HomeMy WebLinkAboutWI0300328_DEEMED FILES_20160815Pe~mit; :.m.be~ WI0300328
Program Category
Deemed Ground Water
Permit Type
Injection Deemed Tracer Well
Primary Reviewer
shristi.shrestha
Coastal SWRule
Permitted Flow
Facility
Facility Name
Akzo Nobel
Location Address
485 Cedar Spring
Salisbury
Owner
Owner Name
NC
Akzonobel Surface Chemistry LLC
Dates/Events
Orig Issue
8/15/2016
App Received
8/10/2016
Regulated Activities
Groundwater remediation
Outfall
Waterbody Name
28147
Draft Initiated
Scheduled
Issuance Public Notice
Central Files: APS SWP
8/15/2016
Permit Tracking Slip
Status
Active
Version
1.00
Project Type
New Project
Permit Classification
Individual
Permit Contact Affiliation
Brian Owen
485 Cedar Springs Rd
Salisbury NC 28147
Major/Minor
Minor
Facility Contact Affiliation
Owner Type
Non-Government
Owner Affiliation
Jerry McMurray
485 Cedar Springs Rd
Salisbury
Region
Mooresville
County
Rowan
NC
Issue
8/15/2016
Effective
8/15/2016
28147
Expiration
Requested /Received Events
Streamlndex Number Current Class Subbasin
5hrestha, Shristi R
From: 5hrestha, Shristi R
Sent: Monday, August 15, 2016 3:02 PM
To: 'thornas.darby@arcadis.com'; 'brian.owen@akzonebel.com'
Cc: Rogers, Michael; Basinger, Corey; Pitner, Andrew; Watson, Edward M
Subject: WI0300328 NOI Akzo Nobel surface chemistry LLC
Thank you for submitting the Notice of Intent to Construct or Operate Injection Welts (N01) for the above referenced
site.
Please remember to submit the following regarding this injection activity:
1) Well Construction Records (GW-1) and Abandonment Records (GW-30) when completed. Please provide copies of
the GW-1s and CAW-30s if not already submitted (originals go the address printed on the form). NOTE: Direct
push or Geoprobe wells are considered wells and require construction (GW-1) and abandonment forms (GW-
30). If welt construction/abandonment information is the same for the wells, only one form needs to be
completed- just indicate total number of injection points in the Comments/Remarks section of form. These farms
can be found on our website at
http : / 'deq. nc. ov/about/divisions/water-resources/water-resources-cue rm itsiwastewate r-b ra n ch/ ground-wate r-
n rotection/g-rou n d-water-reoorti ng-forms
2) injection Event Records (1ER). Ail injections, including air and passive systems require an IER. The IER can be
modified for air sparge wells (e.g., air flow 'continuous' for date or rate of injection, etc.).
You can scan and send these forms directly to me at Shristi.shresthaE1nedenroov or via regular mail to address
below. When submitting the above forms, you wiil need to enter the nine -digit alpha -numeric number on the form
(i.e., WIOXXXXXX) that has been assigned to the injection activity at this site. This notification has been given the
deemed permit number WID300328. This number is also referenced in the subject line of this email. You may if you
wish, scan and send back as attachments in reply to this email, as it will already have the assigned deemed permit
number in the subject line.
Thank you for your cooperation,
Shristi
Shristi R. Shrestha
Hydrogeologist
Water Quality Regional Operations Section
Animal Feeding Operations & Groundwater Protection Branch
North Carolina Department of Environmental Quality
919 807-6406 office
sh risti_shrestha te.,ncdenr.00v
512N. Salisbury Street
1636 Mail Service Center
Raleigh, NC 27699 1 636
�Nothrng re=
Email correspondence to and from this address is subject to the
Ninrfh i' irr 1ifia Pr,hlir P rnrrk 1 a1AF annf m571/ i]R dlerfingcre tr third r-I r ia.c
Shrestha, Shristi R
From: Shrestha, Shristi R
Sent: Monday, August 15, 2016 3:04 PM
To: Basinger, Corey; Pitner, Andrew; Watson, Edward M
Cc: Rogers, Michael
Subject WI0300328 NCI Akio Nobel Surface chemistry LLC
Attachments: NOI.pdf; Maps.pdf
Please find the attached NOI,
Shristi
Shristi R. Shrestha
Hydrogeologist
Water Quality Regional Operations Section
Animal Feeding Operations & Groundwater Protection Branch
North Carolina Department of Environmental Quality
919 807-6406 office
s h ri sti. s hresth a; n cden r. c ov
512N_ Salisbury Street
1636 Mail Service Center
Raleigh, NC 27699 1636
Nc4t ,nr1 CfyFT�C�'fr'•�
Erne correspondence to and from this address is sribject to the
North Carolina Public Records Law and may be disclosed to third parries.
IMF C/ADIS , tiuiltassets
NOTICE OF INTENT TO OPERATE
INJECTION WELLS
Former National Starch & Chemical Company
Superfund Site
Salisbury, Rowan County, North Carolina
August 2016
~ A RCADIS I ir.a:ltancy
DWR -UIC Program
1636 Mail Service Center
Raleigh, NC 27699
Subject:
Notice of Intent to Operate Injection Wells
RECEIVr::'1'NCOEQ/OWR
AUG O 9 2016
Water Quality kegional
Operations Section
Former National Starch & Chemical Company Superfund Site
Salisbury, Rowan County, North Carolina
To Whom It May Concern :
On behalf of Akzo Nobel Surface Chemistry LLC (AkzoNobel}, Arcadis is pleased
to provide the Notice of Intent to Operate Injection Wells for an in-well tracer test
at the Former National Starch & Chemical Company Superfund Site located at
485 Cedar Springs Road in Salisbury, North Carolina.
Should you have any further comments regarding this project, please contact me
at 864.987.3918 or via email at Thomas.Darby@arcadis.com.
Sincerely,
Arcadis G&M of North Carolina, Inc.
Thomas Darby 11, P.G.
Senior Hydrogeologist
Copies :
David Mattison, NCDEQ (Electronic)
Brett Whittleton , P.E., Akzo Nobel (Electronic)
Brian Owen, Akzo Nobel (Electronic}
Angela Dohl, Akzo Nobel (Electronic}
Chris Fleming, Akzo Nobel (Electronic)
John Miller, Akzo Nobel (Electronic}
George Yanku, Akzo Nobel (Electronic)
David Simons, Akzo Nobel (Electronic)
Encl osures:
Notice of Intent to Operate Injection Wells
Arcadis G&M of North Carolina,
Inc.
