WQ0002702_Regional Office Historical File Pre 2018 (27)

PAR Laboratories, Inc.
PARLABORATORIES, INC. ChaP.0Boxrlotte,, NNC 83
ChaC 28241-1483
Phone: [phone] Fax: [phone]
AIC CERT #20, SC CERT #99003
www.parfabs.com
REPORT OF ANALYSES
Attn: TRENT TIDWELL
ALCHEM ?NC PROJECT NAME: DEC 09
8135 RED ROAD T-1lTE. 02 j 0 i�I1 0
ROCKWELL, NC 28138-
SAMPLE NUMBER- 93823
SAMPLE ID-
RESIDUALS ANALYSIS #
2
SAMPLE MATRIX- SO
DATE SAMPLED- 12/29/09
TIME SAMPLED- 0905
DATE RECEIVED- 12/29/09
SAMPLER- NOT SPECIFIED
RECEIVED BY- .DJ
TIME RECEIVED- 1330
DELIVERED BY- TT
TYPE SAMPLE- Grab
Page 2 of 6
ANALYSIS
ANALYSIS
METHOD
DATE
TIME
BY
RESULT
UNITS
pH VP.,LUE
5M 450OH-B
12/31/09
1700
CN
5.12
units
SILVER, TOTAL
EPA
200.7
12/31/0.9
1030
CT
< 0.10
mg/L
ALUMINUM, TOTAL
EPA
2,00.7.
12i31/09
1030
CT
795
mg/L
ARSENIC, TOTAL
EPA
200.7
12/31/09
1030
CT
< 0.10
mg/L
BARIUM, TOTAL,
EPA
200.7
121121/09
1030
CT
28.4
mg/L
CALCIUM, TOTAL
EPA
200.7
12/31/09
1030
CT
3,040
mg/L
CADMIUM, TOTAL,
EPA
200.7
12/31/09
1030
CT
< 0.10
mg/L
CHROMIUM, TOTAL
EPA
200.7
12/31/09
1030
CT
8.92
mg/L
COPPER, TOTAL
EPA
200.7
12/31/09
1030
CT
2.00
mg/L
MERCURY, TOTAL
EPA
245.2
01/15/10
EL
< 0-0002
mg/L
MAGNESIUM, TOTAL
EPA
200.7
12/31/09
1030
CT
74.6
mg/L
MANGANESE, TOTAL
EPA
200.7
12/31/09
1030
CT
0.954
mg/L
SODIUM, TOTAL
EPA.
200.7
12/31/09
1030
CT
2-12
mg/L
NICKEL, TOTAL
EPA
200.7
12/31/09
1030
CT
2-11
mg/L
PHOSPHORUS, TOTAL
EPA
200.7
12/31/09
1030
CT
9.97
mg/L
LEAD, TOTAL
EPA,
200.7
12j31/09
1030
CT
5.78
mg/L
SELENIUM, TOTAL,
EPA.
200.7
12/31/09
1030
CT
0.782
mg/L
ZINC, TOTAL
EPA,
2,00.7
12/31/09
1030
CT
1.74
mg/L
LABORATORY DIRECTOR`'~ `

ALCHEM, INC.
Corporate Office Sales and Manufacturing
2042 Buie Philadelphus Road 8135 Red Road
Red Springs, NC 28377 Rockwell, NC 28138
Tel. [phone] — Fax [phone] / Tel. [phone] — Fax [phone]
[e-mail] ` NC
j DEPT. OFEH-Vt:iROEi•.Nt•I.tE1.T
ANtAJ73
[e-mail]
D �-A. c.
JAN 1 8 2002
November 2, 2001 y �
m
J.R. Joshi
NC Division of Water Quality �u'r►�
1617 Mail Service Center
Raleigh, NC 27699-1617 z
RE: WQ0016338
Dear Mr. Joshi:
In response to your email of November 1, 2001, we are sending copies of the analysis on
the residuals testing. This includes the four analysis you requested. This request is in
accordance with our permit. Please let me know if you need anything further.
Best regards,
ALCHEM, INC
/ �C(
Randall Andrews,
President
Enc.
pcd

SPECIALIZED
ASSAYS, INC.
2960 Foster Creighton Dr.
P.O. Box 40566
Nashville, TN 37204-0566
Phone [phone]
36,70
-'1~I F41-:. . T 1=fR
:ir-1 11. PINE STR'L-T, ST1=
;i' DEP. T 0N' 11% 23:358
= o y e,_ t N Cne : ALCHEM, INC.
ainp l 7 : 4vr�'rr�il Dtz'r;=
r.r:'a1S Result: Uriits
+`%"gn. LL Y T I <-- e�-% IL_ R 1= R iQ FR T
Lab Number: 17V.--Al2,3315
5 a m p 1 e ID: LAr('1+,:1'V *4
Sarrlpie "fyNe: i lid was.;e
Site ID:
Date Collected: C_"12 1 qo
Time Collected: 7: r;C,
Dote Received: 6l:11-ri.
Tit°ne Received: 5: GAO
Repor't Ru3r1 Dil .----��
Litilt Lihit Factor Date •T1He Ari3lgEt I1et110d Uatctl
:{9i_TA .:,X
=iluni::ur
15244.6
ngrkg
9.785
9.1181)
1
8131199
7:37
G.Fobiiism
601013)
1512
Rp 5er:1.
RD
tiglkg
0.978
0.778
1
8r'31199
7: -17
S. Fo`ai i.5 )it
6010D
1512
42.662
ny!kg
0.978
U.978
1.
Sr131l99
7: `37
9.Fobi1,.3jn
601.00
1512
:?drii:Jr
RD
ng14:g
0.978
U.978
1
813DW
7:37
9.Ro1)1fis.3n
60100
i512
167.515
uglkg
9.-r85
Y.785
1
8iKI97
7:37
o.Robii!5on
5010[1
1512
CA;vn:i;n
10.959
ngtl;g
0.778
U.978
1
&`31199
7:37
Robii,s•3ri
6010[t
1512
i'igdnq
0.978
U.978
1
8131199
77
7.Robit:sin
601013
1i12
?3ti
14. 481
it In.
0.?78
0.978
1
8131199
7:37
'c. Ro ili is Jrl
601013
15!2
'I gr,::. u^
71.755
1iglHg
7.785
7.735
1
8/31I99
7:37
0.Rucs3r,
60101t
1512
0.978
0.978
1
8i31199
7:37
G.Fobiit5)n
601061
1512
nglii:g
0.097
0.097
1
8l26M
9:53
G.Robirs)«
(471
916
ND.
n jr'kg
0.978
U. 978
1
8;'31199
7: 37
G. Fo b i ;,$) it
6010D
1512
�ler:i:,r
RD
rgrkq
0.978
0.978
1
81 IM
7:37
0.Rob i:s3n
60103
1'1
::i11Jer
RD
r,g1k.q
0.778
0.Y78
1
813157
7:37
G.Fob_i,$)r1
601Utt
1512
0 fit i
1M. 02Z
:igikg
9.785
7.785
1
8, 3.1i99
7: 37
6. Fob: i:sor:
601U[t
1512
i10
RD
npIig
9.785
9.785
1
8:'3:Li99
7:37
G.Rob ii;53a
601013
1512
o RE^rL CIi�11T �.7RY ljAR11"E?£!i � •'
WMIC+ris°t 1 8.'2415'9 Il:CiG J. Fro_.i 3Di5 83ti
t�„} ;torus a.• e 16.4 8r2 5,'lY 19:.',U Ciiall:t: t =_a4 365.2 �l II32

(13:09%UU 12:33 FAX [phone] TBL THE BEST LAB
TcctRnerica Orlando
iestAme
ric
irco.row�teo
March 8, ZUvo
CLIENT: ITM BEST LAB
2003 NORTH PIKE STREET
S13=TE 2
LUMBERTON, NC 28350
dTT]T : PAM NESTER
iZ 02
4E77 E5b W28 P.O1/a-)
Order 17uaiber: 2367
Project Name: TBL-10313
sazvla LD: LAGOON h3
Lab Number: 00-F3$02
Date Collected: 02/24/00
Time Collected: 07:00
Date Recelvcd: 02/25/0'0
Repo" oft
a.,alyce
AesUlt 0 Units
Limit Factor
Cate rim&
Analyar
Nathed
catch
'4ElAl.5•
Atuaircn
13300. J4 mv/kv
t.5000 1
2/28100
KS
'1467
Arsenic
< 5.0000 U me/kg
S.0000 1
2/28/00
01 606
kariva
<1•700 J4 t$/kv
1.5000 1
2/za/00
KF
60109
7467
red,luo
< 0.5p000 U/ka
0.50000 }
2/26/00
Ks
60102
7467
ealcirm
112.00 e�1/kg
25.000 t
Ma/Do/DO
KE
6oiL'e
7467
Chrom;,a
14.wo J4 ag/kv
0.50000 1
2128100
Ks
60101
r467
Coppor
2.0200. 1 a�/fcp
f.0(10Q 1
KY
bolas
7467
teas
14,000 Mg/kg
510000 1
2/2d100
Kl
60100
7467
Refl nrafue
46.s00 sQ/kv
Z5•a00 1
z/28/OD
2/2E/00
KS
64103
7467
R�v"•'�e
1,5400 k C
1.5000 1
Z/2ti/00
KS
6010i
7467
< 0.010 U RG/ka
0.010 1
3/ 210 9:21
C9
60106
7467
WiekNicke
l e
2.2�,00 vQ/W
1.5000 1
Z/211/00
RQ
7471
7579
Seteniun
U r61k8
5.0000 1
212fl100
KE
60105
7W
silver
< O.SO90p U wQ/ka
0.50tD00 1
2/28/QO
KS
60101t
7467
Sodium
t75.00 g
Ipp/k
25.000 1
KS
60106
7467
Zin
5.5500 Ira/ka
1-Sam 1
1128/00
KS
6010E
7467
Zl26/00
Ks
6010u!
7/•67
'GE'1UAi
pert ant Total ►ho6phvte
12. PH units
D,pp
I
2/25/00 14:1c
xF
V"5
1i59
.4 cuaLiiinr for
X 0.000 1
Ali Cr 1tditates poor'VJV i apiko'r6cvvury,
3/ 7/00
ap
7850
14 pmlifi@r far
Be irdltat"
non-haa vncoo;.a
eh&ple
poor 40k• rrcoaery, gwtrfx
fnterferwme
p•Ppzoved 8y;
..
af016rr.1 Alt, Laboratory Director
kerk RLMLtr, Laboratory pjwWCr
K.9. Vault, Client "tvicee gonager
Eliz40ith A, Rtch, O.A. Offir
North Carodna Lertifiat,'on
ilWrbe— E0327 /02KNA DW12708
i
4310 L43r AhDL: rson RLw I Oiu-Owo, FL 32s 121407-95
1-2380
/ FAX: 407-$5fi-08U
t

ATTN:
Testy America
INCO RPO RATED
2 7'.2000 .
• 4. F•
^• THE BEST LAB
_`2003 NORTH PINE STREET
-SUITE 2
LUMBERTON, NC 28358
PAM HESTER
Order Number: 5268
Project Name: TBL=10643
Sample ID: LAGOON #3
Lab Number: 00-F14646
Date Collected: 07/25/00
Time Collected: /OB-:-00-- -.
Date Received:
LABORATORY REPORT
Report
oil
Analyte
------------------------
Result
------------
Q
---
Units
------
Limit
------
Factor
------
Date
--------
Time
-----
Analyst
----------
Method
---------
Batch
-----
*METALS*
Aluminum
18740
J4
mg/kg
2.500
1
8/
4/00
14:50
KS
60108
7647
Arsenic
< 5.000
U
mg/kg
5.000
1
8/
4/00
14:50
KS
6010B
7647
Barium
38.78
mg/kg
1.500
1
8/
4/00
14:50
KS
6010B
7647
Cadmium
< 0.5000
U
mg/kg
0.5000
1
8/
4/00
14:50
KS
6010E
7647
Calcium
115.0
mg/kg
25.00
1
8/
4/00
14:50
KS
6010E
7647
Chromium
13.79
mg/kg
0.5000
1
8/
4/00
14:50
KS
6010B
7647
Copper
< 5.000
U
mg/kg
5.000
1
8/
4/00
14:50
KS
6010E
7647
Lead
12.22
mg/kg
5.000
1
8/
4/00
14:50
KS
6010E
7647
Magnesium
50.60
mg/kg
25.00
1
8/
4/00
14:50
KS
6010B
7647
Manganese
1.688
mg/kg
1.500
1
8/
4/00
14:50
KS
6010B
7647
Mercury
< 0.01000
U
mg/kg
0.01000
1
8/
2/00
9:37
RQ
7471A
7349
Nickel
2.411
mg/kg
1.500
1
8/
4/00
14:50
KS
6010B
7647
Selenium
< 5.000
U
mg/kg
5.000
1
8/
4/00
14:50
KS
6010E
7647
Silver
< 0.5000
U
mg/kg
0.5000
1
8/
4/00
14:50
KS
6010E
7647
Sodium
157.0
mg/kg
25.00
1
8/
4/00
14:50
KS
6010B
7647
Zinc
9.815
mg/kg
1.500
1
8/
4/00
14:50
KS
6010B
7647
*GENERAL PARAMETERS*
11
0H�~ -= '3.G`4 pH units 1 8/ 1/00 11:20 NF 9045C 7333
Phosphate, total as P 0.210 mg/kg 0.200 1 8/18/00 10:05 BJR 8600
J4 qualifier indicates the matrix interfered with the ability to make an accurate determination.
Approved B :
PP Y
Mark Rusler, Director of Technical Services
K.R. Vault, Client Services Manager
Elizabeth A. Rich, Q.A. Officer
North Carolina Certification Number: ENV#327/DEHNR DW12708
4310 EAST ANDERSON ROAD / ORLANDO, FL 32812 / 407-851-2560 / FAX: [phone]

L L"
12065 Lebanon
Rd.
AF
Mt. Juliet, TN
37122
ENVIRONMENTAL
758-5858
-800
1-800-767-5859
SCIENCE CORP.
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT OF ANALYSIS
Ms. Pam Hester
November 27,
2000
TBL Laboratory
2003 North Pine Street; Suite 2
Lumberton, NC 28358
ESC Sample #
L29845-01
Date Received November 17, 2000
ESC Key
TBLLAB-ALCHEM
Description Solid - Alchem,
Inc.
Site ID
Sample ID LAGOON 3
Project #
TBL-10842
Collected By Wayne Drye
Collection Date 11/13/00 08:00
Parameter
Result
Det. Limit
Units
Method
Date
Dil.
•pH,
su
9045C
11/17/00
1
Phosphorus,Total
0.71
0.025
mg/kg
365.2
11/21/00
1
Total Solids
75.
%
2540G
11/18/00
1
Mercury
0.049
0.020
mg/kg
7471
11/21/00
1
Aluminum
10000
5.0
mg/kg
6010E
11/25/00
1
Arsenic
BDL
0.25
mg/kg
601013
11/25/00
1
Barium
36.
0.10
mg/kg
601013
11/25/00
1
Cadmium
BDL
0.10
mg/kg
6010B
11/25/00
1
Calcium
95.
5.0
mg/kg
6010B
11/25/00
1
Chromium
5.5
0.10
mg/kg
6010B
11/25/00
1
Copper
1.2
0.50
mg/kg
6010B
11/25/00
1
Lead.
8.9
0.25
mg/kg
6010B
11/25/00
1
Magnesium
27.
5.0
mg/kg
6010B
11/25/00
1
Manganese
0.61
0.50
mg/kg
6010B
11/25/00
1
Nickel
BDL
0.50
mg/kg
6010B
11/25/00
1
Selenium
0.64
0.25
mg/kg
6010B
11/25/00
1
Silver
BDL
0.10
mg/kg
6010E
11/25/00
1
Sodium
170
25.
mg/kg
6010E
11/25/00
1
Zinc
2.4
0.50
mg/kg
6010B
11/25/00
1
Terri Fudge, E C Rep esentative
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Page 1 of 3

ALCHEM,
INC.''-
Corporate Office Sales and Manufacturing
2042 Buie Philadelphus Road 8135 Red Road
Red Springs, NC 28377 Rockwell, NC 28138
Tel. [phone] — Fax [phone] Tel. [phone] --- Fax [phone]
[e-mail] [e-mail]
March 14, 2000
Mr. Kevin Barnett
NC Division of Water Quality
Water Quality Section
Non -Discharge Compliance/ Enforcement Unit
512 North Salisbury Street
9t' Floor
Raleigh NC 27604
Dear Mr. Barnett:
#ADV,
Non D/, Q�q4 ?dull
haf 9e COmp S,OrON
�hGG
F7f
Enclosed is the Monitoring and Reporting Requirements for our permit number
WQ0016338.
For the year of 1999, we used 2,755 tons of Silica residual from our on -site Bauxite
digestion process as a fill material. Following you will find the remaining requirements
for our permit.
We would like to thank you for allowing our company additional days for sending this
information to your office. If you have any questions, please let me know.
Best Regards,
ALCHEM, INC.
Randall Andrews,
President
TV

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding laboratory analysis.
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this foram.
Permit Number Laboratory 1
Facility Maine Ec.Kon Ac , z ZOO r i�i`r1e S¢v
NPDES ff 3 jo er4o jt, NC -IS35
Of Wq a (10"81 0*lsdvuw)
WWTP Name
a��iAol annhrelc Ilafa
Data sampled (grab) or
'
Date Co sailed
a3 9q
Percent Solids
(l►
w
■�..
_ . 1.
�...�®�C..`
.(VC
(VC V-
rim...,��
�M�
-Total Phosphorus
X
(SIGNATURE OF PREPARER) DATE m 5
I certify, under penally of taw, that this doctiment was prepared under my direction or supervision in accordance with a sys&i
v
dasigrnd to assure that qualtiied personnel properly gathered and evaluated the infotntstlon submitted. 1 am aware that tt101e:
aigal0unt pi for.ubmilting false Wdonnatton. Including the possibi8ly of lines and lrrtprlsonment for knowing violat♦� � ®�
m O 9M FbA-q SSF (10194) .

51 L1U1ALILCU
ASSAYS, ' [Na.
2960 Foster Creighton Dr.
P.O. Box 40566
Nashville, TN 37204-0566
Phone [phone]
TESTAMERICA INC 8650.
PAM HESTER
2003 - N. PINE STREET, STE 2
LUMBERTON, NC 28356
Project: WQ0016386
Project Name: ALCHEM# INC.
Sampler: WAYNE DRYS
Ah1At_YT = AI_ RI=R OFR T
Lab Number: 99-A126315
Sample ID-i L02QVN #3
Sample Type: Solid waste
Site "�D:
Date Collected. 8/23/9?
Time Callecte 7:00
Date Receive 99�
Time Receive 9:00 /
Report Ruan D11
Analgte
Result
Units
Llnit
Llnit
Factor
Date
Time
Analgtt
netbod
Batch
{METALS?'
Aluminum
15244.6
mglkg
9.783
9.783
1
8/31/99
7:37
6.Robinson
6010B
1512
/
Arsenio ( s, 0
RD
•ng/kq
0.978
0.978
1
8/31/99
7:37
6.Roblason
60100
1512
Barium "� (/00'o
42.662
mq/kq
0.978
0.978
1
8/31179
7:37
6.Robinson
60100
1512
Cadmium v
RD
nglkg
0.978
0.978
1
8/31/99
7:37
6.Robinson
60109
1512
Calcium
167.515
ng/kg
7.785
7.785
1
8131177
7:37
6.Robinson
6010
1512
Cbroniun -- sr• 0
'10.959
ng/kg
0.978
0.978
1
8/31/97
7:37
6.Robinson
6010
1517
Copper
RD
mg/kg
0.978
0.978
1
8/31177
7:37
&.Robinson
6010D
1512
Lead
14.481
nglkg
0.778
0.978
1
8131/99
7:37
6.RaH nson
60108
1512
magnesium
74.755
ng/kg
7.785
9.785
1
8/31/99
7:37
6.Robinson
60100
1512
manganese
2.935
ng/kg
0.978
0.978
1
8/31197
7:37
6.Robinson
6010D
1512
nercurg
RD
nq/kq
0.097
0.097
1
8/26/99
9:59
6.90111ason
7471
916
Mickel
RD
ng/kg
0.978
0.978
1
8/31/99
7:37
6.Robinson
60100
1512
Selenium
RD
ng/kg
0.978
0.978
1
8/31199
7:37•
S.Robinson
60100
1512
S111jer
RD
ng/kg
0.778
0.973
1
8/31/77
7:37
6.Robinson
60100
1512
Sodlum
499.022
ng/kg
9.785
9.705
1
8131197
7:37
6.Robinson
6010
1512
Zinc
RD
ng/kq
9.785
9.785
1
8131/99
7:37
S.Robinson
6010D
1512
KERERAL CHEnISTRY FARAMETERSa
units
1•
8/24197
11:00
J. Frost
9045
630
PLasyGary - as P -`�'
no/kg
1.0
1.0
1
8/25199
17:30
CHollingsu
365.2 n
1137

ht�2- 20W 17' 2B
TestArner icb �r Lando
407 9% OEE6 P - 01/02
March 8, 2000
Testhaneric'a0
INS
CLIENT. TH3 BEST LAB
2003 NORTH PINE STREET
SUITE 1
LUMBERTON, KC 28358
AM: PAM HESTER
Order Number: 2367
Project Name. TSL-10316
Sample IDs LAGOON 43
Lab Number: 00-7360a
Date Collected: '0:2:/'2:4/_4:0
Time Collected- 07:00
rate Received: 02/25/00
LABOVATOILY XZP T
Report
O(t
ArMlyto
Resu(t
a
LniCa
I,imoit
FSCLOr
Date Time
Analyst
method
9atch
•FIETAL5•
Alusirtaa
15300.
JS
no/ko
2.5000
1
2lt3/00
KS
60100
7467
Arsenio
< 5,0000
U
w/ke
$.0000
1
2/28/00
KS
60100
7467
aarius
41,100
J4
ow ke
,1.5000
1
MUM
Ks
66100
7467
CaskoiUR
a 0.50000
U
ap/k8
0.50000
1
2/23100
to
60106
7467
Calciun
112,00
*a/kp
25.OQA
1
Zan/00
KS
60105
7467
Chromium
14.800
J4
mg/kp
0.e=
1
212s100
KS
60108
7467
Comer
2.0200
I
sa/ka
5.0000
1
almo0
Ks
60108
7667
mead
14.000
me/kg
5.0000
1
2/28/00
es
60108
7467
rraerxsiuw
46.800
miy/kR
23.000
1
2/28/W
KS
60109.
7467
IlarRanseme
1.5400
■p/kg
1.5000
1
2/28/00
K5
60108
7467
Mercury
< 0.010
U
at/k0
0.010
1
3/ 2/00 9:21
RO
7471
76750
Alcksl
2.2200
mmp/kq
1.5000
1
2128/DO
Ks
6010E
7467
selenium -
< 5.pOpt,+
U
RO/ko
5.0000
1
2128/00
KS
6010E
746T
Silver
< 0.5=13
iJ
of/kp
0.50000
1
2/2E/00
Ks
60108
7467
$odium
175.00
swing
25.000
1
2121/00
KS
6010E
7467
Zirr
5.5500
PWkp
1.50o0
1
2/2Q/0A
K5
60108
7467
~ *%4E k PARANETERBV
p# uniis 1 2123100 14:30 NF 9045 7S39
Perrsrmt Tot'el Pliog{6rots 0.00 X 0.000 1 3/ 7/00 NF 7550
J4 qualifier for Al C Cr irdlcatas poor RpD t spi{w reearery, non-110ab0eneam sample
J4 arsliffer for Be indicates poor spike recowrr, artrfx interfernr=e
Approvmed By;
Richard Alt, Laboratvrr Director
Kark Rmaler, Laboratory nmvk r
r-2. vault, Cl font sarvfcoo Rans"r
Elitabsth A. Rich. Q-A. Officer
Worth Carolirma Certifieation Nmsnber: Ett327 /DEWNR DUIZ708
4310 BAST ANDOW! I ROAD / Oe1.Axno. FL 32812 / 407-851-2560 1 Fix. 407.85&4M

SPECIALIZED
ASSAYS, ' fNc,.
2960 Foster Creighton Dr.
P.O. Box 40566
Nashville, TN 37204-0566
Phone [phone]
TESTAMERICA INC 6690
PAM HESTER
2003-N. PINE STREET, STE 2
LUMDERTON, NC 28358
Project: W000163He
Project Name: ALCHEM,INC.
Sampler: WAYNE DRYS
Afh1ALYT I C AL R I=P MR -r
Lab Number: 99—A128315
Sample ID4 LA N 43
Sample Type: Solid waste
Site IUD:
Date CollectC__7:O;O
Time CollectDate ReceiveTime Receive
TCLP Results
Matrix Spike
Analyte. Result Units Reg Limit Recovery (G) Date Time Analyst Method
-------------------------- ----------- ----- ------- --------- ---- --------- ----- --------- ---------
Arsenic
( 0.10
ng/1
5.0
95
8/27/99
13:08
R.
Kelley
6010B
Barium
( 1.00
m9/1
100
92
8/27199
13:08
R.
Kelley
6010D
Cadmium
( 0.109
119/1
1:0
89
V27177
13:08
R.
Kelley
60100
Chromium
C 0.50
mg/1
5.0
85
8/27177
13:08
R.
Kelley
601UB
Lead
( 0.500
mg/l
5.10
88
8/27177
13:08
R.
Kelley
60100
nercurg
C 0.010
m9/1
0.20
94
8126177
13:55
R.
Kelley
7470A
Selenium
( 0.100
mg/1
1.0
104
8/27/99
13:08
R.
Kelley
6010D
Silver
( 0.19
mg/1
5.0
76
8127!99
13:08
R.
Kelley
6010B
Benzene
C U.05
mg/1
0.5
106
8127/77
6:57
J.Na1ey
8260
COPY 1

SPECIALIZED
ASSAYS, INC.
2960 Foster Creighton Dr.
P.O. Box 40566 .
Nashville, TN 37204-6566 A ICI ^- Y T I G A L- Ft IE F- Q R T'
Phone [phone]
Laboratory Number:-99-A1ZS315
Sample ID: LAGOON #3
Page 2
TCLP Results
flatrix Spike
Analyse Result knits Reg Limit Recovery W Date Time Analyst Rethod
------------------------------------- ------------------------------------- -------=------- ---------
Carbon tetrachloride
( 0.05
mg/l
0.5
98
8/27/99
6:57
J.Haley
8260
Chlarobenzene
< 10.a
mg/i
100
107
8127177
6:57
J.Haley
8260
Chloroform
( 0.060
mg/l
6.0
108
8/27/77
6:57
J.Haley
8260
1,2-Dichloreethane
( 0.05
119/1
0.5
101
8/77177
6:57
J.Haley
8260
1,1-Dlchloroethene
( 0.07
m9/1
0.7
121
8/27177
6:57
J.Haley
8269
Methylethglketone
< 20.0
mg/l
200
126
8/27199
6:57
J.Haley
8260
Tetrachloroethene
{ 0.07
mg/I
0.7
104
8/27/99
6:57
J.Haley
8260
Trichloroethene
C 0.05
mq/I
0.5
103
8127177
6:57
J.Haley
8260
Vinyl Chloride
{ 0.02
119/1
0.2
113
$127/99
6:557
J.Haley
8260
Cresols
< 0.01
mg/l
200
48
9/ 2/99
10:42
M.600drich
8270
ichlorobenzene
< 0.01
mgll
7.5
44
9/ 2/99
10:42
n.Soodrich
8270
2,4-Dinitrotoluene
{ 0.01
mq/1
0.13
86
9/ 2/99
10:42
n.Soodrich
8270
Hexachlorobenzene
f 0.01
mg/l
0.13
88
9/ 2/99
10:42
M.600drich
8270
Hexchlor-1,3-butadien
f 0.01
mg/1
0.5
80
9/ 2/99
10:42
tt.&oodrich
8270
Hexachloroethane
( 0.01
mg/l
3.0
36
9/ 2199
10:42
M.Soodrich
8270
Mitrobenzene
< 0.01
mg/l
2.0
32
9/ 2/99
10:42
M.Soodrich
8270
Pentachlorophenol
{ 0.01
t1911
100
106
9/ 2/99
10:42
n.600drich
$270
Pyridine
{ 0.01
mq/l
5.0
12
9/ 2/99
10:42
tt.Soodrich
8270
2,4,5-Trichlorophenol
( 0.01
mg/l
400
88
9/ 2/97
10:42
M.600drich
8270
2,4,6-Trichlorophenol
{ 0.01
mg/l
2.0
88
9/ 2/99
10:42
M.Goodrich
8270
Chlordane
{ 0.0030
mq/l
0.030
88
8/30/99
16:11
Carmichael
8080
2,4-D
{ 1.0
n5/1
10.0
116
8/30/99
13:55
Carmichael
8150
Endrin
( 0.0020
mg/l
0.02
102
8/30197
16:11
Carmichael
8039
Heptachlor
< 0.0008
m9/1
0.008
63
MGM?
16:11
Carmichael
8080
Lindane
{ 0.040
mg/l
0.4
91
8/30/99
16:11
Carmichael
8080
Methoxychlor
f 1.00
mq/l
10.0
92
8130/99
16:11
Carmichael
8080
Toxaphene
! 0.050
mg/l
0.50
57
8/30/99
16:11
Carmichael
8080
Silvex
( 0.10
mg/1
1.0
99
8/30/99
13:55
Carmichael
8150
Heptaohlor epoxide
< 0.0098
m9/1
9.008
91
8/30/97
16:11
Carmichael
8080
TCLP Extraction
Initiated
8/24/99
16:00
tt. Starks
1311
Zero Headspace Extraction
Initiated
8/24/99
16:00
it -Starks
1311
MD = Not detected at the report limit.
TCLP prepartion follows method 1311, SU-846 Revision J.
Surrogate R Recovery Target Range
------------- ---------- ------------
VOA Surrogate, 1,2-01chloroethane, d4
103.
60.
- 138.
VOA Surrogate, Toluene d8
98.
80.
- 123.
VOA Surrogate, 4-Bromofluorobenzene
102.
73.
- 122.
Burr-Hitrobeazene-0
28.
15.
- 105.
COPY 1

..
iE•� r -w■ laii '
east ■ ■ . MI.
I .ii%��.■
■ ■, a_.
■ate• is•:
or ' ' ' 1. .21 .. . . . ■
v _
IL
■
Lit. -----====
^P4^[—YT' I G AL H 3EF1 QFR T
Laboratory Number: 911�—Al2B315
Sample ID: LAGOON #3
Page 3
Surrogate
-------------
% Recovery
----------
Target
------------
Range
Burr-2-Fluorobiphenyl
10. #
17.
- 110.
Burr-Terphengl d14
94.
10.
- 116.
Burr -Phenol d5
8. 1
10.
- 100.
Burr-2-Flucrophenel
A.
.surr-2,4,6-TrIbronophenol
94.
15.
- 134.
pest surr-TCtX
36.
20.
- 122.
Burr-Dibutylahlorendate
46.
10.
- 120.
Burr-DCPAA
108.
20.
- 130.
Report Approved By
Report Date: 9/ 3/99
Theodore J. Duello, Ph.D., Lab Director
Michael N. Dunn, M. S. , Technical Director
Johnny A. Mitchell, Dir. Technical Services
Eric Smith, Assistant Technical Director
Gail A Lage, Technical Services
Laboratory Certification Number: 387
COPY 1

0
ALCHEM, INC.
Corporate Office
2042 Buie Philadelphus Road
Red Springs, NC 28377
Tel. 9io-843-2121 — Fax [phone]
[e-mail]
December 22, 2000
Mr. Kevin Barnett
NC DIVISION OF WATER QUALITY
WATER QUALITY SECTION
Non -Discharge Compliance/Enforcement Unit
512 North Salisbury Street
9th Floor
Raleigh, NC 27604
Dear Mr. Barnett:
Sales and Manufacturing
8i35 Red Road
Rockwell, NC 28138
Tel. [phone]o8 — Fax [phone]
[e-mail]
Enclosed is the Monitoring and Reforting Requirements for our permit number
WQoo16338. For the year of 2000, we used 2, 885 tons of Silica residual from
our on -site Bauxite digestion process as fill material for our building. Enclosed
you will find the Annual Residual Sampling Summary form and a map. Please
call me if you have any questions.
Best regards,
ALCHEM, INC.
Randall Andrews,
President
vll

o
N �I I I I O v JUDITH E. DRYE
S 00•-55'-30"E
'0
o W
Z
o-
�
/ig2s'
s?�°°F
MARY H.
inNl
SOLOMO N
S 00'-48'-50-E
c
s4z
°od
t
23�9
I l �
S OI'-03'-00"E 810.97- / S 0I'-02'-20"E b,
341.92' f 0'
1 // I/ M ai3
5 89'-II'-30"E l
150.00'
Lagoon
_•_•� / J�� �/ ram/
N 76'-45'-50-W~ B/O N 06'-11'-40'E
131.15'\ 149.64' /-33.739
110
CLAUDE A. PARIS
647-551
10 ` C Acres
o w.n
d� N I ( T90� / O
Spur_Ma2
\Track
a`lyf4.,22'-00
3p E Ca�ROI_IM f - RAIL OA��
1 oA
8 NORTHWESTERN�c ;
�G��O -
7• _ ; o� o
; 01—'Co 0
t0 N
1 15 O/ N to 7 � W � —7?—,
O m °1 m
1 N • , ,n Q t�
to CR
iVtMo Niq J 'vm 0ai i Z
►� i Q Qf
p� V� 0tO N O Z
I 1 2 O O 0 Z I 2
i 2 2 Z \
S
Well M tt I
Top of well elevation = 609.25
Ground elevation a 808.14'
Latitude ■ 35'-33'-52.1"
Longitude - 80'-25'-24J-
Static water level below top of casing =
I Water level from Wayne Drye of ALCEM
Well M 0 2
Top of well elevation a 805J8'
Ground elevation ■ 802.89'
Latitude a 35'-33'-56.6"
Longitude ■ 80'-25'-26.6-
Sta11c water level below top of casing = i
I Water level from well construction recon
Well Mtt3
Top of well elevation a 793.72'
Ground elevation a 791.20'
Latitude - 35•-33'-57.5-
Longitude = 80'-25'-21.5"
Stolle water level below lop of casing = I!
I Water level from well construction record

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding laboratory analysis
Please note that your permit may contain additional parameters to be anaiyed than those required to be summarized on this form.
Permit Number W00016338
Facility Name ALCHEM, INC. LABORATORY 1 TBL LABORATORY
NPDES # 2
or WQ # (residual only Facilities) 3
WWTP Name
Residual Analysis Data
Date Sampled (grab) or 7/25/00 11/17/00
Date Composited
Percent Solids
Parameters (ma/ka dry weiahtl
Aluminum
18,740
10000
Arsenic
<5.000
BDL
Barium
38.78
36.0
Cadmium
<0.5000
BDL
Chromium
13.79
5.5
Copper
<5.000
1.2
Lead
12.22
8.9
Mercury
<0.01000
0.049
Nickel
2.411
BDL
Selenium
<5.000
0.64
Silver
<0.5000
BDL
Sodium
157.0
170
Total Phosphorus 1
+-9.81512.4
0.210
0.71
Zinc
X.
(SIGNATURE OF PREPARER) DATE
I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel property gathered an evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possiblity of fines and imprisonment for knowing violations."
DEM FORM SSF (10194)

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail]
March 13, 2006
DENR/DWQ/Water Quality Section
Mr. Daryl Merritt,
Environmental Specialist I
Non -Discharge Compliance/Enforcement Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Mr. Merritt:
MAR 1 :2006]]
NC DENR MRO
DWO -Auifer Protection
Enclosed is the Monitoring and Reporting requirements for our permit number
WQ0016338.
For the year of 2005, we used 1760 tons of silica residual from our on -site bauxite
digestion process as a fill material. I have included the Annual Residual Sampling
Summary forms ACF, RSSF AND RSSF —B. I have also included the lagoon sand
sample analysis.
Please let me know if you have any questions.
Best regards,
ALCHEM, INC
Wayne Drye,
Plant Manager
pcd
cc: Ms. Ellen Huffman,
Environmental Specialist
Mooresville Regional Office
�Y

r J
9
Permit#:
ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ0016338
County:
ROWAN
Year: 2005
Facility Name (as shown on'
permit):
Land Application Operator:
ALCHEM, WC
WAYNE DRYE, PLANT MANAGER Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
❑p Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total amount of dry tons applied during the year for all application sites: 0
Total number of acres land application occurred during the year: 0
Part B:
Facility was compliant during calendar year 2005 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. p Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this pen -nit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was -performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as, specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
WAYNE D DRYE, PLANT MANAGER
Permittee Name and Title (type or print)
U1q:��,LZ ;5
Signature of Permittee Date
Signature of Preparer* Date Signiture of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r)
DENR FORM ACF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory: 1) Environmental Science Corp
J
Facility Name: ALCHEM, INC 2)
NPDES # or 3)
WQ#:
4)
WWTP Name: 5)
Residual Analysis Data
Sample or
CompositeDate
---
Molybdenum
NEW We "10
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed- to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
-PLwa, i) ' �,L,; -
Signat e of Prepar
'52
Date
DENR FORM RSSF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory:
Facility Name: ALCHEM, INC
NPDES # or
WQ#:
WWTP Name:
Residual Analvsis Data
1) Environmental Science Corp
2)
3)
4)
5)
le or
• I • .• - •.
�•
�.
Total Nitrogen
Magnesium:11
11
----------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
C
Signadire of Prepa r
.390
Date
DENR FORM RSSF-B (512003)

Lebanon R
Mtt.. J 3uliet, TN 7122
ENVIRONMENTAL
1-800-768-5859
SCIENCE CORP.
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT OF ANALYSIS
Ms. Phyllis Drye
January 27,2006
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
ESC Sample
# L230526-01
Date Received January 20, 2006
Description NCDENH Lagoons
Site ID
Sample ID LAGOON SAND SAMPLES
Project #
: WQ0016388
Collected By Wayne Drye
Collection Date 01/18/06 08:00
Parameter Parameter D�Result
Limit
Det. Limit
Units
Units
Method Date
Method Date
DilDet.
Dil.
Nitrate
BDL
1.1
mg/kg
9056
01/24/06
1
Nitrite
BDL
1.1
mg/kg
9056
01/24/06
1
Total Nitrogen
BDL
57.
mg/kg
Calc.
01/26/06
1
Ammonia Nitrogen
BDL
5.7
mg/kg
350.1
01/24/06
1
PH
7.7
su
9045C
01/21/06
1
Organic Nitrogen
BDL
57.
mg/kg
Calc.
01/26/06
1
Phosphorus,Total
3.2
1.1
mg/kg
9056
01/24/66
1
Kjeldahl Nitrogen, TKN
BDL
57.
mg/kg
351.2
01/25/06
1
Total Solids
88.0
254OG
01/27/06
1
Mercury
BDL
0.023
mg/kg
7471
01/25/06
1
Aluminum
38000
28.
mg/kg
6010B
01/25/06
5
Arsenic
BDL
1.1
mg/kg
6010B
01/25/06
1
Barium
88.
0.28
mg/kg
6010B
01/25/06
1
Cadmium
BDL
0.28
mg/kg
6010E
01/25/06
1
Calcium
8500
28.
mg/kg
6010B
01/25/06
1
Chromium
3.0
0.57
mg/kg
6010B
01/25/06
1
Copper
4.2
1.1
mg/kg
6010B
01/25/06
1
Lead
39.
0.28
mg/kg
6010B
01/25/06
1
Magnesium
1800
5.7
mg/kg
6010B
01/25/06
1
Manganese
2.5
0.57
mg/kg
6010B
01/25/06
1
Molybdenum
1.9
0.11,
mg/kg
6010B
01/25/06
1
Nickel
3.5
1.1
mg/kg
6010B
01/25/06
1
Potassium
1200
140
mg/kg
6010B
01/25/06
5
Selenium
3.0
1.1
mg/kg
6010B
01/25/06
1
Silver
BDL
0.57
mg/kg
601013
01/25/06
1
Sodium
1000
140
mg/kg
6010B
01/25/06
5
Zinc
3.0
1.7
mg/kg
6010B
01/25/06
1
L'o". &J—
J y Hunt, ESC
Representative
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Laboratory Certification
Numbers:
AIHA - 100789, AL - 40660, CA -
I-2327, CT-
PH-0197, FL
- E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND
- R=140, SC -
84004, TN - 2006, VA - 00109, WV
- 233
AZ -0612, MN - 047-999-395, NY -
11742, NJ -
81002,
WI - 998093910
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 01/27/06 10:11 Revised: 01/27/06 10:47
Page 1 of 7

r
Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte Qualifier
L230526-01 Arsenic J6
Calcium VJ3
Magnesium V
Molybdenum J6
Ammonia Nitrogen- J6
Phosphorus,Total J6
Page 2 of 7

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
V (ESC) - Additional QC Info: The sample concentration is too -high to
evaluate accurate spike recoveries.
J3 The associated batch QC was outside the established quality control range
for precision.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ) (SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 68-128 64-125
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 76-115 69-118
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromofluorobenzene 79-127 61-134
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 3 of 7

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L230526
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 27, 2006
Analyte Result Units Date Analyzed Batch
PH::.::= ..............0.............. 0121/fl6...6, ? ?........ j"1G23;5503
Ammonia Nitrogen < 5 mcr/kq 01/24/06 11:45 WG235738
Aiuminum
< 5
mg/kg
01/25/06
02:58
WG235750
Arsenic
< 1
mg/kg
01/25/06
02:58
WG235750
xb m...:: ... _....XX
..:...... .......
..:.::.:. <..:.. ;:5:•;:•;:;;::.;:..:.;:....:......tl1J
:.1.:.;;:;;;•.;4.1f.
5,::06;;.;Q2
5 ::;<>;
WG235750.....: ..............
Cadmium
< .25
mg/kg
01/25/06
02:58
WG235750
Calcium
< 25
mg/kg
01/25/06
02:58
WG235750 .
....:... :
h ....................:>::>:::.:::>::»:::::
:.::.....:::::.....:::.:....::.::::.:...:::.:::.:...................:::..:::::::.::.;:.;;;:.;:.;:.::.3
.......:::.:::::::::..:..:::::::::::::::
5
m .: k ......
:..:: g
d i 2 ::fl.6
%...:...:.::.:..:.::::::..
.02:::. $:.::::.:
WG2 : 7 0
3 ... 5.....:.......:::::::::::..:::.:::..
»;::>,:::; :
Copper
< 1
.:.:.............
mg/kg
01/25/06
..:::::::.....:.:..:.
02:58
WG235750
Lead
< 25
mg/kg
01/25/06
02:58
WG235750
Magnes;� um _
< 5 -
.......................
::>::::::::;.
m k.
g/... ............/
Q1 25 A6
.../. ..............
0.2:5$::::ir`:
.
WG2:3.SS75{i.....;::>:':...:>:<:.....
........:::.
Manganese
<.....5
mg kg
O1/25/06
02:58..
WG23575.0.............
Molybdenum
WG235750
.::.:..:....:::.....:....:......:.....:.........:..................................�.....1................................mg/kg............0.1/25/0.6...02:58
Nickel...::.... .::>;:;::;;.`:;::::;;:> ...........::::::......... >:::`:>:.i`»`>>
;<:>::>::>::::::>;;::><<:>:7`» >#s?>`»::?::>::::>::::>::>:....
...::......::::::.:�
::
:;m .,. :;::::(Y
...............?
9%....5................./.....................
.2 .>06..::2
.....al...................8...............G..........................................................
5: :::> ::>...t�l
23:5:7:50::>'
Potassium
25
mg/kg
61/25/06
15:05
WG235750
Selenium ... _ ....
5. .........
02:58
WG23575.0
_ _
Silver - :..............; .:............:... <:; ::.
::.::,.:.,...:.::::.:...::.::..:.:....:....:.:..::.............................................................
_1
<,:::::;.;:;; : ;;:::;;.:. .::.; :<::;.:.
<...,5......
.. .......
;.:;>: »:.;;;«;;::::.:....:
...............M
.mg/.kg ........01/25/06
.k...........0.1..25..0.6....02...55..........WG23.5....5.0....::.>::»:......:................>;
q/....g..................f.......
/...................................................................................................
.:.....
.....
7
Sodium
< 25
mg/kg
O1/25/06
15:05
WG235750
Zinc
< 1.5
mg/kg
01/25/06
02:58
WG235750
.;
.. . . _: ;::..........: ...... a :::: ; r>>::;:
Nitrate
_::..:.:....:.:....:....:::.:.
;: ;;::;;;<»::::::>::: r>::>;::::;.: r: r:::::»r::
< 1
»:<:::::::::>:«:»:z:::::
»::;:::>:>::>::;>:<:Ea»iii<
mg/kg
:.;:::?:>::>E:::::<:;:::<::?;;:
O1/24/06
»»»?::;;;.....?: ` >:::::.::
00:00
..:...:..:..::::::::::::.:::::.......:::.::::
;.. .. :.::::.:::
WG235793
Nitrite
< 1
mg/kg
01/24/06
00 00
WG235793
Ph5bphoru8, Tata1
.. c...
::»::
:::::::..
hlq/kg........01/24/05...00.00......
WG235793......
..
Kjeldahl Nitrogen, TKN
< 50
mg/kg
01/25/06
13:00
WG235904
::.................................................
Total Solids
OOO
.
OI27>/0<fi083z:
i:::..........................::i
.:.... ..............
W235940..............
.. ..
50WG235979.:,:.,.
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
H , :::> ::;: ..:::;:<:::<::...:.;;:
P _....._:...::.>...:..:..............................:....................................:.:.........._:..:..::.........................::......:
.;::•::. Stit':<:<:::;i:r
z:>.::;::4• :5 0 %.........
4. 6A.::::::::::..:.:::
:: .;> <: ;2..
2:.....0.::::::.:
» ::>:`...:;; > :>::::
24::.:::_::.........
2;:
...... 19.::....
.. G 5 06 <:
41.. 23..:5...3..
_ ............_.._........................................................................................................................................................
PH
su
4.50
4.50
.....................................................................................................
0.00
20
L230419-04
WG235503
Ammons <Na tra en _:::::>::::> : ... :::.....:: .>;>.;.:::;::>:>.
....__ . :..g..4.:'::..:.... . I......::..........::.::::.:..::..:::fig
,;:;.;::.> ;..::;»
kg...:::0:+:
>°> ' :>»
?Q.:.::::::.:::..
:?> s a: ' :
4 49;..:::::
'» :::..;. ;
. ..Q..9Q ....::::
..........
4;:::>::'.::`
:.... T�230705?.:.Ol .:..W..G
7 ,.:
..38.
Arsenic
mg/kg
0.00
0.00
0.00
20
L230526-01
WG235750
Barium :..:.. :
mg/k9<.::..1,
.;:.;2:0.:;;:<::><::.>..';Ii2;30526
01
WG235750
Cadmium
mg/kg
.:.:..,:.;;7.7:;,::::
0.00
0.00
;:::.:...5..31.;.
••0.00
20
L230526-01
WG235750
Calcium
mg/kg
9280
7500
21.2
0
L230526-01
WG235750
Chromium :
m
:..........:g
.........;.
9 I :>:.>:;>:<:::.>:2
70
'6. ..........:.20.;:.....
.
;....::.:....
2,230526
Copper
..:g..................................
mg/kg
3.37
3.70
9.34
.20......
L230526-01
WG235756'
Lead
mg/kg
30.9
34.0
9.55
20
L230526-01
WG235750
g.. ::.
m /k .
2�50:.....:::<;::16:Q;0:::;:::::::><:
3 :::>::::>::::>:Q.,;:;::>::>:;::;:::><....
L23tX52f...01...WG23:5750
..... ....... ..:::... ....:......::..::::::.>:.:..
Manganese
.mg./kg.........2...92
...
2...20...
...
......28.:..........20...................L230526-01.:..:WG235750
Molybdenum
mg/kg
1.63
1.70
4.20
0
L230526-01
WG235750
Nickel '.< _:.
-,: _.:
m . k ......:3..,
gL..g......
$::::?>::?:<::3:
10
;::;::..2:::;5 5
2 0:.>.;`:;;:::.:
`: L23 0 52 6 01
W.G2 3 5 "150
.Selenium
mg/kg
.. .
2 . 52
..... 70.
....... 5 ..90........20
.................
L230526-0.1
WG235750
Silver
mg/kg
0.00
0.00
0.00
20
L230526-01
WG235750
Zinc :::::.,::.:......:: <.::.;::.:,.:::.:.:.....:...:..:...:::::......::
m . k :.......:7
>::::::.: ,::.g:9......
3 2 :.
:.:.:
.............................................................................................................................I-
.X.X.: :•:::.
•;;::.;;:;;:2::..70 ; ..
:.........................................................................................
- :.:.;, .....:
• ..::.;:9.2 2
.
2.0..;:i <:,>>>:::;:':
h2.3 0 52:6 01
.........................
WG235 75:0'
............... .
Kjeldahl Nitrogen, TKN
mg/kg
0.00
0.00
0.00
20
L230526-01
WG235904
Total Solids'::s:::<:........................................................................
87.8
8.8:::0:<::.;:.
018:42>0:
..........
:::L23:0526-0:1>:<>WG23
5 -
5 940
i ab6. t t- ;Cori
r; ;l mpl e <;
Page 4 of 7

ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level
II
Rockwell, NC 28138
January 27, 2006
L230526
Analyte
Units
Known
Val Result
% Rec
Limit Batch
......:.:.
;;;;:.....:..:<.....
::>: WG23.5 03 .. ..
Ammonia Nitrogen
mg/kg
305
230.
75.0
50-150 WG235738
Aluminum
s>::,.....
mg/kg
. .
7090
6770
95.0
57.8-142 WG235750
Arsenic
mg/kg.........::1:87
WG235750
Barium :<.....:.::.
.:..:':: m :.k :>::°<::•::.>2:2:8::r:>::>:....
:....:::::::::::::::::1:7.1:;.::::::::.::.::::::::.:::::.9:1.:;:0:72-128
:»>::::>..............................
:: <102.: i
75 .4 125. WG23.5750
..:::
Cadmium
:........:::..g/...g:.:.....::....::..::.:...
mg/kg
125
121.
97...0
80.8-1'19 WG235750
Calcium
mg/kg
3700
3460
94.0
66.8-133 WG235750
:.
Chromium;::>
lI2 :• ;::::>?::>::::>:<<.:....
11.7.->:<::::
•.::.:.
J.0?....:..
7 <5-120: WG235.7
.......................
.....::.
Copper
mg/kg
90.1
.
86.8
96.0
80.4-119 WG235750
Lead
mg/kg
152
144.
95.0
78.6-121 WG235750
Ma nes:um:..:..::..::.;;::.:. ....:.......
m ;:k .::•.::::.:..223tJ
:.: »::::;>: 2Q$0 ::::"::`::»::
<>::>::::::::93.:0 .....72.:.6
727. WC235750
Manganese
mg/kg
284
280.
99.0
79.7-120 WG235750
Molybdenum
;1;z1WG23,5750;:.;;:.;:;.;:
....................................................................
...............mg/kg....:...::::78.:.8•:::::::.::::::::::::::.73;9.::.:::::.::.9.4*:078..2
::.
ctt :.}C.::::::::::<5fi:,:S
.......................6.5....3.:....:>::::`
.. .
;>::::;; c ;:; :.r::.
8'.4:.......77.�>7;-7;22::.Wra`23::575.0
: >:::>::;.. 9.......,..............
... ........ ..................................
Potassium
mg/kg
2140
1946
91.0
71.0-128 WG235750
Selenium
mg/kg
163
153.
94.0
65.6-134 WG235750
....<.
..:::
12 5 .:::;<;:.;:a:::::;::::>::>::::
::::.:...::::.......:::::.:::::::
3:2:
166 ::
9:': 2..:15 0.. WG23575 Q ..... .
Sodium
mg/kg
816
736.
90.0
55.6-144 WG235750
Zinc
mg/kg
232
212.
91.0
46.1-153 WG235750
Nitrate
,:; . . ,:;.;; g
mg/kg
..
314
310.
99.0
75.5-124 WG235793
Phosphorus, Total
mg/kg ...........5.2
..........................67........:::::.:::::::::::::::::12:7::.:::::::::::::::50.
.15:0::::::,: WG235793 ;:;;:;;:
Kjeldahl Nitrogen, TKN
mg/kg
820
780.
95.0
58-141 WG235904
_.
Total Sgl:ads ..::: -:
:<: ::::%;'r'"; ........5�...:........
«:::><'.;;;:;;::,;::.
5.0.2.::...:::::..::::::::..10.:..:..........................
0
SS:.J.15 WG235940
........:..
Mercury
mg/kg
11.7
13.2
113.
66.4-133 WG235979
T abo ato y Contra] Sample D.U l Kate
Analyte
Units
LCSD Res
Ref'Res RPD
Limit Rec
Batch
_.:.::.....:.::::...................::::..;;>......:.................._........_....s
:...:..::.::::.8..:8:0................8..80X.
......._.....O.,.QO.........�i.:.....
.&.....:`.:>>:::...............
.......... ........... ::......:.:.;::......
Ammonia Nitrogen
mg/kg ...240
...............230:':::::.:::.:::::4:':2:6:::::::279WG2357;3;8:::;:.;:;:;:::::;:<;;:.;;.::.
.
:% ,. ... .: -:
Nitrate
;; ii">'r'` ` . '.;.:
mg/kg
;:?s: i'i% oii i'iiG:`,...;:...,
300.
".. ...
310. 3.28
....
20 96
... . .. ......... ..
WG235793
Phosphorus Total
mg/kg
70..0
67.0 4.38
20 133
r:r
WG235793
Kjeldahl Nitrogen, TKN
»:;;
mg/kg
710.
780. 9.40
20 87
WG235904
Total-:;:So.l.ids:,
Analyte
Units
MS Res
Ref Res TV
% Rec Limit
Ref Samp Batch
Ammonia::avltro. en ............:.:::.. ..::::.,;
.::.:
:..<;;:: ;;:::>::>.;m k
::..::..:..g::.9•:•
36:D::;:.:::::,:..::»;;::0..;:00
:..... .........
....540
7;2''0 $0 120
...
L230526 Ol WG235738_:
Aluminum
mg/kg
29500
33000 10
0.0 75-125
L230526-01 WG235750
-:.:.
Arsenic.: _:.:. _:..,:
iil: .;k ....:
3...0.:;.:::«<::<:<:>::>:0<..00<::>::>:<:5'00...:::..12...
7�234526 OL. VG23S74
..........:..
Barium
............gf....g..
mg/kg
.....................
121.
77.0 50
88.0 75-125
L230526-01 WG235750
Cadmium
mg/kg
45 9
0.00 50
92.0 75-125
L230526 01 WG235750
Calcium
m g/kg.»9.:Q.
>:...7.5:0fl:`
:' SQ0
39'8':<: 7 125.....
L2S' 'S25; 42.;WG2357-56
Chromium
mg/kg
.
48.6
2.70 50
92.0 75-125
L230526-01 WG235750
Copper
m k
50.2
3.70 50
,.::.:::::.:::..:,.:::::.,,::::.:::::.......:..::::..:..::...;..:..:.;:;;:............,...:...:;:........:........:..:.......:-
93.0 75-125
L230526-01 WG235750
.................. _......._.........................................:::.::::::9/
Lead _
.5.....
M .k:
>. g/ . g
:723::::::.<.....3.4:0;:;Q
.................... .
:`75-:21
. :t:0:?...WG23 7 0;:
Magnesium
mg/kg
2470
1600 500.
174. 75-125
L230526-01 WG235750
Manganese
mg/kg
50.0
2.20 50
96.0 75 125
L230526 01 WG235750
Molybdenum :.
:.... ?t!3�kJ
..38 7.......<>;:'170......:..
7..0...7$ ]25
T�23056 01 WG23575:0.;
..
.....
Nickel
mg/kg
49.0
3.10 50
92.0 75-125
L230526-01 WG235750
Page 5 of 7

r
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L230526
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615) 758-585S
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 27, 2006
Potassium mq/kq 1340 980. 100 72.0 75-125 L230526-01 WG235750
yFiIaarzar Sp1ke;
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp
Batch
S,el;enium:
mJ1�g.....:7
:::::.::::::::»»`:::7a.......5:0
77 0...75
325...b230:526:..0I.WG23S7SQ,
Silver
mg/kg
47.9
0.00
50
96.0
75-125
L230526-01
WG235750
Sodium
mg/kg
1270
460.
100
162.
75-125
L230526-01
WG235750
::; :>;<::: :: ..
Zinc..:::::..:.::..:.::::>....<....:::::<:............::..............:...........:>;::......................m
::.;>::.::.:;:.: .k.:.:::5.5....Q..........:....:2.,.
:•::.:::::::.: �3.::.!3.::::::.::.::....:::.:...:.:.:............:...........:..
>::>::;:<:>:<:::»:;::..:;
..:.:.::.:.
70.:::.:.
>::>;:
::...
S.Q:..:::::.:..::1:Q;5...::.::.`..5.....325::..:.....................................................
....... .........
::
-23.t1525::.0:1
....... ......... ...............
..w:G23575:0::
.........:.:.:..................................
Nitrate
mg/kg
53.0
0.00
50
106.
80-120
L230526-01
WG235793
;.:.......:,.:::..::.::.....................;<:.:.
Ni;trate::::::..::.::::::::::::::.::::::::::::::::::::::::...:......
.::.m...k......>a4......................1..,.8..........59...............E
g/...5.......................................
.
Q4..,.......&fl...�2.4..::::>2:3:Q57:1;:..18..;WG2.3.579:3:
Nitrite
mg/kg
53.0
0.00
50
106.
80-120
L230526-01
WG235793
Phos horus,Total
:.:...... P :.::.:. :..:::::::.:.,.::::..:: .
mg/kg......2.5..
...................
2...80.........5...................4.4..0...80..-.1.2.0......L230526-0;1:::WG235793
R`` ldahl Nitro e KN.....
Je g
...................
g/ g
a210 >
: 20
>9:508:0:
_2:0L.230751-01
1
VIG235904:
Mercury:.::.:
........ kg
:.::..
9 ':063.0...
25
92 D.::70
.7 3i3
<::WG235979;
Mar1x..;SpzDnplcae.
......MSD
Analyte
Units
Res
Ref Res
RPD
Limit %Rec
Ref Samp
Batch
Ammonia;N.ltrogen :.::.;.
- ?ngf..kg..6Q.........
36:Q:.•.
a.. Ob
.....zfl.......:7.2
0.......L2,0526
Q• WG23573'8
Aluminum
mq/kq
32200
29500
8.75
20
0-.00
L230526-01 WG235750
Barium
Cadmium
Calelum
Chromium
Copper
Lead
Magnesium
Manganese
Molybdenui
Nickel
Potassium
mg/kg
130.
121.
mg/kg
47.2
45.9
mg/kg
49.8
48.6
mg/kg
52.1
50.2
mg/kg
2250
2470
mg/kg
50.0
50.0
mgf...............7..
mg/kg
50.8
49.0
mq/kq
1380
1340
7.17
20
106.
L230526-01
WG235750
2 79
20
94.0
L230526 01
WG235750
..86......,29
<><<'..:290.
Tr2.305�6 .01
.WC�235750
2.44
20
94.6
L230526-01
WG235750
3.71.
20
97.0
L230526-01
WG2357SO
';20
$9:'Q:
`.':2395Z6 Q1
T�1G235750
9.32
20
130.
L230526-01
WG235750
0.00
20
96.0
L230526 01
WG235750
3 6;:.
20 : ......
71. 0 ;
•..:L23.0526 Q1..WCs235750
3.61
20
95.0
L230526-01
WG235750
2.94
20
80.0
L230526-01
WG235750
Silver
mg/kg
48.8
47.9
1.86
20
98.0
L230526-01
WG23575U
Sodium
m /k
9 g
1240
1270
2.39
20
156.
L230526 01
WG235750
Zzric _.:........ ..
,mg/1�g.....6.
4.........?5.:...
...::'
.�� ,51:::
2D:'......0:7:,:.>:::.:.:L23A5&
Ul...WG23575:;0
Nitrate
mc�/kg
53.0
53.0
0.00
20
106.
L230526 01
WG235793
Nitrate' '. :::::•.
m k8
•::•:.: ..:.;.........gl:..g::.
0
.. ::.:.::•:::
::::
$3.,. 0;:;
.............
»r: 9 01
....
2:0 ;<;
f>E".13
L230526 01
............................
93
]G23:5..
:.
Nitrite
mg/kg
53.0
53.0
0.00
20
106.
230526-01
WG235793
Phosphorus Total
mg/kg
25.0
25.0
0 00
20
44.0
L230526 01
WG235793
Kjeldahl Nitrogen, TKN
mg/kg
....
690.
400.
.......
53
24
L2307 51 - O 1
WG2 3 5 9 0 4:.:;..
Mer.cur Y5%...J.
.. k >::.:
::.0.30•::
... ........
..4..2:�.3:.
..? 69
...20.
9,:i7:::`.>:><L...0585
02:WG235979
Batch number /Run number / Sample number cross reference
WG235503: R262558: L230526-01
WG235738: R262742: L230526-01
WG235793: R262846: L230526-01
WG235750: R262898: L230526-01
WG235979: R263012: L230526-01
WG235904: R263068: L230526-01 .
WG235874: R263101: L230526-01
WG235876: R263103: L230526-01
WG235940: R263143: L230526-01
* * Calculations are performed prior to rounding of reported values
Page 6 of 7

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 January 27, 2006
L230526
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a 11J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a 11J5" or a 11J611. The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a 11J3" qualifier.
Page 7 of 7

12065
Lebanon Rd.
0
Mt. Juliet,
TN 37122
ENVIRONMENTAL
615)758-5858
1-800-7677-5859
SCIENCE CORP.
Fax (615)
758-5859
Tax I.D.
62-0814289
'
Est.
1970
REPORT
OF ANALYSIS
Ms. Phyllis Drye
March
03,2006
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
ESC
Sample #
L234332-01
Date Received February 21, 2006
Description NCDENH Lagoons
Site
ID
Sample ID LAGOON SAND SAMPLES
Project
#
W00016388
Collected By Wayne Drye
Collection Date 02/20/06 08:00
Parameter Dry
Result
Det. Limit
Units
Method
Date
Dil.
Nitrate
BDL
1.1
mg/kg
9056
02/24/06
1
Nitrite
BDL
1.1
mg/kg
9056
02/24/06
1
Total Nitrogen.
BDL
1.1
mg/kg
Calc'.
03/02/06
1
Ammonia Nitrogen
BDL
5.5
mg/kg
350.1
03/03/06
1
pH
8.1
su
9045C
02/22/06
1
Organic Nitrogen
BDL
0.55
mg/kg
Calc.
03/03/06
1
Phosphorus,Total•
BDL
1.1
mg/kg
9056
02/24/06
1
Kjeldahl Nitrogen, TKN
BDL
55.
mg/kg
351.2
02/26/06
1
Total Solids
91.4
%
2540G
03/01/06
1
Mercury
0.023
0.022
mg/kg
7471
02/28/06
1
Aluminum
34000
5.5
mg/kg
6010B
02/27/06
1
Arsenic
BDL
1.1
mg/kg
6010B
02/27/06
1
Barium
76.
0.27
mg/kg
6010B
02/27/06
1
Cadmium
BDL
0.27
mg/kg
6010B
02/28/06
1
Calcium
11000
27.
mg/kg
6010E
02/28/06
1
Chromium
20.
0.55
mg/kg
6010B
02/27/06
1
Copper
3.7
1.1
mg/kg
6010B
02/27/06
1
Lead
26.
0.27
mg/kg
6010B
02/27/06
1
Magnesium
2500
5.5
mg/kg
6010B
02/27/06
1
Manganese
3.7
0.55
mg/kg
6010B
02/27/06
1
Molybdenum
0.46
0.11
mg/kg
6010B
02/27/06
1
Nickel
2.6
1.1
mg/kg
6010B
02/27/06
1
Potassium
1000
27.
mg/kg
6010B
02/24/06
1
Selenium
2.1
1.1
mg/kg
6010B
02/27/06
1
Silver
BDL
0.55
mg/kg
6010B
02/27/06
1
Sodium
600
27.
mg/kg
6010B
02/24/06
1
Zinc
6.1
1.6
mg/kg
6010E
02/27/06
1
mmy H t, ESC Representative
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Laboratory
Certification Numbers:
AIHA - 100789, AL - 40660, CA -
I-2327,
CT- PH-0197, FL -
E87487,
GA - 923,
IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704,
ND - R-140, SC -
84004, TN
- 2006,
VA - 00109, WV
- 233
AZ -0612, MN - 047-999-395, NY -
11742, NJ - 81002,
WI - 998093910,
IL-200008
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 03/03/06 17:27 Printed: 03/03/06 17:27
Page 1 of 7

Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte
Qualifier
L234332-01 Aluminum
V
Arsenic
J6
Calcium
V
Magnesium
V
Molybdenum
J6
Potassium
J3
Selenium
J6
Page 2 of 7

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J3 The associated batch QC was outside the established quality control range
for precision.
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
V (ESC) - Additional QC Info: The sample concentration is too high to
evaluate accurate spike recoveries.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'A' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ) (SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 68-128 64-125
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 76-115 69-118
2,4,6-Tribromophenol 51-141 Terphenyl-dl4 43-137 4-Bromofluorobenzene 79-127 61-134
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 3 of 7

12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 03, 2006
L234332
Laboratory'Blank.
Analvte Result Units Date Analvzed Batch
pH
5.60
su
02/22/06
15:45
WG239538
Aluminum
< 5
mg/kg
02/27/06
04:31
WG239919
Arsenic
< 1'
mg/kg_.
02/,27/0.6 `04:31
WG23991.9..":
Barium
< .25
mg/kg
02/27/06
64:31
WG239919
Cadmium
< .25
mg/kg
02/27/06
04:31
WG239919
Calcium
< 251:.
mg/kg_,
02/28/06.20:,18
WG239919.
Chromium
< .5
mg/kg
02/27/06
04:31.
WG239919
Copper
< 1
mg/kg
02/27/06
04:31
WG239919
Lead
< .25,
mg/kg
02/27/06
04:31
WG239919
Magnesium
< 5
mg/kg
02/27/06
04:31
WG239919
Manganese
< .5
mg/kg
02/27/06
04:31
WG239919
Molybdenum
< .1
mg/kg
02/27/06
04:31
WG239919
Nickel
< 1
mg/kg
02/27/06
04:31
WG239919
Potassium
< 25
mg/kg
02/24/06
14:30
WG239919
Selenium
< 1
mg/kg
.02/27/06
04:31'
WG239919
Silver
< .5
mg/kg
02/27/06
04:31
WG239919
Sodium
< 25
mg/kg
02/24/06
14:30
WG239919
Zinc
< 1.5
.. ..;mg/kg,"
02/27/06
04:31
WG239919
Kjeldahl Nitrogen, TKN
< 50
mg/kg
02/26/06
15:00
WG2.39960
Nitrate
< 1
mg%kg
02/24/06
00:00
WG239964
Nitrite
< 1
mg/kg
02/24/06
00:00
WG239964
Phosphorus,Total
< 1
mg/kg..
02/24/0.600-00
WG239964
Mercury
< .02
mg/kg
02/28/06
01:06
WG240349
Total Solids
0.00
%
03/01/06
09:53
WG240432
Ammonia Nitrogen
<".1
mg/1
03/03/06'08:25
WG240586
'Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
pH
su
8•.40
8.50'
1.18
.20
L234179-13
WG239538
pH
su
7.50
7.40
1.34
20
L234179-14
WG239538
Cadmium
mg/kg:`
0.00.",,
0."00
0.00
20
L234332-01
WG239919
Calcium
mg/kg
9300
9800
5.24
0
L234332-01
WG239919
Potassium
mg/kg
1210
890.
30.5
20
L234332-01
WG239919
Sodium
mg/kg'638:1:
470.
30.3 `
20
L234332-01
,WG239,919
Kjeldahl Nitrogen, TKN
mg/kg
0.00
0.00
0.00
20
L234332-01
WG239960
Kjeldahl Nitrogen, TKN
mg/,kg
780.'"
990..,
23.8
20
L234509-01
WG239960
Phosphorus,Total
mg/kg
0.00
0.001.
0.00
20
L234018-09
.WG239964
Total Solids
%
81.6
81.4
0.215
20
L234915-01
WG240932
Ammonia Nitrogen
mg/1
158.'.''
150.'
4,.92.
20
L235225-01
WG240586
Laboratory
Control"Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
pH
su
9
8.80
98.0
85-115 WG239538
Aluminum
mg/kg
7090
7470
105,
57.8-142 WG239919
Arsenic
mg/kg
187"',
176.
94..0
72-128 WG239919
Barium
mg/kg
228
234.
103.
75.4-125 WG239919
Page 4 of 7

1 .,
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Cadmium
Quality Assurance Report
Level II
L234332
125 118.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
(.615) 758-5858
1-800-767-5859
Fax'[phone]
Tax I.D. 62-0814289
Est. 1970
March 03, 2006
0 80.8-119 WG239919
Analyte
UnitsboraKnownCValrol
Sample
Result
% Rec
Limit
Batch
Calcium
mg"/kg,
3700
` 3900.
.105..
66.8-133:WG239919
Chromium
mg/kg
112
108.
96.0
79.5-120
WGZ39919
Copper
mg/kg
90.1
89.5
99.0
80.4-119
WG239919
Lead
mg/kg''
152
150._
99.0
78 6-421.WG239919
Magnesium
mg/kg
2230
2170
97.0
72.6.127
WG239919
Manganese
mg/kg
284
285.
100.
79.7-120
WG239919
Molybdenum
mg/kg
78.8
78.3.:
99.0,
7$,2-121
WG239919.
Nickel
mg/kg
66.5
63.8
96.0
77.77122
WG239919
Potassium
mg/kg
2140
2160
101.
71.0-128
WG239919
Selenium
mg/kg
163,
156.
96.0
65.6-134
WG239919.
Silver
mg/kg
125
132.
106.
49.2-150
P7G239919
Sodium
mg/kg
816
862.
106.
55.6-144
WG239919
Zinc
mg/kg,,
232
202.
87.0
46.1=153
WG239919
Kjeldahl Nitrogen, TKN
mg/kg.
1270
1150
90.0
58-141
WG239960
Nitrate
mg/kg
314
280.
89.0
75.5-124
WG239964
Phosphorus,Total
mg/kg
52.7
59.0
112.
50-150
WG239964
Mercury
mg/kg
11.7
10.1
86.0
66.4-133
WG240349
Total Solids
`50',, .,.,
:50,2,
100.:.
.85-115 -
;WG240432
Ammonia Nitrogen mq/1 7.5 403. 5380 85-115 WG240586
Laboratory Control -Sample.
Duplicate'
Analyte
Units
LCSD Res
Ref Res
RPD
Limit %Rec
Batch
PH
su.
8.90
8.80
.1.13.:
.20
99.
WG239538
Kjeldahl Nitrogen, TKN
mg/kg
1100
1150
4.01
20
87
WG239960
Nitrate
mg/kg
280.
280.
0.00
20
89
WG239964
Phosphorus,Total
mg/kg
59.0
59.0
0.00
20
112
WG239964
Ammonia Nitrogen
mg/1
401.
403.
0.508
20
5350
WG240586
Matrix Spike
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp
Batch
Aluminum
mg/kg
33900....
31000.
50
,5800
.75-125
L234332-01
WG239919
Arsenic
mg/kg
33.4
0.00
50
67.0
75-125
L234332-01
WG239919
Barium
mg/kg
119.
69.0
50
100.
75-125
L234332-01
WG239919
Cadmium
mg/kg
51.8:_
'0.00 .,
5.0..
104.
75-125
L234332-01
WG239919
Calcium
mg/kg
9580
9800
500
0.0
75-125
L234332-01
WG239919
Chromium
mg/kg
65.3
18.0
50
95.0
75-125
L234332-01
WG239919
Copper
mg/kg
52.4
3.40 ,.50
98.0
75-125
L234332-01.WG239919
Lead
mg/kg
69.9
24.0
50
92.0
75-125
L234332-01
WG239919
Magnesium
mg/kg
2100
2300
500
0.0
75-125
L234332-01
WG239919
Manganese
mg/kg
50.2
3.40
50
94.0
75=125
L234332-01
WG239919
Molybdenum
mg/kg
35.8
0.420
50
71.0
75-125
L234332-01
WG239919
Nickel
mg/kg
47.4
2.40
50
90.0
75-125
L234332-01
WG239919
Potassium
mg/kg.1500•
8.90.
500
122.
75-125
L234332-01
WG239919
Selenium
mg/kg
38.9
1.90
50
74.0
75-125
L234332-01
WG239919
Silver
mg/kg
46.8
0.00
50
94.0
75-125
L234332-01
WG239919
Sodium
mg/kg
1020
47.0. '.
500
.110.
75-125'
L234332-01
WG239919
Zinc
mg/kg
47.5
5.50
50
84.0
75-125
L234332-01
WG239919
Kjeldahl Nitrogen, TKN,
mg/kg.4030
;_10000
200".,;,.;;,,
0.,0
80,-120
,L233871701
WG239960
Page 5 of 7

12065 Lebanon Rd.
0 615)75-5858
Mt. Juliet, TN 37122
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135.Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 03, 2006
L234332
Matrix Spike.
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp Batch
Mercury
mg/kg
',-0.240
;.:; 0 00 ':
-.25:
960
70=130 `.:L23
4674-16: WG240399
`Matrix:
Spske.<Duplcate:':
Analyte
Units
MSD"Res .
Ref Res
RPD
Limit %Rec
Ref Samp
Batch
Alumigum
mg%kg'37700:.:
^:33.900 ':
l& 6 `'•.2D
`. 13.400
''L234332r01:.WG239919
Arsenic
mPkg
36.4
33.4
8.60
20
73.0
L234332-'Ol
WG239919
Barium
mg/kg
125.
119.
4.92
20
112.
L234332-01
WG239919
Cadmium
mg/kg
52.4
51.8
1.15:
20
105.
L234332-01
WG239919
Calcium
mg/kg
10000
9580
4.29
20
40.0
L234332-01
WG239919
Chromium
mg/kg
70.3
65.3
7.37
20
105.
L234332-01
WG239919
Copper
mg/kg
55.0
52.4
4.84
20
103.
L234332-01
WG239919
Lead
mg/kg
74.,8
69.9
6.77
20
102.
L234332-01
WG239919
Magnesium
mg/kg
2090
2100
0.477
20
0.00
L234332-01
WG239919
Manganese
mg/kg
:50.3
50.2
0.'199,.20
94.0
L234332-01.WG239919
Molybdenum
mg/kg
37.0
35.8
3.30
20
73.0
L239332-01
WG239919
Nickel
mg/kg
50.4
47.4
6.13
20
96.0
L234332-01
WG239919
Potassium
mg/kg
1620-.
1:500
7,.69
20
.146.
L234332-01
WG239919
Selenium
mg/kg
40.2
38.9
3.29
20
77.0
L234332-01
WG239919
Silver
mg/kg
48.4
46.8
3.36
20
97.0
L234332-01
WG239919
Sodium
mg/kg
-1120-
1020
.9.35
20
130.
L234332--01".WG239919
Zinc
mg/kg
49.4
47.5
3.92
.:
20
88.0
1,234332-01
WG239919
Kjeldahl Nitrogen, TKN
mg/kg
-:3490:."„
4030
14.5
20
0.00
1,233871=01
WG239960
Mercury
mg/kg
0.250
0.240
4.08
20
100.
L234674-16
WG240349
Batch number /Run number / Sample number cross reference
WG239538: R266116: L234332-01
WG239964: R266394: L234332-01
WG239919: R266456: L234332-01
WG239960: R266544: L234332-01
WG240349: R266632: L234332-01
WG240432: R266793: L234332-01
WG240899: R267055: L234332-01
WG240586: R267137: L234332-01
WG241061: R267206: L234332-01
* * Calculations are performed prior to rounding of reported values .
Page 6 of 7

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 March 03, 2006
L234332
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the."B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a "J6". The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 7 of 7

11/28/2005 09:22 7042798418 ALCHEM INC PAGE 01
ALCHEM, INC.
8135 ,>R..Ea3 ROAD
ROCKWELL, PVC 28138
704-279-7908 FAX: [phone]
pdrys alitel.net
TO:
FROM:
Ellen Huffman
_ Wayne Drye
rAX NUMBER:
DATE:
704-663-6040
11/28/ZOOS
COMPANY:
TOTAL NO. OF PAGES INCLUDING COVER:
NCDENR
PHONE NUMBER;
704-663-1699
RE:
Sand Monitoring
Alchem sand monitoring logs.

6i
11/28/2005 09:22 7042798418 ALCHEM INC PAGE 02
PH ELECTROMETRIC MEASUREMENT
1,1 Method 9040 is used to measure the pH of aqueous
wastes and those multiphase wastes where the aqueous
phase constitutes at least 20% of the total volume of the
waste.
7,2Place the sample or buffer solution in a clean glass beaker
using a sufficient volume to cover the sensing elements of
the electrodes and to give adequate clearance for the
magnetic stirring bar. If field measurements are being
made, the electrodes may be immersed directly into the
sample stream to an adequate depth and moved in a
manner to ensure sufficient sample movement across the
electrode — sensing element as indicated by drift — free
readings (<0.1 pH).
7.4 Thoroughly rinse and gently wipe the electrodes prior to
measuring pH of samples. Immerse the electrodes into the
sample beaker or sample stream and gently stir at a constant
rate to provide homogeneity and suspension of solids. Note
and record sample p,H. and temperature. Repeat measurement
on successive aliquots of sample until values differ by <0.1
pH units. Two or three volume changes are usually
sufficient.

11/28/2005 09:22 7042798418 ALCHEM INC PAGE 03
Fah CALIBRATirw ► c)(;
DATE
TIME
4.01
7.00
, c�
10.00
/pO, C)
p..ol
S L 0 P E 4(i✓A]
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/ p
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-7
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-cd
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$' a S • C)
Q ' 50 pry.
-o.S
?'30 4nr
�v!
a
o•�c
,r�
6-5
so AM
10.0i
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v 2--&- oS-
7 r,VO A^
-1-ev
T -107
00
m ) t

11/28/2005 09:22 704279841E ALCHEM INC PAGE 04
Ph CALIBRATION LOG
DATE
TIME
4.01
7.00
10.00
SLOPE&'O
,,'k7-6-jr'
Poo 6/4
r Qb
t A l
/ o FAO
U)
'7: A5 Ate'+
4p f
.o l
nv
8-05
I:'IS AIm
4 00
bl
.o7.
' qS arm
14-62,
, 00
10.01
-;L$ - fii�
a
. 0 l
-.2q p-
: Do rn
.DO
oa
.01
rriD
l �•QQ
- 5
-1:14s M
,o
.00
•W
- 05
la,1S rp,
m. o1
-dl
.0-
- OS
a S) 0 ,,•.
. 0.)-
-1. Oar
16.01
V/0 ;OM
.rya/
7.0/
/D.d l
7-00
IQ
0•, t-OS
1n
LI, oo
-1.60
v
p I. of
.15
Lys
WJ 0 IfA
yrD I
did I
I0, 00
.6c3 61

11/28/2005 09:22 7042796418 ALCHEM INC PAGE 05
ALCHEM SAND MONITORING
DATE
TIME
SAND Ph
LOAD #
COMMENTS
10
-
}
An
-z)
j
r
10
ras
.-D5'
-I
aS
�35/g
d-
_a
p. i5 14Aolly
37

11/28/2005 09:22 7042798418 ALCHEM INC PAGE 06
ALCHEM SAND M()NiTnRlNr,
DATE
TIME
SAND Ph
LOAD #
COMMENTS
-3 ?
3
�- -I
a; .30 ON/J2
o
!fit
�a
4,
a S
a/=15
m oe
- 5`
/2' D nt
tv
r, p
-'
.' ,.
�• ! S.�1
.,'
?
,Cry
9--;Z7-D
Q-Y
12
AP
apt
; do m
L-2!W,�
4- o.s
.20 o
5'
7�
12r�
�Y

11/28/2005 09:22 7042798418 ALCHEM INC PAGE 07
ALCHEM SAND MONITORING
DATE
TIME
SAND Ph
LOAD #
COMMENTS
.o- . a !�r
R.16
74
�Y
®- -a sr
-.Ze !X
. I
7
Y
6 -�5
: ©a /N
-Y2
r
� 15
yl
Y�
.. ._ P,5'
Xv.5r M
a ;b r d e-r

t
ALCHILM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail]
March 9, 2005
DENR/DWQ/Water Quality Section
Mr. Daryl Merritt,
Environmental Specialist I
Non -Discharge Compliance/Enforcement Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Mr. Merritt:
Enclosed are the monitoring and reporting requirements for our permit number
WQ0016338.
For the year of 2004, we did not accumulate enough silica residual to land apply.
Please let me know if you need anything further.
Best regards,
ALCHEM, INC
Lt c'. a OAY-e-
Wayne D. Drye,
Plant Manager
pcd
cc: eMs._Ellen-Huffman;
Environmental Specialist
Mooresville Regional Office

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail]
FEBRUARY 2004
FORM ACF:
Residuals were pumped into holding lagoon.
Alchem, Inc storage area for its fill material discharged into a drainage/wooded area and
stream. This was due somewhat to the large amounts of rain we had the first part of
2003.
Alchem has been collecting the fill material from the wooded area and the stream. A 24'
X 24" trench to divert the storm water from Red Road around the impounded area has
been completed. A 5' X 8' wide berm has been placed around the impoundment area and
all low grade areas. An enlarged settlement basin has been completed.
MARCH 2O05
Residuals were pumped into holding lagoon.
Alchem is continuing the clean-up process. Alchem has increased the berm to 9' X 8'.

