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HomeMy WebLinkAboutWI0400502_DEEMED FILES_20180924Permit Number Program Category Deemed Ground Water Permit Type WI0400502 Injection Deemed In-situ Groundwater Remediation Well Primary Reviewer michael.rogers Coastal SWRule Permitted Flow Facility Facility Name Three Boys Citgo (Fonner Gant #831 Station) Location Address 5000 Old Walkerton Rd Winston Salem Owner Owner Name Gant Oil Company Dates/Events NC Orig Issue 9/19/2018 App Received 8/29/2018 Regulated Activities Groundwater remediation Outfall Waterbody Name 27105 Draft Initiated Scheduled Issuance Public Notice Central Files: APS SWP 9/24/2018 Permit Tracking Slip Status Active Version 1.00 Project Type New Project Permit Classification Individual Permit Contact Affiliation Major/Minor Minor Region Winston-Salem County Forsyth Facility Contact Affiliation Owner Type Non-Government Owner Affiliation Robert E. Gant PO Box68 Walkertown Issue 9/19/2018 Effective 9/19/2018 NC 27051 Expiration Requested /Received Events Streamlndex Number Current Class Subbasin Ro gers, Michael From: Rogers, Michael Sent: To: Wednesday, September 19, 2018 2:31 PM Knight, Sherri; Wang, Shuying Subject: Attachments~ WI0400502 FW: [External] RE: Application for NOi Three Boys Citgo NOi for BAM injections at former Gant 831 site 8.27.18.pdf Please find attached a NOi. From: Bruce Edward Tease [mailto:btease@ramboll.com] Sent: Wednesday, September 19, 2018 1:51 PM To: Rogers, Michael <michael.rogers@ncdenr.gov> Subject: [External] RE: Application for NOi Three Boys Citgo CAUTION: External email. Do not click links or open attachments unless verified Send all suspicious email as an attachment to i~t~l 1<] 0: -->: 11: Michael Lat/long for 5000 Old Walkertown Road in Winston-Salem, NC are as follows Latitude Longitude 36 09' 28.56" 80 12' 16. 70" Bruce Edward Tease Senior Managing Consultant D +1 (413) 8354355 M +1 (413) 8755896 btease@ramboll .com "For what is reality but an image we create to explain uncertainty" (The Little Chicopee Boy, 1987) From: Rogers, Michael <michael.rogers @ncdenr.gov> Sent: Wednesday, September 19, 2018 12:40 PM To: Bruce Edward Tease <btease @ramboll.com> Subject: RE: Application for NOi Three Boys Citgo Pleae give me the lat/long for this site. From: Shrestha, Shristi R Sent: Tuesday, September 18, 2018 4:29 PM To: btease @ramboll.com Cc: Knight, Sherri <sherri.knight@ncdenr.gov>; Rogers, Michael <michael.rogers @ncdenr.gov>; Watts, Debra <debra.watts @ncdenr.gov> Subject: RE: Application for NOi Three Boys Citgo Good afternoon, 1 We just received the approval letter for use of BAM. I am on leave from tomorrow so I have forwarded the NOi package to Michael Rogers. You will hear back from us soon. Thank you, Shristi Shristi R. Shrestha Hydrogeologist Water Quality Regional Operations Section Animal Feeding Operations & Groundwater Protection Branch North Carolina Department of Environmental Quality 919-707-3662 office shristi.shrestha @ncdenr.gov 512N. Salisbury Street 1636 Mail Service Center Raleigh, NC 27699 1636 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. 2 From: Shrestha, Shristi R Sent: Friday, September 14, 2018 2:09 PM To: btease @ramboll.com Cc: Knight, Sherri <sherri.knight@ncdenr.gov>; Rogers, Michael <michael.rogers @ncdenr.gov>; Watts, Debra <debra.watts @ncdenr.gov> Subject: Application for NOi Three Boys Citgo Good afternoon, We have received a NOi application Three Boys Citgo located at 5000 Old Walkertown Road, Winston.:salem, NC 27105. The additive proposed in the application Bioavailable Absorbent Media (BAM) is not on our approved list, hence cannot be injected. Please find the approved list in the following link http s://deg .nc.gov/about/divisions/water-resources/water-g uality-reg ional-o p erations/groundwater- p rotection NC DEQ: Groundwater Protection deq.nc.gov Purpose and Function. The Water Quality Regional Operations Section's Groundwater Protection Programs are responsible for protecting and preserving the high quality of North Carolina's groundwater resources. Thank you, Shristi Shristi R. Shrestha Hydrogeologist Water Quality Regional Operations Section Animal Feeding Operations & Groundwater Protection Branch North Carolina Department of Environmental Quality 919 707-3662 office [sh risti .shrestha@ncde n r.gov ]shristi .shrestha@ncdenr.gov 3 512N. Salisbury Street 1636 Mail Service Center Raleigh, NC 27699 1636 4 Ro g ers , Michael From: Rogers, Michael Sent: To: Wednesday, September 19, 2018 2:31 PM 'Bruce Edward Tease' Cc: Shrestha, Shristi R; Knight, Sherri; Wang, Shuying Subject: WI0400502 RE: [External] RE: Application for NOi Three Boys Citgo Attachments: Deemed Permitted {NOi) In-Situ GW Rem Notification & Aquifer Test Well ( .... docx Thank you for submitting the Notice of Intent to Construct or Operate Injection Wells (NOi) for the above referenced site. Please note we have a newer NOi form (attached). If you look at the signature page, you will see where we request the signature of the "Well Owner". When you submit the forms below after injection please include a revised signature page with the signature of Robert Gant. He is the permittee/applicant and well owner. Please remember to submit the following regarding this injection activity: 1) Well Construction