WQ0024508_Monitoring - 03-2021_20210430

Monitoring Report Submittal
............................................................................................................................................
Permit Number #* WQ0024508
Name of Facility:*
Month:* March
Report Information
Carolina Research Center WWTF
Type *
NDMR, NDAR-1, NDAR-2, NDMLR
Confirmation Email Address:*
Name of Submitter:*
Signature:
Date of submittal:
Initial Review
Year:* 2021
Upload Document*
Smith ers_March.pdf 2.59MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-t, NDAR-2, NDMLR, GW-59).
Jessica. [e-mail]
Jessica Mize
jus l oil
Reviewer: Williams, Kendall N
4/30/2021
This will be filled in automatically

Is the project number correct? * WQ0024508
Is the monitoring report r Yes r No
accepted?*
Regional Office * Winston-Salem
Accepted Date: 5/4/2021

FORM: NDMR 05-16 NON -DISCHARGE MONITORING REPORT (NDMR) Page of
Permit No.: W0002450$
Facility Name: Carolina Research Center WWTF
County: Alamance
Month: March
Year: 2021
PPI: 001
Flow Measuring Point: ❑ Influent 2 Effluent ❑ No flow generated
Parameter Monitoring Point: ❑ influent ❑ Effluent ❑ Groundwater Lowering ❑ surface water
Parameter Code 0
50050­y"
00310
00940
1 50060
31616
00610
00825 s
00620
00600,
00400
00665
70300
00530
>
E
o
E
O
°
L
O
V_
G
9
o -
°u.
°
�
w
Im
o
a
am
{p
w
o
:
�w
ot
i°ai-
rn
24-hr
hrs
GPD -
mg/L
mg/L
mg/L
#1100 mL
mg/L
mg/L ,
mg/L
mg/L.-
Sul
mg/4 <
mg/L
mg/L
1
734
2
734
7.02
3
13:03
0.25
:734 " ` :;
- ..-
4
%734
>2.20
5
:,i`734
61
448
8
448
9
12:31
0.25
,.;448
>2.20
10
448
7.09
11
448,'_
121
523 ",::
,
131
523...;
14
0,4 623
.,
15
-523 ....:
16
17
13:40
0.25
`','-523
>2.20
19
523 .:!
7.03
20
378,
21
22
;a378
23
10:06
0.25378
_ .
16126
>
>2.20�
<1.0
107
142
<0.30
_143 "s
28:5
930
15.2
241
378
25378
7.03
26
`378
27
786
28
786
29
786
7777
31
13:13
0.25
u;78B
s . z
>2.20
{i
Average
a W7
��
16.00
#1;126;00 i s
0.00
1.00, :
107.00
142,00;.'
0.00
7 ,14100;
28 50=;
930.00
15 20 :j
Daily Maximum
„`. 86 ,
16.00
126.00`=
0.00
_
-, :1.00 ', . -
107.00
, :1�L2 W0
0.30
143.00,
7.09
l:28.50
930.00
.1520 :=
Daily Minimum...
378., ==
16.00
126:00"
0.00
_ . 1.00,i :
107.00
14200:
0.30
'143.00-r
7.01
28:50 ::
930.00
15.20 .
Sampling Type:
• .Estimate:R
Grab
=; Grab ;:
Grab
Grab -
Grab
`. Grab ` !
Grab
Grab «?
Grab
Grab =
Grab
Grab
Monthly Limit:,000
.;_
-;;_
-
.
Daily Limit
„ ` �:.;.,,
Sample Frequency:
Monthly ,
3 X Year
,' 3 X Year
Per Event
3 X Year
3 X Year
',"if Year
3 X Year
3 X Year
Per Event
3 X Year
3 X Year
3 X Year

FORM: NDMR 05-16 NON -DISCHARGE MONITORING REPORT (NDMR) Page of
Sampling Person(s)
Certified Laboratories
Name: Glenn Price Name: Pace Analytical Services
Name: Name:
Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? IH-Compliant ❑ Non{.ompriant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator In Responsible Charge (ORC) Certification Permittee Certification
ORC: Glenn Price Permittee: Gus Zieske
Certification No.: 987931/20771 Signing Official: Ron Alcorn
Grade: II Phone Number: 336-996-2841 Signing Official's Title: Manager, Avian and Wildlife Toxicology
Has the ORC changed since the previous NDMR? O Yes 2 No Phone Number: 336-376-0141 Permit Expiration: 8/31/2021
Signature Date Signature Date
By this signature, I certify that this repwt is accurrate and complete to the best of my knowledge. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that 0 qualified personnel property gathered and evaluated the information
submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for
gathering the information, the information submitted is, to the best of my knowledge and better, tnm, accurate, and complete. 1 am
aware that there are significant penalties for submitting false inforrnallon, including the possibility of fines and imprisonment for
knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 276994617

2.6
20
21
22
23
24
26 PC 63 Q
26
27
26
29
30 Cl 63 Q
31

FORM: NDAR-1 05-16
NON -DISCHARGE APPLICATION REPORT (NDAR-1)
Page of
Did the application rates exceed the limits in Attachment B of your permit?
Were adequate measures taken to prevent effluent ponding in or runoff from the sites?
Was a suitable vegetative cover maintained on all sites as specified in your permit?
Were all setbacks listed in your permit maintained for every application to each permitted site?
Were all freeboards maintained in accordance with the specified freeboard heights in your permit?
frcompliant ❑ Non -Compliant
ETCompiiant ❑ Non -Compliant
CLimpliant
❑ Non -Compliant
13�6mpliant
❑ NorrCompliant
vompiiartt
❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
tatten. Anacn aaataonai sneets IT necessary.
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Glenn Price
Permittee: Gus Zieske
Certification No.: 987931/20771
Signing Official: Ron Alcorn
Grade: II Phone Number. 336-996-2741
Signing Official's Title: Manager, Avian and Wildlife Toxicology
Has the ORC changed since the previous NDAR-1? ❑ Yes ❑ No
Phone Number: 336-376-0141 Permit Exp.: 8/31/21
R
' z�2
z
Signature Date
Signature Date
By this signature, I certify that this report is accurate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my
inqulry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the
information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant
penalties for submitting false Information, including the possita"Gty of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

Ll
16
17
18
27
28
29,
30
31'

FORM: NDAR-1 05-16
NON -DISCHARGE APPLICATION REPORT (NDAR-1)
Page of
Did the application rates exceed the limits in Attachment B of your permit?
Were adequate measures taken to prevent effluent ponding in or runoff from the sites?
Was a suitable vegetative cover maintained on all sites as specified in your permit?
Were all setbacks listed in your permit maintained for every application to each permitted site?
Were all freeboards maintained in accordance with the specified freeboard heights in your permit?
EBZ&mpliant
❑ Non -Compliant
gK mpliant
❑ Non -Compliant
iTCompliant
❑ Non-Compilant
&1�cwnpliant ❑ Non -Compliant
(d'Compliartt ❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
taKen. Anacn aaamonai sneets n
Operator in Responsible Charge (ORC) Certification
Permittee Certification
ORC: Glenn Price
Permittee` Gus Zieske
Certification No.: 987931/20771
Signing Official: Ron Alcorn
Grade: II Phone Number: 336-996-2741
Signing Official's Title: Manager, Avian and Wildlife Toxicology
Has the ORC changed since the previous NDAR-1? ❑ Yes ❑ No
Phone Number. 336-376-0141 Permit Exp.: 8/31 /21
1/'2t
4 a 2
Signature Date
Signature Date
By this signature, 1 certify that this report is accurate and complete to the best of my knowledge.
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance
with a system designed to assuro that all qualified personnel property gathered and evaluated the information submitted. Based an my
inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the Information, the
information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significard
penalties for submitting false Information, including the possibility of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

FORM: NDMLR 05-16 NON -DISCHARGE MASS LOADING REPORT (NDMLR) Page of
Permit No.: W00024508
Facility Name: Carolina Research Center WWTF
County: Alamance
Month: March
Year: 2021
Field Name:
2
field Name:
3
Field Name:
4
Field Name:
5
Field Name:
6
Area (acres):
0.3
Area (acres):
o 3 _::''' .
Area (acres):
0.5
Area (acres);
0.3
Area (acres):
0.9
Cover Crop:
Cover. Crop:
Cover Crop:
Cover Crop:
Cover Crop:
Load Type:
PAN
Load_Type:
PAN',
Load Type:
PAN
Load Type:
PAN
Load Type:
PAN
Field Loaded?
❑ Yes p NO
Field Loaded?
❑ YES
IQ No
Field Loaded?
❑ YES p NO
Field Loaded?
D YES p NO
Field Loaded?
❑ YES ❑ NO
w
++
t0
wo
E m
3 C.
>Q
c
d°
Q
w �
Of C
aEi
Q> o
0
Q
a a
�+ lE
= °
CJ
°
w a
m
�a °
J
3
a
w�o;
E °i`
3 C:
C
Q°
a
w
Of C -,
a="
`o
Q
a
��
t0
°
°
>
.,�a
^� °
., 3 + J'
w�
E °'
Q
>
C
d -°�
ago
w«
Ci C
`
Q
Q
a
y.°
M
2 °
'EZ
°
> R
� °
J
�
V
w
E�
O ii
e
a°
aw
w
� C
Q`o
Q
a
�,V
M
0
i
°
> a
;,w
3a °
J
7 '
"rz
Q
U
wv
E 3'
C
> Q
Q°
aw
w:
°t C
u"
> o
QU
Q
a
>,°
t0
= °
° J
2
> a
«A
30 °
J
UE'
Qo.
Month
gal
0
mg/L
Ibs/ac
Ibs/ac
gal;
mg/L-
Ibs/ac
lbs/ac
gal
mg/L
Ibs/ac
Ibs/ac
gal
mg/L
Ibslac
Ibslac
gal
mg1L
Ibstac
Ibs/ac
April
44.4
0.0
0.0
14,000,1
:44€4
4.9
4.9
5,600
44.4
4.1
4.1
0 :
444
0.0 -
0.0
2,800
44.4
1.2
1.2
May
0
44.4
0.0
0.0
0 '
44A
0.0
4.9
8,800
44.4
6.5
10.7
6,000
44.4
7.4
7.4
14,400
44.4
5.9
7.1
June
0
44.4
0.0
0.0
6,000 ;;
44i4
7.4 ":
-12.3.
7,200
44.4
5.3
16.0
6,000
44.4
7.4
14.8
0
44.4
0.0
7.1
July
0
44.4
0.0
0.0
0.,. ,
492'
0.0
12.3:
10,400
49.2
8.5
24.5
0 :
44.4.
0.0­'.
14.8
6,000
49.2
2.7
9.8
August
0
49.2
0.0
0.0
6,000
49.2
8.2 "
'20.6
0
1 49.2
0.0
1 24.5
6,000
49.2
8.2
1 23.0-
3,200
49.2
1.5
11.3
September
0
49.2
0.0
0.0
0,.
49.2
O.Q.w
.20.5,;
0
49.2
0.0
24.5
0
49.2
0.0
23.0;
3.200
49.2
1.5
12.7
October
0
49.2
0.0
0.0
0..
49.2.
0`.0._.
20,5":
0
49.2
0.0
24.5
5,920
49;2,
81
31.1.
3,200
49.2
1.5
14.2
November
0
20.6
0.0
0.0
.0 € ,
20:67
1,200
20.6
0.4
24.9
-- 0:1
20:6...
0.0 l�
31.1
0
20.6
0.0
14.2
December
1 0
20.6
0.0
0.0
3,600 _
20.6'
2.1 ....22.6''
2,800
20.6
1.0
25.9
'0'
20.6:
' 0.0--
311
81000
20.6
1.5
15.7
January
0
20.6
0.0
0.0
0; , .
'20.6'.
0.0 :;
=22.6 <
0
20.6
0.0
25.9
6,000
206
3.4 _
'34.6
6,400
20.6
1.2
16.9
February
0
20.6
0.0
0.0
6,000 ,,..a,
20 6:1i'
3 4
?.26.0
10,400
20.6
3.6
29.5
O� ��".
20.6
0.0 ,.;:
, =34.6 ',;
0
20.6
0.0
16.9
March
0
64.1
0.0
0.0
.0 `:
841
0.0
26,0`?'
0
64.1
0.0
29.5
0:
64.1 -
0.0,'_
` 34.6'
7,600
64.1
4.5
21.5
12 Month Floating PAN Load
Ibslacl :
0.0
26.0
29.5
Annual PAN Load Limit
Ibslac! :
159
159 `
159
159 :'
159

FORM: NDMLR 05-16 NON -DISCHARGE MASS LOADING REPORT (NDMLR) Page of
Did the mass loading rates exceed the limits in Attachment B of your permit?
iJ Compliant ❑ Non -Compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
action(s) taken. Attach additional sheets if necessary.
Operator In Responsible Charge (ORC) Certification
Permittee Certification
ORC: Glenn Price
Permittee:
Gus Zieske
Certification Number: 987931/20771
Signing Official:
Ron Alcorn
Grade: II Phone Number. 336-996-2741
Signing Official's Title: Manager, Avian and Wildlife Toxicology
Has the ORC changed since the previous NDMLR? ❑ Yes 0 No
Phone No.: 336-376-0141 Permit Exp.: 8/31/21
Signature Date
Signature Date
By this signature, I certify that this report is grate and complete to the best of my knowledge.
I certify, under penalty of taw, that this document and all attachments were prepared under my direction or supervision In
accordance with a system designed to assure that all qualified personnel property gathered and evaluated the
information submitted. Based on my Inquiry of the person or persons who manage the system, or those persons directly
responsible for gathering the information, the information submitted Is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 276994617

FORM: NDMLR 05-16 NON -DISCHARGE MASS LOADING REPORT (NDMLR) Page of
Permit No.: WQ0024508
Facility Name: Carolina Research Center WWTF
County: Alamance
Month: March
Year: 2021
Field Name:
7
Fleld.Name:
i :'
Field Name:
Field Name:
Field Name:
Area (acres):
0.3
.. , Area (acres):
Area (acres):
Area {acres}:
Area (acres):
Cover Crop:
Cover Crop
Cover Crop:
cover Crop..
Cover Crop:
Load Type:
PAN
Load Type:
Load Type:
;Load Type:
Load Type:
Field Loaded?
O YES ❑ No
-Field Loaded?
❑:YES
,: 0 W'
Field Loaded?
0 YES 0 No
Field Loaded?
❑ YES, [7_No
Field Loaded?
D YES ❑ No
°
0 0
Z c omnc
d v
z
o
E z
�
'
>
�o.
oCL
ma
Ea
>
oc
�
O
a
OO
o
m�
c
�
O
o
O
c
O
�
V ,i;
E .m
>> Q
cLc
Q o
O
°oc
.j
O
.mym-o
a
-0
V
Month
gal
0
mglL
Ibslac
Ibslac
gaC: k.
mglL='
Ibslac
Ibslac
gal
mglL
Ibslac
ibslac
gal
mglL
ibslac
Ibs/ac
gal
mg1L
ibslac
ibslac
April
44.4
0.0
0.0,
May
6,000
44.4
7.4
7.4
7777777
77" .
June
6,000
44.4
7.4
14.8
July
0
49.2
0.0
1 4 . 8
"..... ' . _,,..
.:77
August
9,200
49.2
12.6
27.4
September
0
49.2
0.0
27.4
October
0
49.2
0.0
27.4;i
,
November
0
20.6
0.0
27.4
,..
December
6,000
20.6
3.4
30.8�.
January
0
20.6
0.0
30.8
_
February 1
0
20.6
0.0
30.8
March
6,000
64.1
10.7
1 41.5t
12 Month Floating PAN Load
Ibslac!
41.5
Oal, r
0.0
0:0
0.0
Annual PAN Load Limit
Ibslac! :
159

FORM: NDMLR 05-16 NON -DISCHARGE MASS LOADING REPORT (NDMLR) Page of
Did the mass loading rates exceed the limits in Attachment B of your permit? 94spfiant ❑Non -compliant
If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective
Men. Hrtacn aaantonai sneers n
Operator in Responsible Charge (ORC) Certification 11 Permittee Certification 1
ORC: Glenn Price
Certification Number: 987931/20771
Grade: 11 Phone Number: 336-996-2741
Has the ORC changed since the previous NDMLR? 0 Yes [21 No
Signature
By this signature, I certify that this report is accurrate and complete to the best of my knowledge.
Pennittee. Gus Zieske
Signing Official:
Ron Alcorn
Signing Official's Title: Manager, Avian and Wildlife Toxicology
Phone No.: 336-376-0141 Permit Exp.: 8/31/21
:/ '73Q 7-
Date Signature Date
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the
Information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly
responsible for gathering the Information, the information submitted Is, to the best of my knowledge and belief, bm,
accurate, and complete. I am aware that there ate significant penalties for submitting false Information, including the
possibility of fines and imprisonment for knowing violations.
Mail Original and Two Copies to:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617

aceAnalytical
www.pacelabs.con
April 07, 2021
Gus Zieske
Smithers Viscient
2900 Quakenbush Rd.
Snow Camp, NC 27349
RE: Project: MW/Eff 3/23/21
Pace Project No.: 92529255
Dear Gus Zieske:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 23, 2021. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNIINELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Stephanie Knott
[e-mail]
704-977-0981
Project Manager
Enclosures
cc: Ronald Alcorn
REPORT OF LABORATORY ANALYSIS
" r��i This report shal[ not be reproduced, except in full.
(q vim/ without the written consent of Pace Analytical Services, LLC. Page 1 of 24
696W

C no
UUAnaljdicalm
Wmptelsbuom
Project: MW/Eff 3/23121
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
[phone]
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification 99030001
Virginia/VELAP Certification 460222
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, LLC. Page 2 of 24

aceAnalytical
wuw.pacelebsiom
if
i
SAMPLE ANALYTE COUNT
Pace Analytical Services, PLC
9800 Itincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: MW/Elf3/23/21
Pace Project No.: 92529255
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92529255001 MW-1
HACH 10206
AFJ
1
PASI-E
SM 254OC-2011
MLS1
1
PASI-E
SM 9222D-2006
MLS1
1
PASI-E
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NAL
1
PASI-A
EPA 365.1 Rev 2.0 1993
NAL
1
PASI-A
SM 531OB-2011
JLH
1
PASI-A
92529255002 MW-2
HACH 10206
AFJ
1
PASI-E
SM 254OC-2011
MLS1
1
PASI-E
SM 9222D-2006
MLS1
1
PASI-E
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NAL
1
PASI-A
EPA 365.1 Rev 2.0 1993
NAL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92529255003 MW3
HACH 10206
AFJ
1
PASI-E
SM 254OC-2011
MLS1
1
PASI-E
SM 9222D-2006
MLS1
1
PASI-E
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NAL
1
PASI-A
EPA 365.1 Rev 2.0 1993
NAL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92529255004 Effluent
HACH 10206
AFJ
1
PASI-E
SM 254OC-2011
MLS1
1
PASI-E
SM 254OD-2011
DAW
1
PASI-E
SM 5210E-2011
MWF
1
PASI-E
SM 9222D-2006
MLS1
1
PASI-E
None
DMN
1
PASI-A
TKN+NO3+NO2 Calculation
EWS
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.0 1993
NAL
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
EPA 365.1 Rev 2.0 1993
NAL
1
PASI-A
PASI-A = Pace Analytical Services -Asheville
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 24

1�5a'cieAnalj6cal&
+ www.paeelab com
f
ANALYTICAL RESULTS
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvilie, NC 28078
[phone]
Sample: MW-1
Parameters
Lab ID: 92529255001 Collected: 03/23/21 10:34
Results Units Report Limit DF
Received: 03/23/21 15:00 Matrix: Water
Prepared Analyzed CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Pace Analytical Services - Eden
Nitrogen, Nitrate
0.41 mg/L 0.30
1
03/23/21 20:56
14797-55-8
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Pace Analytical Services - Eden
Total Dissolved Solids
117 mg/L 25.0
1
03/24/21 09:16
MBIO 9222D Fecal Coliform EDN
Analytical Method: SM 922213-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Eden
Fecal Coliforms
NO CFU/100 mL 1.0
1
03/23/21 15:38 03/24/21 13:38
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
1.8 mg/L 1.0
1
03/26/2104:31
16887-00-6
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
04/01/2111:03
7664-41-7
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L 0.050
1
04/0412115:13 04/05/2111:15
7723-14-0
5310E TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
04/05/21 21:34
7440.44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 24

1�5a'ccieAnalyticals
f WM.Pacelabs.cam
I
ANALYTICAL RESULTS
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: MW-2
Parameters
Lab 1D: 92529255002 Collected: 03/23/21 09:37
Results Units Report Limit OF
Received: 03/23/21 15:00 Matrix: Water
Prepared Analyzed CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Pace Analytical Services - Eden
Nitrogen, Nitrate
0.54 mg/L 0.30
1
03/23/21 20:55
14797-55-8
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services - Eden
Total Dissolved Solids
91.0 mg/L 25.0
1
03/24/21 09:16
MBIO 9222D Fecal Coliform EDN
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Eden
Fecal Coliforms
6.0 CFU/100 mL 1.0
1
03/23/21 15:38 03/24/21 13:38
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
3.5 mg/L 1.0
1
03/26/2104:46
16887-00-6
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
NO mg/L 0.10
1
04/01/21 11:04
7664-01-7
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
NO mg/L 0.050
1
04/04/2115:13 04/05/2111:15
7723-14-0
5310E TOC
Analytical Method: SM 531 OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
NO mg/L 1.0
1
04/04/21 15.41
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04107/2021 07:07 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 24

acemalytical m
www.pacelabucm
ANALYTICAL RESULTS
Project: MW/Eff 3/23121
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: MW-3
Lab ID: 92529255003 Collected: 03/23121 10:02
Received: 03/23/21 15:00 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L 0.30 1
03/23/21 20:55
14797-55-8
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Pace Analytical Services - Eden
Total Dissolved Solids
43.0 mg/L 25.0 1
03/24/21 09:17
MBIO 9222D Fecal Colifonn EDN
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Eden
Fecal Coliforms
ND CFU/100 mL 1.0 1
03/23/21 15:38 03/24/21 13:38
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
5.0 mg/L 1.0 1
03/26/2105:01
16887-00-6
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10 1
04/01/21 11:06
7664-41-7
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
NO mg/L 0.050 1
04104/2115:13 04/05/2111:17
7723-14-0
5310B TOC
Analytical Method: SM 531 OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
NO mg/L 1.0 1
04/04/21 15:59
7440-44-0
Date: 04/07/2021 07:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 24

qD
aceAnalytical
wvw.pecol4bs.com
ANALYTICAL RESULTS
Project: MW/Eff 3/23121
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersviile, NC 28078
[phone]
Sample: Effluent
Lab ID: 92629255004 Collected: 03/23/21 09:18
Received: 03/23/21 15:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Oual
HACH 10206 Nitrogen, Nitrate
Analytical Method: HACH 10206
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L 0.30
1
03123/21 20:55 14797-55-8
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Pace Analytical Services - Eden
Total Dissolved Solids
930 mg/L 50.0
1
03/24/21 09:17
2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
Pace Analytical Services - Eden
Total Suspended Solids
15.2 mg/L 5.7
1
03/26/21 13:06
5210B BOD, 5 day EDN
Analytical Method: SM 5210B-2011 Preparation Method: SM 521 OB-2011
Pace Analytical Services - Eden
BOD, 5 day
16.0 mg/L 2.0
1
03/24/21 10:25 03/29/21 09:17 R6
MBIO 9222D Fecal Coliform EDN
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Eden
Fecal Coliforms
ND CFU/100 mL 1.0
1
03/23/21 15:38 03/24/21 13:38
Plant Available Nitrogen
Analytical Method: None
Pace Analytical Services -Asheville
Plant Available Nitrogen
64.1 mg/L
1
04/05/21 14:00 N2
Total Nitrogen Calculation
Analytical Method: TKN+NO3+NO2 Calculation
Pace Analytical Services -Asheville
Total Nitrogen
143 mg/L 0.52
1
04/02/21 17:08
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
126 mg/L 3.0
3
0312612107.45 16887-00-6
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
107 mg/L 2.5
25
04/01/2113:23 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Kjeldahl, Total
142 mg/L 5.0
10
03/30/21 20:48 03/31/21 06:21 T727-37-9
353.2 Nitrogen, NO2/NO3 pres.
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, NO2 plus NO3
0.14 mg/L 0.040
1
03/31/21 11:45
Date: 04/07/2021 07:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 24

1�5a'cieAnalj&al'D
www.pacelabs.com
7
(
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
Sample: Effluent Lab ID: 92529255004 Collected: 03/23/21 09:18 Received: 03/23/21 15:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus 28.5 mg/L 0.50 10 04/04/21 15:13 04/05/21 11:52 7723-14-0
Date: 04107/2021 07:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, LLC.
Page 8 of 24

aceAnalytical
ti ww.pacelabs.com
f
t
QUALITY CONTROL DATA
Project: MW/Eff 3/23121
Pace Project No.: 92529255
QC Batch: 608696 Analysis Method: HACH 10206
QC Batch Method: HACH 10206 Analysis Description: 10206 Nitrogen, Nitrate
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
METHOD BLANK: 3206326 Matrix: Water
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.30 03/23/21 20:54
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersviile, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3206327
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 5.5 109 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3206328 3206329
MS MSD
92529255003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec ere Rec Limits RPD Qual
Nitrogen, Nitrate mg/L ND 5 5 5.4 5.5 107 110 90-110 2
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 24

aceAnalj6cal
www.pacelabsxom
QUALITY CONTROL DATA
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
QC Batch: 608808 Analysis Method: SM 254OC-2011
QC Batch Method: SM 254OC-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
METHOD BLANK: 3206594 Matrix: Water
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
Blank Reporting
Parameter Units Result Limit Analyzed
Total Dissolved Solids mg/L [r1�7 25.0 03/24/21 09:16
LABORATORY CONTROL SAMPLE: 3206595
Qualifiers
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersvilie, NC 28078
[phone]
Spike LCS LCS °!o Rec
Parameter Units Conc. Result °!° Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 240 96 90-110
SAMPLE DUPLICATE: 3206596
92529255004 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 930 954 g
Results presented on this pegs are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, I.I.C.
Page 10 of 24

aceAnal &cal
(� www ilaeetabaxtiia
i
Project: MW/Eff 3123121
Pace Project No.: 92529255
QC Batch: 609443
QC Batch Method: SM 254OD-2011
Associated Lab Samples: 92529255004
METHOD BLANK: 3210044
Associated Lab Samples: 92529255004
Parameter
Total Suspended Solids
QUALITY CONTROL DATA
Analysis Method: SM 254OD-2011
Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services - Eden
Matrix: Water
Blank Reporting
Units Result Limit Analyzed Qualifiers
mg/L ND 2.5 03126/2113:02
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, INC 28078
[phone]
LABORATORY CONTROL SAMPLE:
3210045
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Total Suspended Solids
mg/L
250 248 99
90-110
SAMPLE DUPLICATE: 3210046
92529226001 Dup
Parameter
Units
Result Result RPD
Qualifiers
Total Suspended Solids
mg/L
21.7 24.4
12
SAMPLE DUPLICATE: 3210047
92529289001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L ND ND
Results presented an this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 24

5anJAIMAnalytical
www.pacelabs.cam
1
QUALITY CONTROL DATA
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
QC Batch: 608797 Analysis Method: SM 521OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Final EON
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92529255004
METHOD BLANK: 3206549 Matrix: Water
Associated Lab Samples: 92529255004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
BOD, 5 day mg/L NO 2.0 03/29/21 08:38
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3206550
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
BOD, 5 day mg/L 198 212 107 84.6-115A
SAMPLE DUPLICATE: 3206552
92529243003 Dup
Parameter Units Result Result RPD Qualifiers
BOD, 5 day mg/L 187 172 9
Results presented on this page are in the units Indicated, by the "Units" column except where an alternate unit is presented to the right of the resuit.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, I.I.C.
Page 12 of 24

1�5a'cmnalytical"
www.pacelaba.ccm
C�14_�'���7► 7�7��Tti �l
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
QC Batch: 608670 Analysis Method: SM 9222D-2006
QC Batch Method: SM 92220-2006 Analysis Description: 9222D Fecal Coliform( MF)-EDN
Laboratory: Pace Analytical Services - Eden
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
METHOD BLANK: 32D6200 Matrix: Water
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 03/24/21 13:38
SAMPLE DUPLICATE: 3206201
92529265003 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL NO ND
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resutL
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 24

aceAnalytical
trww.patelab>.cam
QUALITY CONTROL DATA
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
QC Batch: 609250 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 3208968 Matrix: Water
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 03/26/2115:59
LABORATORY CONTROL SAMPLE: 3208969
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 50 47.3 95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3208970 3208971
MS MSD
92529321001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 5.8 50 50 62.1 57.2 113 103 90-110 8 M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04107/2021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 24

/�5a'ceAnaljftal
trnwv.paeolabs.com
t
i
QUALITY CONTROL DATA
Project: MW/Eff 3123/21
Pace Project No.: 92529255
QC Batch: 610424 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA350.1 Rev 2.01993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92529255001, 92529255002, 92529255003
METHOD BLANK: 3214163 Matrix: Water
Associated Lab Samples: 92529255001, 92529255002, 92529255003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 04/01/21 10:37
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3214164
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 4.9 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3214165
MS
92529407001 Spike
Parameter Units Result Cone.
Nitrogen, Ammonia mg/L 30.9 5
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3214167
MS
92529727001 Spike
Parameter Units Result Cone.
Nitrogen, Ammonia mg/L 0.92 5
3214166
MSD
Spike MS MSD MS MSD % Rec
Cone. Result Result % Rec % Rec Limits RPD
5 35.6 35.7 93 96 90-110 0
3214168
MSD
Spike MS MSD MS MSD % Rec
Cone. Result Result % Rec % Rec Limits RPD
5 5.9 5.9 99 99 90-110 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, I.I.C.
Qual
Qual
Page 15 of 24

aceAnalytical
www.pacelabLeom
I
QUALITY CONTROL DATA
Project: MW/Eff 3/23121
Pace Project No.: 92529255
QC Batch: 610427 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92529255004
METHOD BLANK: 3214182
Associated Lab Samples: 92529255004
Parameter Units
Nitrogen, Ammonia mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 0.10 04101121 12:28
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersviile, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3214183
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 4.9 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3214186 3214187
MS MSD
92529562001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 134 5 5 142 144 154 191 90-110 1 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3215206 3215207
MS MSD
92529562002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc, Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mgiL 88.8 5 5 89.1 91.2 6 47 90-110 2 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 24

1�5a'cmnalytical*
www.pacetabs.com
r
i
QUALITY CONTROL DATA
Project: MW/Eff 3123/21
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 610212
Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993
Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92529255004
METHOD BLANK: 3213255
Matrix: Water
Associated Lab Samples: 92529255004
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/L
ND 0.50 03/31/21 05:20
LABORATORY CONTROL SAMPLE: 3213256
Spike LCS LCS % Rec
Parameter Units
Cone. Result % Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/L
10 9.3 93 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3213257 3213258
MS MSD
92529231001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result % Rec % Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L ND
10 10 9.8 10.1 98 101
90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3213259 3213260
MS MSD
92529231002
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result % Rec % Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L NO
10 10 9.7 9.8 97 98
90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 04/0712021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 24

aceAnalytical
( www.pacalabs.catn
i
QUALITY CONTROL DATA
Project: MW/Eff 3/23121
Pace Project No.: 92529255
QC Batch: 610377 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92529255004
METHOD BLANK: 3213987
Associated Lab Samples: 92529255004
Parameter Units
Nitrogen, NO2 plus NO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.040 03/3112111:15
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3213988
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L 2.5 2.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3213989 3213990
MS MSD
92530288001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L ND 2.5 2.5 2.4 2.4 96 97 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3213991 3213992
MS MSD
92529599001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 0.36 2.5 2.5 2.7 2.7 95 95 90-110 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, I.I.C.
Page 18 of 24

1�5a.'C ie Analytical
www.pacelabs.cam
QUALITY CONTROL DATA
Project: MW/Eff 3123/21
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 611324
Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
METHOD BLANK: 3218511
Matrix: Water
Associated Lab Samples: 92529255001, 92529255002, 92529255003, 92529255004
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Phosphorus mg/L
ND 0.050 04/05/2111:05
LABORATORY CONTROL SAMPLE: 3218512
Spike LCS LCS % Rec
Parameter Units
Cone. Result % Rec Limits Qualifiers
Phosphorus mg/L
2.5 2.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3218513 3218514
MS MSD
92529231007
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result % Rec % Rec
Limits RPD Qual
Phosphorus mg/L ND
2.5 2.5 2.4 2.5 95 98
90-110 4
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3218515 3218516
MS MSD
92529231008
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result % Rec % Rec
Limits RPD Qual
Phosphorus mg/L ND
2.5 2.5 2.5 2.4 98 94
90-110 4
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 24

1�5a'cmnaljftal'D
waay.paeelabs.00m
/
t
QUALITY CONTROL DATA
Project: MW/Eff 3/23121
Pace Project No.: 92529255
QC Batch: 611251 Analysis Method: SM 531OB-2011
QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92529255002, 92529255003
METHOD BLANK: 3218348 Matrix: Water
Associated Lab Samples: 92529255002, 92529255003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 04/04/21 12:15
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville. NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3218349
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg1L 25 23.0 92 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3218350 3218351
MS MSD
92528932011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 8070 25 25 8220 8200 620 540 90-110 0 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3218352 3218353
MS MSD
92529258011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 5310 25 25 5160 5120 -590 -753 90-110 1 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, I.I.C.
Page 20 of 24

aceAnalytical
www.pacelabs.com
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
QC Batch: 611534
QC Batch Method: SM 531OB-2011
Associated Lab Samples: 92529255001
QUALITY CONTROL DATA
Analysis Method: SM 531OB-2011
Analysis Description: 5310B TOC
Laboratory: Pace Analytical Services - Asheville
METHOD BLANK: 3219427 Matrix: Water
Associated Lab Samples: 92529255001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 04/05/21 18:11
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersviile, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3219428
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.4 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3219429 3219430
MS MSD
92529255001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L NO 25 25 23.3 23.4 93 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3219431 3219432
MS MSD
92529789011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Total Organic Carbon mg/L 5050 25 25 5080 5040 149 -27 90-110 1 M6
Results presented on this page are In the units Indicated by the "Units" column except whore an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 24

Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
acemalXical Huntersville, NC 28078
www.pacelabs.com
[phone]
QUALIFIERS
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
POL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
R6 The RPD between valid sample dilutions exceeded 30%.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, I.I.C. Page 22 of 24

�;a'cieAnalj6cal
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: MW/Eff 3/23/21
Pace Project No.: 92529255
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92529255001
MW-1
HACH 10206
608696
92529255002
MW-2
HACH 10206
608696
92529255003
MW-3
HACH 10206
608696
92529255004
Effluent
HACH 10206
608696
92529255001
MW-1
SM 254OC-2011
608808
92529255002
MW-2
SM 254OC-2011
608808
92529255003
MW-3
SM 254OC-2011
608808
92529255004
Effluent
SM 254OC-2011
608808
92529255004
Effluent
SM 254OD-2011
609443
92529255004
Effluent
SM 521OB-2011
608797
SM 521OB-2011
608865
92529255001
MW-1
SM 9222D-2006
608670
SM 9222D-2006
608676
92529255002
MW-2
SM 922213-2006
608670
SM 9222D-2006
608676
92529255003
MW-3
SM 9222D-2006
608670
SM 9222D-2006
608676
92529255004
Effluent
SM 9222D-2006
608670
SM 9222D-2006
608676
92529255004
Effluent
None
611482
92529255004
Effluent
TKN+NO3+NO2
611225
Calculation
92529255001
MW-1
EPA 300.0 Rev 2.1 1993
609250
92529255002
MW-2
EPA 300.0 Rev 2.1 1993
609250
92529255003
MW-3
EPA 300.0 Rev 2.1 1993
609250
92529255004
Effluent
EPA 300.0 Rev 2.1 1993
609250
92529255001
MW-1
EPA 350.1 Rev 2.0 1993
610424
92529255002
MW-2
EPA 350.1 Rev 2.0 1993
610424
92529255003
MW-3
EPA 350.1 Rev 2.0 1993
610424
92529255004
Effluent
EPA 350.1 Rev 2.0 1993
610427
92529255004
Effluent
EPA 351.2 Rev 2.0 1993
610212
EPA 351.2 Rev 2.0 1993
610361
92529255004
Effluent
EPA 353.2 Rev 2.0 1993
610377
92529255001
MW-1
EPA 365.1 Rev 2.0 1993
611324
EPA 365.1 Rev 2.0 1993
611330
92529255002
MW-2
EPA 365.1 Rev 2.0 1993
611324
EPA 365.1 Rev 2.0 1993
611330
92529255003
MW-3
EPA 365.1 Rev 2.0 1993
611324
EPA 365.1 Rev 2.0 1993
611330
92529256004
Effluent
EPA 365.1 Rev 2.0 1993
611324
EPA 365.1 Rev 2.0 1993
611330
92529255001
MW-1
SM 531OB-2011
611534
92529255002
MW-2
SM 531OB-2011
611251
92529255003
MW-3
SM 531OB-2011
611251
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
Date: 04/07/2021 07:07 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 24

CHAIN -OF -CUSTODY Analytical Request Document
areAr)r�lytical
Chain -of -Custody is a LEGAL DOCUMENT - Compfete all relevent fields
Company: Billing Information:
Carolina Research Center
Report To:
Email 70:
SPY To:
Site Collection info/Address:
Customer Project Name/Number.
State: County/City: Time zone Collected:
/ I )PT[ )MTI JCT
[ JET
Phone:
Site/Facility ID it;
Compliance Monitoring?
Email:
I y(Yes I J No
Collected y rint):
Purchase Order #;
DW PWS ID if:
Quote #:
DW Location Code:
Collected By {signature[:
Turnaround Date Required:
Immediately Packia on IM:
[ ]Yes [ J ND
Sample Disposal:
Rush:
rield Filtered (it applicable);
I I Dispose asappropnate I ) Return
I J Same Day [ I Next pay
I J Yes [ ) No
I) Ard*m.- _
( J Z Day 11 3 Day I J 4 Day [) 5 Da y
( ) Hold:
lExpedite Charges Apply)
Analysis:
Matrix Codes (insert In Matrix box below): Drinking Water IDW), Ground Water (GW), Wastewater (WWI,
Product (P), Soil/Solid (5L), QII (6t), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
Comp /
Collected (or
Res
# of
Customer Sample ID
matrix
Grab
Composite Start)
Composite End
Cl
Ctns
Date
Time
Date
Time
UAW--'[
9W
9
3
OW-2
gW
9
/z3 Gf
0937
4
AW-3
1gW
9
IS.&I
1052
4
Customer Remarks / Special Conditions / Pussible Hazards:
GrourKimler Monitoring
I l 1A7§ Afltx IAIo
WO# : 92529255 ��
"�,I'.!•.�'s+t�l� r `fir=?Sa4:
�.���R� �-'�t uzii, fr k�li,`•'�i�-.�.��ts,� jj/E Ir t:�„'.�-
.I rT Container Preservative T 9252 1255 Sin, r
n-.
3 'i-u 2 - 5`i��` 'r1''E ilrYr•x :rr al.,i;� _ c`:k:�i-c•�� ��ll�-FJ�Y'tsi e
— Preservatlive?ypes: (1) nitrk acid 11) sulfuric acid, (3) hydrochlock arid, (4) sodium howxlde, (5) rinc acetate,
(61 methanol, (7) sodiurn bisulfate, (B) sodum thiosulfate. (9) heron, (Al ascorbic acid, (B) ammonium wifale,
(c) ammonium hydroxide, (D) TSP, IUJ Unpreserved, (D) Dlha
O
r
ter
F,i�[
t
�
•
C]
c
D
uished try/Corrtpany: (Signature)
Date imr
RtJEei
l icy/Company tgrr r
Date/Time:
uished /Ca pan r 1 76nature)
Datc/Time:
3-?3"
Recel yj mpany:(5i ature)
Dat une:
- 311L�
wished by/Company: (Signature)
Date/Time:
ReE by omoanv: isknatufel
DatefTlme:
/,,,L, - ✓S Lk�
RESEARCIt & ANA[y-riCAt
IAORATORIESr INC.
wv w.randolabs—om
(33 B) SU B-2B41
Page: