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HomeMy WebLinkAboutWQ0004825_Residual Annual Report 2020_20210224Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* WQ0004825 Applicant/Permittee City of Randleman Email Notifications Does this need review by the hydrogeologist?* 0 Yes r No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* WQ0004825 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * City of Randleman RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for City of Randleman NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Fans, Specifications, Calculations, Bc.) Randleman 2020 Annual FINAL.pdf 10.7MB Upload only 1 FCFdocurrent (less than 250 fvB). Miltiple documents rust be corrbined into one F7Ffile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/24/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 24, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0004825 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the City of Randleman, NC. If you have any questions or need additional information, please do not hesitate to contact Nick Holcomb at (336) 495-7500 or Ryan Copeland at (336) 607-4494. Sincerely, W�1 01_ I t Derrick Shivar Environmental Compliance Manager Enclosures cc: Nick Holcomb, City of Randleman Ryan Copeland, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF RANDLEMAN, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0004825 2020 ANNUAL REPORT City of Randleman, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms & Metals Field Loading Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00004825 County Randolph Year 2020 Facility Name (as shown on permit) City of Randleman WWTP NPDES No. NCO025445 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 18 Total number of fields utilized for land application during the year: 4 Total amount of dry tons applied during the year for all application sites: 130.35 Total number of acres utilized for land application during the year: 85.60 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water QualityX YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Michael Glass, Plant Superintendent Permittee Name and Title (type or print) Signature of Preparer* Date (if different from Permittee) -;, %L--- Sig a o e tte to Ap �lz�l► Si tore of Land A lier. Date (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 RANDLEMAN,NC RANDLEMAN, NC RANDLEMAN WWTP LIQUID MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS January 2020 198,000.00 G 26.75 D 24.26 May 2020 246,000.00 G 33.24 D 30.15 June 2020 260,400.00 G 35.18 D 31.91 September 2020 93,000.00 G 12.57 D 11.40 October 2020 167,400.00 G 22.62 D 20.51 TOTAL 964,800.00 G 130.35 D 118.23 Report Date: 2/8/2021 1:21:59 PM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0004825 Laboratory: Facility Name: RANDLEMAN, NC Waypoint Analytical Virginia Inc. Residual Source WO # or NPDES#: NCO025445 WWTP Name: RANDLEMAN WWTP Residual Analysis Data Product Type Sample or Composite Date LIO 01/22/20 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 3.24 Arsenic 75 <15.6 Cadmium 85 <3.13 Copper 4300 244 Chromium NA 34.1 Lead 840 42.8 Mercury 57 <0.472 Molybdenum 75 10.3 Nickel 420 14.8 Selenium 100 <15.6 Zinc 7500 172 Total Phosphorus NA 8060 TKN NA 46300 Ammonia -Nitrogen NA 6720 Nitrate and Nitrite NA <146 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer* Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (12/2006) Printed: 2/8/2021 7:22:58 PM For: 2027 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0004825 Facility Name: RANDLEMAN, NC Residual Source NPDES # or WQ#: NCO025445 WWTP Name: RANDLEMAN WWTP Residual Analysis Data Product Type LIQ Sample or Composite Date 01/22/20 Parameters (mg/kg dry weight) Aluminium 7220 Calcium 116000 Magnesium 7340 pH (s.u.) 11.90 Potassium 2390 Sodium 1700 PAN 15416 SAR (Ratio) 0.2350 Laboratory: Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." -19-21 Signature of Preparer * Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 2/6/2021 7:22:23 PM For: 2027 01 DENR FORM RSSF-B (12/2006) Waypointo ANALYTICAL 2/3/2020 Synagro Central LLC/ Randleman Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 20-024-0013 Project Description: Randleman WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 1/24/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, �a f• c•—r Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 6 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-024-0013 Client Project Description: Randleman WWTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 70267 Randleman WWTP Solids 01/22/2020 12:25 01/24/2020 SM-2540G WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN 4500NO3F-2011 WP MTN 6010D WP MTN SM-4500-NH3C WP MTN 9045D WP MTN AOAC 955.01 WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 6 i Waypoint. ANALYTICAL 46483 Synagro Central LLC/ Randleman 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Mary Brewer Project Randleman WWTP Report Date : 02/03/2020 284 Boger Road Information : Received : 01/24/2020 Mocksville , NC 27028 Pam« mL 60wr Report Number : 20-024-0013 REPORT OFANALYSIS Pauric McGroary Agronomist Lab No : 70267 Matrix: Solids Sample ID: Randleman WWTP Sampled: 1/22/2020 12:25 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 96.8 % 0.010 1 01/28/2015:34 ADM SM-2540G Calcium Carbonate Equivalent 25.6 % - dry 0.1 1 01/29/20 09:25 DXT AOAC 955.01 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 6720 mg/Kg - dry 3130 1 01/31/20 12:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N <146 mg/Kg - dry 146 1 01/29/20 13:34 ZBD 4500NO3F-2011 Organic N 39700 mg/Kg - dry 7810 1 01/31/20 10:00 CALCULATION pH 11.9 S.U. 1 01/30/20 06:12 JSL 9045D Total Solids 3.24 % 0.010 1 01/28/20 15:34 ADM SM-2540G Total Kjeldahl Nitrogen 46300 mg/Kg - dry 7810 1 01/31/20 10:00 JPJ ;M-4500-NH3C-TKl` Phosphorus 8060 mg/Kg - dry 156 1 01/29/20 17:01 JTR 6010D Aluminum 7220 mg/Kg - dry 156 1 01/29/20 17:01 JTR 6010D Arsenic <15.6 mg/Kg - dry 15.6 1 01/29/20 17:01 JTR 6010D Calcium 116000 mg/Kg - dry 781 1 01/29/20 17:01 JTR 6010D Cadmium <3.13 mg/Kg - dry 3.13 1 01/29/20 17:01 JTR 6010D Chromium 34.1 mg/Kg - dry 7.81 1 01/29/20 17:01 JTR 6010D Copper 244 mg/Kg - dry 7.81 1 01/29/20 17:01 JTR 6010D Iron 7970 mg/Kg - dry 156 1 01/29/20 17:01 JTR 6010D Lead 42.8 mg/Kg - dry 9.38 1 01/29/20 17:01 JTR 6010D Magnesium 7340 mg/Kg - dry 156 1 01/29/20 17:01 JTR 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 6 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46483 Synagro Central LLC/ Randleman Mary Brewer Project Randleman WWTP Report Date : 02/03/2020 284 Boger Road Information : Received : 01/24/2020 Mocksville , NC 27028 Pam« mL 60wr Pauric McGroary Report Number : 20-024-0013 REPORT OFANALYSIS Agronomist Lab No : 70267 Matrix: Solids Sample ID: Randleman WWTP Sampled: 1/22/2020 12:25 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Manganese 242 mg/Kg - dry 15.6 1 01/29/20 17:01 JTR 6010D Mercury <0.472 mg/Kg - dry 0.472 1 01/29/20 12:05 TJS SW-7471B Molybdenum 10.3 mg/Kg - dry 7.81 1 01/29/20 17:01 JTR 6010D Nickel 14.8 mg/Kg - dry 7.81 1 01/29/20 17:01 JTR 6010D Potassium 2390 mg/Kg - dry 156 1 01/29/20 17:01 JTR 6010D Selenium <15.6 mg/Kg - dry 15.6 1 01/29/20 17:01 JTR 6010D Sodium 1700 mg/Kg - dry 781 1 01/29/20 17:01 JTR 6010D Zinc 172 mg/Kg - dry 39.1 1 01/29/20 17:01 JTR 6010D Sulfur 11300 mg/Kg - dry 156 1 01/29/20 17:01 JTR 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit L Limit Exceeded Page 4 of 6 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 2-4237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46483 Customer Name: Synagro Central LLC/ Randleman Report Number: 20-024-0013 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 01/24/2020 13:31:36 Page 5 of 6 111111IIII111Ihill IIIi111111I11111111I�111111II111I1111111 fl-24�o3 SAMPLING LOG # Svnagro Cenlral LLC. Randleman c. 13:30:34 CHAIN OF CUSTODY' Randleman WWTP RECORD & ANALYSIS RECORD �N �N� � l attest that the proper field sampling procedures PROJEGT MANAGER:.T�y _ were used daring the'oolleadon of these samples. l Phone: lm) SAMPLER A & L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAB # SAMPLE I.D. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED ��LO F Rallnqulshed by Sampler. F�PrN C �a�tZ FirID Dade. I z yz0 Time , 5' 30 Recieved by: REMARKS: Relinquished by: Glslte Time Realeved by; Relinquished by. SPECIAL INSTRUCTIONS: -V7'LA'o' r� C WX monitoring purposes. Date Time Reclaved by: im SAMPLE ANALYSIS REOUEST I.D. SLI SL2 NH -N NO -N s t)t�anls Cd Ce NI Pllt As H 9 Se P H COCO ahr. volatile Solids W10 CI NC -N a �1}NOt r'j%'I j0dw rot x0aw air PO pw AOOO pw loot 1409 loot 1400 1400 600 SLi : Total Solids (Moisture), Total Neldahi Nitrogen, Phosphorus, and Potassium SIB: 13aslc Test SLi plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc Page 6 of 6 SECTION 3 FACILITY NAME: RANDLEMAN, NC LANDOWNER: W. HOWARD FIELDS OPERATOR: W. HOWARD FIELDS CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY F®I2 WQ PERMIT #: W00004825 FIELD#: NC-RD-00018-0-0003- ANNUAL DRY TONS APPLIED: 68.42 SITE #: NC RD 00018 PREDOMINANT SOIL SERIES: CORONICA CROP 1 MAX. PAN: 209 CROP 2 NAME: Page: 1 ACRES UTILIZED: 18.9 ACRES PERMITTED: 18.9 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) I Site Name of Crop Type or Cubic Yards (Y) y! Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual p Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate"* � Rate*** mglkg mg/kg mglkg Crop 1 Crop 2 Crop 1 Crop 2 5/11/2020 138,000.00 (G) 3.240 0.987 RAIL DRY "0-<1/2" SUR 0.5 0.30 46,300.00 6,720.00 146.00 30.416 FSH 5(12l2020 108,000.00 (G) 3.240 0.772 RAIL DRY "0-<1/2" SUR 0.5 0.30 46,300.00 6,720.00 14&00 23.804 FSH May-20 246,000.00(G) 9128l2020 93,000.00 (G) i 3.240 0.665 RAL DRY "0-<1/2" SUR 0.5 0.30 46,300.00 6,720.00 146.00 20.498 FSH Sep-20 93,000.00� (G) 10l1/2020 93,000.00, (G) i 3.240 0.665 RAL MOIST 0-<1/2" SUR 0.5 0.30 46,300.00 6,720.00 146.00 20.498 FSH s 10/2/2020 74,400.00'! (G) 3.240 I 0.532 RAL MOIST 0-<1/2" SUR 0.5 0.30 46,300.00 6,720.00 146.00 16.398 FSH a 4 Oct-20 167,400.00 (G) u Total 3.621 Total 111.614 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied s JAnnuai Ibs/acre Applied 0.113 0,0231 1.767 1 0.247 0.310 1 0.003 0.075 0.107 0,113 1.245 5& 5 Date Lbs/Ac Dative Ibs/acre Applied 0.244 j 0.094 1 10.326 1 4.611 0 5.293 1 0.027 1 0.315 1 0. Permit PAN Limit (Ibs/acre) 1st Crop: w� Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 6 375.0 89.0 2,500.0 RAIL = RANDLEMAN, NC RANDLEMAN WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties forssu��bmitting false information, including the possibility of fines and imprisonmentt forknowingkknnoowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required "** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 *'**" See Site pH & Lime Application Records Section of Report Printed: 2/812021 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Randleman, NC WQ0004825 W. Howard Fields Owner: 18.9 Acres Permitted: Total Dry Tons Applied (Annual): 68.42 Cation Exchange Capacity (non 503 only): W. Howard Fields Predominant Soil Series: Coronica 18.9 Site #: NC RD 00018 Field #: RD 00018 0003 RPcidnal Annlvsis Data (Heavy Metals and Total Phosnhorus use mi/kli. % Solids use Raw Percent #): Com- posite Date 1 Total h . • :1.1 Anneal HPaw Metal NSeIl1 1 ,A5k(11n4C I1 *surm1atpa In Insiscrei: Total 1 2 3 4 v 5 6 _7j 8 9 10 11 12 H DT/Ac./51, App. y Event 3.62 Arsenic 0.113 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 1 0.113 Cadmium 0.023 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 Copper 1.767 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.767 Chromium 0.247 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.247 Lead 0.310 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.310 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.003 Molyb- 0.075 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.075 denum Nickel 0.107 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.107 Selenium 0.113 j 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.113 Zinc 1.246 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.246 Total Phos- 58.371 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 58.371 horus "I certify, under penalty of law, that this document was preparea under my airecuon or supervisluu in accvruanec with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: ' FACILITY NAME: RANDLEMAN, NC WQ PERMIT #: WQ0004825 FIELD#: NC-RD-00019-0-0001- ACRES UTILIZED: 30.9 LAND OWNER: ROY HOLDER ANNUAL DRY TONS APPLIED: 26.75 SITE #: NC RD 00019 ACRES PERMITTED: 30.9 OPERATOR: ROY HOLDER PREDOMINANT SOIL SERIES: CECIL CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE PASTURE (FSP) CROP 1 MAX. PAN: 153 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) s Name of Crop Type or Cubic Yards (Y) } 7Dry,Wet, Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate" Rate— mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 1/21/2020 126,000.00 (G) 3.240 0.551 RAL MOIST "0-<1/2" SUR 0.5 0.30 46,300.00 6 6,720.00 146.00 16.986 FSP 1/22/2020 72,000.00 (G) 3.240 D.315 RAL I MOIST "0-<1/2" SUR 0.5 0.30 46,300.00 6,720.00 146.00 9.706 FSP Jan-20 198,000.00 (G) d Total 0.866 Total 26.692 0.000 RAL = RANDLEMAN, NC RANDLEMAN WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there a e significant penalties for submitting false information, including the possibility of fines jand imprisonment for knowing violations." � U 2f SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required ** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation *** C.P.L.R.: Cumulative Pollutant Loading Rate "* Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***'"* See Site pH &. Lime Application Records Section of Report Printed: 2/10/2021 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Randleman, NC Total Dry Tons Applied (Annual): 26.75 Permit #: WQ0004825 Cation Exchange Capacity (non 503 only): Operator: Roy Holder Owner: Roy Holder Predominant Soil Series: Cecil Acres Used: 30.9 Acres Permitted: 30.9 Site #: NC RD 00019 Field #: RD 00019 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Imp, T -� posite Date:000000000000 Total • -ENEEMENEENE. p� M Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 y DT/Ac./ App. Event 0.87 Arsenic 0.027 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Cadmium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.423 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.423 Chromium 0.059 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.059 Lead 0.074 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.074 Mercury 0.001 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 denum Nickel 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Selenium 0.027 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Zinc 0.298 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.298 Total Phos- 13.960 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 13.960 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". P; AA-� LKIAW /Z.n z/ Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: RANDLEMAN, NC WQ PERMIT #: WQ0004825 FIELD#: NC-RD-00019-0-0002- ACRES UTILIZED: 17.3 LANDOWNER: ROY HOLDER ANNUAL DRY TONS APPLIED: 15.08 SITE #: NC RD 00019 ACRES PERMITTED: 17.3 OPERATOR: ROY HOLDER PREDOMINANT SOIL SERIES: APPLING CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE PASTURE (FSP) CROP 1 MAX. PAN: 177 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond, Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual I Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate`* Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 6/23/2020 l 68,200.00 (G) 3.240 0.533 RAL DRY I "0-<1J2" SUR 0.5 0.30 46,300.00 6,720.00 146.00 16.422 FSP 6/24/2020 43,400.00 (G) 3.240 0.339 RAIL DRY 110-<1/2" SUR 0.5 0,30 46,300.00 6,720.00 146.00 10.450 FSP Jun-20 111,600.00 (G) Total 0.872 Total 26.872 0.000 AS�0005�0.4�25�0 PB�<0.0�01 MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.0270.0750.018 0.026 0.027 0.300 14.050 Date LbslAc Ibs/acre Applied 0.108 IE 1 3.761 0.168 89.0 177 RAIL = RANDLEMAN, NC RANDLEMAN WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signific t penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/8/2021 DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Randleman, NC Total Dry Tons Applied (Annual): Permit #: WQ0004825 Cation Exchange Capacity (non 503 only): Operator: Roy Holder Owner: Roy Holder Predominant Soil Series: Acres Used: 17.3 Acres Permitted: 17.3 Site #: NC RD 00019 Field #: 15.08 Appling RD 00019 0002 eavv Metals and Total Phosphorus use mgAkg, % Solids use Raw Percent ft Com- Posite Date Total Phos- phorus A'"VS1101 Anaw Metal Field T,AA 1n4C a cu a e in S acre : a..a..» » . J " - - s ___- _-------a- I - --- 4 - _. . _ 5 6 7 8 9 10 11 12 Total 1 2 3 y DT/Ac./ App. y Event 0.87 Arsenic 1 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Cadmium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.426 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.426 Chromiurn 0.059 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.059 Lead 0.075 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.075 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 denum Nickel 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Selenium 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Zinc 0.300 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.300 Total Phos- 14.057 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 14.057 horus "I certify, under penalty of law, that this document was preparea unaer my uirecuun ur 5upei V 131uli In a%.%.uz uau� a with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier l f Zl Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page. 1 FACILITY NAME: RANDLEMAN, NC WQ PERMIT #: W00004825 FIELD#: NC-RD-00019-0-0003- ACRES UTILrZED: 18.5 LAND OWNER: ROY HOLDER ANNUAL DRY TONS APPLIED: 20.10 SITE #: NC RD 00019 ACRES PERMITTED: 18.5 OPERATOR: ROY HOLDER PREDOMINANT SOIL SERIES: CECIL CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE PASTURE (FSP) CROP 1 MAX. PAN: 156 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report or Cubic Yards (Y) Cond. g Precip Volati- Mineral- Ammonia i Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Arno_un_t UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate" Rate- mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 6/23/2020 37,200.00 (G) 3.240 6.272 RAIL DRY '0-<1/2" SUR 0.5 0.30 46,300.00 6,720.00 146.00 $.376 FSP 6/24/2020 74,400.00 (G) 3.240 0.543 RAL DRY 110-<1/2" SUR i 0.5 0.30 46,300.00 6,720.00 146.00 16.753 FSP 6/25l2020 37,200.00 (G) i I 3.240 0.272 RAL DRY 0-<1/2" SUR � 0.5 0.30 46,300.00 6,720.00 146.00 8.376 � FSP s " Jun-20 148,800.00 (G) u k Total 1.087 Total 33.505 0.000 AS CD CU±�O.Oj74�0,093 B HG MO NI SE I ZN P Lime Applied knnual Ibs/acre Applied 0.034 0.007 0.530 0.001 0.022 0.032 0.034 0.374 17.518 Date LbsiAc 'umulative Ibs/acre Applied 0.074 D.029 3.362 1.726 1.645 0.011 0.098 0.237 0.0$6 5.926 15.0 1 375.0 RAL = RANDLEMAN, NC RANDLEMAN WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." V 21161 7- SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required "** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 See Site pH & Lime Application Records Section of Report DENR FORM FSF (1212006) Printed: 2/812021 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Randleman, NC Total Dry Tons Applied (Annual): 20.10 WQ0004825 Cation Exchange Capacity (non 503 only): Roy Holder Owner: Roy Holder Predominant Soil Series: Cecil 18.5 Acres Permitted: 18.5 Site #: NC RD 00019 Field #: RD 00019 0003 Residual Analvsis Data (Heavv Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Annual Heavy Metal Field Loadings (Calculated in s acre Total Annual Heavy Metal Field Loadings (Calculated in s acre Total 1 2 3 4 5 6 7 8 __gj Lj 11 12 H DT/Ac./ App. 14 Event 1.09 Arsenic 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.034 Cadmium 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.530 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.530 Chromium 0.074 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.074 Lead 0.093 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 1 0.093 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 denum Nickel 0.032 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 Selenium 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.034 Zinc 0.374 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.374 Total Phos- 17.522 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 17.522 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accuruance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". KY-1 La II Signature of Land Applier Zle/2% Date DENR FORM MFLSF (12/2006) SECTION 4 SUMM111 ENVIRONMENTAL TECHN❑LOMZ3. INC ArrzrJy0ca1 Laboralorfas December 30, 2020 Ryan Copeland Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: FAX: RE: Randelman - REVISED Dear Ryan Copeland: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Order No.: 20121121 Summit Environmental Technologies, Inc. received 1 sample(s) on 12/18/2020 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho 01100923, Illinois 200061, Indiana C-011-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP C1,0052, Oklahoma 2019-155, Oregon 0112O0001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah 011009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 39 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 20121121 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 12/30/2020 CLIENT: Synagro Project: Randelman - REVISED WorkOrder Narrative: 20121121: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. REVISED REPORT 12/30/20: Includes QC Summary Report pages for TCLP Herbicices. Revision vI Page 2 of 39 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S Ekiwlt OMM@N-rALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 20121121 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-44E Wehsite: httn:11www.settek.co Date: 12/30/2020 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low () or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low () or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low () or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low () or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Revision vl Page 3 of 39 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMMEWAL TECHNp4,1 ULES,1NC. Cuyahoga Falls, Ohio 44223 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Randelman - REVISED Lab SampleID Client Sample ID 20121121-001 Randleman VAVTP Tag No Date Collected 12/16/2020 11:15:00 AM Workorder Sample Summary WO#: 20121121 30 Dec-20 Date Received Matrix 12/18/2020 10:20:00 AM Sludge Page 4 of 39 SUMMIT Summit Environmental Technologies, Inc. DATES REPORT 3310 Win St. ENVIRONMENTALTECHN❑LOG1ES,1rJG Cuyahoga Falls, Ohio44223 WO#: 20121121 ArWyft cal tai5oralonas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 30 Dee-20 Client: Synagro Project: Randelman - REVISED Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 20121121-OOIA Randleman WWTP 12/16/2020 11:15:00 AM Sludge Ignitability of Solids (SW-846: 1030) 12/29/2020 3:03:57 PM pH (SW9045D) 12/22/2020 11:31:06 AM Reactive Cyanide (9014/7.3.32)-Solid 12/21/2020 2:38:00 PM Reactive Sulfide (9034)/7.3.42 12/21/2020 2:38:00 PM TCLP Herbicides by EPA 8321B 12/22/2020 5:00:00 PM 12/24/2020 11:39:00 AM TCLP Mercury Analysis (SW1311/74712/22/2020 5:00:00 PM 12/28/2020 9:40:00 AM 12/28/2020 4:16:00 PM TCLP Metals Analysis (SW1311/6010' 12/22/2020 5:00:00 PM 12/23/2020 12:25:00 P 12/23/2020 6:12:07 PM TCLP Pesticides Analysis (SW1311/8(12/22/2020 5:00:00 PM 12/22/2020 12:00:00 P 12/23/2020 6:47:00 PM �R TCLP Pesticides Analysis (SW1311/8(12/22/2020 5:00:00 PM 12/22/2020 12:00:00 P �R 12/23/2020 6:47:00 PM TCLP Semi-Volatiles Analysis 12/22/2020 5:00:00 PM 12/23/2020 12:00:00 P 12/23/2020 7:30:00 PM (SW1311/8270) — TCLP Volatiles Analysis 12/22/2020 5:00:00 PM 12/24/2020 7:28:00 AM Revision v 1 Page 5 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 20121121 Date Reported: 12/30/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 12/16/2020 11:15:00 AM Lab ID: 20121121-OOIA Project: Randelman - REVISED Client Sample ID Randleman WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.00500 mg/L SW7470A SW7470A Analyst: ERA 1 12/28/2020 4:16:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW301OA Analyst: EAM TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND 0.500 mg/L 1 12/23/2020 6:12:07 PM TCLP Barium(Ba) ND 5.00 mg/L 1 12/23/2020 6:12:07 PM TCLP Cadmium(Cd) ND 0.100 mg/L 1 12/23/2020 6:12:07 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 12/23/2020 6:12:07 PM TCLP Lead(Pb) ND 0.500 mg/L 1 12/23/2020 6:12:07 PM TCLP Selenium(Se) ND 0.0500 mg/L 1 12/23/2020 6:12:07 PM TCLP Silver(Ag) ND 0.500 mg/L 1 12/23/2020 6:12:07 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW351OC Analyst: SFG TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.200 mg/L 2 12/23/2020 7:30:00 PM 2,4,5-Trichlorophenol ND 0.500 mg/L 2 12/23/2020 7:30:00 PM 2,4,6-Trichlorophenol ND 0.500 mg/L 2 12/23/2020 7:30:00 PM 2,4-Dinitrotoluene ND 0.100 mg/L 2 12/23/2020 7:30:00 PM Cresols, Total ND 10.0 mg/L 2 12/23/2020 7:30:00 PM Hexachloro-1,3-butadiene ND 0.0400 mg/L 2 12/23/2020 7:30:00 PM Hexachlorobenzene ND 0.100 mg/L 2 12/23/2020 7:30:00 PM Hexachloroethane ND 0.200 mg/L 2 12/23/2020 7:30:00 PM Nitrobenzene ND 0.200 mg/L 2 12/23/2020 7:30:00 PM Pentachlorophenol ND 0.500 mg/L 2 12/23/2020 7:30:00 PM Pyridine ND 0.500 mg/L 2 12/23/2020 7:30:00 PM Surr: 2-Fluorophenol 78.7 10 - 157 m %Rec 2 12/23/2020 7:30:00 PM Surr: Phenol-d6 79.0 10 - 169 %Rec 2 12/23/2020 7:30:00 PM Surr: Nitrobenzene-d5 92.8 32.1 - 130 %Rec 2 12/23/2020 7:30:00 PM Surr: 2,4,6-Tribromophenol 110 45.4 - 166 %Rec 2 12/23/2020 7:30:00 PM Surr: 2-Fluorobiphenyl 100 35.7 - 130 %Rec 2 12/23/2020 7:30:00 PM Surr: p-Terphenyl-d14 126 74.7 - 145 %Rec 2 12/23/2020 7:30:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Revision vl RL Reporting Detection Limit U Samples with CalcVal <MDL Page 6 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 20121121 Date Reported: 12/30/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 12/16/2020 11:15:00 AM Lab ID: 20121121-OOIA Project: Randelman - REVISED Client Sample ID Randleman WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW351OC Analyst: CSS TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.0250 mg/L 1 12/23/2020 6:47:00 PM Toxaphene ND 0.0500 mg/L 1 12/23/2020 6:47:00 PM Endrin ND 0.00250 mg/L 1 12/23/2020 6:47:00 PM gamma-BHC ND 0.00250 mg/L 1 12/23/2020 6:47:00 PM Heptachlor ND 0.00250 mg/L 1 12/23/2020 6:47:00 PM Heptachlor epoxide ND 0.00250 mg/L 1 12/23/2020 6:47:00 PM Methoxychlor ND 0.00250 mg/L 1 12/23/2020 6:47:00 PM Surr: TCMX 81.5 10 - 119 %Rec 1 12/23/2020 6:47:00 PM Surr: DCB 93.3 10 - 119 %Rec 1 12/23/2020 6:47:00 PM TCLP HERBICIDES BY EPA 8321B SW8321A Analyst: TM 2,4-D ND 1.00 mg/L 100 12/24/2020 11:39:00 AM 2,4,5-TP ND 1.00 mg/L 100 12/24/2020 11:39:00 AM Surr: 2,4-Dichlorophenylacetic aci 93.7 70 - 130 %Rec 100 12/24/2020 11:39:00 AM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 SW1311M Analyst: SLV TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.250 mg/L 50 12/24/2020 7:28:00 AM 1,2-Dichloroethane ND 0.250 mg/L 50 12/24/2020 7:28:00 AM MEK ND 5.00 mg/L 50 12/24/2020 7:28:00 AM Benzene ND 0.250 mg/L 50 12/24/2020 7:28:00 AM Carbon tetrachloride ND 0.250 mg/L 50 12/24/2020 7:28:00 AM Chlorobenzene ND 2.50 mg/L 50 12/24/2020 7:28:00 AM Chloroform ND 0.250 mg/L 50 12/24/2020 7:28:00 AM Tetrachloroethene ND 0.250 mg/L 50 12/24/2020 7:28:00 AM Trichloroethene ND 0.250 mg/L 50 12/24/2020 7:28:00 AM Vinyl chloride ND 0.100 mg/L 50 12/24/2020 7:28:00 AM Surr: 4-Bromofluorobenzene 97.5 70 - 130 %Rec 50 12/24/2020 7:28:00 AM Surr: Di brom oft uorom ethane 102 70 - 130 %Rec 50 12/24/2020 7:28:00 AM Surr: Toluene-d8 101 70 - 130 %Rec 50 12/24/2020 7:28:00 AM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Revision vl RL Reporting Detection Limit U Samples with CalcVal <MDL Page 7 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGlr,$.IRC Cuyahoga Falls, Ohio 44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 20121121 Date Reported: 12/30/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 12/16/2020 11:15:00 AM Lab ID: 20121121-OOIA Project: Randelman - REVISED Client Sample ID Randleman WWTP Analyses Result RL Qual Units DF Date Analyzed RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.490 mg/Kg 1 12/21/2020 2:38:00 PM IGNITABILITY OF SOLIDS (SW-846: 1030) SW1030 Analyst: CXS Ignitability nonflammable mm/sec 1 12/29/2020 3:03:57 PM RCI SW9045D Analyst: VVK PH (SW9045D) pH 7.0 s.u.