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HomeMy WebLinkAboutWQ0000430_Residual Annual Report 2020_20210222Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* W00000430 Applicant/Permittee City of Cherryville Email Notifications Does this need review by the hydrogeologist?* r Yes r No Regional Office Mooresville CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* WQ0000430 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * City of Cherryville RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for City of Cherryville, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Rans, Specifications, Calculations, Bc.) Cherryville NC 2020 Annual Report FINAL.pdf 6.53MB upload only 1 RCFdocurrent (less than 2501vB). Miltiple docurrents rust be corrbined into one RJFfile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/22/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 22, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0000430 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the City of Cherryville, NC. If you have any questions or need additional information, please do not hesitate to contact Larry Wright at (704) 435-1739 or Alex Fox at (336) 703-8681. Sincerely, P 1�A CY__� Derrick Shivar Environmental Compliance Manager Enclosures cc: Larry Wright, City of Cherryville Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2020 ANNUAL REPORT City of Cherryville, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00000430 County Gaston Year 2020 Facility Name (as shown on permit) City of CheMville WWTP NPDES No. NCO044440 Land Application Operator Svnaaro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part Band proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A— Residuals Application Summary: Total number of application fields in the permit: 8 Total number of fields utilized for land application during the year: 4 Total amount of dry tons applied during the year for all application sites: 131.08 Total number of acres utilized for land application during the year: 61.2 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false infor tion, including the pos ' fines and imprisonment for knowing violations." L Wri ht Plant ORC & Plant Su ervisor _ r 20 jf ee Name and pe or pr' t) Signature of P ttee Date On 0I gnature of Pip arer* Date Signature of Land Applier Date different fro Permi e (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 CHERRYVILLE, NC CHERRYVILLE, NC LIQUID MONTH/YEAR January 2020 December 2020 TOTAL AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 279,000.00 G 45.37 D 41.15 527,000.00 G 85.71 D 77.74 806,000.00 G 131.08 D 118.89 Report Date: 1/29/2021 4:01:55 PM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0000430 Laboratory: Facility Name: CHERRYVILLE, NC Waypoint Analytical Virginia Inc. Residual Source WQ # or NPDES#: NCO044440 WWTP Name: CHERRYVILLE Residual Analysis Data Product Type LIQ Sample or Composite Date 01/20/20 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 3.90 Arsenic 75 <12.8 Cadmium 85 <2.56 Copper 4300 574 Chromium NA 60.8 Lead 840 47.9 Mercury 57 0.513 Molybdenum 75 9.9 Nickel 420 41.5 Selenium 100 <12.8 Zinc 7500 859 Total Phosphorus NA 24100 TKN NA 50500 Ammonia -Nitrogen NA 8380 Nitrate and Nitrite NA <117 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of/fines and imprisonment for!powir�.vi ations " of Preparer* is defined in 40 C 503.9(r) and 105 A NCAC 2T.1102(26) Date DENR FORM RSSF-B (12/2006) Printed: 1/29/2021 4:03:16 PM For: 2008 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0000430 Laboratory: Facility Name: CHERRYVILLE, NC Waypoint Analytical Virginia Inc. Residual Source NPDES # or WQ#: NCO044440 WWTP Name: CHERRYVILLE Residual Analysis Data Product Type LIQ Sample or Composite Date 01/20/20 Parameters (mgikg dry weight) Aluminium 33300 Calcium 13100 Magnesium 3410 pH (s.u.) 6.80 Potassium 2400 Sodium 1660 PAN 16937 SAR (Ratio) 0.6577 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." d ✓ * Date is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 1/29/2021 4:04:10 PM For: 2008 01 DENR FORM RSSF-B (12/2006) Waypointo ANALYTICAL 1 /28/2020 Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 20-021-0003 Project Description: Cherryville 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 1/21/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, �a f• c•—r Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 6 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-021-0003 Client Project Description: Cherryville Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 70228 Cherryville Solids 01/20/202011:15 01/21/2020 70228 Cherryville Solids 01/20/202011:15 01/21/2020 70228 Cherryville Solids 01/20/202011:15 01/21/2020 70228 Cherryville Solids 01/20/202011:15 01/21/2020 70228 Cherryville Solids 01/20/202011:15 01/21/2020 70228 Cherryville Solids 01/20/202011:15 01/21/2020 70228 Cherryville Solids 01/20/202011:15 01/21/2020 70228 Cherryville Solids 01/20/202011:15 01/21/2020 SM-4500-NH3C WP MTN 9045D WP MTN 4500NO3F-2011 WP MTN 6010D WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN SM-2540G WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 6 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46442 Synagro Central LLC/ Cherryville Alex Fox Mary Brewer Project Cherryville Report Date : 01/28/2020 284 Boger Road Information : Received : 01/21/2020 Mocksville , NC 27028 Pam« mL 60wr Submitted By : Alex Fox Pauric ry Report Number : 20-021-0003 REPORT OFANALYSIS Agronomist Lab No : 70228 Matrix: Solids Sample ID : Cherryville Sampled: 1/20/2020 11:15 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 96.1 % 0.010 1 01/23/2016:23 ADM SM-2540G Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 8380 mg/Kg - dry 2560 1 01/28/20 12:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N <117 mg/Kg - dry 117 1 01/27/20 13:34 ZBD 4500NO3F-2011 Organic N 42100 mg/Kg - dry 6410 1 01/28/20 10:00 CALCULATION pH 6.8 S.U. 1 11/27/20 06:44 JSL 9045D Total Solids 3.90 % 0.010 1 01/23/20 16:23 ADM SM-2540G Total Kjeldahl Nitrogen 50500 mg/Kg - dry 6410 1 01/28/20 10:00 JPJ ;M-4500-NH3C-TKl` Phosphorus 24100 mg/Kg - dry 128 1 01/24/20 01:36 KKM 6010D Aluminum 33300 mg/Kg - dry 128 1 01/24/20 01:36 KKM 6010D Arsenic <12.8 mg/Kg - dry 12.8 1 01/24/20 01:36 KKM 6010D Calcium 13100 mg/Kg - dry 641 1 01/24/20 01:36 KKM 6010D Cadmium <2.56 mg/Kg - dry 2.56 1 01/24/20 01:36 KKM 6010D Chromium 60.8 mg/Kg - dry 6.41 1 01/24/20 01:36 KKM 6010D Copper 574 mg/Kg - dry 6.41 1 01/24/20 01:36 KKM 6010D Iron 42600 mg/Kg - dry 128 1 01/24/20 01:36 KKM 6010D Lead 47.9 mg/Kg - dry 7.69 1 01/24/20 01:36 KKM 6010D Magnesium 3410 mg/Kg - dry 128 1 01/24/20 01:36 KKM 6010D Manganese 818 mg/Kg - dry 12.8 1 01/24/20 01:36 KKM 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 6 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46442 Synagro Central LLC/ Cherryville Alex Fox Mary Brewer Project Cherryville Report Date : 01/28/2020 284 Boger Road Information : Received : 01/21/2020 Mocksville , NC 27028 Pam« mL 60wr Submitted By : Alex Fox Pauric ry Report Number : 20-021-0003 REPORT OFANALYSIS Agronomist Lab No : 70228 Matrix: Solids Sample ID : Cherryville Sampled: 1/20/2020 11:15 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Mercury 0.513 mg/Kg - dry 0.405 1 01/24/20 11:28 TJS SW-7471B Molybdenum 9.90 mg/Kg - dry 6.41 1 01/24/20 01:36 KKM 6010D Nickel 41.5 mg/Kg - dry 6.41 1 01/24/20 01:36 KKM 6010D Potassium 2400 mg/Kg - dry 128 1 01/24/20 01:36 KKM 6010D Selenium <12.8 mg/Kg - dry 12.8 1 01/24/20 01:36 KKM 6010D Sodium 1660 mg/Kg - dry 641 1 01/24/20 01:36 KKM 6010D Zinc 859 mg/Kg - dry 32.1 1 01/24/20 01:36 KKM 6010D Sulfur 11300 mg/Kg - dry 128 1 01/24/20 01:36 KKM 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit L Limit Exceeded Page 4 of 6 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 2-4237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46442 Customer Name: Synagro Central LLC/ Cherryville Report Number: 20-021-0003 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 01/21/2020 11:22:43 Page 5 of 6 SAMPLING LOG N as�2 _pp3 ® Ill�lllllllllll1S�111{�41II1111111�1111 �1�1�111�1-Illll� a1.z9_52C �g ,�+ ,�°�, 1 ■ � Svn1110 Central LLC CUSTOMER: S V NAGR .1' � cnerrWiue PROJECT MANAGER; +Y 9x Phone: (' �y) 70 S C.7 d - - — L. A & L CUSTOMER SAMPLING _SAMPLE ## OP LAB # SAMPLE I.D. LOCATION TYPE CONTAINERS nC,ii iyu15, rt�U ray Oarnprer: glex F-z' Relinquished by: Relinquisher! by: 3.rl�ifAI N OF CUSTODY 1ECDRD & ANALYSIS RECORD attest that the proper field sampling procedures were s d durin ction of these samples. SAMPLER SAMPLING METHOD METHOD DATE TIME PRESE13VED SHIPPED Time Recieved by: REMARKS: z 'dam atfs Dal Time Recieved by: Oat Time Recfevad bv. SPECIAL INSTRUCTIONS: r�or monitoring purposes. PO#. SAMPLE ANALYSIS REQUEST l.D. SL1 SL2 NHS-N NO3-N DrgNnic Cd Cr NI Pb As Hg Se PH CaCO3 Volatile �� �'� equiv. Solids M°. Cl NO2..N koo or PW P loor SL1: Total Solids (Moisture), Total Kjefdahi !Nitrogen, Phosphorus, and Potassium Sll2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, iron, Aluminum, Manganese, Capper and Zinc Page 6 of 6 SECTION 3 FACILITY NAME: CHERRYVILLE, NC LAND OWNER: CALVIN WEHUNT OPERATOR: CALVIN WEHUNT CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0000430 FIELD#: NC-LT-00107-0-0001- ANNUAL DRY TONS APPLIED: 28.23 SITE #: NC LT 00107 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 156 CROP 2 NAME: Page: 1 ACRES UTILIZED: 10.7 ACRES PERMITTED: 10.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate— mg/kg mg/kg mg/kg Crop Crop 1 Crop 2 Crop 1 Crop 2 12/3/2020 111,600.00 (G) 3.900 1.696 CHL MOIST 110-<1/2" SUR 0.5 0.30 50,500.00 8,380.00 117.00 57.458 FSP 12/4/2020 62,000.00 (G) 3.900 0.942 CHL DRY "0-<1/2" SUR 0.5 0.30 50,500.00 8,380.00 117.00 31.921 FSP Dec-20 173,600.00 (G) Total 2.638 Total 89.379 0.000 AS Annual Ibs/acre Applied 0.068 CD CU CR PB HG MO NI SE ZN P Lime Applied 0.014 3.029 0.321 0.253 0.003 0.052 0.219 0.068 4.533 127.178 Date Lbs/Ac Cumulative Ibs/acre Applied 0.068 0.014 3.029 0.321 0.253 0.003 0.052 0.219 0.068 4.533 ***** ***** permit PAN Limit (Ibs/acre) 1st Crop I I I I I I I I 1 1 156 =ederal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 1 267.9 1 15.0 1 375.0 1 89.0 1 2,500.0 CHL=CHERRYVILLE, NC LIQUID "I certify, under penalty of law, that th' d current was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are si i cant penalriit€ersiitting false information, including the possibility of fines and imprisonment for knowing violations." NATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ****` See Site pH & Lime Application Records Section of Report Printed: 1/29/2021 DENR FORM FSF (12/2006) FACILITY NAME: CHERRYVILLE, NC LANDOWNER: CALVIN WEHUNT OPERATOR: CALVIN WEHUNT CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT M WQ0000430 FIELD#: NC-LT-00107-0-0002- ANNUAL DRY TONS APPLIED: 30.25 SITE M NC LT 00107 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 156 CROP 2 NAME: Page: 1 ACRES UTILIZED: 12.0 ACRES PERMITTED: 12.0 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 12/3/2020 93,000.00 (G) 3.900 1.260 CHL MOIST 1'0-<1/2" SUR 0.5 0.30 50,500.00 8,380.00 117.00 42.694 FSP 12/4/2020 93,000.00 (G) 3.900 1.260 CHL DRY "0-<1/2" SUR 0.5 0.30 50,500.00 8,380.00 117.00 42.694 FSP Dec-20 186,000.00 (G) Total 2.520 Total 85.388 0.000 AS Annual Ibs/acre Applied 0.065 CD CU CR PB HG MO NI SE ZN P Lime Applied 0.013 2.894 0.307 0.241 0.003 0.050 0.209 0.065 4.331 121.501 Date Lbs/Ac Cumulative Ibs/acre Applied 0.065 0.013 2.894 0.307 0.241 0.003 0.050 0.209 0.065 4.331 ***** ***** permit PAN Limit (Ibs/acre) 1st Crop I I I I I I I 1 1 156 =ederal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 1 267.9 1 15.0 375.0 1 89.0 1 2,500.0 CHL = CHERRYVILLE, NC LIQUID "I certify, under penalty of a that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware tha are signi ' alties for submitting false information, including the possibility of fines and imprisonment for knowing violations." -3--Zf SIGNATU E OF LAND APPLIER DATE NR = Not Reported or Not Required `** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation ** ` C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/29/2021 DENR FORM FSF (12/2006) FACILITY NAME: CHERRYVILLE, NC LAND OWNER: CALVIN WEHUNT OPERATOR: CALVIN WEHUNT CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0000430 FIELD#: NC-LT-00107-0-0004- ANNUAL DRY TONS APPLIED: 27.22 SITE #: NC LT 00107 PREDOMINANT SOIL SERIES: RION CROP 1 MAX. PAN: 167 CROP 2 NAME: Page: 1 ACRES UTILIZED: 10.9 ACRES PERMITTED: 10.9 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 12/9/2020 167,400.00 (G) 3.900 2.498 CHL MOIST 110-<1/2" SUR 0.5 0.30 50,500.00 8,380.00 117.00 84.605 FSH Dec-20 167,400.00 (G) Total 2.498 Total 84.605 0.000 AS CD Annual Ibs/acre Applied 0.064 0.013 CU CR PB HG MO NI SE ZN P Lime Applied 2.867 0.304 0.239 0.003 0.049 0.207 0.064 4.291 120.386 Date Lbs/Ac Cumulative Ibs/acre Applied 0.064 0.013 2.867 0.304 0.239 0.003 0.049 0.207 0.064 4.291 ***** ***** Permit PAN Limit (Ibs/acre) 1st Crop I I I I I I I I 1 1 167 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 1 267.9 1 15.0 1 375.0 1 89.0 1 2,500.0 CHL = CHERRYVILLE, INC LIQUID "I certify, under pen ty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel. properly gathered and evaluated the information submitted. I am aw t t there are si nific nalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." SIG T RE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate '* Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/29/2021 DENR FORM FSF (12/2006) FACILITY NAME: CHERRYVILLE, NC LAND OWNER: WAYNE GILBERT OPERATOR: WAYNE & MARTHA GILBERT CROP 1 NAME: CORN (C) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0000430 FIELD#: NC-LT-00120-0-0002- ANNUAL DRY TONS APPLIED: 45.37 SITE #: NC LT 00120 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 238 CROP 2 NAME: Page: 1 ACRES UTILIZED: 27.6 ACRES PERMITTED: 27.