Records (GW-1) and Abandonment Records (GW-30) when completed. Please provide copies of the GW-ls and GW-30s if not already submitted (originals go the address printed on the form). NOTE: Direct push or Geoprobe wells are considered wells and require construction (GW-1) and abandonment forms (GW-30). If well construction/abandonment information is the same for the wells, only one form needs to be completed-just indicate total number of injection points in the Comments/Remarks section of form . These forms can be found on our website at http :ljde q.nc.gov/about/divisions/water-resources/water-resources-p ermits/wastewater-branch /ground-water- p rotection /ground-water-re porting-forms 2) Injection Event Records (IER). All injections, including ai~ and passive systems require an IER. The IER can be modified for air sparge wells (e.g., air flow 'continuous' for date or rate of injection, etc.). Also, only one IER is needed for passive injection wells-indicate estimated total number of socks to be injected over lifetime of remediation. You can scan and send these forms directly to Shristi.shrestha @ncdenr.gov or via regular mail to address below. When submitting the above forms, you will need to enter the nine-digit alpha-numeric number on the form (i.e., WI0XXXXXX) that has been assigned to the injection activity at this site. This notification has been given the deemed permit number WI0400502. This number is also referenced in the subject line of this email. You may if you wish, scan and send back as attachments in re p ly to this email, as it will already have the assigned deemed permit number in the subject line. Thank you for your cooperation. From: Bruce Edward Tease [mailto:btease@ramboll.com] Sent: Wednesday, September 19, 2018 1:51 PM To: Rogers, Michael <michael.rogers@ncdenr.gov> Subject: [External] RE: Application for NOi Three Boys Citgo CAUTION: External email. bo not click links ·or open attachments unless verified . Send all suspicious email as an attachment to , I 1 I • • • 1 r--.··"'~ ' ·.,.;.,...._~-,I I -1 1!1.1,•'-.:•;·Jl\~ . ____ I __ __ ~--. Michael 1 Lat/long for 5000 Old Walkertown Road in Winston-Salem, NC are as follows Latitude Longitude 36 09' 28.56" 80 12' 16. 70" Bruce Edward Tease Senior Managing Consultant D +1 (413) 8354355 M + 1 ( 413) 8755896 btease@ramboll .com "For what is real ity but an image we create to expla in uncertainty" {The Little Chicopee Boy, 1987) From: Rogers, Michael <michael.rogers@ncdenr.gov> Sent: Wednesday, September 19, 2018 12:40 PM To: Bruce Edward Tease <btease@ramboll.com> Subject: RE: Application for NOi Three Boys Citgo Pleae give me the lat/long for this site. From: Shrestha, Shristi R Sent: Tuesday, September 18, 2018 4:29 PM To: btease@ramboll.com Cc: Knight, Sherri <sherri.knight@ncdenr.gov>; Rogers, Michael <michael.rogers@ncdenr.gov>; Watts, Debra <debra.watts@ncdenr.gov> Subject: RE: Application for NOi Three Boys Citgo Good afternoon, We just received the approval letter for use of BAM. I am on leave from tomorrow so I have forwarded the NOi package to Michael Rogers. You will hear back from us soon. Thank you, Shristi Shristi R. Shrestha Hydrogeologist Water Quality Regional Operations Section Animal Feeding Operations & Groundwater Protection Branch North Carolina Department of Environmental Quality 2 919-707-3662 office shristi.shrestha @ncdenr.g ov 512N . Salisbury Street 1636 Mail Service Center Raleigh, NC 27699 1636 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Shrestha, Shristi R Sent: Friday, September 14, 2018 2:09 PM To: btease @ramboll.com Cc: Knight,Sh!:!rri <sherri.knight@ncdenr.gov>; Rogers, Michael <michael.ro gers @ncdenr.g ov>; Watts, Debra <debra. watts@ncdenr.gov> Subject: Application for NOi Three Boys Citgo Good afternoon, We have.received a NOi application Three Boys Citgo located at 5000 Old Walkertown Road, Winston-Salem, NC 27105. The additive proposed in the application Bioavailable Absorbent Media {BAM) is not on our approved list, hence cannot be injected. Please find the approved list in the following link https://de g .nc.gov/about /divisions /water-resources /water-q uality-regional-o p erations/groundwater- p rotection 3 NC DEQ: Groundwater Protection deq.nc.gov Purpose and Function . The Water Quality Regional Operations Section's Groundwater Protection Programs are responsible for protecting and preserving the high quality of North Carolina's groundwater resources. Thank you, Shristi Shristi R. Shrestha Hydrogeologist Water Quality Regional Operations Section Animal Feeding Operations & Groundwater Protection Branch North Carolina Department of Environmental Quality 919 707-3662 office [sh risti.sh restha@ncdenr.gov )shristi.shrestha@ ncdenr .gov 512N . Salisbury Street 1636 Mail Service Center Raleigh, NC 27699 1636 4 ENGINFEp5 North Carolina Department of Environmental Quality DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 RE: NOTIFICATION OF INTENT TO CONSTRUCT OR Three Boys Citgo (former Gant #t831 Station) 5000 Old Walkertown Road Winston-Salem, NC Incident #3355, Facility # 0-016565 Dear DWR — UIC Program Manager; July 25, 2018 ppr.7.1YEDINCOECVDWR OPERATE IN]ECTION WELLS AUG29 Z013 Water Quality Regional Operations Section REUS Engineers, P.C., (REUS Engineers) formerly Environ Engineers of North Carolina, P.C. is pleased to submit this notification of intent (NOI) to conduct a small-scale injection operation at the above referenced site on behalf of the Gant Oil Company (Gant). Included with this NOI are the following required documents: • Contaminant plume map with isoconcentration lines that show the horizontal extent of the contaminant plume in sail and groundwater, existing monitoring wells, and proposed direct push technology (DPT) injection points; ■ Cross-section to the known depth of contamination that shows the horizontal and vertical extent of the contaminant plume in soil and groundwater, existing monitoring wells, and proposed DPT injection points; • Potentiometric surface map indicating the direction of groundwater movement, plus existing wells and proposed DPT injection points; • Safety data sheet (SDS) for bioavailable absorbent media (BAM); ■ SOS for PermeOx® Ultra; and • Summary table of DPT injection point details. Should you have any questions concerning the information presented in this NOI, please contact Bruce Tease at (413) 875-5896. Sincerely, REUS Engineers, P.C. 16---/-) Russell S. Kernp, PE cc: Assad Elkhoury, Property Owner Christina 5chroeter, NC DEQ Hydrogeologist Bruce Tease, PhD Project Manager North Carolina Department of Environmental Quality-Division of Water Resources NOTIFICATION OF INTENT TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C. 0200. This fo rm shall be submitted at least 2 weeks prior to in iection. AQUIFER TEST WELLS {1 5A NCAC 02C .0220 ) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION {1 5A NCAC 02c .0225) or TRACER WELLS (15A NCAC 02C .0229 ): 1) Passive In jection S ystems -In-well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods. 2) Small-Scale In jection O p erations -Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shaU be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests -Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation. and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells -Used to inject ambient air to enhance in-situ treatment of soil or groundwater. Print Clearly or Type Information. Illegi,ble Submittals Will Be Returned As Incomplete. DATE: July 25 , 2018 PERMIT NO. f,,...Yf c9 :{ 00~02--(to be filled in by DWR) A. WELL TYPE TO BE CONSTRUCTED OR OPERATED B. C. (1) (2) ___ Air Injection Well ...................................... Complete sections B-F, K, N ___ Aquifer Test Well ....................................... Complete sections B-F, K, N (3) ___ Passive Injection System ............................... Complete sections B-F, H-N (4) X Small-Scale Injection Operation ...................... Complete sections B-~CEIVED/NCDEQ/OWR (5) __ Pilot Test.. ............................................... Complete sections B-N AUG 2 9 2018 (6) ___ Tracer Injection Well ................................... Complete sections B-~ . ater O~ahty Regional Operations Sectio STATUS OF WELL OWNER: Business/Organization n WELL OWNER -State name of entity and name of person delegated authority to sign on behalf of the business or agency: Name: Robert Gant, Gant Oil Com pany Mailing Address: 5177 Main Street City: Walkertown State:_ NC_ Zip Code: 27051-0068 County: Forsy th Day Tele No.: (336 ) 595-2152 Cell No.: NA EMAIL Address: __ ~N~A=---------Fax No.: NA UICI In Situ Remed. Notification (Revised 3/2/2015) Page I D. PROPERTY OWNER (if different than well owner) Name: -----'A-"s=s=a=d =E=lkh=o=u,,,rv.,_,.'-'5'"""'B=oy""'z"-"'C""'it~g=-o -"o"-w=n=e=d"""b.,_y--'K=o=u=r..,_v"""an=d"""L~o=k=a=-s =P~ro=p=e=rt'-'-v--'L=L=C~------- Mailing Address: ----=3"'-50=2=-M=e=ad=o .... w-'---"G=le=n_,__C=o=urt=-=---------------------- City: Clemmons State: _NC_ Zip Code:~2~7~0 =12=----__ County: Fors yth Day Tele No.: ____ N.....,__A=-------------Cell No.: (336 ) 624-9290 EMAIL Address: ___ a=s=s=ad=e=lkh=o=u'--'-rv-'--'@=gm==a=il=.c~o=m~--FaxNo.: ___ N....,,._A~------- E. PROJECT CONTACT -Person who can answer technical questions about the proposed injection project. Name: ---~B,,_,ru=ce=---"T.,,_ea,.,s.,.e'------------------------------ Mailing Address: -----=2 ,,_8 _,_Am""""'i'-'..Jl)'----' S=tr=e=e=t.....,S=u=it=e_,,,2,_,_A..__ __________________ _ City: Amherst State: MA_ Zip Code: 01002 County: Hampshire Day Tele No.: (413 ) 835-4355 Cell No.: (413 ) 875-5896 EMAIL Address: ___ b~t~ea=s~e@~.r=am~bo~l~l.~co~m~----Fax No.: __ ___,_N,.._A..__ ______ _ F. PHYSICAL LOCATION OF WELL SITE (1) Physical Address: --~5"-'0~0=0~O~l=d ---'W-'-'a=lk=e=rt=o~wn==-=R=o=a=d'----------------- County: Fors h City: Winston-Salem (2) Geographic Coordinates: St te: NC Zip ypde: 27105 _ Latitude**: J(:; ()°1 d-'1 ( f/U)IVI, L/11;.;J;; j-~ Longitude**: 8 DD Ii! 1.-::t" 5 g,U,,«-r~ Reference Datum: J Accuracy: __ Method of Collection:. ________ _ **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume:~6~.4~0~0 ____ square feet Land surface area ofinj. well network: 400 square feet (S 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: 6.25% (must be S 5% of plume for pilot test injections) H. INJECTION ZONE MAPS -Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. UIC/In Situ Remed. Notification (Revised 3/2/20 I 5) Page 2 I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES -Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration of injection over time. A 10% aqueous solution ofBioavailable Absorbent Media (BAM) shall be in jected under pressure at ei ght direct push technolo gy (DPT) locations with each boring to receive u p to 250 eallons. Similarly. a 5% a queous solution of PermeOx® Ultra shall be injected under pressure at four DPT locations with each boring to receive u p to 100 gallons. Immediate! followin g each injection. the DPT borehole will be plugg ed with h drated bentonite chi ps from the bottom to to p. To prevent da yli ghting, subs eq uent DPT in jections will occur at o pp osite corners of the planned grid (see attached fi gures ). This procedure will provide more time for the h ydrated bentonite to set u p and permanentlv seal the o pen DPT boreholes. The actual volume of BAM and PermeOx® Ultra (calcium peroxide) injected will be empiricall determined based on its acce ptance b y the surrounding saprolite soil matrix. The dis persion of the BAM and PermeOx® Ultra solutions is expected to occur via the same fracture network that the li gh t non-aq ueous phase li quid (LNAPL ) mi gr ated through. To assist in the migr ation of the BAM solution, vacuum extraction will be used simultaneously durine: the in jection event. The g oal of the BAM and PermeOx® Ultra in jections is to reduce free product thickness to< 1/8 inch in site monitoring wells. The BAM will begin to absorb LNAPL once in jected throu l!h its hi cl1 abso rp tion ca pacitv created b v the honev comb pore structure. The purp ose of the PermeOx® Ultra is to enhance the BAM absorption and dis persion efficienc y. A ggr essive fluid/va por recovery (AFVR) will occur durin g the in jection event to enhance treatment dis persion as well as recover LNAPL. if present. Additional in jection and AFVR events ma be performed. should LNAPL persist followin g the first injection event. J. INJECT ANTS -Provide a MSDS and the following for each injectant. Attach additional sheets if necessary. NOTE: Approved injectants (tracers and remediation additives) can be found online at http://portal.ncdenr.org/weblwqlapslgwpro. All other substances must be reviewed by the Division of Public Health, Department of Health and Human Services. Contact the UIC Program for more info (919-807-6496). lnjectant: ______ B_io_a_v_a_il_a_bl_e_A_bs_o_r_b_en_t_M_e_d_ia_(~B_AM_~)~------------- Volume ofinjectant: A pproximately 2 ,000 gallons. Actual volume will be em piricallv determined based on acce ptance ofsurroundim1 cla /silt matrix. Concentration at point of injection: ___ l""'0"""o/c""'o""'a=q""u=e=ous=-s=o=l=ut=i=on=-------------- Percent ifin a mixture with other injectants: NA Injectant: PermeOx® Ultra Volume ofinjectant: A pproximatel v 400 gallons. Actual volume will be em piricallv determined based on acceptance of surrounding clay/silt matrix. Concentration at point of injection: 5% a queous solution Percent if in a mixture with other injectants: NA UICl!n Situ Remed. Notification (Revised 3/2/2015) Page3 K. WELL CONSTRUCTION DATA (1) Number of injection wells: 12 DPT borinri s Proposed ___ O~ __ Existing (2) Provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following: (a) well type as permanent, direct-push, or subsurface distribution system (infiltration gallery) (b) depth below land surface of grout, screen, and casing intervals ( c) well contractor name and certification number -to be determined The remedial treatments shall be injected directly into soil via Oeoprobe at depths corresponding to the zone of contamination (i.e. 25-40 feet) and soil permeability. Treatment injections may occur at existing wells in the event the DPT injection of treatment solutions is not accepted by the soil formation. The total treatment volume into the existing site wells, within the treatment area, will be the same as that proposed for DPT into soil. L. SCHEDULES-Briefly describe the schedule for well construction and injection activities. Week 1 -Utilitv clearance; Week 2 -BAM/PermeOx® Ultra in jection with simultaneous AFVR event; Week 6 -LNAPL gaugim! and OW monitorin g: Week 10 -LNAPL au •in and OW monitorin · Week 14 -LNAPL gam?in g and OW monitorin g: M. MONITORING PLAN -Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchauter 02L result from the injection activity. The dispersion of BAM shall be monitored b the evidence of black suspension in nearbv monitoring and/or remedial wells , and clear sight tubes positioned on each of the AFVR extraction hoses. Additionallv. three groundwater monitoring events will be conducted monthlv . as warranted after the injection event. UIC/Jn Situ Remed. Notification (Revised 3/2/2015) Page4 N. SIGNATURE OF APPLICANT AND PROPERTY OWNER APPLICANT: "1 hereby certtifi; under penalty of law, that ! am familiar with the information submitted in this document and till attachments thereto and that, based on my ingot?), of those individuals immediately responsible for obtaining said information, 1 believe that she infarr►tation is true, accurate and complete. 1 am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. l agree to construct, operate, maintain, repair, and if applicable, abandon the injection well an all related appttrter ces in tic yrtrdalIce with !{ft+l NCC,4C 02C O2QtRules. " Signature of Applicant Russell Kemp Print or Type Full Name PROPERTY OWNER {if the propert} is not owned b) the ermit appiicantp "As owner of the property an which the injection wells. are to be constructed and operated, 1 hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (1 S A NCAC 02C . na rm t .. , "Owner" means any person who holds the fee or other property rights in the welt being constructed. A well is real property and its construction on land shall be deerned to vest ownership in the land owner, in the absence of contrary agreement in writing, Assad EIkhour Signature of Property Owner (it different from applicant) Print or Type Full Fame k An access ureenterrr between the applicant and property owner may be submitted in lieu of a signature on this farm Submit the completed notification package to: DWR - UIC Program. 1636 Mail Service Center Raleigh, NC 27699-1636 feiephone: (919) 807.6464 L1C11n Situ Remed, Notification (Revised 3a12015) Page 5 Former Gant Station #831 5000 Old Walkertown Road, Winston-Salem, North Carolina Number of Type Injection Borings 8 Direct-Push 4 Direct-Push Notes: ft. bgs -feet below ground surface BAM -bioavailable absorbent media HD ENGINEERS Drilling Contractor To Be Determined To Be Determined Boring Dia. Target Depth lnjectant Solution (inches) (ft. bgs) 2 25 -35 10% BAM -- 2 25-35 5% PermeOx Ultra Volume/Boring (gals .) 250 100 -l RE U5 ENGINEERS -3 280 r-' 2Q nnn OLD W ALKERTOM ROAD EW-4 O 0 0 o w o >=Nv -z O O 0 0 • RW-6 0 0 0 Proposed DPT Injection Boring Not To Scale January 2017 EPH C9-C18 Concentration (ug/i) • 900,000 • 25,000 10,000 • 4,000 • 1,000 LEGEND GROUNDWATER CONTOUR (feel arm!) PROPERTY BOUNDARY (APPROXIMATE) • MONITORING WELL • RECOVERY WELL +}F OEEP INJECTION WELL EPH Fractions C9-C18 (January 2017) and Proposed DPT Injection Boring Locations FORMER GANT STATION #831 5000 OLD WALKERTON RD, WINSTON-SALEM, NC FIGURE 1 Former UST Grove Former Pump Island 0 ,m--..r= - _. a - t..._. - 10 i s1W-25 EsIW-1 40 50 0 DIW-1 SIW-2D SIW-3 January 2017 EPH C9-G1B Con cenuadonCu9►k1 • 900.000 • 25,000 10000 • 4,000 • 1,000 EW-1 EW-3 EW-2 AP Proposed DPT Injection Boring 10 20 Distance (feet) 30 40 town 2016 er RE US ENGINEERS Cross Section of EPH Fractions C9-C18 (January 2017) and Proposed DPT Injection Boring Locations FORMER GANT STATION #831 5000 OLD WALKERTON RD, WINSTON-SALEM, NC FIGURE 2 72.6 72.8 73.0 RE US ENGINEERS Not To Scale ® Proposed OPT Injection Boring d'3 &13 t3 LEGEND GROUNCFNATER ccNTaluR nes ows• PROPERTY E*..e..CARY (APPFOWNrE F..ChlTORN 3'AE.J. DEEP IVECTON ?.EL Potentiometric Surface Map (August 7, 2017) and Proposed DPT Injection Boring Locations FORMER GANT STATION D631 5cDa OLD WALKERTON RD, VI NSTON-SALEM. NC FIGURE 3 SDS Safety Data Sheet Section I Chemical Product and Company Identification Product Name Synonyms CAS Number DAM HAM -MILLED 7440-44-0 Active Ingredients Pyrolyzed Cellulosic Material Recommended Use Soil Stabilization, Remedial Activities Restrictions on Use None Formulated by ORIN Technologies, LLC Address 405 Investment Court, Verona, WI 53593 USA Emergency Phone Number 8 AM-5PM CST: 608-838-6699 5 PM -8 AM CST, Weekends, Holidays: 262-821-7024 Section II Hazard(s) Identification Signal Word Warning Hazard Statements Precautionary Statements - Preventian Precautionary Statement — Response May cause Respiratory Irritation Ma) form combustible dust concentrations in air Do not brcaathe dust, fume, gas Wash thoroughly after handling Use only outdoors or in a well -ventilated area Wear cloves, eve, respiratory protection, face protection, and protective clothing IF ON SKIN — Wash with plenty of soap and water IF INHALED — Remove victim to fresh air and keep at rest position comfortable for breathing. IF IN EYES —Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do- Continue Rinsing Call a POISON CENTER or doctor if you feel unwell If skin irritation occurs: Get medical advice or attention. If eye irritation persists: Get medical advice or attention, If respiratory irritation persists: Get medical advice or attention. Take off contaminated clothing and wash before reuse. Storage Store in a well ventilated place. Keep container tightly closed. Store in a secure manner. Exposure Limits Synergistic Products Sensitization/Irritancy: CarcinogenicitylTeratogenicityl Mntagenicity/Reproductive Effects: ND ND ND None Known Section III Composition and Information on Ingredients Chemical Name CAS# wtlwt % Carbon (Wood Derived) 7440-44-00 85-95 (dry basis) Minerals (Wood Derived) N/A 5-10 (dry basis) Water 7780-20-0 10-30% Hazardous Ingredients: NONE Section IV First Aid Measures Skin Eyes Inhalation Ingestion Prolonged contact with skin may result in slight irritation/redness in sensitive individuals. Seek medical attention if persists. Wash with soap and water. Not expected to be harmful under normal conditions of use. May irritate the eyes and cause watering and redness in sensitive individuals. Rinse thoroug hl y with plenty of water to remove forei i;n bodies. Seek medical attention if persists. Inhalation of dust may irritate nose, throat, and lungs. May aggravate pre-existing conditions. Remove affected person to fresh air. Seek medical attention if persists. If suffering gastrointestinal discomfort, treat symptomatically. Do not ingest. Section V Fire-Fighting Measures Flammability This