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HomeMy WebLinkAboutWQ0038087_Residual Annual Report 2020_20210226Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* WQ0038087 Applicant/Permittee Terra Renewal Services, Inc Email Notifications Does this need review by the hydrogeologist?* 0 Yes r No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Rease provide information on the person to be contacted by N B Staff regarding electibnittal, confirmation of receipt, other .......................................................... electronic surece, aner correspondence. _ - Name * Terra Renewal Services Email Address* david.coyle@terrarenewa I. com Project Information ........ ......... ............................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 4797478192 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 IT Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00038087 Fbs CLrrent Existing pernit number Applicant/Permittee Address* P.O. Box 1746 Watkinsville, GA 30677 Facility Name * Terra Renewal Services RLAP Please provide comments/notes on your current submittal below. This is the 2020 annual report for permit # WQ0038087. This in an RLAP based with land sites in Wilkes & Yadkin Counties. There will be NO hard copy submitted. The pdf document is "bookmarked" for easier navigation. If there are any complications or requests for additional information, please contact David Coyle @ 479-747-8192 or david.coyle@terrarenevval.com. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Rans, Specifications, Calculations, Rc.) NC WQ0038087 Terra Renewal Services Annual — — — 7.21 MB Report-2020.pdf upload only 1 FLFdocurrent (less than 250 NB). Witiple docurrents must be combined into one RDFfile unless file is larger than upload linit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/26/2021 M fV TERRA renal PO BOX 399 • DARDANELLE • ARKANSAS • 72834 479.747.8192 terrarenewal.com 2020 ANNUAL REPORT for NC Land Application Permit Number: WQ0038087 (Class B Residuals) Permittee / Submitted By: Terra Renewal Services P.O. Box 399 Dardanelle, AR 72834 Attention: North Carolina Department of Environmental Quality Division of Water Resources Water Quality Permitting Section Non -Discharge Permitting Unit 512 N. Salisbury Street; 6t" Floor Raleigh, NC 27604 TERRA renewal February 25, 2021 North Carolina Department of Environmental Quality Division of Water Resources Water Quality Permit Section Non -Discharge Permitting Unit Information Processing Unit 6th Floor 512 N. Salisbury Street Raleigh, NC 27699 East Region Environmental Office P.O. Box 1746 Watkinsville, GA 30677 phone 479.747.8192 RE: 2020 Annual Report for Land Application Permit No. WQ0038087 Permittee: Terra Renewal Services, Inc Dear Sir or Madam, The enclosed documentation is intended to serve as the annual report for the land application of residuals sources related to the above referenced permit in Wilkes and Yadkin Counties. The following information is provided: PPrmittPP- Terra Renewal Services, Inc. P.O. Box 399 Dardanelle, AR 72834 Preparer & Contact: Terra Renewal Services, Inc David C. Coyle; Environmental Manager P.O. Box 1746 Watkinsville, GA 30677 phone: 479-747-8192 email: david.coyleCcDterrarenewal.com These items are included with the report (in order): 1) The Annual Land Application Certification Form (ACF) 2) The Annual Residuals Sampling Summary Form (RSSF) and Annual Residuals Sampling Summary Form — B (RSSF-B) for each residuals source 3) The Annual Metals Field Loading Summary Form (MFLSF), Annual Land Application Field Summary Form (FSF), and Annual Land Application Field Summary Form Supplement (FSF- SUP) 4) Lab Analyses for Residuals: — Nutrients, Metals, TCLP, Other — Fecal Density (Seven Set) 5) Annual Pathogen and Vector Attraction Reduction Form for NCAC 2T Rules (PVRF 2T) 6) Soil Test Reports (for fields applied in 2020) Page 2 2020 Annual Report WQ0038087 7) Complimentary Data — Executive Summary — Fecal Analysis Summary — Soil Result (pH) Summary — Poultry Litter Analysis Summary and Poultry Litter Analyses On the Annual Land Application Certification Form (ACF), the option "No" is selected under Part B — Annual Compliance Statement for the statement "Facility was compliant during calendar year 2020 with all conditions of the land application permit issued by the Division of Water Resources". The reasons for this are as follows: Item-2 — "Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. " — Lime was applied to these sites in 2020 in the spring (2 tons/ac) and fall (1 ton/ac). Soil samples collected in December 2020 resulted in pH values < 6.0 on fields NC-YK-DM-05, NC-WK-YK-DM-08, NC-WK-MF-10, NC-WK-MF-13, NC-WK-MF-14. Of these fields, NC- WK-YK-DM-08 and NC-WK-MF-10 had pH values of < 6.0 in the previous year. Lime was applied to all of these fields. It can take time for pH adjustment to occur, often six months to one year depending on ambient conditions. Additional lime will be applied prior to planting in the spring of 2021. It should be noted that the requirement for pH maintenance > 6.0 as related to the land application of residuals was removed from this permit during renewal and modification in February 2021. Terra Renewal and its cooperating farmers understand the rationale and importance of maintaining soil pH at optimum agronomic levels. If additional information is required or there are any questions regarding this annual report, please contact David Coyle via the information listed above. Thank you for your cooperation and attention to this matter. Sincerely, David C. Coyle Environmental Manager NC LSS #1315 1 Annual Land Application Certification Form (ACF) ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0038087 County: Wilkes & Yadkin Year: Facility Name (as shown on permit): Land Application Operator: Terra Renewal Services, Inc 2020 Terra Renewal Services, Inc Phone: 479-747-8192 Land application of residuals as allowed by the permit occurred during the past calendar year? 0 Yes ❑ No - If No, slip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of application fields in the permit: 60 Total number of fields utilized for land application during the year: 25 Total amount of dry tons applied during the year for all application sites: 1,417 Total number of acres utilizes for land application during the year: 573 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. ❑ Yes ® No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T . I I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." David C. Coyle; Environmental Manager Permittee Name and Title (type or print) �5,- 2/25/2021 Signature of Permittee Date Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2 Annual Residuals Sampling Summary Form (RSSF) Annual Residuals Sampling Summary Form — B (RSSF-B) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: MiWiTA_Y_Ai;V= Residual Analysis Data WQ0038087 Terra Renewal Services, Inc AdvancePierre Foods - Claremont, NC Laboratory: 1) 2) 3) 4) 5) Shealy Environmental Services Parameter (mg/kg) Cone. Limit (m /lc )a Sample or Composite Date 3/26/20 5/19/20 9/17/20 12/3/20 Percent Solids (%) NA 4.44 6.55 2.3 2.66 Arsenic 75 < 5.6 < 3.6 < 11 < 9.3 Cadmium 85 < 1.9 < 1.2 < 3.5 < 3.1 Copper 4,300 870 31 1200 490 Chromium NA Lead 840 4.2 < 2.4 < 7.0 < 6.2 Mercury 57 < 1.8 < 1.1 < 3.3 < 2.8 Molybdenum 75 < 15 < 9.7 < 28 < 25 Nickel 420 22 < 9.7 < 28 < 25 Selenium 100 < 7.4 < 4.8 < 14 < 12 Zinc 7,500 160 37 190 82 Total Phosphorus NA 7000 1900 860 14000 TKN NA 1900 1500 16000 51000 Ammonia -Nitrogen NA < 230 220 460 550 Nitrate and Nitrite NA 24 16 58 260 'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 Signature of Preparer * *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Residual Source NPDES # or WQ#: WWTP Name: Residual Analvsis Data WQ0038087 Terra Renewal Services AdvancePierre Foods - Claremont, NC Laboratory: 1) 2) 3) 4) 5) Shealy Environmental Services Sample or • • - Date Parameter 11 • 1 111 111 -------- • 11 11 11 11 -------- - • 11 11 11 11 -------- '• •11 111 •11 11 -------- •• ------------ ------------ ------------ ------------ ------------ ------------ "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF - B (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: MiWiTA_Y_Ai;V= Residual Analysis Data WQ0038087 Terra Renewal Services, Inc RVAF (Tyson) - Harmony, NC Laboratory: 1) 2) 3) 4) 5) Shealy Environmental Services Parameter (mg/kg) Cone. Limit (m /lc )a Sample or Composite Date 3/26/20 5/19/20 9/8/20 11/19/20 Percent Solids (%) NA 4.21 2.53 4.48 9.44 Arsenic 75 < 5.8 < 9.5 < 5.5 < 2.6 Cadmium 85 < 1.9 < 3.2 < 1.8 < 0.87 Copper 4,300 39 22 10 < 1.7 Chromium NA Lead 840 < 3.9 < 6.4 5.9 < 1.7 Mercury 57 < 1.9 < 2.9 < 1.7 < 0.9 Molybdenum 75 < 15 < 26 < 15 < 7.0 Nickel 420 < 15 < 26 < 15 < 7.0 Selenium 100 < 7.7 < 13 < 7.4 < 3.5 Zinc 7,500 150 170 57 < 8.7 Total Phosphorus NA 23000 22000 4700 4500 TKN NA 22000 54000 32000 20000 Ammonia -Nitrogen NA 17000 36000 21000 6800 Nitrate and Nitrite NA 27 43 90 12 'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." e :5�,- 2/25/2021 Signature of Preparer * *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Residual Source NPDES # or WQ#: WWTP Name: Residual Analvsis Data WQ0038087 Terra Renewal Services RVAF (Tyson) - Harmony, NC Laboratory: 1) 2) 3) 4) 5) Shealy Environmental Services Sample or • • - Date Parameter 1111 111 111 • 1 -------- • 111 •111 •111 11 -------- - 111 11 :11 1 -------- ' • 11 11 11 11 -------- •• 111 111 •11 11 -------- ------------ ------------ ------------ ------------ ------------ ------------ "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer * *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) 2/25/2021 Date DENR FORM RSSF - B (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: MiTAIiTA_Y_Ai;V= Residual Annlvsis Data WQ0038087 Terra Renewal Services, Inc Tyson - Wilkesboro, NC Laboratory: 1) 2) 3) 4) 5) Shealy Environmental Services Parameter (mg/kg) Cone. Limit (mg/kg) a Sample or Composite Date 2/27/20 4/2/20 5/19/20 9/8/20 11/19/20 Percent Solids (%) NA 4.73 4.73 3.13 8.42 6.15 Arsenic 75 < 15 < 5.1 < 7.7 < 2.8 < 4.0 Cadmium 85 < 5.1 < 1.7 < 2.6 < 0.94 < 1.3 Copper 4,300 59 16 97 8.2 31 Chromium NA Lead 840 15 < 3.4 < 5.1 < 1.9 < 2.7 Mercury 57 < 1.6 < 1.6 < 2.4 < 0.89 < 1.2 Molybdenum 75 < 41 < 14 < 21 < 7.5 < 11 Nickel 420 < 41 < 14 < 21 < 7.5 < 11 Selenium 100 < 20 < 6.9 < 10 < 3.8 < 5.4 Zinc 7,500 170 89 2600 15 69 Total Phosphorus NA 4500 4000 6200 450 3800 TKN NA 73000 43000 71000 6200 93000 Ammonia -Nitrogen NA 2100 2600 3500 1400 1500 Nitrate and Nitrite NA 16 19 31 33 19 'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 Signature of Preparer * *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Residual Source NPDES # or WQ#: WWTP Name: Residual Analvsis Data WQ0038087 Terra Renewal Services, Inc Tyson -Wilkesboro, NC Laboratory: 1) 2) 3) 4) 5) Shealy Environmental Services Sample or Composite Date Parameter (mg/kg) 2/27/20 4/2/20 5/19/20 9/8/20 11/19/20 Aluminum < 410 < 140 370 220 140 Calcium < 5100 < 1700 < 2600 < 940 < 1300 Magnesium < 5100 < 1700 < 2600 < 940 < 1300 Potassium < 5100 4800 < 2600 < 940 < 1300 Sodium < 5100 2500 3300 < 940 1700 PAN 30476 18779 30531 3353 38119 SAR (no units) 2.6 2.2 1.9 1.5 2.0 pH (SU) 3.7 4.1 3.7 4.8 4.2 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF - B (12/2006) 3 Annual Metals Field Loading Summary Form (MFLSF) Annual Land Application Field Summary Form (FSF) Annual Land Application Field Summary Form Supplement (FSF-SUPP) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 48.16 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 21.8 Acres Permitted: 21.8 Site #: WK-CH-01 Field #: 7.9 Danripple WK-CH-01 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 5 6 7 8 9 10 11 12 % Solids 6.6 2.5 3.1 Arsenic 3.6 9.5 7.7 Cadmium 1.2 3.2 2.6 Copper 31.0 22.0 97.0 Chromium Lead 2.4 6.4 5.1 Mercury 1.1 2.9 2.4 Molyb- denum 9.7 26.0 21.0 Nickel 9.7 26.0 21.0 Selenium 4.8 13.0 10.0 Zinc 37.0 170.0 2600.0 Total Phos- horus 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.76 0.63 0.82 Arsenic 0.005 0.012 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Cadmium 0.002 0.004 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.047 0.028 0.159 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.234 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.004 0.008 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.020 Mercury 0.002 0.004 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Molyb- 0.015 0.033 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.082 denum Nickel 0.015 0.033 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.082 Selenium 0.007 0.016 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 Zinc 0.056 0.215 4.254 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.524 Total Phos- 2.888 27.764 10.143 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 40.795 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 2/25/2021 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-CH-01 Acres Utilized: 21.8 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 33.2516 Site #: WK-CH-01 Acres Permitted: 21.8 Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 7.9 Crop 1 Name: Corn Silage Crop 1 Max. PAN: 141 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Jul 6000 6.6 0.076 Advance -Pierre INC 1 0.4 1 1500 220 1 16 0.113 NA Corn-s Jul 132000 2.5 0.631 RVAF INC 1 0.4 54000 36000 43 54.593 NA Corn-s Jul 138000 3.1 0.818 Tyson -Wilkes INC 1 0.4 71000 3500 31 49.968 NA Corn-s 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 43.6 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 43.61 276000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 138.075 FO.000 Lime Applied Annuallbs/acre 0.030 0.010 0.234 0.000 0.020 0.009 0.082 0.082 0.040 4.524 40.795 Date lbs/ac Prior Years Cumulative lbs/ac 0.178 0.075 0.488 0.000 0.152 0.024 0.304 0.305 0.205 5.101 Apr 4000 Current Cumulative lbs/ac 0.208 0.085 0.722 0.000 0.172 0.033 0.386 0.387 0.245 9.625 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop 1 141 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: W00038087 Field #: WK-CH-01 Acres Utilized: 21.8 Land Owner: Mathis Properties Annual Dry Tons Applied: Site #: WK-CH-01 Acres Permitted: 21.8 Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 7.9 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 141.00 Crop 2 Name: Crop 2 Max PAN: 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. (Dry, wet Moist) Precip. Past 24 Hrs. inches a co w L o ? * �. Z `; TKN mg/kg Z a o mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual Application pp Crop 1 Crop 2 Crop 1 Crop 2 April 43.6 1 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 413.61 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 78.46 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 41.6 Acres Permitted: 41.6 Site #: WK-CH-03 Field #: 6.18 Banister WK-CH-03 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 5 6 7 8 9 10 11 12 % Solids 6.6 2.5 3.1 Arsenic 3.6 9.5 7.7 Cadmium 1.2 3.2 2.6 Copper 31.0 22.0 97.0 Chromium Lead 2.4 6.4 5.1 Mercury 1.1 2.9 2.4 Molyb- denum 9.7 26.0 21.0 Nickel 9.7 26.0 21.0 Selenium 4.8 13.0 10.0 Zinc 37.0 170.0 2600.0 Total Phos- horus 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. 14 Event 0.00 0.77 1.12 Arsenic 0.000 0.015 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 Cadmium 0.000 0.005 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Copper 0.000 0.034 0.217 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.251 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.010 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.021 Mercury 0.000 0.004 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Molyb- 0.000 0.040 0.047 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.087 denum Nickel 0.000 0.040 0.047 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.087 Selenium 0.000 0.020 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 Zinc 0.000 0.261 5.819 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.080 Total Phos- 0.000 33.748 13.876 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 47.624 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-CH-03 Acres Utilized: 41.6 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 78.4377 Site #: WK-CH-03 Acres Permitted: 41.6 Operator: Terra Renewal Services Predominant Soil Series: Banister Cation Exchange Capacity (non 503): 6.18 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 225 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Jul -Aug 0 6.6 0.000 Advance -Pierre INC 1 0.4 1 1500 220 1 16 0.000 NA Corn-s Jul -Aug 306000 2.5 0.767 RVAF INC 1 0.4 54000 36000 43 66.321 NA Corn-s Jul -Aug 360000 3.1 1.119 Tyson -Wilkes INC 1 0.4 71000 3500 31 68.309 NA Corn-s 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 83.2 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 83.2 666000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 168.030 FO.000 Lime Applied Annuallbs/acre 0.032 0.213 0.011 0.090 0.251 0.891 0.000 0.000 0.021 0.180 0.010 0.035 0.087 0.377 0.087 0.378 0.042 0.247 6.080 6.808 47.624 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.245 0.100 1.142 0.000 0.201 0.044 0.464 0.465 0.289 12.888 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 225 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-CH-03 Acres Utilized: 41.6 Annual Dry Tons Applied: Site #: WK-CH-03 Acres Permitted: 41.6 Predominant Soil Series: Banister Cation Exchange Capacity (non 503): 6.18 Crop 1 Max. PAN: 225.00 Crop 2 Name: Crop 2 Max PAN: 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. ADD wet,' Moist) precip. Past 24 Hrs. inches a a - a w o ? * �. Z ,c `I TKN mg/kg Z a o � mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 83.2 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 83.21 0 0.000 E33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 75.86 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 35.8 Acres Permitted: 35.8 Site #: WK-CH-04 Field #: 6.07 Codorus WK-CH-04 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 5 6 7 8 9 10 11 12 % Solids 6.6 2.5 3.1 Arsenic 3.6 9.5 7.7 Cadmium 1.2 3.2 2.6 Copper 31.0 22.0 97.0 Chromium Lead 2.4 6.4 5.1 Mercury 1.1 2.9 2.4 Molyb- denum 9.7 26.0 21.0 Nickel 9.7 26.0 21.0 Selenium 4.8 13.0 10.0 Zinc 37.0 170.0 2600.0 Total Phos- horus 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. 14 Event 0.05 0.75 1.32 Arsenic 0.000 0.014 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.035 Cadmium 0.000 0.005 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Copper 0.003 0.033 0.256 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.292 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.010 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.023 Mercury 0.000 0.004 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Molyb- 0.001 0.039 0.056 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.095 denum Nickel 0.001 0.039 0.056 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.095 Selenium 0.000 0.020 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.046 Zinc 0.003 0.255 6.874 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7.133 Total Phos- 0.175 33.044 16.393 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 49.612 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-CH-04 Acres Utilized: 35.8 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 75.8606 Site #: WK-CH-04 Acres Permitted: 35.8 Operator: Terra Renewal Services Predominant Soil Series: Codorus Cation Exchange Capacity (non 503): 6.07 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 213 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Jul 6000 6.6 0.046 Advance -Pierre INC 1 0.4 1 1500 220 1 16 0.069 NA Corn-s Jul 258000 2.5 0.751 RVAF INC 1 0.4 54000 36000 43 64.977 NA Corn-s Jul 366000 3.1 1.322 Tyson -Wilkes INC 1 0.4 71000 3500 31 80.699 NA Corn-s 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 71.6 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 71.61 630000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 179.145 FO.000 Lime Applied Annuallbs/acre 0.035 0.224 0.012 0.094 0.292 0.712 0.000 0.000 0.023 0.191 0.011 0.034 0.095 0.391 0.095 0.392 0.046 0.259 7.133 8.011 49.612 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.259 0.106 1.004 0.000 0.214 0.045 0.487 0.487 0.305 15.145 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop 1 213 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-CH-04 Acres Utilized: 35.8 Annual Dry Tons Applied: Site #: WK-CH-04 Acres Permitted: 35.8 Predominant Soil Series: Codorus Cation Exchange Capacity (non 503): 6.07 Crop 1 Max. PAN: 213.00 Crop 2 Name: Crop 2 Max PAN: 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. ADD wet,' Moist) precip. Past 24 Hrs. inches a a - a w o ? * �. Z ,c `I TKN mg/kg Z a o � mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 71.6 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 71.61 0 0.000 E33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 68.63 Permit #: Operator: Acres Used: WQ0038087 Cation Exchange Capacity (non 503 only): Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series: 21.0 Acres Permitted: 21.0 Site #: WK-DM-05 Field #: 4.4 Clifford W K-DM-05 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 4/2/20 4 Advance Pierre 9/17/20 5 RVAF 9/8/20 6 Tyson- Wilkes 9/8/20 7 8 9 10 j 12 % Solids 4.4 4.2 4.7 2.3 4.5 8.4 Arsenic 5.6 5.8 5.1 11.0 5.5 2.8 Cadmium 1 1.9 1.9 1.7 3.5 1.8 0.9 Copper 1 870.0 39.0 16.0 1200.0 10.0 8.2 Chromium Lead 4.2 3.9 3.4 7.0 5.9 1.9 Mercury 1.8 1.9 1.6 3.3 1.7 0.9 Molyb- denum 15.0 15.0 14.0 28.0 15.0 7.5 Nickel 22.0 15.0 14.0 28.0 15.0 7.5 Selenium 7.4 7.7 6.9 14.0 7.4 3.8 Zinc 160.0 150.0 89.0 190.0 57.0 15.0 Total Phos- horus 7,000 23,000 4,000 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. '~ 14 Event 0.00 0.60 0.78 0.00 0.48 1.40 Arsenic 0.000 0.007 0.008 0.000 0.005 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.028 Cadmium 0.000 0.002 0.003 0.000 0.002 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Copper 0.000 0.047 0.025 0.000 0.010 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.105 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.005 0.005 0.000 0.006 0.005 0.000 0.000 0.000 0.000 0.000 0.000 1 0.021 Mercury 0.000 0.002 0.003 0.000 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Molyb- 0.000 0.018 0.022 0.000 0.014 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.075 denum Nickel 0.000 0.018 0.022 0.000 0.014 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.075 Selenium 0.000 0.009 0.011 0.000 0.007 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.038 Zinc 0.000 0.180 0.140 0.000 0.055 0.042 0.000 0.000 0.000 0.000 0.000 0.000 0.417 Total Phos- 0.000 27.600 6.272 0.000 4.540 1.261 0.000 0.000 0.000 0.000 0.000 0.000 39.673 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 2/25/2021 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-DM-05 Acres Utilized: 21.0 Land Owner: George F Ireland Trust Annual Dry Tons Applied: 68.6299 Site #: WK-DM-05 Acres Permitted: 21.0 Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.4 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 204 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 1 1 � o, o w * Z o ? P_a 0 ��, K � cr. Zmg/kg TKN Z a a o Ei .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Jun 0 4.4 0.000 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.000 NA Corn-s Jun 72000 4.2 0.600 RVAF INC 1 0.4 22000 17000 27 22.851 NA Corn-s Jun 84000 4.7 0.784 Tyson -Wilkes INC 1 0.4 43000 2600 19 29.444 NA Corn-s Oct -Nov 0 2.3 0.000 Advance -Pierre INC 1 0.4 16000 460 58 Na 0.000 S.G. Oct -Nov 54000 4.5 0.483 RVAF INC 1 0.4 32000 21000 90 Na 24.599 S.G. Oct -Nov 84000 8.4 1.401 Tyson -Wilkes INC 1 0.4 6200 1400 33 Na 9.396 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 42 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 42T 294000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 85.695 33.995 Lime Applied Annuallbs/acre 0.028 0.009 0.105 0.000 0.021 0.009 0.075 0.075 0.038 0.417 39.673 Date lbs/ac Prior Years Cumulative lbs/ac 0.130 0.049 0.471 0.000 0.102 0.033 0.279 0.280 0.160 0.831 Apr 4000 Current Cumulative lbs/ac 0.158 0.059 0.576 0.000 0.123 0.042 0.355 0.355 0.198 1.248 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop F 204 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: George F Ireland Trust Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-DM-05 Acres Utilized: 21.0 Annual Dry Tons Applied: Site #: WK-DM-05 Acres Permitted: 21.0 Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.4 Crop 1 Max. PAN: 204.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. ADD wet,' Moist) precip. Past 24 Hrs. inches a a - a w o ? * �. Z ,c `I TKN mg/kg Z a o � mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 42 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 421 0 0.000 E33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 115.74 Permit #: Operator: Acres Used: WQ0038087 Cation Exchange Capacity (non 503 only): Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series: 25.6 Acres Permitted: 25.6 Site #: WK-DM-06 Field #: 4.1 Clifford W K-DM-06 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 4/2/20 4 Advance Pierre 9/17/20 5 RVAF 9/8/20 6 Tyson- Wilkes 9/8/20 7 8 9 10 j 12 % Solids 4.4 4.2 4.7 2.3 4.5 8.4 Arsenic 5.6 5.8 5.1 11.0 5.5 2.8 Cadmium 1 1.9 1.9 1.7 3.5 1.8 0.9 Copper 1 870.0 39.0 16.0 1200.0 10.0 8.2 Chromium Lead 4.2 3.9 3.4 7.0 5.9 1.9 Mercury 1.8 1.9 1.6 3.3 1.7 0.9 Molyb- denum 15.0 15.0 14.0 28.0 15.0 7.5 Nickel 22.0 15.0 14.0 28.0 15.0 7.5 Selenium 7.4 7.7 6.9 14.0 7.4 3.8 Zinc 160.0 150.0 89.0 190.0 57.0 15.0 Total Phos- horus 7,000 23,000 4,000 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 3 4 5 J 7 8 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.04 0.99 1.47 0.00 0.79 1.23 Arsenic 0.000 0.011 0.015 0.000 0.009 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.043 Cadmium 0.000 0.004 0.005 0.000 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Copper 0.075 0.077 0.047 0.000 0.016 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.235 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.008 0.010 0.000 0.009 0.005 0.000 0.000 0.000 0.000 0.000 0.000 1 0.032 Mercury 0.000 0.004 0.005 0.000 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Molyb- 0.001 0.030 0.041 0.000 0.024 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.114 denum Nickel 0.002 0.030 0.041 0.000 0.024 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.115 Selenium 0.001 0.015 0.020 0.000 0.012 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Zinc 0.014 0.296 0.262 0.000 0.090 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.698 Total Phos- 0.602 45.310 11.760 0.000 7.445 1.108 0.000 0.000 0.000 0.000 0.000 0.000 66.225 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-DM-06 Acres Utilized: 25.6 Land Owner: George F Ireland Trust Annual Dry Tons Applied: 115.7425 Site #: WK-DM-06 Acres Permitted: 25.6 Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.1 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 200 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 1 1 � o, o w * Z o ? P_a 0 ��, K � cr. Zmg/kg TKN Z a a o Ei .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 May -Jun 6000 4.4 0.043 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.079 NA Corn-s May -Jun 144000 4.2 0.985 RVAF INC 1 0.4 22000 17000 27 37.489 NA Corn-s May -Jun 192000 4.7 1.470 Tyson -Wilkes INC 1 0.4 43000 2600 19 55.207 NA Corn-s Oct -Nov 0 2.3 0.000 Advance -Pierre INC 1 0.4 16000 460 58 Na 0.000 S.G. Oct -Nov 108000 4.5 0.792 RVAF INC 1 0.4 32000 21000 90 Na 40.358 S.G. Oct -Nov 90000 8.4 1.231 Tyson -Wilkes INC 1 0.4 6200 1400 33 Na 8.258 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 51.2 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 51.2 540000 As Cd Cu Cr Pb H Mo Ni Se Zn P 126,176 48.616 Lime Applied Annuallbs/acre 0.043 0.014 0.235 0.000 0.032 0.013 0.114 0.115 0.057 0.698 66.225 Date lbs/ac Prior Years Cumulative lbs/ac 0.139 0.052 0.560 0.000 0.109 0.036 0.307 0.308 0.173 1.091 Apr 4000 Current Cumulative lbs/ac 0.181 0.066 0.795 0.000 0.141 0.049 0.421 0.423 0.230 1.789 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop F 200 1 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." e 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: George F Ireland Trust Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-DM-06 Acres Utilized: 25.6 Annual Dry Tons Applied: Site #: WK-DM-06 Acres Permitted: 25.6 Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.1 Crop 1 Max. PAN: 200.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. ADD wet,' Moist) precip. Past 24 Hrs. inches a a - a w o ? * �. Z ,c `I TKN mg/kg Z a o � mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 51.2 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 51.21 0 0.000 E33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 148.96 Permit #: Operator: Acres Used: WQ0038087 Cation Exchange Capacity (non 503 only): 4.1 Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series: Clifford 31.5 Acres Permitted: 31.5 Site #: WK-YK-DM-07 Field #: WK-YK-DM-07 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 4/2/20 4 Advance Pierre 9/17/20 5 RVAF 9/8/20 6 Tyson- Wilkes 9/8/20 7 8 9 10 j 12 % Solids 4.4 4.2 4.7 2.3 4.5 8.4 Arsenic 5.6 5.8 5.1 11.0 5.5 2.8 Cadmium 1 1.9 1.9 1.7 3.5 1.8 0.9 Copper 1 870.0 39.0 16.0 1200.0 10.0 8.2 Chromium Lead 4.2 3.9 3.4 7.0 5.9 1.9 Mercury 1.8 1.9 1.6 3.3 1.7 0.9 Molyb- denum 15.0 15.0 14.0 28.0 15.0 7.5 Nickel 22.0 15.0 14.0 28.0 15.0 7.5 Selenium 7.4 7.7 6.9 14.0 7.4 3.8 Zinc 160.0 150.0 89.0 190.0 57.0 15.0 Total Phos- horus 7,000 23,000 4,000 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 3 4 5 J 7 8 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.04 0.73 1.76 0.02 0.79 1.40 Arsenic 0.000 0.009 0.018 0.000 0.009 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Cadmium 0.000 0.003 0.006 0.000 0.003 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Copper 0.061 0.057 0.056 0.043 0.016 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.256 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.006 0.012 0.000 0.009 0.005 0.000 0.000 0.000 0.000 0.000 0.000 1 0.033 Mercury 0.000 0.003 0.006 0.000 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Molyb- 0.001 0.022 0.049 0.001 0.024 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.118 denum Nickel 0.002 0.022 0.049 0.001 0.024 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.118 Selenium 0.001 0.011 0.024 0.001 0.012 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.059 Zinc 0.011 0.220 0.312 0.007 0.090 0.042 0.000 0.000 0.000 0.000 0.000 0.000 0.682 Total Phos- 0.490 33.764 14.040 0.031 7.388 1.261 0.000 0.000 0.000 0.000 0.000 0.000 56.974 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-YK-DM-07 Acres Utilized: 31.5 Land Owner: George F Ireland Trust Annual Dry Tons Applied: 148.9691 Site #: WK-YK-DM-07 Acres Permitted: 31.5 Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.1 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 196 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 1 1 � o, o w * Z o ? P_a 0 ��, K � cr. Zmg/kg TKN Z a a o Ei .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 May 6000 4.4 0.035 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.064 NA Corn-s May 132000 4.2 0.734 RVAF INC 1 0.4 22000 17000 27 27.929 NA Corn-s May 282000 4.7 1.755 Tyson -Wilkes INC 1 0.4 43000 2600 19 65.898 NA Corn-s Nov 6000 2.3 0.018 Advance -Pierre INC 1 0.4 16000 460 58 Na 0.246 S.G. Nov 132000 4.5 0.786 RVAF INC 1 0.4 32000 21000 90 Na 40.088 S.G. Nov 126000 8.4 1.401 Tyson -Wilkes INC 1 0.4 6200 1400 33 Na 9.396 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 63 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 63 684000 As Cd Cu Cr Pb H Mo Ni Se Zn P 127,291 49.730 Lime Applied Annuallbs/acre 0.044 0.014 0.256 0.000 0.033 0.014 0.118 0.118 0.059 0.682 56.974 Date lbs/ac Prior Years Cumulative lbs/ac 0.147 0.055 0.694 0.000 0.115 0.038 0.324 0.325 0.182 1.109 Apr 4000 Current Cumulative lbs/ac 0.190 0.070 0.950 0.000 0.147 0.051 0.442 0.443 0.241 1.792 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop F 196 1 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation ctf�**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: George F Ireland Trust Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-YK-DM-07 Acres Utilized: 31.5 Annual Dry Tons Applied: Site #: WK-YK-DM-07 Acres Permitted: 31.5 Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.1 Crop 1 Max. PAN: 196.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. ADD wet,' Moist) precip. Past 24 Hrs. inches a a - a w o ? * �. Z ,c `I TKN mg/kg Z a o � mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 63 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 631 0 0.000 E33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 126.05 Permit #: Operator: Acres Used: WQ0038087 Cation Exchange Capacity (non 503 only): 4.5 Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series: Clifford 24.6 Acres Permitted: 24.6 Site #: WK-YK-DM-08 Field #: WK-YK-DM-08 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 4/2/20 4 Advance Pierre 9/17/20 5 RVAF 9/8/20 6 Tyson- Wilkes 9/8/20 7 8 9 10 j 12 % Solids 4.4 4.2 4.7 2.3 4.5 8.4 Arsenic 5.6 5.8 5.1 11.0 5.5 2.8 Cadmium 1 1.9 1.9 1.7 3.5 1.8 0.9 Copper 1 870.0 39.0 16.0 1200.0 10.0 8.2 Chromium Lead 4.2 3.9 3.4 7.0 5.9 1.9 Mercury 1.8 1.9 1.6 3.3 1.7 0.9 Molyb- denum 15.0 15.0 14.0 28.0 15.0 7.5 Nickel 22.0 15.0 14.0 28.0 15.0 7.5 Selenium 7.4 7.7 6.9 14.0 7.4 3.8 Zinc 160.0 150.0 89.0 190.0 57.0 15.0 Total Phos- horus 7,000 23,000 4,000 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. '~ 14 Event 0.05 0.77 2.44 0.02 0.82 1.03 Arsenic 0.001 0.009 0.025 0.001 0.009 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.050 Cadmium 0.000 0.003 0.008 0.000 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.016 Copper 0.078 0.060 0.078 0.055 0.016 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.305 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.006 0.017 0.000 0.010 0.004 0.000 0.000 0.000 0.000 0.000 0.000 1 0.037 Mercury 0.000 0.003 0.008 0.000 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.016 Molyb- 0.001 0.023 0.068 0.001 0.025 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.134 denum Nickel 0.002 0.023 0.068 0.001 0.025 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.135 Selenium 0.001 0.012 0.034 0.001 0.012 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.067 Zinc 0.014 0.231 0.434 0.009 0.094 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.812 Total Phos- 0.630 35.374 19.504 0.040 7.746 0.923 0.000 0.000 0.000 0.000 0.000 0.000 64.216 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-YK-DM-08 Acres Utilized: 24.6 Land Owner: George F Ireland Trust Annual Dry Tons Applied: 126.0508 Site #: WK-YK-DM-08 Acres Permitted: 24.6 Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.5 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 189 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 1 1 � o, o w * Z o ? P_a 0 ��, K � cr. Zmg/kg TKN Z a a o Ei .