The URL can be used to link to this page

Home My WebLink AboutWQ0034688_Residual Annual Report 2020_20210224Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* Annual Report Year* Permit Number (IR)* Applicant/Permittee Email Notifications ........................................................................................................................................................................ Does this need review by the hydrogeologist?* Regional Office CO Reviewer Admin Reviewer * Annual Report * Residual Annual Report r Additional Information r Other 2020 W00034688 Neuse Regional Water & Sewer Authority O Yes r No Washington Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00034688 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * Neuse Regional WASA DCAR Please provide comments/notes on your current submittal below. 2020 Annual Report for NeUse Regional Water and Sewer Authority NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Fans, Specifications, Calculations, Bc.) NeUse NC 2020 Annual Report FINAL.pdf 5.5MB Upload only 1 FCFdocurrent (less than 250 NB). Miltiple documents rust be combined into one F7Ffile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/24/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 24, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0034688 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of Neuse Regional Water and Sewer Authority, NC. If you have any questions or need additional information, please do not hesitate to contact Charlie Colie at (252) 522-2567 or Chris Wynne at 336-909-8627. Sincerely, oe"i& Shuuc" ,es Derrick Shivar Environmental Compliance Manager Enclosures cc: Charlie Colie, Neuse Regional Water and Sewer Authority Chris Wynne, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD NEUSE REGIONAL WATER AND SEWER AUTHORITY RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0034688 2020 ANNUAL REPORT Neuse Regional Water and Sewer Authority, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: WQ0034688 County Lenoir Year 2020 Facility Name (as shown on permit) Neuse Regional Water Treatment Plant NPDES No. NC0088111 Land Application Operator Svnagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: NIA Total number of fields utilized for land application during the year: 7 Total amount of dry tons applied during the year for all application sites: 281.91 Total number of acres utilized for land application during the year: 159.6 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T 1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. it. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Harold Herring, Executive Director Z ( l Permittee Name and Title (type or print) Si e e I Signature of Preparer* Date SignatUe of Land Applie Date (if different from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 NEUSE REGIONAL WASA, NC NEUSE REGIONAL WASA, NC WTP LIQUID MONTH/YEAR October 2020 IEel I/_1I AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 3,087,000.00 G 281.91 D 255.70 3.087.000.00 G 281.91 D 255.70 Report Date: 2/5/2021 2:19:01 PM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: W00034688 Laboratory: Facility Name: NEUSE REGIONAL WASA, NC PACE ANALYTICAL Residual Source WQ # or NPDES#: NCO088111 WWTP Name: NEUSE REGIONAL WASA WTP Residual Analysis Data Product Type Sample or Composite Date WPL 08/26/20 WPL 10/21/20 Parameter (mglkg dry weight) Ceiling Conc. Limit Percent Solids (°to) NA 2.19 2.81 Arsenic 75 10 11 Cadmium 85 <2.5 <0.74 Copper 4300 180 530 Chromium NA 30 41 Lead 840 19 28 Mercury 57 <0.85 <0.69 Molybdenum 75 <20 <5.9 Nickel 420 <21 17 Selenium 100 <16 10 Zinc 7500 100 130 Total Phosphorus NA 2800 4900 TKN NA 13000 11000 Ammonia -Nitrogen NA 940 890 Nitrate and Nitrite NA 33.4 37.2 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly pathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the ol possibility of fin s nd imprison nt r Wowing violations." Signs re of Preparer* Date *Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (1212006) Printed: 2/5/2021 2:35:24 PM For: 1703 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: W00034688 Laboratory: Facility Name: NEUSE REGIONAL WASA, NC PACE ANALYTICAL Residual Source NPDES # or WQ#: NCO088111 WWTP Name: NEUSE REGIONAL WASA WTP Residual Analysis Data Product Type WPL WPL Sample or Composite Date 08/26120 10/21/20 Parameters (mg/kg dry weight) Aluminium 180000 170000 Calcium 2400 2000 Magnesium <1300 1300 pH (s.u.) 6.20 6.70 Potassium 2100 3500 Sodium 1900 1900 PAN 5327 4526 SAR (Ratio) 1.1441 1.3568 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines nd imprisonment f nowing violations." Signa Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 2/5/2021 2:32:47 PM For: 1703 01 DENR FORM RSSF-B (12/2006) 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Chris Wynne Project Name: NRWASA Lot Number:VH27084 Date Completed:09/10/2020 NIM�� Mr� 09/10/2020 2:16 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VH27084 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VH27084-001 Description: NRWASA Matrix: Solid Date Sampled:08/26/2020 1100 % Solids: 2.19 08/28/2020 0132 Date Received:08/27/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 08/28/2020 0132 MOM 64970 1 350.1 (Ammonia - N ) 350.1 1 09/01/2020 1146 DMA 65272 1 (Nitrate - N ) 9056A 1 09/02/2020 1703 AMR 65639 1 (Nitrite - N ) 9056A 1 09/02/2020 1703 AMR 65640 1 (Phosphorus) 365.1 2 09/02/2020 1306 DMA 09/02/2020 0857 65438 1 (Soil pH meas) 9045D 1 09/02/2020 2316 SRB 65557 1 351.4 (TKN) 351.2 1 09/02/2020 1614 DMA 09/02/2020 1023 65445 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.19 % 1 Ammonia - N (gas diffusion) 350.1 940 46 24 mg/kg 1 Nitrate - N (soluble) 9056A 28 23 4.6 mg/kg 1 Nitrite - N (soluble) 9056A 5.4 J 9.2 4.6 mg/kg 1 Phosphorus 7723-14-0 365.1 2800 460 92 mg/kg 1 Soil pH measured in water @ 22.2 ° C 9045D 6.2 su 1 TKN 351.2 13000 1100 1100 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 09/04/2020 1608 JAB2 09/04/2020 0655 65431 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 3.5 0.85 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 09/04/2020 0509 KSH2 09/02/2020 1621 65429 2 3050B 601 OD 1 09/10/2020 0334 KSH2 09/02/2020 1621 65429 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 180000 810 300 mg/kg 1 Arsenic 7440-38-2 6010D 10 J 30 10 mg/kg 1 Cadmium 7440-43-9 6010D ND 10 2.5 mg/kg 1 Calcium 7440-70-2 6010D 2400 J 10000 1300 mg/kg 1 Chromium 7440-47-3 6010D 30 20 5.1 mg/kg 1 Copper 7440-50-8 6010D 180 20 9.1 mg/kg 1 Iron 7439-89-6 6010D 49000 200 92 mg/kg 2 Lead 7439-92-1 6010D 19 J 20 9.1 mg/kg 1 Magnesium 7439-95-4 6010D ND 10000 1300 mg/kg 2 Manganese 7439-96-5 6010D 1400 30 12 mg/kg 1 Molybdenum 7439-98-7 6010D ND 81 20 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VH27084-001 Description: NRWASA Matrix: Solid Date Sampled:08/26/2020 1100 % Solids: 2.19 08/28/2020 0132 Date Received:08/27/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 09/04/2020 0509 KSH2 09/02/2020 1621 65429 2 3050B 6010D 1 09/10/2020 0334 KSH2 09/02/2020 1621 65429 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D ND 81 21 mg/kg 1 Potassium 7440-09-7 6010D 2100 J 10000 1300 mg/kg 2 Selenium 7782-49-2 6010D ND 40 16 mg/kg 1 Sodium 7440-23-5 6010D 1900 J 10000 1300 mg/kg 1 Zinc 7440-66-6 6010D 100 100 25 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC --,- IT - �I O IIIIj v'C1 a�31;.� IJUu alRj -WAIu;d tuz-uag ' m h r� JO IB�J ON S � � GY�N 4l�kali$ m I _ Wd }4 y i S is He Y I;1uu [r} r w!7IGI�t�$ .. . f m m c � a a } A r- a l 1D � x F1. 3: dv E R ui x L E o aL d , t 513ci y A i ;7 411 C � x 4 _ { , ; I IEl I b a E 5pti i r� ry r � i, li a i o- 6 L G 4 I u $ "' U° ri < i�41 _ a Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 �I n PACE ANALYTICAL SERVICES, LLC 5hedyP.n%4M)W" Ma; $G*'ICCrti enc. DiKirn¢rA Humtiv, M:;0 M:BC-14 Samp1C 'Rcce1pt Checklist (SRC} Clieelt: Sy rr ;ro Corsix Inapecmd hyidate: 1 mu 09117r`204f1 LOOP: VH271764 3`csi Vf No L. Weie custoay Scala praKafti. rm *L- c per? - QYWI QN131]\.q 2_ Tf rustocv seals Were eMerlt, were theintxt and unbroken? iH Str.'p ID. NA Chlorine Strlp 11)= ]NA _ rested by. NA _ Xig-'nal 1rmperaturc upon receipt 1 D�,riJvedy(CorreU-- ) temparotlue upon receipt Masolid Snap.Cup 1D: 4.0 {4.0 o[, MA fNA ''4 NA i yL ft 4 1NA l40kod: 27ernrei-eft ie Blunk [:)Agaiim, Bottles IR Gun I[7_ _ IFt Cat;r. Can cct:e}n Fat=o1: _ +Lethod of coolant_ ® Wat Ice ❑ Ice Packs ❑ Liv 1= ❑ plane 3. If lcmwawre gFsrrty UOblerexcxzcced 6_O C, wFis Pr+o ect h4r_na c Ni ti�cr.° [T Yes C] No WINA I g r PM was Notified hy_ phone) errtuil11 face -to -tact (Circle One). ® Yes ❑ Jo ❑1h1A 4_ Is tho coutmemistl couriar's pecking slip allacls:,d fr} this fwm2 ® Yes ❑ No 5. #cr0 prDper,:usu]dy p1wedurr.s (1 Jinqxlshc:V ceivad) Wowed? •r 'eLJ Ik2o 6. weru sample IDS list -ad on the Coca Yes [l X-0 11 7_ Wert sa<M, le MA li2tcd an all sample 03ntainrm? Yes ❑Flo' S. >,x -;5011ectior, clM & time listed on the coc? 4-0� 9_ WU aalit:ctiar date& tithe IiaWd on all sampla containers? ❑ .No ]0_ Did a]I cuulaincr label inf wflon {lp, date, time) agreC Withthe CM?0 No ] i . W4-Te tests to be performed listed on the COC2 rtiV l all Ffrerrivn ,2018 ZM 342 0 Oc 3'ca ❑ No 12. Did all samples a rive in the proper coniahWn Fur fiach teft "War in good carrdition [r nbrvken, lids Yos 0 No 13. WM% arj uate s[jep]e volume 2Luai[able2 hd yes Lj No 14, %2m ft[, samples cJ wed witbin -Xr the hrUing tana or 46 ltuu-s, Wh ichmr romrs fin[? Yes Nq -5. Were any samPl&< caudeilm tnissing{excess (;role one) saenp]osNot I;sted on COC? ❑ 3+ ❑ No NA ] 6_ Fvr VOA and 1451-175 sfl1:1pJe5, were buhblos present=;°pcarsi'e".°'ot 6mrn in Jitan�Ker) in an,,. of tlta VOA wfals"1 Y No 1,4A 117, Were aIJ DROlinetalsinutricat sa]-rlp-s�5 rewived at a phi of { 2? ❑ Yee ❑ No NA I S WWere all cyaai& samples received at a pH > t2 and sulfide, sarrtpies mceivrd at a VII> 9? ❑ Yes ❑ hlaI l d NA ❑Ye51 MNOI ®TEA Were client rem arkslruquests i [,c, mgttcsted ditudons, MFVMSD &signalinns, etc_) ecily transcribed from the CPC in-o the cnlnmtM SBCtiurl in LIMS? ! ththe container IaLe-? ICvwr Ouote tr NA Prese:-vAtiuu (Must be v np;eted forarry sample[ incorrectly pr6',3crwed ur with Jieadgra) 1mplr(s) N,4 were receicti lltcCrrrerlly preened stei€l were adfusttxi accordil[gl} +rample rern:ivigg vuitlr NA mLO: Circle brie: 14' 04, I NOI* , HCI, NaO14 axing SR k TEA me of pqe crvatiols N. i If Inora tlban r}n- Preservativc is neeced, please note is the aarl:rrentq bclow- tnplc(s) NA -- —4 were rer,e;ivad wiA bubblos >6 mm in diamexr. niples(s) NA evert rec ived wiL'7 TRC r]_5 'n 1, f]= #19 is Rv) and .VVM jtested ux-A rclingly ki sample rmaivins with sodium tlriusuIFalr, (NE12S ) with Sheol}+ ID. NA burcode labels apoJied by. BMCj Dam., 0:912 2(2o C:ommects; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Chris Wynne Project Name: NRWASA Lot Number:VJ23013 Date Completed:11/02/2020 11/03/2020 3:04 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VJ23013 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Du to low percent solids, sample -001 was analyzed with three times the normal mass. The LOQs have been adjusted accordingly. The following sample was not fully oxidized after the addition of 15mL of HNO3: VJ23013-001. This is indicated by the sample exhibiting persistent brown fumes after acid addition. Due to being a biosolid and having low percent solids, this sample cannot be weighed to a lower mass. Nutrients The method blank for analytical batch 71002 contained phosphorus greater than the method acceptance criteria. The continuing calibration blanks (CCB's) analyzed on the instrument did not show contamination. Due to the large dilutions associated with these samples on the instrument, any contamination from prep was diluted out and the sample results are not impacted. The method blank for analytical batch 71626 contained the analyte ammonia greater than the acceptance criteria. The associated samples contained detections for this analyte at concentrations greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The data has been reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VJ23013-001 Description: NRWASA Matrix: Solid Date Sampled:10/21/2020 1130 % Solids: 2.81 10/26/2020 2236 Date Received:10/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 10/26/2020 2236 MOM 71210 1 350.1 (Ammonia - N ) 350.1 1 10/29/2020 1509 DRD 71626 1 (Nitrate - N ) 9056A 1 10/29/2020 1737 AMR 71640 1 (Nitrite - N ) 9056A 1 10/30/2020 0826 AMR 71750 1 (Phosphorus) 365.1 5 10/27/2020 1653 DMA 10/26/2020 1224 70769 1 (Soil pH meas) 9045D 1 10/24/2020 1820 AAB 71058 1 351.4 (TKN) 351.2 1 10/30/2020 0946 DMA 10/29/2020 1059 71581 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.81 % 1 Ammonia - N (gas diffusion) 350.1 890 36 18 mg/kg 1 Nitrate - N (soluble) 9056A 33 18 3.6 mg/kg 1 Nitrite - N (soluble) 9056A 4.2 J 7.1 3.6 mg/kg 1 Phosphorus 7723-14-0 365.1 4900 890 180 mg/kg 1 Soil pH measured in water @ 20.9 ° C 9045D 6.7 su 1 TKN 351.2 11000 890 890 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 11/02/20201205 JAB2 11/02/2020 1014 71918 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 2.9 0.69 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 10/29/2020 1349 KSH2 10/28/2020 1432 71297 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 170000 240 89 mg/kg 1 Arsenic 7440-38-2 6010D 11 8.9 3.0 mg/kg 1 Cadmium 7440-43-9 6010D ND 3.0 0.74 mg/kg 1 Calcium 7440-70-2 6010D 2000 J 3000 370 mg/kg 1 Chromium 7440-47-3 6010D 41 5.9 1.5 mg/kg 1 Copper 7440-50-8 6010D 530 5.9 2.7 mg/kg 1 Iron 7439-89-6 6010D 39000 59 27 mg/kg 1 Lead 7439-92-1 6010D 28 5.9 2.7 mg/kg 1 Magnesium 7439-95-4 6010D 1300 J 3000 370 mg/kg 1 Manganese 7439-96-5 6010D 1500 8.9 3.5 mg/kg 1 Molybdenum 7439-98-7 6010D ND 24 5.9 mg/kg 1 Nickel 7440-02-0 6010D 17 J 24 6.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VJ23013-001 Description: NRWASA Matrix: Solid Date Sampled:10/21/2020 1130 % Solids: 2.81 10/26/2020 2236 Date Received:10/23/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 10/29/2020 1349 KSH2 10/28/2020 1432 71297 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 3500 3000 370 mg/kg 1 Selenium 7782-49-2 6010D 10 J 12 4.8 mg/kg 1 Sodium 7440-23-5 6010D 1900 J 3000 370 mg/kg 1 Zinc 7440-66-6 6010D 130 30 7.4 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC I 1 G t] _ A O I r L - e'7 .E �k EM I � w x _ wu I4 Sg&:uD we MIS T �91!�ila�ll� erf -J- _ (ue�.eg L5 CD a� f unld ap!=L;= d a7D.l rnd ago- > m M , SIS juu-v LU S �I C7 L j �j J IL sir S3 N T } '.� � I y v 4ti ?P � E7 o �T-C=!j 3 0i o. � rk 15 mr I IQ x 4' 4 1rI•aLL 3 d � i u C Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 4 W. G LJF •• - F c F f QD F I ° 9� 9A a � � L ! 3 I3 fd a � � m TJ � Q Iv v a PACE ANALYTICAL SERVICES, LLC 5arnplesReceiptCttecklist (513C)(ME0018C•L5) lllfilll�� 'II )9f2020 �cv.4raJ,¢o- of Issu:ngAUthority; Pace Er4S/- WCOt VJ23013 ;e 1of 1 ample Receipt cbeckfist }. W Client; _��, 0" ._ _ . C.00lel- ]nsp oed by.1dote. I�' � � 1 LPL Mealmofreceipt: ace client Litips errx C7tt'er: El Yes I 4 . 1. "re CU 3wdy S IS pI ewe oil the rwlei ? `f05 NO .4 7._ Ifcustody seats ti-"LV PreSent, lxe[� V intact and iribrul,cn? l`i stip IU; _ C:hlarinc Strip LD: Tested by: p O ri 13MJ tcmperaturls upcu rcccipt 1 D--rivod (C oo-rcctcd')temperature upon rcee:pt 'Y.SnJ i d Saar'-C Up 1 d; ?Ir NA ;NA c PA ,NA o ail e KA flC olhod: eroperar_1re ank ❑, irpstBottics IRGp;nID-, 5 ift(;uuCrlrrcction Fpoim; t__..._._ac Mettod of triolanr l J wtt fcr, LL Ice. ParkF ❑ ory Jte ❑ bone ❑YES ❑ Na }I 1 t 1_]Ftrd_ll lit' r,f a:]w I:UMt61' eXUUtd--d 6_C! }: waY i P-4ij ruL Miiriagrr Nutt Fpcd? - Phrl kaas Natilied by: a11011a 1 t3l MiI ! rzu L-iu-faL n (_In 1n p11C). i' s LJ No '?-4A 4. is [he comraweial coufier's packing s.ip ae adied to _his Form? Ync Ll No S. Were f:-rrper e mmily nracedures (re Iingl_FolloweLV — — Ycs 0 N-1 b, Wcre sanplt lIDs l:axd on Lhc CX'4 'ryes 1N0 7, Werm.sampl8 IDS liswd oil all uunpla coil'aincrs? Yes No 8, Was ra,l I n0ion date & time, listed on t11e COC".'----___ Yes No 9. Wus collection date & time listed on al I sample containcrs'l es ONO 11), Did r_il f.ont1n7PT 11SM k1fOT-M;M' C11 (lei, date, time) ague with the COC7 11. Wcre tests to be performed listed on the COO - - es El No �r L9 Y,s ❑ Nn 12, Did zi I samples arrive in the proper containers frrr each trse ati Wor in good =71 e.i-: on (unbroken, lids ur. aoc.)? s LJNo I:, Wax adetltaatesalmlilcVol unte WLIailable? Yes No 14. Wcrc all samples mcdvedwith in Yi ite holdin_lime or49' ours. whidie wer comes iil_st? Yes a 15. Wore any wrp.p1cz containers missingia cess (circle one) samples Not listed oli COCA ED -rTYos ❑ Na ZNA If*_ For VOA and RSK-I l5 eamplc5,wcrc buablc: es prrnt>"pco-5ize' (IN'rr 6MM in LiismL![(;r) iinanyofthe VC1A viaEg! Yes Na N.4 117. Were all DF,(VfnetaWr"ien[ scam pies re eived at a pil oi~ < 29. Yt:x LJ No A 18_ e1e all c}auieL sm1:]Flcs 1-=eiVVd at M 1}H 12 and .;I11brL_ srlmp:cs rtaeivc:l HI. }L F14 ❑ Yes []No Ej"k 19. Were all zipp:icable Nl:a,rIJ�Nle}'anidelpF,eeo:ffi25.=?6b8.3 (< (!_Smi+1L) samples free of 1t5i[1UA C11113rinn? ❑20 Yea ❑ Na re . Wec]iem mmarKs(requeets (Le. mquesn5d dilutlot5s. '4Sim SLI dcEigrwtioos, c#G...} ti.^,rrnctly irattscnibed fl'otr, -ht COC :rto .lit ca:nnient scetion in L:l` SD 17Fy--esF7No1 126. W1 §& t:tc uote narnler listed 0_1 the conMin--t- label'' If, ., u; to ly Sample Presimskilon (Musr Lt Completed W Any SOmple{s) iLt4-orrCutly, pricWryed or witli ]teadspace_) Sarr pleas) . . _ wwt received imom'2ctEy jwasarved and were adjusted aeuDR:i-,, lr in smai-jlc rcc living wail mL of&CIc one; ]i� 04, I-NO3. I ICI, Nat7I1 using SR # � me of .-ese-vation ^ if mere than one fireserustive i he�cled, pleas tlrvle in the c�rimmenls below. $W11P''05) 14A wcrc rcccivcd with bubhlas�b mri in diameter, $am p.rd(e NA — —_ — were received with TR.0 . 0_; mgfL (1f ft I9 is rig) and were e Ejtlstcd accordingly it sarnple rc�;eiving with sodium thiasulfate (M@.2520.1) wltli Shealy ED; HA SR barcode labels applied by. Coninic'-Its: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 SECTION 3 ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: NEUSE REGIONAL WASA, NC WQ PERMIT #: WQ0034688 FIELD#: NC-LN-00OX5-0-0001- ACRES UTILIZED: 31.7 LANDOWNER: NEUSE REGIONAL ANNUAL DRY TONS APPLIED: 12.66 SITE #: NC LN 00OX5 ACRES PERMITTED: 31.7 OPERATOR: NEUSE REGIONAL PREDOMINANT SOIL SERIES: KALMIA CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: BERMUDAGRASS, COMMON - CROP 1 MAX. PAN: 173 CROP 2 NAME: CROP 2 MAX. PAN: Ph-1 IRF rRrnM RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site %— Name of Crop Type I or Cubic Yards (Y) Cond. Precip Volatl Mineral, Ammonia Nitrate ` PAN Applied Receiving Residual Date or i or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite 1 (Ibs/acre) Application Month Amount UOM Solids DryTons/Ac Source 4 Moist Inches Method* Rate** � Rate*** � mg/kg mg/kg � mg/kg Crop 1 Crop 2 Crop 1 Crop 2 q 10/24/2020 138,600.001 (G) 2.190 0.399 NRWASAWPL DRY "0-<1!2" SUR 0.5 0.40 13,000.00 940.00 s 33.40 4.254 I y BCOP Oct-20 138,600.00 (G) Total 0.399 Total 4.254 0.000 CD CR PB HG MO SE ZN Lime Applied Annual Ibs/acre Applied 0 008 0 002 0 144 0.0240.015 <0.001 0.016 0.017 0.013 0.080 2.236 k Date LbstAc 0.483 3.679 1 0.523 0.868 1 0.186 Permit PAN Limit (Ibs/acre) 1st Crop Federal C.P.L.R. (Ibs/acre)**** 36.6 34.$ 1,339.0 267.9 15.0 375.0 89.0 2,500.0 NRWASAWPL = NEUSE REGIONAL WASA, NC WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant p f for submitting false information, including the possibility of fines and impriso e7or knowing violations." I I TURE OF LAND APPLIER GIATE NR = Not Reported or No uired *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation *** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/1l2021 DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: NEUSE REGIONAL WASA, NC WQ PERMIT #: WQ0034688 FIELD#: NC-LN-000X5-0-0002- ACRES UTILIZED: 12.4 LAND OWNER: NEUSE REGIONAL ANNUAL DRY TONS APPLIED: 24.74 SITE #: NC LN 00OX5 ACRES PERMITTED: 12.4 OPERATOR: NEUSE REGIONAL PREDOMINANT SOIL SERIES: KALMIA CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: BERMUDAGRASS, COMMON - CROP 1 MAX. PAN: 173 CROP 2 NAME: CROP 2 MAX. PAN: PA QT1 1929= /Pr'nM RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied 6eceiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs qApplication ligation ization TKN Nitrogen and Nitrite (lbs/acre) M Application —-op Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Ratemg/kg mg/kg * Rate— mg/kg i5rCrop 2 Crop 1 Crop 2——5-1-- 10123/2020 201,600.00 (G) 2.190 1.485 NRWASAWPL DRY "0-,1/2" SUR 00.40 .5 13,000.00 946.00 33_,40�_F5.820 57C—op— I I0I21+14020 r 69,300.00 (G) 2.190 0.510 NRWASAWPL DRY "0-<1/2" SUR 0.5 0.40 13,000.00 940.00 33.40 1 5.438 BCOP Oct-20 270,900.00 (G) --------------- Total 1.995 Total 21.258 0.000 AS CD CU GR I)II:1 HG MO NI SE ZN Lime Applied �Annual lbs/acre Applied 0-04-0—F 0-015 y 0.718 1 0.120 0.076 0.003 0.080 0.084 0.064 0.399 11.173 Date Lbs/Ac Cumulative lbs/acre 0A20 1 0.052 0.487 1 0.015 1 0.225 1 0.720 1 0.190 Permit PAN Limit (lbs/acre) 1st Crop, Federal C.P.L.R. (lbs/acre)-- 36.6 34.8 1,339O 267 - 9 15.0 375.0 89.0 2,500.0 NRWASAWPL = NEUSE REGIONAL WASA, NC WTP LIQUID "I certify, under penalty of law, that this dS?cument was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pen or u tong false information, including the possibility of fines and imprjis�ent r knowing violations." URE OF LAND APPLIER *TE NR = Not Reported or Not Req I d Mineralization Rates: Compost-0. 1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation C.P.L.R. : Cumulative Pollutant Loading Rate Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 See Site pH & Lime Application Records Section of Report Printed: 211/2021 DENR FORM FSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page:1 FACILITY NAME: NEUSE REGIONAL WASA, NC WQ PERMIT #: WQ0034688 FIELD#: NC-LN-000X5-0-0003- ACRES UTILIZED: 9.4 LAND OWNER: NEUSE REGIONAL ANNUAL DRY TONS APPLIED: 27.04 SITE #: NC LN 00OX5 ACRES PERMITTED: 9.4 OPERATOR: NEUSE REGIONAL PREDOMINANT SOIL SERIES: KALMIA CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: BERMUDAGRASS, COMMON - CROP 1 MAX. PAN: 173 CROP 2 NAME: CROP 2 MAX. PAN: onc-ri IPF=1rrr1nox RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site I Name of Crop Type Conti. a Preci Volati- Mineral- Ammonia Nitrate ? PAN Applied Receiving Residual 9 or Cubic Yards (Y) P I Date or or Wet Tons (W) % Residual Dry, Wet, s Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibslacre) Application 9 Month Amount I UOM i Solids DryTons/Ac Source Moist Inches Method* i Rate** Rate— � mg/kg mg/kg � mg/kg :1Crop 1 a Crop 2 Crop 1 FCrop 2 10/23/2020 151,200.00k (G) 2.190 1.469 NRWASAWPL' DRY 