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HomeMy WebLinkAboutWQ0010583_Residual Annual Report 2020_20210217Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* WQ0010583 Applicant/Permittee Davie County Email Notifications Does this need review by the hydrogeologist?* 0 Yes r No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Rease provide information on the person to be contacted by N B Staff Name * Brent Collins Email Address* brent.collins@emaresourcesinc.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................... Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 3367511441 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* WQ0010583 Fbs Current Existing permt number Applicant/Permittee Address* 123 Main St, Mocksvi Ile NC 27028 Facility Name * Davie County RLAP Please provide comments/notes on your current submittal below. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form} Engineering Rans, Specifications, Calculations, Bc.) 2020 Davie County Water System Annual Report - 4.43MB WQ0010583.pdf Upload only 1 PCF docurrent (less than 250 M3). Maniple docurrents must be combined into one R7F file unless file is larger than upload linit. * W By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature o 0041, W Submission Date 2/17/2021 February 17, 2021 DENR/Water Quality Section Non -Discharge Compliance Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report — Davie County Water System Treatment and Land Application of Residuals Permit No. WQ0010583 Dear Sir or Madam: Enclosed is one copy of the 2020 Annual Report for the above referenced land application permit. During 2020 EMA Resources, Inc. land applied 188.2 dry tons of wastewater residuals to 100.5 acres of private farmland. Please contact Brent Collins - Director of Technical Services if you have any further questions regarding this report. Sincerely, Z�fz G;2� Brent Collins Director of Technical Services brent.collins(cr,,emaresourcesinc.com Phone 336.751.1441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 ,EMA ---Resources, Inc. Davie County Water System 2020 Annual Report Residuals Land Application Permit No. WQ0010583 Prepared By: EMA Resources, Inc. Phone 336.751.1441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 ANNUAL LAND APPLICA110N [:P;H'FIFICA'I1ON FORM WQ Permit#: WQ0010583 County: Davie Year: Facility Name (as shown on permit): Davie County Water System 2020 Land Application Operator: EMA Resources Inc. Phone: 336-751-1441 Land application of residuals as allowed by the permit occurred during the past calendar year? ❑ Yes 0 No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: Total number of app Iication fields in thepen-nit: 19 Total number of fields utilized for land application during the year: 4 Total amount of dry tons applied during the year for all application sites: 198.2 Total number of acres utilizes for land application during the year: 1 100.5 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality. ❑ Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T . I 1 I 1 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at 4 monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, tinder penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Johnny Lambert - Utilities Director L J. Permittee Name and Title (type or print) S ature o ermittee Date / 6-1.01X 1 1/27/2021 Signature of Pfeparer* Date (if different from Permittee) Ala AAf;-4 ;-A n !'FF 1D—+ zm ❑ t.� —.1 1 S A RiC' At' I ) r Signature of Land Applier Date (if different from Permittee and Preparer) 7 in,) ! 1iCl ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: WWTP Name: Residual Analvsis Data WQ0010583 Davie County Water Systems NCO024872 Cooleemee WWTP Laboratory: 1) Waypoint Analytical 2) 3) 4) 5) Parameter Conc- Limit MMM Molybdenum Total Phosphorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Prep4rer * 0A-1 G - . -U r}- Date *Preparer is defined in 40 CFR Fart 503.9(r) and 15A NCAC 2T .1102 (26) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0010583 Facility Name: Davie County Water Systems Residual Source NC0024872 NPDES # or WQ#: WWTP Name: Cooleemee WWTP Residual Analvsis Data Laboratory: 1) Waypoint Analytical 2) 3) 4) 5) Parameter- Sample or ®--- ------------ ------------ "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.4(r) and 15A NCAC 2T .1102 (25) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Davie County Water System Total Dry Tons Applied (Annual): 15.79 Permit #: WQ0010583 Cation Exchange Capacity (non 503 only): Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: CeB2 Acres Used: 18 Acres Permitted: 18 Site #: NC-DVO08 Field #: 4 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phonis Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 LOJ 11 12 DT/Ac./ App. Event 0.88 Arsenic 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Cadmium 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Copper 0.067 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.067 Chromiuni 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Lead 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 denum Nickel 0.010 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Selenium 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Zinc 0.235 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.235 Total Phos- 2.122 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.122 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 1/27/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Davie County Water System Land Owner: Roger Spillman Operator: Roger Spillman WQ Permit #: WQ0010583 Field #: Annual Dry Tons Applied: 15.79 Site #: Predominant Soil Series: CeB2 Crop 1 Name: Fescue - Hay Crop 1 Max. PAN: 209 Crop 2 Name: 4 NC-DVO08 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 18 18 C y o Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) SoilPrecip. Cond. (Dry, Wet Moist) past 24 Drs. inches > � 5 Q w o o w -- * = - 7� rc * o' TKN mg/kg Z o ac o �. mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 6/11/20 84500 4.48 0.877 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 7.069 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 84500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 7.069 0.000 Lime Applied Annuallbs/acre 0.009 0.001 0.067 0.019 0.011 0.000 0.005 0.010 0.012 0.235 2.122 Date lbs/ac Prior Years Cumulative lbs/ac 5.194 1.017 108.346 0.645 42.143 0.054 2.554 12.121 5.087 332.505 Current Cumulative lbs/ac 5.203 1.018 108.413 0.664 42.154 0.054 2.559 12.131 5.099 332.740 Permitted C. P. L. R. * * * * 36 1 34 1 1338 267 15 374 1 89 2498 Permit PAN Limit 1 st/2nd Crop F 209 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/27/2021 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Davie County Water System Total Dry Tons Applied (Annual): Permit #: WQ0010583 Cation Exchange Capacity (non 503 only): Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: Acres Used: 18 Acres Permitted: 18 Site #: NC-DVO08 Field #: 44.93 M rC2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phonis Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 LOJ 11 12 DT/Ac./ App. Event 2.50 Arsenic 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.192 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.192 Chromiuni 0.055 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.055 Lead 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 denum Nickel 0.029 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Selenium 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.035 Zinc 0.669 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.669 Total Phos- 6.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.040 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 1/27/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Davie County Water System Land Owner: Roger Spillman Operator: Roger Spillman WQ Permit #: WQ0010583 Field #: Annual Dry Tons Applied: 44.93 Site #: Predominant Soil Series: MrC2 Crop 1 Name: Pearl Millet - Hay Crop 1 Max. PAN: 167 Crop 2 Name: NC-DVO08 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 18 18 C Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Sod Cond. Wet Moist) Precip. past 24 Hrs. inches F '5 o w *O o * 7� rc CD�. �. o TKN mg/kg Z o ac ° mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 6/4/20 91000 4.48 0.944 Davie County Dry <.5" S 0.5 0.3 1 8580 6420 1 172 7.612 NA Millet 6/5/20 130000 4.48 1.349 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 10.875 NA Millet 6/8/20 19500 4.48 0.202 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 1.631 NA Millet 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 240500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 20.118 0.000 Lime Applied Annuallbs/acre 0.027 0.002 0.192 0.055 0.030 0.000 0.015 0.029 0.035 0.669 6.040 Date lbs/ac Prior Years Cumulative lbs/ac 1.488 1.016 108.116 0.601 42.098 0.054 2.55 12.099 5.081 331.644 Current Cumulative lbs/ac 1.515 1.018 108.308 0.656 42.128 0.054 2.565 12.128 5.116 332.313 Permitted C. P. L. R. * * * * 36 34 1 1338 267 15 374 1 89 1 2498 Permit PAN Limit 1 st/2nd Crop 167 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/27/2021 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Davie County Water System Total Dry Tons Applied (Annual): Permit #: WQ0010583 Cation Exchange Capacity (non 503 only): Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: Acres Used: 20 Acres Permitted: 20 Site #: NC-DVO08 Field #: 49.78 M rB2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phonis Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 LOJ 11 12 DT/Ac./ App. Event 2.49 Arsenic 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.191 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.191 Chromiuni 0.055 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.055 Lead 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 denum Nickel 0.029 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Selenium 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.035 Zinc 0.667 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.667 Total Phos- 6.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.023 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 1/27/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Davie County Water System Land Owner: Roger Spillman Operator: Roger Spillman WQ Permit #: WQ0010583 Field #: Annual Dry Tons Applied: 49.78 Site #: Predominant Soil Series: MrB2 Crop 1 Name: Pearl Millet - Hay Crop 1 Max. PAN: 198 Crop 2 Name: NC-DVO08 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 20 20 C Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Sod Cond. Wet Moist) Precip. past 24 Hrs. inches F '5 o w *O o * 7� rc CD�. �. o TKN mg/kg Z o ac ° mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 6/2/20 91000 4.48 0.850 Davie County Dry <.5" S 0.5 0.3 1 8580 6420 1 172 6.851 NA Millet 6/3/20 130000 4.48 1.214 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 9.787 NA Millet 6/4/20 45500 4.48 0.425 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 3.426 NA Millet 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 266500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 20.064 1 0.000 Lime Applied Annuallbs/acre 0.027 0.002 0.191 0.055 0.030 0.000 0.015 0.029 0.035 0.667 6.023 Date lbs/ac Prior Years Cumulative lbs/ac 5.191 1.017 108.219 0.621 42.118 0.054 2.552 12.109 5.084 332.032 Current Cumulative lbs/ac 5.218 1.019 108.410 0.676 42.148 0.054 2.567 12.138 5.119 332.699 Permitted C. P. L. R. * * * * 36 34 1 1338 267 15 374 1 89 1 2498 Permit PAN Limit 1 st/2nd Crop 198 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/27/2021 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Davie County Water System Total Dry Tons Applied (Annual): Permit #: WQ0010583 Cation Exchange Capacity (non 503 only): Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: Acres Used: 44.5 Acres Permitted: 44.5 Site #: NC-DVO08 Field #: 77.70 M rB2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phonis Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 LOJ 11 12 DT/Ac./ App. Event 1.75 Arsenic 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.134 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.134 Chromiuni 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.039 Lead 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 denum Nickel 0.020 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Selenium 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.025 Zinc 0.468 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.468 Total Phos- 4.225 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.225 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 1/27/2021 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Davie County Water System Land Owner: Roger Spillman Operator: Roger Spillman WQ Permit #: WQ0010583 Field #: Annual Dry Tons Applied: 77.70 Site #: Predominant Soil Series: MrB2 Crop 1 Name: Pearl Millet - Hay Crop 1 Max. PAN: 198 Crop 2 Name: NC-DVO08 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 44.5 44.5 C Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Sod Cond. Wet Moist) Precip. past 24 Hrs. inches F '5 o w *O o * 7� rc CD�. �. o TKN mg/kg Z o ac ° mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 6/8/20 110500 4.48 0.464 Davie County Dry <.5" S 0.5 0.3 1 8580 6420 1 172 3.739 NA Millet 6/9/20 130000 4.48 0.546 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 4.399 NA Millet 6/10/20 130000 4.48 0.546 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 4.399 NA Millet 6/11/20 45500 4.48 0.191 Davie County Dry <.5" S 0.5 0.3 8580 6420 172 1.540 NA Millet 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 416000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 14.076 0.000 Lime Applied Annuallbs/acre 0.019 0.002 0.134 0.039 0.021 0.000 0.010 0.020 0.025 0.468 4.225 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.019 0.002 0.134 0.039 0.021 0.000 0.010 0.020 0.025 0.468 Permitted C. P. L. R. * * * * 36 1 34 1 1338 267 15 1 1 374 1 89 1 2498 Permit PAN Limit 1 st/2nd Crop 198 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/27/2021 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) Waypointo ANALYTICAL 6/29/2020 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 20-169-0050 Client Project Description: Davie County Coolgemee, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 6/17/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule August 2017) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Danyale Love Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Ijp, Page 1 of 8 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2021 Arizona State Program AZ0816 08/30/2020 Arkansas State Program 88-0650 02/07/2021 California State Program 2904 05/10/2020 Florida State Program - NELAP E871157 06/30/2020 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2020 Illinois State Program - NELAP 200078 10/10/2020 Kentucky State Program 80215 06/30/2020 Kentucky State Program KY90047 12/31/2020 Louisiana State Program - NELAP 04015 06/30/2020 Mississippi State Program MS 05/10/2020 North Carolina State Program 415 12/31/2020 Oklahoma State Program 9311 08/31/2020 Pennsylvania State Program - NELAP 68-03195 05/31/2021 South Carolina State Program 84002 06/30/2021 South Carolina State Program 84002 06/30/2020 Tennessee State Program 02027 02/11/2023 Tennessee A21LA ISO 17025:2017 4313.01 10/31/2021 Texas State Program - NELAP T104704180 09/30/2020 Virginia State Program 00106 06/30/2020 Virginia State Program - NELAP 460181 09/14/2020 Washington State Program C1018 07/31/2020 Page 1 of 1 00001/20-169-0050 Page 2 of 8 Waypoint ANALYTICAL Report Number: 20-169-0050 Client Project Description: Davie County Coolgemee, NC Lab No Client Sample ID 94521 Cooleemee WWTP 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Matrix Date Collected Solids 06/16/202010:00 Date Received 06/17/2020 Page 3 of 8 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Davie County Lab Report Number: 20-169-0050 Date: 6/29/2020 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 94521 (Cooleemee WWTP) Analyte: Calcium QC Batch No: 1-497348/1-496886 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Analyte: Iron QC Batch No: 1-497348/1-496886 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 8 waypANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 20-169-0050 Lab No : 94521 Sample ID : Cooleemee WWTP 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Davie County Information : Coolgemee, NC REPORT OFANALYSIS Report Date : 06/29/2020 Received : 06/17/2020 Danyale Love Project Manager Matrix: Solids Sampled: 6/ 16/ 2020 10:00 Test Results Units MDL MQL DF Date / Time Analyzed By Analytical Method Moisture 95.5 % 0.010 1 06/22/20 16:16 FMM SW-DRYWT Ammonia Nitrogen 6420 mg/Kg - dry 556 556 1 06/26/20 15:00 JPJ 4500NH3C-2011 Nitrate+Nitrite-N 172 mg/Kg - dry 110 110 1 06/25/20 14:35 ZBD 4500NO3F-2011 Organic N 2156 mg/Kg - dry 555.6 555.6 1 06/23/20 15:32 DH CALCULATION pH 11.5 S.U. 1 06/25/20 06:56 JSL 9045D Total Solids 4.48 % 0.010 0.010 1 06/22/20 16:16 FMM 2540G-2011 Total Volatile Solids 25.7 % 0.010 0.010 1 06/22/20 16:16 FMM 2540G-2011 Total Kjeldahl Nitrogen 8580 mg/Kg - dry 1110 1 06/23/20 15:32 CLP 4500NORGD-2011 Phosphorus 1210 mg/Kg - dry 61.3 111 1 06/18/20 23:41 JTR 6010D Aluminum 8020 mg/Kg - dry 103 111 1 06/18/20 23:41 JTR 6010D Arsenic <5.33 mg/Kg - dry 5.33 11.1 1 06/18/20 23:41 JTR 6010D Cadmium <0.444 mg/Kg - dry 0.444 2.22 1 06/18/20 23:41 JTR 6010D Calcium 36900 mg/Kg - dry 860 1110 1 06/18/20 23:41 JTR 6010D Chromium 11.1 mg/Kg - dry 5.24 5.56 1 06/18/20 23:41 JTR 6010D Copper 38.4 mg/Kg - dry 6.89 11.1 1 06/18/20 23:41 JTR 6010D Iron 18300 mg/Kg - dry 189 222 1 06/18/20 23:41 JTR 6010D Lead 6.043 mg/Kg - dry 4.00 6.67 1 06/18/20 23:41 JTR 6010D Magnesium 711 mg/Kg - dry 57.3 111 1 06/18/20 23:41 JTR 6010D Manganese 132 mg/Kg - dry 7.22 11.1 1 06/18/20 23:41 JTR 6010D Mercury <0.0776 mg/Kg - dry 0.0776 0.351 1 06/24/20 13:01 DDB 7471A Molybdenum <3.00 mg/Kg - dry 3.00 5.56 1 06/18/20 23:41 JTR 6010D Nickel 5.73 mg/Kg - dry 2.67 5.56 1 06/18/20 23:41 JTR 6010D Potassium 653 mg/Kg - dry 137 222 1 06/18/20 23:41 JTR 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions L Limit Exceeded MQL Method Quantitation Limit Page 5 of 8 waypANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 20-169-0050 Lab No : 94521 Sample ID : Cooleemee WWTP 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Project Davie County Information : Coolgemee, NC REPORT OFANALYSIS Report Date : 06/29/2020 Received : 06/17/2020 Danyale Love Project Manager Matrix: Solids Sampled: 6/ 16/ 2020 10:00 Test Results Units MDL MQL DF Date / Time Analyzed By Analytical Method Selenium <7.11 mg/Kg - dry 7.11 11.1 1 06/18/20 23:41 JTR 6010D Sodium 5203 mg/Kg - dry 289 556 1 06/18/20 23:41 JTR 6010D Zinc 134 mg/Kg - dry 18.0 27.8 1 06/18/20 23:41 JTR 6010D Sulfur 829 mg/Kg - dry 115 222 1 06/18/20 23:41 JTR 6010D Sodium Absorption Ratio 0.153 Ratio 0.01 0.01 1 06/18/20 23:41 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 6 of 8 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 20-169-0050 Shipping Method ® Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: T99 Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: IHannah R. Brown Date & Time: 06/17/2020 10:57:37 Page 7 of 8 CAL N a Y +r LL �y��� � E RE, •(D a m a Z N 0 0 z Q]m All G C N J y n c� ELI=x ¢e E U 01 A 3 y a a y act II a o$ c0❑ tea❑. o _Q O CD +� Vi C O❑ N a R V �n p T H Y a.i T V u x 2 Z x 2 z V ¢ �c�pv7 N 1/"''�^ .� VI N 7� a 0 x ❑j �i S6 CL m ❑b. 4 rn a m V❑ u, i� x_ C u iu G cr z O a w w ^ v LL ' O _ o CL c -� N E ? } V d 1'1'S di u o A �V C❑❑ 7 L = VJ Q A snl c Y 7 d m H w C] a n co A o G m SPIOS lelol � U a V N :)lu25JOi9Ie4'N N ca EIUOW� ry o n E z � _ b'1N�11 o � ar I76C d o (00 09) �I��aW a "a L> s v4i O c d H u m Q a a;lsodeua(�� ao ge�(91 �4 T T a a -a a (Aa)j al japd) KuleW 3. v t c c c � d � vaule;uo:);o eaquanry � � � n t � � Z a Q0 w m`Lieco nc c a 1cr , m a v0 N\N a m CDw m q C m a _ o tlm 4-. r v •c T V u ED a a co L p a co `o — f O V p M CL m E n a a =O C a3 'u 7 E �a E 0z= d 3 e _wti 4 R N '7 A Z X ro C N a<tna p a n m V T f [n u uJ r- > a M. Q �1 e.i1 Page 8 of 8 aceAnalytical National Center for Testing & Innovation AW ANALYTICAL REPORT June 02, 2020 EMA Resources Sample Delivery Group Samples Received: Project Number: Description: Report To: L1221225 05/22/2020 DAVIE COUNTY Sludge Mr. Brent Collins 755 Yadkinville Road Entire Report Reviewed By Mocksville, NC 27028 ��MJarda ,' P�ti Cassandra Foster Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 1 of 21 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page 1 FP Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 FS COOLEEMEE WWTP L1221225-01 5 Fn Qc: Quality Control Summary 7 Wet Chemistry by Method 9012 B 7 Fr Wet Chemistry by Method 9034-9030B 8 Wet Chemistry by Method 9045D 9 FC Wet Chemistry by Method D93/1010A 10 F Mercury by Method 7470A 11 Metals (ICP) by Method 6010D 12 [Al Volatile Organic Compounds (GC/MS) by Method 8260D 13 Chlorinated Acid Herbicides (GC) by Method 8151A 15 RC Pesticides (GC) by Method 8081B 16 Semi Volatile Organic Compounds (GC/MS) by Method 8270E 17 GI: Glossary of Terms 19 al: Accreditations & Locations 20 Sc: Sample Chain of Custody 21 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 2 of 21 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time COOLEEMEE WWTP L1221225-01 Waste Roy Whitaker 05/21/2014:00 05/22/20 08:00 , C P Method Preparation by Method 1311 Preparation by Method 1311 Wet Chemistry by Method 9012 B Wet Chemistry by Method 9034-9030B Wet Chemistry by Method 9045D Wet Chemistry by Method D93/1010A Mercury by Method 7470A Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Chlorinated Acid Herbicides (GC) by Method 8151A Pesticides (GC) by Method 8081B Semi Volatile Organic Compounds (GC/MS) by Method 8270E Batch WG1482620 WG1484814 WG1482372 WG1482933 WG1482434 WG1485097 WG1483293 WG1483563 WG1485165 WG1483266 WG1483649 WG1483651 Dilution Preparation Analysis date/time date/time 1 05/27/20 09:20 05/27/20 09:20 1 05/30/2019:59 05/30/2019:59 1 05/27/2016:00 05/27/20 20:06 1 05/27/20 23:50 05/27/20 23:50 1 05/26/20 20:09 05/29/20 08:10 1 06/01/2016:35 06/01/2016:35 1 05/28/20 07:55 05/28/2012:03 1 05/28/2018:42 05/29/20 03:45 1 06/01/2014:18 06/01/2014:18 1 05/28/20 09:29 05/28/20 2143 1 05/28/2016:24 06/01/2015:14 1 05/30/2017:15 05/31/2018:32 Analyst IDW CGD SDL LDT KPS MJA ABL TRB BMB RP RP LEA Location FC Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Fn Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Fr Mt. Juliet, TN Mt. Juliet, TN FC Mt. Juliet, TN Mt. Juliet, TN �GI SAI RC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 3 of 21 CASE NARRATIVE ONE LAB. NATIONWIDE. * All sample aliquots were received at the correct temperature, in the proper containers, with the FP appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. 0 Fr FC 7 GI Cassandra Foster Project Manager RC Project Narrative All Reactive Cyanide results reported in the attached report were determined as totals using method 9012B. All Reactive Sulfide results reported in the attached report were determined as totals using method 9034/9030B. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 4 of 21 COOLEEMEE WWTP Collected date/time: 05/21/20 14:00 Preparation by Method 1311 SAMPLE RESULTS - 01 L1221225 Result Qualifier Prep Batch Analyte date / time TCLP Extraction 5/27/2020 9:20:40 AM WG1482620 TCLP ZHE Extraction - 5/30/2020 7:59:56 PM WG1484814 Fluid 1 5/27/2020 9:20:40 AM WG1482620 Initial pH 6.72 5/27/2020 9:20:40 AM WG1482620 Final pH 4.99 5/27/2020 9:20:40 AM WG1482620 Wet Chemistry by Method 9012 B Result Qualifier RDL Dilution Analysis Batch Analyte mg/kg mg/kg date / time Reactive Cyanide ND 0.250 1 05/27/2020 20:06 WG1482372 Wet Chemistry by Method 9034-9030B Result Qualifier RDL Analyte mg/kg mg/kg Reactive Sulfide ND 25.0 Wet Chemistry by Method 9045D Dilution Analysis Batch date / time 1 05/27/2020 23:50 WG1482933 Result Qualifier Dilution Analysis Batch Analyte su date / time Corrosivity by pH 7.18 T8 1 05/29/2020 08:10 WG1482434 Sample Narrative: L1221225-01 WG1482434: 7.18 at 20C Wet Chemistry by Method D93/1010A Result Analyte Deg. F Ignitability DNI at170 Mercury by Method 7470A Qualifier Dilution Analysis Batch date / time 1 06/01/202016:35 WG1485097 Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Mercury ND 0.0100 0.20 Metals (ICP) by Method 6010D Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Arsenic ND 0.100 5 Barium 0.305 0.100 100 Cadmium ND 0.100 1 Chromium ND 0.100 5 Lead ND 0.100 5 Selenium 0.111 0.100 1 Silver ND 0.100 5 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Benzene ND 0.0500 0.50 Carbon tetrachloride ND J3 0.0500 0.50 Chlorobenzene ND 0.0500 100 Chloroform ND 0.250 6 ACCOUNT: PROJECT: EMA Resources DAVIE COUNTY Dilution Analysis Batch date / time 1 05/28/202012:03 WG1483293 Dilution Analysis Batch date / time 1 05/29/2020 03:45 WG1483563 1 05/29/2020 03:45 WG1483563 1 05/29/2020 03:45 WG1483563 1 05/29/2020 03:45 WG1483563 1 05/29/2020 03:45 WG1483563 1 05/29/2020 03:45 WG1483563 1 05/29/2020 03:45 WG1483563 ONE LAB. NATIONWIDE. * Fp Fc FS Fn Fc �GI SAI Rc Dilution Analysis Batch date / time 1 06/01/202014:18 WG1485165 1 06/01/202014:18 WG1485165 1 06/01/202014:18 WG1485165 1 06/01/202014:18 WG1485165 SDG: DATE/TIME: PAGE: L1221225 06/02/20 22:26 5 of 21 COOLEEMEE WWTP SAMPLE RESULTS - 01 Collected date/time: 05/21/20 14:00 L1221225 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Dilution Analysis Analyte mg/I mg/I mg/I date/time 1,2-Dichloroethane ND 0.0500 0.50 1 06/01/202014:18 1,1-Dichloroethene ND 0.0500 0.70 1 06/01/202014:18 2-Butanone (MEK) ND 0.500 200 1 06/01/202014:18 Tetrachloroethene ND 0.0500 0.70 1 06/01/202014:18 Trichloroethene ND 0.0500 0.50 1 06/01/202014:18 Vinyl chloride ND 0.0500 0.20 1 06/01/202014:18 (S) Toluene-dH 105 80.0-120 0610112020 14.18 (S) 4-Bromofluorobenzene 100 77.0-126 0610112020 14.18 (S) 1,2-Dichloroethane-d4 ill 70.0-130 061011202014.18 Chlorinated Acid Herbicides (GC) by Method 8151A Batch WG1485165 WG1485165 WG1485165 WG1485165 WG1485165 WG1485165 WG1485165 WG1485165 WG1485165 ONE LAB. NATIONWIDE. * Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time 2,4,5-TP (Silvex) ND 0.00200 1 1 05/28/2020 2143 WG1483266 2,4-D ND 0.00200 10 1 05/28/2020 2143 WG1483266 (S) Z4-Dichlorophenyl Acetic Acid 58.6 14.0-158 051281202021.43 WG1483266 Pesticides (GC) by Method 8081B Result Qualifier RDL Limit Dilution Analysis Analyte mg/I mg/I mg/I date/time Chlordane ND 0.00500 0.03 1 06/01/202015:14 Endrin ND 0.00500 0.02 1 06/01/202015:14 Heptachlor ND 0.00500 0.0080 1 06/01/202015:14 Lindane ND 0.00500 0.40 1 06/01/202015:14 Methoxychlor ND J4 0.00500 10 1 06/01/202015:14 Toxaphene ND 0.0100 0.50 1 06/01/202015:14 (S) Decochlorobiphenyl 92.6 10.0-128 0610112020 15.14 (S) Tetrochloro-m-xylene 86.7 10.0-127 0610112020 15.14 Semi Volatile Organic Compounds (GC/MS) by Method 8270E Analyte 1,4-Dichlorobenzene 2,4-Dinitrotoluene Hexachlorobenzene Hexachloro-1,3-butadiene Hexachloroethane Nitrobenzene Pyridine 3&4-Methyl Phenol 2-Methylphenol Pentachlorophenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol (S) 2-Fluorophenol (S) Phenol-d5 (S) Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) Z4, 6-Tribromophenol (S) p-Terphenyl-d14 Batch WG1483649 WG1483649 WG1483649 WG1483649 WG1483649 WG1483649 WG1483649 WG1483649 Result Qualifier RDL Limit Dilution Analysis Batch mg/I mg/I mg/I date/time ND 0.100 7.50 1 05/31/202018:32 WG1483651 ND 0.100 0.13 1 05/31/202018:32 WG1483651 ND 0.100 0.13 1 05/31/202018:32 WG1483651 ND 0.100 0.50 1 05/31/202018:32 WG1483651 ND 0.100 3 1 05/31/202018:32 WG1483651 ND 0.100 2 1 05/31/202018:32 WG1483651 ND 0.100 5 1 05/31/202018:32 WG1483651 ND 0.100 400 1 05/31/202018:32 WG1483651 ND 0.100 200 1 05/31/202018:32 WG1483651 ND 0.100 100 1 05/31/202018:32 WG1483651 ND 0.100 400 1 05/31/202018:32 WG1483651 ND 0.100 2 1 05/31/202018:32 WG1483651 48.1 10.0-120 051311202018.32 WG1483651 30.1 10.0-120 051311202018.32 WG1483651 65.4 10.0-127 051311202018.32 WG1483651 74.3 10.0-130 051311202018.32 WG1483651 58.5 10.0-155 051311202018.32 WG1483651 86.9 10.0-128 051311202018.32 WG1483651 Fp Fc FS Fn FA Fc F, SAI Rc ACCOUNT: EMA Resources PROJECT: SDG: DATE/TIME: PAGE: DAVIE COUNTY L1221225 06/02/20 22:26 6 of 21 WG1482372 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9012 B L1221225-01 Method Blank (MB) (MB) R3532323-1 05/27/2019:54 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg Reactive Cyanide U 0.0390 0.250 Original Sample (OS) • Duplicate (DUP) (OS) • (DUP) R3532323-3 05/27/20 20:00 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/kg %_ Reactive Cyanide ND 1 0.000 20 Laboratory Control Sample (LCS) (LCS) R3532323-2 05/27/20 19:55 Spike Amount LCS Result LCS Rec. Analyte mg/kg mg/kg Reactive Cyanide 2.50 2.72 109 Rec. Limits LCS Qualifier 85.0-115 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) ONE LAB. NATIONWIDE. * (OS) • (MS) R3532323-4 05/27/20 20:09 • (MSD) R3532323-5 05/27/20 20:10 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg Reactive Cyanide 1.67 1.67 1.63 89.3 86.5 1 75.0-125 2.80 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 7 of 21 WG1482933 Wet Chemistry by Method 9034-9030B Method Blank (MB) (MB) R3532371-1 05/27/20 23:50 MB Result Analyte mg/kg Reactive Sulfide U MB Qualifier MB MDL MB RDL mg/kg mg/kg 7.63 25.0 L1221084-04 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1221225-01 (OS) L1221034-04 05/27/20 23:50 • (DUP) R3532371-3 05/27/20 23:50 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/kg mg/kg %_ Reactive Sulfide ND ND 1 0.000 20 Laboratory Control Sample (LCS) (LCS) R3532371-2 05/27/20 23:50 Spike Amount LCS Result LCS Rec. Analyte mg/kg mg/kg Reactive Sulfide 100 88.1 88.1 Rec. Limits LCS Qualifier 70.0-130 L1221225-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) ONE LAB. NATIONWIDE. * (OS) L1221225-01 05/27/20 23:50 • (MS) R3532371-4 05/27/20 23:50 • (MSD) R3532371-5 05/27/20 23:50 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Sulfide 100 ND 95.8 95.5 95.8 95.5 1 70.0-130 0.309 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 3 of 21 WG1482434 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9045D L1221225-01 Laboratory Control Sample (LCS) (LCS) R3532973-1 05/29/20 0310 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte su su Corrosivity by pH 10.0 9.95 99.5 99.0-101 Sample Narrative: LCS: 9.95 at 22C ONE LAB. NATIONWIDE. * ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 9 of 21 WG1485097 QUALITY CONTROL SUMMARY Wet Chemistry by Method D93/1010A L1221225-01 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3533850-1 06/01/2016:35 • (LCSD) R3533850-2 06/01/2016:35 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte Deg.F Deg.F Deg.F Ignitability 124 129 127 104 102 95.6-104 1.57 10 ONE LAB. NATIONWIDE. * ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 10 of 21 ■ WG1483293 Mercury by Method 7470A Method Blank (MB) QUALITY CONTROL SUMMARY L1221225-01 (MB) R3532599-1 05/23/201152 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Mercury U 0.00330 0.0100 Laboratory Control Sample (LCS) (LCS) R3532599-2 05/28/201154 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I Mercury 0.0300 0.0300 100 80.0-120 L1221479-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) ONE LAB. NATIONWIDE. * (OS) L1221479-02 05/23/20 11:55 • (MS) R3532599-3 05/23/20 11:57 • (MSD) R3532599-4 05/23/20 1159 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I Mercury 0.0300 ND 0.0304 0.0313 101 104 1 75.0-125 2.80 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 11 of 21 WG1483563 Metals (ICP) by Method 6010D Method Blank (MB) QUALITY CONTROL SUMMARY L1221225-01 (MB) R3532894-1 05/29/20 0340 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Arsenic U 0.0333 0.100 Barium U 0.0333 0.100 Cadmium U 0.0333 0.100 Chromium U 0.0333 0.100 Lead U 0.0333 0.100 Selenium U 0.0333 0.100 Silver U 0.0333 0.100 Laboratory Control Sample (LCS) (LCS) R3532394-2 05/29/20 03:42 Spike Amount LCS Result LCS Rec. Rec. Limits Analyte mg/I mg/I Arsenic 10.0 9.78 97.8 80.0-120 Barium 10.0 9.67 96.7 80.0-120 Cadmium 10.0 9.74 97.4 80.0-120 Chromium 10.0 9.51 95.1 80.0-120 Lead 10.0 9.65 96.5 80.0-120 Selenium 10.0 9.82 98.2 80.0-120 Silver 2.00 1.82 90.9 80.0-120 LCS Qualifier L1221225-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1221225-01 05/29/20 03:45 • (MS) R3532394-4 05/29/20 03:50 • (MSD) R3532394-5 05/29/20 03:52 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits Analyte mg/I mg/I mg/I mg/I Arsenic 10.0 ND 9.59 9.60 95.0 95.2 1 75.0-125 Barium 10.0 0.305 9.76 9.83 94.5 95.2 1 75.0-125 Cadmium 10.0 ND 9.50 9.59 95.0 95.9 1 75.0-125 Chromium 10.0 ND 9.21 9.35 92.1 93.5 1 75.0-125 Lead 10.0 ND 9.44 9.50 94.4 95.0 1 75.0-125 Selenium 10.0 0.111 9.45 9.59 93.4 94.8 1 75.0-125 Silver 2.00 ND 1.76 1.77 87.9 88.3 1 75.0-125 MS Qualifier MSD Qualifier RPD 0.169 0.709 0.968 1.53 0.723 1.52 0.556 ONE LAB. NATIONWIDE. * RPD Limits 20 20 20 20 20 20 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 12 of 21 WG1485165 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1221225-01 ONE LAB. NATIONWIDE. * Method Blank (MB) (MB) R3533742-3 06/01/201154 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Benzene U 0.0167 0.0500 Carbon tetrachloride U 0.0167 0.0500 Chlorobenzene U 0.0167 0.0500 Chloroform U 0.0833 0.250 1,2-Dichloroethane U 0.0167 0.0500 1,1-Dichloroethene U 0.0167 0.0500 2-Butanone (MEK) U 0.167 0.500 Tetrachloroethene U 0.0167 0.0500 Trichloroethene U 0.0167 0.0500 Vinyl chloride U 0.0167 0.0500 (S) Toluene-dH 106 80.0-120 (S) 4-Bromofluorobenzene 82.9 77.0-126 (S) 1,2-Dichloroethane-d4 109 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3533742-1 06/01/20 09:45 • (LCSD) R3533742-2 06/01/2010:53 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits Analyte mg/I mg/I mg/I Benzene 0.250 0.261 0.237 104 94.8 70.0-123 Carbon tetrachloride 0.250 0.301 0.239 120 95.6 68.0-126 Chlorobenzene 0.250 0.245 0.230 98.0 92.0 80.0-121 Chloroform 0.250 0.254 0.233 102 93.2 73.0-120 1,2-Dichloroethane 0.250 0.281 0.253 112 101 70.0-128 1,1-Dichloroethene 0.250 0.289 0.268 116 107 71.0-124 2-Butanone (MEK) 1.25 1.17 1.00 93.6 80.0 44.0-160 Tetrachloroethene 0.250 0.269 0.236 108 94.4 72.0-132 Trichloroethene 0.250 0.285 0.247 114 98.8 78.0-124 Vinyl chloride 0.250 0.263 0.220 105 88.0 67.0-131 (S) Toluene-dH 107 105 80.0-120 (S) 4-Bromofluorobenzene 101 102 77.0-126 (S) 1,2-Dichloroethane-d4 110 108 70.0-130 LCS Qualifier LCSD Qualifier RPD RPD Limits 9.64 20 J3 23.0 20 6.32 20 8.62 20 10.5 20 7.54 20 15.7 20 13.1 20 14.3 20 17.8 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 13 of 21 ONE LAB. NATIONWIDE. * WG1485165 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1221225-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) • (MS) R3533742-4 06/01/20 17:45 • (MSD) R3533742-5 06/01/20 13 05 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I Benzene 0.250 0.246 0.228 98.4 91.2 1 17.0-158 7.59 27 Carbon tetrachloride 0.250 0.256 0.248 102 99.2 1 23.0-159 3.17 28 Chlorobenzene 0.250 0.240 0.216 96.0 86.4 1 33.0-152 10.5 27 Chloroform 0.250 0.260 ND 104 92.8 1 29.0-154 11.4 28 1,2-Dichloroethane 0.250 0.297 0.251 119 100 1 29.0-151 16.8 27 1,1-Dichloroethene 0.250 0.254 0.227 102 90.8 1 11.0-160 11.2 29 2-Butanone (MEK) 1.25 1.60 1.35 128 108 1 10.0-160 16.9 32 Tetrachloroethene 0.250 0.235 0.222 94.0 88.8 1 10.0-160 5.69 27 Trichloroethene 0.250 0.263 0.238 105 95.2 1 10.0-160 9.98 25 Vinyl chloride 0.250 0.222 0.207 88.8 82.8 1 10.0-160 6.99 27 (S) Toluene-dH 106 106 80.0-120 (S) 4-Bromofluorobenzene 99.7 106 77.0-126 (S) 1,2-Dichloroethane-d4 117 115 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 14 of 21 WG1483266 Chlorinated Acid Herbicides (GC) by Method 8151A Method Blank (MB) (MB) R3532975-1 05/23/20 2006 MB Result Analyte mg/I 2,4-D U 2,4,5-TP (Silvex) U (S) Z4-Dichlorophenyl Acetic 64.8 Acid QUALITY CONTROL SUMMARY L1221225-01 MB Qualifier MB MDL MB RDL mg/I mg/I 0.000667 0.00200 0.000667 0.00200 14.0-158 Laboratory Control Sample (LCS) (LCS) R3532975-2 05/23/20 2022 Spike Amount LCS Result LCS Rec. Analyte mg/I mg/I 2,4-D 0.0500 0.0319 63.8 2,4,5-TP (Silvex) 0.0500 0.0374 74.8 (S) Z4-Dichlorophenyl Acetic 672 Acid Rec. Limits LCS Qualifier 50.0-120 50.0-125 14.0-158 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) • (MS) R3532975-3 05/29/20 03:40 • (MSD) R3532975-4 05/29/20 03:57 Spike Amount Original Result MS Result MSD Result MS Rec. Analyte mg/I mg/I mg/I 2,4-D 0.0500 0.0314 0.0312 62.8 2,4,5-TP (Silvex) 0.0500 0.0368 0.0367 73.6 (S) Z4-Dichlorophenyl Acetic 66.0 Acid ONE LAB. NATIONWIDE. * MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 62.4 1 50.0-120 0.639 20 73.4 1 50.0-125 0.272 20 66.4 14.0-158 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 15 of 21 WG1483649 Pesticides (GC) by Method 8081B Method Blank (MB) QUALITY CONTROL SUMMARY L1221225-01 (MB) R3533312-1 06/01/2013:46 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Gamma BHC U 0.00167 0.00500 Endrin U 0.00167 0.00500 Heptachlor U 0.00167 0.00500 Methoxychlor U 0.00167 0.00500 Chlordane U 0.00167 0.00500 Toxaphene U 0.00333 0.0100 (S) Decachlorobiphenyl 96.3 10.0-128 (S) Tetrochloro-m-xylene 88.9 10.0-127 Laboratory Control Sample (LCS) (LCS) R3533812-2 06/01/20 1400 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I Gamma BHC 0.0100 0.00974 97.4 55.0-129 Endrin 0.0100 0.0101 101 57.0-134 Heptachlor 0.0100 0.00851 85.1 27.0-132 Methoxychlor 0.0100 0.0156 156 54.0-155 J4 (S) Decachlorobiphenyl 94.9 10.0-128 (S) Tetrochloro-m-xylene 90.1 10.0-127 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) • (MS) R3533312-3 06/01/20 14:30 • (MSD) R3533312-4 06/01/20 14:45 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte mg/I mg/I mg/I Gamma BHC 0.0100 0.00974 0.00942 97.4 94.2 Endrin 0.0100 0.0100 0.00979 100 97.9 Heptachlor 0.0100 0.00851 0.00813 85.1 81.3 Methoxychlor 0.0100 0.0155 0.0150 155 150 (S) Decachlorobiphenyl 83.2 80.6 (S) Tetrochloro-m-xylene 90.1 87.7 Dilution Rec. Limits MS Qualifier MSD Qualifier RPD 1 14.0-141 3.34 1 10.0-160 2.12 1 16.0-136 4.57 1 10.0-160 P 3.28 10.0-128 10.0-127 ONE LAB. NATIONWIDE. * RPD Limits 40 39 40 34 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 16 of 21 WG1483651 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1221225-01 Method Blank (MB) (MB) R3533553-2 05/31/201703 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I 1,4-Dichlorobenzene U 0.0333 0.100 2,4-Dinitrotoluene U 0.0333 0.100 Hexachlorobenzene U 0.0333 0.100 Hexachloro-1,3-butadiene U 0.0333 0.100 Hexachloroethane U 0.0333 0.100 Nitrobenzene U 0.0333 0.100 Pyridine U 0.0333 0.100 2-Methylphenol U 0.0333 0.100 3&4-Methyl Phenol U 0.0333 0.100 Pentachlorophenol U 0.0333 0.100 2,4,5-Trichlorophenol U 0.0333 0.100 2,4,6-Trichlorophenol U 0.0333 0.100 (S) Nitrobenzene-d5 56.0 10.0-127 (S) 2-Fluorobiphenyl 64.8 10.0-130 (S) p-Terphenyl-d14 76.5 10.0-128 (S) Phenol-d5 23.9 10.0-120 (S) 2-Fluorophenol 39.5 10.0-120 (S) 2,4, 6-Tribromophenol 476 10. 0-155 Laboratory Control Sample (LCS) ONE LAB. NATIONWIDE. * (LCS) R3533553-1 05/31/20 16:47 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I 1,4-Dichlorobenzene 0.500 0.345 69.0 18.0-120 2,4-Dinitrotoluene 0.500 0.385 77.0 49.0-124 Hexachlorobenzene 0.500 0.339 67.8 44.0-120 Hexachloro-1,3-butadiene 0.500 0.292 58.4 19.0-120 Hexachloroethane 0.500 0.363 72.6 15.0-120 Nitrobenzene 0.500 0.348 69.6 27.0-120 Pyridine 0.500 0.183 36.6 10.0-120 2-Methylphenol 0.500 0.325 65.0 28.0-120 3&4-Methyl Phenol 0.500 0.326 65.2 31.0-120 Pentachlorophenol 0.500 0.442 88.4 23.0-120 2,4,5-Trichlorophenol 0.500 0.379 75.8 44.0-120 2,4,6-Trichlorophenol 0.500 0.370 74.0 42.0-120 (S) Nitrobenzene-d5 53.2 10.0-127 (S) 2-Fluorobiphenyl 71.3 10.0-130 (S) p-Terphenyl-d14 77.6 10.0-128 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 17 of 21 WG1483651 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1221225-01 Laboratory Control Sample (LCS) ONE LAB. NATIONWIDE. * (LCS) R3533553-1 05/31/20 16:47 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I (S) Phenol-d5 279 10.0-120 (S) 2-Fluorophenol 44.0 10.0-120 (S) 2,4, 6-Tribromophenol 62.5 10. 0-155 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 18 of 21 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. * Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and ifyou have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). RDL Reported Detection Limit. Rec. Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe samples from the time of collection until delivery to the laboratory for analysis. This section ofyour report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J3 The associated batch QC was outside the established quality control range for precision. J4 The associated batch QC was outside the established quality control range for accuracy. P RPD between the primary and confirmatory analysis exceeded 40%. T8 Sample(s) received past/too close to holding time expiration. Fp Fc FS Fn Fr Fc SAI Rc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources DAVIE COUNTY L1221225 06/02/20 22:26 19 of 21 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing Cp turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Fc State Accreditations Alabama 40660 Nebraska NE-OS-15-05 FS Alaska 17-026 Nevada TN-03-2002-34 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TNO02 Fn California 2932 New Mexico n/a Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Fr Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina 3 41 Georgia' 923 North Dakota R-140 Fc Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 7C71 Indiana C-TN-01 f Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky' 6 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee'" 2006 Louisiana' LA180010 Texas T104704245-18-15 Rc Maine TN0002 Texas 5 LABO152 Maryland 324 Utah TN00003 Massachusetts M-TNO03 Vermont VT2006 Michigan 9958 Virginia 460132 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 9980939910 Montana CERT0086 Wyoming A2 LA Third Party Federal Accreditations A2LA— ISO17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2 LA — ISO 17025 5 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 ' Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA MT ND OR ID SD VWY ` NV T NE T UT CA co KS W o �AZ NM O� T TX AK � . b C, fo • B HI 4 S ACCOUNT: V PROJECT: EMA Resources DAVIE COUNTY ME MN WVI NY MI T IA T PA 4 OH Mo IL Ihi T T WV VAT KY N * r� AR Ms AL GA LA FL SDG: DATE/TIME: PAGE: L1221225 06/02/20 22:26 20 of 21 1J/) Billing Information: EMA Resources Mr. Brent Collins Pres Chk '755 Yadkinville Road 755 Yadkinville Road Mocksville, NC 27028 Mocksville, NC 27028 Email To: brent.collins@emaresourcesinC.Com Report to: Mr. Brent Collins Prciect City/State Please Circle: C�66�N iV PT MT CT ET Collected: LW Car�ad�c � • 4 Description: Sludge Client Project # lab P oject # Phone,336-751-1441 Fax: 336-751-1442 {p Co l�eled bY/ T`� __ _� ., __!J Site/Facility ID # P. d Vrc cow )Ty Z Immediately Packed on Ice N — Y Sample ID : Matrix: �S - Soil AIR - Air F - Filter 3W -Groundwater B- Bioassay NW - WasteWater ]W - Drinking Water X - Other / Relinqui by : (5ign8ture Relinauished by : (5i9nature} Rush? (Lab MUST Be Notified) Quote # Same Day Five Day Next Day _ 5 Day {Rad Onlyl Date Results Needed ~_Two Day _ 10 Day {Rad Only) Three Day Comp/Grab 1 Matrix ` Depth Date Time ss Samples returned viia:� Tracking# UPS _ FedEx V Courier JDate: Time. q� Received by: a + a tJ O Z i No. � of ,ntrs ' d J 2 X X Date r I -me: IReceived by: (Signature Date: Time: Rece- fa #by: (I'tature) pH Temp Flow Other Trip Bank Rece Tl_,l7jy�,( cC Battle Da t Time: Chain of Custody Page f- of 1eMa! ical i 12065 Lebanon Rd � Mount Juliet, TN 37122 s,-: Phone:615-758-5858 phone. goo-767-5859 ' Fax: 615-758-5859 SDG # 7 B06 5 Ta Acctnum: EMARES Temp€ate:T11413 Prelogin; P748417 PM: 8077 -Justin Carr l PB: 1 pt`� ! — '? Shipped via: FedEX Standard Remarks Sample M (lab on ly) SampleR�ce k. DC Sea IPresent/ 1�.tact: R Y N CDC Signed/Accurate: _,,Y _N Bottles arrive intact: rY N �N Correct bottles used: _eY sufficient volume sent: Appli+cable !i _N If VOA Zero Headspace: Y _N Preservation Correct/Checked: N RAD Screen <0.5 mR/hr:�N If preservation required by Login: Date/Time Hol Conditi� NCF / I� K ANNUAL PA'UHUGEN AN1) VEUFORA'1"FRACUION RED UC:'FION k-ORM (021'.Rules) Facility Name: Davie County Water System WWTP Name: Coolccmcc WWTP Monitoring Period: From 1/1/2020 To WQ Permit Number: 2020 NPDES Number: NCO024872 1213 l i2020 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (timeltemp) ❑ I Alt B (Aik Treatment)❑ Alt. C (Prior Testing)❑ Alt.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑ If applicable to alternative performed ((.'lass A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thennophilic ❑ Beta Ray ❑ Gamma Rav ❑ Pasteurization ❑ Class B: jAlt. (1) Fecal Density © Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ I Air Drying ❑ Composting ❑ lAcrobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Cl; 2020 Parameter Allowable Level in Sludge Pathogen Density Number o Excee- nce Frequency of Analysis Sample Type Analytical Tech-nique MinimAGeo. MeanMaximurr Units m Fecal Colifor 2 x 10 to the 6th power per gram of total solids MPN CFU 98 107 121 colll 8 0 Quarterly C SM9222D 1000 mpn per gram of total solid (dry weight) _ Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: A1t.I (VS reduction) 0 Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) ❑ Alt. 4 (Spec. 0,2 uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt, 6 (AIk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ Alt. 8 (Drying - [Instable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) 0 " I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Tim Smith - WWTP ORC Preparer Name and Tid (type or print) Signature of reparer* Date Brent Collins; Director of Technical Services Land Applier Name and Title (if applicable)(type or print) ;ef—e 42�- 1/27/2021 Signature of Land Applier (if applicable) Date *Preparer is defined in 40 C!~R Part 503.9(r) and 15A NCAC 2T .1102 (26) Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 1 Report Date: 6/1/2020 Date Sample Rcvd: 5/22/2020 Meritech Work Order # 05222016 Sample: Cooleemee WWTP C-1 Grab 5/22/20 Parameters Result Analysis Date Reporting Limit Method % Total Solids 8.49 % 5/27/20 0-100 % SM 2540B Fecal Coliform (Sludge) <107 col/g dry wt 5/22/20 107 col/g dry wt SM 9222D Meritech Work Order # OS222017 Sample: Cooleemee WWTP C-2 Grab 5/22/20 Parameters Result Analysis Date Reporting_ Limit Method % Total Solids 7.63 % 5/27/20 0-100 % SM 2540B Fecal Coliform (Sludge) <119 col/g dry wt 5/22/20 119 col/g dry wt SM 9222D Meritech Work Order # 05222018 Sample: Cooleemee WWTP C-3 Grab 5/22/20 Parameters Result Analysis Date Reporting Limit Method % Total Solids 8.88 % 5/27/20 0-100 % SM 2540B Fecal Coliform (Sludge) <102 col/g dry wt 5/22/20 102 col/g dry wt SM 9222D Meritech Work Order # 05222019 Sample: Cooleemee WWTP C-4 Grab 5/22/20 Parameters Result Analysis Date Reporting Limit Method % Total Solids 8.88 % 5/27/20 0-100 % SM 2540B Fecal Coliform (Sludge) <102 col/g dry wt 5/22/20 102 col/g dry wt SM 9222D Meritech Work Order # 05222020 Sample: Cooleemee WWTP C-5 Grab 5/22/20 Parameters Result Analysis Date Reporting Limit Method % Total Solids 8.68 % 5/27/20 0-100 % SM 2540B Fecal Coliform (Sludge) <105 col/g dry wt 5/22/20 105 col/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 All Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Page 2 Report Date: 6/1/2020 Date Sample Rcvd: 5/22/2020 Meritech Work Order # 05222021 Sample: Cooleemee WWTP C-6 Grab Parameters Result Analysis Date Reporting Limit 5/22/20 Method % Total Solids 7.53 % 5/27/20 0-100 % SM 2540B Fecal Coliform (Sludge) 121 col/g dry wt 5/22/20 130 col/g dry wt SM 9222D Meritech Work Order # OS222022 Sample: Cooleemee WWTP C-7 Grab 5/22/20 Parameters Result Analysis Date Reporting Limit Method % Total Solids 9.27 % 5/27/20 0-100 % SM 2540B Fecal Coliform (Sludge) <98 col/g dry wt 5/22/20 98 col/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Q` Ha2Dr- np ,t— Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 r 0 Q ._ . r G L O ❑ F a a z° � O t10 .. O N tf1 c J C tv 0- z E O OOA F F F Q m Q�i Q�i to to w N v a Q N * n , W ❑ Q_- • • U Q C M aJ *k C o J _ i tic z a Li- w a. a 4 3 X ro v O L 1 L� Q Z (k l v fCC0 1\4 V /' J C CL a) r w V W o f6 Y C C i QI Qj w Q cu O 4 � � ro U v1 O O L N i U v F 54-1 O U � �- � � •� � z N a+ •�� j U Q Q v a U o \� V V lJ v ° O c O z a a u (Us E E N C N VW n N -0 w r ro T .. O N fII O F— cr1 M U H 0 E Ln Q p p p Ln m 1° _a Q m m m Z Q o O Q o v 4A » M Q -0 Q a. U- •Q. y W1;6 V Y V ° � o N U- Z w O O can ai A o 5 ro U H 41 o K Ito o L can W O Z E i u LU Z x o `� N i e lD R J1 [ v r V 0 ti U : �. E a C a- C a C O 3 O U O a--1 T N > - V O O N L aJ o L � � = C i- _Q L O N cn Plow❑ Analytical Results EMA Resources, Inc. 755 Yadkinville Rd. Mocksville, NC 27028 Receive Date: 05/21/2020 Reported: 05/22/2020 For: Cooleemee Comments: STATESVILLE C ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200521-33-01 % Volatile Solids IN 0.16 % SM2540G 05/21/2020 MD 200521-33-01 Percent Solids IN 0.27 % SM2540B-2011 05/21/2020 MD 200521-33-02 % Volatile Solids OUT 1.94 % SM2540G 05/21/2020 MD 200521-33-02 Percent Solids OUT 7.75 % SM2540B-2011 05/21/2020 MD Respectfully submitted, �0P --WVG j ' Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 3 Volatile Solids IN 0.16 %Total Solids IN 0.27 Fractional Volatile Solids IN 0.593 Volatile Solids OUT 1.94 Total Solids OUT 7.75 Fractional Volatile Solids OUT 0.250 Volatile Solids As a decimal Volatile Solids In 0.593 Volatile Solids Out 0.250 Volatile Solids Reduction 1 77.0 Condition of Receipt Sample Number 200521-33-01 Temp on Arrival: Parameter Schedule: Percent Solids Parameter Schedule: Sample Number 200521-33-02 Temp on Arrival: Parameter Schedule: Received on Ice Received on Ice Received on Ice Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 3 E }O E 052d L69ti/ZL8/ti0L • L898Z DN 'a!!!nsajejS • 8ZZ xO9 Od n b i �' 0 c �y U � n N E 0 a t C E d o C a V a cn E E RIM `o c coF= 2 U Z m a tz O O E t a (I E E E a a U< co to co w qwo P N C 1� (D E E E E E E E E E 0 H K J E? SIR UG CL Q � a m 0 m ,J o 0 0 0 N a fl Vf a a 0 E E E E O c m cc fa co C N E 0 i L r C w C N Q Mn 'O Of c O> Q > a > L Q) L a) v 0 O oS ; E c m c m E E E d aa)i m m U a d9, Q fL Q F H H H NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL005468 Client: Roger Spillman Advisor: Brent Collins vo- Predictive PO Box 378 EMA Resources Inc Cooleemee, NC 27014 755 Yadkinville Rd .'..,$' Soil Report Mehlich-3 Extraction Mocksville, NC 27028 _ Sampled County : Davie Links to Helpful Information Client ID: 411288 Advisor ID: 405413 Sampled: 09/14/2020 Received: 09/22/2020 Completed: 10/01/2020 Farm: DV08 Sample ID: 00004 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 100 30 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.32 1.10 6.5 96 0.3 7.0 16 61 55 36 41 572 346 445 445 59 0.1 2 Sample ID: 00005 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 30 90 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 1.05 16.9 94 1.1 6.6 46 26 59 33 44 938 571 866 866 216 0.2 1 Sample ID: 00006 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 50 90 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 1.14 14.7 90 1.4 6.3 39 23 57 33 45 961 588 513 513 162 0.1 1 North Carolina Tobin w Trust f wW Ctwninisskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL005468 Roger Spillman Page 2 of 3 Sample ID: 00007 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 60 80 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.32 1.13 14.6 91 1.4 6.4 31 27 57 33 35 1125 686 527 527 173 0.1 1