801 Corporate Center Drive
Suite 300
Raleigh
North Carolina 27607
Tel 919 8541282
Fax 919 854 5448
ENVIRONMENTAL
Date:
August 8, 2016
Contact:
Thomas Darby
Phone :
864.987 .3918
Email :
Thomas.darby@arcadis .com
Our ref:
B0060013.0019
ARCADIS G&M of North Carolina , Inc .
NC Engineering License# C-1869
NC Surveying License# C-1869
Page :
1/1
North Carolina Department of Environmental Quality-Division of Water Resources
NOTIFICATION OF INTENT (NOi) TO CONSTRUCT OR OPERATE INJECTION WELLS
The following are ''permitted by rule" and do not require an individual permit when constructed in accordance
with the rules of ISA NCAC 02C .0200. This fo rm shall be submitted at least 2 WEEKS prior to in iection.
AQUIFER TEST WELLS 0 5A NCAC 02c .0220 )
These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics.
IN SITU REMEDIATION 0 5A NCAC 02C .0225) or TRACER WELLS 0 5A NCAC 02C .0229):
1) Passive Iniection S vstems -In-well delivery systems to diffuse injectants into the subsurface. Examples include
ORC socks, iSOC systems, and other gas infusion methods.
2) Small-Scale In jection Op erations -Injection wells located within a land surface area not to exceed 10,000
square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required
for test or treatment areas exceeding 10,000 square feet.
3) Pilot Tests -Preliminary studies conducted for the purpose of evaluating the technical feasibility of a
remediation strategy in order to develop a full scale remediation plan for future implementation, and where the
surface area of the injection zone wells are located within an area that does not exceed five percent of the land
surface above the known extent of groundwater contamination. An individual permit shall be required to conduct
more than one pilot test on any separate groundwater contaminant plume.
4) Air Injection Wells -Used to inject ambient air to enhance in-situ treatment of soil or groundwater.
Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete. .
RECE\VEOINCDEQ/D 1SR
DATE: Augu st2,2016 PERMIT NO. (N.1.Q:!)00 3 '18 (tobefilledinbyDWR) .
AUG O 9 2016
A. WELL TYPE TO BE CONSTRUCTED OR OPERATED Water Quaiily Regional
Operations Section
(1) ___ Air Injection Well ...................................... Complete sections B through F, K, N
(2) ---'Aquifer Test Well ....................................... Complete sections B through F, K, N
(3)
(4)
(5)
(6)
___ Passive Injection System ............................... Complete sections B through F, H-N
___ Small-Scale Injection Operation ...................... Complete sections B through N
___ Pilot Test. ................................................ Complete sections B through N
X Tracer Injection Well ................................... Complete sections B through N
B. STATUS OF WELL OWNER: Business/Organization
C. WELL OWNER(S) -State name of Business/Agency, and Name and Title of person delegated authority to
sign on behalfof the business or agency:
Name(s): Brian Owen: Akzo Nobel Surface Chemis try LLC
Mailing Address: 485 Cedar S prin gs Road
City: Salisb ury State:~ Zip Code: 28147 County:-'R~ow~an~-----
Day Tele No.: 704-663-1731 CellNo.: ____ _
EMAIL Address: Brian.Owen(ti akzonobel.com Fax No.:
Deemed Permitted GW Remediation NOi Rev. 3-1-2016 Page 1
D. PROPERTY OWNER(S) (if different than well owner)
Name and Title: ---------------------------------
Company Name ---------------------------------
Mailing Address:---------------------------------
City: ____________ _ State: __ Zip Code: _______ County: _____ _
Day Tele No.: ____________ _ Cell No.: __________ _
EMAIL Address: _____________ _ Fax No.: ___________ _
E. PROJECT CONT ACT (Typically Environmental Engineering Firm)
Name and Title: Thomas Darb y
Company Name: ___ =-:Ar=c=a=d=is=-G=&=M=--co=f'--=N-'---o=rt=h"'--=C-=ar"--'o=h=·n =a'------------------------
Mailing Address: --~3~0~P~a=te=-w~o=-o=d"'"D=-"'ri"""v"""e'""'. S=-u=i=te"""1""'5"""5 ___________________ _
City: Greenville State: ~ Zip Code:~2~96~1=5 ____ County: Greenville
Day Tele No.: 864-987-3908 Cell No.: __________ _
EMAIL Address: Thomas.Darb y@ arcadis.com FaxNo.: ___________ _
F. PHYSICAL LOCATION OF WELL SITE
(1) Facility Name & Address: Akzo Nobel Surface Chemis try LLC . 485 Cedar Springs Road. Unit A
City: Salisb ury County: Rowan Zip Code:.-=2=8-=--14-'-'7 __ _
(2) Geographic Coordinates: Latitude**: ___ 0 __ __" or 35.626897 °. _____ _
Longitude**: ___ 0 ____ " or 80.54228°. ______ _
Reference Datum: GCS WGS 1984 Accuracy:. _______ _
Method of Collection:.--'S"-'urv=...!.-"'-ey,__ ______________ _
**FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY
BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES.
G. TREATMENT AREA
Land surface area of contaminant plume: Not A pp licable square feet
Land surface area ofinj. well network: Not A pplicable square feet(::: 10,000 ft 2 for small-scale injections)
Percent of contaminant plume area to be treated: Not A pp licable(must be::: 5% of plume for pilot test injections)
H. INJECTION ZONE MAPS -Attach the following to the notification.
A pp licable Figures included in Attachment 1
(1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the
contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and
proposed injection wells; and
(2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical
extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed
monitoring wells, and existing and proposed injection wells.
(3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing
and proposed wells.
Deemed Permitted GW Remediation NOI Rev. 3-1-2016 Page2
I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES -Provide a brief narrative regarding the
purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration
of injection over time.
Fluorescein d ye will be mixed into NS-31 in an interval from 120 to 150 feet below ground surface b y usin2. a
packer to isolate that s pecific interval. After the dye is mixed in the water column , samples will be collected on
a predetermined schedule to evaluate the wash-out of the d ye from the borehole to determine groundwater flux
throu gh the borehole over the isolated interval.
J. APPROVED INJECT ANTS -Provide a MSDS for each injectant. Attach additional sheets if necessary.
NOTE: Only injectants approved by the NC Division of Public Health, Department of Health and Human
Services can be injected. Approved injectants can be found online at h trp ://deg .nc.gov/about/divisions/water-
resources/water-resources-permits/wastewater-branch/ ground-water-protection/ irround-water-approved-in j ectants.
All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919-
807-6496).
Injectant: Fluorescein dye-SDS included in Attachment 2
Volume of injectant:~15=c.....;~=arn=s~--------------------------
Concentration at point of injection: The target concentration is 10 m g/l
Percent if in a mixture with other injectants: _____________________ _
Injectant:
Volumeofinjectant: _____________________________ _
Concentration at point of injection:
Percent if in a mixture with other injectants: ____________________ _
Injectant:
Volume ofinjectant: _____________________________ _
Concentration at point of injection:
Percent if in a mixture with other injectants:
K. WELL CONSTRUCTION DATA
(1) Number of injection wells: _____ Proposed ___ l~ __ Existing (provide GW-ls)
(2) For Proposed wells or Existing wells not having GW-ls, provide well construction details for each
injection well in a diagram or table format. A single diagram or line in a table can be used for
multiple wells with the sarne construction details. Well construction details shall include the
following (indicate if construction is proposed or as-built):
(a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery
(b) Depth below land surface of casing, each grout type and depth, screen, and sand pack
( c) Well contractor narne and certification number
Deemed Permitted GW Remediation NOI Rev. 3-1-2016 Page3
Well Information included in Attachment 3
L. SCHEDULES — Briefly describe the schedule for well construction and injection activities.
The tracer- test is scheduled for September 6, 2016 and is anticipated to last for approximately 4 weeks,
M. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine
if violations of groundwater quality standards specified in Subchapter 021. result from the injection activity.
After the fluorescein dye is mixed into NS-31 samples will be collected according to the schedule defined below
Days 1 to 3: Twice daily
Days 4 to 7: Once daily
Week 2: Twice per week
Week 3 and 4: Once per week
In addition groundwater monitoring (including sampIing ofNS 31) is completed annually on -site
N. SIGNATURE OF APPLICANT AND PROPERTY OWNER
APPLICANT: "1 hereby certlf ; under penalty of Taw, that I ant familiar with the information submitted in this
document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible
for obtaining said information, I believe that the information is true accurate and complete. I am aware that
there are sign cant penalties, including the passibility of fines and imprisonment far submitting false
information. I agree to construct, operate, maintain, repair, and if applicable abandon the injection well and
all rotated appal at, ces in accordance with the I ,ir3 NC't C 02C Q20Q Rides."
€gnature of Applicant Print or Type Fail Name and Title
PROPERTY OWNER (if the property, is pot owned bathe permit applicant):
"As owner of the property on which the injection wells) are to be constructed and operated, I hereby consent to
allow the applicant to construct each injection well as outlined ill this application and agree that it shall be the
responsibility of the applicant to ensure that the infection wells) conform to the Well Construction Standards
(15A NCAC 02C .0200). "
"Owner" means any person who holds the fee or other property rights in the well being constructed. A well
is real property and its construction on land shall be deemed to vest ownership in the land owner, in the
absence of contrary agreement in writing.
Signature* of Property Owner (if different from applicant) Print or Type Full Name gad Title
*An access agreement between the applicant and property owner may be submitted in lieu ofa signature on this form_
Submit the completed notification package to:
DWR — UIC Program
1636 Mail Service Center
Raleigh, NC 27699-1636
Telephone: (919) 807-6464
Deemed Permitted OW Rerediation NO1 Rev. 3-1-2016 Page 4
ATTACHMENT 1
injection Zone Maps
ATTACHMENT 2
Fluorescein SDS
t,
SIG MA -A LDRICH sigml!-aldrich. com
. -.
SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION
1.1 Product identifiers
Product name
Product Number
Brand
GAS-No.
Fluorescein
F7505
Sigma
2321-07-5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company Sigma-Aldrich
Telephone
Fax
1.4 Emergency telephone number
Emergency Phone #
2. HAZARDS IDENTIFICATION
3050 Spruce Street
SAINT LOUIS MO 63103
USA
+1 800-325-5832
+1 800-325-5052
(314) 776-6555
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Eye irritation (Category 2A), H319
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram
Signal word
Hazard statement(s)
H319
Precautionary statement( s)
P264
P280
Warning
Causes serious eye irritation.
Wash skin thoroughly after handling.
Wear protective gloves/ eye protection/ face protection.
Version 3.6
Revision Date 06/17/2014
Print Date 08/05/2016
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
2.3 Hazards not otherwise classified (HNOC} or not covered by GHS -none
COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Synonyms : Acid Yellow 73
Sigma -F7505 Page 1 of 7
Formula
Molecular Weight
CAS-No.
EC-No.
H d azar ous components
Component
C20H12O5
332.31 g/mol
2321-07-5
219-031-8
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid
I Classification
I Eve lrrit. 2A; H319
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1 Description of first aid measures
General advice
I Concentration
I -
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician .
If swallowed
Never give anything by mouth to an unconscious person . Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available
5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate
ventilation. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains .
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections
For disposal see section 13.
Sigma -F7505 Page 2 of 7
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Sigma -F7505
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved
under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:
EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It
should not be construed as offering an approval for any specific use scenario.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the concentration and
amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level
protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Page 3 of 7
Control of environmental exposure
Do not let product enter drains .
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
9.2
a) Appearance Form: powder
Colour: red
b} Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing 320 °C (608 °F)
point
f) Initial boiling point and no data available
boiling range
g) Flash point no data available
h} Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
I) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n-no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available
10. ST ABILITY AND REACTIVITY
10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizing agents
Sigma -F7505 Page 4 of 7
10.6 Hazardous decomposition products
Other decomposition products -no da.ta available
In the event of fire: see section 5
.1. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
Inhalation: no data available
Dermal: no data available
LD50 Intravenous -mouse -300 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
ACGIH:
NTP:
OSHA:
No component of this product present at levels greater than or equal to 0.1 % is identified as
probable, possible or confirmed human carcinogen by IARC.