0-<1/2" SUR 0.5 0.40 13,000.00 940.00 33.40 15.651 BCOP I 10/24/2020 144,900.00� (G) 2.190 1.408 NRWASAWPL DRY "0-<1/2" SUR 0.5 OAO 13,000,00 940.00 33.40 14.999 BCOP k, F opt-2o 2ss,aoo.00 (G) I _ t E Total 2.877 Total 30.650 0A00 AS CD GU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.058 0.014 1,036 0 173 0.109 0.005 0.115 0.121 0.092 0.575 16.109 Date LbstAc Cumulative Ibslacre Applied 0.481 0.058 50.725 3.376 0.534 0.021 0.301 @ 0.706 0.221�3.110 iPermit PAN Limit (Ibs/acre) 1st Crop � 173 ,Farlara) C'. P.i_R_ (Ibslacre)**** 36.6 34.8 1,339.0 � 267.9 P 15.D 375.0 89.0 2,500.0 NRWASAWPL = NEUSE REGIONAL WASA, NC WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penaltie bmi g false information, including the possibility of fines and imprison nt f r knowing violations." Zitze SIG U E OF LAND APPLIER DA E NR = Not Reported or Not Requ ** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 `***' See Site pH & Lime Application Records Section of Report Printed: 2/1/2021 DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page:1 FACILITY NAME: NEUSE REGIONAL WASA, NC WQ PERMIT #: WQ0034688 FIELD#: NC-LN-OQOX6-0-0001- ACRES UTILIZED: 13.6 LAND OWNER: SOVEREIGN REAL ESTATE ANNUAL DRY TONS APPLIED: 17.84 SITE #: NC LN 00OX6 ACRES PERMITTED: 13.6 OPERATOR: MICHAEL GINN PREDOMINANT SOIL SERIES: JOHNS CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: SOYBEANS (SB) CROP 1 MAX. PAN: 174 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) i Cond. Precip 3 Volati- Mineral- i Ammonia Nitrate PAN Applied Receiving Residual Date or j or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist I Inches Method y I Rate— Rate— i mg/kg EE6 mg/kg S mg/kg C or' p 11 � Crop 2 1 Crop 1 � Crop 2 4 10123/2020 195,300.00 (G) 2.190 1.311 NRWASAWPL I DRY "0 <1/2" I� SUR 0.5 0.40 13,000.00 94000 33.40 � 13.973 SB s Oct-20� 195,300.00 (G) Ott a Total 1.311 Total 13.973 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied �Annuai Ibs/acre Applied 0.026 0.007 0.472 0.079 Q 050 0.002 0.052� 0.055 0.042 0.262 7 344 Date gLbs/Ac re Applied (ibslacre) 39.077 0.237 96 1 3.168 i Federal C.P.L.R. (Ibs/acre)-- 36.6 34.8 1,339.0 267.9 15.0 375.0 ` 89.0 2,500.0 ILi NRWASAWPL = NEUSE REGIONAL WASA, NC WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe�Itiec4rrbrmt' g false information, including the possibility of fines and imprisre nt or knowing violations." Z(2I SIG TU E OF LAND APPLIER CIATE NR = Not Reported or Not Requl *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/1/2021 DEN FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page:1 FACILITY NAME: NEUSE REGIONAL WASA, NC WQ PERMIT #: WQ0034688 FIELD#: NC-LN-00OX6-0-0002- ACRES UTILIZED: 7.5 LAND OWNER: SOVEREIGN REAL ESTATE ANNUAL DRY TONS APPLIED: 16.11 SITE #: NC LN 00OX6 ACRES PERMITTED: 7.5 OPERATOR: MICHAEL GINN PREDOMINANT SOIL SERIES: KALMIA CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: SOYBEANS (SB) CROP 1 MAX. PAN: 164 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site - Name of Crop Type' Cond. Preci Volati- I Mineral- Ammonia Nitrate PAN Applied Receiving Residual l or Cubic Yards (Y) P p Date or or Wet Tons (W) % i Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre} Application 4 i Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* I Rate"* Rate— mg/kg mg/kg mglkg Crop 1 Cmp 22 +, Crop 1 Crop 2 10/2312020 1 176,400.00 (G) 2.190 2,148 NRWASAWPL DRY "O-<1/2" SUR 0.5 0.40 13,000.00 6 940.00 33.40 22.886 SB Oct-20 " 176,400.00y (Ca) �- Total 2.148 Total 22.886 0A00 AS CD CU GR l PB HG SE ZN P Lime Applied 0.043 0.011 0.773 0.129 0.082 0.004 �MO�Nl 0.069 0.430 12.028 Date Lbs1Ac Cumulative Ibstacre Applied 0.461 0.070 42.24 3.223 0.533 0.018 0.269 0.832 0.230 3.238 ?- Permit PAN Limit (Ibs/acre} 1st Crop � , 164 Federal G.P.L.R. albs/acre)**** 36.6 34.8 1,339.0 � 267.9 15.0 i` 375.0 89.0 2,500.0 �� _...�.�La...� �a NRWASAWPL = NEUSE REGIONAL WASA, NC WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant p ie for sub 'tting false information, including the possibility of fines and impriso em or knowing violations." 2 ,I z A RE OF LAND APPLIER TE NR = Not Reported or Not;Su ir *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR -ace, [NJ - Injection, SURIN - Incorporation **"* C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, injection/incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/112021 DEN FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: NEUSE REGIONAL WASA, NC WQ PERMIT ##: WQ0034688 FIELD#: NC-LN-00OX6-0-0003- ACRES UTILIZED: 26.3 LAND OWNER: SOVEREIGN REAL ESTATE ANNUAL DRY TONS APPLIED: 32.22 SITE M NG LN 000X6 ACRES PERMITTED: 26.3 OPERATOR: MICHAEL GINN PREDOMINANT SOIL SERIES: LUMBEE CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: SOYBEANS (SB) CROP 1 MAX. PAN: 174 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site I _ Name of Crop Type H r i or Cubic Yards (Y) Cond. Precip Volati- Mineral- i Ammonia Nitrate PAN Applied Receiving Residual I yh Date or or Wet Tons (W) % m k Residual Dry, Wet, � Past 24 Hrs. ;Application lization ization TKN # Nitrogen and Nitrite (Ibs/acre) r Application { 9C Month Amount UOM Solids Dry Tons/Ac Source Moist Inches i Method* Rate** Rate— mg/kg i mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 10/23/2020 352,800.00, (Gj 2.190 ; 1.225 NRWASAWPL DRY v "0-<112" SUR 0.5 0.40 13,000.00 940.D0 33.40 13.053 SB Oct-20 352,800.00 (G) Total 1225 Total 13.053 0.000 AS CD GU CR _ IPB HG MO NI SE ZN P I Lime Applied Annual Ibs/acre Applied 0.025 0.006 0.441 0.074 0.047 E 0.002 0.049 0.051 0.039 0.245 6.860 Date Lbs(Ac---- ----- -- Cumulative Ibs/acre Applied 0.198 ! 0.028 Permit PAN Limit 0.233 h 0.011 0.116 I 1.316 174 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 1 15.0 1 375.0 i 89.0 1 2,500A NRWASAWPL = NEUSE REGIONAL WASA, NC WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pen 'es sub 'tang false information, including the possibility of fines and impriso ent r knowing violations." 2 f t z-1 SI RE OF LAND APPLIER F—D-417E NR = Not Reported or Not R ired ** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/1/2021 DENR FORM FSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: NEUSE REGIONAL WASA, NC WQ PERMIT #: WQ0034688 FIELD#: NC-LN-00OX6-0-0004- ACRES UTILIZED: 58.7 LAND OWNER: SOVEREIGN REAL ESTATE ANNUAL DRY TONS APPLIED: 151.31 SITE #: NC LN 00OX6 ACRES PERMITTED: 58.7 OPERATOR: MICHAEL GINN PREDOMINANT SOIL SERIES: JOHNS CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: SOYBEANS (SB) CROP 1 MAX. PAN: 174 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) o Site w Name of Crop Type or Cubic Yards (Y) r Cond. Precip volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual g Date or or Wet Tons (W) x % Residual a Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Month Amount } UOM Solids r, DryTonsiAc Source M Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 I Crop 2 I 10/21/2020 705,600.00 (G) 2.1 00 1. 998 NRWASAWPL DRY SUR 0.5 0.40 13,000.00 940.00 33.40 fi 11.696 I SB 9 10/22/2020 913,500.00 (G) 2A90 1.421 NRWASAWPL DRY "0-<1/2" SUR 0.5 OAO 13,000.00 940.00 33.40 15A42 SB 1 1Of23/2020 37,800.00 (G) 2.190 0,059 NRWASAWPL DRY "0-<1!2" SUR 0.5 0.40 13,000.00 940.00 33.40 0.627 SB 4 dy y k E EEEE Oct-20 1,656,900.00 (G) 1 Total 2.578 Total 27.465 0.000 AS �OZ28� CR �EB�A�OMI�03 �IT�_SEAnnual Ibslacre Applied 0.052 y�CD 155 0.516 14.435 Date Lbs1Ac e *.*.. ....« 29.571 1 2.105 0.215 1 0.363 Permit PAN Limit (lbs/acre) 1st Crop,,, Federal C.P.L.R. (Ibslacre)***' 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 3; NRWASAWPL = NEUSE REGIONAL WASA, NC WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant 2=r tong false information, including the possibility of fines and impris+enj for knowing violations." 2 cl 2i SIGA URE OF LAND APPLIER ATE NR = Not Reported or Not Req ' ed **" Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge 0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 **** See Site pH & Lime Application Records Section of Report Printed: 2/1/2021 DENR FORM FSF (12/2006) SECTION 4 SUMM111 ENVIRONMENTAL TECHN❑LOMZ3. INC Arraly0ca1 Laboralorfas September 09, 2020 Chris Wynne Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: NRWASA Dear Chris Wynne: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Order No.: 20081630 Summit Environmental Technologies, Inc. received 1 sample(s) on 8/27/2020 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, Califomia 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho 01100923, Illinois 200061, Indiana C-011-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 2019-155, Oregon 01I200001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah 011009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 32 SUMMIY Summit Environmental Technologies, Inc. Case Narrative 3310 Win St. ENVIRONMENTAL TEC„NQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 20081630 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 9/9/2020 CLIENT: Synagro Project: NRWASA WorkOrder Narrative: 20081630: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 20081630-001A Ignitability S(1030): does not propagate Analytical Sequence QC Notes: 20081630-OOIADUP Ignitability S(1030): does not propagate 20081630-OOIAMS TCLP-SVOC_8270E: High RPD due to suspected sample inhomogeneity. 20081630-OOIAMSD TCLP-SVOC_8270E: High RPD due to suspected sample inhomogeneity. Original Page 2 of 32 MMIT summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S EkiwllOMM@NTALTECHN❑LOG{r,S,INC Cuyahoga Falls, Ohio442� Wo#: 20081630 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-446 Wehsite: httn:11www.settek.co Date: 9/9/2020 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 32 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMMEWAL YECHHOLOGNUS, INC. Cuyahoga Falls, Ohio 44223 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: NRWASA Lab SampleID Client Sample ID 20081630-001 NRWASA Tag No Date Collected 8/26/2020 11:00:00 AM Workorder Sample Summary WO#: 20081630 09-Sep-20 Date Received Matrix 8/28/2020 11:55:00 AM Sludge Page 4 of 32 SUMM' Summit Environmental Technologies, Inc. 3310 Win St. DATES "PORT ENVIRONMENTAL TECHN❑ L0G1E5, IHC Cuyahoga Falls, Ohio 44223 WO#: 20081630 ArWyft cal Laboraloriag TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 20081630-OOIA NRWASA 8/26/2020 11:00:00 AM Sludge Ignitability of Solids (SW-846: 1030) 8/31/2020 2:00:00 PM Percent Solids by SM2540Mod 9/3/2020 4:50:00 PM pH (SW9045D) 8/28/2020 12:37:32 PM Reactive Cyanide (9014/7.3.3.2)-Solid 9/2/2020 12:54:00 PM Reactive Sulfide (9034)/7.3.4.2 9/3/2020 12:54:00 PM TCLP Herbicides by EPA 8321B 9/2/2020 5:00:00 PM 9/3/2020 10:39:00 PM TCLP Mercury Analysis (SW1311/7479/2/2020 5:00:00 PM 9/4/2020 9:45:00 AM 9/4/2020 2:09:00 PM TCLP Metals Analysis (SW1311/60109/2/2020 5:00:00 PM 9/3/2020 11:20:00 AM 9/4/2020 11:19:01 AM TCLP Pesticides Analysis (SW1311/8(9/2/2020 5:00:00 PM 9/3/2020 1:00:00 PM 9/4/2020 11:38:00 PM TCLP Semi-Volatiles Analysis 9/2/2020 5:00:00 PM 9/3/2020 1:00:00 PM 9/3/2020 9:03:00 PM (SW1311/8270) TCLP Volatiles Analysis 9/2/2020 5:00:00 PM 9/4/2020 11:16:00 AM Original Page 5 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20081630 Date Reported: 9/9/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 8/26/2020 11:00:00 AM Lab ID: 20081630-OOIA Project: NRWASA Client Sample ID NRWASA Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW131117470) TCLP Mercury ND 0.00200 mg/L SW7470A SW7470A Analyst: MJM 1 9/4/2020 2:09:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW3010A Analyst: EAM TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND 0.500 mg/L 1 9/4/2020 11:19:01 AM TCLP Badum(Ba) ND 5.00 mg/L 1 9/4/2020 11:19:01 AM TCLP Cadmium(Cd) ND 0.100 mg/L 1 9/4/2020 11:19:01 AM TCLP Chromium(Cr) ND 0.200 mg/L 1 9/4/2020 11:19:01 AM TCLP Lead(Pb) ND 0.500 mg/L 1 9/4/2020 11:19:01 AM TCLP Selenium(Se) ND 0.0500 mg/L 1 9/4/2020 11:19:01 AM TCLP Silver(Ag) ND 0.500 mg/L 1 9/4/2020 11:19:01 AM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW3510C Analyst: SFG TCLP SEMI-VOLATILES ANALYSIS (SW131118270) 1,4-Dichlorobenzene ND 0.200 mg/L 2 9/3/2020 9:03:00 PM 2,4,5-Trichlorophenol ND 0.500 mg/L 2 9/3/2020 9:03:00 PM 2,4,6-Trichlorophenol ND 0.500 mg/L 2 9/3/2020 9:03:00 PM 2,4-Dinitrotoluene ND 0.100 mg/L 2 9/3/2020 9:03:00 PM Cresols, Total ND 10.0 mg/L 2 9/3/2020 9:03:00 PM Hexachloro-1,3-butadiene ND 0.0400 mg/L 2 9/3/2020 9:03:00 PM Hexachlorobenzene ND 0.100 mg/L 2 9/3/2020 9:03:00 PM Hexachloroethane ND 0.200 mg/L 2 9/3/2020 9:03:00 PM Nitrobenzene ND 0.200 mg/L 2 9/3/2020 9:03:00 PM Pentachlorophenol ND 0.500 mg/L 2 9/3/2020 9:03:00 PM Pyridine ND 0.500 mg/L 2 9/3/2020 9:03:00 PM Surr: 2-Fluorophenol 56.9 10 - 157 %Rec 2 9/3/2020 9:03:00 PM Surr: Phenol-d6 65.2 10 - 169 %Rec 2 9/3/2020 9:03:00 PM Surr: Nitrobenzene-d5 65.5 32.1 - 130 %Rec 2 9/3/2020 9:03:00 PM Surr: 2,4,6-Tribromophenol 72.5 45.4 - 166 %Rec 2 9/3/2020 9:03:00 PM Surr: 2-Fluorobiphenyl 65.6 35.7 - 130 %Rec 2 9/3/2020 9:03:00 PM Surr: p-Terphenyl-d14 86.6 74.7 - 145 %Rec 2 9/3/2020 9:03:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original RL Reporting Detection Limit U Samples with CaleVal < MDL Page 6 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20081630 Date Reported: 9/9/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 8/26/2020 11:00:00 AM Lab ID: 20081630-OOIA Project: NRWASA Client Sample ID NRWASA Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW131118081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 73.7 Surr: DCB 82.1 TCLP HERBICIDES BY EPA 8321 B SW8081 SW3510C Analyst: MES 0.125 mg/L 5 9/4/2020 11:38:00 PM 0.250 mg/L 5 9/4/2020 11:38:00 PM 0.0125 mg/L 5 9/4/2020 11:38:00 PM 0.0125 mg/L 5 9/4/2020 11:38:00 PM 0.0125 mg/L 5 9/4/2020 11:38:00 PM 0.0125 mg/L 5 9/4/2020 11:38:00 PM 0.0125 mg/L 5 9/4/2020 11:38:00 PM 10 - 119 %Rec 5 9/4/2020 11:38:00 PM 10 - 119 %Rec 5 9/4/2020 11:38:00 PM SW8321A SW1311M Analyst: BJH 2,4-D ND 0.500 mg/L 50 9/3/2020 10:39:00 PM 2,4,5-TP ND 0.500 mg/L 50 9/3/2020 10:39:00 PM Surr: 2,4-Dichlorophenylacetic aci 105 70 - 130 %Rec 50 9/3/2020 10:39:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 SW1311M Analyst: RMT TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.250 mg/L 50 9/4/2020 11:16:00 AM 1,2-Dichloroethane ND 0.250 mg/L 50 9/4/2020 11:16:00 AM MEK ND 5.00 mg/L 50 9/4/2020 11:16:00 AM Benzene ND 0.250 mg/L 50 9/4/2020 11:16:00 AM Carbon tetrachloride ND 0.250 mg/L 50 9/4/2020 11:16:00 AM Chlorobenzene ND 2.50 mg/L 50 9/4/2020 11:16:00 AM Chloroform ND 0.250 mg/L 50 9/4/2020 11:16:00 AM Tetrachloroethene ND 0.250 mg/L 50 9/4/2020 11:16:00 AM Trichloroethene ND 0.250 mg/L 50 9/4/2020 11:16:00 AM Vinyl chloride ND 0.100 mg/L 50 9/4/2020 11:16:00 AM Surr: 4-Bromofluorobenzene 93.0 70 - 130 %Rec 50 9/4/2020 11:16:00 AM Surr: Di brom ofl uorom ethane 90.3 70 - 130 %Rec 50 9/4/2020 11:16:00 AM Surr: Toluene-d8 98.2 70 - 130 %Rec 50 9/4/2020 11:16:00 AM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original RL Reporting Detection Limit U Samples with CaleVal < MDL Page 7 of 32 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. Analytical Report ENVIRONMENTAL TECHNOLOGIE-3, IRC Cuyahoga Falls, Ohio 44223 (base report) Arralyt9cal Laboralories TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20081630 Website: http://www.settek.com Date Reported: 9/9/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 8/26/2020 11:00:00 AM Lab ID: 20081630-OOIA Project: NRWASA Client Sample ID NRWASA Analyses Result RL Qual Units DF Date Analyzed RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.490 mg/Kg 1 9/2/2020 12:54:00 PM IGNITABILITY OF SOLIDS (SW-846: 1030) SW1030 Analyst: AJT Ignitability <2.2 mm/sec 1 8/31/2020 2:00:00 PM NOTES: does not propagate PERCENT SOLIDS BY SM2540MOD A2540B Analyst: DHC Percent Solids 3.12 % 1 9/3/2020 4:50:00 PM RCI SW9045D Analyst: VVK PH (SW9045D) pH 6.6 s.u.