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 1/10/2020 148,800.00 (G) 3.900 0.877 CHL MOIST 110-<1/2" SUR 0.5 0.30 50,500.00 8,380.00 117.00 29.700 C 1/22/2020 130,200.00 (G) 3.900 0.767 CHL DRY 110-<1/2" SUR 0.5 0.30 50,500.00 8,380.00 117.00 25.988 C Jan-20 279,000.00 (G) Total 1.644 Total 55.688 0.000 AS Annual Ibs/acre Applied 0.042 CD CU CR PB HG MO NI SE ZN P Lime Applied 0.008 1.887 0.200 0.158 0.002 0.033 0.136 0.042 2.824 79.240 Date Lbs/Ac Cumulative Ibs/acre Applied 0.182 0.079 22.811 2.437 1.415 0.033 0.565 1.987 0.169 33.963 ***** ***** ?ermit PAN Limit (Ibs/acre) 1st Crop I I I I I I I I I I 238 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 1 267.9 1 15.0 1 375.0 1 89.0 1 2,500.0 CHL = CHERRYVILLE, NC LIQUID "I certify, under pen ty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am awa th there are significant f yLbb-mitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, ]NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 "**** See Site pH & Lime Application Records Section of Report Printed: 1/29/2021 DENR FORM FSF (1212006) SECTION 4 SUMM111 ENVIRONMENTAL TECHN❑LOMZ3. INC ArrzrJy0ca1 Laboralorfas April 21, 2020 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Cherryville WWTP Dear Alex Fox: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Order No.: 20040156 Summit Environmental Technologies, Inc. received 1 sample(s) on 4/2/2020 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho 01100923, Illinois 200061, Indiana C-011-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP C1,0052, Oklahoma 2019-155, Oregon 0112O0001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah 011009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 29 mm' y Summit Environmental Technologies, Inc. Case Narrative su3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 20040156 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 4/21/2020 CLIENT: Synagro Project: Cherryville WWTP WorkOrder Narrative: 20040156: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 20040156-OOIA TCLP-SVOC_8270E: Surrogate outside recovery limits. Minimum method criterion of one surrogate within established recovery limits was met. Analytical Sequence QC Notes: PEST 250PPB ccv SVOC-CPEST_NPW(8081): CCV exhibits high recovery for batch specific analyte Endrin. Reported samples are ND Original Page 2 of 29 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S Ekiwlt OMM@N-rALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 20040156 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-44E Wehsite: httn:11www.settek.co Date: 4/21/2020 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low () or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low () or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low () or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low () or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 29 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMMEWAL TECHNp4,1 ULES,1NC. Cuyahoga Falls, Ohio 44223 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Cherryville WWTP Lab SampleID Client Sample ID 20040156-001 Chenyville WWI'P Tag No Date Collected 4/l/2020 10:30:00 AM Workorder Sample Summary WO#: 20040156 21 Apr-20 Date Received Matrix 4/2/2020 10:20:00 AM Sludge Page 4 of 29 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES REPORT ENVIRONMENTALTECHN❑L0G1ES,1rJG Cuyahoga Falls, Ohio44223 WO#: 20040156 ArWyft cal tai5oralonas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 20040156-OOIA Cherryville WWTP 4/l/2020 10:30:00 AM Sludge Flashpoint Determination (1010) 4/10/2020 5:04:05 PM pH (SW9045D) 4/3/2020 2:07:55 PM Reactive Cyanide (9014/7.3.32)-Solid 4/6/2020 9:00:00 AM Reactive Sulfide (9034)/7.3.42 4/6/2020 9:00:00 AM TCLP Herbicides by EPA 8321B 4/9/2020 4:00:00 PM 4/16/2020 6:52:00 AM TCLP Mercury Analysis (SW1311/7474/8/2020 3:00:00 PM 4/10/2020 9:30:00 AM 4/10/2020 1:48:00 PM TCLP Metals Analysis (SW1311/6010'4/8/2020 3:00:00 PM 4/9/2020 1:00:00 PM 4/10/2020 10:55:04 AM TCLP Pesticides Analysis (SW1311/8(4/8/2020 3:00:00 PM 4/10/2020 12:30:00 PM 4/13/2020 9:25:00 PM TCLP Semi-Volatiles Analysis 4/8/2020 3:00:00 PM 4/9/2020 12:00:00 PM 4/14/2020 4:33:00 PM (SW1311/8270) TCLP Semi-Volatiles Analysis 4/8/2020 3:00:00 PM 4/9/2020 12:00:00 PM 4/13/2020 6:01:00 PM (SW1311/8270) TCLP Volatiles Analysis 4/9/2020 4:00:00 PM 4/10/2020 7:41:00 PM Original Page 5 of 29 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 20040156 Date Reported: 4/21/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 4/l/2020 10:30:00 AM Lab ID: 20040156-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND TCLP Barium(Ba) ND TCLP Cadmium(Cd) ND TCLP Chromium(Cr) ND TCLP Lead(Pb) ND TCLP Selenium(Se) ND TCLP Silver(Ag) ND RCI FLASHPOINT DETERMINATION (1010) Flashpoint (140°F) >140 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 2,4,5-Trichlorophenol ND 2,4,6-Trichlorophenol ND 2,4-Dinitrotoluene ND Cresols, Total ND Hexachloro-1,3-butadiene ND Hexachlorobenzene ND Hexachloroethane ND Nitrobenzene ND Pentachlorophenol ND Pyridine ND Surr: 2-Fluorophenol 93.9 Surr: Phenol-d6 90.6 Surr: Nitrobenzene-d5 69.0 SW7470A SW7470A Analyst: MJM 0.00200 mg/L 1 4/10/2020 1:48:00 PM SW6010D SW301OA Analyst: EAM 0.500 mg/L 1 4/10/2020 10:55:04 AM 5.00 mg/L 1 4/10/2020 10:55:04 AM 0.100 mg/L 1 4/10/2020 10:55:04 AM 0.200 mg/L 1 4/10/2020 10:55:04 AM 0.500 mg/L 1 4/10/2020 10:55:04 AM 0.0500 mg/L 1 4/10/2020 10:55:04 AM 0.500 mg/L 1 4/10/2020 10:55:04 AM SW1010 Analyst: TAH °F 1 4/10/2020 5:04:05 PM SW8270 SW351OC Analyst: SFG 0.200 mg/L 2 4/13/2020 6:01:00 PM 0.500 mg/L 2 4/13/2020 6:01:00 PM 0.500 mg/L 2 4/13/2020 6:01:00 PM 0.100 mg/L 2 4/14/2020 4:33:00 PM 10.0 mg/L 2 4/13/2020 6:01:00 PM 0.0400 mg/L 2 4/13/2020 6:01:00 PM 0.100 mg/L 2 4/14/2020 4:33:00 PM 0.200 mg/L 2 4/13/2020 6:01:00 PM 0.200 mg/L 2 4/13/2020 6:01:00 PM 0.500 mg/L 2 4/14/2020 4:33:00 PM 0.500 mg/L 2 4/13/2020 6:01:00 PM 10 - 109 %Rec 2 4/13/2020 6:01:00 PM 10 - 109 %Rec 2 4/13/2020 6:01:00 PM 19 - 120 %Rec 2 4/14/2020 4:33:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Origin U Samples with CalcVal <MDL Page 6 of 29 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 20040156 Date Reported: 4/21/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 4/l/2020 10:30:00 AM Lab ID: 20040156-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) Surr: 2,4,6-Tribromophenol 121 Surr: 2-Fluorobiphenyl 87.3 Surr: p-Terphenyl-d14 123 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 76.5 Surr: DCB 85.8 TCLP HERBICIDES BY EPA 8321B 2,4-D ND 2,4,5-TP ND Surr: 2,4-Dichlorophenylacetic aci 123 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1, 2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND SW8270 SW351OC Analyst: SFG 10 - 120 S %Rec 2 4/13/2020 6:01:00 PM 22 - 117 %Rec 2 4/14/2020 4:33:00 PM 34 - 116 S %Rec 2 4/13/2020 6:01:00 PM SW8081 Analyst: MES 0.0125 mg/L 5 4/13/2020 9:25:00 PM 0.0250 mg/L 5 4/13/2020 9:25:00 PM 0.00250 QC+ mg/L 5 4/13/2020 9:25:00 PM 0.00250 mg/L 5 4/13/2020 9:25:00 PM 0.00250 mg/L 5 4/13/2020 9:25:00 PM 0.00250 mg/L 5 4/13/2020 9:25:00 PM 0.00250 mg/L 5 4/13/2020 9:25:00 PM 10 - 119 %Rec 5 4/13/2020 9:25:00 PM 10 - 119 %Rec 5 4/13/2020 9:25:00 PM SW8321A SW1311M Analyst: BJH 0.500 mg/L 50 4/16/2020 6:52:00 AM 0.500 mg/L 50 4/16/2020 6:52:00 AM 70 - 130 %Rec 50 4/16/2020 6:52:00 AM SW8260 SW1311M Analyst: RMT 0.500 mg/L 100 4/10/2020 7:41:00 PM 0.500 mg/L 100 4/10/2020 7:41:00 PM 10.0 mg/L 100 4/10/2020 7:41:00 PM 0.500 mg/L 100 4/10/2020 7:41:00 PM 0.500 mg/L 100 4/10/2020 7:41:00 PM 5.00 mg/L 100 4/10/2020 7:41:00 PM 0.500 mg/L 100 4/10/2020 7:41:00 PM 0.500 mg/L 100 4/10/2020 7:41:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Origin U Samples with CalcVal <MDL Page 7 of 29 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 20040156 Date Reported: 4/21/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 4/l/2020 10:30:00 AM Lab ID: 20040156-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 SW1311M Analyst: RMT TCLP VOLATILES ANALYSIS Trichloroethene ND 0.500 mg/L 100 4/10/2020 7:41:00 PM Vinyl chloride ND 0.200 mg/L 100 4/10/2020 7:41:00 PM Surr: 4-Bromofluorobenzene 99.5 70 - 130 %Rec 100 4/10/2020 7:41:00 PM Surr: Dibromofluoromethane 94.5 70 - 130 %Rec 100 4/10/2020 7:41:00 PM Surr: Toluene-d8 98.8 70 - 130 %Rec 100 4/10/2020 7:41:00 PM RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.500 mg/Kg 1 4/6/2020 9:00:00 AM RCI SW9045D Analyst: VVK PH (SW9045D) pH 6.4 s.u.@20.3C 1 4/3/2020 2:07:55 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 4/6/2020 9:00:00 AM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Origin U Samples with CalcVal <MDL Page 8 of 29 EF summit Environmental Technologies, Inc. Accreditation Program frSU 3310Win St. MM I Anal tes Report Y ENOROMMEWAL IrECHNOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 Y ArralyVcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20040156 Wehsite: http://www.settek.com 21 Apt'-20 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 20040156-OOIA Sludge Flashpoint Determination (1010) Flashpoint (140°F) A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.32)-Solid Cyanide, Reactive N Sludge Reactive Sulfide (9034)/7.3.42 Sulfide, Reactive N Sludge TCLP Herbicides by EPA 832113 2,4,5-TP A Sludge TCLP Herbicides by EPA 832113 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Key Key NC WW SCM A Accredited NC WW SCM N Not Accredited Original # 1 Page 9 of 29 EF summit Environmental Technologies, Inc. Accreditation Program MM I frSU3310Win St. Anal tes Report Y ENVIROMMEWAL YECHNOWGIES, INC, Cuyahoga Falls, Ohio 44223 Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20040156 Wehsite: http://www.settek.com 21 Apt'-20 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 20040156-OOIA Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM N Not Accredited Original # 1 Page 10 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20040156 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42926 Sample ID: MB-42926 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 lient ID: PBS Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/9/2020 SegNo: 2724283 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.784 Surr: Phenol-d6 0.764 Surr: Nitrobenzene-d5 0.581 Surr: 2,4,6-Tribromophenol 1.13 Surr: 2-Fluorobiphenyl 0.696 Surr: p-Terphenyl-d14 1.17 1.000 78.4 10 109 1.000 76.4 10 109 1.000 58.1 19 120 1.000 113 10 120 1.000 69.6 22 117 1.000 117 34 116 S Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 11 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: 42926 WO#: 20040156 21 Apr-20 Sample ID: LCS-42926 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 Dient ID: LCSS Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/9/2020 SegNo: 2724284 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.460 0.100 0.8000 0 57.6 36.4 130 2,4,5-Trichlorophenol 0.886 0.250 0.8000 0 ill 31.7 132 2,4,6-Trichlorophenol 0.880 0.250 0.8000 0 110 31.1 133 2,4-Dinitrotoluene 0.858 0.0500 0.8000 0 107 43.3 130 o-Cresol 0.680 0.250 0.8000 0 85.0 32.9 130 Cresols, Total ND 5.00 1.600 0 85.0 31.7 130 Hexachloro-1,3-butadiene 0.466 0.0200 0.8000 0 58.3 31.4 130 Hexachlorobenzene 0.804 0.0500 0.8000 0 101 43.1 130 Hexachloroethane 0.438 0.100 0.8000 0 54.7 36.5 130 Nitrobenzene 0.565 0.100 0.8000 0 70.6 39.5 130 Pentachlorophenol 0.816 0.250 0.8000 0 102 34 130 Pyridine 0.324 0.250 0.8000 0 40.5 10 130 Surr: 2-Fluorophenol 0.816 1.000 81.6 17.1 130 Surr: Phenol-d6 0.839 1.000 83.9 10 130 Surr: Nitrobenzene-d5 0.629 1.000 62.9 32.6 130 Surr:2,4,6-Tribromophenol 1.22 1.000 122 4.43 130 Surr: 2-Fluorobiphenyl 0.791 1.000 79.1 41.8 130 Surr: p-Terphenyl-dl4 1.16 1.000 116 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: 42926 WO#: 20040156 21 Apr-20 Sample ID: 20031698-001AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 Dient ID: Batch= Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/10/2020 SegNo: 2724309 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.489 0.200 0.8000 0 61.1 33.8 126 2,4,5-Trichlorophenol 0.909 0.500 0.8000 0 114 28.7 144 2,4,6-Trichlorophenol 0.936 0.500 0.8000 0 117 12.8 153 2,4-Dinitrotoluene 0.927 0.100 0.8000 0 116 20.4 155 o-Cresol 0.704 0.500 0.8000 0 88.0 10 148 Cresols, Total ND 10.0 1.600 0 89.6 10 148 Hexachloro-1,3-butadiene 0.490 0.0400 0.8000 0.006000 60.6 29 126 Hexachlorobenzene 0.909 0.100 0.8000 0 114 33.7 134 Hexachloroethane 0.452 0.200 0.8000 0.006400 55.7 32.8 132 Nitrobenzene 0.602 0.200 0.8000 0 75.2 20 158 Pentachlorophenol 0.703 0.500 0.8000 0 87.9 10 176 Pyridine ND 0.500 0.8000 0 37.2 10 130 Surr:2-Fluorophenol 0.782 1.000 78.2 3.39 130 Surr: Phenol-d6 0.861 1.000 86.1 5 130 Surr: Nitrobenzene-d5 0.648 1.000 64.8 14.5 154 Surr: 2,4,6-Tribromophenol 1.23 1.000 123 19.5 130 Surr:2-Fluorobiphenyl 0.868 1.000 86.8 34.4 130 Surr: p-Terphenyl-d14 1.27 1.000 127 8.86 156 QMR Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 13 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Cherryville WWTP BatchID: 42926 WO#: 20040156 21 Apr-20 Sample ID: 20031698-001AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 Dient ID: Batch= Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/10/2020 SegNo: 2724317 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.549 0.200 0.8000 0 68.6 33.8 126 0.4888 11.6 30 2,4,5-Trichlorophenol 0.870 0.500 0.8000 0 109 28.7 144 0.9092 4.36 30 2,4,6-Trichlorophenol 0.944 0.500 0.8000 0 118 12.8 153 0.9364 0.851 30 2,4-Dinitrotoluene 0.922 0.100 0.8000 0 115 20.4 155 0.9272 0.519 30 o-Cresol 0.797 0.500 0.8000 0 99.6 10 148 0.7036 12.4 30 Cresols, Total ND 10.0 1.600 0 96.7 10 148 0 0 30 Hexachloro-1,3-butadiene 0.586 0.0400 0.8000 0.006000 72.6 29 126 0.4904 17.8 30 Hexachlorobenzene 0.902 0.100 0.8000 0 113 33.7 134 0.9092 0.751 30 Hexachloroethane 0.530 0.200 0.8000 0.006400 65.4 32.8 132 0.4520 15.8 30 Nitrobenzene 0.664 0.200 0.8000 0 83.0 20 158 0.6020 9.79 30 Pentachlorophenol 0.596 0.500 0.8000 0 74.6 10 176 0.7032 16.4 30 Pyridine ND 0.500 0.8000 0 13.8 10 130 0 0 30 Surr:2-Fluorophenol 0.892 1.000 89.2 3.39 130 0 Surr: Phenol-d6 0.927 1.000 92.7 10 130 0 Surr: Nitrobenzene-d5 0.735 1.000 73.5 14.5 154 0 Surr: 2,4,6-Tribromophenol 1.30 1.000 130 19.5 130 0 Surr:2-Fluorobiphenyl 0.900 1.000 90.0 34.4 130 0 Surr: p-Terphenyl-d14 1.25 1.000 125 8.86 156 0 Rm Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20040156 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42928 Sample ID: 20040321-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: Batch= Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724298 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.27 0.500 2.000 0 113 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.6508 99.2 70 130 TCLP Cadmium(Cd) 2.18 0.100 2.000 0.004215 109 70 130 TCLP Chromium(Cr) 2.00 0.200 2.000 0.006405 99.8 70 130 TCLP Lead(Pb) 1.97 0.500 2.000 0 98.4 70 130 TCLP Selenium(Se) 2.46 0.0500 2.000 0.06040 120 70 130 TCLP Silver(Ag) 2.15 0.500 2.000 0 107 70 130 Sample ID: 20040321-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: Batch= Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724299 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.18 0.500 2.000 0 109 70 130 2.269 4.01 20 TCLP Barium(Ba) ND 5.00 2.000 0.6508 97.8 70 130 0 0 20 TCLP Cadmium(Cd) 2.10 0.100 2.000 0.004215 105 70 130 2.178 3.45 20 TCLP Chromium(Cr) 1.98 0.200 2.000 0.006405 98.9 70 130 2.003 0.973 20 TCLP Lead(Pb) 1.92 0.500 2.000 0 96.1 70 130 1.967 2.36 20 TCLP Selenium(Se) 2.45 0.0500 2.000 0.06040 119 70 130 2.465 0.782 20 TCLP Silver(Ag) 2.11 0.500 2.000 0 105 70 130 2.148 1.90 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20040156 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42928 Sample ID: MB-42928 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: PBS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724377 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: LCS-42928 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: LCSS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724378 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.99 0.500 2.000 0 99.7 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 102 80 120 TCLP Cadmium(Cd) 2.07 0.100 2.000 0 104 80 120 TCLP Chromium(Cr) 1.99 0.200 2.000 0 99.7 80 120 TCLP Lead(Pb) 2.02 0.500 2.000 0 101 80 120 TCLP Selenium(Se) 2.10 0.0500 2.000 0 105 80 120 TCLP Silver(Ag) 1.96 0.500 2.000 0 97.9 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20040156 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42928 Sample ID: TCLP BLANK 1 4-9- SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 lient ID: PBS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724380 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: TCLP BLANK 2 4-9- SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 lient ID: PBS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724381 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 29 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040156 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42934 TCLP Mercury ND 0.00200 TCLP Mercury 0.00400 0.00200 0.00400 0 100 80 120 TCLP Mercury ND 0.00200 Sample ID: TCLP BLANK 1 4-9- SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 4/10/2020 RunNo: 111636 Client ID: PBS Batch ID: 42934 TestNo: SW7470A SW7470A Analysis Date: 4/10/2020 SegNo: 2724802 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.00200 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 29 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040156 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42934 TCLP Mercury ND 0.00200 TCLP Mercury 0.00432 0.00200 0.00400 0.000141 104 75 125 Sample ID: 20040321-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 4/10/2020 RunNo: 111636 Client ID: Batch= Batch ID: 42934 TestNo: SW7470A SW7470A Analysis Date: 4/10/2020 SegNo: 2724813 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00441 0.00200 0.00400 0.000141 107 75 125 0.00432 2.06 20 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit Original RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20040156 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42936 Sample ID: MB-42936 SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: 4/9/2020 RunNo: 111633 lient ID: PBS Batch ID: 42936 TestNo: SW8260 SW1311M Analysis Date: 4/10/2020 SegNo: 2724722 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.0500 1,2-Dichloroethane ND 0.0500 MEK ND 1.00 Benzene ND 0.0500 Carbon tetrachloride ND 0.0500 Chlorobenzene ND 0.500 Chloroform ND 0.0500 Tetrachloroethene ND 0.0500 Trichloroethene ND 0.0500 Vinyl chloride ND 0.0200 Surr: 4-Bromofluorobenzene 493 Surr: Dibromofluoromethane 466 Surr: Toluene-d8 472 500.0 98.6 70 130 500.0 93.2 70 130 500.0 94.3 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 20 of 29 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20040156 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: 42951A Sample ID: MB-42951 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 4/10/2020 RunNo: 111755 Client ID: PBS Batch ID: 42951A TestNo: SW8081 Analysis Date: 4/13/2020 SegNo: 2730551 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 QC+ gamma-BHC ND 0.000500 Heptachlor ND 0.000500 Heptachlor epoxide ND 0.000500 Methoxychlor ND 0.000500 Surr: TCMX 13.3 20.00 66.7 10 119 Surr: DCB 15.4 20.00 77.2 10 119 m Sample ID: LCS-42951 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 4/10/2020 RunNo: 111755 Client ID: LCSS Batch ID: 42951A TestNo: SW8081 Analysis Date: 4/13/2020 SegNo: 2730552 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.0112 0.000500 0.0100 0 112 10 130 QC+ gamma-BHC 0.00849 0.000500 0.0100 0 84.9 10 130 Heptachlor 0.00893 0.000500 0.0100 0 89.3 10 130 Heptachlor epoxide 0.00946 0.000500 0.0100 0 94.6 10 130 Methoxychlor 0.0104 0.000500 0.0100 0 104 10 178 Surr: TCMX 13.8 20.00 69.1 10 130 Surr: DCB 13.5 20.00 67.7 10 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 21 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20040156 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: R111355 Sample ID: CHECK 7 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@22.8C Prep Date: RunNo: 111355 Client ID: LCSS Batch ID: R111355 TestNo: SW9045D Analysis Date: 4/3/2020 SegNo: 2713536 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 99.9 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 29 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040156 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: R111355 Sample ID: LCS-R111355 SampType: LCS TestCode: pH_Oil(9045D Units: s.u.@19.9C Prep Date: RunNo: 111355 Client ID: LCSW Batch ID: R111355 TestNo: SW9045D Analysis Date: 4/3/2020 SegNo: 2712755 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Sample ID: 20040173-001ADUP SampType: DUP TestCode: pH_Oil(9045D Units: s.u.@22.3C Prep Date: RunNo: 111355 Client ID: Batch= Batch ID: R111355 TestNo: SW9045D Analysis Date: 4/3/2020 SegNo: 2712757 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 6.8 0 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 6.7 0.7 10 E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 23 of 29 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040156 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: R111515 Cyanide, Reactive ND 0.481 Cyanide, Reactive 8.98 0.485 10.00 0 89.8 85 115 Cyanide, Reactive ND 0.476 0.5000 0 92.5 65 135 Sample ID: 20040156-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 111515 Client ID: Cherryville WWTP Batch ID: R111515 TestNo: SW9014 Analysis Date: 4/6/2020 SegNo: 2719602 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.43 0.476 10.00 0 84.3 75 125 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 24 of 29 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040156 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: R111515 Sample ID: 20040156-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 111515 Client ID: Cherryville WWTP Batch ID: R111515 TestNo: SW9014 Analysis Date: 4/6/2020 SegNo: 2719602 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 20040156-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 111515 Client ID: Cherryville WWTP Batch ID: R111515 TestNo: SW9014 Analysis Date: 4/6/2020 SegNo: 2719603 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.00 0.485 10.00 0 90.0 75 125 8.431 6.56 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 25 of 29 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040156 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: R111516 Sulfide, Reactive ND 25.0 Sulfide, Reactive 4610 25.0 4800 0 96.0 85 115 Sulfide, Reactive 4560 25.0 4800 0 95.0 80 120 Sample ID: 20040156-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 111516 Client ID: Cherryville WWTP Batch ID: R111516 TestNo: SW9034 Analysis Date: 4/6/2020 SegNo: 2719611 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4580 25.0 4800 0 95.4 80 120 4560 0.438 30 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 26 of 29 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 20040156 21 Apr-20 Client: Synagro Project: Cherryville WWTP BatchID: R111516 Sample ID: 20040156-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 111516 Dient ID: Cherryville WWTP Batch ID: R111516 TestNo: SW9034 Analysis Date: 4/6/2020 SegNo: 2719611 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 27 of 29 DBPix io%mmmit Envirommental Technologies, Inc. 3310Win Street ' Analysis RequesttChain of Custody Cuy211109,1 Falls, Ohio 44223 330-253.82I 1 Fax. 330.253.4489 For Summit Environmen€al Technolvgics, Inc, use do SET Ni3, Company Name (Please Print} Project I+iame Page -of f Analytical Pa>rarneteis and Methods Company Address r ee1 A G S,rr L Client Phane No. ��{�SReport to t � Client Fax Np. Please Fax Res�lj]aJ PDT Client Ernad r to ].H nl� iI Quote No. Sampled by ¢�J Check if # Sample tdentiiication CD � t ter• N 00 O N CO L ems+ ti • v C o� � 4 . 1PsamplesJ tiQ ,� o 'I1 � iC L v Date Cutlected Cdlectert t ? �: a J ry e� 16 f L% Pkax e:Q iirne Rash tit4 uested $g' Mum be approved _ Date bylahrnanager While and yellow pages should sooampany aamp€es w the €aborawy. Chi: client retains the pink page. b �I �� { {(1Q 2405 www.ai Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGa1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.coin Client Name: SYN-NC-27028 Work Order Number: 20040156 RcptNo: 1 Logged by: Jesseca E. Westfall 4/2/2020 10:20:00 AM A4,�G Completed By: Jesseca E. Westfall 4/2/2020 3:16:19 PM Reviewed By: Jennifer Woolf 4/2/2020 5:20:41 PM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes ❑ No ❑d 15. Is it clear what analyses were requested? Yes V No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 15.4 Goodl Not Present Page 29 of 29 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Cherryville WQ Permit Number: WQ0000430 WWTP Name: City of Cherryville WWTP NPDES Number: NCO044440 Monitoring Period: From Jan 1, 2020 To Dec 31, 2020 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion rf. ..T. 10. +., .,1+0-+. f a IV] c A nr f l..ee Rl thv fnllnwina mnnitarinu data - Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10 to the 6' MPN 406 1871 4474 MPN/g 0 Annual Grab SM9221 C Coliform power per gram E-2006 of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0ption/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) X (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certifications jncluding fine and imprisonment." *Yreparer 1s oetmed In 4U Part 503.9(r) and 15A NCAC 2T.1102 (26) lier Nam tle (if applicable) (type or print) Of of Land Applier (if applicable) %VS R (older, more conservative method) %VS in 0.5483 Enter in %VS Out F 0.4953 decimal form %VSR= (%VS in - %VS out) ((%VS in - (%VS in x %VS out)) %VSR= 19.15 (method from p.132 of WH manual) %VSR= (%VS in - %VS out) %VS in %VSR= 9,67 Results must be either greater than 38%; less than 17% for a 40-day bench - scale test; or less than 15% for a 30-clay bench -scale test. Analytical Results Synagro 284 Boger Rd. Mocksville, NC 27028 Receive Date: 01/20/2020 Reported: 02/28/2020 For: Cherryville WWTP Comments: Geometric Mean: 1265 MPN/g STATESVILLE ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200120-20-01 Fecal Coliforms 1 3553 MPNIg SM92210E-2006 01/20/2020 MD 200120-20-01 Percent Solids 1 3.94 % SM254OB-2011 01/20/2020 MD 200120-20-02 Fecal Coliforms 2 875 MPNIg SM92210E-2006 01/20/2020 MD 200120-20-02 Percent Solids 2 4.57 % SM254OB-2011 01/20/2020 MD 200120-20-03 Fecal Coliforms 3 897 MPNIg SM92210E-2006 01/20/2020 MD 200120-20-03 Percent Solids 3 4.46 % SM25408-2011 01/20/2020 MD 200120-20-04 Fecal Coliforms 4 2477 A1fPNlg SM9221CF-2000 01/20/2020 MD 200120-20-04 Percent Solids 4 4.44 % SM254OB-2011 01/20/2020 MD 200120-20-05 Fecal Coliforms 5 406 MPNIg SM92210E-2006 01/20/2020 MD 200120-20-05 Percent Solids 5 4.93 % SM2546B-2011 01/20/2020 MD 200120-20-06 Fecal Coliforms 6 412 MPNIg SM92210E-2006 01/20/2020 MD 200120-20-06 Percent Solids 6 4.86 % SM25408-2011 01/20/2020 MD 200120-20-07 Fecal Coliforms 7 4474 MPNIg SM92210E-2006 01/20/2020 MD 200120-20-07 Percent Solids 7 3.8 % SM25408-2011 01/20/2020 MD 200120-20-08 30 Day Benchscale Cherryville 19.2 % EPA625-R-9210 01/20/2020 WC WWTP Respectfully submitted, & _w1n, jll�lt ') Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NCO0909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page t of 9 Condition of Receipt Sample Number 200120-20-01 Temp on Arrival: 3.5 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200120-20-02 Temp on Arrival: 3.5 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200120-20-03 Temp on Arrival: 3.5 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200120-20-04 Temp on Arrival: 3.5 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200120-20-05 Temp on Arrival: 3.5 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 9 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200120-20-06 Temp on Arrival: 3.5 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200120-20-07 Temp on Arrival: 3.5 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 200120-20-08 Temp on Arrival: 3.5 Parameter Schedule: Chemicals in containers, lab Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 9 Criern: d �TATESVILLE ANALYTICAL L Address: P A 2-v / JC /� 122 Court Street t - ] :[). Eiez L''S SLWC�vllle. NC 214687 _ 170,11 97'---iA97 Ch:lil! Of Custody Record Contact Person_ Phone #It Ees. FAXJt PO # Requisitioned by: X (l me aI I ��� rp / rQ Customer Sample IDA Lab-1D a Time 5arnpted (Grate Only) Dole Sampled (Grab Only) Matra ww I':muncicn requested fnra�mlvgia Z 0 0 Co � Q 30 D, OS Relinquished by: Time arn. p !Z� Z-0 Sampled by: Received by: Time P 469 ame Date 144724 Transported by: S Relinquished by: Time am, pm Date �1-1— Holding times met: Received by: Time am, pm Date �1�/ Compliance work: X Composite Sa�kln _C Time begin am. pm Date 11 Non-compliance work: Time end am, pm Date �1 !�. Lab Comments: Samples Transported On lta: Composite Sampling#2: Time begin am, pm Date __I__I_. Time end pm Date. I�l__ --am. Initials: n 00 t,p 00 N U Z 0i t11 V) 00 (V N X O m 0 t1 Sample #: 200120-20-08 Client: Synagro 0yn�0 30 Day Bench Test- Aerobic Sample Name: Cherryville WWTP; Collect Dt: Jar: 20 2020 11:15AM Elm EPA625-R-9210 SM 5Q0 ,2111 Tests: 30 Day !late began: 'l} `, i Digester Dimensions: Analyst: Volume of sample in digester: mis rinse Started: Initial DO reading of sample: 'j � (>2) initial Dav DO: 3J (>2) Tens ; 6i C Day DO- J-µ14 (>2) Temp:X, C Date: Time: �Date: 1 17 , ime f l nl, % Total Solids % Total Solids Dish #: 10 _ Dish #: 10 Dry Wt.-' Dish Wt.: Dry Wt. + Dish Wt,: — �. � q— Dish Wt,: Dish Wt,-, _ 1� S a m p I c Wt.: 1 u Sample Wt.: _- %Total Solids: %Total Solids: Ye Volatile Solids % Volatile Solids Dry Wt,& Dish Wt,: 4-3 3 ! Dry WU Dish Wt.: �f 2S j Ash Wt.: A�f Ash Wu tt Sample Wt.: % T Sample Wt.: % Vol. Solids: y % Vol. Solids: Yo Total Solids % Total Solids Dish tk Ui Dish #: ,{ Dry Wt. + Dish Wt.: tl / 7 ,.�_ Dry Wt. +Dish Wt.: _4 Dish Wt.. Dish Wt.: -- Sample Wt.: �"? _ Sample Wt.: _ % Total Solids: % Total Solids: Yo Volatile Solids % Volatile Solids Dry Wt.& Dish Wt.. 1 Dry Wt,& Dish Wt.: 41)0��� Ash Wt.: lQ Ash Wt.: - Sample Wt.: Sample Wt,: % Vol. Solids: ........ Z % Vol. Solids: r Yo Total Solids( % Total Solids Dish 9:y Dish ft: Dry Wt. + Dish Wt.: 1. Dry Wt. i- Dish Wt.: �} Dish Wt.: Dish Wt.: Sample Wt.:_ _ Sample Wt.: % Total Solids: % Total Solids: Yo Volatile Solids % Volatile Solids ' Try Wt,& Dish Wt,: CD _ _ Dry Wt.& Nish Wt.: Ash Wt.: 5 Ash Wt,: k ' Sample Wt.: - Sample Wt,: _ °/u Vol. Solids: �. y I % Vol. Solids: --- [Type here] PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 5 of 9 Sample 1D# Dar 12 DO: •7 5 (>2) m T �p :`�.61 C Date: 2 � Time: OU Day, 18 DO: 3.�fi (>2) Temp: q C 9- hne: Date: Yo Total Solids 1 % Total Solids Dish #: 1 Dish #: Dry Wt. + Dish Wt.: Dry Wt. + Dish Wt.: , �Q Dish Wt.: Dish Wt.: Sample Wt.: Sample Wt.: %'Total Solids: _ O. !� 4 % Total Solids: Ye Volatile Solids 1 ,, % Volatile Solids Dry Wt.& Dish Wt.: Dry Wt.& Dish Wt.: q4. 1el3 Ash Wt,: Ash Wt.. Q, Sample Wt.: Sample WL: % Vol. Solids: 0. r' % Vol. Solids: Yo Total Solids Dish #: % Total Solids / Dish #: "! Dry Wt. + Dish Wt,: Dry Wt. + Dish Wu !7 Dish Wt.: Dish Wt.: Sample Wt.: Sample Wt.: % Total Solids: d. '�/ _ % Total Solids: Yo Volatile Solids % Volatile Solids lx Dry Wt.& Dish Wt.: 4cl. iMq Dry Wt.& Dish Wt Ash Wt.: Ash Wt.. D? Sample Wt.: �� �/� Sample Wt.: % Vol. Solids: �, 3 r % Vol. Solids: Yo Total Solids , j , Dish #: �-1` % Total Solids Dish #: Dry Wt, + Dish Wt.: Dry Wt. + Dish Wt.: !i 9 Dish Wt.: Dish Wt: Sample Wt.: Sample Wt.: % Total Solids: % Total Solids: .......Y..SC A Volatile Solids nn Dry WU Dish A-Vi 53LOC % Volatile Solids Wt.: . Dry Wt.