product should not come into contact with naked flames. Means of Extinguishing Foam, Water Spray, CO2, Dry Chemical, Advice for Fire Fighters Wear self-contained breathing apparatus for firefighting if necessary Flashpoint NA Auto-Ignition Temperature ND UEL NA TDG Flammability Class ND LEL NA Hazardous Combustion Products NA Section VI Accidental Release Measures Personal Precautions, Protective Equipment, Emergency Procedures Environmental Precautions Methods and materials for Containment and Cleanu p Reference for other sections Avoid dust formation. Avoid breathing vapors, mist, or gas. For personal protection, see Section 8 No specific environmental precautions required. Sweep up and shovel. Keep in suitable, closed containers for disposal. For disposal, see section 13. Section VII Handling and Storage Engineering Controls Ventilate Leak or Spill Procedure Sweep up into suitable container. Prevent entry into waterways. Handling Procedures and Equipment Avoid direct and prolonged contact with skin Storage Requirements Store in a cool, well ventilated, dry place Section VIII Exposure Controls/Personal Protection Personal Protective Equipment Respiratory: Eyes: Gloves: Proper dust masks should be worn if prolonged use of this product is expected. Use type N95 dust masks for nuisance levels. Use respirators and components tested and approved under a ppro priate 2.ovemment standards !NIOSH J. Use of safety glasses recommended to avoid contact with eyes (NIOSH). Use of gloves recommended to avoid direct skin contact. Section IX Physical and Chemical Properties Physical State Solid Odor and Appearance Slightly earthy odor. Brown or black solid particles Odor Threshold NOA Specific Gravity 1.5-2.1 for solid matrix, Evaporation NDA bulk densi ry varies. Rate Vapor Pressure NOA Vapor Density NDA Density Varies Boiling Point NA Freezing Point NDA pH 7-9.5 May form Flammability combustible Explosive Properties Dust Explosion dust Kst=32 +/-30% St 1 (solid, gas) concentrations Barm/s Class in air Water Solubility Not soluble Auto Ignition Temp. NDA Relative NDA Density Partition Coefficient NOA Decomposition NDA Viscosity NDA Tem p . Section x Stability and Reactivity Chemical Stability: Stable Incompatibility; Strong acids, alkalis, and oxidizing agents. Conditions of Reactivity: NA Hazardous Decomposition Strong oxidizers such as ozone, liquid oxygen, chlorine, permanganate, etc. may result in rapid Products: combustion. Avoid contact with Strome acids. Section XI Toxicological Information No Data Available To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Section XII Ecological Information No Data Available Section XIII Disposal Considerations Disposal Sweep, vacuum or shovel material into labeled container. if at all possible, reuse product. Keep out of an bodies of water. Section XIV Transport Information Shipping Information Not regulated (DOT) The information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof. The information and recommendations are supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. En no event will OR1N Technologies, LLC, or any of its agents be responsible for damages of any nature whatsoever resulting from the use of or reliance upon the information and recommendations_ No representations or warranties, either expressed or implied, of merchantability, fitness, or a particular purpose or of any other nature are made here under with respect to information or the product to which information refers_ Preparation Date: July, 2018 MAR Reason for Revision: Updated Field Values SAFETY DATA SHEET PermeOx® Ultra SOS # : 1305-79-9-2 Revision date: 2015-04-21 Format: NA Version 1 PeroxyChem 1. PRODUCTAND COMPANY IDENTIFICATION Product Identifier Product Name Other means of identification CAS -No Perme0x® Ultra 1305-79-9 Recommended use of the chemical and restrictions on use Recommended Use: Restrictions on Use: Manufacturer/Supplier Emergency telephone number Environmental applications Use as recommended by the label. PeroxyChem LLC 2005 Market Street Suite 3200 Philadelphia, PA 19103 Phone: +1 267/ 422-2400 (General Information) E-Mail: sdsinfo[ peroxychem_com For leak, fire, spill or accident emergencies, call; 1 800 / 424 9300 (CHEMTREC - U.S.A.) 1 7031527 3887 (CHEMTREC - Collect - All Other Countries) 1 303/ 389-1409 (Medical - U.S. - Call Collect) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Serious eye damage/eye irritation Specific target organ toxicity (single exposure) Oxidizing Solids Category 1 Category 3 Category 2 GHS Label etementsjggluding.gr$cajtippary statements EMERGENCY OVERVIEW Danger Hazard Statements H318 - Causes serious eye damage Page 1 / 8 PernieOx® Ultra SDS # : 1305-79-9-2 Revision date: 2015-04-21 Version 1 H335 - May cause respiratory irritation 11272 - May intensify fire; oxidizer Precautionary Statements - Prevention P260 - Wear eye protection/ face protection P261 - Avoid breathing dust. P271 - Use only outdoors or in a well -ventilated area P210 - Keep away from heat P220 - Keep/Store away from clothing/combustible materials P221 - Take any precaution to avoid mixing with combustibles Precautionary Statements - Response P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P304 + P340 - IF INHALED Remove person to fresh air and keep comfortable for breathing P312 - Call a POISON CENTER or doctor if you feel unwell P370 + P378 - In case of fire: Use water spray for extinction Precautionary Statements - Storage P403 - Store in a well -ventilated place Precautionary Statements - Disposal P501 - Dispose of contents/ container to an approved waste disposal plant Hazards not otherwise classified t_HNOCY. No hazards not otherwise classified were identified. Other Information Reacts with moisture to liberate oxygen Unknown acute toxicity 0% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS -No 1 Weight % Calcium Peroxide 1305-79-9 1 >75 Calcium Hydroxide 1305-62-0 <25 Synonyms are provided in Section 1 4. FIRST AID MEASURES Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids intermittently. Consult a physician. Skin Contact Wash off with soap and water. Get medical attention if irritation develops and persists. Inhalation Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial Page 2 / 8 PermeOx® Ultra Ingestion Most important symptoms and effects, both acute and delayed Indication of immediate medical attention and special treatment needed, if necessary SDS # : 1305-79-9-2 Revision date: 2015-04-21 Version t respiration. If breathing difficulty or discomfort occurs and persists, obtain medical attention. Rinse mouth with water and afterwards drink. plenty of water or milk. Do not induce vomiting or give anything by mouth to an unconscious person. Call a poison control center or doctor immediately for treatment advice. Never give anything by mouth to an unconscious person. Corneal lesions and irreversible damage if contact with the eyes Treat symptomatically 5. FIREFIGHTING MEASURES Suitable Extinguishing Media Unsuitable extinguishing media Specific Hazards Arising from the Chemical Explosion data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Protective equipment and precautions for firefighters Flood with water. Dry chemical. Foam. Decomposes under fire conditions to release oxygen that intensifies The fire Not sensitive, Not sensitive. As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Move containers from fire area if you can do it without risk. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Other Environmental Precautions Methods for Containment Methods for cleaning up Avoid contact with the skin and the eyes. Avoid dust formation. Ensure adequate ventilation. For personal protection see Section 8. For further clean-up instructions, call PeroxyChem Emergency Hotline number listed in Section 1 "Product and Company identification" above. Prevent material from entering into soil, ditches, sewers, waterways, and/or groundwater. See Section 12, Ecological Information for more detailed information. Vacuum or shovel waste into a drum and label contents for disposal. Do not return product to the original storage container/tank due to risk of decomposition. Keep combustibles (wood, paper, oil, etc) away from spilled material. After cleaning, Flush away traces with water. Do not flush powdered material to sewer; Runoff to sewer may create fire or explosion hazard. Handling Storage Incompatible products 7.'HANDLING AND STORAGE Avoid contact with skin and eyes. Ensure adequate ventilation. In case of insufficient ventilation, wear suitable respiratory equipment if release of airborne dust is expected. If compounded with organics or combustible materials be sure to exclude moisture. Keep tightly closed in a dry and cool place. Keep away from heat and sources of ignition i.e., steam pipes, radiant heaters, hot air vents or welding sparks. Reacts with moisture. Keep container tightly closed. Heavy metals. Combustible materials. B. EXPOSURE CONTROLS/PERSONAL PROTECTION' Control parameters Page 3 / 8 PermeOx® Ultra SAS # : 1305-79-9-2 Revision date: 2015-04-21 Version 1 Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH Mexico Calcium Hydroxide 1305-62-0 TWA: 5 mg/m3 TWA: 15 mglm3 TWA: 5 rn /m3 TWA: 5 mglm3 Mexico: TWA 5 mglm3 Chemical name British Columbia Quebec Ontario TWAEV Alberta Calcium Hydroxide 1305-62-0 TWA: 5 mglm3 TWA: 5 mglm3 TWA: 5 mglm3 TWA: 5 mglm3 Appropriate engineering controls Engineering measures Ensure adequate ventilation. Individual protection measures such askersona[Erotective equipment Eye/Face Protection Skin and Body Protection Hand Protection Respiratory Protection Hygiene measures General information For dust, splash, mist or spray exposure, Wear chemical protective goggles. Wear suitable protective clothing. Protective shoes or boots. Rubber/latex/neoprene or other suitable chemical resistant gloves. Wash the outside of gloves with soap and water prior to removal. Inspect regularly for leaks. For dust, splash, mist or spray exposures wear a filtering mask. Clean water, preferably an eyewash station and a safety shower, should be available for washing in case of eye or skin contamination. Handle in accordance with good industrial hygiene and safety practice_ If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers. These recommendations apply to the product as supplied. 9. PHYSICAL AND CHEMICAL PROPERTIES information on basic physical and chemical properties Appearance Physical State Color Odor Odor threshold pH Melting point/freezing point Boiling Point/Range Flash point Evaporation Rate Flammability (solid, gas) Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Density Specific gravity Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive properties Granules Solid White to off white odorless Not applicable (1% solution) 10.5 -11.8 co 25'C Decomposes on heating @ —275 °C No information available Not flammable No information available Substance does not burn but will support combustion Not applicable No information No information 2.g2 glcm3 2.92 slightly soluble No information No information Product is not s 275 °C No information No information No information available available available available elf -ignitable. available (Solid) available available Page 4 / 8 PermeOx® Ultra Oxidizing properties Molecular weight Bulk density Strong oxidizer 72.8 (CaO2) 45 Ibfcu ft (loose) SDS # : 13O5.79-9-2 Revision date: 2015-04-21 Version 1 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Possibility of Hazardous Reactions Hazardous polymerization Conditions to avoid Incompatible materials Strong oxidizer. Stable under recommended storage conditions. Decomposition can occur on exposure to heat or moisture. Oxidizable material can be ignited by grinding and may become explosive. Hazardous polymerization does not occur Heat (decomposes at 275 °C). Humid air. Grinding with organics. Heavy metals. Combustible materials. Hazardous Decomposition Products Oxygen which supports combustion. Calcium Oxides. 11, TOXICOLOGICAL INFORMATION Product Information Unknown acute toxicity LD50 Oral LD50 Dermal LC50 Inhalation Serious eye damage/eye irritation Skin corrosion/irritation Sensitization Information on toxicological effects Symptoms O% of the mixture consists of ingredient(s) of unknown toxicity • 5 glkg (rat) > ID g/kg (rat) > 17 mg/L 1 hr (rat) Corrosive. Risk of serious damage to eyes. Non -irritating (rabbit). May cause skin irritation in susceptible persons. No information available. Dust is irritating eyes, nose, throat, and lungs. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic toxicity Carcinogenicity Mutagenicity Reproductive toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard No known effect. There are no known carcinogenic chemicals in this product. This product is not recognized as rnutagenic by Research Agencies This product is not recognized as reprotox by Research Agencies. May cause respiratory irritation. No information available. No information available. 12. ECOLQGICAL INFORMATION Ecotoxicity Page 5 1 8 PermeOx® Ultra Ecotvxicity effects Persistence and degradability Sioaccumulation Mobility Other Adverse Effects SOS # : 1305-79-9-2 Revision date: 2015-04-21 Version 1 The environmental impact of this product has not been fully investigated Biodegradability does not pertain to inorganic substances Does not bioaccumulate. No information available. None known. Waste disposal methods US EPA Waste Number Contaminated Packaging 13. DISPOSAL CONSIDERATIONS 1 This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Dispose of in accordance with local regulations. D001 Empty remaining contents. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. ,TRANSPORT INFORMATION DOT UN/ID no Proper Shipping Name Hazard class Packing Group TDG UNIID no Proper Shipping Name Hazard class Packing Group ICAO/IATA IMDG/IMO UN/ID no Proper Shipping Name Hazard class Packing Group ADR/RID UN/ID no Proper Shipping Name Hazard class Packing Group OTHER INFORMATION 1457 CALCIUM PEROXIDE MIXTURE 5.1 11 1457 CALCIUM PEROXIDE MIXTURE 5.1 !t Oxidizers are prohibited from aircraft. 1457 CALCIUM PEROXIDE MIXTURE 5.1 I1 UN 1457 OXIDIZING SOLID, n.o.s. (Calcium Peroxide) 5.1 it This material is shipped in 25 lb. plastic pails, and 30 lb. and 100 [b. fiber drums. 15. REGULATORY INFORMATION U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Page 618 ParmaOx® Ultra SDS # : 1305-79-9-2 Revision date: 2045-04-21 Version 1 SARA 3111312 Hazard Categories Acute health hazard Yes Chronic health hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA International Inventories Component TSCA (United States) DSL (Canada) EINECSIEL INCS (Europe) ENCS (Japan) China (IECSC) KECL (Korea) PICCS (Phlilpptnes ) AICS (Australia) NZloC (New Zealand) Calcium Peroxide 1305-79-9 ( >75 ) X X X X X X X X X Calcium Hydroxide 1305-62-0 , <25 ) X X X X X X X X X CANADA WHMIS Hazard Class C - Oxidizing materials E - Corrosive material 16. OTHER INFORMATION NFPA Health Hazards 2 Flammability 0 Stability 1 Special Hazards OX HMIS Health Hazards 2 Flammability 0 PhysicaI hazard 0 Special precautions J NFPA/HMIS Ratings Legend Revision date: Revision note Special Hazards: OX = Oxidizer ProtectionnJ (Safety goggles, gloves, apron, combination dust and vapor respirator) 2015-04-21 Initial Release Disclaimer PeroxyChem believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specified product designated and may not be applicable where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use are beyond the control of PeroxyChem, PeroxyChem expressly disclaims any and all liability as to arty results obtained or arising from any use of the products or reliance on such information. Prepared By: PeroxyChem PERMEOX - Trademark of PeroxyChem Page 7F8 PermeOx® Ultra © 2015 PeroxyChem. All Rights Reserved. End of Safety Data Sheet Page 8 / 8 SDS # : 1305-79-9-2 Revision date: 2015-04-21 Version 1