@20.6C 1 8/28/2020 12:37:32 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive 70.0 25.0 mg/Kg 1 9/3/2020 12:54:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original RL Reporting Detection Limit U Samples with CaleVal < MDL Page 8 of 32 Summit Environmental Technologies, Inc. Accreditation Program frSU MM'EF 3310 Win St. Anal�7n tes Report ENOROMMEWAL IrECHNOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20081630 Wehsite: http://www.settek.com 09-Sep-20 Client: Synagro State: NW Project: NRWASA Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 20081630-OOIA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge Percent Solids by SM2540Mod Percent Solids U Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive N Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive N Sludge TCLP Herbicides by EPA 8321B 2,4,5-TP A Sludge TCLP Herbicides by EPA 8321B 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Key Key Key NC WW SCM A Accredited NC WW SCM N Not Accredited NC WW SCM U Unavailabl Original #1 Page 9 of 32 Summit Environmental Technologies, Inc. Accreditation Program MM'EF frSU3310 Win St. Anal�7n tes Report ENVIROMMEWAL IrECHHOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20081630 Wehsite: http://www.settek.com 09-Sep-20 Client: Synagro State: NW Project: NRWASA Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 20081630-OOIA Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM N Not Accredited NC WW SCM U Unavailabl Original #1 Page 10 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT Client: Synagro Project: NRWASA BatchID: 45155 WO#: 20081630 09-Sep-20 Sample ID: MB-45155 SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: 9/2/2020 RunNo: 117455 lient ID: PBS Batch ID: 45155 TestNo: SW8260 SW1311M Analysis Date: 9/4/2020 SegNo: 2958953 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0.00500 MEK ND 0.100 Benzene ND 0.00500 Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.0500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 Surr: 4-Bromofluorobenzene 47.7 Surr: Dibromofluoromethane 44.7 Surr: Toluene-d8 49.6 50.00 95.4 70 130 50.00 89.4 70 130 50.00 99.2 70 130 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 11 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT Client: Synagro Project: NRWASA BatchID: 45168 WO#: 20081630 09-Sep-20 Sample ID: 20081630-001AMS SampType: MS TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 9/3/2020 RunNo: 117450 Dient ID: NRWASA Batch ID: 45168 TestNo: SW8270 SW3510C Analysis Date: 9/4/2020 SegNo: 2958627 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.474 0.200 0.8000 0 59.3 15.2 124 2,4,5-Trichlorophenol 0.716 0.500 0.8000 0 89.4 30.6 152 2,4,6-Trichlorophenol 0.646 0.500 0.8000 0 80.8 27.6 150 2,4-Dinitrotoluene 0.752 0.100 0.8000 0 94.0 58 141 o-Cresol 0.591 0.500 0.8000 0 73.8 26.9 132 Cresols, Total ND 10.0 1.600 0 76.0 27.6 132 Hexachloro-1,3-butadiene 0.495 0.0400 0.8000 0 61.8 -5.3 156 Hexachlorobenzene 0.820 0.100 0.8000 0 103 54.3 142 Hexachloroethane 0.456 0.200 0.8000 0 57.0 1.92 131 Nitrobenzene 0.632 0.200 0.8000 0 79.0 21 135 Pentachlorophenol 0.778 0.500 0.8000 0 97.2 47.4 134 Pyridine ND 0.500 0.8000 0 46.7 -10.3 64.2 Surr:2-Fluorophenol 0.649 1.000 64.9 9.77 146 Surr: Phenol-d6 0.670 1.000 67.0 20.7 130 Surr: Nitrobenzene-d5 0.665 1.000 66.5 13.9 156 Surr:2,4,6-Tribromophenol 0.857 1.000 85.7 27.3 183 Surr:2-Fluorobiphenyl 0.710 1.000 71.0 21.4 153 Surr: p-Terphenyl-d14 1.01 1.000 101 54.8 154 mQMR Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT Client: Synagro Project: NRWASA BatchID: 45168 WO#: 20081630 09-Sep-20 Sample ID: 20081630-001AMSD SampType: MSD TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 9/3/2020 RunNo: 117450 Dient ID: NRWASA Batch ID: 45168 TestNo: SW8270 SW3510C Analysis Date: 9/4/2020 SegNo: 2958628 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.474 0.200 0.8000 0 59.3 15.2 124 0.4744 0 30 2,4,5-Trichlorophenol 0.766 0.500 0.8000 0 95.7 30.6 152 0.7156 6.75 30 2,4,6-Trichlorophenol 0.697 0.500 0.8000 0 87.2 27.6 150 0.6460 7.62 30 2,4-Dinitrotoluene 0.803 0.100 0.8000 0 100 58 141 0.7516 6.59 30 o-Cresol 0.598 0.500 0.8000 0 74.8 26.9 132 0.5908 1.28 30 Cresols, Total ND 10.0 1.600 0 76.8 27.6 132 0 0 30 Hexachloro-1,3-butadiene 0.504 0.0400 0.8000 0 63.0 -5.3 156 0.4948 1.76 30 Hexachlorobenzene 0.832 0.100 0.8000 0 104 54.3 142 0.8204 1.36 30 Hexachloroethane 0.440 0.200 0.8000 0 55.0 1.92 131 0.4560 3.57 30 Nitrobenzene 0.646 0.200 0.8000 0 80.7 21 135 0.6316 2.19 30 Pentachlorophenol 0.819 0.500 0.8000 0 102 47.4 134 0.7780 5.16 30 Pyridine ND 0.500 0.8000 0 20.2 -10.3 64.2 0 0 30 Surr:2-Fluorophenol 0.636 1.000 63.6 9.77 146 0 Surr: Phenol-d6 0.660 1.000 66.0 20.7 130 0 Surr: Nitrobenzene-d5 0.666 1.000 66.6 13.9 156 0 Surr:2,4,6-Tribromophenol 0.910 1.000 91.0 27.3 183 0 Surr:2-Fluorobiphenyl 0.736 1.000 73.6 21.4 153 0 Surr: p-Terphenyl-d14 1.08 1.000 108 54.8 154 0 R Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 13 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT Client: Synagro Project: NRWASA BatchID: 45168 WO#: 20081630 09-Sep-20 Sample ID: MB-45168 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 9/3/2020 RunNo: 117364 lient ID: PBS Batch ID: 45168 TestNo: SW8270 SW3510C Analysis Date: 9/3/2020 SegNo: 2955952 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.543 Surr: Phenol-d6 0.661 Surr: Nitrobenzene-d5 0.619 Surr: 2,4,6-Tribromophenol 0.849 Surr: 2-Fluorobiphenyl 0.593 Surr: p-Terphenyl-d14 0.792 1.000 54.3 10 109 1.000 66.1 10 109 1.000 61.9 19 120 1.000 84.9 10 120 1.000 59.3 22 117 1.000 79.2 34 116 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT Client: Synagro Project: NRWASA BatchID: 45168 WO#: 20081630 09-Sep-20 Sample ID: LCS-45168 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 9/3/2020 RunNo: 117364 Dient ID: LCSS Batch ID: 45168 TestNo: SW8270 SW3510C Analysis Date: 9/3/2020 SegNo: 2955953 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.338 0.100 0.8000 0 42.3 36.4 130 2,4,5-Trichlorophenol 0.669 0.250 0.8000 0 83.6 31.7 132 2,4,6-Trichlorophenol 0.701 0.250 0.8000 0 87.7 31.1 133 2,4-Dinitrotoluene 0.776 0.0500 0.8000 0 97.0 43.3 130 o-Cresol 0.508 0.250 0.8000 0 63.5 32.9 130 Cresols, Total ND 5.00 1.600 0 65.1 31.7 130 Hexachloro-1,3-butadiene 0.382 0.0200 0.8000 0 47.7 31.4 130 Hexachlorobenzene 0.665 0.0500 0.8000 0 83.2 43.1 130 Hexachloroethane 0.372 0.100 0.8000 0 46.5 36.5 130 Nitrobenzene 0.452 0.100 0.8000 0 56.5 39.5 130 Pentachlorophenol 0.675 0.250 0.8000 0 84.4 34 130 Pyridine 0.309 0.250 0.8000 0 38.7 10 130 Surr: 2-Fluorophenol 0.459 1.000 45.9 17.1 130 Surr: Phenol-d6 0.527 1.000 52.7 10 130 Surr: Nitrobenzene-d5 0.482 1.000 48.2 32.6 130 Surr:2,4,6-Tribromophenol 0.838 1.000 83.8 4.43 130 Surr:2-Fluorobiphenyl 0.556 1.000 55.6 41.8 130 Surr: p-Terphenyl-d14 0.785 1.000 78.5 36.4 130 m Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 20081630 09-Sep-20 Client: Synagro Project: NRWASA BatchID: 45175 Sample ID: MB-45175 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 9/3/2020 RunNo: 117398 Client ID: PBS Batch ID: 45175 TestNo: SW6010D SW3010A Analysis Date: 9/4/2020 SegNo: 2956640 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: LCS-45175 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 9/3/2020 RunNo: 117398 Client ID: LCSS Batch ID: 45175 TestNo: SW6010D SW3010A Analysis Date: 9/4/2020 SegNo: 2956643 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.02 0.500 2.000 0 101 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 105 80 120 TCLP Cadmium(Cd) 2.01 0.100 2.000 0 101 80 120 TCLP Chromium(Cr) 2.09 0.200 2.000 0 104 80 120 TCLP Lead(Pb) 2.09 0.500 2.000 0 104 80 120 TCLP Selenium(Se) 2.04 0.0500 2.000 0 102 80 120 TCLP Silver(Ag) 2.07 0.500 2.000 0 104 80 120 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 20081630 09-Sep-20 Client: Synagro Project: NRWASA BatchID: 45175 Sample ID: 20081710-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 9/3/2020 RunNo: 117398 Client ID: Batch= Batch ID: 45175 TestNo: SW6010D SW3010A Analysis Date: 9/4/2020 SegNo: 2956656 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.95 0.500 2.000 0 97.6 70 130 TCLP Barium(Ba) ND 5.00 2.000 1.938 89.7 70 130 TCLP Cadmium(Cd) 1.89 0.100 2.000 0.001973 94.3 70 130 TCLP Chromium(Cr) 1.80 0.200 2.000 0.001061 90.1 70 130 TCLP Lead(Pb) 1.70 0.500 2.000 0 85.2 70 130 TCLP Selenium(Se) 2.11 0.0500 2.000 0.03013 104 70 130 TCLP Silver(Ag) 2.02 0.500 2.000 0.001195 101 70 130 Sample ID: 20081710-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 9/3/2020 RunNo: 117398 Client ID: Batch= Batch ID: 45175 TestNo: SW6010D SW3010A Analysis Date: 9/4/2020 SegNo: 2956659 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.93 0.500 2.000 0 96.5 70 130 1.951 1.12 20 TCLP Barium(Ba) ND 5.00 2.000 1.938 88.1 70 130 0 0 20 TCLP Cadmium(Cd) 1.88 0.100 2.000 0.001973 93.7 70 130 1.889 0.688 20 TCLP Chromium(Cr) 1.79 0.200 2.000 0.001061 89.4 70 130 1.804 0.807 20 TCLP Lead(Pb) 1.70 0.500 2.000 0 85.1 70 130 1.705 0.146 20 TCLP Selenium(Se) 2.10 0.0500 2.000 0.03013 103 70 130 2.108 0.439 20 TCLP Silver(Ag) 2.01 0.500 2.000 0.001195 100 70 130 2.023 0.755 20 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT Client: Synagro Project: NRWASA BatchID: 45175 WO#: 20081630 09-Sep-20 Sample ID: TCLP BLANK 9-3-20 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 9/3/2020 RunNo: 117398 lient ID: PBS Batch ID: 45175 TestNo: SW6010D SW3010A Analysis Date: 9/4/2020 SegNo: 2956678 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 32 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: 45177 TCLP Mercury ND 0.00200 TCLP Mercury 0.00383 0.00200 0.00400 0 95.8 80 120 TCLP Mercury ND 0.00200 Sample ID: 20081640-001AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM Prep Date: 9/4/2020 RunNo: 117406 Client ID: Batch= Batch ID: 45177 TestNo: SW7470A SW7470A Analysis Date: 9/4/2020 SegNo: 2956980 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.0200 0.00400 0.0204 -424 75 125 SQMR Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 32 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: 45177 TCLP Mercury ND 0.0200 0.00400 0.0204 -402 75 125 0 0 20 RS Sample ID: M1132-45177 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 9/4/2020 RunNo: 117406 Client ID: PBS Batch ID: 45177 TestNo: SW7470A SW7470A Analysis Date: 9/4/2020 SegNo: 2956995 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.00200 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 20 of 32 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117088 Sample ID: 20081646-001ADUP SampType: DUP TestCode: pH_Oil(9045D Units: s.u.@21.00 Prep Date: RunNo: 117088 Client ID: Batch= Batch ID: R117088 TestNo: SW9045D Analysis Date: 8/28/2020 SegNo: 2940495 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 6.7 0 0 6.6 0.5 10 Sample ID: 20081675-001ADUP SampType: DUP TestCode: pH_Oil(9045D Units: s.u.@21.3C Prep Date: RunNo: 117088 Client ID: Batch= Batch ID: R117088 TestNo: SW9045D Analysis Date: 8/28/2020 SegNo: 2941046 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 6.8 0 0 6.7 0.3 10 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 21 of 32 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117088 pH 7.0 7.0 0 100 98.6 101.4 pH 7.0 7.0 0 100 98.6 101.4 Sample ID: CHECK 7 SampType: LCS TestCode: pH_NPW(450 Units: s.u.@21.6C Prep Date: RunNo: 117088 Client ID: LCSW Batch ID: R117088 TestNo: SW9045D Analysis Date: 8/28/2020 SegNo: 2941074 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 99.9 98.6 101.4 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 32 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117185 Ignitability 8.14 7.240 0 112 70 130 Ignitability <2.2 0 0 20 NOTES: does not propagate Sample ID: 20081572-001ATRIP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 117185 Client ID: Batch= Batch ID: R117185 TestNo: SW1030 Analysis Date: 8/31/2020 SegNo: 2944140 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability <2.2 0 0 20 NOTES: does not propagate Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 23 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 20081630 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117185 Sample ID: 20081630-001ADUP SampType: DUP TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 117185 lient ID: NRWASA Batch ID: R117185 TestNo: SW1030 Analysis Date: 8/31/2020 SegNo: 2944142 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability NOTES: does not propagate <2.2 0 0 20 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 24 of 32 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117333 Cyanide, Reactive ND 0.495 Cyanide, Reactive 9.25 0.485 10.00 0 92.5 85 115 Cyanide, Reactive 0.524 0.481 0.5000 0 105 65 135 Sample ID: 20081541 -001 AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 117333 Client ID: Batch= Batch ID: R117333 TestNo: SW9014 Analysis Date: 9/2/2020 SegNo: 2952987 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.00 0.485 10.00 0 90.0 75 125 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 25 of 32 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117333 Sample ID: 20081541 -001 AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 117333 Client ID: Batch= Batch ID: R117333 TestNo: SW9014 Analysis Date: 9/2/2020 SegNo: 2952987 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 20081541-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 117333 Client ID: Batch= Batch ID: R117333 TestNo: SW9014 Analysis Date: 9/2/2020 SegNo: 2952988 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.17 0.485 10.00 0 91.7 75 125 8.995 1.93 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 26 of 32 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117334 Sulfide, Reactive ND 25.0 Sulfide, Reactive 3230 25.0 3310 0 97.6 85 115 Sulfide, Reactive 3270 25.0 3310 0 98.8 80 120 Sample ID: 20081541-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 117334 Client ID: Batch= Batch ID: R117334 TestNo: SW9034 Analysis Date: 9/3/2020 SegNo: 2952997 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 3080 25.0 3310 0 93.1 80 120 3270 5.98 30 Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 27 of 32 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,-"-m,.settek.com QC SUMMARY REPORT WO#: 20081630 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117334 Sample ID: 20081541-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 117334 Dient ID: Batch= Batch ID: R117334 TestNo: SW9034 Analysis Date: 9/3/2020 SegNo: 2952997 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifies: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 28 of 32 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20081630 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 09-Sep-20 Client: Synagro Project: NRWASA BatchID: R117416 Sample ID: MB-R117416 SampType: MBLK TestCode: PctSolid_S(2 Units: % Prep Date: RunNo: 117416 Client ID: PBS Batch ID: R117416 TestNo: A2540B Analysis Date: 9/3/2020 SegNo: 2957316 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Percent Solids ND 0 0 Sample ID: 20081819-001ADUP SampType: DUP TestCode: PctSolid_S(2 Units: % Prep Date: RunNo: 117416 Client ID: Batch= Batch ID: R117416 TestNo: A2540B Analysis Date: 9/3/2020 SegNo: 2957319 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Percent Solids 16.6 0 0 16.53 0.362 5 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 29 of 32 sv cQ CD W 0 0 W N Summit Environmental Technologies, Inc. Analysis Request/Chain of Custody 3310 Win Street For Summit Environmental Technokigieq, Inc. use onlynftfta Cuyahoga Falls, Ohio 44223 TeL. 330.253.821 t Fax: 330.253.4489 Page of slur [va. xarrte Ylea�e Print Project Name Aimalvticall Parameters and Methods Company 1;1f rq �? MASH Company 0 ►dress � t +� ' ` �+ ai j►ri I IV r � Project Address ^4 clitm( Phone ,No, 331 _ I0�I Ft [ 1 Report to Client Fax No, Pt z ��ulL] PON ma Client Eil Please L�mai!_ offs JJ W GhhG 6 FA.Spm Qnote Na comes Person ri � s Ir*�i ►+ n ru Sampled by /ti j 5 Mitt �r {r' ` Check if Ohio VAP samples J El # Saawk Yd ndt'ication �� CuMccled 11Mae Collected 9 WA M 6 p a Ln a o Raelin ubl*d 'fbne NoteslComments: ns Received in lab bate 75me Must be appr(wed Rash k e(loegted By-. �� by lab manager f / White and yellow pages should a ccompanY MMPICs to the laborainfy. The clienl retains the pink page, S Xc of Salnp1E Otipa FOR COMPLIANCE YE CERTIFCATION R D No REPORT TO STATE[nW ONLY) YES No If yes, pie-c P,mWidc PWS. STU, & MP •'It iKu ��+n'P0.YF ¢ET, ]n�. euurnca •cost is ingM:iuhlc and will mN rcP,l uw .--I- ai yune 121432 1 PDF created with pdfFactory Pro trial version www.i)dffactory.com Sumrok Enwiron urental T�ft.hrwdirgieN, Inc, Analysis Request/Chain of Cudody 331G Win .k't,ccl Fw SULTunit EwLwiiarmall T64J L 1„00f, Inc. war WL'y paw{l}ahag{ k'a11a, {k7iu22s 7c1' i0.2i;.82.1 I Fllx; ?30.253.d1fi' Ld - �. �� Sk'L Ctlh {:anean4 riWnc �ndp} rm r RY Anudytimt Paratneirm and Methods I rrra # 8�- IO � � e 1 _ ; IT � i `� �s � s, s � t L.4 Nto 101 ��P�� lA rtlu KUL FNu FS77 i�iil f'Ir 1 I I'I&Y5� �slt fFc dls J (jcluFe M19l ml.uL Ils�u} L �+35 a Wq 111 ,4 171Jp I+WI 5SG5p1f LdCJlllil{aI;19R �� L1fLQnrold {'dlrLed HH ' Wi mac- J IUB {AM[L6W¢ �� f 1�1��+" � [NIII M14A!ifJd HiS RFPLX"1f iDpFAIT,lV ON4 M SO �• �' I�i'wFLl ..rc �iw. �Ert a�Y}'W. ,N *&dF[d io Imh ,--.. Igl1G 7iiL! mill $CV'Ia..1oA Fill: tri li] 4i�R:� • i .I� ah • "wl-i'.:a� Irx da, ss� rmi rC�g W d"Filil Fug 12143 2 PDF created with pdfFactory Pro trial version www.r)dffactory.com Page 31 of 32 �� Summit Environmental Technologies, Inc. SU3310 Win St. ENVIRONMENTALTECHNOLOGiES.lftC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafyacal Laboralnrlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.com Client Name: SYN-NC-27028 Work Order Number: 20081630 RcptNo: 1 Logged by: Jennifer C. Richards 8/27/2020 Completed By: Jennifer C. Richards 8/28/2020 12:12:51 PM Reviewed By: Sara E. Kidd 8/28/2020 2:29:02 PM Xl�ltl4'1G+GL Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? FedEx Lop In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ g. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes V No ❑ 15. Is it clear what analyses were requested? Yes 0 No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 11.4 Goodl Not Present Page 32 of 32 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name:. Neuse Regional Water and Sewer Authority WQ Permit Number: WQ0034688 WWTP Name: Neuse Regional Water Treatment Plant NPDES Number: NCO088111 Monitoring Period: From 01/01/20 To 12/31/20 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) It. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class A: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion to alternative the ER Analytical PERMIT DOES NOTD 1. T E Technique Fecal Coliform MONITORING FOR PATHOGEN REDUCTION bacteria (i+ lieu of fecal Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) _ Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) _ Option/Alt. 9 (Injection) Option/Alt. 10 (Incorporation) No vector attraction reduction alternatives were performed X CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Harold Herring Executive Director NRWASA Preparer Name Title ty mt) Sign atur f Preparer* Date Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) SECTION 6 Agricultural Lime Application Log Year: 2020 Project: Neuse Regional WASA Field Soil Lime Requirement Tons/Acre Date Applied (state -county -site -field) pH (tons/acre) Applied NC-LN-X6-1 5.7 0.4 NC-LN-X6-2 5.8 0.3 NC-LN-X6-3 5.8 0.3 0.6 NC-LN-X6-4 5.6 NC-LN-X5-1 5.7 0.5 NC-LN-X5-2 5.2 1 NC-LN-X5-3 6.1 0 *Lime will be applied in Spring 2021 SECTION 7 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011205 Client: Brandon Garner Advisor: Chris Wynne vo- Predictive 2811 Barrus Rd Synagro LLC La Grange, NC 28551 284 Boger Road .'..,$' Soil Report Mehlich-3 Extraction Mocksville, NC27028 _ Sampled County: Lenoir Links to Helpful Information Client ID: 364809 Advisor ID: 509090 Sampled: 10/23/2020 Received: 10/29/2020 Completed: 11/13/2020 Farm: In-x5 Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Com. Bermuda/Bahia 0.5 100-150 0 60 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.71 1.16 5.7 73 1.5 5.7 86 41 53 17 84 100 77 95 95 807 0.1 2 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Com. Bermuda/Bahia 1.0 100-150 20 90 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.71 1.19 4.0 54 1.8 5.2 65 26 40 11 122 91 72 133 133 721 0.1 3 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Com. Bermuda/Bahia 0.0 100-150 0 40 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.81 1.14 8.0 83 1.4 6.1 94 53 71 9 85 116 86 69 69 675 0.1 1 North Carolina Tobww Trust Fw►d C47mmisslan Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011205 Brandon Garner Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011229 Client: Brandon Garner Advisor: Chris Wynne vo- Predictive 2811 Barrus Rd Synagro LLC La Grange, NC 28551 284 Boger Road .'..,$' Soil Report Mehlich-3 Extraction Mocksville, NC27028 _ Sampled County: Lenoir Links to Helpful Information Client ID: 364809 Advisor ID: 509090 Sampled: 10/19/2020 Received: 10/29/2020 Completed: 11/13/2020 Farm: In-x6 Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.4 0 0 10 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 1.80 1.24 5.8 78 1.3 5.7 100 78 55 16 98 80 58 94 94 552 0.1 2 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.3 0 20 20 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 1.31 1.21 4.1 72 1.2 5.8 54 64 50 14 117 72 53 78 78 805 0.1 2 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.3 0 10 30 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 1.43 1.21 3.8 68 1.2 5.8 57 58 47 13 116 76 56 91 91 726 0.1 3 North Carolina r Tobww Trust FwW C47mmisslan Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011229 Brandon Garner Page 2 of 3 Sample ID: 4 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.6 0 0 20 0 0 0 0 0 0 Note: 3 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 1.87 1.19 4.6 65 1.6 5.6 62 67 44 14 92 56 44 70 70 495 0.1 2 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011229 Brandon Garner Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm