WQ0000020 Aville Arpt Surface Water Monitoring Nov 2017

synTer
TECHNICAL MEMORANDUM
Date: December 21, 2017 File: 1026.02.44
To: John.Toepfer, Duke Energy
Cc: Kathy Webb, Todd Plating
From: Brian Wilker, NC LG #2546
Area of Wetness Inspection and Sampling Report- November 2017
Subject: Asheville Airport Structural Fill-Area 1
BACKGROUND
The Asheville Airport is located near Arden,North Carolina, approximately 13 miles south of
Asheville, North Carolina. Beneficial reuse of coal ash from the nearby Asheville Steam Electric
Plant,owned by Duke Energy Progress,LLC(Duke Energy), occurred at the Asheville Airport
from 2008 to 2015. The ash was used as structural fill for the construction of one additional taxi
way as well as a potential future hangar construction site.
Structural Fill-Area 1 consists of two primary cells, an east cell and west cell.Historically, a
dendritic headwater drainage existed in the southern portion of the Structural Fill-Area 1 and
continued as a blue-lined stream toward the northern property boundary of the airport.
Recently, an observable increase in groundwater discharges to surface water in lowland areas
and along slopes of the east and west cells of Structural Fill-Area 1 have been documented. In a
letter dated November 17,2017(Davidson to Draovitch),Duke Energy received a Notice of
Violation(NOV)regarding violations of the structural fill permit WQ0000020.SynTerra
conducted two separate field surveys and sampling events in Structural Fill-Area 1 in
November 2017.Photographs taken during each field investigation are included in Attachment
A.
FIELD ASSESSMENTS AND SAMPLING
November 01, 2017
On November 01,2017,SynTerra performed site reconnaissance and split samples with NCDEQ
of recognized surface water locations within Structural Fill-Area 1 (Figure 1).Seven surface
water locations (SWl-Al,SW-3A1,SW4-Al, SW5-Al,SW6-Al,SW7-Al, SW8-Al) in Area 1
were sampled for analysis of total and dissolved phase metals, alkalinity, chloride, and sulfate
(Table 1). SW7-Al was a stagnant puddle at the eastern cell toe-of-slope with limited volume of
water, and was only sampled for dissolved metals due to volume limitations and turbidity(out
of range). The analytical laboratory report for these samples is presented in Attachment B.The
field sampling logs associated with these samples are included in Attachment C.
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Structural
Fill-Area 1 AOW Inspection and Sampling Memo.docx

Area of Wetness Inspection and Sampling Report December 21,2017
Asheville Airport Structural Fill-Area 1 Page 2
November 29, 2017
On November 29,2017,SynTerra conducted an additional groundwater/surface water
inspection of the east and west cells of Area 1 in response to the NOV received November 17,
2017. Area 1,from the top of slope of the east and west cells to lowland areas (e.g. historical
retention basins),was inspected for groundwater seepage and wetted areas.For this field
assessment, standard operating procedures (SOP)for the Duke Energy semi-annual"area of
wetness" (AOW) inspections were followed.The last recordable rain event prior to this
inspection occurred on November 18,2017(0.13 inches).
Identified areas of groundwater seepage were flagged and surveyed for latitude/longitude and
elevation in feet. Samples were collected from six surface water locations and analyzed for
parameters included in the airport structural fill permit as well as dissolved phases of metals.
These analytical results are not yet available,but will be submitted with an evaluation in a
future report upon availability. The field sampling logs are included in Attachment C.
Two of the surface water locations sampled on November 29,2017 were also sampled on
November 01,2017. One location, designated SW4S-Al, is most likely representative of SW4-Al
(as sampled on November 01,2017),however the groundwater was emerging approximately 10
feet north of the previous (SW4-Al) sample location. The seep channel of SW4-Al sampled in
the beginning of November no longer contained flow on November 29,2017. Flow observed at
SW8-Al had also decreased from conditions observed on November 01,2017, and was not
sufficient to sample.
Stagnant water from three of the surface water sample locations (SW1-Al,SW6-Al, and SW7-
A1)was sampled on November 01,2017. Since stagnant water may not be representative of
actual groundwater emerging from the subsurface, the AOW SOP does not recommend
sampling stagnant water. Stagnant conditions were again noted at these locations on November
29,2017 and therefore not sampled. The reinforced culvert connected to the pooled water at
SW1-Al was dry(Attachment A),with flowing water heard within but not visible.Note this
location has been intermittently sampled under the NPDES permit as SW1-Al,however the
intended location for permitting purposes was the 18" culvert immediately west of this pool
(Figure 1). This location was designated as SW9-Al and sampled during this investigation.
A new seep was found upwelling at the toe of slope in the western cell, discharging to the small
retention basin upgradient of SW3-Al (Figure 1). A sample was collected from this location and
designated SW10-Al. A spring downgradient of the eastern cell was also sampled and
designated SW11-Al.This location was assessed on November 01,2017 with NCDEQ as a
potential additional background location,however was determined to contain more
groundwater input from beneath I-26 and thus not related to the structural fill.
At most locations inspected on November 29,2017, an observable increase in iron bacteria/floc
mass was present,especially at SW3-Al. A photographic comparison between the beginning
and end of November at SW3-Al is included in Attachment A.
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Fill-Area 1 AOW Inspection and Sampling Memo.docx

Area of Wetness Inspection and Sampling Report December 21,2017
Asheville Airport Structural Fill-Area 1 Page 3
DATA EVALUATION AND CONCLUSIONS
The French Broad River in the vicinity of the Asheville Airport structural fills is classified as
Class B waters. Note the 15A NCAC 02B standards for Class B waters(2B)presented in Table 1
are for reference purposes only, as the analytical results from the one-time samples displayed
do not meet determinative criteria for compliance with an acute or chronic metals standard as
outlined in 15A NCAC 02B .0211(11)(e).
On November 01,2017, the concentration of dissolved arsenic in SW8-Al was detected greater
than the chronic freshwater metals standard outlined in 15A NCAC 02B .0211(11)(b)(ii).
Dissolved oxygen results for several samples were reported below the minimum instantaneous
value of 4.0 mg/L,however these sample locations may qualify for a lower standard value
based on 15A NCAC 02B .0211(6). One pH value (SW1-Al,5.6) and one turbidity value (SW7-
A1, out of range) were not within the 2B standards. No other analytical results were reported
greater than the 2B standards for surface water samples collected November 1,2017.
For evaluating potential impacts to groundwater and surface water from coal ash,indicator
constituents were selected in general accordance with Tier 1 procedures outlined in the
Groundwater Quality Signatures for Assessing Potential Impacts for Coal Combustion Product Leachate
(EPRI,2012). Constituents selected for this evaluation based on site-specific information
included boron, strontium, and sulfate. Samples impacted from coal ash associated with the
structural fills have the potential to show elevated concentrations of these constituents.
Boron is not typically detected in background groundwater, and is highly mobile in
groundwater. Therefore boron is widely considered to.be an indicator constituent when
evaluating data for coal ash impacts. Four of the seven surface water results collected(SW4-Al,
SW5-Al,SW7-Al,SW8-Al) contained boron greater than the method reporting limit of 50 µg/L.
SW8-Al contained the greatest concentration of boron in both total and dissolved phases (1,290
and 1,380 µg/L), approximately one order of magnitude greater than the other detections. There
is no 2B standard for boron. For reference, the groundwater(2L) standard for boron is 700 µg/L.
Elevated strontium concentrations in the four samples with detectable boron may indicate coal
ash impacts, specifically in SW5-Al,SW7-Al, and SW8=A1.However,the dissolved
concentrations detected in SW7-Al (1,200 µg/L) and SW8-Al (2,240 µg/L)were much greater
than the detection in SW5-Al (331 µg/L). SW7-Al was only analyzed for dissolved metals.
There are no 2B or 2L standards for strontium.
The greatest sulfate concentration, consistent with boron and strontium,was detected at SW8-
Al (32 mg/L). The next greatest concentration was detected in SW5-Al (9.9 mg/L);SW7-Al was
not analyzed for sulfate. There is no 2B standard for sulfate. For reference,the 2L standard for
sulfate is 250 mg/L.
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Structural
Fill-Area 1 AOW Inspection and Sampling Memo.docx

Area of Wetness Inspection and Sampling Report December 21,2017
Asheville Airport Structural Fill-Area 1 Page 4
In summary:
0 Four wet areas were identified,in addition to previously documented wet areas,by
SynTerra along the slope or toe of slope in Structural Fill-Area 1.These areas include
Syn1, Syn2,Syn3, and SW7-AI.
Four areas (SWO-Al, SW8-A1, SW10-Al, SW11-Al) of active groundwater seepage
were identified and surveyed near or below the toe of slope in Structural Fill-Area 1.
'01 Seven surface water samples were collected from Structural Fill-Area 1 on November
01,2017.
h Six surface water samples were collected from Structural Fill-Area 1 on November 29,
2017.
y Two locations (SW3-Al,SW5-Al) were sampled in both events.
,6i Groundwater interaction with surface water does not appear to be causing 2B
exceedances. Subsequent monitoring could indicate future impacts to surface water in
Structural Fill-Area 1.
,67 Four out of seven(4 of 7) surface water samples taken November 01,2017,may indicate
varying concentrations of constituents associated with coal ash.
Figure 1 provides a visual layout of sample locations and dates of sample collection.
Please contact me with any questions or concerns.Thank you for the opportunity to provide our
services.
Figures:
Figure 1 Structural Fill-Area 1 Site Layout Map
Tables:
Table 1 Surface Water Analytical Results
Attachments:
Attachment A Photographic Log
Attachment B Analytical Laboratory Report
Attachment C Field Sampling Logs
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Structural
Fill-Area 1 AOW Inspection and Sampling Memo.docx

Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
FIGURE 1
SITE LAYOUT MAP
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo Structural
Fill-Area 1 AOW Inspection and Sampling Memo.docx

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LEGEND 1.ik
0 SURFACE WATER COLLECTED 11-01-2017 7.
00Iri/; SURFACE WATER COLLECTED 11-01-2017 AND 11-29-2017
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SURFACE WATER COLLECTED 11-29-2017
Q5 REVIEW BOUNDARY MONITORING WELL
COAL COMBUSTION PRODUCT LIMITS
REVIEW BOUNDARY
GRAPHICSCALE
50 0 50 100 FIGURE I
-COMPLIANCE BOUNDARY
SITE LAYOUT MAP IN FEET
PROPERTY LINE(APPROXIMATE)
DUKE ENERGY PROGRESS
SAMPLE COLLECTION INFORMATION:
SAMPLES COLLECTED ON NOVEMBER 1.2017 BY SYNTERRA AND NCDEQ. AREA I
SAMPLES COLLECTED ON NOVEMBER 29.2017 BYSYNTERRA.
STRUCTURAL FILL
SOURCE DRAWN BY.JOHN CHASTAIN DATE'IW15/2017 IEVILLE REGIONAL AIRPORT
MARCH 6,'2015 AERIAL PHOTOGRAPH OBTAINED FROM NG ONE MAP GEOSPATIAL PORTAL AT
BRIAN I
http'.//data.nconemap.00m/geoponaV�talog/mster/download.page dp PROJECT MANAGER MILKER
wsN�119"A 14&-,4 1"L-P I M.1,K-R 1;�11�14�vlgw_L�=_rp."Iffit"Vlku Jpxlll;aznm?&&u�9&111 4wl env_wm�lm_ LAYOUT..FIG I(SITE I AY01 IT MAP) ARDEN, NORTH CAROLINA
S&ME DRAWING TTILED'GROUNDWATER FLOW MAP STRUCTURAL FILV,DATED 1246-2010. lifiv..'llm .... i0l"t-1.10

Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
TABLE 1
SURFACE WATER ANALYTICAL RESULTS
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Structural
Fill-Area 1 AOW Inspection and Sampling Memo.docx

TABLE 1
SURFACE WATER ANALYTICAL RESULTS
ASHEVILLE AIRPORT STRUCTURAL FILL-AREA 1
ARDEN, NC
Analytical Parameter pH ORP DO Spec Cond Turbidity Temp Alkalinity Aluminum Antimony Arsenic Barium Beryllium Bi-carbonate Boron [Calcium Cadmium Carbonate Chloride Chromium
Alkalinity Alkalinity
Reporting Units S.U. mV mg/L umhos/cm NTU Deg C mg/L ug/L ug/L ug/L ug/L ug/L mg/L ug/L I mg/L ug/L mg/L mg/L ug/L
Phase -- -- -- -- -- -- -- T D T D T D T D T D -- T D -- T D -- -- T D
_ 15A'NCAC 02B(Class"6) 6 0=9 Oi NE 4.0`1` ' NE 50"+Z __;ts;3�.; NE NE NE NE NE NE 150 NE NE NE G 5 NE NE NE NE NE :O 15_'4 NE NE NE 24_,°{
Location ID L�Sample FIELD PARAMETERS ANALYTICAL RESULTS
Collection Date
SW1-Al 11/1/2017 5'6 y= 108.9 T.38 1 99.2 2.38 12 28.8 15 8 <1 <1 <1 <1 40 43 <1 <1 28.8 <50 <50 7.43 <0.1 <0.1 <5.0 10 <1 <1
SW3-A1 11/1/2017 6.4 79.2 6.78 98 1.95 13 23.4 20 <5 <1 <1 <1 <1 37 38 <1 <1 23.4 <50 <50 8.04 <0.1 <0.1 <5.0 11 <1 <1
SW4-Al 11/1/2017 6.1 106 3'51 108 14.1 12 29.3 291 7 <1 <1 <1 <1 19 19 <1 <1 29.3 85 93 7.18 <0.1 <0.1 <5.0 6.3 <1 <1
SWS-Al 11/1/2017 6.6 7.5 6.52 217 4.93 9 86.5 8 <5 <1 I <1 <1. <1 42 47 <1 <1 86.5 168 191 23.5 <0.1 <0.1 <5.0 11 <1 <1
SW6-Al 11/1/2017 6.2 45.2 2 94 78.8 3.01 11 14.7 54 16 <1 <1 2.59 2.8 27 35 <1 <1 14.7 <50 <50 4.11 <0.1 <0.1 <5.0 7.9 <1 <1
SW7-Al 11/1/2017 7.2 -54.6 112 534 OOf 19 NA NA 11 NA <1 NA 1.7 NA 67 NA <1 NA NA 351 NA NA <0.1 NA NA NA <1
SWS-Al 11/1/2017 6.9 -89.5 O';fi8 LL 937 4.1 15 523 65 39 <1 <1 219 2'17''=, 219 230 L <1 <1 523 1290 1380 147 <0.1 <0.1 <5.0 3.8 <1 <1
_ Prepared by: BDW Checked by: TDP
Notes:
Values for 15A NCAC 02B,Class B(French Broad River)Ammended Effective January 1,2015.
The lower value of either the acute or chronic standard outlined in 15A NCAC 02B.0211(11)(b)is displayed.Also note the data displayed represents a one-time,single sample;therefore,compliance with either the acute or chronic standard may not be determined based on 15A NCAC 02B.0211 (11)(e).
<-concentration not detected at or above the reporting limit
T-total phase mg/L-milligrams per liter NE-not established Temp-temperature
D-dissolved phase umhos/cm-micro ohms per centimeter ORP-oxidation reduction potential Spec Cond-specific conductance
OOR-out of range ug/L-micrograms per liter DO-dissolved oxygen
S.U.-standard units NTU-nephelometric turbidity unit Deg C-degrees Celcius
mV-millivolts NA-not analyzed - not applicable
1.Dissolved oxygen values presented are instantaneous values- 15A NCAC 02B.0202(40).
2.Per 15A NCAC 02B.0211(21),turbidity in the receiving water shall not exceed 50 NTU in streams not designated as trout water(French Broad River).
3.The Site is designated as mountain/upper piedmont waters;temperature standard based on 15A NCAC 02B.0202(40).
4.Hardness-dependent dissolved metals standards for cadmium,chromium(III),copper,lead,nickel,and zinc are based on the minimum applicable instream hardness of 25 mg/L per 15A NCAC 02B.0211(11)(c).
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TABLE 1
SURFACE WATER ANALYTICAL RESULTS
ASHEVILLE AIRPORT STRUCTURAL FILL-AREA 1
ARDEN, NC
.-[Analytical Parameter Cobalt Copper Iron Lead Magnesium Manganese Mercury Molybdenum Nickel Potassium Selenium Silver Sodium Stro ntium Sulfate Thallium Total Hardness Vanadium Zinc
Reporting Units ug/L ug/L ug/L ug/L mg/L ug/L ug/L ug/L ug/L mg/L ug/L ug/L mg/L ug/L mg/L ug/L mg/L(CaCO3) ug/L ug/L
Phase T D T D T D T D -- T D T D T D T D -- T D T D -- T D -- T D -- T D T D
SSA NC-AC 02B(C(ass B) NE NE NE 2_T4 NE NE NE U 54° NE NE NE U. b2 NE NE NE NE 16° NE 6 NE NE O 6& NE NE NE NE NE NE NE NE NE NE 3
Location ID Sample ANALYTICAL RESULTS
Collection Date
SWl-Al 11/1/2017 2.12 2.06 <1 <1 1190 1200 <0.2 <0.2 2.48 406 466 <0.05 <0.05 <1 <1 <1 <1 1.49 <1 <1 <0.3 <0.3 4.23 69 75 1.5 <0.2 <0.2 28.8 <0.3 <0.3 10 12
SW3-Al 11/1/2017 <1 <1 <1 <1 288 192 <0.2 <0.2 3.41 221 220 <0.05 <0.05 <1 <1 <1 <1 1.72 <1 <1 <0.3 <0.3 5.26 63 67 2.8 <0.2 <0.2 34.1 <0.3 <0.3 9 7
SW4-Al 11/1/2017 1.35 1.31 <1 <1 2710 1750 <0.2 <0.2 3.93 428 476 <0.05 <0.05 <1 <1 <1 <1 1.54 <1 <1 <0.3 <0.3 3.6 78 84 7.9 <0.2 <0.2 34.1 0.421 <0.3 <5 <5
SW5-Al 11/1/2017 1.48 1.52 <1 <1 2210 2110 <0.2 <0.2 7.97 1000 1070 <0.05 <0.05 2.34 2.36 <1 <1 3.29 <1 <1 <0.3 <0.3 4.4 312 331 9.9 <0.2 <0.2 91.6 <0.3 <0.3 <5 <5
SW6-Al 11/1/2017 <1 1.25 <1 <1 5110 7050 <0.2 <0.2 1.94 188 262 <0.05 <0.05 <1 <1 <1 <1 2.01 <1 <1 <0.3 <0.3 2.8 36 43 6.2 <0.2 <0.2 18.3 0.396 <0.3 <5 <5
SW7-A1 11/1/2017 NA 2.04 NA 1.06 NA 140 NA <0.2 NA NA 2080 NA <0.05 NA 14.7 NA I <1 NA NA <1 <0.3 <0.3 NA NA 1200 NA NA <0.2 NA NA 0.508 NA 10
SW8-A1 11/1/2017 18.1 17.8 <1 <1 2160 2390 <0.2 <0.2 31 9420 9820 <0.05 <0.05 151 149 1.24 1.09 4.42 <1 <1 <0.3 <0.3 7.17 2180 2240 32 <0.2 <0.2 439 0.543 <0.3 <5 <5
Prepared by: BDW Checked by: TDP
Notes:
Values for 15A NCAC 02B,Class B(French Broad River)Ammended Effective January 1,2015.
The lower value of either the acute or chronic standard outlined in 15A NCAC 02B.0211(11)(b)is displayed.Also note the data displayed represents a one-time,single sample;therefore,compliance with either the acute or chronic standard may not be determined based on 15A NCAC 02B.0211 (11)(e).
<-concentration not detected at or above the reporting limit
T-total phase mg/L-milligrams per liter NE-not established Temp-temperature
D-dissolved phase umhos/cm-micro ohms per centimeter ORP-oxidation reduction potential Spec Cond-specific conductance
OOR-out of range ug/L-micrograms per liter DO-dissolved oxygen
S.U.-standard units NTU-nephelometric turbidity unit Deg C-degrees Celcius
mV-millivolts NA-not analyzed ---not applicable
1.Dissolved oxygen values presented are instantaneous values- 15A NCAC 02B.0202(40).
2.Per 15A NCAC 02B.0211(21),turbidity in the receiving water shall not exceed 50 NTU in streams not designated as trout water(French Broad River).
3.The Site is designated as mountain/upper piedmont waters;temperature standard based on 15A NCAC 02B.0202(40).
4.Hardness-dependent dissolved metals standards for cadmium,chromium(III),copper,lead,nickel,and zinc are based on the minimum applicable instream hardness of 25 mg/L per 15A NCAC 02B.0211(11)(c).
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Table 1 Surface Water Analytical Results.xlsx Page 2 of 2

Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
ATTACHMENT A
PHOTOGRAPHIC LOG
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Fill-Area 1 AOW Inspection and Sampling Memo.docx

Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
PHOTOGRAPHIC LOG
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Photograph 1. SW1-Al- concrete headwall at the northern
discharge of south to north culvert beneath Area 1 (taken
November 29, 2017).
1
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Attachment
A-Photographic Log.docx

Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
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Photograph 2. SW1-Al- dry concrete culvert(taken November
29, 2017).View is toward the south, taken from drain gate (see
Photograph 1)..
2
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Attachment
A-Photographic Log.docx

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Asheville Airport-
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Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
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Photograph 8. SW5-Al- downstream end of culvert draining the
historic storm water retention basin. View is toward the south
(taken November 29,2017).
8
Pt'\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Attachment
A-Photographic Log.docx

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Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
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Photograph 10. SW7-Al-no apparent flow, seepage at toe of
repaired slope. Sample collected for dissolved metals analysis
only. View is toward the east (taken November 01,2017).
10
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Attachment
A-Photographic Log.docx

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12
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Asheville Airport-Structural Fill Area 1 SynTerra
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Photograph 14. SW10-Al- seep (upwelling of groundwater) at
west cell toe-of-slope basin(taken November 29, 2017).
14
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Attachment
A-Photographic Log.docx

Area of -•ness Inspection and Sampling December 1
Asheville Airport-
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downgradient of east cell in Area 1 (taken November 29, 2017).
15
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Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
ATTACHMENT B
ANALYTICAL LABORATORY REPORT
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Structural
Fill-Area 1 AOW Inspection and Sampling Memo.docx

Revised Report
KE Analytical Laboratory Page 1 of47
ENERGY.
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex-MG03A2
Phone:[phone] Fax: [phone]
Order Summary Report
Order Number: J17110036
Project Name: AVL Airport Fill Area 1--Surface Water(DEQ Split)
Customer Name(s): John Toepfer
Customer Address: 200 CP and L Drive
Arden,NC 28704
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: Date: 12/22/2017
(Signature) 4- 6-V Waxi
Peggy endall
Program Comments:
This is a revised report and supercedes the original dated 11/22/17. The Total Ag(LL) reporting limit was incorrect.
At the customer's request,turbidity was analyzed for all samples but SW7-A1.The sample aliquots were taken from the
alkalinity containers.
Data Flags&Calculations:
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis(sample results)
under the qualifiers heading. All results are reported on a dry wQJght basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative.An estimation of
the uncertainty of measurement for the results in the report is available upon request.This report shall not be reproduced,except
in full,without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions.The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package,Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub-contracted Laboratory Results, Customer Specific Data Sheets, Reports&
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody(COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina(DENR) Certificate#248,South Carolina
(DHEC) Laboratory ID#99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Revised Report
Sample Us & Descriptions: Page 2 of47
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2017037951 ASHEVILLE 01-Nov-17 9:10 AM Brian Wilker SW1-Al
2017037952 ASHEVILLE 01-Nov-17 10:50 AM Brian Wilker SW3-A1
2017037953 ASHEVILLE 01-Nov-17 2:40 PM Brian Wilker SW4-A1
2017037954 ASHEVILLE 01-Nov-17 12:42 PM Brian Wilker SW5-A1
2017037955 ASHEVILLE 01-Nov-17 12:10 PM Brian Wilker SW6-A1
2017037956 ASHEVILLE 01-Nov-17 2:05 PM Brian Wilker SW7-A1
2017037957 ASHEVILLE 01-Nov-17 1:25 PM Brian Wilker SW8-A1
7 Total Samples

Revised Report
Page 3 of 47
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals ❑d Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. Yes ❑ No
Report Sections Included:
d❑ Job Summary Report d❑ Sub-contracted Laboratory Results
�/❑ Sample Identification ❑ Customer Specific Data Sheets, Reports,&Documentation
❑ Technical Validation of Data Package ❑ Customer Database Entries
❑� Analytical Laboratory Certificate of Analysis Chain of Custody
❑ Analytical Laboratory QC Report ❑ Electronic Data Deliverable(EDD)Sent Separate]
Reviewed By: DBA Account Date: 11/22/2017

C:�:Jficate of Laborator Anal S15` Revised Report
y y Page 4 of 47
This report shall not be reproduced, except in full.
Order#A 7110036
Site: SW 1-Ai Sample#: 2017037951
Collection Date: 11/01/2017 09:10 AM Matrix: SURF WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
ALKALINITY(FIXED END POINT 4.5)-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 10 mg/L 0.2 2 EPA 300.0 11/06/2017 15:40 BGN9034
Sulfate 1.5 mg/L 0.2 2 EPA 300.0 11/06/2017 15:40 BGN9034
MERCURY(COLD VAPORY IN WATER
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/03/2017 14:09 DMFRANC
Mercury Dissolved(cold vapor)in Water(Filtered)
Mercury(Hg) <,0.05 ug/L 0.05 1 EPA 245.1 11/09/2017 13:05 DMFRANC
DISSOLVED METALS BY ICP
Aluminum(AI) 0.008 mg/L 0.005 1 EPA 200.7 11/17/2017 10:18 JJMACKE
Barium(Ba) 0.043 mg/L 0.005 1 EPA 200.7 11/17/2017 10:18 JJMACKE
Boron(B) <0.05 mg/L 0.05 1 EPA 200.7 11/17/2017 10:18 JJMACKE
Iron(Fe) 1.20 mg/L 0.01 1 EPA 200.7 11/17/2017 10:18 JJMACKE
Manganese(Mn) 0.466 mg/L 0.005 1 EPA 200.7 11/17/2017 10:18 JJMACKE
Strontium(Sr) 0.075 mg/L 0.005 1 EPA 200.7 11/17/2017 10:18 JJMACKE
Zinc(Zn) 0.012 mg/L 0.005 1 EPA 200.7 11/17/2017 10:18 JJMACKE
UNDIGESTED METALS BY ICP
Calcium(Ca) 7.43 mg/L 2 1 EPA 200.7 11/17/2017 15:17 JJMACKE
Magnesium(Mg) 2.48 mg/L 0.005 1 EPA 200.7 11/17/2017 15:17 JJMACKE
Potassium(K) 1.49 mg/L 0.1 1 EPA 200.7 11/17/2017 15:17 JJMACKE
Sodium(Na) 4.23 mg/L 0.05 1 EPA 200.7 11/17/2017 15:17 JJMACKE
Total Hardness(Ca and Mg) 28.8 mg/L 0.045 1 EPA 200.7 11/17/2017 15:17 JJMACKE
(CaCO3)
TOTAL RECOVERABLE METALS BY ICP
Aluminum(AI) 0.015 mg/L 0.005 1 EPA 200.7 11/09/2017 14:39 JJMACKE
Barium(Ba) 0.040 mg/L 0.005 1 EPA 200.7 11/09/2017 14:39 JJMACKE
Boron(B) <0.05 mg/L 0.05 1 EPA 200.7 11/09/2017 14:39 JJMACKE
Iron(Fe) 1.19 mg/L 0.01 1 EPA 200.7 11/09/2017 14:39 JJMACKE
Manganese(Mn) 0.406 mg/L 0.005 1 EPA 200.7 11/09/2017 14:30 JJMACKE
Strontium(Sr) 0.069 mg/L 0.005 1 EPA 200.7 11/09/2017 14:39 JJMACKE
Zinc(Zn) 0.010 mg/L 0.005 1 EPA 200.7 11/09/2017 14:39 JJMACKE

Revised Report
CeRiTicate of Laboratory Analysis Page 5 of47
This report shall not be reproduced, except in full.
Order#J17110036
Site: SW 1-Ai Sample#: 2017037951
Collection Date: 11/01/2017 09:10 AM Matrix: SURF WW
Analyse Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 1.1/08/2017 21:03 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Cobalt(Co) 2.06 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:03 CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Cobalt(Co) 2.12 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
t
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/10/2017 12:16 CWSPEN3
TURBIDITY-(Analysis Performed by Pace Laboratories)
Turbidity Complete Vendor Method V_PACE

Certificate of Laborator Anal sis Revised Report
y y Page 6 of 47
This report shall not be reproduced, except in full.
Order#A 7110036
Site: SW3-A1 Sample#: 2017037952
Collection Date: 11/01/2017 10:50 AM Matrix: SURF WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
ALKALINITY(FIXED END POINT 4.5)-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L 0.2 2 EPA 300.0 11/06/2017 15:57 BGN9034
Sulfate 2.8 mg/L 0.2 2 EPA 300.0 11/06/2017 15:57 1 BGN9034
MERCURY(COLD VAPOR)IN WATER
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/03/2017 14:16 DMFRANC
Mercury Dissolved(cold vapor)in Water(Filtered)
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/09/2017 13:07 DMFRANC
DISSOLVED METALS BY ICP
Aluminum(Al) <0.005 mg/L 0.005 1 EPA 200.7 11/17/2017 10:31 JJMACKE
Barium(Ba) 0.038 mg/L 0.005 1 EPA 200.7 11/17/2017 10:31 JJMACKE
Boron(B) <0.05 mg/L 0.05 1 EPA 200.7 11/17/2017 10:31 JJMACKE
Iron(Fe) 0.192 mg/L 0.01 1 EPA 200.7 11/17/2017 10:31 JJMACKE
Manganese(Mn) 0.220 mg/L 0.005 1 EPA 200.7 11/17/2017 10:31 JJMACKE
Strontium(Sr) 0.067 mg/L 0.005 1 EPA 200.7 11/17/2017 10:31 JJMACKE
Zinc(Zn) 0.007 mg/L 0.005 1 EPA 200.7 11/17/2017 10:31 JJMACKE
UNDIGESTED METALS BY ICP
Calcium(Ca) 8.04 rng/L 2 1 EPA 200.7 11/17/2017 15:30 JJMACKE
Magnesium(Mg) 3.41 mg/L 0.005 1 EPA 200.7 11/17/2017 15:30 JJMACKE
Potassium(K) 1.72 mg/L 0.1 1 EPA 200.7 11/17/2017 15:30 JJMACKE
Sodium(Na) 5.26 mg/L 0.05 1 EPA 200.7 11/17/2017 15:30 JJMACKE
Total Hardness(Ca and Mg) 34.1 mg/L 0.045 1 EPA 200.7 11/17/2017 15:30 JJMACKE
(CaCO3)
TOTAL RECOVERABLE METALS BY ICP
Aluminum(Al) 0.020 mg/L 0.005 1 EPA 200.7 11/09/2017 14:54 JJMACKE
Barium(Ba) 0.037 mg/L 0.005 1 EPA 200.7 11/09/2017 14:54 JJMACKE
Boron(B) <0.05 mg/L 0.05 1 EPA 200.7 11/09/2017 14:54 JJMACKE
Iron(Fe) 0.288 mg/L 0.01 1 EPA 200.7 11/09/2017 14:54 JJMACKE
Manganese(Mn) 0.221 mg/L 0.005 1 EPA 200.7 11/09/2017 14:54 JJMACKE
Strontium(Sr) 0.063 mg/L 0.005 1 EPA 200.7 11/09/2017 14:54 JJMACKE
Zinc(Zn) 0.009 mg/L 0.005 1 EPA 200.7 11/09/2017 14:54 JJMACKE

vised
rt
Certificate of Laboratory Analysis Re
ePage 77 of47
9
This report shall not be reproduced, except in full.
Order#J17110036
Site: SW3-A1 Sample#: 2017037952
Collection Date: 11/01/2017 10:50 AM Matrix: SURF WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Chromium (Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Cobalt(Co) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:13 CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Cobalt(Co) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 18:26 CWSPEN3
TURBIDITY-(Analysis Performed by Pace Laboratories)
Turbidity Complete Vendor Method V_PACE

Ger"iificate of LaboratoryAnal Sls Revised Report
y Page 8 of 47
This report shall not be reproduced, except in full.
Order#J17110036
Site: SW4-A1 Sample#: 2017037953
Collection Date: 11/01/2017 02:40 PM Matrix: SURF WW
Analyle Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
ALKALINITY(FIXED END POINT 4.5)-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 6.3 mg/L 0.1 1 EPA 300.0 11/06/2017 16:15 BGN9034
Sulfate 7.9 mg/L 0.1 1 EPA 300.0 11/06/2017 16:15 BGN9034
MERCURY(COLD VAPOR)IN WATER
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/03/2017 14:19 DMFRANC
Mercury Dissolved(cold vapor)in Water(Filtered)
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/09/2017 13:10 DMFRANC
DISSOLVED METALS BY ICP
Aluminum (AI) 0.007 mg/L 0.005 1 EPA 200.7 11/17/2017 10:35 JJMACKE
Barium(Ba) 0.019 mg/L 0.005 1 EPA 200.7 11/17/2017 10:35 JJMACKE
Boron(B) 0.093 mg/L 0.05 1 EPA 200.7 11/17/2017 10:35 JJMACKE
Iron(Fe) 1.75 mg/L 0.01 1 EPA 200.7 11/17/2017 10:35 JJMACKE
Manganese(Mn) 0.476 mg/L 0.005 1 EPA 200.7 11/17/2017 10:35 JJMACKE
Strontium(Sr) 0.084 mg/L 0.005 1 EPA 200.7 11/17/2017 10:35 JJMACKE
Zinc(Zn) <0.005 mg/L 0.005 1 EPA 200.7 11/17/2017 10:35 JJMACKE
UNDIGESTED METALS BY ICP
Calcium(Ca) 7.18 mg/L 2 1 EPA 200.7 11/17/2017 15:34 JJMACKE
Magnesium(Mg) 3.93 mg/L 0.005 1 EPA 200.7 11/17/2017 15:34 JJMACKE
Potassium(K) 1.54 mg/L 0.1 1 EPA 200.7 11/17/2017 15:34 JJMACKE
Sodium(Na) 3.60 mg/L 0.05 1 EPA 200.7 11/17/2017 15:34 JJMACKE
Total Hardness(Ca and Mg) 34.1 mg/L 0.045 1 EPA 200.7 11/17/2017 15:34 JJMACKE
(CaCO3)
TOTAL RECOVERABLE METALS BY ICP
Aluminum(AI) 0.291 mg/L 0.005 1 EPA 200.7 11/09/2017 14:58 JJMACKE
Barium(Ba) 0.019 mg/L 0.005 1 EPA 200.7 11/09/2017 14:58 JJMACKE
Boron(B) 0.085 mg/L 0.05 1 EPA 200.7 11/09/2017 14:58 JJMACKE
Iron(Fe) 2.71 mg/L 0.01 1 EPA 200.7 11/09/2017 14:58 JJMACKE
Manganese(Mn) 0.428 mg/L 0.005 1 EPA 200.7 11/09/2017 14:58 JJMACKE
Strontium(Sr) 0.078 mg/L 0.005 1 EPA 200.7 11/09/2017 14:58 JJMACKE
Zinc(Zn) <0.005 mg/L 0.005. 1 EPA 200.7 11/09/2017 14:58 JJMACKE

Certificate of Laborator Anal SIS Revised Report
y y Page 9 of 47
This report shall not be reproduced, except in full.
Order#J17110036
Site: SW4-A1 Sample#: 2017037953
Collection Date: 11/01/2017 02:40 PM Matrix: SURF WW
Analyse Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Cobalt(Co) 1.31 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L- 0.3 1 EPA 200.8 11/08/2017 20:36 CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Cobalt(Co) 1.35 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/201.7 19:03 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
Vanadium(V)Low Level 0.421 ug/L 0.3 1 EPA 200.8 11/08/2017 19:03 CWSPEN3
TURBIDITY-(Analysis Performed-by Pace Laboratories)
Turbidity Complete Vendor Method V_PACE

1. Revised Report
Ceruflcate of Laboratory/ Analysis Page 10 of47
This report shall not be reproduced, except in.full.
Order#A 7110036
Site: SW5-Ai Sample#: 2017037954
Collection Date: 11/01/2017 12:42 PM Matrix: SURF WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
r
ALKALINITY(FIXED END POINT 4.5)-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 11 mg/L 0.2 2 EPA 300.0 11/06/2017 16:33 BGN9034
Sulfate 9.9 mg/L 0.2 2 EPA 300.0 11/06/2017 16:33 BGN9034
MERCURY(COLD VAPOR)IN WATER
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/03/2017 14:21 DMFRANC
Mercury Dissolved(cold vapor)in Water(Filtered)
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/09/2017 13:12 DMFRANC
DISSOLVED METALS BY ICP
Aluminum(AI) <0.005 mg/L 0.005 1 EPA 200.7 11/17/2017 10:40 JJMACKE
Barium(Ba) 0.047 mg/L 0.005 1 EPA 200.7 11/17/2017 10:40 JJMACKE
Boron(B) 0.191 mg/L 0.05 1 EPA 200.7 11/17/2017 10:40 JJMACKE
Iron(Fe) 2.11 mg/L 0.01 1 EPA 200.7 11/17/2017 10:40 JJMACKE
Manganese(Mn) 1.07 mg/L 0.005 1 EPA 200.7 11/17/2017 10:40 JJMACKE
Strontium(Sr) 0.331 mg/L 0.005 1 EPA 200.7 11/17/2017 10:40 JJMACKE
Zinc(Zn) <0.005 mg/L 0.005 1 EPA 200.7 11/17/2017 10:40 JJMACKE
UNDIGESTED METALS BY ICP
Calcium(Ca) 23.5 mg/L 2 1 EPA 200.7 11/17/2017 15:39 JJMACKE
Magnesium(Mg) 7.97 mg/L 0.005 1 EPA 200.7 11/17/201715:39 JJMACKE
Potassium(K) 3.29 mg/L 0.1 1 EPA 200.7 11/17/2017 15:39 JJMACKE
Sodium(Na) 4.40 mg/L 0.05 1 EPA 200.7 11/17/2017 15:39 JJMACKE
Total Hardness(Ca and Mg) 91.6 mg/L 0.045 1 EPA 200.7 11/17/2017 15:39 JJMACKE
(CaCO3)
TOTAL RECOVERABLE METALS BY ICP
Aluminum(Al) 0.006 mg/L 0.005 1 EPA 200.7 11/09/2017 15:03 JJMACKE
Barium(Ba) 0.042 mg/L 0.005 1 EPA 200.7 11/09/2017 15:03 . JJMACKE
Boron(B) 0.168 mg/L 0.05 1 EPA 200.7 11/09/2017 15:03 JJMACKE
Iron(Fe) 2.21 mg/L 0.01 1 EPA 200.7 11/09/2017 15:03 JJMACKE
Manganese(Mn) 1.00 mg/L 0.005 1 EPA 200.7 11/09/2017 15:03 JJMACKE
Strontium(Sr) 0.312 mg/L 0.005 1 EPA 200.7 11/09/2017 15:03 JJMACKE
Zinc(Zn) <0.005 mg/L 0.005 1 EPA 200.7 11/09/2017 15:03 JJMACKE

Revised Report
Certificate of Laboratory Analysis Page 11 of47
This report shall not be reproduced, except in full.
Order#J17110036
Site: SW5-Al Sample#: 2017037954
Collection Date: 1 1/01/201 7 1 2:42 PM Matrix: SURF WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Cobalt(Co) 1.52 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Molybdenum(Mo) 2.36 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:22 CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Arsenic(As) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Cobalt(Co) 1.48 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Molybdenum(Mo) 2.34 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 19:12 CWSPEN3
TURBIDITY-(Analysis Performed by Pace Laboratories)
Turbidity Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Revised ReportPage 12 of47
This report shall not be reproduced, except in full.
Order#J17110036
Site: SW6-A1 Sample#: 2017037955
Collection Date: 1 1/01/201 7 12:10 PM Matrix: SURF WW
Analyse Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
ALKALINITY(FIXED END POINT 4.5)-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 7.9 mg/L 0.1 1 EPA 300.0 11/06/2017 16:51 BGN9034
Sulfate 6.2 mg/L 0.1 1 EPA 300.0 11/06/2017 16:51 BGN9034
MERCURY(COLD VAPOR)IN WATER
Mercury(Hg) <0.05 ug/L 0.05 1- EPA 245.1 11/03/2017 14:24 DMFRANC
Mercury Dissolved(cold vapor)in Water(Filtered)
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/09/2017 13:15 DMFRANC
DISSOLVED METALS BY ICP
Aluminum(AI) 0.016 mg/L 0.005 1 EPA 200.7 11/17/2017 10:45 JJMACKE
Barium(Ba) 0.035 mg/L 0.005 1 EPA 200.7 11/17/2017 10:45 JJMACKE
Boron(B) <0.05 mg/L 0.05 1 EPA 200.7 11/17/2017 10:45 JJMACKE
Iron(Fe) 7.05 mg/L 0.01 1 EPA 200.7 11/17/2017 10:45 JJMACKE
Manganese(Mn) 0.262 mg/L 0.005 1 EPA 200.7 11/17/2017 10:45 JJMACKE
Strontium(Sr) 0.043 mg/L 0.005 1 EPA 200.7 11/17/2017 10:45 JJMACKE
Zinc(Zn) <'0.005 mg/L 0.005 1 EPA 200.7 11/17/2017 10:45 JJMACKE
UNDIGESTED METALS BY ICP
Calcium(Ca) 4.11 mg/L 2 1 EPA 200.7 11/17/2017 15:44 JJMACKE
Magnesium(Mg) 1.94 mg/L 0.005 1 EPA 200.7 11/17/2017 15:44 JJMACKE
Potassium(K) 2.01 mg/L 0.1 1 EPA 200.7 11/17/2017 15:44 JJMACKE.
Sodium(Na) 2.80 mg/L 0.05 1 EPA 200.7 11/17/2017 15:44 JJMACKE
Total Hardness(Ca and Mg) 18.3 mg/L 0.045 1 EPA 200.7 11/17/2017 15:44 JJMACKE
(CaCO3)
TOTAL RECOVERABLE METALS BY ICP
Aluminum(AI) 0.054 mg/L 0.005 1 EPA 200.7 11/09/2017 15:07 JJMACKE
Barium(Ba) 0.027 mg/L 0.005 1 EPA 200.7 11/09/2017 15:07 JJMACKE
Boron(B) <0.05 mg/L 0.05 1 EPA 200.7 11/09/2017 15:07 JJMACKE
Iron(Fe) 5.11 mg/L 0.01 1 EPA 200.7 11/09/2017 15:07 JJMACKE
Manganese(Mn) 0.188 mg/L 0.005 1 EPA 200.7 11/09/2017 15:07 JJMACKE
Strontium(Sr) 0.036 mg/L 0.005 1 EPA 200.7 11/09/2017 15:07 JJMACKE
Zinc(Zn) <0.005 mg/L 0.005 1 EPA 200.7 11/09/2017 15:07 JJMACKE

Ceniificate of Laborator Anal sis Revised Report
y y Page 13 of 47
This report shall not be reproduced, except in full.
Order#A 7110036
Site: SW6-Ai Sample#: 2017037955
Collection Date: 11/01/2017 12:10 PM Matrix: SURF WW
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Arsenic(As) 2.80 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Cobalt(Co) 1.25 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8' 11/08/2017 21:31 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:31 CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Arsenic(As) 2.59 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11✓08/2017 19:50 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Cobalt(Co) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Molybdenum(Mo) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Nickel(Ni) <.1 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Selenium(Se). <1 ug/L 1 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
Vanadium(V)Low Level 0.396 ug/L 0.3 1 EPA 200.8 11/08/2017 19:50 CWSPEN3
TURBIDITY-(Analysis Performed by Pace Laboratories)
Turbidity Complete Vendor Method V_PACE

s„ Revised Report
Cerilficate of Laboratory Analysis Page 14 of47
This report shall not be reproduced, except in full.
Ord r#J17110036
Site: SWTA1 Sample#: 2017037956
Collection Date: 1 1/01/201 7 02:05 PM Matrix: SURF WW
Analyte Result Units Qualifiers RDL DF Method Analysis bate/Time Analyst
Mercury Dissolved(cold vapor)in Water(Filtered)
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/09/2017 13:17 DMFRANC
DISSOLVED METALS BY ICP
Aluminum (AI) 0.011 mg/L 0.005 1 EPA 200.7 11/17/2017 10:49 JJMACKE
Barium(Ba) 0.067 mg/L 0.005 1 EPA 200.7 11/17/2017 10:49 JJMACKE
Boron(B) 0.351 mg/L 0.05 1 EPA 200.7 11/17/2017 10:49 JJMACKE
Iron(Fe) 0.140 mg/L 0.01 1 EPA 200.7 11/17/2017 10:49 JJMACKE
Manganese(Mn) 2.08 mg/L 0.005 1 EPA 200.7 11/17/2017 10:49 JJMACKE
Strontium(Sr) 1.20 mg/L 0.005 1 EPA 200.7 11/17/2017 10:49 JJMACKE
Zinc(Zn) 0.010 mg/L 0.005 1 EPA 200.7 11/17/2017 10:49 JJMACKE
TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Arsenic(As) 1.70 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Cobalt(Co) 2.04 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Copper(Cu) 1.06 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Molybdenum(Mo) 14.7 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Nickel(Ni) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:40 CWSPEN3
Vanadium(V)Low Level 0.508 ug/L 0.3 1 EPA 200.8 11/08/2017 21:40 CWSPEN3

Revised Report
Certificate of Laboratory Analysis Page 15 of47
This report shall not be reproduced, except in full.
Order#A 7110036
Site: SW8-A1 Sample#: 2017037957
Collection Date: 11/01/2017 01:25 PM Matrix: SURF WW
Analyse Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
ALKALINITY(FIXED END POINT 4.5)-(Analysis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE
INORGANIC IONS BY IC
Chloride 3.8 mg/L 0.5 5 EPA 300.0 11/06/2017 17:09 BGN9034
Sulfate 32 mg/L 0.5 5 EPA 300.0 11/06/2017 17:09 BGN9034
MERCURY(COLD VAPOR)IN WATER
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/03/2017 14:26 DMFRANC
Mercury Dissolved(cold vapor)in Water(Filtered)
Mercury(Hg) <0.05 ug/L 0.05 1 EPA 245.1 11/09/2017 13:19 DMFRANC
DISSOLVED METALS BY ICP
Aluminum(Al) 0.039 mg/L 0.005 1 EPA 200.7 11/17/2017 10:54 JJMACKE
Barium(Ba) 0.230 mg/L 0.005 1 EPA 200.7 11/17/2017 10:54 JJMACKE
Boron(B) 1.38 mg/L 0.05 1 EPA 200.7 11/17/2017 10:54 JJMACKE
Iron(Fe) 23.9 mg/L 0.01 1 EPA 200.7 11/17/2017 10:54 JJMACKE
Manganese(Mn) 9.82 mg/L 0.005 1 EPA 200.7 11/17/2017 10:54 JJMACKE
Strontium(Sr) 2.24 mg/L 0.005 1 EPA 200.7 11/17/2017 10:54 JJMACKE
Zinc(Zn) <0.005 mg/L 0.005 1 EPA 200.7 11/17/2017 10:54 JJMACKE
UNDIGESTED METALS BY ICP
Calcium(Ca) 147 mg/L 2 20 EPA 200.7 11/17/2017 15:48 JJMACKE
Magnesium(Mg) 31.0 mg/L 0.1 20 EPA 200.7 11/17/2017 15:48 JJMACKE
Potassium(K) 4.42 mg/L 0.1 1 EPA 200.7 11/17/2017 15:48 JJMACKE
Sodium(Na) 7.17 mg/L 0.05 1 EPA 200.7 11/17/2017 15:48 JJMACKE
Total Hardness(Ca and Mg) 439 mg/L 0.045 1 EPA 200.7 11/17/2017 15:48 JJMACKE
(CaCO3)
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al) 0.065 mg/L 0.005 1 EPA 200.7 11/09/2017 15:11 JJMACKE
Barium(Ba) 0.219 mg/L 0.005 1 EPA 200.7 11/09/2017 15:11 JJMACKE
Boron(B) 1.29 mg/L 0.05 1 EPA 200.7 11/09/2017 15:11 JJMACKE
Iron(Fe) 21.6 mg/L 0.01 1 EPA 200.7 11/09/2017 15:11 JJMACKE
Manganese(Mn) 9.42 mg/L 0.005 1 EPA 200.7 11/09/2017 15:11 JJMACKE
Strontium(Sr) 2.18 mg/L 0.005 1 EPA 200.7 11/09/2017 15:11 JJMACKE
Zinc(Zn) <0.005 mg/L. 0.005 1 EPA 200.7 11/09/2017 15:11 JJMACKE

Revised Report
Cc,dficate of Laboratory Analya'l* Page 16 of47
This report shall not be reproduced, except in full.
Order#A 7110036
Site: SW8-A1 Sample#: 2017037957
Collection Date: 11/01/2017 01:25 PM Matrix: SURF WW
Analyse Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Arsenic(As) 217 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Cobalt(Cc) 17.8 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Molybdenum(Mo) 149 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Nickel(Ni) 1.09 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
Vanadium(V)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 21:50 CWSPEN3
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony(Sb) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Arsenic(As) 219 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Beryllium(Be) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Cadmium(Cd)Low Level <0.1 ug/L 0.1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Chromium(Cr) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Cobalt(Co) 18.1 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Copper(Cu) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Lead(Pb)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Molybdenum(Mo) 151 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Nickel(Ni) 1.24 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Selenium(Se) <1 ug/L 1 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Silver(Ag)Low Level <0.3 ug/L 0.3 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Thallium(TI)Low Level <0.2 ug/L 0.2 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
Vanadium(V)Low Level 0.543 ug/L 0.3 1 EPA 200.8 11/08/2017 19:59 CWSPEN3
TURBIDITY-(Analysis Performed by Pace Laboratories)
Turbidity Complete Vendor Method V_PACE

Revised Report
CerWicate of Laboratory Analysis Page 17 of 47
This report shall not be reproduced, except in full.
Order#J17110036
Level II QC Summary
Q17110095 Dionex INORGANIC IONS BY IC
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Chloride 0.0132 0.0132 mg/L 1 0.1 <1/2 RDL
Sulfate -0.0387 -0.0387 mg/L 1 0.1 <1/2 RDL
IS #1
Parameter Measured Final Units: Dil Soilce %Recovery LCL UCL Qualifier
Chloride 3.2 160 mg/L 50 150 101 80 120
Sulfate 6.66 3330 mg/L 500 1500 89 80 120
ISD #1
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Chloride 3.19 159 mg/L 50 150 101 80 120 0.244
Sulfate 6.65 3320 mg/L 500 1500 88.5 80 120 0.5
LCS #1
Parameter Measured Final Units: Dil Saike %Recovery LCL UCL Qualifier
Chloride 4.99 4.99 mg/L 1 5 99.7 90 110
Sulfate 4.93 4.93 mg/L 1 5 98.7 90 110

Gi;rilficate of Laborator Anal SYb Revised Report
Y Y Page 18 of 47
This report shall not be reproduced, except in full.
Order#A 7110036
Level II QC Summary
Q1.7.110084 HG 245.1 MERCURY(COLD VAPOR)IN WATER
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Mercury(Hg) 0.008 0.008 ug/L 1 0.05 <1/2 RDL
Blank #2
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Mercury(Hg) 0.013 0.013 ug/L 1 0.05 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Sgike %Recovery LCL UCL Qualifier
Mercury(Hg) 1.9 1.9 ug/L 1 2 94.8 85 115
LCS #2
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Mercury,(Hg) 1.9 1.9 ug/L 1 2 94.8 85 115
MS #1 Parent Sample: J17090036 -- 2017030816
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Mercury(Hg) 0.761 15.2 ug/L 20 20 71.4 70 130
MSD #1 Parent Sample: J17090036 -- 2017030816
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Mercury(Hg) 0.779 15.6 ug/L 20 20 73.2 - 70 130 2.49
MS #4 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Mercury(Hg) 0.961 0.961 ug/L 1 1 95.1 70 130
MSD #4 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Mercury(Hg) 0.962 0.962 ug/L 1 1 95.2 70 130 0.105

Revised Report
r lf Ceicate of Laboratory Analysis* Page 19of47
This report shall not be reproduced, except in full.
Order#A 7110036
Level II QC Summary
Q17.110375 ICP Dissolved DISSOLVED METALS BY ICP
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Aluminum(AI) -0.000443 -0.000443 mg/L 1 0.005 <1/2 RDL
Barium(Ba) -0.000067 -0.000067 mg/L 1 0.005 <1/2 RDL
Boron(B) 0.000042 0.000042 mg/L 1 0.05 <1/2 RDL
Iron(Fe) -0.000055 -0.000055 mg/L 1 0.01 <1/2 RDL
Manganese(Mn) -0.000325 -0.000325 mg/L 1 0.005 <1/2 RDL
Strontium(Sr) -0.000016 -0.000016 mg/L 1 0.005 <1/2 RDL
Zinc(Zn) 0.0006.72 0.000672 mg/L 1 0.005 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Aluminum(AI) 2.11 2.11 mg/L 1 2 106 85 115
Barium(Ba) 0.984 0.984 mg/L 1 1 98.4 85 115
Boron(B) 1.99 1.99 mg/L 1 2 99.7 85 115
Iron(Fe) 2.06 2.06 mg/L 1 2 103 85 115
Manganese(Mn) 0.975 0.975 mg/L 1 1 97.5 85 115
Strontium(Sr) 1.9 1.9 mg/L 1, 2 95 85 115
Zinc(Zn) 1.03 1.03 mg/L 1 1 103 85 115
MS #1 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Aluminum (AI) 5.22 5.22 mg/L 1 5 104 70 130
Barium(Ba) 5.26 5.26 mg/L 1 5 104 70 130
Boron(B) 5.17 5.17 mg/L 1 5 103 70 130
Iron(Fe) 6.15 6.15 mg/L 1 5 98.8 70 130
Manganese(Mn) 5.66 5.66 mg/L 1 5 104 70 130
Strontium(Sr) 5.05 5.05 mg/L 1 5 99.4 70 130
Zinc(Zn) 5.27 5.27 mg/L 1 5 106 70 130
MSD #1 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Aluminum(AI) 5.32 5.32 mg/L 1 5 106 70 130 1.86
Barium(Ba) 5.3 5.3 mg/L 1 5 105 70 130 0.84
Boron(B) 5.22 5.22 mg/L 1 5 104 70 130 0.868
Iron(Fe) 6.22 6.22 mg/L 1 5 100 70 130 1.53
Manganese(Mn) 5.73 5.73 mg/L 1 5 105 70 130 1-.2
Strontium(Sr) 5.1 5.1 mg/L 1 5 100 70 130 0.981
Zinc(Zn) 5.33 5.33 mg/L 1 5 106 70 130 1.15

Revised Report
Gai-dficate of Laboratory Analys6 Page 20 of 47
This report shall not be reproduced, except in full.
Order#J17110036
Level II QC Summary
Q17110405 ICP Undigested UNDIGESTED METALS BY ICP
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Calcium (Ca) 0.000963 0.000963 mg/L 1 0.01 <1/2 RDL
Magnesium(Mg) -0.000019 -0.000019 mg/L 1 0.005 <1/2 RDL
Potassium(K) -0.00985 -0.00985 mg/L 1 0.1 <1/2 RDL
Sodium (Na) 0.00186 0.00186 mg/L 1 0.05 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Calcium(Ca) 1.02 1.92 mg/L 1 2 96 85 115
Magnesium(Mg) 1.88 1.88 mg/L 1 2 93.8 85 115
Potassium(K) 3.77 3.77 mg/L 1 4 94.3 85 115
Sodium (Na) 8 8 mg/L 1 8.1 98.7 85 115 f
MS #1 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Calcium (Ca) 12 12 mg/L 1, 5 92.1 70 130
Magnesium(Mg) 8.81 8.81 mg/L 1 5 127 70 130
Potassium(K) 6.53 6.53 mg/L 1 5 101 70 130
8
Sodium (Na) 8.66 8.66 mg/L 1 5 88.6 70 130
MSD #1 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Spike %Recovenr LCL UCL RPD Qualifier
Calcium(Ca) 12.2 12.2 mg/L 1 5 96.3 70 130 4.44
Magnesium(Mg) 8.98 8.98 mg/L 1 5 130 70 130 2.56
Potassium(K) 6.62 6.62 mg/L 1 5 103 70 130 1.85
Sodium (Na) 8.81 8.81 mg/L 1 5 91.5 70 130 3.26

Ce1 Lificate of LaboratoryAnalysis Revised Report
Y Page 21 of 47
This report shall not be reproduced, except in full.
Order#.A 7110036
Level II QC Summary
Q17110173 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Aluminum(AI) 0.00108 0.00108 mg/L 1 0.005 <1/2 RDL
Barium(Ba) 0.000191 0.000191 mg/L 1 0.005 <1/2 RDL
Boron(B) 0.000766 0.000766 mg/L 1 0.05 <1/2 RDL
Iron(Fe) 0.00151 0.00151 mg/L 1 0.01 <1/2 RDL
Manganese(Mn) 0.000114 0.000114 mg/L 1 0.005 <1/2 RDL
Strontium(Sr) 0.000079 0.000079 mg/L 1 0.005 <1/2 RDL
Zinc(Zn) 0.00109 0.00109 mg/L 1 0.005 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Aluminum(AI) 4.88 4.88 mg/L 1 5 97.6 85 115
Barium(Ba) 4.69 4.69 mg/L 1 5 93.7 85 115
Boron(B) 4.8 4.8 mg/L 1 5 95.9 85 115
Iron(Fe) 4.68 4.68 mg/L 1 5 93.6 85 115
Manganese(Mn) 4.7 4.7 mg/L 1 5 94 85 115
Strontium(Sr) 4.73 4.73 mg/L 1 5 94.6 85 115
Zinc(Zn) 4.87 4.87 mg/L 1 5 97.5 85 115
MS #1 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Aluminum(Al) 4.79 4.79 mg/L 1 5 95.4 70 130
Barium(Ba) 4.95 4.95 mg/L 1 5 98.1 70 130
Boron(B) 4.66 4.66 mg/L 1 5 93.1 70 130
Iron(Fe) 5.87 5.87 mg/L 1 5 93.5 70 130
Manganese(Mn) 5.16 5.16 mg/L 1 5 95.1 70 130
Strontium(Sr) 4.94 4.94 mg/L 1 5 97.3 70 130
Zinc(Zn) 4.77 4.77 mg/L 1 5 95.2 70 130
MSD #1 Parent Sample: J17110036 -- 2017037951
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL RPD Qualifier
Aluminum(AI) 5.04 5.04 mg/L 1 5 100 70 130 5.09
Barium(Ba) 4.79 4.79 mg/L 1 5 95 70 130 3.27
Boron(B) 4.74 4.74 mg/L 1 5 94.6 70 130 1.6
Iron(Fe) 5.94 5.94 mg/L 1 5 94.9 70 130 1.46
Manganese(Mn) 5.21 5.21 mg/L 1 5 96.1 70 130 1.09
Strontium(Sr) 4.84 4.84 mg/L 1 5 95.5 70 130 1.89
Zinc(Zn) 5.05 5.05 mg/L 1 5 101 70 130 5.67

Q rdficate of LaboratoryAnalysis Revised Report
7 Page 22 of 47
This report shall not be reproduced, except in full.
Order#A 7110036
Level II QC Summary
Q17110175 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Antimony(Sb) 0.023 0.023 ug/L 1 1 <1/2 RDL
Arsenic(As) 0.009 0.009 ug/L 1 1 <1/2 RDL
Beryllium(Be) 0 0 ug/L 1 1 <1/2 RDL
Cadmium(Cd)Low Level 0.001 0.001 ug/L 1 0.1' <1/2 RDL
Chromium(Cr) 0.159 0.159 ug/L 1 1 <1/2 RDL
Cobalt(Co) 0.003 0.003 ug/L 1 1 <1/2 RDL
Copper(Cu) -0.079 -0.079 ug/L 1 1 <1/2 RDL
Lead(Pb)Low Level 0.002 0.002 ug/L 1 0.2 <1/2 RDL
Molybdenum(Mo)' 0.015 0.015 ug/L 1 1 <1/2 RDL
Nickel(Ni) 0.016 0.016 ug/L 1 1 <1/2 RDL
Selenium (Se) 0.065 0.065 ug/L 1 1 <1/2 RDL
Silver(Ag)Low Level 0 0 ug/L 1 0.3 <1/2 RDL
Thallium(TI)Low Level 0.004 0.004 ug/L 1 0.2 <1/2 RDL
Vanadium(V)Low Level 0.005 0.005 ug/L 1 0.3 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Antimony(Sb) 49.5 49.5 ug/L 1 50 99.1 85 115
Arsenic(As) 49.4 49.4 ug/L 1 50 98.9 85 115
Beryllium(Be) 46.6 46.6 ug/L 1 50 '93.2 85 115
Cadmium(Cd)Low Level 48.9 48.9 ug/L 1 50 97.8 85 115
Chromium(Cr) 49.9 49.9 ug/L 1 50 99.9 85 115
Cobalt(Co) 46 46 ug/L 1 50 92.1 85 115
Copper(Cu) 49.1 49.1 ug/L 1 50 98.2 85 115
Lead(Pb)Low Level 48.3 48:3 ug/L 1 50 96.6 85 115
Molybdenum(Mo) 49.7 49.7 ug/L 1 50 99.3 85 115
Nickel(Ni) 49.4 49.4 ug/L 1 50 98.7 85 115
Selenium (Se) 47.4 47.4 ug/L 1 50 94.8 85 115
Silver(Ag)Low Level 49.5 ug/L 1 50 98.9 85 115
Thallium(TI)Low Level 44.5 44.5 ug/L 1 50 89 85 115
Vanadium(V)Low Level 49 ug/L 1 50 98.1 85 115
MS #1 Parent Sample: J17110036 -- 2017037953
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Antimony(Sb) 50.3 50.3 ug/L 1 50 101
Arsenic(As) 50.8 50.8 ug/L 1 50 101
Beryllium(Be) 48.5 48.5 ug/L 1 50 96.6
Cadmium(Cd)Low Level 49.7 49.7 ug/L 1 -, 50 99.3
Chromium(Cr) 50.7 50.7 ug/L 1 50 101
Cobalt(Co) 48 48 ug/L 1 50 93.4

Cendicate of Laboratory Analysis Revised Report
s Page 23 of 47
This report shall not be reproduced, except in full.
Order#A 7110036
Level II QC Summary
Q17110175 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS(DISSOLVED)
MS #1 Parent Sample: J17110036 -- 2017037953
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Copper(Cu) 49.9 49.9 ug/L 1 50 99.7
Lead(Pb) Low Level 49 49 ug/L 1 50 98
Molybdenum(Mo) 50.8 50.8 ug/L 1 50 102
Nickel(Ni) 49.8 49.8 ug/L 1 50 99.2
Selenium(Se) 49.3 49.3 ug/L 1 50 97.4
Silver(Ag)Low Level 50.2 ug/L 1 50 100
Thallium(TI)Low Level 44.6 44.6 ug/L 1 50 89
Vanadium (V)Low Level 50.4 ug/L 1 50 101
MSD #1 Parent Sample: J17110036 -- 2017037953
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Antimony(Sb) 49.8 49.8 ug/L 1 50 99.6 0.969
Arsenic(As) 49.7 49.7 ug/L 1 50 99.1 2.13
Beryllium(Be) 50.1 50.1 ug/L 1 50 99.9 3.34
Cadmium (Cd)Low Level 48.5 48.5 ug/L 1 50 97 2.38
Chromium(Cr) 50.6 50.6 ug/L 1 50 101 0.236
Cobalt(Co) 47.3 47.3 ug/L 1 50 92 1.56
Copper(Cu) 48.8 48.8 ug/L 1 50 97.6 2.14
Lead(Pb)Low Level 48.2 48.2 ug/L 1 50 96.4 1.64
Molybdenum(Mo) 50.2 50.2 ug/L 1 50 100 1.16
Nickel(Ni) 49.1 49.1 ug/L 1 50 97.7 1.52
Selenium(Se) 48.1 48.1 ug/L 1 50 95 2.48
Silver(Ag)Low Level 49.2 ug/L 1 50 98.4 2.01
Thallium(TI)Low Level 43.9 43.9 ug/L 1 50 87.7 1.51
Vanadium(V)Low Level 50.1 ug/L 1 50 100 0.531

Cuelificate of LaboratoryAnaw$i� Revised Report
7 Page 24 of 47
This report shall not be reproduced, except in full.
Order#J17110036
Level II QC Summary
Q171101.81 IMS_TRM TOTAL RECOVERABLE METALS BY ICI'-MS
Blank #1
Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier
Antimony(Sb) 0.014 0.014 ug/L 1 1 <1/2 RDL
Arsenic(As) 0.007 0.007 ug/L 1 1 <1/2 RDL
Beryllium(Be) 0 0 ug/L 1 1 <1/2 RDL
Cadmium(Cd)Low Level 0.001 0.001 ug/L 1 0.1 <1/2 RDL
Chromium (Cr) 0.043 0.043 ug/L 1 1 <1/2 RDL
Cobalt(Co) 0.002 0.002 ug/L 1 1 <1/2 RDL
Copper(Cu) -0.08 -0.08 ug/L 1 1 <1/2 RDL
Lead(Pb) Low Level 0 0 ug/L 1 0.2 <1/2 RDL
Molybdenum(Mo) 0.003 0.003 ug/L 1 1 <1/2 RDL
Nickel(Ni) 0.024 0.024 ug/L 1 1 <1/2 RDL
Selenium(Se) 0.054 0.054 ug/L 1 1 <1/2 RDL
Silver(Ag)Low Level 0.006 0.006 ug/L 1 0.3 <1/2 RDL
Thallium(TI)Low Level -0.001 -0.001 ug/L 1 0.2 <1/2 RDL
Vanadium(V)Low Level 0.008 0.008 ug/L 1 0.3 <1/2 RDL
LCS #1
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Antimony(Sb) 47.2 47.2 ug/L 1 50 94.3 85 115
Arsenic(As) 47.2 47.2 ug/L 1 50 94.5 85 115
Beryllium(Be) 48.8 48.8 ug/L 1 50 97.5 85 115
Cadmium(Cd)Low Level 47.2 ug/L 1 50 94.5 85 115
Chromium(Cr) 47.6 47.6 ug/L 1 50 95.2 85 115
Cobalt(Co) 44.4 44.4 ug/L 1 50 88.8 85 115
Copper(Cu) 47.1 47.1 ug/L 1 50 94.1 85 115
Lead(Pb) Low Level 46.4 46.4 ug/L 1 50 92.8 85 115
Molybdenum(Mo) 47.6 47.6 ug/L 1 50 95.2 85 115
Nickel(Ni) 47.7 47.7 ug/L 1 50 95.3 85 115
Selenium(Se) 46.3 46.3 ug/L 1 50 92.6 85 115
Silver(Ag)Low Level 47.7 ug/L 1 50 95.4 85 115
Thallium(TI)Low Level 42.7 42.7 ug/L 1 50 85.5 85 115
Vanadium(V)Low Level 47.4 47.4 ug/L 1 50 94.9 85 115
MS #1 Parent Sample: J17110036 -- 2017037952
Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Qualifier
Antimony(Sb) 48.5 48.5 ug/L 1 50 96.8 70 130
Arsenic(As) 48.9 48.9 ug/L 1 50 97.6 70 130
Beryllium(Be) 51.7 51.7 ug/L 1 50 103 70 130
Cadmium (Cd)Low Level 47.9 ug/L 1 50 95.7 70 130
Chromium(Cr) 49 49 ug/L 1 50 97.8 70 130
Cobalt(Co) 45.7 45.7 ug/L 1 50 90.1 70 130

Cerilricate of Laborator Anal Revised Report
Y Analysis Page 25 of 47
This report shall not be reproduced, except in full.
Order#J17110036
Level II QC Summary
Q17110181 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS #1 Parent Sample: J17110036 -- 2017037952
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL Qualifier
Copper(Cu) 48.6 48.6 ug/L 1 50 96.8 70 130
Lead(Pb)Low Level 47.5 47.5 ug/L 1 50 95 70 130
Molybdenum(Mo) 49.1 49.1 ug/L 1 50 98.2 70 130
Nickel(Ni) 48.5 48.5 ug/L 1 50 95.9 70 130
Selenium (Se) 47 47 ug/L 1 50 93.4 70 130
Silver(Ag)Low Level 48.3 ug/L 1 50 96.6 70 130
Thallium(TI)Low Level 42.9 42.9 ug/L 1 50 85.8 70 130
Vanadium(V)Low Level •49.2 49.2 ug/L 1 50 97.8 70 130
MSD #1 Parent Sample: J17110036 -- 2017037952
Parameter Measured Final Units: Dil Spike %Recovery LCL UCL RPD Qualifier
Antimony(Sb) 48.9 48.9 ug/L 1 50 97.7 70 130 0.886
Arsenic(As) 48.3 48.3 ug/L 1 50 96.4 70 130 1.21
Beryllium(Be) 50.7 50.7 ug/L 1 50 101 70 130 1.96
Cadmium(Cd)Low Level 48.1 ug/L 1 50 96.1 70 130 0.421
Chromium(Cr) 49.2 49.2 ug/L 1 50 98.3 70 130 0.475
Cobalt(Co) 46 46 ug/L 1 50 90.7 70 130 0.699
Copper(Cu) 48.7 48.7 ug/L 1 50 97 70 130 0.184
Lead(Pb)Low Level 47.2 47.2 ug/L 1 50 94.3 70 130 0.706
Molybdenum(Mo) 49.2• 49.2 ug/L 1 50 98.4 70 130 0.165
Nickel(Ni) 48.9 48.9 ug/L 1 50 96.7 70 130 0.766
Selenium(Se) 46.2 46.2 ug/L 1 50 91.8 70 130 1.72
Silver(Ag)Low Level 48.8 ug/L 1 50 97.6 70 130 0.98
Thallium(TI)Low Level 43.2 43.2 ug/L 1 50 86.4 70 130 0.674
Vanadium(V)Low Level 49.6 49.6 ug/L 1 50 98.7 70 130 0.875

P e Ana cal S rvices,LLC
evised Pepor�
.aCeA/+Q ►7 ( -• 4t�lf�gc� a Suite 100
rt�lyfiCa y Huntersville,NC 28078
wwwpe' leb&- [phone]
November 06, 2017
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J171.10036
Pace Project No.: 92361711
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on November 02, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact.me.
Sincerely,
Bonnie Vang for
Kevin Herring
[e-mail]
1(704)875-9092
HORIZON Database Administrator
Enclosures
cc: Program Manager,Duke Energy
s f 3
REPORT OF LABORATORY ANALYSIS
�d
This report shall not be reproduced,except in full,
v r without the written consent of Pace Analytical Services,LLC. Page 1 of 20

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CERTIFICATIONS
Project: J17110036
Pace Project No.: 92361711
Asheville Certification IDS
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 Virginia/VELAP Certification#:460222
North Carolina Drinking Water Certification#:37712
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services,LLC. Page 2 of 20

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SAMPLE SUMMARY
Project: J17110036
Pace Project No.: 92361711
Lab ID Sample ID Matrix Date Collected Date Received
92361711001 2017037951 Water 11/01/17 09:10 11/02/17 13:15
92361711002 2017037952 Water 11/01/1710:50 11/02/17.1.3:15
92361711003 2017037953 Water 11/01/1714:40 11/02/1713:15
92361711004 2017037954 Water 11/01/1712:42 11/02/1713:15
92361711005 2017037955 Water 11/01/1712:10 11/0211713:15
92361711006 2017037957 Water 11/01/1713:26 11/02/1713:15
REPORT OF LABORATORY ANALYSIS
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[phone]
SAMPLE ANALYTE COUNT
Project: J17110036
Pace Project No.: 92361711
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92361711001 2017037951 EPA 180.1 KDF1 1 PASI-A
SM 2320B KDF1 3 PASI-A
92361711002 2017037952 EPA 180.1 KDF1 1 PASI-A
SM 232013 KDF1 3 PASI-A
92361711003 2017037953 EPA 180.1 KDF1 1 PASI-A
SM 2320B KDF1 3 PASI-A
92361711004 2017037954 EPA 180.1 KDF1 1 PASI-A
SM 2320B KDF1 3 PASI-A
92361711005 2017037955 EPA 180.1 KDF1 1 PASI-A
SM 2320B KDF1 3 PASI-A
92361711006 2017037967 EPA 180.1 KDF1 1 PASI-A
SM 2320B KDF1 3 PASI-A
r
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 4 of 20

P e Anac cal Sr rvices,LLC
eviseL epo
016 89n/e. Suite100
t
Huntersville,NC 28078
vriylvpecela6s:i»rr,
[phone]
SUMMARY OF DETECTION
Project: J17110036
Pace Project No.: 92361711
Lab Sample ID Client Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
92361711001 2017037951
EPA 180.1 Turbidity 1.6 NTU 1.0 11/03/17 08:59
SM 2320B Alkalinity,Bicarbonate(CaCO3) 28.8 mg/L 5.0 11/03/17 15:54
SM 2320B Alkalinity,Total as CaCO3 28.8 mg/L 5.0 '11/03/17 15:54
92361711002 2017037952
SM 2320B Alkalinity,Bicarbonate(CaCO3) 23.4 mg/L 5.0 11/03/17 16:06
SM 2320B Alkalinity,Total as CaCO3 23.4 mg/L 5.0 11/03/17 16:06
92361711003 2017037953
EPA 180.1 Turbidity 6.4 NTU 1.0 11/03/17 08:59
SM 2320B Alkalinity,Bicarbonate(CaCO3) 29.3 mg/L 5.0 11/03/17 16:17
SM 2320B Alkalinity,Total as CaCO3 29.3 mg/L 5.0 11/03/17 16:17
92361711004 2017037954
EPA 180.1 Turbidity 10.1 NTU 1.0 11/03/17 08:59
SM 2320B Alkalinity,Bicarbonate(CaCO3) 86.5 mg/L 5.0 1.1/03/17 16:28
SM 2320B Alkalinity,Total as CaCO3 86.5 mg/L 5.0 11/03/17 16:28
92361711005 2017037955
EPA 180.1 Turbidity 8.8 NTU 1.0 11/03/17 08:59
SM'2320B Alkalinity,Bicarbonate(CaCO3) 14.7 mg/L 5.0 11/03/17 16:41
SM 2320B Alkalinity,Total as CaCO3 14.7 mg/L 5.0 11/03/17 16:41
92361711006 2017037957
EPA 180.1 Turbidity 252 NTU 1.0 11/03/17 08:59
SM 2320B Alkalinity,Bicarbonate(CaCO3) '523 mg/L. 5.0 11/05/17 16:10
SM 2320B Alkalinity,Total as CaCO3 523 mg/L 5.0 11/05/17 16:10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services,LLC. Page 5 of 20

' PKev8lsedKVepoA?,Frvices,LLC
e. Suite100
aCBAtla�yfiCal �J Huntersville,NC 28078
wvwp8celeb&;coin, [phone]
PROJECT NARRATIVE
Project: J17110036
Pace Project No.: 92361711
Method: EPA 180.1
Description: 180.1 Turbidity
Client: Duke Energy
Date: November 06,2017
General Information:
6 samples were analyzed for EPA 180.1. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form(SCUR)attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes: "
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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2? P e Ana cal S rvices,LLC
evised epor�
aceAn 'Iyta-al 0§6�1 2cgy4Aye. Suite 100
Huntersville,NC 28078
VwW.paceh0s,.Co'
[phone]
PROJECT NARRATIVE
Project: J17110036
Pace Project No.: 92361711
Method: SM 2320B
Description: 2320B Alkalinity
Client: Duke Energy
Date: November 06,2017
General Information:
6 samples were analyzed for SM 23206. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form(SCUR)attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank,where applicable,with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences(RPDs)were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services,LLC. Page 7 of 20

P e Ana cal S rvices,LLC
evise epor����� � Suite 100
aceAnal�rfrcI ���'Huntersville,NC 2$078
wx vpacelaba q-M [phone]
ANALYTICAL RESULTS
Project: J17110036
Pace Project No.: 92361711
Sample: 2017037951 Lab ID: 92361711001 Collected: 11/01/17 09:10 Received: 11/02/17 13:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
180.1 Turbidity Analytical Method:EPA 180.1
Turbidity 1.6 NTU 1.0 1 11/03/17 08:59
2320B Alkalinity Analytical Method:SM 2320B
Alkalinity,Bicarbonate(CaCO3) 28.8 mg/L 5.0 1 11/03/17 15:54
Alkalinity,Carbonate(CaCO3) ND mg/L 5.0 1 11/03/17 15:54
Alkalinity,Total as CaCO3 28.8 mg/L 5.0 1 11/03/17 15:54
REPORT OF LABORATORY ANALYSIS
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Date:11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 20

e Pp e dycapl r1ces,LLCAeoy�4c6ySuite
�� 100
/7 /+ (CAI IaII�Vt Huntersville,NC 28078
rov vtvpaWabs caIr:
[phone]
ANALYTICAL RESULTS
Project: J17110036
Pace Project No.: 92361711
Sample: 2017037952 Lab ID: 92361711002 Collected: 11/01/17 10:50 Received: 11/02/17 13:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
180.1 Turbidity Analytical Method:EPA 180.1
Turbidity ND NTU 1.0 1 11/03/17 08:59
2320B Alkalinity Analytical Method:SM 2320B
Alkalinity,Bicarbonate(CaCO3) 23.4 mg/L 5.0 1 11/03/17 16:06
Alkalinity,Carbonate(CaCO3) ND mg/L 5.0 1 11/03/17 16:06
Alkalinity,Total as CaCO3 23.4 mg/L 5.0 1 11/03/17 16:06
REPORT OF LABORATORY ANALYSIS
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Date: 11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 20

P e Anadvlical S�rvices,LLC
evlse lepo
g a ( tf��c�� e. Suite 100
aCeAtlaly ICal y Huntersvilla,NC 28078
wwwp6tvlebs corn [phone]
ANALYTICAL RESULTS
Project: J17110036
Pace Project No.: 92361711
Sample: 2017037953 Lab ID: 92361711003 Collected: 11/01/17 14:40 Received: 11/02/17 13:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
180.1 Turbidity Analytical Method:EPA 180.1
Turbidity 6.4 NTU 1.0 1 11/03/17 08:59
2320B Alkalinity Analytical Method:SM 2320B
Alkalinity,Bicarbonate(CaCO3) 29.3 mg/L 5.0 1 11/03/17 16:17
Alkalinity,Carbonate(CaCO3) ND mg/L 5.0 1 11/03/17 16:17
Alkalinity,Total as CaCO3 29.3 mg/L 5.0 1 11/03/17 16:17
REPORT OF LABORATORY ANALYSIS
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Date: 11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 20

P e Ana cal S rvices,LLC
006�Qcffee. Suite 100
ace.,Analyical Huntersville,NC 28078
wwWpace/a65 cdi», [phone]
ANALYTICAL RESULTS
Project: J17110036
Pace Project No.: 92361711
Sample: 2017037954 Lab ID: 92361711004 Collected: 11/01/17 12:42 Received: 11/02/17 13:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
180.1 Turbidity Analytical Method:EPA 180.1
Turbidity 10.1 NTU 1.0 1 11/03/17 08:59
2320B Alkalinity Analytical Method:SM 2320B
Alkalinity,Bicarbonate(CaCO3) 86.5 mg/L 5.0 1 11/03/17 16:28
Alkalinity,Carbonate(CaCO3) ND mg/L 5.0 1 11/03/17 16:28
Alkalinity,Total as CaCO3 86.5 mg/L 5.0 1 ' 11/03/17 16:28
REPORT OF LABORATORY ANALYSIS
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Date:11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 20

® PKevisetl"Kepor rv'ces,LLc
9t+ n9I +/� ( 0§88 `9�-WYe. Suite 100
UORAnglyitV,af Huntersville,NC 28078
www.paqeia44.com
[phone]
ANALYTICAL RESULTS
Project: J17110036
Pace Project No.: 92361711
Sample: 2017037955 Lab ID: 92361711005 Collected: 11/01/17 12:10 Received: 11/02/17 13:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
180.1 Turbidity Analytical Method:EPA 180.1
Turbidity 8.8 NTU 1.0 1 11/03/17 08:59
2320B Alkalinity Analytical Method:SM 2320B
Alkalinity,Bicarbonate(CaCO3) 14.7 mg/L 5.0 1 11/03/17 16:41
Alkalinity,Carbonate(CaCO3) ND mg/L 5.0 1 11/03/17 16:41
Alkalinity,Total as CaCO3 14.7 mg/L 5.0 1 11/03/17 16:41
REPORT OF LABORATORY ANALYSIS
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Date:11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 20

P e Ana cal S
evise a eporf rvices,LLC
c?CeA/+® Iigc�� e. Suite 100
11al,Jf�ICa� y Huntersvilla,NC 28078
vn»vpacelehs earn
[phone]
ANALYTICAL RESULTS
Project: J17110036
Pace Project No.: 92361711
Sample: 2017037957 Lab ID: 92361711006 Collected: 11/01/17 13:25 Received: 11/02/17 13:15 Matrix:Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
180.1 Turbidity Analytical Method:EPA 180.1
Turbidity 252 NTU 1.0 1 11/03/17 08:59
2320B Alkalinity Analytical Method:SM 2320B
Alkalinity,Bicarbonate(CaCO3) 523 mg/L 5.0 1 11/05/17 16:10
Alkalinity,Carbonate(CaCO3) ND mg/L 5.0 1 11/05/17 16:10
Alkalinity,Total as CaCO3 523 mg/L 5.0 1 11/05/17 16:10
REPORT OF LABORATORY ANALYSIS
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Date:11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 20

PKeviseCl"Kepor rvices,LLC'
e. Suite100
dCeAlc3lyf(Cal' �J Huntersville,NC 28078
tvww p&c%bS:,corri: [phone]
QUALITY CONTROL DATA
Project: J17110036
Pace Project No.: 92361711
QC Batch: 385123 Analysis Method: EPA 180.1
QC Batch Method: EPA 180.1 Analysis Description: 180.1 Turbidity
Associated Lab Samples: 92361711001,92361711002,92361711003,92361711004,92361711005,92361711006
METHOD BLANK: 2135286 Matrix: Water
Associated Lab Samples: 92361711001,92361711002,92361711003,92361711004,92361711005,92361711006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Turbidity NTU ND 1.0 11/03/17 08:59
LABORATORY CONTROL SAMPLE: 2135287
1 Spike LCS LCS %Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
Turbidity NTU 10 10.0 100 90-110
SAMPLE DUPLICATE: 2135288
92361711001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Turbidity NTU 1.6 1.6 1 10
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 20

P`fe AnagyA2p S rvices,LLc
e. Suite 100
a�e�llalyttal Huntersville,NC 28078
y4wlppQa%b8cbmr, [phone]
QUALITY CONTROL DATA
Project: J17110036
Pace Project No.: 92361711
QC Batch: 385113 Analysis Method:. SM 2320B
QC Batch Method: SM 2320B Analysis Description: 2320B Alkalinity
Associated Lab Samples: 92361711001,92361711002,92361711003,92361711004,92361711D05,92361711006 .
METHOD BLANK: 2135247 Matrix: Water
Associated Lab Samples: 92361711001,92361711002,92361711003,92361711004,92361711005,92361711006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Alkalinity,Carbonate(CaCO3) mg/L ND 5.0 11/03/17 11:13
Alkalinity,Total as CaCO3 mg/L ND 5.0 11/03/17 11:13
Alkalinity,Bicarbonate(CaCO3) mg/L ND 5.0 ' 11/03/17 11:13 -
LABORATORY CONTROL SAMPLE: 2135248
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Alkalinity,Total as CaCO3 mg/L 50 47.7 95 80-120
MATRIX'SPIKE&MATRIX SPIKE DUPLICATE: 2135249 2135250
MS MSD
92361521001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Alkalinity,Total as CaCO3 mg/L 6.5.8 50 50 114 115 95 99 80-120 2 25
MATRIX SPIKE&MATRIX SPIKE DUPLICATE:' 2135251 2135252
MS MSD
92361521011 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Alkalinity,Total as CaCO3 mg/L 29.4 50 50 76.5 76.6 94 94 80-120 0 25
Results presented an this page are in the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 20
R

PKevisetl'Hepor rvices,Lac
aceAna/y ieal 0§6� 195M� e. Suite 100
Huntersville,NC 28078
wvwpoelabs con
[phone]
QUALIFIERS
Project: J17110036
Pace Project No.: 92361711
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services-Asheville
REPORT OF LABORATORY ANALYSIS
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PF2VIS2r1"htepOr[rv'ces,LLc
09Q�1�i V40 Suite 100
y aCeAnalytica
Huntersville,NC 28078
tnyvpecelabS_cam
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J17110036
Pace Project No.: 92361711
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92361711001 2017037961 EPA180.1 385123
92361711002 2017037952 EPA 180.1 385123
92361711003 2017037953 EPA180.1 385123
92361711004 2017037954 EPA180.1 385123
92361711005 2017037955 EPA180.1 385123
92361711006 2017037957 EPA 180.1 385123
92361711001 2017037951 SM 2320B 385113
92361711002 2017037952 SM 2320B 385113
92361711003 2017037953 SM 2320B 385113
92361711004 2017037954 SM 2320B 385113
92361711005 2017037965 SM 2320B 385113
92361711006 2017037957 SM 2320B 385113
REPORT OF LABORATORY ANALYSIS
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Date:11/06/2017 03:58 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 20

Revised Re ort
Document Name: Document Revised:August4,3808743 of 47
c7C6AR �.. Sample Condition Upon Recel t(SCUR) Page 1 of 2
Document No.: Issuing authority:
F-CAR-CS-033-Rev.04 Pace Quality Office
Laboratory receiving samples:
Asheville❑ Eden[] Greenwood❑ Huntersville'[] Raleigh[] MechanicsviilQ[]
Sample Condition
ClIentre:...
Project '..'/` �� .1.`41..+-.
C.M '- LISPS QCIlent--
❑Commercial Pace 00ther:_____
Custody Seal Present? []Yes Na Seals intact? ❑Yes 090 g
Oate/Inhlafa Person Examining Contemn:r. _ tLS�
Packing Materiel: ❑Hubble Wrap ❑Bubble gags None ❑ Other Biological Tissue QqnO
Thermometer• ❑Yes '❑No N/A
IR Type f I
Gun C Wet ❑Flue ❑None
Correction Factor: Cooler Temp Corrected(%J. Temp should be above freezing to 6'C
Qsamples out of temp criteria.Samples on Ice,cooling process
has begun
USOA Regulated Sell N/A,watersample)
Did samples origi in a quarantine zone within the United States:CA,NY,or SC(check maps)? Did samples originate from a foreign source(inter ,
Yes rAD Including Hawaii and Puarto Rico)?[]Yes No
Comments/Oiscre ancy:
Chain of Custody Present? 0 v r1No N A 1.
-Samples Arrived within Hold Time? ves QN. N A 2.
Short Hold Time Analysis 42 hr.)? QYes o ❑N/A 3.
Rush Turn Around Time Requested? v No /A 4.
Sufficient Volume? Yoe QNo 13WA S.
Correct Containers Used? yes ❑WA 6.
-Pace Containers Used? LIVes No N/A
Containers Intact? o No N/ 7.
Dissolved analysis:Samples Reid Filtered? MM ONo /A 9.
Sample Labels Match COC? Kveu ❑Nu ❑N/A 9.
-includes Date/Time/ID/Analysis Matrix:
Head space In VOA Vials(;,S-6mm)? oves N/A W.
Trip Blank Present? QYes ONo rNJA
11,
-TripBlank Custody Seals Present? Yes No
CLIENT NOTIFICATION/RESOLUTION Field data Required? []Yes []No
Person Contacted: Date/Time:
Comments/Sample Discrepancy:
Lot 10 of split containers:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Note: Whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form will be cent to the North Carolina DEHNR CertiflwUon Office(Le.
Out of hold,Incorrect preservative,out of temp,Incorrect containers)
Page 18 of 20

Revised Re ort
Document Name: Document Revised:August 4,FP�jaq 44 o 47
Sam l*Condition Upon Recei t(scuR) Page 2 of 2
aceAnalytkal� Document No.: __IssuingAuthorjty:
F-CAR-M033-PAv.04 � _---- - -T- ---
*Check marls top half of hox if pH and/or dechlorinatlon Project p r, 9235.1.7
Is verified and within the acceptance range forI'l:KLMi. Due. Y ' ?
preservation samples. 92.-thrita a1:::. ? l
**Bottom half of box is to list numbor of bodes _:._:...
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_ a v N iq ry c 9 ry $ ? 3 Q
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pH Adjustment Log for Preserved Samples
Sample ID Tppe of presmatiue pH upon receipt Date preaervatlon adjusted Time presarvat[on Amount of Presma&e dot 0
adjusted added
Page 19 of 20

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'

Revised Report
Page 47 of 47 ; r
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B" Da�crip.ofi of,5brface Water am Sing Situ �` �� r
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• 5W1 At Di char[Q�e from p� ed stream beneathCCP structural 11 Currently be►ng� �
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ampied}ih pry{and Note ber, .° 4
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,November `
. SW3-Al' namedt fbUta' of Asheitille pir o,rt ro'e boon a
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,5W5-A ,A1 ernative:.bac) untl sc�r€ace utates� e
Su de Water Monitarin Anaiytes
Metals-, Wet Chemistry
At0 -1hum Cfilpr�de'g h { lk '#..� k # a S .r
Antirriony Sulfate x
gie
,.Arsenic
-Bariurrc °:k Other Parameters
4"Beryllium
S r
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Atka '
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Cobalt
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,
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rat
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ercury
try �`'�/` H.yy
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;Nickel_ .
.►Potassium
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K`
Silver 5}
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' e

Area of Wetness Inspection and Sampling December 21,2017
Asheville Airport-Structural Fill Area 1 SynTerra
ATTACHMENT C
FIELD SAMPLING LOGS
P:\Duke Energy Progress.1026\02.ASHEVILLE PLANT\44.AOW Area 1\Dec.20 REV DRAFT Memo\Structural
Fill-Area 1 AOW Inspection and Sampling Memo.docx

x
GROUNDWATER MONITORING DUKE ENERGY 'PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
STRUCTURAL FILL I
I w LOW FLOW SAMPLING LOG
FIELD PERSONNEL:
WEATHER: ❑ SUNNY, ;OVERCAST❑ RAIN TEMPERATURE(APPROX): v
148 River street Suite 220 .MULTI METER-TYPE/S#:
Greenville South Carolina 29601 s
(864)42t-9999.[phone] Fax
www.synTerracorp.com TUBITIDY METER TYPE/S#
.WELL ID: •.v PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: . i END PURGE TIME:
WELL DIAMETER: ON END PURGE DATE: FINAL READING TIME:
I WELL DEPTH: (FT) TOTAL VOLUME PURGED: titAL
DEPTH TO WATER: (Fr) SAMPLE DATE: SAMPLE COLLECTION
( - TIME:
k
PURGE METHOD: ❑Grundfos Pump ❑12 Volt Pump Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer [IPolyethylene Bailer
l is r SAMPLE METHOD. ❑Grundfos Pump ❑12 Volt Pump Peristaltic Pump [IDedicated Pump ❑'Teflon Bailer [IPolyethylene Bailer
WATER
: r LEVEL FLOW RATE TEMPERATURE DO CONDUCTANCE pH ORP' TURBIDITY' OBSERVATION
fl( r_. tiear, oudyt," NOTES
(FT) (mVmin) (°Celsiusl 1mg/L) (115/cm) (SU) (mV) (NTU) ;;Floc,
_w/Flneaa=
> It I Z. , 39 9 t _Z S Vo 6 Z.
,
a
NUMBER OF CONTAINERS PRESERVATION-
;,
G CONSTITUENTS SAMPLED :• , _ a 9
METAL$.4 MERCURY.. -..: 1. . r.
ITRATE.SNLOfIlGE SULFATE
Trims 7 �"
ALKALINITY.BICARBONATE,CARBONATE 7` Z .. -.
COMMENTS: IF TURBIDITY>10 NTUS,'REDEVELOPMENT NEEDED ❑YES ❑NO ALL SAMPLES ON ICE❑YES
IF YES,OBSERVATIONS FOLLOWING LOWERING OF TUBING OR PUMP IN WELL:
IF NO,PROVIDE OBSERVATIONS REGARDING NATURAL CONDITIONS:
FIELD VEHICLE':ACCESSIBLE❑YES ❑!NO
Associated niidda /end=of-da D0,conductfvl
!iY 2d0-w}�Cch° TYieter y NOtyp /wgithin nge7e'e calibration sheet for this sampl"e'date) YES�'NO_ oirld be.considered as�fia �cd'accerd l �,
SynTerra is not'NC-certified for these parameters.Data-collected'for information purposes only.
To convert ORP to Eh iisiil YSI Professional Plus 205 mV,,
WELL TAG PROTECTIVE CASING LOCK T CAP 11 CONCB.ETE PAD
❑GOOD ❑BADS ❑NONE ❑GOOD ❑BAD ❑NONE L}GOCD ❑BAD 1]NONE GOOD BAD, NE ❑GOOD ' ❑BAD ❑NONE;
y �
fi I .. .l
P:\Duke Energy Progress,102MOO BLANK'SAMPLE LOGS PER SITE.Ashevllle�Low Flow Sampling Log-STRUCTURAL FILL WOO

GROUNDWATEk viONITORING DUKE .�ERGY PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
STRUCTURAL FILL I
LOW FLOW SAMPLING LOG .
414AFIELD PERSONNEL:
V
WEATHER: El SUNNY Q OVERCAST 0 RAIN TEMPERATURE(APPROX):
synT(
148 River Street,Suite 220 MULTI METER TYPE/S#:,
Greenville,South Carolina 29601
(B64)4214999-(864)42114909 Fax
www.synTerracorp.corn TUBITIDY METER TYPE/S#.
4,
W PUMP/TUBING INTAKE�DEPTH: (FT) START PURGE TIME:
dEASUklq-,X01 T... T START PURGE DATE: END PURGE TIME:
_POIN 'CIC
WELL DIAMETER: END PURGE DATE: FINAL READING TIME: �0
WELL DEPTH: (FT) TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER: (FT), SAMPLE DATE: SAMPLE COLLECTION
11j, TIME-.
PURGE METHOD. ❑Grundfas Pump ❑12 Volt Pump I:EI Peristaltic Pump [:I Dedicated Pump ❑Teflon Bailer [:I Polyethylene Bailer
SAMPLE METHOD: ❑Grundfos Pump D 12 Volt Pump Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
WATER' P ORP*
LEVEL 'FLOW CONDUCTANCE, TURBIDITY,* OBSERVATION
RATE TEMPERATURE DO
TIME Cigar,Cloudy, NOTES
(FT) (rnIJrnIn) (I Celsius) (milifl-) (gs1cm) (su) (rhv) (NTU) w/Floc,
...--w/Fines i
_C
5
NUMBER OF CONTAINERS PRESERVATION-
2 2
CONSTITUENTS SAMPLED
METALS Ft MERCURY
".NITRATE'CimILCROE.SULFATE A .1
TDSJTSS- u^
ALKALINITY,BICARBONATE,CARBONATE_. 1 1 1 71 1, 1'
COMMENTS: IF TURBIDITY>10 NTUS,REDEVELOPMENT NEEDED [I YES baXO
IF YES,OBSERVATIONS FOLLOWING LOWERING OF TUBING OR PUMP IN WEL
;IF NO, PROVIDE OBSERVATIONS REGARDING NATURAL CONDITIONS:
FIELD VEHICLE ACCESSIBLE❑YES
Associated middiy1end--of-day'DO,-conductivity,OH within range? (S&i'callbration sheet for this sample date)Ej'YES 0 NO.
If.NO,whichparameter NOTE that reported data should be considered.as-fiagged accordingly.
'SynTerra is fidt'NC-certified-for th6sLi'p&Wrrieters._Data collected116FInforifikion purposes only.
To convert ORP to EhLljjfjgrYSI Professional Plus Multi-Meter,-add 205 mV.
WELL 13 TAG
PROTECTIVE CASING CAP CONCRETE PAD
GOOD 13 RAI [I f-, 0 rONE 0 oli jor dNoHE 0 GO D [3 BA [I NONE, q GOOD 1 [I BAD NONE11 [3 000D] ❑BAD 0 ONE P:kDuke Energy Progress.1 026\00 BLANK SAMPLE LOGS PER SITE\AshevilleNLow Flow Sampling Log-STRUCTURAL FILL Ldoc

rticry, v�r .i vvct_c� uJKE'ENERGY.PROGRESS, LLC
t 4 . ASHEVILLE STEAM ELECTRIC PLANT
G�
LOW FLOW SAMPLING LOG
FIELD PERSONNEL: rt _
` t ( WEATHER: ❑ SUNNY- OVERCAST ❑ RAIN TEMPERATURE(APPROX): rp
_
148 River Street,Suit
e 220, ?
lxa . Greenville,south-Carolina=29601 MULTI METER TYPE/S#:
[phone]•[phone] Fax
www.synTerracorp.com TURBIDITY METER'TYPE/S# .^k' D d G
WELL ID; . PUMP/TUBING INTAKE DEPTH (FT) START PURGE TIME: `
_ a -..._
MEASURING POINT-: "TOC START PURGE DATE _ � _ END PURGE TIME:
WELL DIAMETER: (iN) END PURGE DATE: FINAL READING TIME:
WELL.DEPTH: ' (FT) TOTAL VOLUME PURGED; - (GAL) -
- . _
SAMPLE COLLECTION
' DEPTH TO WATER (FT)' SAMPLE DATE I f TIME'
PURGE METHOD: ❑Grundfos Pump ❑12 Volt Pump ❑Peristaltic Pump [I Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
SAMPLE METHOD;. ❑Grundfos Pump ❑12 Volt Pump .00-6ristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
`LEVEL FLATER
OW^RATE TEMPERATURE DO CONDUCTANCE I pH ORP OBSERVATION,
_ T
h TIME o �: Clear,Cloudy, NOTES
(FT) (mL/min) Celsius) (mg/L) (µ5lem) ! (su) (mV) (NU) w/Floc
.. •. [�URBTI.D"
_. w/Fines -s
jo
r : - — -
IL-420
16
. _.
NUMBER OF.CONTAINERS.. .-., x._... .PRESERVATION:.,
o f a
E E. E E E E. E i E
CY
N
CONSTITUENTS SAMPLED
{ ,`METALS._,=._-.... _-..._.._.. -=-- :. .._-.. :.,. .:�=' .,-.-' •1�` ✓ -
SULFIx
ALKALINITYBICARBONATE'CARBONATE—""'"- -"":"` -_ 1 -
�`TOTAL`ORGANIC CARBON
CL,504. f
TDS.TSS; :_ _ 1'- 1. ✓
.:CNROMRIM(Vl). - -- v _-c; ,. 1 ... '- - -.✓, -
COMMENTS: IF TUR81aC[Y>70 N1U ,RECiEyEi,OPh�MT'NEED9d.[j',Y ❑NO ALL SAMPLES ON 14 ES
IF YES 5QB$El i/AFlt)NS EOLWVI(1 44 LQWI:R)iYG Ol'TlI IKG OR PUMP IN°,WE :"•
IF NO PR011(DECiBSER #iltONSftEARAING;NA`fUtAE_GONOITIONS:
FIELD VEHICLE ACCESSIBLE❑YES O
Associated midday/end=of•day"DO,conductivity,pH within range?(See calibration sheet-for this sample date) YES El NO.
-".;-If-NO .which "arameter -.-- NOTE that reported,data should be considered as-flagged accordiii l . _
SynTerra IS"notNC-certified fort ese parameters Data collected for Information purposes only;
To convert.ORPao Eh uslli'-:YSI Pf3ates3l'" h:Plus Multi-Meter;add 205..mV:
WELL TAG ` PROTECTIVE CASING LOCK " CAP _ ___." -CONCRETE PAD
a-p GOOD i ❑BAD ❑NONE ❑GOODS 0 D D ii p BAD OEiE ` ❑GOOD ❑BAD 0 NONE f ❑GOOD _(]BAD ❑NONE.
P:\Duke Energy Progress.1026\00 BLANK SAMPLE LOGS PER SITEVAsheville\Low Flow Sampling Log IMP.dooc�"= -

GROUNDWATEF DNITORING DUKE .,4�ERGY PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
STRUCTURAL FILL I
LOW FLOW SAMPLING LOG
FIELD PERSONNEL:
sy OT(e WEATHER: 0 SUNNYOVERCAST [3 RAIN TEMPERATURE(APPROX):' r o
148RIver Street,Suite 220 MULTI METER TYPE/S#-.
Greenville,South Carolina 29601(864)421.9999-[phone] Fax V(X)
www.synTerracorp.com TUBITIDY METER TYPE/S#
WELL ID: Sw PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME;,'
WELL DIAMETER,., END PURGE DATE: FINAL READING T Mt..
WELL DEPTH: (FT) TOTAL VOLUME
DEPTH TO WATER: (FT) SAMPLE, .DATE:' SAMPLE COLLECTION
TIME:
El Grundfos Pump [112 Volt
PURGE METHOD: t Pump ❑krisialtic-Aurn'P: [I Dedicated Pump [:I Teflon Bailer [I Polyethylene Bailer
f V SAMPLE METHOD: El Grundfas Pump 0 12 Volt Pump -�A§fRta�JC�k 0 Dedicated Pump El Teflon Bailer [I Polyethylene Bailer
WATEV-7,.
LEVEL. . FLOW RATE TEMPERATURE DO CONDUCTANCE PH ORP- TURBIDrry4,. OBSERVATION
TIME Clear,Cloudy, NOTES
(FT) (ml./min) (1 Celsius) (mgll.) (AS/CM) (5U) (MV) (NTU) w/Floc,
w/Fines
z7v_s Ll-13
•
0::t_>e.5 _L4
�
I,. NUMBER OF CONTAINERS PRESERVATION
>1 >t
C5 C5 < P4
CONSTITUENTS SAMPLED 2
x 2.
METALS 6:MERCURY
k7CHLORIDE SULFATE
DSfgS 7
I- I-
I ALKALIWrY.BICARBONATE.CARBONATE ,j_�
COMMENTS: IF TURBIDITY>10 NTUS,REDEVELOPMENT NEEDED ❑YES ❑NO ALL SAMPLES ON ICE
IF YES,OBSERVATIONS FOLLOWING LOWERING OF TUBING OR PUMP
S'
IF NO,PROVIDE OBSERVATIONS REGARDING NATURAL CONDITIONS:
FIELD VEHICLE ACCESSIBLE❑YES'
Associated midday/end-ofoday DO,conductivity,PH within range?(See calibration'sheet for this sample date)El YES No.
If NO,which parameter._..-NOTE that reported data should be considered as flagged accordingly.
SynTerra is not NC-ceftified for these parameters.Data collected for fnformation'F!ur os ,
To convert ORP to Eh IuifnA!YSI Professional Plus Multi-Meter,,add'205
WELL TAG 00��!Ntrl 7"1* _ LACK CAP CONCRETE PAD
[3 GOOD [I I:ii i D [I NONE.OD E3 NONE -.P99 T ON qT ti P�A�T
PADuke Energy Progress,1026\00 BLANK SAMPLE LOGS PER SITE\Asheville\Low Flow Sampling Log-STRUCTURAL FILL I.doc

GROUNDWATER i-i,..,NITORING DUKE F-INILAGY PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
LOW FLOW SAMPLING LOG - STRUCTURAL FILL I
-
FIELD PERSONNEL: N-3
C-
TeWEATHER: El SUNNY' OVERCAST 0 RAIN TEMPERATURE(APPROX):
-sw
dr
148 River Street,Suite 220
MULTI METER TYPE/S#:
Greenville,South Carolina 29601
[phone]-,[phone] Fax
www.synTerracorp.com TUBITIDY METER TYPEIS# a
WELL ID: PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT- TOC START PURGE DATE: END PURGE TIME:
WELL DIAMETER: END PURGE DATE: FINAL READING TIME: Zy
WELL DEPTH: (FT) TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER: (FT) IJAMPLE DA:r,E*. SAMPLE COLLECTION TIME:
tleA Jr -
PURGE METHOD: Ej Grundfas Pump El 12 Volt Pump El Per-kiilkk Pump. ❑Dedicated Pump []Teflon Bailer [I Polyethylene Bailer
SAMPLE METHOD: ❑Gruhdfas Pump [112 Volt Pump�[FP,prjstalt1cFPump 0 Dedicated Pump E]Teflon Bailer [I Polyethylene Bailer
WATER
LEVEL LOW RATE TEMPERATURE DO CONDUCTANCE PH ORP* TURBIDITY" OBSERVATION
TIME Clear,Cloudy, NOTES
Celsius)
(FT) (m]LImin) Celsius) (mg/L) (PS/CM) (su) (MV) (NT.U) w/FlGc,
w/Fines
MPOZA-A-1
Jf
OA
-NUMBER OF CONTAINERS PRESERVATION
0 0
2
0
CONSTITUENTS SAMPLED
0,
,METALS&MERCURY -7-
-'NITRATECH
TDS/TSS
��LINITY],BICARBONATE,CARBONATE j_ Lt—
COMMENTS;� IF TURBIDITY>10 NTUIS, REDEVELOPMENT NEEDED ❑YES ❑NO ALL SAMPLES ON 1;CE-eYES
IF YES,OBSERVATIONS FOLLOWING LOWERING OF TUBING OR PUMP IN
IF NO, PROVIDE--085*VATIONS REGARDING NATURAL CONDITIONS:
FIELD VEHICLEACCESSIBLE F-1 YES Nil'
cc ted Ilbfdd�qlflri a O9011cUy1ty,,pH Within range?(See calibration sheet for.,thisSarnpid dqte),,0�yj;Sr1'Q NO;
it 146i'.which`PaMmet4r,n-a z140it ihatf6a6fteilldata should be considered as,flaklid"accor'llngly
SynTerra is not-NC eertlfbad for th'esie pairBm!=,i,,.=collectecIfor information purposes only. "u
-
To convert ORPto.Eh.us�YSIOr"ofessional. lusMdlt!!W 'Id.? 5-mV.
WELL TAG -PROTECTIVELOCK CAP i CONCRETE PAD
0 GOOD J]BAD NE [3 GOOD f a BA;j 0 NONE Coc 13 BAD 0 NONE
t-- 13
0 NO .1 -A��-7
PADuke Energy Progress.1 026\00 BLANK SAMPLE LOGS PER SITE\Asheville\Low Flow Sampling Log-STRUCTURAL FILL'[-,doc

;i.
GROUNDWATEF DNITORING DUKE —.JERGY PROGRESS, LLC a,
ASHEVILLE STEAM ELECTRIC PLANT
— STRUCTURAL FILL I
LOW FLOW SAMPLING LOG
FIELD PERSONNEL:
tw _ 1.
.Wn� Yy�' WEATHER SUNNY ❑ OVERCAST ❑ RAIN TEMPERATURE(APPROX): �`J
1 1�rA
1'48 River Street,Suite 220
MULTI METERTYPE/S#: =
Greenville,South Carolina 29601 Y ks
[phone]•[phone]:':Fax r -
www.synTerracorp.com TUBITIDY METER TYPE/S#
s WELL ID: ,A( PUMP/TUBINGINTAKE DEPTH:_. (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME:
WELL,DIAMETER: (IN) END PURGE DATE: ��° FINAL READING TIME: t(O-
WELL DEPTH: (Fr) TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER: (FT) SAMPLE DATE: j SAMPLE COLLECTION
_.• I,—f TIME: �1 bs.
PURGE METHOD: ❑Grundfos Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
SAMPLE METHOD: ❑Grundfos Pump []12 Volt Pump Peristaltic Pump [I Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
WATER
A EL FLOW RATE'q` TEMPERATURE DO CONDUCTANCE pH ORP• TURBIDITY' OBSERVATION
_ .. _
TIME Clear,Cloudy, : NOTES i
(FT) (mUmin) (•Celsius) (mg/L) (PS/CM) (SU) (mV) (NTU) w/Floc,
w/Fines
i � , k
JJ�(e
m ,
I
✓tip , on S�a e
- i
NUMBER OF CONTAINERS PRESERVATION
T14,
E_..-CONSTITUENTSSAMPLED -
METALS.rYMERCURY -. a _ _. ... __ _... _.»..- _-___. ._., 1 '=•r ...,. - , ✓ _..
,...NITRATE:CHLORIDE,SULFATE..:
TDS/TSS � _. - — :: — _ A; �'. ✓.
"ALKALINITY"BICARBONATE}CARBONATE '
COMMENTS: IF TURBIDITY>10 NTUS, REDEVELOPMENT NEEDED ❑YES ❑NO Y ALL SAMPLES ON ICE'❑YES
IF YES,OBSERVATIONS FOLLOWING LOWERING OF TUBING OR PUMP IN WELL:
IF'NO,PROVIDE OBSERVATIONS REGARDING NATURAL CONDITIONS:
FIELD VEHICLE ACCESSIBLE❑YES ❑NO
Associated midday/end-of-day DO,conductivity,pH within range?(See calibration sheet for this sample date)❑YES❑ NO.
If NO,which parameter _NOTE,that reported data shouldbe considered as_1`12gged accordingly._
"SynTerra is not NC-certified for these parameters.Data collected for information purposes only.
To convert ORP to Eh using_YSI Professional Plus Multi-Meter,add 205mV.
WELL TAG PROTECTIVE CASING LOCK CAP CONCRETE PAD
Q GOOD ❑BAD ❑NONE ❑GOOD i ❑BAD ❑NONE []GOOD: ❑BAD~ ❑NONE ❑GOOD ❑BAD ❑NONE ❑GOOD ❑BAD ❑NONE
PADuke Energy'Progress;1026\00 BLANK SAMPLE LOGS PER SITEVAsheville\Low Flow Sampling Log-STRUCTURAL FILL'Ldoc

GROUNDWATER 1-., .QITORING DUKE E.--RGY PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
STRUCTURAL FILL I
LOW FLOW SAMPLING LOG
FIELD PERSONNEL:
fferra WEATHER: SUNNY 0 OVERCAST 0 RAIN TEMPERATURE(APPROX):
sy
jilv.r Street,Suite 220 MULTI METER TYPE/S#:
Greenville,South Carolina 29601
(o
64)421-9999-[phone] Fax
ww#.synTerracarp.com TUBITIDY METER TYPE/S# 7,(c)a Cs-
Q l V;\ $� (FT)
PUMPITUBING INTAKE DEPTH: START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME:
WELL DIAMETER: END PURGE DAT FINAL READING TIME:
WELL DEPTH: TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER, (FT) SAMPLE DATE: SAMPLE COLLECTION
TIME: 132 S
PURGE METHOD: [I Grundfos Pump [1 12 Volt Pump .1771 Peristaltic Pump El Dedicated Pump ❑Teflon Bailer [I Polyethylene.Baller
SAMPLE METHOD: 0 Grundfos Pump ❑ 12 Volt Pump XPeristaltic Pump ❑Dedicated Pump E]Teflon Bailer [I Polyethylene Bailer
WATER LEVEL FLOW RATE TEMPERATURE DO CONDUCTANCE' PH ORP, TURBIDrTY* OBSERVATION
TIME Clear,Cloudy. NOTES
(FT) (mlJmin) (*Celsius) (Mg/0 (Wcm) (su) (mV) (NTU) i WIFIOC,
w/Fines
C, C C,
NUMBER OF CONTAINERS PRESERVATION
0
CONSTITUENTS SAMPLED
METALS St MERCURY
f NITRATE-CHLORIDE.SULFATE' J
TD S/TSS11
L A I f'ALKAUNITY.BICARBONATE.CARBONATE ------
COMMENTS: IF TURBIDITY>1 0 NTUS, REDEVELOPMENT NEEDED E]YES E]NO ALL SAMPLES ON IC06ES
IF YES,OBSERVATIONS FOLLOWING LOWERING OF TUBING OR PUMP IN )
IF NO, PROVIDE OBSERVATIONS REGARDING NATURAL CONDITIONS:
FIELD VEHICLE ACCESSIBLE El YES "NO
Attoti4l6ed middi U;tlyl;y, PH,within range?(See calibration ftetfor,thiS,sain --ddtt)�FT-YES(JR0.
If Nl.. which'64 et6porti!d.-data should be considered�s'tlkl
SyhTdrrAJs.notAC=Cert1fIe-d for,these parameters. 0C0 f I'fl'
or n prm ati,
"I ta l To convert ORP to Eh using YSI'Professional
Plus MUlti;.Mbter 2.05�ml�t,
CAP CONCRETE PAD,,WELL TAG PROTECTIVE CASING LOCK
ON❑�GOO� El BAD 0 NONE [I NONE E3 GOID El BAD [I GOOD 0 BAD
PAD
'VAQ�J_Cl NONE— 0 NONE
P:\Duke Energy Progress.1026100 BLANK SAMPLE LOGS PER SITElAsheville\Low Flow Sampling Log-STRUCTURAL FILL Ldoc

SURFACE WATER MONITORING DUKE tNERGY PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
- STRUCTURAL FILL I
LOW FLOW SAMPLING LOG
FIELD PERSONNEL:
WEATHER SUNNY ❑'OVERCAST ❑ RAIN TEMPERATURE(APPROX):
- --
' 148 River Street,Suite 220 MULTI METER TYPE/S#: `.t
Greenville,South Carolina 29601
[phone].(B64)421-9909 Fax "-
www.synTerracerp.com TUBITIDY METER'TYPE/S#
p,.. WELL ID: Is,
q1 PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME:
WELL DIAMETER; ;"tN} END PURGE DATE: FINAL READING TIME:
WELL DEPTH: (FT) TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER: (Fr) SAMPLE DATE: 7('L�1, SAMPLE COLLECTION
I TIME: lots-
PURGE METHOD: ❑Grun os Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer .'
SAMPLE METHOD: ❑Grundfos Pump ❑12 Volt Pump ❑,Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer -❑Polyethylene BIIiler,"-• "
WATER ... mm....
LEVEL
FLOW RATE TEMPERATURE DO CONDUCTANCE pH ORP' TURBIDITY' OBSERVATION e
TIME _ .___ _ --- -- Clear,Cloudy, NOTES
(FT) (mumin) (°Celsius) (mg/L) (4/cm) (SU) (mV) (NTU) w/Floc,
w/Fines
: 3 .�.. - t our ca!r�
t
r
-
NUMBER OF CONTAINERS - PRESERVATION
CONSTITUENTS.SAMPLED =, ZJ X _. _.. .�
METALS aMERCURY ._.._., .- r-.,-. ,:._..-5. .1• .,.,. -.. i..„ _._
;PYES
tfITRATE;�LORIDE SULFATE» :-��.,TDS/TSS_ALKALINITY.BICARBONATE,-CARBONATE _- ,1 " -COMMENTS: IF TURBIDITY>10 NTUS,REDEVELOPMENT NEEDED ❑YES ❑1� ALL SAMPLES ON ICE
IF YES,OBSERVATIONS FOLLOWING LOWERING OF'IUBIN
IF NO,PROVIDE OBSERVATIONS REGARDING NATURAL.- DITi0 S.
FIELD VEHICLE ACCESSIBLE❑YES 'NO
iAf NO wh hf araatttete o c y"DO,cd-ndUctilvityj PH
that orted.da within-
`?-(S`ee litlT?�tioh 5 t for this tAfnpla )Q-Y65
to should be considered as flag#edlactmrdiri ( .
•SynTerra is not NC-certified for tbesdoparameters. Data collected for information purposes only: `
J` To convert ORP to Eh using YSI Professional Plus Multi-Meter,add 205.mV.
WELL TAG PROTECTIVE 6sI4& k GAP"""`"" .... CONLRETE PAD
❑GOOD- ❑-BAD 19 ❑BAD ❑NONE ❑GOOD ❑ ): y .I• :, AO �-.'Q'?TO t-' ❑GOOD ❑BAD ❑NONE
P:\Duke Energy Progress 1026\00 BLANK SAMPLE LOGS PER SITE\Asheville\Low Flow Sampling Log-STRUCTURAL FILL I,doc

Ir
r SURFACE WATER MONITORING DUKE ENERGY PROGRESS,, LLC
ASHEVILLE STEAM ELECTRIC PLANT
- STRUCTURAL FILL I
C` LOW FLOW SAMPLING LOG
FIELD PERSONNEL
WEATHER:
�!".. ,SUNNY ❑ OVERCAST ElRAIN TEMPERATURE(APPROX)
148 River Street,Suite 220 MULTI METER TYPE/S# -
y Greenville,South Carolina 29601
'l I [phone].(864)421-99D9 Fax — w
wwwsynTerracorp.cam TUBITIDY METER TYPE/S#
f WELL ID: PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME:
WELL DIAMETER: (IN) ® END PURGE DATE: FINAL READING TIME:
WELL DEPTH: (FT) TOTAL VOLUME PURGED: (GAL)
- SAMPLE COLLECTION
DEPTH TO WATER: (FT) SAMPLE DATE (,' ,/ TIME: J✓�
PURGE METHOD- ❑Grundfas Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
r SAMPLE METHOD: ❑Grundfas Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
WATER
-LEVEL FLOW RATE TEMPERATURE DO CONDUCTANCE -PH j ORP• TURBIDITY- OBSERVATION
l TIME `. Clear,Cloudf4 NOTES i
(FT) I (mUmin) (°Celsius) (mg/L) (µS/cm) (su) (mV) (NTU) w/Floc,
w/Fines
I
-
__ -.NUMBER OF CONTAINERS �� , '_._ _ -.PRESERVATION
E E E
m
jCONSTITUENTS SAMPLED_ ,___.—___. _ 'r_ _� $ _.` __ _ _ _
METALS It MERCURY,
`
--
'. NITRATE-CHLORIDE SOLFATE '-.:..- .. _ ky1.' _+ ;_ _
TDSfrSS
=ALRAuNITYR;BICARBONATE„CARBONATETt
- - —
COMMENTS: IF TURBIDITY>10 NTUS,REDEVELOPMENT NEED U"YEO ALL SAMPLES ON ICE YES
IF YES,OBSERVATIONS FOLLOWING LOWERING t MPIF NO, PROVIDE OBSERVATIONS REGARDING NATURA
FIELD VEHICLE ACCESSIBLE❑YES 0
,_ -
Assaei$ted mf itittzt[vity,pI {+t3thlh T`ItoT:(5ecalibration sheet far tF►is sample dte�'_ YES fiy0
R NO,:which.pafametet -- NOTE:1hat:rep6�,f6d data shauld.be considered as ffagge�l accordingly. „
�:S.ynTDj fiXh-usnY P
,DatiftIt cted for info. matlon.-purposes only,
Tvert RPto add205mVgSI Professional Plus Mue
f r
❑G D ❑BAD []NON _ ONC
. __.
EtLT PROTECT $ iNG LOCK 1 CAP C BAD ONE
E,� ❑GOOD ❑BAD ONE ❑GOOD ❑ ❑NO ❑G000 ! ❑qA ❑NO E ❑GOOD —
PADuke Energy Progress.1026\00 BLANK SAMPLE LOGS PER SITE\Asheviile\Low Flow Sampling Log-STRUCTURAL FILL I.doc

SURFACE WATER MONITORING DUKE ENERGY PROGRESS LLC
ASHEVILLE STEAM ELECTRIC PLANT
— STRUCTURAL FILL I
LOW FLOW SAMPLING LOG
bw
v .
FIELD PERSONNEL: y - ^= -� -
-- -
WEATHER SUNNY ❑ OVERCAST ❑-RAIN TEMPERATURE(APPROX): 6.o
148 River Street,Suite Z20
Greenville,South Carolina 29601 MULTI METER TYPE/Sq ( E .
[phone]•[phone] Fax
TUBITIDY METER"TYPE/Sq :_ "
wwws nTerracor .com {{
Y P a G'��. b .',.
WELL ID; -` ,` PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME:
WELL DIAMETER: AN) END PURGE DATE: FINAL READING TIME:
WELL DEPTH: (FT> TOTAL VOLUME PURGED: (GAL)
SAMPLE COLLECTION
DEPTH TO SKATER: (FT) SAMPLE DATE: TIME: Z S�
_ PURGE METHOD: ❑Grundfos Pump ❑12 Volt Pump ❑'Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
SAMPLE METHOD: ❑Grundfos Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
I: WATER
LEVEL FLOW RATE TEMPERATURE Do CONDUCTANCE -pH ORP• TURBjorry- `OBSERVATION
TIME t Clear,Cloudy, NOTES'(Fr) (mL/min m(°Celsius) ( g/) (µ5lcm) (su) (mV L ) (NTU) ;,� wlFloc,
w/Flnes
oo i� dam.
• -
,
I ; F
-
f i
NUMBER OF CONTAINERS _ __PRESERVATII-ON
p
O O' O
t f
CONSTITUENTS SAMPLED ; . _ __; _ Z. o '
.:'"MErALS&.MERCURY•,.,::.. - u v <: , 1 _ ... -` - `- F: ,,. ,r �: _
'..NITRATE;'CHLORIDE,SULFATE - ` "".,"'" _ _.•-'.1.: - - n.:. a:
TDSLTSS_- w , y - -
ALKALINITY,BICARBONATE:CARBONATE ::�" _--_.- .. 1 ✓ - -
COMMENTS: IF TURBIDITY>10 NTUS, REDEVELOPMENT NEED ,d ?1�6"`` ALL SAMPLES ON I ES.
Y
IF YES, OBSERVATIONS FOLLOWING LOWERING OlF Ut ,G OR PUMP IN WELL:
IF NO, PROVIDE OBSERVATIONS REGARDING NATd NDITIONS:
FIELD VEHICLE ACCESSIBLE❑YES NO
Assn tote t miditVf and-af`d DOr adIrldo'tivity,'pH`vttthin fa►tge7:�Se i as,br tiorr s Dtfor,,thi sample date'* YES* > NO
If:NO;-which 8ea he#er .-NOTE that'te orted,data should.be considered as;fli6 etl atcordingl _ .. _' "
•SynTerra is not'NC-certified for these Parameters.DAta.c011ected for:3nfortrtatipn purposes-oni.;
To convert ORP to Eh tislflgYSl_Professional Plus Multi,Mete�;.add_205 rnV._
. _ si ai
r _
WELL TAG '�.'`PRCI`iVECASINO++ - ,`L ' t` CA, CRET�"PAD
❑GOOD ❑BAD ❑NO1 ❑GOOD []BAD ❑NONE ❑GOOD BAD NONE D ❑BAD f. ❑NONE GOOD ❑BAD ❑NONE; '
PADuke Energy Progress.1026\00 BLANK SAMPLE LOGS PER SITE\Asheville\Low Flow Sampling Log-STRUCTURAL FILL Ldoc

SURFACE WATER MONITORING DUKE ENERGY PROGRESS, LLC
AS'HEVILLE STEAM ELECTRIC PLANT
- STRUCTURAL FILL I
S w� ljI LOW FLOW SAMPLING LOG
FIELD PERSONNEL:
�/�^�Ter� WEATHER ki SUNNY ❑ OVERCAST ❑ RAIN TEMPERATURE(APPROX): tp U
148 River Street,Suite 220 — _ __._
{®c �� MULTI METER TYPE/S#: /
/ Greenville,South Carolina 29601 � [ >�"• � -
(864)-421.9999•(954)4ZI.9909 Fax TUBITIDY METER TYPE/S#
www.synTerracarp.com 'If 0 0 _
WELL ID: 1 . -� PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME:
WELL DIAMETER: (Ix) END PURGE DATE: FINAL READING TIME:
WELL DEPTH: (Fr) TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER: (FT) SAMPLE DATE: - SAMPLE COLLECTION
_ 1 LA TIME:
PURGE METHOD: ❑Grundfos Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
1 SAMPLE METHOD: ❑Grundfos Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
j: WATER
LEVEL FLOW RATE TEMPERATURE DO CONDUCTANCE pH ORP• TURBIDITY- OBSERVATION j
TIME '' --" I'Clear,Cloudy NOTES `
(FT) (mUmin) (°Celsius) (mg/L) (AS/CM) (Sul (mV) (NTU) w/Floc,
+ (� j q
' i !
t,.
j
NUMBERAF_CONTAINERS_ _ -PRESERVATION=
g g o
CONSTITUENTS_SAMPLED �_ - g: Z = _. 1
METALS$:MERCURY .. '• - - f• _ - - _ 'g.,; ,./ I __ E
NITRATE CHLORIDE SULFATE _. 1 ..; •- �/. - ... _- _ .
TDS/TSS 1 _
ALKAuNrry,,B1CARaONATE,CAUCHATE-
COMMENTS: IF TURBIDITY>10 NTUS, REDEVELOPMENT NEEDED "t6N
ALL SAMPLES ON ICEIF YES,OBSERVATIONS FOLLOWING LOWERING OF'TUWELL:
IF'NO, PROVIDE OBSERVATIONS REGARDING NATURAL
FIELD VEHICLE ACCESSIBLE❑YES ( j No
Associated midday/end-of=day DO,conductivity,pH within range?(See calibration sheet for this sample date),E];Ygs' 'P. 'A
If N0,which parameter NOTE that ieported data Should be considered_as.flagged accorclingly._
*SynTerra is not NC-certifled for these parameters.Data collected for Information purposes-only.
To convert ORP to Eh using YSI Professional Plus Multi-Meter,.add 205 mV.
WELL TAG PROTEC7(V ;- CAP ' _. RITE PAD
❑GO [)gA,-i ❑NONE ❑. - ❑BAD []. E !t' ❑BA ❑NONE ❑ 0 6 AD I ❑NONfi, GOOD, BAD ❑NONE
PADuke Energy Progress.1026\oO BLANK SAMPLE LOGS PER SITE\Asheville\Low Flow Sampling Log-STRUCTURAL FILL Ldoc

SURFACE WATER MONITORING DUKE ENERGY PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
- STRUCTURAL FILL I
LOW FLOW SAMPLING LOG
FIELD PERSONNEL " `
Cil
---- .
WEATHER ':SUNNY ❑ OVERCAST ❑ RAIN TEMPERATURE(APPROX):
SynTena
148 River Street,Suite 220
Greenville,south Carolina 29601 MULTI METER TYPE/$//
[phone]-[phone] Fax BITIDY METER TYPE/S U /t `
www.synTerracarp.com T
WELL ID: S . AA
PUMP/TUBING INTAKE DEPTH: (FT) START PURGE TIME:
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME:
WELL DIAMETER: (IN) END PURGE DATE: FINAL READING TIME:
WELL DEPTH: (FT)' TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER. I (FT) SAMPLE DATE: SAMPLE COLLECTION
7
_ ++ '� TIME: ..._..(
PURGE METHOD: ❑Grundfos Pump [1 12 Volt Pump Peristaltic Pump El Dedicated Pump ❑Teflon Bailer E]Polyethylene Bailer
❑SAMPLE METHOD: ❑Grundfos Pump 12 Volt Pump Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
r WATER FLOW RATE TEMPERATURE Do CONDUCTANCE �pli ORP- TURBIDITY- I OBSERVATION
LEVEL
TIME Clear,Cloudy, NOTES
f (FT) (mUmin) i (°Celsius) (mg/L) (AS/CM) (Su) (mV) (Kru) w/Floc,
w/Fines
' f
I ,
,
I
NUMBER OF CONTAINERS_ _
- _.. _ - PRESERVATION
_..
I , o i2l,.
E E E m
_ —CONSTITUENTS SAMPLED
.METALS.B'MERCURY _--............ __. .•. „ _ __ _ .. .; ',..... _ ;,1• __. _
NITRATE'CHLORIDE SULFATE - '.:'. -`_ �.-..., •-• ' ._.,, _ --
s
•'TDSCfSS _. 1
ALKALINITY.8ICAR00NATE,,.CARB0MTE -- - - '. 1 ,.7 i n :��. _. .✓ -.,, '- _
COMMENTS: IF TURBIDITY>10 NTUS,REDEVELOPMENT NEEDED YES' NO ALL SAMPLES ON ICEhf YES
IF YES,OBSERVATIONS FOLLOWING LOWERING OF :U.1N(a;OR PUMP IN WELL:
IF NO,PROVIDE OBSERVATIONS REGARDING NATURAL CONDITIONS:
FIELD VEHICLE ACCESSIBLE❑YES NO
-,AssZpated mid ytiend of days f -caf) ri tiv[tpr,att Within rphgo?'�5ee calE�;arin) s#ii t fer t{1s afSipl a cfat+ .O YES' NO., p
If FiO;which. aremeter -.:NOTE that re ort"data'should be consldered as A ed a�ciodlfiglY.
SynTerra Is not NC-certifled for these'parameters.Data.coilletted for infortnatlort.purposes only;!
To convert ORP to Eh using YSl Professional Plus Multl-Meter,add 205 mVi. _
WELL T AG PROTECTIVE CASING LOCK CAP. CONCRETE PAD
❑G00 ❑b ❑No„ _ ❑BAD 0 ❑G00 ❑b NON ❑GOOD BAD D ❑BA_,y ❑NON
PADuke Energy Progress.1026100 BLANK SAMPLE LOGS PER SITE\Asheville\Low Flow Sampling Log-STRUCTURAL FILL I.dod

SURFACE WATER MONITORING DUKE ENERGY PROGRESS, LLC
ASHEVILLE STEAM ELECTRIC PLANT
- STRUCTURAL FILL I
LOW FLOW SAMPLING LOG
FIELD PERSONNEL:
WEATHER. ` SUNNY ❑ OVERCAST ❑ RAIN TEMPERATURE(APPROX): G
148 River street,suite 220 MULTI METER TYPE/Stf:
Greenville,South Carolina 29601
[phone]•[phone] Fax
www.synTerracurp.com TUBITIDY METER TYPE/Sl'!
WELL ID; S�J( 1' PUMP/TUBING INTAKE DEPTH: ( START PURGE TIME:
`
MEASURING POINT: TOC START PURGE DATE: END PURGE TIME
WELL DIAMETER: ((Np END PURGE DATE: FINAL READING TIME:'
WELL DEPTH: (FT) TOTAL VOLUME PURGED: (GAL)
DEPTH TO WATER: (FT) SAMPLE DATE i SAMPLE COLLECTION
TIME: 3
L
PURGE METHOD:. ❑Grundfos Pump ❑12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump '❑Teflon Bailer ❑Polyethylene Bailer
SAMPLE METHOD:. ❑Grundfos.Pump ❑ 12 Volt Pump ❑Peristaltic Pump ❑Dedicated Pump ❑Teflon Bailer ❑Polyethylene Bailer
---µ, WATER
FLOW RATE' •TEMPERATURE ` DO CONDUCTANCE pH oRF• TURBIDITY' OBSERVATION .
LEVEL _
TIME Clear,Cloudy, NOTES
(FT) (mL/min) (°Celsius) (mg/L) (AS/CM) (su) (mV) (NTU) w/Floc,
L133 s l S,_9 . i zs �,! o
-_ _NUMBER NUMBER-OF CONTAINERS --_-PRESERVATION
{ I s
i
W E E E CS
CONSTITUENTS SAMPLED _ . .
-METALS.Q:MEkcuRY... ,-.
"NITRATe.''CHLORIDE-SU FATE „..._._...
TDSTTSS
'ALKALINITY]BICARBONATE;CARBONATE -'s`_" _ .�;? `. .:1t -1 -.i : :--' .._.. ' -
COMMENTS: IF 7URB#DIiY*10"TLISi4tEDE►/ELOPtdENT,NEE1}ED (]Y ¢ ALL SAMPLES ON`ICE
A(P,
( IF YES,t]85 YATlQt�Sd]LC�W#N C OWER#ND 0 61 R'PU ELL:
P:
' IF NO, Itt3YtbE D85ERYt�` tl NIS'REGARDING NA iR/1L ONb1?IQhIS,; ' ° `
FIELD VEHICLE ACCESSIBLE❑YES Nq '
V�
"Associated"midday/end of=day DO,':t6hiliddlyl i pH within.°" a?"See calibration"sheet for tWi Satit'_te dAte ' YE5 = NQ " X
tY. i►�n8 ( R 1 CI'
If PIO,:.which alrismetdr' — --,NOTE that orted data_should be considered as fla id accordin #';
*SynTdrea Is not'NC tbrtifted'for.those'parameters.DataimIlectedloc Information.purposes only.
TO convert ORP fo Eh usingYSI Professional Plus MUIti-Meter,'a&205-mV.
�•_ � -
VIE� _Ao PR4TEt! PING ; LGCK '- ~~ CAP _.� CONCRETE PAD
d* ❑BAD] ❑NONE_ �❑GOOD ❑BAD Dm„NE�i GtA$ I�BAD ❑NONE _ 0 t ❑BAD ❑NONE Gt�t}Q`, ❑BAD ❑NONE v
P:\Duke Energy Progress.1 026\00 BLANK SAMPLE LOGS PER SITEWsheville\Low Flow Sampling Log-STRUCTURAL FILL I,doc

._
AC44715 North Carolina I sion of Water Resources Water Seim iection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44715
County: BUNCOMBE Collector: B LAVERTY VisitlD SW1-A1 PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 09_10 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 1/9118
Report Print Date: 01/09/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 3.8 °C 1113/17 ESTAFFORD1
MET
7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 Al by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-38-2 As by ICPMS, 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-38-3 Ba by ICP 10 41 ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca by ICP 0.10 8.2 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-47-3 Cr by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5A 11/27/17 ESTAFFORD1
7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-89-6 Fe by ICP 50 1300 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORD1
7440-09-7 K by ICP 0.10 1.5 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-93-2 Li ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-95-4 Mg by ICP 0.10 2.6 mg/L EPA200.7 Rev4A 11/20/17 ESTAFFORD1
7439-96-5 Mn by ICP 10 450 ug/L EPA200.7 Rev4A 11/21/17 ESTAFFORD1
7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-23-5 Na by ICP 0.10 4.2 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-31-5 Sri by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-24-6 Sr by ICPMS 10 63 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-28-0 Thallium(TI)ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-32-6 Ti(Titanium)by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/14/17 ESTAFFORD1
7440-62-2 V by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

AC44716 North Carolina D: on of Water Resources Water Sciencf action Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44716
County: BUNCOMBE Collector: B LAVERTY MOO SW1-Al PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 09_20 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
CDC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 12/16/17
Report Print Date: 01/04/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 3.8 °C 11/3/17 ESTAFFORDI
WET
Bromide 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8117 CGREEN
Chloride 1.0 10 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Fluoride 0.4 0.4U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Sulfate 2.0 2.2 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
MET
7440-22-4 Ag-Dissolved Silver by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 Al-Dissolved Aluminum by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-38-2 As-Dissolved by ICPMS Arsenic 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 B Dissolved by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-38-3 Ba-Dissolved Barium by ICP 10 39 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be-Beryllium Dissolved by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-70-2 Ca-Dissolved Calcium by ICP 0.10 8.1 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440A3-9 Cd-Dissolved Cadmium by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-48-4 Cobalt Dissolved by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-47-3 Cr-Dissolved Chromium by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu-Dissolved Copper by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-89-6 Fe-Dissolved Iron by ICP 50 1100 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-97-6 Hg 245.1 Dissolved 0.2 0.20 U ug/L EPA 245.1 Rev3 11/7/17 ESTAFFORDI
7440-09-7 K-Dissolved Potassium by ICP 0.10 1.5 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-93-2 Li DISSOLVED ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-95-4 Mg-Dissolved Magnesium by ICP 0.10 2.6 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-96-5 Mn Dissolved by ICP 10 440 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-98-7 Mo Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na-Dissolved Sodium by ICP 0.10 4.3 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-02-0 Ni-Dissolved Nickel by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-92-1 Pb-Dissolved Lead by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-36-0 Sb Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7782-49-2 Se-Dissolved Selenium by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-31-5 Sn Dissloved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
Sr Dissolved by ICPMS 10 62 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-28-0 Thallium(TI)Dissolved by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-32-6 Ti(Titanium)Dissolved by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/14/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 2

NC DWk ratory Section 1§sufts/Sampfe Comments/Quafifier JD ions
Sample ID: AC44716
CAS# Analyte Name PQL Result/ Method Analysis
Qualifier Units Reference Date Validated by
7440-62-2 V Dissolved by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-66-6 Zn-Dissolved Zinc by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 2

AC44792 North Carolina L...3ion of Water Resources Water Scienc.�Jection Laboratory Results
Loc.Descr.: ASHEVILLEAIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44792
County: BUNCOMBE Collector: B LAVERTY VisitlD SW1-A1 PO Number# ARO
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/02/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 11_63
Emergency Collect Time: 09_20 Sample Matrix: SURFACEWATER Labworks LoginlD KJIMISON2
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 119/18
Report Print Date: 01/0 912 0 1 8
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated bV
ARO
Alkalinity4.5 1.0 28 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Alkalinity8.3 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Bicarbonate 1.0 28 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Carbonate 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
pH Alkalinity 6.3 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Sample temperature at receipt by lab 6.0 °C 1112/17 RBYRD
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

VasatID;
North Carolina Division of Water Resources Tag Lab LdS4' R/y
Water Sample Collection&Submittal Form SW 1-A1 1 -- --- -------------------=`
Central Laboratory(Water Sciences Section) (op`ttonat) 1D- Cvboratory`
.;••.� , 'I'r.? q e Samplelyumtier
Locotlon Descrrpt & Asheville Airport-61 Terminal Drive Fletcher, NC Location Code 1111ASHEVILLEAIRPORT
1 vote Received r:,,
a`.
County Buncombe Collector Brett Laverty Priorrty. WaterMotrix: Location Type:
�
DWd2 Regions �DWR IWIiO River/Stream ��l.ake e Received
Asheville RegionalOperations ❑Ambient
ibasedE-oncaurrty);ti„ {orayedcynarrYej- ❑SurfaC2 ❑Estuary ❑Canal
❑✓ ❑stormwater Routine ReceiuedBya�''�
Rive�BasiR French Broad River Dote 11/1/2017 !!
State Courier
❑Compliance ❑Ground ❑Monitoring Well ❑Water Supply '
Notes: SW1-A1 Tame �` 9:10 AM Delivery Method:' ❑Hand Delivery
❑COC ❑Waste ❑Effluent ❑Influent pia . ,, , ❑Other:
Sampling ❑Grab Composite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field El Other: ❑Emergency ❑Blank Filter Blank [:]Trip Blank
IVlethod ��' Temperature .C
❑ (°'��
Dissolved analysis:Enter"DIS" on Arrival:: .
❑Filtered in Field in check-boxes for parameters SompleDepffe ❑CA ❑Solution ❑Other: '�
Coltectdir's Ct1rh11Yents: --i
Mic vbiology;,Parameters MBAS(surfactants) mg/L j MetalsParanneters.• .r X Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L X Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L
BOD:Biochemical oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L
Coliform:Total MF /loom[ Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /loom[ TDS-Total Dissolved Solids mg/L X Calcium(Ca) mg/L
Coliform:Tube Total /100m[ Silica mg/L X Chromium(Cr),Total µg/L Qrganics Parameters:
Specific Conductance,at 25°C umhos/cm Sulfide mg/L X. Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides
�OtherEarameters.s �, X Lead(Pb) µg/L Organophosphorus Pesticides
;Wet ChdniiteVParamet#ts. pH S.U. X Lithium(U) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L
Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range
Sulfate mg/L NutrierrtsPar`ameters. sae X Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADM] c.u. Nitrate-Nitrite as N(NO3+NO2-N) mg/L X Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological;.'
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L
LAB COMMENTS:
m�;.; r,- 4 k.. �..
Fieid Paramete`rs(optlonal/: 'WaterTemp('C)c° p (emu.):" Dissolved Oxygen(ppm): �� Conductivity(µmhos/cm): Salinity(ppt)�°'_'�
Revision:2/06/2015

North Carolina Division of Water Resources Y1sitID.•, Ta Lvb USG11tI
Water Sample Collection&Submittal Form k, SW 1-A1 2
Central Laboratory(Water Sciences Section) (aptianaC) iD Laboratory''
5arriple Number:
Location Description: Asheville Airport-61 Terminal Drive Fletcher, NC Location Code: 1111ASHEVILLEAIRPORT
Qare Received
County. Buncombe Collector: Brett Laverty Priority WtrterMatrixr Locatlontype
ii Time Received:
15WRRegl6n:', DWROffee: URiver/Stre am ❑Lake
Asheville Regional Operations ❑Ambient
(baseJon caurr�l.=.,_ (oragenncyrro�ef= ❑Surface ❑Estuary ❑Canal m Received By:
River Basin:" French Broad River Dater 11/1/2017 ORoutine ❑Stormwater i
El Compliance El Ground ❑Monitoring Well ❑Water Supply Delr ! State Courier
Notes: SW 1-A1 Time • °; 9:20 AM veryMe Pod. ❑Hand Delivery
❑COC ❑Waste ❑Effluent ❑Influent d ❑Other:
sampling ❑✓ Grab Composite ❑Field Blank 3
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank
Method: ❑Other: ❑Filter Blank Temperature("C)'
Dissolved analysis:Enter"DIS" onArrival
❑Filtered in Field SaMpTeDepthr ❑QA ❑Solution ❑other:
in check-boxes for parameters
Collector's Comments:
IVlicfobiologyfiarameters „ e, ,o, ,*„ ., �, �'. MBAS(surfactants) mg/L Metals Parameters,`, � ,��, °,_ � � DIS Tin(Sn) µg/L
Acidity,as CaCC3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L DIS Aluminum(AI) µg/L DIS Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L DIS Antimony(Sb) µg/L DIS Vanadium(V) µg/L
Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L DIS Arsenic(As) µg/L DIS Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L DIS Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L DIS Beryllium(Be) µg/L DIS Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L DIS Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /loom] TDS-Total Dissolved Solids mg/L DIS Calcium(Ca) mg/L
Coliform:Tube Total /100ml Silica mg/L DIS Chromium(Cr),Total µg/L " •�-Organics Parameters,z o
Specific Conductance,at 25°C umhos/cm Sulfide mg/L DIS Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L DIS Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU DIS Iron(Fe) µg/L Organonitrogen Pesticides
TtherPardriie#erss DIS Lead(Pb) µg/L Organophosphorus Pesticides
���WeCfiemistry`Parameters. `i pH s.u. DIS Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L DIS Magnesium(Mg) mg/L.
X Chloride mg/L DIS Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L DIS Mercury(Hg) µg/L TPH Diesel Range
X Sulfate mg/L „:1urientsiPaPaineters. " DIS Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L DIS Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L DIS Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L DIS Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical oxygen Demand mg/L Total Phosphorus as P(TP) mg/L DIS Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L DIS Sodium(Na) mg/L. Biologicah•
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L DIS Strontium(5r) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L DIS Thallium(TI) µg/L
LAB COMMENTS:
Field,Parameters(optlonoii: WaterTemp(°C): pH(s.u.): � Qt)issolved Oxygen(ppm):-. Conductivity(µmhos/cm): , n Salinity(p,-
Revision:2/06/2015

North Carolina Division of Water Resources P Yisrt ID Tcig� y Ldb USe Q' h-
y(Water Sciences Section)Asheville Laboratory Water Sample Collection&Submittal Form SW 1-Al ID 2 ---- -- - -
Laonat)a ` Laboratory a
SamFle Numtier.
Location Descrwran: Asheville Airport-61 Terminal Drive Fletcher, NC Location Code. 1111ASHEVILLEAIRPORT
^ � � Dpte�Recekved�
y _
County Buncombe Collector "`1 Brett Laverty Priority WbterMatriX: tocatronType
° Time Receiver/ ,
OW�44e rpn " fJWR�DffiCe t River/Stream Lake
$• m �"� Asheville Regional Operations Ambient
(basedoricauntyj (aragency-aamej' 9 p ❑� Surface ❑Estuary ❑Canal
g Q Routine ❑Stormwater Re`eeivetl By
RrvetBasm .x French Broad River Date 11/1/2017
El Compliance ❑Ground ❑Monitoring Well ❑Water Supply e
s State Courier
Notes: SW 1-Al Time 9:20 AM Relivery Methi7d:= El Hand Delivery
❑COC ❑waste ❑Effluent ❑Influent ❑Other:
Sampiing 0 Grab Composite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank
Ntetf�od ❑Other: ❑Filter Blank Temperature ro
Dissolved analysis:Enter"DIS" ' onAmvai
❑Filtered in Field Samp7epepth: ❑CIA ❑Solution ❑other:
in check-boxes for parameters ) 1 f
Collectors Comments:
41
Microbiology Parameters:
Acidity,as CaCO3,to pH 4.5/8.3 mg/L
X Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Solids Parameters:
Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L h w°
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L `
Coliform:Tube Total /100m1
Specific Conductance,at 25°C umhos/cm
Turbidity NTU "
Otherfarameters:`
p H S.U.
m
e •
LAB COMMENTS:
,m �. "'@ mral� t'p .•r r: wa r _x n •k Ems_. ", krE KA
;Geld Par`aweters(ogtionall WaterTehtp�(°C)r�� pH(s O), Dissolved Dzygen{pprn) .• � ? Conductivity(µmhos/em): : , 5aliniy(ppt)
Revision:2/06/2015

AC441117 North Carolina L_._..;ion of Water Resources Water Scienc_ jection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44717
County: BUNCOMBE Collector: B LAVERTY VisitlD SW3-A1 PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 10_50 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 1/9118
Report Print Date: 0110 9/2 0 1 8
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 3.8 °C 11/3/17 ESTAFFORD1
MET
7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 Al by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-38-3 Ba by ICP 10 36 ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca by ICP 0.10 7.8 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-47-3 Cr by ICPMS 5.0 6.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-89-6 Fe by ICP 50 280 ug/L EPA200.7 Rev4A 11/21/17 ESTAFFORD1
7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 1IM17 ESTAFFORDI
7440-09-7 K by ICP 0.10 1.5 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-93-2 Li ICP 25 25 U ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-95-4 Mg by ICP 0.10 3.1 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-96-5 Mn by ICP 10 220 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na by ICP 0.10 4.6 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-31-5 Sn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-24-6 Sr by ICPMS 10 58 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-28-0 Thallium (TI)ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-32-6 Ti(Titanium)by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/14/17 ESTAFFORDI
7440-62-2 V by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

tAC44?18 North Carolina I pion of Water Resources Water Scienc__ ._section Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44718
County: BUNCOMBE Collector: B LAVERTY MOO SW3-A1 PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 11_00 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 119/18
Report Print Date: 01/0 912 0 1 8
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 3.8 °C 11/3117 ESTAFFORD1
WET
Bromide 0.4 0.4U mg/L EPA 300.0 rev2.1 11/8117 CGREEN
Chloride 1.0 11 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Fluoride 0.4 0.4 U mg/L EPA 300.0 rev2.1 1118/17 CGREEN
Sulfate 2.0 3.1 mg/L EPA300.0 rev2.1 11/8/17 CGREEN
MET
7440-22-4 Ag-Dissolved Silver by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 AI-Dissolved Aluminum by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-38-2 As-Dissolved by ICPMS Arsenic 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 B Dissolved by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-38-3 Ba-Dissolved Barium by ICP 10 35 ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be-Beryllium Dissolved by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca-Dissolved Calcium by ICP 0.10 7.8 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-43-9 Cd-Dissolved Cadmium by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-48-4 Cobalt Dissolved by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-47-3 Cr-Dissolved Chromium by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-50-8 Cu-Dissolved Copper by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-89-6 Fe-Dissolved Iron by ICP 50 180 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-97-6 Hg 245.1 Dissolved 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORD1
7440-09-7 K-Dissolved Potassium by ICP 0.10 1.6 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-93-2 Li DISSOLVED ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-95-4 Mg-Dissolved Magnesium by ICP 0.10 3.2 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-96-5 Mn Dissolved by ICP 10 210 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-98-7 Mo Dissolved by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-23-5 Na-Dissolved Sodium by ICP 0.10 4.8 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-02-0 Ni-Dissolved Nickel by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-92-1 Pb-Dissolved Lead by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-36-0 Sb Dissolved by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se-Dissolved Selenium by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-31-5 Sri Dissloved by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
Sr Dissolved by ICPMS _ 10 56 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-23-0 Thallium(TI)Dissolved by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-32-6 Ti(Titanium) Dissolved by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/14/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 2

NC O`er., ioratory Section 1§suCts/Sampee Comments/QuaCfier ition s
Sample ID: AC44718
CAS# Analyte Name PQL Result/ Method Analysis
Qualifier Units Reference Date Validated by
7440-62-2 V Dissolved by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn-Dissolved Zinc by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 2

AC441F93 North Carolina I lion of Water Resources Water Scienc section Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44793
County: BUNCOMBE Collector: B LAVERTY VisitiD SW3-A1 PO Number# ARO
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/02/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 11_53
Emergency Collect Time: 11_00 Sample Matrix: SURFACEWATER Labworks Login1D KJIMISON2
COG Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 119/18
Report Print Date: 01/09/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
ARO
Alkalinity4.5 1.0 23 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Alkalinity8.3 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Bicarbonate 1.0 23 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Carbonate 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
pH Alkalinity. 6.7 mg/L as CaCO3 SM 23208-1997 11/13/17 ESTAFFORD1
Sample temperature at receipt by lab 6.0 °C 11/2/17 RBYRD
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

North Carolina Division of Water Resources at1D Tad
Central Laboratory(Water Sciences Section) Water Sample Collection&Submittal Form (ozp>ionalJ' ' SW3-A1 /Dt`I 3 Ldburaeory,-
Sample Number.,
Location Description Asheville Airport-61 Terminal Drive Fletcher, NC d Location Code: 1111 ASHEVILLEAIRPORT ,II
' Date Received:.
bounty `e. Buncombe `Coiiector: Brett Laverty P.r[orrry: WoterMatrin: Lo cut ibn.Type: �
DWR7Reg1on: DWRgffiee: ❑� River/Stream ❑Lake Time Received:
Asheville Regional Operations ❑Ambient
{kcs"edoncourtJ- {orvgencyname) ❑Surface ❑Estuary ❑Canal y
�m Recewed By:
RiverSasint" French Broad River Date: 11/1/2017 ❑� Routine ❑Stormwater
III ❑Compliance Ll State Courier
p El ❑Monitoring Well El Supply
Notes: SW3-Al 10:50 AM DeliverylV�ethodi. ❑Hand Delivery
❑COC ❑Waste ❑Effluent El Influent ❑Other:
❑
❑ Chlorinated ❑ Sampling Q Grab Composite De-chlorinated in Field ❑Emergency ❑ Field Blank Blank ❑Trip Blank
Method: ❑Other: ❑Filter Blank Temperature I"Cl.
Dissolved analysis:Enter"DIS" on Arrival:
El Filtered in Field y �Swnp1'eDepth ❑CIA ❑Solution ❑Other: a
in check-boxes for parameters
Coltector's Comments:
. .,�;�; ( ) g/ _ X Tin ) µg/Micra6iolo Parameters , o MBAS surfactants m L MetalsPararneters:.=.,,r _ (Sn L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L X Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X -Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L X Calcium(Ca) mg/L
Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Otgar►ics Parameters ,.
Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides
f3ther,Paratneers, X Lead(Pb) µg/L Organophosphorus Pesticides
"1Net'thehliStryP,araitt0Eer5",° "' '� ��`` pH s.u. X Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L
Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range
Sulfate mg/L 'Nutrients;Parameters:, X Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L X Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological;`
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L
LAB COMMENTS:
Field Parameters{apHanaq: Water Temp(°C): pH(s,u,): Dissolved Oxygen(ppm): Gohductiv§jµmhos/cm): Salinity(ppt)r
_
Revision:2/06/2015

North Carolina Division of Water Resources VisttID kl
Lab Use ahfjo Water Sample Collection&Submittal Form SM-A1 4 --- -----Central Laboratory(Water Sciences Section) faiZt�anat} ; Loborotory,
Sarripie Number"
Gocatioma7escrrprranr Asheville Airport-61 Terminal Drive Fletcher, NC Location Coded 1111ASHEVILLEAIRPORT
DaL�Received• _
County Buncombe Collector. ' Brett Laverty Priorrtyd `" ' 1NaterMatrix: LocotronTypes I
° Time Received'
OWR j?egron t1. DWk Oce�, River/Strea m ❑Lake
Asheville Regional Operations R. ❑Ambient
u(basedorscouaty)� ' (orogenGy4ame) ❑Surface ❑Estuary ❑Canal
Received By: °-
RiverBasrn ° .t French Broad River Date;,, 11/1/2017 ❑� Routine ❑Stormwater
El Compliance El Ground ❑Monitoring Well ❑Water Supply " �,� , " State Courier
Notes: SW3-Al rme. 11:00 AM DeliveryiHTethodr El Hand Delivery
$$$ ❑COC ❑ ❑Waste ❑Effluent Influent El Other:
Sdrt►Pifng `: ❑✓ Grab LIComposite ❑Field Blank s '
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank
Method: 1 ❑Other: ❑Filter Blank Teriperoture(--Q
Dissolved analysis:Enter"DIS" J or Amvok;,E.
,
❑Filtered in Field somp�ei7epth`_ ❑0A ❑Solution ❑other.
in check-boxes for parameters
Collector s Comments:
"°Mic'robiologV'Parameters<° MBAS(surfactants) mg/L Metal Parameters: DIS Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L DIS Aluminum(AI) µg/L DIS Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L DIS Antimony(Sb) µg/L DIS Vanadium(V) µg/L
Boo:Biochemical oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L DIS Arsenic(As) µg/L DIS Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L DIS Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L DIS Beryllium(Be) µg/L DIS Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L DIS Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L DIS Calcium(Ca) mg/L
Coliform:Tube Total /100m] Silica mg/L DIS Chromium(Cr),Total µg/L Organics Parameters:.
Specific Conductance,at 25°C umhos/cm Sulfide mg/L DIS Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L DIS Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU DIS Iron(Fe) µg/L Organonitrogen Pesticides
Outer Parameters:'_ DIS Lead(Pb) µg/L Organophosphorus Pesticides
Wet Chemistry Parameters: pH S.U. DIS Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L DIS Magnesium(Mg) mg/L
X Chloride mg/L DIS Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L DIS Mercury(Hg) µg/L TPH Diesel Range
X Sulfate mg/L N6trients Parameters: ,� DIS Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L DIS Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L DIS Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L DIS Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L DIS Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L DIS Sodium(Na) mg/L Biologicals
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L DIS Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L DIS Thallium(TI) µg/L
LAB COMMENTS:
field Parameters(optionol): ._Water Temp(°C):;i pN(s.U.): , Dissolved Oxygen(ppm): u; "Conductivity(µmhos/crii): Salinity(ppt):"`
Revision:2/06/2015

North Carolina Division of Water Resources DISC'
Water Sample Collection&Submittal Form = SW 3-A1 4 - - : ---- - --------
Asheville Laboratory(Water Sciences Section) jopteona(J 1 !D Lo6oratery
1 €�_� 5arnple Number°4
tocbtrvn°Descrfpfoni Asheville Airport-61 Terminal Drive Fletcher, NC Location Coder 1111 ASHEVILLEAIRPORT
dote Rece{ved pa
k _. fl e iR1 54pY i s•p X J I i r+ .a, .¢S a� 3 K i l `d �',M � '.:
County Buncombe Collector Brett Laverty Priority WaterMatrrxc LocotronType
�_ xinr Rece�vefl;.-
D 1111#tiRegton: �DVVli�jficet, QRiver/Stream
Asheville Regional Operations ❑Ambient
(basedoncountyf (or agencynorne) ❑Surface ❑Estuary ❑Canal
By.
^ RiverBasrn:� French Broad River Dote 11/1/2017 El Routine ❑stormwater u
`.$ L State Courier
El Compliance El Ground ❑MonitoringWell ❑Water Supply
DebrieryMethod` ❑Hand Delivery
Notes: SW3-A1 —Time 3 11.00 AM V
❑COC ❑Waste ❑Effluent El Influent ❑Other:
Sa►riplggs r ❑✓ Grab Lcomposite ❑Field Blank
❑ Chlorinated ❑ ❑De-chlorinated in Field " ❑Emergency Blank [:]Trip Blank Temp
ilRethod " ❑Other: ❑Filter Blank eroture{'CJe
Dissolved analysis:Enter"DIS" ❑Other: onArrwai.
❑Filtered in Field SorttpfeDeptff ❑Q ❑A Solution
in check-boxes for parameters
Collector s Gomrtments:Y
Microbiology Parameters:
Acidity,as CaCO3,to pH 4.5/8.3 mg/L
X Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Solids Parameters:
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L
CBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L
Coliform:Tube Total /loom)
Specific Conductance,at 25°C umhos/cm °
Turbidity NTU
Other Parameters:
s.u.
LAB COMMENTS:
Field Patameters(optranall: WaterTemp(°C� P (s u), Dissolyed Dxygen(pPml Conductivity(µp rhos/cm}� SahnitY(PPt)
Revision:2/06/2015

AC447-49 North Carolina L _.-sion of Water Resources Water Sciew iection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44719
County: BUNCOMBE Collector: B LAVERTY VisitlD SW6-A1 PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 12_10 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 119118
Report Print Date: 01/09/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result! Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 3.8 °C 11/3/17 ESTAFFORD1
MET
7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 Al by ICP 50 54 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-38-2 As by ICPMS 2.0 2.7 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-38-3 Ba by ICP 10 28 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-70-2 Ca by ICP 0.10 4.1 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-47-3 Cr by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-89-6 Fe by ICP 50 4400 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORD1
7440-09-7 K by ICP 0.10 1.8 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-93-2 Li ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-95-4 Mg by ICP 0.10 1.9 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-96-5 Mn by ICP 10 140 ug/L EPA 200.7 Rev4A 11/21/17 ESTAFFORD1
7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na by ICP 0.10 3.1 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-31-5 Sn by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-24-6 Sr by ICPMS 10 33 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-28-0 Thallium(TI)ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-32-6 Ti(Titanium)by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/14/17 ESTAFFORDI
7440-62-2 V by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

AC4479d' North Carolina D-.___on of Water Resources Water Science ,ction Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44720
County: BUNCOMBE Collector: B LAVERTY VisitlD SW6-Al. PO Number#
Region: ARO Report To ARID Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 12_26 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 12/15/17
Report Print Date: 01/04/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Units Method Analysis
CAS# Analvte Name PQL Qualifier Reference Date Validated by
LAB
Sample temperature at receipt by lab 3.8 °C 11/3/17 ESTAFFORD1
WET
Bromide 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Chloride 1.0 8.8 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Fluoride 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8117 CGREEN
Sulfate 2.0 5.8 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
MET
7440-22-4 Ag-Dissolved Silver by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDi
7429-90-5 Al-Dissolved Aluminum by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1.
7440-38-2 As-Dissolved by ICPMS Arsenic 2.0 2.6 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 B Dissolved by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-38-3 Ba-Dissolved Barium by ICP 10 34 ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-41-7 Be-Beryllium Dissolved by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca-Dissolved Calcium by ICP 0.10 4.3 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440A3-9 Cd-Dissolved Cadmium by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-48-4 Cobalt Dissolved by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-47-3 Cr-Dissolved Chromium by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu-Dissolved Copper by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-89-6 Fe-Dissolved Iron by ICP 50 6200 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-97-6 Hg 245.1 Dissolved 0.2 0.20 U ug/L EPA245.1 Rev3 1117/17 ESTAFFORDI
7440-09-7 K-Dissolved Potassium by ICP 0.10 2.4 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-93-2 Li DISSOLVED ICP 25 25 U ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-95-4 Mg-Dissolved Magnesium by ICP 0.10 2.1 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-96-5 Mn Dissolved by ICP 10 210 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-98-7 Mo Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na-Dissolved Sodium by ICP 0.10 3.1 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-02-0 Ni-Dissolved Nickel by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-92-1 Pb-Dissolved Lead by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-36-0 Sb Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se-Dissolved Selenium by ICPMS U 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-31-5 Sn Dissloved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
Sr Dissolved by ICPMS 10 36 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-28-0 Thallium (TI)Dissolved by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-32-6 Ti(Titanium)Dissolved by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/14/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 2

NC MAX I X -. story Section ResuCts/SampCe Comments/QuaC�r D io�is
Sample ID: AC44720
CAS# Analyte Name PQL Result/ Method Anal sis
Qualifier Units Reference Date Validated by
7440-62-2 V Dissolved by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn-Dissolved Zinc by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 2

AC44794 North Carolina L.-3ion of Water Resources Water ScienL-- jection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44794
County: BUNCOMBE Collector: B LAVERTY VisitlD SW6-A1 PO Number# ARO
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/02/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 11_53
Emergency Collect Time: 12_26 Sample Matrix: SURFACEWATER Labworks LoginlD KJIMISON2
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 119118
Report Print Date: 01/09/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
ARO
Alkalinity4.5 1.0 22 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Alkalinity8.3 1.0 1 U mg/L as CaCO3 SM 232OB-1997 11/13/17 ESTAFFORDI
Bicarbonate 1.0 22 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Carbonate 1.0 1 U mg/L as CaCO3 SM 232OB-1997 11/13/17 ESTAFFORDI
pH Alkalinity 6.2 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Sample temperature at receipt by lab 6.0 °C 11/2/17 RBYRD
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

North Carolina Division of Water Resources iriSit lD Tad �DbIUSe DYI��/
Water Sample Collection&Submittal Form SW 6-Al
Central Laboratory(Water Sciences Section) (opttonal) lD Coboratary
Sampe Nuinbei:.
Coedtlon,aescnption:`! Asheville Airport-61 Terminal Drive Fletcher, NC Locatlon Code' 1111 ASHEVILLEAIRPORT
4te Received.
km
County Buncombe Collector Brett Laverty Prrortty Water Matrix. Location Type �
f °TTne Receivers
DWRRegton: DWROfjite ❑River/Stream Lake
Asheville Regional Operations ❑Ambient
cy
(taysedgrrcountyj. :, (orogenna e)I ❑Surface ❑Estuary ❑Canal
Reifen+edBy�`t',�
Riveroasin: . French Broad River r Date 11/l/2017 Q Routine ❑Stormwater
El Compliance El Ground ❑Monitoring Well ❑Water Supply'' State Courier
Notes: SW6-A1 r6e 12:10 PM DejJveryibletho' :i El Hand Delivery
:, ❑COC ❑Waste ❑Effluent ❑Influent ITf ❑Other:
satnp09 Grab TTComposite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ElBlank [:]Trip Blank
°Ntethad. ❑Other: [:]Filter Blank Temperature'("�1.:
Dissolved analysis:Enter"DIS" :
m onAval „
❑Filtered in Field 5ampleDepth.� ❑QA ❑Solution ❑other ,
in check-boxes for parameters
Gallectnr s'Caraments;
NticcobiologynParameters ,`_ ...,. a,� m ,t MBAS(surfactants) mg/L =,,Metals Parameters ', `;- X Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L X Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TD5-Total Dissolved Solids mg/L X Calcium(Ca) mg/L
Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters . L,
Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides
Ot(ter,(? jamers:.;. 4e. X Lead(Pb) µg/L Organophosphorus Pesticides
Wet ChemiAry Parameters � �` pH S.U. X Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L
Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range
Sulfate mg/L "';NtitriibnParainetes:' ,` X Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADM[ C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L X Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg X Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological:
f
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L
LAB COMMENTS:
Field Parameters(oPtic at): 4 WaterTemp(°C): pH'(s u) bisso(ved Oxygen(ppm): • Conductivity(µmhosJcm). Salinity(ppt):
Revision:2/06/2015

North Carolina Division of Water Resources Visit ID: Ta , Lp�? ESL'dR�� -�
Water Sample Collection&Submittal Form SW 6-Ai 6 -- --=- -=-- -
Central Laboratory(Water Sciences Section) (opfianpl) ID' taboratorq.
Sample Number.
pAirport
tacatton De.�crt tion`. Asheville -61 Terminal Drive Fletcher, NC tacatiotr Code � 1111 ASHEVILLEAIRPORT
II Date Recetved:j
County Buncombe Collector Brett Laverty Priarity WoteEMatrix: Location Type ,
g, kt
-
DWR �me Recetved
Regton �ee: LJ ,
Brrsergonrot�n Asheville DWR=O RegionalO Operations ❑Ambient -�--� Lake River/Stream
( t3h (d)&gencyndrrie/ p Surface ❑Estuary ❑Canal '
' Recetved By:
` Riirer8asrn.,i French Broad River �bate 11/1/2017 ❑Routine ❑stormwater f
❑Compliance ❑Ground ❑Monitoring Well ❑Water Supply Ll State Courier
Notes: SW6-Al Time 12:26 PM Deliv�ryMetfibd El Hand Delivery
i ❑COC ❑Waste ❑Effluent El Influent
�a o ❑Other:
Sampling= Q Grab Composite [:]Field Blank -
❑ Chlorinated ❑De-chlorinated in Field ❑❑Other: Emergency El Blank
Blank ❑Blank Trip Blank
Teipperature'('Cj�
Dissolved analysis:Enter"DIS" �onAmval: ,o
El Filtered in Field SompfeDepthr ❑CIA El Solution ❑other:
in check-boxes for parameters
L"Collector 5 Comrrientsi'
Microbiology"Parameters `; MBAS(surfactants) mg/L Metals Parameters DIS Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L DIS Aluminum(AI) µg/L DIS Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L DIS Antimony(Sb) µg/L DIS Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L DIS Arsenic(As) µg/L DIS Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L DIS Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L DIS Beryllium(Be) µg/L DIS Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L DIS Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L DIS Calcium(Ca) mg/L.
Coliform:Tube Total /100ml Silica mg/L DIS Chromium(Cr),Total µg/L Organics Parameters:,
Specific Conductance,at 25°C umhos/cm Sulfide mg/L DIS Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L DIS Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU DIS Iron(Fe) µg/L Organonitrogen Pesticides
o.c '�therPatameters:,: .9 9 ,, �� +�a js DIS Lead(Pb) µg/L Organophosphorus Pesticides
Wet Chemistry Parameters: pH S.U. DIS Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L DIS Magnesium(Mg) mg/L.
X Chloride mg/L DIS Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L DIS Mercury(Hg) µg/L TPH Diesel Range
X Sulfate mg/L } Nutriehts�e ir'ameters _ : � ,%g DIS Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L DIS Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L DIS Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L DIS Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L DIS Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L DIS Sodium(Na) mg/L. .Biological. a_,
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L DIS Strontium(Sr) µg/L Phytoplankton/Algae m .
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L DIS Thallium(TI) µg/L
LAB COMMENTS:
,Field PBrameters(aFhonall: °.;Water Temp.(°C}::tii ;P6:(s u} ';,, °Dissolved Oxygen(ppm}.`; Cor+ductivity(µmhos/crp):•^ m SaiinitY{ppt):"°
Revision:2/06/2015

North Carolina Division of Water Resources lsirtlll PI
Q�?(/SEQ (}f w
Water Sample Collection&Submittal Form SW6-Al 6 - ------
Asheville Laboratory(Water Sciences Section) (irfiand!) Laborattory
nI „i, a 1' i Smnple Number;
Cacativi Ve, c itfan, Asheville Airport-61 Terminal Drive Fletcher, NC Laication.Cod�: 1111ASHEVILLEAIRPORT
Rgi+°tiecefved ,
lr a 5��. x it r N Imp ,s a fi> `: dri
County- Buncombe Collector Brett Laverty PrFority WoterrMairnc LacatlonType `
fNRltegion' ;f?lWl#(yCj1C� River/Stream LakemerRefved
Asheville Regional Operations River/Stream
jbos�}fp4ourr�y/ (orbgec}�na�e) ❑Surface ❑Estuary ❑Canalti'
�teceied Bye,
RiverBasm. "° French Broad River Dote 11/1/2017 ❑� Routine ❑Stormwater
7rr .`, • ro � State Courier
❑Compliance El Ground ❑Monitoring Well ❑Water Supply '
Notes: SW6-Al Time 12:26 PM De%veryfHetfrod El Hand Delivery
rt ❑COC El Waste ❑Effluent ❑Influent i` �•a ; ❑Other:
Sampffng 0 Grab Composite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field 1� .g ❑Emergency ❑Blank ❑Trip Blank
Mtbd,� t' ❑Other: ❑Filter Blank Teir)p"erasure(;CJ•
Dissolved analysis:Enter"DIS" oni4af
❑Filtered in Field in check-boxes for parameters Sarfrp# DeptJi? ❑QA ❑Solution ❑Other: ., :
�CvltectoY*F�Corf�ir�eats� ;�
—Micr
u Acidityolo,, CaCO3a o p 4.5/8.3 m /4
gY� P
X Alkalinity,as CaCC3,to H 4.5 8.3 m L Parameters::'.,,,'.P / g/
Solids Par
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L � - - ,
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L
0.
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L
Coliform:Tube Total /100ml
Specific Conductance,at 25°C umhos/cm
Turbidity NTU ,
Other Parameters:
pH S.U.
to
°
,
t
ya s
LAB COMMENTS:
¢,, .g_ � a° �..
Plelcl PaetersopUonol}: "WaterTctnp lyiasotved O�rygen(ppm}.�3 Cuncucllitity(µmhosJcm): � Sa inity{ppt).c a�,
Revision:2/06/2015

AC44708 North Carolina D,._-ion of Water Resources Water Science_ -ction Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44708
County: BUNCOMBE Collector: B LAVERTY VisitlD SW5-A1 PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 12_42 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 12/15/17
Report Print Date: 01/04/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Units Method Analysis
CAS# Analyte Name PQL Qualifier Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.6 °C 11/3/17 ESTAFFORDI
MET
7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 Al by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-38-3 Ba by ICP 10 46 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be by ICP 5.0 6.0 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-70-2 Ca by ICP 0.10- 26 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-47-3 Cr by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-89-6 Fe by ICP 50 2400 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 Rev3 1117/17 ESTAFFORDI
7440-09-7 K by ICP 0.10 3.5 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-93-2 Li ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-95-4 Mg by ICP 0.10 8.7 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-96-5 Mn by ICP 10 1100 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na by ICP 0.10 4.8 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7782-49-2 Se by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-31-5 Sri by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-24-6 Sr by ICPMS 10 310 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-28-0 Thallium (TI)ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-32-6 Ti(Titanium)by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/14/17 ESTAFFORDI
7440-62-2 V by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

AC44709 North Carolina D:_ __!on of Water Resources Water Science'_ _ action Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44709
County: BUNCOMBE Collector: B LAVERTY VisitlD SW5-Al PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 13_01 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 12/15/17
Report Print Date: 01/04/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Units Method Analysis
CAS# Analyte Name PQL Qualifier Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.6 °C 11/3/17 ESTAFFORDI
WET
Bromide 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Chloride 1.0 12 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Fluoride 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Sulfate 2.0 10 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
MET
7440-22-4 Ag-Dissolved Silver by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 Al-Dissolved Aluminum by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-38-2 As-Dissolved by ICPMS Arsenic 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 B Dissolved by ICP 50 180 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-38-3 Ba-Dissolved Barium by ICP 10 45 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be-Beryllium Dissolved by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-70-2 Ca-Dissolved Calcium by ICP 0.10 26 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd-Dissolved Cadmium by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-48-4 Cobalt Dissolved by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-47-3 Cr-Dissolved Chromium by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu-Dissolved Copper by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-89-6 Fe-Dissolved Iron by ICP 50 1900 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-97-6 Hg 245.1 Dissolved 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORD1
7440-09-7 K-Dissolved Potassium by ICP 0.10 3.4 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-93-2 U DISSOLVED ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-95-4 Mg-Dissolved Magnesium by ICP 0.10 8.7 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-96-5 Mn Dissolved by ICP 10 1100 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-98-7 Mo Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na-Dissolved Sodium by ICP 0.10 4.7 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-02-0 Ni-Dissolved Nickel by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-92-1 Pb-Dissolved Lead by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-36-0 Sb Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se-Dissolved Selenium by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-31-5 Sn Dissloved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
Sr Dissolved by ICPMS 10 300 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-28-0 Thallium(TI)Dissolved by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-32-6 Ti(Titanium)Dissolved by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/14/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 2

.NC rD`A, ratory Sectioit 1§sults/Samp[e Comments/Quariji�r D ons
Sample ID: AC44709
CAS# Ana]yte Name PQL Result/ Method Analysis
Qualifier Units Reference Date Validated by
7440-62-2 V Dissolved by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn-Dissolved Zinc by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 2

AC44795 North Carolina E__ _ion of Water Resources Water Scienc ection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44795
County: BUNCOMBE Collector: B LAVERTY Visit]D SW5-A1 PO Number# ARO
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/02/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 11_53
Emergency Collect Time: 13_01 Sample Matrix: SURFACEWATER Labworks LoginlD KJIMISON2
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 1/9/18
Report Print Date: 01/09/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
ARO
Alkalinity4.5 1.0 81 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Alkalinity8.3 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Bicarbonate 1.0 81 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Carbonate 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
pH Alkalinity 7.1 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Sample temperature at receipt by lab 6.0 °C 11/2/17 RBYRD
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

North Carolina Division of Water Resources
Water Sample Collection&Submittal Forma� . 1 SW5-Al 7 �� r.wWwa .��
Central Laboratory(Water Sciences Section) P � o nrrl ID: ��Lgr#io7a' 4
VAN, irldpPI"'M �- .SAn7 4x tlln�?Q y`
occttrvn�bexwrr�ptron Asheville Airport-61 Terminal Drive Fletcher, NC +cifiatCbde 1111ASHEVILLEAIRPORT
n�
rsr t �3'.w' r ar �'r�d" fE^ es?.7k" S Rr�
sYr' , . 11 a
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i 4u .�r, 'r ta? ,`. r t -�—iC"r; ,i r# 's -_ iI '`3 -
�&ofrnt Buncombe Cttt(etGt Brett Laverty � Pr>rorr#�r�«u rater;Matrt ., ncaeiorr�pp ��°��� �
rt`'" -z"ez,�a�Kr=sib z L�` --r�. 9,� '�' r"•� E�{iE'C�iNE�16
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Asheville L�IRiver/Stream Lake T t '
Regional Operations ❑Ambient
4 rX9 d /t�Qtl n UMC J —�' -j g rxty} TQg clR ) Surface ❑Estuary ❑Canal
�f �@ 11/1/2017 ❑� Routine
li 1V T T ra
R1 ei~Basin French Broad River ❑Stormwater
.State Courier
L � El Compliance ❑Ground Monitoring Well ❑Water Supply & 3 _
Notes: SW5-A1efrveryiVtpthcd ❑Hand Delivery
trr 12:42 PMSt
�
T` ❑ ❑Waste ❑Effluent ❑Influent �i��w�r , ;� ,a ❑Other:
< COC
Chlorinated ❑De-chlorinated in Field 5amptln Grab Composite ❑Field Blank 4 ' CIA
❑ , ❑Emergency ❑Blank. ❑Trip Blank ,
❑Other: ❑Filter Blank �n+Pn �
Dissolved analysis:Enter"DIS" I�4 ,; �,9k [t3pottr 6 "
❑Filtered in Field �Sgfrpl 4C iT lii El CIA ❑Solution ❑Other:
s
in check-boxes for parameters
L�o�"tecCo�s'"`�imrtents;`
Mrcrobrolo ParalNteterS, w tx� ;9; MBAS surfactants m L 'I _;NyetalsPfi ►1IEtEC$ '� ., X Tin Sn L
.. _ "ram .
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L X Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100mi TDS-Total Dissolved Solids mg/L X Calcium(Ca) mg/L
Coliform:Tube Total /100m[ Silica mg/L X Chromium(Cr),Total µg/L g�t}Tgaglas Qalaih3 teCS e�
Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides
T Otfttt?adtilet5 : ' ?` rJ i I'; X Lead(Pb) µg/L Organophosphorus Pesticides
1Ylletltemp5try4P�TamtiCs, ; ,_ pH S.U. X Lithium Li( ) µg/L PCBs(polychlorinated biphenyls)
4aBromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L
Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range
Sulfate mg/L ,in4uErierwt5 PaCamet " c F iva ,," X Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L X Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L ImOrthophosphate as P(PO4) mg/L X Thallium(TI) µg/L
LAB COMMENTS:
"`, ! `64:!, a-. ^.:R
Fie(d Patan9ete! aptfanalJ 1raterTQmp(° ) _ pH(s u} bissalved Oicjrgen4pP : Candvrftvit)!(ltm6os/crn} iu6? Salit7i` i t
&
Revision:2/06/2015 _ � z

North Carolina Division of Water Resources 'YisitlD: T°a 1 Ldb B!s"e•Dithl
Water Sample Collection&Submittal Form SW 5-Al 8 _ Y ------ --- ----
Central Laboratory(Water Sciences Section) (optional) 1D Laboratory
SaMple 14tsrrnber,
Descri tf.a. Asheville Airport-61 Terminal Drive Fletcher, NC Location Code: 1111 ASHEVILLEAIRPORT
Location
P P
7 � �_
Date,Received.*
County: Buncombe Collector Brett Laverty Priority. Water Matrix. LoeatlonType'
QMVRRegi6h.- -,i 7DM gOffice QRiver/Stream Lakee � eReceived
Asheville Regional Operations ❑Ambient
(bused on county) (or agencynamei ❑Surface ❑Estuary ❑Canal
`Received By:
i ❑� Routine ❑Stormwater
f6ver8drsinc ° °� French Broad River Date 11/1/2017
El Compliance ❑Ground Monitoring Well ❑Water Supply State Courier
Notes: SW5-Ai ir`itte 1:01 PM Delivery Method: ❑Hand Delivery
ElCOC El waste ❑Effluent ❑Influent ❑Other:
Sampiing ❑Grab Composite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank
Method ❑Other: ❑Filter Blank Temperature(
Dissolved analysis:Enter"DIS" on Arrival:
❑Filtered in Field Sample Depth ❑ctA El Solution ❑other.
in check-boxes for parameters
Cotlectar"s.Gonernettts:
Microbiology Parameters: MBAS(surfactants) mg/L Metals Parameters: DIS Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L DIS Aluminum(Al) µg/L DIS Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L DIS Antimony(Sb) µg/L DIS Vanadium(V) µg/L
Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L DIS Arsenic(As) µg/L DIS Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L DIS Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L DIS Beryllium(Be) µg/L DIS Boron(B),Total µg/L
Coliform:Total MF. /100ml Residue:Volatile/Fixed,Suspended mg/L DIS Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /looml TDS-Total Dissolved Solids mg/L DIS Calcium(Ca) mg/L
Coliform:Tube Total /100ml Silica mg/L DIS Chromium(Cr),Total µg/L Organics Parameters:
w,mti
Specific Conductance,at 25°C umhos/cm Sulfide mg/L DIS Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L DIS Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU DIS Iron(Fe) µg/L Organonitrogen Pesticides
Other`Parameters: " DIS Lead(Pb) µg/L Organophosphorus Pesticides
UyetChemistryiPgrameters pH S.U. DIS Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
rX
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L DIS Magnesium(Mg) mg/L
Chloride mg/L DIS Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L DIS Mercury(Hg) µg/L TPH Diesel Range
Sulfate mg/L Nutrients:Parameters: DIS Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L DIS Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI c.u. Nitrate-Nitrite as N(NO3+NO2-N) mg/L DIS Potassium(K) mg/L.
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L DIS Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical oxygen Demand mg/L Total Phosphorus as P(TP) mg/L DIS Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L DIS Sodium(Na) mg/L Biological:
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L DIS Strontium(Sr) µg/L Phytoplankton./Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L DIS Thallium(TI) jig/I.
LAB COMMENTS:
Field Parameters(opHonalJ. .i Water Temp(°C}:;1 pN(s u)e a 'Dissolved O�rygen(ppm): °°Conductivity(µmhos(cm)i Salinity(ppt)
Revision:2/06/2015

North Carolina Division of Water Resources Visit ID SW 5-Al Ta 13 lo/1 USE'.Q/i1 „
Water Sample Collection&Submittal Form - ---- -=-----
Asheville Laboratory(Water Sciences Section)
catron,Descuptran Asheville Airport-61 Terminal Drive Fletcher, NC location Code 1111ASHEVILLEAIRPORT
11 oote'Fteceiued{
si 4 4 a r+e
Cal�hty. Buncombe Collector Brett Laverty Prrarity .°' Woto"Motrhr. LocatPori Type -t
99 _ rMeRecelved�'
c River/Stream a Lake 't "
Asheville ; °e`� Regional Operations ❑Ambient
(based ohcountyj. (ortrge» home) ❑Surface ❑Estuary ❑Canal
o ❑✓ Routine ❑Stormwater Receivedl3y
Rive asih: French Broad River Die 11/1/2017
State Courier
El Compliance ❑Ground Monitoring Well ❑Water Supply
Notes: SW5-Ai r€rne: 1:01 PM De(frreryMethgd:� El Hand Delivery
y ❑COC ❑Waste El Effluent ❑Influent J. ❑Other:
SaMP ng ❑✓ Grab LIComposite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank [:]Trip Blank
Method, ❑Other: ❑Filter Blank Temperature(C)�
Dissolved analysis:Enter"DIS" oi(-A
❑ lnrival
Filtered in Field 500eflept4: ❑CtA ❑Solution ❑Other:
in check-boxes for parameters „
°*Coitego"`sComritents:fl,:
Microbiology Parameters:
Acidity,as CaCO3,to pH 4.5/8.3 mg/L
X Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L ::Solids PetameterS:,, ,,
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L
Coliform:Tube Total /100ml
,rt
Specific Conductance,at 25°C umhos/cm
Turbidity NTU
Other Parameters:`-
pH S.U.
�.x a` � :
x+
y
LAB COMMENTS:
a
fielmeters(o�pflnnol/• 'VilterYemp`(°C� Disso ved t5xyghn{Pp
d P�ra Y{PP j:
Cohdu`ctivi mhos cm Salinl t
Revision:2/06/2015

AC44710 North Carolina D_.-_ion of Water Resources Water Science__ _ection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44710
County: BUNCOMBE Collector: B LAVERTY VisitlD SW8-Al PO Number#
Region: ARID Report To ARID Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 13_26 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 12/16/17
Report Print Date: 01/04/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.6 °C 11/3/17 ESTAFFORDI
MET
7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 Al by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-38-2 As by ICPMS 2.0 210 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-38-3 Ba by ICP 10 230 ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
744041-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca by ICP 0.10 150 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
744048-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
744047-3 Cr by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFF0RD1
7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-89-6 Fe by ICP 50 23000 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFF0RD1
7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORDI
7440-09-7 K by ICP 0.10 4.4 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-93-2 Li ICP 25 39 ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-95-4 Mg by ICP 0.10 33 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-96-5 Mn by ICP 10 10000 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-98-7 Mo by ICPMS 10 170 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na by ICP 0.10 7.4 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-02-0 Ni by furnace 2.0 2.0 U ug/L EPA 200.9 Rev2.2 11/22/17 ESTAFF0RD1
7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-31-5 Sri by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 .11/27/17 ESTAFFORD1
7440-24-6 Sr by ICPMS 10 2200 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFF0RD1
7440-28-0 Thallium(TI)ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-32-6 Ti(Titanium)by ICP 10 10 U ug/L EPA200.7 Rev4.4. 11/14/17 ESTAFFORDI
7440-62-2 V by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFF0RD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

AC44711 r North Carolina D. ion of Water Resources Water Scienct -ction Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44711
County: BUNCOMBE Collector: B LAVERTY VisitlD SW8-Al PO Number#
Region: ARID Report To ARID Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 13_48 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier.
Final Report Date: 12/15/17
Report Print Date: 0 110 4/2 0 1 8
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Units Method Analysis
CAS# Analyte Name PQL Qualifier Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.6 °C 11/3/17 ESTAFFORDI
WET
Bromide 0.4 0.68 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Chloride 1.0 4.1 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Fluoride 0.4 0.46 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Sulfate 2.0 34 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
MET
7440-22-4 Ag-Dissolved Silver by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 Al-Dissolved Aluminum by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-38-2 As-Dissolved by ICPMS Arsenic 2.0 200 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 B Dissolved by ICP 50 1400 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-38-3 Ba-Dissolved Barium by ICP 10 230 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-41-7 Be-Beryllium Dissolved by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca-Dissolved Calcium by ICP 0.10 150 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd-Dissolved Cadmium by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-48-4 Cobalt Dissolved by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-47-3 Cr-Dissolved Chromium by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-50-8 Cu-Dissolved Copper by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-89-6 Fe-Dissolved Iron by ICP 50 23000 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-97-6 Hg 245.1 Dissolved 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORD1
7440-09-7 K-Dissolved Potassium by ICP 0.10 4.4 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-93-2 Li DISSOLVED ICP 25 38 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-95-4 Mg-Dissolved Magnesium by ICP 0.10 33 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-96-5 Mn Dissolved by ICP 10 10000 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-98-7 Mo Dissolved by ICPMS 10 160 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na-Dissolved Sodium by ICP 0.10 7.4 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-02-0 Ni Dissolved by furnace 2.0 2.0 U ug/L EPA200.9 Rev2.2 11/22/17 ESTAFFORD1
7439-92-1 Pb-Dissolved Lead by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-36-0 Sb Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7782-49-2 Se Dissolved by furnace 1.0 1.0 U ug/L EPA 200.9 Rev2.2 11/22/17 ESTAFFORDI
7440-31-5 Sn Dissloved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
Sr Dissolved by ICPMS 10 2100 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-28-0 Thallium(TI)Dissolved by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-32-6 Ti(Titanium)Dissolved by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/14/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 2

NC IDMX story Section l§sufts/Satnpre Comments/Quafifwr Do oils
Sample ID: AC44711
CAS# Analyte Name PQL Result/ Method Analysis
Qualifier Units Reference Date Validated by
7440-62-2 V Dissolved by ICP 10 IOU ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-66-6 Zn-Dissolved Zinc by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 2

AC44796 North Carolina L _._sion of Water Resources Water Scien Section Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44796
County: BUNCOMBE Collector: B LAVERTY VisitlD SW8-A1 PO Number# ARO
Region: ARID Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/02/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 11_53
Emergency Collect Time: 13_48 Sample Matrix: SURFACEWATER Labworks LoginlD KJIMISON2
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 119/18
Report Print Date: 0110912018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
ARO
Alkalinity4.5 1.0 490 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Alkalinity8.3 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Bicarbonate 1.0 490 mg/L as CaCO3 SM 2320B-1997 11/13/17 - ESTAFFORD1
Carbonate 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
pH Alkalinity 7.4 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Sample temperature at receipt by lab 6.0 °C 11/2/17 RBYRD
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

North Carolina Division of Water Resources � Is<tIll.R", Tad ; L!>'>{1 USe ?11��/,
Water Sample Collection&Submittal Form 4 SW8-A1
Central Laboratory(Water Sciences Section) (optional)` l 110 9 :Lahorataiy
Sample Number:
Locatron Descry tlon% Asheville Airport-61 Terminal Drive Fletcher, NC tocatron Code: 1111ASHEVILLEAIRPORT
E 11� Dote Recetpetl
County Buncombe rroLLllector."" Brett Laverty Prforrty; WaterMatrrXr LocattonType $ `
i TimeReeeived .
DWR�Regron " DWR ice ❑✓ River/Stream Lake
Asheville Regional Operations ❑Ambient
(based-oncougtyi (9rogencynamel ❑Surface ❑Estuary ❑Canal r , 51
. '.Recetrred 8y ° '
,I?/r asln""�. " French Broad River Date 11/1/2017 El
Routine ❑stormwater
Ll
111 El Compliance El Ground ❑Monitoring Well ❑Water Supply State Courier
Delivery Method; ❑Hand Delivery
Noies: SW8-A1 77txle 1:25 PM
El Waste El Effluent ❑Other:El CoC
Svmplirtg❑ Chlorinated ❑ Grab Composite De-chlorinated in Field ❑ [:]Field Blank Emergency ❑Blank ❑Trip Blank '
Method IE10ther:
❑Filter Blank Temperafare{"C)
Dissolved analy�s:Enter"DIS"
El ❑
$ onArrtgal:� a
Filtered in Field in check-boxes for ammeters SampteDepth QA El Solution ❑Other:
Collectors comments.,
Ml obrology ar met rs ar,.,,;; e,ny F,,, MBAS(surfactants) mg/L ,„� 'MotalSylPa ameLeCS .4 T,� � �`� X Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L X Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X. Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L
Coliform:Total MF /looml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L X Calcium(Ca) mg/L
Coliform:Tube Total /100m1 Silica mg/L X Chromium(Cr),Total µg/L �Orgariics, aiarrietersr
Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides
;`OttierParameters:;� r ,=M v �� , .11, ase X Lead(Pb) µg/L Organophosphorus Pesticides
s=-WetthemistyParamefers �' � era: pH S.U. X Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L
Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range
Sulfate mg/L "l lN_ ytrients'Rar X Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L X Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological:'
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L
LAB COMMENTS:
Field'Parameter`s(optona): rVdaterTemp(°C);` p (s u J;� Dissolved Oxygen'(ppm) wf, Conductivity(µmhos/cm) , .� Salinity(ppt):."
�f
Revision:2/06/2015

North Carolina Division of Water Resources visit ID: Tag' Lab Use Qnly-
Water Sample Collection&Submittal Form SW 8-Al 10 --=- -----
Central Laboratory(Water Sciences Section) (opClvtta!) ,; IDo Loliomtory �
Sampie`Number
Location Descriptian:1 Asheville Airport-61 Terminal Drive Fletcher, NC Location Code 1111ASHEVILLEAIRPORT
DateRecerved ;
County ' ;, Buncombe Collectoi;° Brett Laverty Pitority -�ti-` WaterMatrix:: LocritronType
DWRJ;egron DWRi,f? ee„,; ❑✓ River/Stream Lake 7;meRecetved b
Asheville Regional Operations ❑Ambient
(6oaedoncountyJ° `. (or ayettcy`hbmctf° ❑Surface ❑Estuary ❑Canal eecetvedBycf+,
RrverBosln French Broad River 'Date 11/1/2017 ❑� Routine ❑stormwater
i is a• State Courier
❑Com Compliance p ❑Ground ❑Monitoring Well ❑Water Supply
Notes: SW8-Ai rime 1:48 PM ❑CDC DelrveryMethod; ❑Hand Delivery
❑Waste ❑Effluent ❑Influent ❑Other:
SvmpGng' ❑✓ Grab Composite ❑Field Blank �` '
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency Blank El Blank
Method• ❑Other: ❑Filter Blank Temperature(`CJ
Dissolved analysis:Enter"DIS" onAndval
❑Filtered in Field �SampfeDepth ❑QA Solution ❑Other:
in check-boxes for parameters
Collectors comlgentsr
Mrceobiolo 'Parameters �_„x' '`a,=F'MetaiN{ arameters`• DIS Tin Sn L
gy Q _ MBAS(surfactants) mg/L „_• u, ( ) µg/
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L DIS Aluminum(AI) µg/L DIS Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L DIS Antimony(Sb) µg/L DIS Vanadium(V) µg/L
BOD:Biochemical oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L DIS Arsenic(As) µg/L DIS Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L DIS Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L DIS Beryllium(Be) µg/L DIS Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L DIS Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L DIS Calcium(Ca) mg/L
Coliform:Tube Total /100ml Silica mg/L DIS Chromium(Cr),Total µg/L iOrgariics Parameters.r
Specific Conductance,at 25°C umhos/cm Sulfide mg/L DIS Cobalt(Co) µg/L Acid Herbicides
TOC-TotalOrganicCarbon mg/L Tannin&Lignin mg/L DIS Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU DIS Iron(Fe) µg/L Organonitrogen Pesticides
Qttier ftrarneters DIS Lead(Pb) µg/L Organophosphorus Pesticides
Wet iChemistry`Parameters:' pH S.U. DIS Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L DIS Magnesium(Mg) mg/L
X Chloride mg/L DIS Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L DIS Mercury(Hg) µg/L TPH Diesel Range
X Sulfate mg/L Nu;r'rents,? rameters�s DIS Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L DIS Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADM C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L DIS Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L DIS Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L DIS Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L DIS Sodium(Na) mg/L Biological:
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L DIS Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(1304) mg/L DIS Thallium(TI) µg/L
LAB COMMENTS:
„� S.J' as ixj vo i
Field Parameters(optlanot/ '";WaEerTemp(°C).'` pN"fs u•)• t Dissolved Oicygen{ppm) "° Conductivit}r(µmhosJcm)' Salui
Revision:2/06/2015

North Carolina Division of Water Resources Vis[t:1D Ta Lctb Use 001Y.'
Water Sample Collection&Submittal Form SW8-Ai ___
10 _
Asheville Laboratory(Water Sciences Section) fQt ona11,,,' ID � La6orator±
Samdj&Nuinbei
cat►on Descnptron Asheville Airport-61 Terminal Drive Fletcher, NC Location Cade 1111 ASHEVILLEAIRPORT
�> RatReceti%ed+,
CO my Buncombe Co[%c[or Brett Laverty Priority: °� Wow—atrtic tocorzron Tyde
rme Recefved•,
Q,Wleglon ,�, f�Wt; ?J}ic�,.1 River/Stream lake '
Asheville Regional Operations ❑Ambient
(bvseifvncnuaryj"• �� joi vgec}trtorrie} ❑Surface ❑Estuary ❑Canal
Recerved' '
FHver Basin �; .r French Broad River flae 11/1/2017 El Routine ❑Stormwater =
❑ �' ,r� State(,iourler Compliance El El ❑Water Supply Deiiverjr.Method: ❑Hand Delivery
Notes: SW8-Al Tme 1:48 PM
❑COC ❑Waste ❑Effluent ❑Influent o ❑Other:
f' Sarhpiing '' ❑✓ Grab Composite [:]Field Blank
❑ Chlorinated ❑De-chlorinated in Field � .„ Emergency Blank ❑Trip Blank
Methad !g ❑Other: ❑Filter Blank Tempe;aWre("C)
Dissolved analysis:Enter"DIS" ohArrivai _P
❑Filtered in Field y Sarriptr�fkptfi ❑0A ❑Solution ❑other:
in-check-boxes for parameters y
a Coiiector`s Comments
dam, w. 6
Microbiology Parameters:.. x
Acidity,as CaCO3,to pH 4.5/8.3 mg/L
X Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L' Solids Parameters:
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L
Coliform:Tube Total /100ml ¢ _
Specific Conductance,at 25°C umhos/cm
Turbidity NTU
Other Pa"ra'rrieters',
pH S.U.
..G
t
LAB COMMENTS:
field Pa'xameters(opt�onail f�tdaterTenip(°C)�: pH Dissolved t7Xygen IPpYn}, Conductivity(µrnhosJcm): , 5ainity(pptj
Revision:2/06/2015

AC44712 , North Carolina D__ ion of Water Resources Water Science -ction Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44712
County: BUNCOMBE Collector: B LAVERTY VisitlD SW7-A1 PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 14_19 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 12/16/17
Report Print Date: 01/04/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Units Method Analysis
CAS# Analyte Name PQL Qualifier Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.6 °C 11/3/17 ESTAFFORDI
WET
Bromide 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Chloride 1.0 1.9 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Fluoride 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Sulfate - 2.0 12 mg/L EPA 300.0 rev2.1 11/8117 CGREEN
MET
7440-22-4 Ag-Dissolved Silver by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7429-90-5 Al-Dissolved Aluminum by ICP 50 50 U ug/L EPA 200.7 Rev4A 11/21/17 ESTAFFORDI
7440-38-2 As-Dissolved by ICPMS Arsenic 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 B Dissolved by ICP 50 340 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-38-3 Ba-Dissolved Barium by ICP 10 50 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-41-7 Be-Beryllium Dissolved by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca-Dissolved Calcium by ICP 0.10 8.3 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd-Dissolved Cadmium by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-48-4 Cobalt Dissolved by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-47-3 Cr-Dissolved Chromium by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5A 11/27/17 ESTAFFORD1
7440-50-8 Cu-Dissolved Copper by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7439-89-6 Fe-Dissolved Iron by ICP 50 50 U ug/L EPA 200.7 Rev4A 11/21/17 ESTAFFORDI
7439-97-6 Hg 245.1 Dissolved 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORDI
7440-09-7 K-Dissolved Potassium by ICP 0.10 13 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-93-2 Li DISSOLVED ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-95-4 Mg-Dissolved Magnesium by ICP 0.10 20 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-96-5 Mn Dissolved by ICP 10 1100 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-98-7 Mo Dissolved by ICPMS 10 14 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na-Dissolved Sodium by ICP 0.10 3.6 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7440-02-0 Ni Dissolved by furnace 2.0 2.0 U ug/L EPA 200.9 Rev2.2 11/22/17 ESTAFFORDI
7439-92-1 Pb-Dissolved Lead by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-36-0 Sb Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se Dissolved by furnace 1.0 1.0 U ug/L EPA200.9 Rev2.2 11/22/17 ESTAFFORDI
7440-31-5 Sri Dissloved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
Sr Dissolved by ICPMS 10 1100 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-28-0 Thallium (TI)Dissolved by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-32-6 Ti(Titanium)Dissolved by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/28/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 2

NC ID`A, atory Section Resufts/Satnpre Comments/QuaCfrerQ Otis t
Sample ID: AC44712
CAS# Analyte Name PQL Result/ Method Analysis
Qualifier Units Reference Date Validated by
7440-62-2 V Dissolved by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn-Dissolved Zinc by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 2

A-44797 v. North Carolina L_ sion of Water Resources Water Seim-_ _section Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT 61 TERMINAL DRIVE FLETCHER,NC - Sample ID: AC44797
County: BUNCOMBE Collector: B LAVERTY VisitlD SW7-A1 PO Number# ARO
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/02/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 11_53
Emergency Collect Time: 14_19 Sample Matrix: SURFACEWATER Labworks LoginlD KJIMISON2
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 119/18
Report Print Date: 01/0 912 0 1 8
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
ARO
Alkalinity4.5 1.0 290 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Alkalinity8.3 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Bicarbonate 1.0 290 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Carbonate 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
pH Alkalinity 7.7 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Sample temperature at receipt by lab 6.0 °C 11/2/17 RBYRD
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

North Carolina Division of Water Resources `YisitLD,. lab U$A Drily
Central Laboratory(Water Sciences Section) Water Sample Collection&Submittal]Form (tipianat) ;, SW 7-Al ID; 11 --- - -- -�-
Laboratory
Sample Number•.'
location Description Asheville Airport-61 Terminal Drive Fletcher, NC Location Code: 1111ASHEVILLEAIRPORT
•Date Reteivea:
County Buncombe Collecto`rc" Brett Laverty Prrorriy: Water`_Matrix. L-atronType
DWR;Regron' DVVRrOffee: QRiver/Stream ❑Lake Time Received:
Asheville Regional Operations ❑Ambient
1(based oncau{�t9Js a, (oragepsynamef ❑Surface ❑Estuary []Canal
r Retetved Byc `:
y El Routine ❑Stormwater �� ;
River eosin: French Broad River Dote: I 11/1/2017
El Compliance El Ground ❑Monitoring Well ❑Water Supply State Courier
Notes: SW7-Al aims 2:19 PM Delivery Method: ❑Hand Delivery
b ❑COC ❑Waste ❑Effluent ❑Influent ❑Other:
sampling ❑✓ Grab LIComposite ❑Field Blank "
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank [—]Trip Blank
Method:. Other: ❑Filter Blank Temperature('C}
Dissolved analysis:Enter"DIS" r anArrivat
❑Filtered in Field in check-boxes for parameters Samp�eDepth: ❑GA Solution other:
Colle'ctor's Comments: B
�6Microbiologys`Paramefe ;�. ¢� a ,, n` MBAS(surfactants) mg/L Meta)s Parametois,, . a ,A„ DIS Tin(Sn) µg/L
Acidity,as CaCO3,to'pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L DIS Aluminum(AI) µg/L DIS Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L DIS Antimony(Sb) µg/L DIS Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L DIS Arsenic(As) µg/L DIS Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L DIS Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L DIS Beryllium(Be) µg/L DIS Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L DIS Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L DIS Calcium(Ca) mg/L
Coliform:Tube Total /100ml Silica mg/L DIS Chromium(Cr),Total µg/L ;'off,° Organics Par�rrieters:a�.er,� "t r"
Specific Conductance,at 25°C umhos/cm Sulfide mg/L DIS Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L DIS Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU DIS Iron(Fe) µg/L Organonitrogen Pesticides
4therParaineters;.: ',g DIS Lead(Pb) µg/L Organophosphorus Pesticides
Wet.Chemistry"Parameters, '' pH S.U. DIS Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L DIS Magnesium(Mg) mg/L
X Chloride mg/L DIS Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L DIS Mercury(Hg) µg/L TPH Diesel Range
X Sulfate mg/L 'NuttientsParameters ;gig . `. DIS Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L DIS Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L DIS Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L DIS Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L DIS Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L DIS Sodium(Na) mg/L " Biological:`-
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L DIS Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L DIS Thallium(TI) µg/L
LAB COMMENTS:
Parameters(aptional/: WaterITemp(°C): PN'(s•u.)4 Dissolved Oxygen Conductivity, Salinity(ppt):
Revision:2/06/2015

North Carolina Division of Water Resources Vi it ID: Ta Ldb USE:on/y
Water Sample Collection&Submittal Form ]SW 7-Al 11 ----- - -------- -------
Asheville Laboratory(Water Sciences Section) (optional) 1D I Laboratory
Soerple Number
Locat�o ,Descrrpton: Asheville Airport-61 Terminal Drive Fletcher, NC iocatron Code 1111 ASHEVILLEAIRPORT n -
�/i;4Ce�'VpL� liR
�,Gounty Buncombe Coflectar Brett Laverty Pr"rorrty m WatecMatrix LocatioisTypex
R
DWR Regran DWR(3fflce: River/Stream Lake lime Received l
Asheville Regional Operations ❑Ambient
(bvsed,onmuntyJ name) ❑Surface ❑Estuary ❑Canal
Received By
R+uetRasin French Broad River pa#e 11/1/2017 ❑Routine ❑stormwater ,
❑Compliance ❑Ground ❑Monitoring Well ❑Water Supply
State Courier
Notes: SW7-Allme 2:19 PM DelweryMethoi3 ❑Hand Delivery
❑COC ❑Waste [I Effluent ❑Influent ❑Other:
Sampling ❑� Grab Composite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank
Mtrgd .! ❑Other: ❑Filter Blank Temeroture("C)fi
Dissolved analysis:Enter"DIS"
El Filtered ❑ ❑ onArzit�af�,�°
Filtered in Field San�pC�Depth; QA Solution other: ,
in check-boxes for parameters ,dXr
Collector Comments:,
Microbiology Parameters:
Acidity,as CaCO3,to pH 4.5/8.3 mg/L
X Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Solids Parameters:.
Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L -
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L
Coliform:Tube Total /100m1
Specific Conductance,at 25°C umhos/cm
Turbidity NTU
.Other Parameters:.
pH S.U.
LAB COMMENTS:
Field Parameiers(opUoncf) Water Temp{C). P (s u) " DissoivedbO ygen,(ppm): ConductlVity(µmhos/cm).. .a Salinity(ppt) {
Revision:2/06/2015

AN4713 }" North Carolina 1, sion of Water Resources Water Rim __. >ection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44713
County: BUNCOMBE Collector: B LAVERTY VisitlD SW4-A1 PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_:20
Emergency Collect Time: 14_40 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 1/9/18
Report Print Date: 01/09/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.6 °C 11/3/17 ESTAFFORD1
MET
7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 Al by ICP 50 300 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-38-3 Ba by ICP 10 19 ug/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-41-7 Be by ICP - 5.0 6.0 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca by ICP 0.10 7.9 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-47-3 Cr by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-89-6 Fe by ICP 50 2600 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORDI
7440-09-7 K by ICP 0.10 1.5 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-93-2 Li ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORD1
7439-95-4 Mg by ICP 0.10 4.1 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-96-5 Mn by ICP 10 470 ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 1.1/27/17 ESTAFFORDI
7440-23-5 Na by ICP 0.10 3.5 mg/L EPA200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORD1
7782-49-2 Se by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-31-5 Sn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-24-6 Sr by ICPMS 10 71 ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-28-0 Thallium(TI)ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-32-6 Ti(Titanium)by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/14/17 ESTAFFORD1
7440-62-2 V by ICP 10 10 U ug/L EPA200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
WSS Chemistry Laboratory»1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

A044714 North Carolina D on of Water Resources Water Scienu action Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44714
County: BUNCOMBE Collector: B LAVERTY VisitlD SW4-Al PO Number#
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/03/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 08_20
Emergency Collect Time: 14_53 Sample Matrix: SURFACEWATER Labworks LoginlD MSWIFT
COC Yes/No YES Sample Depth Loc.Type: RIVER/STREAM Delivery Method NC Courier
Final Report Date: 12/15/17
Report Print Date: 01/04/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analvte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.6 °c 11/3/17 ESTAFFORDI
WET
Bromide 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Chloride 1.0 6.5 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Fluoride 0.4 0.4 U mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
Sulfate 2.0 8.1 mg/L EPA 300.0 rev2.1 11/8/17 CGREEN
MET
7440-22-4 Ag-Dissolved Silver by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 Al-Dissolved Aluminum by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-38-2 As-Dissolved by ICPMS Arsenic 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7429-90-5 B Dissolved by ICP 50 93 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-38-3 Ba-Dissolved Barium by ICP 10 18 ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-41-7 Be-Beryllium Dissolved by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-70-2 Ca-Dissolved Calcium by ICP 0.10 7.9 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7440-43-9 Cd-Dissolved Cadmium by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-48-4 Cobalt Dissolved by ICP 50 50 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORDI
7440-47-3 Cr-Dissolved Chromium by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-50-8 Cu-Dissolved Copper by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-89-6 Fe-Dissolved Iron by ICP 50 1600 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-97-6 Hg 245.1 Dissolved 0.2 0.20 U ug/L EPA245.1 Rev3 11/7/17 ESTAFFORDI
7440-09-7 K-Dissolved Potassium by ICP 0.10 1.6 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-93-2 Li DISSOLVED ICP 25 25 U ug/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-95-4 Mg-Dissolved Magnesium by ICP 0.10 4.1 mg/L EPA 200.7 Rev4.4 11/20/17 ESTAFFORDI
7439-96-5 Mn Dissolved by ICP 10 450 ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7439-98-7 Mo Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-23-5 Na-Dissolved Sodium by ICP 0.10 3.6 mg/L EPA 200.7 Rev4A 11/20/17 ESTAFFORD1
7440-02-0 Ni-Dissolved Nickel by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7439-92-1 Pb-Dissolved Lead by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-36-0 Sb Dissolved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7782-49-2 Se Dissolved by furnace 1.0 1.0 U ug/L EPA 200.9 Rev2.2 11/22/17 ESTAFFORDI
7440-31-5 Sn Dissloved by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
Sr Dissolved by ICPMS 10 69 ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORD1
7440-28-0 Thallium(TI)Dissolved by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 11/27/17 ESTAFFORDI
7440-32-6 Ti(Titanium)Dissolved by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/14/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL'.
Page 1 of 2

.NC MR ratory Section q?fsufts/Sampfe Comments/Qzucfifwr(D fora
Sample ID: AC44714
CAS# Analyte Name PQL Result/ Method Analysis
Qualifier Units Reference Date Validated by
7440-62-2 V Dissolved by ICP 10 10 U ug/L EPA 200.7 Rev4.4 11/21/17 ESTAFFORD1
7440-66-6 Zn-Dissolved Zinc by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 11/27/17 ESTAFFORDI
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 2 of 2

AC44798 • ' North Carolina I -.--don of Water Resources Water Scienc _ ection Laboratory Results
Loc.Descr.: ASHEVILLE AIRPORT-61 TERMINAL DRIVE FLETCHER,NC Sample ID: AC44798
County: BUNCOMBE Collector: B LAVERTY VisitlD SW4-AI PO Number# ARO
Region: ARO Report To ARO Location ID: 1111ASHEVILLEAIRPOR Date Received: 11/02/2017
River Basin FBR Collect Date: 11/01/2017 Priority ROUTINE Time Received: 11_63
Emergency Collect Time: 14_63 Sample Matrix: SURFACEWATER Labworks LoginlD KJIMISON2
COC Yes/No YES Sample Depth Loc.Type: RIVERISTREAM Delivery Method NC Courier
Final Report Date: 119118
Report Print Date: 01/09/2018
Final Report
If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS# Analyte Name PQL Qualifier Units Reference Date Validated by
ARO
Alkalinity4.5 1.0 33 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Alkalinity8.3 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Bicarbonate 1.0 33 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORD1
Carbonate 1.0 1 U mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
pH Alkalinity 6.4 mg/L as CaCO3 SM 2320B-1997 11/13/17 ESTAFFORDI
Sample temperature at receipt by lab 6.0 °c 11/2/17 RBYRD
WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 [phone]
"Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 1

North Carolina Division of Water Resources Viskb- Tag `�_�� ESL'' `'
Central Laboratory(Water Sciences Section) Water Sample Collection&Submittal Form (optional)' SW4-Al 11D•1( 12 Laboratory I
i �5oritple Number..
LoGatfon b6scription: Asheville Airport-61 Terminal Drive Fletcher, NC Location Code.l 1111 ASHEVILLEAIRPORT
a Date Received:
Gounty Buncombe cooector Brett Laverty rrorrty; t�ot� Matrix., Lo atronType Ap,
DWR4egron DWR Ogee:" ❑ ❑River/stream ❑Lake Time Received:.
Asheville Regional Operations Ambient
(b¢sedvncnurrtyJ {orager¢cyrrame) ❑Surface El Estuary ❑Canal
Received By;
/tiveiRosin French Broad River "Date 11/1/2017 ❑� Routine ❑Stormwater
State Courier
El Compliance El Ground ❑Monitoring Well ❑Water Supply `` N.
Notes: SW4-Al ,Time " 2:40 PM
DeliveryMethtid: ❑Hand Delivery
❑COC ❑Waste El Effluent ❑Influent ❑Other:
Chlorinated ❑De-chlorinated in Field Sat�¢ptrng 0 Grab Composite Emergency ❑Field Blank
❑ g y ❑Blank [:]Trip Blank
1►7ethod ❑Other: ❑ ❑Filter Blank Temperature("C)
Dissolved analysis:Enter"DIS" onAmval:
❑Filtered in Field SampteDepth..] ❑QA ❑Solution ❑other:
in check-boxes for parameters
Collector's Comments:--I
MicrobiologyPaiameters i MBAS(surfactants) mg/L Metals,Parameters:„ Y X Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L X Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L
Coliform:Total MF /100m[ Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100m[ TDS-Total Dissolved Solids mg/L X Calcium(Ca) mg/L
Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters:
Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides
,,-,QtherPapameters:< .•°w. X Lead(Pb) µg/L Organophosphorus Pesticides
Wet CbemistrYParameters: ":t pH S.U. X Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L
Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range
Sulfate mg/L �z,;`,NutrlentsParameters. p °� e'q a X Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Nil µg/L Volatile Organics(VOA)
Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L X Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L siological. .
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae
Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L
LAB COMMENTS:
Field Parameters(optona¢ ;WaterTemp(°C):, pH(s u) Dissolved Oxygen(ppm): Conductivity(µmhos/cm): Salinity(ppt): .
Revision:2/06/201S

North Carolina Division of Water Resources �' 1i;stop Ta a �(7 �/3e apt��
Water Sample Collection&Submittal Form SW 4-A1 f 13
Central Laboratory(Water Sciences Section) .(optional) II ID,I ltrboratary
Sanrple Nurrrfier
Locotrvn Description Asheville Airport-61 Terminal Drive Fletcher, NC Location Cade: 1111ASHEVILLEAIRPORT
Date Received:
County ! Buncombe Collector Brett Laverty Priority., 1!Vater Matrix Location Type:p ,
DWR"RegiO»:; " DWR=Uff1Ge,' ❑� River/Stream Lake Time Received.:,
Asheville l Regional Operations ❑Ambient
(trasedoncounW (orogenrynamej ❑Surface ❑Estuary —]canal
1 1 KeceroedSy:
Routine ❑Stormwater ,i
RrverBasin:`_ French Broad River Date 11/1/2017
El Compliance El Ground ❑Monitoring Well ❑Water Supply State Courier
DeJiperp`Mettwod: ❑Hand Delivery
Notes: SW4-Ai 7"mtea 2:53 PM
❑COC ❑Waste ❑Effluent ❑Influent ❑Other:
Sornpdng v' ❑✓ Grab Composite ❑Field Blank b, a �_
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency El Blank [:]Trip Blank
Method ❑Other: ❑Filter Blank Temperature('C)
Dissolved analysis:Enter"DIS" oaArrivgi:;
❑Filtered in Field In check-boxes for parameters �S4mpleDepth ❑CIA ❑Solution ❑Other:
x
Colleclor's,Cotnments:
-Microbiology Parameters; MBAS(surfactants) mg/L Metals Parameters: DIS Tin(Sn) µg/L
Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L DIS Aluminum(AI) µg/L DIS Titanium(Ti) µg/L
Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L DIS Antimony(Sb) µg/L DIS Vanadium(V) µg/L
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L DIS Arsenic(As) µg/L DIS Zinc(Zn) µg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L DIS Barium(Ba) µg/L
Coliform:Fecal MF /looml Residue:Suspended(Suspended Solids) mg/L DIS Beryllium(Be) µg/L DIS Boron(B),Total µg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L DIS Cadmium(Cd) µg/L Mercury 1631,low-level ng/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L DIS Calcium(Ca) mg/L
Coliform:Tube Total /loom[ Silica mg/L DIS Chromium(Cr),Total µg/L Orgi!glcs,Parameters:, ° jj
Specific Conductance,at 25°C umhos/cm Sulfide mg/L DIS Cobalt(Co) µg/L Acid Herbicides
TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L DIS Copper(Cu) µg/L Organochlorine Pesticides
Turbidity NTU DIS Iron(Fe) µg/L Organonitrogen Pesticides
Other Parameters: :° DIS Lead(Pb) µg/L Organophosphorus Pesticides
Wrt-Chemistry Paramefgrs „` ..: � ;:,; pH S.U. DIS Lithium(Li) µg/L PCBs(polychlorinated biphenyls)
Bromide mg/L Hardness,Total as CaCO3-by titration mg/L DIS Magnesium(Mg) mg/L
X Chloride mg/L DIS Manganese(Mn) µg/L Semi-Volatile Organics(BNAs)
Fluoride mg/L DIS Mercury(Hg) µg/L TPH Diesel Range
X Sulfate mg/L Nutrients'Parameters-
DIS Molybdenum(Mo) µg/L
Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L DIS Nickel(Ni) µg/L Volatile Organics(VOA)
Color:ADM] C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L DIS Potassium(K) mg/L
Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L DIS Selenium(Se) µg/L TPH Gasoline Range
COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L DIS Silver(Ag) µg/L
Cyanide,Total mg/L Nitrite as N(NO2-N) mg DIS Sodium(Na) mg/L Biological:
Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L DIS Strontium(Sr) µg/L Phytoplankton/Algae
Hexava[ent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L DIS Thallium(TI) µg/L
LAB COMMENTS:
Field ParameEers(opt/onap m WaterTt mp(aC)a;) pH(s u).; Dissolved O_Jcygen(ppm): Conductivity(µmhos/an): Salt
N ,f, a r u ce r ..
Revision:2/06/2015

North Carolina Division of Water Resources 'Tag, Ldb
W4 LiSeeQllr' °
Water Sample Collection&Submittal Form Ylst><D S -Al 13
Asheville Laboratory(Water Sciences Section) (optroreatj - ID toturntory
' • °� ` ' 3arrr`pleAturgfier
cotron,Descrrptoci; Asheville Airport-61 Terminal Drive Fletcher, NC Egci#ronCrnle 1111ASHEVILLEAIRPORT
Dgte Recahrad.,
County 4x . ,s°, Buncombe Colfecto� ° Brett Laverty F F Prrofity WaterMatirx LocatronTypet r Rm a
a € 1"
Time Received e=
© RegiQn 'I Asheville dW � e ` River/Stream Lake t i
6gsedonco (� agar} a Regional Operations ❑Ambient
Ld( wrtyJ° /tee fYQprri/ ❑surface ❑Estuary ❑Canal
Received�y ,
f�Rlrrer8as►n. .� French Broad River 11/1/2017 ❑Routine ❑stormwater
❑Compliance ❑Ground ❑MonitoringWell ❑Water Supply , State Courier
a ❑t
Hand Delivery
SW4-A1 Time 2:53 PM
Notes: COC ❑Waste [:]Effluent ❑Influenti ❑Other:
Saiiplirrg ,° ❑✓ Grab Composite ❑Field Blank
❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ElBlank ❑Trip Blank
O'bod.-r, j ❑Other: ❑Filter Blank Temberot4rei("C�
Dissolved analysis:Enter"DIS" anAmvai..
El Filtered in Field SvmpleDepth., El CA ❑Solution ❑Other:
in check-boxes for parameters
Collector`sComnients
Microbiology Parameters: °; m
Acidity,as CaCO3,to pH 4.5/8.3 mg/L
X Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L - Solids Parameters*-
A �� o�-
BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L
cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L
-,
Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L
Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L
Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L g,
Coliform:Tube Total /100ml
Specific Conductance,at 25°C umhos/cm
Turbidity NTU
Other Parameters: ' r
e
j
pH S.U.
�R
-
_: -
LAB COMMENTS:
su svedOxeMatr g Do m41 , SanField Parameters{optkna) o np °Gj ity(Pptj e°
Revision:2/06/2015

Report to: 7 SURFACE WATER SECTION Page of
CHAIN OF CUSTODY(COC)RECORD
NC DENRIDWR LABORATORY(check one): []CENTRAL`eARO
For Investigation of: /4s e v,/le A A 1 rA C'C f S'Tr u c-f u l-A L ic,j l
Sample collector (print name) /� r
and DM-1 forins completed by: /)2 r LAV E(?_'f, Sample collector's signature:<,.
Field storage conditions and location(when applicable):
av )C F, S Gil Leo co o Lt-2 b9Z S"A IDA C/o A 6 0 M
Lab Use Ouiy NUMBER
DATE TIME OF
LAB NO: STATION NO. STATION LOCATION SAMPLED SAMPLED CONTAINERS
i._/i t �I2 G l C C- j� �, rr v c_'ram�.sl L , ► + ,� ,.� �. .i �, f
Sw3 -ii1 f1 ,I , 1l QG +
122-I0
5'lAj 5-- ,q
10 ,
Is Lill -AI
Rejinggished y�s'gnature): Date Time Received b signatu ): Date Time
Relmquis ed (signature): ffat Time Received y(signature): Dafe Time
Relinquished by(signature): Date Time Received by(signature): Date Time
Method of Shipment(circle one): State Courier Hand-delivered Federal Express UPS Other:
Sealed by: Broken by:
Security Type and Conditions:
INTRALABORATORY CHAIN OF CUSTODY - Lab Use Only
LAB NUMRERS =:="A UMBER. ANALYSES• . •:. :ItELINQULSSHED RECEIVED DATE TIME
FROM THROUGH:.- "'.11 f-EiES REQIMSTED::.`. :BY::.
QMFonnslSample ReceivinglCOC form WR 4110/01dbs Revised:M3/2613 ntg

Reportto: lA✓ety SURFACE WATER SECTION Page 1 of �=
CHAIN OF CUSTODY(COC)RECORD
NC DENRIDWR LABORATORY(check one): J�{CENTRAL []ARO
For Investigation of: /'
�.v,J1� , r O•/'� �t _ CC. S'�'r �� C vi t
Sample collector {print name) n
and DM-1 forms completed by: !9 f AE / G V , (L:C Sample collector's signature:
Field storage conditions and location(when applicable):
p yv ,eel 5'eliteo Cp e /e l /4rz G Sr{.4t Ie
Lab Use.Only NUMBER
DATE TIME OF
LAB-N.0_ STATION NO. STATION LOCATION SAMPLED SAMPLED CONTAINERS
5WI-AI A C Cj9 Sr.-velue I I octa 1.7 9;/G
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Relinq ' d. signa re); Date Time Received by(signature): Date Time
/t 2 r' +ot J 7
�Relin uished by 'ature): D e Time Received by(signature): Date Time
Relinquished by(signature); Date Time Received by(signature): Date Time
Method of Shipment(circle one): State Courier Hand-delivered Federal Express UPS Other:
Seated by: Broken by:
Security Type and Conditions;
INTRALABORATORY CHAIN OF CUSTODY - Lab Use OnI
LAB NUMBERS• NUMBER,,:,. :ANALYSES RELINQUISHED RECEIVED....: DATE TIME
FROM THROU('rI?c BOTTLES. REQUESTED BY: BY::
QAWormslSample ReceivinglCOC form WR 4/10/Oldbs Revised:8I23/2013 ntg

Reportto: �'�r� L�rJ���C, SURFACE WATER SECTION Page 2 of �—
f CHAIN OF CUSTODY(COC)RECORD
NC DENRIDWR LABORATORY(check one): ,CENTRAL 1 l AR0
For Investigation of; 4,5htVr fl ,
Sample collector (print name) Q
and DM-1 forms completed by: L)!C- f a? 1/l'OLD' Sample collector's signature:
Field storage conditions and location(when applicable):
of "cam Sc' EU Coo e,- d/L4 SRM �� ✓� ��'�'�
•Lab Use Only NUMBER
DATE TIME OF
LAB NO:."' STATION NO. STATION LOCATION SAMPLED SAMPL19D CONTAINERS
` SWk--A e,4 1 C d S7/c3 Ez t
5W7-AI 17 a J9
Swy._/ ) !
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R by(s' nature): Date Time Received by(signature): Date 'Tim
ee
Re mquishe b signature): D to 'Time Received by(signature): Date .Time
Relinquished by(signature): Date Time Received by(signature): Date Time
Method of Shipment(circle one): State Courier Band-delivered Federal Express UPS Other:
Sealed by: Broken by:
Security Type and Conditions:
INTRALABORATORY CHAIN OF CUSTODY - Lab Use Onl
LAB NUMBERS :j NUMBER ANALYSES.*:':.:- '.RELINQUISHED RECEIVED DATE TIME
FROM THROUGH . ..;BOTTLES REQUESTED` :: BY: : :.:: BY:
QMFormslSample ReceivinglCOC form WR 4/10101dbs Revised:8/23/2013 ntg