NC0003298_Monitoring Report_20111228

NPDES DOCUWENT SCANNINS COVER SHEET
NPDES
Permit:
NC0003298
Riegelwood
Paper Mill
Document
:
Permit Issuance
Wasteload Allocation
Authorization to Construct (AtC)
Permit Modification
Speculative
Limits
Monitoring Report
Instream Assessment (67B)
Environmental Assessment (EA)
Permit
History
Document
Date:
December 28, 2011
IrJblas document le; prLated cork reuse paper - %aore aszy
content on the re'erse Bide

INTERNATIONALS PAPER
RIEGELWOOD MILL
JOHN L. RIEGEL ROAD
RIEGELWOOD, NC 28456
December 28, 2011
Certified Mail: 7005 1820 0007 8389 4367
Mr. Jay Sauber
Chief, Environmental Sciences Section
NC DENR Division of Water Quality
1621 Mail Service Center
Raleigh, NC 27699-1621
SUBJECT: Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the
International Paper Company Mill at Riegelwood, NC — 2011 Report
NPDES Permit No. NC0003298
Dear Mr. Sauber:
Please find enclosed the 2011 annual report for fish tissue dioxin monitoring conducted on the Cape
Fear River in the vicinity of International Paper's Riegelwood Mill.
If you have questions or need additional information, please call me at 910/362-4753.
Sincerely,
Kimberly W. Fa(l, P.E.
Senior Environmental Engineer
Enclosure
cc: James H. Gregson, Surface Water Protection Supervisor
NCa DENR — Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405
Jeff Poupart, Point Source Branch Supervisor
NC DENR Division of Water Quality
512 North Salisbury Street
Raleigh, NC 27603
-1.4viv@ig
JAN - 3 N1
DEI, FTE QUALITY
POINT 5�WfTCH
kwf
S:\Groups\Environmental\Wastewater\Fish Tissue1201 I\Annual Fish "I issue dioxin Report 2011 12281 I.docx

DIOXIN MONITORING STUDY OF FISH TISSUE
FROM THE CAPE FEAR RIVER IN THE VICINITY OF
THE INTERNATIONAL PAPER COMPANY MILL
AT RIEGELWOOD, NORTH CAROLINA
2011 REPORT
Prepared for
International Paper Company
Riegelwood Mill
John L. Riegel Road
Riegelwood, North Carolina 28456
Prepared by
CZR Incorporated
4709 College Acres Drive, Suite 2
Wilmington, North Carolina 28403
December 2011

DIOXIN MONITORING STUDY OF FISH TISSUE
FROM THE CAPE FEAR RIVER IN THE VICINITY OF
THE INTERNATIONAL PAPER COMPANY MILL
AT RIEGELWOOD, NORTH CAROLINA
TABLE OF CONTENTS
Page
TABLE OF CONTENTS
LIST OF TABLES iii
LIST OF FIGURES iii
LIST OF APPENDICES iii
1.0 INTRODUCTION 1
2.0 METHODS 2
2.1 Sampling Stations 2
2.2 Species Selection 8
2.3 Sample Collection Methodology 8
2.4 Sample Preparation and Shipment 11
2.5 Chemical Analysis 12
3.0 RESULTS AND DISCUSSION 13
3.1 Fish Collection 13
3.2 Tissue Analyses 13
REFERENCES 21
ii

LIST OF TABLES
Table Page
2-1 Summary of physicochemical measurements taken in conjunction with fish
collections on the Cape Fear River during 2011 7
2-2 Fish collection dates, techniques, effort, and fish caught in the Cape Fear
oft, River study areas during 2011 9
3-1 Summary of 2011 fish composites submitted from three Cape Fear River
stations in the vicinity of the International Paper Company Mill at Riegelwood,
North Carolina 14
oft; 3-2 Fish composite data for three Cape Fear River stations in the vicinity of the
International Paper Company Mill at Riegelwood, North Carolina, collected
during 2011 17
3-3 Summary of analytical results from fish tissue composites collected in the
ram, Cape Fear River near the International Paper Company Mill at Riegelwood,
North Carolina, during 2011 18
3-4 Comparison of dioxin (2,3,7,8-TCDD) concentrations among gamefish and
bottom feeder composites from the Cape Fear River from 1992 to 2011 20
Ant
LIST OF FIGURES
Figure Page,
2-1 Sampling Stations — Sites of Fish Collection on the Cape Fear River near
Riegelwood, NC 3
2-2 Sampling Station 1 -- Site of Fish Collection on the Cape Fear River near
Riegelwood, NC 4
2-3 Sampling Station 2 -- Site of Fish Collection on the Cape Fear River near
Riegelwood, NC 5
2-4 Sampling Station 3 -- Site of Fish Collection on the Cape Fear River near
Riegelwood, NC 6
LIST OF APPENDICES
APPENDIX A: DIOXIN MONITORING STRATEGY
APPENDIX B: NORTH CAROLINA SCIENTIFIC COLLECTION PERMITS
APPENDIX C: LETTER OF TRANSMITTAL/CHAIN OF CUSTODY
APPENDIX D: LABORATORY DATA REPORTS
/02, iii

eseAt
Oto1
1.0 INTRODUCTION
International Paper Company's (International Paper) NPDES permit (No.
NC0003298) for the Riegelwood mill requires the collection and analysis of fish tissue for
the presence of dioxins and furans. The mill is located along the Cape Fear River near
Riegelwood, Columbus County, North Carolina. The dioxin monitoring program is
administered by the North Carolina Division of Water Quality (DWQ), formerly the Division
'" ) of Environmental Management. International Paper contracted CZR Incorporated (CZR) to
ei`` collect fish samples during 2011. To maintain report consistency, the format and style of
this report are similar to CZR Incorporated's past monitoring reports (1993 through 2010
"AN Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the
Federal Paper Board's Mill at Riegelwood, North Carolina) which were modeled and
derived from the September 1992 report (EA Report No. 12347.01) titled "Dioxin Monitoring
Study of Fish Tissue from the Cape Fear River in the Vicinity of Federal Paper's
Riegelwood, North Carolina Mill" prepared by EA Engineering, Science, and Technology,
Inc.
Monitoring protocols were established in September 1990 to comply with the Special
rat, Order by Consent (SOC) EMC WQ No. 84-30 AD II effective 12 July 1990. The protocols
comply with both the NPDES permit and the SOC. The following sections discuss sampling
stations, sample collection techniques, sample preparation, and analytical results.
else
roit
PAR
1

Alb1
2.0 METHODS
o
oft,
ors,2.1 Sampling Stations
ems
Fish collections occurred in the sampling areas established from previous studies
(EA Engineering, Science, and Technology, Inc., 1992). Sampling stations were originally
selected as required by the current NPDES permit and SOC. North Carolina's current
DWQ fish tissue dioxin monitoring strategy for the Riegelwood mill is provided in Appendix
A. One station was located upstream of the mill's discharge and the remaining stations
were located downstream of the mill (Figure 2-1).
Station 1 is approximately 11 miles upstream of Lock & Dam No. 1 in the vicinity of
Elwell's Ferry (SR 1730). This station is a control site located approximately 20 miles
upstream of the mill ouffall and separated from the mill by a physical barrier, Lock & Dam
,", No. 1 (Figure 2-2). Station 2 is approximately 2 miles downstream of the mill discharge
near Green Bank Landing (Figure 2-3). Station 3 is approximately 13 miles downstream of
(A) the mill discharge near the confluence of the Cape Fear River and the Black River (Figure
2-4).
Generally, fish habitat was sparse and varied among the three sampling stations.
The available fish habitat consisted of inundated tree roots, aquatic macrophytes,
(081
taken in conjunction with fish collections at each sampling station are found in Table 2-1.
611.111
Obo
overhanging riparian vegetation, snags, and fallen timber. Physicochemical measurements

LEGEND
SAMPLING STATION
+ SITE OF PAPER MILL
SOURCE:
NORTH CAROUNA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NAD83 FEET, 1:24000—SCALE, USGSTopoTile018,SID
0
20,000
40,000
SCALE IN FEET
SAMPLING STATIONS
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
SCALE: AS SHOWN
DATE: 12/09/08
APPROVED BY:
DRAWN BY: TLJ
FILE: 1340-KEY
ZR
INCORPORATED
DMNONYENEAL CONSILTUDS
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROUNA 28403
TEL [phone]
FAX [phone]
CP#1340.16
FIGURE 2-1
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LEGEND
SAMPLING STATION 1
SAMPLING STATION
f...
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
0 2,000 4,000
SCALE: AS SHOWN
APPROVED BY:
DRAWN BY: TLJ
DATE: 12/09/08
FILE: 1340—SP1
,' :
4709 COLLEGE ACRES DRIVE
CP# 1340.16
SOURCE:
SCALE IN FEET
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NAD83 FEET, 1:24000-SCALE, USGSTopoTile018.SID
SUITE 2
a � WILMINCTON, NORTH CAROLINA 29403
:' INCORPORATED TEL [phone]
DMRONVENru CONSULT/MS FAX [phone]
FIGURE 2-2

))))))))))))))))))))))))))))))))))))))))))�
LEGEND
SAMPLING STATION
SOURCE:
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NAD83 FEET, 1:24000—SCALE, USGSTopoTile018.SID
0 2,000
4,000
SCALE IN FEET
SAMPLING STATION 2
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
SCALE: AS SHOWN
DATE: 12/09/08
ZR
INCORPORATED
DMRONN[NTAL CON0ULT ATS
APPROVED BY:
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROLINA 28403
TEL [phone]
FAX [phone]
DRAWN BY: TLJ
FILE: 1340-SP1
CP# 1340.16
FIGURE 2-3

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LEGEND
SAMPLING STATION
SOURCE:
NORTH CAROLINA DEPARTMENT OF TRANSPORTATION,
USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE,
NAD83 FEET, 1:24000-SCALE, USGSTopoTile018.SID
0
2,000 4,000
SCALE IN FEET
SAMPLING STATION 3
SITES OF FISH COLLECTION ON THE
CAPE FEAR RIVER NEAR RIEGELWOOD, NC
SCALE: AS SHOWN
DATE: 12/09/08
APPROVED BY:
DRAWN BY: TLJ
FILE: 1340-SP1
ZR
INCORPORATED
DATRONUENTAL CONSULTANTS
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROLINA 28403
TEL [phone]
FAX [phone]
CP#1340.1 6
FIGURE 2-4

Table 2-1. Summary of physicochemical measurements taken in conjunction with fish collections on
the Cape Fear River during 2011.a
Station Date Time
Temperature Conductivity
(C) (pS)
pH
Salinity D.O Secchi
(ppt) (mg/l) (in)
1 22 Aug 1915 30.6 218.9 7.3 0.1 8.05 38.75
1 23 Aug 1100 29.0 212.4 6.9 0.1 5.58 37.50
1 13 Sept 0940 27.2 191.9 6.4 0.1 5.73 --b
2 23 Aug 1615 29.8 224.6 6.9 0.1 5.37 42.50
2 24 Aug 0925 29.3 291.8 7.1 0.1 4.75 40.50
2 25 Aug 0925 29.1 297.4 7.1 0.1 4.21 43.50
2 13 Sept 1100 28.0 386.4 6.5 0.2 4.63 ----b
2 14 Sept 0800 27.6 380.0 7.1 0.2 5.52 29.50
3 23 Aug 1500 29.8 364.0 7.1 0.2 4.60 30.50
3 24 Aug 1200 29.4 338.0 7.0 0.2 4.30 32.00
3 25 Aug 1145 28.8 311.2 6.9 0.1 4.04 34.50
3 13 Sept 1455 27.5 250.7 6.6 0.1 4.04 ----b
3 14 Sept 1135 27.5 268.0 6.9 0.1 3.30 24.25
aMeasurements made 0.5 m below surface.
bData not available
7

2.2 Species Selection
The goal of the fish collection effort was to obtain four composite samples at each
sampling location with each sample consisting of ten individuals of the same species and of
similar length and weight. Larger (adult) specimens were given preference. Composites at
each station were composed of gamefish and bottom feeding species fillets. Target
species listed in the state's dioxin strategy include:
•
one composite sample for largemouth bass with sunfish (bluegill, redbreast,
etc.) as fallback species;
one composite sample for bluegill with other sunfish (redbreast, redear, etc.)
as fallback species;
one composite sample for catfish (order of preference being flathead,
channel, blue, and others) or carp;
one composite sample for catfish (order of preference being flathead,
channel, blue, or others with fallback species as edible finfish).
2.3 Sample Collection Methodology
Various active and passive methods of fish collection were used to obtain target
species. Fish were collected under scientific fish collecting Permit Number SECP-707778
(North Carolina Division of Marine Fisheries) and License Number 11-SFC00004 (North
Carolina Wildlife Resources Commission) (Appendix B). A telephone crank generator was
used in an attempt to shock catfish while slowly moving along the river by boat. Stunned
fish caught in the electrical field float to the surface where they can be dip -netted from the
boat. Gill nets (flounder nets; 5.50-inch mesh x 20 mesh x 100 yards and 5.75-inch mesh x
15 mesh x 100 yards), trot lines, and hook and line fishing were also used to collect fish.
Descriptions of effort and gear types used are given in Table 2-2.
8

Table 2-2. Fish collection dates, techniques, effort, and fish caught in the Cape Fear River study areas during 2011.
Station Sampling dates
Gear type
Level of effort Fish caught
1
1
1
2
22 Aug 11
23 Aug 11
13 Sept 11
23 Aug 11
2 24Aug 11
2
25 Aug 11
Hook & Line
Hook & Line
Gillnets
Trot Lines
Crank Shocker
Gillnets
Trot Lines
Crank Shocker
Hook & Line
Crank Shocker
Hook & Line
Gillnets
Trot Lines
Hook & Line
Gillnets
Trot Lines
Crank Shocker
2 12 Sept 11 Hook & Line
Crank Shocker
2 lines, 0.75 hours
2 lines, 0.75 hours
8 nets, 1 night
2 lines, 50 hooks
0.25 hours
4 nets, 1 night
2 lines, 50 hooks
0.25 hours
6 bluegill (5 bluegill released)
11 bluegill (2 released)
14 blue catfish (1 blue catfish
released), 1 channel catfish, 1
longnose gar (released)
1 blue catfish
0 fish
3 blue catfish, 1 flathead catfish
1 blue catfish
0 fish
2 lines, 0.50 hours 4 bluegill
0.25 hours
2 lines, 0.75 hours
4 nets, 1 night
1 line, 26 hooks
0 fish
4 bluegill
4 blue catfish, 3 flathead catfish, 1
common carp
1 blue catfish (released), 1 channel
catfish (released), 1 longnose gar
(released)
2 lines, 0.50 hours 1 bluegill
4 nets, 1 night
6 blue catfish (1 blue catfish
released), 5 common carp, 1
southem flounder (released)
1 line, 25 hooks 0 fish
0.50 hours 0 fish
2 lines, 0.50 hours 4 bluegill
0.25 hours 0 fish
9

eaq
!�1
Station Sampling dates Gear type Level of effort Fish caught
�'► 2 13 Sept 11 Gillnets 4 nets, 1 night 2 blue catfish, 2 common carp, 1
longnose gar (released)
Trot Lines 2 lines, 50 hooks 3 blue catfish, 1 flathead catfish
Crank Shocker 0.25 hours 0 fish
2 14 Sept 11 Gillnets 1 net, 1 night 3 blue catfish
Trot Lines 1 line, 24 hooks 0 fish
3 23 Aug 11 Hook & Line 2 lines, 0.50 hours 2 bluegill (1 bluegill released)
Crank Shocker 0.25 hours 0 fish
3 24 Aug 11 Hook & Line 2 lines, 1.00 hours 14 bluebill
on) Gillnets 4 nets, 1 night 3 blue catfish, 1 flathead catfish, 5
gizzard shad (released), 2 longnose
gar (released)
emeN
Trot Lines 2 lines, 50 hooks 0 fish
3 25 Aug 11 Gillnets 4 nets, 1 night 1 blue catfish, 2 gizzard shad
(released)
Trot Lines 2 lines, 50 hooks 2 blue catfish
Crank Shocker 0.25 hours 0 fish
(4112
3 13 Sept 11 Hook & Line 2 lines, 0.25 hours 5 bluegill
,4EKN Crank Shocker 0.25 hours 0 fish
3 14 Sept 11 Gillnets 7 nets, 1 night 4 blue catfish, (1 blue catfish
released) 2 flathead catfish, 1
gizzard shad (released)
Trotlines 2 lines, 49 hooks 2 blue catfish
Crank Shocker 0.25 hours 0 fish
effaN
ribs 10

2.4 Sample Preparation and Shipment
Collected fish were descaled or skinned, filleted, and preserved by CZR. SGS
Environmental Services (5500 Business Dr., Wilmington, North Carolina 28405) was
responsible for final sample preparation (i.e., homogenization) and chemical analysis. To
prevent cross -contamination between stations and composites, all equipment used to
handle fish (excluding nets) was solvent rinsed with pesticide -grade acetone and hexane or
was wrapped with aluminum foil (e.g., measuring boards and scale pans) which was
changed between composites. Fish from different stations were held in separate coolers
and disposable latex gloves were worn and frequently changed when handling fish during
each phase of sample preparation.
As fish were collected, they were placed on wet ice until processing. Fish were
filleted with knives on cutting boards wrapped with aluminum foil (dull side up). Cutting
board wraps were changed and fillet knives were solvent rinsed between composites. Fillet
samples consisted of flesh from both sides of each specimen, including the skin (for
gamefish) but not the scales. Catfish and carp specimens were skinned. Samples were
wrapped in aluminum foil (dull side toward the fish) to shield it from light and were labeled
with sample location, species, and date of collection. All labeled samples making up a
single composite were placed in individual plastic "zip -lock" bags, then all composite
sample bags were sealed inside a larger bag for each station. Samples were frozen to
await delivery to the laboratory for analysis. Where available, a portion of each composite
was retained from laboratory analysis and remains frozen with International Paper
Company or CZR Incorporated.
On 6 October 2011, the frozen samples were hand -delivered to SGS Environmental
Services in Wilmington, North Carolina, in coolers packed with ice. A copy of the letter
of transmittal/chain of custody that accompanied samples is included in Appendix C.
11

e
/lb1
rotbk
2.5 Chemical Analysis
SGS Environmental Services performed the chemical extraction and analyses in
Asis
accordance with EPA Method 8290 for 2,3,7,8-TCDD and 2,3,7,8-TCDF. The presence of
tetrachlorinated dibenzo-p-dioxins and dibenzofurans was detected using high -resolution
chromatography/high-resolution mass spectrometry.
All summary results were reported as 2,3,7,8-TCDD; 2,3,7,8-TCDF; and estimated
Total Toxic Equivalent Values (TEVs). Total extractable lipid content was also determined
`®` for each composite sample. A composite sample of blue catfish from Station 1 was
designated for duplicate laboratory analysis. A quantity sufficient for re -extraction of each
composite sample (where available) was retained and will be held frozen for a period of 30
days at the lab following the analysis. Duplicate samples will be held at CZR for three
months following the completion of this report.

root
3.0 RESULTS AND DISCUSSION
3.1 Fish Collection
robs
A summary description of the 2011 fish composites is found in Table 3-1. Gamefish
ram, and bottom feeder target species were collected from each of the three stations. Gamefish
or water -column feeding species submitted for analysis included bluegill (Lepomis
offg macrochirus) from Stations 1, 2, and 3. Bottom feeder species submitted for analysis
included blue catfish (lctalurus furcatus) from Stations 1, 2, and 3; common carp (Cyprinus
`®' carpio) from Station 2; and flathead catfish (Pylodictis olivaris) from Stations 1, 2, and 3.
Sample composites with calculated average total fish lengths and weights are found in
rat,
Table 3-2.
ram+
3.2 Tissue Analyses
Dioxin (2,3,7,8-TCDD) concentrations (all reported in parts per trillion — ppt) in all
composite samples represent values between the method detection limit and the lower
method calibration limit or were not detected and therefore represent estimates (Table 3-3).
The highest concentration of dioxin was 0.439 ppt found in flathead catfish composite
oft, number 6 (composite of 4 individuals) at Station 2. The next highest concentration was
0.399 ppt found in common carp composite number 8 (composite of 8 individuals), also
located at Station 2. The only reported dioxin concentration from Station 1 was 0.295 ppt.
Reported dioxin concentrations from Station 2 ranged from 0.339 ppt to 0.439 ppt, and
there were no detected dioxin concentrations at Station 3.
,, Furan (2,3,7,8-TCDF) concentrations (all reported in parts per trillion — ppt) in all
composite samples represent values between the method detection limit and the lower
method calibration limit or were not detected and therefore represent estimates (Table 3-3).
The highest concentration of furan was 0.434 ppt found in common carp at Station 2. The
only reported furan concentration from Station 1 was estimated at 0.277 ppt. Reported
�► furan concentrations ranged from an estimated 0.112 ppt to 0.434 ppt at Station 2, and
from an estimated 0.140 ppt to an estimated 0.149 ppt at Station 3.
13

Table 3-1. Summary of 2011 fish composites submitted from three Cape Fear River stations in
the vicinity of the International Paper Company Mill at Riegelwood, North Carolina.
Station Composite Species Length
Weight (g) Fillet A (g) Ka
1 Channel catfish 475 1,050 58 0.98
1 1 Bluegill 160 80 15 1.95
1 1 Bluegill 160 65 10 1.59
1 1 Bluegill 129 40 5 1.86
1 1 Bluegill 158 60 10 1.52
1 1 Bluegill 139 40 5 1.49
1 1 Bluegill 135 40 10 1.63
1 1 Bluegill 130 40 5 1.82
1 1 Bluegill 172 110 15 2.16
1 1 Bluegill 149 65 10 1.96
1 1 Bluegill 145 60 10 1.97
1 2 Flathead catfish 555 1,575 160 0.92
1 3 Blue catfish 563 1,690 240 0.95
1 3 Blue catfish 600 2,300 332 1.06
1 3 Blue catfish 571 2,300 335 1.24
1 3 Blue catfish 499 1,325 325 1.07
1 3 Blue catfish 600 2,350 361 1.09
1 3 Blue catfish 510 1,400 210 1.06
1 3 Blue catfish 521 1,350 171 0.95
1 3 Blue catfish 593 1,950 270 0.94
1 4 Blue catfish 640 3,025 455 1.15
1 4 Blue catfish 670 2,950 401 0.98
1 4 Blue catfish 696 2,825 332 0.84
1 4 Blue catfish 709 3,325 411 0.93
1 4 Blue catfish 631 2,610 399 1.04
1 4 Blue catfish 611 2,900 404 1.27
1 4 Blue catfish 600 2,500 416 1.16
1 4 Blue catfish 542 2,800 328 1.76
1 4 Blue catfish 600 2,375 361 1.10
1 4 Blue catfish 666 3,200 352 1.08
2 Bluegill 142 40 5 1.40
2 Bluegill 131 40 5 1.78
2 Blue catfish 733 4,900 576 1.24
2 Blue catfish 230 258 40 2.12
2 Blue catfish 405 525 78 0.79
2 Blue catfish 525 1,150 160 0.79
2 Blue catfish 805 8,850 840 1.70
2 5 Bluegill 150 65 10 1.93
14

Table 3-1. (continued)
Station Composite Species
Length
(mm)
Weight (g) Fillet A (g) Ka
2 5 Bluegill 161 75 10 1.80
2 5 Bluegill 146 50 10 1.61
2 5 Bluegill 133 45 10 1.91
2 5 Bluegill 148 64 10 1.97
2 5 Bluegill 145 58 10 1.90
2 5 Bluegill 134 46 5 1.91
2 5 Bluegill 146 60 10 1.93
2 5 Bluegill 160 70 10 1.71
2 5 Bluegill 146 60 5 1.93
2 5 Bluegill 160 65 10 1.59
2 6 Flathead catfish 630 2,500 306 1.00
2 6 Flathead catfish 645 3,200 357 1.19
2 6 Flathead catfish 725 4,050 521 1.06
2 6 Flathead catfish 795 5,108 548 1.02
2 7 Blue catfish 574 1,750 256 0.93
2 7 Blue catfish 637 2,800 413 1.08
2 7 Blue catfish 649 2,650 337 0.97
2 7 Blue catfish 650 2,600 401 0.95
2 7 Blue catfish 640 2,200 356 0.84
2 7 Blue catfish 589 2,100 332 1.03
2 7 Blue catfish 613 2,400 398 1.04
2 7 Blue catfish 577 1,900 306 0.99
2 7 Blue catfish 640 3,850 444 1.47
2 7 Blue catfish 695 3,750 504 1.12
2 7 Blue catfish 642 3,075 390 1.16
2 7 Blue catfish 680 3,400 445 1.08
2 8 Common carp 621 3,450 338 1.44
2 8 Common carp 610 3,500 425 1.54
2 8 Common carp 605 2,925 378 1.32
2 8 Common carp 613 3,150 374 1.37
2 8 Common carp 642 3,450 392 1.30
2 8 Common carp 645 3,700 465 1.38
2 8 Common carp 621 3,300 474 1.38
2 8 Common carp 558 2,350 322 1.35
3 Blue catfish 855 6,800 836 1.09
3 9 Bluegill 151 66 10 1.92
3 9 Bluegill 146 55 5 1.77
3 9 Bluegill 154 64 10 1.75
3 9 Bluegill 158 69 10 1.75
3 9 Bluegill 155 68 5 1.83
3 9 Bluegill 155 68 10 1.83
3 9 Bluegill 132 45 5 1.96
3 9 Bluegill 138 45 5 1.71
3 9 Bluegill 138 40 10 1.52
15

Table 3-1. (concluded)
Station Composite Species
Length
(mm)
Weight (g) Fillet A (g) Ka
3 9 Bluegill 142 50 10 1.75
3 10 Bluegill 158 70 10 1.77
3 10 Bluegill 177 85 10 1.53
3 10 Bluegill 180 114 15 1.95
3 10 Bluegill 176 125 20 2.29
3 10 Bluegill 171 104 15 2.08
3 10 Bluegill 159 80 10 1.99
3 10 Bluegill 155 72 5 1.93
3 10 Bluegill 178 104 15 1.84
3 10 Bluegill 160 80 10 1.95
3 10 Bluegill 181 100 15 1.69
3 11 Flathead catfish 557 1,950 228 1.13
3 11 Flathead catfish 623 2,550 219 1.05
3 11 Flathead catfish 570 1,840 208 0.99
3 12 Blue catfish 595 2,250 300 1.07
3 12 Blue catfish 701 3,600 516 1.05
3 12 Blue catfish 748 3,600 488 0.86
3 12 Blue catfish 536 1,600 242 1.04
3 12 Blue catfish 520 1,150 174 0.82
3 12 Blue catfish 592 2,110 324 1.02
3 12 Blue catfish 725 4,300 540 1.13
3 12 Blue catfish 670 3,200 424 1.06
3 12 Blue catfish 664 3,100 329 1.06
3 12 Blue catfish 632 2,560 434 1.01
aFulton..type condition factor - (weight(g)/length(mm)3)*100000
16

Table 3-2. Fish composite data for three Cape Fear River stations in the vicinity of the International Paper
Company Mill at Riegelwood, North Carolina, collected during 2011.
Station Composite Typea Species
number
Number in
composite
Average
length
(mm)
Average
weight (g)
Average
fillet
weight (g)
1 1 G Bluegill 10 147.7 60.0 9.5
1 2 B Flathead catfish 1 555.0 1,575.0 160.0b
1 3 B Blue catfish 8 557.1 1,833.1 280.5
1 4 B Blue catfish 10 636.5 2,851.0 385.9
2 5 G Bluegill 11 148.1 59.8 9.1
2 6 B Flathead catfish 4 698.8 3,714.5 433.0
2 7 B Blue catfish 12 632.2 2,706.3 381.8
2 8 B Common carp 8 614.4 3,228.1 396.0
3 9 G Bluegill 10 146.9 57.0 8.0
3 10 B Bluegill 10 169.5 93.4 12.5
3 11 B Flathead catfish 3 583.3 2,113.3 218.3
3 12 B Blue catfish 10 638.3 2,747.0 377.1
aG = Gamefish/water-column feeder; B = Bottom feeder.
bSingle fish composite.
17

Table 3-3. Summary of analytical results from fish tissue composites collected in the Cape Fear River near
the International Paper Company Mill at Riegelwood, North Carolina, during 2011. Detailed case
narratives of the laboratory results are found in Appendix D.
Station
1
1
1
1
1
2
2
2
2
3
3
3
3
Notes:
a
b
c
d
e
9
Species Composite (#)
Bluegill (1)
Flathead catfish (2)
Blue catfish (3)
Blue catfish (4)
Blue catfish (13)f
Bluegill (5)
Flathead catfish (6)
Blue catfish (7)
Common carp (8)
Bluegill (9)
Bluegill (10)
Flathead catfish (11)
Blue catfish (12)
2,3,7,8-TCDD (ppt)
Concentration
N D(0.123)°
ND(0.117)c'd
0.295e'g
ND(0.181)c
ND(0.205)c
N D(0.184)°
0.439e
ND(0.200)c
0.399e
ND(0.107)c
ND(0.208)c
ND(0.156)°
ND(0.256)c
Percent
recover?
71.0
89.0
87.0
69.0
95.0
96.0
101.0
72.0
96.0
92.0
98.0
97.0
83.0
2,3,7,8-TCDF (ppt)
Percent Percent
Concentration recover? TEVb lipid
ND(0.050)c 72.0 0.128 0.26
ND(0.048fd 90.0 0.122 0.17
0.277e'g 88.0 0.323 2.44
ND(0.219)c 69.0 0.203 3.69
0.234e 99.0 0.228 1.38
ND(0.053)c 97.0 0.189 0.54
0.112e'g 104.0 0.450 0.73
ND(0.085)c 72.0 0.209 3.13
0.434e 97.0 0.442 1.71
0.140e'9 96.0 0.121 0.52
0.149" 100.0 0.223 0.49
0.147e 100.0 0.171 0.32
ND(0.083)c 84.0 0.264 1.18
± 5% statistical variability.
Estimated Maximum possible Toxic Equivalent Value [TCDD conc. + (0.1*TCDF conc.)] using
detection limits and/or estimated concentration.
Not detected. Estimated Detection Limit for sample is reported in parenthesis.
Single specimen sample.
Amount detected is between the Method Detection Limit and the Lower Calibration Limit.
Duplicate sample of composite #4.
Estimated Maximum possible Concentration.
18

Percent lipid contents ranged from 0.17 (flathead catfish at Station 1) to 3.69 (blue
catfish from Station 1). Reported TEV estimates represent the maximum possible values
from each sample. Analytical results for fish tissue composites collected and submitted
during 2011 are summarized in Table 3-3. Laboratory data reports (149 pages) provided
by SGS Environmental Services are included in Appendix D.
The US Environmental Protection Agency recommends a screening value of 0.7 ppt
for dioxins; however, the State of North Carolina currently uses a dioxin concentration of
4.0 ppt in issuing an advisory (NCDENR 2006). Dioxin concentrations below this amount
are considered safe and acceptable by the North Carolina Division of Water Quality. None
of the samples submitted for analysis in 2011 contained dioxin concentrations above the
state advisory level. Conclusive concentrations of dioxin were not detected from any
samples and the highest concentration of 0.439 ppt in flathead catfish from Station 2 was
between the method detection limit and the lower method calibration limit. Average dioxin
concentrations from game and bottom feeding fish in the vicinity of the Riegelwood Mill
have remained well below the state advisory standard during the course of annual sampling
periods over the last twenty years (Table 3-4).
19

''°'iN Table 3-4. Comparison of dioxin (2,3,7,8-TCDD) concentrations among gamefish and bottom feeder composites
from the Cape Fear River from 1992 to 2011.
'iit‘ 2,3,7,8-TCDD average concentration (ppt)
Year Fillet composite type
Station 1 Station 2 Station 3
Amq 1992 Gamefish 0.09 0.38 0.35
Bottom feeder 0.15 2.09 1.15
rifq
1993 Gamefish 0.09a 0.17b 0.33
oltN Bottom feeder 0.16 0.59 0.38
1994 Gamefish 0.08 0.32 0.22
Bottom feeder ND 0.20 0.42
filli 1995 Gamefish ND ND ND
roq Bottom feeder ND 0.21b ND
1996 Gamefish ND ND ND
At\ Bottom feeder ND 0.37b 0.12
oak, 1997 Gamefish ND 0.20a ND
Bottom feeder 0.17b 0.25a 0.06b
'im' 1998 Gamefish ND ND ND
esiiN Bottom feeder ND ND 0.31
1999 Gamefish ND 0.08b ND
`'it' Bottom feeder 0.05b 0.17b 0.31 b
" 2000 Gamefish ND 0.18b 0.09b
Bottom feeder ND° ND ND
2001 Gamefish ND 0.11b 0.11b
oq Bottom feeder ND° 0.19b 0.08b
2002 Gamefish ND ND ND
Bottom feeder 0.26b 0.29b ND
2003 Gamefish ND ND ND
Bottom feeder ND 0.05b 0.63
2004 Gamefish ND ND 0.26
(At\ Bottom feeder 0.25b 0.14 0.10
2005 Gamefish 0.23 0.12 0.20
Bottom feeder 0.34a 0.43 0.26a
oft, 2006 Gamefish 0.07b ND ND
oq Bottom feeder 0.22a 0.24a 0.36a
2007 Gamefish ND ND ND
'"'' Bottom feeder 0.33a 0.15a 0.07b
" 2008 Gamefish ND ND ND
Bottom feeder 0.42a 0.11 0.33a
2009 Gamefish 0.42 0.32 0.56b
rfi Bottom feeder 0.70 1.13 0.49
2010 Gamefish ND ND 0.14b
Bottom feeder 0.30b 0.29b 0.12b
eats 2011 Gamefish ND ND ND
/alb+ Bottom feeder 0.10b 0.42 ND
*1992 data were obtained from EA Report No. 12347.01 (EA Engineering, Science, and Technology, Inc., 1992).
ND = Not detected; detection limits were not used in calculating average concentrations of 2,3,7,8-TCDD.
a Values represent average of dioxin concentrations and estimated concentrations.
b Values represent average of estimated concentrations.
__,a14\° Estimated concentration found in replicate.
ARN
A°` 20

REFERENCES
EA Engineering, Science, and Technology, Inc. 1992. Dioxin Monitoring Study of Fish
Tissue from the Vicinity of Federal Paper Board Company's Riegelwood Mill.
Prepared for Federal Paper Board Company, Inc., EA Engineering, Science, and
Technology, Inc., Smyrna, Georgia. Report No. 12347.01.
Taylor, K., and K. M. Rudo. 1990. Risk Assessment of Dioxin Contaminated Fish.
Division of Epidemiology, NC Department of Environment, Health, and Natural
Resources. Raleigh, North Carolina.
CZR Incorporated. 1993. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina.
CZR Incorporated. 1994. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina.
CZR Incorporated. 1995. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina.
CZR Incorporated. 1996. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 1997. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 1998. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 1999. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2000. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2001. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
21

CZR Incorporated. 2002. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2003. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2004. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2005. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2006. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2007. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2008. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2009. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
CZR Incorporated. 2010. Dioxin Monitoring Study of Fish Tissue from the Cape Fear
River in the Vicinity of the International Paper Company Mill at Riegelwood, North
Carolina.
NCDENR. 2006. Standard Operating Procedures Fish Tissue Assessments. North
Carolina Department of Environmental and Natural Resources, 13 pp.
22

APPENDIX A
DIOXIN MONITORING STRATEGY

Monitoring Strategy for International Paper Company at Riegelwood, North Carolina
Composite Sample Guidance
All fish samples will be composited to maximize the number of sampled individuals and the
potential of sampling contaminated fish. Composite samples will consist of single species,
ideally represented by a maximum of ten individual fish. Composites will be prepared by
combining fillet fish tissue from similar sized individual fish, with a preference for larger fish.
Individual length and weight (metric) will be recorded for each fish and the average weight
and length for composites will be calculated. Whole fish tissue analysis is not required.
Fillets will be prepared by leaving skin on and removing scales for most species, with the
exception of catfish which will be skinned. Individual fish will be identified to species. A
sufficient quantity of each (un-extracted) composite sample will be retained and archived
(frozen) for a period of three months following submission of the final report.
Sample Collections Total laboratory samples to be analyzed = 13 (12 samples and one
duplicate)
Sampling Site 1 - Cape Fear River in the vicinity of SR 1730 Bladen County
Four composite samples will be analyzed for dioxin at this station:
-one composite sample for largemouth bass with sunfish as fallback species,
-one composite sample for bluegill with other sunfish as fallback species
(redbreast, redear, etc.),
- one composite sample for catfish (flatheads, channels, blue, other) or carp,
- one composite sample for catfish (flatheads, channels, blue, other) with
other edible finfish as fallback species.
Sampling Site 2 - Cape Fear River in the vicinity of Bryant Mill Creek
Four composite samples will be analyzed for dioxin at this station:
-one composite sample for largemouth bass with sunfish as fallback species,
- one composite sample for bluegill with other sunfish as fallback species
(redbreast, redear, etc.),
- one composite sample for catfish (flatheads, channels, blue, other) or carp,
-one composite sample for catfish (flatheads, channels, blue, other) with
other edible finfish as fallback species.
Sampling Site 3 - Cape Fear River in the vicinity of confluence with Black River

Four composite samples will be analyzed for dioxin at this station:
-one composite sample for largemouth bass with sunfish as fallback species,
-one composite sample for bluegill with other sunfish as fallback species
(redbreast, redear, etc.),
-one composite sample for catfish (flatheads, channels, blue, other) or carp,
-one composite sample for catfish (flatheads, channels, blue, other) with
other edible finfish as fallback species.
Laboratory Analysis and Reporting Procedures
Samples will be analyzed for Dioxin and Furans in accordance with analytical protocols set
out in Appendix C of USEPA/Paper Industry Cooperative Dioxin Screening Study (EPA
440/1-88-025, March 1988) or other equivalent analytical protocol approved by EPA.
Analysis will include the determination of concentrations of 2,3,7,8 TCDD and 2,3,7,8
TCDF. Dioxin analysis will be performed using high resolution Mass Spectrometry as
required by EPA Methods 624, 625, 8290, 1613 or other approved methods.
Required Analysis of Dioxins and Furans
Matrix Compound Quantitative Limits
Fish 2,3,7,8 TCDD 1 part per trillion
Fish 2,3,7,8 TCDF 1 part per trillion
Results will be reported in ppt with a minimum quantitative limit of 1 ppt. Where the
compound is detected at concentrations less than the minimum quantitative limit, an
estimate of the concentration will be given. If a compound is not detected it will be so
noted.
Reports
A monitoring report will be submitted that will include:
-sampling locations shown on copies of topographical maps (1:2400);
-analytical methods and procedures with name of laboratory;
-individual specimen description (species, length, weight, condition);
-composite descriptions (species, average length, average weight);
-All results will be reported as 2,3,7,8 TCDD and 2,3,7,8 TCDF in parts per trillion
(PPt)•
Monitoring reports (with results) will be sent in triplicate and directed to:
Mr. Steve Tedder
Chief, Water Quality Section
Division of Environmental Management
PO Box 27687
Raleigh, North Carolina 27611
A-2

APPENDIX B
NORTH CAROLINA SCIENTIFIC COLLECTION PERMITS

Atk Scientific Fish Collecting License
AA'',,
® North Carolina Wildlife Resources Commission
Division of Inland Fisheries
Phone: [phone] MSC 1721
Fax: [phone] Raleigh, NC 27699-1721
AUTHORITY
STATUTES
r,
113-272.4
PERMITTEEILICENSEE
SAMUEL COOPER
CZR, INC.
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NC 28403
PERMIT NUMBER
11-SFC00004
EFFECTIVE
02/01/2011
EXPIRES
12/31/2011
,
Conditions and Authorizations: .
The above permittee is authorized to collect the species/organism fisted below. The permittee is
requirements and laws specified by the U.S. Fish and Wildlife Service as they pertain to these species/organisms.
or possession of federally or state listed endangered, threatened, or special concern species Is
license.
SPECIES/ORGANISMS:
Amblyopsfdae; Amiidae; Anguillidae; Aphredoderldae; Atherinopsidae; Catostomidae; Centrarchidae;
Cottidae; Cyprinidae; Eiassomatidae; Esocidae; Fundulidae; Ictalurldae; Lepisosteidae; Moronidae;
Petrcmyzontidae; Poeciliidae; Salmonidae; Umbridae
BODIES OF WATER:
Print Date: 03/25/2011
required to comply
not authorized under
Clupeidae;
Percidae;
with all
The take
this
MICH
CAPE FEAR - Bladen County
CAPE FEAR- Brunswick County
CAPE FEAR - Columbus County
CAPE FEAR- Pender County
ROANOKE -Bertie County
ROANOKE - Marlin County
ROANOKE -Washington County
TAR-PAMLICO - Beaufort County
COUNTIES:
Beaufort Bertie Bladen Brunswick ChowanColumbus
SAMPLING METHOD:
Electrofishing, Boat; Net, Dip; Net, Fyke; Net, Gill; Seines;
ASSISTANTS:
SHERRY BANNER JULIA BERGER KATHARINE BRALY
AEL HUBBARD JIM HUDGENS BEN KEARNS LORRIE
PULLEY MAVERICK RABER JASON HALL
SPECIAL CONDITIONS:
1
I
g -EU W
_Ii
MAR 2 5 2011
CZR Incorpore:ed
Wiir-incl:n, NC
Martin Pender Washington
Trawls; Other
NICOLE CARPENTER ALEXANDER CRAIG
LALIBERTE ADRIAN MOON DAN MOORE RANDALL
PATRICK AMICO
This permit/license is non -transferable and expires at midnight on the above specified expiration date.
ISSUED BY:
deA.14: AK ete/e,
TITLE:
Chief

ea q
f''41
eats
ItN
est
Ogit
embN
tit)
tbN
esbN
taas
ENDANGERED NORTHN.C.G.S.
2. AUTHORITY - STATUTES
113-331 THRU
113-337
REGULATIONS
15A N.C.A.C. 10I.0001
THRU .0005
SPECIES PERMIT]
RESOURCES
North Carolina Wildlife Resources Commission CIAVAASSO
Division of Wildlife Management
MSC 1722 Tele: [phone]
Raleigh, NC 27699-1722 FAX: [phone]
1. PERMITTEE
3 al�l�
• Samuel Cooper r-Ct1 r f
CZR, Inc.
4709 College Acres Drive
Wilmington, NC 28403
• TELE: [phone] FAX: [phone]
3. PERMIT NUMBER
NCE-2011Es22
4. RENEWABLE
fl
YES
5. MAY
COPY
/ /
❑
YES
NO
6. EFFECTIVE
03/07/2011
7. EXPIRES
12/31/2011
8. NAME AND TITLE OF PRINCIPAL OFFICER Will is :a business)
• N/A
7. TYPE OF PERMIT
• Survey, Incidental Take
10. SPECIES AUTHORIZED:
• State -Listed Endangered, Threatened, & Special Concern Fish Species EXCLUDING Federally -listed
Endangered, Threatened, and Special Concern Fish Species
11. LOCATION WHERE AUTHORIZED ACTIVITY MAY BE CONDUCTED:
• Statewide
12. CONDITIONS AND AUTHORIZATIONS:
A. Authorized for incidental take of state -listed fish species while conducting fish collection activities as a designated agent of
the NC Wildlife Resources Commission. A Fish Collection License is required from the NCWRC, Div. of Inland
Fisheries.
B. Possession and transportation of dead specimens is permitted only as authorized by this permit.
1. Unless specifically authorized by this permit, collected voucher specimens must be deposited in the North Carolina
Museum of Natural Sciences, Raleigh, North Carolina or the Smithsonian Institution, Washington, D.C.
C. All activities must be supervised ON -SITE by the permittee.
1. All individuals conducting activities under this permit must carry a copy of this permit in their possession and a letter
of authorization signed by the permittee. The permittee will be responsible for all actions of individuals working
under his supervision.
2. Authorized subpermittees: Jim Hudgens, Julia Berger, Sherry Banner, Lorrie Laliberte, Katharine Braly, Randall
Pulley, Michael Hubbard, Nicole Carpenter, Alexander Craig, Ben Kearns, Adrian Moon, Dan Moore, and Maverick
Raber
D. All activity conducted under an Endangered Species Collection Permit must be .reported to the NC Wildlife Resources
Commission via an online data entry web site to meet the reporting requirements (https://ncpaws.org/paws/). Some fields
are required and are marked with an asterisk, but fill in as many of the remaining fields as you can. The report is due
within 30 days of the expiration of this permit. Your user name is (first initial and last name) and the default password is
"Aqu@tics01". The first time you log in you will be prompted to change your password and enter security questions.
Once in the PAWS system click on the "+" before the Fisheries to view and click on the aquatics database link. Next add
a new submission, then you will be able to click on the add/edit link to begin entering site data. Inside the data entry
pages you can cursor over the green question marks for detailed information about a particular field. For some data entry
boxes, we have provided specific examples of how we would like the data entered. Help documents are available online
and additional questions can be sent to Ryan Heise ([e-mail]).
A
ADDITIONAL CONDITIONS AND AUTHORIZATIONS ON REVERSE ALSO APPLY (PAGE 1 OF 1)
13. REPORTING REQUIREMENTS:
• Within 15 days after expiration. VALID 30 DAYS AFTER EXPIRATION, IF RENEWAL REQUESTED.
ISSUED BY:
/4),47/
TITLE:
Permits Supervisor
DATE:
03/07/2011
DISTRIBUTION LIST: Division of Wildlife Enforcement U.S. Fish & Wildlife Service, Enf. Sect., Raleigh, NC; Todd Ewing

eit'N
fot)
/1111
Idoft
Oa)
elet
e1
talIPN
North Carolina Division of Marine Fisheries
Proof of Purchase
UPDATE : Scientific or Educational Collection Permit : Permit Number 707778
Permit Number : 707778
Permit Year : 2011
NC Residency :
Qualifying Product :
Effective Date/I'imc : 01/14/2011 08:05
Expiration Date/1ime : 12/31/2011 23:59 Status : Active
Issue Date/Time : 01/14/2011 08:05 Status Date : 01/14/2011
Sales Outlet : DMF Morehead City Office
Terminal Numbcr : NI M0153
Fee :
0.00
Permit Holder
: 730069 CZR, INC.
Business Type:
Physical Address : 4709 COLLEGE ACRES DRIVE
M © m a V '.—\
�Iai
i
lddress : •
SUITE 2,
WILMINGTON, NC, 28403
United States
County : New Hanover
Race :
,f
MAR 2 8 2011
Sjes
:
•
Weight
Gender : Date
of Birth : CZR incorpora-ed Hair :
Wilmington, NC
:
Height : ft. Inches
Home Phone : [phone] Primary Residence : NC Prior !Fames :
Business Phone : [phone] Secondary Residence :
Fax : [phone]
Ids : E-Mail : czrwilm a czr-inc.com
Business Agent : 730085 COOPER, SAMUEL
Physical Address : 5425 ANDOVER ROAD, Mailing Address : .
WILMINGTON, NC, 28403
United States
County : New Hanover .County :
Race : Caucasian Eyes : Brown Weight : 160
Gender : Male Date of Birth 03/12/1963 Hair : Brown Height-: 5 ft. 10 Inches
Home Phone : [phone] Primary Residence : NC Prior Names :
Business Phone : [phone] Secondary Residence :
Fax : [phone]
Ids : E-Mail :
Contact Information
Contact Person
Contact Person DOB
Contact Person Telephone #
SAMUEL COOPER
03/12/1963
[phone]
Purpose of Collection
X
Research
Teaching Specimens
Educational Display (Aquariums)
Other (specify) SECTION 401 WQC MONITORING & DIOXIN SCANS
Collectors
Participantld Name DOB Contact Phone
JULIA K. BERGER 02/02/1951 [phone]
SHERRY BANNER 07/21/1943 [phone]
JIM HUDGENS 09/17/1942 . [phone]
LORRIE LALIBERTE BOSWELL 06/29/1981 [phone]
KATHARINE BRALY 03/02/1984 • [phone]
NICOLE CARPENTER 05/14/1986 [phone]
RANDALL PULLEY 02/02/1978 [phone]
ALEXANDER CRAIG 10/1I/1983 [phone]
MICHAEL HUBBARD 05/24/1963 [phone]
MAVERICK RABER 08/28/1980 [phone]
BEN KEARNS 05/25/1986 [phone]
ADRIAN MOON 01/13/1974 [phone]
DAN MOORE 10/30/1971 [phone]
• JASON HALL 06/05/1973 [phone]
PATRICK AMICO 03/19/1985 [phone]
'Tinted : 3/25/2011
DMF Morehead City Office, 3441 Arendell St., PO Box 769, Morehead City NC., 28557-0769
SUEANN i3A'
Page :

North Carolina Division of Marine Fisheries
peat, Proof of Purchase
UPDATE : Scientific or Educational Collection Permit : Permit Number 707778
Pate Permit Number : 707778 NC Residency :
Permit Year : 2011 Qualifying Product :
tot1
Effective Date/Time : 01/14/2011 08:05
eAt1 Expiration Date/Time : 12/31/2011 23:59 Status : Active
Issue DateTI'imc : 01/142011 08:05 Status Date : 01/14/2011
/1'a1
Owl
Olt\
tot)
I�1
Igeb
f�1
/aq
Sales Outlet : DMF Morehead City Office
Terminal Number : N 1 M0153
Fee :
0.00
Restriction Information
Restriction Type : Gear Code : Species Group : _
eWater Body :
RESTRICT TO Gcar Quantity : Species Quantity :
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments: GEARS OR METHODS: ELECTROFISHING; GILL NETS; FYKE NETS; TROT LINES; DIP NETS; TRAWL; SEINE; HOOK AND LINE; FISH
TRAPS
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity :
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time: .
Comments: SPECIES: ALL EXCEPT THOSE LISTED AS ENDANGERED OR THREATENED.
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 1201020204-W11ITEHU
RST CREEK
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments:
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 1900000000-CAPE
FEAR RIVER
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments:
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 0205010000-MUDDY
CREEK
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments:
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 0208000000-CHOWAN
RIVER
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments:
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 0200000000-ALBEMAR
LE SOUND
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments:
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity :
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments: WATER BODY: PCS PROJECT AREA I1
Restriction Type : Gear Code : Species Group : Water Body :
RESTRICT TO Gear Quantity : Species Quantity : 0528070201-BAILEY
CREEK
Gear Units : Species Size :
Time : Species Units :
Start Time: End Time:
Comments:
' Printed : 3/252011
DMF Morehead City Office. 3441 Arcade!! St.. PO Box 769, Morehead City NC., 28557-0769
SUEANN BA'
Page :

F�1
ANN
/legitst
egats
OR1
f�1
North Carolina Division of Marine Fisheries
Proof of Purchase
UPDATE : Scientific or Educational Collection Permit : Permit Number 707778
Permit Number : 707778
Permit Year : 2011
NC Residency :
Qualifying Product :
Effective Date/Time : 01/14/2011 08:05
Expiration Date/Timc : 12/31/2011 23:59 Status : Active
Issue Date/Time : 01/14/2011 08:05 Status Date : 01/14/2011
Sales Outlet : DMF Morehead City Office
Terminal Number : NIM0153
Fee : 0.00
Restriction Type :
RESTRICT TO
Time :
Start Time:
Comments:
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Restriction Type :
RESTRICT TO
Time :
Stara Time:
Comments:
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0528370000-SOUTH
CREEK
0528370100-TOOLEV
CREEK
Restriction Type :
RESTRICT TO
Time :
Start Time:
Comments:
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0528360000-HUDDLES
GUT
Restriction Type : Gear Code :
RESTRICT TO Gear Quantity :
Time :
Start Time:
Comments:
End Time:
Gear Units :
'Restriction Type :
I-1 RESTRICT TO
Time :
Start Time:
Comments:
roiq
Restriction Type :
RESTRICT TO
Time :
Start Time:
Comments:
End Time:
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Gear Code:
Gear Quantity :
Gear Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0528370300-JACKS
CREEK
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0210000000-ROANOKE
RIVER
Water Body :
0210020000-W ELCH
CREEK
estN Restriction Type :
RESTRICT TO
tits
eft► rime :
Start Time:
Astt, 3omments:
testriction Type :
2ESTR1 CT TO
egitN
ime :
toz1;tart Time:
:omments:
End Time:
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Gear Code :
Gear Quantity :
Gear Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0528000000-PAMLICO
RIVER
Water Body :
0528370201-DRINKWA
TER CREEK
testriction Type :
LESTRICT TO
,mad 'ime :
:tart Time:
elat :omments:
ealiN
Gear Code :
Gear Quantity :
Gear Units :
End Time:
Species Group :
Species Quantity :
Species Size :
Species Units :
Water Body :
0528370200-JACOBS
CREEK
DMF Morehead City Office, 3441 Mendell St., PO Box 769, Morehead City NC., 28557-0769
rinted : 3/25/2011
fsa1
SUEANN BA'
Pagc

tots
North Carolina Division of Marine Fisheries
Proof of Purchase
UPDATE : Scientific or Educational Collection Permit : Permit Number 707778
!ten► Permit Number : 707778 NC Residency : - Sales Outlet : DMF Morehead City Office
Permit Year : 2011 Qualifying Product : Terminal Number : N1M0153
Effective Date/Time : 01/14/2011 08:05 Fee : 0.00
E"t1 Expiration Date/Time : I2/312011 23:59 Status : Active
Issue Date/me : 01/14/2011 08:05 Status Date : 01/14/2011
Restriction Type : Gear Code :
RESTRICT TO Gear Quantity :
Time :
Start Time:
Commcnts:
End Time:
Gear Units :
Species Group : Water Body :
Species Quantity : 0528350400-PORTER
CREEK
Species Size :
Species Units :
foit Restriction Type :
RESTRICT TO
, Time :
Start Time:
▪ Comments:
End Time:
Gear Code :
Gear Quantity :
Gear Units :
Species Group : Water Body :
Species Quantity : 0528063302-SCOTT
. CREEK
Species Size :
Species Units :
Restriction Type :
tms RESTRICT TO
Time :
Aq Start Time:
Comments:
r
tati
Gear Code :
Gear Quantity :
Gear Units :
End Time:
Species Group : Water Body :
Species Quantity : 0535301000-SCOTI'
CREEK
Species Size :
Species Units :
Request To Sell?
Issued By: evict
Authorized to Sell?
Li
Issued Date: J'o '%I
DMF Morehead City Office, 3441 Arendell St., PO Box 769, Morehead City NC., 28557-0769
esga1 Printed : 3/25/2011
SUEANN BA
Page :

APPENDIX C
LETTER OF TRANSMITTAL/CHAIN OF CUSTODY

ZR
INCORPORATED
ENVIRONMENTAL CONSULTANTS
TO: SGS Environmental Services
Attn: Amy Boehm
5500 Business Drive
Wilmington, NC 28405
DATE: 6 October 2011
CHAIN OF CUSTODY
3110D1'75
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROLINA 28403-1725
TEL [phone]
FAX [phone]
czrwilm@czr-Inc,com
FROM: Sam Cooper
CZR Incorporated, Suite 2
4709 College Acres Drive
Wilmington, NC 28403
[e-mail]
RE: International Paper Company, Inc., Annual Fish Project (IP 2011 PO# S-066125110 to SGS)
Analysis of fish tissues for 2, 3, 7, 8 TCDD (Dioxin), 2, 3, 7, 8, TCDF (Furan), and lipids (%)
ENCLOSED ITEMS:
Thirteen (13) frozen composite fish tissue (fillets) samples, each fillet wrapped in aluminum foil (dull side toward
fish) and enclosed in labeled "zip -lock" plastic bags. Composites are identified below.
Composite #
1
2
3
4
5
6
7
8
9
10
11
12
13
COMMENTS:
SAMPLE ID #
Site Species (number of fish fillets)
1
1
1
1
2
2
2
2
3
3
3
3
1
Bluegill (10 "A" fillets)
Flathead Catfish (1 "A" fillet)
Blue Catfish smaller (8 "A" fillets)
Blue Catfish larger (10 "A" fillets)
Bluegill (11 "A" fillets)
Flathead Catfish (4 "A" fillets)
Blue Catfish (12 "A" fillets)
Common Carp (8 "A" fillets)
Bluegill smaller (10 "A" fillets)
Bluegill larger (10 "A" fillets)
Flathead Catfish (3 "A" fillets)
Blue Catfish (10 "A" fillet)
Blue Catfish large replicate (10 "B" fillets)
- Send one digital version and two hard copies of the report to Sam Cooper/CZR at the above address.
- Forward the invoice to Ms. Kim Fail International Paper Company John L. Riegel Road Riegelwood,
NC 28456 ([e-mail]@ipaper.com) phone: [phone] fax: [phone]
Relinquishef y.
___-----"Received by:
loM( 13;1,r
Date/time
to I' 13:1tS
ate/time
CP #1340.19
} Nn s.ea
2151 Altemat6 A1A South • SUITE 2000 • JUPITER, FLORIDA 33477-3902
TEL [phone] • FAX [phone] • [e-mail] • www.CZRINC.com

APPENDIX D
LABORATORY DATA REPORTS

Laboratory Report of Analysis
To: Sam Cooper
CZR Incorporated
Suite 2
4709 College Acres Drive
Wilmington, NC 28403
Report Number: 31102775
Client Project: Annual Fish Project 2011
Dear Sam Cooper,
Enclosed are the results of the analytical services performed under the referenced project for the received
samples and associated QC as applicable. The samples are certified to meet the requirements of the National
Environmental Laboratory Accreditation Conference Standards. Copies of this report and supporting data will be
retained in our files for a period of five years in the event they are required for future reference. All results are
intended to be used in their entirety and SGS is not responsible for use of less than the complete report. Any
samples submitted to our laboratory will be retained for a maximum of thirty (30) days from the date of this report
unless other arrangements are requested.
If there are any questions about the report or services performed during this project, please call Amy J. Boehm at
[phone]. We will be happy to answer any questions or concerns which you may have.
Thank you for using SGS North America Inc. for your analytical services. We look forward to working with you
again on any additional analytical needs.
Sincerely,
SGS North America Inc.
Amy J. Boehm
Project Manager
[e-mail]
Date
Print Date. 11/01/2011
N.C. Certification # 481
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
Member of SGS Group
Page 1 of 149

SGS
Laboratory Qualifiers
J
Report Definitions
DL Method, Instrument, or Estimated Detection Limit per Analytical Method
CL Control Limits for the recovery result of a parameter
LOQ Reporting Limit
DF Dilution Factor
RPD Relative Percent Difference
LCS(D) Laboratory Control Spike (Duplicate)
MS(D) Matrix Spike (Duplicate)
MB Method Blank
Qualifier Definitions
Recovery or RPD outside of control limits
B Analyte was detected in the Lab Method Blank at a level above the LOQ
U Undetected (Reported as ND or < DL)
✓ Recovery is below quality control limit. The data has been validated based on a favorable signal-to-noise
and detection limit
A Amount detected is less than the Lower Method Calibration Limit
J Amount detected is between the Method Detection Limit and the Lower Calibration Limit
O The recovery of this analyte in the OPR is above the Method QC Limits and the reported concentration in
the sample may be biased high
E Amount detected is greater than the Upper Calibration Limit
S The amount of analyte present has saturated the detector. This situation results in an
underestimation of the affected analyte(s)
Q Indicates the presence of a quantitative interference. This situation may result in an
underestimation of the affected analyte(s)
I Indicates the presence of a qualitative interference that could cause a false positive or an
overestimation of the affected analyte(s)
DPE Indicates the presence of a peak in the polychlorinated diphenylether channel that could
cause a false positive or an overestimation of the affected analyte(s)
TIC Tentatively Identified Compound
EMPC Estimated Maximum possible Concentration due to ion ratio failure
ND Not Detected
K Result is estimated due to ion ratio failure in High Resolution PCB Analysis
P RPD > 40% between results of dual columns
D Spike or surrogate was diluted out in order to achieve a parameter result within instrument calibration
range
Samples requiring manual integrations for various congeners and/or standards are marked and dated by the analyst. A code
definition is provided below:
M1 Mis-identified peak
M2 Software did not integrate peak
M3 Incorrect baseline construction (Le. not all of peak included; two peaks integrated as one)
M4 Pattern integration required (i.e. DRO, GRO, PCB, Toxaphene and Technical Chlordane)
M5 Other - Explained in case narrative
Note Results pages that include a value for "Solids (%)" have been adjusted for moisture content.
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.G. Certification # 481
Member of SGS Group
Page 2 of 149

ZR
INCORPORATED
ENVIRONMENTAL CONSULTANTS
TO: SGS Environmental Services
Attn: Amy Boehm
5500 Business Drive
Wilmington, NC 28405
DATE: 6 October 2011
CHAIN OF CUSTODY
31 }0D1175
4709 COLLEGE ACRES DRIVE
SUITE 2
WILMINGTON, NORTH CAROLINA 28403-1725
TEL [phone]
FAX [phone]
[e-mail]
FROM: Sam Cooper
CZR Incorporated, Suite 2
4709 College Acres Drive
Wilmington, NC 28403
[e-mail]
RE: International Paper Company, Inc., Annual Fish Project (IP 2011 PO# S-066125110 to SGS)
Analysis of fish tissues for 2, 3, 7, 8 TCDD (Dioxin), 2, 3, 7, 8, TCDF (Furan), and lipids (%)
ENCLOSED ITEMS:
Thirteen (13) frozen composite fish tissue (fillets) samples, each fillet wrapped in aluminum foil (dull side toward
fish) and enclosed in labeled "zip -lock" plastic bags. Composites are identified below.
Composite #
1
2
3
4
5
6
7
8
9
10
11
12
13
COMMENTS:
SAMPLE ID #
Site Species (number of fish fillets)
1
1
1
1
2
2
2
2
3
3
3
3
1
Bluegill (10 "A" fillets)
Flathead Catfish (1 "A" fillet)
Blue Catfish smaller (8 "A" fillets)
Blue Catfish larger (10 "A" fillets)
Bluegill (11 "A" fillets)
Flathead Catfish (4 "A" fillets)
Blue Catfish (12 "A" fillets)
Common Carp (8 "A" fillets)
Bluegill smaller (10 "A" fillets)
Bluegill Iarger (10 "A" fillets)
Flathead Catfish (3 "A" fillets)
Blue Catfish (10 "A" fillet)
Blue Catfish large replicate (10 "B" fillets)
- Send one digital version and two hard copies of the report to Sam Cooper/CZR at the above address.
- Forward the invoice to Ms. Kim Fail International Paper Company John L. Riegel Road Riegelwood,
NC 28456 ([e-mail]@ipaper.com) phone: [phone] fax: [phone]
/Received by:
Date/time
!o 1' 13: iS
ate/time
. 5.eq
2151 Altemat6 A1A South • SUITE 2000 • JUPITER, FLORIDA 33477-3902
TEL [phone] • FAX [phone] • [e-mail] • www.CZRINC.com
�. 3C.
CP #1340.19
Page 3 of 149

!^
!4"\
SGS North America Inc.
Sample Receipt Checklist (SRC)
Client: International Paper Work Order No.: 31102775 'd"\
1. Shipped Notes:
x Hand Delivered
r4"b%
2. x COC Present on Receipt
No COC
Additional Transmittal Forms fAR's
3. Custody Tape on Container
x No Custody Tape
4. x Samples Intact
Samples Broken / Leaking r"N
5. x Chilled on Receipt Actual Temp.(s) in °C: 0.0, -2.1, -6.3 '^
Ambient on Receipt
Walk-in on Ice; Coming down to temp.
Received Outside of Temperature Specifications
6. x Sufficient Sample Submitted
Insufficient Sample Submitted
7. Chlorine absent NA
HNO3 < 2 !.`"N
HCL < 2 elq
Additional Preservatives verified (see notes)
!mb`
8. x Received Within Holding Time
Not Received Within Holding Time
No sample collection date or time on COC or
9. No Discrepancies Noted bags. e.,
x Discrepancies Noted
NCDENR notified of Descrepancies* /"t'
10. No Headspace present in VOC vials
Headspace present in VOC vials >6mm
Comments:
roN
eihN
e..,
etaN
Inspected and Logged in by: TP r►,
Date: Fri-10/7/11 00:00
Page 4 of 149
*NCDENR must be notified when collection, holding time or preservation requirements are not met. MI_11.6
r4"\

Sample Summary
Client Sample ID Lab Sample ID Collected Received Matrix
Comp#1 Site 1 Bluegill 31102775001 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#2 Site 1 Flathead Catfish 31102775002 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#3 Site 1 Blue Catfish sm 31102775003 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#4 Site 1 Blue Catfish Ig 31102775004 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#5 Site 2 Bluegill 31102775005 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#6 Site 2 Flathead Catfish 31102775006 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#7 Site 2 Blue Catfish 31102775007 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#8 Site 2 Common Carp 31102775008 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#9 Site 3 Bluegill sm 31102775009 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#10 Site 3 Bluegill Ig 31102775010 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#11 Site 3 FlatheadCatfish 31102775011 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#12 Site 3 Blue Catfish 31102775012 10/06/2011 00:00 10/06/2011 13:15 Tissue
Comp#13 Site 1 Blue Catfish Ig 31102775013 10/06/2011 00:00 10/06/2011 13:15 Tissue
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sas.com
N.C. Certification # 481
Member of SGS Group
Page 5 of 149

Results of Comp#1 Site 1 Bluegill
Client Sample ID: Comp#1 Site 1 Bluegill
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775001
Lab Project ID: 31102775
a
}-{Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result EMPC Qual DL LOQ/CL Units RT Ratio
2,3,7,8-TCDD ND U 0.123 0.459 pg/g
2,3,7,8-TCDF ND U 0.0501 0.459 pglg
\ J
Print Date: 11/01/2011 N.C. Certification # 481
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903f 910.350.1557 www.us.sas.com
Member of SGS Group
Page 6 of 149

Results of Comp#1 Site 1 Bluegill
Client Sample ID: Comp#1 Site 1 Bluegill
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 1102775001
Lab Project ID: 3 102775
>-LResults by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result
71.0
72.0
76.0
Batch Information
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/29/2011 21:07
Dilution: 1
EMPC
L. DL
LOQ/CL Units RT
40.0-135
40.0-135
40.0-135
Ratio
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt./Vol.: 10.9 g
Prep Extract Vol: 20 uL
Print Date: 11 /01 /2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903f 910.350.1557 www.us.sas.com
N.C. Certification # 481
Member of SGS Group
Page 7 of 149

e-LResults of Comp#1 Site 1 Bluegill
Client Sample ID: Comp#1 Site 1 Bluegill
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775001-A
Lab Project ID: 31102775
}{Results by Gravametric
Parameter
% Lipids
r—lBatch Information
Result
0.260
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
EMPC Qual DL LOQ/CL, Units RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 8 of 149

)))))))))))))))))))))))))))))))))))))))))))
Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:1MassLynx\Default.prolResultslb29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29octlla-4
Date: 29-Oct-2011
Time:21:07:59 J
ID: 311027750011
Submitter: HRD1459
Task:
MS Method Name: C:1MassLynxIDEFAULT.PROIACQUDBIdioxins_db5ms dw2.EXP
Description: Comp#1 Site 1 Bluegill
-fm 11')-II
1
2
3
4
5
6
7
:Name : Response. lon1Area: Ion2Area. RA .:RAFaiI?: RT; pg/pL. EDL; Heightl . Noisel; SN1. Height2::Noise2. SN2 ; M1 . M2. User RF
2378-TCDF - NO - 0.0273 591 552 1.004
;2378-TCDD NO / - 0.0670 1072 - - 999 1.171
ES:13C-2378-TCDD 5.256e5 2.288e5 2.969e5 0.77 NO 27.24 0.739 0.0999 2.870e6 1844 1556.5 3.610e6 2074 1740.1 bb bb 1.026
.ES:13C-2378-TCDF 8.193e5 3.618e5 4.575e5 0.79 NO 26.35, 71.737 0.0659 4.598e6 1812 2537.2 5.882e6 2158 2725.6 bb bb 1.577
.JS:13C-1234-TCDD 7.242e5 3.206e5 4.036e5 0.79 NO 26.55/ 100.000 0.1025 4.229e6 1844 2293.5 5.355e6 2074 2581.6 bb bb 1.000
• CS:37C1-2378-TCDD 1.332e5 1.332e5 - - 27.26/ 15.100 0.0182 1.653e6 848 1949.7 - bb 1.218
•F1 Lock Mass - - 51073 - -

Quantify Sample Report MassLynx 4.1 SCN640
###TCOD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Method: C:IMassLynxIDEFAULT.PROIMethDB1db5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:lMas¢..ynx1DEFAULT.PRO1CurveDBImtetras-051611d new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-4, Date: 29-Oct-2011, Time: 21:07:59, ID: 31102775001, Submitter: HRD1459, Task:
2378-TCDD
b29oct11 a-4
23.94 24.00:24.07
0 22.70 23.3923.69, �'AF\ 24.2024.4324.73 25.42
70 22.18 22.59 -..c 25.24
48- :� , sir-• - _ -1-----.- -^!. , .... , ... , i . ri ---- .7: �r-r � : s . i 1 :V-; - , ,-, i -r
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50
2378-TCDD
b29oct11 a-4
39-
Voltage SIR,EI+
319.8965
26.36 26.6427.49 27.90 6.272e+004
26.04 26.96 28.07 28.4428.68 29.05 29.38
.. .:"i 1-e= . , . �; �- r-r �, , ti , i -rr-s-r•-nrT?,-r-- . min
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
23.85 24.09.24.07
23.64�i
24.20 24.50 24.74
22.24 25.1925.42 25.93.26.01
26.44 26.96 27.23 27.36- -
28.76
22 00
ES-TCDD
b29oct11 a-4
22.50
23.00
%]1 ."1" 1
22 00 22.50 23.00
ES-TCDD
b29oct11a-4
23.50
24.00
24.50
25.00
25.50
23.50 24.00 24.50 25.00 25.50
26.00
26.50
27.00 27.50
26.55 ES:13C-2378-TCDD
27.24
26.00 26.50 27.00 27.50
26.55
I. ,. I I I . 1 1 , J
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00
ES:13C-2378-TCDD
27.24
CS-TCDD
b2 ,oct11 a-4
28.00
28.50
29.00
28.00 28.50 29.00
Voltage SIR,EI+
321.8936
29.65 7.938e+004
min
29.50 30.00
Voltage SIR,EI+
331.9368
4.286e+006
.., �...,� min
29.50 30.00
Voltage SIR,EI+
333.9339
5.426e+006
min
27.50 28.00 28.50 29.00 29.50 30.00
CS:37CI-2378-TCDD
27.26
\,
22.00
Ff'Lock Mass
b29oct11 a-4
e22.04 22.37 22.70
`\. •• 23.06
22.50 23.00
II
23.50 24.00 24.50 25.00 25.50 26.00
26.50 27.00 27.50
23.48 23.74 23.99 24.20 24 68 24.84 25 29 25.5025. 96 26.14 26.22 26.68 27.01
Voltage SIR,EI+
327.8847
1.693e+006
i min
28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
304.9824
27.87 28.0528 28 28.58 28.97 29.14 29 43 3.060e+006
min
22 00 22.50 23.00
23:50 24.00 24.50 25.00
25.50 26.00 26.50 27.00 27.50
28.00 28.50 29.00
29.50 30.00

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Name: b29oct11a-4, Date: 29-Oct-2011, Time: 21:07:59, ID: 31102775001, Submitter: HRD1459, Task:
2378-TCDF
b29oct11a-4 Voltage SIR,EI+
24.73 303.9016
5.162e+004
% 22.0822.31.• .1\ .....97 2928 .298923.28 23.59 24.05 ..25.06 .26.01 26 45,26.54 27.51 28,36 28.44 �.'A_ ' A_ ,, .,. .,. .,. ,,, , min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
b29oct11a-4 Voltage SIR,EI+
28.68 305.8987
�� 4.392e+004
22.09 26.39
22.34 22.7022.8223.16 23.59 23.84 24.0224.36 24.71 25.07 25.48 25.86 26.22 /`26.72 ,26.82 27.38 5 28.03 28.48 28.74 29.30
r r w i 29.09 29.91
66, `. , , , ,min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11 a-4
ES:13C-2378-TCDF
26.36
1 ; ., , , .. , .•i, , , , ,,,1 . , , , 1
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50
27.00 27.50 28.00
Voltage SIR,EI+
315.9419
4.668e+006
,,.,.,,.,,,,.,,,.,,.. ,,,, min
28.50 29.00 29.50 30.00
ES-TCDF
b29oct11a-4 ES:13C-2378-TCDF Voltage SIR,EI+
26.36 317.9389
i 5.962e+006
70-
cV2 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 i T 27.50 28.00 28.50 29.00 29.50 30.00�n
F'Lock Mass
bZoct11 a-4
22.04
Ole
Voltage SIR,EI+
304.9824
3.060e+006
22.37 24.20 24.84 25.50 25.96 27.87 28.97 29.88
22.70 23.06 23.48 23.74 23.99 24.68 25.29 26.14 26.22 26.68 27.01 28.0528.28 28.58 29.14 29.43
35 , , , ; min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

SG$
Results of Comp#2 Site 1 Flathead Catfish
Client Sample ID: Comp#2 Site 1 Flathead Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775002
Lab Project ID: 31102775
}-Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result EMPC gl& DL LOQ/CL Units RT Ratio
2,3,7,8-TCDD ND U 0.117 0.462 pg/g
2,3,7,8-TCDF ND U 0.0481 0.462 pg/g
Print Date: 11/01/2011 N.C. Certification # 481
SGS North America Iic.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
Member of SGS Group
Page 12 of 149

SG$
Results of Comp#2 Site 1 Flathead Catfish
Client Sample ID: Comp#2 Site 1 Flathead Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775002
Lab Project ID: 3 102775
Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
e—IBatch Information
Result EMPC
89.0
90.0
94.0
ual DL
LOQ/CL Units RT
40.0-135
40.0-135
40.0-135
%
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/29/2011 21:44
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.NoI.: 10.82 g
Prep Extract Vol: 20 uL
Print Date: 11 /01/2011
SGS North America Inc.
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sas.com
Member of SGS Group
Page 13 of 149

SG$
Results of Comp#2 Site 1 Flathead Catfish
Client Sample ID: Comp#2 Site 1 Flathead Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775002-A
Lab Project ID: 31102775
}-{ Results by Gravametric
Parameter
% Lipids
Batch Information
Result EMPC
0.170
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Qual DL
LOQ/CL
Units
0/0
RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903f 910.350.1557 www.us.sgs.com
N.G. Certification # 481
Member of SGS Group
Page 14 of 149

)))))))))))))))))))))))))))))))))))))))))))
Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:IMassLynxlDefault.prolResults\b29octila-ltetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
lbl '-I-Ii
Name: b29oct11a-54"
Date: 29-Oct-20 )/
Time: 21:44:39
ID: 31102775002
Submitter: HRD1459
Task:
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins__db5ms_dw2.EXP
Description: Comp#2 Site 1 Flathead Catfish
1
2
3
4
5
6
7
:Name : Response- Ion1Area: lon2Area: RA .:RAFaiI?: RT: pg/NL- EDL: Heightl - Noisel: SN1: Height2 :• Noise2 - SN2 : M1 : M2- User RF
:2378-TCDF NO 0.0260 - 902 520 1.004
:2378-TCDD - NO -/ - 0.0633 1196 - - 1346 - - 1.171
:ES:13C-2378-TCDD 6.710e5 2.954e5 3.756e5 0.79 NO 27.24 88.867 0.0857 3.774e6 1747 2159.8 4.799e6 1695 2830.8 bb bb 1.026
: ES:13C-2378-TCDF 1.047e6 4.572e5 5.899e5 0.78 NO 26.36/ 90.225 0.0625 5.953e6 1926 3090.8 7.451e6 1931 3857.7 bb bb 1.577
•JS:13C-1234-TCDD 7.359e5 3.274e5 4.085e5 0.80 NO 26.55//100.000 0.0879 4.355e6 1747 2492.5 5.440e6 1695 3208.8 bb bb 1.000
• CS:37CI-2378-TCDD 1.680e5 1.660e5 - 27.26/ 18.744 0.0216 2.066e6 1030 2005.9 - bb 1.218
:F1 Lock Mass - - 55705 -
6b1. 1° 9 6 a6ed

Quantify Sample Report
###TCDD TCDF Only ###
Dataset: Untitled
MassLynx 4.1 SCN640
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Method: C:1MassLynxIDEFAULT.PROIMethOBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:IM7LynxxDEFAULT.PRO1CurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-5, Date: 29-Oct-2011, Time: 21:44:39, ID: 31102775002, Submitter: HRD1459, Task:
2378-TCDD
b29oct11 a-5
24.00
23.23 23.74 24.10 24.73 26.16 26.34 26.49 26.70 27.26 27.7127.94 28.2328.46 28.84
44° : 22.5222.59 22.87 23.38���24.33- ,24.89 25.32 25.76
22 00
2378-TCDD
b29oct11 a-5
22.50
23.00
23.50
24.00
24.50
25.00
23.97 24.04
°io 22.16 23.77. , \ 24.58 24.96
34-
22.00 22.50 23.00 23.50
ES-TCDD
b29oct11 a-5
%1
22 00 22.50 23.00
ES-TCDD
b29oct11 a-5
1 ...,,...I.,..,,
24.00
24.50
25.50
26.00
26.50
25.45 25.73 26.26.26.34
27.00
27.50
28.00
28.50
Voltage SIR,EI+
319.8965
29.52 6.854e+004
29.00
27.26 27.71 27.97 28.71 29.17
25.00
25.50
26.00
26.50
27.00
27.50
ES:13C-2378-TCDD
26.55 27.24
28.00
28.50
29.00
29.50
min
30.00
Voltage SIR,EI+
321.8936
8.927e+004
min
29.50 30.00
Voltage SIR,EI+
331.9368
4.411 a+006
,...,,.,r.,,,. .............. .... ,....,....� min
23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50
ES:13C-2378-TCDD
26.55 27.24
26.00 26.50 27.00 27.50
Voltage SIR,EI+
333.9339
5.509e+006
.................... ..................4 min
28.00 28.50 29.00 29.50 30.00
CS-TCDD
b2goct11 a-5 CS:37CI-2378-TCDD
27.26
11 A
2 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
F1 Lock Mass
b29oc
Voltage SIR,EI+
327.8847
2.107e+006
t11a-5 Voltage SIR,EI+
`.22.04 22.37 22.62 22.90 23.58 24.05 25.3725.fi0 26.32 26.90 27.66 28,96 304.9824
23.36 24.27 24.73 24.96 ,25.06 26.11 27.08 27.8728.10 28.58 29.07 29.50 2.471e+006
41--� ... _ - . , ..__'.. . , � -, - ,-"�, ,min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Name: b29oct11a-5, Date: 29-Oct-2011, Time: 21:44:39, ID: 31102775002, Submitter: HRD1459, Task:
2378-TCDF
b29oct11a-5
1 22.08 22.74 22.88
23.23
23.6223.85 24.27 24.91 25.06
I J� �/� 24 56/V
\1\_�-•,...._
25.52 25.90
26.41 26.57
26.82 27.10
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00
Voltage SIR,EI+
303.9016
3.562e+004
27.26 27.71 27.90 28.46 28.73 29.15 29.5629.68
,.,,,,,, ,, min
27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
b29oct11a-5 Voltage SIR,EI+
24.60 305.8987
22.0822.31 3.593e+004
24.51 26.37
23.72 23.$5 25.37 25.55 27.29 27.57 29.63 29.76 29.86
;1 22.87 22.95 23.41 24•.68 25.04 !� 26.64 26.70,26.96 28.08 28.38.28.46 29.05 29.47 ^•
1.! :� r.�/ ' L� /�-J1 �n /`. r`� `�-. ^-� f J ' �� 2617 1 J� 1/ /` 11; �•-
1. . fJ �. , ,-_;. ,, ,,. , .-_.,..,.Aft._, 1! �' /1 `'�r`✓, .,��/l-' , f�_.%---- . �t
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11a-5
1
22 00
ES-TCDF
b29oct11 a-5
22.50 23.00 23.50 24.00 24.50 25.00
R22 00 22.50 23.00 23.50 24.00 24.50 25.00
v
F'eLock Mass
b22oct11a-5
ES:13C-2378-TCDF
26.36
A
I t
T. .., .. .. min
25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
315.9419
6.030e+006
ES:13C-2378-TCDF Voltage SIR,EI+
26.36 317.9389
7.522e+006
.1 j, ,.,.r... ,ir,.,....,., , • .,.I,,. ....r. ,......I., i min
25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
22.04 304.9824
2.471e+006
\ 22.23.58 24.05 25.3725.60
37 26.32 26.90 27.66 28.96
22;62 22.90 23.3624.27 24.7324.96...25.06 26.11 27.08 27.8728.10 28.58 29.07 29.50 29.88
41 ,. , , min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

Results of Comp#3 Site 1 Blue Catfish sm
Client Sample ID: Comp#3 Site 1 Blue Catfish sm
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775003
Lab Project ID: 31102775
>{Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result EMPC Qual DL LOQ/CL Units RT Ratio
2,3,7,8-TCDD 0.295 J 0.0983 0.459 pglg 27.26 0.62*
2,3,7,8-TCDF 0.277 J 0.0767 0.459 pglg 26.37 1.85*
Print Date: 11/01/2011
SGS North America Inc.
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sas.com
Member of SGS Group
Page 18 of 149

e-LResults of Comp#3 Site 1 Blue Catfish sm
Client Sample ID: Comp#3 Site 1 Blue Catfish sm
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775003
Lab Project ID: 31102775
}-Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
r-lBatch Information
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
87.0
88.0
90.0
Qual DL
LOQ/CL Units RT
40.0-135
40.0-135
40.0-135
%
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical DatefTime: 10/29/2011 22:21
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.NoI.: 10.9 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 19 of 149

c-LResults of Comp#3 Site 1 Blue Catfish sm
Client Sample ID: Comp#3 Site 1 Blue Catfish sm
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775003-A
Lab Project ID: 31102775
>-f Results by Gravametric
Parameter
% Lipids
Batch Information
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
2.44
Qual DL LOQ/CL Units RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sas.com
N.C. Certification # 481
Member of SGS Group
Page 20 of 149

Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only # /4
Dataset: C:IMassLynx1Default.prolResultslb29oct1 la-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29octlla-6
Date: 29-Oct-2011
Time:22:21:19
ID: 31102775003 4
Submitter: HRD1459
Task:
MS Method Name: C:1MassLynx\DEFAULT.PROIACQUDBtdioxins_db5ms_dw2.EXP
Description: Comp#3 Site 1 Blue Catfish sm
1
2
3
4
5
6
7
:Name
:2378-TCDF
2378 TCDD
: ES:13C-2378 TCDD
: ES:13C-2378-TCDF
•JS:13C-1234-TCDD
• CS:37CI-2378-TCDD
•F1 Lock Mass
Response- Ion1Area: Ion2Area. RA .RAFait?•
1.310e3 8.505e2 4.593e2 1.85 YES
1.056e3 4.021e2 6.539e2 0.61 YES
5.593e5 2.478e5 3.115e5 0.80 NO
8.644e5 3.787e5 4.857e5 0.78 NO
6.230e5 2.807e5 3.424e5 0.82 NO
1.372e5 1.372e5 -
RV pg!pL-
26.37/ 0.151
27.26' 0.161
27.23 87.496
26.36/ 87.978
26.54,z100.000
27.26, 18.077
EDL: Heightl - Noisel: SN1- Height2 :• Noise2 - SN2 : M1 : M2- User RF
0.0418 1.327e4 770 17.2 6.578e3 1082 6.1 bb bb 1.004
0.0536 5.400e3 872 6.2 9.121e3 905 10.1 MM MM 1.171
0.0978 3.134e6 1968 1592.8 4.003e6 1215 3294.8 bb bb 1.026
0.0746 4.829e6 1821 2652.3 6.164e6 1912 3223.6 bb bb 1.577
0.1003 3.574e6 1968 1816.0 4.317e6 1215 3553.3 bb bb 1.000
0.0288 1.748e6 1113 1570.5 - bb 1.218
57205 -
C_TCbFi -, )' 3 /0e3
8'•G NttpS
6P1.10 I. 96ed
2ooOpJ
/o q 3
1
i. aay/(,
0. X7-7-pi
-f.,r, 11-I- ! I

Quantify Sample Report
###TCDD TCDF Only ###
Dataset: Untitled
MassLynx 4.1 SCN640
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Method: C:IMassLynxIDEFAULT.PRO1MethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:IMas LynxIDEFAULT.PRO1CurveDBlmtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-6, Date: 29-Oct-2011, Time: 22:21:19, ID: 31102775003, Submitter: HRD1459, Task:
2378-TCDD
b29octl1a-6 Voltage SIR,EI+
23.97 24.05319.8965
27.26 6.757e+004
22.23 23.11 --'� �,.24.30�24.5824.81 25.24_25.34 25.6826.03 26.34 26.62 28.61 28.97 29.22 29.55
45 T, T . , , ,-1=y , , , ,1-, . , , , .. , r, , . , -'riYrr -e. i i-rt , . =, . , ,' rr.,s-rr, . , ,--n--•frr.-, .. , . j , -1 , • . ri ... , .'r. -i min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11a-6 Voltage SIR,EI+
23.9224.Q4 321.8936
25.42 26.54 27.05 7.535e+004
41� 22..14 23.38,23.48 - - - \,_ 24.33 ,24.43 24.91 25.22 25.80 26.11 26.36 i 27.24 27.99 29.25
--1, , , • , . , .,.-ip,i,�j ,f:'�' ,,,.r,1 , ,, , ,, • . , ,. r„ ,min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-6 ES:13C-2378-TCDO Voltage SIR,EI+
26.54 27.23 331.9368
%- . ,.. . , .. 3.615e+006
,,. ,. ,. ,. ,. ,. ;, ,, �,,.• . ,. ., ,. ,. ,. ,. 1 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11 a-6
22 00
22.50 23.00 23.50 24.00 24.50
ES:13C-2378-TCDD
26;,54 27.23
Voltage SIR,EI+
333.9339
4.379e+006
., , ..i ..i,... .,i min
25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b2%octlla-6 CS:37CI-2378 TCDD Voltage SIR,EI+
cu 27.26 327.8847
11 .. n 1.788e+006
.. ,, ,. ,, ,. ,. ,. ,, ,, , ,. ,. .,. ,. .,. 1 min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
F1`°Lock Mass
b29oct11a-6 Voltage SIR,EI+
22.04 22.37 22.93 26.29 28.25 29.63 304.9824
cAl22.54 23.53 23.85 24.46 24.53 24.63 25.14 25.53 25.88 26.18 - _ 26.92 26.98 27.41 .27.51` ` 28.08 _; 28.38 28.48 29.15.29.42 2.572e+006
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

)))))))))))))))))))))))))))))))))))))))))))
879ar3$1 t+•6 Smeotn(S0,1x2)
41
23.97
24.05
24 30
24.58 24 01
25 24 35.34
elirtell
2378-TCDD
402.127260
0.16 o 4jL
25.66 28.326182634 2862 6` 2961 2897
-.1
2922 2955
Vollage SIR,EI•
319 8965
6757e•004
29 68 30.0Z
min
829adi 1 a•6 Smoothr'S0.1,33
4t
23.9924 04
23.81
23.38 21.46Y^, Jrh
24 33 24.43 25.22 25.53
24.84 24.91 25.42 25.80 2811 28.38 26544
b:9asIt 18.8 8mcoth00,1 x2)
b79ac111 a•6 Srnoctlt7S0,1 %2)
26.54
2854
2378-TCOD
27.24
653 93
27.05 1009
27.99
96
1
22.75 23.00 23.25 23.50 2375 24..00 24:25 24.50 24 75 25.00 2525 25:50 25.75 26.00 26.2S 25.50 26.75 I7.00
61' 610 £Z a6ed
ES 13C-2370•T000
27.23
247785 23
87 50 pg$1L
1592 77
ES 13C•2378•TCDD_
2123
31152013
3294 81
VO t7gv SIR,EI•
321.8936
7 535e•004
29 25 30 01
min
Voltage SIR,EI•
3310388
3.6158.006
min
Vgtlage EIR•E1•
333 8339
4.3708.008
27.25
min
21,50 27.75 28.00 28'75 28.50 28.75 • 29.00 29.25 29.50 29.75 30.00

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Name: b29oct11a-6, Date: 29-Oct-2011, Time: 22:21:19, ID: 31102775003, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-6
25.68 2378-TCDF Voltage I 303.9016
22.32 25.62 1 26.37 4.643e+004
- 22.04/ 22.69 23.38 25.7625.99 28.08 28.46
22.75 23.62 23.87 24.25 24.38 25.12 25.29
` /,r ^ Jt ��24.46 - _ , l 26.72 27.03 27.43 27.89 \ �` /28.54 29.14 29.50 29.71
22 00 22.50 23.00 23.50 24.00 24.50 25.00 i 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 i ' 29.50 30.00
2378-TCDF
b29oct11a-6
22.34
22.041\ 22:74
\22.57
Voltage SIR,EI+
305.8987
4.341 a+004
2637
3.05 23.25 23.59 23.84 24.20 24 46 26.i 1 26.95 28.05 28.43 28.79
�,�� - �� 25.02_. j! ,25y14� ; 2fi.73 27.46 �„ d1 ,\ 29.12 29.61 29.86
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
25.09 25.47 25.67 28.23
ES-TCDF
b29oct11a-6 ES:13C-2378-TCDF Voltage SIR,E1+
26.36 315.9419
4.903e+006
,.,..,., .,.,. ,.... ,,,..,...,�, ..,,... ,.1., ,,,,,.,. . ..,....... ,,.,. . ..... ........ min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11 a-6
%_
ES:13C-2378-TCDF
26.34
Voltage SIR,EI+
317.9389
6.244e+006
,.j,, .,,,.,. min
12 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
N
A
F19Lock Mass
b2sDoct11 a-6
CO Voltage SIR,EI+
,22.04
+
22.37 22.54
2.572e+006
\ -1 Jt•22.75 23.25 23.53 23.85 24.46 24.53 24.63 25.14 25.53 25.88 26.1826.29 26.92 26.98 27.41 27.51 28.0828.25 28.38 28.48 29.24 29.42 29.63 29.91
- ��_ -__- _ _._ _�•.Y r-..•w��..
�. ,, 1.= , min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

c-LResults of Comp#4 Site 1 Blue Catfish Ig
Client Sample ID: Comp#4 Site 1 Blue Catfish Ig
Client Project ID: Annual Fish Project 2011
Lab Sample ID: Z1102775004
Lab Project ID: 31102775
Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Result EMPC
ND
ND
Qual DL LOQ/CL Units RT
U 0.181 0.489 pg/g
U 0.219 0.489 pg/g
Ratio
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 25 of 149

e-LResults of Comp#4 Site 1 Blue Catfish Ig
Client Sample ID: Comp#4 Site 1 Blue Catfish Ig
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775004
Lab Project ID: 31102775
}-)Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
rd Batch Information
Result EMPC
69.0
69.0
71.0
Qual DL LOQ/CL Units RT
40.0-135 %
40.0-135 %
40.0-135 %
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/29/2011 22:58
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.NoI.: 10.22 g
Prep Extract Vol: 20 uL
Print Date: 11 /01!2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sos.com
N.C. Certification # 481
Member of SGS Group
Page 26 of 149

Results of Comp#4 Site 1 Blue Catfish !g
Client Sample ID:
Client Project ID:
Lab Sample ID: 3
Comp#4 Site 1 Blue Catfish Ig
Annual Fish Project 2011
1102775004-A
Lab Project ID: 31102775
}-Results by Gravametric
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result
% Lipids 3.69
Batch Information
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
EMPC
ual DL
LOQ/CL
Units
ok
RT
Ratio
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 27 of 149

Quantify Sample Summary Report
###TCDD TCDF Only ##1#
MassLynx 4.1 SCN640
Dataset: C:1MassLynx\Default.prolResults1b29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11a-7/
Date: 29-Oct-20111
Time: 22:58:05
ID: 31102775004,
Submitter: HRD1459
Task:
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins_db5ms_dw2.EXP
Description: Comp#4 Site 1 Blue Catfish ig
1
2
3
4
5
8
7
:Name
:2378-TCDF
:2378-TCDD
: ES:13C-2378-TCDD
: ES:13C-2378-TCDF
-JS:13C-1234-TCDD
• CS:37C1-2378-TCDD
• F1 Lock Mass
• Response- Ion1Area• Ion2Area: RA .:RAFail?•
NO
NO
4.485e5 1.997e5 2.488e5 0.80
6.908e5 3.076e5 3.832e5 0.80
6.366e5 2.784e5 3.582e5 0.78
1.098e5 1.098e5
NO
NO
NO
RT: pg/pL. EDL: Heightl: Noisel:
0.1121 - 1550
0.0925 - 1237
27.23f/ 68.676 0.0940 2.512e6 1781
26.34f 68.810 0.0809 3.786e6 1742
26.54�100.000 0.0965 3.510e6 1781
27.26/ 14.156 0.0466 1.341e6 1821
50792
1410.6 3.160e8
2173.1 4.777e6
1970.8 4.615e6
736.0
SN1: Height2 :. Noise2 - SN2 ; M1
2278
1207
1315 2402.8 bb
2351 2032.2 bb
1315 3508.8 bb
- bb
M2 User RF
1.004
1.171
bb 1.026
bb 1.577
bb 1.000
1.218
6t410 8Z e6ed

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Method: C:IMassLynxIDEFAULT.PROIMethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:IMassLynxIDEFAULT.PROICurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-t1', Date: 29-Oct-2011, Time: 22:58:05, ID: 31102775004, Submitter: HRD1459, Task:
2378-TCDD
b29oct11a-7
22.11 23.81. 23.90 23.99
22.57 22.92 23.54 24.58 24.76
22.00 22.50 23.00 23.50 24.00 24.50
25.20 25.29 25.63 26.21 26.36 26.90.26.96 27.26
25.00
25.50
26.00
26.50
27.00
Voltage SIR.EI+
319.8965
5.734e+004
27.79 28.03 28.31 28.82 28.9229.15 29.80��
min
27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11 a-7
Voltage SIR.EI+
24.00 321.8936
syd 22.09 23.6123.90. .^, 24.22 28.17 9.084e+004
33 _22.59 23.39., r ; J ` �� 25.14..25.24 25.63 26.3626.59 26.92 27.26 27.51 27.80 28.30
r'. r,-•r -1-, r-- 29.0T,-�. 29.fi0
,..- 1�,-�- T ,,. r--�,-�,-�..�............. T , j,. ••min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11 a-7
1•
26.54 ES:13C-2378-TCDD
;'\ 2A
i,,,,T,,..,,.. ,,, .;.. t min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 n 26.50 27.00 27.50 28.00 28.50 29.00 29., 50 30.00
Voltage SIR.EI+
331.9368
3.551e+006
ES-TCDD
b29oct11 a-7
ES:13C-2378-TCDD Voltage SIR,EI+
26.54
333.9339
01��27 23
n 4.669e+006
, 1,,, ,, 1 .1„.; T;i ,. ,; ,;„,,
1'= min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b29oct11 a-7
-v CS:37CI-2378-TCDD Voltage SIR.EI+
23.61 27.26 327.8847
I
23.25 ; , 25.14 25.40 / `. 1.685e+006
= = i min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
F1`ci.ock Mass
b29oct11a-7 Voltage SIR.EI+
22.04 22.37 22.90 24.05 24.64 24.92 25.32 27.69 28.25 304.9824
% I mo_ 22.72 23.46 23.56 24.20 _ 25.11 25.6625.90.25.99 26.27 26.83 27.6127.67 28.07 28.86 -_28.96 29.55 2.485e+006
40 �,,..�. ,. ,, , , , . „1 .,1,.,,, i_..__ min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Name: b29oct11a-7, Date: 29-Oct-2011, Time: 22:58:05, ID: 31102775004, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-7
2807 Voltage SIR,EI+
.
25.66 28.20 303.9016
',o y 11 \ �'y 1.026e+005
22.36 23.58 24.23 24.45 25.07 %! 25.98 26.37 27.43 27.77 � 29. i 5 29.76 29.89
' : - 22.72 23.25 23.85 25.48/ \ 26.72 27.21 27.61 28.46 28.94
v1 r . .I.,r,�- `.i,�..;....i....�'.. Amin
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
b29oct11 a-7
28.05 28.20
25.65 ill
%- 22.32 24.25 25.09 �' 25.98 1 �t
22.74 23.23 23.58 23.87 :1 24.74 r-., 25.50 26.34 26.72 27.00 27.44
22 00 22.50 23.00 23.50 24.00 _ 24.50 1 25.00 25.50 26.00 26.50 27.00 27.50 27.77 i \i \ 28.43
ES-TCDF
b29oct11 a-7
%-
ES:13C-2378-TCDF
26.34
'
22 00 22.50 23.00I 23.50 24.00 ' . T 24.50 25.00 I 25.50 26.00
ES-TCDF
b29oct11 a-7
%-
t
26.50
ES:13C-2378-TCDF
26.34
28.00
28.50
27.00 27.50 28.00 28.50
28.94 29.14
•
29.00
29.50
Voltage SIR.EI+
305.8987
1.156e+005
29.89
29.63 ' ,
min
30.00
Voltage SIR,EI+
315.9419
3.837e+006
29.00 29.50
, min
30.00
Voltage SIR,EI+
317.9389
4.851e+006
,, ,. ,. I. ,, ,. ,• I ,. I. ,'"i "r ri.rr., I min
2 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
F1.ock Mass
b2ict11a-7
co .22.04
22.37
22.90 24 0 .05 24.64 24.92 25.32 28.25 28.86.28.96 29.55 29.81
I I
�� 22.7223.46,23.56 24.20 25.11 25.6625.90.25.99-.26.27 26.83 27.5127.572769
' - 28.07
40 , �...,,...... ,. , r min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 3-0.00
Voltage SIR,EI+
304.9824
2.485e+006

r-LResults of Comp#5 Site 2 Bluegill
Client Sample ID: Comp#5 Site 2 Bluegill
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775005
Lab Project ID: 31102775
8Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Result
ND
ND
EMPC Qual DL
U 0.184
U 0.0528
LOQ/CL
0.457
0.457
Units RT
pg/g
Pglg
Ratio
•
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sas.com
N.C. Certification # 481
Member of SGS Group
Page 31 of 149

ii,Results of Comp#5 Site 2 Bluegill
Client Sample ID: Comp#5 Site 2 Bluegill
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775005
Lab Project ID: 31102775
}-I Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
Batch Information
Result
96.0
97.0
106
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
EMPC Qual DL LOQ/CL Units RT
40.0-135 %
40.0-135 %
40.0-135 %
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/29/2011 23:34
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.Nol.: 10.95 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 32 of 149

/—[Results of Comp#5 Site 2 Bluegill
Client Sample ID: Comp#5 Site 2 Bluegill
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775005-A
Lab Project ID: 31102775
}-(Results by Gravametric
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result
% Lipids 0.540
Batch Information
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
EMPC Qual DL LOQ/CL Units
RT
Ratio
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 33 of 149

Quantify Sample Summary Report
###TCDD TCDF Only Mt
MassLynx 4.1 SCN640
Dataset: C:1MassLynx1Default.pro1Results1b29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11 a-8-,
Date: 29-Oct-2011/
Time: 23:34:50
ID: 31102775005 /
Submitter: HRD1459
Task:
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins db5ms_dw2.EXP
Description: Comp#5 Site 2 Bluegill
1
2
3
4
5
6
7
:Name : Response: IonlArea: Ion2Area: RA . RAFaiI?: RT: pg/pL. EDL: Heightl . Noisel: SN1. Height2 :• Noise2: SN2 : M1 . M2: User RF
:2378-TCDF NO - 0.0289 659 988 - 1.004
:2378-TCDD NO / ' - 0.1009 2520 - - 1649 1.171
: ES:13C-2378-TCDD 7.083e5 3.148e5 3.935e5 0.80 NO 27.21 95.580 0.0865 3.921e6 1604 2443.7 4.857e6 1701 2856.0 bb bb 1.026
.ES:13C-2378-TCDF 1.109e6 4.887e5 6.202e5 0.79 NO 26.32/ 97.351 0.0738 6.248e6 1948 3207.9 7.923e6 2384 3323.1 bb bb 1.577
•JS:13C-1234-TCDD 7.223e5 3.219e5 4.004e5 0.80 NO 26.52/ 100.000 0.0888 4.149e6 1604 2585.9 5.158e6 1701 3032.5 bb bb 1.000
• CS:37CI-2378-TCDD 1.863e5 1.863e5 27.25/ 21.178 0.0249 2.337e6 1131 2066.1 - bb 1.218
:F1 Lock Mass - 44009 -
61410 ti£ e6ed

)))))))))))))))))))))))))))))))))))))))))))
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Method: C:1MassLynxIDEFAULT.PROIMethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:1Ma sLynADEFAULT.PRO1CurveDBlmtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-8, Date: 29-Oct-2011, Time: 23:34:50, ID: 31102775005, Submitter: HRD1459, Task:
2378-TCDD
b29oct11a-8 Voltage SIR,EI+
23.87.23.97 24.13 319.8965
6°/400 22.32 23.53 �� _ 26.32 26 55 - -- 28.53 - 4.803e+004
_„_ 22.7422.97 2_ _ j, ✓" ' "�.--� 24.53 25.19 25.25 25.88 25.98 26.82 27.24 27.52 27.89 28.31 29.04 29.33
i : .r'rr''i f. , ?'r min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11a-8 Voltage SIR.EI+
2384 23.94 321.8936
.
22.09 22.41 22.88 ; \, 24.17 25.37 29.736.799e+004
%\. 23.08 23.58- _ _ _ \_ 24.84. 25.12_25.22 25.73 26.04 26.34 27.26 27.79 28.66
45, . ,-q , , ,< i r .. , , F , , , .. • r • .'r. T .'' - ; 1 ' . , , . t p--r, I --' ; - ,-r n (7, - , r i -.. ,_ ,.-r.. i rrrr rr-1-.-f- 1---r.- --.-.-ram min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11 a-8 ES:13C-2378-TCDD
26.52 27.21
'
1 ., , i„ .i i ,. ,
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50
Voltage SIR,EI+
331.9368
4.204e+006
, ..•imin
28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29octlia-8 ES:13C-2378-TCDD Voltage SIR,EI+
26.52 27.21 333.9339
r,/o A f 5.212e+006
,.. =I== `i=. 'T,,.-,i,.,.i,,..i,,,.I .-,T,,,- 7,..,,.,,.,�,_ ,,,..I, ..,,..-.,. �',\ ,.,i.,, i,.,,i,.,.i,,., ._. I....,... i .,.i min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b29oct11a-8 CS:37CI-2378-TCDD Voltage SIR,EI+
27.24 327.8847
al „ „ „ .. 2.390e+006
i i. .i, ., .i ; ., i i , i , , ,, , i min
%2.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
A
t0
F1 Lock Mass
b29oct1'la-8 Voltage SIR,EI+
22.0822,37 304.9824
,/o 23.92 24.20 28.64 29.45 29.73g,g53e+006
22.80 23.31 23.74 24.71 25.01 25.34 25.68 26.16 26.46 26.92 27.64. 27.72 28.02 28.26 - 28.86
39 �`� ��-, Tom -iT - :- iT_._-.,_ ,,..,, --,1 , _ _-, :�- i-----i min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Name: b29oct11a-8, Date: 29-Oct-2011, Time: 23:34:50, ID: 31102775005, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-8
Voltage SIR,EI+
29.98
23.36 303.9016
22.11
22.29 22.72 22.97 .., - • ,�_6.4 26.o i27.95
�...., ` _.. _
- ca.u�r 1b.4/ ) �. �w �. i .1S.I6 j
22 00 22.50 23.00
2378-TCDF
b29oct11a-8
23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
22.31 25.63 26.36 305.8987
P 4.186e+004
i' .� 23.08 23.49 24.00 24.13 24.30 � i � 26.55 27.48 28.02 28.22 28.46 29.24
�. i, 22.49 24.53 25.06 25.43125.80 26.11 i`26.70 27.13 27.8222.74 23 21 , 1 1 :1::�,..,,,, .,i...,i .. ..,,....i,,..,....i. r.,.i. i.,,.,....i...,,.... ..,,�,,.,,,,,,..... ...........i,. ,i.'..i ..,,-.. ...t min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30..0
ES-TCDF
b29oct11a-8
%,
0
22 00
22.50
ES:13C-2378-TCDF
26.32
11\
,,. , „ ,...,r,.. , ,,,, , min
Voltage SIR,EI+
315.9419
6.314e+006
23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11a-8 ES:13C-2378-TCDF Voltage SIR,EI+
26.32 317.9389
7.989e+006
%-
O,, „ .,,,.,,,,..,i..,.., i ,.,..i.. , i ; , 1 . , i., ,.,..i. i ,..I ,. ..i .. , , 1 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
w
0)
F'ILock Mass
b22pct11a-8 Voltage SIR,EI+
22.08 304.9824
2.853e+006
22.37
23.92 24.20 28.64 29.58
22.80 23.31 23.74 24.71 25.01 25.34 25.68 26.16 26.45 26.92 27.64 27.72 28.02 28.26 28.86 29.73
39---.,.; .� ._ ,.,, , ' -, ;.,•.i ,_.. -__ �- --,: min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
)))))))))))))))))))))))))))))))))))))))))))

e-IResults of Comp#6 Site 2 Flathead Catfish
Client Sample ID: Comp#6 Site 2 Flathead Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775006
Lab Project ID: 31102775
}-{Results by SW-846 8290A
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Result
0.439
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
EMPC
0.112
Qual DL LOQ/CL Units RT Ratio
J 0.0955 0.457 pg/g 27.24 0.85
J 0.0467 0.457 pg/g 26.37 1.68*
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 37 of 149

SG$
Results of Comp#6 Site 2 Flathead Catfish
Client Sample ID: Comp#6 Site 2 Flathead Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775006
Lab Project ID: 31102775
Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
Batch Information
Result EMPC
101
104
106
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Qual DL LOQ/CL, Units RT
40.0-135 %
40.0-135 %
40.0-135 %
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/30/2011 00:11
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.Nol.: 10.93 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc.
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sus.com
Member of SGS Group
Page 38 of 149

Results of Comp#6 Site 2 Flathead Catfish
Client Sample ID: Comp#6 Site 2 Flathead Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775006-A
Lab Project ID: 31102775
}-[Results by Gravametric
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
% Lipids
Batch Information
Result EMPC
0.730
Qua! DL
LOQICL
Units
RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc.
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.scis.com
Member of SGS Group
Page 39 of 149

Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:1MassLynxlDefault.pro\Results1b29oct11a-1tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11a-9 ,
Date: 30-Oct-2011 /
Time: 00:11:31
ID: 31102775006 /
Submitter: HRD1459
Task:
MS Method Name: C:1MassLynxIDEFAULT.PROIACQUDBIdioxins db5ms_dw2.EXP
Description: Comp#6 Site 2 Flathead Catfish
1
2
3
4
5
6
7 :F1 Lock Mass
:Name Response: lon1Area:Ion2Area:
:2378-TCDF 7.712e2 4.830e2 2.881e2
:2378-t.2D 2.2444e + 1.028e3 1.215e3
: ES:13C-2378-TCDD 7.984e5 3.530e5 4.453e5
.ES:13C-2378-TCDF 1.262e6 5.582e5 7.039e5
. JS:13C-1234-TCDD 7.707e5 3.397e5 4.310e5
• CS:37CI-2378-TCDD 1.999e5 1.999e5 -
RA . RAFail?:
1.68 YES
0.85 NO
0.79 NO
0.79 NO
0.79 NO
RT: pg/pL:
26.37/ 0.061
27.24/ 0.240
27.2100.963
26.34/ 103.846
26.54/ 100.000
27.26 / 21.290
EDL: Heightl . Noisel: SN1: Height2 :. Noise2 . SN2 : M1 - M2- User RF
0.0255 7.728e3 657 11.8 3.870e3 995 3.9 bb bb 1.004
0.0522 1.137e4 1142 10.0 1.611e4 1326 12.2 MM MM 1.171
0.0927 4.461e6 1881 2371.4 5.592e6 1894 2952.1 bb bb 1.026
0.0580 7.140e6 1776 4019.8 8.979e6 1853 4844.6 bb bb 1.577
0.0951 4.374e6 1881 2325.6 5.532e6 1894 2920.1 bb bb 1.000
0.0244 2.474e6 1180 2097.4 - bb 1.218
46844 -
Ercbb3 �-?L {e3 - - ..r-
~ `Vosges- 10.939 1.171�
1
61410 Ott eBed

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Method: C:1MassLynx%DEFAULT.PROIMethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:IMas,Lynx10EFAULT.PROICurveDB%mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-9, Date: 30-Oct-2011, Time: 00:11:31, ID: 31102775006, Submitter: HRD1459, Task:
2378-TCDD
b29oct11 a-9
22.28 23.3023.53 23.892, 3.95�24.05 24.33
2214 , 26 55 27 24 27.46 29.01 5.943e+004
22.65 23.10�� _ �24.5824.99 25.27 25.76 26A6 26.36 , ' 27.94 28.31 28.58 29.329.38
51 r� r � r . ^, �-t . , r �-; --r r,-z- r r
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11 a-9
23.84 23.97 24.12
,�0 22.08 22 92 23.64 1. 24.94 25.25
_ 22.65 n :_.., 24.59 25.0626.36
43. - . ri- - 25.65 25 90
.ram_ - ..... .... _ -:
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50
Voltage SIR,EI+
319.8965
Voltage SIR,EI+
321.8936
26.85 27.26 „_ ,.., 28.41 28.84 7.071e+004
28.63
min
28.00 28.50 29.00 29.50 30.00
27.00
27.50
ES-TCDD
b29oct11a-9 ES:13C-2378 TCDD Voltage SIR,EI+
26.54 27.23 331.9368
4.516e+006
1,.. , , ,. , , •, „ , .,I „ ,,,, „ , .. i '-, . , • , ., , , • . , „ ,. „ , . min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 ^ 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11 a-9
o0a_1
ES:13C-2378-TCDD
26.54 27.23
.., , , ..,.., ,. . ,. . , .., ,. ..,, , it min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
333.9339
5.641e+006
CS-TCDD
b29 ct11a-9 CS:37CI-2378-TCDD Voltage SIR,EI+
co 27.26 327.8847
11 , , . , . , „ „ 2.529e+006
. ,. , , , ,, ,., , I I 'i' ,, L ;, i, .,,. .,. ,. i I ,, , min
32.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
it
FI Lock Mass
b29oct11a-9
Voltage SIR,EI+
.22.04 22.41 304.9824
,�o'� 25.32 26.31 28.66 29.68 2.653e+006
f�____ 22.9723.20 23.44 23.82 24.15 24.46 24.78 25.17 25.73 26.13 26.96 27.43 27.72 28.18 28.26 29.09
39' .,...., -- • ' ,..,.I,,,.i -_.- - ..- ;___--,- --- T _�_ ,. ,... min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

0228111 a-9 StocothiS0.1 0)
96
51
2330
22 65 2310 !�
24.38
/ 24.58 2173 24.99
L! `!V 4...-J252548 2576
26,05
26 35
26.55 26 98
Voltage SIR,EI•
319 89R5
5 9436.004
2378-TCDD
27.24
1028.31
0.74 WA_
995
29.38 29.93 30 04 30.16
Z7 46 27.94 28.3 2 32} - 28 7� 0� !30
15
0290c11 t a•9 Smoom7S0,1 r2)
43
6ti 6 Jo Zb 86ed
23 97
23.84
2377
24.12
22.92
i 236\
tjI '�Isi
22 65 /
22.75 23.00 23.25 23.50 73.75 24:00 24:25
24.18
voltage SRO.
321.6938
7 0714.004
2370.TCDD
27.26
121530
1215
1 26.36
24.5� , 2, 8 25 5.6 26.09 1 28�89`��}36 28.41 28.63 78 84 3819 30./7
24 50 24 75 755.00 25.25 • 25.50 25:75 26 00 26.25 266 50�2�6:75 27 00 27.25 27:50 27'75 • 28.00 2825 28T50 28'75 29.00 29.25 29:50 29 75 30'80 30 25 30.50 ml„

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Name: b29oct11a-9, Date; 30-Oct-2011, Time: 00:11:31, ID: 31102775006, Submitter: HRD1459, Task:
2378-TCDF
b29oct11a-9
-1 70 . „•, ,..,.. „•,•.,•,, ,., „..1 ..'t • , , .,,, ...r--.•.••.•1••• •.•,•.,•,•,. „ •.•,,,,,1•, ,...,,••• r „ , ,. , ,. .. ..., ., , ,,,I min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
2378-TCDF 28.73 303.9016
26.37 '1 4.207e+004
22.28 22.69 23.38 25.50 25.91 26.09 26.72 26.93 28.07 28.46 i 29.20
\ 23.5623.79 24.08 24.45 24.69 25.0927.44 27.71 1 9 04 29.4229.65 29.96
2378-TCDF
b29oct11a-9
22.31 25.48 2378 TCDF
28
A
2463
92
22.37 23.34 23.49 23.74 .
24.17 24.78 25.14
26.24
25.65 26.36 26.73 26.95 27.43 28.05 28.46
28.61 .
29.02
t.f� �` /\ 28.00•
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00
ES-TCDF
b29oct11 a-9
ofo
0
ES:13C-2378-TCDF
26.34
Voltage SIR,EI+
305.8987
29.43 3.846e+004
29.71 29.81
29.50 30.00
Voltage SIR,EI+
315.9419
7.233e+006
22 00 22.50
ES-TCDF
b29oct11 a-9
",,
23.00 23.50 24.00
i " ' I " 1 ' I
24.50 25.00
25.50 26.00 26.50 27.00 27.50 28.00
V2 00 22.50
F'S.Lock Mass
b2 oct11a-9
�22.04
23.00
23.50 24.00
"
o � .41 22.57
22.97 23.20 23.44 23.82
22
•
39 ,,,,.,
22.00 22.50 23.00 23.50
24.50 25.00 25.50
24.15 24.46 24.78 25.17 25.32 25.73
ES:13C-2378-TCDF
26.34
III
28.50 29.00 29.50 30.00
Voltage SIR,EI+
317.9389
9.056e+006
26.00 26.50 27.00 27.50 28.00 28.50 29.00 291.50 30.00
min
26.13 26.31 26.96
24.00 24.50 25.00
25.50 26.00 26.50 27.00
Voltage SIR,EI+
304.9824
2.653e+006
28.66
27.43 27.72 28.18-.28.26 29.09 29.58 29.68,:29 78
min
27.50 28.00 28.50 29.00 29.50 30.00

id Results of Comp#7 Site 2 Blue Catfish
Client Sample ID: Comp#7 Site 2 Blue Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775007
Lab Project ID: 31102775
}Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result EMPC Qual DL LOQ/CL Units RT Ratio
2,3,7,8-TCDD ND U 0.200 0.473 pg/g
2,3,7,8-TCDF ND U 0.0853 0.473 pglg
Print Date: 11/01/2011 N.C. Certification # 481
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
Member of SGS Group
Page 44 of 149

r-LResults of Comp#7 Site 2 Blue Catfish
Client Sample ID: Comp#7 Site 2 Blue Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 1102775007
Lab Project ID: 3 102775
> -R Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
Batch Information 111
Result
72.0
72.0
76.0
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
EMPC Qual DL
LOQ/CL Units RT
40.0-135
40.0-135
40.0-135
OA
%
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Datemme: 10/30/2011 00:48
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt./Vol.: 10.57 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 45 of 149

Results of Comp#7 Site 2 Blue Catfish
Client Sample ID: Comp#7 Site 2 Blue Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775007-A
Lab Project ID: 31102775
Results by Gravametric
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result
% Lipids 3.13
Batch Information
EMPC Quai DL LOQ/CL Units
%
RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903f 910.350.1557 www.us.sas.com
Member of SGS Group
Page 46 of 149

Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:1MassLynx\Default.prolResults1b29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11 a-10/
Date: 30-Oct-2011
Time: 00:48:16
ID: 31102775007
Submitter: HRD1459
Task:
`1 11-1-)
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins_db5ms_
Description: Comp#7 Site 2 Blue Catfish
dw2.EXP
1
2
3
4
5
6
7
:Name
:2378-TCDF
2378-TCDD
: ES:13C-2378-TCDD
: ES:13C-2378-TCDF
.JS:13C-1234-TCDD
• CS:37CI-2378-TCDD
• F1 Lock Mass
Response: Ion1Area: Ion2Area :
4.436e5 1.950e5 2.486e5 0.78
6.836e5 3.027e5 3.810e5 0.79
6.002e5 2.680e5 3.322e5 0.81
1.112e5 1.112e5
RA • RAFaiI?;
NO
NO
NO
NO
NO
RT: pg/pL- EDL:
0.0451
0.1059
27.2� 72.034 0.1242
26.34/ 72.234 0.0879
26.54/ 100.000 0.1274
27.24/ 15.208 0.0257
Heightl - Noisel; SN1. Height2 Noise2 . SN2 : M1 M2: User RF
592 973 1.004
1179 - - 1561 1.171
2.428e6 1669 1455.1 3.068e6 2276 1347.6 bb bb 1.026
3.827e6 2054 1863.5 4.876e6 2239 2177.5 bb bb 1.577
3.457e6 1669 2072.0 4.281e6 2276 1880.6 bb bb 1.000
1.422e6 970 1465.3 - bb 1.218
45074
6f'1. Jo Lb 96ed

Quantify Sample Report
###TCDD TCDF Only ###
Dataset: Untitled
MassLynx 4.1 SCN640
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Method: C:1MassLynxIDEFAULT.PROIMethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:lMassLynxIDEFAULT.PRO1CurveDBlmtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-10, Date: 30-Oct-2011, Time: 00:48:16, ID: 31102775007, Submitter: HRD1459, Task:
2378-TCDD
b29oct11a-10 Voltage SIR.EI+
22.39 23.62
23.87 24.00 319.8965
%,1 22.23 22.7422.97 23.10 -, - - `-' __`24.10 24.5824.69 25 20 25.68 26.2426.36 27.23 27.52 28.89 29.14 29.63 +
%� 26.78 27.61 28.23 28.53 \ \ 29.28 •5.731 a 004
51 -? .. , , , . i 'i, .. . , i T , , . , 1 ' , , i � . . , , . ... ... „ , . .. T ". , " - ri-, T-r-rrrr, , 1 i T , 1 , .. 1 . , , I \ . i . . 1 miff
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11 a-10
36
23.8223.94 24.09
2,2.08 22.36 2458
22.74 23.36 24.28 .24.79 25.22
26.34 26.47
7"L
27.21,2 r.31
28.23
29.19
Voltage SIR,E1+
321.8936
29.71 8.326e+004
22.00
ES-TCDD
b29oct11 a-10
1,
22.50
23.00
23.50
24.00
24.50
25.00
25.50
26.00
26.50
27.00
27.50
26.54 ES:13C-2378-TCDD
27.21
min
28.00 28.50 29.00 29.50 30.00
22.00 22.50 23.00 23.50
ES-TCDD
b29oct11 a-10
24.00 24.50
25.00 25.50 26.00 26.50
961 1
22 00 22.50 23.00 23.50 24.00 24.50 25.00
CS-TCDD
b2soct11 a-10
w
27.00 27.50 28.00
26.54 ES:13C-2378-TCDD
27.21
�1 n,
25.50 26.00 26.50
27.00 27.50 28.00
CS:37CI-2378-TCDD
27.24
/`.
°%2 00 22.50 23.00 23.50 24.00
co
F1Lock Mass
b29oct11 a-10
22.04
28
22.00
22.77 22.95
22.50 23.00 23.50 24.00 24.50 25.00 25.50
24.50 25.00 25.50 26.00
26.50 27.00 27.50
28.50 .29.00 1 29.50
Voltage SIR.EI+
331.9368
3.512e+006
,min
28.50 29.00 29.50 30.00
Voltage SIR,EI+
333.9339
4.320e+006
min
30.00
Voltage SIR.EI+
327.8847
1.463e+006
, 1 min
28.00 28.50 29.00 29.50 30.00
23.56 23.94 24.25 24.56 24.69 25.12 25.52 25.78 26.2126.27 26.98 27.05 27.56 27.69
26.00 26:50
27.00 27.50
Voltage SIR.EI+
304.9824
28.22 28.61 28.99 29.37 _ 2.804e+006
28.00 28.50 29.00 29.50 30.00

2378-TCDF
b29oct11 a-10
Voltage SIR,EI+
305.8987
22.34 26.42 3.945e+004
' 22 5122.74 22.87 23.1123.46 23.90 24.3324.45 25;0 26.14 v' 26.72 26.96 27.44 28.00� 0? 28.33 28.71 28.87 29•6529.71
�,n� 1� , ,`� 24.92 25.22 25.78 i �! " ` 29.15 �'`
,. ,,, ,,,. .,,, ,. , , .,. .,. .,, .T .,. .,, r. ,. r,.-, ,.,,,,. ,..., ... ......:..... min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11 a-10
i
22 00 22.50
ES-TCDF
b29oct11a-10
%_
23.00 23.50 24.00
24.50 i 25.00 25.50
ES:13C-2378-TCDF
26.34
Voltage SIR,EI+
315.9419
3.884e+006
ill
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES:13C-2378-TCDF
26.32
Voltage SIR,EI+
317.9389
4.945e+006
,,,,,,,,,,,,,,,.,,,,,,..,, ,,,..,,.:.,...,,., ,,,, ,.,..,..,,,. ,... , ,....,,..,,,,,.,.,,., min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
A
CD
F'FLock Mass
b22oct11a-10 Voltage SIR,EI+
. 22.04 304.9824
2.804e+006
%22,77 22.95 23.56 23.94 24.25 24.56 24.69
25.12 25.52 25.78 26.2126.27 26.9827.05 27.56 27•69 28.22 28.61 28.99 29.37 29.6629'78
l
)))))))))))))))))))))))))))))))))))))))))
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:44 Eastern Daylight Time
Name: b29oct11a-10, Date: 30-Oct-2011, Time: 00:48:16, ID: 31102775007, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-10
Voltage SIR,EI+
26.95 303.9016
22.36 23.87 4.818e+004
22.19 22.72 23.07 23.33 23.61 23.99 24.8825.11 25.48 25.7525.98 28.22 28.76 29.04
26.37 26.44 27 71 28.40 29.3329.56 29.63 29.81
-.11---� - �.r.�._�; •...,�..-.._/- �,_ _ - 24.43-•`-- .A v.,--� 27.47 .----�-- -^ `__ - --�
59 ,..,,, .................. ,,...,,1.. .,-..,,,,..,.. .,,,.,, ,.,, ..,..,., ,.,r ,., ,, ,....,,..,,. ,,,. ...,,,, ,...,,... ,... ,,...,, i min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
26.36
28 ,.,.., ,.. , ,. ,,... , ..T ,.,, ,.,,.. min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

SG$
c-LResults of Comp#8 Site 2 Common Carp
Client Sample ID: Comp#8 Site 2 Common Carp
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775008
Lab Project ID: 31102775
Results by SW-846 8290A
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
0.399
0.434
Qual DL LOQICL Units RT Ratio
J 0.120 0.491 p9/9 27.25 0.66
J 0.0639 0.491 pg/g 26.36 0.74
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 50 of 149

f—LResults of Comp#8 Site 2 Common Carp
Client Sample ID: Comp#8 Site 2 Common Carp
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775008
Lab Project ID: 31102775
}-{ Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
,e-lBatch Information
J
Result EMPC
96.0
97.0
105
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Qual DL LAQ/CL Units RT
40.0-135 %
40.0-135 %
40.0-135 %
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/30/2011 01:25
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.Nol.: 10.18 g
Prep Extract Vol: 20 uL
Print Date: 11 /01 /2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sos.com
N.C. Certification # 481
Member of SGS Group
Page 51 of 149

p-LResults of Comp#8 Site 2 Common Carp
Client Sample ID: Comp#8 Site 2 Common Carp
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775008-A
Lab Project ID: 31102775
}-Results by Gravametric
Parameter
% Lipids
r—lBatch Information
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
1.71
go! DL LOQ/CL Units RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.scts.com
N.C. Certification # 481
Member of SGS Group
Page 52 of 149

)))))))))))))))))))))))))))))))))))))))))))
Quantify Sample Summary Report MassLynx 4.1 SCN640
####TCDD TCDF Only ###
Dataset: C:IMassLynx\Default.prolResultslb29oct11a-ltetras.g1d
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11 a-11
Date: 30-Oct-2011
Time: 01:25:02
ID: 31102775008/
Submitter: HRD1459
Task:
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins_db5ms_dw2.EXP
Description: Comp#8 Site 2 Common Carp
-114N 11-1-11
:Name : Response. Ion1Area: Ion2Area. RA .:RAFai1?: RT: pglpL. EDL: Heightl . Noisel: SN1. Height2:.Noise2. SN2 : M1 : M2. User RF
1 :2378 TCDF 2.20,� _ 9.382e2 1.271e3 0.74 NO 26.36, 0.221 0.0325 1.578e4 861 18.3 1.611e4 841 19.2 bb bb 1.004
2 :2378- CDT D 1.524e3 6.059e2 9.182e2 0.66 NO 27.25// 0.203 0.0610 8.558e3 1035 8.3 1.211e4 1292 9.4 MM MM 1.171
3 : ES:13C-2378-TCDD 6.403e5 2.818e5 3.585e5 0.79 NO 27.23' 96.150 0.1242 3.584e6 2478 1446.1 4.559e6 1878 2427.7 bb bb 1.026
4 .ES:13C-2378-TCDF 9.948e5 4.382e5 5.567e5 0.79 NO 26.34/ 97.191 0.0745 5.742e6 1820 3154.7 7.375e6 2198 3354.5 bb bb 1.577
5 .JS:13C-1234-TCDD 6.491e5 2.881e5 3.610e5 0.80 NO 26.54 /100.000 0.1274 3.793e6 2478 1530.6 4.797e6 1878 2554.1 bb bb 1.000
6 • CS:37CI-2378-TCDD 1.657e5 1.657e5 - 27.25 20.964 0.0233 2.041e6 971 2101.6 - bb 1.218
7 • F1 Lock Mass 47722 - -
Crn3F3 ; d. �•O9e3�
6171. Jo £5 a6ed
0.Lty.(6/

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:45 Eastern Daylight Time
Method: C:1MassLynxIDEFAULT.PRO1MethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:1MasstynxIDEFAULT.PRO1CurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-11, Date: 30-Oct-2011, Time: 01:25:02, ID: 31102775008, Submitter: HRD1459, Task:
2378-TC D D
b29oct11a-11 Voltage SIR,EI+
23.77 23.95 319.8965
701 22.36 22.42 22.83 23.13 23.61 �.04 2,4.35 24.58 24.94 2 4 25.52 25.73 26.36 26.44 2T.08 27.24 28.3Q.28.36 28.74 29.27 29.63 6.692e+004
46� Y, i i ; ; i _. r r,--r. , . , . r i �r, , , , . , , ,1 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29octl l a-11
23.74 23.90 23.97 24.36
° 22.16 �''�-� 24.96 25.24 27.08 27.24
/° 22.24 22.52 22.97 23.56_ �~'" i t _ 24.73 25.63 2fi.32. 26.5,7 27.54
40 r.,;..r-�.,,.�r.,� -,
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50
ES-TCDD
b29oct11 a-11
°1°I
22 00
ES:13C-2378-TCDD
26.54 27.23
i
i
27.99
28.00
28.61 29.4029.47
28.50
29.00
29.50
Voltage SIR,EI+
321.8936
7.442e+004
min
30.00
Voltage SIR,EI+
331.9368
3.838e+006
ES-TCDD
b29oct11 a-11
%it
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00
22.50 23.00 23.50 24.00 24.50
25.00 25.50 26.00 26.50 27.00 27.50 28.00
ES:13C-2378-TCDD
26.54 27.23
28.50 29.00
29.50 30.00
Voltage SIR,EI+
333.9339
4.847e+006
26.50 27.00 27.50 28.00
28.50 29.00 29.50 30.00
CS-TCDD
b2$oct11a-11 CS:37C1-2378-TCDD Voltage SIR,EI+
`g 27.24 327.8847
�; `� 2.077e+006
..,,,. , ;,,,,,,,,,,,,,,,,,,,;,, i, ,.i, „ ;,,., �„ ,.,,, ,,. ,,.,.,,,...,. ,,,,,i.,,,,.,,,�„ ,. min
12.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
F1 Lock Mass
b29oct11 a-11
22.04 22.44
341 ,.�....
22 00 22.50
Voltage SIR,EI+
24.81 27.16 28.74 304.9824
-.._._- _ .. _......_. ___ .__ 3 27.77 2.7.84 28.20 28.8929.12 2.9.60 2.694e+006
23.00 23.2523.48.23.56 24.05 24.41 25.01 25.3925.80..25.90 26.27 26.6T 27.
TTT
23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 , ' . , , . , " i min
27.50 28.00 28.50 29.00 29.50 30.00

))))))))))))I))))))))))))))))))))))))))))))
b29oi1114•I I Sn li53.112)
96
25.24
2.1t62458 2471
�.. / 24,94 25.01
t1 ti-1\,--'1/V
65
029 of t111.11 0 mc0mtS0.112)
55
614 10 55 abed
25 21
21.96
I4.46
/
N4 56 2473�
25.34
25 52
25 732595 25.9426.11
25.63 25.63 26 01
26 36
26.32
2378-TCDD
27.24
605.92
020pg$14.
8 27
26.52 26.6926.8527-01 27.08
2370•TCDD
27.24
91823
9.38
28 57 26 61 27 DO 27 08
,ry 1\
lo�j'
29.83
29.30 28.36
27.75 28.05 / 28.74 ?9 01 29 27 29.40
27.99
Voltage 3IR,E1•
319 S955
4.7822.004
29.99
min
Vo'.1agv SIR,EI•
321.6936
5.4284.03s
27.54 29.4029 47
27.11 27 69 �` 2615 29 6128.73 9 0 29 4 •
29.66 29.94
27.48 27 6D 27.00 28.00 26.20 28.40 29.60 28.60 29,00 29.20 29 40 20,60 29.80 30 00 min
24:60 24.80 25.00 25.20 25110 25 60 25 80 26 OD 26:20 26 40 28 60 28.80 27.00 7 27.20

Quantify Sample Report
###TCDD TCDF Only ###
MassLynx 4.1 SCN640
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:45 Eastern Daylight Time
Name: b29oct11a-11, Date: 30-Oct-2011, Time: 01:25:02, ID: 31102775008, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-11
2378-TCDF
26.36
Voltage SIR,EI+
303.9016
4.794e+004
%22.3222.44 22.72 25.47 25.81 26.70 26.88 27.16 28.02
�� 23.33 23.41 23.87 24.2224.2824.69 25.04 28.41 28 48 29.14 29.57
�r�Y_.�--•�_- _... _ . r�, -� .._ ,1- _./\.. 26.19 ,..�. 27.72 29.76
64 , . , , , . , ... - .: ".. . .. ; . . - - _�n�--- �., �.. _,�. _._ ✓ '�, -�---� . �� 1 _ _ _�.- min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
b29oct11a-11 2378-TCDF Voltage SIR,EI+
26.37 305.8987
.\ 4.842e+004
22.32 22.70 23.13 2 25.50 25.57 25 67 2.72 27.06 28.05 29.14 29.71 29.91
; 23.59 3.8423g�24.17 24.71 25.04 �� �� 26.08 \27.48 27.72 28.41�28.51
1 ,. .,,:, ,,..,,,,,,,, ,,,,, ,;,.:,....,....i... i' • i`••.,: :1....,.-.1•••• ,..,. ,-'-..,.(..1.,,.,....-,-•.-.-; .,1min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11 a-11
1 i min
22 00 22.50 1 23.00 i 23.50 24.00 i 24.50 25.00 25.50 26.00 26.50 27.00 r 27.50 28.00 i 28.50 , 29.00 29.50 30.00
ES:13C-2378-TCDF
26.34
Voltage SIR,EI+
315.9419
5.807e+006
ES-TCDF
b29oct11 a-11
%;
.00 22.50
gin
F1sL.ock Mass
b29 ict11a-11
..22.04
%
34 -
23.00 23.50 24.00 24.50 25.00
22.44 22.57
24.81 2716 28.74 29.75
23.00 23.2523.48 23.56 24.05 24.41 25.01 25.39 25.80.25.90 26.27 26.67 27.03 : ' 27.77 27.84 28.20 28.8929.12 29.60
�l
ES:13C-2378-TCDF
26.34
l\
Voltage SIR,EI+
317.9389
7.444e+006
,....�..,,,..,,, , ,,,, ,,, I,..,.,,,,,.. . , min
25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
•
22 00 22.50 23.00 23.50
Voltage SIR,EI+
304.9824
2.694e+006
24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50
• min
30.00
))))))))))))�

Results of Comp#9 Site 3 Bluegill sm
Client Sample ID: Comp#9 Site 3 Bluegill sm
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775009
Lab Project ID: 31102775
8Results by SW-846 8290A
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Result
ND
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
EMPC g1.4 DL LOQ/CL Units RT Ratio
U 0.107 0.495 pglg
0.140 J 0.0435 0.495 pg/g 26.36 0.98*
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 57 of 149

Results of Comp#9 Site 3 Bluegill sm
Client Sample ID: Comp#9 Site 3 Bluegill sm
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775009
Lab Project ID: 31102775
}-Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
,Batch Information
Result
92.0
96.0
98.0
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
EMPC Qual DL LOQ/CL Units RT
40.0-135
40.0-135
40.0-135
OA
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/30/2011 02:01
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.NoI.: 10.11 g
Prep Extract Vol: 20 uL
Print Date: 11 /01 /2011
SGS North America Inc.
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sos.com
Member of SGS Group
Page 58 of 149

Results of Comp#9 Site 3 Bluegill sm
Client Sample ID: Comp#9 Site 3 Bluegill sm
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 1102775009-A
Lab Project ID: 3 102775
>-Results by Gravametric
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result EMPC Qual DL LOQ/CL Units
% Lipids 0.520 °Ao
riBatch Information
1
RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/me: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.NoI.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SCS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sc s.com
N.C. Certification # 481
Member of SGS Group
Page 59 of 149

Quantify Sample Summary Report
###TCDD TCDF Only ###
MassLynx 4.1 SCN640
Dataset: C:IMassLynx\Default.prooResults1b29oct1 l a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11a-12/
Date: 30-Oct-2011
Time: 02:01:42
ID: 31102775009 I
Submitter: HRD1459
Task:
MS Method Name: C:1MassLynx1DEFAULT.PROIACQUDBIdioxins_db5ms_dw2.EXP
Description: Comp#9 Site 3 Bluegill sm
I
1
2
3
4
5
6
7
:Name
:2378-TCDF
:2378-TCDD
: ES:13C-2378-TCDD
. ES:13C-2378-TCDF
• JS:13C-1234-TCDD
• CS:370-2378-TCDD
:F1 Lock Mass
: Response. Ion1Area; Ion2Area. RA • RAFaiI?•
7.391e2 3.666e2 3.725e2 0.98 YES
NO
6.469e5 2.835e5 3.634e5 0.78 NO
1.0�6 4.608e5 5.748e5 0.80 NO
6.821e5 3.080e5 3.741e5 0.82 NO
1.633e5 1.633e5 -
RT:/ pgfpL.
26.36 0.071
27.21 j 92.428
26.34 96.272
26.54/ 100.000
27.24/ 19.659
EDL: Heightl - Noisel. SN1: Height2 ;. Noise2 . SN2 ; M1 : M2. User RF
0.0220 5.135e3
0.0539
0.1154 3.588e6
0.0776 6.049e6
0.1184 4.159e6
0.0238 2.052e6
525
1062
1919 1869.9 4.556e6
2180 2774.9 7.448e6
1919 2167.2 5.056e6
1069 1919.7
51260 -
9.8 5.928e3
674 8.8 bb
1006
2443 1865.0 bb
2331 3195.2 bb
2443 2069.6 bb
- bb
bb 1.004
1.171
bb 1.026
bb 1.577
bb 1.000
1.218
( 0-o0T.237
I. 3(,/(5,j_ /-00q/1/
6t76 to 09 abed

)
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:45 Eastern Daylight Time
Method: C:1MassLynxIDEFAULT.PROIMethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:1Mass ynx1DEFAULT.PRO1CurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-1 , Date: 30-Oct-2011, Time: 02:01:42, ID: 31102775009, Submitter: HRD1459, Task:
2378-TCDD
b29oct11a-12 Voltage SIR,EI+
23.77 23.92 319.8965
_ -,� 24.00 24.41 24.63 25.19 25.39 25.80 26.29.26.36 26.88 27.03 6.401e+004
°4 2 0 22.52 22.88 23.28 23 59, _-
i 27.75 28.1528.38 29.14.29.22 29.51
46 '`-- - - r- , -1 - I . , ; r- -; -�-.•- . . r - r� .�., min
�`i I r . . I . T . �-�,-_- I I I . I . ; . I I
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 •
27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11a-12 Voltage SIR,EI+
23.89 23.95.24.02 321.8936
722.04 22.24 23.00 • 24. .5123624.94 25.27 25.55,E. <2 26.22 6.34 26.64 27.24 27.69 28.10 28.36 28.89 7.976e+004
•.,� min39 rrr „I „I I
i I 1
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-12 ES:13C-2378-TCDD Voltage SIR,EI+
26.54 27.21 331.9368
070 /` ,1 4.207e+006
1 I I ; .,�., �, , ,,,• , I,., , ,, ,min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-12 ES:13C-2378-TCDD Voltage SIR,EI+
26.54 27.21 333.9339
off° A A5.121 a+006
• „
,,, ,,. ,i,r ,I .T, ,,, ,I, ,,, .I, ,I. .I, �� „ I•�I, .,,T.�.,..i,.,,I, .I, ,I,50,,,, .30.i 00min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.
CS-TCDD
b2$oct11a-12 CS:37CI-2378-TCDD Voltage SIR,EI+
il
27.24 327.8847
6, , ,. ,, I •,, ,, �I I' ,, ,. ,. A , ,, ,, �. ,, min
°%,2.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 •
28.00 28.50 29.00 29.50 30.00
co
F1 Lock Mass
b29oct11a-12
Voltage SIR,EI+
22.04 22,39 304.9824
22.69 23,20 25.11 25.40 26.19 26.85 27.47 28.49
%1 23.33 23.64 23.97 24.33 24.60 24.94 25.98 27.03 27.6127.84 28.13 28,69 29.05 29.33 29.76? 666e+006
39 ----- - _ _T _ _ .._. . , min
22.00 22.50 23.00 _ 23.50 I 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 I 28.00 28.50 29.00 29.50 30.00

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:45 Eastern Daylight Time
Name: b29oct11a-12, Date: 30-Oct-2011, Time: 02:01:42, ID: 31102775009, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-12 2378-TCDF
26.36 26.88
24.12 25.47 26.52
22.31 23.77 24.27 25.06 25 81 25.90
22.41.22.65,.22.92 23.41 24.33 24.88 / ,
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50
--A/A.71
26.00 26.50 27.0
Voltage SIR,EI+
303.9016
3.683e+004
28.96
27.16 27.62 27.95 28.4128,64 29.3829.50 29.88
IVJ-min
0 27.50 2/�8.00 28.50 29.00 29.50 30.00
2378-TCDF
b29oct11a-12 2378-TCDF Voltage SIR,EI+
26.36 305.8987
22.39 25.50 26.82 29.53 3.784e+004
23.53 23.77 23.84 24.94 25.04 25.35 25.83 ! 26.7227.15 28.43 28.76 29.14
/a ,J 2.52 22.90 . 24.23 24.30 l�, , ! " f \ . ,l il\
27.41 27.74 28.36 !1N . A J�1 �.,.. _.,A 29.70
,,, , " r� .,. .,. .1 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11a-12 ES:13C-2378-TCDF Voltage SIR,EI+
26.34 315.9419
P 6.119e+006
%- )
1 .T... ,. i : ,....i....,... , , 1 ,.. 1 ..; ..............................................min.,.1 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11 a-12
(22 00 22.50
0)
FiLock Mass
b*octll a-12
_ ,22.04
122.39
% - '*ts. 22.69
39 . 1
22 00 22.50
23.00 23.50 24.00
24.50 25.00 25.50
ES:13C-2378-TCDF
26.34
Voltage SIR,E1+
317.9389
7.536e+006
i....,....I ..... .................... ...,.. ,},...,....i min
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
304.9824
2.666e+006
23.20 25.11 25.40 26.19 26.85 27.47 28.49 29.56
23.33 23.64 23.97 24.33 24.60 24.94 25.98 • 27.03 27.6127.84 28.13 28.69 29.05 29.76
•,., r.,,,1 min
23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

Results of Comp#10 Site 3 Bluegill Ig
Client Sample ID Comp#10 Site 3 Bluegill ig
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 1102775010
Lab Project ID: 31102775
Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Result
ND
EMPC Qual DL LOQ/CL Units RT Ratio
U 0.208 0.465 pg/g
0.149 J 0.0524 0.465 pg/g 26.37 0.54*
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 63 of 149

SG$
ii,Results of Comp#10 Site 3 Bluegill Ig
Client Sample ID: Comp#10 Site 3 Bluegill Ig
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775010
Lab Project ID: 31102775
}-{Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
-1Batch Information 11
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result
98.0
100
104
EMPC Qual DL LOQ/CL Units RT
40.0-135 %
40.0-135 %
40.0-135 %
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/30/2011 02:38
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.NoI.: 10.76 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc.
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
Member of SGS Group
Page 64 of 149

ri,Results of Comp#10 Site 3 Bluegill Ig
Client Sample lD1 Comp#10 Site 3 Bluegill Ig
Client Project ID:l Annual Fish Project 2011
Lab Sample ID: 31102775010-A
Lab Project ID: 31102775
?--LResults by Gravametric
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result EMPC Qual DL LOQ/CL Units
% Lipids 0.490 %a
Batch Information
RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sas.com
N.C. Certification # 481
Member of SGS Group
Page 65 of 149

Quantify Sample Summary Report
###TCDD TCDF Only ###
MassLynx 4.1 SCN640
Dataset: C:lMassLynx\Default.prolResultslb29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11 a-13/
Date: 30-Oct-2011/
Time: 02:38:27
ID: 31102775010
Submitter: HRD1459
Task:
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins db5ms_dw2.EXP
Description: Comp#10 Site 3 Bluegill Ig
1
2
3
4
5
6
7
:Name : Response: Ion1Area: Ion2Area- RA RAFaiI?: RT, pg/pL- EDL: Height1- Noised: SN1. Height2:. Noise2 SN2 : M1 : M2: User RF
2378-TCDF 8.986 3.145e2 5.841e2 0.54 YES 26.37' 0.080 0.0282 4.235e3 760 5.6 6.894e3 854 8.1 bb bb 1.004
:2378-TCDD NO - 0.1118 3007 - - 1802 1.171
: ES:13C-2378-TCDD 7.176e5 3.180e5 3.996e5 0.80 NO 27.2V98.452 0.0891 4.069e6 1715 2372.4 5.150e6 1701 3028.6 bb bb 1.026
: ES:13C-2378-TCDF 1.124e6 4.960e5 6.276e5 0.79 NO 26.32� 00.298 0.0707 6.286e6 2190 2870.2 8.063e6 1975 4081.9 bb bb 1.577
.JS:13C-1234-TCOD 7.104e5 3.143e5 3.962e5 0.79 NO 26.52 //100.000 0.0914 4.133e6 1715 2410.2 5.158e6 1701 3033.0 bb bb 1.000
• CS:37C1-2378-TCDD 1.797e5 1.797e5 - 27.25/ 20.772 0.0210 2.287e6 957 2390.4 - - bb 1.218
:F1 Lack Mass - 49131 - -
ti--c„b6
617L 10 99 e6ed
/O•7-65..
I• oog1 ,
0. I 14 geil5
-rw,/, 1

Quantify Sample Report MassLynx 4.1 SCN-640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:45 Eastern Daylight Time
Method: C:IMassLynx1DEFAULT.PRO1MethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:1MassLynx1DEFAULT.PRO1CurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-13, Date: 30-Oct-2011, Time: 02:38:27, ID: 31102775010, Submitter: HRD1459, Task:
2378-TCDD
b29oct11a-13 Voltage SIR,EI+
22.11 23.67 23.81.23.89 319.8965
a�o1 T c , 22.34 22.7422.97 23.21 . -/ . s' -- 4 �0 24.60 24.73 25.24 25.39 25.88 26.01 26.31 26.69 27.08 '21`27.43 28.15 28.74 28.99 29.38 29.56 5.683e+004
53 .,--,, : ,--- -- -r,, ;-.. - . i .. , 1-:--1; .. ; ..., .. i .. ,-.-.-r,-,�-- ., - 1 . T.ri:_, . , , .. , 7 1 ...., , , u.. , , ...... - .`, min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29octi 1a-13
22.08 22.39 22.92
42- .; :-.
22.00 22.50 23.00
ES-TCDD
b29oct11 a-13
23.8123.92
23.74 24.18
_ - 24.66
23.50
24.00
24.50
25.20 25.60
25.00
25.50
26.32 26.83 _ 27.23
26.00 26.50 27.00
27.50
ES:13C-2378-TCDD
26.52 27.21
27.85 28.02 28.58 28.87 29.09
28.00
28.50
29.00
29.50
Voltage SIR,EI+
321.8936
7.102e+004
min
30.00
Voltage SIR,EI+
331.9368
4.196e+006
, ... , . I min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-13
%01
26.52
ES:13C-2378 TCDD
27.21
Voltage SIR,EI+
333.9339
5.207e+006
,,,. .;... , , ;,.t.�r .,�,,,. 1.. .,,1 .,,T .,.; ,... min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b22oct11a-13 CS:37CI-2378-TCDD Voltage SIR,EI+
27.24 327.8847
2.337e+006
,, ;,., ,. , , ,,..,� , �,.., ,n, , , ,.,, , f,?., , , , , , .. , 1min
%2.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
A
CO
F1Lock Mass
b29oct11a-13 Voltage SIR,EI+
..22.08 22.87 23.18 24.97 25.25 26.92 28.10 28.69 29.40 29.65 304.9824
22.74 23.69 24.0424.27 24.60 25.11 25.42 26.08 , 27.13 27.4627.69 28.28 .28.8229.05 2.540e+006
o _
28 1 , T . , . , , . , , . - .. , - --i - , .-_-------- -, ---•- -- - .-. _.:.. _ - -- � , �, . , , , , ; , .. -- --._,_ ' ._.._l , _..._.. _. • - min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

2378-TCDF
b29oct11a-13 2378-TCDF Voltage SIR,EI+
26.36 305.8987
1
3.932e+004
23.61 26.69 29.02
22.31 23,g1 2q,86 25.04 25.47 25.53 26.24 27 38 27.51 27.99 28.43 28.51 i 29.86
v` ji_ 22.74 22.80 23.23 , 24.2 24.30 25.86 27.00 /� 28.10 j 29.29 29.fi1
ES-TCDF
b29oct11a-13
0 ..
22 00
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only MN
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:45 Eastern Daylight Time
Name: b29oct11a-13, Date: 30-Oct-2011, Time: 02:38:27, ID: 31102775010, Submitter: HRD1459, Task:
2378-TCDF
b29oct11a-13 Voltage SIR.EI+
23.34 303.9016
24.18 2378-TCDF 27.61 4.159e+004
.23237,1 ;:1
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
f , , i ' , , , , i T ,• min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES:13C-2378-TCDF
26.32
Voltage SIR,EI+
315.9419
6.351e+006
r , . � � . . � I i . I .•, r , i r . ,•. , r• , r r . i . . , , , . . i .r , r r . , . r , ,
min
22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDF
b29oct11 a-13
ES:13C-2378-TCDF
26.32
Voltage SIR.EI+
317.9389
8.132e+006
r ..... ..... ... , ...., , , ,,.rr,.,
c�2 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
rn
co
Ff-Lock Mass
b2 ct11a-13
.22.08
%
28
Voltage SIR,EI+
304.9824
2.540e+006
22.74 22.87 23.18 23.69 24.0424.27 24.60 24.97 25.11 25.2525.42 26.08 26.92 27.13 27.4627.69 28.10 28.28 28.69 28.8229.05 29.40 29.65 29.96
Tr T. r f. ,..
22 00 22.50 23.00 23.50 24.00 24.50
,.., , .,,,.., ,., ,..r,,r r.,, f....i min
25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

Results of Comp#11 Site 3 FlatheadCatfish
MR.
Client Sample ID: Comp#11 Site 3 FlatheadCatfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775011
Lab Project ID: 31102775
}-I Results by SW-846 8290A
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Collection Date: 10/06/2011 00'.00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
ND
0.147
Qual DL LOQ/CL Units RT Ratio
U 0.156 0.490 pg/g
J 0.0588 0.490 pg/g 26.35 0.70
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 69 of 149

Results of Comp#11 Site 3 FlatheadCatfish
Client Sample ID: Comp#11 Site 3 FlatheadCatfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775011
Lab Project ID: 31102775
>d Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
Batch Information
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
97.0
100
103
Qual DL LOQ/CL Units RT
40.0-135
40.0-135
40.0-135
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/30/2011 03:15
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.Nol.: 10.21 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 70 of 149

e-LResults of Comp#11 Site 3 FlatheadCatfish
Client Sample ID: Comp#11 Site 3 FlatheadCatfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775011-A
Lab Project ID: 31102775
Results by Gravametric
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
% Lipids
Batch Information
Result EMPC
0.320
ual DL
LOQ/CL
Units
RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.NoI.: 1 mL
Prep Extract Vol: 1 mL
Print Date: 11/01/2011
SGS North America Inc
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 71 of 149

Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:IMassLynxlDefault.prolResults1b29oct1 l a-1 tetras.gld
Last Altered: 01-November-11 8:13:12 AM Eastern Daylight Time
Printed: 01-November-11 8:43:40 AM Eastern Daylight Time
Method: Untitled 31 Oct 2011 09:53:18
Calibration: C:IMassLynnxxDEFAULT.PROtCurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-14
Date: 30-Oct-2011
Time: 03:15:08 /
ID: 31102775011
Submitter: HRD1459
Task:
Description: Comp#11 Site 3 FlatheadCatfish
1
2
3
4
5
6
:Name
2378-TCDF�
2378-TCDD
ES:13C-2378-TCDD
ES:13C-2378-TCDF
. JS:13C-1234-TCDD
• CS:37CI-2378-TCDO
7 . F1 Lock Mass
Response. Ion1Area; Ion2Area. RA • RAFaii?;
8.739e2 3.611e2 5.128e2 0.70 NO
NO
7.271e5 3.199e5 4.072e5 0.79 NO
115.115e5 6.435e5 0.80 NO
7.340e5 3.260e5 4.080e5 0.80 NO
1.843e5 1.843e5 -
RT pg/NL.
26.35 / 0.075
27.23/j 96.555
26.34� 99.786
26.54/ 00.000
27.24 / 20.614
EDL; Heightl. Noisel;
0.0300 6.709e3 1200
0.0798
0.0906 4.076e6
0.0598 6.670e6
0.0930 4.356e6
0.0224 2.407e6
SN1: Height2:. Noise2 : SN2 ; M1 : M2- User RF
5.6 6.656e3 618 10.8 MM MM 1.004
1877 - 1586 - 1.171
2159 1887.6 5.173e6 1487 3478.7 bb bb 1.026
1707 3908.3 8.392e6 1995 4206.3 bb bb 1.577
2159 2017.3 5.420e6 1487 3644.9 bb bb 1.000
1068 2253.6 - - bb 1.218
43913 •-
EFC ij Pi - •
/. SSec
6176 J0 ZL 96ed
aC7UUpC
J
ro.ata
-ion i -1- If

)))))))))))))))))))))))))))))))))i))))) ))) )
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:46 Eastern Daylight Time
Method: C:IMassLynxIDEFAULT.PRO1MethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:lMass ynx1DEFAULT.PRO1CurveDBlmtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-14, Date: 30-Oct-2011, Time: 03:15:08, ID: 31102775011, Submitter: HRD1459, Task:
2378-TCDD
b29oct11 a-14
%
52
22 00
22.36
23.79 24.02
23.90 25.29
23.25 24.17
23.05•57 ;� r r •����24.40 25.45 25.75
2378-TCDD
b29oct11a-14
%l 22.18
43
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50
ES-TCDD
b29oct11a-14
01 ., .. , ., 1 .. IT. ,. 1 „ , .. 1 ,
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50
ES-TCDD
b29oct1 l a-14
22.50
23.00
23.50
24.00
24.50
25.00
25.50
Voltage SIR.EI+
319.8965
26.2126.32 26.49 28.30 28.69 29.27 5.860e+004
26.95 27.26 27.54 28.10 28.51 29.45
min
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
23.64
23.8423.95
22.69 23.25 \ < 224.10 24.53 24.91 25.24\ 25.43 25.88 26.36 26.49 27.24 27.54 28.13 28.56
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
in
ES:13C-2378-TCOD
26.54 27.23
Voltage SIR,E1+
321.8936
7.097e+004
Voltage SIR,E1+
331.9368
4.407e+006
I" , �,,. , , ,• ,,.. min
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
%1 I� / \ 5.468e+006
1Amin
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b2%octl 1a-14
ca
w
-
ES:13C-2378-TCDD Voltage SIR,E1+
26.54 27.23 333.9339
CS:37CI-2378-TCDD
27.24
22.00 22.50 23.00 23.50
m
F1 Lock Mass
b29oct11 a-14
24.00 24.50 25.00 25.50 26.00 26.50
11
�., , .,, i min
27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,E1+
327.8847
2.448e+006
Voltage SIR,E1+
22.04 22.42 304.9824
o �`23.74 25.91 26.17 26.90 27.80 - 28.56 28.84 2.596e+006 /, 22.85 23.30 23,54 24.15 24.46 24.78 25.1225.35 25.76 . 26.70 27.05 27.59. 28.02 28.72 29.23 29.56
37- , ,.,'� ,... r,.,.,, ,,..., -�� `.T,.. ,.'� min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:46 Eastern Daylight Time
Name: b29octlla-14, Date: 30-Oct-2011, Time: 03:15:08, ID: 31102775011, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-14
2378-TCDF
22.26.22.34 ..2.26.36 26.60 26.93
.34 22.95 2315 2438 5.47 2555 23.53 23.92 24.22 25.02.25.10 27.57 28.02 28.36
22 00 22.50
2378-TCDF
b29oct11 a-14
23.00 23.50 24.00 24.50
Voltage SIR,EI+
29.60 303.9016
A 5.228e+004
28.87 29.45� �9.73 29.79
25.00 , ... .. , , , , , . ; ; i - ^--�. , . , `, ... ,.. ,�, . ;, min
25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
22.04 22.51 Atc..2 22.72 23.62 24.8724.99
.80 23.21 23.92 24.41.24.66,
2378-TCOF
26.36
25.45 26.29 ;` .
f 26.5926.70 27.44 27.52 2
j 25.6625.89 27.70
r r tw„ • A`��
22.00 22.50 23.00 23.50 24.00 24.50 25.00
ES-TCDF
b29oct11 a-14
°Jo
0.
25.50
26.00
26.50
ES:13C-2378-TCDF
26.34
27.00 27.50
22.00 22.50 23.00
ES-TCDF
b29oct11a-14
23.50
.,,, .�.. ; ..,,. ,I .,,
(12 00 22.50 23.00 23.50
v
F1 Lock Mass
b2toct1la-14
m 22.04
Ok
24.00 24.50
ir
24.00 24.50 25.00
,i,, i,,,.,, „f,
25.00 25.50 26.00
26.50 27.00 27.50
ES:13C-2378-TCDF
26.34
I
!'
1
25.50 26.00 26.50
Voltage SIR,EI+
29.61 305.8987
A 3.866e+004
7.95 29.53 29.88
f) 28.20 28.44 28.72 29.35.
A,.,.•1min
28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
315.9419
6.740e+006
.1...,, T,,,.I,..,I,,,,,...,I,..,i m1n
28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
317.9389
8.481e+006
.,,.. �.r,,,. ,,, ........... ....... ...... ,.,,.I min
27.00 27.50 28.00 28.50 29.00 29.50 30.00
22.42 54 23
22.85 23.30 2325.91 26.17 26.90 27.80
..7424.46
24.15 24.78 25.1225.35 25.76
_ -26.70. 27.05 27.59 -
37 :/, , ... ,
22.00 22.50
23.00 23.50 24.00 24.50
25.00 25.50 26.00
Voltage SIR,EI+
304.9824
2.596e+006
28.02 28.56 28.7228.84 29.23 29.8829.94
26.50 27.00 27.50 28.00
1 I , r, It, l min
28.50 29.00 29.50 30.00
3))))))) ))) ))))))))T)))))))))))))))))) )

))))))))) ))))))))))))) 1))))))))))))))))) )
b29oct1 t a-14 Smooth(S0,1x2)
83
b29act11a•14 Smooth(S0,1x2)
25.27
96
5.75 25 86 25 93 26.04
25.45
2378•TCDF;26.36;361.14;0.08 pg/p1.45.59
25.3: 25.55 25.60 25.66 25.76 25.81 25.89 25.96 26.09
26.21
b29oct11 a•14 Smooth(SO,1 x2)
b29oct11 a-14 Smooth(S0,1 x2)
96-
25.20 25.30 25.40 25.50 25.60 25.70 25.60 25 90 26.00 26.10 26.20 26.30 26.40 26.50 26.60 26.70 26.80 26.90 27.00
2378-TCDF;26.36;512.81;10.77
26.29
26.52
26.49
ES:13C•2378-TCDF;26.34,511482.13;99.79 pg/1L;3908.31
E S:13 C-2378-TCDF;26.34;643524.69;4206.32
26.60
26.59
26.70
26.70
28.82
Voltage SIR,EI•
303.9016
3.775e+004
26.93 27.00
26.80 28.91
min
Voltage SIR,EI+
305.8987
3 787e•004
min
Voltage SIRE!.
315.9419
6 740e'005
min
Voltage SIR.EI+
317.9389
8 481 a+006
6ti6 !a SL a6ad

id Results of Comp#12 Site 3 Blue Catfish
Client Sample ID: Comp#12 Site 3 Blue Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775012
Lab Project ID: 31102775
Results by SW-846 8290A
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
1
Result EMPC
ND
ND
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
ual DL LOQ!CL Units RT
U 0.256 0.478 pglg
U 0.0825 0.478 pg/g
Ratio
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 76 of 149

f-LResults of Comp#12 Site 3 Blue Catfish
Client Sample ID: Comp#12 Site 3 Blue Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 1102775012
Lab Project ID: 3 102775
>-1Results by SW-846 8290A
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
Batch Information
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
83.0
84.0
86.0
Qual DL
LOQ/CL Units RT
40.0-135
40.0-135
40.0-135
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/3012011 03:51
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.Nol.: 10.47 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 77 of 149

Results of Comp#12 Site 3 Blue Catfish
Client Sample ID: Comp#12 Site 3 Blue Catfish
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775012-A
Lab Project ID: 31102775
>id Results by Gravametric
Parameter Result
% Lipids 1.18
Batch Information
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
EMPC
Qual DL LOQ/CL Units RT
0/0
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
J
Print Date: 11/01/2011
SGS North America Inc
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 78 of 149

))))) :))) )))))) ))))))))) ))) )))) )))))))) )) ) )
Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:1MassLynxlDefault.pro1Resultslb29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11 a-15
Date: 30-Oct-2011
Time:03:51:49
ID: 31102775012/
Submitter: HRD1459
Task:
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins_db5ms_
Description: Comp#12 Site 3 Blue Catfish
dw2.EXP
1
2
3
4
5
6
7
:Name
:2378-TCDF
: 2378-TCDD
ES:13C-2378-TCDD
: ES:13C-2378-TCDF
• JS:13C-1234-TCDD
• CS:370-2378-TCDD
:F1 Lock Mass
Response: lonlArea: Ion2Area: RA •:RAFaiI?•
NO
• NO
3.856e5 1.700e5 2.156e5 0.79 NO
6.035e5 2.655e5 3.380e5 0.79 NO
4.551e5 2.003e5 2.548e5 0.79 NO
9.574e4 9.574e4 - -
RT pglpL-
27.21'/ 82.568
26.32+ 84.085
26.52 /100.000
27.24J 17.272
EDL:
0.0432
0.1342
0.1086
0.1003
0.1114
0.0395
Heightl: Noisel:
668 -
1308 -
2.168e6 1389 1561.0 2.769e6
3.305e6 1571 2103.2 4.235e6
2.597e6 1389 1869.2 3.309e6
1.166e6 1136 1026.3
48794
SN1: Heightl :. Noise2 :
636
1784
1241
2162
1241
SN2 • M1 •, M2- User RF
1.004
1.171
2231.3 bb bb 1.026
1959.0 bb bb 1.577
2667.0 bb bb 1.000
- bb 1.218
6b1. Jo 6L abed

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:46 Eastern Daylight Time
Method: C:IMassLynxIDEFAULT.PRO1MethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:lMassLynxIDEFAULT.PRO1CurveDBlmtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-15, Date: 30-Oct-2011, Time: 03:51:49, ID: 31102775012, Submitter: HRD1459, Task:
2378-TCDD
b29oct11a-15 Voltage SIR,EI+
23.81 23.9424.00 319.8965
Vol 22.29 ' �� 24.17 24.92 25.24 25.3225.4325.78 25.85 26.3626.47 27.00 27.24 5.653e+004
22.16 22.82 23.08 23.61 . - 27.72 28.22 28.7628.99 29.43
�_
54 . .,,�;,-,��f�-,�..i---„,, _ _ min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11a-15
23.89 Voltage SIR,EI+
23.64 24.00 321.8936
° w - 24.13 25.3825.62 26.21 28.94 7.602e+004
40 22.3222.55 23.11 ,... .24.32,24.56 25.25 26.09 26.67 26.95 27.26 27.69 27.94 28.23:.28.3328.74 29.30
22 00 22 �50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00 in
ES-TCDD
b29oct11a-15
%
ES:13C-2378-TCDD
26.52 27.21
\
n
Voltage SIR,EI+
331.9368
2.643e+006
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00 in
ES-TCDD
b29oct11 a-15
0421 i
4
ES:13C-2378-TCDD
26.52 27.21
`
Voltage SIR,EI+
333.9339
3.353e+006
.,..,h,.,,.j.. .,..,,1„ 1 ,.,,,I..,.,,,,.T,..., ,,,,,,,.,,,I ,.,,,,, .,.. 1„ , ,..,.l 1 1 ,,,,.,,',.,.,, l,,.,1. ,.,..,. ,.,.� min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b29oct11a-15
CS:37CI-2378-TCDD
27.24
Voltage SIR,EI+
327.8847
1.201e+006
, ,,.,.,.• ,,,,,,,,,,,,,,,,,,,,, , ,,,,,,....,.,,,,..,, ,, ,,.r. r,..,,, ;...., ,.,.,,...., .,, min
(22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
F'f Lock Mass
b29oct11 a-15
Voltage SIR,EI+
22.08 22.37
22.60 23.43 23.69 25.47 27.05 27.51 28.10 29.24 304.9824
/°1 __, .22.80 23.25 24.12 24.50 24.78 25.25. 25.66 25.98 26.26 26.7026.93. 27.64 27.74 .28.31 28.81 29.38 2.742e+006
;r r,r T:;-,; -',: '�., ,min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00� 29.50 30.00
�� )))))�)�))�))�))�)� ))))

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:46 Eastern Daylight Time
Name: b29oct11a-15, Date: 30-Oct-2011, Time: 03:51:49, ID: 31102775012, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-15
22.21 .22.31
..22.57 23.23 23.62 23.76 24.46 25.17
,'! 24,00 24.6324.69 25.53 25.81,25.88
►7 .
22 00 " 22.50
Voltage SIR,EI+
26.36 7 29.75 303.9016
�.881e+004
26.57 26.65 27.18 27.62 28.00 2- -28.51 29.09 29.3729.60`!
�+\ _ /���^•^V-. .___A____ �•1_ i� %�r".ti .._ �" ,., .�f•/'\ �/1�_ i'�-�/
,....,.. �.•.., , ,,., ,.., ,.. , v\-.. , i ., ,,..v,•., Amin
23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
b29oct11a-15
22.32
/0 22.13 ti 22.74 23.72 24.23 24.38 24.79
�4 22.80 23.26 23.85
82 , ..,.r.i. ,..r.� ...,. .....
22 00 22.50 23.00 23.50 24.00 24.50 25.00
ES-TCDF
b29oct11 a-15
1•
r.
22 00 22.50 23.00
25.12
I 1
25.01
1
25.63 26.31 26.93 27.11 27.41 28.03 28.45
25.725 96 26.52 27.97
25.50 26.00 26.50 27.00 27.50 28.00r 28.50
ES:13C-2378-TCDF
26.32
Voltage SIR,EI+
305.8987
3.692e+004
28.82 29.00 29.60
29.40
min
29.00 29.50 T 30.00
Voltage SIR,EI+
315.9419
4.151e+006
ES-TCDF
b29oct11 a-15
23.50 24.00
24.50 25.00 25.50
25.01
i
26.00 26.50
ES:13C-2378-TCDF
26.32
27.00 27.50 28.00 28.50
,i
, ,, min
29.00 29.50 30.00
Voltage SIR,E1+
317.9389
5.098e+006
00 22.50
m
00
F1 �.ock Mass
b29Rct11 a-15
co �22.08
22.37
`4 22.60
22.80 23.25
43 ..
23.00 23.50 24.00
23.43 23.69
24.12
24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50
24.50 24.78 25.25. 25.47 25.66 25.98 26.26
26.7026.9327'0527.51 27.64 27.74 28.10 28.31
T 1min
29.00 29.50 30.00
Voltage SIR,EI+
304.9824
2.742e+006
28.81 29.24 29.38 29.81
22 00
22.50 23.00 23.50 24.00
24.50 25.00 25.50 26.00 26.50 27.00
27.50 28.00 28.50
i........., min
29.00 29.50 30.00

Results of Comp#13 Site 1 Blue Catfish Ig
Client Sample ID: Comp#13 Site 1 Blue Catfish Ig
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775013
Lab Project ID: 31102775
}-IResults by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter Result EMPC Qual DL. L OQ/CL. Units RT Ratio
2,3,7,8-TCDD ND U 0.205 0.491 pg/g
2,3,7,8-TCDF 0.234 J 0.119 0.491 pg/g 26.34 0.68
J
Print Date: 11/01/2011 N.C. Certification # 481
SGS North America Inc
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sQs.com
Member of SGS Group
Page 82 of 149

Results of Comp#13 Site 1 Blue Catfish Ig
Client Sample ID: Comp#13 Site 1 Blue Catfish Ig
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775013
Lab Project ID: 3 102775
Results by SW-846 8290A
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Parameter
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
HBatch Information
Result EMPC
95.0
99.0
101
Qua! DL LOQ/CL Units RT
40.0-135 %
40.0-135 %
40.0-135 %
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/30/2011 04:28
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.Nol.: 10.18 g
Prep Extract Vol: 20 uL
Print Date: 11 /01 /2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 83 of 149

e-LResults of Comp#13 Site 1 Blue Catfish Ig
Client Sample ID: Comp#13 Site 1 Blue Catfish Ig
Client Project ID: Annual Fish Project 2011
Lab Sample ID: 31102775013-A
Lab Project ID: 31102775
> {Results by Gravametric
Parameter
% Lipids
te—lBatch Information
Collection Date: 10/06/2011 00:00
Received Date: 10/06/2011 13:15
Matrix: Tissue
Solids (%):
Result EMPC
1.38
Qual DL
LOQ/CL
Units
aka
RT
Ratio
Analytical Batch: HXX1347
Analytical Method: Gravametric
Instrument: BAL10
Analyst: RSS
Analytical Date/Time: 10/24/2011 17:00
Dilution: 1
Prep Batch: HXX1347
Prep Method: Gravametric
Prep Date/Time: 10/24/2011 17:00
Prep Initial Wt.Nol.: 1 mL
Prep Extract Vol: 1 mL
♦
Print Date: 11/01/2011
SGS North America Inc.
N.C. Certification # 481
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sos.com
Member of SGS Group
Page 84 of 149

)))))))))))))))))))))))))))))))))))))))))))
Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:1MassLynx\Default.prolResultslb29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11a-16
Date: 30-Oct-201 y
Time: 04:28:36
ID: 31102775013
Submitter: HRD1459
Task:
MS Method Name: C:IMassLynxIDEFAULT.PROIACQUDBIdioxins_db5ms_dw2.EXP
Description: Comp#13 Site 1 Blue Catfish Ig
1
2
3
4
5
6
7
:Name
237� -TCDF
: 2378-TCDD
ES:13C-2378-TCDD
ES:13C-2378-TCDF
• JS:13C-1234-TCDD
• CS:37CI-2378-TCDD
:F1 Lock Mass
Response. Ion1Area: ton2Area. RA • RAFaiI?:
7.5 65e2 3.065e2 4.500e2 0.68 NO
NO
3.925e5 1.740e5 2.185e5 0.80 NO
6.321e5 2.804e5 3.517e5 0.80 NO
4.049e5 1.779e5 2.270e5 0.78 NO
9.946e4 9.946e4 - -
RT:/ pg/pL: EDL: Heightl : Noisel; SN1- Height2 :. Noise2 . SN2 : M1 . M2. User RF
26.34 0.119 0.0605 5.664e3 1260 4.5 6.584e3 677 9.7 bb bb 1.004
0.1044 823 - - 1587 1.171
27.21/ 94.501 0.1449 2.185e6 1473 1482.8 2.773e6 1642 1689.1 bb bb 1.026
26.32/ 99.012 0.1086 3.534e6 1842 1918.7 4.443e6 1747 2543.8 bb bb 1.577
26.52/100.000 0.1486 2.302e6 1473 1562.3 2.913e6 1642 1774.1 bb bb 1.000
27.23/ 20.170 0.0337 1.225e6 861 1423.2 - bb 1.218
- 46910 - -
ITCbq -r- 1..565e 2.
�.3aItes
61'610 59 96ed
o qc5A. 060,0

Quantify Sample Report MassLynx 4.1 SCN640
DD TCDF Only ###
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00
ES-TCDD
b29oct11 a-16
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:46 Eastern Daylight Time
Method: C:lMassLynxIDEFAULT,PRO1MethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:1MassynxlDEFAULT.PRO1CurveDBlmtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29octlla-16, Date: 30-Oct-2011, Time: 04:28:36, ID: 31102775013, Submitter: HRD1459, Task:
2378-TCDD
b29oct11 a-16
Voltage SIR,EI+
22.60 23.15 ,' 319.8965
701 22.21 22.31 . 23.46 r- 24.35 24.63 24.84 26.54 27.06 4.815e 004
- l _,_-_• _ 25�19 25�48 25.91 26.32 27.21 4�27.33 28.05,28.15 28.50 28.86 29.25 29.80 +
22 00 .. 22�50 , •, `�- n • -(� • , .: ; . , , r, .-- i-----_-..-. , i i . , i r, �-r r� j-7�.7-: r ce'. ; i , ?-r ,-r---ri"'"r �-i min
23.00 23.50 24.00 i 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11 a-16
23.71 23.81 23.95
23 82 23 92 Voltage SIR,EI+
321.8936
90- -22.19 y2,49 22.74 2.88 r 23.56 . ,_..� 24.17 24.69 25:17 25.45,25.55 25.94 26.32 26.72226.80 27.23 27.77 28.02 28.31 28.79 29.24 29.56 6.094e+004
i ,--,Li i T" - - -- --
*�-� min
30.00
28.50
29.00
29.50
ES:13C-2378-TCDD Voltage SIR,EI+
26.52 27.21
n 331.9368
1 ;
22 00 22.50 " 23.00T23.50 24.00 24.50 „ 25j00 25�50 l min
26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-16 ES:13C-2378-TCDD Voltage SIR,EI+
10 , . „ 26 52 27.21 333.9339
2.952e+006
22.00 22.50 i 23.00 23.50 24.00 i 24�50 i 25.00 i i j J 25.50 f 26.00 26i50 27.00 i j 27.50 T 28.00 28.50 i , i 29.00 i r J 29.50 30.00 in
CS-TCDD
b29oct11 a-16
0
CS:37CI-2378-TCDD
27.23
I i „ 1 „ i i,, . i ,, i
.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00
Voltage SIR,EI+
327.8847
1.263e+006
27.50�n
j 28.00 28.50 , i 29.00 29.50 30.00
F1 tock Mass
b29oct11a-16
22.04 22.37
•Voltage SIR,EI+
304.9824
22.64 22.88 23.99 24.79 26.01 26.67 26.97 27.67 28.51 2.690e+006
44 j - - 23.39 23.77 24.4524.79 25.63 25.88 26.82 2T.31 27.87 28.40 29.01 29.78
22.00 22 .50 * J 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00 in

)))))))))))))))i))))))))))))))) )))))) ))))) )
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only NM
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:46 Eastern Daylight Time
Name: b29oct11a-16, Date: 30-Oct-2011, Time: 04:28:36, ID: 31102775013, Submitter: HRD1459, Task:
2378-TCDF
b29oct11 a-16
22.32 Voltage SIKH+
303.9016
0/ 24.68 2378-TCDF 4.738e+004
22.26 22.72 24.2024.524.68
.20 26.34
22.8323.07 23.56 23.87 24.09, 26.70 27.18
-.r�� 24 5 25.01 .47 2611,27297272840 L_-_.-5'\.r, . _ 2874 29.04293329562980
i".,.I.,,.I....I...,I.. .1 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
b29oct11 a-16
I
22 29 Voltage SIR,EI+
`� 2378-TCOF 305.8987
4.483s+004
%o
0
l 22.70 22.83 23.23 23.49 23.58 23.89 24.45 24.71 226.37
-IV/ 5.07 L_o&
3 2547 28'83 25,91 _,'S �- y I .. I `. "'�'1� /I I � -i _'� 1 I 1/`'�r�/ i `• ,. �'I 22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00min
29.50 30.00
ES-TCDF
b29oct11a-16
22 00 22.50
ES-TCDF
b29oct11a-16
%-
y
I I . I .. I" I I i I I 'I I .. 'I I r l 1 min
00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
w
F1Lock Mass
b2tct11a-16
'O �22.04
‘-'\` 22.37
44 .. I?,.,
22 00 22.50
ES:13C-2378-TCDF
26.32
Voltage SIR,EI+
315.9419
3.585e+006
23.00 23.50 I 24.00 i 24.50 25.00 I 25.50 26.00 26.50 i 27.00 27.50 28.00 28.50 29.00 I 29.50 r 30.00 in
ES:13C-2378-TCDF
26.32
Voltage SIR,EI+
317.9389
4.503e+006
Voltage SIR,EI+
304.9824
2.690e+006
22.64 22.88 26.01 26.67 26.97 27.67 28.51
23.39 23.77 23.99 24.4524.79 24.9225.16 25.63 25.88 26.82 27.31 , • 27.87 28.40 29.01 29.78 29.86
; ;. T . �- _-- 29.7 . -. _ ..� min
23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 ~~~ 28.50 29.00 ` 29.50 30.00

SG$
ri!,:tatch Summary
Analytical Method: SW-846 8290A
Prep Method: SW-846 3540C/HRMS
Prep Batch: HXX1337
Prep Date: 10/28/2011 17:00
Client Sample ID
OPR for HBN 14044 [HXX11337]
LMB for HBN 14044 [HXX/1337]
Comp#1 Site 1 Bluegill
Comp#2 Site 1 Flathead Catfish
Comp#3 Site 1 Blue Catfish sm
Comp#4 Site 1 Blue Catfish Ig
Comp#5 Site 2 Bluegill
Comp#6 Site 2 Flathead Catfish
Comp#7 Site 2 Blue Catfish
Comp#8 Site 2 Common Carp
Comp#9 Site 3 Bluegill sm
Comp#10 Site 3 Bluegill Ig
Comp#11 Site 3 FlatheadCatfish
Comp#12 Site 3 Blue Catfish
Comp#13 Site 1 Blue Catfish Ig
Lab Sample ID Analysis Date
46213 10/29/2011 19:36
46212 10/29/2011 20:32
31102775001 10/29/2011 21:07
31102775002 10/29/2011 21:44
31102775003 10/29/2011 22:21
31102775004 10/29/2011 22:58
31102775005 10/29/2011 23:34
31102775006 10/30/2011 00:11
31102775007 10/30/2011 00:48
31102775008 10/30/2011 01:25
31102775009 10/30/2011 02:01
31102775010 10/30/2011 02:38
31102775011 10/30/2011 03:15
31102775012 10/30/2011 03:51
31102775013 10/30/2011 04:28
Analytical Batch Instrument Analyst
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HR01459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
HRD1459 HRMS2 JHL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 88 of 149

ri,
Method Blank Summary
Blank ID: LMB for HBN 14044 [HXX11337] Matra: Tissue
Blank Lab ID: 46212
QC for Samples:
31102775001, 31102775002, 31102775003, 31102775004, 31102775005, 31102775006, 31102775007, 31102775008,
31102775009, 31102775010, 31102775011, 31102775012, 31102775013
> Results by SW-846 8290A
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Labeled Standards
13C-2378-TCDD
Result
ND
ND
99.0
13C-2378-TCDF 98.0
37CI-2378-TCDD 102
Batch Information
EMPC
ual DL LOQ/CL Units RT
U 0.0902 0.500 pglg
U 0.0438 0.500 pg/g
40.0-135 %
40.0-135 %
40.0-135 %
Ratio
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Analytical Date/Time: 10/29/2011 20:32
Dilution: 1
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Prep Initial Wt.Nol.: 10 g
Prep Extract Vol: 20 uL
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 89 of 149

Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:IMassLynx\Default.prolResultslb29oct11a-1tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11 a-3
Date: 29-Oct-2011/
Time: 20:32:14
�/
iD:46212
Submitter: HRD1459
Task:
MS Method Name: C:1MassLynxIDEFAULT.PROIACQUDBIdioxins__db5ms_dw2.EXP
Description: LMB for HBN 14044 [HXX11337]
-ri 1 1-1-11
1
3
4
5
6
7
:Name : Response. IonlArea: Ion2Area. RA . RAFaiI?: RT: pg/pL. EDL: Heights . Noisel: SN1: Height2 :• Noise2 - SN2 : M1 - M2. User RF
:2378-TCDF - NO - 0.0219 504 - 603 1.004
:2378-TCDD - - NO / - 0.0451 961 - - 735 1.171
: ES:13C-2378-TCDD 6.570e5 2.893e5 3.677e5 0.79 NO 27.23� 98.639 0.1001 3.533e6 1597 2211.9 4.566e6 1839 2482.7 bb bb 1.026
.ES:13C-2378-TCDF 1.006e6 4.444e5 5.620e5 0.79 NO 26.36/98.301 0.0664 5.554e6 1706 3255.8 7.074e6 1800 3929.9 bb bb 1.577
.JS:13C-1234-TCDD 6.492e5 2.813e5 3.679e5 0.76 NO 26.54/ 100.000 0.1027 3.625e6 1597 2269.5 4.765e6 1839 2591.0 bb bb 1.000
• CS:37C1-2378-TCOD 1.618e5 1.618e5 - 27.26/ 20.464 0.0192 2.042e6 782 2611.0 - bb 1.218
• F1 Lock Mass - - - 50713 ' -
617110 06 a6ed

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Method: C:1MassLynxIDEFAULT.PROIMethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:IMasfynxIDEFAULT.PROICurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29octlla-3, Date: 29-Oct-2011, Time: 20:32:14, ID: 46212, Submitter: HRD1459, Task:
2378-TCDD
b29octl la-3 Voltage SIR,EI+
23.69
�...,�..2S,36 319.8965
22 08 23.24..7,1 2u 29124 29.434.065e+00422.47 22.54 23.28..', r23.7424.25 25.39 25.90;25.99 26.59 26.83 2739 27.66 28.22 28.69=1, i, IT ,. I, I i
�,
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11a-3 Voltage SIR,EI+
25.19 27.61 321.8936
j 22.14 22.32 22.97 23.4323.54 24.02 24.43 '.2_24_.8_9 �' �25.34 25.7825.90 26.32 26.6 26.75 27.26 t ` 27.67 28.28�28.38 _ 28.8929.12 29.45 4.390e+004
. , I ' I . �' i i , , i'S., i •I- 4 i , i , I i•, i , , . I i . 1 , i� ,' T. i 77 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-3 ES:13C-2378-TCDD Voltage S1R,EI+
26.54 27.23 331.9368
n 3.673e+006
01� ,, I 1 1 i . i i I I ., I I i ri ,, I ` I i ,•, i I ,min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-3
22.00 22.50 23.00
ES:13C-2378-TCDD
26.54 27.23
/'�
Voltage SIR,EI+
333.9339
4.812e+006
23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b299octlla-3 CS:37CI-2378-TCDD Voltage SIR,EI+
CD 27.26 327.8847
IT . , T i I
1 I I I...I
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
A
F1` Lock Mass
b29oct11 a-3
o K22.04 22.70 22.83 23.08
/0 23.53 23.99 24.38 24.83
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
Voltage SIR,EI+
26.78 27.13 27.61 27.94 28.26 28.76 29.04 304.9824
25.88
25.34 25.67 - . 26.24 26.95 27.77 29.24 29.55 3.109e+006
-- - - t- i , , . ; .. ..._.._�; 1 ....�_.l min

Quantify Sample Report
###TCDD TCDF Only ###
Dataset: Untitled
MassLynx 4.1 SCN640
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:43 Eastern Daylight Time
Name: b29oct11a-3, Date: 29-Oct-2011, Time: 20:32:14, ID: 46212, Submitter: HRD1459, Task:
2378-TCDF
b29oct11a-3
22.16 22.31 22.9023.20 23.26 23.39
22.00 22.50 23.00
2378-TCDF
b29oct11a-3
OA
23.94 / 24.40 24.84 24^t91 25.22
\! \ J _ t / �r ! 1^ n f 1
23.50 24.00 24.50 25.00
25.47 26.39
I 27.13 . 25.8125.90 27r24 27.56 2807 28.46
pf\e_26.45
25.50 26.00 26.50 27.00 27.50 28.00 28.50
Voltage SIR,EI+
303.9016
3.481e+004
29.01 29.55 29 65
29.00 29.50 30.00
Voltage SIR,EI+
22.08 305.8987
24.56 26.37 3.96`! a+004
23 28 23.53 24.91 25.47 26;82 27.52 27.72 28.31 28.40 29.0T 29.48
I' 22 52 22.93 23.76_ 23.84 24.40 • 25.04 25.91 / `
' ^ -_/ t.Il 'p^ /,,. 26.21/ i l 27.11 n 0 28.46 - 29.63 11
78 , i i.., ,.,. , ,- „ i, , , .., i,,. i ;,.. , ,i min
23.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
22 00 22.50 23.00
ES-TCDF
b29oct11 a-3
22.00 22.50 23.00
ES-TCDF
b29oct11 a-3
24.00 24.50 25.00
23.50 24.00
i
24.50 25.00
25.50 26.00 26.50
ES:13C-2378-TCDF
26.36
�1
T
25.50 26.00 26.50
ES:13C-2378-TCDF
26.34
i
�`
i i .. ,
27.00 27.50 28.00
Voltage SIR,EI+
315.9419
5.635e+006
, , •i , i min
28.50 29.00 29.50 30.00
Voltage SIR,E1+
317.9389
7.143e+006
(12.00 22.50 23.00 23.50
c°
N
FtJock Mass
b2,ct11a-3
4° 22.04
29
24.00 24.50 25.00
22.70 22.83 23.08
23.53 23.99 24.38 24.83
25.50 26.00 26.50
25.34 25.67 25.88 26.24
27.00 T 27.50 i 28.00
, min
28.50 29.00 29.50 30.00
Voltage SIR,EI+
304.9824
3.109e+006
26.78 26.95 27.13 27.61 27.77 27.94 28.26 28.76 29.04 29.24 29.55 29.80
22.00 22.50 23.00 23.50
24:00 24.50 25.00
, ,..,,;,. , min
25.50 26.00 26.50 27.00
27.50 28.00 28.50 29.00 29.50 30.00
I ) ) ))))))))��)

SG$
ii,Blank Spike Summary
Blank Spike ID: CPR for HBN 14044 [HXX/1337]
Blank Spike Lab ID: 46213
Date Analyzed: ' 0/29/2011 19:36
Matrix: Tissue
QC for Samples: 31102775001, 31102775002, 31102775003, 31102775004, 31102775005, 31102775006, 31102775007,
131102775008, 31102775009, 31102775010, 31102775011, 31102775012, 31102775013
}-1Results by SW-846 8290A
Parameter
2,3,7,8-TCDD
2,3,7,8-TCDF
Labeled Standards
13C-2378-TCDD
13C-2378-TCDF
37CI-2378-TCDD
Batch Information
Analytical Batch: HRD1459
Analytical Method: SW-846 8290A
Instrument: HRMS2
Analyst: JHL
Blank Spike (pg/g)
Spike Result Rec (%)
20.0 20.2 101
20.0 21.1 105
88
92
96
CL
40.0-135
40.0-135
40.0-135
Prep Batch: HXX1337
Prep Method: SW-846 3540C/HRMS
Prep Date/Time: 10/28/2011 17:00
Spike Init Wt.NoI.: 10 g Extract Vol: 20 uL
Pnnt Date: 1170 t72011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 93 of 149

Quantify Sample Summary Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:IMassLynx\Default.pro1Results1b29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:03:37 PM Eastern Daylight Time
Name: b29oct11 a-2
Date: 29-Oct-2011/
Time: 19:36:51 ./
ID: 46213✓
Submitter:
Task:
MS Method Name: C:IMassLynx\DEFAULT.PROIACQUDBIdioxins_db5ms.EXP
Description: OPR
`7-1/,l 11 __ l' /l
:Name
:2378-TCDF
2 ; 2378-TCDD
3 : ES:13C-2378-TCDD
4 : ES:13C-2378-TCDF
5 • JS:13C-1234-TCDD
6 - CS:37C1-2378-TCDD
7 :F1 Lock Mass
Response: IonlArea: lon2Area:: RA . RAFaiI?;
6.065e4 2.708e4 3.358e4 0.81 NO
4.267e4 1.791e4 2.476e4 0.72 NO
3.603e5 1.589e5 2.014e5 0.79 NO
5.736e5 2.514e5 3.222e5 0.78 NO
3.970e5 1.772e5 2.198e5 0.81 NO
9.324e4 9.324e4 -
RT: pg/pL.
26.35, 10.531
27.24/ 10.110
27.22, 88.460
26.33/ 91.617
26.53/ 100.000
27.24/ 19.284
EDL; Height1 • Noisel; SN1- Height2;-Noise2 . SN2 : M1 M2- User RF
0.0408 3.421e5 527 648.7 4.404e5 681 646.8 bb bb 1.004
0.0476 2.347e5 507 462.6 3.182e5 492 647.1 MM MM 1.171
0.1137 1.975e6 830 2378.8 2.495e6 1620 1540.3 bb bb 1.026
0.0979 3.230e6 1416 2280.5 4.141e6 1828 2265.5 bb bb 1.577
0.1166 2.345e6 830 2824.0 2.945e6 1620 1817.6 bb bb 1.000
0.0317 1.193e6 812 1469.2 - bb 1.218
53495
61410 t 6 abed

)))))))))))))))))))))))))))))))))))))))))))
Quantify Sample Report
###TCDD TCDF Only #1##
Dataset: Untitled
MassLynx 4.1 SCN640
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:42 Eastern Daylight Time
Method: C:1MassLynxIDEFAULT.PRO1MethDBldb5ms-tetrascurve.mdb 31 Oct 2011 09:53:18
Calibration: C:1MassLynxIDEFAULT.PROICurveDB%mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-2, Date: 29-Oct-2011, Time: 19:36:51, ID: 46213, Submitter: , Task:
2378-TCDD
b29oct11a-2 F1:Voltage SIR,EI+
27.24 319.8965
/O A +11 22r.70 . 24.97„ .: , „ : , . , . 28.26 „ , , , . 2.6fi . 1 min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDD
b29oct11a-2 F1:Voltage SIR,EI+
27.24 321.8936
3.493e+005
9 ,,..:r.....! min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 26.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11 a-2
°/a-1
ES:13C-2378-TCDD
26.53 27.22
\ f
,. , ., r,.,,T,,,.� .. �.,,,,r. ; „ , , , {,,.,` .,, r .. r....r ,. ,. {,:.., ,. ! min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
ES-TCDD
b29oct11a-2
ES:13C-2378-TCDD
26.53 27.22
F1:Voltage SIR,EI+
331.9368
2.389e+006
F1:Voltage SIR,E1+
333.9339
2.991e+006
r „ !., r
I .I .,,{ {,..,1 ,..,,.r,{.,.,r .,,r,.,,r..............r....r .,.r..,.r. ..r , ,r .r .. r,"'r.
....! min
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
CS-TCDD
b299octlla-2 CS:37CI-2378-TCDD F1:Voltage SIR,EI+
i 27.24 327.8847
i r r' r ! min
$,2 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
j
F'ftock Mass
b29oct11a-2 F1:Voltage SIR,EI+
,,22.04 22.95 24.7124.94 28.42 304.9824
1 \ 22.39 22.75 23.44 23.85.23.94 24.33 25.14 25.63 _ __ 26.06 26.47 26.86 27.1927.6027.85.27.95 28.23 3.303e+006
26 . , ', . 1 • _ _-� .- , • „ , min
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

b294t1113-2 SmcctP CSG,1 .7)
96
11
22.70
2497
2378•TCDD
27.24
17908.54
10.13DVA.
462.64
929ott11a4 Sn:cct1 SG,14.2)
I
2378•TCDD
27.24
24761.92
647.09
F1-Vo-tage SIR,EI.
319 6995
2 668e•005
28.26
• man
F1 Voltage SIR,FI•
321 E938
3-4934.005
22.25 22.50 22.75 23 00 23.25 23.50 23.75 24.00 24 25 24.50 24 75 25.00 25 25 25.50 25 75 26.00 26 25 26.50 26.75 27.00 27.25 27.50 27.75 28 00 28.25 I8 50
6ti6 10 96 abed
min

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Untitled
Last Altered: Monday, October 31, 2011 10:04:49 Eastern Daylight Time
Printed: Monday, October 31, 2011 10:05:42 Eastern Daylight Time
Name: b29oct11a-2, Date: 29-Oct-2011, Time: 19:36:51, ID: 46213, Submitter: , Task:
2378-TCDF
b29oct11 a-2
22.00
2378-TCDF
b29oct11 a-2
%-
6
22.50 23.00
I I
23.50
2378-TCDF F1:Voltage S1R,E1+
26.35 303.9016
(' 3.751e+005
J
I i I i ir, , , I .,.,,,.,r.,. , ,.,,,,,.I I [ r T 1. min
24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00
2378-TCDF
26.35
F1:Voltage SIR,EI+
305.8987
4.742e+005
22 00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50
ES-TCDF
b29oct11 a-2
1
25.00
r \
ES:13C-2378-TCDF
26.34
27.00 27.50 28.00
28.50 29.00 29.50
,.., min
30.00
F1:Voltage SIR.EI+
315.9419
3.464e+006
22.00 22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00
ES-TCDF
b29oct11 a-2
•
22 00
CD
V
F>~,Lock Mass
b4goct11 a-2
CO 22.04
25.00
A
ES:13C-2378-TCDF
26.34
11
27.50 28.00
28.50 29.00 29.50
...i min
30.00
F1:Voltage SIR,EI+
317.9389
4.408e+006
22.50 23.00 23.50
24.00 24.50 25.00 25.50
26.00 26.50 27.00 27.50 28.00
min
28.50 29.00 29.50 30.00
F1:Voltage SIR,EI+
304.9824
3.303e+006
22 39 22 75 22.95 23.4423.85.23.94 24.33 24.7124.94 25.14 25.63 26.06 26.47 26.86 27.1927.60.27.85 27.95 28.23 28.42
26
22.00
min
22.50 23.00 23.50 24.00 24.50 25.00 25.50 26.00 26.50 27.00 27.50 28.00 28.50 29.00 29.50 30.00

617l 10 86 abed
Analytical Method' 829 1613 8280
1 668A DLM Other:
QC Date
Prev. WGv.
I PreWG
Workgroup*
Logbook#
19
Page#
1337
' 28-Oct-11
N/A
-
Extraction by Modified Method
s� 3540C
(Soxhlet Extraction) — Dean -Stark? L re•Sox?
Extract Cleanup by
Method 3630/3620 (Silica/Florisil)
Modified
injection
Prep.
Sample Identification
Client
Sample ID
SGS Sample ID*
Sample
Matrix
Sample
Weight*
ES Amt.*
(pL)
MX Amt.
(pL)
CS Amt.*mt
(pL)
PCU
Analyst
PCU
# / Train
JS A *
(pL)
i.
46212
LMB1337
Tissue
10.00 _
40
N/A
40
HHJ
Z 1
20
Comp#1 Site 1 Bluegill
31102775001
Tissue
18,9 0
40 -
N/A
40 ,
HHJ
Z 2
20
Comp#2 Site 1 Flathead Catfish
31102775002
,
Tissue
tok ta
40
N/A
40
HHJ
7. 3
20
Comp#3 Site 1 Blue Catfish sm
31102775003
Tissue
'Di 90
40
N/A
40
HHJ
2. ti--
20
Comp#4 Site 1 Blue Catfish Ig
31102775004
Tissue
l a q a
40
N/A
40
HHJ
2 '5
20
Camp#5 Site 2 Bluegill
31102775005
Tissue
i 0, 5
40
N/A
40
HHJ
2 cc,
20Comp#6
Site 2 Flathead Catfish
31102775006
Tissue
j0A 3
40
N/A
40 "
HHJ
Z .7
20
Comp#7 Site 2 Blue Catfish
31102775007
Tissue
to , 5
40
N/A
40
HHJ
Z
20
Comp#8 Site 2 Common Carp
31102775008
Tissue
pi g
40
N/A
40
HHJ
'L 9
20
Comp#9 Site 3 Bluegill sm
31102775009
Tissue
r0, j
40
N/A
40
HHJ
j. j (1
20
Comp#10 Site 3 Bluegill Ig
31102775010
Tissue
f p,-7 6
40
N/A
40
HHJ
'L (1
20
Comp#11 Site 3 FlatheadCatfish
31102775011
Tissue
_ ID, 1.1
40
N/A
40
HHJ
Z t z
20
Comp#12 Site 3 Blue Catfish
31102775012
Tissue
1014
40
N/A
40
HHJ
2. j
20
Com #13 Site 1 Blue Catfish Ig
p
31102775013
Tissue
(j), l4
40
N/A
40
HHJ
2. 2.
20
46213
OPR
Tissue
10.00
40
40
40
HHJ
'L.
20
Dioxin Standards
Lot #
Conc.
Ina/uL)
Analyst
Witness
Items
Lot #
Extraction Std.
s39•15pa.
D.cS
. /7f5
Toluene
STL1-1
Matrix Spike
539.149
Q;005
$5•
7%,'
Tridecane
-
Cleanup Std.
541-I(2'v
_01
qA fi
P_I.
McCI
STL1-2
Injection Std.
Salt
SPL2-237
PCB Standards
Hexane
DD787
Extraction Std.
Acid Silica
SPL3-7
-
Matrix Spike
Base Silica
SPL3-7
Cleanup Std.
Silica
22-22 -
Injection Std.
��
Fiorisil
SPL3-6
• _
_
Balance Refers ce:
WB1 w1B1
Extraction Da e/Time
Start: c
Finish:
Extraction alyst:
!./6ata in prep table?
Cleanup Dat Imo:
Comments: *or ty \()(& \ -c-r) nalyvela -
-u4PS
f0(Zel(ll
.- To"be entered in the Prep Table. odata in prep to
DC_308.8

Batch Summary
Analytical Method:
Gravimetric
Prep Method: Gravimetric
Prep Batch: HXX1347
Prep Date: 10/24/2011 17:00
Client Sample ID
Comp#1 Site 1 Bluegill
Comp#2 Site 1 Flathead Catfish
Comp#3 Site 1 Blue Catfish sm
Comp#4 Site 1 Blue Catfish lg
Comp#5 Site 2 Bluegill
Comp#6 Site 2 Flathead Catfish
Comp#7 Site 2 Blue Catfish
Comp#8 Site 2 Common Carp
Comp#9 Site 3 Bluegill sm
Comp#10 Site 3 Bluegill Ig
Comp#11 Site 3 FlatheadCatfish
Comp#12 Site 3 Blue Catfish
Comp#13 Site 1 Blue Catfish lg
Lab Sample ID Analysis Date
31102775001 10/24/2011 17:00
31102775002 10/24/2011 17:00
31102775003 10/24/2011 17:00
31102775004 10/24/2011 17:00
31102775005 10/24/2011 17:00
31102775006 10/24/2011 17:00
31102775007 10/24/2011 17:00
31102775008 10/24/2011 17:00
31102775009 10/24/2011 17:00
31102775010 10/24/2011 17:00
31102775011 10/24/2011 17:00
31102775012 10/24/2011 17:00
31102775013 10/24/2011 17:00
Analytical Batch Instrument Analyst
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
HXX1347 BAL10 RSS
Print Date: 11/01/2011
SGS North America Inc.
5500 Business Drive, Wilmington, NC 28405
t 910.350.1903 f 910.350.1557 www.us.sgs.com
N.C. Certification # 481
Member of SGS Group
Page 99 of 149

Lipid
SGS Project: 31102775
Sample ID Client ID Sample Weight Initial Weight Final Weight % Lipid ('h
1
2775-001
10.50
32.7123
32.7392
0.26 /
2
2775-002
10.57
32.6063
32.6242
0.17 ✓
3
2775-003
10.02
32.5531
32.7971
2.44
4
2775-004
11.46
32.5091
32.9321
3.69
5
2775-005
10.42
32.5534
32.6098
0.54
6
2775-006
11.28
32.5343
32.6162
0.73
7
2775-007
10.04
32.5608
32.8755
3.13 ,/
8
2775-008
10.96
32.5338
32.7208
1.71
9
2775-009
10.65
32.5507
32.6057
0.52
10
2775-010
10.81
32.5205
32.5732
0.49
11
2775-011
10.71
32.5955
32.6298
0.32
12
2775-012
10.65
32.5225
32.6487
1.18
13
2775-013
10.87
32.4688
32.6183
1.38
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DiV/0!
#DIV/0!
14'1!
Initials:
etN
P"N
r'L'N
raN
Page 100 of 149

SoN
EARN
r
rmk,
Sample ID
% Lipid
SGS Project: 31102775
Client ID Sample Weight Initial Weight Final Weight % Lipid
1
2775-001
10.50
32 i 23 _
3.17. %
0.00
2
2775-002
10.57
3). 6063
3 a.4.1`ix
0.00
3
2775-003
10.02
13. 5.$31
3. 797I
0.00
4
2775-004
11.46
32 . 5a 91
32. M (
0.00
5
2775-005
10.42
32. SS 3 LJ-
3 d 44 951
0.00
6
2775-006
11.28
3�, 62043
3a. 16
0.00
7
2775-007
10.04
"TaL5gtst
3 , $7S3
0.00
8
2775-008
10.96
3a . 5.3343
32. --go--goi
0.00
9
2775-009
10.65
3a. 5S'O )
32 . Lac?
0.00
10
2775-010
10.81
3.Q. gaits
3e.I .71x
0.00
11
2775-011
10.71
-9Sr
2. 9
0.00
12
2775-012
10.65
5 )5
_
a ,$1
0.00
13
2775-013
10.87
39. L�
oZ • ClIt 3
0.00
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/01
#DIV/0!
#DIV/oi
#DIV/01
#DIV/01 ,
Initials:
e•At► Page 101 of 149

Quantify Compound Summary Report MassLynx 4.1 SCN640
### !CAL Summary ###
Dataset: Y:IDefault.prolCurved blb 16may11 d-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:10:56 Eastern Daylight Time
YYl a-k-vctS n 5 i t I kn-e_LO
Method: Untitled 31 Oct 2011 09:53:18
Calibration: 31 Oct 2011 14:10:32
Compound name: 2378-TCpF
Response Factor: 1.00416 J
RRF SD: 0.0464143, Relative SD: 4.62219
Response type: Internal Std ( Ref 4 ), Area * ( IS Conc. / IS Area )
Curve type: RF
Filename Sample ID Std. Conc. RRF / IS#
1 bl6maylld-2 CS0.5_S37-4... 0.25 1.084/ 4
2 bl6maylld-3 CS1_S37-40... 0.50 1.024 4
3 bl6maylld-4 CS2_S37-401J 2.00 1.012 4
4 bl6maylld-5 CS3 S36-206J 10.00 0.968 4
5 bl6mayl 1d-6 CS4_S37-401L 40.00 0.976 4
6 bl6mayl ld-7 CS5_S37-40... 200.00 0.961/ 4
Compound name: 2378-TpDD
Response Factor: 1.1714 v/
RRF SD: 0.116561, Relative SD: 9.95056
Response type: Internal Std ( Ref 3 ), Area * ( IS Conc. / IS Area )
Curve type: RF
Filename Sample ID Std. Conc. RRF IS#
1 bl6may11 d-2 CS0.5 537-4... 0.25 1.396 3
2 bl6maylld-3 CS1_S37-40... 0.50 1:153/ 3
3 bl6maylld-4 CS2_S37-401J 2.00 1.181 3
4 bl6maylld-5 CS3_S36-206J 10.00 1.130 3
501 bl6mayl 1 d-6 CS4_S37-401L 40.00 1.070 3
6 bl6maylld-7 CS5_S37-40... 200.00 1.099 3
N
O
co
J
eINA I

)))))))))))))))))))))))))))) )).)) )..) )J.) ).).) ) ) )
Quantify Compound Summary Report MassLynx 4.1 SCNG40
### ICAL Summary M#
Dataset: Y:lDefault.prolCurvedblb16may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:10:56 Eastern Daylight Time
Compound name: ES:13C-,2378-TCDD
Response Factor: 1.02637
RRF SD: 0.0375477, Relative SD: 3.65829
Response type: Internal Std ( Ref 5 ), Area * ( IS Conc. / IS Area )
Curve type: RF
Filename Sample ID Std. Conc. RRF IS#
1 bl6may11d-2 CS0.5 S37-4... 100.00 1.028 5
2 bl6may11d-3 CS1_S37-40... 100.00 0.990 5
3 bl6maylld-4 CS2_S37-401J 100.00 1.017✓ 5
4 b16may11d-5 CS3_S36-206J 100.00 0.994 5
5 1316may11d-6 CS4_S37-401L 100.00 1.035 5
6 bl6may11d-7 CS5_S37-40... 100.00 1.094 5
Compound name: ES:13C-2378-TCDF
Response Factor: 1.5771 /
RRF SD: 0.0366419, Relative SD: 2.32338
Response type: Internal Std ( Ref 5 ), Area * ( IS Conc. / IS Area )
Curve type: RF
Filename Sample ID Std. Conc. RRF IS#
1 bl6may11d-2 CS0.5_S37-4... 100.00 1.600 5
2 b16may11d-3 CS1 S37-40... 100.00 1.543 5
3 bl6may11d-4 CS2 S37-401J 100.00 1.598 / 5
4 bl6mayl ld-5 CS3 S36-206J 100.00 1.523 ✓ 5
5 bl6may11 d-6 CS4_S37-401L 100.00 1.582 5
6 bl6may11d-7 CS5_S37-40... 100.00 1.617 5
Compound name: JS:13C-1234-TCDD
Response Factor. 1
RRF SD: 0, Relative SD: 0
R6ponse type: Internal Std ( Ref 5 ), Area * ( IS Conc. / IS Area )
Cave type: RF
Filename Sample ID Std. Conc. RRF IS#
1 . bl6mayl 1d-2 CS0.5 S37-4... 100.00 1.000 5
2 bl6mayl1d-3 CS1 S37-40... 100.00 1.000 5
J

Quantify Compound Summary Report
### ICAL Summary ###
MassLynx 4.1 SCN640
Dataset: Y:IDefault.prolCurvedblb16may11 d-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:10:56 Eastern Daylight Time
Compound name: JS:13C-1234-TCDD
Filename Sample ID Std. Conc. RRF IS#
3 bl6may11 d-4 CS2_S37-401J 100.00 1.000 5
4 b16may11d-5 CS3_S36-206J 100.00 1.000 5
5 bl6may11 d-6 CS4_S37-401L 100.00 1.000 5
6 bl6may11 d-7 CS5_S37-40... 100.00 1.000 5
Compound name: CS:37C12378-TCDD
Response Factor: 1.21831
RRF SD: 0.0703355, Relative SD: 5.77319
Response type: Internal Std ( Ref 5 ), Area * (IS Conc. / IS Area )
Curve type: RF
Filename Sample ID Std. Conc. RRF IS#
1. bl6maylld-2 CSO.5 S37-4... 0.25 1.315 5
2 bl6may11d-3 CS1_S37-40... 0.50 1.263 5
3 bl6mayl1d-4 CS2_S37-401J 2.00 1.179 5
4 bl6mayl 1 d-5 CS3_S36-206J 10.00 1.128 5
5 bl6mayl 1 d-6 CS4_S37-401L 40.00 1.170 5
6 bl6may11d-7 CS5_S37-40... 200.00 1.255 5
6VL Jo VOL abed

)))))))))))))))))))))))))))))))) .) ) ) 10.
Quantify Sample Summary Report MassLynx 4.1 SCN640
### ICAL Summary###
Dataset: Y:1Default.prolCurvedb1b16may11d-tetras.g1d
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:12:40 Eastern Daylight Time
Method: Untitled 31 Oct 2011 09:53:18
Calibration: 31 Oct 2011 14:10:32
Na e: 16may11 d-2
ID C . _S37-401G
D .1 -May-2011
Time: 18:05:48
User: JLJ
Submitter:
Task:
1
Name Response Ion1Area lon2Area RT }A RAFaiI? RRF MRRF %RSD IS# Heightl Noisel SN1 Height2 Noise2 SN2 M
1 2378-TCD 1.0 48e4 4.909e3 5.570e3 30.97 9.88 NO 1.084. 1.004 4.6 4 6.872e4 894 76.9 6.796e4 838 81.1 MM
2 2378-TCDD 8.671e3 3.962e3 4.709e3 31.56/ .84 NO 1.396, 1.171 10.0 3 6.343e4 820 77.4 7.063e4 1176 60.0 MM
3 ES:13C-2378-TCDD 2.485e6 1.091e6 1.394e6 31.54/9.78 NO 1.028, 1.026 3.7 5 1.681e7 1043 16116.9 2.123e7 1413 15024.4 bb
4 ES:13C-2378-TCDF 3.867e6 1.714e6 2.153e6 30.95/ 0 0 NO 1.600. 1.577 2.3 5 2.129e7 1693 12574.7 2.654e7 1946 13637.9 bb
5 JS:13C-1234-TCDD 2.417e6 1.075e6 1.342e6 31.11 p.80 NO 1.000. 1.000 0.0 5 1.446e7 1043 13870.9 1.782e7 1413 12614.8 bb
6 CS:37C1-2378-TCDD 7.946e3 7.946e3 - 31.54/ - 1.315, 1.218 5.8 5 1.194e5 704 169.6 - bb
ao pj,4 .2
3 .W (v7 et, O. c; 57 4 .
6bl. Jo 50L a6ad
/.os
TO , v-314 I

F1:Voltage SIR,EI+
331.9368
0 { , , . , i 1 i . I , - 1 i , . . 4 , { . . , 1 i , 1 ! T 1 1 , I ! { 1 1 1 { ! 1 1 I 1 { { . I { { I i { { , l 1 { ( { I T . { { ' { ' { { I , '1.689e+007
28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 311.00 31.25 31.50 T 31.75 32.00 32.25 32.501n
ES-TCDD
bl6may11d-2 ES:13C-2378-TCDD F1:Voltage SIR,EI+
100- 31.54 333.9339
n 2.133e+007
-01 { i.{,.. 1 1 r T. I i ,. I i i T i,- I i. i I.. i I- I i T. l{, T r . i T T I l, I 1 i I 1 i I min
28.00 28.25 28.150 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
CS-TCDD
b16mayl 1d-2
4131 1 rI ,
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:1Default.prolCurvedb1b16may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Method: Untitled 31 Oct 2011 09:53:18
Calibration: 31 Oct 2011 14:04:30
Name: bl6may11d-2, Date: 16-May-2011, Time: 18:05:48, ID: CS0.5_S37-401G, Submitter: , Task:
2378-TCDD
bl6may11d-2
28.30 28.43 29.90 30.211 (3/0.29 30.57 30.93 31.10
32 . 1 I 1 i 1 I I i . ' { i , i , 1 I r 1 T 1 1 i 1 T .low- 1 , •. 1 { I 1
28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25
2378-TCDD
bl6may11d-2
F1:Voltage SIR,EI+
319.8965
31.80 32.17 32.26 9.528e+004
{�{ F{ i . 1min
31.75 32.00 32.25 32.50
F1:Voltage SIR,EI+
321.8936
28.43 30.21 30.90 31.38 - 1.028e+005
- . I - I r T I . . { . I , . . I I . I { - , r l . l , - „ I - _ min
28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
bl6mayl 1 d-2 ES:13C-2378-TCDD
31.11
3�
31.56
31.50
31.56
31.54
CS:37CI-2378-TCDD
31.54
{ I I I 1 i I r r . . I
28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
F1a.ock Mass
bl6may11d-2
28'20 28.33 29.43 29.63 30 32
28.121 , 28.58 28.79 28.99 29.17 29 55� ' �29.75 30.01 - 30 26 3 ' 30.52 30.65 30.85 31.01
89 '. I
28 00 28.25 28.50 28.75 29.00
31.39 31 48
31.24
F1:Voltage SIR,EI+
327:8847
32.25 1 '514e+005
r{ { . { i min
F1:Voltage SIR,EI+
31.87 31'99 32.20 32.28 304.9824
+006
min
29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
)J))))) )1))) ))

))))))))))))))))))))))) ) ) ) .) ) ).__)
b 1 &may11 d• 2 Smooth(SG,1 x2)
CSO.5_537.401 O
26.08
30.93
27.58 28.30 28.43 29.90
30.21 � '29 30.57 I 31.10
2378-TCDD
31.56
F1 voltage SIR,EI+
319.8965
9.528e+004
31.80 32.17 32 26
bl6mayl 1d•2 Smooth(SG,1x2)
CS0.5_837-4010
30
6176 10 LOI. abed
6.04
26.37 26.52 26.88 27.87 28.43 30.21 30.90 31.38
.min
26.25 26.50 26.75 27.00 27 25 27.50 27.75 28.00 28.25 28.50 28.75 29 00 29.25 29.50 29.75 3000 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDD
31.56
F1-Voltage SIR,EI•
321.8936
1.028e •005

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:1Default.prolCurvedb1b16may11 d-tetras.gtd
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6mayll d-2, Date: 16-May-2011, Time: 18:05:48, ID: CS0.5_S37-401 G, Submitter: , Task:
2378-TCDF
bl6may11 d-2
30 28.45 28.88
28 00 28.25
2378-TCDF
bl6may11 d-2
28.50
28.60
31� ,1--rTT.T, i
28.75
28 00 28.25 28.50 28.75
ES-TCDF
blCmayl ld-2
%.
0
28 00
29.00
29.25
29.50
29.65
29.75
29.29 29.70
29.00 29.25 29.50 29.75
30.00
r
30.00
30.25
30.25
30.60 30.75
30.50
30.50
30.75
30.75
2378-TCDF
30.97
31.00
2378-TCDF
30.97
31.00
ES:13C-2378-TCDF
30.95
31.25
31.25
31.50
31.52
31.50
31.75
31.75
F1:Voltage SIR,Et+
303.9016
1.005e+005
31.89 32.36
32.00
32.00
32.25
min
32.50
F1:Voltage StR,EI+
305.8987
1.002e+005
32.25
min
32.50
F1:Vo!tage SIR,EI+
315.9419
2.142e+007
,,rr
ES-TCDF
bl6may11d-2
7.
28.25
28.50
28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES:13C-2378-TCDF
30.95
F1:Voltage SIR,EI+
317.9389
2.670e+007
- r r r.. r r r.. r,. r t r, r. r r -r . r r r i r, r,... .. , r r r r r r, r r r r r r r r r r,; r. r r min
c8 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
F'.ock Mass
blfirnay11d-2
co_
89
28.20 28.58 29.43 29.55 29.63
28.12 28.33 28.79 28.99 29.17 29.75 30.01
28 00
30.2630.32
30.5230.65 30.85 31.01
31.24
31.39 31.48
F1:Voltage SIR,EI+
31.99 32.20 32.28 304.9824
31.87 :7 +006
. . . r . r , , r , , , , , , , , , , , , , . , , , , , , , . , , r . T r , r r 1 min
28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

) ) ) ) �)) ... .. ..�1._ �l ) ). ._l ...�. )
bt 6may11 d.2 Sm14th0G.1x2)
CS0 5 S37.401O
96
26.79
30
bl 6mayl td-2 Smooth(SG,1x2)
C90.5_837-4010
96
2378•TCDF
30.97
27.59 28.45 28.88 29.65 30.60 30.75
28.60
29 29 _� 9.70 31.52
31 s", 1 1 minr
26.25 26.50 26.75 27.00 27.25 27.50 27.75 28.00 28.25 28.50 26., 75' 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
lab
2378-TCDF
30.97
F1:VOltage SIR,EI*
303.9016
1.005e•005
31.89 32.36
min
F1 Voltage SIR.EI+
305.8987
1.002e•005
6176 Jo 601. 962d
26.08

Quantify Sample Summary Report MassLynx 4.1 SCN640
##f# ICAL Summary###
Dataset: Y:lDefault.prolCurvedb1b16may11 d-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:12:40 Eastern Daylight Time
Na e: b 6may11 d-3
ID: CS1 S37-401H
Da -May-2011
Time: 18:52:44
User: JLJ
Submitter:
Task:
J
1
Name Response Ion1Area Ion2Area RT 5A RAFaiI7 RRF MRRF %RSD IS# Heightl Noise1 SN1 Height2 Noise2 SN2 M
1 2378-TCDF 1.690e4 7.528e3 9.369e3 30.96'' .80 NO 1.024 • 1.004 4.6 4 1.082e5 563 192.3 1.374e5 677 203.0 bb
2 2378-TCDD 1.221e4 5.368e3 6.846e3 31.56'.78 NO 1.153. 1.171 10.0 3 8.948e4 734 121.8 1.210e5 1102 109.7 MM
3 ES:13C 78-TCDD 2.11 6 9.327e5 1.186e6 31.54".79 NO 0.990. 1.026 3.7 5 1.645e7 1036 15873.7 2.124e7 1269 16742.1 bb
4 ES:13C-2378-TCDF 3.301e6 1.454e6 1.847e6 30.95�79 NO 1.543. 1.577 2.3 5 2.030e7 1299 15625.3 2.595e7 1903 13631.7 bb
5 - JS:13C-1234-TCDD 2.139e6 9.418e5 1.197e6 31.11�79 NO 1.000• 1.000 0.0 5 1.446e7 1036 13958.6 1.850e7 1269 14578.2 bb
6 CS:37CI-2378-TCDD 1.351e4 1.351e4 - 31.56 " - - 1.263 • 1.218 5.8 5 2.513e5 715 351.5 - - bb
--rc:042-1= 1. -)-al -ti-I
61410 013 a6ed
j.i53
: 3►-1 J

))))))))))))))))))))))) .) ) ..)) )... j.))) ...) )..) ..)))))) )
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:1Default.prolCurvedb1b16may11d-tetras.g1d
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-3, Date: 16-May-2011, Time: 18:52:44, ID: CS1_S37-401H, Submitter: , Task:
2378-TCDD
bl6may11d-3
%_
26
28 00
28.61 28.86
29.32 29.73
30.95
31.56
F1:Voltage SIR,EI+
319.8965
1.204e+005
28.25
2378-TCDD
bl6may11 d-3
20
28 00 28.25
28.50
28.75
29.00
29.25
29.50
29.75
min
30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
31.56
F1:Voltage SIR,EI+
321.8936
1.536e+005
30.93 31.36 32.18
min
28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
bl6mayl ld-3
31.11
ES:13C-2378-TCDD
31.54
I 1 f r 1 T . r r 1 1 . T 1 1 1 1 1 i . . . T 1 I . T . . . I { ' . T T r T
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00
ES-TCDD
bl6may11 d-3
100
31.11
31.25 31.50
l I 1 1
31.75 32.00
ES:13C-2378-TCDD
31.54
F1:Voltage SIR,EI+
331.9368
1.652e+007
. . , { min
32.25 32.50
F1:Voltage SIR,EI+
333.9339
2.132e+007
•0- . , 1 . . . 1 T 1 1 . T i , T T i . . . 1 . 1 { 1 . 1 . . 1 . . 1 1 . , 1 1 . , , . . . , i i 1 T I 1 i . , i , 1 f >� I 1 . 1 , 1 1 { 1 I min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.1 75 30.00 30.. T 25 30.50 30.75 31.If
31.25 31.50 31.75 32.00 32.25 32.50
CS-TCDD
bl6may11d-3
13
�° 1
I.4 _ `y
1 . 1 . I 1 . , . I 1 T 1 1 1 I 1 1 t I I 1 1 1 1 i 1 1 1 i { 1 I i I { I 1 1 I 1 1 1 1 I ! T i T I i i l i I i . I 1 . T 1 1 S 1 r 1 . 1 1 1 I • T I r i i . T r I i 1 1 1 I min
8.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
0
FiLock Mass
bl6may11d-3 F1:Voltage SIR,EI+
28.02 28.25 28.61 28.66 28.86 28.97 29.24 29.43 29.50 29.70 29.88 30.08 30.22 30.32 30.45 30.75 30.83 31.01 31.06 31.3131.44 31.67 31.80 31.90 32.20 32.38 304.+006
9824
%
CS:37CI-2378-TCDD
31.56
88y
28 00 28.25
F1:Voltage SIR,EI+
327.8847
2.822e+005
28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00
min
31.25 31.50 31.75 32.00 32.25 32.50

bt dmayl l d-3 Smooth(SG.1 x2)
CS1 S37-401H
96
26.09
26 82 28.86 29.32
/
26
7 .•
bl 6may11 d-3 Smodin(S3,1 x2)
CS7 S37-441H
30.95
29.73
2378-TCDD
31.56
2378•TC00
31.56
F1:Vottage SIR,EI•
319.8965
1.204e+005
.. , .... ,min
F1:Voltage SRO.
321.8936
1.536e+005
32.18
20
min
26.25 26.50 26.75 27.00 27.25 27.50 f 27.75 28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
6t 4 Jo Z 61. abed

)))))) .))))))))).))))))A. .:1.))...))...)._.j))
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only###
Dataset: Y:1Default.prolCurvedb1b16may1ld-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: blfimaylld-3, Date: 16-May-2011, Time: 18:52:44, ID: CS1_S37-401H, Submitter: , Task:
2378-TCDF
bl6may11d-3 2378-TCDF F1:Voltage SIR,EI+
30.96 303.9016
1.400e+005
%:
22 . 30.16 . . . . . , , . . . . ,
. � � � 1.. �, I I� I I . t,� 1 I I I I ., 11.. , � . 1 r 1 P I . 1 . 1 , I min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDF
bl6may11d-3
%:
29.66
18 , 1 . 1 . I 1 , ram. 1 . , . 1 1 . . ( r r 1 . . . i . . . 1 , . i , . . 1 , , 1 min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDF F1:Voltage SIR,El+
30.96 305.8987
1.714e+005
ES-TCDF
bl6mayl ld-3
ES:13C-2378-TCDF
30.95
F1:Voltage SIR,EI+
315.9419
2.044e+007
•. . 1 , 1 , I . . ( min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDF
bl6may11d-3
ES:13C-2378-TCDF
30.95
F1:Voltage SIR, El+
317.9389
2.614e+007
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00
Fl -ock Mass
b11tnay11d-3
co
28.02 28.25
28 00
28.25
28.61 28.66 28.86 28.97
Amin
30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
29.24 29.88 30.08 30.22 30.32
29.4329.80 29.70 30.45
30.75 30.83 31 3131.44
31.01 31.06
F1:Voltage SIR,EI+
3190 32.20 32.38 304.9824
31.67 31.80.27 +006
. . . 1 . . 1 . 1 . 1 , 1 1 . I . . 1 T I „ 1 , 1 1 1 . • min
28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00
31.25 31.50 31.75 32.00 32.25 32.50

Quantify Sample Summary Report
### ICAL Summary ###
MassLynx 4.1 SCN640
Dataset Y:\Default.prolCurvedb\b16may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:12:40 Eastern Daylight Time
Na e: 16may11 d-4
ID CS2 S37-401J
D te: -May-2011
Ti .19:42:50
User: JLJ
Submitter:
Task:
Name Response Ion1Area Ion2Area RT 5A RAFaii't RRF MRRF %RSD IS# Heightl Noise1 SN1 Height2 Noise2 SN2 M
1 2378-TCDF 6.080e4 2.701e4 3.379e4 30.97/0.80 NO 1.012• 1.004 4.6 4 3.449e5 613 562.7 4.314e5 822 524.9 bb
2 2378-TCDD 4.515e4 1.995e4 2.520e4 31.56/0.79 NO 1.181 • 1.171 10.0 3 3.280e5 604 542.8 4.121e5 747 551.8 MM
3 ES:13C-2378-TCDD 1.91� 8.410e5 1.070e6 31.54/ .79 NO 1.0� 7. 1.026 3.7 5 1.369e7 1119 12236.6 1.740e7 755 23031.4 bb
4 ES:13C-2378-TCDF 3.003e6 1.317e6 1.686e6 30.95 0.78 NO 1.598• 1.577 2.3 5 1.642e7 1653 9934.3 2.126e7 1967 10807.7 bb
5 ' JS:13C-1234-TCDD 1.880e6 8.313e5 1.048e6 31.114.79 NO 1.000 • 1.000 0.0 5 1.128e7 1119 10078.6 1.440e7 755 19061.2 bb
6 CS:37C1-2378-TCDD 4.432e4 4.432e4 - 31.561 - - 1.179 • 1.218 5.8 5 7.198e5 802 897.3 - bb
I_gisuee ►oop,5r6,4
6P1. 10 PR a62d
1. 01(,S
-7,/0 31- 1)

) ) ) ) ) ) ) ) ) ). ) ) ) ) 1 ) ) ) ) ) ) ) ). )..
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:1Default.prolCurvedblb16may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-4, Date: 16-May-2011, Time: 19:42:50, ID: CS2_S37-401J, Submitter: , Task:
2378-TCDD
bl6may11d-4
31.56
0/01 9
28 00 28.25 28.50 28.75 29.00 29.25 , 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDD
bl6may11 d-4
31.56
F1:Voltage SIR,EI+
319.8965
3.613e+005
1
7 , , , . , , . , , , , . , , ( min
14
28 00 28.25 28.50 28.75 29.00 29., 25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
bl6may11d-4
100
14
31.11
ES:13C-2378-TCDD
31.54
F1:Voltage SIR,EI+
321.8936
4.443e+005
F1:Voltage SIR,EI+
331.9368
1.378e+007
0 , . , . ▪ , + , , , , , , . , , . . , , , . , 14 , , , , , , , min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
bl6may11 d-4
100
-0 . . , . , T , , . . ,
28 00 28.25 28.50 28.75 29.00
CS-TCDD
bl6mayl 1d-4
Zt▪ 8 00 28.25 28.50 28.75 29.00
0
FiLock Mass
bl6may11 d-4
- 28.13 ^ono -288428.97
89
28 00
28.25 28.50
31.11
. , , , , . . ,T " . , . . 1 min
29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
29.25 29.50 29.75
ES:13C-2378-TCDD
31.54
CS:37C1-2378-TCDD
31.56
F1:Voltage SIR,EI+
333.9339
1.748e+007
F1:Voltage SIR,EI+
327.8847
7.537e+005
, , , . . , , . , . i . ? . . , , , , , , min
30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
29.19 29.45 29.57 29.85 29.93 30.14
F1:Voltage SIR,EI+
30.47 30.57 30.6730.80 31.28 1.31 31.49 31.69 31.95 32.00 32.30 304.9824
31.03 +006
,..,..,.imin
28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

b1 amay1 ld-4 Smootf(S0,1x2)
C82_537-401 J
9 ;1r r r -1 i . �", 7 77. S'^,,"'. �--Y,
bl6maylld-4 Smootb(S0,1x2)
CSZ 537-401J
2378•TCDD
31.56
Ft:Voltage SIR,EI•
319.8965
3.613e•005
- min
2378-TCOD
31.56
F1 :Voltage SIR,EI.
321.8936
4.443e.005
•. , •r• � r .T1 � min
26.25 f 26.50 26.75 27.00 27.25 27.50 27.75 28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00T 31.25, 31.50 31.75 32.00 32.25 32.50
6til 10 91.I. e68d
))))))))))))))))) MY) )))))))))))))T))))3

)))))))))))1*))))))))))))))))))))_)))))))))))
Quantify Sample Report MassLynx 4.1 SCN640
#k##TCDD TCDF Only ###
Dataset: Y:\Default.pro1Curvedblbl6may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-4, Date:16-May-2011, Time: 19:42:50, ID: CS2_S37-401J, Submitter: , Task:
2378-TCDF
bl6may11d-4
2378-TCDF F1:Voltage SIR,EI+
30.96 303.9016
/1 3.794e+005
min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDF
bl6mayl ld-4
°
2378-TCDF F1:Voltage SIR,EI+
30.96 305.8987
/1 4.652e+005
/a
7 . I . . . . . . . . i . . . . . . . . . ( . . . . . . . . r j . . . . . 1 . . . . . . . . r i r . . r r . . . min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES TCDF
b l6mayl l d-4
%-
ES:13C-2378-TCDF
30.95
0
2800 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
F1:Voltage SIR,EI+
315.9419
1.651e+007
ES-TCDF
bl6mayl 1d-4
%y
T
-
D- 1 1 1 ( 1 . . . . 1 / j , 1 r . 1 . . , . 1 l . . I~ T . 1 . . . . . . . . 1 . . . . 1 . . . . 1 . . . . I min
(28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES:13C-2378-TCDF
30.95
min
F1:Voltage SIR,EI+
317.9389
2.136e+007
-1
F'FLock Mass
b1 may11d-4
28.13 28.38 28.48 28.66 28.8428.97 29.19
29.45 29.57 29.85 29.93 30.14
F1:Voltage SIR,EI+
31.95 32.00 32.30 304.9824
30.47 30.57 30.67 30.80 31.28 1.31 31.49 31.69 - • +006
31.0331.10
89 - , i j , . , . i , . . , � . , . , . , . . , i min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

Quantify Sample Summary Report MassLynx 4.1 SCN640
### iCAL Summary ###
Dataset: Y:(Default.prolCurvedblbl6may1ld-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:12:40 Eastern Daylight Time
Na ► e:' 16may11d-5
ID: CS3 - 36-206J
Da e: 1 May-2011
Tim •.20:32:51
User: JLJ
Submitter:
Task:
Name Response IonlArea Ion2Area RT RAFaiI? RRF MRRF %RSD IS# Heightl Noisel SN1 Height2 Noise2 SN2 M
1 2378-TCDF 4.735e5 2.057e5 2.678e5 30.977 0.77 NO 0.968- 1.004 4.6 4 2.683e6 663 4045.0 3.576e6 2181 1639.6 bb
2 2378-TCDD 3.609e5 1.592e5 2.017e5 31.56.479 NO 1.130. 1.171 10.0 3 2.637e6 996 2648.8 3.318e6 890 3726.4 MM
3 ES:13C-2378-TCDD 3.195e6 1.407e6 1.788e6 31.54 99 NO 0.994. 1.026 3.7 5 2.389e7 1245 19189.5 3.038e7 1044 29089.3 bb
4 ES:13C-2378-TCDF 4.893e6 _ 2.153e6 2.740e6 30.95700.79 NO 1.523- 1.577 2.3 5 2.862e7 1763 16232.6 3.630e7 1457 24910.8 bb
5 JS:13C-1234-TCDD 3.214e6 1.426e6 1.788e6 31.11480 NO 1.000- a 1.000 0.0 5 2.097e7 1245 16846.0 2.603e7 1044 24927.8 bb
6 CS:37C1-2378-TCDD 3.625e5 3.625e5 - 31.56/ - - 1.128. 1.218 5.8 5 6.029e6 603 10000.3 - - bb
6ti1. 10 91.1. abed
E5 -1i1 b � $4- 793P
5
/00
I. 5D. -
-rrr»bo-31- 1/
)))))))))))))))))))))))

) ) ) ). ).. ) )
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:IDefault.pro\Curvedb\b16may11d-tetras.g1d
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-5, Date: 16-May-2011, Time: 20:32:51, ID: CS3_S36-206J, Submitter: , Task:
2378-TCDD
bl6may11d-5
31.56
F1:Voltage SIR,EI+
319.8965
2.668e+006
, ; , r . , . . . . ; , I, r r ; r ; . . . ; , , r . . . . • . . , , . , . r , ; , , , min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDD
bl6may11d-5
31.56
F1:Voltage SIR,EI+
321.8936
3.350e+006
%-
1- ..,•;,..;rrrF,,..;r.r; .;.• min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
bl6may11d-5
100-
oIo
28.00 28.25
ES-TCDD
bl6may11d-5
31.11
ES:13C-2378-TCDD
31.54
F1:Voltage SIR,EI+
331.9368
2.403e+007
, , . . r , . ; r . r r . . . ; , , ; , , . . r . r . ; . , , . . , , r ; . . . , ; , . . l c , . r ; . 1 r . . r . . . r . r . ; , . . . 1 min
28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
31.11
ES:13C-2378-TCDO
31.54
1001
OA
-O • I • . ; . . r . •, r ; r , , i r i . i , , . ; ; r , r „ r j min
28 00 28.25 28., 50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
CS-TCDD
bl6may11d-5
v
Z88 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75
0
FiJ
Lock Mass
bl6may11d-5
28.15 28.3628.43 28.64 28.83 29.04 29.24 29.34 29.53 29.78 29.98 30.26 30.41 30.57 30.77
�o
85
30.00 30.25 30.50
30.75 31.00 31.25
CS:37CI-2378-TCDD
31.56
F1:Voltage SIR,EI+
333.9339
3.056e+007
F1:Voltage SIR,EI+
327.8847
6.080e+006
. . r . i . . •i r ; . min
31.50 31.75 32.00 32.25 32.50
F1:Voltage SIR,EI+
31.11 31.23 31.39 31.47 31.74 31.85 32.1332.20 30 .824
9824
28 00 28.25 28.50 28.75
29.00
29.25
29.50
29.75
30.00 30.25
30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

bThmay11 d•5 Smaoth(SG,1 x2)
CS3_836.206J
1
blOmay11 d-5 8mooth(S0,1x2)
CS3_S36.206J
2378•TCDD
31.58
2378•TCDD
31.56
F1:Vottago SIR,EI
319.8985
2.668e•006
min
F1:Vottage SIR,EI•
321.8936
3.350e•006
min
26.25 26.50 26.75 27.00 27.25 27.50 27.75 28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
6P1, Jo OZ6 a68d

)))))) )))))))))))))))).).. ..... ........ ))
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:1Default.prolCurvedblbl6may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-5, Date:16-May-2011, Time: 20:32:51, 1D: CS3_S36-206J, Submitter: , Task:
2378-TCDF
bl6may11d-5
%L:
2378-TCDF F1:Voltage SIR,EI+
30.96 303.9016
/1 2.728e+006
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDF
bl6may11d-5
%-]
1 1 . . . . 1 . . r . 1 . . . . 1 . . 1 . T 1 . I . . . 1 . r . . I . . . I I . l i i I . I . r I . I . i I . . . 1 min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 2'9.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDF
bl6may11d-5
0 . . . . I . . . I . . , I .
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75
ES-TCDF
bl6mayl 1 d-5
"0_-
8 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
Fi.Lock Mass
b'lmay11 d-5
30.00
2378-TCDF F1:Voltage SIR,EI+
30.96 305.8987
3.629e+006
ES:13C-2378-TCDF
30.95
F1:Voltage SIR,EI+
315.9419
2.885e+007
i min
30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES:13C-2378-TCDF
30.95
F1:Voltage SIR,EI+
317.9389
3.656e+007
85
28 00
28.15 28.3628.43 28.64 28.83 29.04 29.24 29.34 29.53
29.78 29.98 30.26
0.41 30.57 30.77
,.I.I.,,..II..Imin
31.23 31.39 31.47 31.74 31.85
31.11
F1:Voltage SIR,EI+
32.1332.20 304.9824
2. 89e+006
I . . . . I . . . . I . . . I . . . . I . . I , , . . . I I I . I r . . . I . . . .1 min
28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

Quantify Sample Summary Report MassLynx 4.1 SCN640
### ICAL Summary ###
Dataset: Y:(Default.prolCurvedblb16may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:12:40 Eastern Daylight Time
Na c bl6may11 d-6
ID: S4 = 37-401L
Da - : 1 'May-2011
Time: 21:22:53
User: JLJ
Submitter:
Task:
Name Response Ion1Area Ion2Area RT RA RAFaiI? RRF MRRF %RSD IS# Heightl Noisel SN1 Height2 Noise2 SN2 M
1 2378-TCDF 1.808e6 7.916e5 1.016e6 30.96/9.78 NO 0.976 • 1.004 4.6 4 1.191e7 762 15630.5 1.550e7 1083 14318.8 bb
2 2378-TCDD 1.297e6 5.735e5 7.235e5 31.56.79 NO 1.070, 1.171 10.0 3 1.078e7 1233 8744.4 1.364e7 1452 9391.6 MM
3 ES:13C-2378-TCDD 3.030e6 1.333e6 1.697e6 31.54/.79 NO 1.035. 1.026 3.7 5 2.501e7 916 27285.9 3.206e7 1708 18776.5 bb
4 ES:13C-2378-TCDF 4.632e6 2.045e6 2.586e6 30.95' 0 79 NO 1.582. 1.577 2.3 5 3.021e7 1723 17528.8 3.850e7 1882 20459.9 bb
5 JS:13C-1234-TCDD 2.928e6 1.281e6 1.647e6 31.11 �78 NO 1.000- 1.000 0.0 5 2.082e7 916 22719.8 2.660e7 1708 15578.9 bb
6 CS:37C1-2378-TCDD 1.370e6 1.370e6 - 31.56/ - 1.170, 1.218 5.8 5 2.599e7 723 35926.5 - bb
CS-i- b =_1, 1 60
6b6 Jo ZZI. abed
i 00 i /04
I, 11-9_,
,a-31-)1

))))))))))))))))))))))))))) ._ ) i),))))))
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:1Default.pro\Curvedblbl6may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-6, Date: 16-May-2011, Time: 21:22:53, ID: CS4_S37-401L, Submitter: , Task:
2378-TCDD
bl6may11d-6
31.56
F1:Voltage SIR,El+
319.8965
1.081 a+007
r , i . r . , I . r , , ' . . , , ' . , , , . . , + . , . , . . r . , ( , . , , . , ' . . , , . i , , 1 min
28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDD
bl6may11d-6
31.56
F1:Voltage SIR,EI+
321.8936
1.368e+007
0 = . . . I . . , . , . . , . . . , . , . , r . , , . , . , . . , , . . . . I . . , I . . . . . . . . . . . . . . . . . . . . . . . . , , . , . . , , , . . . min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
bl6may11d-6
100-
, r , , , I i , . . I r . . . I . . . , min
28.00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
bl6mayl 1 d-6
100
-0 , . ,
28 00 28.25
CS-TCDD
bl6may11d-6
1c y
31.11
31.11
ES:13C-2378-TCDD
31.54
ES:13C-2378-TCDD
31.54
F1:Voltage SIR,EI+
331.9368
2.507e+007
F1:Voltage SIR,EI+
333.9339
3.224e+007
:28.50
28.75
. r I , , r j . . . . . . .
29.00 29.25 29.50
29.75 30.00 30.25 30.50 30.75 31.00
31.25
31.50 31.75
CS:37CI-2378-TCDD
31.56
32.00
. . i min
32.25 32.50
Fl:Voltage SIR,EI+
327.8847
2.604e+007
min
/8 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
FiLock Mass
bl6may11 d-6
88
28 00
28.69
28.81 28.9629.25
28.20 28.45 8.5829.20
28.25
F1:Voltage SIR.EI+
29.75 29.93 30.75 31.05 31.34 31.42 31.6731.77 31.85 32.03 32.38 304 9824
024
29.48 29 63 0.04 30.29 30.49 30 82 31.24
min
28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

b16may11(1.6 Smoolh(S0,1 x2)
CS4_S37.401L
%•
0
2378-TCDD
31.58
F1:Votiage SIR,E1+
319.8955
1.091 a+007
bl6may11d-6 Smooth(S0,1x2)
CS4_S37•401L
96-
6b 6 Jo bZ 6 abed
1
2378-TCDD
31.56
min
Fi VotiageSIR,EI•
321.8936
1.368e+007
min
26.25 28.50 26.75 27.00 27.25 27.50 27.75 28.00 20.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

)))))))))))))))))))))))))))))))))))))))))))
Quantify Sample Report
###TCDD TCDF Only ###
MassLynx 4.1 SCN640
Dataset: Y:1Default.pro1Curvedblb16may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-6, Date: 16-May-2011, Time: 21:22:53, ID: CS4_S37-401L, Submitter: , Task:
2378-TCDF
bl6maylld-6 2378-TCDF F1:Voltage SIR,EI+
30.96 303.9016
Il 1.201e+007
0
I r r „ i t r i, c r r , r, r i r r, r( r . r r, r, r r r 1 r r r 1, r r r 1 r r r r r „ i „ r, i r r r, i min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDF
bl6may11d-6
%
o•
28 00 28.25
ES-TCDF
bl6mayl ld-6
2378-TCDF Fi :Voltage SIR,EI+
30.96 305.8987
/l 1.561e+007
r , i „ r r Ir r , r i „ r , . r , i r r r , r r , r i, , , i r „ r i r , r r r r r i r r, l „ r , i , r r r i r , r r i r r „ i „ r , 1 min
28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES:13C-2378-TCDF
30.95
F1:Voltage SIR,EI+
315.9419
3.039e+007
0 r , r r , , . , , , , , i, r r r i r r , r i r „ r r „ r i r r r , , , , r , r r r r r , r i , rr r r „ i „ , r „ , i r r r r r r , i r r , r min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDF
bl6mayl ld-6 ES:13C-2378-TCDF F1:Voltage SIR,EI+
30.95 317.9389
3.871e+007
r i, r,,, r r r r r r, I r r r, r r, r i „ r. i r r i „ r i r r c r i, r, , r, r i,,,, i, r r, i,., r, r r, i r r r min
V8 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
N
F..ock Mass
b1anayl1d-6 F1:Voltage SIR,EI+
30.75 31.34 31,42 31.77 31.85 32.03 32.38� 304.982440�
28.69 28.81 28.96 29.25 29.63 29.75 29.93 30.29 30.82 31.05 31.67 "�O
28.20 28.45 8.58 29.20 29.48 30.04 30.49 31.24
r, r r, r i min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

Quantify Sample Summary Report MassLynx 4.1 SCN640
### ICAL Summary ###
Dataset: Y:1Default.pro\Curvedblb16may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:10:32 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:12:40 Eastern Daylight Time
Na . 16may11d-7
ID* CS5 37-401M
D te: ay-2011
Ti e: :13:00
User: JLJ
Submitter:
Task:
Name Response IonlArea Ion2Area RT RA RAFaiI7 RRF MRRF %RSD IS# Heightl Noisel SN1 Height2 Noise2 SN2 M
1 2378-TCDF 5.788e6 2.520e6 3.268e6 30.971 .77 NO 0.96 1 1.004 4.6 4 3.836e7 1269 30226.8 4.955e7 970 51086.4 bb
2 2378-TCDD 4.473e6 1.970e6 2.503e6 31.56,9.79 NO 1.099 • 1.171 10.0 3 3.702e7 843 43905.5 4.714e7 1060 44452.7 MM
3 ES:13C-2378-TCDD 2.036e6 8.957e5 1.140e6 31.54,9.79 NO 1.094• 1.026 3.7 5 1.604e7 983 16322.2 2.072e7 835 24808.1 bb
4 ES:13C-2378-TCDF 3.010e6 1.327e6 1.683e6 30.95( 0.79 NO . 1.617. 1.577 2.3 5 1.962e7 1072 18304.8 2.463e7 1075 22897.9 bb
..r-
5 JS:13C-1234-TCDD 1.861e6 8.211e5 1.040e6 31.114.79 NO 1.000. 1.000 0.0 5 1.271e7 983 12936.5 1.625e7 835 19462.4 bb
6 CS:37CI-2378-TCDD 4.671e6 4.671e6 - 31.56/ - 1.255, 1.218 5.8 5 8.776e7 1125 77979.3 - - bb
2!-
3.0(Oe.-t gOdi),,k
6t►L 10 9Z1. abed
D •q�
-Fyn to- 3►-/

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only #1##
Dataset: Y:(Default.prolCurvedblblfimaylld-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-7, Date: 16-May-2011, Time: 22:13:00, ID: CS5_S37-401M, Submitter: , Task:
2378-TCDD
bl6may11d-7 F1:Voltage SIR,EI+
31.56 319.8965
100 3.711e+007
-Q00 . „`, . , 1 , 1 . , , . , , 1 , , , . 1 , y min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDD
bl6may11d-7
100
-�/ . 1 , 1 1 , , , 1 , 1 , , 1 . , . 1 , 1 , . . 1 . 1 , 1 , , min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
31.56
ES-TCDD
bl6mayl 1d-7
31.11
ES:13C-2378-TCDD
31.54
0
0°1
„ , . , . , 1 . , 1 , , . , 1 , 1 , , 1� 1 ,, l , , 1 1 „ l , min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDD
b 16may11 d-7
31.11
ES:13C-2378-TCDD
31.54
F1:Voltage SIR,EI+
321.8936
4.726e+007
F1:Voltage SIR,E1+
331.9368
1.607e+007
F1:Voltage SIR,EI+
333.9339
2.077e+007
, min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
0
CS-TCDD
bl6may11 d-7
1-
CS:37CI-2378-TCDD
31.56
0 8 00 28.25
FiLock Mass
bl6may11d-7
%
I ,
F1:Voltage SIR,EI+
327.8847
8.788e+007
1 . min
28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
28.10 28.30 28.43 28.5128.74 28.79 28.89 29.1529.22
83 1.,.,1
28 00 28.25 28.50
28.75 29.00
29.43 29.58
29.80 30.1630.22 30.37 30.64 30.70 30.78
31.34 31.44 31.74
31.0631.20
F1:Voltage SIR,EI+
31.87 32.05 32.30 304.9824
8. +006
m
29.25 29.50 29.75 30.001n
30.25 30.50 30.75 31 .00 31 .25 31 .50 31 .75 32.00 32.25 32.50

b1 bmay11 d•7 Smooth(SG,1x2)
C85_537.401M
100
-0... .., .j.
bl6may11d•7 Smooth(30,1x2)
CS5_537-401141
100
-0
6v410 9ZL axed
•
2378-TCDD
31.56
Ft :Voltage SIRE •
319.8965
3.711e•007
4=? tmin
2378-TCDD
31.56
1.1
F1:Voltape SIR,EI•
321.8930
4.726e•007
•
26.25 26.50 26.75 27.00 27.25 f 27.50 27.75 28.00 28 25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31 00 31.25 31.50 31.75 32.00 32.25 32.50
min

) )_) ) ) )_,) .)
Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: Y:1Default.prolCurvedblbl6may11d-tetras.gld
Last Altered: Monday, October 31, 2011 14:05:07 Eastern Daylight Time
Printed: Monday, October 31, 2011 14:06:18 Eastern Daylight Time
Name: bl6may11d-7, Date: 16-May-2011, Time: 22:13:00, ID: CS5 S37-401 M, Submitter: , Task:
2378-TCDF
bl6may11 d-7
2378-TCDF F1:Voltage SIR,EI+
30.97 303.9016
n 3.859e+007
0 . . i r r . r . . . . . . r , r , . I" , . r . min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
2378-TCDF
bl6may11d-7
0' . i . . . . i . i , i r , . . , . . . . i i . r i . . , , ,i , i min
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
ES-TCDF
bl6may11 d-7
2378-TCDF F1:Voltage SIR,E1+
30.97 305.8987
4.984e+007
ES:13C-2378-TCDF
30.95
0 " . . i , r i . . , i . . . , i , ,•
28 00 28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
F1:Voltage SIR,EI+
315.9419
1.972e+007
ES-TCDF
bl6may11d-7
ES:13C-2378-TCDF
30.95
i min
F1:Voltage SIR,EI+
317.9389
2.475e+007
%
-.p�:
a - . , . . , , . i . . , , , , , , . . , . , , . , , , . . . 1 min
1800 28.25 28.50 28.75 29.00 29.25 29.50 29.75' 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50
N
cD
F1R...ock Mass
bltnay11d-7
28.10 28.30 28.43 28.5128.74 28.79 28.89 29.15 29.22 29.43 29.58 29.80
83 ,
28 00
30.1630.22 30.37 30.6430.70 30.78
31.0631.20
31.34 31.44 31.74
F1:Voltage SIR,EI+
. 3205 304.9824
31.87 32.30 1.98 +006
, . . , i . . . . ,• , . r , ,•, . r , . . , . . i , . . ,•i i , , r . , . min
28.25 28.50 28.75 29.00 29.25 29.50 29.75 30.00 30.25 30.50 30.75 31.00 31.25 31.50 31.75 32.00 32.25 32.50

614 io 0£ 6 a6ed
Instrument:
Data File
b29octlla-1
b29octlla-2
b29octlla-3
b29octlla-4
b29octlla-5
b29octlla-6
b29octlla-7
b29octlla-8
b29octlla-9
b29octlla-10
b29octlla-11
b29octlla-12
b29octlla-13
b29octlla-14
b29octlla-15
b29octlla-16
b29octlla-17
SGS North America, Inc.
HRMS2
Sample ID
Retcon_S39 -59D
46213
46212
31102775001
31102775002
31102775003
31102775004
31102775005
31102775006
31102775007
31102775008
31102775009
31102775010
31102775011
31102775012
31102775013
Retcon_S39 -59D
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
JHL
An alyst Acquisition Date/Time Inj.Vol
2011-10-29 18:44:55 1 uL
2011 -10-29 19:36:51 1 uL
2011 -10-29 20:32:14 1 uL
2011 -10-29 21:07:59 1 uL
2011 -10-29 21:44:39 1 uL
2011 -10-29 22:21:19 1 uL
2011 -10-29 22:58:05 1 uL
2011 -10-29 23:34:50 1 uL
2011 -10-30 00:11:31 1 uL
2011 -10-30 00:48:16 1 uL
2011 -10-30 01:25:02 1 uL
2011 -10-30 02:01:42 1 uL
2011 -10-30 02:38:27 1 uL
2011 -10-30 03:15:08 1 uL
2011 -10-30 03:51:49 1 uL
2011 -10-30 04:28:36 1 uL
2011-10-30 05:05:18 1 uL
Iwc03\-
Page 1 of 1
)))))))))))))))))))))))))))))))))

)))))))))))))))))))))))))))))))))))))))))))
Sample List Report MassLynx 4.1 SCN640
Sample List:
Last Modified:
Printed:
C:1MassLynxlDefault.prolSampledblb29oct11 a.SPL
Saturday, October 29, 2011 20:05:54 Eastern Daylight Time
Saturday, October 29, 2011 20:05:59 Eastem Daylight Time
File Name Bottle HRD(Batch) Lab Sample ID
1 b29oct11a-1 1
2 b29oct11 a-2 4 HRD1459
3 b29oct11a-3 5 HRD1459
4 b29oct11a-4 6 HRD1459
5 b29oct11a-5 7 HRD1459
6 b29oct11a-6 8 HRD1459
7 b29oct11a-7 9 HRD1459
8 b29oct11a-8 10 HR01459
9 b29oct11 a-9 11 HRD1459
10 b29oct11 a-10 12 HRD1459
11 b29oct11a-11 13 HRD1459
12 b29oct11 a-12 14 HRD1459
13 b29oct11a-13 15 HRD1459
14 b29oct11 a-14 16 HRD1459
15 b29oct11 a-15 17 HRD1459
16 b29oct11 a-16 18 HRD1459
17 b29oct11 a-17 1 --
6i4 10 6£6 abed
Retcon_539-59D
46213
46212
31102775001
31102775002
31102775003
31102775004
31102775005
31102775006
31102775007
31102775008
31102775009
31102775010
31102775011
31102775012
31102775013
Retcon_S39-59D
Customer Sample ID
OPR for HBN 14044 [HXX/1337J
LMB for HBN 14044 [HXX/1337J
Comp#1 Site 1 Bluegill
Comp#2 Site 1 Flathead Catfish
Comp#3 Site 1 Blue Catfish sm
Comp#4 Site 1 Blue Catfish Ig
Comp#5 Site 2 Bluegill
Comp#6 Site 2 Flathead Catfish
Comp#7 Site 2 Blue Catfish
Comp#8 Site 2 Common Carp
Comp#9 Site 3 Bluegill sm
Comp#10 Site 3 Bluegill Ig
Comp#11 Site 3 FlatheadCatfish
Comp#12 Site 3 Blue Catfish
Comp#13 Site 1 Blue Catfish Ig
Page 1 of 2
Page Position (1, 1)
Sample Type MS File Inlet File
QC dioxins_db5ms dioxin_db5ms
Analyte dioxins db5ms dioxin_db5ms
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins db5ms dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
Analyte dioxins_db5ms_dw2 dioxin_db5ms_dw2
QC dioxins db5ms dioxin_db5ms

Experiment Calibration Report
File:
Printed:
MassLynx 4.1 SCN640
Experiment: dioxins_db5ms.exp Refe ence: pfk.ref Function: 1 @ 200 (ppm)
Saturday, October 29, 2011 18:39:5 Eastern Daylight Time
M 292.9824 R 10917
M 342.9792 R 10728
I 41
I i
l i
E= �P I
— -- _ - -- 11'04
6b 610 Z£ 6 96Bd
M 304.9824 R 11159 M 318.9792 R 13017
M 354.9792 R 10122
M 366.9792 R 10869
r`
Page 1 of 1
M 330.9792 R 10588
M 380.9760 R 11630 Z

)))))))))))))))))))))))))))))))))))))))))))
Experiment Calibration Report MassLynx 4.1 SCN640
File: Experiment: dioxins_db5ms.exp Refer7e: pfk.ref Function: 2 @ 200 (ppm)
Printed: Saturday, October 29, 2011 18:40:11 Eastern Daylight Time
M 330.9792 R 11261
�N r 6.)
M
_ i.
Dili 111.
. 4111 ill
M 380.9760 R 11626 /
614 Jo eel abed
M 342.9792 R 11519
66.
146
1111,
S;,I
M 392.9760 R 11207
.64
Page 1 of 1
M 354.9792 R 11014
M 404.9760 R 11961
•
M 366.9792 R 10822
IM
10'
Ji
M 416.9760 R 12197
r�.

Experiment Calibration Report MassLynx 4.1 SCN640
File: Experiment: dioxins_db5ms.exp Ref ence: pfk.ref Function: 3 @ 200 (ppm)
Printed: Saturday, October 29, 2011 18:40:36 astern Daylight Time
M 366.9792 R 12689
M 416.9760 R 12373
6P 6 Jo PEI. abed
M 380.9760 R 10681
Page 1 of 1
M 430.9728 R 11312
.ra•
.1
1f.
1
M 392.9760 R 10917
)tiv
011
M 442.9728 R 11012
140
1/)i
M 404.9760 R 12018
1)0
AR
M 454.9728 R11112

➢))➢)))))))➢)))))))))))))))))))))))))))))))
Experiment Calibration Report MassLynx 4.1 SCN640
File: Experiment: dioxins_db5ms.exp Ref ence: pfk.ref Function: 4 © 200 (ppm)
Printed: Saturday, October 29, 2011 18:42:3 Eastern Daylight Time
M 404.9760 R 10967
M 454.9728 R 11905
6IL 10 9£6 abed
Page 1 of 1
M 430.9728 R 11961
IIM 416.9760 R 11683
M 466.9728 R 12952
•
M 442.9728 R 12693

Experiment Calibration Report MassLynx 4.1 SCN640
File: Experiment: dioxins_db5ms.exp Refer nce: pfk.ref Function: 5 @ 200 (ppm)
Printed: Saturday, October 29, 2011 18:42:58 astern Daylight Time
Page 1 of 1
M 430.9728 R 12256
M 480.9696 R 12820
M 442.9728 R 11792
2.9696 R 11994
1111
AI?
617l 10 9E6 abed
M 454.9728 R 10778
M 504.9696 R 12195
M 466.9728 R 12016
1or
iw
liliiJ"y'
M 516.9697 R 11061

))))))))))))))))))))))))))))))))))))))))
Resolution Check Report
MassLynx 4.1 SCN640
Printed: Sunday, October 30, 2011 06:00:01 Eastern Daylight Time
Page 1 of 4
M 292.9824 R 12261
M 342.9792 R 12196
6I'I Jo LEI abed
M 304.9824 R 13111
M 354.9792 R 13459
11
1..--
, ,11.11 L_
__.`, i --1 {{ _
M 342.9792 R 11859
— -
1—---
L_.
,�---- LI 'I—L I _
�, ��1� - i 1441,11I
,�- — -
M 318.9792 R 16080
- -----------
- 1- _____
(ri
M 366.9792 R 13640
M 354.9792 R 13851
M 330.9792 R 11829
M 380.9760 R 12490
M 366.9792 R 13297

Resolution Check Report MassLynx 4.1 SCN640
Printed: Sunday, October 30, 2011 06:00: 1 Eastern Daylight Time
Page 2 of 4
M 380.9760 R 12872
Ij
! II
id H
41_ L _ .
- -
,„
M 366.9792 R 12828
I
It 1 � lilI
- I-• --
f- ;i I tiril
JI L
.- .1 .�,rr t� - Ivy {li JI_.,
M416.9760 R 14631
1 IN IIII, I 1 1
th
1
6b 610 9£ I. a6ed
M 392.9760 R 12627
� 1
I I
---I---- t—.--_
Li,
1 14i/
M 380.9760 R 11905
M 430.9728 R 12239
M 416.9760 R 14730
M 404.9760 R 12890
--—f--——t-- —-
lj��'—i'rl'--I—•—
M 404.9760 R 14426
1 I 1
1 1
----t-- 1T—r--
w I ��' j
- I--
- al
1 I I �'I 1
--L l I- .��. �-- —-
Ij I _kph_ __:__ __1 v Ij
, ... ...
M 392.9760 R 14264
M 442.9728 R 13370

)))))))))))))))))))))))))))))))))))))))))))
Resolution Check Report MassLynx 4.1 SCN640
Printed: Sunday, October 30, 2011 06:00: Eastern Daylight Time
Page 3 of 4
M 404.9760 R 14651
I
Hilbf I
; I LI L
' I 140 I
M 454.9728 R 13592
10
6116
10
M 442.9728 R 13899
r•�
61110 6£1 abed
M 416.9760 R 15437
, I i
: 1 I
--1-- ;ih-; -t- - --
n I 1
[:-. _ _ __ _ ji i L
I1I
ijj itii.
M 466.9728 R 16929
06
t:
60
M 454.9728 R 13321
I— --
— —
I
— -114
M 430.9728 R 14060
110,
L —
L— al --1 :41I
M 480.9696 R 14893
•
M 466.9728 R 15389
: 1-
I 1
1
- L _ . ��
ri t Lt..T
M 442.9728 R 13670
106
1101
---1-
Y.
M 430.9728 R 14285
M 480.9696 R 14244

Resolution Check Report / MassLynx 4.1 SCN640
Printed: Sunday, October 30, 2011 06:00:01 Eastern Daylight Time
Page 4 of 4
M 492.9696 R 13232
..—__,__ .
-
1
_ -- ti `'I a� 1_--.
II
- __ ,
6b610 OI' abed
M 504.9696 R 13481
�r
M 516.9697 R 16790
����)3) -1))))

)))))))))))i)))))))))))))))))) ) ) ) ) ) )
6171. Jo 141. abed
b29octi 1a-1 Sb (1,1.00 )
100-
0
26.40
26.58
1;\
27.09
/1
I \
26.96
Retcon_S39-59D
27.27
29-Oct-20111
18:44:55
1: Voltage SIR 16 Channels El+
319.8965
6.06e5
1---._.-- . ,-- ---ij
----. .... __..-_. ..___ _ _
26.60 26.80 27.00 27.20 27.40 27.60 27.80 28.00 28.20 _28.40 ..
28.31
Time

Quantify Sample Summary Report MassLynx 4.1 SCN640
### 8299 CCAL Summary ###
Dataset✓✓: C:IMassLynx\Default.prolResults1b29oct1 l a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:10:27 PM Eastern Daylight Time
Method: Untitled 31 Oct 2011 09:53:18
J
Calibration: C:IMassLynADEFAULT.PRO1CurveDB1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-1
Date: 29-Oct-2011
Time: 18:44:55
ID: Retcon_S39-59D
Instrument:
User: JHL
1
2
3
4
5
6
7
:Name Response:. Ion1Area: Ion2Area : RT:A :RAFaiI?. pg/pL. %Der1,. RRF:. Height1.: Noisel:: SN1.: Height2 - Noise2 : SN2 • M :User RF
:2378-TCDF 1.632e5 7.044e4 9.273e4 26.30.76 NO 9.762 -2.4 0.980 8.959e5 1172 764.3 1.177e6 1048 1123.9 bb 1.00
:2378-TCDD 1.072e5 4.643e4 6.078e4 27.27/0.76 NO 9.977 -0.2 1.169 5.841e5 786 743.5 7.499e5 972 771.6 MM 1.17
: ES:13C-2378-TCDD 9.173e5 4.106e5 5.066e5 27.24,,0,81 NO 86.074 -13.9 0.883 5.145e6 1418 3629.3 6.319e6 1258 5024.6 bb 1.03
: ES:13C-2378-TCDF 1.664e6 7.308e5 9.337e5 26.371)0.78 NO 101.617 1.6 1.602 9.124e6 966 9448.5 1.161e7 1302 8917.2 bb 1.58
•JS:13C-1234-TCDD 1.039e6 4.614e5 5.773e5 26.57.80 NO 100.000 0.0 1.000 5.810e6 1418 4098.3 7.312e6 1258 5813.9 bb 1.00
• CS:37CI-2378-TCDD 1.065e5 1.065e5 - 27.27' - - 8.415 -15.9 1.025 1.349e6 923 1462.2 - bb 1.22
• F1 Lock Mass 55328
6b L Jo Zb 6 abed

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:1MassLynx\Default.pro\Resultslb29oct11 a-1 tetras.gld
Last Altered: 01-November-11 8:13:12 AM Eastern Daylight Time
Printed: 01-November-11 8:16:14 AM Eastern Daylight Time
Method: Untitled 31 Oct 2011 09:53:18
Calibration: C:1MassLynxIDEFAULT.PRO1Curve0B1mtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct'l1a-1, Date: 29-Oct-2011, Time: 18:44:55, ID: Retcon_S39-59D, Submitter: , Task:
2378-TCDD
b29oct11a-1 2378-TCDD F1:Voltage SIR.EI+
23.95 26.58 26.96 27.27 28.31 319.8965
6.915e+005
> > 1 ( S 1 1 ` r r i min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
2378-TCDD
b29oct11a-1 2378-TCDD F1:Voltage SIR.EI+
23.95 26.58 26.94 27.27 28.31 321.8936
% 5
, 25.48 /\ , '`f\ t \ A8.424e+00
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 2'7.5 28.0 28.5 29.0 29.5 30.0
ES-TCDD
b29oct11a-1 ES:13C-2378-TCDD F1:Voltage SIR.EI+
26.57 27.24 331.9368
5.867e+006
1 1/.1.,,�• ; �•
, min
20.0 20.0 20.5 21i.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
ES-TCDD
b29oct11 a-1
ES:13C-2378-TCDD
26.55 27.24
,, .,,,� �..� ,,�1 �,, ..1min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
F1:Voltage SIR,EI+
333.9339
7.378e+006
CS-TCDD
b2ioct11a-1 CS:37C1-2378-TCDD F1:Voltage SIR,EI+
27.27 327.8847
Gt► _ A 1.392e+006
t7` i , , , , , , , . , , , , 1 min
0.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
co
F1 Lock Mass
b29octlla-1 F1:Voltage SIR,EI+
22.04 24.13 25.97 304.9824
% 1 22.37 22.75 23.33 23.89 24.31 24.89 24.9725.48 25.79 26.20 27.04 27.35 27.81 27.93 28.57 3.319e+006
27 - - __.._. . min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0

929ot111:-1 Smootn(S3.1x2)
520v111a•1 SrnoathiSO 1i21
22.25
6I1-Jotiti1-a6ed
22.50
22 75
23 03
23 25
23 50
23 75
23 95
1
23 95
24 00
24 25
24.50 24'75
25.00
25.40
25 25 25.50 25 75 28 00 25 25 26 50
28.58
26.58
27 09
2696
2709
28.94
2575 2700
2378-TCOD
27.27
44737.42
9 72 pghl
732.53
2378-TCDO
27.27
59172.55
764.39
F1:vatage SlR,EI•
319 6465
6915e•005
28 31
J
Ft:Ve33g? 0IR.0
)21 8436
203f 8424e•005
i
27 25 27 50 27.75 28.00 28.25
min
28.50

Quantify Sample Report
###TCDD TCDF Only ###
MassLynx 4.1 SCN640
Dataset: C:1MassLynx\Default.prolResults1b29oct1l a-1 tetras.gld
Last Altered: 01-November-11 8:13:12 AM Eastern Daylight Time
Printed: 01-November-11 8:16:14 AM Eastern Daylight Time
Name: b29oct11a-1, Date: 29-Oct-2011, Time: 18:44:55, ID: Retcon_S39-59D, Submitter: , Task:
2378-TCDF
b29oct11a-1 2378-TCDF Fi:Voltage SIR,EI+
22.34 26.39 303.9016
o j i 28.44 1.057e+006
To;
� 25.50 1` ,.
3 ,�.� ,.,.� �.,;, ,,, ` �., , , ,min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
2378-TCDF
b29oct11a-1 2378-TCDF F1:Voltage SIR,EI+
22.34 26.39 305.8987
111 ,; 28.44 1.259e+006
25.50 I 1
2,.., . ,r , 1min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
ES-TCDF
b29oct11 a-1
ES:13C-2378-TCDF F1:Voltage SIR,EI+
26.37 315.9419
9.252e+006
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
ES-TCDF
b29oct11 a-1
ES:13C-2378-TCDF F1:Voltage SIR,EI+
26.35 317.9389
1.169e+007
min
7420.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
oi
FELock Mass
b29oct11a-1 F1:Voltage SIR,EI+
22.04 304.9824
3.319e+006
22.37 22.75 23.33 23 89 24.13 24 31 24.89 24.9725.48 25.79 25.97 26.20 27.04 27.35 27.81..27.93 _ 28.57
27 . , , min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
ova

Quantify Sample Summary Report MassLynx 4.1 SCN640
### 8290 C YAL Summary###
Dataset: C:1MassLynxlDefault.pro\Resultslb29oct11 a-1 tetras.gld
Last Altered: 31-October-11 5:03:18 PM Eastern Daylight Time
Printed: 31-October-11 5:10:45 PM Eastern Daylight Time
Method: Untitled 31 Oct 2011 09:53:18
Calibration: C:IMassLynxIDEFAULT.PROICurveDBlmtetras-051611d_new.cdb 31 Oct 2011 10:04:21
Name: b29oct11a-17/
Date: 30-Oct-2011
Time: 05:05:18 /
ID: Retcon_S39-59D
Instrument:
User: JHL
1
2
3
4
5
6
7
:Name
:2378-TCDF
:2378-TCDD
: ES:13C-2378-TCDD
: ES:13c-2378-TCDF
. JS:13C-1234-TCDD
• CS:37CI-2378-TCOD
:F1 Lock Mass
J
Response:. IonlArea• Ion2Area . RT• RA •RAFai1?- pg/µL- %Dev. RRF:. Heightl. Noisel.: SN1•: Height2 - Noise2 • SN2 - M ; User RF
1.271e5 5.603e4 7.107e4 26.334.79 NO 10.066 0.7 1.011 7.038e5 942 746.9 9.468e5 1237 765.4 bb 1.00
9.038e4 3.989e4 5.048e4 27.22.1.79 NO 9.753 -2.5 1.142 4.800e5 783 613.1 6.460e5 2118 305.0 MM 1.17
7.911e5 3.457e5 4.454e5 27.21/9.78 NO 94.097 -5.9 0.965 4.459e6 1118 3989.9 5.791e6 1226 4721.5 bb 1.03
1.257e6 5.578e5 6.997e5 26.32�.80 NO 97.308 -2.7 1.535 7.470e6 1605 4654.8 9.288e6 1266 7337.4 bb 1.58
8.194e5 3.692e5 4.502e5 26.5e 0.82 NO 100.000 0.0 1.000 4.854e6 1118 4342.5 5.962e6 1226 4861.5 bb 1.00
9.465e4 9.465e4 - 27.22/ - - 9.484 -5.2 1.155 1.231e6 833 1477.6 - bb 1.22
39571
6t410 9171. eBed

Quantify Sample Report MassLynx 4.1 SCN640
###TCDD TCDF Only ###
Dataset: C:1MassLynx\Default.pro\Resultslb29oct11 a-1 tetras.gld
Last Altered: 01-November-11 8:13:12 AM Eastern Daylight Time
Printed: 01-November-11 8:16:14 AM Eastern Daylight Time
Name: b29oct11a-17, Date: 30-Oct-2011, Time: 05:05:18, ID: Retcon_S39-59D, Submitter: , Task:
2378-TCDD
b29oct11 a-17
23.92
26.55 27.04 2378-TCDD 28.26
�6.91 27.22 f
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
F1:Voltage SIR.EI+
319.8965
5.871e+005
2378-TCDD
b29oct11a-17 2378-TCDD F1:Voltage SIR,EI+
23.90 26.91 27.22 28.26 321.8936
26.53 7.780e+005
°70 A 25.41 (\.... 1 . i min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
ES-TCDD
b29oct11a-17 ES:13C-2378-TCDD F1:Voltage SIR,EI+
26.52 27.21 331.9368
i\ 4.907e+006
1 i _ 1 _ i 1 _ i . . _ , _ . . i . . r , T _ I , . . . . , , 1 min)
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
ES-TCDD
b29oct11a-17 ES:13C-2378-TCDD
26.52 27.21
%-i
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5
F1:Voltage SIR,EI+
333.9339
6.019e+006
.. . ....,. ..,....min
28.0 28.5 29.0 29.5 30.0
CS-TCDD
b29oct11a-17 CS:37C1-2378-TCDD F1:Voltage SIR,EI+
27.22 327.8847
IT r 1 1.267e+006
,,- �.-; ,, r �.,. ', min
;20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0
.A
F1'Lock Mass
b29oct11a-17 F1:Voltage SIR,EI+
22.04 304.9824
24.87 25.66 26.02 28.34 2.413e+006
%] 1 22.4923.00.23.13 ` 23.56 24.0824.17 24.61^� 25.48 26.73 _27.09 27.49 28.08.28.182 .__.�
25 , , � , . 1 , f , 1 min
20.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0

6t4Jo8b696ed
679of.t11 a-17 Smoot1;S0.14)
0290 Dia-17 Smco040.1.22)
2392
23 93
J
25 41
22.25 22 50 22.75 23 00 23.25 23 50 23 75 24.00 24.25 24.50 24.75 25 00 25.25 25.50 25.75 28.00 26 25 20
26 55
26.53
26.91
ti-----"-- -----ice
27.n04
•
2378-TCDD
27 77
41707.66
1015 09MU1-
623 60
2378-TCDD
27.22
51912.99
309.56
27.04
75 2700 21.25 7750 2775
29 26
29-26
F1:VoDa9a SIR,EI•
319 8955
5 871 e•035
71:Vota;o COUP,
321 6936
7 7800.005
3)))))))�)���))))))���� j

))))) I. )._. i))))))))))))))) )__ ) )) _))))))))))))))) )
Quantify Sample Report MassLynx 4.1 SCN640
####TCDD TCDF Only ###
Dataset: C:1MassLynx\Default.pro\Resultslb29oct1la-ltetras.gld
Last Altered: 01-November-11 8:13:12 AM Eastern Daylight Time
Printed: 01-November-11 8:16:14 AM Eastern Daylight Time
Name: b29oct11a-17, Date: 30-Oct-2011, Time: 05:05:18, ID: Retcon_S39-59D, Submitter: , Task:
2378-TCDF
b29oct11 a-17
%-
3
20.0
r I r (. I- r. . r.. r, r . r r,
20.5 21.0 21.5 •22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0 �n
2378-TCDF
b29oct11 a-17
2
20.0 20.5
ES-TCDF
b29oct11a-17
22.31 2378-TCDF F1:Voltage 303SI 90116
!\,
26.33 28.41
ssi �
25.46 t
22.31 2378-TCDF F1:Voltage SIR,EI+
305.8987
26.33 28.39 1.236e+006
, ,fi \
25.46 1\ A
, ,
21.0 21.5 ...,
22.0 22.5 23.0 23.5 24.0 24.5 25.0 26.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30, min
.0
ES:13C-2378-TCDF F1:Voltage SIR,EI+
26.32 315.9419
/,_ t 7.551e+006
0' r
20.0 20.5 21r.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0min
ES-TCDF
b29oct11a-17
ES:13C-2378-TCDF
26.32
30.0 20.5 21.0 21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0• in
m
F1 t.ock Mass
b2Act11 a-17
22.04 F1:Voltage SIR,EI+
304.9824
2.413e+006
o/Q
25
24.87 25.66 26.02
22.4923.00.23.13 23.56 24.0824.17 24.61 4 25.48 26.73 27.09 27.49 28.08 28.18 28.34
F1:Voltage SIR.EI+
317.9389
9.384e+006
20.0
20.5
21.0
21.5 22.0 22.5 23.0 23.5 24.0 24.5 25.0 25.5 26.0 26.5 27.0 27.5 28.0 28.5 29.0 29.5 30.0 in