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Apr -May 6000 4.4 0.045 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.083 NA Corn-s Apr -May 108000 4.2 0.769 RVAF INC 1 0.4 22000 17000 27 29.260 NA Corn-s Apr -May 306000 4.7 2.438 Tyson -Wilkes INC 1 0.4 43000 2600 19 91.564 NA Corn-s Nov 6000 2.3 0.023 Advance -Pierre INC 1 0.4 16000 460 58 Na 0.315 S.G. Nov 108000 4.5 0.824 RVAF INC 1 0.4 32000 21000 90 Na 41.999 S.G. Nov 72000 8.4 1.025 Tyson -Wilkes INC 1 0.4 6200 1400 33 Na 6.875 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 49.2 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 49.2 606000 As Cd Cu Cr Pb H Mo Ni Se Zn P 154,306 49.189 Lime Applied Annuallbs/acre 0.050 0.016 0.305 0.000 0.037 0.016 0.134 0.135 0.067 0.812 64.216 Date lbs/ac Prior Years Cumulative lbs/ac 0.113 0.041 0.423 0.000 0.087 0.031 0.262 0.263 0.144 1.066 Apr 4000 Current Cumulative lbs/ac 0.163 0.057 0.728 0.000 0.124 0.046 0.396 0.398 0.210 1.878 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop F 189 1 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." e �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: George F Ireland Trust Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-YK-DM-08 Acres Utilized: 24.6 Annual Dry Tons Applied: Site #: WK-YK-DM-08 Acres Permitted: 24.6 Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 4.5 Crop 1 Max. PAN: 189.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. ADD wet,' Moist) precip. Past 24 Hrs. inches a a - a w o ? * �. Z ,c `I TKN mg/kg Z a o � mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 49.2 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 49.21 0 0.000 E33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 27.44 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 13.2 Acres Permitted: 13.2 Site #: WK-MF-9 Field #: 7.5 Fairview WK-MF-9 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 2/27/20 4 Advance Pierre 5/19/20 5 RVAF 5/19/20 6 Tyson- Wilkes 5/19/20 7 8 9 10 11 12 % Solids 4.4 4.2 4.7 6.6 2.5 3.1 Arsenic 5.6 5.8 15.0 3.6 9.5 7.7 Cadmium 1 1.9 1.9 5.1 1.2 3.2 2.6 Copper 1 870.0 39.0 59.0 31.0 22.0 97.0 Chromium Lead 4.2 3.9 15.0 2.4 6.4 5.1 Mercury 1.8 1.9 1.6 1.1 2.9 2.4 Molyb- denum 15.0 15.0 41.0 9.7 26.0 21.0 Nickel 22.0 15.0 41.0 9.7 26.0 21.0 Selenium 7.4 7.7 20.0 4.8 13.0 10.0 Zinc 160.0 150.0 170.0 37.0 170.0 2600.0 Total Phos- horus 7,000 23,000 4,500 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 3 4 5 J 7 8 91 10 11-1 12 DT/Ac./ App. 14 Event 0.08 0.40 0.89 0.00 0.24 0.47 Arsenic 0.001 0.005 0.027 0.000 0.005 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Cadmium 0.000 0.002 0.009 0.000 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.015 Copper 0.144 0.031 0.105 0.000 0.010 0.091 0.000 0.000 0.000 0.000 0.000 0.000 0.382 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.001 0.003 0.027 0.000 0.003 0.005 0.000 0.000 0.000 0.000 0.000 0.000 1 0.038 Mercury 0.000 0.002 0.003 0.000 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Molyb- 0.002 0.012 0.073 0.000 0.012 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.120 denum Nickel 0.004 0.012 0.073 0.000 0.012 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.121 Selenium 0.001 0.006 0.036 0.000 0.006 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.059 Zinc 0.027 0.119 0.303 0.000 0.081 2.444 0.000 0.000 0.000 0.000 0.000 0.000 2.973 Total Phos- 1.162 18.308 8.019 0.000 10.428 5.828 0.000 0.000 0.000 0.000 0.000 0.000 43.745 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-9 Acres Utilized: 13.2 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 27.4469 Site #: WK-MF-9 Acres Permitted: 13.2 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 7.5 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 190 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Mar 6000 4.4 0.083 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.154 NA Corn-s Mar 30000 4.2 0.398 RVAF INC 1 0.4 22000 17000 27 15.147 NA Corn-s Mar 60000 4.7 0.891 Tyson -Wilkes INC 1 0.4 73000 2100 16 54.300 NA Corn-s Aug 0 2.3 0.000 Advance -Pierre INC 1 0.4 1500 220 16 Na 0.000 S.G. Aug 30000 2.5 0.237 RVAF INC 1 0.4 54000 36000 43 Na 20.491 S.G. Aug 48000 3.1 0.470 Tyson -Wilkes INC 1 0.4 71000 3500 31 Na 28.704 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 26.4 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 26.4 174000 As Cd Cu Cr Pb H Mo Ni Se Zn P 103.001 49.195 Lime Applied Annuallbs/acre 0.044 0.015 0.382 0.000 0.038 0.008 0.120 0.121 0.059 2.973 43.745 Date lbs/ac Prior Years Cumulative lbs/ac 0.175 0.078 0.787 0.000 0.162 0.019 0.276 0.277 0.195 2.675 Apr 4000 Current Cumulative lbs/ac 0.220 0.093 1.169 0.000 0.200 0.027 0.396 0.398 0.254 5.648 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 1 374 1 89 2498 Permit PAN Limit I st/2nd Crop 1 190 1 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-MF-9 Acres Utilized: 13.2 Annual Dry Tons Applied: Site #: WK-MF-9 Acres Permitted: 13.2 Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 7.5 Crop 1 Max. PAN: 190.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond.% ADD wet,' Moist) Precip. Past 24 Hrs. inches a a a w o ? * �. Z ,c `I TKN mg/kg Z a Ei o � mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 26.4 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0. 000 0.0 0.000 TOTALS: 26.41 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 25.04 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 14.1 Acres Permitted: 14.1 Site #: WK-MF-10 Field #: 7.2 Fairview WK-MF-10 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 2/27/20 4 Advance Pierre 5/19/20 5 RVAF 5/19/20 6 Tyson- Wilkes 5/19/20 7 8 9 10 11 12 % Solids 4.4 4.2 4.7 6.6 2.5 3.1 Arsenic 5.6 5.8 15.0 3.6 9.5 7.7 Cadmium 1 1.9 1.9 5.1 1.2 3.2 2.6 Copper 1 870.0 39.0 59.0 31.0 22.0 97.0 Chromium Lead 4.2 3.9 15.0 2.4 6.4 5.1 Mercury 1.8 1.9 1.6 1.1 2.9 2.4 Molyb- denum 15.0 15.0 41.0 9.7 26.0 21.0 Nickel 22.0 15.0 41.0 9.7 26.0 21.0 Selenium 7.4 7.7 20.0 4.8 13.0 10.0 Zinc 160.0 150.0 170.0 37.0 170.0 2600.0 Total Phos- horus 7,000 23,000 4,500 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. 14 Event 0.00 0.30 0.75 0.00 0.18 0.55 Arsenic 0.000 0.003 0.023 0.000 0.003 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.038 Cadmium 0.000 0.001 0.008 0.000 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Copper 0.000 0.023 0.089 0.000 0.008 0.107 0.000 0.000 0.000 0.000 0.000 0.000 0.226 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.002 0.023 0.000 0.002 0.006 0.000 0.000 0.000 0.000 0.000 0.000 1 0.033 Mercury 0.000 0.001 0.002 0.000 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Molyb- 0.000 0.009 0.062 0.000 0.009 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.103 denum Nickel 0.000 0.009 0.062 0.000 0.009 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.103 Selenium 0.000 0.005 0.030 0.000 0.005 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.050 Zinc 0.000 0.089 0.255 0.000 0.060 2.860 0.000 0.000 0.000 0.000 0.000 0.000 3.265 Total Phos- 0.000 13.708 6.759 0.000 7.788 6.820 0.000 0.000 0.000 0.000 0.000 0.000 35.075 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-10 Acres Utilized: 14.1 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 25.0450 Site #: WK-MF-10 Acres Permitted: 14.1 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 7.2 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 179 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Mar 0 4.4 0.000 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.000 NA Corn-s Mar 24000 4.2 0.298 RVAF INC 1 0.4 22000 17000 27 11.344 NA Corn-s Mar 54000 4.7 0.751 Tyson -Wilkes INC 1 0.4 73000 2100 16 45.751 NA Corn-s Aug -Sep 0 2.3 0.000 Advance -Pierre INC 1 0.4 1500 220 16 Na 0.000 S.G. Aug -Sep 24000 2.5 0.177 RVAF INC 1 0.4 54000 36000 43 Na 15.347 S.G. Aug -Sep 60000 3.1 0.550 Tyson -Wilkes INC 1 0.4 71000 3500 31 Na 33.589 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 28.2 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 28.21 162000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 90.495 48.936 Lime Applied Annuallbs/acre 0.038 0.013 0.226 0.000 0.033 0.007 0.103 0.103 0.050 3.265 35.075 Date lbs/ac Prior Years Cumulative lbs/ac 0.176 0.076 0.395 0.000 0.156 0.025 0.294 0.295 0.200 3.947 Apr 4000 Current Cumulative lbs/ac 0.214 0.088 0.622 0.000 0.189 0.032 0.397 0.397 0.250 7.212 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 179 1 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." e �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-MF-10 Acres Utilized: 14.1 Annual Dry Tons Applied: Site #: WK-MF-10 Acres Permitted: 14.1 Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 7.2 Crop 1 Max. PAN: 179.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond.% ADD wet,' Moist) Precip. Past 24 Hrs. inches a a a w o ? * �. Z ,c `I TKN mg/kg Z a Ei o � mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 28.2 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0. 000 0.0 0.000 TOTALS: 28.21 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 23.35 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 16.8 Acres Permitted: 16.8 Site #: WK-MF-11 Field #: 8.3 Fairview WK-MF-11 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 2/27/20 4 Advance Pierre 5/19/20 5 RVAF 5/19/20 6 Tyson- Wilkes 5/19/20 7 8 9 10 11 12 % Solids 4.4 4.2 4.7 6.6 2.5 3.1 Arsenic 5.6 5.8 15.0 3.6 9.5 7.7 Cadmium 1 1.9 1.9 5.1 1.2 3.2 2.6 Copper 1 870.0 39.0 59.0 31.0 22.0 97.0 Chromium Lead 4.2 3.9 15.0 2.4 6.4 5.1 Mercury 1.8 1.9 1.6 1.1 2.9 2.4 Molyb- denum 15.0 15.0 41.0 9.7 26.0 21.0 Nickel 22.0 15.0 41.0 9.7 26.0 21.0 Selenium 7.4 7.7 20.0 4.8 13.0 10.0 Zinc 160.0 150.0 170.0 37.0 170.0 2600.0 Total Phos- horus 7,000 23,000 4,500 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. 14 Event 0.00 0.19 0.49 0.00 0.11 0.60 Arsenic 0.000 0.002 0.015 0.000 0.002 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.028 Cadmium 0.000 0.001 0.005 0.000 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.000 0.015 0.058 0.000 0.005 0.116 0.000 0.000 0.000 0.000 0.000 0.000 0.194 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.001 0.015 0.000 0.001 0.006 0.000 0.000 0.000 0.000 0.000 0.000 1 0.024 Mercury 0.000 0.001 0.002 0.000 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Molyb- 0.000 0.006 0.040 0.000 0.006 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.077 denum Nickel 0.000 0.006 0.040 0.000 0.006 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.077 Selenium 0.000 0.003 0.020 0.000 0.003 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.037 Zinc 0.000 0.056 0.167 0.000 0.038 3.120 0.000 0.000 0.000 0.000 0.000 0.000 3.381 Total Phos- 0.000 8.648 4.410 0.000 4.928 7.440 0.000 0.000 0.000 0.000 0.000 0.000 25.426 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-11 Acres Utilized: 16.8 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 23.3437 Site #: WK-MF-11 Acres Permitted: 16.8 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 8.3 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 146 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Mar 0 4.4 0.000 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.000 NA Corn-s Mar 18000 4.2 0.188 RVAF INC 1 0.4 22000 17000 27 7.141 NA Corn-s Mar 42000 4.7 0.490 Tyson -Wilkes INC 1 0.4 73000 2100 16 29.865 NA Corn-s Sep 0 2.3 0.000 Advance -Pierre INC 1 0.4 1500 220 16 Na 0.000 S.G. Sep 18000 2.5 0.112 RVAF INC 1 0.4 54000 36000 43 Na 9.660 S.G. Sep 78000 3.1 0.600 Tyson -Wilkes INC 1 0.4 71000 3500 31 Na 36.648 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 33.6 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 33.61 156000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 70.406 46.308 Lime Applied Annuallbs/acre 0.028 0.010 0.194 0.000 0.024 0.006 0.077 0.077 0.037 3.381 25.426 Date lbs/ac Prior Years Cumulative lbs/ac 0.294 0.141 0.323 0.000 0.284 0.022 0.362 0.362 0.307 2.030 Apr 4000 Current Cumulative lbs/ac 0.322 0.150 0.517 0.000 0.307 0.027 0.439 0.439 0.345 5.411 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop F 146 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-MF-11 Acres Utilized: 16.8 Annual Dry Tons Applied: Site #: WK-MF-11 Acres Permitted: 16.8 Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 8.3 Crop 1 Max. PAN: 146.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond.% ADD wet,' Moist) Precip. Past 24 Hrs. inches a a a w o ? * �. Z ,c `I TKN mg/kg Z a Ei o � mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 33.6 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0. 000 0.0 0.000 TOTALS: 33.61 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 36.74 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 33.8 Acres Permitted: 33.8 Site #: WK-MF-13 Field #: 5.1 Fairview WK-MF-13 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 2/27/20 4 Advance Pierre 5/19/20 5 RVAF 5/19/20 6 Tyson- Wilkes 5/19/20 7 8 9 10 11 12 % Solids 4.4 4.2 4.7 6.6 2.5 3.1 Arsenic 5.6 5.8 15.0 3.6 9.5 7.7 Cadmium 1 1.9 1.9 5.1 1.2 3.2 2.6 Copper 1 870.0 39.0 59.0 31.0 22.0 97.0 Chromium Lead 4.2 3.9 15.0 2.4 6.4 5.1 Mercury 1.8 1.9 1.6 1.1 2.9 2.4 Molyb- denum 15.0 15.0 41.0 9.7 26.0 21.0 Nickel 22.0 15.0 41.0 9.7 26.0 21.0 Selenium 7.4 7.7 20.0 4.8 13.0 10.0 Zinc 160.0 150.0 170.0 37.0 170.0 2600.0 Total Phos- horus 7,000 23,000 4,500 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 3 4 5 J 7 8 91 10 11-1 12 DT/Ac./ App. 14 Event 0.00 0.16 0.17 0.02 0.17 0.57 Arsenic 0.000 0.002 0.005 0.000 0.003 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Cadmium 0.000 0.001 0.002 0.000 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 0.000 0.012 0.021 0.001 0.007 0.111 0.000 0.000 0.000 0.000 0.000 0.000 0.152 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.001 0.005 0.000 0.002 0.006 0.000 0.000 0.000 0.000 0.000 0.000 1 0.015 Mercury 0.000 0.001 0.001 0.000 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Molyb- 0.000 0.005 0.014 0.000 0.009 0.024 0.000 0.000 0.000 0.000 0.000 0.000 0.052 denum Nickel 0.000 0.005 0.014 0.000 0.009 0.024 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Selenium 0.000 0.002 0.007 0.000 0.004 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.025 Zinc 0.000 0.047 0.059 0.001 0.057 2.985 0.000 0.000 0.000 0.000 0.000 0.000 3.148 Total Phos- 0.000 7.130 1.566 0.065 7.348 7.118 0.000 0.000 0.000 0.000 0.000 0.000 23.226 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-13 Acres Utilized: 33.8 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 36.7294 Site #: WK-MF-13 Acres Permitted: 33.8 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 5.1 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 178 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Mar 0 4.4 0.000 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.000 NA Corn-s Mar 30000 4.2 0.155 RVAF INC 1 0.4 22000 17000 27 5.915 NA Corn-s Mar 30000 4.7 0.174 Tyson -Wilkes INC 1 0.4 73000 2100 16 10.603 NA Corn-s Sep 6000 2.3 0.017 Advance -Pierre INC 1 0.4 1500 220 16 Na 0.025 S.G. Sep 54000 2.5 0.167 RVAF INC 1 0.4 54000 36000 43 Na 14.405 S.G. Sep 150000 3.1 0.574 Tyson -Wilkes INC 1 0.4 71000 3500 31 Na 35.030 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 67.6 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 67.61 270000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 49.918 49.460 Lime Applied Annuallbs/acre 0.019 0.006 0.152 0.000 0.015 0.005 0.052 0.052 0.025 3.148 23.226 Date lbs/ac Prior Years Cumulative lbs/ac 0.210 0.096 0.420 0.000 0.194 0.018 0.307 0.307 0.230 3.800 Apr 4000 Current Cumulative lbs/ac 0.229 0.102 0.573 0.000 0.209 0.023 0.359 0.359 0.256 6.948 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop F 178 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-MF-13 Acres Utilized: 33.8 Annual Dry Tons Applied: Site #: WK-MF-13 Acres Permitted: 33.8 Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 5.1 Crop 1 Max. PAN: 178.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond.% ADD wet,' Moist) Precip. Past 24 Hrs. inches a a a w o ? * �. Z ,c `I TKN mg/kg Z a Ei o � mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 67.6 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0. 000 0.0 0.000 TOTALS: 67.61 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 21.11 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 21.9 Acres Permitted: 21.9 Site #: WK-MF-14 Field #: 5.2 Fairview WK-MF-14 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 2/27/20 4 Advance Pierre 5/19/20 5 RVAF 5/19/20 6 Tyson- Wilkes 5/19/20 7 8 9 10 j 12 % Solids 4.4 4.2 4.7 6.6 2.5 3.1 Arsenic 5.6 5.8 15.0 3.6 9.5 7.7 Cadmium 1 1.9 1.9 5.1 1.2 3.2 2.6 Copper 1 870.0 39.0 59.0 31.0 22.0 97.0 Chromium Lead 4.2 3.9 15.0 2.4 6.4 5.1 Mercury 1.8 1.9 1.6 1.1 2.9 2.4 Molyb- denum 15.0 15.0 41.0 9.7 26.0 21.0 Nickel 22.0 15.0 41.0 9.7 26.0 21.0 Selenium 7.4 7.7 20.0 4.8 13.0 10.0 Zinc 160.0 150.0 170.0 37.0 170.0 2600.0 Total Phos- horus 7,000 23,000 4,500 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. 14 Event 0.00 0.10 0.22 0.00 0.23 0.43 Arsenic 0.000 0.001 0.006 0.000 0.004 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Cadmium 0.000 0.000 0.002 0.000 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 0.000 0.007 0.025 0.000 0.010 0.082 0.000 0.000 0.000 0.000 0.000 0.000 0.125 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.001 0.006 0.000 0.003 0.004 0.000 0.000 0.000 0.000 0.000 0.000 1 0.014 Mercury 0.000 0.000 0.001 0.000 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.000 0.003 0.018 0.000 0.012 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.050 denum Nickel 0.000 0.003 0.018 0.000 0.012 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.050 Selenium 0.000 0.001 0.009 0.000 0.006 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.025 Zinc 0.000 0.029 0.073 0.000 0.078 2.210 0.000 0.000 0.000 0.000 0.000 0.000 2.389 Total Phos- 0.000 4.416 1.935 0.000 10.032 5.270 0.000 0.000 0.000 0.000 0.000 0.000 21.653 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-14 Acres Utilized: 21.9 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 21.1169 Site #: WK-MF-14 Acres Permitted: 21.9 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 5.2 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 148 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Mar 0 4.4 0.000 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.000 NA Corn-s Mar 12000 4.2 0.096 RVAF INC 1 0.4 22000 17000 27 3.652 NA Corn-s Mar 24000 4.7 0.215 Tyson -Wilkes INC 1 0.4 73000 2100 16 13.091 NA Corn-s Sep 0 2.3 0.000 Advance -Pierre INC 1 0.4 1500 220 16 Na 0.000 S.G. Sep 48000 2.5 0.228 RVAF INC 1 0.4 54000 36000 43 Na 19.761 S.G. Sep 72000 3.1 0.425 Tyson -Wilkes INC 1 0.4 71000 3500 31 Na 25.951 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 43.8 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 43.81 156000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 50.143 45.713 Lime Applied Annuallbs/acre 0.018 0.006 0.125 0.000 0.014 0.004 0.050 0.050 0.025 2.389 21.653 Date lbs/ac Prior Years Cumulative lbs/ac 0.036 0.013 0.322 0.000 0.029 0.009 0.087 0.087 0.046 2.468 Apr 4000 Current Cumulative lbs/ac 0.055 0.020 0.448 0.000 0.043 0.013 0.137 0.137 0.071 4.857 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop F 148 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services, Inc Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-MF-14 Acres Utilized: 21.9 Annual Dry Tons Applied: Site #: WK-MF-14 Acres Permitted: 21.9 Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 5.2 Crop 1 Max. PAN: 148.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond.% ADD wet,' Moist) Precip. Past 24 Hrs. inches a a a w o ? * �. Z ,c `I TKN mg/kg Z a Ei o � mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 43.8 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0. 000 0.0 0.000 TOTALS: 43.81 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 9.18 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 13.6 Acres Permitted: 13.6 Site #: WK-MF-15 Field #: 6.65 Fairview WK-MF-15 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 5 6 7 8 9 10 11 12 % Solids 6.6 2.5 3.1 Arsenic 3.6 9.5 7.7 Cadmium 1.2 3.2 2.6 Copper 31.0 22.0 97.0 Chromium Lead 2.4 6.4 5.1 Mercury 1.1 2.9 2.4 Molyb- denum 9.7 26.0 21.0 Nickel 9.7 26.0 21.0 Selenium 4.8 13.0 10.0 Zinc 37.0 170.0 2600.0 Total Phos- horus 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. 14 Event 0.00 0.28 0.40 Arsenic 0.000 0.005 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Cadmium 0.000 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.000 0.012 0.077 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.090 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.004 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.008 Mercury 0.000 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.000 0.014 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 denum Nickel 0.000 0.014 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Selenium 0.000 0.007 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 Zinc 0.000 0.094 2.075 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.169 Total Phos- 0.000 12.144 4.948 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 17.092 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-15 Acres Utilized: 13.6 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 9.1823 Site #: WK-MF-15 Acres Permitted: 13.6 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 6.65 Crop 1 Name: Small Grains Crop 1 Max. PAN: 80 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Aug 0 6.6 0.000 Advance -Pierre INC 1 0.4 1 1500 220 1 16 0.000 NA S.G Aug 36000 2.5 0.276 RVAF INC 1 0.4 54000 36000 43 23.866 NA S.G Aug 42000 3.1 0.399 Tyson -Wilkes INC 1 0.4 71000 3500 31 24.377 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 78000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 48.243 0.000 Lime Applied Annuallbs/acre 0.011 0.547 0.004 0.269 0.090 0.443 0.000 0.000 0.008 0.539 0.004 0.031 0.031 0.597 0.031 0.597 0.015 0.556 2.169 4.177 17.092 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.558 0.273 0.533 0.000 0.547 0.034 0.628 0.628 0.572 6.345 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop 80 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 27.63 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 6.7 Fairview 23.8 Acres Permitted: 23.8 Site #: WK-MF-23A Field #: WK-MF-23A Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 3/26/20 2 RVAF 3/26/20 3 Tyson- Wilkes 2/27/20 4 Advance Pierre 5/19/20 5 RVAF 5/19/20 6 Tyson- Wilkes 5/19/20 7 8 9 10 11 12 % Solids 4.4 4.2 4.7 6.6 2.5 3.1 Arsenic 5.6 5.8 15.0 3.6 9.5 7.7 Cadmium 1 1.9 1.9 5.1 1.2 3.2 2.6 Copper 1 870.0 39.0 59.0 31.0 22.0 97.0 Chromium Lead 4.2 3.9 15.0 2.4 6.4 5.1 Mercury 1.8 1.9 1.6 1.1 2.9 2.4 Molyb- denum 15.0 15.0 41.0 9.7 26.0 21.0 Nickel 22.0 15.0 41.0 9.7 26.0 21.0 Selenium 7.4 7.7 20.0 4.8 13.0 10.0 Zinc 160.0 150.0 170.0 37.0 170.0 2600.0 Total Phos- horus 7,000 23,000 4,500 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 3 4 5 J 7 8 91 10 11-1 12 DT/Ac./ App. 14 Event 0.00 0.22 0.25 0.00 0.24 0.46 Arsenic 0.000 0.003 0.007 0.000 0.005 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Cadmium 0.000 0.001 0.003 0.000 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.000 0.017 0.029 0.000 0.010 0.088 0.000 0.000 0.000 0.000 0.000 0.000 0.145 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.002 0.007 0.000 0.003 0.005 0.000 0.000 0.000 0.000 0.000 0.000 1 0.017 Mercury 0.000 0.001 0.001 0.000 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Molyb- 0.000 0.007 0.020 0.000 0.012 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.058 denum Nickel 0.000 0.007 0.020 0.000 0.012 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.058 Selenium 0.000 0.003 0.010 0.000 0.006 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Zinc 0.000 0.066 0.084 0.000 0.081 2.371 0.000 0.000 0.000 0.000 0.000 0.000 2.602 Total Phos- 0.000 10.166 2.223 0.000 10.428 5.654 0.000 0.000 0.000 0.000 0.000 0.000 28.471 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-23A Acres Utilized: 23.8 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 27.6221 Site #: WK-MF-23A Acres Permitted: 23.8 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 6.7 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 165 Crop 2 Name: Small Grains Crop 2 Max. PAN: 50 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Mar 0 4.4 0.000 Advance -Pierre INC 1 0.4 1 1900 230 1 24 0.000 NA Corn-s Mar 30000 4.2 0.221 RVAF INC 1 0.4 22000 17000 27 8.401 NA Corn-s Mar 30000 4.7 0.247 Tyson -Wilkes INC 1 0.4 73000 2100 16 15.058 NA Corn-s Aug 0 2.3 0.000 Advance -Pierre INC 1 0.4 1500 220 16 Na 0.000 S.G. Aug 54000 2.5 0.237 RVAF INC 1 0.4 54000 36000 43 Na 20.457 S.G. Aug 84000 3.1 0.456 Tyson -Wilkes INC 1 0.4 71000 3500 31 Na 27.859 S.G. 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 47.6 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 47.6 198000 As Cd Cu Cr Pb H Mo Ni Se Zn P 56.859 48.316 Lime Applied Annuallbs/acre 0.021 0.007 0.145 0.000 0.017 0.005 0.058 0.058 0.029 2.602 28.471 Date lbs/ac Prior Years Cumulative lbs/ac 0.695 0.342 0.571 0.000 0.686 0.039 0.768 0.768 0.709 3.960 Apr 4000 Current Cumulative lbs/ac 0.717 0.349 0.716 0.000 0.703 0.044 0.826 0.826 0.738 6.562 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 1 374 1 89 2498 Permit PAN Limit I st/2nd Crop 165 1 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Field #: WK-MF-23A Acres Utilized: 23.8 Annual Dry Tons Applied: Site #: WK-MF-23A Acres Permitted: 23.8 Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 6.7 Crop 1 Max. PAN: 165.00 Crop 2 Name: Small Grains Crop 2 Max PAN: 50.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond.% ADD wet,' Moist) Precip. Past 24 Hrs. inches a a a w o ? * �. Z ,c `I TKN mg/kg Z a Ei o � mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 47.6 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0. 000 0.0 0.000 TOTALS: 47.61 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." cf�e �� 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation E**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 15.67 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 3.49 Fairview 21.2 Acres Permitted: 21.2 Site #: WK-MF-23B Field #: WK-MF-23B Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 5 6 7 8 9 10 11 12 % Solids 6.6 2.5 3.1 Arsenic 3.6 9.5 7.7 Cadmium 1.2 3.2 2.6 Copper 31.0 22.0 97.0 Chromium Lead 2.4 6.4 5.1 Mercury 1.1 2.9 2.4 Molyb- denum 9.7 26.0 21.0 Nickel 9.7 26.0 21.0 Selenium 4.8 13.0 10.0 Zinc 37.0 170.0 2600.0 Total Phos- horus 1,900 22,000 6,200 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. 14 Event 0.08 0.30 0.37 Arsenic 0.001 0.006 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Cadmium 0.000 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.005 0.013 0.071 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.089 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.004 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.008 Mercury 0.000 0.002 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.002 0.015 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 denum Nickel 0.002 0.015 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 Selenium 0.001 0.008 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.016 Zinc 0.006 0.100 1.903 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.009 Total Phos- 0.296 12.980 4.538 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 17.815 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MF-23B Acres Utilized: 21.2 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 15.6625 Site #: WK-MF-23B Acres Permitted: 21.2 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 3.49 Crop 1 Name: Small Grains Crop 1 Max. PAN: 98 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Aug 6000 6.6 0.078 Advance -Pierre INC 1 0.4 1 1500 220 1 16 0.117 NA S.G Aug 60000 2.5 0.295 RVAF INC 1 0.4 54000 36000 43 25.517 NA S.G Aug 60000 3.1 0.366 Tyson -Wilkes INC 1 0.4 71000 3500 31 22.340 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 126000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 47.974 0.000 Lime Applied Annuallbs/acre 0.012 0.354 0.365 0.004 0.174 0.178 0.089 0.316 0.404 0.000 0.000 0.000 0.008 0.349 0.356 0.004 0.019 0.023 0.032 0.388 0.420 0.032 0.388 0.420 0.016 0.360 0.376 2.009 3.107 5.117 17.815 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 98 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 80.54 WQ0038087 Terra Renewal Services Owner: 19.6 Acres Permitted: Cation Exchange Capacity (non 503 only): 8.5 Mathis Properties, LLC Predominant Soil Series: Dan River/Comus 19.6 Site #: WK-NIRF-03 Field #: WK-MRF-03 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 Advance Pierre 12/3/20 5 RVAF 11/19/20 6 Tyson- Wilkes 11/19/20 7 8 9 10 j 12 % Solids 6.6 2.5 3.1 2.7 9.4 6.2 Arsenic 3.6 9.5 7.7 9.3 2.6 4.0 Cadmium 1.2 3.2 2.6 3.1 0.9 1.3 Copper 31.0 22.0 97.0 490.0 1.7 31.0 Chromium Lead 2.4 6.4 5.1 6.2 1.7 2.7 Mercury 1.1 2.9 2.4 2.8 0.9 1.2 Molyb- denum 9.7 26.0 21.0 25.0 7.0 11.0 Nickel 9.7 26.0 21.0 25.0 7.0 11.0 Selenium 4.8 13.0 10.0 12.0 3.5 5.4 Zinc 37.0 170.0 2600.0 82.0 8.7 69.0 Total Phos- horus 1,900 22,000 6,200 14,000 4,500 3,800 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. 14 Event 0.00 0.58 0.99 0.00 1.20 1.35 Arsenic 0.000 0.011 0.015 0.000 0.006 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.043 Cadmium 0.000 0.004 0.005 0.000 0.002 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Copper 0.000 0.025 0.192 0.000 0.004 0.083 0.000 0.000 0.000 0.000 0.000 0.000 0.305 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.007 0.010 0.000 0.004 0.007 0.000 0.000 0.000 0.000 0.000 0.000 1 0.029 Mercury 0.000 0.003 0.005 0.000 0.002 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Molyb- 0.000 0.030 0.042 0.000 0.017 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.118 denum Nickel 0.000 0.030 0.042 0.000 0.017 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.118 Selenium 0.000 0.015 0.020 0.000 0.008 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.058 Zinc 0.000 0.196 5.143 0.000 0.021 0.186 0.000 0.000 0.000 0.000 0.000 0.000 5.545 Total Phos- 0.000 25.300 12.264 0.000 10.800 10.222 0.000 0.000 0.000 0.000 0.000 0.000 58.586 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MRF-03 Acres Utilized: 19.6 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 80.5394 Site #: WK-MRF-03 Acres Permitted: 19.6 Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 8.5 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 144 Crop 2 Name: Corn -silage ('21) Crop 2 Max. PAN: 143 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 5A o o w * Z o ? rn~ .°n ��, a K � cr. .°n fKN mg/kg Z a �t Ei o .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Jun 0 6.6 0.000 Advance -Pierre INC 1 1 0.4 1500 220 16 0.000 NA Corn-s Jun 108000 2.5 0.574 RVAF INC 1 0.4 54000 36000 43 49.681 NA Corn-s Jun 150000 3.1 0.989 Tyson -Wilkes INC 1 0.4 71000 3500 31 60.409 NA Corn-s Dec 0 2.7 0.000 Advance -Pierre INC 1 0.4 51000 550 260 Na 0.000 Corn (2 1) Dec 60000 9.4 1.200 RVAF INC 1 0.4 20000 6800 12 Na 29.019 Corn(21) Dec 102000 6.2 1.345 Tyson -Wilkes INC 1 0.4 93000 1500 19 Na 102.575 Corn(21) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 39.2 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 39 2F 420000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 143.490 131.595 Lime Applied Annuallbs/acre 0.043 0.014 0.305 0.000 0.029 0.013 0.118 0.118 0.058 5.545 58.586 0.588 0.285 0.692 0.000 0.570 0.041 0.694 0.694 0.608 6.995 0.631 0.299 0.997 0.000 0.599 0.054 0.812 0.812 0.666 12.540 36 34 1338 N/A 267 15 N/A 374 89 2498 144 1 143 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac Nov 2000 Permitted C. P. L. R.**** Permit PAN Limit 1 st/2nd Crop "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: W00038087 Field #: WK-MRF-03 Acres Utilized: 19.6 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: Site #: WK-MRF-03 Acres Permitted: 19.6 Operator: Terra Renewal Services Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 8.5 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 144.00 Crop 2 Name: Corn-s ('21) Crop 2 Max PAN: 143.