No component of this product present at levels greater than or equal to 0 .1 % is identified as a
carcinogen or potential carcinogen by ACGIH.
No component of this product present at levels greater than or equal to 0 .1 % is identified as a
known or anticipated carcinogen by NTP.
No component of this product present at levels greater than or equal to 0 .1 % is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity -single exposure
no data available
Specific target organ toxicity -repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: LM5075000
To the best of our knowledge, the chemical, physical , and toxicological properties have not been thoroughly
investigated.
Liver -Irregularities -Based on Human Evidence
Liver -Irregularities -Based on Human Evidence
12. ECOLOGICAL INFORMATION
12.1 Toxicity
no data available
-12.2 Persistence and degradabllity
no data available
Sigma • F7505 Page 5 of 7
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
no data available
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
15. REGULATORY INFORMATION
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title 111, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title Ill, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid
New Jersey Right To Know Components
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid
California Prop. 65 Components
CAS-No.
2321-07-5
CAS-No.
2321-07-5
Revision Date
Revision Date
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
Sigma -F7505 Page 6 of 7
Eye lrrit.
H319
HMIS Rating
Health hazard:
Eye irritation
Causes serious eye irritation.
2
Chronic Health Hazard : *
Flammability:
Physical Hazard
NFPA Rating
Health hazard:
Fire Hazard:
Reactivity Hazard:
Further information
0
0
1
0
0
Copyright 2014 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a
guide. The information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the
product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling
or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing
slip for additional terms and conditions of sale.
Preparation Information
Sigma-Aldrich Corporation
Product Safety -Americas Region
1-800-521-8956
Version: 3.6
Sigma -F7505
Revision Date: 06/17/2014 Print Date: 08/05/2016
Page 7 of 7
ATTACl w
I EN 3
Well Construction Data
---------
/ ,
/
/
/
/
Attachment 3
Monitoring Well Details
Former National Starch Chemical Company Superfund Site
485 Cedar Springs Road, Salisbury. NC
la[CAD 15 henlfaue�a r
Ground Top of
Well ID Type Elev. (ft Casing Elev
MSL) (ft MSL)
North
Coordinate
East Coordinate
(y) feet (x) feet
Casing Open Hole Interval
Well Diameter Depth
(inches) (ft bgs) Top (ft bgs) Bottom (ft bgs)
NS 31 Permanent 709.16 712,73 686649.764 1541702.887 3 80.00 80 150
NOTE: Horizontiai and Vertical datum based upon benchmark N.C.G.S. Monument "ABEX'
NAD 83 (2001) & NAVD 88
N = 689,253.39' E = 1,549,321.49' EL. 783.28'
MSL = Mean Sea Level
bgs = below ground surface
Page 1 of 1
Arcadis G&M of North Carolina,
Inc.
801 Corporate Center Drive
Suite 300
Raleigh
North Carolina 27607
Tel 919 854 1282
Fax 919 854 5448
Page:
1/1
DWR – UIC Program
1636 Mail Service Center
Raleigh, NC 27699
Subject:
Notice of Intent to Operate Injection Wells
Former National Starch & Chemical Company Superfund Site
Salisbury, Rowan County, North Carolina
To Whom It May Concern:
On behalf of Akzo Nobel Surface Chemistry LLC (AkzoNobel), Arcadis is pleased
to provide the Notice of Intent to Operate Injection Wells for an in-well tracer test
at the Former National Starch & Chemical Company Superfund Site located at
485 Cedar Springs Road in Salisbury, North Carolina.
Should you have any further comments regarding this project, please contact me
at 864.987.3918 or via email at Thomas.Darby@arcadis.com.
Sincerely,
Arcadis G&M of North Carolina, Inc.
Thomas Darby II, P.G.
Senior Hydrogeologist
Copies:
David Mattison, NCDEQ (Electronic)
Brett Whittleton, P.E., Akzo Nobel (Electronic)
Brian Owen, Akzo Nobel (Electronic)
Angela Dohl, Akzo Nobel (Electronic)
Chris Fleming, Akzo Nobel (Electronic)
John Miller, Akzo Nobel (Electronic)
George Yanku, Akzo Nobel (Electronic)
David Simons, Akzo Nobel (Electronic)
Enclosures:
Notice of Intent to Operate Injection Wells
ENVIRONMENTAL
Date:
August 8, 2016
Contact:
Thomas Darby
Phone:
864.987.3918
Email:
Thomas.darby@arcadis.com
Our ref:
B0060013.0019
ARCADIS G&M of North Carolina, Inc.
NC Engineering License # C-1869
NC Surveying License # C-1869
ARCADIS I
Oesign&Consultancy
fornatural and
built assets
Deemed Permitted GW Remediation NOI Rev. 3-1-2016 Page 1
North Carolina Department of Environmental Quality – Division of Water Resources
Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete.
DATE: August 2, 2016 PERMIT NO. (to be filled in by DWR)
A. WELL TYPE TO BE CONSTRUCTED OR OPERATED
(1) Air Injection Well……………………………..…Complete sections B through F, K, N
(2) Aquifer Test Well……………………….………..Complete sections B through F, K, N
(3) Passive Injection System…………………..……..Complete sections B through F, H -N
(4) Small-Scale Injection Operation………………….Complete sections B through N
(5) Pilot Test………………………………………….Complete sections B through N
(6) X Tracer Injection Well………………………….….Complete sections B through N
B. STATUS OF WELL OWNER: Business/Organization
C. WELL OWNER(S) – State name of Business/Agency, and Name and Title of person delegated authority to
sign on behalf of the business or agency:
Name(s): Brian Owen; Akzo Nobel Surface Chemistry LLC
Mailing Address: 485 Cedar Springs Road
City: Salisbury State: __NC_ Zip Code: 28147 County: Rowan
Day Tele No.: 704-663-1731 Cell No.:
EMAIL Address: Brian.Owen@akzonobel.com Fax No.:
NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS
The following are “permitted by rule” and do not require an individual permit when constructed in accordance
with the rules of 15A NCAC 02C .0200. This form shall be submitted at least 2 WEEKS prior to injection.
AQUIFER TEST WELLS (15A NCAC 02C .0220)
These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics.
IN SITU REMEDIATION (15A NCAC 02C .0225) or TRACER WELLS (15A NCAC 02C .0229):
1) Passive Injection Systems - In-well delivery systems to diffuse injectants into the subsurface. Examples include
ORC socks, iSOC systems, and other gas infusion methods.
2) Small-Scale Injection Operations – Injection wells located within a land surface area not to exceed 10,000
square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required
for test or treatment areas exceeding 10,000 square feet.
3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a
remediation strategy in order to develop a full scale remediation plan for future implementation, and where the
surface area of the injection zone wells are located within an area that does not exceed five percent of the land
surface above the known extent of groundwater contamination. An individual permit shall be required to conduct
more than one pilot test on any separate groundwater contaminant plume.
4) Air Injection Wells - Used to inject ambient air to enhance in-situ treatment of soil or groundwater.
Deemed Permitted GW Remediation NOI Rev. 3-1-2016 Page 2
D. PROPERTY OWNER(S) (if different than well owner)
Name and Title:
Company Name
Mailing Address:
City: State: ____ Zip Code: County:
Day Tele No.: Cell No.:
EMAIL Address: Fax No.:
E. PROJECT CONTACT (Typically Environmental Engineering Firm)
Name and Title: Thomas Darby
Company Name: Arcadis G&M of North Carolina
Mailing Address: 30 Patewood Drive, Suite155
City: Greenville State: _SC_ Zip Code: 29615 County: Greenville
Day Tele No.: 864-987-3908 Cell No.:
EMAIL Address: Thomas.Darby@arcadis.com Fax No.:
F. PHYSICAL LOCATION OF WELL SITE
(1) Facility Name & Address: Akzo Nobel Surface Chemistry LLC, 485 Cedar Springs Road, Unit A
City: Salisbury County: Rowan Zip Code: 28147
(2) Geographic Coordinates: Latitude**: o ′ ″ or 35.626897 o.
Longitude**: o ′ ″ or 80.54228o.
Reference Datum: GCS WGS 1984 Accuracy:
Method of Collection: Survey
**FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY
BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES.
G. TREATMENT AREA
Land surface area of contaminant plume: Not Applicable square feet
Land surface area of inj. well network: Not Applicable square feet (< 10,000 ft2 for small-scale injections)
Percent of contaminant plume area to be treated: Not Applicable(must be < 5% of plume for pilot test injections)
H. INJECTION ZONE MAPS – Attach the following to the notification.
Applicable Figures included in Attachment 1
(1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the
contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and
proposed injection wells; and
(2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical
extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed
monitoring wells, and existing and proposed injection wells.
(3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing
and proposed wells.
Deemed Permitted GW Remediation NOI Rev. 3-1-2016 Page 3
I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES – Provide a brief narrative regarding the
purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration
of injection over time. Fluorescein dye will be mixed into NS-31 in an interval from 120 to 150 feet below ground surface by using a
packer to isolate that specific interval. After the dye is mixed in the water column, samples will be collected on
a predetermined schedule to evaluate the wash-out of the dye from the borehole to determine groundwater flux
through the borehole over the isolated interval.
J. APPROVED INJECTANTS – Provide a MSDS for each injectant. Attach additional sheets if necessary.
NOTE: Only injectants approved by the NC Division of Public Health, Department of Health and Human
Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water-
resources/water-resources-permits/wastewater-branch/ground-water-protection/ground-water-approved-injectants.
All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919-
807-6496).
Injectant: Fluorescein dye– SDS included in Attachment 2
Volume of injectant: 15 grams
Concentration at point of injection: The target concentration is 10 mg/l
Percent if in a mixture with other injectants:
Injectant:
Volume of injectant:
Concentration at point of injection:
Percent if in a mixture with other injectants:
Injectant:
Volume of injectant:
Concentration at point of injection:
Percent if in a mixture with other injectants:
K. WELL CONSTRUCTION DATA
(1) Number of injection wells: Proposed 1 Existing (provide GW-1s)
(2) For Proposed wells or Existing wells not having GW-1s, provide well construction details for each
injection well in a diagram or table format. A single diagram or line in a table can be used for
multiple wells with the same construction details. Well construction details shall include the
following (indicate if construction is proposed or as-built):
(a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery
(b) Depth below land surface of casing, each grout type and depth, screen, and sand pack
(c) Well contractor name and certification number
Well Information included in Attachment 3
L. SCHEDULES — Briefly describe the schedule for well construction and injection activities.
The tracer test is scheduled for September 6, 2016 and is anticipated to last for approximately 4 weeks.
M. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine
if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity.
After the fluorescein dve is mixed into NS-31 samples will be collected according to the schedule defined below
Days 1 to 3: Twice daily
Days 4 to 7: Once daily
Week 2: Twice per week
Week 3 and 4: Once per week
In addition, groundwater monitoring (including sampling of NS-31) is completed annually on -site
N. SIGNATURE OF APPLICANT AND PROPERTY OWNER
APPLICANT: "1 hereby cerlify, under penalty of law, that I am familiar with the information submitted in this
document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible
for obtaining said infor nation, I believe that the information is true, accurate and complete. I am aware that
there are significant penalties, including the possibility of fines and imprisonment, for submitting false
information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and
all rkited appurt al ces in accordance with the 15A NCAC 02C 0200 Rules."
ignature of Applicant
lek
(,)co
Print or Type Full Name and Title
PROPERTY OWNER (if the property is not owned by the permit applicant):
"As otvner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to
allow the applicant to construct each injection well as outlined in this application and agree that it shall be the
responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards
(15A NCAC 02C .0200)."
"Owner" means any person who holds the fee or other property rights in the well being constructed, A well
is real property and its construction on land shall be deemed to vest ownership in the land owner, in the
absence of contrary agreement in writing.
Signature* of Property Owner (if different from applicant) Print or Type Full Name and Title
*An access agreement between the applicant and property owner may be submitted in lieu nfa signature an this form.
Submit the completed notification package to:
DWR — UIC Program
1636 Mail Service Center
Raleigh, NC 27699-1636
Telephone: (919) 807-6464
Deemed Permitted GW Remediation NOl Rev. 3-]-2016 Page 4
ATTACHMENT 1
Injection Zone Maps
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NS-57
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NS-55
NS-45
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NS-34
NS-32
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NS-28
NS-27
NS-26
NS-25
NS-22
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P-03
P-04
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NS-30
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EX-02
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NS-24
NS-47
SW-13
SW-11
SW-10
SW-09
SE-13
SE-11
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SG-6
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NS-73
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NS-21A
EX-11
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\\Scottsdale-AZ\Project\NSCC\GIS\Projects\Tracer test work plan 08-2016\Figure 2 site plan.mxd 8/4/2016LEGEND
SITE PLAN
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NOTES
· Aerial photo source: ESRI World Imagery.
Access road
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NATIONAL STARCH & CHEMICAL COMPANY
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SALISBURY, NORTH CAROLINA
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\\Scottsdale-AZ\Project\NSCC\GIS\Projects\SMR 2015\Figure 10 site-wide GWECs shallow bedrock 12-2015.mxd 5/19/2016LEGEND
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
POTENTIOMETRIC SURFACE OF THESHALLOW BEDROCK AQUIFER, DECEMBER 2015
FIGURE
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NOTES
· Aerial photo source: ESRI World Imagery.
· Depths to groundwater were measured on 12/10/2015.
· Potentiometric surface elevations are expressed in
feet above mean sea level (ft amsl).
· * = potentiometric surface elevation measurement is
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· NM = potentiometric surface elevation not measured.
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\\Scottsdale-AZ\Project\NSCC\GIS\Projects\SMR 2015\Figure 14 OU1 bedrock 12-2015 (12DCA).mxd 5/19/2016LEGEND
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
OU1 1,2-DICHLOROETHANE PLUME IN THEBEDROCK AQUIFER, DECEMBER 2015
FIGURE
A1-3
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Scale: 1" = 250'
Feet
0 125 250
Groundwater monitoring well (shallow bedrock)
NOTES
· Aerial photo source: ESRI World Imagery.
· Wells were sampled from 12/1/2015 to 12/9/2015.
· Concentrations are expressed in micrograms per liter (µg/L).
· OU1 Record of Decision (ROD) performance standard for
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· U = analyte not detected above indicated reporting limit.
· J = concentration is estimated.
· B = analyte was detected in associated method blank.
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\\Scottsdale-AZ\Project\NSCC\GIS\Projects\SMR 2015\Figure 15 OU1 bedrock 12-2015 (12DCP).mxd 5/19/2016LEGEND
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
OU1 1,2-DICHLOROPROPANE PLUME IN THEBEDROCK AQUIFER, DECEMBER 2015
FIGURE
A1-4
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Scale: 1" = 250'
Feet
0 125 250
Groundwater monitoring well (shallow bedrock)
NOTES
· Aerial photo source: ESRI World Imagery.
· Wells were sampled from 12/1/2015 to 12/9/2015.
· Concentrations are expressed in micrograms per liter (µg/L).
· OU1 Record of Decision (ROD) performance standard for
1,2-dichloropropane = 6 µg/L.
· U = analyte not detected above indicated reporting limit.
· J = concentration is estimated.
· B = analyte was detected in associated method blank.
!(
Site boundary
Stream
1,2-DICHLOROPROPANECONCENTRATIONS (µg/L)
>6 and <100
>100 and <1,000
>1,000 and <10,000
Groundwater monitoring well (deep bedrock)!(
Un
n
a
m
e
d
T
r
i
b
u
t
a
r
y
Keystone Dr
Hollybrook CtSteven Dr 61001,0006
6
100
1,000
D
"
~ARCADIS
!(
!(
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!(
!(
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!(
!(
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!(
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!(
!(
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!(!(
!(
!(
!(
NS-75
NS
NS-74
NS
NS-21
28
EX-10
80
EX-05
NS
EX-04
13
EX-03
17
EX-01
NS
NS-58B
42
NS-21A
NS
EX-11
260
EX-09
250
EX-07
110
NS-73
2,000
NS-57
9,400
NS-31
4,300
NS-28
2,300
EX-08
9,200
NS-56
12,000
NS-26
53,000
NS-17
49,000
NS-72
200,000
NS-58A
43,000
NS-72A
180,000
NS-15
< 10 U
NS-29
< 25 U
EX-02
< 10 U NS-55
< 5.0 U
NS-32
< 5.0 U
NS-27
< 5.0 U
NS-25
< 5.0 U
NS-22
< 5.0 U
NS-30
< 5.0 U
NS-31B
< 5.0 U
\\Scottsdale-AZ\Project\NSCC\GIS\Projects\SMR 2015\Figure 16 OU1 bedrock 12-2015 (ACE).mxd 5/19/2016LEGEND
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
OU1 ACETONE PLUME IN THEBEDROCK AQUIFER, DECEMBER 2015
FIGURE
A1-5
£
Scale: 1" = 250'
Feet
0 125 250
Groundwater monitoring well (shallow bedrock)
NOTES
· Aerial photo source: ESRI World Imagery.
· Wells were sampled from 12/1/2015 to 12/9/2015.
· Concentrations are expressed in micrograms per liter (µg/L).
· OU1 Record of Decision (ROD) performance standard for
acetone = 3,500 µg/L.
· U = analyte not detected above indicated reporting limit.
· J = concentration is estimated.
· B = analyte was detected in associated method blank.
· * = concentration is considered to be anomalous
and is not used in contouring.
!(
Site boundary
Stream
ACETONECONCENTRATIONS (µg/L)
>3,500 and <6,000
>6,000 and <60,000
>60,000 and <600,000
Groundwater monitoring well (deep bedrock)!(
Un
n
a
m
e
d
T
r
i
b
u
t
a
r
y
Keystone Dr
Hollybrook CtSteven Dr 3,5006,000
6
0
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0
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0 3,5006,0003,500
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5
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~ARCADIS I
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NS-75
NS
NS-74
NS
NS-31
64
NS-15
12
EX-05
NS
EX-03
16
EX-01
NS
NS-73
320
NS-55
410
NS-21A
NSNS-21
1.2
EX-11
840
EX-10
130
NS-29
960
EX-02
550
NS-58B
740
NS-72
1,400
NS-57
8,600
NS-56
3,900
NS-31B
0.51
NS-28
9,000
NS-26
4,600
EX-08
4,900
EX-07
2,400
NS-72A
7,000
NS-58A
3,100
NS-27
0.30 J
NS-17
25,000
EX-09
11,000
EX-04
0.45 J
NS-32
< 0.50 U
NS-25
< 0.50 U
NS-22
< 0.50 U
NS-30
< 0.50 U
\\Scottsdale-AZ\Project\NSCC\GIS\Projects\SMR 2015\Figure 17 OU1 bedrock 12-2015 (TOL).mxd 5/19/2016LEGEND
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
OU1 TOLUENE PLUME IN THEBEDROCK AQUIFER, DECEMBER 2015
FIGURE
A1-6
£
Scale: 1" = 250'
Feet
0 125 250
Groundwater monitoring well (shallow bedrock)
NOTES
· Aerial photo source: ESRI World Imagery.
· Wells were sampled from 12/1/2015 to 12/9/2015.
· Concentrations are expressed in micrograms per liter (µg/L).
· OU1 Record of Decision (ROD) performance standard for
toluene = 2,000 µg/L.
· U = analyte not detected above indicated reporting limit.
· J = concentration is estimated.
· B = analyte was detected in associated method blank.
!(
Site boundary
Stream
TOLUENECONCENTRATIONS (µg/L)
>2,000 and <20,000
Groundwater monitoring well (deep bedrock)!(
Un
n
a
m
e
d
T
r
i
b
u
t
a
r
y
Keystone Dr
Hollybrook CtSteven Dr 2,0002,000D
"
0
~ARCADIS
!(
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NS-75
NS
NS-74
NS
NS-73
90
NS-27
15
NS-22
78
EX-05
NS
EX-04
35
EX-01
NS
NS-32
1.6
NS-31
180
NS-21A
NS
EX-10
210
NS-30
110
EX-03
360
NS-58B
120
NS-58A
180
NS-31B
530
EX-11
18 JNS-57
910 B
NS-55
2,700
NS-28
1,300
NS-21
6,400
EX-07
9.5 J
NS-29
3,200
EX-02
1,300
NS-26
16,000
NS-72
7,900 B
NS-56
6,800 B
NS-72A
9,400 B
NS-17
< 17 U
EX-08
< 16 U
NS-25
< 1.8 U NS-15
< 1.6 U
EX-09
< 170 U
\\Scottsdale-AZ\Project\NSCC\GIS\Projects\SMR 2015\Figure 18 OU1 bedrock 12-2015 (DCEE).mxd 5/19/2016LEGEND
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
OU1 BIS (2-CHLOROETHYL) ETHER PLUME IN THEBEDROCK AQUIFER, DECEMBER 2015
FIGURE
A1-7
£
Scale: 1" = 250'
Feet
0 125 250
Un
n
a
m
e
d
T
r
i
b
u
t
a
r
y
Groundwater monitoring well (shallow bedrock)
NOTES
· Aerial photo source: ESRI World Imagery.
· Wells were sampled from 12/1/2015 to 12/9/2015.
· Concentrations are expressed in micrograms per liter (µg/L).
· OU1 Record of Decision (ROD) performance standard for
bis (2-chloroethyl) ether = 5 µg/L.
· U = analyte not detected above indicated reporting limit.
· J = concentration is estimated.
· B = analyte was detected in associated method blank.
!(
Site boundary
Stream
BIS (2-CHLOROETHYL) ETHERCONCENTRATIONS (µg/L)
>5 and <100
>100 and <1,000
>1,000 and <10,000
>10,000 and <100,000
Keystone Dr
Hollybrook CtSteven Dr
Groundwater monitoring well (deep bedrock)!(51001,00010,0005
1001,00010,000
5
D
"
0
0
~ARCADIS I
!(
!(
!(
!(
!(
!(
!(!(
!(
!(
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!(
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!(
!(!(
!(
!(
!(
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!(
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NS-75
NS
NS-74
NS
NS-31
34
EX-05
NS
EX-01
NS
NS-32
140
NS-21A
NS
NS-31B
230
NS-73
3,000
NS-27
2,300
NS-25
9.9 J
NS-17
6,500
NS-30
1,200
NS-29
2,200
EX-04
4,200
EX-03
8,700
EX-02
7,500
NS-57
22,000
NS-56
30,000
NS-55
39,000
NS-28
44,000
NS-26
27,000
NS-22
14,000
NS-15
13,000
EX-11
39,000
EX-10
58,000
EX-09
33,000
EX-08
52,000
EX-07
36,000
NS-72
170,000
NS-58B
36,000
NS-21
3,800 V
NS-72A
270,000
NS-58A
170,000
\\Scottsdale-AZ\Project\NSCC\GIS\Projects\SMR 2015\Figure 19 OU1 bedrock 12-2015 (MN).mxd 5/19/2016LEGEND
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
OU1 TOTAL MANGANESE PLUME IN THEBEDROCK AQUIFER, DECEMBER 2015
FIGURE
A1-8
£
Scale: 1" = 250'
Feet
0 125 250
Groundwater monitoring well (shallow bedrock)
NOTES
· Aerial photo source: ESRI World Imagery.
· Wells were sampled from 12/1/2015 to 12/9/2015.
· Concentrations are expressed in micrograms per liter (µg/L).
· OU1 Record of Decision (ROD) performance standard for
total manganese = 7,700 µg/L.
· U = analyte not detected above indicated reporting limit.
· J = concentration is estimated.
· B = analyte was detected in associated method blank.
!(
Site boundary
Stream
TOTAL MANGANESECONCENTRATIONS (µg/L)
>7,700 and <77,000
>77,000 and <770,000
Groundwater monitoring well (deep bedrock)!(
Un
n
a
m
e
d
T
r
i
b
u
t
a
r
y
Keystone Dr
Hollybrook CtSteven Dr 7,7007,700
7,70077,00077,0007,700D
"
0
0
~ARCADIS I
Unamed TributaryEX-02NS-29NS-31NS-26EX-08NS-56EX-09NS-21NS-07NS-31ANS-31BNS-22 (Offset)NS-72 ( Offset)NS-72A ( Offset)NS-21ANS-75D e e p B e d r o c k
D e e p B e d r o c k
S h a l l o w B e d r o c k
S h a l l o w B e d r o c k
S a p r o l i t e
S a p r o l i t e
<1.0
<1.0 5.3
5,700
6,500
12,000
110
120
<1.0
<1.0
<10
<2.0
<5.0
<1.0
<1.0
7,600
LINE B - B'1,2-DCA CONCENTRATIONS
FIGURE
A1-9
NATIONAL STARCH & CHEMICAL COMPANY
CEDAR SPRINGS ROAD PLANT
SALISBURY, NORTH CAROLINA
Graphic Scale
Vertical Exaggeration: 5X
0 250 500 Feet
Legend
1,2 -DCA Results - November/December 2015
Water Level - December 2015
Well
1,2-DCA Concentration
5 µg/L
50 µg/L
500 µg/L
5,000 µg/L
Well Screen
Trench
Vertical Fracture
Saprolite
Shallow Bedrock
Weathered Bedrock
Deep Bedrock
!(
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INSET LEGEND
!(MW, Saprolite
!(MW, Shallow Bedrock
!(MW, Deep Bedrock
$+EW, Shallow Bedrock
#0 PZ, Shallow Bedrock
Line B - B'
NOTE:
OU1 ROD performance standard is 5 µg/L for 1,2-DCA
NS-21A not sampled in 2015
CITY:(KNOXVILLE) DIV/GROUP:(ENV/GIS) DB: ssutton LD: PIC: PM: TM: PROJECT: TN000000.0000.00000 PATH: Z:\GISPROJECTS\_ENV\ENV_National_Starch\Arcgis\2016\2015SMR\4_XsectionB.mxd200 400 600 800 1,000 1,200 1,400 1,600 1,800 2,000 2,200 2,400 2,600
825
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~ARCADIS
ATTACHMENT 2
Fluorescein SDS
Sigma - F7505 Page 1 of 7
SIGMA-ALDRICH sigma-aldrich.com
SAFETY DATA SHEET
Version 3.6
Revision Date 06/17/2014
Print Date 08/05/2016
1. PRODUCT AND COMPANY IDENTIFICATION
1.1 Product identifiers
Product name : Fluorescein
Product Number : F7505
Brand : Sigma
CAS-No. : 2321-07-5
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances
1.3 Details of the supplier of the safety data sheet
Company : Sigma-Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103
USA Telephone : +1 800-325-5832
Fax : +1 800-325-5052
1.4 Emergency telephone number
Emergency Phone # : (314) 776-6555
2. HAZARDS IDENTIFICATION
2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Eye irritation (Category 2A), H319
For the full text of the H-Statements mentioned in this Section, see Section 16.
2.2 GHS Label elements, including precautionary statements
Pictogram
Signal word Warning Hazard statement(s)
H319 Causes serious eye irritation. Precautionary statement(s)
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none
3. COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substances
Synonyms : Acid Yellow 73
Sigma - F7505 Page 2 of 7
Formula : C20H12O5
Molecular Weight : 332.31 g/mol
CAS-No. : 2321-07-5
EC-No. : 219-031-8
Hazardous components
Component Classification Concentration
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid
Eye Irrit. 2A; H319 -
For the full text of the H-Statements mentioned in this Section, see Section 16.
4. FIRST AID MEASURES
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
no data available
5. FIREFIGHTING MEASURES
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
no data available
6. ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate
ventilation. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections
For disposal see section 13.
I I
I I
Sigma - F7505 Page 3 of 7
7. HANDLING AND STORAGE
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved
under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method:
EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the
supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an
industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It
should not be construed as offering an approval for any specific use scenario.
Body Protection
impervious clothing, The type of protective equipment must be selected according to the concentration and
amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level
protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Sigma - F7505 Page 4 of 7
Control of environmental exposure
Do not let product enter drains.
9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
a) Appearance Form: powder
Colour: red
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing
point
320 °C (608 °F)
f) Initial boiling point and
boiling range
no data available
g) Flash point no data available
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower
flammability or
explosive limits
no data available
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n-
octanol/water
no data available
p) Auto-ignition
temperature
no data available
q) Decomposition
temperature
no data available
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
9.2 Other safety information
no data available
10. STABILITY AND REACTIVITY
10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
no data available
10.5 Incompatible materials
Strong oxidizing agents
Sigma - F7505 Page 5 of 7
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5
11. TOXICOLOGICAL INFORMATION
11.1 Information on toxicological effects
Acute toxicity
Inhalation: no data available
Dermal: no data available
LD50 Intravenous - mouse - 300 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: LM5075000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated. Liver - Irregularities - Based on Human Evidence
Liver - Irregularities - Based on Human Evidence
12. ECOLOGICAL INFORMATION
12.1 Toxicity
no data available
12.2 Persistence and degradability
no data available
Sigma - F7505 Page 6 of 7
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects no data available
13. DISPOSAL CONSIDERATIONS
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATION
DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
15. REGULATORY INFORMATION
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid
CAS-No.
2321-07-5
Revision Date
New Jersey Right To Know Components
2-(6-Hydroxy-3-oxo-(3H)-xanthen-9-yl)benzoic acid
CAS-No.
2321-07-5
Revision Date
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
16. OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
Sigma - F7505 Page 7 of 7
Eye Irrit. Eye irritation
H319 Causes serious eye irritation.
HMIS Rating
Health hazard: 2
Chronic Health Hazard: *
Flammability: 0
Physical Hazard 0
NFPA Rating
Health hazard: 1
Fire Hazard: 0
Reactivity Hazard: 0
Further information
Copyright 2014 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a
guide. The information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the
product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling
or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing
slip for additional terms and conditions of sale.
Preparation Information
Sigma-Aldrich Corporation
Product Safety – Americas Region
1-800-521-8956 Version: 3.6 Revision Date: 06/17/2014 Print Date: 08/05/2016
ATTACHMENT 3
Well Construction Data
Attachment 3Monitoring Well DetailsFormer National Starch Chemical Company Superfund Site485 Cedar Springs Road, Salisbury, NCNorth CoordinateEast Coordinate(y) feet (x) feetTop (ft bgs) Bottom (ft bgs)NS 31 Permanent 709.16 712.73 686649.764 1541702.887 3 80.00 80150NOTE: Horizontial and Vertical datum based upon benchmark N.C.G.S. Monument "ABEX" NAD 83 (2001) & NAVD 88 N = 689,253.39' E = 1,549,321.49' EL. 783.28' MSL = Mean Sea Level bgs = below ground surface Open Hole IntervalWell Diameter (inches)Well ID TypeGround Elev. (ft MSL)Top of Casing Elev. (ft MSL)Casing Depth (ft bgs) Page 1 of 1