& Dish Wt.: Ash Wt.: Ash Wt.: ! •� Sample Wt.: Sample Wt,: % Vol. Solids: % Vol. Solids: 0, qj [Type here] PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 6 of 9 Sample ]DO ._ 41611261_ 9g a Dav24 DO: (>2) Temp: .�% C Day 30 DO '7, ��' (>2} Temp: Date 2 m Time• 62Q1j Date: 2 Time: dQ . Total Solids % Total Solids Dish #: /Z Dish#: Dry Wt. + Dish Wt.: S�. ;A // _...._ . Dry Wt. + Dish Wt: DishWt.:... jy /.4 Dish Wt: L 19 Sample Wt.-. 5 Sample Wt: , % Total Solids: n, ^tZ % Total Solids. Yo Volatile Solids % Volatile Solids Dry Wt. & Dish Wt.: 5a, ull Dry Wt. & Dish Wt: i _ 96 f3 Ash Wt.: ___.. fo,..,Zj/,3 Ash Wt: _ 7146 Sample Wt.: Sample Wt: 15 % Vol. Solids: — Q_ �/s % Vol Solids: Yo Total Solids % Total Solids Dish #: _ ,� Dish#: i Dry Wt. + Dish Wt.: Vtf, 316,94 Dry Wt. + Dish Wt:.., tf k, 7452 Dish Wt.: VV Z 02-4 . Dish Wt: Qftf. Sample Wt.; '15-41146�_ Sample Wt: r` %Total Solids: Q, 7/cr %Total Solids: Yo Volatile Solids % Volatile Solids Dry Wt. & Dish W€.: q, Jgg.f Dry Wt. & Dish Wt: x Ash Wt.- �! _ z993 Ash Wt: Sample Wt.: Sample Wt: Zr % Vol. Solids: d(e % Vol Solids: Yo Total Solids % Total Solids Dish #: p Dish#: Dry Wt. -* Dish Wt.: -T/. 04 Dry Wt. + Dish Wt: Dish Wt.: 51. j / 56 Dish Wt: Sample Wt.: Z6 Sample Wt: 2 ,- % Total Solids: !1 `l2 % Total Solids: Yo Volatile Solids % Volatile Solids Dry Wt. & Dish Wt.: „�!- itQ 73 Dry Wt. & Dish Wt: Ash Wt.: Yl2YZ _ Ash Wt: V6. 524'z Sample Wt.: Sample Wt: 7 5 % Vol. Solids: Q., .i (e % Vol Solids: [Type here] PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 7 of 9 VOTE: oil/particle free air was supplied to the bottom of the Digester via a porous stone at a rate sufficient to mix the ;ample 10 day bench checklist —COMPLETE DAILY Sample v( I�X,ob **DO METER CALIBRATION" Da Water level Sample Temp 2OX Scrape Sollds/Mi DO Meter % DO Meter 'I'em °C DO Meter Calm 1. Comments 1 i 2I• � 2 A qX.2 22 . -7 0 Z 22.3G 1 t5- E;-1 4 3 _ �5•2 21. -71 6 l 2 7 b 2 . LP . 5 8 U 5 2 3 � 0 22.57 37 10 1l2 G10 21• 54 12 . l j -- 13 2.q . 14 2-2 , 00' ?. 20 . 15 qT 1 23.1 3 160 17 i ,�` q -7 . 9 7 , z 23 . I 21,07 .30 - b. U LP 18 12 C)-1.2 2.2.24 l9 5 2 •' 1 20 21 f 22.1 22 1 23 Ib. D 24 p 1 25 26 _..... 2 Z. 27 5 �_._._...._. 26 1P ✓ 29 30 ✓ , DI 7 !_ tt— [Type here] PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 8 of 9 30 Day Bench Worksheet Sample 11) #1001110. MA WEEK 1 Samples I Total Solids Volatile Solids % Volatile Fraction 1 1. 7 -7U 2 rj2 .1530 3 1j414 Average: 0 . C) {p 0. 53 0 • 4'9 WEEK 2 Sam les Total Solids Volatile Solids % Volatile Fraction 1 �3 z 0 `t - 5057 3 1 1 2 ,T -46i 3 Average: 1 I -0-4 0.52..O. 50-3 WEEK 3 —Samples Total Solids Volatile Solids % Volatile Fraction 1 0-35 D,5 72. 2 `71 3 3 0_ 3CI 0. Average: d. 7 50-a 0.4s,62 WEEK 4 Samples I Total Solids Volatile Solids % Volatile Fraction I -'7 d.3 7 2 0. CIO 0.43 0 1 `l I O. ..Average; $ j p . 393 q WEEK 5 Samples Total Solids Volatile Solids % Volatile Fraction 1 " U0 2 rl '1 l7 3 Average. 0. 7 9` Q . (p 01 5000 WEEK 6 Samples I Total Solids Volatile Solids % Volatile Fraction 0 0 3 5 0 2 0.71 0.35 0. 3 3 O. Q, 2 Avera e• . 10 0-4PS5 0.5g83-0.140153 �Ioo G•543-M5Ur�=3X O.u0153) Van Kleeck Reduction: Initial % Vol. Frac. - °/a Finat Vol. Frac. X 100 = % 01 514 ?3- 0. 12-1 U Initial % Vol. Frac. — ( Initial % Vol. Frac. X Final % Vol. Frac) 1 p, 53 x !aa FINAL. RESULT % OCl— q__ — � 0/ 0) PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 9 of 9 SECTION 6 Agricultural Lime Application Log Year: 2020 Project: Cherryville Field (state -county -site -field) Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied LT-120-2 6.1 .6 T/Ac. .75T/Ac LT-107-1 5.2 1.0 T/Ac 1 T/Ac LT-107-2 4.9 1.2 T/Ac 1 T/Ac LT-107-4 5.5 0.5 1 T/Ac SECTION 7 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011123 Client: Calvin (John) Wehunt Advisor: Synagro vo- Predictive 2385 Norman Parker Synagro Cherryville, NC 28021 284 Boger Rd. .'..,$' Soil Report Mehlich-3 Extraction Mocksville, NC27028 _ Sampled County: Lincoln Links to Helpful Information Client ID: 324632 Advisor ID: 503079 Sampled: 10/23/2020 Received: 10/28/2020 Completed: 11/12/2020 Farm: LT-107 Sample ID: 4 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.5 120 - 160 0 50 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.36 1.24 4.0 70 1.2 5.5 72 44 50 15 27 160 113 50 50 54 0.1 3 Sample ID: 5 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.7 120 - 160 80 80 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.32 1.16 3.9 67 1.3 5.3 25 28 47 16 85 75 62 34 34 49 0.1 3 Sample ID: 6 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.7 120 - 160 70 90 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.46 1.15 4.1 68 1.3 5.4 29 24 49 16 57 61 54 44 44 56 0.1 2 North Carolina r Tobww Trust Fw►d C47mmisslan Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011123 Calvin (John) Wehunt Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011127 �5{i �141..tiL Client: Synagro Advisor: Synagro Predictive Synagro Synagro ;• 284 Boger Rd. 284 Boger Rd. $. Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Mocksville, NC 27028 Links to Helpful Information Sampled County: Lincoln Client ID: 503079 Advisor ID: 503079 Sampled: 10/23/2020 Received: 10/28/2020 completed: 11/12/2020 Farm: LT-107/ Jason Hewitt Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.0 120-200 90 60 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.81 1.08 5.0 64 1.8 5.2 22 39 46 14 86 113 85 70 70 42 0.1 2 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.2 120-200 90 100 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.60 1.29 3.4 48 1.8 4.9 22 20 34 11 42 138 100 66 66 35 0.1 3 Noah Carolina i� FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011127 Synagro Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 19-326-0589 Account No: 46442 Advisor: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Wayne Giber 1 Cherryville WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: LT-120 Date Received: 11/22/2019 Date of Report: 11 /25/2019 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na SS-1 NO3 N 16366 2 2 MIN 6.1 0.7 66 36 31 144 140 140 150 4.9 86 58 24 0.8 0 Crop Recommendations: Rec Uom Lime (Vacre) N P205 K20 S Mn Mn-AI Zn Cu B Mg Last Crop 1- Corn lb/acre 0.5 160 10 66 20 0 102 0 0 1.2 0 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.