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. ADD wet,' Moist) Precip. Past 24 Hrs. inches a co w o ? * �. Z `; TKN mg/kg Z.a o mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual lication Application Crop 1 Crop 2 Crop 1 Crop 2 April 39.2 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 39.21 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 57.84 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 4.41 Danripple 25.3 Acres Permitted: 25.3 Site #: WK-NIRF-05 Field #: WK-MRF-05 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 12/3/20 2 RVAF 11/19/20 3 Tyson- Wilkes 11/19/20 4 5 6 7 8 9 10 j 12 % Solids 2.7 9.4 6.2 Arsenic 9.3 2.6 4.0 Cadmium 1 3.1 0.9 1.3 Copper 1 490.0 1.7 31.0 Chromium Lead 6.2 1.7 2.7 Mercury 2.8 0.9 1.2 Molyb- denum 25.0 7.0 11.0 Nickel 25.0 7.0 11.0 Selenium 12.0 3.5 5.4 Zinc 82.0 8.7 69.0 Total Phos- horus 14,000 4,500 3,800 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.00 1.67 0.61 Arsenic 0.000 0.009 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.000 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.000 0.006 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.006 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.009 Mercury 0.000 0.003 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.000 0.023 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.037 denum Nickel 0.000 0.023 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.037 Selenium 0.000 0.012 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Zinc 0.000 0.029 0.085 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.114 Total Phos- 0.000 15.057 4.659 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 19.716 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties, LLC Operator: Terra Renewal Services Crop 1 Name: Corn -silage ('21) WQ Permit #: WQ0038087 Field #: WK-MRF-05 Acres Utilized: 25.3 Annual Dry Tons Applied: 57.8462 Site #: WK-MRF-05 Acres Permitted: 25.3 Predominant Soil Series: Danripple Crop 1 Max. PAN: 199 Crop 2 Name: Cation Exchange Capacity (non 503): 4.41 Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 4 o o w * Z o ? rn 0 ��, K � cr. .°n TKN mg/kg Z. a a o .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Dec 0 2.7 0.000 Advance -Pierre INC 1 0.4 51000 550 260 0.000 NA Corn (21) Dec 108000 9.4 1.673 RVAF INC 1 0.4 20000 6800 12 40.466 NA Corn (21) Dec 60000 6.2 0.613 Tyson -Wilkes INC 1 0.4 93000 1500 19 46.744 NA Corn (21) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 168000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 87.211 0.000 Lime Applied Annuallbs/acre 0.014 0.005 0.044 0.000 0.009 0.004 0.037 0.037 0.018 0.114 19.716 Date lbs/ac Prior Years Cumulative lbs/ac 0.692 0.328 0.878 0.000 0.656 0.060 0.881 0.882 0.730 3.827 Apr 4000 Current Cumulative lbs/ac 0.705 0.332 0.922 0.000 0.665 0.064 0.918 0.919 0.748 3.941 Nov 2000 Permitted C. P. L. R.**** 36 t 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 199 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 63.79 WQ0038087 Terra Renewal Services Owner: 24.9 Acres Permitted: Cation Exchange Capacity (non 503 only): 11.26 Mathis Properties, LLC Predominant Soil Series: Dan River/Comus 24.9 Site #: WK-NIRF-06 Field #: WK-MRF-06 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 Advance Pierre 12/3/20 5 RVAF 11/19/20 6 Tyson- Wilkes 11/19/20 7 8 9 10 j 12 % Solids 6.6 2.5 3.1 2.7 9.4 6.2 Arsenic 3.6 9.5 7.7 9.3 2.6 4.0 Cadmium 1.2 3.2 2.6 3.1 0.9 1.3 Copper 31.0 22.0 97.0 490.0 1.7 31.0 Chromium Lead 2.4 6.4 5.1 6.2 1.7 2.7 Mercury 1.1 2.9 2.4 2.8 0.9 1.2 Molyb- denum 9.7 26.0 21.0 25.0 7.0 11.0 Nickel 9.7 26.0 21.0 25.0 7.0 11.0 Selenium 4.8 13.0 10.0 12.0 3.5 5.4 Zinc 37.0 170.0 2600.0 82.0 8.7 69.0 Total Phos- horus 1,900 22,000 6,200 14,000 4,500 3,800 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. 14 Event 0.00 0.18 0.28 0.00 1.80 0.31 Arsenic 0.000 0.003 0.004 0.000 0.009 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Cadmium 0.000 0.001 0.001 0.000 0.003 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.000 0.008 0.054 0.000 0.006 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.087 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.002 0.003 0.000 0.006 0.002 0.000 0.000 0.000 0.000 0.000 0.000 1 0.013 Mercury 0.000 0.001 0.001 0.000 0.003 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Molyb- 0.000 0.009 0.012 0.000 0.025 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.053 denum Nickel 0.000 0.009 0.012 0.000 0.025 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.053 Selenium 0.000 0.005 0.006 0.000 0.013 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Zinc 0.000 0.060 1.456 0.000 0.031 0.043 0.000 0.000 0.000 0.000 0.000 0.000 1.590 Total Phos- 0.000 7.744 3.472 0.000 16.155 2.364 0.000 0.000 0.000 0.000 0.000 0.000 29.735 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties, LLC Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: WQ0038087 Field #: WK-MRF-06 Acres Utilized: 24.9 Annual Dry Tons Applied: 63.8010 Site #: WK-MRF-06 Acres Permitted: 24.9 Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 11.26 Crop 1 Max. PAN: 160 Crop 2 Name: Corn -silage ('21) Crop 2 Max. PAN: 180 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 1 1 � o, o w * Z o ? P_a 0 ��, K � cr. Zmg/kg TKN Z a a o Ei .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Jun 0 6.6 0.000 Advance -Pierre INC 1 0.4 1 1500 220 1 16 0.000 NA Corn-s Jun 42000 2.5 0.176 RVAF INC 1 0.4 54000 36000 43 15.208 NA Corn-s Jun 54000 3.1 0.280 Tyson -Wilkes INC 1 0.4 71000 3500 31 17.118 NA Corn-s Dec 0 2.7 0.000 Advance -Pierre INC 1 0.4 51000 550 260 Na 0.000 Corn (2 1) Dec 114000 9.4 1.795 RVAF INC 1 0.4 20000 6800 12 Na 43.401 Corn(21) Dec 30000 6.2 0.311 Tyson -Wilkes INC 1 0.4 93000 1500 19 Na 23.748 Corn(21) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 49.8 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 49.81 240000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 65.726 67.148 Lime Applied Annuallbs/acre 0.019 0.007 0.087 0.000 0.013 0.006 0.053 0.053 0.026 1.590 29.735 Date lbs/ac Prior Years Cumulative lbs/ac 0.678 0.323 0.835 0.000 0.647 0.055 0.844 0.845 0.711 3.713 Apr 4000 Current Cumulative lbs/ac 0.698 0.330 0.922 0.000 0.660 0.062 0.897 0.898 0.738 5.303 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop F 160 1 180 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc Land Owner: Mathis Properties, LLC Operator: Terra Renewal Services Crop 1 Name: Corn -silage WQ Permit #: W00038087 Annual Dry Tons Applied: Field #: WK-NMF-06 Site #: WK-N RF-06 Acres Utilized: 24.9 Acres Permitted: 24.9 Predominant Soil Series: Danripple Cation Exchange Capacity (non 503): 11.26 Crop 1 Max. PAN: 160.00 Crop 2 Name: Corn -silage ('21) Crop 2 Max PAN: 180.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. (Dry, wet Moist) Precip. Past 24 Hrs. inches a co w L o ? * �. Z `; TKN mg/kg Z a o mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual Application pp Crop 1 Crop 2 Crop 1 Crop 2 April 49.8 1 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 49.8 0 0.000 33.4 0.000.6.� "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 111.57 WQ0038087 Terra Renewal Services Owner: 25.1 Acres Permitted: Cation Exchange Capacity (non 503 only): 7.34 Mathis Properties, LLC Predominant Soil Series: Dan River/Comus 25.1 Site #: WK-NIRF-12 Field #: WK-MRF-12 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 5/19/20 2 RVAF 5/19/20 3 Tyson- Wilkes 5/19/20 4 Advance Pierre 12/3/20 5 RVAF 11/19/20 6 Tyson- Wilkes 11/19/20 7 8 9 10 j 12 % Solids 6.6 2.5 3.1 2.7 9.4 6.2 Arsenic 3.6 9.5 7.7 9.3 2.6 4.0 Cadmium 1.2 3.2 2.6 3.1 0.9 1.3 Copper 31.0 22.0 97.0 490.0 1.7 31.0 Chromium Lead 2.4 6.4 5.1 6.2 1.7 2.7 Mercury 1.1 2.9 2.4 2.8 0.9 1.2 Molyb- denum 9.7 26.0 21.0 25.0 7.0 11.0 Nickel 9.7 26.0 21.0 25.0 7.0 11.0 Selenium 4.8 13.0 10.0 12.0 3.5 5.4 Zinc 37.0 170.0 2600.0 82.0 8.7 69.0 Total Phos- horus 1,900 22,000 6,200 14,000 4,500 3,800 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 6j 7 81 91 10 11-1 12 _5j DT/Ac./ App. 14 Event 0.00 0.72 0.96 0.05 1.97 0.74 Arsenic 0.000 0.014 0.015 0.001 0.010 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.046 Cadmium 0.000 0.005 0.005 0.000 0.003 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.015 Copper 0.000 0.032 0.186 0.053 0.007 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.323 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.009 0.010 0.001 0.007 0.004 0.000 0.000 0.000 0.000 0.000 0.000 1 0.030 Mercury 0.000 0.004 0.005 0.000 0.004 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Molyb- 0.000 0.038 0.040 0.003 0.028 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.124 denum Nickel 0.000 0.038 0.040 0.003 0.028 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.124 Selenium 0.000 0.019 0.019 0.001 0.014 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.061 Zinc 0.000 0.246 4.982 0.009 0.034 0.102 0.000 0.000 0.000 0.000 0.000 0.000 5.373 Total Phos- 0.000 31.812 11.879 1.512 17.712 5.639 0.000 0.000 0.000 0.000 0.000 0.000 68.554 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-MRF-12 Acres Utilized: 25.1 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 111.5392 Site #: WK-MRF-12 Acres Permitted: 25.1 Operator: Terra Renewal Services Predominant Soil Series: Pfafftown Cation Exchange Capacity (non 503): 7.34 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 190 Crop 2 Name: Corn -silage ('21) Crop 2 Max. PAN: 187 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, We Moist) Precip. past 24 Hrs. inches y 1 1 � o, o w * Z o ? P_a 0 ��, K � cr. Zmg/kg TKN Z a a o Ei .°n mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Jun 0 6.6 0.000 Advance -Pierre INC 1 0.4 1 1500 220 1 16 0.000 NA Corn-s Jun 174000 2.5 0.723 RVAF INC 1 0.4 54000 36000 43 62.503 NA Corn-s Jun 186000 3.1 0.958 Tyson -Wilkes INC 1 0.4 71000 3500 31 58.494 NA Corn-s Dec 12000 2.7 0.054 Advance -Pierre INC 1 0.4 51000 550 260 Na 2.260 Corn(21) Dec 126000 9.4 1.968 RVAF INC 1 0.4 20000 6800 12 Na 47.587 Corn(21) Dec 72000 6.2 0.742 Tyson -Wilkes INC 1 0.4 93000 1500 19 Na 56.540 Corn(21) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 50.2 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 33.400 0.000 TOTALS: 50.2 570000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 154.396 106.387 Lime Applied Annuallbs/acre 0.046 0.015 0.323 0.000 0.030 0.014 0.124 0.124 0.061 5.373 68.554 Date lbs/ac Prior Years Cumulative lbs/ac 0.339 0.161 0.553 0.000 0.321 0.028 0.435 0.435 0.358 6.020 Apr 4000 Current Cumulative lbs/ac 0.384 0.176 0.877 0.000 0.351 0.042 0.560 0.560 0.419 11.393 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop F 190 1 187 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Supplemental Information PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: W00038087 Field #: WK-MRF-12 Acres Utilized: 25.1 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: Site #: WK-MRF-12 Acres Permitted: 25.1 Operator: Terra Renewal Services Predominant Soil Series: Pfafftown Cation Exchange Capacity (non 503): 7.34 Crop 1 Name: Corn -silage Crop 1 Max. PAN: 190.00 Crop 2 Name: Corn -silage ('21) Crop 2 Max PAN: 187.00 0 o Volume applied (enter one) Tons Gallons Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, W #, Fert., Animal Waste, etc) Soil Cond. (Dry, wet Moist) Precip. Past 24 Hrs. inches a co w L o ? * �. Z `; TKN mg/kg Z a o mg/kg Nitrate and Nitrite mg/kg PAN Remaining (lbs/acre) Name of Crop Type Receiving Residual Application pp Crop 1 Crop 2 Crop 1 Crop 2 April 50.2 1 59.8 1.196 Poultry Litter S 0.5 27,950 33.400 NA Corn-s 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.0 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 0.000 0.0 0.000 TOTALS: 550.21 0 0.000 33.4 0.000 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date ***C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (SUPP) (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 53.87 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 14.4 Acres Permitted: 14.4 Site #: WK-YF-01 Field #: 8.0 Nathalie WK-YF-01 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 9/17/20 2 RVAF 9/8/20 3 Tyson- Wilkes 9/8/20 4 5 6 7 8 9 10 11 12 % Solids 2.3 4.5 8.4 Arsenic 11.0 5.5 2.8 Cadmium 1 3.5 1.8 0.9 Copper 1 1200.0 10.0 8.2 Chromium Lead 7.0 5.9 1.9 Mercury 3.3 1.7 0.9 Molyb- denum 28.0 15.0 7.5 Nickel 28.0 15.0 7.5 Selenium 14.0 7.4 3.8 Zinc 190.0 57.0 15.0 Total Phos- horus 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.04 0.78 2.92 Arsenic 0.001 0.009 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Cadmium 0.000 0.003 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Copper 0.096 0.016 0.048 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.160 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.001 0.009 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.021 Mercury 0.000 0.003 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Molyb- 0.002 0.023 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.069 denum Nickel 0.002 0.023 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.069 Selenium 0.001 0.012 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.035 Zinc 0.015 0.089 0.088 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.192 Total Phos- 0.069 7.351 2.627 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.047 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-YF-01 Acres Utilized: 14.4 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 53.8681 Site #: YK-YF-01 Acres Permitted: 14.4 Operator: Terra Renewal Services Predominant Soil Series: Nathalie Cation Exchange Capacity (non 503): 8.0 Crop 1 Name: Small Grains Crop 1 Max. PAN: 98 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Oct 6000 2.3 0.040 Advance -Pierre INC 1 0.4 1 16000 460 1 58 0.538 NA S.G Oct 60000 4.5 0.782 RVAF INC 1 0.4 32000 21000 90 39.860 NA S.G Oct 120000 8.4 2.919 Tyson -Wilkes INC 1 0.4 6200 1400 33 19.575 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 186000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 59.973 0.000 Lime Applied Annuallbs/acre 0.026 0.167 0.009 0.076 0.160 0.323 0.000 0.000 0.021 0.157 0.008 0.015 0.069 0.243 0.069 0.243 0.035 0.183 0.192 0.776 10.047 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.193 0.085 0.483 0.000 0.178 0.023 0.312 0.312 0.218 0.968 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 98 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation C� **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 62.43 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 22.4 Acres Permitted: 22.4 Site #: WK-YF-03 Field #: 7.53 Clifford WK-YF-03 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 9/17/20 2 RVAF 9/8/20 3 Tyson- Wilkes 9/8/20 4 5 6 7 8 9 10 11 12 % Solids 2.3 4.5 8.4 Arsenic 11.0 5.5 2.8 Cadmium 1 3.5 1.8 0.9 Copper 1 1200.0 10.0 8.2 Chromium Lead 7.0 5.9 1.9 Mercury 3.3 1.7 0.9 Molyb- denum 28.0 15.0 7.5 Nickel 28.0 15.0 7.5 Selenium 14.0 7.4 3.8 Zinc 190.0 57.0 15.0 Total Phos- horus 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.03 0.60 2.16 Arsenic 0.001 0.007 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Cadmium 0.000 0.002 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 0.062 0.012 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.110 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.007 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.016 Mercury 0.000 0.002 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Molyb- 0.001 0.018 0.032 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 denum Nickel 0.001 0.018 0.032 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Selenium 0.001 0.009 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Zinc 0.010 0.069 0.065 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.143 Total Phos- 0.045 5.668 1.942 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7.655 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-YF-03 Acres Utilized: 22.4 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 62.4249 Site #: YK-YF-03 Acres Permitted: 22.4 Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 7.53 Crop 1 Name: Small Grains Crop 1 Max. PAN: 120 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Sep -Oct 6000 2.3 0.026 Advance -Pierre INC 1 0.4 1 16000 460 1 58 0.346 NA S.G Sep -Oct 72000 4.5 0.603 RVAF INC 1 0.4 32000 21000 90 30.749 NA S.G Sep -Oct 138000 8.4 2.158 Tyson -Wilkes INC 1 0.4 6200 1400 33 14.471 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 216000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 45.567 0.000 Lime Applied Annuallbs/acre 0.019 0.124 0.006 0.057 0.110 0.226 0.000 0.000 0.016 0.117 0.006 0.011 0.052 0.178 0.052 0.178 0.026 0.136 0.143 0.529 7.655 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.144 0.064 0.336 0.000 0.133 0.018 0.230 0.230 0.162 0.672 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop 120 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 16.96 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 23.3 Acres Permitted: 23.3 Site #: WK-YF-04 Field #: 5.69 Clifford WK-YF-04 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 9/17/20 2 RVAF 9/8/20 3 Tyson- Wilkes 9/8/20 4 5 6 7 8 9 10 11 12 % Solids 2.3 4.5 8.4 Arsenic 11.0 5.5 2.8 Cadmium 1 3.5 1.8 0.9 Copper 1 1200.0 10.0 8.2 Chromium Lead 7.0 5.9 1.9 Mercury 3.3 1.7 0.9 Molyb- denum 28.0 15.0 7.5 Nickel 28.0 15.0 7.5 Selenium 14.0 7.4 3.8 Zinc 190.0 57.0 15.0 Total Phos- horus 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.00 0.10 0.63 Arsenic 0.000 0.001 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Cadmium 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.000 0.002 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.004 Mercury 0.000 0.000 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.000 0.003 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 denum Nickel 0.000 0.003 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Selenium 0.000 0.001 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Zinc 0.000 0.011 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Total Phos- 0.000 0.912 0.568 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.480 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-YF-04 Acres Utilized: 23.3 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 16.9636 Site #: YK-YF-04 Acres Permitted: 23.3 Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 5.69 Crop 1 Name: Small Grains Crop 1 Max. PAN: 120 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Oct 0 2.3 0.000 Advance -Pierre INC 1 0.4 1 16000 460 1 58 0.000 NA S.G Oct 12000 4.5 0.097 RVAF INC 1 0.4 32000 21000 90 4.927 NA S.G Oct 42000 8.4 0.631 Tyson -Wilkes INC 1 0.4 6200 1400 33 4.234 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 54000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 9.161 0.000 Lime Applied Annuallbs/acre 0.005 0.135 0.002 0.063 0.012 0.192 0.000 0.000 0.004 0.128 0.001 0.009 0.012 0.180 0.012 0.180 0.006 0.145 0.030 0.485 1.480 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.140 0.065 0.205 0.000 0.132 0.010 0.193 0.193 0.152 0.515 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit 1 st/2nd Crop 120 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 43.60 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 27.1 Acres Permitted: 27.1 Site #: WK-YF-5A Field #: 8.24 Clifford WK-YF-5A Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 9/17/20 2 RVAF 9/8/20 3 Tyson- Wilkes 9/8/20 4 5 6 7 8 9 10 11 12 % Solids 2.3 4.5 8.4 Arsenic 11.0 5.5 2.8 Cadmium 1 3.5 1.8 0.9 Copper 1 1200.0 10.0 8.2 Chromium Lead 7.0 5.9 1.9 Mercury 3.3 1.7 0.9 Molyb- denum 28.0 15.0 7.5 Nickel 28.0 15.0 7.5 Selenium 14.0 7.4 3.8 Zinc 190.0 57.0 15.0 Total Phos- horus 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. '~ 14 Event 0.00 0.29 1.32 Arsenic 0.000 0.003 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Cadmium 0.000 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.000 0.006 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.003 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.008 Mercury 0.000 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.000 0.009 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 denum Nickel 0.000 0.009 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Selenium 0.000 0.004 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Zinc 0.000 0.033 0.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.073 Total Phos- 0.000 2.735 1.186 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.922 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: YK-YF-5A Acres Utilized: 27.1 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 43.6099 Site #: YK-YF-5A Acres Permitted: 27.1 Operator: Terra Renewal Services Predominant Soil Series: Clifford Cation Exchange Capacity (non 503): 8.24 Crop 1 Name: Small Grains Crop 1 Max. PAN: 120 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Oct 0 2.3 0.000 Advance -Pierre INC 1 0.4 1 16000 460 1 58 0.000 NA S.G Oct 42000 4.5 0.291 RVAF INC 1 0.4 32000 21000 90 14.826 NA S.G Oct 102000 8.4 1.318 Tyson -Wilkes INC 1 0.4 6200 1400 33 8.841 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 144000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 23.667 0.000 Lime Applied Annuallbs/acre 0.011 0.122 0.132 0.004 0.056 0.060 0.027 0.193 0.220 0.000 0.000 0.000 0.008 0.114 0.123 0.003 0.010 0.013 0.029 0.174 0.202 0.029 0.174 0.202 0.014 0.133 0.147 0.073 0.524 0.597 3.922 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 120 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." e �Q 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 62.98 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 20.5 Acres Permitted: 20.5 Site #: WK-YF-513 Field #: 8.0 Fairview WK-YF-5B Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 9/17/20 2 RVAF 9/8/20 3 Tyson- Wilkes 9/8/20 4 5 6 7 8 9 10 11 12 % Solids 2.3 4.5 8.4 Arsenic 11.0 5.5 2.8 Cadmium 1 3.5 1.8 0.9 Copper 1 1200.0 10.0 8.2 Chromium Lead 7.0 5.9 1.9 Mercury 3.3 1.7 0.9 Molyb- denum 28.0 15.0 7.5 Nickel 28.0 15.0 7.5 Selenium 14.0 7.4 3.8 Zinc 190.0 57.0 15.0 Total Phos- horus 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. 14 Event 0.00 0.71 2.36 Arsenic 0.000 0.008 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Cadmium 0.000 0.003 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.000 0.014 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.053 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.008 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.017 Mercury 0.000 0.002 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Molyb- 0.000 0.021 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 denum Nickel 0.000 0.021 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Selenium 0.000 0.011 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 Zinc 0.000 0.081 0.071 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.152 Total Phos- 0.000 6.712 2.122 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.834 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-YF-5B Acres Utilized: 20.5 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 62.9753 Site #: WK-YF-5B Acres Permitted: 20.5 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 8.0 Crop 1 Name: Small Grains Crop 1 Max. PAN: 80 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Sep -Oct 0 2.3 0.000 Advance -Pierre INC 1 0.4 1 16000 460 1 58 0.000 NA S.G Sep -Oct 78000 4.5 0.714 RVAF INC 1 0.4 32000 21000 90 36.399 NA S.G Sep -Oct 138000 8.4 2.358 Tyson -Wilkes INC 1 0.4 6200 1400 33 15.813 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 216000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 52.212 0.000 Lime Applied Annuallbs/acre 0.021 0.118 0.007 0.053 0.053 0.170 0.000 0.000 0.017 0.109 0.007 0.013 0.057 0.183 0.057 0.183 0.028 0.132 0.152 0.573 8.834 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.140 0.060 0.223 0.000 0.127 0.020 0.240 0.240 0.160 0.725 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 80 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 31.00 WQ0038087 Terra Renewal Services Cation Exchange Capacity (non 503 only): Owner: Mathis Properties, LLC Predominant Soil Series: 10.3 Acres Permitted: 10.3 Site #: WK-YF-07 Field #: 9.75 Fairview WK-YF-07 Residual Analysis Data (Heavy Metals and Total Phosphorus use mPA2. % Solids use Raw Percent ft Sample or Com- posite Date 1 Advance Pierre 9/17/20 2 RVAF 9/8/20 3 Tyson- Wilkes 9/8/20 4 5 6 7 8 9 10 11 12 % Solids 2.3 4.5 8.4 Arsenic 11.0 5.5 2.8 Cadmium 1 3.5 1.8 0.9 Copper 1 1200.0 10.0 8.2 Chromium Lead 7.0 5.9 1.9 Mercury 3.3 1.7 0.9 Molyb- denum 28.0 15.0 7.5 Nickel 28.0 15.0 7.5 Selenium 14.0 7.4 3.8 Zinc 190.0 57.0 15.0 Total Phos- horus 860 4,700 450 Annual Heavy Metal Field Loadings (Ualculated in lbs/acre): Total 1 2 j 3 j 4 5J 6j 7 81 91 10 11-1 12 DT/Ac./ App. 14 Event 0.00 0.77 2.25 Arsenic 0.000 0.008 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Cadmium 0.000 0.003 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.000 0.015 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Chromium 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Lead 0.000 0.009 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.018 Mercury 0.000 0.003 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Molyb- 0.000 0.023 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 denum Nickel 0.000 0.023 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Selenium 0.000 0.011 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 Zinc 0.000 0.087 0.067 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.155 Total Phos- 0.000 7.191 2.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 9.212 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/25/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038087 Field #: WK-YF-07 Acres Utilized: 10.3 Land Owner: Mathis Properties, LLC Annual Dry Tons Applied: 30.9998 Site #: WK-YF-07 Acres Permitted: 10.3 Operator: Terra Renewal Services Predominant Soil Series: Fairview Cation Exchange Capacity (non 503): 9.75 Crop 1 Name: Small Grains Crop 1 Max. PAN: 98 Crop 2 Name: Crop 2 Max. PAN: 0 0 p Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons oho Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (Dry, Moist) Precip. past 24 Hrs. inches y o °o *Z o ? rn * °� ��, * * fKN mg/kg Z a 07 o .°n �. mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 Sep 0 2.3 0.000 Advance -Pierre INC 1 0.4 1 16000 460 1 58 0.000 NA S.G Sep 42000 4.5 0.765 RVAF INC 1 0.4 32000 21000 90 39.009 NA S.G Sep 66000 8.4 2.245 Tyson -Wilkes INC 1 0.4 6200 1400 33 15.052 NA S.G 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 108000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 54.060 0.000 Lime Applied Annuallbs/acre 0.021 0.133 0.007 0.063 0.052 0.148 0.000 0.000 0.018 0.130 0.007 0.012 0.057 0.180 0.057 0.180 0.028 0.143 0.155 0.508 9.212 Date lbs/ac Prior Years Cumulative lbs/ac Apr 4000 Current Cumulative lbs/ac 0.154 0.070 0.200 0.000 0.147 0.019 0.236 0.236 0.172 0.662 Nov 2000 Permitted C. P. L. R.**** 36 34 1338 N/A 267 15 N/A 374 89 2498 Permit PAN Limit I st/2nd Crop 98 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2/25/2021 *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date * * * Mineralization Rates: Compost -0. 1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) 4 Laboratory Analyses: - Nutrients, Metals, TCLP, Other aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:VB28001 Date Completed:03/13/2020 03/16/2020 4:08 PM Approved and released by: Lab Director - Greenville: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs'in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 9 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: VB28001 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 9 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: VB28001 Sample Number Sample ID Matrix Date Sampled Date Received 001 Tyson-Wilsboro Solid 02/27/20201500 02/28/2020 (1 sample) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 9 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: VB28001 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Tyson-Wilsboro Solid % Volatile Solids SM 2540G- 98 B % 5 001 Tyson-Wilsboro Solid Ammonia - N (gas 350.1 2100 mg/kg 5 001 Tyson-Wilsboro Solid Nitrate -Nitrite - N (soluble) 353.2 16 mg/kg 5 001 Tyson-Wilsboro Solid Phosphorus 365.1 4500 mg/kg 5 001 Tyson-Wilsboro Solid TKN 351.2 73000 mg/kg 5 001 Tyson-Wilsboro Solid Copper 6010D 59 mg/kg 6 001 Tyson-Wilsboro Solid Lead 6010D 15 mg/kg 6 001 Tyson-Wilsboro Solid Zinc 6010D 170 mg/kg 6 (8 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VB28001-001 Description: Tyson-Wilsboro Matrix: Solid Date Sampled:02/27/2020 1500 % Solids: 4.73 02/29/2020 0020 Date Received:02/28/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (% Volatile S) SM 254OG-1997 1 03/05/2020 2347 MOM 47064 1 350.1 (Ammonia - N ) 350.1 5 03/09/2020 1306 SLC 46871 1 (Nitrate-Nitr) 353.2 1 03/04/2020 1923 AMR 47003 1 (Phosphorus) 365.1 5 03/02/2020 1721 DMA 03/02/2020 1403 46592 1 (Soil pH meas) 9045D 1 03/03/2020 1936 SRB 46787 1 351.4 (TKN) 351.2 2 03/03/2020 1432 DMA 03/03/2020 0936 46595 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 2540G- 98 B % 2 Ammonia - N (gas diffusion) 350.1 2100 1100 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 16 4.2 mg/kg 1 Phosphorus 7723-14-0 365.1 4500 530 mg/kg 1 Soil pH measured in water @ 21.3 o C 9045D 3.7 su 1 TKN 351.2 73000 1100 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 1 03/12/2020 2025 NCM 03/11/2020 1700 47546 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 350 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 350 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 350 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 350 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 350 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 350 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 350 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 83 41-132 Tetrachloro-m-xylene 82 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 03/04/2020 1443 KSH2 03/04/2020 1130 46556 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.6 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VB28001-001 Description: Tyson-Wilsboro Matrix: Solid Date Sampled:02/27/2020 1500 % Solids: 4.73 02/29/2020 0020 Date Received:02/28/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/03/2020 0303 LLL 02/29/2020 1123 46242 Parameter CAS Analytical Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D ND 410 mg/kg 1 Arsenic 7440-38-2 6010D ND 15 mg/kg 1 Cadmium 7440-43-9 6010D ND 5.1 mg/kg 1 Calcium 7440-70-2 6010D ND 5100 mg/kg 1 Copper 7440-50-8 6010D 59 10 mg/kg 1 Lead 7439-92-1 6010D 15 10 mg/kg 1 Magnesium 7439-95-4 6010D ND 5100 mg/kg 1 Molybdenum 7439-98-7 6010D ND 41 mg/kg 1 Nickel 7440-02-0 601OD ND 41 mg/kg 1 Potassium 7440-09-7 601OD ND 5100 mg/kg 1 Selenium 7782-49-2 601OD ND 20 mg/kg 1 Sodium 7440-23-5 6010D ND 5100 mg/kg 1 Zinc 7440-66-6 6010D 170 51 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 9 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 9 PACE ANALYTICAL SERVICES, LLC eChat».00CVtfOffyrl;•ocord Rep n o} ow a cr 7mgrl"A a+ts, I.:, 3lf A 113fllrvarlL-• LTJE TMY .jh" ---.ram �•}•w agta ie"--43'M 1171whr INIy a�b1 Hwh.'kuc 1l -drx, Note, All ail llpbau ara I ;.less rifler S!ree_y Z[IYCbhmental �erYlCes. rx 106 VanhMfi AOifi E]nwc J.';4 t 4<4mtl51 SMh Cerallra cz7172 Aumb r V-_1hcrCka[., aG3j7SL,87CC =.rx Ho•{g3M7G-pIii wM�ndlirt 1�n i'bpidh! Nx I �ru GCRxn d74 77F.8iki 1 dfxb,.�l }gNl.arnrxN,� .,. M.1h i I A1aYftt Vo of CalltffrlurF 7i �cervehNo Bea Atl:ll Tyoc p 4Lkk lErp ' kfEl-fl--4d VB28001 kr. wy � x � la x x X "11L4 .1 N5f4P1L,1L hY:l[y:41q n,r5;,1+1ck h11 aa}q-pnMn Foot�la�u1: .t•h,a,l lry�:a4 •++IQrtr. a1.r0 e:4r.,rai fin.-aa 57, Mk3ivm rk"pi ..h3 UBh 0 C1Y' ' )-- u:ad`J. 9![1ih5w14x 7c1a. Y N 16i.Mtl< ri nviµT 4. 6o-w-'G rw.1...,a �jkr. WEbi2V", Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 9 PACE ANALYTICAL SERVICES, LLC %hrIvTrviiiorimmel krAms, Inc. pCip I a] oaauMar,e Nwnbsr: 3+iL4] t SC -ICI ZtTsstius Dote: 8.+2f2u is Sample Receiptl�ecl�list (�:� C'-lieaLi: Terri Rennval Ctxr[nr lnhpcx" byldat�-.; L]U.1 r 0212812020 Lot k; VMSODI of raceipr ❑E31 ❑ Ye"I 0 N IC, 1 1- WrLre custody seal presenL or the cTojer7 Ye{ No AAA 2- II` , tWly uL.Le-s WON prese11, wtun: tl,ev 4Ttact and -:inb c}kcu? pl I ID; NA Chlorines grip TD- NA _ 1u5tcd by,. NA Original tem�-,eealum uP;tr rccoipt l Uariv-d 'CeSncatcd) teiuperWure upon rcccipt °b�gllt! �n$p-pup rii: l4 as' 3 ;'.6 14-6 QC MA INA aC NA INA qC NA INA oc ---Met[7oJ: ❑Trantn.ry]Lim Blank 2]Aepiti;1Bottics IR Gur 10: 6 iCt Urin C:or.ce:t:on Fact= Q 'Q MiAl.od Of CA]O]atrt ® WOt Ice ❑ le-2 Pacts ❑ Dry Ice ❑ T (,ne J `has ❑ T[o -� -�+' 3- If tamperal.nre, of any cooler exc�emW S.()PC, was Project Manager Ntotitied? PM was Notified by: plror-e J e,na.J f face-ra-t ec (cimla o,)c), Yes ❑ No ❑ NA 111. Is the ctran:iterc ia] courier's pprWng slip attached to this form? _® Yes El Nla 15. Were proper custody Gruexdures (rc1[nquisttedlreoeivod) fo]li,we,.l? Q,l Yes ❑ Na 6. Weis samply 19s listed on the COC: Yes ❑ N-D 7, Were sa,nglu JDs listed fin atJ sample L'onta[mrs7 Yes ❑ No 8. Maas co[1cct=fin dart & time listed pn lac COC?LJ - Yrs No _ 9- VWs� imllcvtim date & timu lists- on a]J sr=mp=V Wata=ners'? 10, Did a]I coma--ne.r [abo- a fbrlr,nticrrt ICID, dare, time) agree Witt :he CQC? 11. w rc twists to he pertormcd listed on the COC? Ye{ ❑ No ENO IZI Yes ❑ No 12. Did 411 aauaples arrive in the,, FrOper cantal[uars forcaoh rest and,'or in goad COndj&D 1(Lu6-njKvq Ii& on, etc,)' Yes 0 Ttiar I :. Vw'3s adequam St.mp:o voluerle. xvaeilab4c7 - Yes F7 No 14- WfIxe all same=es recciv:d within Ya the holding Here Or �$ hOLLIS tiv[tiCti�urr comes li_.;'? -yesil0 15. Wcm any+ sompl}s oantai:iers mi,,.sing!excess i,e;wA6 one) sate leh plot Jistec on COC? El Yes ❑ No NA16. For VOA mind R K-175 satrtplc& wcrc buhblm present �• Q-S ice° ` (! a"or 6 ir. m in dianiete:, in any ofthe Y(?h witty? ❑ Yes l�lo NA 17, Wcrc a l l f)R.(]hneta;s riuti ieitl LmmpJes received at a pH of < 2? T I ' YCE ❑ Nr, ® NAI 18, Were all U}Mni&- sHro tes receivod at a p-I > 12 HLsd stllti& sremp[ci rece]vrc[ ad M pH > 9? ❑ it No I ONA 1'- We-m J I "licabile,: 3lTJK. oymide�pRorro1'625 <0-5TrzjL}salrpletifineofrA:s-dual ❑ Yes ©lvJa NA 2D, Mac elient reir.arkstrayuest3 (j.e, rcyucsmel dilutions. 7v1&eMSD desigmatlam. eje—) ormctly tramodbed =rom the COC into the cartmelu Sei:tlun in T.IC++157 Q t': s Nq 21. VWaE the qijuft number fisted on Clic mrtainer 1;RbcJ` if yes, Quote 0 NA JPr,eserv;ition (?�it1s: bo cam�i�#ed floc ttrtyr saenple�s) inc�o_•r,:c`:}• prescr+�ad fir wrilfi lt�ads]r.ce,] iample(s) NA n sarrmp!e Wir'.r NA Circa of pmerwa[iar NA larnplc(L) NA wtTo raceivM=ncornecllY prua.Tvcd a rid vv U: c Adjustad a x!DTdi-ia[y lr]LW cliulc ono; H2Sat HNO3,1-I0, WOH using 5R-M NA _ _ . 1f moil than one po+ erwakive i headed, picHse cute ire the cor7t�]ee]Is bdow- were reL�Civcd Wit') bL;bblus --r inin in dimr-eu-r, m(s) NA--- were meived will TICC > 0,5 mg{L, (If #1 9 is no ) and mire ,d .3murdin¢ly in SDrnple receiving with sod [urn lhiosulfate a252 ) wall S.waly il}; Nth barkxde lab-cls applied by, LKH Cot=,iuents; Daft: 02 B12020 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 9 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:VC27001 Date Completed:04/08/2020 04/08/2020 3:40 PM Approved and released by: Lab Director - Greenville: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs'in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 11 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: VC27001 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids samples -001 and -002 were weighed out at 3 times the normal amount. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 11 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: VC27001 Sample Number Sample ID Matrix Date Sampled Date Received 001 TYSON/ Harmony Solid 03/26/2020 03/27/2020 002 Advanced Foods/Claremont Solid 03/26/2020 03/27/2020 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of I I PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: VC27001 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 TYSON/ Harmony Solid % Volatile Solids SM 2540G- 86 % 5 001 TYSON/ Harmony Solid Ammonia - N (gas 350.1 17000 mg/kg 5 001 TYSON/ Harmony Solid Nitrate -Nitrite - N (soluble) 353.2 27 mg/kg 5 001 TYSON/ Harmony Solid Phosphorus 365.1 23000 mg/kg 5 001 TYSON/ Harmony Solid TKN 351.2 22000 mg/kg 5 001 TYSON/ Harmony Solid Aluminum 6010D 20000 mg/kg 6 001 TYSON/ Harmony Solid Calcium 6010D 67000 mg/kg 6 001 TYSON/ Harmony Solid Copper 6010D 39 mg/kg 6 001 TYSON/ Harmony Solid Magnesium 6010D 2000 mg/kg 6 001 TYSON/ Harmony Solid Potassium 6010D 4100 mg/kg 6 001 TYSON/ Harmony Solid Sodium 6010D 4000 mg/kg 6 001 TYSON/ Harmony Solid Zinc 6010D 150 mg/kg 6 002 Advanced Foods/Claremont Solid % Volatile Solids SM 2540G- 93 % 7 002 Advanced Foods/Claremont Solid Nitrate -Nitrite - N (soluble) 353.2 24 mg/kg 7 002 Advanced Foods/Claremont Solid Phosphorus 365.1 7000 mg/kg 7 002 Advanced Foods/Claremont Solid TKN 351.2 1900 mg/kg 7 002 Advanced Foods/Claremont Solid Aluminum 6010D 7400 mg/kg 8 002 Advanced Foods/Claremont Solid Copper 6010D 870 mg/kg 8 002 Advanced Foods/Claremont Solid Lead 6010D 4.2 mg/kg 8 002 Advanced Foods/Claremont Solid Nickel 6010D 22 mg/kg 8 002 Advanced Foods/Claremont Solid Sodium 6010D 10000 mg/kg 8 002 Advanced Foods/Claremont Solid Zinc 6010D 160 mg/kg 8 (22 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 11 Client: Terra Renewal Services, Inc. Laboratory ID:VC27001-001 Description: TYSON/ Harmony Matrix: Solid Date Sampled:03/26/2020 % Solids: 4.21 03/28/2020 0008 Date Received: 03/27/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 04/01/2020 2341 MOM 49737 1 350.1 (Ammonia - N ) 350.1 25 03/30/2020 1415 DRD 49331 3 (Nitrate-Nitr) 353.2 1 04/08/2020 0000 AMR 50324 1 (Phosphorus) 365.1 25 03/27/2020 1235 DMA 03/27/2020 0758 49065 1 (Soil pH meas) 9045D 1 03/27/2020 1930 SRB 49261 1 351.4 (TKN) 351.2 1 03/31/2020 1341 DMA 03/30/2020 0822 49288 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 2540G- 86 % 1 Ammonia - N (gas diffusion) 350.1 17000 5900 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 27 4.8 mg/kg 3 Phosphorus 7723-14-0 365.1 23000 3000 mg/kg 1 Soil pH measured in water @ 22.4 ° C 9045D 6.2 su 1 TKN 351.2 22000 590 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 3665A 8082A 1 04/07/2020 1943 DAL1 04/06/2020 2220 50123 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 390 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 390 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 390 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 390 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 390 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 390 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 390 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 74 41-132 Tetrachloro-m-xylene 80 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 03/31/2020 1312 KSH2 03/31/2020 0244 49286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.9 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 11 Client: Terra Renewal Services, Inc. Laboratory ID:VC27001-001 Description: TYSON/ Harmony Matrix: Solid Date Sampled:03/26/2020 % Solids: 4.21 03/28/2020 0008 Date Received:03/27/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/31/2020 2002 LLL 03/28/2020 1257 49279 Parameter CAS Analytical Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 20000 150 mg/kg 1 Arsenic 7440-38-2 6010D ND 5.8 mg/kg 1 Cadmium 7440-43-9 6010D ND 1.9 mg/kg 1 Calcium 7440-70-2 6010D 67000 1900 mg/kg 1 Copper 7440-50-8 6010D 39 3.9 mg/kg 1 Lead 7439-92-1 6010D ND 3.9 mg/kg 1 Magnesium 7439-95-4 6010D 2000 1900 mg/kg 1 Molybdenum 7439-98-7 6010D ND 15 mg/kg 1 Nickel 7440-02-0 6010D ND 15 mg/kg 1 Potassium 7440-09-7 6010D 4100 1900 mg/kg 1 Selenium 7782-49-2 6010D ND 7.7 mg/kg 1 Sodium 7440-23-5 6010D 4000 1900 mg/kg 1 Zinc 7440-66-6 6010D 150 19 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 11 Client: Terra Renewal Services, Inc. Laboratory ID:VC27001-002 Description: Advanced Foods/Claremont Matrix: Solid Date Sampled:03/26/2020 % Solids: 4.44 03/28/2020 0008 Date Received: 03/27/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 04/01/2020 2341 MOM 49737 1 350.1 (Ammonia - N ) 350.1 1 03/30/2020 1451 DRD 49331 3 (Nitrate-Nitr) 353.2 1 04/08/2020 0000 AMR 50324 1 (Phosphorus) 365.1 10 03/27/2020 1315 DMA 03/27/2020 0758 49065 1 (Soil pH meas) 9045D 1 03/27/2020 1935 SRB 49261 1 351.4 (TKN) 351.2 1 03/31/2020 1341 DMA 03/30/2020 0822 49288 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 2540G- 93 % 1 Ammonia - N (gas diffusion) 350.1 ND 230 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 24 4.5 mg/kg 3 Phosphorus 7723-14-0 365.1 7000 1100 mg/kg 1 Soil pH measured in water @ 22.4 ° C 9045D 6.2 su 1 TKN 351.2 1900 560 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 3665A 8082A 1 04/07/2020 1956 DAL1 04/06/2020 2220 50123 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 370 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 370 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 370 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 370 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 370 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 370 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 370 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 81 41-132 Tetrachloro-m-xylene 87 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 03/31/2020 1315 KSH2 03/31/2020 0244 49286 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 11 Client: Terra Renewal Services, Inc. Laboratory ID:VC27001-002 Description: Advanced Foods/Claremont Matrix: Solid Date Sampled:03/26/2020 % Solids: 4.44 03/28/2020 0008 Date Received:03/27/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/31/2020 2006 LLL 03/28/2020 1257 49279 Parameter CAS Analytical Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 7400 150 mg/kg 1 Arsenic 7440-38-2 6010D ND 5.6 mg/kg 1 Cadmium 7440-43-9 6010D ND 1.9 mg/kg 1 Calcium 7440-70-2 6010D ND 1900 mg/kg 1 Copper 7440-50-8 6010D 870 3.7 mg/kg 1 Lead 7439-92-1 6010D 4.2 3.7 mg/kg 1 Magnesium 7439-95-4 6010D ND 1900 mg/kg 1 Molybdenum 7439-98-7 6010D ND 15 mg/kg 1 Nickel 7440-02-0 6010D 22 15 mg/kg 1 Potassium 7440-09-7 601OD ND 1900 mg/kg 1 Selenium 7782-49-2 601OD ND 7.4 mg/kg 1 Sodium 7440-23-5 6010D 10000 1900 mg/kg 1 Zinc 7440-66-6 6010D 160 19 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 11 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 11 PACE ANALYTICAL SERVICES, LLC 5hapV Erulmumnm I Servl:es, Inc. 1CO V•ar"o PcinL ar e KSI." CAaB1 oFCusCddyRecnrd 4'h "I Wurnf.,4Sxl1h C-"hiz 2SI72 HuLnbar 1�ItPh�chb,160.�j 7J1-0it+7 Fir Yc.(�°}7}i.97ii .,�rdH�h'.r4.rr11 Einrl: 7T4, ■+hk.+il Rare, 1. CYrt— 1.ip .M Hx flari MTL C:}i4 AT4T�IJ-0'ia I SY+YIFv1lrpCj.lnl.,wl�ron Y117d N!. MAI— F-Mlw.30 a4U.Tu•. Im�iiti*".:a X._ .. �. ,I..rad nw.15 btw—p— N -.d.Q Pile II � �J.I11 C I7I11� 117IL�h11�IV1i; J�LIIII� �IA■U19V`lTUlu+ +l2 r M-• f!rkavl4 AM TZFM fiCh ii11 FLL"Mffm PK}�a lance: Fo hl�. CaWu'hlya Cdh.ln C S i-,. i.1a.7% asgym9 hlo of �'ornal�lrs ty FNacwaV.tr Type 59B Iaa!l�rkfiui._K, vtla}k 1rL+mFaacsrwson.es�c..l.w rb I AF." Ra c x x x c x �L x c x x x c x x x o x x x c x x x - x ,nU..11—Fm re V. uL,-.W-J a aliu ry YrFal4•,--0r s�FYFYi 9Js7Y F%""aU1 *b IIIA&W1 FuUnIp Awr. LIspkGAby Lq;&�# ASYLij.ivLa}1rirSY-]1151 MLAdd A_M.1 u7WdI 111111a011145', ( `RWfii4ftyjl� ]oirW, YrE�lr '�� aReWdsiodby no, TM 7. ryl X?M.,7 rlrlw rY 7%prFr)+s-adbf o}�l�rF,}} _ �....d ar .I. II rYaSWr:.tl by 77 y� f fr T�OV -RM��yy ..fir ,•��+ r'� �/ 4. LI[4YIrN rd: hWi= f -413 r F 7YfN Y Syr. VCIC: Al 5I:FM16a Se rulkined h4-ha 4 -,rs T.VII reoiipl IIlkCY LII'er CI[S�YJIIry�ar' In�G. LAMUCCCCLY Pw*-rd w 1w%h q-;'1 Y !1 ry Fi* —d•I6.T._— —L• C&FM"II tine tie.. RM32PY! a - Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 11 PACE ANALYTICAL SERVICES, LLC 51m.y T.mA:rorPrr4nt.l ycrrkv-F, :rs. 1.,2gc I of I Dccumaut Nurote_' ir1kd0018C-L4 bfedi.v !:ULm. rd2.WL A Sample Receipt, Checklist (SRC) Client, Terra Rtacwtal Cooler Insawted 'da!, LKH 103A'27=0 Lot-9. VC2 1301 Means: nfweip ❑ SCSI ❑ CEOnt 91 UPS 0 Fed6x Lj Other: - _aYcsl ® Nc l . Were ajA> ndy saftle; rttde4cot 4n t110 coaler� - Yeas No iA f_. Ifcttstody3enfi, wece reSeii� WIM r-t_cy iniw t andunbroker_, PH Strip, Ili, _KA OilorLlL- Strict 1D: NA Tested h 'dA Drtinal lwnprrature upon receipt 11=teriY, ;j (CwTeul.od) tcmpramtum elm receipt °fuSolid Snap -Cup IR �19.20'-3 2.1 2,1 PC. NA !NA uC, - A 1NA "C NA INA °C MP-thDd' E]TemperftureB[a1=k WdApiur:1. Rottici TR Curl j1; 5 TR Gun Corrcetion Factor_ 0 Arinfhod of coaiflar! 0 %Vet, Icc 11 Ice Packs ❑ Drw Toe © gone [� Yes ❑ No O NA '. 1ftenaperattue ul' auy mx ukc exceeded 6.0 . wsrs Praj-no: Manager Noril'Led' PM wss Notifik.d �y: photle f emai[ f fam. to face (circle ono). 0 Yos' ❑ ,Na ❑NA 4. is [lie cfxmme--r ;:VI coLr.icr's packing Ap-aL€avhcd to this fnrm? ® Ye; 0 flu 5. W= proper custody prOWUTTs (rolinquisl dlrm+ti cd) HIGwc& Yci fl No 6, `i4'e[C wunpit lDz listed on the EOC19 7Y ❑ No ?, Wore sample IDc Iistcd on all sale .le. containm? _ ❑ Ycs 0 -No 8. Vd#L5 Colioct:on da=e c c tinge l[5WC[ on thr C:OC ❑ Yes 10 mc, 9. Was ca I I eci on r1we tine I [sroed on all s&mp;c conta:ner99 0 Yes ❑ No 10. Did aril Lonrainer libel inibrination (ID, date, tirr:e) 85mo vith Jle COC? ❑ Ys� ❑ No 11. 1 Nv. Irsts to be Pea'fottued Iistcd an tim CQc? ® Yes ❑ Ne 12, Did till kimploa ar-ivc i n the proprr containers :or t!ih Lay L KMSVor i n good co rLdi tiC n (unRsrnker-. lids on, otc_j7 _ V'es ❑ NO € . WaS adsaquate Sample vnlumo ava=lable'1 ye" NQ 14. Were ail souuplc3 rmcived within ',� Ihe. holding thine or 48 hours, w ichever noiilcS first? No 15. Were ary samples cogt dnm miminecxcess (circle otic) samples Not 1 sIc11 cm CC+C7 YGs ❑i�D 0NA. 115. FoT VOA aid RSK-175 sampics, vieve IpUbblc4 prment> pea-!ize" (1/Tor Clnir_ in di tc:l _n any of-dic VOA Oils? ❑ Yes 0 No NA l 7. Were alJ DKLilniet sel:tC[Jml. 3am31ss m eivr. at a fi of < 2'i ❑ Yes ❑ ND NA I $. W4�ro al. cyanide sampl.* T-cceived at a pH > I2 prLd sulfide $Rmples =c[vL:d at a pi-T> 9? 19_ Wcre ftE ap; cUj t TNTit)T Nicj�anideiphuntrli .Srng{J,) sxmp:cs free of r>rsidua[ El Yes El No' NA chlori,�? ❑ Yes ❑ Nu NA 20, Were client rcrrlarlslrequests (ix. requested dilutions, Iw SINI5D designations, etc_„) cmrwdv tradfscril.nd rium the. C:OC: into the coauneot serjiQTL in -IMS'F n Y, s MCI 21 _ Waa tits quote numb -a Ji3wd on Tlw wuntairur label's If 'es toac 9 NA ;ample Preservvqun (Must be complelod for any siamplc(s) incorrectly presc­md or vei[h I-AINPWc.) ;ample(s) NA wgm r=clved incorrnrtly preserved ui id wcrc a,d j ustltd a.- L -din gly ti;am plcratccivin;�xith NA7 mLofcircleotre;H 9044 11N07,HC4Na0HusingSR0 MA Cimc ,rd pmservation IAA 11'mnre d;an one � Mservative is ncodcd, please na: ill tliQ cfrnur:r,L[s.kxflow. were T mived with bubbles >6 mm in dla=tcr. ; r 1pJcs(s) NA were received with TRC > 0.5 nig'L (If 019 is no) and were u1iUN[V i acumdinly in sar --ile. =eiying vita sadiumt7[osulikte Fha2R,�W with Shealy Tll: NA Woode labels applied by; .LKH Date, 43127,2020 Cnmme:i . Na coJ[-tution times Iived un COC or sate is containers. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 11 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:VD03002 Date Completed:04/10/2020 04/15/2020 5:16 PM Approved and released by: Lab Director - Greenville: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs'in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 9 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: VD03002 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 9 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: VD03002 Sample Number Sample ID Matrix Date Sampled Date Received 001 TYSON/ Wilksboro Solid 04/02/2020 1430 04/03/2020 (1 sample) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 9 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: VD03002 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 TYSON/ Wilksboro Solid % Volatile Solids SM 2540G- 98 % 5 001 TYSON/ Wilksboro Solid Ammonia - N (gas 350.1 2600 mg/kg 5 001 TYSON/ Wilksboro Solid Nitrate -Nitrite - N (soluble) 353.2 19 mg/kg 5 001 TYSON/ Wilksboro Solid Phosphorus 365.1 4000 mg/kg 5 001 TYSON/ Wilksboro Solid TKN 351.2 43000 mg/kg 5 001 TYSON/ Wilksboro Solid Copper 6010D 16 mg/kg 6 001 TYSON/ Wilksboro Solid Potassium 6010D 4800 mg/kg 6 001 TYSON/ Wilksboro Solid Sodium 6010D 2500 mg/kg 6 001 TYSON/ Wilksboro Solid Zinc 6010D 89 mg/kg 6 (9 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VD03002-001 Description: TYSON/ Wilksboro Matrix: Solid Date Sampled:04/02/2020 1430 % Solids: 4.73 04/03/2020 2139 Date Received:04/03/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 04/08/2020 2336 MOM 50417 1 350.1 (Ammonia - N ) 350.1 5 04/06/2020 1346 DMA 50065 2 (Nitrate-Nitr) 353.2 1 04/08/2020 0000 AMR 50324 1 (Phosphorus) 365.1 5 04/06/2020 1620 DMA 04/06/2020 1221 50071 1 (Soil pH meas) 9045D 1 04/07/2020 1951 SRB 50256 1 351.4 (TKN) 351.2 1 04/07/2020 1521 DMA 04/07/2020 0952 50060 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 2540G- 98 % 1 Ammonia - N (gas diffusion) 350.1 2600 1100 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 19 4.2 mg/kg 2 Phosphorus 7723-14-0 365.1 4000 530 mg/kg 1 Soil pH measured in water @ 21.8 ° C 9045D 4.1 su 1 TKN 351.2 43000 530 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 3665A 8082A 1 04/07/2020 2023 DAL1 04/06/2020 2220 50123 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 350 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 350 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 350 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 350 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 350 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 350 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 350 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 79 41-132 Tetrachloro-m-xylene 85 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 04/07/2020 1119 KSH2 04/07/2020 0517 50143 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.6 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VD03002-001 Description: TYSON/ Wilksboro Matrix: Solid Date Sampled:04/02/2020 1430 % Solids: 4.73 04/03/2020 2139 Date Received:04/03/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 04/09/2020 1657 KSH2 04/08/2020 1523 50361 Parameter CAS Analytical Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D ND 140 mg/kg 1 Arsenic 7440-38-2 6010D ND 5.1 mg/kg 1 Cadmium 7440-43-9 6010D ND 1.7 mg/kg 1 Calcium 7440-70-2 6010D ND 1700 mg/kg 1 Copper 7440-50-8 6010D 16 3.4 mg/kg 1 Lead 7439-92-1 6010D ND 3.4 mg/kg 1 Magnesium 7439-95-4 6010D ND 1700 mg/kg 1 Molybdenum 7439-98-7 6010D ND 14 mg/kg 1 Nickel 7440-02-0 6010D ND 14 mg/kg 1 Potassium 7440-09-7 6010D 4800 1700 mg/kg 1 Selenium 7782-49-2 6010D ND 6.9 mg/kg 1 Sodium 7440-23-5 6010D 2500 1700 mg/kg 1 Zinc 7440-66-6 6010D 89 17 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 9 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 9 PACE ANALYTICAL SERVICES, LLC Shealy Fl rvil urll l3t�"'.;71 Sexes, Ina 111 F1I1 G�lI �il] IFl I� Ch.gM of Cusfod`r Reccrd Mi l Cokffn� a skull cxwkw qEj-ra NUM VD 03002 Teen No. rexMt. (110) -91't ]hldGl nslr. T-0 M—wr R!DWI i3 Corms Al 'n�p,r�c: 'A. Cot }95 S.mlor3�81S'uu� •• t" ••••, �+h.4 j}lW3[.1llnap ••. "tUfac.�r+�..TMt.tan mrrekm paH _ o i ur ;laEd p �vrlli72 {n raga x +aWiK.rm rJG:Rjrjppw N rbrrd: J;"341Ui1h* Lmoakrr Wri,.t" ?Igad aurJSol Pfilad fl Vc cFCoatalmrstrJ Prr.nlvx4rp at'd WnlrX �:9' nt Caw tir,�teeur. I. ; P)P0 Li18 klru 1 ° T 57Y1 � SFIJ Wpm I rlY lia W f r rt. Y.y r.6+, arciAxa..vd .Fbr..I FfflwA;i tbk. it}. y + x ..._ -4 c x x x x x C i x I X T C x x x c1XIXI I I Ix — c x x x M:rsr ClLV RNa'+�IJ.N Ii+q.t •f u�iW h�.aaLLit MT; 7k',rw,rl a .r pl1/.rlm77r. �'J 81r YAxh - 'JIi •lRRIOIj` i„xil R m Tbay+t.Y } �n1i,. h {I'4 n CAV+•rl lre Lw x sa t.—M, 4n Wl U-G"Yol. Ik Lr r I.R.s+r! k +4 4+.I.iJ In C2 �I.Y 2. Ih—i WL r — ]Fel:by 1!3k Ir 3.Ro6.NoetY a Ira I 4.UE—oLY!: Vw unUST01i' 1 y'y G.r rm r-� Nmr'Ail sr}YidYn}lgrluiF4'rl:Lru framn3.rN uJ=alhu am peyi enim Yre metlt_ r-0.'%*—hr1'C- �' N Ia r1 F*xJt1i. .r}. •c C4 iwrxrir:to_M1liJ:MJW 3 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 9 PACE ANALYTICAL SERVICES, LLC Sl!aely r•.nviranmcu101 `ServirCS, Tnc NEC I Dr I r+�srmau PJ,�nbc,1�1D44: BGI 4 rim Daec: #�1� 16 Sample Receipt heck list ( IRC) CJ [e nt; "Terra Renewal Ca aler ] nspccted +date; LKIA i 04.103120'0 Lot rJ; V Tap 3'S0Z .[ i;ans of`rzccipt; -- 2 SES] ❑ Client 0 UPS ❑ FedEx Gthcr. [� Y cs 1�lo _ I _ Y re custod call prawnt bn Nio uwlt<o Yes o NA 2. Ifcust�od seals were Pllts�—t v��� they Irr=t aitid a:tlirvkon'd p1-1 Stri :O, NA _ Chln_ rrra Strip ID: NA Testdi by_ NA Qri [na[7elnporature uppfirzaci[rlT7r,ived Ccrrrrtcd) tempidl'2,txlreuporo roceiYt %So[id SuLpr-C UP ID' 1�-2043 $,5 {8,3 OC i1A jNA 8C TJA N �4 NA 'NA-°L uihod: ❑Tetnperat-jr Blank mA airyst]3cd1ez; TT{ Gun 1D: 5 C orrccciao aC Method IafeaaJant; _IRt;un El T. V ioe packs ❑ � Ice [� IVorl:e LiLL—A , s ❑ No [INA 3, Iftcmp�rttttro afalty Lmoler exceeded 6_00r, LA -as Project Manager?Jotificd? Pia was NCrtifitxi by: phone email f` ae 0a taee CC! rcle L3rIG ® Yes ❑ No DNA #_ 15 tho colntrlarc:ia; coarim� :lip Httackd Lcr this form? Yes ❑ tNo 5. Wrrc ,r,T reustodv ooedute; [rclinquisl�edlr e[red3 Jtolfnvw d7 0 Yrss U Thu, 6, Wcsn sample TT)$ listfd on Ow Crc7 yes Q No 7_ W sartsp[t. IDs listed an a] [ salnp]c cDrrt;rj nom? ® Yes I7 N4} 3_ Wau ca][ec W, date & lime :istcd on the COC? ❑ Yes ® N 4. Vas coil4r tion dare 8c time fisted on all sample caru&[ners7 Yes Lj No 1 -did a1[ cwptailher [alsel iafnrindLiur. (ILA, datr, 11Fne)agr•ee with t:se CCC2 Yes ❑ l+lp 1 l . Wdre Luts in he porfarmed lisicd on rltc COS"? 1 Yes [] No J 2, Did all sMmp:es $rrivc in'Jie proper crnoiiinns #`or okulE tq'st andler [u goon wndition (wiboken, lid<a ar., 6CI 1(cs LJ No 1 1.3_ Wtu Oidequite sampltr voJtttne avaiWD[c7 14. Wmv �lrrtpjos tee[vt`cl w[tl)jt1 th❑ hnldingtilneo: +[$ ]tiours, wluc�tiew, comes fist? 15, �4em M sa�-tplas Containers m156in�Jex ur•ss (circle -one) satr,�lcs N of Letcd on CDC? ,Id, Fo: VOA stud RSK-175 M111311:3, viem -.ibblcs pre�cnt>1`pe3_.slxc'° (1"nr Gram in dittriaar) ui any cC`ha 4'QA via]s? ] 7_ Wwc all 1)RiC netcl5kil1rient 9aru1j]Cs i'&L!t:iv d at a pH of-:: 27 19. Were a[! 4yttnidc Ramples reoelvcd at a pH > 12 and sr:lfido ,�mpics t`e::civcxl at a pH > 9? 19: WereI[ appliu3alr. 1H;11{T;loyaludc+honol.+65 ( ,7rt,L)satnJ)[as frem Ff rtsidultl Yes, Y ❑ No No 7] YO E7 Na 0 NA I•] yes -4 NA 66 NA 0 Ye5 ❑ Yr ❑ l+lo ❑7tio� ®iA �Y:L3!3 V" ❑ No �pj. 20.Wulm client rainark Virqucsts.(Le. re�ques�cd diluldon& �d&M9D d-csi lions,etcorn-LGIly 1raiLwrjbt:d from the COC jrtF the aammm secli in N LIMS? wo 21, Ylas t1le note n� nbcr lie d on the oortut[ncr lobe[? if uey, Quote# NA ample Preservation (MLisr I)vtDmplered for ally sample{s} Endarnve'ly prcsc!ved or u•;t6 ]; ada,:ape.) an_pJe(s) NA ,ve r cejved i.rlaoMetly preservL� and wemsid[uso&1 acmrding]y t satnp:e remeiviitgv4ilh NA.—mL ofoirc]e one. 1-12S0$_ HNo3,-HU1, NMOH LISiTrsg Sly9 N21 'ime ofpreservaitron NA �. II" mitre than carte prese native is needed, pImse note ij -.-- the bcio.t-, ample(s) NA -Ore retie€vcd w[ih bubb.es �6 mni iv diameter. 8anftlss(3 MA. � _ VfetC receil'ed witls'TRC � 0_5 rn�;Jl, �If 1+19 is,Prr }and weft Ilusiodacccw�:inlyin somPle rerHvingwjffi sodium thi:osaMix (Na2` O;) wily Shealy ]] D. NA lx<rrude lahalL; a-pplied by, L,K.H ca nmorits; I-F,IW. 0410312M Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 9 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:VE20027 Date Completed:06/05/2020 06/10/2020 2:24 PM Approved and released by: Lab Director - Greenville: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs'in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 26 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: VE20027 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. pH Sample VE20027-001 had a pH that excedes the constraints of the pH daily calibration. When a pH buffer of 1.00 SU was run along side the batch, the buffer failed to recover within acceptance criteria. Metals by ICP Due to the matrix, the initial sample amount used for the following samples deviated from the standard procedure: VE20027-001, VE20027-002, VE20027-003. Due to low % solids the initial amount of these samples was 3 times the standard proceduret. The LOQ has been adjusted accordingly. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 26 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: VE20027 Sample Number Sample ID Matrix Date Sampled Date Received 001 Tyson-Willksboro Solid 05/19/20201330 05/20/2020 002 Tyson -Harmony Solid 05/19/20201400 05/20/2020 003 Advanced Foods -Claremont Solid 05/19/2020 1430 05/20/2020 (3 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 26 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: VE20027 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Tyson-Willksboro Solid % Volatile Solids SM 2540G- 98 B % 5 001 Tyson-Willksboro Solid Ammonia - N (gas 350.1 3500 mg/kg 5 001 Tyson-Willksboro Solid Nitrate -Nitrite - N (soluble) 353.2 31 mg/kg 5 001 Tyson-Willksboro Solid Phosphorus 365.1 6200 mg/kg 5 001 Tyson-Willksboro Solid TKN 351.2 71000 mg/kg 5 001 Tyson-Willksboro Solid Aluminum 6010D 370 mg/kg 6 001 Tyson-Willksboro Solid Copper 6010D 97 mg/kg 6 001 Tyson-Willksboro Solid Iron 6010D 2800 mg/kg 6 001 Tyson-Willksboro Solid Manganese 6010D 40 mg/kg 6 001 Tyson-Willksboro Solid Sodium 6010D 3300 mg/kg 6 001 Tyson-Willksboro Solid Zinc 6010D 2600 mg/kg 6 002 Tyson -Harmony Solid % Volatile Solids SM 2540G- 88 B % 7 002 Tyson -Harmony Solid Ammonia - N (gas 350.1 36000 mg/kg 7 002 Tyson -Harmony Solid Nitrate -Nitrite - N (soluble) 353.2 43 mg/kg 7 002 Tyson -Harmony Solid Phosphorus 365.1 22000 mg/kg 7 002 Tyson -Harmony Solid TKN 351.2 54000 mg/kg 7 002 Tyson -Harmony Solid Aluminum 6010D 25000 mg/kg 8 002 Tyson -Harmony Solid Calcium 6010D 76000 mg/kg 8 002 Tyson -Harmony Solid Copper 6010D 22 mg/kg 8 002 Tyson -Harmony Solid Iron 6010D 1600 mg/kg 8 002 Tyson -Harmony Solid Manganese 6010D 59 mg/kg 8 002 Tyson -Harmony Solid Potassium 6010D 7700 mg/kg 8 002 Tyson -Harmony Solid Sodium 6010D 11000 mg/kg 8 002 Tyson -Harmony Solid Zinc 6010D 170 mg/kg 8 003 Advanced Foods -Claremont Solid % Volatile Solids SM 2540G- 94 B % 9 003 Advanced Foods -Claremont Solid Ammonia - N (gas 350.1 220 mg/kg 9 003 Advanced Foods -Claremont Solid Nitrate -Nitrite - N (soluble) 353.2 16 mg/kg 9 003 Advanced Foods -Claremont Solid Phosphorus 365.1 1900 mg/kg 9 003 Advanced Foods -Claremont Solid TKN 351.2 1500 mg/kg 9 003 Advanced Foods -Claremont Solid Aluminum 6010D 940 mg/kg 10 003 Advanced Foods -Claremont Solid Copper 6010D 31 mg/kg 10 003 Advanced Foods -Claremont Solid Iron 6010D 330 mg/kg 10 003 Advanced Foods -Claremont Solid Manganese 6010D 12 mg/kg 10 003 Advanced Foods -Claremont Solid Potassium 6010D 2000 mg/kg 10 003 Advanced Foods -Claremont Solid Sodium 6010D 8200 mg/kg 10 003 Advanced Foods -Claremont Solid Zinc 6010D 37 mg/kg 10 (36 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 26 Client: Terra Renewal Services, Inc. Laboratory ID:VE20027-001 Description: Tyson -Will ksboro, Matrix: Solid Date Sampled:05/19/2020 1330 % Solids: 3.13 05/21/2020 0052 Date Received: 05/20/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 05/21/2020 0012 MOM 54580 2 350.1 (Ammonia - N ) 350.1 5 05/21/2020 1117 DMA 54698 1 (Nitrate-Nitr) 353.2 1 05/29/2020 1319 AMR 55413 1 (Phosphorus) 365.1 5 05/26/2020 1230 DMA 05/26/2020 0842 54971 1 (Soil pH meas) 9045D 1 05/20/2020 2004 SRB 54570 1 351.4 (TKN) 351.2 1 05/21/2020 1049 DMA 05/20/2020 2034 54567 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 2540G- 98 B % 1 Ammonia - N (gas diffusion) 350.1 3500 1600 mg/kg 2 Nitrate -Nitrite - N (soluble) 353.2 31 6.4 mg/kg 1 Phosphorus 7723-14-0 365.1 6200 800 mg/kg 1 Soil pH measured in water @ 18.8 ° C 9045D 3.7 su 1 TKN 351.2 71000 800 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 1 05/29/2020 1211 NCM 05/28/2020 1215 55199 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 530 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 530 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 530 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 530 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 530 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 530 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 530 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 60 41-132 Tetrachloro-m-xylene 73 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 05/22/2020 0926 KSH2 05/22/2020 0534 54597 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 2.4 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 26 Client: Terra Renewal Services, Inc. Laboratory ID:VE20027-001 Description: Tyson -Will ksboro, Matrix: Solid Date Sampled:05/19/2020 1330 % Solids: 3.13 05/21/2020 0052 Date Received:05/20/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 05/27/2020 1317 LLL 05/21/2020 2359 54722 2 3050B 6010D 1 06/05/2020 1306 LLL 05/21/2020 2359 54722 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 370 210 mg/kg 1 Arsenic 7440-38-2 6010D ND 7.7 mg/kg 1 Boron 7440-42-8 6010D ND 26 mg/kg 2 Cadmium 7440-43-9 6010D ND 2.6 mg/kg 1 Calcium 7440-70-2 6010D ND 2600 mg/kg 1 Copper 7440-50-8 6010D 97 5.1 mg/kg 1 Iron 7439-89-6 6010D 2800 51 mg/kg 1 Lead 7439-92-1 6010D ND 5.1 mg/kg 1 Magnesium 7439-95-4 6010D ND 2600 mg/kg 1 Manganese 7439-96-5 6010D 40 7.7 mg/kg 1 Molybdenum 7439-98-7 6010D ND 21 mg/kg 1 Nickel 7440-02-0 6010D ND 21 mg/kg 1 Potassium 7440-09-7 6010D ND 2600 mg/kg 1 Selenium 7782-49-2 6010D ND 10 mg/kg 1 Sodium 7440-23-5 6010D 3300 2600 mg/kg 1 Zinc 7440-66-6 6010D 2600 26 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 26 Client: Terra Renewal Services, Inc. Laboratory ID:VE20027-002 Description: Tyson -Harmony Matrix: Solid Date Sampled:05/19/2020 1400 % Solids: 2.53 05/21/2020 0052 Date Received: 05/20/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 05/21/2020 0012 MOM 54580 2 350.1 (Ammonia - N ) 350.1 25 05/21/2020 1119 DMA 54698 1 (Nitrate-Nitr) 353.2 1 05/29/2020 1320 AMR 55413 1 (Phosphorus) 365.1 25 05/26/2020 1310 DMA 05/26/2020 0842 54971 1 (Soil pH meas) 9045D 1 05/20/2020 2006 SRB 54570 1 351.4 (TKN) 351.2 1 05/21/2020 1049 DMA 05/20/2020 2034 54567 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 2540G- 88 B % 1 Ammonia - N (gas diffusion) 350.1 36000 9900 mg/kg 2 Nitrate -Nitrite - N (soluble) 353.2 43 7.9 mg/kg 1 Phosphorus 7723-14-0 365.1 22000 4900 mg/kg 1 Soil pH measured in water @ 18.7 ° C 9045D 6.3 su 1 TKN 351.2 54000 990 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 1 05/29/2020 1224 NCM 05/28/2020 1215 55199 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 670 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 670 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 670 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 670 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 670 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 670 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 670 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 63 41-132 Tetrachloro-m-xylene 77 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 05/22/2020 0933 KSH2 05/22/2020 0534 54597 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 2.9 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 26 Client: Terra Renewal Services, Inc. Laboratory ID:VE20027-002 Description: Tyson -Harmony Matrix: Solid Date Sampled:05/19/2020 1400 % Solids: 2.53 05/21/2020 0052 Date Received:05/20/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 05/27/2020 1322 LLL 05/21/2020 2359 54722 2 3050B 6010D 1 06/05/2020 1322 LLL 05/21/2020 2359 54722 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 25000 260 mg/kg 1 Arsenic 7440-38-2 6010D ND 9.6 mg/kg 1 Boron 7440-42-8 6010D ND 32 mg/kg 2 Cadmium 7440-43-9 6010D ND 3.2 mg/kg 1 Calcium 7440-70-2 6010D 76000 3200 mg/kg 1 Copper 7440-50-8 6010D 22 6.4 mg/kg 1 Iron 7439-89-6 6010D 1600 64 mg/kg 1 Lead 7439-92-1 6010D ND 6.4 mg/kg 1 Magnesium 7439-95-4 6010D ND 3200 mg/kg 1 Manganese 7439-96-5 6010D 59 9.6 mg/kg 1 Molybdenum 7439-98-7 6010D ND 26 mg/kg 1 Nickel 7440-02-0 6010D ND 26 mg/kg 1 Potassium 7440-09-7 6010D 7700 3200 mg/kg 1 Selenium 7782-49-2 6010D ND 13 mg/kg 1 Sodium 7440-23-5 6010D 11000 3200 mg/kg 1 Zinc 7440-66-6 6010D 170 32 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 26 Client: Terra Renewal Services, Inc. Laboratory ID:VE20027-003 Description: Advanced Foods -Claremont Matrix: Solid Date Sampled:05/19/2020 1430 % Solids: 6.55 05/21/2020 0052 Date Received: 05/20/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 05/21/2020 0012 MOM 54580 2 350.1 (Ammonia - N ) 350.1 1 05/21/2020 1121 DMA 54698 1 (Nitrate-Nitr) 353.2 1 05/29/2020 1322 AMR 55413 1 (Phosphorus) 365.1 5 05/26/2020 1230 DMA 05/26/2020 0842 54971 1 (Soil pH meas) 9045D 1 05/20/2020 2007 SRB 54570 1 351.4 (TKN) 351.2 1 05/21/2020 1049 DMA 05/20/2020 2034 54567 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 2540G- 94 B % 1 Ammonia - N (gas diffusion) 350.1 220 150 mg/kg 2 Nitrate -Nitrite - N (soluble) 353.2 16 3.1 mg/kg 1 Phosphorus 7723-14-0 365.1 1900 380 mg/kg 1 Soil pH measured in water @ 18.8 ° C 9045D 5.1 su 1 TKN 351.2 1500 380 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 1 05/29/2020 1237 NCM 05/28/2020 1215 55199 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 250 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 250 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 250 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 250 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 250 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 250 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 250 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 64 41-132 Tetrachloro-m-xylene 81 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 05/22/2020 0935 KSH2 05/22/2020 0534 54597 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.1 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 26 Client: Terra Renewal Services, Inc. Laboratory ID:VE20027-003 Description: Advanced Foods -Claremont Matrix: Solid Date Sampled:05/19/2020 1430 % Solids: 6.55 05/21/2020 0052 Date Received:05/20/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 05/27/2020 1328 LLL 05/21/2020 2359 54722 2 3050B 6010D 1 06/05/2020 1328 LLL 05/21/2020 2359 54722 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 940 97 mg/kg 1 Arsenic 7440-38-2 6010D ND 3.6 mg/kg 1 Boron 7440-42-8 6010D ND 12 mg/kg 2 Cadmium 7440-43-9 6010D ND 1.2 mg/kg 1 Calcium 7440-70-2 6010D ND 1200 mg/kg 1 Copper 7440-50-8 6010D 31 2.4 mg/kg 1 Iron 7439-89-6 6010D 330 24 mg/kg 1 Lead 7439-92-1 6010D ND 2.4 mg/kg 1 Magnesium 7439-95-4 6010D ND 1200 mg/kg 1 Manganese 7439-96-5 6010D 12 3.6 mg/kg 1 Molybdenum 7439-98-7 6010D ND 9.7 mg/kg 1 Nickel 7440-02-0 6010D ND 9.7 mg/kg 1 Potassium 7440-09-7 6010D 2000 1200 mg/kg 1 Selenium 7782-49-2 6010D ND 4.8 mg/kg 1 Sodium 7440-23-5 6010D 8200 1200 mg/kg 1 Zinc 7440-66-6 6010D 37 12 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 26 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 26 PACE ANALYTICAL SERVICES, LLC ekL "gin Of C%r yRCCOrj iinr TSd.& ", Xj 9 141y Enwanmentg1$ONFdaG, [.-r_ 130 L49ra8M PF&A E-jdUq ti5ko+l Oakrn6lo, 4-914; rWiCS29172 T3rpHca•No,(967d7UIZMC .71K H,400M f$'+91y7 r..n�esllri�lrt m alwrarsvc I ;dy svm zu,- M YrrgK4 AR 7-m 7c _::�l -... '.p. \Ytr.r Nn AszhllS 1M wY[IIl .anl�ll rri1N11F '+uJoY Yuba PAW r ar 6n I:N 4hrbv C.6,io r n [C J MR119 8aN $r .No SiirF1+16, diFrdro--. Dw[ Ilm TIJ ' �'t, c x x 0 x x } x r+yH1��Y r�IlYcrl4ynHn+.'a13.i w�.iYtlTATi :4a:1(O Cisxrnl va, lya rn4 g-k.K rir, wlt*. v4.:r pwmlyyly ri Nrn X2dIIe< YWLkaq_ P,CiHiEn_a� rkk .a ;IN fQli W fur iourwcrko ftm Fp%L07AtyeMflMs ale I[7ddo. =G+ no- SmnoarY �crr �+r amwr pM 4S! Number -1!011111l1l1 l VE20027 I0 p I-� ILrrr y nay C [uslrwrk�nr-.r NE99�1%1C}i Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 26 PACE ANALYTICAL SERVICES, LLC North Carolina Permit Parameters 2, Rorjduala shall 1r, xaalrmd to & E nstrate they set ro- an;ucx C' mscrvatien aid R.ecnvay Art (RCRA� TLe anal yes >rquc�.oy speaiuca in itffi hi1Xe11# A, and tt<C Yetmlttoc -Sbaf m$ Ll'i' � ths� rMults far A miui;mum Of fiuc Mr-E. Any CyOepuons from fae zCgl frdmtnts in `his.couditoa shall br, sp=if:.ed» Atmchmi2v A. T 10e ra +Sis shall include ilm ftuawing Pannieters {tac ropbtory icvcl in milLitrams pee ]fir is in POy=tlzGsrs); I An .analysis sL &E lx: conr4tcred a-, �r-Slduals fivrrl Md sa-1111100 generating fa=li#y at fbe fi,cquerkcy spemfied in AUxLmmt A, and the PmDjttee shall Mitmtain ttm rasuts for a MHUMUM Of five yeale. Ule analysis shall iricludc the following pan=ters: Alt,iu:m A Ira ulikLilH-;�it�-o�eu ArmniL CAM= calcium Lead magaasilru .. 144ci>;ury TvIalybdeium kkd Nit ate-Nkr'to N-ttrogcn �1�roent 'fatal Solids 1potassium klenuum TKN pH zinc Pha3pharus Volatile Solids PCP's TERRA RENEWAL SERVICES 479--747-8192 A#tachmerrtoo C fa€,,._,5oumes: L+'rtar' � .. Data: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 26 PACE ANALYTICAL SERVICES, LLC Slitaty Mvimnmcnrpl SBrtti�, 1n Rxunr.nLNL.,1Eu::Mr.,,uixir:< N." r�El ' ixl+�e�atr 8�b'�D18 Sample Receipt Cheddist (SRC:) C.3cnt; TERRA ]] L? L4i+AL Cooler Ins ccted by:+daka: r._rc } 50.20IZ0N Lok #; VT'20427 �c�uts o F rruci�t: L-'j ST SZ ❑ CI ie,7t UPS 1.-I FedEx F1 Other., L j YJ Noj : , �Ycic custody is Present cot Ihv cooler! - M V es Rio ;,IA �, 1f cu.594d seals werr went. Horn the • intact urn d ii n brokEn? 717 SWi ID: Two r F -.. - Chlorine St1'fp li]: NA _ Te~;texl b}-. NA DrigJnal temperatuMe ;apon reoeipl / Uctired (Oa=roG d) tarupmAure upon receipt ly Sal[d Snax-Cup M, �?(1d 5A )5.1 °C NA ''NA °C: _NA iNA 'C', NA INTA o� - 41c%ad: E]TemrxTature Mil k m.Agairtct Sotrles JR Oun 1D- tR Gun { orNction rEwitor; U ac vlcthod ormmliw. 0 Wet lee U lcc Packs ❑ D Ice ❑ None 31 if tC t f s Yms ❑two ®r A mpera W.; o any COoler exceedad 6,Q up was Prerdaot lwiana_fjer Ngttficd'� PM was Nolihud by_ phone 1 email I fee -to -face (ci rc]e one)- YeS ❑ PIo �] TwA Is die commercial o�wriers packiu Sl [p attaelfe ] Itr this farm? yes ❑ No ,5. Wets proper custody �rocedu:� (relinquishte�imrPived) f0j[aurodF J Yes No 6. Wcrc sarrpie 1D: Cslve tin the MC'? Y ; ❑ NoT. 7, Were xrnpie 10s [:steel On all sampictamtainers? ® Yes El No 9. Was collectiou date & Gmu lisred an tLye coc? ❑ YN No 9, Was Collection date & k me liared m all sarm le 00"inUS? ® Yes ❑ t ;a 10_ J�id al] COdtainor label infbnuat[ou (ID, gate_ Lyme) H m-e with �c CDC? ZJ Yes ❑ 1 0 1 [. c:� testy 1 o be perPor113a:s1 iisred on the COC7 ® Yes ]❑7 —7:S Y� . Yes ❑ Yes ❑ Yea D] Y ❑ yer, ❑ ❑ Yes I ❑ col 112. Dig[ all samples timve it' tke proper coulAincrs Liar each rest aadeur in good condition (un'aroken, lids on, e[�)? -- NQ 13, [k'M ado�jllatestl:n-0f-C Yu[ume; ivailaUie? TTq 14, lk'exe r[I samples rareiYad►+'iiltin !� he hlpldmgtimeOr4$ flours, whi(ZWY r cwncs rFrst? No 15. Were arl • samples containers mWin 'Nice cir,_e delta ssrnples NiA Iistnd on COC� to "MA '`'- ForVOA Lod > SKA 75 samples_ vem hul�b[es pre�ert '•�e _s;z ° C/4„or 6rr.%m in dialnet�,'- m any of the VOA v[als? i lea NA17,VvereallMahnetu-w'runientSarnplasMojvcdata PITvf¢2? 1tia NA ] 6. u ere ttr: c}�anifk samples rmcived at a H > 12 and sulfide sack lei roceiued at a pH > 97 � 14 ' ere all tlpp ie Ie I XN{oyttnidc,phtierse1162 Cl.-5rn l.`'j sample a at-residnal F 20. Were clierd m-narkq!mgaests (i.e requw Mel dtltition�, MSeUgT) dwaignariwla, etc enrrestriy t1�inLT'hMe frLITI It, COC intq fir, uanunetkt sectior. sn h.l1'ES? 21. Wg the quote RW11l_?Cr =isned on tha rorrainer laFX- If was- f]unre 11 1NA triple Preservation {Must bC [Cdrtplelrci far: any 82mple(S� irlCoiTeCtly pr�M'7vcd nr Y`'M Lieadsp u,) n, 1npte(s) NA were neceivW ineozealy preserveil Hn4d were lqustcd anconJingly sainp:e rarlvi"Z with R-A MJ- of cimin one: H2SO4, H 03, I lie, NaC11 cry ing SX 9 NA TLC of crvatiau NA�. lfmore iharr cute preserYtttivc :s needed, lrleesc nape in the comrnelits bc]our, NA - were r-Ccoived IvIth budhies >6 mm in diauwtar. nple:(s) 1tiA _ tivere mcaivOd with TRC > 0.5 mVL (if #19 ;6 riu ) and weiv 1J-9Ced acoerdingly in sa-,npk receiving. with sodium thiosiulfab-, (Na2S20a) with Shealy ID. NA baTWL Jabal - Fpplied by; ME-r. Ccmmaym. Dare; WZ0220 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 26 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:V109002 Date Completed:09/17/2020 09/21/2020 2:28 PM Approved and released by: Project Manager II: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs-in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 9 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: V109002 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids, sample -001 was weighed out at 3 times the normal amount. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 9 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: V109002 Sample Number Sample ID Matrix Date Sampled Date Received 001 Tyson/ Hammond Solid 09/08/2020 1430 09/09/2020 (1 sample) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 9 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: V109002 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Tyson/ Hammond Solid % Volatile Solids SM 2540G- 91 % 5 001 Tyson/ Hammond Solid Ammonia - N (gas 350.1 21000 mg/kg 5 001 Tyson/ Hammond Solid Nitrate -Nitrite - N (soluble) 353.2 90 mg/kg 5 001 Tyson/ Hammond Solid Phosphorus 365.1 4700 mg/kg 5 001 Tyson/ Hammond Solid TKN 351.2 32000 mg/kg 5 001 Tyson/ Hammond Solid Aluminum 6010D 15000 mg/kg 6 001 Tyson/ Hammond Solid Calcium 6010D 19000 mg/kg 6 001 Tyson/ Hammond Solid Copper 6010D 10 mg/kg 6 001 Tyson/ Hammond Solid Lead 6010D 5.9 mg/kg 6 001 Tyson/ Hammond Solid Potassium 6010D 2200 mg/kg 6 001 Tyson/ Hammond Solid Sodium 6010D 2600 mg/kg 6 001 Tyson/ Hammond Solid Zinc 6010D 57 mg/kg 6 (12 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VI09002-001 Description: Tyson/ Hammond Matrix: Solid Date Sampled:09/08/2020 1430 % Solids: 4.48 09/10/2020 0214 Date Received:09/09/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 09/13/2020 2016 MOM 66521 1 350.1 (Ammonia - N ) 350.1 25 09/15/2020 1534 KMC 66593 1 (Nitrate-Nitr) 353.2 1 09/10/2020 1457 AMR 66347 1 (Phosphorus) 365.1 5 09/10/2020 1555 DMA 09/10/2020 1043 66200 1 (Soil pH meas) 9045D 1 09/14/2020 1240 AAB 66608 1 351.4 (TKN) 351.2 1 09/10/2020 1820 DMA 09/10/2020 1126 66184 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 254OG-1997 91 % 1 Ammonia - N (gas diffusion) 350.1 21000 5600 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 90 4.5 mg/kg 1 Phosphorus 7723-14-0 365.1 4700 560 mg/kg 1 Soil pH measured in water @ 20.6 ° C 9045D 5.9 su 1 TKN 351.2 32000 560 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 1 09/10/2020 1756 NCM 09/09/2020 1604 66092 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 370 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 370 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 370 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 370 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 370 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 370 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 370 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 76 41-132 Tetrachloro-m-xylene 80 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 09/11/2020 1617 JAB2 09/11/2020 1052 66330 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VI09002-001 Description: Tyson/ Hammond Matrix: Solid Date Sampled:09/08/2020 1430 % Solids: 4.48 09/10/2020 0214 Date Received:09/09/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 09/10/2020 2203 KSH2 09/09/2020 1520 66081 Parameter CAS Analytical Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 15000 150 mg/kg 1 Arsenic 7440-38-2 6010D ND 5.5 mg/kg 1 Cadmium 7440-43-9 6010D ND 1.8 mg/kg 1 Calcium 7440-70-2 6010D 19000 1800 mg/kg 1 Copper 7440-50-8 6010D 10 3.7 mg/kg 1 Lead 7439-92-1 6010D 5.9 3.7 mg/kg 1 Magnesium 7439-95-4 6010D ND 1800 mg/kg 1 Molybdenum 7439-98-7 6010D ND 15 mg/kg 1 Nickel 7440-02-0 6010D ND 15 mg/kg 1 Potassium 7440-09-7 6010D 2200 1800 mg/kg 1 Selenium 7782-49-2 6010D ND 7.4 mg/kg 1 Sodium 7440-23-5 6010D 2600 1800 mg/kg 1 Zinc 7440-66-6 6010D 57 18 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 9 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 9 PACE ANALYTICAL SERVICES. LLC M Al C n e 3 4` di ri ! � � I I I - 3 E Y to rA w b; 5: LT 3 , T, I �LL p 3 dP i LLI 4 S G C]' -• 3 r7G� di x lt� € ! % x x x FT r 47 r. � n 2 iC ❑ Ul a 4 E 02 fe co a 4 V as "SG E =� pID a� Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 9 H T PACE ANALYTICAL SERVICES, LLC Shta yavirmocula. ScMcec, line. L J3uc�cDI lvmtu; ND9018C-t�l tMY#hts daW: X1�,�LU;R Sample Receipt Ilteck 6;t (SRC) C l ier t. T -KRA Cooler ]n., e:ted byrdate: BIAG ,-09AW2020 LoL !I. V i09A 02 IieHns n#reset t ❑ $ [l ©CTieu' 0 :Jpi ❑ FedEx U Onccr, LI YLls ND 1. Were cusoody seals p_ese=i4QiJ Ulu coolpr? -- YesFIN-al NA4 2_ If c1.33110J sruls w-vro aresJeiit, Iverethey irract ud unbmken7 pH Strip iD: NA Chlorine Strip n NA TeswJ by: NA -igint]ts:mpvraturouuOn-�UiptllteriJv-d(CfffeL, )tumperatureuponrccafpc �r6S41idSnap-i),p1D,l_2i�-i438 �.7 f 5-7 ae NA J LTA OC. NA J +III {C' NA INA elkAL ❑'i'emperature €ilnnk R]Aguinst bottics 1R Gun TlD; _5 IR Gust C.[NTddirm Factor 0 Mothod QC zoo:i3rt: 71 Wet ice ❑ Ic0 N010 Notw ❑ []NO ®NA'.[FtnmperaturvQLJ13ycus�lorexcaeded-6.VC,was Pmjct:Ma��ae�r��[iliadF Yes FK4 wuH Hotified by; phDnc ! entail f tao�--tc-fare (circle one)_ ❑Flo F-1M A 4. Ts the oomrl1ercia1 Couricr's packi7usl7.p attacli�,i to alis roan? Q Yeti ❑ NL% 3. Wert mppr -LL9tC3Jy ccdures (Mlinquid►cdfrgcoived) fblkwcO 0 Yes LJ N❑ 6. Were sanslytc IDS l istcd on the CCP — 0 vp�' F1 No 17, ', uc sample lf)t listedoJl a:] aa:tlp[ecnnminexc? 0 yC51 Cl Ni g_ Was co-llectipu dslL' & tilne listed on tte GOC? ❑ Yes mNa '1. Was collection date dt Erna 1i9t- d on211 5zmjpjc coil tbi,jen.? 0 YCi ElN No 10. 0ida]I oaniainorlabie] uifa,_.-i n (ID, date, time)agmowitlithe CC C? 0 yq61 L7 No I -.. Wo-R, tests to bt! performed listed on the COG7 m Ye: LJ No' 12. Did �0 Samples aeriac in the proper cQntaitteta for rich rrsr iutdj4;T in goad 00nditiOn (unb: oken, ]ids (In, titr,)T 'es QNO 13.Was adegiiresamplevol umr-avaUl --I.? - Yes U No I/- Were r<II ;uunplus reee[yod Y itiiin' tlin holding timt: or 49 hours, whichever comas firat'f Ye9 MG 15, Were any sackplcs ci}nta iners m hsin excrws (circ'e ane) stem pies �lol fisted on COC7 ❑ Yvs ❑No 0 NA 16. For VOA sr_d RSK-175 samples. =N bubhles pri ent 6mni in dianidcr) lu stay Dfthe VDA, vials' Yes 1Nt, Nil 17_ Wer'e a]] DKO Imclelslnuttrient sarn cs roceived ail :i pH of c 2? ❑ Yea ❑ NO ® NA 18. Wcro 81 cyanide sgnk Jes i-ectivtA at a T� > 12 an i sulfc& s�;mples recelvcd at a l4 > 9' Yes ❑�la ®7�A 19, VJer d;l spplicabfe T*fH FKWcyanidelphealw 'Es25 (< ,5mg7.) calrp 7 five of residual ❑ Cb lorina7 ❑ Y-as ❑i No O NA 20, tie client tcrnwrks1requt;sl.s (i,fi, requested dilutioruw A7S1 Li des;gne[cuu, vtc:,,,) correctly transcribtd from the OX iuta the cQJnmei:t section irl LIMS? Yes No 21. Was the HUCAC nrtmher Iis7od on the C[In#aincr [ahel? I+' 'es_ Quote 0 NA ample Pmservntion (Miry' becomplvted fay any;iumpi-(s) incpt'1eaN Ilr+ixcrve1l0rwit'a IledSpace-} Samples) Ali LL +ax r: cci� ed incorrectly pa ved snd wore odjustac€ A-ordingly iii €ample receiving with ILIA mL of e[rclo Hite: I12r04, HNO3, HCl, NaOH us,ieg $ K + NA ime of r"EervudDn NA ff mvrc than one pwuy rw3t:ye is neodod, plea.5e a0#e in the commc" below. SantIc(s) NA wcrc Lweived —th bubbleN>6run in din marer- Satnplc (s) NA y _vitroreceATdwith'FRc> 0.5 Jng/L (if419 is pro) and were cl"iislyd accordingly in sample reecivi-19 %with RAium t'k1cKt ilfi,tc (N-axSj.) wtdl Shouly iD_ NA SR "cudc labels applied by, BMG Hzi1c: OL,' tM 7,02G Cotni;lvn ts: l Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 9 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:V109001 Date Completed:09/17/2020 09/21/2020 2:22 PM Approved and released by: Project Manager II: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs-in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 10 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: V109001 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids, sample -001 was weighed out at 3 times the normal amount. The LOQ has been elevated to reflect the dilution. PCBs by GC The following sample was diluted due to the nature of the sample matrix: V109001-001. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 10 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: V109001 Sample Number Sample ID Matrix Date Sampled Date Received 001 Tyson/ Wilkesboro Solid 09/08/2020 1530 09/09/2020 (1 sample) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3of10 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: V109001 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Tyson/ Wilkesboro Solid % Volatile Solids SM 2540G- 97 % 5 001 Tyson/ Wilkesboro Solid Ammonia - N (gas 350.1 1400 mg/kg 5 001 Tyson/ Wilkesboro Solid Nitrate -Nitrite - N (soluble) 353.2 33 mg/kg 5 001 Tyson/ Wilkesboro Solid Phosphorus 365.1 450 mg/kg 5 001 Tyson/ Wilkesboro Solid TKN 351.2 6200 mg/kg 5 001 Tyson/ Wilkesboro Solid Aluminum 6010D 220 mg/kg 6 001 Tyson/ Wilkesboro Solid Copper 6010D 8.2 mg/kg 6 001 Tyson/ Wilkesboro Solid Zinc 6010D 15 mg/kg 6 (8 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 10 Client: Terra Renewal Services, Inc. Laboratory ID:VI09001-001 Description: Tyson/ Wilkesboro Matrix: Solid Date Sampled:09/08/2020 1530 % Solids: 8.42 09/10/2020 0214 Date Received:09/09/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 09/13/2020 2016 MOM 66521 1 350.1 (Ammonia - N ) 350.1 5 09/15/2020 1532 KMC 66593 1 (Nitrate-Nitr) 353.2 1 09/10/2020 1455 AMR 66347 1 (Phosphorus) 365.1 1 09/10/2020 1550 DMA 09/10/2020 1043 66200 1 (Soil pH meas) 9045D 1 09/14/2020 1236 AAB 66608 1 351.4 (TKN) 351.2 1 09/10/2020 1820 DMA 09/10/2020 1126 66184 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 254OG-1997 97 % 1 Ammonia - N (gas diffusion) 350.1 1400 590 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 33 2.4 mg/kg 1 Phosphorus 7723-14-0 365.1 450 59 mg/kg 1 Soil pH measured in water @ 20.5 ° C 9045D 4.8 su 1 TKN 351.2 6200 300 mg/kg 1 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 5 09/11/2020 1036 NCM 09/09/2020 1604 66092 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 1000 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 1000 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 1000 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 1000 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 1000 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 1000 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 1000 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 58 41-132 Tetrachloro-m-xylene 63 35-106 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 09/11/2020 1615 JAB2 09/11/2020 1052 66330 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 0.89 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 10 Client: Terra Renewal Services, Inc. Laboratory ID:VI09001-001 Description: Tyson/ Wilkesboro Matrix: Solid Date Sampled:09/08/2020 1530 % Solids: 8.42 09/10/2020 0214 Date Received:09/09/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 09/10/2020 2157 KSH2 09/09/2020 1520 66081 Parameter CAS Analytical Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 220 75 mg/kg 1 Arsenic 7440-38-2 6010D ND 2.8 mg/kg 1 Cadmium 7440-43-9 6010D ND 0.94 mg/kg 1 Calcium 7440-70-2 6010D ND 940 mg/kg 1 Copper 7440-50-8 6010D 8.2 1.9 mg/kg 1 Lead 7439-92-1 601OD ND 1.9 mg/kg 1 Magnesium 7439-95-4 601OD ND 940 mg/kg 1 Molybdenum 7439-98-7 6010D ND 7.5 mg/kg 1 Nickel 7440-02-0 6010D ND 7.5 mg/kg 1 Potassium 7440-09-7 601OD ND 940 mg/kg 1 Selenium 7782-49-2 601OD ND 3.8 mg/kg 1 Sodium 7440-23-5 6010D ND 940 mg/kg 1 Zinc 7440-66-6 6010D 15 9.4 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 10 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 10 PACE ANALYTICAL SERVICES. LLC # _ZO ri c_ !i r3 N � O C I W f4 `.ti elj cL x X x X X x I x �' t a m I v LL n A H u x j` C SE n !v 4l I 4 -97 s R � i1 J � dry�ry0ryry �_ U3 x }{ }C S 7G }G C 3C ai m a x x x x x }C } co F m C ^ 2 al _ '- n{ -- - ; ] CJ ( U ru U [) u A ❑ Il i a }ep O 4 i m ' I, a E F i' �11ti G ro o u _ [3 15 n" !� G � i LQQ� fS ! cE •� m� z 2 S ¢ = a v ce i j Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 10 *S T PACE ANALYTICAL SERVICES, LLC North Carolina Permit Parametom 2. Residuais shF% kt, analvzod to dunousp.ate they are ' nurcc :n� extr2tirn knd Rccovccy Art (J_l{ U), '11.te SA -CS aha F�rnrod a� Rxl���rxcy sgc;caf�+f in Attarhrnerl A, ail tlrc Pcrmittoo shall maintain these results far a inhAmum of five years. Aqy cmi ptior, fn"rn thu r um-unfs In ibis, cmditi,nn slnll be Specifjed r A'_tzulinn !u A. '1 �naly$iR shed include the ltobwing parauietera (1h regulatory l i+c_ in -nilli ;lms p--F liter is in pa=theses); I An zinaiyds A all be oonduci;>d ur< twiduaLt from each sourc& l -"ad faci ity at the itequenoy specified in Agent A, and flta Pc=ttac steal.1 maintain the tcaults fo.v a min,�nuna oP � yeas. The amiysis s includa thc: followirlg patariwWa; IV Al, min>2m -.Aercu + Ammwr p--Nitmgca Molybdenum N-Uxl �ci�,iuru So kun tr!" Arsenic �U3A r1trate- n6m Mrrogmn LU ]Pmr.=t Toptal Solids Tl CalcEun� pf 'u Lead Phosphorm Volatile -solids gaeiwaa Ps's �I TERRA RENEWAL SERVICES 479-747-8182 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 10 PACE ANALYTICAL SERVICES, LLC 3[xi.yi:riroi�uittl^.ul$2:rIt�S,ke. �np ldl _b: urnClu Nmnxr: MUM [ PC-14 Effective rbw RQW 19 Sample }receipt f'.heeklisf (SR ) CGelit: TRRPA Cooler 1rgieuLu.lh4'}Jate:.Br'U- 109r'0.9/2020 LotV. V109001 raru of receipt: ❑ SES: ICE:= 0 UPS 2 FcdEx paler. - Yes ] No - 1 _ Were: vu5WU .v K:913 -CAMt vn tU COole:'q 2. if custody seals were preEenS vfere th and unbroken Y ex Tr o _Z TEA pi [ Strip ID: NA Chigrine Strip II7; NA _ Tr,tmi try; NA 04blal 1191inpea'ffinre r]1i01S o6celpt I Derived ( imrelyd) Lumper3turc 'J3on receipt %Solid Snap -Cup ID- 2G-1+4A 5.7 15.7 -C NA YNA QC NA fNA vL NA ; NA aC Method: O'femperawre Blank Against Bottles IR Gim 1D. _ - 5 IR Gtin Cprrmli0a Factor: b °C; Method of t uulw,t: 0l3,'at Tex ❑ lax i'a cks ❑ Tee ❑ None ❑ Yes ❑ No OTti, 3, If tt~anpBmliim of any coo=el' exceWW 6.0°C, was Project !Manager Na:[fled? PM wa. N-otified by; pfionef einaiI I t4;�-W-Faoc (oir>rlo anc). 4. is Jt<- coo nmurciul oauricr's packinv.1ip attached #,a H,fs fg:m? i, here prroper Cu9tody roeeduras (1'elii3quislse(lrr�_eeived) folJay.,cd? , 'Were sample, Os listed an the COC9 ?. Were t:nmPlC IDS listed an ail Sam [5In contoiuurs? 18. Waq L011t;u tun dtltu & [twit' lisped ii11 the CDC? - -- ® VW ❑ No Ff TEA Yc3 0 No Vez Tea 0 Ye-s I El No 0 Yt�?, L] Nu ❑ 1(os ONO 9, 'Was collcctinn data & time listed pas all - am* cml.a;r_el's'I I0, f) [[[all n4mtainer 1a lacv i�fa~�natiou (ID, �lattr, l imt) agree with the COO; 1-1. Wrr* tcs-:N W b4 performed l isted on the COC? - W] Yes ❑ Ni 0 Yes ❑ Nu! i 1-2. Did €r3 samples arrive. in the proper containers forcach test andlor i3, goad camelhis;n (unb17roo k,cn, I ids -an, etc.)? 11 Was ad*ua[& swjlrll� Vninmr` im3flsble'? 14_ Were all sampl" 'twined within '/� tlV8 :[oldins time 41' N 11911=5, w1iid3UVCr comps first? 15. Vkfere any s`m p6q "intoiners ir_isshi excess {ti'relc Lnc) samples Kkx, IiSM[I On COC } 16. F-ur VOA and MK-I +S garrrlo-lrs, were bubbles present >1'pca-sizv" (Y+"or 6imrl in diamrrtcr) in any of the VOA vi ais? S F 21 ! es ❑ o Yes ❑ No i El Ye: Z NO + ❑ o ®NA ❑ Y� No N-A 17. Wcrc all DMYmeMISMtttrient ;alrjlcs r,.ocived eLt d p[T Of 7 I C. Were all c aiiidn N,,rnplm r(: bred at a r:11 ? 12 _irul 5iilfide saga los r4xcivcd at a pi I > 9? I crc a applicable NT],r fKTw cyai,ide+p ua f625 fk 0_Srrrg�L) samplesteee rrFros[ tsa rdllorine? ❑ Vm ❑ No ® NA G Ycg El Nc NA U Yes I-1 c s11 ©N`4 ® NA Were client remarksh quc5ts (ix. regpesled dilutions, P1MSv'h'1$D dnsignatkkny, etc...) ;G[rectiv transcribed frtmrt the. COG into tltie cc7nmrnc stetion in LIMS? I. Was the gurAe ltiurrlbsr ]is[ i 0:3 the Wiltwin" labc.17 if rs. Quote t7 NA Na -6.'ampleiareservati0n (Must laccamplatedCorany' aripla(s)inoarrect['fir-SCe►edarw:l=y11�xdyixec. Sampk(s) NA _ %Vera re, .—vcd inmnvudy r. m3e rvafl end W6re adjL:,Ied u": .,rdlnLl- in m-n-ple rcmiving wit LNA *-nL of circle alle: 1-12204, HNal, FICA, Naol-I usiisg SIB # '!A - �m of prescrvat[an NA If mom dmtl Oise p -cF&ry-mt ivt; is iweded, pime ttctz in t9lc cammen lFi 6:low. aunpic('�j IrA _. ••_-'xara received u'it{1 bubbl�s>f nrrrr iii eli;,mef�r, anlplegs) NA —. _ wire -eaeived with TRC > 0.5 Tne. (If 919 is i,v) and were adjusted accordin-,�y In samplu r=lvlrkZ wiffi aDdiuni t usu'fate (N;L;S,C]s) wish Shealy ID; NA Slt barcadc labels applied lay: 3MG Dale J9![19i70?.0 Carnni9nm- Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 10 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:V118101 Date Completed:10/02/2020 10/05/2020 4:00 PM Approved and released by: Project Manager II: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs-in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 9 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: V118101 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 9 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: V118101 Sample Number Sample ID Matrix Date Sampled Date Received 001 Perdue/Concord Solid 09/17/20201430 09/18/2020 002 Advanced Foods/Claromont Solid 09/17/2020 1530 09/18/2020 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 9 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: V118101 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Perdue/Concord Solid % Volatile Solids SM 2540G- 87 B % 5 001 Perdue/Concord Solid Ammonia - N (gas 350.1 6700 mg/kg 5 001 Perdue/Concord Solid Nitrate -Nitrite - N (soluble) 353.2 23 mg/kg 5 001 Perdue/Concord Solid Phosphorus 365.1 1200 mg/kg 5 001 Perdue/Concord Solid TKN 351.2 22000 mg/kg 5 001 Perdue/Concord Solid Aluminum 6010D 17000 mg/kg 5 001 Perdue/Concord Solid Copper 6010D 21 mg/kg 5 001 Perdue/Concord Solid Potassium 6010D 4000 mg/kg 5 001 Perdue/Concord Solid Sodium 6010D 6600 mg/kg 5 001 Perdue/Concord Solid Zinc 601OD 51 mg/kg 5 002 Advanced Foods/Claromont Solid % Volatile Solids SM 2540G- 87 B % 6 002 Advanced Foods/Claromont Solid Ammonia - N (gas 350.1 460 mg/kg 6 002 Advanced Foods/Claromont Solid Nitrate -Nitrite - N (soluble) 353.2 58 mg/kg 6 002 Advanced Foods/Claromont Solid Phosphorus 365.1 860 mg/kg 6 002 Advanced Foods/Claromont Solid TKN 351.2 16000 mg/kg 6 002 Advanced Foods/Claromont Solid Aluminum 6010D 17000 mg/kg 6 002 Advanced Foods/Claromont Solid Copper 6010D 1200 mg/kg 6 002 Advanced Foods/Claromont Solid Nickel 6010D 41 mg/kg 6 002 Advanced Foods/Claromont Solid Potassium 6010D 4600 mg/kg 6 002 Advanced Foods/Claromont Solid Sodium 6010D 14000 mg/kg 6 002 Advanced Foods/Claromont Solid Zinc 6010D 190 mg/kg 6 (21 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VI18101-001 Description: Perdue/Concord Matrix: Solid Date Sampled:09/17/2020 1430 % Solids: 5.66 09/18/2020 2321 Date Received:09/18/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 09/22/2020 0012 MOM 67398 1 350.1 (Ammonia - N ) 350.1 10 09/24/2020 1047 DMA 67705 1 (Nitrate-Nitr) 353.2 1 09/25/2020 0921 AMR 67984 1 (Phosphorus) 365.1 2 10/02/2020 1638 DMA 10/01/2020 1025 67605 1 (Soil pH meas) 9045D 1 09/21/2020 1617 AAB 67392 1 351.4 (TKN) 351.2 1 09/30/2020 1506 DMA 09/26/2020 0850 67906 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 254OG-1997 87 B % 1 Ammonia - N (gas diffusion) 350.1 6700 1800 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 23 3.5 mg/kg 1 Phosphorus 7723-14-0 365.1 1200 180 mg/kg 1 Soil pH measured in water @ 19.7 ° C 9045D 5.0 su 1 TKN 351.2 22000 440 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 09/21/2020 1437 JAB2 09/21/2020 1204 67290 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.4 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 09/24/2020 2306 KSH2 09/24/2020 0853 67507 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 17000 110 mg/kg 1 Arsenic 7440-38-2 6010D ND 4.3 mg/kg 1 Cadmium 7440-43-9 601OD ND 1.4 mg/kg 1 Calcium 7440-70-2 601OD ND 1400 mg/kg 1 Copper 7440-50-8 6010D 21 2.9 mg/kg 1 Lead 7439-92-1 6010D ND 2.9 mg/kg 1 Magnesium 7439-95-4 6010D ND 1400 mg/kg 1 Molybdenum 7439-98-7 6010D ND 11 mg/kg 1 Nickel 7440-02-0 6010D ND 11 mg/kg 1 Potassium 7440-09-7 6010D 4000 1400 mg/kg 1 Selenium 7782-49-2 6010D ND 5.7 mg/kg 1 Sodium 7440-23-5 6010D 6600 1400 mg/kg 1 Zinc 7440-66-6 6010D 51 14 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 9 Client: Terra Renewal Services, Inc. Laboratory ID:VI18101-002 Description: Advanced Foods/Claromont Matrix: Solid Date Sampled:09/17/2020 1530 % Solids: 2.30 09/18/2020 2321 Date Received:09/18/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 09/22/2020 0012 MOM 67398 1 350.1 (Ammonia - N ) 350.1 1 09/24/2020 1055 DMA 67705 1 (Nitrate-Nitr) 353.2 1 09/25/2020 0922 AMR 67984 1 (Phosphorus) 365.1 1 10/02/2020 1633 DMA 10/01/2020 1025 67605 1 (Soil pH meas) 9045D 1 09/21/2020 1622 AAB 67392 1 351.4 (TKN) 351.2 1 09/30/2020 1506 DMA 09/26/2020 0850 67906 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 254OG-1997 87 B % 1 Ammonia - N (gas diffusion) 350.1 460 440 mg/kg 1 Nitrate -Nitrite - N (soluble) 353.2 58 8.7 mg/kg 1 Phosphorus 7723-14-0 365.1 860 220 mg/kg 1 Soil pH measured in water @ 19.5 ° C 9045D 4.4 su 1 TKN 351.2 16000 1100 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 09/21/2020 1439 JAB2 09/21/2020 1204 67290 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 3.3 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 09/24/2020 2312 KSH2 09/24/2020 0853 67507 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 17000 280 mg/kg 1 Arsenic 7440-38-2 6010D ND 11 mg/kg 1 Cadmium 7440-43-9 601OD ND 3.5 mg/kg 1 Calcium 7440-70-2 601OD ND 3500 mg/kg 1 Copper 7440-50-8 6010D 1200 7.0 mg/kg 1 Lead 7439-92-1 6010D ND 7.0 mg/kg 1 Magnesium 7439-95-4 6010D ND 3500 mg/kg 1 Molybdenum 7439-98-7 6010D ND 28 mg/kg 1 Nickel 7440-02-0 6010D 41 28 mg/kg 1 Potassium 7440-09-7 6010D 4600 3500 mg/kg 1 Selenium 7782-49-2 6010D ND 14 mg/kg 1 Sodium 7440-23-5 6010D 14000 3500 mg/kg 1 Zinc 7440-66-6 6010D 190 35 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 9 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 9 PACE ANALYTICAL SERVICES. LLC M i u� lu iL � � I I a }� W � q ai 3 x 34 I4 X X e - -- CL �M.Z A f z LL I_ ' Tex 6 zCL I i V -1 of X€ { . It rl F� F g x xC X X X C O z z iOr jr Y ru $ ££ p 4 27 .2 w G Ll . I z c O - j i Q o y� C] i7 ��✓✓ h �, yq t to ., m ,y N •� 2 23 4r - Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 9 c F c a PACE ANALYTICAL SERVICES, LLC Shculg 6lrvircmincntn; Scrvicm, [Tic. IIlagc t of a DgUWA NurnEor, h.bWIOC 14 b lti-G-- 3 [kLr,o M12M9 Sample Receipt Checklist ( R Client; TERRA - RENEWAL Cooler Inspected byidate; ➢MFI 11 9V 8;20 TA1 �[: V 18101 .Mk!P-rs-uFreoeipE; © SES1 ❑ Clicnt 0 LJPS ❑ FodEx U O-Jur; El Yesl 10 No 11 _ W"O Custody seals presarit on the "er? _ 2_ lfiwa�crd ' ue_„!u_v,orcL present, were they intact and unbroken9' Yes Nol 0 NA- pH 5uip 1D: NA Cldorble SEYrp TD; NA _. Tested by: NA igil W tzuLptmLurc upon rcmipl 1 Derived (Corrected) temperature upon receipt ' Solid Snap -Cup ID; 20-14�8 1_6 1 5.6 vC NA, _?-NA DC -HA INA oC Njk !NA oe Mc1Fnd; ❑Ternpe&ilrel3[anko k&i[nst 9nit;es TR Crum 'D: IRCLIP Cori -Ceti on Factor: 0 °c MelhLA of coolant; m wet toe U Ice :'acks 0 Dr-y fee uuu i ❑ Yc5 ❑NO �i ❑l�lAtelnperatur�e of any cisnl, r crrceeded fi.%'f C,' wms Pre j" Twi anapr Noel ed', i PM was Nodfied by: phone J Cans[] ? face ta. face (circle one). 1Z Ycs U No ❑ NA'-2, is t c coinme_ , a1 °oou_'Jer'F pir:.l i ug slip raLWfjhud LO [his fcnTn? TZ Yap, ❑ No °3. Wem pmpef cuskvEy pmoedures (a+el[nquishe &received) followW f Yes ND G_ Wpm sample TDs 1k .Lacl on th❑ COC? ❑ Ycs ❑ No _ 7. Wur sample IDs lisl:M or; 01 %4mpla toFGtHincr�? - Yas © No S. Wes oollcolior. &64; & time iistcd on the ((X.: ( Ytis ❑ i�1D 9. Was oollectior_ damp & tuna listed on al3 sarr lecanta[ner3'? -- ❑ Ycs ❑ No _ 10, Did all containcr iaba infior laOfM (ID, ilaltt:, tiTto).a8TOC 1i'[tJt the CUC.7 ® Ye., ❑ Nv I i . YWc rm tom; is to br Our4'ormod fisted on the Yes ❑ Ne 12_ Did alr samples arrive in fhe proper cautaiaerss R r v>,e1, Ir,.+i andfvr in goad reMijoll (uMbFULCrF, lids an, etc.,1 _... 0 yes ❑ No 113_'A1rnS rujpuuutr- strsnple voJunne availarile? Y'es ❑ No 114. Were. EL11 widen 14 the holding Ikmc ur 4E houim whichever comes fans Yes _ 6 No 15. 1% Orc any camp lrz containers missi n iEUM (ol role one) sam l&fi Nrrt li.,dcd on. COO El Yes ❑ O ❑ NA I4, For VOA zuid RSK-175 suniiplt�;, wi%r. bubbles pr'es!nt>apt�-S:Ze"(114"o; Gmm it diameter) to any of Ilia VOA viels? n Yes L1 No ®NA 17_ Were all DRO!mez1srr.�;Tti'icersarnpleq r&.rcived at a pH aF<_ 2? ❑ Ycs EJ [fin V1 NA 1 .�_ Wem all +:yan de mmples received bt :a J}H > ] 2 and suh-ide Farr les t'CCOi OCd at a pH > 9? ❑ YCS ❑ No ®T+A 19. VV� rc �r11 rapplicable NI ?31TKNIc}^8m]dcjpllenc ( .5raglL) samp]o3 frea of residual cl:lnrin�? ❑ Ycs ❑ No O NA 1von-cWy ' %Ve-e elieut rearrar(i.e. reque d 614Our 'LMSJMSD designabri.s, cic...) lramcFibed frDm r e COG [nf4 Ehe Mmment see -ion in r.IMg? vesl hd Nq 12I. Urag the kW; oainbca' listed on 11P-- e,:unkrincr kibel? If yes, [?tiot>,;i NA Sample Preservation (Mmgt to cc rtupleted for'sny sampJc(s) incorrectly preserwt[ ar With lieadslaru e-) Samp➢u(s) NA %were racei"d in"uccdy Prase:-vtxl and wrrcadjLixted acoorcingly III santple tt citing with NA n_1. rkfcir: le. 071c; FZS04, ] NOS, ICI, NuOH using SR 4 NA _ irrre of preservttt otl NA _ U more than -one prrscrvative m neec[W. picas: nofo in the coMML-,ras Mlow, Sample(s) MA were r=1vuw with bubbles >6 mrr. hi diamutcn Smiple;(S) NA _ Ware received with TRC > 0.5 mgjr. (ITA19 is pro) and were 'cliusted accordingly in sample ravaiying twit:t sn,l4im Lhiosrtifate (Rra29,0.)) wi11, Shealy ID, NA Slt buraadc labels appiied hy: ETJ3 N ir; 9r 1 &20 CA n3mrnis: x Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 9 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:VK20022 Date Completed:12/04/2020 12/08/2020 10:32 AM Approved and released by: Project Manager II: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs-in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 15 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: VK20022 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP VK20022-002 This sample was able to oxidize after 15mLs of HNO3 was added. Due to low % solids the initial amount of sample -001 and -002 was 3 times the standard procedure amount. The LOQ has been adjusted accordingly. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 15 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: VK20022 Sample Number Sample ID Matrix Date Sampled Date Received 001 Tyson/Harmony Solid 11/19/20201430 11/20/2020 002 Tyson/Wilksboro Solid 11/19/20201530 11/20/2020 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3of15 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: VK20022 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Tyson/Harmony Solid % Volatile Solids SM 2540G- 90 % 6 001 Tyson/Harmony Solid Ammonia - N (gas 350.1 6800 mg/kg 6 001 Tyson/Harmony Solid Ignitability (Pensky-Martens 1010A >140 ° F 6 001 Tyson/Harmony Solid Nitrate -Nitrite - N (soluble) 353.2 12 mg/kg 6 001 Tyson/Harmony Solid Paint Filter Test 9095B Fail pass/fail 6 001 Tyson/Harmony Solid Phosphorus 365.1 4500 mg/kg 6 001 Tyson/Harmony Solid TKN 351.2 20000 mg/kg 6 001 Tyson/Harmony Solid 3+4-Methylphenol 8270E 0.86 mg/L 7 001 Tyson/Harmony Solid Aluminum 6010D 920 mg/kg 9 001 Tyson/Harmony Solid Calcium 6010D 3700 mg/kg 9 001 Tyson/Harmony Solid Potassium 6010D 1400 mg/kg 9 001 Tyson/Harmony Solid Sodium 6010D 1500 mg/kg 9 002 Tyson/Wilksboro Solid % Volatile Solids SM 2540G- 99 % 10 002 Tyson/Wilksboro Solid Ammonia - N (gas 350.1 1500 mg/kg 10 002 Tyson/Wilksboro Solid Ignitability (Pensky-Martens 1010A >140 ° F 10 002 Tyson/Wilksboro Solid Nitrate -Nitrite - N (soluble) 353.2 19 mg/kg 10 002 Tyson/Wilksboro Solid Paint Filter Test 9095B Fail pass/fail 10 002 Tyson/Wilksboro Solid Phosphorus 365.1 3800 mg/kg 10 002 Tyson/Wilksboro Solid TKN 351.2 93000 mg/kg 10 002 Tyson/Wilksboro Solid Aluminum 6010D 140 mg/kg 13 002 Tyson/Wilksboro Solid Copper 6010D 31 mg/kg 13 002 Tyson/Wilksboro Solid Sodium 6010D 1700 mg/kg 13 002 Tyson/Wilksboro Solid Zinc 6010D 69 mg/kg 13 (23 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-001 Description: Tyson/Harmony Matrix: Solid Date Sampled:11/19/2020 1430 % Solids: 9.44 11/21/2020 0052 Date Received:11/20/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 11/25/2020 0153 MOM 74558 1 350.1 (Ammonia - N ) 350.1 25 11/25/2020 1106 CAG2 74610 1 (Ignitability) 1010A 1 11/25/2020 1010 KMC 74780 1 (Nitrate-Nitr) 353.2 1 11/25/2020 1732 AMR 74846 1 (Paint Filter) 9095B 1 11/25/2020 1150 KMC 1 (Phosphorus) 365.1 10 11/25/2020 1249 DMA 11/24/2020 2011 74700 1 (Reactive Cya) 7.3.3 1 11/30/2020 1746 KFE 11/24/2020 2018 1 (Reactive Sul) 7.3.4 1 11/24/2020 2212 GDC 11/24/2020 2018 1 (Soil pH meas) 9045D 1 11/24/2020 2310 AAB 74709 1 351.4 (TKN) 351.2 1 12/02/2020 1200 DMA 12/01/2020 1908 75167 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 254OG-1997 90 % 1 Ammonia - N (gas diffusion) 350.1 6800 2600 mg/kg 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 o F 1 Nitrate -Nitrite - N (soluble) 353.2 12 2.1 mg/kg 1 Paint Filter Test 9095B Fail pass/fail 1 Phosphorus 7723-14-0 365.1 4500 530 mg/kg 1 Reactive Cyanide 7.3.3 ND 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 mg/kg 1 Soil pH measured in water @ 19.3 ° C 9045D 5.6 su 1 TKN 351.2 20000 260 mg/kg 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 12/03/20201211 TML 75398 11/23/20201856 CAS Analytical Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260D ND 0.050 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 mg/L 1 Tetrachloroethene 127-18-4 8260D ND 0.050 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-001 Description: Tyson/Harmony Matrix: Solid Date Sampled:11/19/2020 1430 % Solids: 9.44 11/21/2020 0052 )ate Received: 11/20/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 108 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 104 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 12/02/2020 2058 SCD 11/25/2020 1030 74744 11/20/2020 2300 CAS Analytical Parameter Number Method Result Q LOQ Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 mg/L 1 3+4-Methylphenol 106-44-5 8270E 0.86 0.040 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 56 37-129 2-Fluorophenol 32 24-127 Nitrobenzene-d5 57 38-127 Phenol-d5 39 28-128 Terphenyl-d14 59 10-148 2,4,6-Tribromophenol 55 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 12/01/2020 2004 JJG 11/23/2020 1050 74442 11/20/2020 2300 CAS Analytical Parameter Number Method Result Q LOQ Units Run 2,4-D 94-75-7 8151A ND 0.020 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 71 50-112 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-001 Description: Tyson/Harmony Matrix: Solid Date Sampled:11/19/2020 1430 % Solids: 9.44 11/21/2020 0052 Date Received:11/20/2020 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 1 11/25/2020 1731 DAL1 11/24/2020 1020 74581 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 180 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 180 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 180 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 180 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 180 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 180 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 180 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 83 41-132 Tetrachloro-m-xylene 77 35-106 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 12/02/20201553 DAL1 11/25/20201530 74810 11/20/20202300 CAS Analytical Parameter Number Method Result Q LOQ Units Run gamma-BHC(Lindane) 58-89-9 8081B ND 0.00040 mg/L 1 Chlordane 57-74-9 8081B ND 0.0040 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 77 20-131 Tetrachloro-m-xylene 69 26-132 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 11/30/2020 1020 JAB2 11/30/2020 0806 74615 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 0.85 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-001 Description: Tyson/Harmony Matrix: Solid Date Sampled:11/19/2020 1430 % Solids: 9.44 11/21/2020 0052 Date Received: 11/20/2020 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 11/26/2020 0014 JMH 11/24/2020 0504 74494 11/20/2020 2300 1 1311/7470A 7470A 1 11/23/2020 1249 JAB2 11/23/2020 0656 74404 11/20/2020 2300 CAS Analytical Parameter Number Method Result Q LOQ Units Run Arsenic 7440-38-2 6010D ND 0.15 mg/L 1 Barium 7440-39-3 6010D ND 0.25 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 mg/L 1 Chromium 7440-47-3 601OD ND 0.10 mg/L 1 Lead 7439-92-1 601OD ND 0.10 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 mg/L 1 Silver 7440-22-4 6010D ND 0.10 mg/L 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 11/30/2020 1943 JMH 11/30/2020 0433 74737 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 920 70 mg/kg 1 Arsenic 7440-38-2 6010D ND 2.6 mg/kg 1 Cadmium 7440-43-9 6010D ND 0.87 mg/kg 1 Calcium 7440-70-2 6010D 3700 870 mg/kg 1 Copper 7440-50-8 6010D ND 1.7 mg/kg 1 Lead 7439-92-1 6010D ND 1.7 mg/kg 1 Magnesium 7439-95-4 6010D ND 870 mg/kg 1 Molybdenum 7439-98-7 601OD ND 7.0 mg/kg 1 Nickel 7440-02-0 601OD ND 7.0 mg/kg 1 Potassium 7440-09-7 6010D 1400 870 mg/kg 1 Selenium 7782-49-2 6010D ND 3.5 mg/kg 1 Sodium 7440-23-5 6010D 1500 870 mg/kg 1 Zinc 7440-66-6 6010D ND 8.7 mg/kg 1 Footnote(s): 'Paint Filter: 54mL collected; LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-002 Description: Tyson/Wilksboro Matrix: Solid Date Sampled:11/19/2020 1530 % Solids: 6.15 11/21/2020 0052 Date Received:11/20/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 11/25/2020 0153 MOM 74558 1 350.1 (Ammonia - N ) 350.1 5 11/25/2020 1108 CAG2 74610 1 (Ignitability) 1010A 1 11/25/2020 1050 KMC 74780 1 (Nitrate-Nitr) 353.2 1 11/25/2020 1733 AMR 74846 1 (Paint Filter) 9095B 1 11/25/2020 1150 KMC 1 (Phosphorus) 365.1 5 11/25/2020 1130 DMA 11/24/2020 2011 74700 1 (Reactive Cya) 7.3.3 1 11/30/2020 1747 KFE 11/24/2020 2018 1 (Reactive Sul) 7.3.4 1 11/24/2020 2212 GDC 11/24/2020 2018 1 (Soil pH meas) 9045D 1 11/24/2020 2311 AAB 74709 1 351.4 (TKN) 351.2 5 12/02/2020 1135 DMA 12/01/2020 1908 75167 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 254OG-1997 99 % 1 Ammonia - N (gas diffusion) 350.1 1500 810 mg/kg 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 o F 1 Nitrate -Nitrite - N (soluble) 353.2 19 3.3 mg/kg 1 Paint Filter Test 9095B Fail pass/fail 1 Phosphorus 7723-14-0 365.1 3800 410 mg/kg 1 Reactive Cyanide 7.3.3 ND 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 mg/kg 1 Soil pH measured in water @ 19.3 ° C 9045D 4.2 su 1 TKN 351.2 93000 2000 mg/kg 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 12/03/20201234 TML 75398 11/23/20201856 CAS Analytical Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260D ND 0.050 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 mg/L 1 Tetrachloroethene 127-18-4 8260D ND 0.050 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-002 Description: Tyson/Wilksboro Matrix: Solid Date Sampled:11/19/2020 1530 % Solids: 6.15 11/21/2020 0052 )ate Received: 11/20/2020 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 106 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 98 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 12/02/2020 2033 SCD 11/25/2020 1030 74744 11/20/2020 2300 CAS Analytical Parameter Number Method Result Q LOQ Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 63 37-129 2-Fluorophenol 34 24-127 Nitrobenzene-d5 65 38-127 Phenol-d5 34 28-128 Terphenyl-d14 66 10-148 2,4,6-Tribromophenol 58 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 12/01/2020 2050 JJG 11/23/2020 1050 74442 11/20/2020 2300 CAS Analytical Parameter Number Method Result Q LOQ Units Run 2,4-D 94-75-7 8151A ND 0.020 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 76 50-112 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-002 Description: Tyson/Wilksboro Matrix: Solid Date Sampled:11/19/2020 1530 % Solids: 6.15 11/21/2020 0052 Date Received:11/20/2020 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 1 11/25/2020 1744 DAL1 11/24/2020 1020 74581 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 270 ug/kg 1 Aroclor 1221 11104-28-2 8082A ND 270 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 270 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 270 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 270 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 270 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 270 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 83 41-132 Tetrachloro-m-xylene 77 35-106 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 12/02/20201624 DAL1 11/25/20201530 74810 11/20/20202300 CAS Analytical Parameter Number Method Result Q LOQ Units Run gamma-BHC(Lindane) 58-89-9 8081B ND 0.00040 mg/L 1 Chlordane 57-74-9 8081B ND 0.0040 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 74 20-131 Tetrachloro-m-xylene 68 26-132 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 11/30/2020 1023 JAB2 11/30/2020 0806 74615 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 1.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 11 of 15 Client: Terra Renewal Services, Inc. Laboratory ID:VK20022-002 Description: Tyson/Wilksboro Matrix: Solid Date Sampled:11/19/2020 1530 % Solids: 6.15 11/21/2020 0052 Date Received: 11/20/2020 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 11/26/2020 0017 JMH 11/24/2020 0504 74494 11/20/2020 2300 1 1311/7470A 7470A 1 11/23/2020 1251 JAB2 11/23/2020 0656 74404 11/20/2020 2300 CAS Analytical Parameter Number Method Result Q LOQ Units Run Arsenic 7440-38-2 6010D ND 0.15 mg/L 1 Barium 7440-39-3 6010D ND 0.25 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 mg/L 1 Chromium 7440-47-3 601OD ND 0.10 mg/L 1 Lead 7439-92-1 601OD ND 0.10 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 mg/L 1 Silver 7440-22-4 6010D ND 0.10 mg/L 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 11/30/2020 1947 JMH 11/30/2020 0433 74737 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 140 110 mg/kg 1 Arsenic 7440-38-2 6010D ND 4.0 mg/kg 1 Cadmium 7440-43-9 6010D ND 1.3 mg/kg 1 Calcium 7440-70-2 6010D ND 1300 mg/kg 1 Copper 7440-50-8 6010D 31 2.7 mg/kg 1 Lead 7439-92-1 601OD ND 2.7 mg/kg 1 Magnesium 7439-95-4 6010D ND 1300 mg/kg 1 Molybdenum 7439-98-7 601OD ND 11 mg/kg 1 Nickel 7440-02-0 601OD ND 11 mg/kg 1 Potassium 7440-09-7 6010D ND 1300 mg/kg 1 Selenium 7782-49-2 6010D ND 5.4 mg/kg 1 Sodium 7440-23-5 6010D 1700 1300 mg/kg 1 Zinc 7440-66-6 6010D 69 13 mg/kg 1 Footnote(s): 'Paint Filter: 19mL collected; LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 12 of 15 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 15 PACE ANALYTICAL SERVICES, LLC z rc I t] E E E E V i I CA TZ y E r w i TZ Q , as cv °X x X x 9 I X X3{ X '0 c a p , rr ec m a M F 00 -- I S4 17 4 -5 i 4 I .sue i a _Q J s — i3 h0 Cj 03 L� q�� 139 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 15 PACE ANALYTICAL SERVICES, LLC Samples Receipt t dist (SRCI IMC0012Revi5ed;5J29f 2420 1�2rvxluw of IssuingAuthority_ Pace ENV - W+ 01l Page 7_ o11 Sample .receipt Checklist (S-kc) li nt; TcimRemiml Cooler Inipwlud avldate: KL5C r' Jir=o.+2ttzu 'Loco; YK2002 R�ranS ar receipt- I__I t'act C bent YJ UPS Fedfsx Other Yes , Na 1. W= custody seals Iwc%mt cm the cooler'' Yr4l lWol-NA 12. If EMIr 'esem, wuri; Crwy intactarduhhrokon? PH Str'P lU; _`' Chlat•iue Strip ID-. I Tested by: 1a.1 5.8 87nal LImperatum upon rei:ript) Derived ( S�rr CtCG wmparaaire ill}Un rKei). rosolid Sn�(;up ID• 20. Ic R 5,8 f5.9 c + VA DNA IC NA iKA vC• NA 1h1,'. c�C I Method, LjTc iperamre sham Q inst Bolles 1R Gun 1D: IR GOu C6rrdUiUu FKr W. 0 uc I ethod t3f coolant; ❑ Wel kc W1 Ica pack€ U pin- lee ❑ N�1rtc — ~— ❑ YO No [ NA 3- It-tempemtto-e of any cooler axcccded bA°C, tv2s Pioject A4anager NotiT&d? Phi was Notified bye pllanc I cma=1,' facerto-toga (e jrola Due). Yes Na UNA14. Is the commmr- al courier's pau:kiug slip aumched to;tE k i`b m7 Yas No S- Were proper cunt<idy procedtu-es (rclir,qu=shedfre4eived} follOwad`t Yes- No 16. %Ycm sample IDS listed on the COC? 'r-cs 'No 7- Wore sally le Ifs li%fm on all sample Containers mm Yes Ake 8- W,71.: rol lect=elti 11Q'e time listed an the COG? � _/ LCsYetia Iwro 9. Was collcc:inn dam & lime listed on all swmplc car3 9lneDrs? ,l No Id. Did All contakia- Iubul informatiaw (ID, &%ta, t:r>le) hgree with thrr. COVI ( Yes 10 y t I- WVr�c tests to be perfonlned listed art the COC ? i - �, Y--s ❑'No 12. Did all smmples arrive in the proper coaminens for each test etidlur in guud condition 4-ibmken, lids (va, ctc j) yd 9 Ll Nr3 I .1. 'Alas Hdeq Gate su n.-PIC volume a'Jailltblc - J F Yes No 14, Wrrnc :] sam ley tCCCivad within 'A the 'haMiEg Fine ar 48 hours. whicFeVeT cam CS first'# Yes No 15. Wt° rc wiy sample€ coatarincrs mi�gln excess (cir> Jclou�) garnple 7,lot listed ou COO? ❑VIM �N' irNo 16. For VOA and HS -175-arupka, xcrc hubhles present>'pea-se'(A"Ot6nlm in diatneter) in ar.y nfrhe VOA vials! Yol LJ No J NA 17, Wore all DROlmulafi'nutr3cnt samples received at _pH of < 1. 27 Yes! Talc, J NA 18. VG'ea a aI N eywode xa,nples receivvd , t a pH 12 oriel eu. lde sarnple5 t e Elv> d at a p I! > 9? El❑h 4 OlxlA 19-. V4 r rC a�T applieablr? A� �� Cy+in_elc'ph,.,,p ti25- i i6l}8, .5mAlL) sarrgAe-s frze of Y cs ❑Yes ❑ fro W]NA 2B, Were olicnt remarksfr2g1lesls (Lz. rcqu,'st&1 dilutiaris, Mg-' 1 D Jcsigrm ions, etc,--) carrectly ttpnSCribed rjuii Ilse COC into the celmmt!nt section in LlJoSL? Yes + No ' l - Was thu quote Tiumber lislud m the container l0>SC17 IF QUOLc # . sample pruervnti011 ([lust be completed for any sar pies) Imurrcc#ly pre9erk�r1 rn' Mvitll IleadHIM".) a,nple{sj ra.n -A-cre 17eceIveer hKTr, xrIy preRerved arui were adjusW iiccordirkgGv lit sample receiving with ' mLofcir lc ant_ 1T2SO4, HNO3, MCI, NUj)H usingSR0 NA Timc o£ preserv2tion NA 1Fmone than nne pTzrian mdvu - is needed, pleasq matt in the caminent; below. 5art:plc(s) >TA _ W= rCVeiiTd with Fnthb;es >6 Frm indiamel.cg i r+r4 4 'Were r=!ived with TR ACe9rdi'391Y in sample rcw1v'tk9 whit sodium d i(Imi1J'.a1 t" a:SaO3) with barc-ede labels applied by_ !c yr- _Late I I"�Oi�D2� Comments: > 0.5 nLgL. (If i#19 15 fed ) and were Irsly 117: rli� Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 15 aceAnalytical Report of Analysis Terra Renewal Services, Inc. PO Box 3036 Russellville, AR 72811 Attention: David Coyle Project Name: NC Samples Lot Number:VL05007 Date Completed:12/23/2020 12/23/2020 2:25 PM Approved and released by: Project Manager II: Lucas Odom ¢p ACCi/FQ, J 2� AILB_ TNl Nriraue nareauynon eaaI; !4$OR1CS4� A C G R E �[ T£ � rrs-in : � aevuq�cm The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 16 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Terra Renewal Services, Inc. Lot Number: VLO5007 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to the matrix and low percent solids, the initial sample amount used for the following samples was 3X more than the standard procedure: VL05007-001, VL05007-002. The LOQ has been adjusted accordingly. TCLP Herbicide Due to the matrix, the initial sample amount used for the following sample deviated from the standard procedure: VL05007-001. The LOQ has been adjusted accordingly. PCBs by GC The following sample was diluted due to the nature of the sample matrix: VL05007-001. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 16 PACE ANALYTICAL SERVICES, LLC Sample Summary Terra Renewal Services, Inc. Lot Number: VLO5007 Sample Number Sample ID Matrix Date Sampled Date Received 001 Advanced Foods/Clue Meat Solid 12/03/2020 1430 12/04/2020 002 Perdue/Concord Solid 12/03/20201530 12/04/2020 (2 samples) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3of16 PACE ANALYTICAL SERVICES, LLC Detection Summary Terra Renewal Services, Inc. Lot Number: VLO5007 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Advanced Foods/Clue Meat Solid % Volatile Solids SM 2540G- 90 % 6 001 Advanced Foods/Clue Meat Solid Ammonia - N (gas 350.1 550 mg/kg 6 001 Advanced Foods/Clue Meat Solid Flashpoint (Pensky- 1010B >140 ° F 6 001 Advanced Foods/Clue Meat Solid Nitrate -Nitrite - N (soluble) 353.2 260 mg/kg 6 001 Advanced Foods/Clue Meat Solid Phosphorus 365.1 14000 mg/kg 6 001 Advanced Foods/Clue Meat Solid TKN 351.2 51000 mg/kg 6 001 Advanced Foods/Clue Meat Solid Aluminum 6010D 14000 mg/kg 9 001 Advanced Foods/Clue Meat Solid Copper 6010D 490 mg/kg 9 001 Advanced Foods/Clue Meat Solid Potassium 6010D 4200 mg/kg 9 001 Advanced Foods/Clue Meat Solid Sodium 6010D 14000 mg/kg 9 001 Advanced Foods/Clue Meat Solid Zinc 6010D 82 mg/kg 9 002 Perdue/Concord Solid % Volatile Solids SM 2540G- 87 % 10 002 Perdue/Concord Solid Ammonia - N (gas 350.1 1100 mg/kg 10 002 Perdue/Concord Solid Flashpoint (Pensky- 1010B >140 ° F 10 002 Perdue/Concord Solid Nitrate -Nitrite - N (soluble) 353.2 150 mg/kg 10 002 Perdue/Concord Solid Phosphorus 365.1 36000 mg/kg 10 002 Perdue/Concord Solid TKN 351.2 61000 mg/kg 10 002 Perdue/Concord Solid Aluminum 6010D 29000 mg/kg 13 002 Perdue/Concord Solid Copper 6010D 8.0 mg/kg 13 002 Perdue/Concord Solid Potassium 6010D 6600 mg/kg 13 002 Perdue/Concord Solid Sodium 6010D 12000 mg/kg 13 002 Perdue/Concord Solid Zinc 6010D 22 mg/kg 13 (22 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 16 Client: Terra Renewal Services, Inc. Laboratory ID:VL05007-001 Description: Advanced Foods/Clue Meat Matrix: Solid Date Sampled:12/03/2020 1430 % Solids: 2.66 12/05/2020 1622 )ate Received:12/04/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Volatile S) SM 254OG-1997 1 12/10/2020 0057 MOM 76072 1 350.1 (Ammonia - N ) 350.1 1 12/09/2020 1046 DRD 75729 1 (Flashpoint () 1010B 1 12/14/2020 1245 KMC 76475 1 (Nitrate-Nitr) 353.2 1 12/14/2020 2351 SRB 76618 1 (Phosphorus) 365.1 10 12/14/2020 1333 DMA 12/11/2020 1750 76330 1 (Reactive Cya) 7.3.3 1 12/15/2020 1633 KFE 12/14/2020 1914 1 (Reactive Sul) 7.3.4 1 12/22/2020 2150 GDC 12/14/2020 1917 1 (Soil pH meas) 9045D 1 12/08/2020 2248 AAB 75895 2 351.4 (TKN) 351.2 2 12/10/2020 1156 DMA 12/09/2020 1742 76045 CAS Analytical Parameter Number Method Result Q LOQ Units Run % Volatile Solids SM 254OG-1997 90 % 1 Ammonia - N (gas diffusion) 350.1 550 380 mg/kg 1 Flashpoint (Pensky-Martens Closed -Cup) 1010B >140 140 o F 1 Nitrate -Nitrite - N (soluble) 353.2 260 7.5 mg/kg 1 Phosphorus 7723-14-0 365.1 14000 1900 mg/kg 1 Reactive Cyanide 7.3.3 ND 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 mg/kg 1 Soil pH measured in water @ 17.5 ° C 9045D 5.3 su 1 TKN 351.2 51000 1900 mg/kg 2 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 12/15/2020 1240 TML 76566 12/09/2020 0138 CAS Analytical Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260D ND 0.050 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 mg/L 1 Tetrachloroethene 127-18-4 8260D ND 0.050 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 104 70-130 1,2-Dichloroethane-d4 103 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 16 Client: Terra Renewal Services, Inc. Laboratory ID:VL05007-001 Description: Advanced Foods/Clue Meat Matrix: Solid Date Sampled:12/03/2020 1430 % Solids: 2.66 12/05/2020 1622 Date Received:12/04/2020 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 12/17/2020 1728 SCD 12/13/2020 1609 76377 12/09/2020 0138 CAS Analytical Parameter Number Method Result Q LOQ Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 94 37-129 2-Fluorophenol 56 24-127 Nitrobenzene-d5 126 38-127 Phenol-d5 86 28-128 Terphenyl-d14 107 10-148 2,4,6-Tribromophenol 94 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 12/17/2020 0421 JJG 12/10/2020 2043 76184 12/09/2020 0138 CAS Analytical Parameter Number Method Result Q LOQ Units Run 2,4-D 94-75-7 8151A ND 0.20 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 79 50-112 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 10 12/18/2020 1019 NCM 12/09/2020 1730 76039 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1016 12674-11-2 8082A ND 6400 ug/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 16 Client: Terra Renewal Services, Inc. Laboratory ID:VL05007-001 Description: Advanced Foods/Clue Meat Matrix: Solid Date Sampled:12/03/2020 1430 % Solids: 2.66 12/05/2020 1622 Date Received:12/04/2020 PCBs by GC Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3550C 366013/3665A 8082A 10 12/18/2020 1019 NCM 12/09/2020 1730 76039 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aroclor 1221 11104-28-2 8082A ND 6400 ug/kg 1 Aroclor 1232 11141-16-5 8082A ND 6400 ug/kg 1 Aroclor 1242 53469-21-9 8082A ND 6400 ug/kg 1 Aroclor 1248 12672-29-6 8082A ND 6400 ug/kg 1 Aroclor 1254 11097-69-1 8082A ND 6400 ug/kg 1 Aroclor 1260 11096-82-5 8082A ND 6400 ug/kg 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 59 41-132 Tetrachloro-m-xylene 67 35-106 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 12/14/2020 1643 DAL1 12/13/2020 1601 76376 12/09/2020 0138 CAS Analytical Parameter Number Method Result Q LOQ Units Run gamma-BHC (Lindane) 58-89-9 8081B ND 0.00040 mg/L 1 Chlordane 57-74-9 8081B ND 0.0040 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 51 20-131 Tetrachloro-m-xylene 73 26-132 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 12/09/2020 0802 JAB2 12/09/2020 0447 75828 CAS Analytical Parameter Number Method Result Q LOQ Units Run Mercury 7439-97-6 7471B ND 2.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 16 Client: Terra Renewal Services, Inc. Laboratory ID:VL05007-001 Description: Advanced Foods/Clue Meat Matrix: Solid Date Sampled:12/03/2020 1430 % Solids: 2.66 12/05/2020 1622 Date Received:12/04/2020 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 12/15/2020 1957 KSH2 12/11/2020 0445 76098 12/09/2020 0138 1 1311/7470A 7470A 1 12/10/2020 1439 JAB2 12/10/2020 0610 76093 12/09/2020 0138 2 1311/3010A 601OD 1 12/16/2020 1028 KSH2 12/11/2020 0445 76098 12/09/2020 0138 CAS Analytical Parameter Number Method Result Q LOQ Units Run Arsenic 7440-38-2 6010D ND 0.15 mg/L 1 Barium 7440-39-3 6010D ND 0.25 mg/L 1 Cadmium 7440-43-9 601OD ND 0.050 mg/L 2 Chromium 7440-47-3 601OD ND 0.10 mg/L 1 Lead 7439-92-1 601OD ND 0.10 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 mg/L 1 Silver 7440-22-4 6010D ND 0.10 mg/L 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 12/10/2020 1732 JMH 12/09/2020 0830 75795 2 3050B 6010D 1 12/11/2020 1452 JMH 12/09/2020 0830 75795 CAS Analytical Parameter Number Method Result Q LOQ Units Run Aluminum 7429-90-5 6010D 14000 250 mg/kg 1 Arsenic 7440-38-2 6010D ND 9.3 mg/kg 1 Cadmium 7440-43-9 6010D ND 3.1 mg/kg 1 Calcium 7440-70-2 6010D ND 3100 mg/kg 1 Copper 7440-50-8 6010D 490 6.2 nrl 1 Lead 7439-92-1 601OD ND 6.2 mg/kg 1 Magnesium 7439-95-4 601OD ND 3100 mg/kg 1 Molybdenum 7439-98-7 6010D ND 25 mg/kg 1 Nickel 7440-02-0 6010D ND 25 mg/kg 1 Potassium 7440-09-7 6010D 4200 3100 mg/kg 2 Selenium 7782-49-2 601OD ND 12 mg/kg 1 Sodium 7440-23-5 6010D 14000 3100 mg/kg 2 Zinc 7440-66-6 6010D 82 31 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 16 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 13 of 16 PACE ANALYTICAL SERVICES. LLC 7$ o d x F A ( m rS1 L �F � � A x z L t ---- w q c� � r v 13 IJ Pr ,yyp IIIIj ����jj JSJ x x x+ X i r x x I x } n 12 U7 d0 $ 7 2O y d y x W Z {l CS }, q x X X X X x }C x xCY, ,sue g ' m m: n 7 F CY y b FSt .h C ,rFS � 152 � u a pp r Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 14 of 16 3 Id T PACE ANALYTICAL SERVICES, LLC North Carolina Permit Parametem ., P2esiduals shall be. amalymd to dcanonstrt tc tllj--y are e Cotutrvstion a i recovery r ct (RCS}. the a L a orroaRity} ignitnbibty, 1etiWi multi toxielty c11xrRiAcrislA4' leac..king pr-acedaw Lr S11.91 e'quaucy spec:iied in Attaclulaent A, and the Perraittee 6911 maintain lficsc msuits lfu a uwrimum of five years. And• e-wo%iow from the xcquim meats fg JHs. condition shall be mocifted in AttacWU=t A. Tht=Paiialysls sl_ali inoladetlie fotlowingparamctus (the iegulatcry level i-i mil[i2r.ro- - prsIitea- � in parentht�ts)• R �7x�ui000-0) i,2-Dichlarpetl�ane{D,Sj I,l- icliloroe ;jleoe (0.7) --- Fcntac111orDpktei4I{100.0) - Bmazc a (0-5) i'yvr in: (5.4) w Cadmiuin (I.0) .;-l]initrotolFIPTLP (0-13) ' rj�UiUTR (1,0) Arbon tetraclilo do (0.5) Fzulrin (4.02) Salver (5,0} Chlordana (OX) Hex hl bt--nzene ((1-11) Tclydcl�Ioro�thyl (0.7) Chlorabmmnt (IOD,0) C1:3omfxr»n (�,oj Hgtachlor (and iti -00T Taxeph=(0,5) )«exacl�l��0-�,3-L�utudiene �fii.;) Ti2c11lazaethylene {tk.5} (�4b0.4j Chranliuzn (5,0) F) xahloroetlyane .0),4,5-Iriclrnaflanul m-Cresol (200-0) Lead (5.) 2,4,6-Trichlorophennl (2.0) 2,4,5-'YP (Silvex) (1-0) 4-Crewl (200.4) Lutda,nn (0.4) P-Cresol (200k) Cresol (MO.0) Mercury (0.2) Vinyl chloride (0-2) rir,X 4hoxycWor (10.0) - 3. An analysis shall be con4ucted on f&-dun% frola each soku 0 gala-Ating facility at the fiequeucv spacifled in Attaehmeart A, and the Pcrmittee shall inainiaan tee rasn'lo far a njjniva1,T Of five Lr 3 y - TEt analysis all.-i=lude dw FaFLowiug parain,eters: Me Aluminum i].emcury potassium - A ntonia-T#it� girl Ualybdenuak Scltr uxa PXicktl Arsenic Sodium Cadmium N-trate-Nitrite Nitrogea CaMunr Per,"Rtal solids TKN cower pH ... Zinc Vnlaflle Solids JU lead Phoephoms � � �i�Raesiutn PGFi's �r TERRA RENEWAL SERVICES 479-747-8192 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 15 of 16 PACE ANALYTICAL SERVICES, LLC SarkIP1 &S MLUipt CheE:kJ ist (SRC) (moo(jj8C-15) Rcvisrd=9f29f2020 €'aceAr�aly7rcrl Issuing AuthuriLy: Pace ENV WCOf Rage Sample Receipt Checklist (SRC) clkat; Tarn Rriww,r Cooler lily :eWd l}y'rd-a'.]4; Al lrr f I2tsf202u WL03477 M ean4 4A mcq#r- U Pauc 4' l i}-n[ © UPS . ❑ Fexlr a€ D Odser; _ YLJ es; Z No I I _ Were r-astodv seals pr-9CnL 4n dtc cooler',' — ❑ Ye i I No J 1-.4 2. IfcusEadv Gila ucro rescin. were Lhey intact ffitd Wilxxdccn? pH 5Lr iP ID. NA C Irlorinc Strip 113: MA TCstod bv_.aru Or4itlal tesmprr tum upon receipt I Derived (Conwwd) Jcmperatum upon receipt VoSalid Sllup-Cup III. 20.2056 i'tA rNA e WA A+NA a T+'A iN4 aC+ Mcthcd. ❑Temperamro Blank �tirrsl. Rvtrles I 0t:n ID; _6_ _ IR Gurl Comcetion Factor, 'C Mcthod ,3C,;exolar,t: 0 wet Ice ❑ Ict PucU ❑ Dry Ice Ij 'one -- - ❑ ` ❑ Flo ❑,� NA 3, if tcrrperatLj-e of anv e.r-ulc: exceeded F_O°C, was 1rL-aject Van:q,!ar Notified$ PM was 1+lotitied 1y phr.nn / etluail / Beau-W-F=t ; (circle arse). _ Yes No �-7--'NA 14. Is the cnu,u,te:,cial courier`s Fg3c:kiyg slip atrachrd w this f0111t1: �10 15. Were prt4mrcustody (rvIingLLMad,receivq,r,) followed? I es bra G_ Wei simple lllte listed nn Om Cf C9 f Yes No 7_ %Vere sample IDs listed em aIL sample oontaimore f Yes NU S_ Was oollcctiut dale & time I isred u, i Lhe COC? — Q Yes No 9_ %VM U0111Mtiun date & time listed on all sgerlpl-v cuntainers? Ye;s ❑ 1%0 10_ Did ali cumafrer label irLfvrmation (11), &11r., tune) agree widI lh�; COO � Yt5 - Nu 11 _ Won: lusts to be let" elrmad listed oli 11:e COC", 12, Did all swn les cr a7rive in the proContainers rbr each tc5t andiar irr gr:-rLra [l .jd3t=on ❑ Yes ❑° (unLrukcn, lids on, eta.)? P y Yesi iJND Ldye'.1 UND Yes I YJNj ❑ Ya5 ❑ h[o Y4 Ll No Yes N ❑ 1'es ❑ ?du U Yes ❑ WC3 Yet~ I V-0,,c, 13. Was 9rd--pa{t 5antpla V0111i Le Eivailable? — - [4_ %Mdre; LLll suarn les 3r"ivc:d withila %. rao; holding th-ne or4l 110tirs, whichever eximes first/ 15_ WeM 111y samples mltaincrs miss:n 'excess (cirolcs Me) LiarirfrlrS Not listed or. COC? [DNA 16L For VOA and UK-175 sarr,plrs, w= bubbler. presmi ;-"M-siiC' (W'iDr 6mm 'r. diameter) in aiiy r FC Lhe; VOA vials' q4 17. Vdrm all DRD rneb.Is,6uHcnt sarn ley remived at a cH uf< 2? 7. NA 18, Were all ctianide samples reeseK-r-,d aa a pl-I } 12 Hrerl so[4& saetrples received at a pH- 9'2 �N. S. Were all apr,liCnb H KNire,yo-tni&c 13Lienali625.1f60 l,< 0.5rng1L} samp!es fro- o et'sielurrl ¢hlnrine" 20. Wffm r.lieurrensprltSrLxquusts (i_e. requested diltltiorns, hi${4ISD dcsi-natior. , a„r__-} cnrrmly transcribed lion: thL COC intr the Oxuryclit seCGuu in UMS? 21. WJlSthe qu❑tea nrm,be~listed ark (he c^stainer label? IfV'cs, Ehicite €t ple i'mervsifion [iJTttSt bC C4mpictod for env sa+nplc{E;} irycoe:eckly prrscn�d nr wilh h adsp ce:} rnpeeels) -._ — _ were received incorrectly Ilruwrved wid were adjusted aeo"ingly SAMpIc rccci,Ang wilh NATaL Of circle Cnc; Wk04, IINO3, HC1, NaDI3 u5iog rile of pruscrvall n N� II utaL ll,air uric prexervative is n�rcled, p[e s nsrCe in the ccmrlen�s below_ Tl}l�C) NA "were rectiyed WTi 1XI131s105 �-6 mir, in dia7nrltsr, .np[es(s) NA -w um rCCeived Zvi th TRC 1J,S ]ngli. 0f419 is HO ) and were Iuri*d accorelingly in -99nip[e reoeivitig wjtit sodiurn thiosuifatc (LN%32Cy) wW1 Slx,ah p ID, 1<n lrPrcudc labcls applied 1xy, AHD Date: 1202024 C4au„m4nt5; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 16 of 16 Laboratory Analyses: - Seven Set Fecal Coliform Data Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 03/26/2020 Reported: 03/27/2020 For: Tyson Advance Claremont Comments: GM <402 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200326-10-01 Fecal Coliforms 1 <407 MPN/g SM92210E-2006 03/26/2020 WC 200326-10-01 Percent Solids 1 4.91 % SM2540B-2011 03/26/2020 WC 200326-10-02 Fecal Coliforms 2 <463 MPN/g SM92210E-2006 03/26/2020 WC 200326-10-02 Percent Solids 2 4.32 % SM2540B-2011 03/26/2020 WC 200326-10-03 Fecal Coliforms 3 <303 MPN/g SM92210E-2006 03/26/2020 WC 200326-10-03 Percent Solids 3 6.60 % SM2540B-2011 03/26/2020 WC 200326-10-04 Fecal Coliforms 4 <319 MPN/g SM92210E-2006 03/26/2020 WC 200326-10-04 Percent Solids 4 6.26 % SM2540B-2011 03/26/2020 WC 200326-10-05 Fecal Coliforms 5 <980 MPN/g SM92210E-2006 03/26/2020 WC 200326-10-05 Percent Solids 5 2.04 % SM2540B-2011 03/26/2020 WC 200326-10-06 Fecal Coliforms 6 <230 MPN/g SM92210E-2006 03/26/2020 WC 200326-10-06 Percent Solids 6 8.68 % SM2540B-2011 03/26/2020 WC 200326-10-07 Fecal Coliforms 7 <410 MPN/g SM92210E-2006 03/26/2020 WC 200326-10-07 Percent Solids 7 4.88 % SM2540B-2011 03/26/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200326-10-01 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200326-10-02 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200326-10-03 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200326-10-04 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200326-10-05 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200326-10-06 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200326-10-07 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 v O W 0 x N N 00 sv z n N 00 rn 00 client: Terra Renewal r, 7 -� r r � eV 3 ? t r. ANALI i rL.AL 122CouaStreet - P.Q. Box UE Address: P.O. Box 399 Dardaneile, AR 721334 A StM5villc, NC 711687 (7Q4js7&4 697 �% Chain of Custody Re�nrd Contact Person: Phone # David Coyle 479-747-f3192 FAX# PD # Contact Vanya Colburn for PO (479-264-04i67) Requisitioned by: Jordan Mathis ��,�u 3Dale)0 Customer LatriO Sampro ION Time Sampled (Grab Or*/) D819 S9iYp6atl (Grab Only) F h6alr�x Psramdas ra�uested rar s�aow ww U&Y51a Advance-Clarmnt F1 7.3y Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarmnt F2 02 ; 35 3 -.2a Fecal Conform (Report in Dry Units MPN or CFU Ig) Advance-Clarmnt F3 Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarmnt F4 1 04/• �$ Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarmnt F5 D5 $%I Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarmnt F6 ?!�C�< a — --tC ✓ ✓ Fecal Coldarm (Report in Dry Units MPN or CFU Ig) Advance-Clarmnt F7 3 Fecal C.omorm (Report in Dry Units MPN or CFU Ig) Relinquished by. Time i,; ( , pm Date 44 1 w sampled by: Received by, _ Timed pm Date'A�_Jkl_? Transported by: Relinquished by: Time am, pm Date Holding times met: Received by: _ � Time am, pm Date ,1 I _ Compliance work: 3� Compos-ite.Sim-plin # : Time lbegin _ am, pm Date I 1 Non-compliance work: Time and am, pm Cate Lab Cammants. Samples Transported On Ice; Composite Sampling #2: Time beglnam, pm Date _! ! Time end am, pm Date �J Initals: Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 05/19/2020 Reported: 05/20/2020 For: Advance Claremont Comments: GM <513 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200519-22-01 Fecal Coliforms 1 <673 MPN/g SM92210E-2006 05/19/2020 WC 200519-22-01 Percent Solids 1 2.97 % SM2540B-2011 05/19/2020 WC 200519-22-02 Fecal Coliforms 2 <676 MPN/g SM92210E-2006 05/19/2020 WC 200519-22-02 Percent Solids 2 2.96 % SM2540B-2011 05/19/2020 WC 200519-22-03 Fecal Coliforms 3 <980 MPN/g SM92210E-2006 05/19/2020 WC 200519-22-03 Percent Solids 3 2.04 % SM2540B-2011 05/19/2020 WC 200519-22-04 Fecal Coliforms 4 <398 MPN/g SM92210E-2006 05/19/2020 WC 200519-22-04 Percent Solids 4 5.03 % SM2540B-2011 05/19/2020 WC 200519-22-05 Fecal Coliforms 5 <396 MPN/g SM92210E-2006 05/19/2020 WC 200519-22-05 Percent Solids 5 5.05 % SM2540B-2011 05/19/2020 WC 200519-22-06 Fecal Coliforms 6 <338 MPN/g SM92210E-2006 05/19/2020 WC 200519-22-06 Percent Solids 6 5.91 % SM2540B-2011 05/19/2020 WC 200519-22-07 Fecal Coliforms 7 <394 MPN/g SM92210E-2006 05/19/2020 WC 200519-22-07 Percent Solids 7 5.07 % SM2540B-2011 05/19/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200519-22-01 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200519-22-02 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200519-22-03 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200519-22-04 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200519-22-05 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200519-22-06 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200519-22-07 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 Client: Terra Renewal Address: P.O. Box 399 ANALT i PLAL 122 Court street - ra. Box 228 Dardanelle, AR 72834 �. sttfrb.;nj709J872.9597e, NC 28687 t ontact Person: David Coyle phone # 473 7+f7.8i92 FAXP Chain of PO 0Contact Vanya Colburn far PC (479-264-0467) Floquisniuned by: Jordan Mathis �i�r�� � ) Custody Record Cuslwnw TlmeSampled Sample IDo 4tb•ia M (Grab Only) Date SumpiW (GmbO* M9tmr Puaoc"M = ° � SW for mw w wve 7 Advance-Clarrmnt F1 0 q , 27. ��,`uv 5-/� �a�o �/ �/ Fecal Colifofm (Report in Dry Units MPN or CFU 1g) Advance-Clafmnt F2 Fecal Colifarm (Report in Dry Units MPN or CFU !g) Advance-Clarmnt F3 Q Fecal Colifofm (Report in Dry Units MPN or CFU Ig) Advance- Clarmnt F4 04 a.jS atn ,S-1? Fecal Colifofm (Repot in Dry Units MPN or CFU Ig)� Advance-Ciarmnt F5 05 �� •�� �/ �/ Fecal Colifofm (Repod in Dry Units MPN or CFU 1g) Advance-Clafmnt FB [j� �a - S-% �/ fecal Colifofm (Report in Dry Units MPN or CFU !g) Advance-Clarmnt F7 0-7 �'o," ae.�-� �/ V/ Fecal Coiiform (Flepod in Dry Units MPN or CFU 1g) Relinquished by: p-g.., / � �(, _� Time �fo am pm Date j} n� Sampled by: Received by: _ WIA Time (,,,� am, m Data 61 t 4? Transported by: Relinquished by, Time am, pm Date —1" 1-_ ... Holding times met: Received by: Time am, pm Date J ! Compliance work: Composite Sampling #1: Time begin am, pm Date _j__/_ Ivan -compliance work: Time end _ .__ am, pm bate ��_ Lab Comments- - Samples Transported an Ice: C_QE&€t Time begin am, pm Date —j--1 f Time end____ _am, pm Date /� Initlats. r` 00 1.0 00 N U Ln ai 4J +n 00 N N X O m O a- Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 09/17/2020 Reported: 09/18/2020 For: Claremont Advance Comments: GM <452 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200917-16-01 Fecal Coliforms 1 <361 MPN/g SM92210E-2006 09/17/2020 WC 200917-16-01 Percent Solids 1 5.54 % SM2540B-2011 09/17/2020 WC 200917-16-02 Fecal Coliforms 2 <428 MPN/g SM92210E-2006 09/17/2020 WC 200917-16-02 Percent Solids 2 4.67 % SM2540B-2011 09/17/2020 WC 200917-16-03 Fecal Coliforms 3 <394 MPN/g SM92210E-2006 09/17/2020 WC 200917-16-03 Percent Solids 3 5.07 % SM2540B-2011 09/17/2020 WC 200917-16-04 Fecal Coliforms 4 <515 MPN/g SM92210E-2006 09/17/2020 WC 200917-16-04 Percent Solids 4 3.88 % SM2540B-2011 09/17/2020 WC 200917-16-05 Fecal Coliforms 5 <372 MPN/g SM92210E-2006 09/17/2020 WC 200917-16-05 Percent Solids 5 5.37 % SM2540B-2011 09/17/2020 WC 200917-16-06 Fecal Coliforms 6 <581 MPN/g SM92210E-2006 09/17/2020 WC 200917-16-06 Percent Solids 6 3.44 % SM2540B-2011 09/17/2020 WC 200917-16-07 Fecal Coliforms 7 <571 MPN/g SM92210E-2006 09/17/2020 WC 200917-16-07 Percent Solids 7 3.50 % SM2540B-2011 09/17/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200917-16-01 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200917-16-02 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200917-16-03 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200917-16-04 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200917-16-05 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200917-16-06 Temp on Arrival: 3.0 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200917-16-07 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 Client Terra Renewalr { — s. --- Lil l i Address: P,p- Box399 f►iRl.r t I{.i1t. tzx Caen soot r-a- eas zzs Dardanelle, AR 72834 _ Statesvilk, NC 28687 f (704) 872A697 Chain Of Contact Person: David Coyle PhD 479-747-8192 FAxu PO 0 Contact Vanya Colbum for PO (479-264-0467) RL-quisitioned by: Jordan Mathis (TimeALA 9a c ca y Record wwtym cWt)mgr Lab -In # " Sampled Dale 58mplad Sample It]# (Grab Only) (GMI3 afry) _ Matnt Paraructcrs n:qucslcd fug awn.f w Iwvr Advance-Clarmnt F1 20 - JI .1 .01 2A-V gel Fecal Coliform (Report in Dry UNts MPN of CFU )gj Advance-Clarmnt F2 _ 02 %:af 7-) 7 Fecal Colitorm (Re part in Dry Units MPN or CFU )g) Advance-Clarmnt F3 03 7f)V Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarrrtnt F4 6 Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarmnt F5 Fecal CalHorm (Report in Dry Units MPS! or CFU )g) Advance-Clamint F6 Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarm nt F7 1- 6e 6e Fecal Coliform (Report in Dry Units MPN or CFU 19) Relinquished by: �pft�/3 Z'rj Time pm Date 9--1aL-:9—W Sampled by: Received by: Tim %/� m, m Date �I� Transported by: Relinquished by' Time ern, pm Rate !� Holding times met: % Received by: Time am, pm Date ! Compliance work: Composite m li Time begin am, pm Date —I--J— Non-compliance work: Time end am, pm Date Lab Comments: Samples Transported On Ice: C&Mosite Sampling; Time begin- arn, pm Date_ _1I� Time end am, pm Date--j�1� Initrxls: fe-A n 00 00 N U Ln Ln ro U0 00 N N x 0 m O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 12/03/2020 Reported: 12/07/2020 For: ADVANCE CLARMONT Comments: Geometric Mean <309 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 201203-19-01 Fecal Coliforms AC1 <295 MPN/g SM92210E-2006 12/03/2020 WC 201203-19-01 Percent Solids AC1 6.78 % SM2540B-2011 12/03/2020 WC 201203-19-02 Fecal Coliforms AC2 <346 MPN/g SM92210E-2006 12/03/2020 WC 201203-19-02 Percent Solids AC2 5.77 % SM2540B-2011 12/03/2020 WC 201203-19-03 Fecal Coliforms AC3 <349 MPN/g SM92210E-2006 12/03/2020 WC 201203-19-03 Percent Solids AC3 5.73 % SM2540B-2011 12/03/2020 WC 201203-19-04 Fecal Coliforms AC4 <290 MPN/g SM92210E-2006 12/03/2020 WC 201203-19-04 Percent Solids AC4 6.9 % SM2540B-2011 12/03/2020 WC 201203-19-05 Fecal Coliforms AC5 <303 MPN/g SM92210E-2006 12/03/2020 WC 201203-19-05 Percent Solids AC5 6.61 % SM2540B-2011 12/03/2020 WC 201203-19-06 Fecal Coliforms AC6 <269 MPN/g SM92210E-2006 12/03/2020 WC 201203-19-06 Percent Solids AC6 7.44 % SM2540B-2011 12/03/2020 WC 201203-19-07 Fecal Coliforms AC7 <318 MPN/g SM92210E-2006 12/03/2020 WC 201203-19-07 Percent Solids AC7 6.29 % SM2540B-2011 12/03/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 201203-19-01 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 201203-19-02 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 201203-19-03 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 201203-19-04 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 201203-19-05 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 201203-19-06 Temp on Arrival: 3.0 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 201203-19-07 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 Client. Terra Renewal �� +A14AII I lk,AL 122 Court Stwv • P.O. Box 7.28 Slalesrdle, NC 28647 r (704) 872.4647 Address: P.O. Box 399 Dardanelle, AR 72834 Contact Person: David Coyle Ptlone # 47�747-0192 FAx# Chain of Custody Record PC * Contact Vanya Colburn for PC (479-264-0467) Requisitioned by: Jordan Mathis s'a °a°BI ,� Customar Sample ION Lail D N Time Sampled [Grab only) DaW Sampled (Grab Only] matrix Paramaus requested Fw aialys s s wa w +w Advance-Clarmnt Ft � _ / j Fecal Coliform (Report in Dry Units MPN or CFU ig) Advance-Ciarmnt F2 �} i; of Fecal Coliform (Report in Dry Units MPN or CFU Ig) Advance-Clarrnni F3 ; §A _� �/ �%1 Fecal Coliform (Report in Dry Units MPN or CFU Jg) Advance-Clarmnt F4 ( : 515 Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU lg) Advance-Clarmnt F5 0512,1 C10 Advance-Clarmnt FB Q r a3 IA-3 V Fecal Caliform (Repoli in Dry Units MPN or CFU ig) Advance-Ciarmnt Fi Fecal Coliform (Report in Dry Units MPN or GFU fg) Relinquished by: Time .Z,2 am,&r Date !�_j3jff�o Sampled by: Received by: Y " Time a Date 4 11 JZC Transported by: �1 Relinquished by: Time am, pm Date - Holding times met: Received by: Time am, pm Date 1I- . - Compliance work: ✓ti Composite -sampling #1. Time begin am, pm Date ..-1I Non-compliance work: Time end am, pm Date Composite Sampling #2: I_ Lab Comments: Samples Transported On Ice: Time begin am, pm Date Time end am, pm Date I� Initials: fe-A 00 00 N U Ln ro +0 00 N N X O m O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 03/26/2020 Reported: 03/27/2020 For: Tyson Harmony Comments: GM 108,850 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200326-11-01 Fecal Coliforms 1 133333 MPN/g SM92210E-2006 03/26/2020 WC 200326-11-01 Percent Solids 1 3.75 % SM2540B-2011 03/26/2020 WC 200326-11-02 Fecal Coliforms 2 94340 MPN/g SM92210E-2006 03/26/2020 WC 200326-11-02 Percent Solids 2 5.30 % SM2540B-2011 03/26/2020 WC 200326-11-03 Fecal Coliforms 3 95057 MPN/g SM92210E-2006 03/26/2020 WC 200326-11-03 Percent Solids 3 5.26 % SM2540B-2011 03/26/2020 WC 200326-11-04 Fecal Coliforms 4 107991 MPN/g SM92210E-2006 03/26/2020 WC 200326-11-04 Percent Solids 4 4.63 % SM2540B-2011 03/26/2020 WC 200326-11-05 Fecal Coliforms 5 154321 MPN/g SM92210E-2006 03/26/2020 WC 200326-11-05 Percent Solids 5 3.24 % SM2540B-2011 03/26/2020 WC 200326-11-06 Fecal Coliforms 6 102670 MPN/g SM92210E-2006 03/26/2020 WC 200326-11-06 Percent Solids 6 4.87 % SM2540B-2011 03/26/2020 WC 200326-11-07 Fecal Coliforms 7 88496 MPN/g SM92210E-2006 03/26/2020 WC 200326-11-07 Percent Solids 7 5.65 % SM2540B-2011 03/26/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200326-11-01 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200326-11-02 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200326-11-03 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200326-11-04 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200326-11-05 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200326-11-06 Temp on Arrival: 3.2 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200326-11-07 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 uiienx Terra Renewal Address: P.O. Box 399 Dardanefle, AR 72834 GDrdact Person: David Coyle Phone # 479-747-8192 PO # Contact Vanya Colburn for PO (479-264-0467) i e00sh6ned by: Jordan Mathis Cuatomor 8ampre ID* !eh-iD * Tree aer ow [tared ❑rm Dais Sampled (Grab CWy) � Tyson -Harmony Fi `RI -e Tyson -Harmony F2 02 3 _;., f Tyson -Harmony F3 05 Z, �A' 3_.4 Tyson -Harmony F4 04 evor V/ Tyson -Harmony F5 0 'dG - G ✓ Tyson -Harmony F6 UP l Tyson -Harmony F7 (Dq r3 ; 3 a Relinquished by, Received by: Relinquished by: Received by: Composite Sampling #1: Time begin am, pm Date Time end am, pm Date _J_J_ Composite 5air+ ling #2: Time begin_ _-__ am, pm Date — Time end am, pm Date 1__J_ FAX# �Ts�rs'r_urs I r ANALT M AL 122 Coup 9ftm - F-D. Box 228 Slaresvill .K(' 28587 1704) 8724647 Chain of Custody Record PBCY[¢{lCr6 fE1]IIE$(0{I r�C :G3� �Sl3 Fecal Caliform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Ig) F9cal Conform (Report in Dry Units MPN or CFU 1g) Fecal Collform (Report in Dry Units MPN or CFU 1p� Time �ajr pm Date -I�ID Sampled t)y: Time E (An, pm Date 1�_ Transported by 44 Time am, pm Date / / _ Holding times rnet: xi Time am, pm Date T1�� Compliance work: 'fi Lab Comments: Non-compliance work; Samples Transpwrrsd On ice. Initials: r` rn 1-0 v � N O 00 V O a- r` r\ 00 00 N U z Ln N ro 00 N N x 0 m O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 05/14/2020 Reported: 05/15/2020 For: Tyson Harmony Comments: GM <343 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200514-21-01 Fecal Coliforms 1-Harmony <286 MPN/g SM92210E-2006 05/14/2020 WC 200514-21-01 Percent Solids 1-Harmony 5.77 % SM2540B-2011 05/14/2020 WC 200514-21-02 Fecal Coliforms 2-Harmony <278 MPN/g SM92210E-2006 05/14/2020 WC 200514-21-02 Percent Solids 2-Harmony 6.73 % SM2540B-2011 05/14/2020 WC 200514-21-03 Fecal Coliforms 3-Harmony <287 MPN/g SM92210E-2006 05/14/2020 WC 200514-21-03 Percent Solids 3-Harmony 6.07 % SM2540B-2011 05/14/2020 WC 200514-21-04 Fecal Coliforms 4-Harmony <277 MPN/g SM92210E-2006 05/14/2020 WC 200514-21-04 Percent Solids 4-Harmony 5.55 % SM2540B-2011 05/14/2020 WC 200514-21-05 Fecal Coliforms 5-Harmony <263 MPN/g SM92210E-2006 05/14/2020 WC 200514-21-05 Percent Solids 5-Harmony 5.22 % SM2540B-2011 05/14/2020 WC 200514-21-06 Fecal Coliforms 6-Harmony <267 MPN/g SM92210E-2006 05/14/2020 WC 200514-21-06 Percent Solids 6-Harmony 5.80 % SM2540B-2011 05/14/2020 WC 200514-21-07 Fecal Coliforms 7-Harmony <289 MPN/g SM92210E-2006 05/14/2020 WC 200514-21-07 Percent Solids 7-Harmony 6.08 % SM2540B-2011 05/14/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200514-21-01 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-21-02 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-21-03 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-21-04 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-21-05 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-21-06 Temp on Arrival: 3.0 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-21-07 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 Client: Terra Renewal �- T A-r 7 c % I , ; r Add rasa. P.O. BOX 399 A N A L f i li. A L �� -._ -. - 122 CoI>it Street RO. r3ax 228 Dardanelie, AR 72834 swties�al�,xc xs6s� Contact Person: David Coyle 'Pllcrne # FAX# 479.747-8192 (704)872-4697 chain of Custody Retard Po 4 Contact Vanya Colburn for PO (479-264�D467] Requisitioned lay: Jordan Mantis M"'e o�) L�13[ameT "to ID# Lab -ID R u.!l Time Samped Grab OW .JM Dale Sampled (Grab 0*) _ MatTlIS U aW rs+ F�f80 dud uefted f% 5Q w ww Tyson -Harmony F1 .� � , ��. � i" 1ya.-za'9 ✓ ✓ Fecal Coliform (Report in Dry Units MPN or CFU Ig) Tyson -Harmony F2 Fecal Coliform (Report in Dry Units MPN or CFU Ig) Tyson -Harmony F3 Q . 9d �-/� ✓ ✓ Fecal Conform (Report in Dry Units MPN or CFU Ig) Tyson -Harmony F4 f. � J� - ✓ ✓ Fecal Coliform (Report in dry Units MPN or CFU /g) Tyson -Harmony F5 4 ✓ ✓ Fecal Coliform [Report in Dry Units MPN or CFU !g] Tyson -Harmony Ffi 5' )!� ✓ ✓ Fecal Coliform (Repay! in Dry Units MPN or CFU 1g) Tyson -Harmony F7 Fecal Coliform (Report in Dry Units MPN or CFU Ig) Relinquished by: Time ��-! Z 6R. pm Date ,f-)2 1jWJ4 Sampled by: Received by: ll Time . k I&m Date Transported by: Relinquished by: _ Time am, pm Date Holding times met - Received by: - Time am, pm Date Compliance work: Cornposite SanRliSan ligg A#1: Time begin am, pm Date ,�I� Non-compliance work: _ Time end am, pm Date _I-1 Lab Comrnenrs: Samples Teansporled On Ice: Cornto 1 #R;. Time begin am, pm Date .-1I Time end am, pm Dale 1- 1 Initials: n 00 1.0 00 N U z ai N Ln 00 N N X O m O a- Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 09/08/2020 Reported: 09/10/2020 For: Tyson Harmony Comments: GM 127584 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200908-34-01 Fecal Coliforms 1-11 226131 MPN/g SM92210E-2006 09/09/2020 WC 200908-34-01 Percent Solids 1-11 3.98 % SM2540B-2011 09/09/2020 WC 200908-34-02 Fecal Coliforms H2 133333 MPN/g SM92210E-2006 09/09/2020 WC 200908-34-02 Percent Solids H2 3.75 % SM2540B-2011 09/09/2020 WC 200908-34-03 Fecal Coliforms H3 256410 MPN/g SM92210E-2006 09/09/2020 WC 200908-34-03 Percent Solids H3 3.51 % SM2540B-2011 09/09/2020 WC 200908-34-04 Fecal Coliforms H4 122850 MPN/g SM92210E-2006 09/09/2020 WC 200908-34-04 Percent Solids H4 4.07 % SM2540B-2011 09/09/2020 WC 200908-34-05 Fecal Coliforms H5 86806 MPN/g SM92210E-2006 09/09/2020 WC 200908-34-05 Percent Solids H5 5.76 % SM2540B-2011 09/09/2020 WC 200908-34-06 Fecal Coliforms H6 243243 MPN/g SM92210E-2006 09/09/2020 WC 200908-34-06 Percent Solids H6 3.70 % SM2540B-2011 09/09/2020 WC 200908-34-07 Fecal Coliforms H7 274390 MPN/g SM92210E-2006 09/09/2020 WC 200908-34-07 Percent Solids H7 3.28 % SM2540B-2011 09/09/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200908-34-01 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-34-02 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-34-03 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-34-04 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-34-05 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-34-06 Temp on Arrival: 3.0 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-34-07 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 Client: Terra Renewal cZT p T r C ►f l I t IP f' ANALT 111yAL 122 Court Street - P.O. Box 228 Address: P.Q. Box 399 bardanelle, AR i28. 4 S[atcsrlllc, NC 28697 (704) 8724697 .. Chain of Custody Record CorltBct Pm0n: David Coyle Pt1D"B # 479-747-8192 FAX# PO # Contact Vanya Coburn for PO (479-264-0467) Requisitioned by: Jordan Mathis (rPme/,,,, INNA cuslomer sample IDe Lo41Q y Time Sampled iGrah ) Dale Sampled {Gtar,Od�} Wtrix Par metres requested for m-dysia w now Tyson -Harmony Fll f a �-s -.Q. ✓ Fecal Coliform (Report In Dry Units MPN or CFU Jg) Tyson -Harmony F2 �} rr r ' �, `!r -�8 �% ✓ Fecal Coliform (Deport in Cry Units MPNI or CFU /g) Tyson -Harmony F3 a l.? • y p pill, Fecal WHorm (Report in Dry Units MPN or CFU lg) Tyson -Harmony F4 Fecal Coliform (Report in Dry Units MPN or CFU /g) Tyson -Harmony F5 .-3p Q- yen -'�v _ �/ Fecal Conform (Report in Dry Units MPN or CFU fg) Tyson -Harmony FB �,�: 95P // Fecal Coliform {Report in Dry Units MPN or CFU Igy Tyson -Harmony F7 A^1 Fecal Coliform (Report in Dry Units MPN or CFU !g) Relinquished by: 0�'40' �'14}fe'� Time ,Z amL9 Date Sampled by: Received by: C Tirn��12 a/ am Date y l 4 Transported by: Cr Relinquished by: Time am, pm pate Hoiding times met: Received by: Time am, pm Date -Compliance work: -Composite SamPliy #1: Time begin am, pm Date a-1_ Aton-compliance work: Time end am, pm Date _I 1� Lob Cnmrnenls. - Samples TraaSp6ftd On loe: Composite Sampling #2: Time begin am, pm Time end am, pm Date I! I 1nlUals: fe-A 00 00 N U Ln ro 00 N N x 0 m O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 12/10/2020 Reported: 12/11/2020 For: Tyson -Harmony Comments: GEOMETRIC MEAN: 42262 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 201210-13-01 Fecal Coliforms F-1 44910 MPN/g SM92210E-2006 12/10/2020 CJE 201210-13-01 Percent Solids F-1 6.68 % SM2540B-2011 12/10/2020 MD/CE 201210-13-02 Fecal Coliforms F-2 44378 MPN/g SM92210E-2006 12/10/2020 CJE 201210-13-02 Percent Solids F-2 6.76 % SM2540B-2011 12/10/2020 MD/CE 201210-13-03 Fecal Coliforms F-3 44444 MPN/g SM92210E-2006 12/10/2020 CJE 201210-13-03 Percent Solids F-3 6.75 % SM2540B-2011 12/10/2020 MD/CE 201210-13-04 Fecal Coliforms F-4 71736 MPN/g SM92210E-2006 12/10/2020 CJE 201210-13-04 Percent Solids F-4 6.97 % SM2540B-2011 12/10/2020 MD/CE 201210-13-05 Fecal Coliforms F-5 35582 MPN/g SM92210E-2006 12/10/2020 CJE 201210-13-05 Percent Solids F-5 6.94 % SM2540B-2011 12/10/2020 MD/CE 201210-13-06 Fecal Coliforms F-6 33994 MPN/g SM92210E-2006 12/10/2020 CJE 201210-13-06 Percent Solids F-6 7.06 % SM2540B-2011 12/10/2020 MD/CE 201210-13-07 Fecal Coliforms F-7 31331 MPN/g SM92210E-2006 12/10/2020 CJE 201210-13-07 Percent Solids F-7 7.66 % SM2540B-2011 12/10/2020 MD/CE Respectfully submitted, &_W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 2 aleglul - -- !` aie0 urd 'um pua awls alep wd'wa-- —uibeq awll [ uuv3 :-I as W .L Nows sweum qVI f 1 alECi wd 'wa pua awi1 :XJOM aOUelWwo3-UaN ��l ale(I wd 'we uidoq owl_i i =L# ulf weg Woodww f woM 030130uaao �!r elefl wd 'wu awLL I+q panlavaU 1 10LU sawn bulploH �� �� ®lea wd 'wr ow11 :Rq paLISlnbu!la>d :dq pa;)Odsuej_L 1 a7 awa wd 'we awls - - :;[q panlaoa�{ =�4 paldweg � a;ep wd ' °� awl :dq pagslnbujlaa A nio JO Nd6N nun hjp ul podou) wx19oo I$oed 0004 d/-�/ � ��: Ld XuMWuH-UOSA_L (61 n:JD JO NdW suun ► a ul ijode ) mospJ ".A i� /� o/-`�� SS=9d v AUOLUJVH-uos;L� (8r n_Ao io NdW spun ka ul ijodau) wi-op J Ind /� /� �/- �� a/- Y/ vj • S`h 5d Ru4wreH-uWAI (Sr flda jfl NdW S3!un 1[j❑ ul �jodeU) Lwflkloo lsagd trd (uaw_jeH-WgA_L �6r 0=10 10 NdW sim tia ul podeUj uLio)IPO Irmd /1 g-4 RuvwJeH-OOSA {6r NO ja NdW s-un fud u, ijodad) uuw oo }eaad /1 4I - P/ �: � l - Z j AUODUeH-UOGAI A nzio JO NdIN miufl ;Ga ui ljodaa) uuo;ll 0/ er d -:� Gd AUOLweH-uQSA L eisd�eass�paxann��s�aumeasa M . i�1�09�91 peows awo f�W04�J1 Pgdtu9S awi F ❑1•Q�F rplOwes jawgi3no VMWY p �o3ag fpa�tin� a ■mot/ ��: (am o uu) sl a ue ja -- jo Lun ul W P f at4 pauollislnbed �L9�Q ti9Z-BLpi Od 1 410� B;4ueA jDBluo� # Od jo uley;) #](tld ZB G8•L1aL-6Ltr # Ud e1[aj P!ABIJ - .11Mad PMuCO L84t'ZLa (VOL) LMZ ]N `altlns 5 trEBzL 8v `ellswpjad szzxoe'Od - 7 4svno�trl M"'O'd :snippy Uell3 fe-A 00 00 N U Ln ro Ln +o UO 00 N N X O m O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 02/27/2020 Reported: 03/02/2020 For: Wilkesboro TYSON Comments: GM <269 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200227-27-01 Fecal Coliforms F1 <405 MPN/g SM92210E-2006 02/28/2020 WC 200227-27-01 Percent Solids F1 4.94 % SM2540B-2011 02/28/2020 WC 200227-27-02 Fecal Coliforms F2 <246 MPN/g SM92210E-2006 02/28/2020 WC 200227-27-02 Percent Solids F2 8.14 % SM2540B-2011 02/28/2020 WC 200227-27-03 Fecal Coliforms F3 <251 MPN/g SM92210E-2006 02/28/2020 WC 200227-27-03 Percent Solids F3 7.97 % SM2540B-2011 02/28/2020 WC 200227-27-04 Fecal Coliforms F4 <235 MPN/g SM92210E-2006 02/28/2020 WC 200227-27-04 Percent Solids F4 8.52 % SM2540B-2011 02/28/2020 WC 200227-27-05 Fecal Coliforms F5 <260 MPN/g SM92210E-2006 02/28/2020 WC 200227-27-05 Percent Solids F5 7.68 % SM2540B-2011 02/28/2020 WC 200227-27-06 Fecal Coliforms F6 <265 MPN/g SM92210E-2006 02/28/2020 WC 200227-27-06 Percent Solids F6 7.56 % SM2540B-2011 02/28/2020 WC 200227-27-07 Fecal Coliforms F7 <251 MPN/g SM92210E-2006 02/28/2020 WC 200227-27-07 Percent Solids F7 7.96 % SM2540B-2011 02/28/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200227-27-01 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-27-02 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-27-03 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-27-04 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-27-05 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-27-06 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-27-07 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 client: Terra Renewal � ANALT I It.:AL Address: P.a, BOX 399 im Cours Street • P.Q. 8ux 228 Dardanalle, AR 72834 Statesville, NC 2SM7 ` 7 Chain Chain n of Custody Record t�ntaO P"or,: Phone # David Coyle 479-747-8T92 FAX# Po # Contact Vanya Colbum for PO (479-264-0467) Requisitioned by: Jordan Mathis mime -aa,e� � Customer Semple IN LabJp x Trrne-98MP d [(Grab Orly] Date Sampled (Gmb Orly) � hfa[rtx Pareniete s requesud far sndys u y ��, w vM Tyson -Wilkesboro F1 f1 M, ve, -.;z Fecal Cal Norm (Report in Dry Units MPN or CFU lg) Tyson -Wilkesboro F2 % Fecal Coliform (Report in Dry Units MPN or CFU Jg) Tyson -Wilkesboro F3 0 .F„ fb l� �% Fecal Coliform (Report in Dry Units MPN or CFU Ig) Tyson -Wilkesboro F4 j,�: �/ �% Fecal Col'llorm (Report in Dry Units MPN or CFU Ig) Tyson -Wilkesboro F5 05 _ ✓ / Fecal Col•Iform (Report in Dry Units MPN or CFU Ig) Tyson -Wilkesboro F6 a U, � ✓ �/ Fecal Cvliform (Report in Dry Units MPN or CFU Ig) Tyson -Wilkesboro F7 W 1.7; /n -,g 7 Fecal ColMrm (Report in Dry Units MPN or CFU Ig) - Relinquished by: tJar.�!ran ; Time 3.d} am,Date .2, J3�1?e7 Sampled by. i Received by: rl } Time [� am, L Date 12-724) Transported by: Relinquished by: Time am, pm Date J�J� Holding times met: Received by: Time — - — — am, pm Date Compliance work. �( Gannoslte sampling #-I % Time begin am, pm Date Non-compliance work: Time end am, Pm Date ��� Lab Comments: Sarnples Transported On Ica: Composite Sampling #2: Time begin am, pm Date Time end am, pm Date �_ i Initlels: fe-A r\ 00 r9 00 N U z Ln N U0 00 N N x 0 Co O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 04/02/2020 Reported: 04/03/2020 For: Tyson Wilkesboro Comments: GM 1236 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200402-11-01 Fecal Coliforms TW 1 1057 MPN/g SM92210E-2006 04/02/2020 WC 200402-11-01 Percent Solids TW 1 7.57 % SM2540B-2011 04/02/2020 WC 200402-11-02 Fecal Coliforms TW 2 994 MPN/g SM92210E-2006 04/02/2020 WC 200402-11-02 Percent Solids TW 2 8.05 % SM2540B-2011 04/02/2020 WC 200402-11-03 Fecal Coliforms TW 3 1128 MPN/g SM92210E-2006 04/02/2020 WC 200402-11-03 Percent Solids TW 3 7.09 % SM2540B-2011 04/02/2020 WC 200402-11-04 Fecal Coliforms TW 4 1028 MPN/g SM92210E-2006 04/02/2020 WC 200402-11-04 Percent Solids TW 4 7.78 % SM2540B-2011 04/02/2020 WC 200402-11-05 Fecal Coliforms TW 5 2230 MPN/g SM92210E-2006 04/02/2020 WC 200402-11-05 Percent Solids TW 5 5.83 % SM2540B-2011 04/02/2020 WC 200402-11-06 Fecal Coliforms TW 6 1572 MPN/g SM92210E-2006 04/02/2020 WC 200402-11-06 Percent Solids TW 6 8.27 % SM2540B-2011 04/02/2020 WC 200402-11-07 Fecal Coliforms TW 7 1031 MPN/g SM92210E-2006 04/02/2020 WC 200402-11-07 Percent Solids TW 7 7.76 % SM2540B-2011 04/02/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200402-11-01 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200402-11-02 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200402-11-03 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200402-11-04 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200402-11-05 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200402-11-06 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200402-11-07 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 uxenu Terra Renewal Address: P.Q. gpx 399 i7ardanelle, AR 72834 Contact Person: David Coyle PO * Contact Vanya Colbum far PO (479.264-W7) Customer Semple tON fah-1pM ime sample GmbOrkN) Tyson -Wilkesboro F1 i Tyson -Wilkesboro F2 Tyson -Wilkesboro F3 Tpon-Wilkesboro F4 4 ' S Tyson -Wilkesboro F5 rJ .;. za Tyson -Wilkesboro FB Tyson -Wilkesboro FT Q /.I 3'e "One H 479-747-8192 Requisitioned by: Jordan Mathis obra semped bow y I -.fin .✓1 y-.,?--.w STAT£SVI!? t_F ANALYTICAL 12-7 C" svm - P.U. Box 228 Sipcsrillc. NC 28M7 (70 ) V24697 ' Chain of pawl Custody Record r,r�.�„ rid r� erry,ls Fecal Colilorm (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in pry Units MPN or CFU Ig) Fecal Cotiform (Report in dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Jg) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Collform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Igj Relinquished by: , I Time 7j_A5 am, pm Data Received try: Time 1 � 2-5 Relinquished by: Received t)y: ,orwip" a Ssmplif)9 #1' Time begin am, pm Date —1-1— Time end am, pm Com � in Time begin_ am, pm Date ��— Time end am, pm pate Time am, pm Date J Time am, pin Date �« Lob Commenls: Sampled by: (�' Ia .07t' Transported by: k Holding limes met: Compliance work: Non-compliance work: Samples Transported On Ice InWals: rn N O 00 0 C) O d 00 110 00 N U Z ai v N N N x 0 m O a- Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 05/14/2020 Reported: 05/15/2020 For: Tyson Wilkesboro Comments: GM <278 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200514-20-01 Fecal Coliforms 1-Wilkes <347 MPN/g SM92210E-2006 05/14/2020 WC 200514-20-01 Percent Solids 1-Wilkes 7.00 % SM2540B-2011 05/14/2020 WC 200514-20-02 Fecal Coliforms 2- Wilkes <297 MPN/g SM92210E-2006 05/14/2020 WC 200514-20-02 Percent Solids 2- Wilkes 7.19 % SM2540B-2011 05/14/2020 WC 200514-20-03 Fecal Coliforms 3- Wilkes <329 MPN/g SM92210E-2006 05/14/2020 WC 200514-20-03 Percent Solids 3- Wilkes 6.96 % SM2540B-2011 05/14/2020 WC 200514-20-04 Fecal Coliforms 4- Wilkes <360 MPN/g SM92210E-2006 05/14/2020 WC 200514-20-04 Percent Solids 4- Wilkes 7.22 % SM2540B-2011 05/14/2020 WC 200514-20-05 Fecal Coliforms 5- Wilkes <383 MPN/g SM92210E-2006 05/14/2020 WC 200514-20-05 Percent Solids 5- Wilkes 7.61 % SM2540B-2011 05/14/2020 WC 200514-20-06 Fecal Coliforms 6- Wilkes <345 MPN/g SM92210E-2006 05/14/2020 WC 200514-20-06 Percent Solids 6- Wilkes 7.50 % SM2540B-2011 05/14/2020 WC 200514-20-07 Fecal Coliforms 7-Wilkes <329 MPN/g SM92210E-2006 05/14/2020 WC 200514-20-07 Percent Solids 7-Wilkes 6.93 % SM2540B-2011 05/14/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200514-20-01 Temp on Arrival: 5.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-20-02 Temp on Arrival: 5.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-20-03 Temp on Arrival: 5.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-20-04 Temp on Arrival: 5.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-20-05 Temp on Arrival: 5.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-20-06 Temp on Arrival: 5.0 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200514-20-07 Temp on Arrival: 5.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 Client Terra Renewal - r TA V r n LI r I t C Address: P.D. Box 399 �y �■ AN A L'f 1 ILA L 122 Ccxui Streit - P,b, (lox 229 — Dardanelle, AR 72834 u Stawsvdic, NC 29687 r (7N) 872-4697 - tbain of RC°rd Contact Parson Phone q David Coyle 479-747-8192 FA}C1k PO # Contact Vanya Cokburn for PO (479.2154-0467} Requisktioned by: Jordan Mathis w �'�� Date Customer Semple I nN LaIrID it rme Sampled (Grab only) Dale Sampled (Drab only) n �' Matrix Iwge w wI! Pa��ranerers reques7ed for analyera Tyson -Wilkesboro F1 .� $: 5- -Avg a Fecal Coliform (Report in Dry Units MPN or CFU /g) Tyson -Wilkesboro F2 Fecal Caliform (Report in Dry Units MPN or CPU Ig) Tyson -Wilkesboro F3 1 03 5; /e 5 Fecal Coliform (Report in Dry Units MPN or CFU !g) Tyson -Wilkesboro F4 o 4 /f; /,5 .6-10 ✓ ✓ Fecal Coliform (Report in Dry Units MPN or CFU Ig) Tyson -Wilkesboro F5 ;tea $ Feca3 Coliform (Report in Dry Units MPN or CFU Ig) Tyson -Wilkesboro F5 ou t1 Fecal Coliform, (Report in Dry Units WIN or CFU /g) Tyson -Wilkesboro F7 Fecal Coliform (Report in Dry Units MPN or CFU Ig) Relinquished by: Vv/ Time W. pm Date r,-02!�!49 Sampled by: Received by: ��� rime Pm Date - Transported by: ` Relinquished by: Time Mill, Pm Date __J Holding times met: Received by; Time am, pm Data �I 1 Compliance work: Time begin am, pm Date ��_ (Von -compliance work: Time end am, pm Date `J� Lab Comments: Samples Transported On Ice: Com�s��ampling 42#2: _ _ Time begin am, pm Date Time endam, pm Date I� Initials: fe-A r\ 00 00 N U Ln ro U0 00 N N x 0 m O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 09/08/2020 Reported: 09/10/2020 For: TYSON WILKESBORO Comments: GM 125033 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200908-35-01 Fecal Coliforms W1 95420 MPN/g SM92210E-2006 09/09/2020 WC 200908-35-01 Percent Solids W1 5.24 % SM2540B-2011 09/09/2020 WC 200908-35-02 Fecal Coliforms W2 228426 MPN/g SM92210E-2006 09/09/2020 WC 200908-35-02 Percent Solids W2 3.94 % SM2540B-2011 09/09/2020 WC 200908-35-03 Fecal Coliforms W3 129870 MPN/g SM92210E-2006 09/09/2020 WC 200908-35-03 Percent Solids W3 3.85 % SM2540B-2011 09/09/2020 WC 200908-35-04 Fecal Coliforms W4 129534 MPN/g SM92210E-2006 09/09/2020 WC 200908-35-04 Percent Solids W4 3.86 % SM2540B-2011 09/09/2020 WC 200908-35-05 Fecal Coliforms W5 116009 MPN/g SM92210E-2006 09/09/2020 WC 200908-35-05 Percent Solids W5 4.31 % SM2540B-2011 09/09/2020 WC 200908-35-06 Fecal Coliforms W6 100402 MPN/g SM92210E-2006 09/09/2020 WC 200908-35-06 Percent Solids W6 4.98 % SM2540B-2011 09/09/2020 WC 200908-35-07 Fecal Coliforms W7 111857 MPN/g SM92210E-2006 09/09/2020 WC 200908-35-07 Percent Solids W7 4.47 % SM2540B-2011 09/09/2020 WC Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200908-35-01 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-35-02 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-35-03 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-35-04 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-35-05 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-35-06 Temp on Arrival: 3.0 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200908-35-07 Temp on Arrival: 3.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 Client: Terra Renewal Address: P.0. Box 399 Dardanelle, AR 72834 Contact Person: David Coyle PO * Contact Vanya Colbum for PO (479-264-0467) Gu9lomgr Sam*IOr l.ab-Ip Time Same (Grab OW Tyson -Wilkesboro F1 .350 02 Pap Tyson -Wilkesboro F2 Tyson -Wilkesboro F3 0 �y. Tyson -Wilkesboro F4 rid Tyson -Wilkesboro F5 .r3° Tyson -Wilkesboro F6 CU r#5 Tyson -Wilkesboro F7 Q .0' Relinquished by: C1w i�j Deceived by: Relinquished by: Received by: 90MR941 Samptina t'k1: Time begin _ am, pm Date �_ 1 Time end am, pm Date 1 cmPoalte_ Sam tip: . Time begin am, pm Date 1� Time end am, pm Date Phone 4 479-747-8192 FAX* Requisitioned by: Jordan Mathis Date Sompled (0ra6 Only) — surge r l -$ �Aa ✓ ✓ -S�Zr7 � 1r 9- ANALYr 31CAL 122 coon street • PL7. Box 228 S[atesvMe,ttC' 29687 (704)972-4697 Chain of oatel Custody R€ ord °a 8-640.fo Panmcurs Tura wfor asalysk iw Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Conform (Report in Dry Units MPN of CFU Ig) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Fecal Colitorm (Report in Dry Units MPN or CFU fg) Fecal Coliform (Report in Dry Units MPN or CFU Ig) Time 2tL am 49r Date 1 1 v Sampled by: Time lelZ 3 am,mate Ill n Transported by, _SA ss Time am, pm Date �� 1 Holding times mat: Time am, }gym Date Compliance work: jl Non-compiiarrce work: Lab Cornment9: Samples Transported On !cs Initials: r— rn 1-0 v � 00 N O 0 V O a- 00 00 N U Z Ln aj ro +- UO N N x 0 Co O a Analytical Results Terra Renewal PO Box 306 Yadkinville, NC 27055 Receive Date: 11/19/2020 Reported: 11 /20/2020 For: TYSON WILKESBORO Comments: GEOMETRIC MEAN: <258 MPN/g STATESVILLE I, y ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 201119-13-01 Fecal Coliforms W1 <262 MPN/g SM92210E-2006 11/19/2020 MD 201119-13-01 Percent Solids W1 7.62 % SM2540B-2011 11/19/2020 MD 201119-13-02 Fecal Coliforms W2 <261 MPN/g SM92210E-2006 11/19/2020 MD 201119-13-02 Percent Solids W2 7.66 % SM2540B-2011 11/19/2020 MD 201119-13-03 Fecal Coliforms W3 <255 MPN/g SM92210E-2006 11/19/2020 MD 201119-13-03 Percent Solids W3 7.83 % SM2540B-2011 11/19/2020 MD 201119-13-04 Fecal Coliforms W4 <257 MPN/g SM92210E-2006 11/19/2020 MD 201119-13-04 Percent Solids W4 7.78 % SM2540B-2011 11/19/2020 MD 201119-13-05 Fecal Coliforms W5 <255 MPN/g SM92210E-2006 11/19/2020 MD 201119-13-05 Percent Solids W5 7.84 % SM2540B-2011 11/19/2020 MD 201119-13-06 Fecal Coliforms W6 <256 MPN/g SM92210E-2006 11/19/2020 MD 201119-13-06 Percent Solids W6 7.8 % SM2540B-2011 11/19/2020 MD 201119-13-07 Fecal Coliforms W7 <257 MPN/g SM92210E-2006 11/19/2020 MD 201119-13-07 Percent Solids W7 7.79 % SM2540B-2011 11/19/2020 MD Respectfully submitted, &-W9, J'11� -) Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 2 Client: Terra Renewal , C ANAL 1 , 1 L A r, Address: P.O. Box 399 122 Coup Sues► • PO- Flax 228 SUWsvlle, NC 28687 +r (704) 972-46W Dardanelle, AR 72834 Contact Person: David Coyle Phone 479-747-8192 F°x# Chain of Custody Record PO # Contact Vanya Colbum for PO (479.264-0467) Requisitian9d kry Jordan Mathis ""B - ° i CCmtonw Lab-lC N Tim sampledmp {drab on Della Saled ItllBlfilc Rarame�ers rcques�ed for anal Ysls Tyson-Wilkesboro F1 �; �f �� �% Fecal Coliform ( Report in Dry Units MPN or CFU l9) Tyson -Wilkesboro F2 ` $!p� �/- / f �% Fecal Coliform (Report in Dry Units MPN or GFU /g) Tyson -Wilkesboro F3 } g; �e J / �/ Iv Fecal Coliform (Report in Dry Units MPN or CFU !g} Tyson -Wilkesboro F4 $ �� _ / 7 _ / �/ ij V Fecal Coliform (Report in Dry Units MPN or CFU to Fecal Coliform (Report in Dry Units MPN or CFU fg) Fecal Coliform (Report in Dry Units MPN or CFU 1g) Fecal Cetiform (Report in Dry Units MPN or CFU !9) Tyson -Wilkesboro F5 0 �, Tyson -Wilkesboro F6 01j) Tyson -Wilkesboro FT QT '5; 30 Relinquished by: "/.l .. � �� _ rime F om Daite IIIA910P Sampled by:�-'� Received by. Time n m Date Y Transported by- t# Relinquished by. Time _ am, Pm Date Holding times met; �{ Received by: _ Time am, pm Date f- �1_.. Compliance work' C mpositg 5amplina P, - Time begin_-- am, pm Date Non-complianoe work: Time end am, pm Date JJ_ _ Composite Sampling #2: Lab GOf" samples Transported on ice: Time begin am, pm Date 1I Time end am, pm Date _1- J_- Inibal5: fe-A � N N O N 0 O a- r— n 00 00 N U Z ro +� 00 N N x 0 m O a 5 Annual Pathogen & Vector Attraction Reduction Form for NCAC 2T Rules (FORM PVRF 2T) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087 WWTP Name: AdvancePierre Foods - Claremont, NC NPDES Number: N/A Monitoring Period: From l/l/2020 To 3/31/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 230 402 980 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087 WWTP Name: AdvancePierre Foods - Claremont, NC NPDES Number: N/A Monitoring Period: From 4/l/2020 To 6/30/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 338 513 980 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087 WWTP Name: AdvancePierre Foods - Claremont, NC NPDES Number: N/A Monitoring Period: From 7/l/2020 To 9/30/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 361 452 581 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WQ Permit Number: WQ0038087 WWTP Name: AdvancePierre Foods - Claremont, NC NPDES Number: N/A Monitoring Period: From 10/1/2020 To 12/31/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 269 309 349 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) (] No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WWTP Name: River Valley Animal Foods (Tyson) - Harmony, NC Monitoring Period: From l/l/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 3/31/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 88496 108850 154321 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) (] No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle: Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WWTP Name: River Valley Animal Foods (Tyson) - Harmony, NC Monitoring Period: From 4/l/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 6/30/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 263 278 289 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WWTP Name: River Valley Animal Foods (Tyson) - Harmony, NC Monitoring Period: From 7/l/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 9/30/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 86806 177277 274390 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc WWTP Name: River Valley Animal Foods (Tyson) - Harmony, NC Monitoring Period: From 10/1/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 12/31 /2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 31331 42262 71736 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc. WWTP Name: Tyson - Wilkesboro, NC Monitoring Period: From l/l/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 3/31/2021 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 235 269 405 MPN/g 0 4/yr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) 0 No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc. WWTP Name: Tyson - Wilkesboro, NC Monitoring Period: From 4/l/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 6/30/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 994 1236 2230 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc. WWTP Name: Tyson - Wilkesboro, NC Monitoring Period: From 4/l/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 6/30/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 297 340 383 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc. WWTP Name: Tyson - Wilkesboro, NC Monitoring Period: From 7/l/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 9/30/2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 95420 125033 228426 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Terra Renewal Services, Inc. WWTP Name: Tyson - Wilkesboro, NC Monitoring Period: From 10/1/2020 To WQ Permit Number: WQ0038087 NPDES Number: N/A 12/31 /2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ I Alt B (Alk Treatment)❑ Alt. C (Prior Testing)[] A1t.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray 01 Cramma Ray ❑ Pasteurization El Class B: jAlt. (1) Fecal Density r❑ Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ I Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g l3' Number o Excee- dences Frequency ofAnalysis Sample Type na ytica Tech - ni ue Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN 255 258 262 MPN/g 0 1/Qtr Grab 92210E CFU 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ 1Alt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) &I No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) LI "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." David C. Coyle; Enviro. Manager Preparer Name and Title (type or print) 2/25/2021 Land Applier Name and Title (if applicable)(type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM PVRF 02T (12/2006) 6 Soil Test Reports (for fields applied in 2020) Soil Analysis Report - NCDA Index Waters Agricultural Laboratories, Inc 364 W. Park Drive I Warsaw, NC 28398- 1 Phone (910) 293-2108 "I ■YLp rov ice►ug Crovtjv . . wU;Vsa&nCe Denali Water Solutions [200581 Grower: NC RLAP WQ0038087 Page 1 Farm: MATHIS PO BOX 399 LID: Target pH: 6.5 Dardanelle, AR 72834- Test Method: Mehlich III Received: 12/11/2020 Processed: 12/15/2020 M P-1 K-1 Mg (%) Ca (%) pHw Ac S-1 Zn-1 Zn-AI Mn-1 Mn-AI Cu-1 Na ESP CEC BS (%) HIM (%) Soil Class 73CH 7 8668770W 215 48 16 74 6.1 0.6 54 1022 1022 291 192 352 0.1 1 7.9 92 0.35 Min 8668780W 153 26 18 77 6.7 0.2 53 508 508 178 113 428 0.1 2 6.2 97 0.37 Min 8668790W 93 49 22 71 6.3 0.2 84 494 494 206 141 200 0.1 2 6.1 97 0.33 Min DM 5 866880OW 61 26 20 54 5.8 1.0 48 292 292 156 111 118 0.1 2 4.4 77 0.40 Min DM 6 866881OW 102 31 23 64 6.3 0.4 22 332 332 134 97 135 0.1 2 4.1 90 0.34 Min DM 7 8668820W 92 27 21 61 6.4 0.6 23 281 281 128 94 125 0.1 2 4.1 85 0.44 Min DM 8 8668830W 167 29 20 68 5.8 0.4 27 546 546 106 81 260 0.1 2 4.5 91 0.60 Min MF 9 8668840W 433 38 21 66 6.4 0.8 45 854 854 134 97 878 0.1 1 7.5 89 0.43 Min MF 10 8668850W 460 39 17 64 5.8 1.2 58 862 862 156 111 838 0.1 1 7.2 83 0.66 Min MF 11 8668860W 433 58 21 66 6.4 0.8 75 1139 1139 128 94 805 0.2 3 8.3 90 0.58 Min Explanation of Symbols - % (percent), -1 (Index); Sodium (Na) and CEC reported in meq/100cm3 (milli -equivalent per 100 cubic centimeters) Abbreviations: Ac (Acidity), CEC (Cation Exchange Capacity), BS (Base Saturation), HIM (Humic Matter), ESP (Exchangeable Sodium Percentage) NCDA Soil Fertility Recommendations (Ibs/A) Lime Tons/Acre N Nitrogen P205 Phosphate K20 Potash Mg Magnesium s Sulfur B Boron Zn Zinc Mn Manganese Cu Copper See Note CH 1 CORN SILAGE 0.5 220 100 3 CH 3 CORN SILAGE 220 150 3 CH 4 CORN SILAGE 0.3 220 100 3 DM 5 CORN SILAGE 0.9 220 30 150 3 DM 6 CORN SILAGE 0.3 220 140 20 3 DM 7 CORN SILAGE 0.3 220 150 20 3 DM 8 CORN SILAGE 0.4 220 140 3 MF 9 CORN SILAGE 0.4 220 120 3 MF 10 CORN SILAGE 1.1 220 120 3 MF 11 CORN SILAGE 0.4 220 80 3 Explanation of Symbols - Ibs/A (pounds per acre) Fertilizer recommendations are based on the philosophy and recommendations of the NCDA Agronomic Division DWQ Laboratory Certification Number 635 This document may be reproduced only in its entirety. Waters Agricutural Laboratories has no control over the manner in which samples are taken, therefore, analysis is based solely on the sample as received. Laboratory liability is limited to the fee assessed on the referenced sample. Soil Analysis Report - NCDA Index Waters Agricultural Laboratories, Inc 364 W. Park Drive I Warsaw, NC 28398- 1 Phone (910) 293-2108 "I ■YLp rov ice►ug Crovtjv . . wU;Vsa&nCe Denali Water Solutions [200581 Grower: NC RLAP WQ0038087 Page 2 Farm: MATHIS PO BOX 399 LID: Target pH: 6.5 Dardanelle, AR 72834- Test Method: Mehlich III Received: 12/11/2020 Processed: 12/15/2020 M P-1 K-1 Mg (%) Ca (%) pHw Ac S-1 Zn-1 Zn-AI Mn-1 Mn-AI Cu-1 Na ESP CEC BS (%) HIM (%) Soil Class 7MF 7 8668870W 280 48 14 74 5.8 0.4 49 700 700 159 112 702 0.1 2 5.1 92 0.50 Min 8668880W 98 45 15 54 5.9 1.4 59 412 412 59 52 288 0.1 2 5.2 73 0.54 Min 8668890W 256 26 16 80 6.6 0.2 38 469 469 97 66 572 0.1 1 6.7 97 0.74 Min MF 23A 866890OW 147 39 21 64 6.3 0.8 44 720 720 66 57 285 0.1 2 6.7 88 0.52 Min MF 23B 866891OW 72 19 28 64 6.0 0.2 89 292 292 38 40 242 0.1 2 3.5 94 0.95 Min MRF 3 8668920W 236 38 16 75 6.6 0.6 45 368 368 269 169 590 0.1 1 8.5 93 0.57 Min MRF 5 8668930W 267 49 22 67 6.2 0.6 55 408 408 441 282 548 0.1 2 7.7 92 0.48 Min MRF 6 8668940W 503 85 16 75 6.7 0.6 36 832 832 153 98 950 0.2 1 11.3 95 0.62 Min MRF 12 8668950W 398 43 21 74 6.5 0.2 45 708 708 203 131 675 0.1 2 7.3 97 0.43 Min YF 1 866896OW 310 41 21 74 7.1 0.2 35 476 476 109 66 730 0.1 1 8.0 98 0.16 Min Explanation of Symbols - % (percent), -1 (Index); Sodium (Na) and CEC reported in meq/100cm3 (milli -equivalent per 100 cubic centimeters) Abbreviations: Ac (Acidity), CEC (Cation Exchange Capacity), BS (Base Saturation), HIM (Humic Matter), ESP (Exchangeable Sodium Percentage) NCDA Soil Fertility Recommendations (Ibs/A) Lime Tons/Acre N Nitrogen P205 Phosphate K20 Potash Mg Magnesium s Sulfur B Boron Zn Zinc Mn Manganese Cu Copper See Note MF 13 CORN SILAGE 0.4 220 100 3 MF 14 CORN SILAGE 1.2 220 110 3 MF 15 CORN SILAGE 220 150 3 MF 23A CORN SILAGE 0.5 220 120 3 MF 23B CORN SILAGE 0.3 220 20 160 3 MRF 3 CORN SILAGE 220 120 3 MRF 5 CORN SILAGE 0.5 220 100 3 MRF 6 CORN SILAGE 220 40 3 MRF 12 CORN SILAGE 220 110 3 YF 1 CORN SILAGE 220 120 3 Explanation of Symbols - Ibs/A (pounds per acre) Fertilizer recommendations are based on the philosophy and recommendations of the NCDA Agronomic Division DWQ Laboratory Certification Number 635 This document may be reproduced only in its entirety. Waters Agricutural Laboratories has no control over the manner in which samples are taken, therefore, analysis is based solely on the sample as received. Laboratory liability is limited to the fee assessed on the referenced sample. Soil Analysis Report - NCDA Index Waters Agricultural Laboratories, Inc 364 W. Park Drive I Warsaw, NC 28398- 1 Phone (910) 293-2108 "I ■YLp rov ice►ug Crovtjv . . wU;Vsa&nCe Denali Water Solutions [200581 Grower: NC RLAP WQ0038087 Page 3 Farm: MATHIS PO BOX 399 LID: Target pH: 6.5 Dardanelle, AR 72834- Test Method: Mehlich III Received: 12/11/2020 Processed: 12/15/2020 M P-1 K-1 Mg (%) Ca (%) pHw Ac S-1 Zn-1 Zn-AI Mn-1 Mn-AI Cu-1 Na ESP CEC BS (%) HIM (%) Soil Class 75AYF 7 866897OW 215 33 21 74 6.9 0.2 34 568 568 122 77 600 0.1 1 7.5 97 0.34 Min 8668980W 96 43 21 68 6.8 0.4 32 214 214 106 68 375 0.1 2 5.7 93 0.35 Min 8668990W 293 41 17 78 6.8 0.2 26 652 652 169 106 525 0.1 1 8.2 98 0.26 Min YF 5B 8669000W 257 42 15 73 6.5 0.8 26 419 419 216 139 430 0.1 1 8.0 90 0.38 Min YF7 866901OW 420 39 11 85 6.9 0.2 29 711 711 147 92 470 0.1 1 9.8 98 0.22 Min Explanation of Symbols - % (percent), -1 (Index); Sodium (Na) and CEC reported in meq/100cm3 (milli -equivalent per 100 cubic centimeters) Abbreviations: Ac (Acidity), CEC (Cation Exchange Capacity), BS (Base Saturation), HIM (Humic Matter), ESP (Exchangeable Sodium Percentage) NCDA Soil Fertility Recommendations (Ibs/A) Lime Tons/Acre N Nitrogen P205 Phosphate K20 Potash Mg Magnesium s Sulfur B Boron Zn Zinc Mn Manganese Cu Copper See Note YF 3 CORN SILAGE 220 130 3 YF 4 CORN SILAGE 220 110 3 YF 5A CORN SILAGE 220 120 3 YF 5B CORN SILAGE 220 120 3 YF7 CORN SILAGE 220 120 3 Explanation of Symbols - Ibs/A (pounds per acre) Fertilizer recommendations are based on the philosophy and recommendations of the NCDA Agronomic Division DWQ Laboratory Certification Number 635 This document may be reproduced only in its entirety. Waters Agricutural Laboratories has no control over the manner in which samples are taken, therefore, analysis is based solely on the sample as received. Laboratory liability is limited to the fee assessed on the referenced sample. WAT RS ICL�LRAL k,AOR IES,�HC. 1 Soil Analysis Report Waters Agricultural Laboratories, Inc 364 W. Park Drive I Warsaw, NC 28398- 1 Phone (910) 293-2108 f(jMPrM4Gr0V&.. M Ste' Denali Water Solutions [200581 Grower: NC RLAP WQ0038087 Page 1 Farm/Field: MATHIS PO BOX 399 LID: Target pH: 6.5 Dardanelle, AR 72834- Test Method: Mehlich III Received: 12/11/2020 Processed: 12/15/2020 JL Ibs/A Ibs/A Ibs/A Ibs/A Soil Buffer Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A % Ibs/A meq K Mg Ca H Na CH 1 8668770W 516 VH 186 M 296 H 2330 VH 6.1 7.85 52 A 1.6 A 81.8 VH 93 A 366 H 14.1 VH 51 0.35 8.6 2.8 14.3 67.7 13.9 1.3 CH 3 8668780W 368 VH 101 L 270 H 1889 VH 6.7 7.95 51 A 1.6 A 40.6 VH 57 M 375 H 17.1 VH 51 0.37 6.5 2.0 17.3 72.8 62 1.7 CH 4 866879OW 224 VH 191 M 314 VH 1727 H 6.3 7.95 81 H 1.5 A 39.5 VH 66 A 341 H 8.0 H 55 0.33 6.4 3.8 20.5 67.6 6.3 1.9 DM 5 866880OW 146 A 100 L 215 A 955 M 5.8 7.75 46 M 0.5 L 23.4 VH 50 M 245 H 4.7 A 47 0.40 5.5 2.3 162 43.3 36.3 1.9 DM 6 866881 OW 244 VH 121 L 223 A 1037 A 6.3 7.90 21 L 0.7 L 26.6 VH 43 M 255 H 5.4 A 32 0.34 4.5 3.4 20.4 57.0 17.6 1.5 DM 7 8668820W 221 VH 106 L 212 A 1009 A 6.4 7.85 22 L 0.6 L 22.5 VH 41 M 288 H 5.0 A 36 0.44 4.8 2.8 18.3 52.3 24.9 1.6 DM 8 8668830W 401 VH 112 L 210 A 1217 A 5.8 7.90 26 M 0.6 L 43.7 VH 34 M 293 H 10.4 H 38 0.60 4.9 2.9 17.7 61.5 162 1.7 MF 9 8668840W 1039 VH 149 M 380 VH 1952 VH 6.4 7.80 43 M 12 M 68.3 VH 43 M 452 VH 35.1 VH 46 0.43 8.4 2.3 19.0 58.4 192 12 MF 10 8668850W 1103 VH 152 M 300 VH 1839 VH 5.8 7.70 56 A 1.3 M 69.0 VH 50 M 495 VH 33.5 VH 45 0.66 8.5 2.3 14.6 53.8 28.1 1.1 MF 11 8668860W 1040 VH 225 A 411 VH 2185 VH 6.4 7.80 72 A 1.5 A 91.1 VH 41 M 338 H 322 VH 96 0.58 9.3 3.1 18.5 58.9 17.3 2.3 Report values represent available plant nutrients in the soil. Rating Codes: L (Low), M (Medium), A (Adequate), H (High), VH (Very High) Abbreviations: ENR (Estimated Nitrogen Release), C.E.C. (Cation Exchange Capacity), OM (Organic Matter) Soil Fertility Recommendations (Ibs/A) Sampi .p me Gypsum N I Mn Fe ,in "or Tons/Acre Nitrogen '. I Potash Magnesium Manganese Iron "ospq mg i_ or CH 1 CORN SILAGE 20TONS 0.5 160 100 5 CH 3 CORN SILAGE 20TONS 160 185 5 CH 4 CORN SILAGE 20TONS 0.3 160 100 5 DM 5 CORN SILAGE 20TONS 0.9 160 40 185 5 0.7 DM 6 CORN SILAGE 20TONS 0.3 160 165 24 0.5 DM 7 CORN SILAGE 20TONS 0.3 160 180 23 0.6 DM 8 CORN SILAGE 20TONS 0.9 160 175 19 0.6 1 MF 9 CORN SILAGE 20TONS 0.3 160 140 5 MF 10 CORN SILAGE 20TONS 0.9 160 135 5 MF 11 CORN SILAGE 20TONS 0.3 160 100 5 Explanation of Symbols - * (maintenance), % (percent), ppm (parts per million), Ibs/A (pounds per acre), Ibs/1000 sq. ft. (pounds per 1000 square feet), mmhos/cm (milli -mhos per centimeter), meq (meq/100g: milli -equivalent per 100 grams) Comments: 15 LBS OF NITROGEN AND 50 LBS OF PHOSPHATE RECOMMENDED AS A STARTER ON ALL CORN. FERTILIZER APPLIED AS A STARTER, SHOULD BE DEDUCTED FROM ABOVE. BE SURE THAT SULFUR IS APPLIED IN ORDER THAT NITROGEN -SULFUR RATIO IS MAINTAINED. A PORTION OF THE NIRTOGEN AND POTASSIUM SHOULD BE APPLIED THROUGH THE IRRIGATION SYSTEM IF AVAILABLE, BEGINNING PRIOR TO TASSEL. 25% OF POTASSIUM SHOULD BE APPLIED IN SPLIT APPLICATIONS OF NO MORE THAN 20 LBS OF EACH. This document may be reproduced only in its entirety. Waters Agricutuml Laboratories has no control over the manner in which samples are taken, therefore, analysis is based solely on the sample as received. Laboratory liability is limited to the fee assessed on the referenced sample. WAT RS ICL�LRAL k,AOR IES,�HC. 1 Soil Analysis Report Waters Agricultural Laboratories, Inc 364 W. Park Drive I Warsaw, INC 28398- 1 Phone (910) 293-2108 f(jMPrM4Gr0V&.. M Ste' Denali Water Solutions [200581 Grower: NC RLAP WQ0038087 Page 2 Farm/Field: MATHIS PO BOX 399 LID: Target pH: 6.5 Dardanelle, AR 72834- Test Method: Mehlich III Received: 12/11/2020 Processed: 12/15/2020 Ibs/A Ibs/A Ibs/A Ibs/A Soil Buffer Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A % Ibs/A meq K Mg Na Ca H MF 13 8668870W 672 VH 187 M 171 A 1507 H 5.8 7.90 47 M 0.9 L 56.0 VH 51 M 278 H 28.1 VH 39 0.50 5.6 4.3 12.7 672 14.3 1.5 MF 14 8668880W 236 VH 176 M 185 A 1131 A 5.9 7.65 57 A 0.8 L 33.0 VH 19 L 153 A 11.5 H 52 0.54 6.7 3.3 11.4 42.0 41.6 1.7 MF 15 866889OW 614 VH 100 L 247 A 2116 VH 6.6 7.95 36 M 1.3 M 37.5 VH 31 M 309 H 22.9 VH 41 0.74 6.9 1.8 14.8 76.3 5.8 1.3 MF 23A 866890OW 352 VH 152 M 342 VH 1721 H 6.3 7.80 42 M 0.8 L 57.6 VH 21 L 445 VH 11.4 H 48 0.52 7.6 2.6 18.7 56.4 21.0 1.4 MF 23B 866891 OW 173 H 76 L 235 A 887 M 6.0 7.95 85 H 0.7 L 23.4 VH 12 L 201 H 9.7 H 37 0.95 3.8 2.6 25.9 58.7 10.6 2.1 MRF 3 866892OW 566 VH 148 M 329 VH 2553 VH 6.6 7.85 43 M 1.1 M 29.4 VH 86 A 309 H 23.6 VH 51 0.57 9.3 2.1 14.8 69.0 13.0 12 MRF 5 866893OW 641 VH 190 M 397 VH 2O64 VH 62 7.85 53 A 0.9 L 32.6 VH 141 A 302 H 21.9 VH 54 0.48 8.4 2.9 19.8 61.6 14.3 1.4 MRF 6 866894OW 1207 VH 331 H 427 VH 3382 VH 6.7 7.85 35 M 1.4 M 66.6 VH 49 M 383 H 38.0 VH 69 0.62 12.0 3.5 14.8 70.4 10.0 12 MRF 12 866895OW 956 VH 167 M 365 VH 2164 VH 6.5 7.95 43 M 1.0 M 56.6 VH 65 A 448 VH 27.0 VH 54 0.43 7.7 2.8 19.8 70.6 52 1.5 YF 1 866896OW 743 VH 159 M 411 VH 2354 VH 7.1 7.95 34 M 1.6 A 38.1 VH 35 M 295 H 292 VH 44 0.16 8.3 2.5 20.6 70.9 4.8 12 Report values represent available plant nutrients in the soil. Rating Codes: L (Low), M (Medium), A (Adequate), H (High), VH (Very High) Abbreviations: ENR (Estimated Nitrogen Release), C.E.C. (Cation Exchange Capacity), OM (Organic Matter) Soil Fertility Recommendations (Ibs/A) Sampi .p me Gypsum N I Mn Fe "or Tons/Acre Nitrogen '. I Potash Magnesium Manganese Iron "ospq mg i_ i gr MF 13 CORN SILAGE 20TONS 0.9 160 100 5 0.3 MF 14 CORN SILAGE 20TONS 0.9 160 110 5 0.4 10 MF 15 CORN SILAGE 20TONS 160 185 9 4 MF 23A CORN SILAGE 20TONS 0.3 160 135 5 0.4 10 MF 23B CORN SILAGE 20TONS 0.6 160 * 40 210 5 0.5 10 MRF 3 CORN SILAGE 20TONS 160 140 5 0.1 MRF 5 CORN SILAGE 20TONS 0.4 160 100 5 0.3 MRF 6 CORN SILAGE 20TONS 160 80 10 MRF 12 CORN SILAGE 20TONS 160 120 5 02 YF 1 CORN SILAGE 20TONS 160 130 11 Explanation of Symbols - * (maintenance), % (percent), ppm (parts per million), Ibs/A (pounds per acre), Ibs/1000 sq. ft. (pounds per 1000 square feet), mmhos/cm (milli -mhos per centimeter), meq (meq/100g: milli -equivalent per 100 grams) Comments: 15 LBS OF NITROGEN AND 50 LBS OF PHOSPHATE RECOMMENDED AS A STARTER ON ALL CORN. FERTILIZER APPLIED AS A STARTER, SHOULD BE DEDUCTED FROM ABOVE. BE SURE THAT SULFUR IS APPLIED IN ORDER THAT NITROGEN -SULFUR RATIO IS MAINTAINED. A PORTION OF THE NIRTOGEN AND POTASSIUM SHOULD BE APPLIED THROUGH THE IRRIGATION SYSTEM IF AVAILABLE, BEGINNING PRIOR TO TASSEL. 25% OF POTASSIUM SHOULD BE APPLIED IN SPLIT APPLICATIONS OF NO MORE THAN 20 LBS OF EACH. This document may be reproduced only in its entirety. Waters Agricutuml Laboratories has no control over the manner in which samples are taken, therefore, analysis is based solely on the sample as received. Laboratory liability is limited to the fee assessed on the referenced sample. WAT RS ICL�LRAL k,AOR IES,�HC. 1 Soil Analysis Report Waters Agricultural Laboratories, Inc 364 W. Park Drive I Warsaw, INC 28398- 1 Phone (910) 293-2108 f(jMPrM4Gr0V&.. M Ste' Denali Water Solutions [200581 Grower: NC RLAP WQ0038087 Page 3 Farm/Field: MATHIS PO BOX 399 LID: Target pH: 6.5 Dardanelle, AR 72834- Test Method: Mehlich III Received: 12/11/2020 Processed: 12/15/2020 JL Ibs/A Ibs/A Ibs/A Ibs/A Soil Buffer Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A Ibs/A % Ibs/A meq K Mg Ca H Na YF 3 866897OW 516 VH 129 M 383 VH 2229 VH 6.9 7.95 33 M 1.7 A 45.4 VH 39 M 252 H 24.0 VH 44 0.34 7.8 2.1 20.4 712 5.1 12 YF 4 866898OW 231 VH 170 M 293 H 1542 H 6.8 7.90 31 M 1.3 M 17.1 VH 34 M 194 A 15.0 VH 42 0.35 62 3.5 19.7 62.3 12.9 1.5 YF 5A 866899OW 704 VH 159 M 334 VH 2577 VH 6.8 7.95 25 M 1.3 M 522 VH 54 M 189 A 21.0 VH 45 026 8.5 2.4 16.3 75.5 4.7 1.1 YF 5B 8669000W 616 VH 163 M 285 H 2320 VH 6.5 7.80 25 M 1.1 M 33.5 VH 69 A 239 H 172 VH 46 0.38 8.9 2.3 13.3 652 18.0 1.1 YF7 866901OW 1008 VH 152 M 248 A 3328 VH 6.9 7.95 28 M 1.5 A 56.9 VH 47 M 241 H 18.8 VH 49 022 10.1 1.9 10.3 82.7 4.0 1.1 Report values represent available plant nutrients in the soil. Rating Codes: L (Low), M (Medium), A (Adequate), H (High), VH (Very High) Abbreviations: ENR (Estimated Nitrogen Release), C.E.C. (Cation Exchange Capacity), OM (Organic Matter) Soil Fertility Recommendations• Crop e me Gypsum N IK Mg Mn Fe Sampl,in "w Tons/Acre Nitrogen "ospha Potash Magnesium a ur Zinc Manganese Iron ---------- ---------- Explanation of Symbols -' (maintenance), % (percent), ppm (parts per million), Ibs/A (pounds per acre), Ibs/1000 sq. ft. (pounds per 1000 square feet), mmhos/cm (milli -mhos per centimeter), meq (meq/100g: milli -equivalent per 100 grams) Comments: 15 LBS OF NITROGEN AND 50 LBS OF PHOSPHATE RECOMMENDED AS A STARTER ON ALL CORN. FERTILIZER APPLIED AS A STARTER, SHOULD BE DEDUCTED FROM ABOVE. BE SURE THAT SULFUR IS APPLIED IN ORDER THAT NITROGEN -SULFUR RATIO IS MAINTAINED. A PORTION OF THE NIRTOGEN AND POTASSIUM SHOULD BE APPLIED THROUGH THE IRRIGATION SYSTEM IF AVAILABLE, BEGINNING PRIOR TO TASSEL. 25% OF POTASSIUM SHOULD BE APPLIED IN SPLIT APPLICATIONS OF NO MORE THAN 20 LBS OF EACH. This document may be reproduced only in its entirety. Waters Agricutuml Laboratories has no control over the manner in which samples are taken, therefore, analysis is based solely on the sample as received. Laboratory liability is limited to the fee assessed on the referenced sample. 7 COMPLIMENTARY DATA: Executive Summary Fecal Analysis Summary Soil Result (pH) Summary Poultry Litter Analysis Summary Poultry Litter Analyses Executive Summary Annual Report -2020 Permit No. WQ0038087 Permittee: Terra Renewal Services, Inc 1W A-W s Ink TERRA renewal Dry Tons ADDlied Der Source Field ID Permitted Acres Utilized Acres Application Period (Months) Crop RYE PAN (lb/ac) Adjusted 2020PAN (lb/ac) PAN Applied Residuals (lb/ac) PAN Applied Supplement* (lb/ac) Total PAN Applied (lb/ac) AdvPierre Claremont (DT/Field) RVAF Harmony (DT/Field) Tyson Wilkesboro (DT/Field) Annual Dry Tons Applied (DT/Field) NC-WK-CH-01 21.8 21.8 Jul Corn Silage 179 141 105 33.4 138 1.7 13.8 17.8 33.3 NC-WK-CH-03 41.6 41.6 Jul -Aug Corn Silage 285 225 135 33.4 168 31.9 46.6 78.4 NC-WK-CH-04 35.8 35.8 Jul Corn Silage 270 213 146 33.4 179 1.6 26.9 47.3 75.9 NC-YK-DM-05 21.0 21.0 Jun Oct -Nov Corn Silage Sm Grains 246 120 204 50 53 34 33.4 86 34 12.6 10.1 16.5 29.4 68.6 NC-YK-DM-06 25.6 25.6 May -Jun Oct -Nov Corn Silage Sm Grains 246 120 200 50 93 49 33.4 126 49 1.1 25.2 20.3 37.6 31.5 115.7 NC-WK-YK-DM-07 31.5 31.5 May Corn Silage Sm Grains 246 120 196 50 94 50 33.4 127 50 1.1 0.6 23.1 24.8 55.3 44.1 149.0 NC-WK-YK-DM-08 24.6 24.6 Apr -May Nov Corn Silage Sm Grains 231 112 189 50 121 49 33.4 154 49 1.1 0.6 18.9 20.3 60.0 25.2 126.1 NC-WK-MF-09 13.2 13.2 Mar Aug Corn Silage Sm Grains 214 98 190 50 70 49 33.4 103 49 1.1 5.3 3.1 11.8 6.2 27.4 NC-WK-MF-10 14.1 14.1 Mar Aug -Sep Corn Silage Sm Grains 214 98 179 50 57 49 33.4 90 49 4.2 2.5 10.6 7.8 25.0 NC-WK-MF-11 16.8 16.8 Mar Sep Corn Silage Sm Grains 174 80 146 50 37 46 33.4 70 46 3.2 1.9 8.2 10.1 23.3 NC-WK-MF-13 33.8 33.8 Mar Sep Corn Silage Sm Grains 214 98 178 50 17 49 33.4 50 49 0.6 5.2 5.6 5.9 19.4 36.7 NC-WK-MF-14 21.9 21.9 Mar Sep Corn Silage Sm Grains 174 80 148 50 17 46 33.4 50 46 2.1 5.0 4.7 9.3 21.1 NC-WK-MF-15 13.6 13.6 Aug Sm Grains 80 80 48 48 3.8 5.4 9.2 NC-WK-MF-23A 23.8 23.8 Mar Aug Corn Silage Sm Grains 214 98 165 50 24 48 33.4 57 48 5.3 5.6 5.9 10.9 27.6 NC-WK-MF-23B 21.2 21.2 Aug Sm Grains 98 98 48 48 1.7 6.3 7.8 15.7 NC-WK-MRF-03 19.6 19.6 Jun Dec Corn Silage Corn Silage 179 179 144 143 111 132 33.4 144 132 11.3 23.5 19.4 26.4 80.5 NC-WK-MRF-05 25.3 25.3 Dec Corn Silage 212 199 87 87 42.3 15.5 57.8 NC-WK-MRF-06 24.9 24.9 Jun Dec Corn Silage Corn Silage 212 212 160 180 33 67 33.4 66 67 4.4 44.7 7.0 7.7 63.8 NC-WK-MRF-12 25.1 25.1 Jun Dec Corn Silage Corn Silage 219 219 190 187 121 106 33.4 154 106 1.4 18.1 49.4 24.0 18.6 111.5 NC-YK-YF-01 14.4 14.4 Oct Sm Grains 98 98 60 60 0.6 11.3 42.0 53.9 NC-YK-YF-03 22.4 22.4 Sep -Oct Sm Grains 120 120 46 46 0.6 13.5 48.3 62.4 NC-YK-YF-04 23.3 23.2 Oct Sm Grains 120 120 9 9 2.3 14.7 16.9 NC-YK-YF-SA 27.1 27.1 Oct Sm Grains 120 120 24 24 7.9 35.7 43.6 NC-WK-YF-SB 20.5 20.5 Sep -Oct Sm Grains 80 80 52 52 14.6 48.3 63.0 NC-WK-YF-07 10.3 10.3 Sep Sm Grains 98 98 54 54 7.9 23.1 31.0 TOTALS: 573 14 538 866 1,417 *Supplement= Broiler Litter @ 16.7 lb PAN/ton Fecal Analysis Summary - 2020 Permit No: WQ0038087 Permittee: Terra Renewal Services, Inc AW a TERRA renewal Facility: AdvancePierre Foods - Claremont Result (MPN/gram) Sample Date 1 2 3 4 5 6 7 Geo Mean 3/26/2020 407 463 303 319 980 230 410 402 5/20/2020 673 676 980 398 396 338 394 513 9/17/2020 361 428 394 515 372 581 571 452 12/3/2020 295 346 349 290 303 269 318 309 Facility: RVAF (Tyson) - Harmony Result (MPN/gram) Sample Date 1 2 3 4 5 6 7 Geo Mean 3/26/2020 133,333 94,340 95,057 107,991 154,321 102,670 88,496 108,850 5/14/2020 286 278 287 277 263 267 289 278 9/8/2020 226,131 133,333 256,410 122,850 86,806 243,243 274,390 177,277 12/10/2020 44,910 44,378 44,444 71,736 35,582 33,994 31,331 42,262 Facility: Tyson - Wilkesboro Result (MPN/gram) Sample Date 1 2 3 4 5 6 7 Geo Mean 2/27/2020 405 246 251 235 260 265 251 269 4/2/2020 1,057 994 1,128 1,028 2,230 1,572 1,031 1,236 5/14/2020 347 297 329 360 383 345 329 340 9/8/2020 95,420 228,426 129,870 129,534 116,009 100,402 111,857 125,033 11/19/2020 262 261 255 257 255 256 257 258 2020 Soil Result (PH) Summary Permit #: WQ0038087 Permittee: Terra Renewal Services Soil Test Result Field # pH 2O17 pH 2O18 pH 2O19 pH 2O20 CH-1 5.9 5.7 6.5 6.1 CH-3 6.6 7.1 7.2 6.7 CH-4 5.1 7.0 6.9 6.3 DM-5 6.2 6.7 6.3 5.8 DM-6 6.3 5.9 6.3 6.3 DM-7 5.6 7.1 6.2 6.4 DM-8 6.5 5.8 5.7 5.8 M F-9 6.2 6.4 6.1 6.4 M F-10 5.9 6.0 5.6 5.8 M F-1 1 6.3 6.4 6.9 6.4 M F-13 6.3 6.3 6.1 5.8 M F-14 6.6 6.6 6.2 5.9 MF-15 6.3 6.2 6.7 6.6 MF-23A 6.2 5.8 6.1 6.3 MF-23B 6.2 6.1 6.1 6.0 M RF-3 6.9 6.4 6.4 6.6 M RF-5 6.5 6.0 6.4 6.2 M RF-6 6.2 6.9 6.5 6.7 MRF-12 6.3 6.9 6.3 6.5 YF-1 6.7 7.2 6.5 7.1 YF-3 6.6 6.8 6.8 6.9 YF-4 6.5 6.6 6.4 6.8 YF-5 A 6.6 7.5 6.6 6.8 YF-5 B 6.6 6.3 6.8 6.5 YF-7 6.8 6.9 6.7 6.9 Poultry Litter Analysis Summary - 2020 Source: ASJ Mathis Farms Sample ID Total N (ppm) Dry Matter N PAN (lb/ton) MF-1 32,200 74.1 23.9 MF-2 29,600 31.2 9.2 M F-3 29,200 48.4 14.1 MF-4 26,600 79.1 21.0 MF-5 18,600 41.2 7.7 MF-6 34,900 82.1 28.7 MF-7 29,600 67.8 20.1 MF-8 30,100 22.3 6.7 MF-9 24,400 71.6 17.5 MF-10 24,300 79.9 19.4 Average: 27,950 59.8 16.7 lb/ton = ((%DM/100)*2000 lb/ton) * (Total N ppm/1,000,000) * (MR) MR = Mineralization Rate = 50% (expressed as decimal: 0.5) NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 4�Predictive Client: Luke Mathis Advisor: ' ASJ Mathis Farms, LLC 615 Mathis Farm Rd w A Waste Report Roaring River, NC 28669 P. w Wilkes County you„EDkal'" Links to Helpful Information Sampled: 03/17/2020 Received: 03/20/2020 Farm: 801 Completed: 03/25/2020 PALS #: 801 PALS #: Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF1 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na Cl Code: FCP Total N: 32200 110400 26700 14400 6020 6900 5650 329 270 275 36.6 - 310000 4080 7230 - Description: Inorganic: Composted Poultry NH4-N Waste NO3-N SS EC pH BD CCE ALE C:N DM Grower Comments: (105 S/cm) (MS/cm) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) yadkin farm 2160 21.60 5.30 - - - 9.64 : 1 74.1 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na Cl Broadcast 23.9 35.2 47.4 21.4 8.91 10.2 8.37 0.49 0.40 0.41 0.05 - 6.05 10.7 - Soillncorporated 28.6 35.2 47.4 21.4 8.91 10.2 8.37 0.49 0.40 0.41 0.05 - 6.05 10.7 - Agronomist's Comments: North Carolina f 'a x =l { Tobacco Trust Fund Commission Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 2 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF2 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code: FCP Total N: 29600 20000 14600 29900 9590 4710 7170 744 600 594 38.9 - 292000 11600 3390 - Description: Inorganic: Composted Poultry NH4-N Waste NO3-N SS EC pH BD CCE ALE C:N DM Grower Comments: (105 S/cm) (MS/cm) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) Ashley (solar panels) 733 7.33 6.88 - - - 9.87 : 1 31.2 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 9.22 28.6 10.9 18.7 5.98 2.94 4.47 0.46 0.37 0.37 0.02 - 7.25 2.11 Soil Incorporated 11.1 28.6 10.9 18.7 5.98 2.94 4.47 0.46 0.37 0.37 0.02 - 7.25 2.11 - Agronomist's Comments: NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 3 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF3 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code: FCP Total N: 29200 118300 43800 25100 10000 7420 8300 972 658 543 62.9 - 247000 9910 8350 - Description: Inorganic: Composted Poultry NH4-N Waste NO3-N SS EC pH BD CCE ALE C:N DM Grower Comments: (105 S/cm) (MS/cm) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) Myers Dairy 2090 20.90 7.39 - - - 8.45 : 1 48.4 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 14.1 40.6 50.8 24.3 9.69 7.17 8.02 0.94 0.64 0.53 0.06 - 9.58 8.07 - Soillncorporated 17.0 40.6 50.8 24.3 9.69 7.17 8.02 0.94 0.64 0.53 0.06 - 9.58 8.07 - Agronomist's Comments: NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 4 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF4 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na Cl Code: HLT Total N: 26600 110300 28200 15600 4630 8890 548 292 292 310 40.0 - - 587 9050 - Description: Turkey Inorganic: House NH4-N Grower Comments: NO3-N SS EC pH BD CCE ALE C:N DM Chatham Rd (10 S/cm) (MS/CM) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) - - - - - - - 79.1 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na Cl Broadcast 21.1 37.4 53.6 24.7 7.32 14.1 0.87 0.46 0.46 0.49 0.06 - 0.93 14.3 - Soillncorporated 25.3 37.4 53.6 24.7 7.32 14.1 0.87 0.46 0.46 0.49 0.06 - 0.93 14.3 - NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 5 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF5 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code: FCP Total N: 18600 15600 3940 29400 6170 2940 12100 586 420 394 16.0 - 161000 8790 330 - Description: Inorganic: Composted Poultry NH4-N Waste NO3-N SS EC pH BD CCE ALE C:N DM Grower Comments: (105 S/cm) (MS/cm) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) East High 167 1.67 6.34 - - - 8.64 : 1 41.2 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 7.67 29.4 3.90 24.2 5.09 2.43 10.0 0.48 0.35 0.33 0.01 - 7.25 0.27 - Soillncorporated 9.20 29.4 3.90 24.2 5.09 2.43 10.0 0.48 0.35 0.33 0.01 - 7.25 0.27 - Agronomist's Comments: NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 6 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF6 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code: HLT Total N: 34900 13000 31000 18500 5450 9440 2400 321 301 310 44.2 - - 3900 8780 - Description: Turkey Inorganic: House NH4-N Grower Comments: NO3-N SS EC pH BD CCE ALE C:N DM Dr. Beale (10 S/cm) (MS/CM) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) - - - - - - - 82.1 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 28.6 48.7 61.1 30.3 8.95 15.5 3.94 0.53 0.49 0.51 0.07 - 6.41 14.4 - Soillncorporated 34.4 48.7 61.1 30.3 8.95 15.5 3.94 0.53 0.49 0.51 0.07 - 6.41 14.4 - NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 7 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF7 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code:HLT Total N:29600 9200 24700 12000 4950 6780 3680 287 308 285 35.9 - - 3070 6550 - Description: Turkey Inorganic: House NH4-N Grower Comments: NO3-N SS EC pH BD CCE ALE C:N DM Sparks Place (10 S/cm) (MS/CM) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) - - - - - - - 67.8 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 20.1 28.6 40.2 16.3 6.72 9.20 5.00 0.39 0.42 0.39 0.05 - 4.17 8.89 - Soillncorporated 24.1 28.6 40.2 16.3 6.72 9.20 5.00 0.39 0.42 0.39 0.05 - 4.17 8.89 - NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 8 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF8 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code: FCP Total N: 30100 25200 9060 33100 13600 3910 2500 596 380 500 29.5 - 380000 2900 1630 - Description: Inorganic: Composted Poultry NH4-N Waste NO3-N SS EC pH BD CCE ALE C:N DM Grower Comments: (105 S/cm) (MS/cm) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) Berry's Lane 456 4.56 6.81 - - - 12.6 : 1 22.3 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 6.72 25.7 4.85 14.8 6.08 1.75 1.12 0.27 0.17 0.22 0.01 - 1.29 0.73 - Soillncorporated 8.07 25.7 4.85 14.8 6.08 1.75 1.12 0.27 0.17 0.22 0.01 - 1.29 0.73 - Agronomist's Comments: NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 9 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF9 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code: HLT Total N: 24400 9510 25600 12400 4210 5370 954 250 256 251 43.3 - - 1320 5600 - Description: Turkey Inorganic: House NH4-N Grower Comments: NO3-N SS EC pH BD CCE ALE C:N DM Solar Panels (10 S/cm) (MS/CM) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) - - - - - - - 71.6 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 17.5 31.2 44.1 17.8 6.02 7.68 1.37 0.36 0.37 0.36 0.06 - 1.89 8.01 Soil Incorporated 20.9 31.2 44.1 17.8 6.02 7.68 1.37 0.36 0.37 0.36 0.06 - 1.89 8.01 - NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-WO05941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 10 of 11 Sample Information Nutrient Measurements are given in units of parts per million (ppm), unless utherwise specifed. Other Results ID: MF10 Nitrogen (N) P K Ca Mg S Fe Mn Zn Cu B Mo C Al Na CI Code: HLT Total N: 24300 110400 27800 14100 4640 9690 700 278 287 293 39.1 - - 748 9420 - Description: Turkey Inorganic: House NH4-N Grower Comments: NO3-N SS EC pH BD CCE ALE C:N DM North Wilkesboro (10 S/cm) (MS/CM) (Unitless) (lb/yd3) (%) (tons) (Unitless) (%) - - - - - - - 79.9 Estimate of Nutrients Available for First Year (lb/ton) Other Results (lb/ton) Application Method: N P205 K20 Ca Mg S Fe Mn Zn Cu B Mo Al Na CI Broadcast 19.5 38.3 53.3 22.5 7.41 15.5 1.12 0.45 0.46 0.47 0.06 - 1.20 15.1 Soil Incorporated 23.3 38.3 53.3 22.5 7.41 15.5 1.12 0.45 0.46 0.47 0.06 - 1.20 15.1 - NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-W005941 Luke Mathis Sampled: 03/17/2020 1 Received: 03/20/2020 1 Completed: 03/25/2020 Page 11 of 11 Understanding the Waste Report Nutrient concentrations and other data on this report are provided so that waste materials can be applied at agronomic rates, thereby supplementing or reducing fertilizer application and preventing environmental contamination. In reading the Laboratory Results section, remember that materials with < 15% dry matter (generally liquids) are analyzed as received; all other wastes are dried first. Values in the Estimate of Nutrients Available for First Crop section are based on the type of waste and method of application you specify and reflects the fact that only 40-60% of the nitrogen becomes available within one year of application. The remainder may ormay not ever become available. ALE is Agricultural Lime Equivalence. The ALE DM% is percent Dry Matter [for semi -solid and Al = Aluminum Cu = Copper NH4-N = Ammonium -N indicates the amount of the waste material that solid waste, this value facilitates conversion of As = Arsenic Fe = Iron Ni = Nickel provides a limiting effect equivalent to one ton of dry -basis concentrations (ppm) back to B = Boron K = Potassium NO3-N = Nitrate -N agricultural grade limestone. wet -basis of original sample]. Ca = Calcium Mg = Magnesium P = Phosphorus BD is Bulk Density in Ib/yd3. EC (Electrical Conductivity) measures Cd = Cadmium Mn = Manganese Pb = Lead CCE is Calcium Carbonate Equivalence and is salinity, or soluble salts (SS). Cl = Chloride Mo = Molybdenum S = Sulfur used to determine ALE. pH measures basicity/acidity. Cr = Chromium N = Nitrogen Se = Selenium C:N ratio is the Carbon:Nitrogen ratio. Na = Sodium meq/L = milliequivalent per liter; mS = millisiemens; ppm = parts per million or mg/L; S = siemens; T = trace (<0.005 lb/unit) Additional information: www.ncagr.gov/agronomi/pdffiles/uwaste.pdf & www.ncagr.qov/agronomi/pdffiles/wasteguide.pdf