NC0001121_NPDES Permit App_20060512

Kenneth Verhulst
Dynapar Corp.
2100 West Broad St.
Elizabethtown, NC
Dear Mr. Verhulst
28337
May 12, 2006
Michael F. Easley, Govemor
William G. Ross Jr., Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Klimek, P.E. Director
Division of Water Quality
DENR-F9
MAY 15 2006
Subject Receipt of permit renewal application
NPDES Permit NC0001121
Danaher Sensors & Controls
Bladen County
The NPDES Unit received your permit renewal application on May 12, 2006. A member of the NPDES Unit will
review your application. They will contact you if additional information is required to complete your permit renewaL You
should expect to receive a draft permit approximately 30-45 days before your existing permit expires. The requirements in
your existing permit will remain in effect until the permit is renewed (or the Division takes other action).
If you have any additional questions concerning renewal of the subject permit, please contact me at [phone],
extension 363.
Sincerely,
Carolyn Bryant
Point Source Branch
cc: CENTRAL FTT FS
Fayetteville Regional Office/Surface Water Protection-
NPDES Unit
N Carolina
amNaturally
North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Phone [phone] Customer Service
Internet h2o.enr.state.nc.us 512 N. Salisbury St. Raleigh, NC 27604 FAX [phone]
An Equal Opportunity/Affirmative Action Employer— 50% Recycled/10% Post Consumer Paper

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NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial
Minor industrial, manufacturing and commercial facilities.
Mail the complete application to:
N. C. Department of Environment and Natural Resources
Division of Water Quality / NPDES Unit
1617 Mail Service Center, Raleigh, NC 27699-1617
NPDES Permit Number
NC0001121
If you are completing this form in computer use the TAB key or the up - down arrows to move from one
field to the next. To check the boxes, click your mouse on top of the box. Otherwise, please print or type.
1. Contact Information:
Owner Name
Facility Name
Mailing Address
City
State / Zip Code
Telephone Number
Fax Number
e-mail Address
Kenneth J. Verhulst - Plant Manager
Danaher Sensors & Controls
2100 West Broad Street
Elizabethtown
North Carolina / 28337
[phone]
[phone]
[e-mail]
2. Location of facility producing discharge:
Check here if same as above El
Street Address or State Road
City
State / Zip Code
County
3. Operator Information:
Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the
Operator in Responsible Charge or ORC)
Name
Mailing Address
City
State / Zip Code
Telephone Number
Fax Number
Dynapar Corporation
2100 West Broad Street
Elizabethtown
North Carolina / 28337
[phone]
[phone]
Page 1 of 5 C-MI 03105

NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial
Minor industrial, manufacturing and commercial facilities.
4. Ownership Status:
Federal " ❑ State ❑ Private ® Public ❑
5. Standard Industrial Classification (SIC) code(s): 3824
6. Number of employees: 350
7. Describe the treatment system List all installed waste treatment components with capacities,
describe the processes that generate wastewaters. If the space provided is not sufficient attach a
separate sheet of paper with the system description.
Waste Treatment - Chrome batch treatment tanks (2 each,0.0155MG), Cyanide batch
treatment tanks (2 each,0.0375MG), Wet Well (0.005MG), Clarifier (0.085MG), Sludge
Filter Press and Sludge Holding Tank (0.010MG)
Plating Operation - Various metal parts are cleaned and finished either by electroplating
or dipping into aqueous solutions. The solutions include zinc cyanide, copper cyanide,
nickel sulfate, chromium, phosphate conversion,chromate conversion, silver cyanide,
alkaline cleaning, acid salts pickling, rinsing and rust preventative. The solution require
periodic replacement or replentishment of chemical contents. Separate drains within
the facility connect to specific treatment tanks.
8. Is facility covered under federal effluent limitation guidelines? No ® Yes ❑
If yes, specify the category?
9. Principal product(s) produced: Mechanical- Electrical Counters and Sensors, Plastic
Bushings, Electronic Voting Machines, Chart Recorders,Temperature Controllers
Principal raw material(s) consumed: Plastic Resin, Steel, Brass, Copper, Aluminum
Briefly describe the manufacturing process(es):
Molding of Plastic Counter Wheels, Bushings and Associated Parts, Assembly of Mechanical -
Electrical Counters, Assembly of Chart Recorders, Assembly of Electronic Voting Machines,
Assembly of Temperature Controllers, Painting, Plating, Machining of Metal Parts
10. Amount of principal product produced or raw material consumed
Page 2 of 5 C-MI 03/05

NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial
Minor industrial, manufacturing and commercial facilities.
ist s ecific amounts consumed and/or units of production over the last three years
q�
P
Product Produced or Raw Material
Consumed
(AVERAGE)
Product Produced or Raw Material
Consumed
(PEAK)
per Day
PLATING CHEMICALS CONSUMED
per Month
per Year
24,232 pounds
11. Frequency of discharge: Continuous ® Intermittent ❑
If intermittent:
Days per week discharge occurs: 7 Duration: 5
12. Types of wastewater discharged to surface waters only
Discharge
Flow
(GALLONS PER DAY).
Sanitary - monthly average
0
Non -contact Cooling 002, etc. -
monthly average
2000
Process wastewater 001 -
monthly average
20000
Boiler, Chiller, Heat Treat, Local Storm
Water to Storm Drain - monthly average
10000
Other - monthly average
Explain: Groundwater Recovery 003
150000
Monthly Average
total discharge (all types)
182000
13. Number of separate discharge points: 4
Outfall Identification number(s) 001 - Wastewater Treatment, 002 - Non -contact Cooling,
003 - Groundwater Recovery through Air Stripping Tower, 004 - Combined 001, 002, 003
Outfalls
14. Name of receiving stream(s) (Provide a map showing the exact location of each outfall, including
latitude and longitudes
Cape Fear River
Page 3 of 5
C-MI 03/05

NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial
Minor industrial, manufacturing and commercial facilities.
15. Effluent Data
Provide data for the parameters listed. Temperature and pH shall be grab samples, for all other parameters 24hour
composite sampling shall be used. If more than one analysis is reported, report daily maximum and monthly average.
If only one analysis is reported, report as daily maximum.
Parameter
Daily
Maximum
Monthly
Average
Units of
Measurement
Biochemical Oxygen Demand (BOD5)
Chemical Oxygen Demand (COD)
Total Organic Carbon
Total Suspended Solids
4
2
mg/L
Ammonia as N
Temperature (Summer)
22
20
Celsius
Temperature (Winter)
18
17
Celsius
pH
7.8 max
7.6 min
Stand. Units
Fecal Coliform (If sanitary waste is
present)
Total Residual Chlorine (if chlorine is
used)
0.01
0.01
mg/L
Notes to Permit Writer: 1. The existing permit limitation being reported in pounds per day, in
effect, requires that the effluent total suspended solids monthly average be less than 4 mg/L.
The daily maximum limit requires that the effluent total suspended solids never exceed 9 mg/L.
We believe these limitations place an unreasonable burden for compliance on this facility. 2.
The 90% effluent concentration for the acute toxicity test was written into the permit when the
total effluent flow included 0.152 MGD of non -contact cooling water from Outfall 002. The FRO
was notified of this change in a letter dated May 10, 2004. We request that you consider the
higher proportion of process wastewater that now exists and the potential for total dissolved
solids affecting the outcome of this analysis.
16. List all permits, construction approvals and/or applications (check all that apply and provide permit
numbers or check none if not applicablef:
Type Permit Number Type Permit Number
Hazardous Waste (RCRA) NCD041466251 NESHAPS (CAA) none
UIC (SDWA) none Ocean Dumping (MPRSA) none
NPDES NC0001121 Dredge or fill (Section 404 or CWA) none
PSD (CAA) none Other NCG030175
Non -attainment program none
Page 4 of 5 C-MI 03/05

NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial
Minor industrial, manufacturing and commercial facilities.
17. List any chemicals that may be discharged (Please list and explain source and potential
amounts.)
Hydraulic Oil - small potential most quantities would be captured by oil water separator on
002.
18. Is this facility located on Indian country? (check one)
Yes ❑ No
19. Applicant Certification
I certify that I am familiar with the information contained in the application and that to the
best of my knowledge and belief such information is true, complete, and accurate.
Kenneth J. Verhult 1 1 r(e\ Plant Manager
Printed 'name of Per oh Simi 'g Title
J
f $J7 ID
A ice - ` .
Signature of Applicat Date
Northi Carolina General Statute 143-215.6 (b)(2) provides that: Any person who knowingly makes any false
statement representation, or certification in any application, record, report, plan, or other document files or
required to be maintained under Article 21 or regulations of the Environmental Management Commission
implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or
monitoring device or method required to be operated or maintained under Article 21 or regulations of the
Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable
by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section
1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both,
for a similar offense.)
Page 5 of 5 C-MI 03/05

Addendum to:
NPDES PERMIT APPLICATION - SHORT FORM C - Minor Industrial
Sludge Management Plan
Danaher Sensors & Controls
NPDES Permit No. NC 0001121
RCRA Permit No. NCD041466251
Sludge is generated at this facility from the two separate batch treatment processes for
chrome containing wastewater and cyanide containing wastewater. Settled sludge is also
recovered during the semiannual cleanout of the clarifier.
Chrome containing wastewater is treated as follows:
1. Adjust pH to 2.0 using sulfuric acid.
2. Add sodium meta-bisulfite to revert hexavalent chrome to trivalent chrome.
3. Adjust pH to 8.5 using caustic soda.
4. Add Polyfloc AS1002 polymer.
5. Add Metclear MR 2405 polymer (optional).
6. Allow sludge to settle and pump off.
Cyanide containing wastewater is treated as follows:
1. Adjust pH to 13.0 using caustic soda.
2. Add sodium hypochlorite to destroy cyanide.
3. Add sodium meta-bisulfite to destroy residual chlorine.
4. Add Klaraid CDP 1311 polymer.
5. Add Novus CE 2681 polymer.
6. Allow sludge to settle and pump off.
Sludge is stored in a 10,000 gallon above ground storage tank that also serves as a
thickener. Final dewatering of the sludge is achieved using a JWI recessed chamber filter
press. Filtrate from the filter press is returned to the cyanide batch treatment tank.
The sludge is considered a RCRA hazardous waste under waste codes F006 and F007.
The most recent TCLP waste analysis conducted on 12/20/2005 indicated no toxic
characteristic constituents above their regulatory levels.
The dewatered sludge is transferred to cubic yard cardboard storage containers with
plastic liners, then moved to a 90-day storage location. The sludge is transported by
Clean Harbors Environmental Services (MAD0393222560) to a designated facility
(NCD000648451).

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NPDES Permit No. NC0001 121
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DANAHER
SENSORS & CONTROLS
2100 West Broad Street
Elizabethtown, NC 28337
June 5, 2006
Mrs. Carolyn Bryant
NC DENR/DWQ/Point Source Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: NPDES Application for Permit Renewa
NPDES Permit No. NC0001121
Danaher Sensors & Controls
Bladen County
DENR-FRO
JuN 15 2006
Oi3301"?1010311 1-0131t11 8
N3d
li
APO C I wry'
Dear Mrs. Bryant:
Enclosed you will find (3) copies of the Priority Pollutant Analysis to add to our permit
renewal package that you received on May 12, 2006.
Please contact me if you have any questions about this information.
Sincerely,
Rodney H. ang
EHS Engineer, ORC
910-862-5453
Enclosures
DENR - WATER QUALITi
POINT SOURCE BRANCH .....:

www.pacelabs.com
May 26, 2006
Ht. Rod Lang
Danaher Controls
2100 W. Broad Street
Elizabethtown, NC 28337
RE: Lab Project Number: •92119559
Client Project ID: Priority Pollutants/2006 Perrot
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: 704.875,9091
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
1PDIES ?eCrti+ i Q,OCo00t at
Dear Mr. Lang:
Enclosed are the analytical results for sample(s) received by the laboratory on May 17, 2006. Results reported
herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of
the report.
Inorganic Wet Chemistry and Metals Analyses were performed at our Pace Asheville laboratory and Organic testing
was performed at our Pace Charlotte laboratory unless otherwise footnoted.
If you have any questions concerning this report please feel free to contact me.
Sincerely,
Richard Swartz
Ricbard.Swartzepacelabe.com
Project Manager
Enclosures
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87848
"`REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
E
J U N 9 2006
L_ __-___.__f
DENR - 1".;TER QUALITY
P1!iT SOURCE l�_,",_NCH --
Charlotte Certification IDS
NG Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
Lab Sample No: 926991753
Client Sample ID: ODTPtLL 004 COMP
Parameters
Metals
Metals by Trace ICP
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Thallium
Zinc
Date Digested
Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Phenolics, Total Recoverable
Phenolics, Total Recoverable
GC/MS Semivolatiles
Extractablea in Water by 625
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(k)fluoranthene
Senzo(b)fluoranthene
Benzo(a)anthracene
Benzo(g,h,i)perylene
Benzo(a)pyrene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
bie(2-Chloroethoxy)methane
bie(2-Chloroethyl) ether
Date: 05/26/06
Results
Unite
Project Sample Number: 92119559-001
Matrix: Water
Revort Limit DP
Prep/Method: EPA 3010 / EPA
ND mg/1
ND
ND
ND
ND
ND
ND
0.0057
ND
ND
ND
0.016
05/20/06 12:00
tog/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1 .
Method: EPA 7470
ND mg/1
6010
0.0050
0.0050
0.0010
0.0010
0.0020
0.0020
0.0050
0.0050
0.0050
0.0020
0.010
0.010
Date Collected: 05/16/06 07:30
Date Received: 05/17/06 09:15
Analyzed By CAS No.
1.0 05/25/06 21:53 JDA1 7440-36-0
1.0 05/25/06 21:53 JDA1 7440-38-2
1.0 05/25/06 21:53 JDA1 7440-41-7
1.0 05/25/06 21:53 JDA1 7440-43-9
1.0 05/25/06 21:53 JDA1 7440-47-3
1.0 05/25/06 21:53 JDA1 7440-50-8
1.0 05/25/06 21:53 JDA1 7439-92-1
1.0 05/25/06 21:53 JDA1 7440-02-0
1.0 05/25/06 21:53 JDA1 7782-49-2
1.0 05/25/06 21:53 JDA1 7440-22-4
1.0 05/25/06 21:53 JDA1 7440-28-0
1.0 05/25/06 21:53 JDA1 7440-66-6
05/20/06 12:00
0.00020 1.0 05/19/06 10:21 ALV 7439-97-6
Method: EPA 420.2
0.022 mg/1 0.010
Prep/Method: EPA 625
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
ND ug/1
Asheville Certification 106
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
1.0 05/23/06 19:30 TMR
SP / EPA 625
5.0 1.0 05/25/06 17:36 BET 83-32-9
5.0 1.0 05/25/06 17:36 BET 208-96-8
5.0 1.0 05/25/06 17:36 BET 120-12-7
50. 1.0 05/25/06 17:36 BET 92-87-5
5.0 1.0 05/25/06 17:36 BET 207-08-9
5.0 1.0 05/25/06 17:36 BET 205-99-2
5.0 1.0 05/25/06 17:36 BET 56-55-3
5.0 1.0 05/25/06 17:36 BET 191-24-2
5.0 1.0 05/25/06 17:36 BET 50-32-8
5.0 1.0 05/25/06 17:36 BET 101-55-3
5.0 1.0 05/25/06 17:36 BET 85-68-7
5.0 1.0 05/25/06 17:36 BET 59-50-7
5.0 1.0 05/25/06 17:36 BET 111-91-1
5.0 1.0 C5/25/06 17:36 BET 111-44-4
REPORT OF LABORATORY ANALYSIS
Ills report shall not be reproduced. except in full,
without the written consent=ofPPaaacee Analytical Services, Inc.
nt
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
5C 99006
FL NELAP E87627
Dual Reatmt,
Page: 1 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: 828.252,4618
Lab Project Number: 92119559
Client Project ID: Priority Pollutante/2006 Permt
Lab Sample No: 926991753
Client Sample ID: OUTFALL 004 COMP
parameters
bie(2-Chloroisopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chryeene
Dibenz(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3r-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Iaophorone
Naphthalene
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitroeodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Data: 05/26/06
Project Sample Number: 92119559-001
Matrix: Water
Date Collected: 05/16/06 07:30
Date Received: 05/17/06 09:15
Results Unite Report Limit DP Analyzed By CAS No.
AgeldlieCertification1Do
NCWastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
ND ug/1 5.0 1.0 05/25/06 17:36 BET 39638-32-9
ND ug/1 5.0 1.0 05/25/06 17:36 BET 91-58-7
ND ug/1 5.0 1.0 05/25/06 17:36 BET 95-57-8
ND ug/1 5.0 1.0 05/25/06 17:36 BET 7005-72-3
ND ug/1 5.0 1.0 05/25/06 17:36 BET 218-01-9
ND ug/1 5.0 1.0 05/25/06 17:36 BET 53-70-3
ND ug/1 5.0 1.0 05/25/06 17:36 BET 95-50-1
ND ug/1 5.0 1.0 05/25/06 17:36 BET 541-73-1
ND ug/1 5.0 1.0 05/25/06 17:36 BET 106-46-7
ND ug/1 10. 1.0 05/25/06 17:36 BET 91-94-1
ND ug/1 5.0 1.0 05/25/06 17:36 BET 120-83-2
ND ug/1 5.0 1.0 05/25/06 17:36 BET 84-66-2
ND ug/1 5.0 1.0 05/25/06 17:36 BET 105-67-9
ND ug/1 5.0 1.0 05/25/06 17:36 BET 131-11-3
ND ug/1 5.0 1.0 05/25/06 17:36 BET 84-74-2
ND ug/1 25. 1.0 05/25/06 17:36 BET 534-52-1
ND ug/1 25. 1.0 05/25/06 17:36 BET 51-28-5
ND ug/1 5.0 1.0 05/25/06 17:36 BET 121-14-2
ND ug/1 5.0 1.0 05/25/06 17:36 BET 606-20-2
ND ug/1 5.0 1.0 05/25/06 17:36 BET 117-84-0
ND ug/1 5.0 1.0 05/25/06 17:36 BET 117-81-7
ND ug/1 5.0 1.0 05/25/06 17:36 BET 206-44-0
ND ug/1 5.0 1.0 05/25/06 17:36 BET 86-73-7
ND ug/1 5.0 1.0 05/25/06 17:36 BET 87-68-3
ND ug/1 5.0 1.0 05/25/06 17:36 BET 118-74-1
ND ug/1 10. 1.0.05/25/06 17:36 BET 77-47-4
ND ug/1 5.0 1.0 05/25/06 17:36 BET 67-72-1
ND ug/1 5.0 1.0 05/25/06 17:36 BET 193-39-5
ND ug/1 5.0 1.0 05/25/06 17:36 BET 78-59-1
ND ug/1 5.0 1.0 05/25/06 17:36 BET 91-20-3
ND ug/1 5.0 1.0 05/25/06 17:36 BET 98-95-3
ND ug/1 5.0 1.0 05/25/06 17:36 BET 88-75-5
ND ug/1 25. 1.0 05/25/06 17:36 BET 100-02-7
ND ug/1 5.0 1.0 05/25/06 17:36 BET 62-75-9
ND ug/1 5.0 1.0 05/25/06 17:36 BET 621-64-7
ND ug/1 5.0 1.0 05/25/06 17:36 BET 86-30-6
ND ug/1 25. 1.0 05/25/06 17:36 BET 87-86-5
ND ug/1 5.0 1.0 05/25/06 17:36 BET 85-01-8
ND ug/1 5.0 1.0 05/25/06 17:36 BET 108-95-2
.REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except In full.
without the written consent of Pace Analytical Services, Inc.
griehr:c ..Crj6
Charlotte Certification IDs'
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Qual RegLmt
Page: 2 of 20

winv.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: 828252,4618
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
Lab Sample No: 926991753
Client Sample ID: OUTFALL 004 COMP
Parameters
Pyrene
1,2,4-Trichlorobenzene
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d5 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Date Extracted
Date: 05/26/06
Project Sample Number: 92119559-001
Matrix: Water
Date Collected: 05/16/06 07:30
Date Received: 05/17/06 09:15
Results Unite #teport Limit _RE__ Analyzed By CAS No. ual RegLmt
ND ug/1 5.0 1.0 05/25/06 17:36 BET 129-00-0
ND ug/1 5.0 1.0 05/25/06 17:36 BET 120-82-1
ND ug/1 5.0 1.0 05/25/06 17:36 BET BB-06-2
40 % 1.0 05/25/06 17:36 BET 4165-60-0
49 % 1.0 05/25/06 17:36 BET 321-60-8
65 % 1.0 05/25/06 17:36 BET 1718-51-0
21 % 1.0 05/25/06 17:36 BET 4165-62-2
30 % 1.0 05/25/06 17:36 BET 367-12-4
42 % 1.0 05/25/06 17:36 BET 118-79-6
05/23/06 05/23/06
Asheville Certification IDS
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NC Drinking Water 37712
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IDs
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Page: 3 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Sulte 100
Huntersville, NC28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Perrot
Lab Sample No: 926991761
Client Sample ID: OUTFALL 004 GRAB
Parameters
Wet Chemistry
Cyanide, Total, Water
Cyanide
GC/MS Volatiles
Volatile GC/MS by 624
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
2thylbenzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Date: 05/26/06
Project Sample Number: 92119559-002
Matrix: Water
Date Collected: 05/16/06 07:30
Date Received: 05/17/06 09:15
Results Unite Report Limit DF Analyzed By CAS No. ual ReaLmt
Method: EPA 335.2
ND mg/1 0.0050 1.0 05/25/06 05:43 MLS1 57-12-5
Method: EPA 624
ND ug/1 25. 1.0 05/24/06 18:59 MCK 107-02-8
ND ug/1 25. 1.0 05/24/06 18:59 MCK 107-13-1
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 71-43-2
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 75-27-4
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 75-25-2
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 74-83-9
ND ug/1 5.0 1.0 05/24/06 18:59 MCA 56-23-5
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 108-90-7
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 75-00-3
ND ug/1 10. 1.0 05/24/06 18:59 MCA 110-75-8
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 67-66-3
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 74-87-3
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 124-48-1
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 95-50-1
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 541-73-1
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 106-46-7
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 75-34-3
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 107-06-2
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 75-35-4
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 156-59-2
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 156-60-5
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 78-87-5
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 10061-01-5
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 10061-02-6
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 100-41-4
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 75-09-2
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 79-34-5
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 127-18-4
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 108-88-3
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 71-55-6
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 79-00-5
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 79-01-6
ND ug/1 5.0 1.0 05/24/06 18:59 MCK 75-69-4
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REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except In full,
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Page: 4 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 KlnceyAvenue, Suite 100
Huntersville, NC 28078
Phone: 704.875,9092
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
Lab Sample No: 926991761
Client Sample ID: OUTFALL 004 GRAB
Parameters
Vinyl chloride
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Date: 05/26/06
Results .Units
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
ND ug/1
97
98
98
Project Sample Number: 92119559-002
Matrix: Water '
Date Collected: 05/16/06 07:30
Date Received: 05/17/06 09:15
Report Limit DF Analyzed By
5.0 1.0 05/24/06 18:59 MCK
1.0 05/24/06 18:59 MCK
1.0 05/24/06 18:59 MCK
1.0 05/24/06 18:59 MCK
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full.
without the written consent of Pace Analytical Services, Inc.
Stkiggfi
CAS No. Qual RegLmt
75-01-4
2037-26-5
460-00-4
1868-53-7
Charlotte Certification ID6
NC Wastewater 12
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SC 99006
FL NELAP E87027
Page: 5 of 20

Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
PARAMETER FOOTNOTES
Dilution factor shown represents the factor applied to the reportedresult and reporting limit due to changes
in sample preparation, dilution of the extract, or moisture content
ND
NC
MDL
(S)
Method 90718 modified to use ASE.
All pH, Free Chlorine, Total Chlorine and Ferrous Iron analyses conducted outside of EPA recommended immediate
hold time.
Depending on the moisture content the PRLs can be elevated for all soil samples reported on a dry weight basis.
2-Chloroethyl vinyl ether has been shown to degrade in the presence of acid.
Not detected at or above adjusted reporting limit
Not Calculable
Estimated concentration above the adjusted method detection limit and below the adjusted reporting
Adjusted Method Detection Limit
Surrogate
Date: 05/26/06
Asheville Certification IDs
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REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
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Charlotte Certification IDs
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SC 99006
FL NELAP E87627
limit
Page: 6 of 20

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersvilte, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
QC Batch: 157911
QC Batch Method: EPA 625 SF
Aeeociated Lab Samples:
926991753
Analysis Method: EPA 625
Analysis Description: Extractablee in Water by 625
METHOD BLANK: 927010298
Associated Lab Samples: 926991753
Parameter
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(k)fluoranthene
Benzo(b)fluoranthene
Benzo(a)anthracene
Benzo(g,h,i)perylene
Benzo(a)pyrene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
bia(2-Chloroethoxy)methane
bie(2-Chloroethyl) ether
bis(2-Chloroieopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
Date: 05/26/06
Blank
Unite Result
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
ug/1 ND
Asheville Certilication IDs
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Reporting
Limit Footnotes
5.0
5.0
5.0
50.
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
5.0
10.
5.0
5.0
5.0
5.0
5.0
25.
25.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IDs
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SC 99006,
FL NELAP E87627
Page: 7 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
METHOD BLANK: 927010298
Associated Lab Samples: 926991753
Parameter
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Ieophorone
Naphthalene
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitroeodimethylamine
N-Nitroeo-di-n-propylamine
N-Nitroeodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d5 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Date: 05/26/06
Blank Reporting
Unite Result
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 10.
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 25.
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 25.
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
Limit Footnotes
$ 69
62
$ 78
$ 25
$ 39
$ 74
Asheville Certification IOs
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NC Drinking Water 37712
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REPORT OF LABORATORY ANJ+9.YSiS
This report shall not be reproduced, except in full,
Without the written consent of Pace Analytical Services, Inc.
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Page: 8 of 20

www.pacelarbs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Pax: 704.875.9091
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
LABORATORY CONTROL SAMPLE: 927010306
Parameter
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(k)fluoranthene
Benzo(b)fluoranthene
Benzo(a)anthracene
Benzo(g,h,i)perylene
Benzo(a)pyrene
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-Chloro-3-methylphenol
bis(2-Chloroethoxy)methane
bie(2-Chloroethyl) ether
bie(2-Chloroieopropyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Dibenz(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethylphthalate
2,4-Dimethylphenol
Dimethylphthalate
Di-n-butylphthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
bis(2-Ethylhexyl)phthalate
Fluoranthene
Fluorene
Date: 05/26/06
Spike LCS LCS
Unite Conc. Result % Rec Footnotes
ug/1 50.00 34.60 69
ug/1 50.00 34.98 70
ug/1 50.00 40.22 80
ug/1 100.00 16.62 17
ug/1 50.00 38.68 77
ug/1 50.00 36.63 73
ug/1 50.00 39.93 80
ug/1 50.00 39.87 80
ug/1 50.00 41.93 84
ug/1 50.00 39.90 B0
ug/1 50.00 38.16 76
ug/1 50.00 39.83 80
ug/1 50.00 31.82 64
ug/1 50.00 28.47 57
ug/1 50.00 27.84 56
ug/1 50.00 32.13 64
ug/1 50.00 28.92 58
ug/1 50.00 37.95 76
ug/1 50.00 40.57 81
ug/1 50.00 41.62 83
ug/1 50.00 23.21 46
ug/1 50.00 21.13 42
ug/1 50.00 22.33 45
ug/1 100.00 38.65 39
ug/1 50.00 37.15 74
ug/1 50.00 39.07 78
ug/1 50.00 33.24 66
ug/1 50.00 38.61 77
ug/1 50.00 40.21 80
ug/1 50.00 39.71 79
ug/1 50.00 38.26 76
ug/1 50.00 40.99 82
ug/1 50.00 40.99 82
ug/1 50.00 39.56 79
ug/1 50.00 38.60 77
ug/1 50.00 40.02 80
ug/1 50.00 36.39 73
Asheville Certification 105
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NC Drinking Water 37712
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REPORT OF LABORATORY ANALYSIS
This report shall not ho reproduced. except in full,
without the written consent of Pace Analytical Services, Inc.
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SC 99006
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Page: 9 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kinney Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: 828,252.4618
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
LABORATORY CONTROL SAMPLE: 927010306
Parameter
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitroeodimethylamine
N-Nitroso-di-n-propylamine
N-Nitroeodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,6-Trichlorophenol
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d5 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Date: 05/26/06
Spike LCS LCS
Unite Conc. Result % Rec Footnotes
ug/1 50.00 21.85 44
ug/1 50.00 41.48 83
ug/1 50.00 20.50 41
ug/1 50.00 19.45 39 1
ug/1 50.00 40.31 81
ug/1 50.00 62.28 125
ug/1 50.00 27.89 56
ug/1 50.00 32.41 65
ug/1 50.00 33.02 66
ug/1 50.00 16.34 33
ug/1 50.00 17.19 34
ug/1 50.00 33.10 66
ug/1 50.00 46.77 94
ug/1 50.00 40.80 82
ug/1 50.00 38.87 78
ug/1 50.00 12.80 26
ug/1 50.00 38.20 76
ug/1 50.00 27.06 54
ug/1 50.00 38.95 78
61
63
75
24
35
86
Asheville Certification 105
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
-1.
666
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Page: 10 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 KinceyAvenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: 828,252.4618
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
QC Batch: 15B044
QC Batch Method: EPA 624
Associated Lab Samples:
926991761
Analysis Method: EPA 624
Analysis Description: Volatile GC/MS by 624
METHOD BLANK: 927016360
Associated Lab Samples: 926991761
Parameter
Acrolein
Acrylonitrile
Benzene
Bromodichloromethaae
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
Dibromochloromethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Date: 05/26/06
Blank
Unite Result
ug/1 ND 25.
ug/1 ND 25.
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 10.
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
ug/1 ND 5.0
Asheville Certification IDs
NC Wastewater 40
NO Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
Reporting
Limit Footnotes
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IDg
NO Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Page: 11 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28809
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
METHOD BLANK: 927016360
Associated Lab Samples: 926991761
Blank Reporting
Parameter Unite Result Limit Footnotes
Trichloroethene ug/1 ND 5.0
Trichlorofluoromethane ug/1 ND 5.0
Vinyl chloride ug/1 ND 5.0
Toluene -dB (S) % 98
4-Bromofluorobenzene (S) % 96
Dibromofluoromethane (S) % 93
LABORATORY CONTROL SAMPLE: 927016378
Spike LCS LCS
Parameter Unite Conc. Result Reg Footnotes
Benzene ug/1 20.00 17.80 89
Bromodichloromethane ug/1 20.00 16.75 84
Bromoform ug/1 20.00 17.30 86
Bromomethane ug/1 20.00 25.82 129
Carbon tetrachloride ug/1 20.00 17.48 87
Chlorobenzene ug/1 20.00 17.40 87
Chloroethane ug/1 20.00 18.70 94
2-Chloroethylvinyl ether ug/1 20.00 31.80 159
Chloroform ug/1 20.00 16.36 82
Chloromethane ug/1 20.00 12.54 63
Dibromochloromethane ug/1 20.00 16.73 84
1,2-Dichlorobenzene ug/1 20.00 17.83 89
1,3-Dichlorobenzene ug/1 20.00 17.81 89
1,4-Dichlorobenzene ug/1 20.00 17.47 87
1,1-Dichloroethane ug/1 20.00 16.26 81
1,2-Dichloroethane ug/1 20.00 15.42 77
1,1-Dichloroethene ug/1 20.00 18.71 94
cis-1,2-Dichloroethene ug/1 20.00 17.11 86
trans-1,2-Dichloroethene ug/1 20.00 17.56 88
1,2-Dichloropropane ug/1 20.00 16.51 82
cis-1,3-Dichloropropene ug/1 20.00 15.79 79
trans-1,3-Dichloropropene ug/1 20.00 15.53 78
Ethylbenzene ug/1 20.00 27.01 135
Methylene chloride ug/1 20.00 17.56 88
Date: 05/26/06
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IOs
NC Wastewater 12
NC Drinking Water .37706
SC 99006
FL NELAP E87627
Page: 12 of 20

riaceAnalytical r"
www.pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 26804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
LABORATORY CONTROL SAMPLE: 927016378
Spike LCS LCS
Parameter Unite Conc. Result % Rec Footnotes
1,1,2,2-Tetrachloroethane ug/1 20.00 17.49 88
Tetrachloroethene ug/1 20.00 18.61 93
Toluene ug/1 20.00 17.16 86
1,1,1-Trichloroethane ug/1 20.00 16.76 84
1,1,2-Trichloroethane ug/1 20.00 16.23 81
Trichloroethene ug/1 20.00 17.43 87
Trichlorofluoromethane ug/1 20.00 20.43 102
Vinyl chloride ug/1 20.00 20.47 102
Toluene-d8 (S) 98
4-Bromofluorobenzene (S) 100
Dibromofluoromethane (S) 95
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 927021162 927021170
927003277 Spike MS MSD MS MSD
Parameter Unite Result Conc. Result Result % Rec % Rec RPD Footnotes
Benzene ug/1 0 20.00 23.45 23.47 117 117 0
Bromodichloromethane ug/1 3.769 20.00 25.28 25.71 108 110 2
Bromoform ug/1 0 20.00 21.45 21.70 107 108 1
Bromomethane ug/1 0 20.00 61.71 63.37 308 317 3 2,2
Carbon tetrachloride ug/1 0 20.00 20.02 20.94 100 105 5
Chlorobenzene ug/1 0 20.00 23.23 23.42 116 117 1
Chloroethane ug/1 0 20.00 29.54 29.07 148 145 2
Chloroform ug/1 5.033 20.00 27.25 27.23 111 111 0
Chloromethane ug/1 0 20.00 29.66 30.02 148 150 1
Dibromochloromethane ug/1 0 20.00 23.91 23.94 120 120 0
1,2-Dichlorobenzene ug/1 0 20.00 22.96 23.58 115 118 3
1,3-Dichlorobenzene ug/1 0 20.00 22.35 22.55 112 113 1
1,4-Dichlorobenzene ug/1 0 20.00 22.47 23.20 112 116 3
1,1-Dichloroethane ug/1 0 20.00 22.05 22.41 110 112 2
1,2-Dichloroethane ug/1 0 20.00 22.59 21.46 113 107 5
1,1-Dichloroethene ug/1 0 20.00 25.34 25.05 127 125 1
cis-1,2-Dichloroethene ug/1 0 20.00 23.43 23.28 117 116 1
trans-1,2-Dichloroethene ug/1 0 20.00 23.77 23.79 119 119 0
1,2-Dichloropropane ug/1 0 20.00 22.00 22.22 110 111 1
Date: 05/26/06 Page: 13 of 20
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except In full,
Without the written consent of Pace Analytical Services, Inc.
... y5' IY`(.
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627

Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 927021162 927021170
Parameter
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Toluene -dB (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Date: 05/26/06
927003277 Spike MS MSD MS MSD
Units Result Conc. Result Result % ec % Rec RPD
ug/1 0 20.00 19.32 19.53 97 98 1
ug/1 0 20.00 19.74 19.36 99 97 2
ug/1 0 20.00 25.13 24.42 126 122 3
ug/1 0.4061 20.00 21.27 22.66 104 111 6
ug/1 0 20.00 23.30 24.25 116 121 4
ug/1 0 20.00 24.06 23.53 120 118 2
ug/1 0 20.00 22.72 22.79 114 114 0
ug/1 0 20.00 22.09 22.14 110 111 0
ug/1 0 20.00 22.55 22.01 113 110 2
ug/1 0 20.00 22.59 22.93 113 115 2
ug/1 0 20.00 25.91 26.31 130 132 2
ug/1 0.1412 20.00 27.71 27.44 138 136 1
97 98
98 99
96 98
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
Thls report shall not he reproduced, except in full.
without the written consent of Pace Analytical Services, Inc.
Footnotes
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Page: 14 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
QC Batch: 157609
QC Batch Method: EPA 7470
Associated Lab Samples:
926991753
Analysis Method: EPA 7470
Analysis Description: Mercury, CVAAS, in Water
METHOD BLANK: 926998766
Associated Lab Samples: 926991753
Parameter
Mercury
unite
mg/1
Blank Reporting
Result Limit Footnotes
ND 0.0002
LABORATORY CONTROL SAMPLE: 926998774
Parameter
Mercury
Unite
mg/1
Spike LCS LCS
Conc. Result % Rec Footnotes
0.0025 0.0027 108
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 926998782 926998790
Parameter
Mercury
Date: 05/26/06
Units
mg/1
Asheville Certification I05
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP 687648
926990607 Spike
Result Conc.
0.00001 0.0025
MS MSD MS MSD
Result Result % Rec % Rec RPD Footnotes
0.0028 0.0026 113 105 7
REPORT OF LABORATORY ARALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Page: 15 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Kinney Avenue, Sulte 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
QC Batch: 157730
QC Batch Method: EPA 3010
Associated Lab Samples:
926991753
Analysis Method: SPA 6010
Analysis Description: Metals by Trace ICP
METHOD BLANK: 927004754
Associated Lab Samples: 926991753
Parameter
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Thallium
Zinc
Unite
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
mg/1
Blank Reporting
Result Limit Footnotes
ND 0.0050
ND 0.0050
ND 0.0010
ND 0.0010
ND 0.0020
ND 0.0020
ND 0.0050
ND 0.0050
ND 0.0050
ND 0.0020
ND 0.010
ND 0.010
LABORATORY CONTROL SAMPLE: 927004762
Parameter
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Thallium
Zinc
Date: 05/26/06
Spike LCS LCS
Unite Conc. Result % Rec Footnotes
mg/1 0.5000 0.5300 106
mg/1 0.5000 0.4470 89
mg/1 0.5000 0.4430 89
mg/1 0.5000 0.4480 90
mg/1 0.5000 0.4540 91
mg/1 0.5000 0.4500 90
mg/1 0.5000 0.4470 89
mg/1 0.5000 0.4470 89
mg/1 0.5000 0.4500 90
mg/1 0.2500 0.2600 104
mg/1 0.5000 0.4170 83
mg/1 0.5000 0.4520 90
Asheville Certification IDS
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSES
This report shall not he reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Page: 16 of 20

aceAnalyticaP
www.pacelabs.com
Pace Analytical Services, Inc.
9800 KinceyAvenue, Suite 100
HuntersviNe, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
MATRIX SPIRE: 927004770
Parameter
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Thallium
Zinc
926999798 Spike
Units Result Conc.
mg/1 0 0.5000 0.5250
mg/1 0.06870 0.5000 0.5140
mg/1 0.00010 0.5000 0.4380
mg/1 0 0.5000 0.4270
mg/1 0.00014 0.5000 0.4380
mg/1 0.00057 0.5000 0.4480
mg/1 0.00239 0.5000 0.4390
mg/1 0.00221 0.5000 0.4310
mg/1 0.00224 0.5000 0.4560
mg/1 0.00004 0.2500 0.2560
mg/1 0.00027 0.5000 0.4230
mg/1 0.05410 0.5000 0.4910
MS MS
Result % Rec Footnotes
105
89
88
85
88
90
87
86
91
102
84
87
SAMPLE DUPLICATE: 927004788
Parameter
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Thallium
Zinc
Date: 05/26/06
926992405 DUP
Unite Result Result RPD Footnotes
mg/1 ND ND NC
mg/1 0.00780 0.00980 23 3
mg/1 0.00130 0.00150 9
mg/1 0.00210 0.00210 2
mg/1 0.00720 0.00780 8
mg/1 0.00220 0.00260 18
mg/1 0.01500 0.01600 6
mg/1 0.04500 0.04500 0
mg/1 ND ND NC
mg/1 ND ND NC
mg/1 ND ND NC
mg/1 0.2600 0.2400 6
Asheville Certification !Ds
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANAL.YSCS
This report shall not he reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IDS
NC Wastewater 12
NC Drinking Water .37706
SC 99006
FL NELAP E87627
Page: 17 of 20

• r
www. pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersvllle, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
QC Batch: 157980
QC Batch Method: SPA 420.2
Associated Lab Samples:
926991753
Analysis Method: EPA 420.2
Analysis Description: Phenolics, Total Recoverable
METHOD BLANK: 927014944
Associated Lab Samples: 926991753
Parameter Unite
Phenolics, Total Recoverable mg/1
Blank
Result
ND
Reporting
Limit Footnotes
0.010
LABORATORY CONTROL SAMPLE: 927014951
Parameter Unite
Phenolics, Total Recoverable mg/1
Spike LCS LCS
Conc. Result % Rec Footnotes
0.2500 0.2518 101
MATRIX SPIKE: 927014969
Parameter Unite
Phenolics, Total Recoverable mg/1
926978289
Result
0.1263
Spike MS MS
Conc. Result % Rec Footnotes
0.2500 0.2414 46 2
SAMPLE DUPLICATE: 927014977
Parameter Units
Phenolics, Total Recoverable mg/1
Date: 05/26/06
Asheville Certification 105
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
926978297 DUP
Result Result RPD Footnotes
0.2200 0.1600 30 3
IIEPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc.
i i l JeIac
Charlotte Certification IDs
NG Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Page: 18 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
QC Batch: 157987
QC Batch Method: EPA 335.2
Associated Lab Samplee:
926991761
Analysis Method: EPA 335.2
Analysis Description: Cyanide, Total, Water
METHOD BLANK: 927015115
Associated Lab Samples: 926991761
Parameter
Cyanide
Unite
mg/1
Blank Reporting
Result Limit Footnotes
ND
0.0050
LABORATORY CONTROL SAMPLE: 927015123
Parameter
Cyanide
Unite
mg/1
Spike LCS LCS
Conc. Result % Rec Footnotes
0.1000 0.0958 96
MATRIX SPIKE: 927015131
Parameter
Cyanide
927014407 Spike MS MS
Unite Result Conc. Result % Rec Footnotes
mg/1 0.00070 0.1000 0.0583 58 2
SAMPLE DUPLICATE: 927015149
Parameter
Cyanide
Date: 05/26/06
Unite
mg/1
Asheville Certification lDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
926991233
Result
ND
DUP
Result RPD Footnotes
ND NC
REPORT OF LABORATORY ANALYSES
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Page: 19 of 20

www.pacelabs.com
Pace Analytical Services, Inc.
9800 Klncey Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax: [phone]
Pace Analytical Services, Inc.
2225 Riverside Drive
Asheville, NC 28804
Phone: [phone]
Fax: [phone]
Lab Project Number: 92119559
Client Project ID: Priority Pollutants/2006 Permt
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines, unrounded concentrations are displayed and have been used to calculate % Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DIP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
[1] The surrogate and/or spike recovery was outside acceptance limits.
[2] The spike recovery was outside acceptance limits for the MS and /or MSD due to matrix interference. The LCS
and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is
acceptable.
[3] The calculated RPD was outside QC acceptance limits.
Date: 05/26/06
Asheville Certification IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
Thts report shall not he reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
:tl .s
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water .37706
SC 99006
FL NELAP E87627
Page: 20 of 20