@20.3C 1 12/22/2020 11:31:06 AM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive 30.0 25.0 mg/Kg 1 12/21/2020 2:38:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Revision vl U Samples with CalcVal <MDL Page 8 of 39 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal tes Report Y ENOROMMEWAL IrECHNOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 Y ArralyVcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20121121 Wehsite: http://www.settek.com 30 Dec-20 Client: Synagro State: NW Project: Randelman - REVISED Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 20121121-OOIA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.32)-Solid Cyanide, Reactive N Sludge Reactive Sulfide (9034)/7.3.42 Sulfide, Reactive N Sludge TCLP Herbicides by EPA 832113 2,4,5-TP A Sludge TCLP Herbicides by EPA 832113 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Key Key NC WW SCM A Accredited NC WW SCM N Not Accredited Version #2 Page 9 of 39 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal tes Report Y EMOROMMEWAL YECHNOWGIES, INC, Cuyahoga Falls, Ohio 44223 Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20121121 Wehsite: http://www.settek.com 30 Dec-20 Client: Synagro State: NW Project: Randelman - REVISED Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 20121121-OOIA Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM N Not Accredited Version #2 Page 10 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20121121 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46981 Sample ID: 20121120-001ams SampType: MS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 12/22/2020 RunNo: 121733 Client ID: Batch= Batch ID: 46981 TestNo: SW8081 SW3510C Analysis Date: 12/22/2020 SegNo: 3131109 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00850 0.000500 0.0100 0 85.0 10 224 gamma-BHC 0.00791 0.000500 0.0100 0 79.1 10 192 Heptachlor 0.00851 0.000500 0.0100 0 85.1 10 197 Heptachlor epoxide 0.00897 0.000500 0.0100 0 89.7 10 208 Methoxychlor 0.00937 0.000500 0.0100 0 93.7 10 251 Surr: TCMX 13.5 20.00 67.7 10 157 Surr: DCB 16.0 20.00 80.0 10 194 Sample ID: 20121120-001amsd SampType: MSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: 12/22/2020 RunNo: 121733 Client ID: Batch= Batch ID: 46981 TestNo: SW8081 SW3510C Analysis Date: 12/22/2020 SegNo: 3131110 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00950 0.000500 0.0100 0 95.0 10 224 0.00850 11.0 30 gamma-BHC 0.00858 0.000500 0.0100 0 85.8 10 192 0.00791 8.12 30 Heptachlor 0.00932 0.000500 0.0100 0 93.2 10 197 0.00851 9.09 30 Heptachlor epoxide 0.00997 0.000500 0.0100 0 99.7 10 208 0.00897 10.5 30 Methoxychlor 0.0106 0.000500 0.0100 0 106 10 251 0.00937 12.2 30 Surr: TCMX 14.0 20.00 70.0 10 157 0 Surr: DCB 17.6 20.00 87.9 10 194 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 11 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20121121 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46981 Sample ID: LCS-46981 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 12/22/2020 RunNo: 121733 Client ID: LCSS Batch ID: 46981 TestNo: SW8081 SW3510C Analysis Date: 12/22/2020 SegNo: 3131111 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00926 0.000500 0.0100 0 92.6 10 130 gamma-BHC 0.00856 0.000500 0.0100 0 85.6 10 130 Heptachlor 0.00878 0.000500 0.0100 0 87.8 10 130 Heptachlor epoxide 0.00961 0.000500 0.0100 0 96.1 10 130 Methoxychlor 0.0102 0.000500 0.0100 0 102 10 178 Surr: TCMX 14.9 20.00 74.4 10 130 Surr: DCB 17.6 20.00 88.0 10 130 Sample ID: MB-46981 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 12/22/2020 RunNo: 121733 Client ID: PBS Batch ID: 46981 TestNo: SW8081 SW3510C Analysis Date: 12/22/2020 SegNo: 3131112 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 gamma-BHC ND 0.000500 Heptachlor ND 0.000500 Heptachlor epoxide ND 0.000500 Methoxychlor ND 0.000500 Surr: TCMX 13.8 20.00 68.9 10 119 Surr: DCB 16.6 20.00 83.2 10 119 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46992 Sample ID: 20121117-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121888 lient ID: BatchQC Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/28/2020 SegNo: 3136399 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 1.92 0.500 2.00 0 96.0 13.6 202 1,2-Dichloroethane 1.83 0.500 2.00 0 91.3 55.7 138 MEK ND 10.0 10.0 0 90.5 65.3 118 Benzene 1.85 0.500 2.00 0 92.7 49.2 145 Carbon tetrachloride 2.12 0.500 2.00 0 106 26.7 156 Chlorobenzene ND 5.00 2.00 0 94.1 33.7 159 Chloroform 1.92 0.500 2.00 0 96.0 48.5 145 Tetrachloroethene 1.89 0.500 2.00 0 94.6 19.2 191 Trichloroethene 1.85 0.500 2.00 0 92.5 38.4 167 Vinyl chloride 2.13 0.200 2.00 0 107 27.3 161 Surr:4-Bromofluorobenzene 4990 5000 99.8 70 130 Surr: Dibromofluoromethane 5110 5000 102 70 130 Surr: Toluene-d8 5020 5000 100 70 130 Sample ID: 20121117-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121888 lient ID: BatchQC Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/28/2020 SegNo: 3136400 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 1.97 0.500 2.00 0 98.3 13.6 202 1.92 2.32 25 1,2-Dichloroethane 1.86 0.500 2.00 0 93.2 55.7 138 1.83 2.06 25 MEK ND 10.0 10.0 0 92.6 65.3 130 0 0 25 Benzene 1.90 0.500 2.00 0 95.2 49.2 145 1.85 2.61 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 13 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46992 Sample ID: 20121117-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121888 lient ID: BatchQC Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/28/2020 SegNo: 3136400 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 2.20 0.500 2.00 0 110 26.7 156 2.12 3.75 25 Chlorobenzene ND 5.00 2.00 0 96.2 33.7 159 0 0 25 Chloroform 1.97 0.500 2.00 0 98.5 48.5 145 1.92 2.57 25 Tetrachloroethene 1.94 0.500 2.00 0 97.2 19.2 191 1.89 2.66 25 Trichloroethene 1.91 0.500 2.00 0 95.6 38.4 167 1.85 3.35 25 Vinyl chloride 2.28 0.200 2.00 0 114 27.3 161 2.13 6.84 25 Surr:4-Bromofluorobenzene 4990 5000 99.8 70 130 0 25 Surr: Dibromofluoromethane 5120 5000 102 70 130 0 25 Surr: Toluene-d8 5030 5000 101 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46992 Sample ID: MB-46992 SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: 12/22/2020 RunNo: 121812 Client ID: PBS Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/24/2020 SegNo: 3134102 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.250 1,2-Dichloroethane ND 0.250 MEK ND 5.00 Benzene ND 0.250 Carbon tetrachloride ND 0.250 Chlorobenzene ND 2.50 Chloroform ND 0.250 Tetrachloroethene ND 0.250 Trichloroethene ND 0.250 Vinyl chloride ND 0.100 Surr: 4-Bromofluorobenzene 2400 Surr: Dibromofluoromethane 2510 Surr: Toluene-d8 2480 2500 96.0 70 130 2500 100 70 130 2500 99.2 70 130 Sample ID: LCS-46992 SampType: LCS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121812 Client ID: LCSS Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/24/2020 SegNo: 3134103 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.986 0.250 1.00 0 98.6 64.7 136 1,2-Dichloroethane 0.930 0.250 1.00 0 93.0 70 130 MEK ND 5.00 5.00 0 92.1 55.1 149 Benzene 0.954 0.250 1.00 0 95.4 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46992 Sample ID: LCS-46992 SampType: LCS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121812 lient ID: LCSS Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/24/2020 SegNo: 3134103 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 1.06 0.250 1.00 0 106 70 130 Chlorobenzene ND 2.50 1.00 0 98.9 70 130 Chloroform 0.987 0.250 1.00 0 98.7 70 130 Tetrachloroethene 0.984 0.250 1.00 0 98.4 70 134 Trichloroethene 0.972 0.250 1.00 0 97.2 62.8 160 Vinyl chloride 1.10 0.100 1.00 0 110 67.1 130 Surr:4-Bromofluorobenzene 2500 2500 100 70 130 Surr: Dibromofluoromethane 2540 2500 102 70 130 Surr: Toluene-d8 2510 2500 100 70 130 Sample ID: 20121123-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121812 lient ID: Batch= Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/24/2020 SegNo: 3134111 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.946 0.250 1.00 0 94.6 13.6 202 1,2-Dichloroethane 0.896 0.250 1.00 0 89.6 55.7 138 MEK ND 5.00 5.00 0 90.8 65.3 118 Benzene 0.932 0.250 1.00 0 93.2 49.2 145 Carbon tetrachloride 1.05 0.250 1.00 0 105 26.7 156 Chlorobenzene ND 2.50 1.00 0 95.6 33.7 159 Chloroform 0.957 0.250 1.00 0 95.7 48.5 145 Tetrachloroethene 0.936 0.250 1.00 0 93.6 19.2 191 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46992 Sample ID: 20121123-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121812 lient ID: BatchQC Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/24/2020 SegNo: 3134111 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Trichloroethene 0.953 0.250 1.00 0 95.3 38.4 167 Vinyl chloride 1.12 0.100 1.00 0 112 27.3 161 Surr:4-Bromofluorobenzene 2510 2500 100 70 130 Surr: Dibromofluoromethane 2540 2500 102 70 130 Surr: Toluene-d8 2510 2500 101 70 130 Sample ID: 20121123-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121812 lient ID: BatchQC Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/24/2020 SegNo: 3134112 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.983 0.250 1.00 0 98.2 13.6 202 0.946 3.79 25 1,2-Dichloroethane 0.944 0.250 1.00 0 94.4 55.7 138 0.896 5.22 25 MEK ND 5.00 5.00 0 97.4 65.3 130 0 0 25 Benzene 0.975 0.250 1.00 0 97.5 49.2 145 0.932 4.51 25 Carbon tetrachloride 1.07 0.250 1.00 0 107 26.7 156 1.05 1.98 25 Chlorobenzene ND 2.50 1.00 0 98.9 33.7 159 0 0 25 Chloroform 0.995 0.250 1.00 0 99.5 48.5 145 0.957 3.89 25 Tetrachloroethene 0.976 0.250 1.00 0 97.6 19.2 191 0.936 4.08 25 Trichloroethene 0.974 0.250 1.00 0 97.4 38.4 167 0.953 2.18 25 Vinyl chloride 1.15 0.100 1.00 0 115 27.3 161 1.12 2.91 25 Surr:4-Bromofluorobenzene 2490 2500 99.7 70 130 0 25 Surr: Dibromofluoromethane 2570 2500 103 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46992 Sample ID: 20121123-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 121812 Client ID: Batch= Batch ID: 46992 TestNo: SW8260 SW1311M Analysis Date: 12/24/2020 SegNo: 3134112 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr: Toluene-d8 2540 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 2500 102 70 130 0 25 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46996 Sample ID: 20121280-001AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 12/23/2020 RunNo: 121831 lient ID: BatchQC Batch ID: 46996 TestNo: SW8270 SW3510C Analysis Date: 12/24/2020 SegNo: 3134706 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.517 0.200 0.8000 0 64.7 33.8 126 2,4,5-Trichlorophenol 0.788 0.500 0.8000 0 98.5 28.7 144 2,4,6-Trichlorophenol 0.771 0.500 0.8000 0 96.4 12.8 153 2,4-Dinitrotoluene 0.752 0.100 0.8000 0 94.0 20.4 155 o-Cresol 0.620 0.500 0.8000 0 77.5 10 148 Cresols, Total ND 10.0 1.600 0 78.0 10 148 Hexachloro-1,3-butadiene 0.532 0.0400 0.8000 0 66.5 29 130 Hexachlorobenzene 0.715 0.100 0.8000 0 89.4 33.7 134 Hexachloroethane 0.467 0.200 0.8000 0 58.4 32.8 132 Nitrobenzene 0.563 0.200 0.8000 0 70.4 20 158 Pentachlorophenol 0.771 0.500 0.8000 0 96.4 10 176 Pyridine ND 0.500 0.8000 0 28.7 10 130 Surr:2-Fluorophenol 0.704 1.000 70.4 3.39 130 Surr: Phenol-d6 0.814 1.000 81.4 5 130 Surr: Nitrobenzene-d5 0.730 1.000 73.0 14.5 154 Surr: 2,4,6-Tribromophenol 1.01 1.000 101 19.5 130 Surr:2-Fluorobiphenyl 0.846 1.000 84.6 34.4 130 Surr: p-Terphenyl-d14 1.10 1.000 110 8.86 156 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits mQC+ E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Randelman - REVISED BatchID: 46996 WO#: 20121121 30-Dec-20 Sample ID: 20121280-001AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 12/23/2020 RunNo: 121831 Dient ID: Batch= Batch ID: 46996 TestNo: SW8270 SW3510C Analysis Date: 12/24/2020 SegNo: 3134707 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.635 0.200 0.8000 0 79.4 33.8 126 0.5172 20.5 30 2,4,5-Trichlorophenol 0.870 0.500 0.8000 0 109 28.7 144 0.7880 9.89 30 2,4,6-Trichlorophenol 0.877 0.500 0.8000 0 110 12.8 153 0.7708 12.9 30 2,4-Dinitrotoluene 0.825 0.100 0.8000 0 103 20.4 155 0.7520 9.28 30 o-Cresol 0.738 0.500 0.8000 0 92.2 10 148 0.6200 17.4 30 Cresols, Total ND 10.0 1.600 0 92.3 10 148 0 0 30 Hexachloro-1,3-butadiene 0.648 0.0400 0.8000 0 81.0 29 130 0.5320 19.7 30 Hexachlorobenzene 0.776 0.100 0.8000 0 97.0 33.7 134 0.7152 8.10 30 Hexachloroethane 0.584 0.200 0.8000 0 73.0 32.8 132 0.4672 22.2 30 Nitrobenzene 0.672 0.200 0.8000 0 84.0 20 158 0.5632 17.6 30 Pentachlorophenol 0.827 0.500 0.8000 0 103 10 176 0.7708 7.01 30 Pyridine ND 0.500 0.8000 0 35.4 10 130 0 0 30 mQC+ Surr:2-Fluorophenol 0.870 1.000 87.0 3.39 130 0 Surr: Phenol-d6 0.978 1.000 97.8 10 130 0 Surr: Nitrobenzene-d5 0.870 1.000 87.0 14.5 154 0 Surr: 2,4,6-Tribromophenol 1.11 1.000 ill 19.5 130 0 Surr:2-Fluorobiphenyl 0.932 1.000 93.2 34.4 130 0 Surr: p-Terphenyl-dl4 1.23 1.000 123 8.86 156 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 20 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46996 Sample ID: MB-46996 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 12/23/2020 RunNo: 121785 lient ID: PBS Batch ID: 46996 TestNo: SW8270 SW3510C Analysis Date: 12/23/2020 SegNo: 3133120 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.764 Surr: Phenol-d6 0.729 Surr: Nitrobenzene-d5 0.761 Surr: 2,4,6-Tribromophenol 0.852 Surr: 2-Fluorobiphenyl 0.840 Surr: p-Terphenyl-d14 1.03 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 1.000 76.4 10 130 1.000 72.9 10 130 1.000 76.1 19 130 1.000 85.2 10 130 1.000 84.0 22 130 1.000 103 34 130 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 21 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 46996 Sample ID: LCS-46996 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 12/23/2020 RunNo: 121785 lient ID: LCSS Batch ID: 46996 TestNo: SW8270 SW3510C Analysis Date: 12/23/2020 SegNo: 3133121 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.576 0.100 0.8000 0 72.0 36.4 130 2,4,5-Trichlorophenol 0.689 0.250 0.8000 0 86.2 31.7 132 2,4,6-Trichlorophenol 0.681 0.250 0.8000 0 85.1 31.1 133 2,4-Dinitrotoluene 0.703 0.0500 0.8000 0 87.9 43.3 130 o-Cresol 0.642 0.250 0.8000 0 80.2 32.9 130 Cresols, Total ND 5.00 1.600 0 81.5 31.7 130 Hexachloro-1,3-butadiene 0.560 0.0200 0.8000 0 70.0 31.4 130 Hexachlorobenzene 0.717 0.0500 0.8000 0 89.7 43.1 130 Hexachloroethane 0.553 0.100 0.8000 0 69.1 36.5 130 Nitrobenzene 0.636 0.100 0.8000 0 79.5 39.5 130 Pentachlorophenol 0.791 0.250 0.8000 0 98.9 34 130 Pyridine ND 0.250 0.8000 0 21.6 10 130 Surr: 2-Fluorophenol 0.779 1.000 77.9 17.1 130 Surr: Phenol-d6 0.744 1.000 74.4 10 130 Surr: Nitrobenzene-d5 0.724 1.000 72.4 32.6 130 Surr:2,4,6-Tribromophenol 0.945 1.000 94.5 4.43 130 Surr:2-Fluorobiphenyl 0.818 1.000 81.8 41.8 130 Surr: p-Terphenyl-d14 1.08 1.000 108 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits m E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 47002 Sample ID: TCLP BLANK 12-24- SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 12/24/2020 RunNo: 121855 lient ID: PBS Batch ID: 47002 TestNo: SW6010D SW3010A Analysis Date: 12/28/2020 SegNo: 3135349 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 23 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 47002 Sample ID: MB-47002 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 12/23/2020 RunNo: 121731 Client ID: PBS Batch ID: 47002 TestNo: SW6010D SW3010A Analysis Date: 12/23/2020 SegNo: 3132362 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: LCS-47002 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 12/23/2020 RunNo: 121731 Client ID: LCSS Batch ID: 47002 TestNo: SW6010D SW3010A Analysis Date: 12/23/2020 SegNo: 3132363 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.95 0.500 2.000 0 97.7 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 98.4 80 120 TCLP Cadmium(Cd) 1.89 0.100 2.000 0 94.7 80 120 TCLP Chromium(Cr) 1.98 0.200 2.000 0 98.9 80 120 TCLP Lead(Pb) 1.99 0.500 2.000 0 99.3 80 120 TCLP Selenium(Se) 1.94 0.0500 2.000 0 97.1 80 120 TCLP Silver(Ag) 1.96 0.500 2.000 0 98.1 80 120 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 24 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 47002 Sample ID: TCLP BLANK 1 12-2 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 12/23/2020 RunNo: 121731 lient ID: PBS Batch ID: 47002 TestNo: SW6010D SW3010A Analysis Date: 12/23/2020 SegNo: 3132364 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: TCLP BLANK 2 12-2 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 12/23/2020 RunNo: 121731 lient ID: PBS Batch ID: 47002 TestNo: SW6010D SW3010A Analysis Date: 12/23/2020 SegNo: 3132365 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 25 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20121121 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 47002 Sample ID: 20121288-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 12/23/2020 RunNo: 121731 Client ID: Batch= Batch ID: 47002 TestNo: SW6010D SW3010A Analysis Date: 12/23/2020 SegNo: 3132384 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.01 0.500 2.000 0.03037 99.1 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.3891 81.5 70 130 TCLP Cadmium(Cd) 1.73 0.100 2.000 0.003133 86.6 70 130 TCLP Chromium(Cr) 1.67 0.200 2.000 0 83.6 70 130 TCLP Lead(Pb) 1.54 0.500 2.000 0 77.1 70 130 TCLP Selenium(Se) 2.14 0.0500 2.000 0.1040 102 70 130 TCLP Silver(Ag) 1.86 0.500 2.000 0 93.0 70 130 Sample ID: 20121288-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 12/23/2020 RunNo: 121731 Client ID: Batch= Batch ID: 47002 TestNo: SW6010D SW3010A Analysis Date: 12/23/2020 SegNo: 3132385 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.00 0.500 2.000 0.03037 98.7 70 130 2.013 0.445 20 TCLP Barium(Ba) ND 5.00 2.000 0.3891 80.7 70 130 0 0 20 TCLP Cadmium(Cd) 1.72 0.100 2.000 0.003133 85.8 70 130 1.735 0.903 20 TCLP Chromium(Cr) 1.66 0.200 2.000 0 83.0 70 130 1.673 0.711 20 TCLP Lead(Pb) 1.52 0.500 2.000 0 76.1 70 130 1.542 1.33 20 TCLP Selenium(Se) 2.16 0.0500 2.000 0.1040 103 70 130 2.141 0.688 20 TCLP Silver(Ag) 1.85 0.500 2.000 0 92.6 70 130 1.860 0.361 20 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 26 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20121121 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 47029 TCLP Mercury ND 0.00200 TCLP Mercury 0.00389 0.00200 0.00400 0 97.2 80 120 TCLP Mercury 0.00389 0.00200 0.00400 0 97.2 75 125 Sample ID: 20121404-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 12/28/2020 RunNo: 121864 Client ID: Batch= Batch ID: 47029 TestNo: SW7470A SW7470A Analysis Date: 12/28/2020 SegNo: 3135864 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00395 0.00200 0.00400 0 98.8 75 125 0.00389 1.53 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 27 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: 47029 TCLP Mercury ND 0.00200 TCLP Mercury ND 0.00200 Sample ID: TCLP Blank2 12-22- SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 12/28/2020 RunNo: 121864 Client ID: PBS Batch ID: 47029 TestNo: SW7470A SW7470A Analysis Date: 12/28/2020 SegNo: 3135970 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.00200 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 28 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121658 Sample ID: CHECK 7 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@20.6C Prep Date: RunNo: 121658 Client ID: LCSS Batch ID: R121658 TestNo: SW9045D Analysis Date: 12/22/2020 SegNo: 3129603 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 7.0 0 101 90 110 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 29 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121658 Sample ID: 20121292-001ADUP SampType: DUP TestCode: pH_Oil(9045D Units: s.u.@20.3C Prep Date: RunNo: 121658 lient ID: BatchQC Batch ID: R121658 TestNo: SW9045D Analysis Date: 12/22/2020 SegNo: 3129871 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.5 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 0 0 6.5 0.3 10 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 30 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20121121 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121658 pH 7.0 7.0 0 100 98.6 101.4 pH 6.9 7.0 0.3 5 H Sample ID: CHECK 7 SampType: LCS TestCode: pH_NPW(450 Units: s.u.@20.4C Prep Date: RunNo: 121658 Client ID: LCSW Batch ID: R121658 TestNo: SW9045D Analysis Date: 12/22/2020 SegNo: 3129878 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 98.6 101.4 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 31 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Wm St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20121121 4rrafyt�cal iaboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121675 Sulfide, Reactive ND 25.0 Sulfide, Reactive 3020 25.0 3080 0 98.1 85 115 Sulfide, Reactive 2980 25.0 3080 0 96.8 80 120 Sample ID: 20121170-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 121675 Client ID: Batch= Batch ID: R121675 TestNo: SW9034 Analysis Date: 12/21/2020 SegNo: 3129630 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 2860 25.0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 3080 0 92.9 80 120 2980 4.11 30 E Value above quantitation range H Holding times for preparation or anal} M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 32 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121675 Sample ID: 20121170-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 121675 lient ID: BatchQC Batch ID: R121675 TestNo: SW9034 Analysis Date: 12/21/2020 SegNo: 3129630 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 33 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Wm St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20121121 4rrafyt�cal iaboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121688 Cyanide, Reactive ND 0.500 Cyanide, Reactive 9.43 0.500 10.00 0 94.3 85 115 Cyanide, Reactive 0.528 0.500 0.5000 0 106 65 135 Sample ID: 20121170-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 121688 Client ID: Batch= Batch ID: R121688 TestNo: SW9014 Analysis Date: 12/21/2020 SegNo: 3129973 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.71 0.472 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 10.00 0 87.1 75 125 E Value above quantitation range H Holding times for preparation or anal} M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 34 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20121121 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121688 Sample ID: 20121170-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 121688 Client ID: Batch= Batch ID: R121688 TestNo: SW9014 Analysis Date: 12/21/2020 SegNo: 3129973 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 20121170-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 121688 Client ID: Batch= Batch ID: R121688 TestNo: SW9014 Analysis Date: 12/21/2020 SegNo: 3129974 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.41 0.500 10.00 0 94.1 75 125 8.706 7.78 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 35 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20121121 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121832 Sample ID: MB SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 121832 Client ID: PBS Batch ID: R121832 TestNo: SW8321A Analysis Date: 12/23/2020 SegNo: 3136111 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D ND 0.0100 2,4,5-TP ND 0.0100 Surr: 2,4-Dichlorophenylacetic acid 1.02 1.000 102 70 130 Sample ID: LCS SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 121832 Client ID: LCSS Batch ID: R121832 TestNo: SW8321A Analysis Date: 12/24/2020 SegNo: 3136112 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.358 0.0100 0.3000 0 119 60.5 141 2,4,5-TP 0.326 0.0100 0.3000 0 109 68.3 144 Surr: 2,4-Dichlorophenylacetic acid 3.07 3.000 102 70 130 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 36 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20121121 30-Dec-20 Client: Synagro Project: Randelman - REVISED BatchID: R121916 Sample ID: LCS-R121916 SampType: LCS TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 121916 Client ID: LCSS Batch ID: R121916 TestNo: SW1030 Analysis Date: 12/29/2020 SegNo: 3137049 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability 8.33 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 7.240 0 115 70 130 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound ReVlslon V 1 P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 37 of 39 (Q CD W 00 0 W co I5CbC336 Rsv, 4-; SUMMIT Analysis Request 1 dann of Custody ENVIRONMENTAL TEC"NOWOIES. INC. 3310 VAd 5"4s Refer to Terms Itud Cp� at *ww-detteiccom cPI,Pr"40 h,u,, O*D 4422a •� PVv- rjjn,��- ! Cticu 1'fame ���' p11�ECt�CYtIaL4�� Z �rj' V y dp O.W AJ.kxw +a1aSr 91riCl Addrns -� - ;w { d - -� as r lCSVi 91me Nt- zip ZV4 cily p stsu N yap 2131 "0 Mac PYooa��� } C7 14 ' G C.Mid lA�i�D PO Q.�o.r�l�a�r 4 GCeMEEmdlAddrm FW51D FwdlltyED r �', . dAvieSkdKrel S+emrpplWedahaytX(rrM+nlNh rdqw >t dvt�meu4l0id Prtl �awwo Sri! //A hi.YAA�P s8PAPbrGY DrWay w■ra C..Wai ., ` - �_"'� J" Lwe t9FtF& klryj% Ub May Otb-Cempldwt(LFaSUWPrNrzm) R pa$ Q. *ply: si .' #•-- '..&hipll�AlrlSD' - Srlaeplridrndi[ratl4a Old*•' Cdkned Tbw cailegfs�A kAf 1UX l AJ W i� kq # tI XS L U 1 i cffoqudebed b*: I -Dats Tim 1welved by: ullre a rrme J.Kyo {rsP+ rAhl 11 1 z 1111 av JV-DD - - Far FJi=Ct c 174ie.1"1/2013 Page I of 1 bu. Rf40fl�! •- Aftly#cal Parameters and Methods requested - WAS 1cwufdeuee: $olfcient solidus provided to run lQi 4FS EINQ CookrF S []NO RwtvLd Summit by: Ads Time cam Bush Requested: Day[s) Rw&ed Temps D mEr Coataiuer. A� 10292 Must be approwd by Lab Mawger � c' Ice PrawfY �FS �1WQ [:]MELTEDlVi Page '1 of 1 tr ' "'- Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGa1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.coin Client Name: SYN-NC-27028 Work Order Number: 20121121 RcptNo: 1 Logged by: Christina N. Jager 12/18/2020 10:20:00 AMr' Completed By: Christina N. Jager 12/18/2020 12:50:07 PMdrx Reviewed By: Jennifer Woolf 12/18/20201:25:11 PM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? FedEx Lop In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes V No ❑ 15. Is it clear what analyses were requested? Yes 0 No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 10.6 Goodl Not Present Page 39 of 39 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Randleman WWTP WQ Permit Number: WQ 0004825 WWTP Name: Town of Randleman WWTP NPDES Number: NC 0025445 Monitoring Period: From 01/01/20 To 12/31/2020 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) All. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens X If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization X Air Drying Composting Aerobic Digestion Anaerobic Digestion Parameter Allowable Level in Sludge Pathogen Density No. of Excee- Frequency of Sample Type Analytical Technique Minimum Geo, Mean Maximum Units dences Analysis Fecal 2x10 to the 61h MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt_ 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) X (Drying — Stable) (Drying — Unstable) Option/Alt. 9 (Injection) Option/Alt. 10 (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an _ explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Michael Glass, Plant Superintendent Preparer Name and Title ( type or print) Signature of Preparer* Date Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) CLASS 33/1'W pH LONG SHEET Using a pH Meter with Two -Point Standardization and Automatic Temperature Compensation (ATC) Probe Analysis Method: SW-846/lMethod 9045D, Soil And Waste pH MONTIVYEAR: Meg + � o FACILITY/LOCATION: gaiz ' it ll--zl SAMPLING LOCATION h Z I uifial pH 12.0 S.U. 2 Hour PH 12.0 S.U. 24 Hour pR ?:11.5 S.U. w � R ° x O � s Q. � w � � Initial p�lsu Temp/°C Adjusted initial PH /su � � � �ryry ti b � n y .� 2-Hr :� /su P° Templ C Adjusted 3 2-]3[r * PH !su �' � g g � �, � � � N - � ` � �' � bppd{ 24-Hr E/su P Temp!°C Adjusted 24-Idi' P H*Isu 5--F5- 13co\ \2 ay q VL . ©,9 1'2 00 SSa �f 95 ' 1_2. / t ie. Zs°C. 12, o�, A69 1 i2.� 258E IZ.�� 3S ®�3z 11H3 �535 "` �:CjllIValBlltpl-1 Yc`1,LA0 aL'L�"l:� 1i01TECLlOIll"a.000T �l.t'J = V.VJ �� uuiw 7: � 1. lvluyGlA��.uG.uiccww.viuv.��—�.✓ v�� .0 1.............� yam.. Continents: -23- SECTION 6 Agricultural Lime Application Log Year: 2020 Project: Randleman Field (state -county -site -field code) 11 Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied 11 Date Applied RDA 8-3 6.7 0.0 tons/ac. RDA 9-1 6.9 0.0 tons/ac. RDA 9-2 63 0.0 tons/ac. RDA 9-3 6.5 0.0 tons/ac. SECTION 7 Page 1 of 1 Report No: 19-397-0511 Account No: 07216 Advisor: Synagro Central LLC/ Durham Mary Brewer 284 Boger Road Mocksville NC 27028 Waypointo ANALYTICAL Client: Howard Fields 2850 Daisy Lane, Wilson, NC 27896 Main 252-206-1721 ° Fax 252-206-9973 www.waypointanalytical.com Farm: RD-18 Submitted By: Synagro Central LLC/ Durham Date Received: 0 1 /19/2021 Date of Report: 01/21/2021 Lab No Field ID Sample ID Soil Class HM% WN pH Ac P-1 K-1 S-1 Mn-I Zn-1 Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na SS-1 NO3 N 21355 Fld 3 RD-18-3 MIN 0.4 6.7 70.0 127 21 54 525 308 301 210 82.1 13 27 3 1.1 0.1 Comment Test result units = CEC and Na in meq/100cm3; NO3-N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Carolina, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL017507 Client: Chris Holder Advisor: Ryan Copeland vo- Predictive 4660 Randolph Church Rd SYNAGRO Liberty, NC 27298 284 Boger Road .'..,$' Soil Report Mehlich-3 Extraction Mocksville, NC27028 Sampled County: Randolph Links to Helpful Information Client ID: 365867 Advisor ID: 499503 Sampled: Received: 11/25/2020 Completed: 01/13/2021 Farm: RD-19 Sample ID: RD191 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.46 1.01 11.5 93 0.8 6.9 156 37 81 10 44 696 421 470 470 387 0.1 1 Sample ID: RD192 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.51 0.97 9.7 91 0.9 6.6 73 91 74 13 47 988 600 261 261 265 0.1 1 Sample ID: RD193 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 60 0 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.60 0.96 9.9 91 0.9 6.5 32 174 71 11 51 759 464 148 148 140 0.1 1 North Carolina r Tobww Trust Fw►d C47mmisslan Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SLO17507 Chris Holder Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm