.343
0.569
Total HpCDF
ND
0.262
Total PCDD/Fs
22.2
23.2
WHO-2005 TEQs
TEQ: ND=0
0.66
0.684
5500 Business Drive
0.0774
0.687
Wilmington, NC 28405, USA
SGS1
TEQ: ND=DU2
TEQ: ND=DL
0.667
0.673
0.155
0.689
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 128-860-BBK
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 09:59 Analyst: AC

Sample ID: Comp#4 Site 1 Common CE TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_004
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
QC Batch No.: 12595
Date Collected: 26-Aug-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 07-Oct-2014 21:06
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
0.153
J
0.0535
0.153
0.153
0.153
12378-PeCDD
0.243
J
0.0581
0.122
0.243
0.243
123478-HxCDD
0.271
J
0.0442
0.0271
0.0271
0.0271
123678-HxCDD
0.706
J
0.0481
0.0706
0.0706
0.0706
123789-HxCDD
0.372
J B
0.0466
0.0372
0.0372
0.0372
1234678-HpCDD
3.15
0.0569
0.0315
0.0315
0.0315
OCDD
15.8
0.117
0.0158
0.00158
0.00473
2378-TCDF
0.22
J
0.0394
0.022
0.022
0.022
12378-PeCDF
(0.0378)
0.0378
(0.00189)
(0.00189)
(0.00113)
23478-PeCDF
0.234
J
0.0399
0.117
0.117
0.0703
123478-HxCDF
[0.0652]
J
0.0259
[0.00652]
[0.00652]
[0.00652]
123678-HxCDF
[0.0575]
J
0.0256
[0.00575]
[0.00575]
[0.00575]
234678-HxCDF
[0.103]
J
0.0243
[0.0103]
[0.0103]
[0.0103]
123789-HxCDF
(0.0333)
0.0333
(0.00333)
(0.00333)
(0.00333)
1234678-HpCDF
[0.151]
J B
0.0354
[0.00151]
[0.00151]
[0.00151]
1234789-HpCDF
(0.0501)
0.0501
(0.000501)
(0.000501)
(0.000501)
OCDF
(0.104)
0.104
(0.000104)
(0.0000104)
(0.0000312)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.596
0.704
0.66
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.603
0.711
0.667
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.61
0.718
0.673
www.us.sgs.com
EMPC = 0, < J-level = 0
0.0473
0.0331
0.0362
SGS
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.62
0.623
0.626
0.728
0.731
0.734
0.684
0.687
0.689
EMPC = EMPC, < J-level = 0
0.0473
0.0331
0.0362
Checkcode: 128.860-B B K
SGS Environmental Services - D/F 2014 Rev. 4.31
)))))))))))Y)))))))))))) )))))))))) ) ) ) )

Sample ID: Comp#5 Site 2 Bluegill Method 1613B
Client Data
CZR Incorporated
2014 Annual Fish Project
22-Sep-2014
Sample Data
Laboratory Data
Date Received: 30-Sep-2014
Date Extracted: 02-Oct-2014
Date Analyzed: 07-Oct-2014
Time Analyzed: 22:00:01
Name:
Project ID:
Date Collected:
Matrix: Tissue
WeightNolume: 10.08 g
% Lipid: 0.298
Split: -
Lab Project ID: A7174
Lab Sample ID A7174_12595_DF_005
QC Batch No: 12595
Dilution: -
Analyte
Conc. (pglg)
DL (pg/g)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD --
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-11pCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
- -- - ND- -
ND
ND
ND
0.128
0.226
1.27
ND
ND
ND
ND
ND
ND
ND
0.0509
ND
0.181
- 0.0597
0.0642
0.0431
0.0461
0.0409
0.0295
0.0369
0.037
0.0365
0.0357
0.0518
0.0579
J B
J B
J B
J B
J B
ES 2378-TCDD
ES 12378-PeCDD
ES 123478-HxCDD
ES 123678-HxCDD
ES 123789-HxCDD
ES 1234678-HpCDD
ES OCDD
ES 2378-TCDF
ES 12378-PeCDF
ES 23478-PeCDF
ES 123478-HxCDF
ES 123678-HxCDF
ES 234678-HxCDF
ES 123789-HxCDF
ES 1234678-HpCDF
ES 1234789-HpCDF
-ES OCDF
82.2
81.6
80.6
73.6
71.2
69.6
53.6
81.8
86.2
75.7
73.7
73.3
81.3
70.1
69
68.8
49.7
Totals
Standard
CS/AS Recoveries
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
0.128
0.351
ND
ND
ND
0.0509
0.0597
0.0642
0.0409
0.0329
0.0397
ND
ND
0.128
0.351
ND
ND
ND
0.0509
CS 37CI-2378-TCDD
CS 12347-PeCDD
CS 12346-PeCDF
CS 123469-HxCDF
CS 1234689-HpCDF
AS 1368-TCDD
AS 1368-TCDF
95.9
97.2
95.2
88.6
83.6
94.3
93.2
Total PCDD/Fs
1.98
1.98
WHO-2005 TEQs
TEQ: ND=O
TEQ: ND=DU2
TEQ: ND=DL
0.0161
0.0988
0.182
0.0857
0.171
0.0161
0.0988
0.182
SGS1
5500 Business Drive
Wilmington, NC 28405, USA
www.us.sgs.com
[phone]; Toll -Free 866 846-8290
Tel:
Checkcode: 906-864-PJY
SGS Environmental Services - D!F 2014 Rev. 4.31
Report Created: 09-Oct-2014 09:59 Analyst: AC

Sample ID: Comp#5 Site 2 Bluegill TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_005
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.08 g
QC Batch No.: 12595
Date Collected: 22-Sep-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 07-Oct-2014 22:00
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
(0.0597)
0.0597
(0.0597)
(0.0597)
(0.0597)
12378-PeCDD
(0.0642)
0.0642
(0.0321)
(0.0642)
(0.0642)
123478-1-IxCDD
(0.0431)
0.0431
(0.00431)
(0.00431)
(0.00431)
123678-HxCDD
(0.0461)
0.0461
(0.00461)
(0.00461)
(0.00461)
123789-HxCDD
0.128
J B
0.0472
0.0128
0.0128
0.0128
1234678-HpCDD
0.226
J B
0.0636
0.00226
0.00226
0.00226
OCDD
1.27
J B
0.134
0.00127
0.000127
0.000382
2378-TCDF
(0.0409)
0.0409
(0.00409)
(0.00409)
(0.00409)
12378-PeCDF
(0.0295)
0.0295
(0.00148)
(0.00148)
(0.000885)
23478-PeCDF
(0.0369)
0.0369
(0.0185)
(0.0185)
(0.0111)
123478-HxCDF
(0.037)
0.037
(0.0037)
(0.0037)
(0.0037)
123678-HxCDF
(0.0365)
0.0365
(0.00365)
(0.00365)
(0.00365)
234678-HxCDF
(0.0357)
0.0357
(0.00357)
(0.00357)
(0.00357)
123789-HxCDF
(0.0518)
0.0518
(0.00518)
(0.00518)
(0.00518)
1234678-HpCDF
0.0509
J B
0.0396
0.000509
0.000509
0.000509
1234789-H pC DF
(0.0579)
0.0579
(0.000579)
(0.000579)
(0.000579)
OCDF
0.181
J B
0.163
0.000181
0.0000181
0.0000544
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.0171
0.0158
0.0161
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.0878
0.103
0.0988
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.158
0.189
0.182
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
SGS
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.0171
0.0878
0.158
0.0158
0.103
0.189
0.0161
0.0988
0.182
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 906-864-PJY
SGS Environmental Services - D/F 2014 Rev. 4.31
))))))))))))))))))))))))))))))))))))))))

Sample ID: Comp#6 Site 2 Bluegill Method 1613B
Client Data
Samule Data
Laboratory Data
Name: CZR Incorporated
Matrix:
Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
WeightNolume: 10.00 g
Lab Sample ID A7174_12595_DF_006
Date Extracted: 02-Oct-2014
Date Collected: 24-Sep-2014
% Lipid: 0.536
QC Batch No: 12595
Date Analyzed: 07-Oct-2014
Split: -
Dilution: -
Time Analyzed: 22:53:19
Analyte
Conc. (pglg)
DL (pg/g)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD
- ND-
0.0518
ES 2378-TCDD
82.9
12378-PeCDD
ND
0.068
ES 12378-PeCDD
79.2
123478-HxCDD
ND
0.0495
ES 123478-HxCDD
71
123678-HxCDD
EMPC
0.0611
J
ES 123678-HxCDD
65.5
123789-HxCDD
EMPC
0.0911
J B
ES 123789-HxCDD
59.8
1234678-HpCDD
0.167
J B
ES 1234678-HpCDD
51
OCDD
0.584
J B
ES OCDD
32.8
2378-TCDF
ND
0.0348
ES 2378-TCDF
84.4
12378-PeCDF
ND
0.0358
ES 12378-PeCDF
85
23478-PeCDF
ND
0.0413
ES 23478-PeCDF
78.3
123478-HxCDF
ND
0.0306
ES 123478-HxCDF
70.8
123678-HxCDF
ND
0.0284
ES 123678-HxCDF
71.5
234678-HxCDF
ND
0.0317
ES 234678-HxCDF
71.4
123789-HxCDF
ND
0.0419
ES 123789-HxCDF
64.4
1234678-HpCDF
ND
0.054
ES 1234678-HpCDF
56.4
1234789-HpCDF
ND
0.0924
ES 1234789-HpCDF
56.1
OCDF
ND
0.219
-ES OCDF
35.2
Totals
Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
91.1
Total TCDD
ND
0.0518
ND
CS 12347-PeCDD
95.1
Total PeCDD
ND
0.068
ND
CS 12346-PeCDF
91
Total HxCDD
ND
0.152
CS 123469-HxCDF
84.5
Total HpCDD
0.167
0.167
CS 1234689-HpCDF
79.4
AS 1368-TCDD
86
Total TCDF
ND
0.0348
ND
AS 1368-TCDF
85.6
Total PeCDF
0.0607
0.0607
Total HxCDF
ND
0.0326
ND
Total HpCDF
ND
0.071
ND
Total PCDD/Fs
0.812
0.964
WHO-2005 TEQs
TEQ: ND=O
0.00185
0.0171
5500 Business Drive
TEQ: ND=DU2
0.086
0.0847
0.0953
SGS1
Wilmington, NC 28405, USA
TEQ: ND=DL
0.17
0.169
0.174
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 232-687-RSH
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:00 Analyst: AC

Sample ID: Comp#6 Site 2 Bluegill TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_006
Cliend Project ID: 2014 Annual Fish Project
Weight/Volume: 10.00 g
QC Batch No.: 12595
Date Collected: 24-Sep-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 07-Oct-2014 22:53
Lab Project No: A7174
Units pglg
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
(0.0518)
0.0518
(0.0518)
(0.0518)
(0.0518)
12378-PeCDD
(0.068)
0.068
(0.034)
(0.068)
(0.068)
123478-HxCDD
(0.0495)
0.0495
(0.00495)
(0.00495)
(0.00495)
123678-HxCDD
[0.0611]
J
0.0557
[0.00611]
[0.00611]
[0.00611]
123789-HxCDD
[0.0911]
J B
0.0624
[0.00911]
[0.00911]
[0.00911]
1234678-HpCDD
0.167
J B
0.0957
0.00167
0.00167
0.00167
OCDD
0.584
J B
0.213
0.000584
0.0000584
0.000175
2378-TCDF
(0.0348)
0.0348
(0.00348)
(0.00348)
(0.00348)
12378-PeCDF
(0.0358)
0.0358
(0.00179)
(0.00179)
(0.00107)
23478-PeCDF
(0.0413)
0.0413
(0.0207)
(0.0207)
(0.0124)
123478-HxCDF
(0.0306)
0.0306
(0.00306)
(0.00306)
(0.00306)
123678-HxCDF
(0.0284)
0.0284
(0.00284)
(0.00284)
(0.00284)
234678-HxCDF
(0.0317)
0.0317
(0.00317)
(0.00317)
(0.00317)
123789-HxCDF
(0.0419)
0.0419
(0.00419)
(0.00419)
(0.00419)
1234678-HpCDF
(0.054)
0.054
(0.00054)
(0.00054)
(0.00054)
1234789-HpCDF
(0.0924)
0.0924
(0.000924)
(0.000924)
(0.000924)
OCDF
(0.219)
0.219
(0.000219)
(0.0000219)
(0.0000657)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.00226
0.00173
0.00185
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.074
0.0903
0.086
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.146
0.179
0.17
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
EMPC = EMPC, ND = 0
0.0175
0.0169
0.0171
EMPC =EMPC, ND = DL / 2
0.0833
0.0997
0.0953
EMPC = EMPC, ND = DL
0.149
0.182
0.174
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 232-687-RSH
SGS Environmental Services - D/F 2014 Rev. 4.31

Sample ID: Comp#7 Site 2 Blue Catfish Method 1613B
Client Data
Sample Data
Laboratory Data
Name:
CZR Incorporated
Matrix:
Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
Lab Sample ID A7174_12595_DF_007
Date Extracted: 02-Oct-2014
Date Collected: 27-Aug-2014
% Lipid: 1.456
QC Batch No: 12595
Date Analyzed: 08-Oct-2014
Split: -
Dilution: -
Time Analyzed: 01:41:14
Analyte
Conc. (pglg)
DL (pg/g)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD-
- -- 0.0759
J -
ES 2378=TCDD -
- 91.7
12378-PeCDD
EMPC
0.0936
J
ES 12378-PeCDD
95.5
123478-HxCDD
EMPC
0.0838
J
ES 123478-HxCDD
90
123678-HxCDD
0.285
J
ES 123678-HxCDD
84.1
123789-HxCDD
EMPC
0.206
J B
ES 123789-HxCDD
87.3
1234678-HpCDD
0.656
J B
ES 1234678-HpCDD
82.4
OCDD
1.95
J B
ES OCDD
60.5
2378-TCDF
ND
0.0354
ES 2378-TCDF
92.7
12378-PeCDF
EMPC
0.0459
J
ES 12378-PeCDF
101
23478-PeCDF
EMPC
0.0825
J
ES 23478-PeCDF
91.7
123478-HxCDF
EMPC
0.0473
J
ES 123478-HxCDF
86.1
123678-HxCDF
EMPC
0.0502
J
ES 123678-HxCDF
87
234678-HxCDF
EMPC
0.0572
J
ES 234678-HxCDF
94.4
123789-HxCDF
0.071
J
ES 123789-HxCDF
83.5
1234678-HpCDF
EMPC
0.105
J B
ES 1234678-HpCDF
84.5
1234789-HpCDF
EMPC
0.0834
J
ES 1234789-HpCDF
85.1
OCDF
0.336
J B
-ES OCDF
57.8
Totals
Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
101
Total TCDD
0.0759
0.0759
CS 12347-PeCDD
102
Total PeCDD
ND
0.0936
CS 12346-PeCDF
101
Total HxCDD
0.285
0.575
CS 123469-HxCDF
90.7
Total HpCDD
0.801
0.801
CS 1234689-HpCDF
90.6
AS 1368-TCDD
93.9
Total TCDF
ND
0.0354
ND
AS 1368-TCDF
94.8
Total PeCDF
ND
0.128
Total HxCDF
0.071
0.226
Total HpCDF
ND
0.189
Total PCDD/Fs
3.52
4.37
WHO-2005 TEQs
TEQ: ND=0
0.119
0.285
5500 Business Drive
TEQ: ND=DU2
0.171
0.081
0.287
SGS1
Wilmington, NC 28405, USA
TEQ: ND=DL
0.223
0.162
0.288
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 675-218-QFW
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:00 Analyst: AC

Sample ID: Comp#7 Site 2 Blue Catfish TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_007
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
QC Batch No.: 12595
Date Collected: 27-Aug-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 08-Oct-2014 01:41
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
0.0759
J
0.0443
0.0759
0.0759
0.0759
12378-PeCDD
[0.0936]
J
0.0614
[0.0468]
[0.0936]
[0.0936]
123478-HxCDD
[0.0838]
J
0.0602
[0.00838]
[0.00838]
[0.00838]
123678-HxCDD
0.285
J
0.0694
0.0285
0.0285
0.0285
123789-HxCDD
[0.206]
J B
0.0697
[0.0206]
[0.0206]
[0.0206]
1234678-HpCDD
0.656
J B
0.0551
0.00656
0.00656
0.00656
OCDD
1.95
J B
0.116
0.00195
0.000195
0.000584
2378-TCDF
(0.0354)
0.0354
(0.00354)
(0.00354)
(0.00354)
12378-PeCDF
[0.0459]
J
0.0364
[0.0023]
[0.0023]
[0.00138]
23478-PeCDF
[0.0825]
J
0.0412
[0.0412]
[0.0412]
[0.0247]
123478-HxCDF
[0.0473]
J
0.0404
[0.00473]
[0.00473]
[0.00473]
123678-HxCDF
[0.0502]
J
0.0398
[0.00502]
[0.00502]
[0.00502]
234678-HxCDF
[0.0572]
J
0.0414
[0.00572]
[0.00572]
[0.00572]
123789-HxCDF
0.071
J
0.0563
0.0071
0.0071
0.0071
1234678-HpCDF
[0.105]
J B
0.0329
[0.00105]
[0.00105]
[0.00105]
1234789-HpCDF
[0.0834]
J
0.0489
[0.000834]
[0.000834]
[0.000834]
OCDF
0.336
J B
0.101
0.000336
0.0000336
0.000101
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.12
0.118
0.119
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.162
0.175
0.171
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.203
0.232
0.223
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
SG$
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.257
0.259
0.261
0.302
0.304
0.305
0.285
0.287
0.288
EMPC = EMPC, < J-level = 0
0
0
0
Check code: 675-218-Q F W
SGS Environmental Services - D/F 2014 Rev. 4.31
) 3 ) )I ) 1 ) ) ) ) ) ) ) ) ) 1 ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) 3 3 ) 1 ) ) 3 3 3

Sample ID: Comp#8 Site 2 Common Carp Method 1613B
Client Data
Sample Data
Laboratory Data
Name: CZR Incorporated
Matrix: Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
WeightNolume: 10.05 g
Lab Sample ID A7174_12595_DF_008
Date Extracted: 02-Oct-2014
Date Collected: 28-Aug-2014
% Lipid: 0.836
QC Batch No: 12595
Date Analyzed: 08-Oct-2014
Split: -
Dilution: -
Time Analyzed: 02:34:31
Analyte
Conc. (pg!g)
DL (pg/g)
EMPC (pg/g)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD-
- EMPC
0.0932
J
ES 2378-TCDD
83.2
12378-PeCDD
0.147
J
ES 12378-PeCDD
79.8
123478-HxCDD
0.153
J
ES 123478-HxCDD
82.4
123678-HxCDD
0.296
J
ES 123678-HxCDD
76.5
123789-HxCDD
EMPC
0.182
J B
ES 123789-HxCDD
78.6
1234678-HpCDD
1.11
J B
ES 1234678-HpCDD
74.5
OCDD
4.85
J B
ES OCDD
61.2
2378-TCDF
0.127
J
ES 2378-TCDF
88.3
12378-PeCDF
ND
0.0393
ES 12378-PeCDF
87
23478-PeCDF
0.108
J
ES 23478-PeCDF
79
123478-HxCDF
ND
0.0485
ES 123478-HxCDF
77.1
123678-HxCDF
ND
0.0481
ES 123678-HxCDF
77.1
234678-HxCDF
0.0626
J
ES 234678-HxCDF
89.5
123789-HxCDF
ND
0.0644
ES 123789-HxCDF
74
1234678-HpCDF
0.0803
J B
ES 1234678-HpCDF
72.8
1234789-HpCDF
ND
0.0571
ES 1234789-HpCDF
75.4
OCDF
ND
0.128
ES OCDF
54.4
Totals
'Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
96.8
Total TCDD
ND
0.163
CS 12347-PeCDD
93.9
Total PeCDD
0.147
0.147
CS 12346-PeCDF
91.2
Total HxCDD
0.449
0.63
CS 123469-HxCDF
88.3
Total HpCDD
1.26
1.26
CS 1234689-HpCDF
86.7
AS 1368-TCDD
91.1
Total TCDF
0.127
0.127
AS 1368-TCDF
93
Total PeCDF
0.108
0.108
Total HxCDF
0.136
0.136
Total HpCDF
0.0803
0.148
Total PCDD/Fs
7.17
7.58
WHO-2005 TEQs
TEQ: ND=0
0.257
0.368
5500 Business Drive
TEQ: ND=DU2
0.301
0.113
0.377
SGSI Wilmington, NC 28405, USA
TEQ: ND=DL
0.344
0.227
0.386
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 446-588-ZCJ
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:00 Analyst: AC

Sample ID: Comp#8 Site 2 Common CE TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_008
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.05 g
QC Batch No.: 12595
Date Collected: 28-Aug-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 08-Oct-2014 02:34
Lab Project No: A7174
Units pglg
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
[0.0932]
J
0.0638
[0.0932]
[0.0932]
[0.0932]
12378-PeCDD
0.147
J
0.106
0.0736
0.147
0.147
123478-HxCDD
0.153
J
0.0496
0.0153
0.0153
0.0153
123678-HxCDD
0.296
J
0.055
0.0296
0.0296
0.0296
123789-HxCDD
[0.182]
J B
0.0571
[0.0182]
[0.0182]
[0.0182]
1234678-HpCDD
1.11
J B
0.0936
0.0111
0.0111
0.0111
OCDD
4.85
J B
0.146
0.00485
0.000485
0.00146
2378-TCDF
0.127
J
0.0475
0.0127
0.0127
0.0127
12378-PeCDF
(0.0393)
0.0393
(0.00197)
(0.00197)
(0.00118)
23478-PeCDF
0.108
J
0.0421
0.0542
0.0542
0.0325
123478-HxCDF
(0.0485)
0.0485
(0.00485)
(0.00485)
(0.00485)
123678-HxCDF
(0.0481)
0.0481
(0.00481)
(0.00481)
(0.00481)
234678-HxCDF
0.0626
J
0.0443
0.00626
0.00626
0.00626
123789-HxCDF
(0.0644)
0.0644
(0.00644)
(0.00644)
(0.00644)
1234678-HpCDF
0.0803
J B
0.0389
0.000803
0.000803
0.000803
1234789-H pCDF
(0.0571)
0.0571
(0.000571)
(0.000571)
(0.000571)
OCDF
(0.128)
0.128
(0.000128)
(0.0000128)
(0.0000384)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.208
0.278
0.257
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.253
0.322
0.301
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.297
0.366
0.344
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
SG$
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.32
0.329
0.339
0.389
0.398
0.408
0.368
0.377
0.386
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 446-588-ZCJ
SGS Environmental Services - D/F 2014 Rev. 4.31
))))))))))))))))))3)))))))))))))•))))))))))

Sample ID: Comp#9 Site 3 Bluegill Method 1613B
Client Data
Sam ' le Data
Laboratory Data
Name: CZR Incorporated
Matrix:
Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
Weight/Volume: 10.04 g
Lab Sample ID A7174_12595_DF_009
Date Extracted: 02-Oct-2014
Date Collected: 08-Sep-2014
% Lipid: 0.256
QC Batch No: 12595
Date Analyzed: 08-Oct-2014
Split: -
Dilution: -
Time Analyzed: 03:27:49
Analyte
Conc. (pg/g)
DL (pg/g)
EMPC (pg/g)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD - -
- - - ND - -
0.0612
ES 2378-TCDD
79.7
12378-PeCDD
ND
0.0688
ES 12378-PeCDD
75.6
123478-HxCDD
ND
0.0512
ES 123478-HxCDD
81.3
123678-HxCDD
ND
0.0608
ES 123678-HxCDD
71.8
123789-HxCDD
0.127
J B
ES 123789-HxCDD
74.2
1234678-HpCDD
0.109
J B
ES 1234678-HpCDD
71.8
OCDD
0.422
J B
ES OCDD
53
2378-TCDF
ND
0.046
ES 2378-TCDF
84.1
12378-PeCDF
ND
0.0367
ES 12378-PeCDF
83.4
23478-PeCDF
ND
0.0428
ES 23478-PeCDF
73.7
123478-HxCDF
ND
0.04
ES 123478-HxCDF
73.1
123678-HxCDF
ND
0.0363
ES 123678-HxCDF
72.7
234678-HxCDF
EMPC
0.0465
J
ES 234678-HxCDF
82.9
123789-HxCDF
ND
0.0476
ES 123789-HxCDF
77.1
1234678-HpCDF
EMPC
0.0333
J B
ES 1234678-HpCDF
70.4
1234789-HpCDF
ND
0.0495
ES 1234789-HpCDF
71.5
OCDF
ND
0.14
_ES OCDF
49.9
Totals
Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
96.7
Total TCDD
ND
0.0612
ND
CS 12347-PeCDD
92.3
Total PeCDD
ND
0.0688
ND
CS 12346-PeCDF
91.8
Total HxCDD
0.127
0.127
CS 123469-HxCDF
85.6
Total HpCDD
0.109
0.109
CS 1234689-HpCDF
86.1
AS 1368-TCDD
91.3
Total TCDF
ND
0.046
ND
AS 1368-TCDF
90.4
Total PeCDF
ND
0.0395
ND
Total HxCDF
ND
0.0465
Total HpCDF
ND
0.0333
Total PCDD/Fs
0.658
0.738
WHO-2005 TEQs
TEQ: ND=O
0.014
0.0189
5500 Business Drive
TEQ: ND=DU2
0.102
0.0916
0.105
SGS1
Wilmington, NC 28405, USA
TEQ: ND=DL
0.191
0.183
0.192
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 727-826-GTX
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:00 Analyst: AC

Sample ID: Comp#9 Site 3 Bluegill TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_009
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.04 g
QC Batch No.: 12595
Date Collected: 08-Sep-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 08-Oct-2014 03:27
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
(0.0612)
0.0612
(0.0612)
(0.0612)
(0.0612)
12378-PeCDD
(0.0688)
0.0688
(0.0344)
(0.0688)
(0.0688)
123478-HxCDD
(0.0512)
0.0512
(0.00512)
(0.00512)
(0.00512)
123678-HxCDD
(0.0608)
0.0608
(0.00608)
(0.00608)
(0.00608)
123789-HxCDD
0.127
J B
0.0579
0.0127
0.0127
0.0127
1234678-HpCDD
0.109
J B
0.0743
0.00109
0.00109
0.00109
OCDD
0.422
J B
0.147
0.000422
0.0000422
0.000127
2378-TCDF
(0.046)
0.046
(0.0046)
(0.0046)
(0.0046)
12378-PeCDF
(0.0367)
0.0367
(0.00184)
(0.00184)
(0.0011)
23478-PeCDF
(0.0428)
0.0428
(0.0214)
(0.0214)
(0.0128)
123478-HxCDF
(0.04)
0.04
(0.004)
(0.004)
(0.004)
123678-HxCDF
(0.0363)
0.0363
(0.00363)
(0.00363)
(0.00363)
234678-HxCDF
[0.0465]
J
0.0355
[0.00465]
[0.00465]
[0.00465]
123789-HxCDF
(0.0476)
0.0476
(0.00476)
(0.00476)
(0.00476)
1234678-HpCDF
[0.0333]
J B
0.0322
[0.000333]
[0.000333]
[0.000333]
1234789-HpCDF
(0.0495)
0.0495
(0.000495)
(0.000495)
(0.000495)
OCDF
(0.14)
0.14
(0.00014)
(0.000014)
(0.000042)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.0142
0.0139
0.014
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.09
0.107
0.102
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.166
0.2
0.19
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
SGS
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.0192
0.0931
0.167
0.0188
0.11
0.201
0.0189
0.105
0.192
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 727-826-GTX
SGS Environmental Services - D/F 2014 Rev. 4.31
)))))))))))))))))))))))))))))))))► ))))))))))

Sample ID: Comp#10 Site 3 Bluegill Method 1613B
Client Data
CZR Incorporated
2014 Annual Fish Project
08-Sep-2014
Sample Data,
Tissue
10.03 g
0.418
-
Laboratory Data
Date Received: 30-Sep-2014
Date Extracted: 02-Oct-2014
Date Analyzed: 08-Oct-2014
Time Analyzed: 04:21:05
Name:
Project ID:
Date Collected:
Matrix:
Weight/Volume:
% Lipid:
Split:
Lab Project ID: A7174
Lab Sample ID A7174_12595_DF_010
QC Batch No: 12595
Dilution: -
Analyte
Conc. (pglg)
DL (pglg)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD -
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
-- ND -- -- -
ND
ND
EMPC
EMPC
0.167
0.582
ND
ND
ND
ND
ND
0.0664
ND
ND
ND
ND
- - 0.0613
0.093
0.06
0.0474
0.0465
0.0542
0.0389
0.0398
0.0566
0.0489
0.0751
0.155
0.065
0.135
J
J B
J B
J B
J
ES 2378-TCDD -
ES 12378-PeCDD
ES 123478-HxCDD
ES 123678-HxCDD
ES 123789-HxCDD
ES 1234678-HpCDD
ES OCDD
ES 2378-TCDF
ES 12378-PeCDF
ES 23478-PeCDF
ES 123478-HxCDF
ES 123678-HxCDF
ES 234678-HxCDF
ES 123789-HxCDF
ES 1234678-HpCDF
ES 1234789-HpCDF
-ES OCDF
89.4
85.4
80.9
77.6
80.5
78.9
60.3
89.9
89.9
80.1
79.4
80.3
90
75.1
76.9
74.8
54.8
Totals
Standard
CS/AS Recoveries
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
0.167
ND
ND
0.0664
ND
0.0613
0.093
0.0474
0.05
0.0604
ND
ND
0.2
0.296
ND
ND
0.0664
ND
CS 37CI-2378-TCDD
CS 12347-PeCDD
CS 12346-PeCDF
CS 123469-HxCDF
CS 1234689-HpCDF
AS 1368-TCDD
AS 1368-TCDF
104
99.9
92.4
88.5
86.8
96.1
92.6
Total PCDD!Fs
0.816
1.15
WHO-2005 TEQs
TEQ: ND=O
TEQ: ND=DU2
TEQ: ND=DL
0.00849
0.113
0.218
0.107
0.213
0.0285
0.127
0.226
SGS1
5500 Business Drive
Wilmington, NC 28405, USA
www.us.sgs.com
[phone]; Toil -Free 866 846-8290
Tel:
Checkcode: 264-816-QSX
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:01 Analyst: AC

Sample ID: Comp#10 Site 3 Bluegill TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_010
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
QC Batch No.: 12595
Date Collected: 08-Sep-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 08-Oct-2014 04:21
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
(0.0613)
0.0613
(0.0613)
(0.0613)
(0.0613)
12378-PeCDD
(0.093)
0.093
(0.0465)
(0.093)
(0.093)
123478-HxCDD
(0.06)
0.06
(0.006)
(0.006)
(0.006)
123678-HxCDD
[0.065]
J
0.0575
[0.0065]
[0.0065]
[0.0065]
123789-HxCDD
[0.135]
J B
0.0587
[0.0135]
[0.0135]
[0.0135]
1234678-HpCDD
0.167
J B
0.0672
0.00167
0.00167
0.00167
OCDD
0.582
J B
0.178
0.000582
0.0000582
0.000175
2378-TCDF
(0.0474)
0.0474
(0.00474)
(0.00474)
(0.00474)
12378-PeCDF
(0.0465)
0.0465
(0.00233)
(0.00233)
(0.0014)
23478-PeCDF
(0.0542)
0.0542
(0.0271)
(0.0271)
(0.0163)
123478-HxCDF
(0.0389)
0.0389
(0.00389)
(0.00389)
(0.00389)
123678-HxCDF
(0.0398)
0.0398
(0.00398)
(0.00398)
(0.00398)
234678-HxCDF
0.0664
J
0.0352
0.00664
0.00664
0.00664
123789-HxCDF
(0.0566)
0.0566
(0.00566)
(0.00566)
(0.00566)
1234678-H pC D F
(0.0489)
0.0489
(0.000489)
(0.000489)
(0.000489)
1234789-HpCDF
(0.0751)
0.0751
(0.000751)
(0.000751)
(0.000751)
OCDF
(0.155)
0.155
(0.000155)
(0.0000155)
(0.0000465)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.0089
0.00837
0.00849
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.0962
0.119
0.113
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.183
0.229
0.218
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
EMPC = EMPC, ND = 0
0.0289
0.0284
0.0285
EMPC = EMPC, ND = DL / 2
0.11
0.133
0.127
EMPC = EMPC, ND = DL
0.192
0.238
0.226
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 264-816-QSX
SGS Environmental Services - D/F 2014 Rev. 4.31
))))))))))))))))))))))))))))))))))l))))))))

Sample ID: Comp#11 Site 3 Blue Catfish Method 1613B
Client Data
Sample Data
Laboratory Data
Name:
CZR Incorporated
Matrix:
Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
Weight/Volume: 10.03 g
Lab Sample ID A7174_12595_DF_011
Date Extracted: 02-Oct-2014
Date Collected: 09-Sep-2014
% Lipid: 1.79
QC Batch No: 12595
Date Analyzed: 08-Oct-2014
Split: -
Dilution: -
Time Analyzed: 05:14:23
Analyte
Conc. (pg/g)
DL (pg!g)
EMPC (pg/g)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD
- EMPC- -
-- - -
0.0597
J-
ES 2378-TCDD
85
12378-PeCDD
EMPC
0.109
J
ES 12378-PeCDD
81.5
123478-HxCDD
ND
0.0672
ES 123478-HxCDD
81.7
123678-HxCDD
0.298
J
ES 123678-HxCDD
73.1
123789-HxCDD
0.247
J B
ES 123789-HxCDD
74.5
1234678-HpCDD
0.771
J B
ES 1234678-HpCDD
74.6
OCDD
2.23
J B
ES OCDD
62.6
2378-TCDF
ND
0.0464
ES 2378-TCDF
86.4
12378-PeCDF
ND
0.0368
ES 12378-PeCDF
87.9
23478-PeCDF
0.0709
J
ES 23478-PeCDF
76
123478-HxCDF
ND
0.036
ES 123478-HxCDF
71.9
123678-HxCDF
ND
0.0342
ES 123678-HxCDF
71.9
234678-HxCDF
ND
0.0296
ES 234678-HxCDF
81.2
123789-HxCDF
ND
0.0447
ES 123789-HxCDF
71.6
1234678-HpCDF
0.0561
J B
ES 1234678-HpCDF
72.3
1234789-HpCDF
ND
0.064
ES 1234789-HpCDF
74
OCDF
ND
0.144
_ES OCDF
57.2
Totals
Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
98.7
Total TCDD
ND
0.0597
CS 12347-PeCDD
95.5
Total PeCDD
ND
0.109
CS 12346-PeCDF
92.9
Total HxCDD
0.545
0.545
CS 123469-HxCDF
82.7
Total HpCDD
0.924
0.924
CS 1234689-HpCDF
85.1
AS 1368-TCDD
94.3
Total TCDF
ND
0.0464
ND
AS 1368-TCDF
94.5
Total PeCDF
0.0709
0.0709
Total HxCDF
0.0425
0.0425
Total HpCDF
0.0561
0.0561
Total PCDD/Fs
3.86
4.03
WHO-2005 TEQs
TEQ: ND=0
0.0847
0.253
5500 Business Drive
TEQ: ND=DU2
TEQ: ND=DL
0.161
0.238
0.0912
0.182
0.267
0.281
SGS1
Wilmington, NC 28405, USA
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 723-046-SJC
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:01 Analyst: AC

Sample ID: Comp#11 Site 3 Blue Catfis TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_011
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.03 g
QC Batch No.: 12595
Date Collected: 09-Sep-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 08-Oct-2014 05:14
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
[0.0597]
J
0.0573
[0.0597]
[0.0597]
[0.0597]
12378-PeCDD
[0.109]
J
0.0679
[0.0544]
[0.109]
[0.109]
123478-HxCDD
(0.0672)
0.0672
(0.00672)
(0.00672)
(0.00672)
123678-HxCDD
0.298
J
0.0726
0.0298
0.0298
0.0298
123789-HxCDD
0.247
J B
0.073
0.0247
0.0247
0.0247
1234678-HpCDD
0.771
J B
0.0679
0.00771
0.00771
0.00771
OCDD
2.23
J B
0.136
0.00223
0.000223
0.000668
2378-TCDF
(0.0464)
0.0464
(0.00464)
(0.00464)
(0.00464)
12378-PeCDF
(0.0368)
0.0368
(0.00184)
(0.00184)
(0.0011)
23478-PeCDF
0.0709
J
0.0462
0.0354
0.0354
0.0213
123478-HxCDF
(0.036)
0.036
(0.0036)
(0.0036)
(0.0036)
123678-HxCDF
(0.0342)
0.0342
(0.00342)
(0.00342)
(0.00342)
234678-HxCDF
(0.0296)
0.0296
(0.00296)
(0.00296)
(0.00296)
123789-HxCDF
(0.0447)
0.0447
(0.00447)
(0.00447)
(0.00447)
1234678-HpCDF
0.0561
J B
0.0408
0.000561
0.000561
0.000561
1234789-HpCDF
(0.064)
0.064
(0.00064)
(0.00064)
(0.00064)
OCDF
(0.144)
0.144
(0.000144)
(0.0000144)
(0.0000432)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.1
0.0984
0.0847
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.16
0.175
0.161
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.22
0.252
0.237
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
SGS1
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL 12
EMPC = EMPC, ND = DL
0.215
0.229
0.243
0.267
0.281
0.295
0.253
0.267
0.281
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 723-046-SJC
SGS Environmental Services - D/F 2014 Rev. 4.31
))))))))))))))))))))))))))))))))))))))))))

Sample ID: Comp#12 Site 3 Common Carp Method 1613B
Client Data
Sample Data
Laboratory Data
Name: CZR Incorporated
Matrix:
Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
WeightNolume: 10.00 g
Lab Sample ID A7174_12595_DF_012
Date Extracted: 02-Oct-2014
Date Collected: 09-Sep-2014
% Lipid: 1.47
QC Batch No: 12595
Date Analyzed: 08-Oct-2014
Split: -
Dilution: -
Time Analyzed: 06:07:39
Analyte
Conc. (pglg)
DL (pglg)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD -
-EMPC
- -
0.0813
J -
ES 2378-TCDD
84.9
12378-PeCDD
EMPC
0.112
J
ES 12378-PeCDD
83
123478-HxCDD
0.127
J
ES 123478-HxCDD
83.4
123678-HxCDD
0.412
J
ES 123678-HxCDD
76
123789-HxCDD
0.236
J B
ES 123789-HxCDD
71.2
1234678-HpCDD
1.69
J
ES 1234678-HpCDD
60.9
OCDD
6.4
B
ES OCDD
28.9
2378-TCDF
EMPC
0.179
J
ES 2378-TCDF
86.6
12378-PeCDF
ND
0.0377
ES 12378-PeCDF
87.1
23478-PeCDF
0.112
J
ES 23478-PeCDF
78.1
123478-HxCDF
ND
0.039
ES 123478-HxCDF
78.4
123678-HxCDF
ND
0.0384
ES 123678-HxCDF
78.5
234678-HxCDF
EMPC
0.0422
J
ES 234678-HxCDF
84
123789-HxCDF
ND
0.0501
ES 123789-HxCDF
75.9
1234678-HpCDF
0.114
J B
ES 1234678-HpCDF
66.7
1234789-HpCDF
ND
0.0524
ES 1234789-HpCDF
73
OCDF
ND
0.176
ES OCDF
42.3
Totals
Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
96.4
Total TCDD
0.227
0.308
CS 12347-PeCDD
94.7
Total PeCDD
ND
0.112
CS 12346-PeCDF
92.2
Total HxCDD
0.775
0.775
CS 123469-HxCDF
88.7
Total HpCDD
1.79
1.79
CS 1234689-HpCDF
88.6
AS 1368-TCDD
90.2
Total TCDF
0.101
0.28
AS 1368-TCDF
87.3
Total PeCDF
0.112
0.258
Total HxCDF
ND
0.166
Total HpCDF
0.114
0.187
Total PCDD/Fs
9.52
10.3
WHO-2005 TEQs
TEQ: ND=O
0.131
0.346
5500 Business Drive
TEQ: ND=DU2
0.193
0.0777
0.354
G
Wilmington, NC 28405, USA
TEQ: ND=DL
0.255
0.155
0.361
www.us.sgs.com
Tel: [phone]; Toff -Free 866 846-8290
Checkcode: 730-995-LMN
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:01 Analyst: AC

Sample ID: Comp#12 Site 3 Common C TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_012
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.00 g
QC Batch No.: 12595
Date Collected: 09-Sep-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 08-Oct-2014 06:07
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
[0.0813]
J
0.0451
[0.0813]
[0.0813]
[0.0813]
12378-PeCDD
[0.112]
J
0.0563
[0.0559)
[0.112]
[0.112]
123478-HxCDD
0.127
J
0.0525
0.0127
0.0127
0.0127
123678-HxCDD
0.412
J
0.0592
0.0412
0.0412
0.0412
123789-HxCDD
0.236
J B
0.0625
0.0236
0.0236
0.0236
1234678-HpCDD
1.69
J
0.0867
0.0169
0.0169
0.0169
OCDD
6.4
B
0.208
0.0064
0.00064
0.00192
2378-TCDF
[0.179]
J
0.0375
[0.0179]
[0.0179]
[0.0179]
12378-PeCDF
(0.0377)
0.0377
(0.00189)
(0.00189)
(0.00113)
23478-PeCDF
0.112
J
0.0439
0.056
0.056
0.0336
123478-HxCDF
(0.039)
0.039
(0.0039)
(0.0039)
(0.0039)
123678-HxCDF
(0.0384)
0.0384
(0.00384)
(0.00384)
(0.00384)
234678-HxCDF
[0.0422]
J
0.0381
[0.00422]
[0.00422)
[0.00422]
123789-HxCDF
(0.0501)
0.0501
(0.00501)
(0.00501)
(0.00501)
1234678-HpCDF
0.114
J B
0.035
0.00114
0.00114
0.00114
1234789-HpCDF
(0.0524)
0.0524
(0.000524)
(0.000524)
(0.000524)
OCDF
(0.176)
0.176
(0.000176)
(0.0000176)
(0.0000528)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.158
0.152
0.131
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.206
0.214
0.193
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.254
0.276
0.255
www.us.sgs.com
EMPC = 0, < J-level = 0
0.0064
0.00064
0.00192
EMPC = EMPC, ND = 0
0.317
0.367
0.346
EMPC = EMPC, ND = DL / 2
0.325
0.375
0.354
EMPC = EMPC, ND = DL
0.333
0.383
0.361
EMPC = EMPC, < J-level = 0
0.0064
0.00064
0.00192
C h e ckcode: 730-995-L M N
SGS Environmental Services - D/F 2014 Rev. 4.31
) 1) 1)))))))))))) )
))))))))))) ))))))) ) ) )

Sample ID: Comp#13 Site 1 Blue Catfish Method 1613B
Client Data
Sample Data
Laboratory Data
Name: CZR Incorporated
Matrix: Tissue
Lab Project ID: A7174
Date Received: 30-Sep-2014
Project ID: 2014 Annual Fish Project
WeightNolume: 10.01 g
Lab Sample ID A7174_12595_DF_013
Date Extracted: 02-Oct-2014
Date Collected: 26-Aug-2014
% Lipid: 1.99
QC Batch No: 12595
Date Analyzed: 08-Oct-2014
Split: -
Dilution: -
Time Analyzed: 07:00:57
Analyte
Conc. (pglg)
DL (pg/g)
EMPC (pg/g)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD
- - 0.0972
J
ES 2378-TCDD
91.1
12378-PeCDD
EMPC
0.181
J
ES 12378-PeCDD
90.8
123478-HxCDD
0.182
J
ES 123478-HxCDD
89
123678-HxCDD
0.487
J
ES 123678-HxCDD
79.7
123789-HxCDD
0.33
J B
ES 123789-HxCDD
84.3
1234678-HpCDD
1.57
J
ES 1234678-HpCDD
81
OCDD
5.55
B
ES OCDD
65.3
2378-TCDF
0.0955
J
ES 2378-TCDF
93.3
12378-PeCDF
ND
0.0389
ES 12378-PeCDF
93.6
23478-PeCDF
0.15
J
ES 23478-PeCDF
85.8
123478-HxCDF
ND
0.0333
ES 123478-HxCDF
82.7
123678-HxCDF
0.0535
J
ES 123678-HxCDF
83.6
234678-HxCDF
0.0608
J
ES 234678-HxCDF
90.7
123789-HxCDF
ND
0.0419
ES 123789-HxCDF
80.8
1234678-HpCDF
0.293
J B
ES 1234678-HpCDF
80.9
1234789-HpCDF
ND
0.0489
ES 1234789-HpCDF
81.4
OCDF
ND
0.0942
ES OCDF
60.6
Totals
Standard
CS/AS Recoveries
CS 37CI-2378-TCDD
98.4
Total TCDD
0.18
0.18
CS 12347-PeCDD
99.3
Total PeCDD
ND
0.248
CS 12346-PeCDF
95.5
Total HxCDD
1
1
CS 123469-HxCDF
90.3
Total HpCDD
1.57
1.74
CS 1234689-HpCDF
90.2
AS 1368-TCDD
92.2
Total TCDF
0.18
0.345
AS 1368-TCDF
93.1
Total PeCDF
0.381
0.424
Total HxCDF
0.114
0.29
Total HpCDF
0.293
0.356
Total PCDD/Fs
9.27
10.1
WHO-2005 TEQs
TEQ: ND=O
0.283
0.465
5500 Business Drive
TEQ: ND=DU2
TEQ: ND=DL
0.32
0.357
0.0837
0.167
0.469
0.474
SGS1
Wilmington, NC 28405, USA
www.us.sgs.com
Tel: [phone]; Toll -Free 866 846-8290
Checkcode: 877-284-LYV
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 10:02 Analyst: AC

Sample ID: Comp#13 Site 1 Blue Catfis TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: A7174_12595_DF_013
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.01 g
QC Batch No.: 12595
Date Collected: 26-Aug-2014
Split: -
Date Extracted: 02-Oct-2014
Date Received: 30-Sep-2014
Dilution: -
Date Analyzed: 08-Oct-2014 07:00
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
0.0972
J
0.0482
0.0972
0.0972
0.0972
12378-PeCDD
[0.181]
J
0.0645
[0.0907]
[0.181]
[0.181]
123478-HxCDD
0.182
J
0.0691
0.0182
0.0182
0.0182
123678-HxCDD
0.487
J
0.0761
0.0487
0.0487
0.0487
123789-HxCDD
0.33
J B
0.0747
0.033
0.033
0.033
1234678-HpCDD
1.57
J
0.061
0.0157
0.0157
0.0157
OCDD
5.55
B
0.119
0.00555
0.000555
0.00166
2378-TCDF
0.0955
J
0.0349
0.00955
0.00955
0.00955
12378-PeCDF
(0.0389)
0.0389
(0.00195)
(0.00195)
(0.00117)
23478-PeCDF
0.15
J
0.0434
0.075
0.075
0.045
123478-HxCDF
(0.0333)
0.0333
(0.00333)
(0.00333)
(0.00333)
123678-HxCDF
0.0535
J
0.0307
0.00535
0.00535
0.00535
234678-HxCDF
0.0608
J
0.0289
0.00608
0.00608
0.00608
123789-HxCDF
(0.0419)
0.0419
(0.00419)
(0.00419)
(0.00419)
1234678-HpCDF
0.293
J B
0.0334
0.00293
0.00293
0.00293
1234789-HpCDF
(0.0489)
0.0489
(0.000489)
(0.000489)
(0.000489)
OCDF
(0.0942)
0.0942
(0.0000942)
(0.00000942)
(0.0000283)
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.317
0.312
0.283
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.339
0.35
0.32
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.36
0.387
0.357
www.us.sgs.com
EMPC = 0, < J-level = 0
0.00555
0.000555
0.00166
SGS1
EMPC = EMPC, ND = 0
EMPC =EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.408
0.413
0.418
0.494
0.499
0.504
0.465
0.469
0.474
EMPC = EMPC, < J-level = 0
0.00555
0.000555
0.00166
Checkcode: 877-284-LYV
SGS Environmental Services - D/F 2014 Rev. 4.31
))) l 1 1) 1))))))))))))))))))))))))))))))) ) ) )

Sample ID: Method Blank A7174_12595 Method 1613B
Client Data
Sam • le Data
Laboratory Data
Date Received: n/a
Date Extracted: 02-Oct-2014
Date Analyzed: 07-Oct-2014
Time Analyzed: 17:33:37
Name: CZR Incorporated
Project ID: 2014 Annual Fish Project
Date Collected: n/a
Matrix: Tissue
WeightlVolume: 10.00 g
% Lipid: n/a
Split: -
Lab Project ID: A7174
Lab Sample ID MB1_12595_DF_SDS
QC Batch No: 12595
Dilution: -
Analyte
Conc. (pglg)
DL (pglg)
EMPC (pglg)
Qualifiers
Standard
ES Recoveries
Qualifiers
2378-TCDD -
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
234678-HxCDF
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
- --ND --
ND
ND
ND
EMPC
0.139
0.846
ND
ND
ND
ND
ND
ND
ND
EMPC
ND
0.182
-0.0496-
0.0619
0.0576
0.0658
0.0455
0.0366
0.042
0.0411
0.0401
0.0356
0.0524
0.0576
-- --
0.176
0.0661
-
J
J
J
J
J
ES 2378-TCDD -
ES 12378-PeCDD
ES 123478-HxCDD
ES 123678-HxCDD
ES 123789-HxCDD
ES 1234678-HpCDD
ES OCDD
ES 2378-TCDF
ES 12378-PeCDF
ES 23478-PeCDF
ES 123478-HxCDF
ES 123678-HxCDF
ES 234678-HxCDF
ES 123789-HxCDF
ES 1234678-HpCDF
ES 1234789-HpCDF
ES OCDF
88.7
84.9
87.1
81.1
82
82.9
65.1
90
93.2
81.4
82.5
83.6
97.5
79.1
82
82.4
61.7
Totals
Standard
CS/AS Recoveries
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
0.139
ND
ND
ND
ND
0.0496
0.0619
0.0455
0.039
0.0416
ND
ND
0.176
0.239
ND
ND
ND
0.0661
CS 37CI-2378-TCDD
CS 12347-PeCDD
CS 12346-PeCDF
CS 123469-HxCDF
CS 1234689-HpCDF
AS 1368-TCDD
AS 1368-TCDF
94.1
92
88.5
86.9
87.9
89.4
87.4
Total PCDD/Fs
1.17
1.51
WHO-2005 TEQs
TEQ: ND=O
TEQ: ND=DU2
TEQ: ND=DL
0.0017
0.085
0.168
0.0837
0.167
0.02
0.0998
0.18
G
5500 Business Drive
Wilmington, NC 28405, USA
www.us.sgs.com
[phone]; Toil -Free 866 846-8290
Tel:
Checkcode: 920-465-YCD
SGS Environmental Services - D/F 2014 Rev. 4.31
Report Created: 09-Oct-2014 09:29 Analyst: AC

Sample ID: Method Blank A7174_1259! TEQ Summary Method 1613B
Client Project Name: CZR Incorporated
Matrix: Tissue
Lab Sample ID: MB1_12595_DF_SDS
Cliend Project ID: 2014 Annual Fish Project
WeightNolume: 10.00 g
QC Batch No.: 12595
Date Collected: n/a
Split: -
Date Extracted: 02-Oct-2014
Date Received: n/a
Dilution: -
Date Analyzed: 07-Oct-2014 17:33
Lab Project No: A7174
Units pg/g
Analyte
Result
Qualifiers
DLs
I-TEQ
WHO-1998
WHO-2005
2378-TCDD
(0.0496)
0.0496
(0.0496)
(0.0496)
(0.0496)
12378-PeCDD
(0.0619)
0.0619
(0.031)
(0.0619)
(0.0619)
123478-HxCDD
(0.0576)
0.0576
(0.00576)
(0.00576)
(0.00576)
123678-HxCDD
(0.0658)
0.0658
(0.00658)
(0.00658)
(0.00658)
123789-HxCDD
[0.176]
J
0.0665
[0.0176]
[0.0176]
[0.0176]
1234678-HpCDD
0.139
J
0.0685
0.00139
0.00139
0.00139
OCDD
0.846
J
0.136
0.000846
0.0000846
0.000254
2378-TCDF
(0.0455)
0.0455
(0.00455)
(0.00455)
(0.00455)
12378-PeCDF
(0.0366)
0.0366
(0.00183)
(0.00183)
(0.0011)
23478-PeCDF
(0.042)
0.042
(0.021)
(0.021)
(0.0126)
123478-HxCDF
(0.0411)
0.0411
(0.00411)
(0.00411)
(0.00411)
123678-HxCDF
(0.0401)
0.0401
(0.00401)
(0.00401)
(0.00401)
234678-HxCDF
(0.0356)
0.0356
(0.00356)
(0.00356)
(0.00356)
123789-HxCDF
(0.0524)
0.0524
(0.00524)
(0.00524)
(0.00524)
1234678-HpCDF
[0.0661]
J
0.0371
[0.000661]
[0.000661]
[0.000661]
1234789-HpCDF
(0.0576)
0.0576
(0.000576)
(0.000576)
(0.000576)
OCDF
0.182
J
0.117
0.000182
0.0000182
0.0000547
TEQ Summaries
5500 Business Drive
EMPC = 0, ND = 0
0.00242
0.00149
0.0017
Wilmington, NC 28405, USA
EMPC = 0, ND = DL / 2
0.0748
0.0894
0.085
Tel: [phone]; Toll -Free 866 846-8290
EMPC = 0, ND = DL
0.147
0.177
0.168
www.us.sgs.com
EMPC = 0, < J-level = 0
0
0
0
SGS
EMPC = EMPC, ND = 0
EMPC = EMPC, ND = DL / 2
EMPC = EMPC, ND = DL
0.0207
0.0896
0.158
0.0198
0.104
0.189
0.02
0.0998
0.18
EMPC = EMPC, < J-level = 0
0
0
0
Checkcode: 920-465-YCD
SGS Environmental Services - D/F 2014 Rev. 4.31
)))))))))))))))) m)) 1 ) 1))))))))))) ))))))))) )

METHOD 1613B PCDD/F ONGOING PRECISION AND RECOVERY (OPR) FORM 8A
Lab Name: SGS Environmental Services
Initial Calibration: ICAL: MM3_DF_01172014 23AUG2014
Instrument ID: MM3 GC Column ID: ZB-5ms
VER Data Filename: 141007R12 Analysis Date: 07-OCT-2014 15:46:57
Lab ID: OPR1_12595_DF
SPIKE CONC. RANGE
NATIVE ANALYTES CONC. FOUND (ng/mL) OK
2,3,7,8-TCDD 10 9.84 6.7 15.8 Y
1,2,3,7,8-PeCDD 50 49.9 35 71 Y
1,2,3,4,7,8-HxCDD 50 53.6 35 82 Y
1,2,3,6,7,8-HxCDD 50 54.4 38 67 Y
1,2,3,7,8,9-HxCDD 50 50.6 32 81 Y
1,2,3,4,6,7,8-HpCDD 50 52.1 35 70 Y
OCDD 100 104 78 144 Y
2,3,7,8-TCDF 10 10 7.5 15.8 Y
1,2,3,7,8-PeCDF 50 50.7 40 67 Y
2,3,4,7,8-PeCDF 50 52.8 34 80 Y
1,2,3,4,7,8-HxCDF 50 50.9 36 67 Y
1,2,3,6,7,8-HxCDF 50 50.9 42 65 Y
2,3,4,6,7,8-HxCDF 50 50.9 35 78 Y
1,2,3,7,8,9-HxCDF 50 49.2 39 65 Y
1,2,3,4,6,7,8-HpCDF 50 53.4 41 61 Y
1,2,3,4,7,8,9-HpCDF 50 52.1 39 69 Y
OCDF 100 104 63 170 Y
Contract -required concentration limits for OPR as specified in Table 6,
Method 1613. 10/94
Processed: 09 Oct 2014 09:29 Analyst: AC

METHOD 1613B
PCDD/F ONGOING PRECISION AND RECOVERY (OPR) FORM 8B
Lab Name: SGS Environmental Services
Initial Calibration: ICAL: MM3 DF 01172014 23AUG2014
Instrument ID: MM3 GC Column ID:
VER Data Filename: 141007R12 Analysis Date:
Lab ID: OPR1 12595 DF
ZB-5ms
07-OCT-2014 15:46:57
SPIKE CONC. RANGE
LABELED ANALYTES CONC. FOUND (ng/mL) OK
13C-2,3,7,8-TCDD 100 91.5 20 175 Y
13C-1,2,3,7,8-PeCDD 100 88.4 21 227 Y
13C-1,2,3,4,7,8-HxCDD 100 88.2 21 193 Y
13C-1,2,3,6,7,8-HxCDD 100 82.3 25 163 Y
13C-1,2,3,7,8,9-HxCDD 100 83.6 26 166 Y
13C-1,2,3,4,6,7,8-HpCDD 100 83.2 26 166 Y
13C-OCDD 200 133 26 397 Y
13C-2,3,7,8-TCDF 100 90.8 22 152 Y
13C-1,2,3,7,8-PeCDF 100 97.4 21 192 Y
13C-2,3,4,7,8-PeCDF 100 83.5 13 328 Y
13C-1,2,3,4,7,8-HxCDF 100 83.4 19 202 Y
13C-1,2,3,6,7,8-HxCDF 100 84.1 21 159 Y
13C-2,3,4,6,7,8-HxCDF 100 97.9 22 176 Y
13C-1,2,3,7,8,9-HxCDF 100 82.4 17 205 Y
13C-1,2,3,4,6,7,8-HpCDF 100 83.5 21 158 Y
13C-1,2,3,4,7,8,9-HpCDF 100 85.2 20 186 Y
13C-OCDF 200 130 26 397 Y
CLEANUP STANDARD
37CI-2,3,7,8-TCDD
40 39.6 12.4 76.4 Y
Contract -required concentration limits for OPR as specified in Table 6,
Method 1613. 10/94
Processed: 09 Oct 2014 09:29
Analyst: AC

SG
Business Drive
Wilmington, NC 28405 USA
Tel: [phone]
Toll Free: 866 846-8290
Fax: [phone]
Sample Receipt Notification
Project Manager:
Receipt Date & Time:
AP Project name:
Requested TAT:
Projected due date:
Matrix:
Phone#:
Email Address:
Amy Boehm
30-Sep-14 at 14: 30
..17/7-1
21-Oct-14
Tissue
910-794-1613
[e-mail]
Company Contact:
Company:
Project Name & Site:
Project PO#:
QAAP/Contract #:
Requested Analysis:
Phone#:
Email Address:
Sam Cooper
CZR Incorporated
2014 Aninzia/ 1 islr l'rujert
S066133 5S9
N/A
Method 16138
9103929253
[e-mail]
Client Smp ID
AP Smp ID
Sample Condition & Notes
Quantity
Size
Sammy ling
Sampling Time
ReceivedTemp
Container #
Shipping #
Comp#1 Site 1 Bluegill
A7174_001
Bluegill (10 "A" fillets)
10
bag
25-Aug-14
00:00
-6
1
na
Comp#2 Site 1 Bluegill
A7174_002
Bluegill (10 "A" fillets)
10
bag
25-Aug-14
00:00
-6
1
na
Comp#3 Site 1 Blue Catfish
A7174_003
Blue Catfish (10 "A" fillets)
10
bag
26-Aug-14
00:00
-6
1
na
Comp#4 Site 1 Common Carp
A7174_004
Common Carp (9 "A" fillets)
9
bag
26-Aug-14
00:00
-6
1
na
Comp#5 Site 2 Bluegill
A7174_005
Bluegill (10 "A" fillets)
10
bag
22-Sep-14
00:00
-6
1
na
Comp#6 Site 2 Bluegill
A7174_006
Bluegill (10 "A" fillets)
10
bag
24-Sep-14
00:00
-6
1
na
Comp#7 Site 2 Blue Catfish
A7174_007
Blue Catfish (10 "A" fillets)
10
bag
27-Aug-14
00:00
-6
2
na
Comp#8 Site 2 Common Carp
A7174_008
Common Carp (2 "A" fillets)
2
bag
28-Aug-14
00:00
-6
2
na
Comp#9 Site 3 Bluegill
A7174_009
Bluegill (10 "A" fillets)
10
bag
08-Sep-14
00:00
-6
2
na
Comp#10 Site 3 Bluegill
A7174_010
Bluegill (10 "A" fillets)
10
bag
08-Sep-14
00:00
-6
2
na
Comp# 11 Site 3 Blue Catfish
A7174_011
Blue Catfish (7 "A" fillets)
7
bag
09-Sep-14
00:00
-6
2
na
Comp#12 Site 3 Common Carp
A7174_012
Common Carp (5 "A" fillets)
5
bag
09-Sep-14
00:00
-6
2
na
Comp#13 Site 1 Blue Catfish
A7174_013
Blue Catfish - replicate (10 "B" fillets)
10
bag
26-Aug-14
00:00
-6
2
na
Preservation Type:
Sample Seals: No
sample will be stored for 90 days from
storage fees may apply for any
than 90 days.
Notes/Comments:
Samples received intact
Any un-extracted
reporting date. Additional
samples stored longer
Received ht': Barham Hager
togged iu hv. Barbara Hager
All services are rendered in accordance with the applicable SGS General Conditions of Service accessible via:
http://www.ses.com/terms and conditions.htm
UC'ed IT: AK 30 Sep 14
SGS Analytical Perspectives

L
INCORPORATED
ENVIRONMENTAL CONSULTANTS
TO: SGS Environmental Services
Attn: Amy Boehm
5500 Business Drive
Wilmington, NC 28405
CHAIN OF CUSTODY
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROLINA 28403-1725
TEL [phone]
FAX [phone]
[e-mail]
FROM: Sam Cooper
CZR incorporated, Suite 2
4709 College Acres Drive
Wilmington, NC 28403
[e-mail]
DATE: 30 September 2014
RE: International Paper Company, Inc., 2014 Annual Fish Project (IP PO# S066133589 to SGS)
TESTS: Analysis of fish tissues for percent lipid (extraction) and 2, 3, 7, 8 TCDD (Dioxin), 2, 3, 7, 8, TCDF
(Furan) with full screen of congeners (Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans)
via EPA Method 1613B.
ENCLOSED ITEMS:
Thirteen (13) frozen composite fish tissue (fillets) samples, each fillet wrapped in aluminum foil (dull side toward
fish) and enclosed in labeled "zip -lock" plastic bags. Composites are identified below.
SAMPLE ID #
Composite # Site Species (number of fish fillets)
1 1 Bluegill (10 "A" fillets)
2 l Bluegill (10 "A" fillets)
3 1 Blue Catfish (10 "A" fillets)
4 1 Common Carp (9 "A" fillets)
5 2 Bluegill (10 "A" fillets)
6 2 Bluegill (10 "A" fillets)
7 2 Blue Catfish (10 "A" fillets)
8 2 Common Carp (2 "A" fillets)
9 3 Bluegill (10 "A" fillets)
10 3 Bluegill (10 "A" fillets)
11 3 Blue Catfish (14MITTITZT17
12 3 Common Carp (5 "A" fillets) t ea es It
13 1 Blue Catfish - replicate (10 "B" fillets)
COMMENTS:
- Send one digital version and two hard copies of the report to Sam Cooper/CZR at the above address. We
also request permission to include the report as an appendix to CZR's report summarizing the 2014
collection efforts and results.
- Forward the invoice to International Paper -Riegelwood, Shared Services, P.O. Box 792, Milford, OH
45150
- A detailed fish composite data table is also enclosed.
Relinquished by:
Received by:
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International Paper - Cape Fear River
whorl fnll with "Site 2. Blueaill (1), date caught, 'A' or 'B'' Put same species from same site in zip -lock by A or B fillet. A u left filial
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Blue Catfish (8)
Blue Catfish (12)
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Blue Catfish (5)
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01)14
Site 2 - 2014
International Paper - Cape Fear River
Label foil with "Site 2, Blueglll (1), date caught 'A' or 'B" Put same species from same site in zip lock by A or B fillet. A = left fillet
Date Caujht
By:
Date Filleted
By
Site
Species (it)
Total Length (mm)
Total Weight (g)
Fillet A Weight (g)
Fillet B Weight (g)
Potential
Composite
Alit-
8/27/2014
RP/NT
8/28/2014
LLB
2
Blue Catfish (6)
535
1,325
233
7
8/27/2014
RP/NT
8/28/2014
NT
2
Blue Catfish (4)
565
1,800
350
8/27/2014
RP/NT
8/28/2014
SF
2
Blue Catfish (3)
561
1,850
290
9/9/2014
RP/SC
9/10/2014
LLB
2
Blue Catfish (11)
569
1,950
315
9/9/2014
RP/SC
9/10/2014
SF
2
Blue Catfish (7)
607
2,300
362
9/9/2014
RP/SC
9/10/2014
SF
2
Blue Catfish(9)
624
2,425
363
9/9/2014
RP/SC
9/10/2014
SF
2
Blue Catfish (5)
670
3,075
415
9/10/2014
RP/SC
9/11/2014
SF
2
Blue Catfish (1)
664
3,550
480
9/10/2014
RP/SC
9/11/2014
NT
2
Blue Catfish (2)
680
3,600
495
9/23/2014
RP/SF
9/24/2014
SF
2
Blue Catfish (10)
693
3,600 _
540
9/22/2014
RP/SF
9/24/2014
RP
2
Bluegill (21)
151
60
16
5
9/23/2014
RP/SF
9/24/2014
SF
2
Bluegill(23)
149
60
14
9/23/2014
RP/SF-
9/24/2014
RP
2
Bluegitl(24)
147
62
14
9/23/2014
RP/SF
9/24/2014
SF
2
Bluegill (25)
151
63
16
9/23/2014
RP/SF
9/24/2014
RP
2
Bluegill (17)
152
65
16
9/23/2014
RP/SF
9/24/2014
SF
2
Blue(11lI15)
148
70
18
9/23/2014
RP/SF
9/24/2014
RP
2
Rluegill(15)
158
77
18
9/23/2014
RP/SF
9/24/2014
SF
2
Bluegi1l(8)
162
83
20
9/23/2014
RP/SF
9/24/2014
RP
2
Bluegill (11)
163
83
20
9/23/2014
RP/SF
9/24/2014
SF
2
Bluegitl(18)
173
97
20
9/23/2014
RP/SF
9/24/2014
SF
2
Bluegill (16)
167
100
20
6
9/23/2014
RP/SF
9/24/2014
RP
2
Bluegill (7)
181
122
22
9/23/2014
RP/SF
9/24/2014
RP
2
Bluegill(12)
182
124
24
9/23/2014
RP/SF
9/24/2014
SF
1
Bluegill (3)
175
125
20
9/23/2014
RP/SF
9/24/2014
SF
2
Bluegill (13)
189
138
28
9/23/2014
RP/SF
9/24/2014
SF
2
Bluegill(4L
192
152
30
9/23/2014
RP/SF
9/24/2014
LLB
2
Bluegill(2)
195
154
30
9/23/2014
RP/SF
9/24/2014
LLB
2
Bluegill(1)
200
160
39
9/23/2014
RP/SF
9/24/2014
RP
2
Bluegill(14)
219
200
34
9/23/2014
RP/SF
9/24/2014
Sr
2
Biuegill (10)
216
218
48
8/27/2014
RP/NT
8/28/2014
RP
2
Carp (2)
520
2,150
230
8
9/23/2014
RP/SF
9/24/2014
NT
2
Carp (1)
620
2,400
175
Composite 5
Comopslte 6
Composite 7
Composite 8
Site 2
Site 2
Site 2
Site 2
ulueglll
Rluegill
Blue catfish
Common carp
10
10
10
,8,11,15,17,18,21,23,24,25 - A title
1, 2,3,4, 7,10,12,13,14,16 - A fillets
1,2,3,4,5,6,7,9,10,11 - A fillets
1,2 - A fillets
)) ) 3 ) ) ) / ) ) ) ) ) ) ) l ) / l 3 3 3 / 3 ) 3 ) ) ) 3 ) 3 3 3 3 1 3 3 ) ) ) 3

) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) ) )
0411-4
Site 3 - 2014
International Paper - Cape Fear River
Label foll with "Site 2, Bluegill
(1), date caught, A' or'B"' Put same species from same site in zip -lock by A or B fillet. A = left fillet
Date Caught
By:
Date Filleted
By
Site
Species eft)
Total Length (rum)
Total Weight (g)
Fillet A Weight (g)
Fillet B Weight (g)
Potential
Composite
9/23/2014
RP/SF
9/24/2014
SF
3
Blue Catfish (111
604
2,150
364
11
9/10/2014
RP/SC
9/11/2014
SF
3
Blue Catfish (10)
601
2,175
345
9/9/2014
RP/SC
9/10/2014
SF
3
Blue Catfish (4)
563
2,200
340
9/10/2014
RP/SC
9/11/2014
SF
3
Blue Catfish (9)
633
2,650
390
9/10/2014
RP/SC
9/11/2014
SF
3
Blue Catfish (7)
658
3,025
470
9/10/2014
RP/SC
9/11/2014
LLB
3
Blue Catfish (6)
636
3,200
500
9/9/2014
RP/SC
9/10/2014
SF
3
Blue Catfish (5)
666
3,650
•160
9/23/2014
RP/SF
9/24/2014
RP
3
Bluegill (20)
129
41
10
9
9/23/2014
RP/SF
9/24/2014
RP
3
Rluegill(16)
145
57
12
9/23/2014
RP/SF
9/2.1/2014
SF
3
Bluegill (19)
144
57
11
9/23/2014
RP/SF
9/24/2014
SF
3
Bluegill (17)
150
62
17
9/10/2014
RP/SC
9/10/2014
1111
3
Bluegill (11)
155
63
18
9/23/2014
RP/SF
9/24/2014
RP
3
Bluegill(18)
153
65
36
9/23/2014
RP/SF
9/24/2014
HP
3
Rlueglll(14)
161
81
12
9/8/2014
RP/SC
9/10/2014
LLB
3
Bluepfll(2)
170
82
20
9/10/2014
RP/SC
9/10/2014
SF
3
Bluegill_(10)
178
91
18
9/10/2014
RP/SC
9/10/2014
SF
3
Bluegill (9)
172
92
20
9/9/2014
RP/SC
9/10/2014
SF
3
Bluegill (5)
186
95
18
10
9/9/2014
RP/SC
9/10/2014
SF
3
Bluegill(4)
180
98
18
9/23/2014
RP/SF
9/24/2014
SF
3
Bluegill (15)
173
109
22
9/9/2014
RP/SC
9/10/2014
SF
3
Bluegill (3)
188
124
21
9/8/2014
RP/SC
9/10/2014
SF
3
Bluegill (1)
187
141
28
9/10/2014
RP/SC
9/10/2014
LLB
3
Biuegill(8)
193
150
25
9/10/2014
RP/SC
9/10/2014
LLB
3
Bluegill (6)
192
152
30
9/23/2014
RP/SF
9/24/2014
SF
3
Bluegill(13)
193
157
25
9/10/2014
RP/SC
9/10/2014
SF
3
Bluegill()
202
170
32
9/23/2014
RP/SF
9/24/2014
HP
3
Bluegill (12)
197
176
28
9/9/2014
RP/SC
9/10/2014
SP
3
Carp (1)
603
2,900
422
12
9/9/2014
RP/SC
9/10/2014
LLB
3
Carp (2)
579
3,050
460
9/10/2014
RP/SC
9/11/2014
SF
3
Carp (4)
591
3,100
492
9/23/2014
RP/SF
9/24/2014
RP
3
Carp (5)
638
3,900
388
9/9/2014
ftP/SC
9/10/2014
SF
3
Carp (3)
670
4,150
550
Composite 9
Composite 10
Composite 11
Composite 12
Site 3
Site 3
Site 3
Site 3
Blueg II
Bluegill
Blue ca fish
Common carp
10
10
7
5
,`J, IU,11,1'i,1U, 1/,1O,A7,LV - H 1111
1,3,4,5,6,7,8,12,13,15 - A fillets
4,5,6,7,9,10,11- A fillets
1,2,3,4,5 - A fillets