ANNUAL LAND APP.LICA?'ION CERTIFICATION FORM
Permit#: WQ0016338 County: ROWAN Year:
Facility Name (as shown on permit):
Land Application Operator:
ALCHEM, INC
2004
WAYNE DRYE, PLANT MANAGER Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
❑ Yes ❑p No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit:
0
Total number of fields land application occurred during the year:
0
Total amount of dry tons applied during the year for all application sites:
0
Total number of acres land application occurred during the year:
0
Part B:
Facility was compliant during calendar year with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. ❑ Yes p No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Wayne D Drye, Plant Manager H
Permittee Name and Title (type or print) Signature of'Permittee Date
Signa re of Prepar * Date Signiture of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r)
DENR FORM ACF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory:
Facility Name:
NPDES # or
WQ#:
WWTP Name:
Residual Analysis Data
ALCHEM, INC
1) Environmental Science Corp
2)
3)
4)
5)
Sample or
Composite Date
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signatkire of Prepar
3 �
Ds
Date
DENR FORM RSSF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to beanalyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory: 1) Environmental Science Corp
Facility Name:
NPDES # or
WQ#:
WWTP Name:
Residual Analysis Data
ALCHEM,INC
2)
3)
4)
5)
• ,• • • •Date
EMEEMEEMEEME
' 1
-__-----�-
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
P�6', )� b,�
Signatule of Prepa r
3/91/os-
Date
DENR FORM RSSF-B (5/2003)

1 � �
12065 Lebanon Rd.
Mt. Juliet, TN 7122
ENVIRONMENTAL
16800-767-5859
SCIENCE CORP.
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT
OF ANALYSIS
Pam Hester
August
19,2004
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
ESC
Sample
# L164185-01
Date Received August 04, 2004
Description 14417 - Alchem, Inc.
Site
ID
Sample ID LAGOON 3
Project
#
TBL-14417
Collected By Wayne Drye
Collection Date 07/28/04 08:00
Parameter Dry
Result
Det. Limit
Units
Method Date
Dil.
pH
5.5
su
9045C
08/04/04
1
Phosphorus,Total
3.0
1.2
mg/kg
9056
08/11/04
1
Total Solids
83.7
%
254OG
08/09/04
1
Mercury
0.093
0.024
mg/kg
7471
08/06/04
1
Aluminum
17000
6.0
mg/kg
6010B
08/11/04
1
Arsenic
BDL
0.60
mg/kg
6010B
08/12/04
1
Barium
75.
0.30
mg/kg.
6010B
08/11/04
1
Cadmium
BDL
0.30
mg/kg
6010B
08/12/04
1
Calcium
9200
30.
mg/kg
6010B
08/18/04
1
Chromium
12.
0.60
mg/kg
6010B
08/11/04
1
Copper
6.9
0.60
mg/kg
6010B
08/11/04
1
Lead
23.
0.30
mg/kg
6010B
08/12/04
1
Magnesium
510
6.0
mg/kg
601013
08/11/04
1
Manganese
18.
0.60
mg/kg
6010B
08/18/04
1
Nickel
6.6
0.60
mg/kg
6010B
08/18/04
1
Selenium
BDL
0.60
mg/kg
6010B
08/11/04
1
Silver
BDL
0.30
mg/kg
6010B
08/11/04
1
Sodium
610
30.
mg/kg
6010B
08/10/04
1
Zinc
43.
1.8
mg/kg
6010B
08/11/04
1
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
MN - 047-999-395, NY - 11742
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 08/19/04 12:15 Printed: 08/19/04 14:23
Page 1 of 5

ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received August 04, 2004
Description 14417 - Alchem, Inc.
Sample ID LAGOON 3
Collected By Wayne Drye
Collection Date 07/28/04 08:00
f
12065 Lebanon Rd. r T
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
August 19,2004
ESC Sample # : L164185-02
Site ID
Project TBL-14417
Parameter Result Det. Limit Units Limit Method Date Dil
TCLP Extraction
Mercury
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
TCLP ZHE Extraction
TCLP Volatiles
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1,1-Dichloroethene
2-Butanone (MEK)
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogate Recovery
Dibromofluoromethane
Toluene-d8
4-Bromofluorobenzene
TCLP Pesticides
Chlordane
Endrin
Heptachlor
Lindane
Methoxychlor
Toxaphene
Surrogate Recovery
_
1311
08/04/04 1
BDL
0.0010
mg/l
0.20
7470A
08/09/04 1
BDL
0.050
mg/l
5.0
6010B
08/06/04 1
0.052
0.050
mg/l
100
6010B
08/06/04 1
BDL
0.050
mg/1
1.0
6010B
08/06/04 1
BDL
0.050
mg/l
5.0
6010B
08/06/04 1
BDL
0.050
mg/l
5.0
6010B
08/06/04 1
BDL
0.050
mg/l
1.0
6010B
08/06/04 1
BDL
0.050
mg/l
5.0
6010B
08/06/04 1
_
1311
08/06/04 1
BDL
0.050
mg/l
0.50
826013
08/10/04 1
BDL
0.050
mg/l
0.50
8260B
08/10/04 1
BDL
0.050
mg/l
100
8260B
08/10/04 1
BDL
0.25
mg/l
6.0
8260B
08/10/04 1
BDL
0.050
mg/l
0.50
8260B
08/10/04 1
BDL
0.050
mg/l
0.70
8260B
08/10/04 1
BDL
0.50
mg/1
200
826013
08/10/04 1
BDL
0.050
mg/l
0.70
8260B
08/10/04 1
BDL
0.050
mg/l
0.50
8260B
08/10/04 1
BDL
0.050
mg/l
0.20
8260E
08/10/04 1
100
% Rec.
8260B
08/10/04 1
95.
%- Rec.
8260B
08/10/04 1
120
Rec.
8260B
08/10/04 1
BDL
0.0050
mg/l
0.030
8081A
08/09/04 1
BDL
0.0050
mg/l
0.020
8081A
08/09/04 1
BDL
0.0050
mg/l
0.00'80
8081A
08/09/04 1
BDL
0.0050
mg/l
0.40
8081A
08/09/04 1
BDL
0.0050
mg/l
10.
8081A
08/09/04 1
BDL
0.010
mg/1
0.50
8081A
08/09/04 1
Laboratory Certification Numbers:
AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
Page 2 of 5

ENVIRONMENTAL
SCIENCE CORP.
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received August 04, 2004
Description 14417 - Alchem, Inc.
Sample ID LAGOON 3
Collected By Wayne Drye
Collection Date 07/28/04 08:00
Parameter
Decachlorobiphenyl
Tetrachloro-m-xylene
TCLP Herbicides
2,4,5-TP (Silvex)
2,4-D
Surrogate Recovery
2,4-Dichlorophenyl Acetic Acid
TCLP Semi-Volatiles
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
Nitrobenzene
Pyridine
m&p-Cresol
o-Cresol
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogate Recovery
Nitrobenzene-d5
2-Fluorobiphenyl
p-Terphenyl-dl4
Phenol-d5
2-Fluorophenol
2,4,6-Tribromophenol
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
August 19,2004
ESC Sample # : L164185-02
Site ID
Project TBL-14417
Result
Det. Limit
Units
Limit
Method
Date
Dil
72.
% Rec.
8081A
08/09/04
1
73.
% Rec.
8081A
08/09/04
1
BDL
0.0020
mg/l
1.0
8151A
08/09/04
1
BDL
0.0020
mg/l
10.
8151A
08/09/04
1
83.
% Rec.
8151A
08/09/04
1
BDL
0.10
mg/l
7.5
8270C
08/06/04
1
BDL
0.10
mg/l
0.13
8270C
08/06/04
1
BDL
0.10
mg/l
0.13
8270C
08/06/04
1
BDL
0.10
mg/l
0.50
8270C
08/06/04
1
BDL
0.10
mg/l
3.0
8270C
08/06/04
1
BDL
0.10
mg/l
2.0
8270C
08/06/04
1
BDL
0.10
mg/l
5.0
8270C
08/06/04
1
BDL
0.10
mg/l
400
8270C
08/06/04
1
BDL
0.10
mg/l
200
8270C
08/06/04
1
BDL
0.10
mg/l
100
8270C
08/06/04
1
BDL
0.10
mg/l
400
8270C
08/06/04
1
BDL
0.10
mg/l
2.0
8270C
08/06/04
1
52.
% Rec.
8270C
08/06/04
1
71.
% Rec.
8270C
08/06/04
1
89.
% Rec.
8270C
08/06/04
1
58.
% Rec.
8270C
08/06/04
1
61.
% Rec.
8270C
08/06/04
1
74.
% Rec.
r
8270C
08/06/04
1
Chef B ucher, ESC Representative
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 08/19/04 12:15 Printed: 08/19/04 14:23
Page 3 of 5

Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte
Qualifier
L164185-01 Sodium B
L164185-02 Trichloroethene J4
Pentachlorophenol J4
2,4,6-Trichlorophenol J3J6
Methoxychlor J5
Page 4 of 5

y a ,
j Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
B (EPA) - The indicated compound was found in the associated method blank as
well as the laboratory sample..
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
J3 The associated batch QC was outside the established quality control range
for precision.
J4 The associated batch QC was outside the established quality control range
for accuracy.
J5 The sample matrix interfered with the ability to make any accurate
determination; spike value is high
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of.
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ)
(SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 79-126
83-119
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 81-114
82-116
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromofluorobenzene 65-129
72-126
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 5 of 5

Y
{
12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL
16800-767-5859
SCIENCE CORP.
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT OF ANALYSIS
Pam Hester
September 15,2004
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
ESC Sample # L169377-01
Date Received August 24, 2004
Description 14412 - Alchem, Inc.
Site ID
Sample ID LAGOON 3
Project # TBL-14417
Collected By Wayne Drye
Collection Date 07/28/04 08:00
Parameter Dry
Result
Det. Limit
Units Method Date
Dil.
Nitrogen
100
0.10
mg/kg SSSA 09/15/04
1
Ammonia Nitrogen
BDL
6.7
mg/kg 350.1 09/13/04
1
Nitrate -Nitrite
1.1
0.10
mg/kg 9056 09/15/04
1
Organic Nitrogen
100
10.
mg/kg Calc. 09/15/04
1
Kjeldahl Nitrogen, TKN
100
10.
mg/kg 351.2 09/14/04
1
Total Solids
74.3
%. 2540G 09/14/04
1
Potassium
570
25.
mg/kg 6010B 08/10/04
1
C/6
Cheli Boucher, ESC Representative
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
MN - 047-999-395, NY - 11742
Note:
This report shall not be reproduced, except in full, without -'the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 09/15/04 15:51 Printed: 09/15/04 15:51
Page 1 of 1

ENVIRONMENTAL
SCIENCE CORP.
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
Date Received February 15, 2005
Description NCDENH Lagoons
Sample ID A-1
Collected By Wayne Drye
Collection Date 02/14/05 10:00
Parameter D
Nitrate
Nitrite
Ammonia Nitrogen
pH
Phosphorus,Total
Kjeldahl Nitrogen, TKN
Total Solids
Mercury
Aluminum
Arsenic
Barium
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Manganese
Molybdenum
Nickel
Selenium
Silver
Sodium
Zinc
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122'
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
March 05,2005
ESC Sample # : L188117-01
Site ID
Project #
Result
Det. Limit
Units
Method
Date
Dil.
BDL
1.0
mg/kg
9056
02/16/05
1
BDL
1.0
mg/kg
9056
02/16/05
1
BDL
5.2
mg/kg
350.1
02/22/05
1
4.0
su
9045C
02/17/05
1
12.
1.0
mg/kg
9056
02/16/05
1
BDL
52.
mg/kg
351.2
02/17/05
1
95.8
%
254OG
02/16/05
1
0.038
0.021
mg/kg
7471
02/18/05
1
14000
5.2
mg/kg
6010B
02/16/05
1
BDL
1.0
mg/kg
6010B
02/16/05
1
45.
0.26
mg/kg
6010E
02/16/05
1
BDL
0.26
mg/kg
6010B
02/16/05
1
540
26.
mg/kg
6010B
02/16/05
1
14.
0.52
mg/kg
6010B
02/16/05
1
2.7
1.0
mg/kg
6010B
02/16/05
1
19.
0.26
mg/kg
6010B
02/16/05
1
120
5.2
mg/kg
6010B
02/16/05
1
8.4
0.52
mg/kg
6010B
02/16/05
1
0.64
0.10
mg/kg
6010B
02/16/05
1
12.
1.0
mg/kg
6010E
02/16/05
1
1.8
1.0
mg/kg
6010E
02/16/05
1
BDL
0.52
mg/kg
6010B
02/16/05
1
280
26.
mg/kg
6010E
03/04/05
1
BDL
1.6
mg/kg
6010B
02/16/05
1
&64W A44t
mmy H t, ESC Representative
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Laboratory Certification Numbers:
AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233
AZ -0612, MN - 047-999-395, NY - 11742, NJ - 81002, WI - 998093910
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 03/05/05 09:39 Printed: 03/05/05 09:39
Page 1 of 8

Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte Qualifier
L188117-01 Kjeldahl Nitrogen, TKN J3
Phosphorus,Total B,J3
Page 2 of 8

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J3 The associated batch QC was outside the established quality control range
for precision.
B (EPA) - The indicated compound was found in the associated method blank as
well as the laboratory sample.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ) (SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 93-118 Dibromfluoromethane 79-126 83-119
Phenol-d5 12-134 2-Fluorobiphenyl 95-128 Toluene-d8 81-114 82-116
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromofluorobenzene 65-129 72-126
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 3 of 8

Summary of Remarks For Samples Printed
03/05/05 at 09:39:48
TSR Signing Reports: 350
R4 - Required TAT
Sample: L188117-01 Account: ALCHEMRNC Received: 02/15/05 09:00 Due Date: 02/22/05 00:00 RPT Date: 03/05/05 09:39
Removed -02 thru -05 jg-2/16; Subbed NAICP to ASI, PO S6589 - metals WG191663-cb 2/28

12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL 1-800_767-5859
CIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 05, 2005
L188117
Laboratory, -,Blank
Analyte
Result
Units
Date Analyzed
Batch
Aluminum
< 5
'mg/kg
02/16/05
15:16
WG190322
Arsenic
< 1
mg/kg
02/16/05
15:16
WG190322
Barium
< .25
mg/kg
02/16/05
15:16
WG190322
Cadmium
1< .25
mg/kg
02/16/05
15:16
WG190322
Calcium
< 25
mg/kg
02/16/05
15:16
WG190322
Chromium
< .5
mg/kg
02/16/05
15:16
WG190322
Copper
< 1
mg/kg
02/16/05
15:16
WG190322
Lead
< .25
mg/kg
02/16/05
15:16
WG190322
Magnesium
< 5
mg/kg
02/16/05
15:16
WG190322
Manganese
< .5
mg/kg.
02/16/05
15:16.
WG190322
Molybdenum
< .1
mg/kg
02/16/05
15:16
WG190322
Nickel
< 1
mg/kg
02/16/05
15:16
WG190322
Selenium
< 1
mg/kg
02/16/05
15:16
WG190322
Silver
< .5
mg/kg
02/16/05
15:16
WG190322
zinc
< 1.5
mg/kg
02/16/05
15:16
WG190322
Nitrate
< 1
mg/kg
02/16/05
0'0:00
WG190348
Nitrite
< 1
mg/kg
02/16/05
00:00
WG190348
Phosphorus,Total
2.60
mg/kg
02/16,/05
00;00 _,
WG190348
Kjeldahl Nitrogen, TKN
< 50
mg/kg
02/17/05
12:00
WG190430
pH
6.40
su
02%17/05
15:45
WG190688
Mercury
< .02
mg/kg
02/18/05
00:44
WG190816
Total Solids
0.00
%
02/18/05
16:40
WG190899
Ammonia Nitrogen
< 5
mg/kg
02/22/05'11:45
WG191072
Sodium
< 25
mg/kg
03/04/05
11:55
WG192680
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
Nitrate
mg/kg
0.920
0.00
200.
20
L188117-01
WG190348
Nitrate
mg/kg
0.00
0.00
0.00
20
L188125-02
WG190348
Nitrite
mg/kg
0.00
0.00
0.00
20
L188117-01
WG190348
Phosphorus,Total
mg/kg
2.57
.12.0
129.
20
L188117-01
WG190348
Phosphorus,Total
mg/kg 218.
220.
0.867
20
L188125-02'
WG190348
Kjeldahl Nitrogen, TKN
mg/kg
0.00
0.00
0.00
20
L188117-01
WG190430
pH
su
7.00
7.00
0.00
20
L188083-01
WG190688
pH
su
7.70
7.70
0.00
20
L188125-02
WG190688
Total Solids
%
91.6
90.5
1.22
20
L187166-09
WG190899
Ammonia Nitrogen
mg/kg 489.
480.
1.87
20
L188333-16
WG191072
Laboratory.Control
Sample
Analyte
Units
Known
Val
Result
% Rec
Limit Batch
Aluminum
mg/kg
6700
7810
117.
57.9-142
WG190322
Arsenic
mg/kg
146
134.
92.0
78.8-121
WG190322
Barium
mg/kg
140
138.
98.2
77.9-122
WG190322
Cadmium
mg/kg
244
226.
92.8
'80.3-120
WG190322
Calcium
mg/kg
3320
'3450
104.
77.4-122
WG190322
Chromium
mg/kg
99.2
91.4
92.2
78.5-121
WG190322
Copper
mg/kg
70
64.9
92.7
77.9-122
WG190322
Page 4 of 8

ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality
Assurance
Report
Level
II
Rockwell, NC 28138
March
05, 2005
L188117
Lead
mg/kg
72.8
63.6
87.3
79.9-119 WG190322
Laboratory
Control Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
Magnesium
mg/kg
2040
2110
104.
76.5-124 WG190322
Manganese
mg/kg
249
244.
98.1
76.3-123 WG190322
Molybdenum
mg/kg
31.2
31.1
99.5
78.2-121 WG190322
Nickel
mg/kg
82.4
64.1
77.8
76.9-122 WG190322
Selenium
mg/kg
86.5
84.2
97.4
69.1-130 WG190322
Silver
mg/kg
126
127.
101.
60.3-139 WG190322
Zinc
mg/kg.
138
124.
90.2
77.5-122 WG190322
Nitrate
mg/kg
106
120.
113.
77.4-122 WG190348
Phosphorus,Total
mg/kg
39
42.0,
108.
67.9-132 WG190348
Kjeldahl Nitrogen, TKN
mg/kg
820
880.
107.
58.0-141 WG190430
pH
su
8.37
9.10
109.
85-115 WG190688
Mercury
mg/kg
8.31
8.90
107.
61.9-138 WG190816
Total Solids
%
50
50.0
100.
85-115 WG190899
Ammonia Nitrogen
mg/kg
305
270.
88.5
50-153.1 WG191072
Sodium
mq/kq
392
366.
93.5
55.5-144 WG192680
Laboratory Control
Sample Duplicate
Analyte
Units
LCSD Res
Ref Res
RPD
Limit %Rec
Batch
Aluminum
mg/kg
7780
7810
0.354
20 116.
WG190322
Arsenic
mg/kg
134.
134.
0.209
20 91.8
WG190322
Barium
mg/kg
137.
138.
0.598
20 97.7
WG190322
Cadmium
mg/kg
222.
226.
1.94
20 91.0
WG190322
Calcium
mg/kg
3310
3450
4.18
20 99.6
WG190322
Chromium
mg/kg
92.3
91.4
0.936
20 93.0
WG190322
Copper
mg/kg
64.8
64.9
0.247
20 92.5
WG190322
Lead
mg/kg
63.6
63.6
0.0315
20 87.3
WG190322
Magnesium
mg/kg
2150
2110
1.85
20 106.
WG190322
Manganese
mg/kg
244.
244.
0.299
20 97.8
WG190322
Molybdenum
mg/kg
31.0
31.1
0.0967
20 99.4
WG190322
Nickel
mg/kg
64.1
64.1
0.0312
20 77.8
WG190322
Selenium
mg/kg
82.7
84.2
1.88
20 95.6
WG190322
Silver
mg/kg
125.
127.
1.45
20 99.4
WG190322
Zinc
mg/kg
125.
124.
0.0321
20 90.2
WG190322
Nitrate
mg/kg
120.
120.
0.00
20 113.
WG190348
Phosphorus,Total
mg/kg
41.0
42.0
2.41
20 105.
WG190348
Kjeldahl Nitrogen, TKN
mg/kg
660.
880.
28.6
20 80.5
WG190430
pH
su
9.10
9.10
0.00
20 109.
WG190688
Mercury
mg/kg
10.4
8.90
15.6
20 125.
WG190816
Ammonia Nitrogen
mg/kg
270.
270.
0.00
20 88.5
WG191072
sodium
mg/kg
366.
366.
0.0191
20 93.5
WG192680
Matrix Spike
Analvte
Units
MS Res
Ref Res
TV %_Rec
Limit
Ref Samp Batch
Aluminum mg/kg 9510 8650 50 1720 75-125 L188083-03 WG190322
Page 5 of 8

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Arsenic
Quality Assurance Report
Level II
L188117
48.2 0.00 50
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tar. I.D. 62-0814289
Est. 1970
March 05, 2005
75-125 L188083-03 WG190322
Matrix.Spike
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp
Batch
Barium
mg/kg
206:.
20.0.:.
50.
. 12.1
757125.-L188083-03.WG190322
Cadmium
mg/kg
51.3
1.20
50
100.
75-125
L188083-03
WG190322
Calcium
mg/kg
3700
2680
500
203.
75-125
L188083-03
WG190322
Chromium
mg/kg
61`.2
14-.0
50
94.5
75-125
`L188083-03
WG190322
Copper
mg/kg
92.6
43.8
50
97.6
75-125
L188083-03
WG190322
Lead
mg/kg
79.8
26.0
50
108.
75-125
L188083-03
WG190322
Magnesium
mg/kg
1250
787.
500
92.2
75-125
L188083-03
WG190322
Manganese
mg/kg
103.
58.4
50
89.8
75-125
L188083-03
WG190322
Molybdenum
mg/kg
48.2
1.20
50
94.1
75-125
L188083-03
WG190322
Nickel
mg/kg.
34._2..;
0.00
50
68.4.75-125
L188083-03
WG190322
Selenium
mg/kg
42.0
4.30
50
75.4
75-125
L188083-03
WG190322
Silver
mg/kg
45.5
0.00
50
90.9
75-125
L188083-03
WG190322
Zinc
mg/kg
226.
139.
50
175::.75-125
L188083703
WG190322
Kjeldahl Nitrogen, TKN
mg/kg
390.
170.
200
110.
80-120
L187191-01
WG190430
Mercury
mg/kg
0.353
0.0500
.25
121.
70-130
L188083-03
WG190816
Ammonia Nitrogen
mg/kg
470.
0.00
500
94.0
80-120
L188745-01
WG191072
Sodium
mg/kg
854.
430.
500
84.7
75-125
L187464-04
WG192680
Matrix Spike
Duplicate `
Analyte
Units
MSD Res
Ref Res
RPD
Limit %Rec
Ref Samp
Batch
Aluminum
mg/kg
10200
9510
7.40
20
3190
L188083-03
WG190322
Arsenic
mg/kg
47.7
48.2
1.12
20
95.4
L188083-03
WG190322
Barium
mg/kg
218.
206.
5.48
20
35.3
L188083-03
WG190322
Cadmium
mg/kg
49.7.
51.3
3.27
20
96:9
L188083-0,3
WG190322
Calcium
mg/kg
3550
3700
4.01
20
174.
L188083-03
WG190322
Chromium
mg/kg
61.6
61.2
0.604
20
95.2
L188083-03
WG190322
Copper
mg/kg
91 8;
'92.6
0.805:'20
96.2
L188083-03.WG190322
Lead
mg/kg
78.0
79.8
2.31
20
104.
1,188083-03
WG190322
Magnesium
mg/kg
1300
1250
3.69
20
102.
L188083-03
WG190322
Manganese
mg/kg
107i.
103.
3.16
20
96.4,
L188083-03
WG190322
Molybdenum
mg/kg
46.5
48.2
3.77
20
90.5
L188083-03
WG190322
Nickel
mg/kg
35.7
34.2
4.22
20
71.4
L188083-03
WG190322
Selenium
mg/kg
39.3
42.0
6.57
20
70.1
L188083-03
WG190322
Silver
mg/kg
44.0
45.5
3.32
20
88.0
L188083-03
WG190322
Zinc
mg/kg
212.
226.
6.37
20
147.
L188083-03
WG190322
Kjeldahl Nitrogen, TKN
mg/kg
380.
390.
2.60
20
105.
L187191-01
WG190430
Mercury
mg/kg
0.305
0.353
14.6,.
20
102.
L188083-03
WG190816
Ammonia Nitrogen
mg/kg
460.
470.
2.15
20
92.0
L188745-01
WG191072
Sodium
mg/kg
829.
854,
2.99
20
79.7
L187464-04
WG192680
Batch number /Run number / Sample number cross reference
WG190322: R223683: L188117-01
WG190348: R223698: L188117-01
WG190430: R223782: L188117-01
WG190688: R223837: L188117-01
WG190816: R223876: L188117-01
WG190899: R223948: L188117-01
WG191072: R224204: L188117-01
Page 6 of 8

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
WG192680: R225438: L188117-01
Quality Assurance Report
Level II
L188117
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Far. [phone]
Tart I.D. 62-0814289
Est. 1970
March 05, 2005
* denotes out of limit range result. See Attachment B of standard report for list of qualifiers.
* * Calculations are performed prior to rounding of reported values .
Page 7 of 8

ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Alchem, Inc. Est. 1970
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 05, 2005
L166117
ESC Level 2 Data Package
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a "J6". The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 8 of 8

i
ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0016338 County: ROWAN Year:
Facility Name (as shown on permit): ALCHEM, INC
Land Application Operator: WAYNE DRYE, PLANT MANAGER Phorh'Z
2003
�n�� ors
Land application of residual solids as allowed by the permit occurred during the p4strcalender year? OFFICE
❑ Yes ❑a No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
MAR 0 2 2004
Total number of application fields in permit:
Total number of fields land application occurred during the year:
Total amount of dry tons applied during the year for all application sites:
1�1,9;1
Total number of acres land application occurred during the year:
a'
Part B:
Facility was compliant during calendar year with all conditions of the land application permit
(including but not limited to items 1=12 below) issued by the Division of Water Quality. ❑ Yes p No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to 6v
ntAkat
least 6.0 or the limit specified in the permit. N _
3. Annual soils analysis were performed on each site receiving residuals during the past c� dar e d three
(3) copies of laboratory results are attached. ' `�
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory res-4Jkt Es'gio,tJWW,ION
5. All other monitoring was performed in accordance with the permit and reported duri-W10Fj%0r°TsY"MR4u&d
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Wayne D Drye, Plant Manager
Permittee Name and Title (type or print)
Signat e of Prepar
(if different from Permittee)
Preparer is defined in 40 CFR Part 503.9 (r)
11,33
Date
lc% t, � b 3) o
Signature of Permittee Date
Signiture of Land Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/2003)

ALCHEM, INC
8135 RED ROAD.
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail]
FORM ACF:
Residuals were pumped into holding lagoon.
Alchem, Inc's storage area for its fill material discharged into a drainage/wooded area
and stream. This was due somewhat to the large amounts of rain we had the first part of
2003.
Alchem has been collecting the fill material from the wooded area and the stream. A 24"
X 24" trench to divert the storm water from Red Road around the impounded area has
been completed. A 5' X 8' wide berm has been placed around the impoundment area and
all low grade areas. An enlarged settlement basin has been completed.

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338
Facility Name: ALCHEM, INC
NPDES # or
WQ#:
WWTP Name:
Residual Analysis Data
Laboratory: 1) TBL LABORATORY
2)
3)
4)
5)
Sample or
Composite Date
------------
----------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
pb,� � I - --
Signa re of Prep er
I la3a
Date
DENR FORM RSSF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338
Laboratory: 1) TBL LABORATORY
Facility Name: ALCHEM, INC
2)
NPDES # or
3)
WQ#:
4)
WWTP Name:
5).
Residual Analysis Data
Sample or
CompositeDate
--------
---
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
ffi&� i)a, -
Signatilae of Prepare
lb.3 a
Date
DENR FORM RSSF-B (5/2003)

el,
elementOne
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Sample #
Sample Matrix
Date Sampled 7/29/03
Delivered by Picked Up
Page 1 of 1
Parameter
Sodium
Magnesium
Aluminum
Phosphorus
Calcium
Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Silver
Cadmium
Barium
Lead
Mercury
pH
Element One Inc.
5022-C Wrightsville Ave.
Wilmington, NC 28403
Phone: [phone]
Fax: [phone]
el [e-mail]
FINAL REPORT OF ANALYSES
August 13, 2003
Client Project Name ALCHEM, INC
Client Project Number TBL-13205
PO Number
E1 Project Number e2075
Sample ID
Lagoon.#3
Sample Type
Date Received 7/31/03
Time Sampled
0800 Time Received 1630
Sampler
Wayne Dryer Received by PDS
E1 Sample #
2075-1
Result
Unit
153
mg/L
105
mg/L
16800
mg/L
76.1
mg/L
827
mg/L
12.6
mg/L
4.14
mg/L
1.23
mg/L
2.93
mg/L
1.65
mg/L
< 0.5..
mg/L
< 6.5
mg/L
0.210
mg/L
< 0.2
mg/L
66.3
mg/L
25.9
mg/L
0.0865
mg/L
3.60
SU
7e"n'Smith., Laboratory Director
Dilution
DL
Method
Date
5
0.01
EPA 200.8
8/1/03
5
0.01
EPA 200.8
8/1/03
5000
0.005
EPA 200.8
8/1/03
5
0.01
EPA 200.8
8/1/03
5
0.02
EPA 200.8
8/1/03
5
0.005
EPA 200.8
8/1/03
5
0.005
EPA 200.8
8/1/03
1
0.005
EPA 200.8
8%1/03
5
0.003
EPA 200.8
8/1/03
1
0.005
EPA 200.8
8/1/03
1
0.005
EPA 200.8
8/1/03
1 .
0.605
EPA 200.8
8/1/03
1
0.002
EPA 200.8
8/1/03
1
0.002
EPA 200.8
8/1/03
5
'0.005
EPA 200.8
8/1/03
5
0.003
EPA 200.8
8/1/03
1
0.0002
EPA 245.1
8/6/03
1
EPA 9045C
8/6/03
NC Certifications: DW 37788 and DWQ DENR 604

elementOne
FINAL REPORT OF ANALYSES
Element One Inc.
5022-C Wrightsville Ave.
Wilmington, NC 28403
Phone: [phone]
Fax: [phone]
el [e-mail]
Pam Hester
December 29, 2003
TBL Laboratory
Client Project Name Alchem, Inc.
P.O. Box 589
Client Project Number TBL-13616
Lumberton, NC 28359
PO Number
E1_ Project Number'e2615 -
Sample #
Sample ID
Lagoon #3.
Sample Matrix
Sample Type
Date Received 12/16/03
Date Sampled 12/11/03
Time Sampled
0800 Time Received 1515
Delivered by Picked Up
Sampler
Wayne Drye Received by PDS
Page 1 of 1
E1 Sample #
2615-1
Parameter
Result
Unit
Dilution
Sodium
218
mg/Kg
1
Magnesium
139
mg/Kg
1
Aluminum
21402
mg/Kg
1000
Phosphorus
85.4
mg/Kg
1
Calcium
885
mg/Kg
5
Chromium
14.3
mg/Kg
1
Manganese
4.15
mg/Kg
1
Nickel
1.32
mg/Kg
1
Copper
3.13
mg/Kg ,
1
Zinc
1.57
mg/Kg
1
Arsenic
0.889
mg/Kg
1
Selenium
0.889
mg/Kg
1
Silver
0.356
mg/Kg
1
Cadmium
0.356
mg/Kg
1
Barium
82.4
mg/Kg
2
Lead
29.7
mg/Kg
2
Mercury
0.0849
mg/Kg
1
pH
3.57
SU
1
7l
0.02
0.02
0.005
0.02
0.05
0.005
0.005
0.005
0.003
0.005
0.005
0.005
0.002
0.002
0.005
0.003
0.0002
Method
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 200.8
EPA 245.1
EPA 9045C
Date
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/17/03
12/23/03
12/17/03
NC Certifications: DW 37788 and DWQ DENR 604

w R
}
ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
104-279-7908 fax [phone]
[e-mail]
March 19,2007
DENR/DWQ/Water Quality Section
Mr. Daryl Merritt,
Environmental Specialist I
Non -Discharge Compliance/Enforcement Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Mr. Merritt:
MAR 2 3 2007 1
Enclosed is the Monitoring and Reporting requirements for our permit number
WQ0016338.
For the year of 2006, we did not land apply any silica residuals. I have included the
Annual Residual Sampling Summary forms ACF, RSSF and RSS-B. I have also
included the lagoon sand sample analysis.
Please let me know if you have any questions.
Best regards,
ALCHEM, INC
-ju'x-t Jt`dicY- l prd
Trent Tidwell,
Plant Manager
pcd
cc: Ms. Ellen Huffman,
Environmental Specialist
Mooresville Regional Office

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0016338 County:
Facility Name (as shown on permit):
Land Application Operator:
ROWAN
Year: 2006
ALCHEM, INC
Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calendar year?
❑ Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Trent Tidwell, Plant Manager
Total number of application fields in permit: 0
Total number of fields land application occurred during the year: 0
Total amount of dry tons applied during the year for all application sites: 0
Total number of acres land application occurred during the year: 0
Part B:
Facility was compliant during calendar year 2006 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. ❑ Yes ❑ Nc
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 5
u a �J r s).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR
rt 50'
r
complied with (applicable to 40 CFR Part 503 regulated facilities).
�
8. All operations and maintenance requirements in the permit were complied with or, in th
oc f
0f levi�
prior authorization was received from the Division of Water Quality.
>
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or e
o w
?1 atior►s of
violations are attached to include appropriate actions and remediations.
o
o
10. Vegetative cover as specified in the permit was maintained on this site and the crops gr
"i
erei�mo
in accordance with the crop management plan.
o
11. No runoff of residuals from the application sites onto adjacent property or nearby surfac
waters 1
12. All buffer requirements as specified on the permit were maintained during each application
o
residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
This is in exception to the NOV's A&chem has rece' ed th t a�rbei�{rg cot rested.
Trent Tidwell, Plant Manager � , ��, 3 .)-
Permittee Name and Title (type or print) Signature of Permittee Date
I • )-2 6
Signa re of Pr arer* Date
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r)
Signature of Land Applier
(if different from Permittee and Preparer)
Date
DENR FORM ACF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory:
Facility Name: ALCHEM, INC
NPDES # or
WQ#:
16338
1) Environmental Science Corp
2)
3)
4)
WWTP Name: 5)
Residual Analvsis Data
Sample or
CompositeDate
Total Nitroge
Organic NitrogenC
----------
•
Potassium
• :1
11
----------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
SignatuA of PrepareP Date
DENR FORM RSSF-B (5/2003)

ENVIRONMENTAL
SCIENCE CORP.
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
Report Summary
Friday March 02, 2007
Report Number: L281445
Samples Received: 02/22/07
Client Project: WQ0016388
Description: NCDENH Lagoons
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have an
questions regarding this data package, please do not hesitate to caly
l.
Reviewed By:
-Jimmy f
unt, f6u 11,epresentative
Laboratory Certification Numbers
A2LA - 1461-01, AIHA - 09227, AL - 40660, CA - I-2327, CT - PH-0197, FL - E87487
GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140
NJ - TNO02, SC - 84004, TN - 2006, VA - 00109, WV - 233
AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, WA - C1915
This report may not be reproduced, except in full, without written approval from Environmental Science Corp.

12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL
1-800-767-5859
SCIENCE CORP.
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
REPORT OF ANALYSIS
Ms. Phyllis Drye
March 02,2007
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
ESC Sample # L281445-01
Date Received 4T'ebruary 22, 2007
Description CDENH a oohs
Site ID
Sample ID LAGOON SAND SAMP
Project # WQ0016388
Collected By Trent Tidwell
Collection Date 02/20/07 08:00
Parameter
Dry Result
Det. Limit
Units
Method
Date
Dil.
Nitrate
BDL
1.2
mg/kg
9056
02/23/07
1
Nitrite
1.5
1.2
mg/kg
9056
02/23/07
1
Phosphorus,Total
1.7
1.2
mg/kg
9056
02/28/07
1
Total Nitrogen
1.5
1.2
mg/kg
Calc.
02/28/07
1
Ammonia Nitrogen
BDL
5.8
mg/kg
350.1
03/01/07
1
�
7�54
7.4;@1�9.O:C•1�:�1`��9:Oi9T5:C
0.?,/r29,✓1017�iFl
Organic Nitrogen
BDL
12.
mg/kg
CALC.
02/28/07
1
Kjeldahl Nitrogen, TKN
BDL
23.
mg/kg
351.2
02/28/07
1
Total Solids
86.2
8
2540G
02/28/07
1
Mercury
BDL
0.023
mg/kg
7471
02/26/07
_ 1
Aluminum
40000
5.8
mg/kg
6010B
02/24/07
1
Arsenic
BDL
1.2
mg/kg
6010B
02/24/07
1
Barium
90.
0.29
mg/kg
6010B
02/24/07
1
Cadmium
BDL
1.4
mg/kg
6010B
02/26/07
5
Calcium
9900
29.
mg/kg
6010B
02/24/07
1
Chromium
25.
0.58
mg/kg
6010B
02/24/07
1
Copper
5.8
1.2
mg/kg
6010B
02/24/07
1
Lead
43.
0.29
mg/kg
6010B
02/24/07
1
Magnesium
2000
5.8
mg/kg
6010B
02/24/07
1
Manganese
3.5
0.58
mg/kg
6010B
02/24/07
1
Molybdenum
0.87
0.12
mg/kg
6010B
02/24/07
1
Nickel
3.4
1.2
mg/kg
6010B
02/24/07
1
Potassium
1300
29.
mg/kg
6010B
02/24/07
1
Selenium
BDL
1.2
mg/kg
6010B
02/24/07
1
Silver
BDL
0.58
mg/kg
6010B
02/24/07
1
Sodium
620
29.
mg/kg
6010B
02/24/07
1
Zinc
5.0
1.7
mg/kg
6010B
02/24/07
1
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 03/01/07 17:17 Revised: 03/02/07 09:56
Page 1 of 8

Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte Qualifier
L281445-01 Cadmium 0
Ammonia Nitrogen J6
Page 2 of 8

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
(ESC) Sample diluted due to matrix interferences that impaired the ability
to make an accurate analytical determination. The detection limit is
elevated in order to reflect the necessary dilution.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ) (SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 68-128 64-125
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 76-115 69-118
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromofluorobenzene 79-127 61-134
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 3 of 8

12065 Lebanon Rd.
0
Mt. Juliet, TN 37122
ENVIRONMENTAL
16800-767-5859
SCIENCE CORP.
Fax [phone]
Tar. I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality
Assurance Report
Level
II
Rockwell, NC 28138
March 02, 2007
L281445
Ldbora-terry MtiLajlk
Analyte
Result
Units
Date Analyzed
Batch
Nitrate
< 1
mg/kg
02/23/07
13:11
WG288401
Nitrite
< 1
mg/kg
02/23/07
13:11
WG288401
Aluminum
< 5
mg/kg
02/24/07
10:43
WG288474
Arsenic
< 1
mg/kg
02/24/07
10:43
WG288474
Barium
< .25
mg/kg
02/24/07
10:43
WG288474
Cadmium
< .25
mg/kg
02/24/07
10:43
WG288474
Calcium
< 25
mg/kg
02/24/07
10:43
WG288474
Chromium
< .5
mg/kg
02/24/07
10:43
WG288474
Copper
< 1.
mg/kg
02/24/07
10:43
WG288474
Lead
< .25
mg/kg
02/24/07
10:43
WG288474
Magnesium
< 5
mg/kg
02/24/07
10:43
WG288474
Manganese
< .5
mg/kg
02/24/07
10:43
WG288474
Molybdenum
< .1
mg/kg
02/24/07
10:43
WG288474
Nickel
< 1
mg/kg
02/24/07
10:43
WG288474
Potassium
< 25
mg/kg
02/24/07
10:43
WG288474
Selenium
< 1
mg/kg
02/24/07
10:43
WG288474
Silver
< .5
mg/kg
02/24/07
10:43
WG288474
Sodium
< 25
mg/kg
02/24/07
10:43
WG288474
Zinc
< 1.5
mg/kg
02/24/07
10:43
WG288474
Mercury
< .02
mg/kg
02/26/07
10:09
WG288512
pH
7.00
su
02/24/07
18:05
WG288594
Kjeldahl Nitrogen, TKN
< 20
mg/kg
02/28/07
10:45
WG288597
Total Solids
0.00
%
02/28/07
09.:00
WG288768
Phosphorus,Total
< 1
mg/kg
02/28/07
11:44
WG289096
Ammonia Nitrogen
< 5
mg/kg
03/01/07
04:35
WG289232
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit Ref Samp
Batch
Nitrate
mg/kg
20.9
19.9
4.90
20
L281206-03
WG288401
Nitrite
mg/kg
56.6
57.6
1.75
20
L281206-03
WG288401
Aluminum
mg/kg
4630
4460
3.74
20
L281503-01
WG288474
Arsenic
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Barium
mg/kg
98.7
89.0
10.3
20
L281503-01
WG288474
cadmium
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Calcium
mg/kg
70700
68800
2.72
20
L281503-01
WG288474
Chromium
mg/kg
5.33
5.20
2.47
20
L281503-01
WG288474
Copper
mg/kg
5.38
4.67
14.1
20
L281503-01
WG288474
Lead
mg/kg
5.57
4.00
32.8
20
L281503-01
WG288474
Manganese
mg/kg
106.
77.3
31.3
20
L281503-01
WG288474
Molybdenum
mg/kg
0.357
0.273
26.7
20
L281503-01
WG288474
Nickel
mg/kg
4.67
3.92
17.5
20
L281503-01
WG268474
Potassium
mg/kg
1400
1350
3.64
20
L281503-01
WG28B474
Selenium
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Silver
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Sodium
mg/kg
450.
465.
3.28
20
L281503-01
WG288474
Zinc
mg/kg
22.5
18.6
19.0
20
L281503-01
WG288474
Mercury
mg/kg
0.0456
0.0630
32.0
20
L281374-04
WG288512
pH
su
9.10
9.00
1.10
20
L281647-01
WG288594
pH
su
9.00
8.60
4.55
20
L281763-01
WG288594
Page 4 of 8

12065 Lebanon Rd.
0 Mt.. Juliet, TN 37122
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 02, 2007
L281445
�R'�D- up!lasca��e�
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp Batch
Kjeldahl Nitrogen, TKN
mg/kg
11000
10000 9.53
20
L281659-01 WG288597
Total Solids
%
86.4
86.2 0.288
20
L281445-01 WG288768
Phosphorus,Total
mg/kg
0.00
0.00 0.00
20
L281896-01 WG289096
Phosphorus,Total
mg/kg
3.48
3.77 8.00
20
L282225-02 WG289096
Ammonia Nitrogen
mg/kg
152.
130. 15.6
20
L282347-01 WG289232
Laboratory
Control Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
Nitrate
mg/kg
177
163.
92.1
817119 WG288401
Aluminum
mg/kg
6320
6000
94.9
57.9-142 WG288474
Arsenic
mg/kg'
161
158.
98.1
79.5-120 WG288474
Barium
mg/kg
252
248.
98.4
82.1-117 WG288474
Cadmium
mg/kg
128
126.
98.4
81.3-118 WG288474
Calcium
mg/kg
3320
3380
102.
79.2-120 WG288474 .
Chromium
mg/kg
69.5
65.8
94.7
78.6-121 WG288474
Copper
mg/kg
148
152.
103.
82.4-117 WG288474
Lead
mg/kg
142
145.
102.
80.3-119 WG288474
Magnesium
mg/kg
2040
2030
99.5
77-123 WG288474
Manganese
mg/kg
408
393.
96.3
79.9-120 WG288474
Molybdenum
mg/kg
84.1
83.6
99.4
79.3-120 WG288474
Nickel
mg/kg
147
143.
97.3
81.6-118 WG288474
Potassium
mg/kg
1920
1790
93.2
71.4-128 WG288474
Selenium
mg/kg
64.2
65.8
102.
75.5-124 WG288474
Silver
mg/kg
130
102.
78.5
53-146.9 WG288474
Sodium
mg/kg
445
422.
94.8
55.5-144 WG288474
Zinc
mg/kg
165
152.
92.1
79.4-120 WG288474
Mercury
mg/kg
11.7
10.3
88.0
66.4-133 WG288512
pH
su
9.55
9.50
99.5
85-115 WG288594
Kjeldahl Nitrogen, TKN
mg/kg
1270
1260
99.1
60-140 WG288597
Total Solids
%
50
50.3
101.
85-115 WG288768
Phosphorus,Total
mg/kg
42.7
47.8
112.
30-170 WG289096
Ammonia Nitrogen
mg/kg
391
297.
75.8
50-150 WG289232
Laboratory Control Sample Duplicate
Analyte
Units
LCSD Res
Ref Res RPD
Limit %Rec
Batch
Nitrate
mg/kg
164.
163. 0.612
20 93
WG288401
pH
su
9.50
9.50 0.00
20 99
WG288594
Kjeldahl Nitrogen, TKN
mg/kg
1290
1260 2.19
20 101
WG288597
Total Solids
%
50.3
50.3 0.0949
20 101
WG288768
Phosphorus,Total mg/kg 48.8 47.8 2.07 20 114 WG289096
Ammonia Nitrogen mg/kg 287. 297. 3.43 20 73 WG289232
Page 5 of 8

12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 02, 2007
L281445
Matrix Spike
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp
Batch
Nitrate
mg/kg
46.9
0.646
50
92.5
80-120
L281206701
WG288401
Nitrite
mg/kg
48.2
0.200
50
96.0
80-120
1,281206-01
WG288401
Aluminum
mg/kg
4900
4460
50
880.
75-125
L281503-01
WG288474
Arsenic
mg/kg
53.1
0.00
10
106.
75-125
L281503-01
WG288474
Barium
mg/kg
143.
89.0
50
108.
75-125
L281503-01
WG288474
Cadmium
mg/kg
44.3
0.00
50
88.6
75-125
L281503-01
WG288474
Calcium
mg/kg
64500
68800
500
0.0
75-125
L281503-01
WG288474
Chromium
mg/kg
50.7
5.20
50
91.0
75-125
L281503-01
WG288474
Copper
mg/kg
55.3
4.67
50
101.
75-125
L281503-01
WG288474
Lead
mg/kg
57.2
4.00
10
106.
75-125
L281503-01
WG288474
Magnesium
mg/kg
26000
33100
500
0.0
75-125
L281503-01
WG288474
Manganese
mg/kg
151.
77.3
50
147.
75-125
L281503-01
WG288474
Molybdenum
mg/kg
46.1
0.273
50
91.7
75-125
L281503-01
WG288474
Nickel
mg/kg
51.5
3.92
50
95.2
75-125
L281503-01
WG288474
Potassium
mg/kg
2010
1350
500
132.
75-125
L281503-01
WG288474
Selenium
mg/kg
47.7
0.00
50
95.4
75-125
L281503-01
WG288474
Silver
mg/kg
49.0
0.00
50
98.0
75-125
L281503-01
WG288474
Sodium
mg/kg
1020
465.
500
111.
75-125
L281503-01
WG288474
Zinc
mg/kg
65.1
18.6
50
93.0
75-125
L281503-01
WG288474
Mercury
mg/kg
0.314
0.0960
.25
87.2
70-130
L281374-05
WG288512
Kjeldahl Nitrogen, TKN
mg/kg
341.
0.00
400
85.3
80-120
L281445-01
WG288597
Phosphorus,Total
mg/kg
0.00
0.00
50
0.0
80-120
L281896-01
WG289096
Ammonia Nitrogen
mg/kg
64.5
0.00
250
25.8
80-120
L281445-01
WG289232
Matrix Spike
Duplicate
Analyte
Units
MSD Res
Ref Res
RPD
Limit %Rec
Ref Samp
Batch
Nitrate
mg/kg
46.1
46.9
1.72
20
90.9
L281206-01
WG288401
Nitrite
mg/kg
48.3
48.2
0.207
20
96.2
L281206-01
WG288401
Aluminum
mg/kg
4400
4900
10.8
20
0.00
L281503-01
WG288474
Arsenic
mg/kg
43.8
53.1
19.2
20
87.6
L281503-01
WG288474
Barium
mg/kg
121.
143.
16.7
20
64.0
L281503-01
WG288474
Cadmium
mg/kg
42.0
44.3
5.33
20
84.0
L281503-01
WG288474
Calcium
mg/kg
74800
64500
14.8
20
1200
L281503-01
WG288474
Chromium
mg/kg
49.2
50.7
3.00
20
88.0
L281503-01
WG288474
Copper
mg/kg
52.1
55.3
5.96
20
94.9
L281503-01
WG288474
Lead
mg/kg
49.0
57.2
15.4
20
90.0
L281503-01
WG288474
Magnesium
mg/kg
31700
26000
19.8
20
0.00
L281503-01
WG288474
Manganese
mg/kg
118.
151.
24.5
20
81.4
L281503-01
WG288474
Molybdenum
mg/kg
44.3
46.1
3.98
20
88.1
L281503-01
WG288474
Nickel
mg/kg
48.8
51.5
5.38
20
89.8
L281503-01
WG288474
Potassium
mg/kg
1940
2010
3.54
20
118.
L281503-01
WG288474
Selenium
mg/kg
44.4
47.7
7.17
20
88.8
L281503-01
WG288474
Silver
mg/kg
47.0
49.0
4.17
20
94.0
L281503-01
WG288474
Sodium
mg/kg
918.
1020
10.5
20
90.6
L281503-01
WG288474
Zinc
mg/kg
58.7
65.1
10.3
20
80.2
L281503-01
WG288474
Mercury
mg/kg
0.316
0.314
0.635
20
88.0,
L281374-05
WG288512
Kjeldahl Nitrogen, TKN
mg/kg
413.
341.
19.1
20
103.
L281445-01
WG288597
Phosphorus,Total
mg/kg
0.00
0.00
0.00
20
0.00
L281896-01
WG289096
Ammonia Nitrogen
mg/kg
67.5
64.5
4.55
20
27.0
L281445-01
WG289232
Page 6 of 8

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L281445
Batch number /Run number / Sample number cross reference
WG288401: R308280: L281445-01
WG288594: R308325: L281445-01
WG288474: R308402: L281445-01
WG288512: R308421: L281445-01
WG288768: R308649: L281445-01
WG288597: R308710: L281445-01
WG289096: R308929: L281445-01
WG289232: R308934: L281445-01
* * Calculations are performed prior to rounding of reported values
Page 7 of
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
March 02, 2007

c
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 March 02, 2007
L281445
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a "J6". The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 8 of 8

1
ENVIRONMENTAL
SCIENCE CORP.
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
Report Summary
Friday December 01, 2006
Report Number: L270234
Samples Received: 11/22/06
Client Project: WQ0016388
Description: NCDENH Lagoons
12065 Lebanon Rd.
Mt. Juliet, TN37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have an
questions regarding this data package, please do not hesitate to caly
l.
Reviewed By: ��� #1414t
-Jimmy f
unt, f6c Representative
Laboratory Certification Numbers
A2LA - 1461-01, AIHA - 09227, AL - 40660, CA - I-2327, CT - PH-0197, FL - E87487
GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140
NJ - TN002, SC - 84004, TN - 2006, VA - 00109, WV - 233
AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, WA - C1915
This report may not be reproduced, except in full, without written approval from Environmental Science Corp.

16
12065 Lebanon Rd.
Mt. Juliet,
TN 37122
ENVIRONMENTAL
1-800-767-5859
SCIENCE CORP.
Fax (615)
758-5859
Tax I.D. 62-0814289
Est. 1970
REPORT
OF ANALYSIS
Ms. Phyllis Drye
December 01,2006
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
ESC Sample #
L270234-01
Date Received NCDENH`er�e22CIOU002
Description NCDENH Lag ns
Site ID
Sample ID LAGOON SAND SAMPLES
Project # WQ0016388
Collected By Wayne Drye
,Collection Date 11/21/06 08:00
Parameter Dry
Result
Det. Limit
Units
Method
Date
Dil.
Nitrate
BDL
1.1
mg/kg
9056
11/29/06
1
Nitrite
2.7
1.1
mg/kg
9056
11/29/06
1
Phosphorus,Total
BDL
1.1
mg/kg
9056
11/29/06
1
Total Nitrogen
2.6
1.1
mg/kg
Calc.
11/30/06
1
Ammonia Nitrogen
BDL
5.5
mg/kg
350.1
11/29/06
1
,�r�-,�.�
?-5���5@E19�C-���su�90�9'5C•�11/t25./10;6
Organic Nitrogen
BDL
11.
mg/kg
CALC.
11/29/06
1
Kjeldahl Nitrogen, TKN
BDL
22.
mg/kg
351.2
11/30/06
1
Total Solids
91.2
' %
2540G
11/29/06
1
Mercury
BDL
0.022
mg/kg
7471
11/29/06
1
Aluminum
32000
5.5
mg/kg
6010B
11/29/06'
1
Arsenic
BDL
1.1
mg/kg
6010B
11/29/06
1
Barium
91.
0.27
mg/kg
6010B
11/29/06
1
Cadmium
BDL
0.27
mg/kg
6010B
11/29/06
1
Calcium
9900
27.
mg/kg
6010B
11/29/06
1
Chromium
21.
0.55
mg/kg
6010B
11/29/06
1
Copper
4.3
1.1
mg/kg
6010B
11/29/06
1
Lead
33.
0.27
mg/kg
6010B
11/29/06
1
Magnesium
2200
5.5
mg/kg
6010B
11/29/06
1
Manganese
4.0
0.55
mg/kg
6010B
11/29/06
1
Molybdenum
1.5
0.11
mg/kg
6010B
11/29/06
1
Nickel
1.8
1.1
mg/kg
6010B
11/29/06
1
Potassium
980
27.
mg/kg
6010B
ll/.29/06
1
Selenium
BDL
1.1
mg/kg
6010B
11/29/06
1
Silver
BDL
0.55
mg/kg
6010B
11/29/06
1
Sodium
610
27.
mg/kg
6010B
11/29/06
1
Zinc
27.
1.6
mg/kg
6010B
11/29/06
1
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 12/01/06 11:32 Printed: 12/01/06 14:46
Page 1 of 6

� •1
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L270234
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Far: [phone]
Tar. I.D. 62-0814289
Est. 1970
December 01, 2006
Analyte
Result
IaMo}ra =o:r B12- k
Units Die Analyzed
Batch
pH
7.60
su 11/25/06
12:05
WG276803
Mercury
< .02
mg/kg 11/29/06
07:05
WG277049
Total Solids
0.00
% 11/29/06
09:57
WG277054
Aluminum
< 5
mg/kg
11/29/06
14:10
WG277095
Arsenic
< 1
mg/kg
11/29/06
14:10
WG277095
Barium
< .25
mg/kg
11/29/06
14:10
WG277095
Cadmium
< .25
mg/kg
11/29/06
14:10
WG277095
Calcium
< 25
mg/kg
11/29/06
14:10
WG277095
Chromium
< .5
mg/kg
11/29/06
14:10
WG277095
Copper
< 1
mg/kg
11/29/06
14:10
WG277095
Lead
< .25
mg/kg
11/29/06
14:10
WG277095
Magnesium
< 5
mg/kg
11/29/06
14:10
WG277095
Manganese
< .5
mg/kg
11/29/06
14:10
WG277095
Molybdenum
< .1
mg/kg
11/29-/06
14:10
WG277095
Nickel
< 1
mg/kg
11/29/06
14:10
WG277095
Potassium
< 25
mg/kg
11/29/06
20:35
WG277095
Selenium
< 1
mg/kg
11/29/06
14:10
WG277095
Silver
< .5
mg/kg
11/29/06
14:10
WG277095
Sodium
< 25
mg/kg
11/29/06
20:35
WG277095
Zinc
< 1.5
mg/kg
11/29/06
14:10
WG277095
Kjeldahl Nitrogen, TKN
< 20
mg/kg
11/30/06
08:44
WG277167
Ammonia Nitrogen
< 5
mg/kg
11/29/06
12:32
WG277169
Nitrate
< 1
mg/kg
11/29/06
12:17
WG277200
Nitrite
< 1
mg/kg
11/29/06
12:17
WG277200
Phosphorus,Total
< 1
mg/kg
11/29/06
12:17
WG277200
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
pH
su
7.60
7.50
1.32
20
L270168-01
WG276803
Mercury
mg/kg
0.00
0.00
0.00
20
L270240-12
WG277049
Total Solids
%
90.9
91.2
0.328
20
L270234-01
WG277054
Aluminum
mg/kg
2390
1620
36.4
20
L270483-02
WG277095
Arsenic
mg/kg
32.2
22.3
36.3
20
L270483-02
WG277095
Barium
mg/kg
196.
151.
25.9
20
L270483-02
WG277095
Cadmium
mg/kg
458.
320.
35.5
20
L270483-02
WG277095
Calcium
mg/kg
33100
23300
34.8
20
L270483-02
WG277095
Chromium
mg/kg
4930
3400
36.7
20
L270483-02
WG277095
Copper
mg/kg
1480
1020
36.8
20
L270483-02
WG277095
Lead
mg/kg
8000
5580
35.6
20
L270483-02
WG277095
Magnesium
mg/kg
185000
130000
34.9
20
L270483-02
WG277095
Manganese
mg/kg
22000
15800
32.8
20
L270483-02
WG277095
Molybdenum
mg/kg
41.9
27.7
40.8
20
L270483-02
WG277095
Nickel
mg/kg
306.
225.
30.5
20
L270483-02
WG277095
Potassium
mg/kg
3300
0.00
NA
20
L270483-02
WG277095
Selenium
mg/kg
0.00
0.00
0.00
20
L270483-02
WG277095
Silver
mg/kg
45.5
32.0
34.8
20
L270483-02
WG277095
Sodium
mg/kg
7030
0.00
NA
20
L270483-02
WG277095
Zinc
mg/kg
74800
65300
13.6
20
L270483-02
WG277095
Kjeldahl Nitrogen, TKN mg/kg 343.
Page 2 of 6
350. 1.89 20 L270539-01 WG277167

12065 Lebanon Rd.
Mt. Juliet, TN 37122
(615)758-858
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 L270239 December 01, 2006
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp Batch
Ammonia Nitrogen
mg/kg
0.00
0.00 0.00
20
L270487-01 WG277169
Nitrate
mg/kg
11.1
11.8 6.11
20
L270547-01 WG277200
Nitrite
mg/kg
0.00
0.00 0.00
20
L270547-01 WG277200
Phosphorus,Total
mg/kg
92.3
89.3 3.30
20
L270547-01 WG277200
Laboratory
Control Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
PH
su
8.1
8.10
100.
85-115 WG276803
Mercury
mg/kg
11.7
9.47
80.9
66.4-133 WG277049
Total Solids
%
50
50.0
99.9
85-115 WG277054 _
Aluminum
mg/kg
6320
5960
94.3
57.9-142 WG277095
Arsenic
mg/kg
161
153.
95.0
79.5-120 WG277095
Barium
mg/kg
252
266.
106.
82.1-117 WG277095
Cadmium
mg/kg
128
131.
102.
81.3-118 WG277095
Calcium
mg/kg
3320
3380
102.
79.2-120 WG277095
Chromium
mg/kg
69.5
66.7
96.0
78.6-121 WG277095
Copper
mg/kg
148
154.
104.
82.4-117 WG277095
Lead
mg/kg
142
140.
98.6
80.3-119 WG277095
Magnesium
mg/kg
2040
2040
100.
77-123 WG277095
Manganese
mg/kg
408
400.
98.0
79.9-120 WG277095
Molybdenum
mg/kg
84.1
84.7
101.
79.3-120 WG277095
Nickel
mg/kg
147
136.
92.5
81.6-118 WG277095
Potassium
mg/kg
1920
1800
93.8
71.4-128 WG277095
Selenium
mg/kg
64.2
60.3
93.9
75.5-124 WG277095
Silver
mg/kg
130
129.
99.2
53-146.9 WG277095
Sodium
mg/kg
445
471.
106.
55.5-144 WG277095
Zinc
mg/kg
165
181-
110.
79.4-120 WG277095
Kjeldahl Nitrogen, TKN
mg/kg
1270
959.
75.5
60-140 WG277167
Ammonia Nitrogen
mg/kg
391
235.
60.2
50-150 WG277169
Nitrate
mg/kg
281
255.
90.7
81-119 WG277200
Phosphorus,Total
mg/kg
63.7
60.7
95.3
43-157 WG277200
Laboratory Control Sample Duplicate
Analyte
Units
LCSD Res
Ref Res RPD
Limit °%Rec
Batch
PH
su
8.10
8.10 0.00
20 100
WG276803
Kjeldahl Nitrogen, TKN
mg/kg
984.
959. 2.65
20 78
WG277167
Ammonia Nitrogen
mg/kg
2B9.
235. 20.3
20 74
WG277169
Nitrate
mg/kg
256.
255. 0.391
20 91
WG277200
Phosphorus,Total
mg/kg
60.6
60.7 0.165
20 95
WG277200
Matrix Spike
Analyte
Units
MS Res
Ref Res TV %
Rec Limit
Ref Samp Batch
Mercury
mg/kg
0.246
0.00 .25
98.4 70-130
L270256-01 WG277049
Aluminum
mg/kg
1830
•1620 5 420.
75-125
L270483-02 WG277095
Arsenic
mg/kg
69.2
22.3 5
93.8 75-125
L270483-02 WG277095
Page 3 of 6

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135-Red Road
Rockwell, NC 28138
Barium
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Quality Assurance Report
Level II
December 01, 2006
L270234
196. 151. 5 90.0 75-125 L270483-02 WG277095
Matrix Spike
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp
Batch
Cadmium
mg/kg
4,03.
320.
5
166.
75-125
L270483-02
WG277095
Calcium
mg/kg
25800
23300
50
500.
75-125
L270483-02
WG277095
Chromium
mg/kg
3780
3400
5
760.
75-125
L270483-02
WG277095
Copper
mg/kg
1180
1020
5
320.
75-125
L270483-02
WG277095
Lead
mg/kg
6190
5580
5
1220
75-125
L270483-02
WG277095
Magnesium
mg/kg
142000
130000
50
2400
75-125
L270483-02
WG277095
Manganese
mg/kg
17000
15800
5
2400
75-125
L270483-02
WG277095
Molybdenum
mg/kg
76.7
27.7
5
98.0
75-125
L270483-02
WG277095
Nickel
mg/kg
288.
225.
5
126.
75-125
L270483-02
WG277095
Potassium
mg/kg
3730
0.00
50
746.
75-125
L270483-02
WG277095
Selenium
mg/kg
33.7
0.00
5
67.4
75-125
L270483-02
WG277095
Silver
mg/kg
66.8
32.0
5
69.6
75-125
L270483-02
WG277095
Sodium
mg/kg
7550
0.00
50
1510
75-125,
L270483-02
WG277095
Zinc
mg/kg
66500
65300
50
240.
75-125
L270483-02
WG277095
Kjeldahl Nitrogen, TKN
mg/kg
508.
160.
400
87.0
80-120
L270539-03
WG277167
Ammonia Nitrogen
mg/kg
164.
0.00
250
65.7
80-120
L270547-01
WG277169
Nitrate
mg/kg
94.9
11.8
50
166.
80-120
L270547-01
WG277200
Nitrite
mg/kg
30.1
0.00
50
60.2
80-120
L270547-01
WG277200
Phosphorus,Total
mg/kg
172.
89.3
50
165.
80-120
L270547-01
WG277200
Matrix Spike
Duplicate
Analyte
Units
MSD Res
Ref Res
RPD
Limit %Rec
Ref Samp
Batch
Mercury
mg/kg
0.215
0.246
13.4
20
86.0
L270256-01
WG277049
Aluminum
mg/kg
1530
1830
17.9
20
0.00
L270483-02
WG277095
Arsenic
mg/kg
60.7
69.2
13.1
20
76.8
L270483-02
WG277095
Barium
mg/kg
264.
196.
29.6
20
226.
L270483-02
WG277095
Cadmium
mg/kg
352.
403.
13.5
20
64.0
L270483-02
WG277095
Calcium
mg/kg
22400
25800
14.1
20
0.00
L270483-02
WG277095
Chromium
mg/kg
3200
3780
16.6
20
0.00
_
L270483-02
WG277095
Copper
mg/kg
1010
1180
15.5
20
0.00
L270483-02
WG277095
Lead
mg/kg`5360
6190
14.4
20
0.00
L270483-02
WG277095
Magnesium
mg/kg
122000
142000
15.2
20
0.00
L270483-02
WG277095
Manganese
mg/kg
14800
17000
13.8
20
0.00
L270483-02
WG277095
Molybdenum
mg/kg
65.2
76.7
16.2
20
75.0
L270483-02
WG277095
Nickel
mg/kg
251.
288.
13.7
20
52.0
L270483-02
WG277095
Potassium
mg/kg
3800
3730
1.86
20
760.
L270483-02
WG277095
Selenium
mg/kg
30.0
33.7
11.6
20
60.0
L270483-02
WG277095
Silver
mg/kg
70.1
66.8
4.82
20
76.2
L270483-02
WG277095
Sodium
mg/kg
7600
7550
0.660
20
1520
L270483-02
WG277095
Zinc
mg/kg
60700
66500
9.12
20
0.00
L270483-02
WG277095
Kjeldahl Nitrogen, TKN
mg/kg
509.
508.
0.201
20
87.3
L270539-03
WG277167
Ammonia Nitrogen
mg/kg
197.
164.
18.3
20
78.9
L270547-01
WG277169
Nitrate
mg/kg
94.5
94.9
0.422
20
165.
L270547-01
WG277200
Nitrite
mg/kg
29.9
30.1
0.667
20
59.8
L270547-01
WG277200
Phosphorus,Total
mg/kg
171.
172.
0.583
20
163.
L270547-01
WG277200
Batch number /Run number / Sample number cross reference
WG276803: R298084: L270234-01
WG277054: R298482: L270234-01
Page 4 of 6

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
WG277049: R298537: L270234-01
WG277095: R298572: L270234-01
WG277200: R298596: L270234-01
WG277167: R298618: L270234-01
WG277169: R298625: L270234-01
Quality Assurance Report
Level II
L270234
* * Calculations are performed prior to rounding of reported values
Page 5 of 6
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
December 01, 2006

M
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 . December 01, 2006
L270234
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter.is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a "J6". The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 6 of 6

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail]
March 19,2007
DENR/DWQ/Water Quality Section
Mr. Daryl Merritt,
Environmental Specialist I
Non -Discharge Compliance/Enforcement Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Mr. Merritt:
I�APR 2 2007
Enclosed is the Monitoring and Reporting requirements for our permit number
W00016338.
For the year of 2006, we did not land apply any silica residuals. I have included the
Annual Residual Sampling Summary forms ACF, RSSF and RSS-B. I have also
included the lagoon sand sample analysis.
Please let me know if you have any questions.
Best regards,
ALCHEM, INC
j
Trent Tidwell,
Plant Manager
pcd
Ad n
cc: Ms. Ellen Huffman, I//ATtj`. �vu
InfPro ' i
Environmental Specialist orrrlalionp�O0�
Mooresville Regional Office cessins Unit
N

' ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0016338 County: ROWAN Year:
2006
Facility Name (as shown on permit): ALCHEM, INC
Land Application Operator: Trent Tidwell, Plant Manager Phone:
704-279-7908
Land application of residual solids as allowed by the permit occurred during.the past calendar year?
❑ Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit:
0
Total number of fields land application occurred during the year:
0
Total amount of dry tons applied during the year for all application sites:
0
Total number of acres land application occurred during the year:
0
Part B:
Facility was compliant during calendar year 2006 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. ❑ Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and repo rted6Re6e ear as required
and three (3) copies of certified laboratory results are attached. Xry-'1CP1
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 offd,� R or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 ft4irt 53eJ1 ted facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices inn it,543.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities). feces''., /Unit
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief', true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
This is in exception to the NOV's AAchem has rece ed th t ar berg co ested.
Trent Tidwell, Plant Manager 3/2
Permittee Name and Title (type or print) Signature of Permittee Date
Signature of Pr6arer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
i Preparer is defined in 40 CFR Part 503.9 (r)
DENR FORM ACF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory: 1) Environmental Science Corp
Facility Name:
NPDES # or
WQ#:
WWTP Name:
Residual Analvsis Data
ALCHEM, INC
16338
2)
3)
4)
5)
• Sample
• • -Percent
1 •
®--------
Solids
UV no M • •
®
1
------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
3b4c)
Signs re of Preps r Date
DENR FORM RSSF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to.be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory
Facility Name:
NPDES # or
WQ#:
WWTP Name:
Residual Analysis Data
ALCHEM, 1NC
16338
1) Environmental Science Corp
2)
3)
4)
5)
Sample or
CompositeDatem.mm,mm,mmm,mmmm
111
1111-------
Potassium
• : 1
11
----------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signatu of Prepare
Date
DENR FORM RSSF-B (5/2003)

WA
ENVIRONMENTAL
SCIENCE CORP.
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
Report Summary
Friday'March 02, 2007
Report Number: L2 814 4 5
Samples Received: 02/22/07
Client Project: WQ0016388
Description: NCDENH Lagoons
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have an
questions regarding this data package, please do not hesitate to caly
l.
Reviewed By:
#44-
'Jimmy f
unt, fsu Representative
La bora tory Certifica tion Numbers
A2LA - 1461-01, AIHA - 09227, AL - 40660, CA - I-2327, CT - PH-0197, FL - E87487
GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140
NJ - TN002, SC - 84004, TN - 2006, VA - 00109, WV - 233
AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, WA - C1915
This report may not be reproduced, except in full, without written approval from Environmental.Science Corp.

Lebanon R
Mtt.. J 3uliet, TN 7122
ENVIRONMENTAL
(615) 7-5859
1-600-767 -5859
_
SCIENCE CORP.
Fax (615)
758-5859
Tax I.D.
62-0814289
Est. 1970
REPORT
OF ANALYSIS
Ms. Phyllis Drye
March
02,2007
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
ESC
Sample #
L281445-01
Date Received February 22, 2007
j
Description NCDENH Lagoons
/
Site
ID
Sample ID AG00.N-S-AND SAMP
Project
# WQ0016388
Collected By Trent Tidwell
Collection Date 02/20/07 08:00
Parameter Dry
Result
Det. Limit
Units
Method
Date
Dil.
Nitrate
BDL
1.2
mg/kg
9056
02/23/07
1
Nitrite
1.5
1.2
mg/kg
9056
02/23/07
1
Phosphorus,Total
1.7
1.2
mg/kg
9056
02/28/07
1
Total Nitrogen
1.5
1.2
mg/kg
Calc.
02/28/07
1
Ammonia Nitrogen
BDL
J5..8-
mg/kg
350.1
03/01/07
1
pH
7.9
7.9@19.0
su
9045C
02/24/07
1
Organic Nitrogen
BDL
12.
mg/kg
CALC.
02/28/07
1
Kjeldahl Nitrogen, TKN
BDL
23.
mg/kg
351.2
02/28/07
1
Total Solids
86.2
%
254OG
02/28/07
1
Mercury
BDL
0.023
mg/kg
7471
02/26/07
1
Aluminum
40000
5.8
mg/kg
6010B
02/24/07
1
Arsenic
BDL
1.2
mg/kg
6010B
02/24/07
1
Barium
90.
0.29
mg/kg
6010B
02/24/07
1
Cadmium
BDL
1.4
mg/kg
6010E
02/26/07
5
Calcium
9900
29.
mg/kg
6010B
02/24/07
1
Chromium
25.
0.58
mg/kg
6010B
02/24/07
1
Copper
5.8
1.2
mg/kg
6010B
02/24/07
1
Lead
43.
0.29
mg/kg
6010B
02/24/07
1
Magnesium
2000
5.6
mg/kg
6010B
02/24/07
1
Manganese
3.5
0.58
mg/kg
6010B
02/24/07,
1
Molybdenum
0.87
0.12
mg/kg
6010B
02/24/07
1
Nickel
3.4
1.2
mg/kg
6010B
02/24/07
1 '
Potassium
1300
29.
mg/kg
6010B
02/24/07
1
Selenium
BDL
1.2
mg/kg
6010B
02/24/07
1
Silver
BDL
0:58
mg/kg
6010B
02/24/07
1
Sodium
620
29.
mg/kg
6010B
02/24/07
1
Zinc
5.0
1.7
mg/kg
6010B
02/24/07
1
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 03/01/07 17:17 Revised: 03/02/07 09:56
Page 1 of 8

Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte Qualifier
L281445-01 Cadmium 0
Ammonia Nitrogen J6
Page 2 of 8

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
(ESC) Sample diluted due to matrix interferences that impaired the ability
to make an accurate analytical determination. The detection limit is
elevated in order to reflect the necessary dilution.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate- Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used'to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ) (SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 68-128 64-125
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 76-115 69-118
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromo£luorobenzene 79-127 61-134
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 3 of 8

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L281445
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tar. I.D. 62-0814289
Est. 1970
March 02, 2007
Laboratory Blank
Analyte
Result
Units
Date Analyzed
Batch
Nitrate
< 1
mg/kg -02/23/07
13:11
WG288401
Nitrite
< 1
mg/kg
02/23/07
13:11
WG288401
Aluminum
< 5
mg/kg
02/24/07
10:43
WG288474
Arsenic
< 1
mg/kg
02/24/07
10:43
WG288474
Barium
< .25
mg/kg
02/24/07
10:43
WG288474
Cadmium
< .25
mg/kg
02/24/07
10:43
WG288474
Calcium
< 25
mg/kg
02/24/07
10:43
WG288474
Chromium
< .5
mg/kg
02/24/07
10:43
WG288474
Copper
< 1
mg/kg
02/24/07
10:43
WG288474
Lead
< .25
mg/kg
02/24/07
10:43
WG288474
Magnesium
< 5
mg/kg
02/24/07
10:43
WG288474
Manganese
< .5
mg/kg
02/24/07
10:43
WG288474
Molybdenum
< .1
mg/kg
02/24/07
10:43
WG288474
Nickel
< 1
mg/kg
02/24/07
10:43
WG288474
Potassium
< 25
mg/kg
02/24/07
10:43
WG288474
Selenium
< 1
mg/kg
02/24/07
10:43
WG288474
Silver
< .5
mg/kg
02/24/07
10:43
WG288474
Sodium
< 25
mg/kg
02/24/07
10:43
WG288474
Zinc
< 1.5
mg/kg
02/24/07
10:43
WG288474
Mercury
< .02
mg/kg
02/26/07
10:09
WG288512
pH
7.00
su
02/24/07
18:05
WG288594
Kjeldahl Nitrogen, TKN
< 20
mg/kg
02/28/07
10:45
WG288597
Total Solids
0.00
%
02/28/07
09:00
WG288768
Phosphorus,Total
< 1
mg/kg
02/28/07
11:44
WG289096
Ammonia Nitrogen
< 5
mg/kg
03/01/07
04:35
WG289232
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
Nitrate
mg/kg
20.9
19.9
4.90
20
L281206-03
WG288401
Nitrite
mg/kg
56.6
57.6
1.75
20
L281206-03
WG288401
Aluminum
mg/kg
4630
4460
3.74
20
L281503-01
WG288474
Arsenic
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Barium
mg/kg
98.7
89.0
10.3
20
L281503-01
WG288474
Cadmium
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Calcium
mg/kg
70700
68800
2.72
20
L281503-01
WG288474
Chromium
mg/kg
5.33
5.20
2.47
20
L281503-01
WG288474
Copper
mg/kg
5.38
4.67
14.1
20
L281503-01
WG288474
Lead
mg/kg
5.57
4.00
32.8
20
L281503-01
WG288474
Manganese
mg/kg
106.
77.3
31.3
20
L281503-01
WG288474
Molybdenum
mg/kg
0.357
0.273
26.7
20
L281503-01
WG288474
Nickel
mg/kg
4.67
3.92
17.5
20
L281503-01
WG288474
Potassium
mg/kg
1400
1350
3.64
20
L281503-01
WG288474
Selenium
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Silver
mg/kg
0.00
0.00
0.00
20
L281503-01
WG288474
Sodium
mg/kg
450.
465.
3.28
20
L281503-01
WG288474
Zinc
mg/kg
22.5
18.6
19.0
20
L281503-01
WG288474
Mercury
mg/kg
0.0456
0.0630
32.0
20
L281374-04
WG288512
pH
su
9.10
9.00
1.10
20
L281647-01
WG288594
pH
su
9.00
8.60
4.55
20
L281763-01
WG288594
Page 4 of 8

12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 L281445 March 02, 2007
Duplicate
Analyte
Units
Result
Duplicate
RPD
Limit
Ref Samp Batch
Kjeldahl Nitrogen, TKN
mg/kg
11000
10000
9.53
20
L281659-01 WG288597
Total Solids
%
86.4
86.2
0.288
20
L281445-01 WG288768
Phosphorus,Total
mg/kg
0.00
0.00
0.00
20
L281896-01 WG289096
Phosphorus,Total
mg/kg
3.48
3.77
8.00
20
L282225-02 WG289096
Ammonia Nitrogen
mg/kg
152.
130.
15.6
20
L282347-01 WG289232
Laboratory
Control Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
Nitrate
mg/kg
177
163.
92.1
81-119 WG288401
Aluminum
mg/kg
6320
6000
94.9
57.9-142 WG288474
Arsenic
mg/kg
161
158.
98.1
79.5-120 WG288474
Barium
mg/kg
252
248.
98.4
82.1-117 WG288474
Cadmium
mg/kg
128
126.
98.4
81.3-118 WG288474
Calcium
mg/kg
3320
3380
102.
79.2-120 WG288474
Chromium
mg/kg
69.5
65.8
94.7
78.6-121 WG288474
Copper
mg/kg
148
152.
103.
82.4-117 WG288474
Lead
mg/kg
142
145.
102.
80.3-119 WG288474
Magnesium
mg/kg
2040
2030
99.5-
77-123 WG288474
Manganese
mg/kg
408
393.
96.3
79.9-120 WG288474
Molybdenum
mg/kg
84.1
83.6
99.4
79.3-120 WG288474
Nickel
mg/kg
147
143.
97.3
81.6-118 WG288474
Potassium
mg/kg
1920
1790
93.2
71.4-128 WG288474
Selenium
mg/kg
64.2
65.8
102.
75.5-124 WG288474
Silver
mg/kg
130
102.
78.5
53-146.9 WG288474
Sodium
mg/kg
445
422.
94.8
55.5-144 WG288474
Zinc
mg/kg
165
152.
92.1
79.4-120 WG288474
Mercury
mg/kg
11.7
10.3
88.0
66.4-133 WG288512
pH
su
9.55
9.50
99.5
85-115 WG288594
Kjeldahl Nitrogen, TKN
mg/kg
1270
1260
99.1
60-140 WG288597
Total Solids
%
50
50.3
101.
85-115 WG288768
Phosphorus,Total
mg/kg
42.7
47.8
112.
30-170 WG289096
Ammonia Nitrogen
mg/kg
391
297.
75.8
50-150 WG289232
Laboratory Control
Sample Duplicate
Analyte
Units
LCSD Res
Ref Res
RPD
Limit %Rec
Batch
Nitrate
mg/kg
164.
163.
0.612
20 93
WG288401
pH
su
9.50
9.50
0.00
20 99
WG288594
Kjeldahl Nitrogen, TKN
mg/kg
1290
1260
2.19
20 101
WG288597
Total Solids
%
50.3
50.31
0.0949
20 101
WG288768
Phosphorus,Total mg/kg 48.8 47.8 2.07 20 114 WG289096
Ammonia Nitrogen mg/kg 287. 297. 3.43 20 73 WG289232
Page 5 of 8

12065 Lebanon Rd.
Mt. Juliet, TN 37122
c615) 758-5859
ENVIRONMENTAL
1-800-767-5859
Fax [phone]
SCIENCE CORP.
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. .Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 L281945 March 02, 2007
Matrix Spike
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp Batch
Nitrate
mg/kg
46_9
0.646
50
92.5
80-120
L281206-01 WG288401
Nitrite
mg/kg
48.2
0.200
50
96.0
80-120
L281206-01 WG288401
Aluminum
mg/kg
4900
4460
50
880.
75-125_
L281503-01 WG288474
Arsenic
mg/kg
53.1
0.00
10
106.
75-125
L281503-01 WG288474
Barium
mg/kg
143.
89.0
50
108.
75-125
L281503-01 WG288474
Cadmium
mg/kg
44.3
0.00
50
88.6
75-125
L281503-01 WG288474
Calcium
mg/kg
64500
68800
500
0.0
75-125
L281503-01 WG288474
Chromium
mg/kg
50.7
5.20
50
91.0
75-125
L281503-01 WG288474
Copper
mg/kg
55.3
4.67
50
101.
75-125
L281503-01 WG288474
Lead
mg/kg
57.2
4.00
10
106.
75-125
L281503-01 WG288474
Magnesium
mg/kg
26000
33100
500
0.0
75-125
L281503-01 WG288474
Manganese
mg/kg
151`.
77.3
50
147.
75-125
L281503-01 WG288474
Molybdenum
mg/kg
46.1
0.273
50
91.7
75-125
L281503-01 WG288474
Nickel
mg/kg
51.5
3.92
50
95.2
75-125
L281503-01 WG288474
Potassium
mg/kg
2010
1350
500
132.
75-125
L281503-01 WG288474
Selenium
mg/kg
47.7
0.00
50
95.4
75-125
L281503-01 WG288474
Silver
mg/kg
49.0
0.00
50
98.0
75-125
L281503-01 WG288474
Sodium
mg/kg
1020
465.
500
111.
75-125
L281503-01 WG288474
Zinc
mg/kg
65.1
18.6
50
93.0
75-125
L281503-01 WG288474
Mercury
mg/kg
0.314
0.0960
.25
87.2
70-130
L281374-05 WG288512
Kjeldahl Nitrogen, TKN
mg/kg
341.
0.00
400
85.3
80-120
L281445-01 WG288597
Phosphorus,Total
mg/kg
0.00
0.00
50
0.0
80-120
L281896-01 WG289096
Ammonia Nitrogen
mg/ka
64.5
0.00
250
25.8
80-120
L281445-01 WG289232
Matrix Spike.Duplicate
Analyte
Units
MSD Res
Ref Res
RPD
Limit %Rec
Ref Samp Batch
Nitrate
mg/kg
46.1'
46.9
1.72
20
90.9
L281206-01 WG288401
Nitrite
mg/kg
48.3
48.2
0.207
20
96.2
L281206-01 WG288401
Aluminum
mg/kg
'4400
4900
10.8
20
0.00
L281503-01 WG288474
Arsenic
mg/kg
43.8
53.1
19.2
20
87.6
L281503-01 WG288474
Barium
mg/kg
121.
143.
16.7
20
64.0
L281503-01 WG288474
Cadmium
mg/kg
42.0
44.3
5.33
20
84.0
L281503-01 WG288474
Calcium
mg/kg
74800
64500
14.8
20
1200
L281503-01 WG288474
Chromium
mg/kg
49.2
50.7
3.00
20
88.0
L281503-01 WG288474
Copper
mg/kg
52.1
55.3
5.96
20
94.9
L281503-01 WG288474
Lead
mg/kg
49.0
57.2
15.4
20
90.0
L281303-01 WG288474
Magnesium
mg/kg
31700
26000
19.8
20
0.00
L281503-01 WG288474
Manganese
mg/kg
118.
151.
24.5
20
81.4
L281503-01 WG288474
Molybdenum
mg/kg
44.3
46.1
3.98
20
88.1
L281503-01 WG288474
Nickel
mg/kg
48.8
51.5
5.38
20
89.8
L281503-01 WG288474
Potassium
mg/kg
1940
2010
3.54
20
118.
L281503-01 WG288474
Selenium
mg/kg
44.4
47.7
7.17
20
88.8
L281503-01 WG288474
Silver
mg/kg
47.0
49.0
4.17
20
94.0
L281503-01 WG288474
Sodium
mg/kg
918.
1020
10.5
20
90.6
1;281503-01 WG288474
Zinc
mg/kg
58.7
65.1
1.0.3
20
80.2
L281503-01 WG288474
Mercury
mg/kg
0.316
0.314
0.635
20
88.0
L281374-05
WG288512
Kjeldahl Nitrogen, TKN
mg/kg
413.
341.
19.1
20
103.
L281445-01
WG288597
Phosphorus,Total
mg/kg
0.00
0.00
0.00
20
0.00
L281896-01
WG289096
Ammonia Nitrogen
mg/kg
67.5
64.5
4.55
20
. 27.0
L281445-01
WG289232
Page 6 of 8

IML
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L281445
Batch number /Run number / Sample number cross reference
WG288401: R308280: L281445-01
WG288594: R308325: L281445-01
WG288474: R308402: L281445-01
WG288512: R308421: L281445-01
WG288768: R308649: L281445-01
WG288597: R308710: L281445-01
WG289096: R308929: L281445-01
WG289232: R308934: L281445-01
* * Calculations are performed prior to rounding of reported values
Page 7 of 8
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
ESt. 1970
March 02, 2007

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 L281445 March 02, 2007
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a'method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a 11J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a 11J61'. The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 8 of 8

ENVIRONMENTAL
SCIENCE CORP.
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
Report Summary
Friday December 01, 2006
Report Number: L270234
Samples Received: 11 / 2 2 / 0 6
Client Project: WQ0016388
Description: NCDENH Lagoons
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have any
questions regarding this data package, please do not hesitate to call.
Reviewed By: 944-
�)immy f
unt, ZSC Representative
Laboratory Certification Numbers
A2LA - 1461-01, AIHA - 09227, AL - 40660, CA - I-2327, CT - PH-0197, FL - E87487
GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140
NJ - TN002, SC - 84004, TN - 2006, VA - 00109, WV - 233
AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, WA - C1915
This report may not be reproduced, except in full, without written approval from Environmental Science Corp.

ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
December 01,2006
Date Received
November 22,
2006
ESC
Sample #
L270234-01
Description (NCDENH
Lagoons
/
�
Site
ID
Sample ID
L 66N-SAN-D-SAMPLES
Project
#
W00016388
Collected By
Wayne Drye
Collection Date
11/21/06 08:00
Parameter
Dry Result
Det. Limit
Units
Method
Date
Dil.
Nitrate
BDL
1.1
mg/kg
9056
11/29/06
1
Nitrite
2.7
1.1
mg/kg
9056
11/29/06
1
Phosphorus,Total
BDL
1.1
mg/kg
9056
11/29/06
1,
Total Nitrogen
2.6
1.1
mg/kg
Calc.
11/30/06
1
Ammonia Nitrogen
BDL
5.5
mg/kg
350.1
11/29/06
1
�pH ^-
J 7.5@19.7C
su
9045C
11� /25/06
11/2�9/06 1
�T^ �
7.5
-"
Organic Nitrogen
BDL
11.
m /k
4 4
CALL.
Kjeldahl Nitrogen,
TKN
BDL
22.
mg/kg
351.2
11/30/06
1
Total Solids
91.2
%
254OG
11/29/06
1
Mercury
BDL
0.022
mg/kg
7471
11/29/06
1
Aluminum
32000
5.5
mg/kg
6010B
11/29/06
1
Arsenic
BDL
1.1
mg/kg
6010B
11/29/06
1
Barium
91.
0.27
mg/kg
6010B
11/29/06
1
Cadmium
BDL
0.27
mg/kg
6010B
11/29/06
1
Calcium
9900
27.
mg/kg
6010B
11/29/06
1
Chromium
21.
0.55
mg/kg
6010B
11/29/06
1
Copper
4.3
1.1
mg/kg
6010B
11/29/06
1
Lead
33.
0.27
mg/kg
6010B
11/29/06
1
Magnesium
2200
5.5
mg/kg
6010B
11/29/06
1
Manganese
4.0
0.55
mg/kg
6010B
11/29/06
1
Molybdenum
1.5
0.11
mg/kg
6010B
11/29/06
1
Nickel
1.8
1.1
mg/kg
6010B
11/29/06
1
Potassium
980
27.
mg/kg
6010B
11/29/06
1
Selenium
BDL
1.1
mg/kg
6010B
11/29/06
1
Silver
BDL
0.55
mg/kg
6010B
11/29/06
1
Sodium
610
27.
mg/kg
6010B
11/29/06
1
Zinc
27.
1.6
mg/kg
6010B
11/29/06
1
Results listed are dry weight basis.
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 12/01/06 11:32 Printed: 12/01/06 14:46
Page 1 of 6

12065 Lebanon Rd.
Mt. Juliet, TN 37122
ENVIRONMENTAL
[phone]
1-800-7-5859
SCIENCE CORP.
Fax. [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC.28138
December 01, 2006
L270234
Laboratory Blank
Analyte
Result
Units
Date Analyzed
Batch
pH
7.60
su
11/25/06
12:05
WG276803
Mercury
< .02
mg/kg
11/29/06
07:05
WG277049
Total Solids
0.00
%
11/29/06
09:57
WG277054
Aluminum
< 5
mg/kg
11/29/06
14:10
WG277095
Arsenic
< 1
mg/kg
11/29/06
14:10
WG277095
Barium
< .25
mg/kg
11/29/06
14:10
WG277095
Cadmium
< .25
mg/kg
11/29/06
14:10
WG277095
Calcium
< 25
mg/kg
11/29/06
14:10
WG277095
Chromium
< .5
mg/kg
11/29/06
14:10
WG277095
Copper
< 1
mg/kg
11/29/06
14:10
WG277095
Lead
< .25
mg/kg
11/29/06
14:10
WG277095
Magnesium
< 5
mg/kg
11/29/06
14:10
WG277095
Manganese
< .5
mg/kg
11/29/06
14:10
WG277095
Molybdenum
< .1
mg/kg
11/29/06
14:10
WG277095
Nickel
< 1
mg/kg
11/29/06
14:10
WG277095
Potassium
< 25
mg/kg
11/29/06
20:35
WG277095
Selenium
< 1
mg/kg
11/29/06
14:10
WG277095
Silver
< .5
mg/kg
11/29/06
14:10
WG277095
Sodium
< 25
mg/kg
11/29/06
20:35
WG277095
Zinc
< 1.5
mg/kg
11/29/06
14:10
WG277095
Kjeldahl Nitrogen, TKN
< 20
mg/kg
11/30/06
08:44
WG277167
Ammonia Nitrogen
< 5
mg/kg
11/29/06
12:32
WG277169
Nitrate
< 1
mg/kg
11/29/06
12:17
WG277200
Nitrite
< 1
mg/kg
11/29/06
12:17
WG277200
Phosphorus,Total
< 1
mg/kg
11/29/06
12:17
WG277200
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
pH
su
7.60
7.50
1.32
20
L270168-01
WG276803
Mercury
mg/kg
0.00
0.00
0.00
20
L270240-12
WG277049
Total Solids
%
90.9
91.2
0.328
20
L270234-01
WG277054
Aluminum
mg/kg
2390
1620
38.4
20
L270483-02
WG277095
Arsenic
mg/kg
32.2
22.3
36.3
20
L270483-02
WG277095
Barium
mg/kg
196.
151.
25.9
20
L270483-02
WG277095
Cadmium
mg/kg
458.
320.
35.5
20
L270483-02
WG277095
Calcium
mg/kg
33100
23300
34.8
20
L270483-02
WG277095
Chromium
mg/kg
4930
3400
36.7
20
L270483-02
WG277095
Copper
mg/kg
1480
1020
36.8
20
L270483-02
WG277095
Lead
mg/kg
8000
5580
35.6
20
L270483-02
WG277095
Magnesium
mg/kg
185000
130000
34.9
20
L270483-02
WG277095
Manganese
mg/kg
22000
15800
32.8
20
L270483-02
WG277095
Molybdenum
mg/kg
41.9
27.7
40.8
20
L270483-02
WG277095
Nickel
mg/kg
306.
225.
30.5
20
L270483-02
WG277095
Potassium
mg/kg
3300
0.00
NA
20
L270483-02
WG277095
Selenium
mg/kg
0.00
0.00
0.00
20
L270483-02
WG277095
Silver
mg/kg
45.5
32.0
34.8
20
L270483-02
WG277095
Sodium
mg/kg
7030
0.00
NA
20
L270483-02
WG277095
Zinc
mg/kg
74800
65300
13.6
20
L270483-02
WG277095
Kjeldahl Nitrogen, TKN mg/kg 343. 350. 1.89 20 L270539-01 WG277167
Page 2 of 6

12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fay [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28136 L270239 December 01, 2006
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp Batch
Ammonia Nitrogen
mg/kg
0.00
0.00 0.00
20
L270487-01 WG277169
Nitrate
mg/kg
11.1
11.8 6.11
20
L270547-01 WG277200
Nitrite
mg/kg
0.00
0.00 0.00
20
L270547-01 WG277200
Phosphorus,Total
mg/kg
92.3
89.3 3.30
20
L270547-01 WG277200
Laboratory
Control Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
pH
su
8.1
8.10
100.
85-115 WG276803
Mercury
mg/kg
11.7
9.47
80.9
66.4-133 WG277049
Total Solids
%
50
50.0
99.9
85-115 WG277054
Aluminum
mg/kg
6320
5960
94.3
57.9-142 WG277095
Arsenic
mg/kg
161
153.
95.0
79.5-120 WG277095
Barium
mg/kg
252
266.
106.
82.1-117 WG277095
Cadmium
mg/kg
128
131.
102.
81.3-118 WG277095
Calcium
mg/kg
3320
3380
102.
79.2-120 WG277095
Chromium
mg/kg
69.5
66.7
96.0
78.6-121 WG277095
Copper
mg/kg
148
154.
104.
82.4-117 WG277095
Lead
mg/kg
142
140.
98.6
80.3-119 WG277095
Magnesium
mg/kg
2040
2040
100.
77-123 WG277095
Manganese
mg/kg
408
400.
98.0
79.9-120 WG277095
Molybdenum
mg/kg
84.1
84.7
101.
79.3-120 WG277095
Nickel
mg/kg
147
136.
92.5
81.6-118 WG277095
Potassium
mg/kg
1920
1800
93.8
71.4-128 WG277095
Selenium
mg/kg
64.2
60.3
93.9
75.5-124 WG277095
Silver
mg/kg
130
129.
99.2
53-146.9 WG277095
Sodium
mg/kg
445
471.
106.
55.5-144 WG277095
Zinc
mg/kg
165
181.
110.
79.4-120 WG277095
Kjeldahl Nitrogen, TKN
mg/kg
1270
959.
75.5
60-140 WG277167
Ammonia Nitrogen
mg/kg
391
235.
60.2
50-150 WG277169
Nitrate
mg/kg
281
255.
90.7
81-119 WG277200
Phosphorus,Total
mg/kg
63.7
60.7
95.3
43-157 WG277200
Laboratory Control
Sample Duplicate
Analyte
Units
LCSD Res
Ref Res RPD
Limit %Rec
Batch
pH
su
8.10
8.10 0.00
20 100
WG276803
Kjeldahl Nitrogen, TKN
mg/kg
984.
959. 2.65
20 78
WG277167
Ammonia Nitrogen
mg/kg
289.
235. 20.3
20 74
WG277169
Nitrate
mg/kg
256.
255. 0.391
20 91
WG277200
Phosphorus,Total
mg/kg
60.6
60.7 0.165
20 95
WG277200
Matrix
Spike
Analyte
Units
MS Res
Ref Res TV %
Rec Limit
Ref Samp Batch
Mercury
mg/kg
0.246
0.00 .25
98.4 70-130
L270256-01 WG277049
Aluminum
mg/kg
1830
1620 5 420.
75-125
L270483-02 WG277095
Arsenic
mg/kg
69.2
22.3 5
93.8 75-125
L270483-02 WG277095
Page 3 of 6

ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality
Assurance Report
Level
II
Rockwell, NC 28138
December 01, 2006
L270234
Barium
mg/kg
196.
151.
5
90.0
75-125
L270483-02 WG277095
Matrix Spike
Analyte
Units
MS Res
Ref Res
TV
o Rec
Limit
Ref Samp Batch
Cadmium
mg/kg
403.
320.
5
166.
75-125
L270483-02 WG277095
Calcium
mg/kg
25800
23300
50
500.
75-125
L270483-02 WG277095
Chromium
mg/kg
3780
3400
5
760.
75-125
L270483-02 WG277095
Copper
mg/kg
1180
1020
5
320.
75-125
L270483-02 WG277095
Lead
mg/kg
6190
5580
5
1220
75-125
L270483-02 WG277095
Magnesium
mg/kg
142000
130000
50
2400
75-125
L270483-02 WG277095
Manganese
mg/kg
17000
15800
5
2400
75-125
L270483-02 WG277095
Molybdenum
mg/kg
76.7
27.7
5
98.0
75-125
L270483-02 WG277095
Nickel
mg/kg
288.
225.
5
126.
75-125
L270483-02 WG277095
Potassium
mg/kg
3730
0.00
50
746.
75-125
L270483-02 WG277095
Selenium
mg/kg
33.7
0.00
5
67.4
75-125
L270483-02 WG277095
Silver
mg/kg
66.8
32.0
5
69.6
75-125
L270483-02 WG277095
Sodium
mg/kg
7550
0.00
50
1510
75-125
L270483-02 WG277095
Zinc
mg/kg
66500
65300
50
240.
75-125
L270483-02 WG277095
Kjeldahl Nitrogen, TKN
mg/kg
508.
160.
400
87.0
80-120
L270539-03 WG277167
Ammonia Nitrogen
mg/kg
164.
0.00
250
65.7
80-120
L270547-01 WG277169
Nitrate
mg/kg
94.9
11.8
50
166.
80-120
L270547-01 WG277200
Nitrite
mg/kg
30.1
0.00
50
60.2
80-120
L270547-01 WG277200
Phosphorus Total
mg/kg
172.
89.3
50
165.
80-120
L270547-01 WG277200
Matrix Spike Duplicate
Analyte
Units
MSD Res
Ref Res
RPD
Limit %Rec
Ref Samp Batch
Mercury
mg/kg
0.215
0.246
13.4
20
86.0
L270256-01 WG277049
Aluminum
mg/kg
1530
1830
17.9
20
0.00
L270483-02 WG277095
Arsenic
mg/kg
60.7
69.2
13.1
20
76.8
L270483-02 WG277095
Barium
mg/kg
264.
196.
29.6
20
226.
L270483-02 WG277095
Cadmium
mg/kg
352.
403.
13.5
20
64.0
L270483-02 WG277095
Calcium
mg/kg
22400
25800
14.1
20
0.00
L270483-02 WG277095
Chromium
mg/kg
3200
3780
16.6
20
0.00
L270483-02 WG277095
Copper
mg/kg
1010
1180
15.5
20
0.00
L270483-02 WG277095
Lead
mg/kg
5360
6190
14".4
20
0.00
L270483-02 WG277095
Magnesium
mg/kg
122000
142000
15.2
20
0.00
L270483-02 WG277095
Manganese
mg/kg
14800
17000
13.8
20
0.00
L270483-02 WG277095
Molybdenum
mg/kg
65.2
76.7
16.2
20
75.0
L270483-02 WG277095
Nickel
mg/kg
251.
288.
13.7
20
52.0
L270483-02 WG277095
Potassium
mg/kg
3800
3730
1.86
20
760.
L270483-02 WG277095
Selenium
mg/kg
30.0
33.7
11.6
20
60.0
L270483-02 WG277095
Silver
mg/kg
70.1
66.8
4.82
20
76.2
L270483-02 WG277095
Sodium
mg/kg
7600
7550
0.660
20
1520
L270483-02 WG277095
Zinc
mg/kg
6.0700
66500
9.12
20
0.00
L270483-02 WG277095
Kj'eldahl Nitrogen, TKN
mg/kg
509.
508.
0.201
20
87.3
L270539-03 WG277167
Ammonia Nitrogen
mg/kg
197.
164.
18.3
20
78.9
L270547-01 WG277169
Nitrate
mg/kg
94.5
94.9
0.422
20
165.
L270547-01 WG277200
Nitrite
mg/kg
_
29.9
30.1
0.667
20
59.8
L270547-01 WG277200
Phosphorus,Total
mg/kg
171.
172.
0.583
20
163.
L270547-01 WG277200
Batch number /Run number / Sample number cross reference
WG276803: R298084: L270234-01
WG277054: R298482: L270234-01
Page 4 of 6

J0
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
WG277049: R298537: L270234-01
WG277095: R298572: L270234-01
WG277200: R298596: L270234-01
WG277167: R298618: L270234-01
WG277169: R298625: L270234-01
Quality Assurance Report
Level II
L270234
* * Calculations are performed prior to rounding of reported values
Page 5 of 6
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
December 01, 2006

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 L270234 December 01, 2006
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank --an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a "J6". The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 6 of 6

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail]
March 13, 2006
DENR/DWQ/Water Quality Section
Mr. Daryl Merritt,
Environmental Specialist I
Non -Discharge Compliance/Enforcement Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Mr. Merritt:
MAR 17 2006
EI"
AQ�RECEIVEDEP TROT DE-jj,,r QVVQ
f�qR VS,,,0rq
2006
Enclosed is the Monitoring and Reporting requirements for our permit.number
WQ0016338.
For the year of 2005, we used 1760 tons of silica residual from our on -site bauxite
digestion process as a fill material. I have included the Annual Residual Sampling
Summary forms ACF, RSSF AND RSSF —B. I have also included the lagoon sand
sample analysis.
Please let me know if you have any questions.
Best regards,
ALCHEM, INC
Wayne Drye,
Plant Manager
pcd
cc: Ms. Ellen Huffman,
Environmental Specialist
Mooresville Regional Office

f I r I ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0016338 County: ROWAN Year: 2005
Facility Name (as shown on permit): ALCHEM, INC
Land Application Operator: WAYNE DRYE, PLANT MANAGER Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
p Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit: 0
Total number of fields land application occurred during the year: 0
Total amount of dry tons applied during the year for all application sites: 0
Total number of acres land application occurred during the year: 0
Part B:
Facility was compliant during calendar year 2005 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. 0 Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
J. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was -performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as, specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
WAYNE D DRYE, PLANT MANAGER
Permittee Name and Title (type or print)
Signa0ure of Prep er* Date
(if different from Permittee)
` Preparer is defined in 40 CFR Part 503.9 (r)
Signature of Permittee Date
Signiture of Land Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338 Laboratory: 1) Environmental Science Corp
Facility Name: ALCHEM, INC 2)
NPDES # or 3)
WQ#:
4)
WWTP Name: 5)
Residual Analysis Data
• .• -sample - -
--M--
----------
MolybdenumPercent
®
1 • '
----—�---
Total Phosphorus
losses
Nitrate and Ki-t—rite
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
NULL'o,
Signat e of Prepare
'59 )6
Date
DENR FORM RSSF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number:
Facility Name:
NPDES # or
WQ#:
WWTP Name:
Residual Analysis Data
WQ0016338
ALCHEM, INC
Laboratory: 1) Environmental Science Corp
2)
3)
4)
5)
le or
Composite ,, Date
-----t
Potassium
11
111
----------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
& �&
Signa re of PreparOr
,3h0
Date
DENR FORM RSSF-B (5/2003)

ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 27,2006
ESC Sample # : L230526-01
Date Received
January 20, 2006
Description
NCDENH Lagoons
Site
ID
Sample ID
LAGOON SAND SAMPLES
Project #
WQ0016388
Collected By
Wayne Drye
Collection Date
01/18/06 08:00
Parameter
Dry Result
Det. Limit
Units
Method
Date
Dil.
Nitrate
BDL
1.1
mg/kg
9056
01/24/06
1
Nitrite
BDL
1.1
mg/kg
9056
01/24/06
1
Total Nitrogen
BDL
57.
mg/kg
Calc.
01/26/06
1
Ammonia Nitrogen
BDL
5.7
mg/kg
350.1
01/24/06
1
pH
7.7
su
9045C
01/21/06
1
Organic Nitrogen
BDL
57.
mg/kg
Calc.
01/26/06
1
Phosphorus,Total
3.2
1.1
mg/kg
9056
01/24/06
1
Kjeldahl Nitrogen, TKN BDL
57.
mg/kg
351.2
01/25/06
1
Total Solids
88.0
2540G
01/27/06
1
Mercury
BDL
0.023
mg/kg
7471
01/25/06
1
Aluminum
38000
28.
mg/kg
6010B
01/25/06
5
Arsenic
BDL
1.1
mg/kg
6010B
01/25/06
1
Barium
88.
0.28
mg/kg
6010B
01/25/06
1
Cadmium
BDL
0.28
mg/kg
6010B
01/25/06
1
Calcium
8500
28.
mg/kg
6010B
01/25/06
1
Chromium
3.0
0.57
mg/kg
6010B
01/25/06
1
Copper
4.2
1.1
mg/kg
6010B
01/25/06
1
Lead
39.
0.28
mg/kg
6010B
01/25/06
1
Magnesium
1800
5.7
mg/kg
6010B
01/25/06
1
Manganese
2.5
0.57
mg/kg
6010B
01/25/06
1
Molybdenum
1.9
0.11
mg/kg
6010B
01/25/06
1
Nickel
3.5
1.1
mg/kg
6010B
01/25/06
1
Potassium
1200
140
mg/kg
6010B
01/25/06
5
Selenium
3.0
1.1
mg/kg
6010B
01/25/06
1
Silver
BDL
0.57
mg/kg
6010B
01/25/06
1
Sodium
1000
140
mg/kg
6010B
01/25/06
5
Zinc
3.0
1.7
mg/kg
6010B
01/25/06
1
J y Hunt,
ESC Representative
Results listed are
dry weight basis.
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Laboratory Certification
Numbers:
AIHA - 100789, AL - 40660, CA - I-2327, CT-
PH-0197, FL
- E87487, GA - 923,
IN - C-TN-01
KY - 90010, KYUST
- 0016, NC - ENV375,DW21704, ND
- R=140, SC
- 84004, TN
- 2006,
VA - 00109, WV
- 233
AZ -0612, MN - 047-999-395, NY -
11742, NJ -
81002, WI -
998093910
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 01/27/06 10:11 Revised: 01/27/06 10:47
Page 1 of 7
J

Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte Qualifier
L230526-01 Arsenic J6
Calcium VJ3
Magnesium V
Molybdenum J6
Ammonia Nitrogen J6
Phosphorus,Total J6
Page 2 of 7

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
V (ESC) - Additional QC Info: The sample concentration is too high to
evaluate accurate spike recoveries.
J3 The associated batch QC was outside the established quality control range
for precision.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to,samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ) (SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 68-128 64-125
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 76-115 69-118
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromofluorobenzene 79-127 61-134
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 3 of 7

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L230526
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 27, 2006
I a xa Cry ;laft
Analyte Result Units Date Analyzed Batch
PH; ......:: 5 ;80 :......... stt Q1/i/06..16. 15........ WG23aS03..........:. ... ..........
Ammonia Nitrogen < 5 mq/kca 01/24/06 11:45 WG235738
Aluminum
< 5
mg/kg
01/25/06
02:58
WG235750
Arsenic
< 1
mg/kg
01/25/06
02:58
WG235750
Barium
-
;:.25.
:'"::>`:;::<::<:;;;;::.:>;1?5/:......:.:::.:.:>Q1J25/D6
:: :<:
. 02.5 ::::::.
::::>:::.....
WG23 7 0:.....:::.::;::;::r:........
.::::...:: .
Cadmium
< .25
mg/kg
01/25/06
02:58
WG235750
Calcium
< 25
mg/kg
01/25/06
02:58
WG235750 .
Chromium.;: _
<::::::>5 :::;:::>::>::,::
m k .........01
.25 ;06
Q2 58
WG23575
:.
Copper
< 1
mg/kg
O1/25/06
02:58
WG235'50
Lead
< 25
m k
g 5
01/25/06
02:58
WG235750
Magnesium _, ..:.: >.....
c 5
.............
...
Ctg{kg
Oa/2/06..0:2.
5$.........
W23750......
Manganese
< .5
mg/kg
O1/25/06
02 58
WG235750
Molybdenum
Y
< .1
mg/kg
01/25/06
02:58
WG235750
:..
__k........_ ................ ......
:>:».... >'>`'
m ::k
01 .2.5.'<06
_ ...../.
.;0:2>:58.....................
.WG�^35ZSU
_ ......._ ...........................
>::.:.::«:;::.;.>;.; : :
Potassium
< 25
m /k
O1/25/06
15:05
WG235750
Selenium
< 1
mg/kg
01/25/06
02:58
WG235750
Silver..::....:.:
< ?........
mg/..k<J ......
Q1.1 5/06.
0..... 5g.......
WG235750......
Sodium
< 25
mg/kg
0]/25/06
15.05
WG235750
zinc
< 1.5
mg/kg
01/25/06
02:56
WG235750
Nitrate
< 1 . • ........
.
...........01/2.4/06..
mg/kg
00 :..00 .............WG235793....:.
Nitrite
< 1
mg/kg
01/24/06
00 00
WG235793
Phosphortiis,Total
..<...
m9%k5.......
1/2 /D6
OD 4a......
WG2 7.93:...
Kjeldahl Nitrogen, TKN
< 50
mg/kg
01/25/06
13:00
WG235904
Total.Soiids>::»>.................................................
..................... .....s>::>:;0.<00:...........::...b1'.2.7.::06`
083:2....'siir.WG235940
.... ..........
...
Mercury -<
mg/:kg
61J25./06
. 17:;.5�iWG235979
..
...'­Up.:ate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
.; .:
sil.::.;:::.::;
:::>::::4'::'SO.:,
4::6fl::>:>::::
2':20::>::::.;;:2::.::;;<:::;::;:::«:>:.>::
2 0 19 :03::::
WG235...
pH
su
4.50
4.50
0.00.........20.........
L230419-04
WG235503
Ammonia :::Nitrogen »
mg/kg....
..! O ..QO:.
:0 • p0:..
.: 4;.00..
20 ..
L23070'Q::41.....WG235'73.'8.r
Arsenic
mg/kg
0.00
0.00
0.00
20
L230526-01
WG235750
B ri m
.h2`
.3052'6 <012357:5i0:
Cadmium
m mg/kg .......:
0.0:0:::::
0 0..0.:::::.:::::.::::.0".0:0::.::2:0
:::
L230526-.0.1:.:.::
WG23.5.7.5.6.
Calcium
mg/kg
9280
7500
21.2
0
L230526-01
WG235750
ma u
g .1Gg::::::•::::a
::::.:.
:.::2 7U....
:::::: 6
.:<23Q526..07
Copper
mg/kg
3.37
3.70
..:.:::...::::Q::
9.34
20
L230526-01
WG235750
Lead
mq/kq
30.9
34.0
9.55
20
L230526-01
WG235750
Manganese
mg/kg
2.92
2.20
28.1
20
L230526-01
WG235750
Molybdenum
mg/kg
1.63
1.70
4.20
0
L230526-01
WG235750
Nickel ,:...:::.
::;;:.:.:.....:.:.m :.k >:;;:..
.., $; ::;:<:::;:::;:::::,3:Y
� 0....::::::
:......2..........:
26 Qk`
3S750
Selenium
mg/kg
2.52
2.70
6.90
20
L230526-01
WG235750
Silver
mg/kg
0.00
0.00
0.00
20
L230526-01
WG235750
Zinc :: ?
:>k:<:::>::>::7..32...;70..
g .:.:: .:::::.:.:.:.....
'«:;:.92';2.::Q.;<:<':.::
.......
:723 26 O1....
... ................
2387>5i6:
Kjeldahl Nitrogen, TKN
mg/kg ..........0...-..00
0.00
0.00
20
1230526-01
WG235904
Tota1Solids:::>:::.........................
....................... 96...:::......;>
»::8:7.:>8:>:::......>::::>::::8:8£.,:0:::.........:>::>:0::::1<8:4:::>::::<Z:O::?:<<........
i:::>:::LZ::<:::>5:2>9:_< :<:»::::Td>
30 0
>.>.::>>4;:<:>
G 359 0
:T abora'tcir Control;»��:ample
Page 4 of 7

ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level
II
Rockwell, NC 28138
January 27, 2006
L230526
Analyte
Units
Known
Val Result
Rec
Limit Batch
PH;`: .:.
.>: su.:;;.:..;...........9:........>:':
$ '8,0
...................
96 0 .
.................. .............................
85 115 WG23:;55:0:3.....;i:>
.........................
Ammonia Nitrogen._..................-...._
_....................Tn9�k9............3.05.......................230.r......................
75.0
50-150 WG235738
Aluminum
mg/kg
7090
6770
95.0
57.8-142 WG235750
Arsenic
mg/kg
187
171.
91.0
72-128 WG235750
.:::.....:.:.::.
;...............:;::;>::>
B.arium:;....:>.:::...:..:;:>:.:.:::.:.:::::::.::..:::::::....:::::.:....:.:::::...:.::::::...._:::::m
:.:..::. .:...:...::....., ..:..:::.::............,
:. ;:.>:::»: .:.:.. ;>:<.>:;:::•
L..k.::.:::.:.::2...8...........:.:::..:::::...3......:..:........:...:........:........................................................................................
• 2
.;;;;;:.;:;::; ::::::::..:::::::.:::
2 2 .::... >::::i:>:
::::>:::»::. -1 :.............:7
2.....W
5 0... > ::
_............................................................................5.....9......................................................................................................................................................................
Cadmium
m /kg
125
121.
9.7.0
80.8-119 WG235750
Calcium
mg/kg
3700
3460
94.'0
66.8-133 WG235750
Chromium <: :.::::.;;:;::>:::::.
:;
.>::::<; m9/..kg.:::::::::::1.....:..:.....:.........:::::7
I2...::::.;>«:>'::<:>::>
::;:;:: ;;::::>::;: ;:<::;..
.7..7:,.:::::.::::.::::::::::.:::::::...........:
;:>::.>:;.. 104
79 -120 WG 3:5750..
5::.........::.::.... 2.......
. _..............:....::..:.::::::.:.:..........:..:::.:.:::.::::..:................................
Copper
mg/kg
90.1
86.8
96.0
_..:.........:.
80.4-119 WG235750
Lead
mg/kg
152
144.
95.0
78.6-121 WG235750
...:.:.:............:.........::. ..........
Ma' nesium..::.,::::'':<:>.>::<:<>::in
.
k.;::`;•:..2:23.b::>>::>:><:<:6:.
`''::<'>:>::'::`:'.'?`:::93:'0:>:::<:`72<6=72:7:..C�1G2:3:TS.O......;::.
Manganese
mg/kg
284
280.
99.0 .79.7-120
WG235750
Molybdenum
WG235750:::::::.::
...................................................................................mg/kg
Nic a ... :-
k 1........................
............7.8...8.......................73....9................................94...�............78...2..-.121
: ;::<<.. <:::>:::<::;:. m ..k ............6.6...5....
Jl....5..................................................................
»::>
:.:... ,: i;>::
55 _ 3..::......:::::::::»......::::>9.8::0::>
; ?s::
7:.. G2 :5 0
77..,......122...W 3. 75 <::
.:::.:.::::::::::::..::.:..::::::....
Potassium
mg/kg
2140
-................................................................................................
1940
91.0
-.......
71.0-128 WG235750
Selenium
mg/kg
163
153.
94.0
65.6-134 WG235750
Silver. ...
............... _ _..........,....................................................:...........
:> . :%::,m ..::k.:>:::>.:.125..:::<:''....::?:::.:>:::132:
/....
9..... J.::::::::::::.::::.::::::..........:::::::::.::::..:.
;..:::>:::>:':<:::>::::'::..1
X..:.X.::::::::::::
::....;`>:::>:::>q9::2.
15.:0;.4tG2:35750...
Sodium
mg/kg
816
736.
90.0
,:.::::::::.:::::: :
55.6-144 WG235150
Zinc
...........m9/k9...........232
212.....................................9.1..0.....
46.1-153 WG235750
......................_.__.......-.......................................
Nitrate
m s::::k.
9/ 9
:« 3
<'>s`..14iz:;>...............::»»s
:0<;:»:........................;::
3
>:g:9< 0::::»:::::<::
7:5:> 5> < s24WG235793 :::....
Phosphorus,Total
mg/kg
52.7
67.0
127.
50-150 WG235793
... ,.;
Kjeldahl Nltrogen, TKN
.. :.....::::...:.:
mg/'kg
:<:3»2 :<i ..............;»>:>:7::>::0
8 0
:::z:.......................;;
8
:>:::9:5 :>:0:::::5:8:_<1:4:1:......
WG2:3:5:9:0:4:....:....
Total So..ilds. ..
%
50 , .:......::.........
5Q:?:,;;;:.;..:.;>;::.::.......;.:;;:10::::.::::.:
85.,115 WG23:594........ ........
Mercury
mg/kg
ll.7
13.2
113.
66.4-133 WG235979
Laboratory Coitrr�l Sample Dupl�Cate ,
Analyte
Units
LCSD Res
Ref Res RPD
Limit %Rec
Batch
p H:::.u:::>:<:::;:::<:::::.8..:80...:::::>::::>::::.8:::8.0............O.:Q9::::>::::>::;24):;r>":r`:':>':::WG235503
.. .
:::
Ammonia Nitrogen
mg/kg
240.
230. 4.26
20 79
WG235738
......
Ni,trate:
.iiiii
..........
mg/kg
;':::ii:ii
i::i
!i:ii:iiii
3<0.0.
:i :iiiii
iii:ii iii;i::iiiii
C
3.28
310. :
siii;°::i i
iii [
i�`
i
20 96
:>i ii;i3 :''<'G.. ;-:
:ii
`': `i%C%;s;i;
ii....
WG235793
Phosphorus,Total...................................................................mg/kg
......70.-.0...............67.0
4.38
20 133
WG235793
Kjeldahl Nitrogen, TKN
mg/kg
710.
780. 9.40
20 87
WG235904
Total::Soklds -..
. ;; :.:...
0
50 .......,..
5 : 2:.;:::<:< >: O . h 9:
ti.........X-X,:,. .. .:. :9
2 0'.::: '.::< <:::> : p 0 .;::>>:>::>:`
WG2 3:5:9.4 0.
Analyte
Units
MS Res
Ref Res TV
% Rec Limit
Ref Samp Batch
_,....
Ammonia zNltro en
m k
360
b...0.0:::5:>`500:>>:>::
72 0<:€>80=12b
L230526. 01 WG23573:8:
Aluminum
mg/kg
29500
33000 10
0.0 75-125
L230526-01 WG235750
Arsenic:.
m9. 9....34...0....
O.:.OQ....50
?.8::.0
Barium
mg/kg
121.
.... .........
77.0 50
.......................................
88.0 75-125
...5:
L230526-01 WG235750
Cadmium
mg/kg
45.9
0.00 50
92.0 75-125
L230526-01 WG235750
Calcium, >:......::.
....... m9 k9..44s
7500<' ? SOO:i:...;;''.
398:::; 75 125
L230526 01 WG235750,
... .:...:.
Chromium
.....
mg/kg
..
48.6
2.70 50
92.0 75-125
L230526-01 WG235750
Copper
WG235750
................................................................................m9/kg.....50..z..................3...70.........50.................93..0....75-125
Lead »
..
....:.::>::::.;..: m :k ;
9/...g
..::72 .3
::: ..:.:...:::::.
;:<34:::.0.:..;: ;::50::::.::;>::
77 , 0 .75:.a25
...L230526-01
1,2305>26: Ql WG23575.0::
Magnesium
........... ................................
mg/kg
2470
1600 500.
174. 75-125
.... ..
L230526-01 WG235750
Manganese
mg/kg
50.0
2.20 50
96.0 75-125
L230526-01 WG235750
Mol: bcienum
m k
38 7
1 .7(} 50
74..0 75 325
:.::..:::::....:.......:.:.:::::.::.::.::::::::::::::.::.::.:......:...:...........:..:.
L230526 U Y�G23575::0.:
Nickel
mg/k4
49.0
3.10 50
92.0 75--125
L230526-01 WG235750
Page 5 of 7

N
ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Rockwell, NC 28138
Quality Assurance Report
Level II
L230526
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 27, 2006
Potassium mq/kq 1340 980. 100 72.0 75-125 L230526-01 WG235750
Ii atr'k' Spikes:
Analyte
Units
MS Res
Ref Res
TV.
% Rec
Limit
Ref Samp Batch
Selena um:.. ..........:.:;:.;..;..:;::::._ >...::.;:::.......:...........gi....5.......................................................................................................
...:.......m :k :::>
.41ai::<:;:.;:.:>:a::::>::>:>2>;:..7.:0.:.:.:
50 .. .....77,.Q:::75z:725
:::;T;2305xxxx,26:-.Uh;;IG2357S:0:<
.................... .
.:..::. ......:.;;
Silver
mg/kg
47.9
0.00
50
96.0
75-125
L230526-01 WG235750
Sodium
mg/kg
1270
460.
100
162.
75-125
L230526-01 WG235750
Zinc _:;:
:. k :::>:<::::8:5:
.. •. •;:::; • . mg/:...g..::::.::.
;0<::::;:`
;.. 2'. 7 0.::: <::;:>50:..:>»::>::>::>::10
..
>:::
::7:5'.:.12::::::>:::
3 2 07 G. 5-
Nitrate
mg/kg
53.0
0.00
50
106.
80-120
L230526-01 WG235793
Nitrate
:.. m >..iC ......54...:0...
g/....g..............
] 80 .....;50
......
.......
041:Q:>;230577
....80-120
.............
.
7 8• .WG235793::
Nitrite...................................................................................
m9/kg
53.0
0.00.......5.0
106.
L230526-01 WG235793
PhosP horus,Total
mg/kg
25.E
2.60
50 ..................44.0
80-120
L230526-01 WG235793
Kjeldahl Nitrogen,T
g/ g
-
- .....4:
s?:2<307:51:-0<1>:WG23590
...
MercurY:.;> .....; . ..::::::.....::
:: :..........: ....::::::.
0.>..063.0....
25 ........
92 <::0
70 .7 30
L23058;5: 02 :41G235979:
?a' k P2k ?:uplz�:a....
Analyte
Units
MSD Res
Ref Res
RPD
Limit %Rec
Ref Samp Batch
Ammonia.:Nitrogen .:
zng/kg.•.36U
..........
360;:. ..........
O..Qfl
20....,.,
72. 0..•.•..E,230S26
O..WG235738 .
Aluminum
mg/kg
32200
29500
8.75
20
0.00
L230526-01 WG235750
::::..:;;
sende.:.:;.;....::....:::....:::.:::::::......:..:::>;;..........:.........................
:. >;;;::. . k ....
2.....:.
:
... .>:. ;:
:.37.:.....::2.0....::::::..::.:0....Q?..:........3Q.........0............2.5......
. ;: >
.;>;
;: .?
::» L2 2 6.:. 1. , WG2 7:5:0
Barium
mg/kg
130.
121.
7.17
20
106.
L230526-01 WG235750
Cadmium
mg/kg
47.2
45.9
2.79
20
94.0
L230526 01 WG235750
Calcium :....:.
mg/1g..8950........
9494
5... ..
:0.
290..
.. .L23 .... 1.WC�23:575;.0
...:::.
Chromium
mg /kg
49.8
48.6
2.44
20
94.0
L230526-01 WG235750
Copper
mg/kg
52.1
50.2
3.71
20
97.0
L230526-01 WG235750
L ad,:.......:>.... _.::.... _ ..:: ;:;:::;>;.:::::»:.;
...::.m ..k ::.:::78..?:::::::
?2::3:•;:::.::.::;:::::4g
20....
....89:::0.>::>:>::>::L23:0�26.Q1.;:NFG235750
- .... .
Magnesium
mg kg
2250
2470
9.32
20
130.
L230526-01 WG235750
Manganese
mg/kg
50.0
50.0
0.00
20
96.0
L230526 Ol WG235750
Molybdenum
....zng/.1.......37
3.......
3:...7........
..<::>3:: 68.
20.,
7J sa:';:
>: i1230526...t1 WG235750
Nickel
mg/kg
50.8
49.0
3.61
20
95.0
L230526-01 WG235750
Potassium
mq/kq
1380
1340
2.94
20
80.0
L230526-01 WG235750
Silver
mg kg
48.8
47.9
1.86
20
98.0
L230526-01
WG235750
Sodium
mg/kg
1240
1270
2.39
20
156
L230526 01
WG235750
....../g56:
4 ...
... 55.: 0........
.. 2, 51 •
....2'0,...:..
1Q7,.
L. 30526 91..•WG23.5.7;50
Nitrate
mg/kq
53.0
53.0
0.00.
20
106
L230526 01
WG235793
Nitrate::':..
mg/k9.....5...:'I.
4<: ..:...
:9 i31..
:0
116:....
26 b:?...WG235793
. . ..;
Nitrite
mg/kg
.....::>>
53.0
53.0
0.00
..: ...:
20
106.
...L23.0.
L230526-01
WG235793
Phosphorus,Total
mg/kg
25.0
25.0
0.00
20
44.0
L230526 01
WG235793
Kjeldahl Nitrogen, TKN
mg/kg
690.
400.
53.2
20
240.
L230751-01
WG235904
Mercur
.
:;:;::.:>::>::>:>::::.:::.>: m :<k.::.
...... ..............................
3 01;>:>:>::<:::>:0::.2
93.:;>;:>;::>z:2
................................
>:::>:::::.:>::> .
-:6:9 .....?.0
.
:.:::.
9.5:; 0.:...:
LZ 3 Q 8 5 D 2
WG2 3 5.9 7:9
Batch number /Run number / Sample number cross reference
WG235503: R262558: L230526-01
WG235738: R262742: L230526-01
WG235793: R262846: L230526-01
WG235750: R262898: L230526-01
WG235979: R263012: L230526-01
WG235904: R263068: L230526-01
WG235874: R263101: L230526-01
WG235876: R263103: L230526-01
WG235940: R263143: L230526-01
* * Calculations are performed prior to rounding of reported values
Page 6 of 7

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 January 27, 2006
L230526
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the "B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a 11J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a 11J5" or a 11J611. The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a 11J3" qualifier.
Page 7-of 7

ENVIRONMENTAL
SCIENCE CORP.
REPORT OF ANALYSIS
Ms. Phyllis Drye
Alchem, Inc.
8135 Red Road
Rockwell, NC 28138
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
March 03,2006
ESC Sample #
L234332-01
Date Received February 21, 2006
Description NCDENH Lagoons
Site ID
Sample ID LAGOON SAND SAMPLES
Project #
WQ0016388
Collected By Wayne Drye
Collection Date 02/20/06 08:00
Parameter Dry
Result
Det. Limit
Units
Method
Date
Dil.
Nitrate
BDL
1.1
mg/kg
9056
02/24/06
1
Nitrite
BDL
1.1
mg/kg
9056
02/24/06
1
Total Nitrogen.
BDL
1.1
mg/kg
Calc.
03/02/06
1
Ammonia Nitrogen
BDL
5.5
mg/kg
350.1
03/03/06
1
pH
8.1
su
9045C
02/22/06
1
Organic Nitrogen
BDL
0.55
mg/kg
Calc.
03/03/06
1
Phosphorus,Total
BDL
1.1
mg/kg
9056
02/24/06
1
Kjeldahl Nitrogen, TKN
BDL
55.
mg/kg
351.2
02/26/06
1
Total Solids
91.4
8
254OG
03/01/06
1
Mercury
0.023
0.022
mg/kg
7471
02/28/06
1
Aluminum
34000
5.5
mg/kg
6010B
02/27/06
1
Arsenic
BDL
1.1
mg/kg
6010B
02/27/06
1
Barium
76.
0.27
mg/kg
6010B
02/27/06
1
Cadmium
BDL
0.27
mg/kg
6010B
02/28/06
1
Calcium
11000
27.
mg/kg
6010B
02/26/06
1
Chromium
20.
0.55
mg/kg
6010B
02/27/06
1
Copper
3.7
1.1
mg/kg
6010B
02/27/06
1
Lead
26.
0.27
mg/kg
6010B
02/27/06
1
Magnesium
2500
5.5
mg/kg
6010B
02/27/06
1
Manganese
3.7
0.55
mg/kg
6010B
02/27/06
1
Molybdenum
0.46
0.11
mg/kg
6010B
02/27/06
1
Nickel
2.6
1.1
mg/kg
6010B
02/27/06
1
Potassium
1000
27.
mg/kg
6010B
02/24/06
1
Selenium
2.1
1.1
mg/kg
6010B
02/27/06
1
Silver
BDL
0.55
mg/kg
6010B
02/27/06
1
Sodium
600
27.
mg/kg
6010B
02/24/06
1
Zinc
6.1
1.6
mg/kg
6010B
02/27/06
1
� mmy H
t, ESC Representative
Results listed are dry weight basis.
(/
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Laboratory
Certification Numbers:
AIHA - 100789, AL - 40660, CA -
I-2327,
CT- PH-0197, FL -
E87467,
GA - 923,
IN - C-TN-01
KY - 90010, KYUST - 0016, NC - ENV375,DW21704,
ND - R-140, SC -
84004,
TN - 2006,
VA - 00109, WV
- 233
AZ -0612, MN - 047-999-395, NY -
11742, NJ - 81002,
WI-.998093910,
IL-200008
Note:
This report shall not be reproduced, except in full, without the written approval from ESC.
The reported analytical results relate only to the sample submitted
Reported: 03/03/06 17:27 Printed: 03/03/06 17:27
Page 1 of 7

Attachment A
List of Analytes with QC Qualifiers
Sample # Analyte Qualifier
L234332-01 Aluminum
V
Arsenic
76
Calcium
V
Magnesium
V
Molybdenum
J6
Potassium
J3
Selenium
J6
Page 2 of 7

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
J3 The associated batch QC was outside the established quality control range
for precision.
J6 The sample matrix interfered with the ability to make any accurate
determination; spike value is low
V (ESC) - Additional QC Info: The sample concentration is too high to
evaluate accurate spike recoveries.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
unless qualified as 'R' (Rejected).
Definitions
Accuracy - The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
Control Limits (AQ) (SS)
2-Fluorophenol 31-119 Nitrobenzene-d5 43-118 Dibromfluoromethane 68-126 64-125
Phenol-d5 12-134 2-Fluorobiphenyl 45-128 Toluene-d8 76-115 69-118
2,4,6-Tribromophenol 51-141 Terphenyl-d14 43-137 4-Bromofluorobenzene 79-127 61-134
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 3 of 7

12065 Lebanon Rd.
0 Mt. Juliet, TN 37122 (615)758-858
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 03, 2006
L234332
".'Laboratory Blank.
Analyte
Result
Units
Date Analyzed
Batch
PH
5.60
su
02/22/06
1545
WG239538
Aluminum
< 5
mg/kg
02/27/06
04:31
WG239919
Arsenic
<01
mg/kg
02/27/06,:04:31
WG239919.
Barium
< .25
mg/kg
02/27/06
04:31
WG239919
Cadmium
< 25
mg/kg
02/27/06
04:31
WG239919
Calcium
<, 25,
mg./kg,.,;
02/28/.0�6.
20;,18
'WG239919
Chromium
< .5
mg/kg
02/27/06
04:31.
_
WG239919
Copper
< 1
mg/kg
02/27/06
04:31
WG239919
Lead
< .25:
mg/kg -
WG239919
Magnesium
< 5
. ..02/27./06,'04,:31
mg/kg
02/27/06
..
04:31
WG239919
Manganese
< .5
mg/kg
02/27/06
04:31
WG239919
Molybdenum
<".1
mg/kg:.
02/27/06:04.::31
WG239.919
Nickel
< 1
mg/kg
02/27/06
04:31
WG239919
Potassium
< 25
mg/kg
02/24/06
14:30
WG239919
Selenium
< 1
mg/kg:': .,02/27/06
.04:31
WG239919
Silver
< .5
mg/kg
02/21/06
04:31
WG239919
Sodium
< 25
mg/kg
02/24/06
14:30
WG239919
Zinc
<:1.5:.,.
=;'mg/.kg.:':•.
,02/2.7/06_'04:31
WG239.919.'
Kjeldahl Nitrogen, TKN
< 50
mg/kg
02/26/06
15:00
WG239960
Nitrate
< 1
mg/kg
02/24/06
00:00
WG2�39964
Nitrite
< 1
mg/kg
02/24/06
00:00
WG239964
Phosphorus,Tota1
< 1 ..
mg/kg .02/2440,6
00:00
WG239964.
Mercury
< .02
mg/kg
02/28/06
01:06
WG240349
Total. Solids
0.00
%
03/01/06
09:53
WG240432
Ammonia Nitrogen
< .1
mg/1
03/03/06
08:25
WG240586
Duplicate
Analyte
Units
Result
Duplicate RPD
Limit
Ref Samp
Batch
PH
- su
8•40
8,50
:1.18:'
_;20:.
L234179-13__WG239538
PH
su
7.56
7.40
1.34
20
L234179-14
WG239538
Cadmium
mg/kg
0::00_:
0.00,
; 0.00
20
L234332-01
',WG239919
Calcium
mg/kg
9300
9800
5.24
0
L234332-01
WG239919
Potassium
mg/kg
1210
890.
30.5
20
L234332-01
WG239919
Sodium
mg/kg
:638:-...,.'„.';470:
.30:.3
20, _,
L234332-01'WG239,919
Kjeldahl Nitrogen, TKN
mg/kg
0.00
0.00
0.00
20
L234332-01
WG239960
Kjeldahl Nitrogen, TKN
mg/kg
780.
990::.
23.8
20
L234509-01
WG239960
Phosphorus,Total
mg/kg
0.00
0.00
0.00
20
L234018-09
.WG239964
Total Solids
%
81.6
81.4
0.215
20
L234915-01
WG240432
Ammonia Nitrogen
mg/1
158.
150.
4.92
20
L23.5225-01
WG240586
Laboratory.Control
Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
PH
su
9
8.80
98.0
85-115 WG239538
Aluminum
mg/kg
7090
7470
105.
57.8-142 WG239919
Arsenic
mg/kg
187.
176.
94.0
72-128 WG239919.
Barium
mg/kg
228
234.
103.
75.4-125 WG239919
Page 4 of 7

12065 Lebanon Rd.
0 (15)75- 5 8
Mt. Juliet, TN 37122
ENVIRONMENTAL 16800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 03, 2006
L234332
Cadmium mg/kq 125 118. 94.0 . 80.8-119 WG239919
.Laboratory,Control
Sample
Analyte
Units
Known
Val Result
% Rec
Limit Batch
Calcium
mg/kg
3700
3900:'
105.' .
66.8-133.WG239919
Chromium
mg/kg
112
108.
96.0
79.5-120 WG239919
Copper
mg/kg
90.1
89.5
99.0
80.4-119 WG239919
Lead
mg/kg
152
150.
99.'0
78.6-121 WG239919
Magnesium
mg/kg
2230
2170
97.0
72.6-127 WG239919
Manganese
mg/kg
284
285.
100.
79.7-120 WG239919
Molybdenum
mg/kg
.78.8
.78.3
-99.0..
78.2-121.WG239919.-
Nickel
mg/kg
66.5
63.8
96.0
77.7-.122 WG239919
Potassium
mg/kg
2140
2160
101.
71.0-128 WG239919
Selenium
mg/kg
163'
156.
96.0
65.6-134 WG239919,
Silver
mg/kg
125
132.
106.
49.2-150 WG239919
Sodium
mg/kg
816
862.
106.
55.,6-144 WG239919
Zinc
mg/kg',,-
.232
:. 202.
87.0` '46.17153
WG239919
Kjeldahl Nitrogen, TKN
mg/kg
1270
1150
90.0
58-141 WG239960
Nitrate
mg/kg
314
280.
89.0
75.5-124' WG239964
Phosphorus,Total
mg/kg
52.7
59.0
112.
50-150 WG239964
Mercury
mg/kg
11.7
10.1
86.0
66.4-133 WG240349
Total Solids
5,0,. -
,:, 50,.2 ;.;
100
857115 '.;WG240432
Ammonia Nitrogen
mg/1
7.5
403.
5380
85-115 WG240586
.Laboratory Control'Sample
Duplicate'
Analyte
Units
LCSD Res
Ref'Res RPD
Limit %Rec
Batch
PH
su
8.90
8:.80 1.13
20 99
WG239538
Kjeldahl Nitrogen, TKN
mg/kg
1100
1150 4.01
20 87
WG239960
Nitrate
mg/kg
280.
280. 0.00
20 89
WG239964
Phosphorus,Total
mg/kg
59.0
59.0 0.00
20 112
WG239964
Ammonia Nitrogen
mg/1
401.
403. 0.508
20 5350
WG240586
Matrix
Spike
Analyte
Units
MS Res
Ref Res TV
8 Rec Limit
Ref Samp Batch
Aluminum
mg/kg
33900
31000 50
5800 75-125
L234332-01 WG239919
Arsenic
mg/kg
33.4
0.00 50
67.0 75-125
L234332-01 WG239919
Barium
mg/kg
119.
69.0 50
100. 75-125
L234332-01 WG239919
Cadmium
mg/kg.
51.8
0.00 . 50,
104. 75-125
L234332-01 WG239919
Calcium
mg/kg
9580
9800 500
0.0 75-125
L234332-01 WG239919
Chromium
mg/kg
65.3
18.0 50
95.0 75-125
L234332-01 WG239919
Copper
mg/kg
52.4
3.40 50
98.0 75-125..L234332-01.WG239919
Lead
mg/kg
69.9
24.0 50
92.0 75-125
L234332-01 WG239919
Magnesium
mg/kg
2100
2300 500
0.0 75-125
L234332-01 WG239919
Manganese
mg/kg
50.2
3.40 50
94.0.75-125
L234332-01 WG239919
Molybdenum
mg/kg
35.8
0.420 50
71.0 75-125
L234332-01 WG239919
Nickel
mg/kg
47.4
2.40 50
90.0 75-125
L234332-01 WG239919
Potassium
mg/kg'.1500.:
,..890..
500 :122.
"75=125
L234332-01 WG239919
Selenium
mg/kg
38.9
1.90 50
74.0 75-125
L234332-01 WG239919
Silver
mg/kg
46.8
0.00 50
94.0 75-125
L234332-01 WG239919
Sodium
mg/kg;1020
470.`y 500
110. 75-125,
L234332-01 WG239919
Zinc
mg/kg
47.5
5.50 50
84.0 75-125
L234332-01 WG239919
Kjeldahl Nitrogen, TKN,
mg/kg.4030
:;.;:
.10000. 200 .,
:,. 0.0 80-120
L233871-01"WG239960
Page 5 of 7

12065 Lebanon Rd.
Mt. Juliet, TN 37122
615)758-5858
ENVIRONMENTAL 1-800-767-5859
SCIENCE CORP. Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Alchem, Inc.
Ms. Phyllis Drye
8135.Red Road Quality Assurance Report
Level II
Rockwell, NC 28138 March 03, 2006
L234332
Matrik ,'Spike;,,;
Analyte
Units
MS Res
Ref Res
TV
% Rec
Limit
Ref Samp
Batch
Mercury
mg/kg:
0.240....
0'00'.'•:25<
-:96
0
707130
'L234674-.16.WG240349
Mat rix'Spike..:-Dupl,icate;'
Analyte
Units
MSD Res.
Ref Res
RPD
Limit %Rec
Ref Samp
Batch
Alumipum
-mg'/kg'
37700: .".
33900
10.6
-" 20
--.•13400
1;234332-01.
WG239919
Arsenic
mg/kg
36.4
33.4
8.60
20
73.0
L234332-01
WG239919
Barium
mg/kg
125.
119.
4.92
20
112.
L234332-01
WG239919
Cadmium
mg/kg'
52.4.
:51.8
1.15.
20
105.
L234332-01
WG239919
Calcium
mg/kg
10000
9580
4.29
20
40.0
L234332-01
WG239919
Chromium
mg/kg
70.3
65.3
7.37
20
105,
L234332-01
WG239919
Copper
mg/kg
55.0
52.4
4.84.
20'
103.
L234332-01
WG239919
Lead
mg/kg
74.,8
69.9
6.77
20
102.
L234332-01
WG239919
Magnesium
mg/kg
2090
2100
0.477
20
0.00
L234332-01
WG239919
Manganese
mg/kg
5.0.3
50.2:
0'199
.20
99.0
1,234332-01.WG239919
Molybdenum
mg/kg
37.0
35.8
3.30
20
73.0
L234332-01
WG239919
Nickel
mg/kg
50.4
47.4
6.13
20
96.0
L234332-01
WG239919
Potassium
mg/kg-1620'
1500
7-..69
20
146.
L234332-01-WG239919
Selenium
mg/kg
40.2
38.9
3.29
20
77.0
L234332-01
WG239919
Silver
mg/kg
48.4
46.8
3.36
20
97.0
L234332-01
WG239919
Sodium
mg/kg
1120
1020
9.35
20
130.
L234332-01
mG239919
Zinc
mg/kg
49.4
47.5
3.92
20
88.0
L234332-01
WG239919
Kjeldahl Nitrogen, TKN
mg/kg
3490,-
4030
14..5
20•.
0.00
`.1,233871-01
WG239960
Mercury
mg/kg
0.250
0.240
4.08
20
100.
L234674-16
WG240349
Batch number /Run number / Sample number cross reference
WG239538: R266116: L234332-01 .
WG239964: R266394: L234332-01
WG239919: R266456: L234332-01
WG239960: R266544: L234332-01
WG240349: R266632: L234332-01
WG240432: R266793: L234332-01
WG240899: R267055: L234332-01
WG240586: R267137: L234332-01
WG241061: R267206: L234332-01
* * Calculations are performed prior to rounding of reported values
Page 6 of 7

ENVIRONMENTAL
SCIENCE CORP.
Alchem, Inc.
Ms. Phyllis Drye
8135 Red Road
Quality Assurance Report
Level II
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Rockwell, NC 28138 March 03, 2006
L234332
The data package includes a summary of the analytic results of the quality
control samples required by the SW-846 or CWA methods. The quality control
samples include a method blank, a laboratory control sample, and the matrix
spike/matrix spike duplicate analysis. If a target parameter is outside
the method limits, every sample that is effected is flagged with the
appropriate qualifier in Appendix B of the analytic report.
Method Blank - an aliquot of reagent water carried through the"
entire analytic process. The method blank results indicate if
any possible contamination exposure during the sample handling,
digestion or extraction process, and analysis. Concentrations of
target analytes above the reporting limit in the method blank are
qualified with the."B" qualifier.
Laboratory Control Sample - is a sample of known concentration
that is carried through the digestion/extraction and analysis
process. The percent recovery, expressed as a percentage of the
theoretical concentration, has statistical control limits
indicating that the analytic process is "in control". If a
target analyte is outside the control limits for the laboratory
control sample or any other control sample, the parameter is
flagged with a "J4" qualifier for all effected samples.
Matrix Spike and Matrix Spike Duplicate - is two aliquots of an
environmental sample that is spiked with known concentrations of
target analytes. The percent recovery of the target analytes
also has statistical control limits. If any recoveries that are
outside the method control limits, the sample that was selected
for matrix spike/matrix spike duplicate analysis is flagged with
either a "J5" or a "J6". The relative percent difference (%RPD)
between the matrix spike and the matrix spike duplicate
recoveries is all calculated. If the RPD is above the method
limit, the effected samples are flagged with a "J3" qualifier.
Page 7 of 7

ALCHEM, INC
8135 REDROAD
"0
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail] 4
February 23, 2004
DENR/DWQ/Water Quality Section
Mr. Daryl Merritt
Non -Discharge Compliance/Enforcement Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Mr. Merritt:
RM240- FM OL13RCES V)0
7 17'7'3U"4A1'0FF1
CE
FEB 2 4 2004
WATER QUALITY SECTO
Enclosed are the monitoring and reporting requirements for our permit number
WQ0016338.
For the year of 2003, we did not accumulate enough Silica residual to land apply.
Please let me know if you need anything further.
Best regards,
ALCHEM, INC
Wayne D. Drye,
Plant Manager
Is'
cc: Mooresville Regional. Office

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0016338 County: ROWAN Year:
2003
Facility Name (as shown on permit):
Land Application Operator:
ALCHEM, INC
WAYNE DRYE, PLANT MANAGER Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calendar year?
® Yes 21 No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit:
Total number of fields land application occurred during the year:
Total amount of dry tons applied during the year for all application sites:
Total number of acres land application occurred during the year:
Part B:
Facility was compliant during calendar year with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. 0 Yes p No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Wayne D Drye, Plant Manager
Permittee Name and Title (type or print)
9 L
Signatt4e of Prepar
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r)
3 )tL�
Date
Signature of Permittee Date
Signiture of Land Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/2003)

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704-279-7908 fax [phone]
[e-mail]
FORM ACF:
Residuals were pumped into holding lagoon.
Alchem, Inc's storage area for its fill material discharged into a drainage/wooded area
and stream. This was due somewhat to the large amounts of rain we had the first part of
2003.
Alchem has been collecting the fill material from the wooded area and the stream. A 24"
X 24" trench to divert the storm water from Red Road around the impounded area has
been completed. A 5' X 8' wide berm has been placed around the impoundment area and
all low grade areas. An enlarged settlement basin has been completed.

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338
Facility Name:
NPDES # or
WQ#:
WWTP Name:
Residual Analysis Data
ALCHEM, INC
Laboratory: 1)
2)
3)
4)
5)
TBL LABORATORY
Sample or
—CompositeDate'MMMMMMMMMMMM
kyj no FIRM
Total Phosphorus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
PIJA, � �) ') -
Signal& of Prep er
I la3D
Date
DENR FORM RSSF (5/2003)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0016338
Facility Name: ALCHEM, INC
NPDES # or
WQ#:
WWTP Name:
Residual Analysis Data
Laboratory: 1) TBL LABORATORY
2)
3)
4)
5)
Sample or
CompositeDate,MMMMMMMMMMMM
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
pid�� '@ fl�'
Signatl& of Prepare
' b.3 a
Date
DENR FORM RSSF-B (5/2003)

el,
elementOne
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Sample #
Sample Matrix
Date Sampled 7/29/03
Delivered by Picked Up
Page 1 of 1
FINAL REPORT OF ANALYSES
Sample ID
Sample Type
Time Sampled
Sampler
E1 Sample #
Element One Inc.
5022-C Wrightsville Ave.
Wilmington, NC 28403
Phone: [phone]
Fax: [phone]
[e-mail]
August 13, 2003
Client Project Name ALCHEM, INC
Client Project Number TBL-13205
PO Number
E1 Project Number e2075
Lagoon #3
0800
Wayne Dryer
2075-1
Date Received
7/31/03
Time Received
1630
Received by
PDS
Parameter
Result
Unit
Dilution
DL
Method
Date
Sodium
153
mg/L
5
0.01
EPA 200.8
8/1/03
Magnesium
105
mg/L
5
0.01
EPA 200.8
8/1/03
Aluminum
16800
mg/L
5000
0.005
EPA 200.8
8/1/03
Phosphorus
76.1
mg/L
5
0.01
EPA 200.8
8/1/03
Calcium
827
mg/L
5
0.02
EPA 200.8
8/1/03
Chromium
12.6
mg/L
5
0.005
EPA 200.8
8/1/03
Manganese
4.14
mg/L
5
0.005
EPA 200.8
8/1/03
Nickel
1.23
mg/L
1
0.005
EPA 200.8
8%1/03
Copper
2.93
mg/L
5
0.003
EPA 200.8
8/1/03
Zinc
1.65
mg/L
1
0.005
EPA 200.8
8/1/03
Arsenic
< 0.5.
mg/L
1
0.005
EPA 200.8
8/1/03
Selenium
< 0.5
mg/L
1
0.005
EPA 200.8
8/1/03
Silver
0.210
mg/L
1
0.002
EPA 200.8
8/1/03
Cadmium
< 0.2
mg/L -
1
0.002
EPA 200.8
8/1/03
Barium
66.3
mg/L
5
0.005
EPA 200.8
8/1/03
Lead
25.9
mg/L
5
0.003
EPA 200.8
8/1/03
Mercury
0.0865 m /L
1
0.0002
EPA 245.1
8/6/03
pH
3.60
1
EPA 9045C
8/6/03
en Smith, Laboratory Director
NC Certifications: DW 37788 and DWQ DENR 604

elementOne
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Sample #
Sample Matrix
Date Sampled 12/11/03
Delivered by Picked Up
Page 1 of 1
FINAL REPORT OF ANALYSES
Sample ID
Sample Type
Time Sampled
Sampler
E1 Sample #
Element One Inc.
5022-C Wrightsville Ave.
Wilmington, NC 28403
Phone: [phone]
Fax: [phone]
[e-mail]
December 29, 2003
Client Project Name Alchem, Inc.
Client Project Number TBL-13616
PO Number
E1 Project Number'e2615
Lagoon.#3
0800
Wayne Drye
2615-1
Date Received 12/16/03
Time Received 1515
Received by PDS
Parameter
Result
Unit
Dilution
DL
Method
Date
Sodium
218
mg/Kg
1
0.02
EPA 200.8
12/17/03
Magnesium
139
mg/Kg
1
0.02
EPA 200.8
12/17/03
Aluminum
21402
mg/Kg
1000
0.005
EPA 200.8
12/17/03
Phosphorus
85.4
mg/Kg
1
0.02
EPA 200.8
12/17/03
Calcium
885
mg/Kg
5
0.05
EPA 200.8
12/17/03
Chromium
14.3
mg/Kg
1
0.005
EPA 200.8
12/17/03
Manganese
4.15
mg/Kg
1
0.005
EPA 200.8
12/17/03
Nickel
1.32
mg/Kg
1
0.005
EPA 200.8
12/17/03
Copper
3.13
mg/Kg ,
1
0.003
EPA 200.8
12/17/03
Zinc
1.57
mg/Kg
1
0.005
EPA 200.8
12/17/03
Arsenic
0.889
mg/Kg
1
0.005
EPA 200.8
12/17/03
Selenium
0.889
mg/Kg
1.
0.005
EPA 200.8
12/17/03
Silver
0.356
mg/Kg
1
0.002
EPA 200.8
12/17/03
Cadmium
0.356
mg/Kg
1
0.002
EPA 200.8
12/17/03
Barium
82.4
mg/Kg
2
0.005
EPA 200.8
12/17/03
Lead
29.7
mg/Kg
2
0.003
EPA 200.8
12/17/03
Mercury
0.0
1
0.0002
EPA 245.1
12/23/03
pH
3.57
SU_J
1
EPA 9045C
12/17/03
en Smit , Laboratory Director
NC Certifications: DW 37788 and DWQ DENR 604

2010 ANNUAL MONITORING
Mrj:4;ktI:4i
Permit Non WQ0016338 .
Bauxite Residuals Mono -fill
Surface Disposal Program
1. Annual Residual Report
2. Residuals Analysis ! 4
APR -42011 t
3. TCLP Analysis _..,..�
4. Quarterly Groundwater Monitoring
5. Lagoon Records, Application Activities

Bauxite Residuals Monofill Surface Prouam
ALCHEM, INC
8135 RED ROAD
ROCKWELL, ROWAN COUNTY, NORTH CAROLINA
PERMIT -NO. WQ0016338
March 1, 2010
SUBJECT: Permit No. WQ0016338
Bauxite Residuals Monofill
Surface Disposal Program
PROPERTY: ALCHEM, INC
8135 RED ROAD
ROCKWELL NC 28138
�
IaP i, — 4

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704.279.7908 fax [phone]
March 30, 2011
NCDENR — DWQ
Information Processing Unit
161.7 Mail Service Center
Raleigh, North Carolina 27699-1617
Dear Mr. Hardee,
Enclosed is the annual report required by Alchem, Inc Permit No. WQ 00016338, Included in this
Submission are the required certification forms and the analytical results.
If you have any questions reguarding the submission, feel free to contact myself, Patty Fry or the
Facility Leader, Trent Tidwell at 704-279-7908.
Trent Tidwell
Facility Leader

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: W (, Q() /(133 �- FACILITY NAME: A 1 e her". Inc _
PHONE: 70e/•-2.79--7gOS- COUNTY: 14�ouoan OPERATOR:
FACILITY TYPE (please check one): IR Surface Disposal (complete Part A (Source(s) and Residual In" Volume only) and Part C)
❑ Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year?260 Yes 'A No ❑ —0- If No skin Darts A. B. C and certify form below
Part A*:
Part B*:
Month
Sources s ( include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January
A4 ;Ae-
CC , 15
H 2. .&
February
0, 0 u Y; e
31-7
March
C"LkXi�e
April
c
May
a
June
{3au i-1c
1I
112..Oq
July
i3o,,L ,4c
T2-k 12
August
(XUXIAW-331.3i
189.0
.01
September
qO"A Xac
3 19, Sil
2,12..(og
October
l
0'4 -LA0
mac`
November -
a� ',fie
O,D
145.12-
December
i3uu
19
Total from FORM DMSDF (sup)
t),53.o3
Totals:
Annual dry tons):
Z. 23
5 1
Amendments tised:1.Milking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Sapp) .
rart C:
Facility was compliant.during the past calendar year with all conditions of the land application permit [AnO
Yes
(including but not limited to items 1-3 below) issued by the Division of Water Quality: -A No s If No, Explain in Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached. Ye S
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization w .r:eDei'N ie Division Water puality, C' S
3. No contravention of Ground Water Quality Standards occurred at a monitoring well. 7'"' e Wye Can (r am n5 0-r and W4, Apr eft any( u� , j�Eve �S
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, h• re;`aocurat� and com'lylete
penalties for submitting false information, including the possibility of flues and imprisonment for knowillgNiolations." y:-• `
1-` o i
Signature of Permittee Da Signatr e of Pre
cc
(if different fi•om Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) e_,F
I am aware that there are significant
3 a 6�"r
Dat
DENR FORM DMSDF (12/2006)

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: �j q. `6 33 County: 0Wc64% Year: al 0 10
Facility Name (as shown on permit): (a 1 C h �r,r� a L N C
Land Application Operator: :.n c 4l �� �el,J g Phone: %tl - 9- igi - I 09
Land application of residuals as allowed by the permit occurred during the past calendar year?
91 Yes ® No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in thepen-nit:
1
Total number of fields utilized for land application during the year:
d
Total amount of dry tons applied during the year for all application sites:
a 56 5 . '!on 5
Total number of acres utilizes for land application during the year:
3 Ar-[-s
Part B - Annual Compiance Statement:
Facility was compliant during calendar year. a b O with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Quality. ❑ Yes [9 No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations. kere a..+•e IrowrA wo.t®r S't-k-rdc-(d Co►v�mje-KA I'oKs-
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto
13) All buffer requirements as specified on the .P i we
Part C - Certification: t- �'•r;"!
"I certify; under penalty of law, that the above':information is, o:tl
and complete. I am aware that there are signifie'a' penal es for su
possibility of fines and imprisonment for known violations."
Permittee Name and Title (type or print) =r. 1: Si`g
2
-rty or nearby surface waters has occurred.
during each application of residuals.
best of my knowledge and belief, true, accurate,
mitting false information, including the
of Permittee
of Land Applier
III
Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

F
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Sample #
Sample Matrix SS
,Date .Sampled=06/30/10
Delivered by FedEx
Element One Inc.
5022-C Wrightsville Ave.
Wilmington, NC 28403
Phone: [phone]
Fax: [phone]
el [e-mail]
FINAL REPORT OF ANALYSES
July 12, 2010
Client Project Name Alchem
Client Project Number TBL-21522
PO Number
E1 Project Number e14792
Sample ID r_Sand Residuals: •�:,
Sample Type Date Received
Time Sampled 1400 Time Received
Sampler Received by
E1 Sample # 14792
07/02/2010
1035
RLC
Parameter
Result
Result
Unit
Dilution
DL
Method
Date
As Received
Dry Basis
Sodium
69.4
118
mg/Kg
50
0.8
EPA 200.8
07/07/2010
Magnesium
713
1208
mg/Kg
50
0.8
EPA 200.8
07/07/2010
Aluminum
20124
34108
mg/Kg
2000
0.08
EPA 200.8
07/07/2010
Phosphorus
26.0
44.1
mg/Kg
1
0.8
EPA 200.8
07/07/2010
Calcium
43076
73010
mg/Kg
500
2.0
EPA 200.8
07/07/2010
Chromium
12.7
21.5
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Manganese
10.9
18.5
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Nickel
4.95
8.39
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Copper
2.48
4.20
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Zinc
36.8
62.4
mg/Kg
50
0.08
EPA 200.8
07/07/2010
Arsenic
0.367
0.622
mg/Kg .
1
0-08
EPA 200.8
07/07/2010
Selenium
< 0.08
< 0.136
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Silver
< 0.08
<'O.136
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Cadmium
0.220
0.373
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Barium
31.6
55.6
mg/Kg
50
0.08
EPA 200.8
07/07/2010
Lead
7.78
13.2
mg/Kg
1
0.08
EPA 200.8
07/07/2010
Mercury
0.098
0.166
mg/Kg
1
0.02
EPA 7471A
07/08/2010
Solids
59.0
%
SM2540G
07/12/2010
pH,- as received-----
_ - _ .9.31 _-
SU
EPA 9045C
07/07/2010
Ken' Smith, Laboratory Director
TBL-21522 Report Compiled by
NC Certifications: DW 37788 and DWQ DENR 604

TBL Alternate billing Information: I
2401 W. Fifth St. #y Chain of Custody
M Page o f-L
Lumberton, NC 28358 Prepared by:
910-738-6190 ENVrRorrMrrTAi,
3.
eport to: ; %A SCIENCE CORP.
`; _ .
mail to: 12065 Lebanon Road
Project Mt. Juliet, TN 37122
Description: ity/Sate
o12 d
Phone: Phone [phone]
Client Project #: ESC Key: Phone [phone]
FAX: ( ,OL
Collected by: = CL _ FAX [phone]
Site/Facility ID#: P.O.#: S
Collected"(signature):. V d
Rush9 (Lab MUST Be Notified
Date Results Needed:'.=`_
Same Day ....... 200% `�%.e:/o`Z ^/ P CJ . + 'CoCode. ;
No. (la.b use onl )
Next Day........ 100% Email? —No Yes
�:.,._ .
=.
Two Day .........50% : �. ~� Tel tplate/Prelogin.
Packed on Ice N y _ °f r V Y
FAX? No Yes
Sample ID cntr, Sh''
Comp/Grab dl „ Ipped.via-
Matrix* Depth Date Time Y
Remarks/Contaminant Sam
S Q I SS I Ple # (lab only)
i
x
:.;: �-
--------------
"Matrix: SS - SoiVSolid GW- Groundwater WW - WasteWater DW - Drinking Water OT - Other ' . t
Remarks: pH Temp
Rel' wished /�' Flow Other _
gnatur) Date: Time:
r 7 Recei d by Ignature) .samples returned via: p UPS
Re n aaa, l G�r1 l Coniiltion: -
d by ( h re _` ❑ FedEx ❑Courier ❑ (leb use onl
y) k ). Date: Time:
Received by: (Signatur .
• - / ., TeRiP
elinquished byBodies Received:
R: (Signs ure)`..,
:. Date: Time: Rec d for lab bySl nature) e
� r .Time
� pH Checked NGF � .

TB L
2401 W. Fifth St.
Lumberton, NC 28358
910-738-6190
Alternate billing information:
-portta:
mail to:
Protect
Description: �� (J (�
ity/Sate
Collected
.
Phone:
FAX:
Client Project M
1
ESC Key:
_
Collected by:
Site/Facility ID#:
p,0.#;
V
Collected by (signature):
Packed on Ice N Y
Rush1 ( Lab MUST Be No
Same Day.......200%
Next Day........ 100%
Two Day .........50%
Date Results Needed:_
("7 -/-aZ -/ �
No.
of
Email? No Yes
FAX? _No Yes
Sample ID
Comp/Grab
I
Matrix'
Depth
Date
Time
Cntrs
=aq%
N
I
. ---- ---------... I
-
- -...-
-Matrix: 55 - SoiVSolid GW- Groundwater WN- WasteWater DW - Drinking Water OT - Other
Remarks:
^�:. w�liaiou .i�naru�
Date:
Time:
Racal ad by Olgnature)
Re ind by, ( inn 'ttto'yCe)
Date:
Time:
udakr
Received by: (SignaturR;
y
Relinquished by: (51gn urej'. L
Date:
Time:
Received fo lab byt"(Sigrid.
Chain of Custody
Page 1 of 1
Prepared by:
ENVIRONMENTAL
SCIENCE CORP.
12065 Lebanon Road
Mt. Juliet, TN 37122
Phone [phone]
Phone [phone]
FAX [phone]

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: W a p o i(-1 3 3 g Laboratory:
Facility Name: ►a I c-I-.em . -t- nc ,
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
1) T"AL �Q.bor•�'Y
2)
3)
4)
5)
Parameter
(mg/kg)
Sample or Composite Date
Soo ; u r"
(D 9 .ki
F7
© -e
t Pp ua
772o►o
rv%e Y1es+u.re%
_] 1%
1 Zel
w. k
S6
0.9
EPA 200.$
1-1-2010
A l y t r% r,%
201 Zy
3y (OS
r, K
2000
o .08
EpA. 2po.8
- -7.Zo ip
C-3kei 4r.
y36110
`13010
r^31ki
Sao
2.0
CpA2ac,/+.
7-7-2otp
r'1dh o.r1.2Se-
IM
m-ilkg
t
6.68
9-po 2m•8
7-1-aelo
co.epec
2.qS
�l.�o
e"jps
I1
0-.08
a 2o0•S
i-i, uiro
5� ver
GO.O$
e0:1SIP
r,, /6c
i
b.o8
E A 2-0QS
{3o.,r , u yy\
31,1Q
55,.(o
M31k
5a
O.0$
EPa100•9
7 1-ZOlo
"I certify, under penalty of law, that this document was prepared under my direction or -supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

1Z " C: E-S
YOUR LAB or CHOICE
Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Report Summary
Tuesday .;a:. nary 11, 2011
Report Pu. :,er: L495437
Stamples =REi_- -ved:=- 1.2,/-2=9/�+7
Client 210 ct: TBL-22173
Description:=;`3idual (Alchem
12065 Leb:,.ion Rr.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0614289
Est. 1970
The analytical results in this r•,�[ - are based upon information supplied
by you, the client, and are. for exclusive use. If you have any questions regarding this data pa , please do not hesitate to call.
1( �
Entire Report Reviewed By: ^�
.1"! D. Blackman ESC Representative
Laboratory Certification Numbers
GALA 92396IN01 CATN-01,1KY78990C.
NJ - TN002,NJ NELAP - TN002, SC
. �.YUSTT-00016, NC27 ENV375/DW201704,END-ER7140
`04, TN - 2006, VA - 00109, WV
TX - 0612, MN - 097-999-395, NY
TX - T109704245, OK-9915
- 233
'42, WI - 998093910, NV - TN000032008A,
Accreditation is only applicable to the ces-
by ESC Lab Sciences.
.s specified on each scope of accreditation held
Note: The use of the preparatory EPA Method
not approved or endorsed by the CA ELAP.
This teport may nut be repruouced, except is
Where applicable, sampling conducted by ESC
without written approval from ESC Lab Sciences.
in laboratory standard operating procedures:
)rmed per guidance provided
. 060303, and 060304.
JA N 14 2011 4

YOUR LAB OF CH DICE
12065 Lebanon Rd.
Mt. Juliet, TN ?7122
(615) 758-'3856
1-600-767-5959
Fax [phone]
Tar, I.D. 62-0814289
Est. 1970
REF 9 = ANALYSIS
Pam Hester
TBL Laboratory January 11,2011
P.O. Box 589
Lumberton, NC 28359
Date Received
Description
Sample ID
Collected By
Collection Date
Parameter
December 29, 2010
Residual (Alchem)
RESIDUALS
Randall Andrews
12/22/10 00:00
Result
,.:t. Limit
Units
ESC Sample 4
Site ID
Project R
Method
L495437-01
TBL-22173
Date
Dil.
Nitrate -Nitrite
Phosphate as P
BDL
2.0
mg/kg
9056
12/30/10
1BDL
1.0
mg/kg
9056
12/30/10
1
Cyanide
BDL
0.25
mg/kg
9012B
01/04/11
1
Ammonia Nitrogen
BDL
5.0
mg/kg
350.1
01/04/11
1
"pH
8.1
su
9045D
12/30/10
1
Kjeldahl Nitrogen,
TKN
24.
20.
mg/kg
351.2
01/04/11
1
1 Mercury
0.15
0.020
mg/kg
7471
12!31/10
1
Aluminum
`Arsenic
28000
5.0
mg/kg
6010E
01/06/11
1
Cadmium
BDL
1.0
mg/kg
6010B
01/06/11
1
`CalciumBDL
50000
0.25
25•
mg/kg
6010B
1/06/11
1
Chromium
0.50
mg/kg
6010B
O1/06/11
1
Copper
97�
1.0
mg/kg
6010E
01/06/11
1
`Lead
11'
0•25
mg/kg
6010B
01/06/11
1
Magnesium
Molybdenum
1100
5.0
mg/kg
mg/kg
6010B
6010B
01/06/11
O1/06/11
1
` Nickel
1.2
5•0
0.25
mg/kg
6010B
O1/06/11
1
1
Potassium
`
240
1.0
25.
mg/kg
6010B
01/06/11
1
Selenium
BDL
1.0
mg/kg
6010B
01/06/11
1
Silver
BDL
0.50
mg/kg
6010B
O1/07/11
1
Sodium
92.
25•
mg/kg
6010B
O1/06/11
1
Zinc
1.5
mg/kg
6010B
O1/06/11
1
mg/kg
6010B
01/06/11
1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL:
Note:
The reported analytical results relate only to ample submitted.
This report shall not be reproduced, except in without the written approval from ESC.
Reported: 01/09/11 14:36 Revised: 01/11/11 09::
L495437-01 (PH) - 8.1@17.9c
Page 2 of 4

12065 Lebanon Rd.
Mt. Juliet, TN 37122
*ESC 758-5858
1-800-767-5859
Fay. [phone]
L•A-a S•C• I - E -N- C E• S -
Tax I.D. 62-0814289
Est. 1970
RE )F ANALYSIS
Pam Hester January 11,2011
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received December
29, 2010
ESC Sample
# L495437-02
Description Residual
(Alchem)
Sample ID RESIDUALS
Site ID
Collected By Randall Andrews
Project
TBL-22173
Parameter
Result
Limit
Units
Limit
Method
Date/Time
By Dil
Corrosivity
Non-Corros,
9045D
01/.06/11
0900
CJM 1
Ignitability
See Footnc-
Deg. F
D93/101
01/05/11
1418
JAL 1
Reactive CN (SW846 7.3.3.2)
BDL
.125
mg/kg
9012B
01A05/11
1349
CWP 1
Reactive Sulf.(SW846 7.3.4.1)
39.
'5.
mg/kg
9034/90
01/03/11
1506
EA.M 1
TCLP Extraction
-
1311
12/30/10
0717
MVE 1
Mercury
BDL
.0010
mg/l
0.20
7470A
12/30/10
1540
MJD 1
Arsenic
Barium
0.060
.050
mg/1
5.0
6010B
01/03/11
1814
JBC 1
Cadmium
0.16
).15
mg/l
100
6010B
01/03/11
1814
JBC 1
Chromium
BDL
.050
mg/1
1.0
6010E
01/03/11
1814
JBC 1
Lead
BDL
.050
mg/l
5.0
6010B
01/03/11
1814
JBC 1
Selenium
BDL
.050
mg/l
5.0
6010B
01/03/11
1814
JBC 1
Silver
BDL
.050
mg/l
1.0
6010B
O1/03/11
1814
JBC 1
BDL
.050
mg/l
5.0
6010B
01/03/11
1814
JBC 1
TCLP ZHE Extraction
-
1311
12/30/10
0830
MVE 1
TCLP Volatiles
Benzene
Carbon tetrachloride
BDL
BDL
.050
mg/1
' 0.50
8260E
12/30/10
1537
JAH 1
Chlorobenzene
BDL
.050
.050
mg/l
mg/l
0.50
100
8260E
8260B
12/30/10
1537
JAH 1
Chloroform
1,2-Dichloroethane
BDL
!.25
mg/l
6.0
8260E
12/30/10
12/30/10
1537
1537
JAH 1
JAH 1
1,1-Dichloroethene
BDL
BDL
.050
mg/l
0.50
8260B
12/30/10
1537
JAH 1
2-Butanone (MEK)
BDL
O50
mg/l
0.70
8260E
12/30/10
1537
JAH 1
Tetrachloroethene
BDL
50
mg/l
200
8260B
12/30/10
1537
JAH 1
rnylchloridee
BDL
.050
mg/1
0.70
8260B
12/30/10
1537
JAH 1
Vinyl chloride
BDL
.050
mg/l
0.50
8260E
12/30/10
1537
JAH 1
Surrogate Recovery
.050
mg/l
0.20
8260B
12/30/10
1537
JAH 1
Toluene-d8
Dibromofluoromethane
106.
110.
% Rec.
114.
8260B
12/30/10
1537
JAH 1
a,a,a-Trifluorotoluene
107.
% Rec.
% Rec.
125.
114.
8260B
8260B
12/30/10
12/j0/10
1537
JAH 1
4-Bromofluorobenzene
105.
% Rec.
128.
1537
JAH 1
8260B
12/30/10
1537
JAH 1
TCLP Pesticides
Chlordane
Endrin
BDL
0050
mg/1
0.030
8081A
01/03/11
1702
ADF 1
Heptachlor
BDL
BDL
0050
mg/l
0.020
8081A
01/03/11
1702
ADF 1
Lindane
BDL
.0050
0050
mg/l
0.0080
8081A
01/03/11
1702
ADF 1
mg/1
0.40
8081A
01/03/11
1702
ADF 1
L495437-02 (IGNITABILITY) - Did Not Ignite @
Page 3 of 4

Pam Hester
TBL Laboratory
P.O. Box 589
Lumberton, NC 28359
Date Received December 29, 2010
Description Residual (Alchem)
Sample ID RESIDUALS
Collected By Randall -Andrews
Collection Date 12/22/10 00:00
Parameter
Methoxychlor
Toxaphene
Surrogate Recovery
Decachlorobiphenyl
Tetrachloro-m-xylene
TCLP Herbicides
2,4,5-TP (Silvex)
2,4-D
Surrogate Recovery
2,4-Dichlorophenyl Acetic Acid
TCLP Semi-Volatiles
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
Nitrobenzene
Pyridine
364-Methyl Phenol
2-Methylphenol
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogate Recovery
2-Fluorophenol
Phenol-d5
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d14
RE: : F ANALYSIS
1?065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5@59
Fax [phone]
Tar. I.D. 62-0814289
Est. 1970
January 11,2011
ESC Sample 0 : L495437-02
Site ID
Project TBL-22173
esult
. Limit Units
Limit
Method
Date/Time
By
Dil
BDL
.0050 mg/l
10.
8081A
01/03/11
1702
ADF
1
BDL
.010 mg/l
0.50
6081A
01/03/11
1702
ADF
1
82.1
% Rec.
123.
8081A
01/03/11
1702
ADF
1
84.8
% Rec.
114.
8081A
01/03/11
1702
ADF
1
BDL
.0020
mg/l
1.0
8151A
01/04/11
21_17
K:,M
1
BDL
0020
mg/1
10.
8151A
01/04/11
2217
KLM
1
77.1
% Rec.
8151A
01/04/11
2217
KLM
1
BDL
.10
mg/l
7.5
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
0.13
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/1
0.13
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
0.50
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/1
3.0
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
2.0
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
5.0
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
400
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
200
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
100
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
400
8270C
12/31/10
1553
JAB
1
BDL
.10
mg/l
2.0
8270C
12/31/10
1553
JAB
1
30.6
% Rec.
87.0
8270C
12/31/10
1553
JAB
1
24.4
% Rec.
67.0
8270C
12/31/10
1553
JAB
1
45.4
% Rec.
120.
8270C
12/31/10
1553
JAB
1
59.0
% Rec.
122.
8270C
12/31/10
1553
JAB
1
80.8
% Rec.
148.
8270C
12/31/10
1553
JAB
1
94.9
% Rec.
149.
8270C
12/31/10
1553
JAB
1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQLI
Limit - Maximum Contaminant Level as establish. the US EPA
Note:
The reported analytical results relate only to 1 sample submitted.
This report shall not be reproduced, except in ! without the written approval from ESC.
Reported: 01/09/11 14:36 Revised: 01/11/11 09:
L495437-02 (IGNITABILITY) - Did Not Ignite @ 1 I
Page 4 of 4

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: (,JQ pp ( (o Laboratory:
Facility Name: Mcher•,, Xnc
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analysis Data
1)`SC .�.�UUfory
2) �-
3)
4)
5)
Parameter
(mg/kg)
Conc. m
Limit
k a
Sample or Composite Date
ReSu��
tar.t4s
Me►M
P
Q i
-
Percent Solids (%)
NA
1
Arsenic
75
V>-
t %0
J/
o.(bS
116 //t
t
Cadmium
85
BOL
0.2.5
k
(001013
l #
1
Copper
4,300
ti•0
1.0
(901A
1 (o I
I
Chromium
NA
IT
0.5.0
01613
11
1
Lead
840
i f .
oav
(,o o B
/I
Mercury
57
6.15
6,0-40
Ike,
-jq i (
tz 31 /0
I
Molybdenum
75-
1.21
Q.�S
Nickel
420
$.6
(.p
Selenium
100
p�
, p
L
Zinc
7,500
(D,
, S
�,
(90lbg
a
Total Phosphorus
NA
b 1,
1.0
gp5b
TKN
NA
Ammonia -Nitrogen
NA
Nitrate and Nitrite__ .
_ . NA_-
_
�- �aa110.VV uiaY�aai IdellIuCJ LuC ceuing concentration smuts listed in this Corm are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared tinder my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature
ate
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use'additional forms as needed.
SC
WQ Permit Number: (,) & pp 1(0 338 Laboratory: 1) i La 6 o rg-4cr fr
Facility Name: A ( C liven,, Zrc- 2)
Residual Source 3)
NPDES # or WQ#: 4)
WWTP Name: 5)
Residual Analvsis Data
Parameter
04
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
3 a 9 2a
ate
*Preparer is defined in 40 CFR Part 5039(r) and 15A NCAC 2T .1102 (26)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: LA) (�, 00 /� 33 Laboratory:
Facility Name: I c k errs 3 X r%c-
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Analvsis Data
1). T 8 L La b a cm4c) �y
2)
3)
4)
5)
Parameter
(mob)
Conc.
Limit
m k a
— /02 — av o Sample or Composite Date
Ay Rtc,el��
Bass
U r i �'
p
p L
Me.N.od4e
..
Percent Solids (%)
NA
57.0
%
S� zs
7 •lz _ 20%
Arsenic
75
b.3(o-1
1
0.08
EPA 200.
7-7- l0
Cadmium
85
, Z.Z.o
10,311
eva.5/1
I
0,69
kcFAUOS
7-Z-20b
Copper
4,300
Z .y 8
Lo
rn,51 K
0,0 S
Efw=os
'! 1-2010
Chromium
NA
Lead
840
-7.-?8
111.2
ray K5
O-OS
EPA2PO4
Mercury
57
0 - 09
10.1(0(0
m k
l
0.61
Epp, 7Y714
74-20K)
Molybdenum
75
Nickel
420
q. 9.5
$ , 34
Vhg k
(
0.0B
6pA•2.po,8
7 7-2o %b
Selenium
100
<010$
V.01136
0.08
EPA UOS
7-1-2o►b
Zinc
7,500
X.T
(DZ -4
rh K
o
0.0 $
E A -too,
Total Phosphorus
NA
.Z(a. C)
ilf{ ,
rr,
6.2
FFA 20o ,8
-1-1-2o 10
TKN
NA
Ammonia=Nitrogen
NA
Nitrate and Nitrite
a..
NA
-
- --
-
-
-
-
For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature
3 ? 20//
Da e
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
nFNR FnPRA F2CQF t1gignnaN

DISPOSED RESIDUALS LAGOON it 1 gni n
DATE
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DISPOSED RESIDUALS LAGOON # 1 ,In In
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DISPOSED RESIDUALS I ArnnN it 1 ;non
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DISPOSED RESIDUALS LAGOON # 3 2010
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DATE
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CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
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DISPOSED RESIDUALS LAGOON # 3 - 2010
3Z
DATE
SOURCE
CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
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DISPOSED RESIDUALS LAGOON # 3 2010
�.3
DATE
SOURCE
CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
7 ao-2-o
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a
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•.{e
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DISPOSED RESIDUALS LAGOON # 3 2010
DATE
SOURCE
CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
g z-�o1d
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DISPOSED RESIDUALS LAGOON # 3 2010
DATE
SOURCE
CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
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DISPOSED RESIDUALS LAGOON # 3 2010
311
CUBIC YARDS
FREEBOARD LEVEL
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1Z
DATE
SOURCE
CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
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DISPOSED RESIDUALS LAGOON # 3 2010
2.6
DATE
SOURCE
• CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
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DISPOSED RESIDUALS LAGOON # 3 2010
3-7
DATE
SOURCE
CUBIC YARDS
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FREEBOARD LEVEL
- Q - 20b
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DISPOSED RESIDUALS LAGOON # 3 2010
3L
DATE
SOURCE
CUBIC YARDS
CUBIC YARD DISPOSED
FREEBOARD LEVEL
/z -1- 2610
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/2- -30- 5-06

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704.279.7908 fax [phone]
[e-mail]
Specified Conditions M
�. The cumulative volume if residuals disposed of the surface
Disposal -unit: 2;231cubic yards.
�. Remaining volume in the surface disposal unit:
2670-.50=gallons.
Estimate of the remaining, useful disposal life for the surface
Disposal unit:; 10 years.

APPENDIX A
GW-59A AND GW-59 FORMS

,ram 7••x- 44 F•.;' '1.)3 i� /' r''l.,�.- T pp Pq `,., FO )l f's:f'))i)i j� ' ! .f..J.f '�•
t.S�4 +J.(1 s.: C�1��,F f.. �aJ :C.f:: id:i;( �L�.` u b h.➢'X�..
(.S'aalmir on > arch menjirorirlg jreriad with
EnieT dais m•DniloxJnT� :resu3.Ls'»ese s3.ue.., ----:) �f1131}� •s�crs?4sJrlrrs� re c�:t� ?A.-'�9 �:rd G 33.A) TM,
j
be sabniTMO afleT'3he �s•Ya�i4'Lshe.d ifal da3e'?
^]
-- - ~ -'
3f�i �3 LZJ;'i T.Pfj)]]3"atl 7.1]'1ri751DSStoiiS) 7SS?;t'i);L"L.`, �:1J 3ba )f'Ji-� S) - :.i�Dr1 1'£77ny3"
_-
tF lha �nsJJaT to rj1le�;orJ ':; ar ?>`. ":IFS ; lr'�tdrJ 1t.�a v�aca prorrjrlad:�cto�r U3-'.' xracijlfl ntil'c`?'+oT3731ir11'D;y/�S� �T?ci f
�`rptaln tha orri:Olarns vnc,�zr.t T1 ire L?Oc:hrfi9ej 1ri ra;llr,cl iaiorr/!ef.i:.
1
J
'£if 11J]33�L1y
{
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1 :?
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"'J�iS'�,
•
1+
7
3i)?Ail'�SCS1:I12r7J f1Y51•ti, SiftII'D�'fs7;�IiF)Y 11, $��Y.��: �( I+1/! S31JS)VEr fi C'ai4:!iC'I ��:P :F£Pilli7.SS� S�li'G•` J0� �L;LG<tGZ4'i''.
�.'5t'4.{)-
9
r,
ATe any rf3073S1Qr8:i1:U`Oi3&3iti:f£i):.3'Qf3)3u{,S).Ur?'•S:i?:.'i8ti#3)Yt:3L'3?3i2*•.J's^ir:�5'?
-
y
if the aff's',pl&r 10 f ue3lion 4 is skip t t iacJlorf it
o + ,,,;__, v ia� J,.rE,. �.;,' ir' c.r• r,,t}i rf;r,�J«{: I:l i c,rr'1 rpR_raYJ'1.lati0A ^hl
answe), 39 que-&Vw..) 4 3s ��� %. i i(ta ;Z,..%i<:f• . r1s . f, .a .>.rj( J,.,,! �;.^., j
r
I
1
excaacliT cj slanfkvds lra saacs ,Ur�,rrkt.�rt bz-)Ow:
Ae
-- ars3s been exs•Ee.c1r3: raysfllssly�r'Zhe y�
far al}s tons1huenis deraii}Sed 3n gi1es'iion 4 Vbove: have s'iat P t !
Y£5 N0
some co»s3itirea)zjs) In ii� sarne � Ov(s) ha ifae las3 MD Y-02TS?
i
If the answw 10 rJo aww" : is 10' s J?i tc ssr.3(an .
11 The ans>erar'to n5 ris *'',YE$—". Prvl.irr 1� s }Jaca trrorrirletl .talon, a`,ch Sr.IZO wit?'i consti.loarrf(s+ c:rcaartincj
lroes-lion
sh)ncdards, Gowen.a?ori{ ) repo<?Fr;, --ind aampia CO)IR<:liorr cl.JJa lar each occurlencs flw Vt& kis-I hwo Ye:rrs).
}{
l
{ ffi
An ale mo njl ^mah3 q s4,015 Xts!ad :z3 v"^:.i'.'di.t>:l` u.`v`t six v y1 •k2' zr. �✓ )-• ::: �=' ::^r -_ • a ..y -
f�
jf
�' a ��I�FT.t��C'I'T;1F:13��1.t71+JA.L
�� She ans�ver is `�i'Ea�= ; a 3�7X?1lT).UY>'a1er'Z�.ur?lil}r probjsm r3)a3+.b,. �currxrFg. ,v<,..
pFFICi>'P�j�j�D1,9T:FL`Y:F.�R .G:13jIJ.�,'f�.�•E. J3-tiJ.e;Zns)�er is �'J�1��'. rraorTilfl�ng �a9ls xJx�y'l�e �m�rppsrly
jocalar7; ;conlacl •8>aER, e�loraa.'1 �}l'Jt;e..
'
i
Is the P rrmiitee ixnp3eJz eniing pr�yiatasly approved actions T•eclsxired by,ibe !MOST D:n 1)v91�ra� dais
i 1bt7
groa)ra�l>?rateT ,gv;i;i3�t ;p's�i)larn3
Tfthe ans�,Er10 rji}F'31)Gr! f is "Y�5", rleacilha Jr�<'a actions in 3r.+a c�,u:JLs orouiciarlbalcys. r — _ _
{� fhe aT)5ar1r•er $o que—slian % is x'.F1)•D"•. cnjsPact:thie Recgional Office aV>iWD 913 days, an : , alua3ion may ;b2_
_— -
fecwlf�ed 1,0 dQler7 one.1be Impact -Me Ylasle CljsyODSa)I sysleJi'] is bayingat SheT.'emi-ew and C•0.77)PjSaAc£'
E
4
bocn,darias $3irr9iE/J 17if) tTJS•� i` .� Il% . :1`ajfj;re 3fl Sig so r7)a3 sgb e �t3L'. „aTT meg- .14 zolol7ca of iLiolaJi.on.
i
j1
fines. anslfAnattles;
� 1?jDi'rsDT3 �II97)�Dli'BT1.7: 1P)lS jrkR7 Jfll) :f } 3 A�-the monigaring rgij d 5jJw ari'd SlTb77J1d :it)is
fcr+n wilt GW-69 forr77s fat .req:uired wzVz to 1— be vdelress ;pro ed Of Me Icap .OfP L3)rrer7A ,GW-59 form.
1
1
11
i hereby acknowledge that the abOVO in4'6rF MIon was evacuated and the infbrmaticn submitted in this
report (Compliance. Report GW-59,A) is true andcomplete to the best of.my 3craovAedge.
-279-10
San 7aw 01'PETf33%Y?$g ; :STTAYE2badz?ii Age'33) 5,7 Ze. A,4 7ve , Date
MY-.59A J21812003

GROUNDWATER QUALITY MONITORING:
iCOMPLIANCE REPORT FORM
Name: { 7
Name (if different): '
Address: ;�31__-5.,�
SUG?All FURM UN
County
act Person: r it.' �_ / 411CIIC_14 Telephone#:,?/ 9
LocationJSfte Name:/;�'2#2 it ,J 4 zr-Ae,-il , .,.d �f C • No. of wells to be sampled:
— I _'
WELL ID NUMBER (from Permit): ✓'% LL`
Well Depth: 1-� ft.
Depth to Water Level 32546: , 9'/ ft. below measuring point
Measuring Point is 1a 56 ft. above land surface
Volume of wa[or pumped/bailed before sampling: > ,
Samnles for metals were collected unfiitored: CRIES ❑
Date sample analyzed; WA 3 -° & ZR a3 JOr�
PARAMETERS NOTE: Values should reflect dissolve
GOD ooam
mg1L
Coliform: MF Fecal 3iei6
1100mL
Coliform: MF Total 3tr0a
! 00mi
aopr: usu WN ❑,clad ear h:alal.;ua•!d eem7:0a)
issoived SolidS:Total 70300
mg/L
pH (Lab) ood0a 5
units
TOC o0660
mg/L
Chloride 0onvo
mg/L
Arsenic 0VD02
ug/I_
Grease and Oft 00552
mg1L
Phenol 22730
ugJL
SUlfate 00945' mg1L
pacific Conductance 0005 ,1
liMhos
Total Ammonia 00610
mg1L
(Anm+onrn r:nrsyon; nN: U, r:; Anu110MI 5dre9en, Teieq
TKN as N oos2s
For Remediation
mg/L
PAVUX VNt.1
PERMIT Number:
Expiration Date:
Non -Discharge
UIC
NPDES
Other jrtiG�G�G'6 L-1'70
TYPE OF PERMITTED OPERATION BEING MONITORED
f t Lagoon
❑ Remediation: infiltration Gallery
❑ Spray Field
❑ Remediation:v
❑ Rotary Distributor
❑ Land Application of Sludge
Dale sample collected: 6 -A. J-y r
Weil Diameter: t;Z in.
Screened Interval: '" ft. to /-:eft.
Relative M.P. Elevatlon: .,,�o ft.
gallons
acidified: UA_'�'ES ❑
❑ Water Source Heat Pump ❑ Other:
FIELD ANALYSES:
pH oo,:oo::' J ( units Temp. coo,0, A-14,3=C
Spec. Cond. 000w:
Odor=R5:
Appenrarice
laboratory Name: 4,,r �r r iir � �z �y1� 5 %, Cartiffcation No. 3Z�l.Z
and colloidal concentrations.
Nitrite (NO2) as N oec15 mg/L Pb - lead oio5i ug/L
Nitrate (NO3) as N OWN mg/L Zn - Zi.rc 01092 mg/L
Phosphorus: Total as P aos;65 mg/L
Orthophosphoto 7(1o'r mg/I. Otho'r (Specify ^,ompounds and Concentration Units):
AI - Aluminum 01 105 Z 9Y mg/L��-
Ba - oadum of ;or ug/L
Ca - Calcium o0 i16 mg/L
Id - Cadmium 01427 ug/L
Chromium: Total 0103: ug/L
DRY at
time of
Cu - Copper 010d2
mg/L
ORGANICS: (by GC, GC!MS. HPLC)
Fe - Iron 01o45
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Hg - Mercury 719rA
ug/L
Lab Report Attached? ❑ Yes ( t) ❑ No (0)
K - Potassium 0011s7
mg/L
VOC 7$732: _, method 11
Mg - Magnesium 0eg27
mgJL
_, method ::
Mn - Manganese 01055
ug/L
method 5
Ni • Nickel Ot0;7
ug/L
method 9
only (Attach Lab Reports): Influent Total VOCs: ^ mg1L Effluent Total VOCs: mg/L VOC Removal%
�•'/{•^o . ,..• :.. ,s •jam/. _ P6, . �J J. n.
! lelt se'1/1 r 4_N3 . `✓J ✓'iJW Y"!•':i31...` ' �� l"�_ _ � ! G^-�0 fr
Pennittea (or Authorized Aganl) Alame ind Ti+Je - Pleas.- print or type siqm- ure f Permi;tea (or Authorized Agent) (Oe{C1
GIN-59 Rey'. 2J2010 J
K

ROUNDWATER QUALITY MONITORING:
OMPLIANCE RI=PORT FORM
TY IN FORMATION r)ee'ne Ynrt l;rreni or ) ype
Name: ,,y le— A C,,n �= t C ,
Name (if different):
Address:
...................
SUBMIT FORM ON YELLO!^! PAPER ONLY
County
act Person: t iL,Yl/ /-, 463P1i< Telephonefu:
Lccaiion/Bile Name y a� Jr.,�e itG• No. of wells to be sampled:
lnu:n�w�nrrcv,vc�rcv,cr<,,cn..c,vn,r,.,.«uou•,o,,... �:�,w„�,�
PERMIT Numbi^r:
Expiration Datfl: e
Nan -Discharge
UIC
NPDES
_ Other
TYPE OF PERMITTED OPERATION 13EING MONITORED
t Lagoon
❑ Remediation: infiltration Ga!!eq,
❑ Spray Pie!d
❑ Remediation:
❑ Rotary Distributor
❑ Land Application cf Sludge
❑ Water Source Heat Pump ❑ Other:
�� �
WELL ID NUM6ER (from permit): hiN — c�—
Uata sample collected: 1 0�l "�
+� ''
FIELD ANALYSES:
WAS
+Atoll Depth:
Well Diameter: ,.„ in.
pH oo^00. _ Q units Temp, 0001o: IJ,�
`"•�
DRY Zit
time of
r t 2S / »�
Depth to'�. Water eves 6 .AS: ) j�,'Y ft. belot. mom.. firing pant
i
Screened !n,ertal; �5 fi. to „� Ft.
g 0 n A4hos
Spec. Cond. 00 ,;,
_
sampling,
Measuring point is-3,74- ft. above land surface
Relative M.P. Elevation; pia .' ft.
Odor o0
checl;
Volume of water pumpedlba(led before sampling: gallons
Appearance
here:
Samoles for metals worn collected unfiltered: lE5 ❑ N-0
and field addliiod: S ❑ NO
Date sample analyzed: ?" - . •-
PARAMETERS NOTE: alues sh
COD 00335
mg/L
Coliforrn: Mr' Fecal stst5
/100m.L
Coliform: RAF Total 31s0a
1100ML
(.Nwe. urn .,a ra n:eliroa r-: !ua!,!y iwhid
Solved Solids;ToW 70300 r� %•.�
mg/L
pH (Lab) 0a c3 f�� r�
units
TOO nprpn
mg/L
Ch!or'de 0024e
mg/L
Arsenic 01002
ugfL
Grease and Oils 00S52
mg/L
Phonoi 327a0
ugfL
Sulfate 00aas %7^> mglL
)eciffc Conductance 00095 r 7 ri 1
p.Mhos
Total Ammonia 00610
mg1L
(An-1-n Nprol:n: HH, O.S.M. Amronia 5troven. Tot.^!)
TKFJ as N oos25
mg/L
r
Laboratory Nami;; -!5 lsAt le r/ Cw
and colloidal concentrations.
Nitrite (F10�,) as N o0nls mg/L Pb - L ead otosl
Nitrate (NO,) as N oor20 mg1L Zn - Zinc, 01002
Phosphorus: Total as P coo,- mg/L
Orthophosphate 7o.`.-Q7 mg/L Other (Specify Compounds and Concentrat!on knits):
A! - Aluminum o1 los Ci. r':�a�%; o mg/L
5a - 5aril:m Ot007 ug1L
Ce - Calcium 00^19 mg/L
Cd - Cadmium o!:;27 ug/L
Chromium: Total o+:ian, ug/L
Certification No. J 71,�7 -
ug/L
mg/L
Cu - Copper 04r:2
mg/L
ORGANICS, (by GC, GCIMS, HPL C)
Fe - Iron 0t045
ug/L
(Specify test and method P, ATTACH LAB REPORT.)
I-Ig - h4ercury 711100
ug/L
Lab Report Attached? ❑ Yes (1) 0 No (0)
K - Potassium oon37
mg/L
_
VOC 7a732: �, method 0,Nog
- Magnesium 0!,,(.:27
mg/L
meihod f
Mn - Manganese oto.s
ug/L
method 1.
Ni • Nickel 01OB7
ug/L
method k
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
mg1L Effluent Total VOCs[ mg/L VOC
1 ,AA
Prrmitlee (or Authorized Agent) name and rlie _ P cse print or type Sig,mturr, f Permillee (or
GW-59 Rev.212010 �

SUbW I i-UK[,n, UN YLLLUNJ FANtK UNLY
UND111/ATER QUALITY MONITORING:
PLIANCE REPORT FORM
FACILITY INFORMATION P"nase Print Clearly or Type
Facility Name:, -
Permit Name (if different):
Facility Address: 01-3S �" S !rl ✓7 c'
hl.:, a"A—/ (:,n::) V/1 _ 1s26132G County
act Person: j ��r ' ; {-e6Ns Tefephonell: 0JtIJ 9•10 --,U,2.f
Location/Site Name: No. of wells to be sampled: _
PERMIT Number: Expiration Date:
Non -Discharge UlC
NPDES Other
TYPE �PERMITTED OPERATION BEING MONITORED
corl ❑ Remedialion: Infiltration Gallery
❑ Spray Field Remediation:�
❑ Rotary Distributer ❑ Land Application of Sludge
❑ water Source lloat Pumo ❑ Other:
WELL ID NUMBER (from Permit): C(i --� Date sample collected; -/
Well Depth: y�ft. 14re11 Diameter: En.
Depth to Water Level 825.16; &'7 ft. below measuring point - Screened interval: 2. f!. to ft.
Measuring Point is ft. above land surface Relative M.P. Elevation: - ft.
Volume of water pumped/bailed before sampling: a • gallons
Samples for metals were collected unfiltered: t ES ❑ NO and field acidified: 2-IES ❑ NO
FIELD ANALYSI-S:
pH oaaoo: J.�A5--nits Temp. 000to: �;i++ Lc°C
Spec. Cond. 00m,-: , ,r uMhos
Odorecoa5: - n _
Appearance �[
AS
DRY al
time of '
sampling,
check
here:
LABORATORY INFORMATION
Date sample analyzed:
Laboratory Name: � ,,Ce /tlz G�1 CCg£� �J�rr/lG_ S cL.�C Certification No-"7 71 3
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N costs
mg/L
Pb - Lead oio51 uglL
Coliform: MF Fecal 3itiw
1100mL
Nitrate (NO$) as N oo62o
mg/L
Zn - zinc WON mg1L
Colfform: MF Total 315o4
/100mL Phosphorus: Total as ? oo6+ s
mg1L
(Note: usn MPr: rnmt 1d (r,rhtghty turHd 5tmptm)
Orthophosphate ,osnT
mg/L
Other (Specify C:omp)urtds and Concentration Units):
issolven' Solids;Total 70ce0 3 i
mg1L
Al - Aluminum of ,'25 -�Q
mg1L
`jam 1 ire c��; ;l
pH (Lab) 00,103 ,
units
Be - Barium 01oc,1
uglL
TOO oorar,
mgli-
Ca - Calcium oohls
mg/L
Chloride 00940
mg1L
Cd - Cadmium 01%.7
ug1L
Arsenic olo-92
uglL
Chromium: Total oiom
ug1L
Grease and Oils oow
mg/L
Cu - Copper 010:12
mglL
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 3273o
ug/L
Fe - Iron o10 5
ug/L
(Specify test and method #, ATTACH LAB REPORT.)
Sulfate o0s45 4402 9
mg1L
Hg - Mercury rlsoo
ug/L
Lab Report Attached? ❑ Yes (1) ❑ No (0)
pecific Conductance 00095 S
µAAhos
K - Pclassium op^52
mg/L
VOC 76732: method P,
Total Ammonia o0eto
mg/L
Mg - Magnesium 00a27
mg/L
method /F
,Amrnontn P➢1rcr!m:.H, as H; Ammonia an ogon, retai)
Mn -Manganese o10ss
ug1L
method
TKN as N 00625
mg1L
Ni - Nickel 010+37
ug/L
method 9
For Remedlation Systems Only (Attach Lab Reports): Influent Total VOCs:
-,1 af�n .� rrse ��/', �r; ���t9✓�fi3l..�s!Stl �f> a -f5 ' 7'Y'�
Penmtlee (or Authorized Agent) Harnfaand Tittt: - P Ioase print or type
GW-59 Rev.212010
mg/L tcttiuent 1 otal vuus: mg/L wu

SUBMIT FORM ON YELLOW PAPER ONLY
o .
DEP,_R-rMENTOF."VIRONMENT:$:.NA'(URALR£SOURCES;;::;';.;;,: ::;.:.,.
GROUNDWATER QUALITY MONITORING:
,�
qI�+1SIDHO.�iVATER(aC1A):ITY'NFORMATiONPRQCESSiNGUNt7y.:_:..:.
COMPLIANCE REPORT FORM
2617M%6l5RVIC8.CENTEWRALEIGH.NG27699.1617. Phon6:[phone] ".::'
FACILITY INFORMATION please prim cleadyorType
PERMIT Number- . Expiration Date: l!•_ G Gar
;
Facility Name: AdU�p°.� �✓2�
Non -Discharge J!C
NPDES
Permit Name (if different):
Facility Address: 3
TYPE OFt RP4I7TED OPERATION BEING MONITORED
!'�
agoon ❑ Remedialion: Infiltration Gallery
ts:.n.x7
l-County ; f rJr2 y1
❑ Spray Field ❑ I:emediation:_
Contact Person: �Gr..�ttdGt,�l ��t�,rEfn.%,�
Telephone#: d ��-.;� �vZ>-1
❑ notary Distributor ❑Land Application of Sludge
Well LocatiorifSite Name:�lj a-f�l � /l�� p yl�. �q
N . No. of wells to be sampled: _ `y�_
❑ Water Source Heat Pump ❑ Other:
SAMPLING INFORMATION
WELL ID NUMBER (from Permit): �• �ccv n
Date sample collected: 2FIELD ANALYSES:
!f WELL
WAS
Well Depth: #4 ft.
Well Diameter:,r14 in.
pH 00,00:(c, }:`� units Temp. ocoso: � i � IS-,;
DRY at
Depth to WaterLevel s25e6:�� - ft. below measuring point
Screened Interval N,4 ft, to f - ft. Spec. Cond. coo--: 1 r1 AN-1hos
time Ofsampling,
Measuring Point is �44 ft. above land surface
Relative M.P. Elevation: ft.
Odorooaas:
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here:
Samples for metals were collected unfiltered: DES ❑
�,.�,✓`
NO and field acidified: ['YES ❑ NO
LABORATORY INFORMATION
Dale sample analyzed: 411W8 - i � (}
/� I //
Laboratory Name: f1�a�ra, r_c L >Pr14��' S_ �� L— Certification No. • j %j,.�
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. v
'
COD co335 mg/L
Nitrite (NO2) as N 006t s
mg1L Pb - Lead oiosl ug/L
Coliforrn: MF Fecal 31616 /100mL
Nitrate (NO3) as N o062o
mg1L Zn - Zinc 01032 mg/L
Cci!form: MF Total 3i5o,, /100mL Phosphorus: Total as P 00695
mg/L
(P,bt9: US:; SA�h merlx7d r.r ht�hh/ IJa:Id 5�mp1E5)
OrOrthophosphateTor,77
mg/L Other (Specify C;vmpounds an.,d v oncen.ration Units):
issolved Solids:Tota! 70300 fr �� mg/L
A! - Aluminum of tos� / yy^
mg/L
pH (Lab) 00003Zn, f ✓ units
Ba - Barium 01007
ug/L
TOC ooese mg/L
Ca - Calcium oo916
mg/L
Chloride 0094o mg/L
Cd - Cadmium o1o27
ug/L
Arsenic 01002 ug/L
Chromium: Total oio:i:
ug/L
Grease and Oils 00552 mg/L
Cu - Copper oto't2
mg/L ORGANICS: (by GC. GC/MS, HPLC)
Phenol 32730 uglL
Fe - Iron otc is
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 (r,^i' mg/L
Hg - Mercury 71800
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
"pecific Conductance o0095 pMhos
K - Potassium o0S37
mg/L VOC 73732: _, method it
W
Total Ammonia 00610 mg/L
Mg - Magnesium OOS27
mg/L _, method
(Amn,or.,a nwoti—:?1.H,as N•Ammonia mtmq ,ToaL)
Mri- Manganese oic5s
ug/L method
TIN as N oo625 mg/L
Ni - Nickel Oter,7
ug/L method m
For Remedintion Systems Only (Attach Lab Reports):
Influent Total VOCs:
.1 c �j) •.lJ P S�"l.LSG'(Lc (9 , �uf1? L}"i, 9 f' 4� 1
Permittee (or Authorized Agent) Name and Tille - Pleass pint or lype 1
hev. L/LVIV
Effluent Total VOCs
mgfL VOC Removal%

1­'AceAnalAcal
:rrrnp3teas�smm
i
June 29, 2010
John Reuscher
Delta Environmental Consultant
8008 Corp. Center Drive
Suite 100
Charlotte, NC 28226
RE: Project: ALCHEM, INC.
Pace Project No.: 927'1890
Pace Analytical Servics-s, ;rat.
2225 Zivarsic'2 Dr.
Asheville, NIC 28804
(828)264-7 t 7S
Pj eAnatjDtW SerACES. )ns.
9800xincav"Wa, suit. 't00
Huatersvilla, MC 28M
(706)876•9092
Dear John Reuscher:
Enclosed are the analytical resulls'for sarnple(s) received by the laboratory on June 2`1, 2010. The
results relate only to the samples included in -this report. Results reported herein conform -to Ahe
most current NELAC standards, where applicable, unless otherwise narrated in the body of -the
report.
Inorganic We'1 Chemistry and Mal' Js anelyses were performed at our Face Asheville Iaboraiory rind
Organic testing was Performed at our Pace Hun'tersviile laboratory unless olbenrAse •footnoted_ AJl
Microbiological analyses were performed at the laboratory where the samples were received.
if you have any questions concerning this report, please feel -free to contact me.
Sincerely,
Kevin Gochvin
kavin.god rvin�pacelabs<com
Project Manager
Enclosures
REPORT DF LABORATORY ANALYSIS
This eaport shall not ba raprotluced. eXcept in t<dl,
without lha writte n wnsant of Paos Analydoal SsrAM.: lac..
occp,�
rage •t of 90

,VaCeAnalocdl
-..• »•atiraaoraaccam
Project: fiLC�Y 4t, 1�1C.
P70o Py0je :t NO.. V27'18—
Asbevilte Cerbilmbon IDS
2225 Riverside De, lshavilla, NC 28804
Connecticut Carltilcation P: P-H-0.106
rlorlda/MLAf' Cartiilcatinrl N: EtMMIS
ouisianall-ELAP Certtficaliori t): 103005
�rlassachusetts Certification � i iMM030
Ne,,l Jersey Cartiiication V: NCO-N
North Carolin_I Bioass<ly C^rt'r nalion r=: 9
North Carolina brinkirlcl Dilater CertiTication -P: 37792
f'ac l'nyT3;ic�l'S�rl} ea, )ne.
2 25 11i'lvSkle Dr.
V,Rhavill;:, me 2880e
(s2a)254: (17s
CE) IFICAMANS
Morro Caroiiasl ir11a< a,l: rtar Cartincaborr
Perrz.ri'tsrl+�i Ce'rzMllcvrf uc 9: 8a-?3b78
SL).vlh Carolirr=l lioels.=,:,y Garbs"icetion ': �J�C3002
South Caloba CarMc.,z)?ion �,,: 9903001
fennassm Carilyhui or ;k 2980
Virclinia f.ErStic_;tic;7' is 00C12
W siVrctiniaCcrtilica6crn �, •i
REPORT OF LABORATORY A'NALYS)S
-i hic report viall wi be raprociucad, eacept in ;ail,
Witbout the vrrittan consent of PaeE Arnalytica! ,C.arricas, the
Pace Analyftz).SirvSCsa, Inc.
9000 Kinc--ytiva. 5uita lOO
` aftl8r"lilla. Mc 2607s
(704)375-SO✓3
P;}0e 2 0l •lo

E NICE. An-O `)b o) Snriicea, Inc• Pact An3;ylir;3J SC' lcaS, hoc.
ac�Ar iyficai 2223rlble(AktaO:. R900Kinmy,3vz. Suite'i00
:•lshzvill2„ N!C 2080d Huntersrilla, 28078
»:nepsr�'ahcccrn
/ ... ('J.'t`?,)2v;-%'i%^o [phone]
Project:
ALCHEMJ, INC.
pace rrojact wu..
i710�o
Lab JD
Sample ID
927189600/
PA`r?1-1
9271896002
NIW-2
9271896003
WN-3
D27.1896004
57REA"'A
SAMPLE SUMMARY
PrJairix
Date Collac,ed
Dale Received
Water
08/21/10 08:0J
08123110.1•3120
I later
0612111D 08:35
OW71110 T):20
W.,00r
061211'10110;'t5
OW111011:20
)NIzemr
06/21/ 10 C0.25
03121/ 10 '11:20
REPORT Of LA-BORATORY ANALYSIS
7his report shall not be reproduced, aacepl in hAl.
,ithout the -Nrilten consent 01 Pace Analytical Szrric=_s, Inc. -
pag
e 3 0l '18

,AceAnaly�cal
J .. w�,•acpa:azhscan
Ps0;1 tt: ALCH_N), N%IC.
Lab ID - Sample )D
DM 89600'1 ?,'11PM
927.1'II98002 VW-2
9271098003 b9lw—s
927/695004 87RE,AM
P;�ca.Ano)y8ca) Sarha-vS. lnc.
2225 P.,wecskl8 Oc
,Ashy-01a, MC 2880"
[phone]
SAMPLE ANALYTE C'D'llN 7'
Arle2hod
SPA M11D
c'PPW 1120. 4
SIM 2UDC
SNl 2:110D
PA DO 410
f•1STsU) D 1&W
F. P+i 80'1 D
;_PA 11210.11
SIM 2b110C
SIM 2x,AOD
EPA 90,30
,tAST,LI D& 38••DO
cP+1 so10
11:?s',1)20.11
SN123=10C
SM 2-540D
CPA 90110
rAS 1 N11)b'1 v-DO
EPA o0'1D
EPA -)20.1
J1412J110C
SM 2540G=
cPA 9040
ASTP/I D5,18-90
-RE*POR7 'CIF LABORATORY AN,AI.�'' S
This rapofi sna)} not be '"(0 LICSCI, SAce57t }n lu11,
xriSzout tt,e ,rriNan consant of t'aca 1nelytical Sandces, ;nc..
Pacs Anaiylic.nl Serv}cas, Inc.
9800 Kincey dbra. Suitt •t00
' Wntacsaillc, MC 28078
(7 (Ift)87b•J092
.Ana)yles
,AnnAj53s
Repar3etl
Jat)tn;
•)
Kt; l
,
AIL Br}
1
aaL1~a
'i
NIUM,
SAJ
1
Jitril,U
1
5D)•1
1
!dLi41
•{
A�1LPrl
9
MUM
1
SF,J
1
JitRtnl
'I
NILM
I
AALM
NUM
I
J%1J
RAID)
I
SDH
IIM ,1f1
!
i<dLtlrl
'1
iAL�A
1
SAJ
I
Pop 1104 18

. ceAna4dical
,J
wwxpacda)c can
Project: ALCHEN), INC..
Symple: Pv WA
F'arwileters
6D9D ME7 ICP
Alurninurn
'120.I Specific CcDducL-)nGQ
Specific Conductance
254DC 7oia1 Diszolved Solids
7o?al Di55D1 Jai? Scd!ds
254OD'Iola1 Suspended Solids
Total Suspended Solids
DO40 pH
PH
ASTm D516-90 atel
Su!fate
Puce Analylkal Svvic a, )ns.
2225',•iiverside De.
Ashaniite. aIC N804
(828)25d-7175
ANALYTICAL RESU' LTS
Pace Anotytica) rAcra.. Inc.
98,110 l(inc&'JPere. Sufis 400
I-iuMersVitt:, MC ^_5078
(704:)075-S09'!
Lab M. 9271;896001 Collected:
06121110 03:00
Recaivad: 08/24/10 91:20 klalrix: 1Pl--atar
Results Units Report Urnil DF
Prepared Analyzed CAS 1Mm. Q'Ial
A'nalylica) Method: Er A 3010 Preparation Nleftcl: EPA MID
71110 ucg/L
IQ0
06/23P10'10:20 DS/211/'1017:93 74129-0-5
Arnriylical Nlcthod: 1 PA 4 20.'!
TID tlrnhos/crn
10.0 1
08/28/10 '14:3r1
inahf?ic �l it,letho&l SNJ 2540C
63O mCh
25.0 '1
m23110 18:1.2
Ana;,Nllic_119dathDd: SM 2540D
'183 rag/L.
8.3 1
061231,10 22:38
AnaAflicai dAelhod: ERA 9940
33 Std. Units
0.10 I
O8/2 :/10 17:07 �I"o
:Analytical I)Aethod: ASTM D516-90
36$ rncl/L
/5.0 l0
06/25110 '13:20 14808-79-8 Fd
Dale: 08r'292010 -REP JR7 OF LABORATORY ANALYSIS Page 5 01,16
This report shah not be raproduc2d, except In h;11.
,vithoui the written corlssnt of Pace An?lytic0l Sanricas, Inc..

.'ace A»;+Tjticn) SBrv}6u3, Inc. 3r:�r„ dlnah/?iCo! 8ervisns, 3nc.
. ���n�� f' 2225 Ri�r2rsi(!2 J]r. 9000 lCincsy:s+ra Suit; 'i00
f
/ ,Py.,�ceUL! Asnsvilla, ?,IC 2980", ' Iunlersvl8a.'SC 28078
xm
toaa)as�?-rI7S t70,g875-mq2
ft
A3dALY11;vAL RE-S-ULTS
�'rojact: : ;L C'r•1ci+B, IMC,
sample: iy)k17-2
=ir�rri�?•ar;
3 ,ab )D-, :92TIT96002 Collected: 0612'31'10 08:3S
Residts UnRZ report Limit DF
-8ecaivad: 0512'1130 '1'1:20 NIsWiX btlater
Pfepsrecl Analyzed CAS No. Clsaeri
6030;' ET ICP
t•`jnsd+r?ica). i+Rzth .l: =F+N 0010 Preparalion rlrlat,:od: 1CPA 3010
U300 ucr?
100 1
O6l23/90 10:20 081241'10 -17:41,0 7429-90.5 .
A lurfimurn
320A Specl bo cond=3117C4
AnahRtcn41�jja'inou: `PA 120.1
Spedfiic. Conductance
20.1 urnho81Cfn
'10.0 ')
UOf2a/70 I1:3=5
26,40C 7ota) D%50,vecl SO)itls
:lnalytical iUTe'had: S11f1.25400'
-io)al Dissolved Soikis
• '133 rn31L
250 .r
06/231-ID •1.813
2640 7ot.11 Suspended 8o11&t
Anaiyfta) Mat'fiod: Sill) 2540O
;atsi) Suspanded Solids
3l8 ritNA
10.0 )
06/231'10 22:39
quo p})
Anol ykal +iMl Ihot): EPA DO 40
4.13 Sad. Units
GACI )
08/24)110'J7:07 YY6
a+-)
eAS710 D636-90 SuNIT3e ` MET
t1,naIy?ica);1jIeftd: ASTNI 0516-90
MUL
'10.0 2
06/25/'10'1310 1480$-7M
Sulfa'la
.48:8
Date: 0612V2030 13:113 AdIll REPORT OF LABORATORY RY ANALY898 �
This report sija1J not be reproduced, except in full.
vyithout the YfrMen consant of Peca AnNYticat Seorices, Inc.

?aco,\nnlyYca?Ssr:i^.ea.Jnc. Pnca.Ana?ytic;,?Seriic•ss,)nc.
fYJ rlc /inra�y��n��R 222artivar3iQ_7,: 9f1C0:(inG�/1H. Sufic^.900
C{l� / 91l'Sd�}�a8>UO�af ; :',shavills, Nc 2UEJ4 lantbrsri{lY.,mC 23078
1' (f728)2a 717E (70 i)ftt5-9U�:
ANALYTICAL RESULTS
Pace: Projact No.: D271C�-8
Sample: MV`1-3
Lab )D: 9271S96003 coliecIed: 0a/21/1010-A
itaceivad: OV-21P10 11:2.0 PrtatriU: ?plater
P�JrJrnat,£rs
t'i=sul2s Uruts Rapnrt Limit LlF
-r:,r_ireti rlrraly<ed CAS vU. �lua1
S09D MET )CP
:-+nal;Y,c:d Wa?bml: EPA 80'10 Prep_vation Nlathocl: Ei''A 3010
Aluminum
I
3$000 ut1/L '100 1
00/23/101020 0S/241'10 17:5o 7429-90-5,
! 120A Speribc conductance
An-@101:a» i&Ielhot: EPA UNA
S peci'It . Conductance
'05 1l 6has/cm 10.0 '1
0SINI' 0 '10:39
2540C Tali] DissoNed 8o11r;`s
Ara!j6C,5t1't+.d ?hcXI: SPIT 2:=)OC
Total Dissolved 5olide.
334 rngd! 25.0 1
0cf23Pt0 1&13
2540D Tola) Suspended Solids
Anal+Rica! i'1)athod: SNI2&,'00
Total Suspended Solids,
319 rncl/L 12.5 •1
OS/23/10 22:39
D040 pH
Amlylica) irlath00: EPA 9040
PH
3-7 SIC). !)nits (.10 1
Oo12V I O 17:07 Flo
ASTM 051S-90 SuNme WWer
,Nrralytic-)) Method: ASTNI D51S-90
Sullata
•429 fncVL '100 20
US/.25/10 ?3:23 11) U-79-b
Date:OS;2cJ12010'i't:latAdr9 EPYJR7 dJ1 LABORATORY ANALYSIS Page 7of 'IS
7ni;. report shall not be reproduced, accept in 1ui1.
nMoot the wr'ittan consant of ?ace Analytical SYnrices, lnc.
.` c yc

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6Ct. sling are+, rtanuF){ CCbG %O'p!c%arpsl SLi FGJf�f��r/G
A
ov{'ssacr,tactes{iR{t:u�raotc� _u{ sasvJ.ag;co{.i�(t`•uyana'!

a�aAr>saPy�ica1
P(nJa0l:
Pace Paijact NV- C.L 1'I VDF,
9aiGetlnohjticn} SrrvSGea, ?nG.
2223 iiiv2 oida Dr.
tic. 28604
(828)254•7378
-01):AUTY G:ONTROL DATA
C2G Eatcir: itAPr2Fl85S7 ;5n�hisbs itta'?nod: EPA Z0')0
QC Batch ??tathod: EPA 30110 ",rtaSysis t�2scription: ^0030 N1E7
1sSociatedLabswo..0)Es: 927S3Eto00't,92.ii3JoUrl, ?T'IO Oi?3>J27'ISc3o00r;
rid;='fH0i3 BLANK: �35cJncJ=' ����..—_ T !rfa4ri:r. 411sr?ur
ASsoeiak'.(1 Lab +rapSas: 927'1396001, - 713WID02. 9e%'?i!JS�+L�9, cJ27't8sJo00r3
G11_SYtA i(2}1L+rtIRQ
P=rrama?rr Umis Raa;.k _ - Limit AnOyzad Quslifiera
N0 1Cv; Ni241.10 '1 "i: e!
3>ace Anv)ylk a) Sm v5G es, Inc.
9800 Kincey -Alre. SWR2 100
t•)untarsri?)£. +\SC 28078
L��s70=2*i'fni•'i`fC0?I'f;:2ni.s;ldr�?L�: r)5�R.t
Spike LCS LCS % Rsc
Pararn2'ta'r ilrri?s Cone. Result % Rae Limits _ Qualifiers
Aluminum uJL _ 5000
dRATRV SPIKE SAMPLE: S159£J�i
927'1890001 Spike tills NIS % Reo
Par�rsrsisr Uniel i2astidt Cone. Result % Rsc ^! imi�ts__� G)u_diliars _
9 oo i ^ 'IS2 75-'325 Pd0
,NurnirIum u�L
5�,41fl`_r ;�iJP11C:\ice: <;o9ncJ5
Ct2f489o002 GLIp +INAm
Paz2m�?ar Uri; . i2asi+t? F�Estt12 RPD IRPID_ Glu�!'rliars_
Aluminum ucdL 10300 t'tdOp 'to 20
Da'?e: OSl2�20.10 '1 t:'!t};1;<r': R.EPOR? .Of LABOAATORY ANALYSIS
This report' Sham not bs reproducad, except i,n MI.
;,irnoui Ana vmi?an consent Services. Inc.
Page J0115

Pas ° ARalylicl)) JCr`/ICE'S. U)L.
J /i�JE
2225 side Of.
�+
/! L4 Am4tical
Tlshavilla^� t\iC 28804
,-, M
QUAL17Y COTT7RO•L .DA7A
Project; .�1LC!•!;_dri, �i`iG.
!'Glln ti f'rJ�dCl J.. Lam••
OC SatcYl: YIET112302
E?A 420.9
L1C S=Itch i+Aethod; EP'\'f?CL't
asr�:/sis Dsscriptlan 120.-1 Snacitic Conductance
Associated Lab Sarnplas: 927't09o0D1, 9?Tf�s9S002
d71fYF)QD sGLt11V1C: <2ii2228
APa?ria: Ylatar--
Associatad Lab Samides: 927.139"0004, V27UG 002
OialtR Rapor(ing
Pararnatar Units
;..,., :1rn:y�ad Oua,liiiers
2<.�ull Limit
Spactlic Condudt MCE;
D,
?ac:ztlnalydica) Srrvte.e3.lnc.
980D Kinc-ay Ava. Suiia 100
HuilrervAlle. MC 2801E
[phone]
LABORATORY CONTROL SAN)PLF: 4M?-rJ�
S;o t2 LGS LGS % tac
Pammater Units Conc. Rasu)t % Rec Lirrlit'_— DUaiiliarS
Specific Conductance ----� urnnoslcrn �'1=:10-'100
Sf\MPLE DUPL1GME:- 482230 -
927'1450002 D> p II/Nm
r, Z•asult Result RPD ftPD
rnenuai'rtiars
Parater —.-_ `_--
Spacitie Conductance - - urnhoslcrn - ^ 009D 09100 0 20
Date: 05/29120.10 1.1:14 AJ11h
REPOR7.OF LABORATORY ANALYSIS
This report steal; not Ds• repralucad. aaCSOt in tuft,
vathout tha v rwen consent of Pace,+lnayicat Sarlicae, Inc..
Page '10 04 t o

� , c�A.rt�lytrcaf
J wr'Upacl M., ca a
rloj£c>.: :\LC;i_14I, )MC.
OC B'Qoh A&,tnod: ERA 12 0. 1
Associaled Lab Sarnp)es: 927"WKEI03, 9711 JSOD'J
iliff-fHOD BLANK: 11,82257 T
:,:soctatad Lab Samp)Frs: ',) IBM0DJ, 927.18-EUD4,
paramatar L'1•+i?s
• Sp=chic Conch4ct<)r,c;a curulOS;C'!A
Pa es �ln 97 rii cal S ervi c ra. b>c.
2225 Riverside Dr
Asievilia. NC 28801;
t82a)2s 3•-r�r -rs
QUALITY ,CON1 7ROL DATA
1lrlafys>r• �llet'r,oci: Erg;\'J2U.'1
Analysis Dzsc-ripbc A: 91D.9 S;oac'rnr. Ccnductav:cr
J)eri;t RcpOiilriCl
Zst:lt Limit r'matysad C11.kililiFos
Paco A naly tic a) Services. )nc.
9800 Klncay,ays. SuR_')00
1•iunlars,dlls. A1C 28078
(70,1)@76-9,092
L;17OR+t70FiY COU7?OL Stl��??! E: �Jb223z�
Sci ca LCS LCS %, Rac
EanulFtar Ur+it . Cone. Res. t % r�ec L)tfl'rl:. UL4aI'riie!$
SpeciRc CorlductancF - r_-- wnhos/crfr'irJ'10
SAMPLE DUPLICNrE: 482259
J2718�JnDD r Dup M-J;(
7aramaisr Unlit: Result Result R°D RpD Ouatirars
spedliic COrK)uct1nCe-•_"-_•-- urrinoslcrrr - 805 892 — - D —�-•+ 20 ~--
Dai'e:05/2J/20101•I:'11;AM RF-.PORT OF LABORATORY ANALYSIS
This moor' snarl riot be reproduced, axcaq? in hilt,
ftur the written conssat oI Paca Anal tic;,) Sarricas, Inc..
PEIge 'J1 01,15

,AceAnaiyfica!x
F'ac'c AlmlylIca) Sari rm.5, Inc.
2225 RivVside Dr
Asnavi)le, dIC 2800<5
(a 20 )254- 7'175
QUALMI CONTROL DATA
Project: ALCi-lEM,1MC.
PP cE Projacl No.: &27130S ,
QC Batch: VIE711284-4 Analysis Method: SM 2540C
QC Batch tNlathod: SM 2540C An-alysis 7escrip:rvI: 2540C Iota) DSsn)vatl Solids
a.>.,..;,.>�.n t ..,. C_,mnla� 9979R7nt1!i•t. n2Tid=Jn002. 927189o00:i. 9tf'239o00�1
YiTce A;)'Wylical Snrvicrs, Inc.
9900!(inc3vras. Suile')00
�)Un?ersville. NIC 290'r's
[phone]
i<AETHOD BLANK: 1380481 4iatti r. Mlats r
;\szocisaed Lab Sarrtplaz: 92718g500'i, 9271898002, !D27'ti9600.3, 927189000=1
giant( Reporting
pararnFlar Units R•asult Limit Analyzed QL1'NViers
7Dtai ihssolved Solids 25.0 Oo(23"i IO
L'1IIOR.1 fOR`T CONTROL SA)MPL E : A50462�—
Sp)1(e LIDS LCS % i <cC
pararnetar Units Cone. Result % Rac Limits Qualifiers
Total Dissolved Solids — mgk -- 250 228 91 80-120
SAMPLE DUPLICFlf£: 480483
pararnetar
-fotai Dissolved Solids
Date: 0812 W20'10 '11:14 ANd
9271822001 Dup i4)ox
Units Rasuit Result RPD RpD Qicaliflcrs
rnc�L --- �— 14300 911300 ) —•� 20 •—
REPORT OF LABORATORY ANALYSIS Pacle •12 of •16
This report sliall not be reproduced, except In full,
without tns• erritten consent of Baca Analytical Services. Inc..

rc�ggp
k`
f' U Pacg+lnajl?iC?7758'lvicea.Inc. i',�cs9ln.�ly?Yc��:�+ErvScu3,10c.
r'
l 6$JOGjj rl. iJGJG l•Kainncta2ry%braSu7225 Rivvsicts Dr. svit, �:C 280
0
VrtryzbSCOM AsheviCs, SC 29304
! (87.8)25':-r•r %"o (704)0"r'5-9092
-Q:UA.L17Y COiJ"iROL DA7A
Pro}2ct: ALCrlENI, HMC.
EC aatch: tvE fM2,,M ll L� ,Analysis iriatnod: SIM 25,10?D
CSC Balch 1IMalhod: 5)?112b•<S0D Analysis D£scriptior?: 2.5400'(01d Susparn)20 Solid.
sociat..,ci L=to Satrapies: 92r,,,89o0✓1, 92(•13MOD2. 92I 329ODD3, 927.189800=1
bdE7h10D rCLt,NS(: 4560604 DISa'tri:i: IPIa'tar.,...�..._____....�.. ----.-.---..—.. -,._
Associated Lab Samples: 9i7';O:Yc•Dvt, 9271098M, 9271MOO-9
Sian. Reporiioc
Par-Wrialar Units. Ri Smll L'rraS't %lrraiy!ed C)tial'rii2rc
Total Suspenciaci Solids mg1L ----•- .----- MD v.-~- � ` Oo!^c.Y=D 22:37
LALMWORY CONTROL SAMPLE: 480205 M~---_--_,__.—
Soit£ LCS LCS %Rac
Pamma4er Units. Con. Result % Rn Urnits Ou'll"hers
7ota1 Suspencled Solids r,^c1'•- 250 230 92 80-120
SANIPLE DUPLICNfc: 1160805 -- --
927203400.I Dup dl'ax
Pararnet2r UrMa. Result R'c^SUIt RPD RP'-) - Ous;Sliers
Total Susp£nr3scl Solids -_ -_� rncJL �34 --- --- 123 20
Dais.: 05129120'101-1:14AtA REPORT OF LABORMORYA?R1ALi'M
This rsgort shall not be racroduc,-d, SRCBOt in w,
;without the vvitten consant of P. Analyficai Ssrviczs, Inc.
Page 13 ofi I

EAnaljdical
lY�x;til+lfrOStCm
PVCtAT3aTjYical S4T%6CQ3, )nc.
2225 FiNerside Dr
„sy2riRa, iIN1C 2001"
la!18125<5,717!�
QUALITY CONTROL DATA
P'f�jac2: i\LCl•iEtLI, tAi�.
,i14 G. 114}l Y.C1 !'iV.. vti/•>Lv:r
Q� latch: VVE T/12063 --- 1'nal9sis drlE3ho0: ?t19€1s10
QG II..Itch srlethact: EFTA DUD ,tAn<)lysis NScrfpt)en: 901;0 PM
31v,SOCi=)tetll.abSa'rnples,: �?7't5.�o004. t�279Fi1J"n00?,92Tt89o003, 92""/')i3��o0ttr)
92TM49001 Uup
i waynE(af
S.W. Units - 8.0 S.0
D-Ma: U812912010.1.1:14 ANI REPORT -OF LABORATORY ANALYSIS
-rhis report shall not be reproducers, except in tuil.
1thouttnE.vuittanc,;onsentofPaceAnaiyticatSenftcas, Inc.
Pace AnaiYbca) Serficea, Inc.
f)800 Mr-cey""M SWE:100
luntaesslla, SC s^II07J
��o=;}L<7a-9092
411ax
(PO Qun�iliws
HS
Uac}2 '14 of '1 S

%aceAr�afyifcal„
g/nY [W-0, M MI)
• Pucs.+lr>,tyL:':ol SAKIViC83, Inc.
2225 uvarsida Dr
P"Shw ia, CSC 28804
[phone]
aQUA UT Y CONTROL DATA
Pro!. -CZ:
P < 2!1,SNZ
1C c etch: tP/r"if�!?SOt3 t' natysis Ma Rod: AST4t D518-W
aC tBa?Ch 11)o�)hod: ASTNI D5'6o-90 Ar&jds Dasceiption: ASTM D518-90 Sui"tat& V11atar
Associated Lao Sarr:o!aS: 9.27•)89000'), 0271U3002, 027189oDD3, 927't89o001S
;mE-7i!OD UN-N)K: 46,1422 Y Motmt:—
:'Issoci_;?zd Lai, Sarrtpias: 027'S39o00't, 9 7189E002, °J2-('iS0o003, 027'139000=1
t
Stank 'r"teportinr
Pararnatar Units. R2su11 t-irni't
Suiiaia rcJL — Mr/ -- = 0 00/251.11, '!2:55
i'as^ e1nD'ryti::DlSsrflcrs, ):nr..
9800 K!no2y Ave. Saila '(00
:-lunrarsvitla, Mc 28078
(70=:)875-9022
LrZ�Oi?,47OR'(COM7rtOL S Itll=Li
4814,23 —
Spike LCS
LCS
% 'Zee
Pwarna4ar
UnR,4
Cone. Rasu{; % Zac
Lirnil<
Qu_ liners
Stt!7.1tt -��
rac -�
20
? I t
?O5
90-'t'10
kj) VRV SPIKE SAN)PLS:
=10'142=,
9.271855001
Spike
d11a
143
% Rae
Para7natar
Unita
Result
Cone.
tics 11
% Ra(.'
Ltrni,s 10 a)i11 Era
Salta?a --��
M01-
1at1fR1;( SPIKE SANIPL-
=lE'1=S.2o
i;
927-17370'10
Spike
MS
itI1S
% F't2c
Pararnaiar
Uni"s
Result
Conc.
Ress)1
% �i2c
Lirnsis Oualiisars
Su!tata
rntt/L
AID
20
'MD
0 75-'1?51r10
i,(%1)PLE DUPLICATE! =)0'1=)25
92-i'189o00'1
Duo
('An;(
Parirnetar
Units
Result
i7asult
�tPD
t?r'D
Clua(ilisrs -
SutN,ta
20 R'1
SAMPLE DUPLICATE: '40':1M
9271737011
Dup
dria:(
Pararnatar
Ui-rits
-Zasult
—
_ rtP7
- F(PD
0tualiiars
Sil!tata
n�3
`Result
MD
1XSD
20
Dai�:0o/29120'10'1'!:4=)1111 REP -.CRT D•FLABO—RA,�TORYANALYSIS
'aka950140
This report shall not ba raoroducad, aaceot in'rull,
yithout (hacritter, consent of ?ace Am)ytical SeNices, Inc..

1!9aceArialyficalo'
1
QI.A1.1r)Efita
Frq ac?: ALC�)c<k), INC.
DEF1NMONS
Par c Azo)yticn)
2Z2S
y.c,C„ } !V6:Solo^ . ,.
h),shav)lia, MC 2MM
(82&)254-7175
na.e r;n;iA3tica) Serircei, )nc.
9&OOitinceyrwa. Su�la'100
'rlunie(sv)l)a, MC 2 OW$
(r04.)& 75•01092
DF - 0!1ution Factor, i- izp to d, rc,.phE rrs:haiaC,ior SI-Pp!iad in tbF I rtad d-al, dua is ch-tngas in sarnpla preparation, dihilion o'i
;ha sample a t;tle; or ale;mILva. co.;QerF1
ME) - Nol Dziacted a'>.COY E-;Wss'sdlii'vit.
J - ESIlrn9'led cor!cantra')ion lilaava )hc au us Fd rna?hod dalnlion !11M? amd balms the attjus?ad r<;por,incj limit.
iNOL - Adjim?ad (1J). ?hod Cr•lact:an Urmi?.
S - Surratiat
•t,_`-Dip'nsrr/Its/tlra�ina {0.2'1&� i`�::eil _,r,•a'sys^r•} tiicornoos o to s\2obanzans.
Cor)sistanl Mlh E If, c)ttitla?i s, w1ro 1'Adat) osl?a ar^. displayad arld hvia 0^cart used zo CalculaiP % raaCOVafy wnd Values,
iCS(D) - U)malont Conpo) Sarrr9l (Dupfica'3a)
P1la3h;t Spike {Dt;aP:c,s•)
DU? - Sample Duplicala
RPD - Relo6va Pvrcaol CiMahence
MC - -Not Caicu)abh,.
U - indicates iha cornp0urid +,rat, anafyzud'?Or. bu? not detactad.
s�2 i�3i?rosot)ip?ranylarrtlna dact>rrrcozas and cannot fla saparaZed -horn Dipheny1mina using ilA.Mod 0270. The result reporiad -or
amb analyle is a corabinad cur.Mnuatiorr_
Pace Amily?ical is 3SEL.AP acvL-dRBd. COMM? yotu P.Ma PM 10? ?ha currant HS'i al accradRad an_,lyles.
ANAL`/ E fU)ALVIERS
Ma Amlysis ipitia eti rr(ora than '6 rnimtias a' -tar SMr(ple CollecZiO,).
Ado AAartrix spikes racovery ar(dlor .rnsraix spike duplicate lacover; avw. ortisida IslflOralon) control -units
R'l RPD valu,- 4, w 32. ta-;take czrlirOt !IrJilis.
Dale: OS/2W201011:14 ANi REPO:R7 'OF LABORATORY ANALYSJS age 'l �, o-1 S
this report she,; not be reproduced, eacept in Mi.
without Gia wdi ar, consent of Papa Analyvcal Services, Inc.

The is a LEGAL 000UI.SENi.All roFsvnhi irNGa bus; Go �:ttplai�d a�ctvaiJy.
mht.pA60!Pnx.cnm .

J Itrc,cny CC II
.. .............
-D
LJ
. ..........
.... ...... . ..
NV-7
-7
..... .. ... ......
............. ............
X
91AIL09i XICh57ORING WLLL
rv)) \•'s•.`. •' \ Irr.EP )ADMIDTONG MLL
\, :4�. — VIA7ER—SUPPO YELL
PRO."FJOY DUMDARY
FENCE LNE
RAILROAD 'TACKS
MON)TORING WELL LOCATION MAP ILL— 5ED805096P
ALCHEM, )NC.
ro/p/0- rlly—�,--I/ll
D E LIA RQCKWELI., NORTH CAROUT
NA —11E.

APPENDIX C
GW-59A AND GW-59 FORMS (OCTOBER 2010)

.xW-'S9A 1;_' \7f,,. 3�i.�t�3.!'v i`, it �I<� -r ��� V). '•
(,S�r bwhoe each mnnitorin" l;erirul mi7i: (rl'i -w jbrmS.J -
.
Enter date monitoring results were due. (Zztt2 I Will this monitoring report (GW-59 and GW.59A.)
YES
NO
2
be submitted after the established due date?
Was any required information missing on the GW-59 report forms?
YES
-
NO
IF the answer to question I -or 2 is 'YES', list in the space provided below the well identification number(s) and
i
explain the problems encountered in obtaining the required information.
Si i� �laP�7 /�i�.s iJ�y', ',i i�1�/� �'�=�T� �, �,r�, •S�l ��n i�i LS U�Cr?L
CGGL�C�i✓ � .
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgroyvn, etc.)? !/'the answer is "Yes", contact lire Regional Officefor guidance.
4
Are any monitored constituents equal to or above the established standards?
ES'
NO
if the answer to question 4 is 'NO", skip to section 8.
If the answer to question 4 is `YES" list the affected wells individually with constituent(s) and concentrations)
11,
1
exceeding standards in the space provided below,
IA
For.the constituents identified in question 4 above, have standards been exceeded previously for the
YES)
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is 'NO", skip to section 8.
if the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
istandards,
concentration('s) reported, and sample collection date for each occurrence (for the last two years).
�
I
J
(y
Are the monitoring wells listed'in section 5 located at or beyond the review boundary?
YES(
NO`
if the answer is "YES'; a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO'; monitoring wells may be improperly
located; contact the Regional Office.
Is the permittee implementing previously approved actions required by the Division involving this
(YES
NO
i I
1
groundwater duality problem?
3
I
_
If the. answer to question % is "YES", describe those sections in the space provided below -
--J
If the answer to question 7 is "hip`; contact the Regional Office within 90 days: an evaluation may bP
required to determine the imnact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subiect the vermittee to a Notice of Violation.
fines, and/or penattles.
I
I
The person completing £his portion (GW-59A) of the monitoring report should sign below- and submit this
form with GSM--59 forms for required wells to the address provided at the top of the current GW-69 form.
I hereby acknowledge that the above information was evaivated and the information submitted in this
report (Compliance Report GW--59A) is:true and•complete'to the best of my knowledge.
_nip tri.i✓ii.Fhr�«-- ,�P-�•f7% f..,.C'v�SI,G��l�i'l.•t'j ,/`/--�—j�
Signature of Permittee (or Authorized Agentj f� �� l,� �� _/_' pate
//�

SUBMIT FORM ON YEL.. _,N PAPER ONLY
GROUNDWATER QL{!gt_tTY MON1T©RtNG:TMW�,,.�o
sa
COMPLIANCE REPORT FORM
•
o o a .
i
FACILITY INFORMATION
Frlease Prinf Ckar.V or 7ype
PF
Facility Name: Alchem, Inc
No
Permit Name (if different): _
NF
Facility Address: 8135 Red Road
T'V
Rockwell "" NC
28i38 County Rowan
Contact Person: Randall F. Andrews
�r Telephoneg: 910-843.2121
Well Location/Site Name: MW-'I /Alchem, Inc.
No. of wells to be sampled: 3
SAMPLING INFORMATION
WELL ID NUMBER (from Penmit); A4ta' 1
X Date sample collected: 10/20/10
VVell Depth: 48�ft,
\Nell Diameter: 2 in.
Depth to Water Level 82546: 19.86 ft. below measuring point Screened Interval: 38 ft.
tc 48 ft.
Measuring Point is ' 806.58 —ft. above land surface
Relative M.P. Elevation: 805.58
fl.
Volume of water pumped/bailed before sampling:
13.8
capons
Samples for metals were collected unfiltered: Z
YES
❑ 140 and field acidified: 0 YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: 10-22 to 10-30-10
Laboratory Name: Pace Analytica_i Services, inc.
PARAMETERS NOTE: Values should reflecttdissolved
and colloidal concentrations.
COD o0335
mg/L
Nitrite (NO2) as N 00615
mg/L
Coliform: MF Fecal 31616�
�110OnL
%100mL
Nitrate (NO3) as N 00620
�mg/L
Coliform: MF Total 31504
Phosphorus: Total as P o0^065
_
(Note: Use MPrlrnethodtot hlghi , turbid samples)
Orthophosphate 70507
_mglL
*solved Solids:Total 70300 1260
mg/L-Al
- Aluminum o1105 52.40
^mg/L
mg/L
J
pH (Lab) ooe.03 4.5
units
Ba - Barium o1oo7
_ug/L
TOC ooem
mg/L
Ca - Calcium oogi6
_mg/L
Chloride 00940
mgll.
Cd -Cadmium 01027
Arsenic 01M- 2 � q
ua/L
ChromiUm: Total 01034 �
� Rug/L
Grease and Oils oo552 _
mg/L
Cu - Copper o1042
rng/L
Phenol 32730�
ua/L
Fe - Iron 01045
_ug/L
Sulfate 00945 661
mg/L
Hg - Mercury 719oo
y ug/L
'pecific Conductance 00095 1360
I.Whos
K - Potassium 00937
_mglL
Total Ammonia oomo
mg/L
Mg - Magnesium 00927
-emu
w.. tlmg/L
(Ammonia Nitrogan; NHaas N; F-,mtronla RiIogen. Total)
Mn -Manganese 01055
_ug/L
T KN as N oos25 _
mg1L
Ni - Nickel 01067
ug/L
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
RMIT Number: Expiration Date: 11-30-07
n-Discharge UiC
'DES Other l"1Q0002702
PE OF PERMITTED OPERATION BEING MONITORED
® Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
FIELD ANALYSES:
pH 00400: 4.58 units Temp. ocolo: 15.65
Spec. Cond. 00094: 1630 pMhos
Odor 00085: None
Appearance Cloudy
Certification No. 37712
Pb - Lead o1051 ug/L
Zn - "Lino otow mg/L
nC DRY at
.-- time of
Other (Specify Compounds and Concentration Units):
TSS = 722 mglL ..-_
here: 0
ORGANICS: (by GC, GOIMS. HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Peport Attached? ] Yes (1) ❑ No (0)
VOC 78732: method # _
method
method #
method
mg/L Effluent Total VOCs:
mg/L VOC Removal%
John D. Reuscher, P.G., Delta Consultants J 1 11-5•SO
Pennittee (or Authorized Agent) Marne and Title - Please print or type aignaFr, a of P.M. (or thorized Agent) (Date)
GW-59 Rev.2/2010 J

GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
or
=acility Name: Alchem, Inc `
'ermit Name (if different):
=acility Address: 8135 RedRoad
Rockwell ::w: — NC 2313%>
SUBMIT FORM ON
County Rowan
PAPER ONLY
ict Person: Randall F. Andrews Telephonem: 910-84' 2121
Location/Site Name: MW-2 /Alchem, Inc. T w No. of wells to be sampled: 3
WELL ID NUMBER (from Permit): MW-2
Well Depth: 35 ft.
Depth to Water Level 62546: 21.42 ft. below measuring point
Measuring Point is 793.74 _ft. above land surface
Volume of water pumped/ba-iled before sampling: 6.6
Samples for metals were collected unfiltered: 0 YES ❑
PERMIT Number: Expiration Date: 11-30-07
Non -Discharge UIC _
NPDES Other W00002702
TYPE OF PERMITTED OPERATIOM BEING MONITORED
® Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Fieid ❑ P,emed'iation:
❑ Rotary Di:>:ributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other
Date sample collected: 10/20/10
Well Diameter: 2 in.
�w�
Screened Interval: 25 ft. to 35 h.
Relative M.P. Elevation: 793.74 ft.
gallons
NO <
YES ❑ NO
FIELD ANALYSES: -
I'M 00400 5.00 units Temp. 000io: 16.83 °C
Spec, Cond. 00094: 304 µMhos
Odor coos5: None
Appearance Clear
Date sample analyzed: 10.22to 1030-10
_
laboratoryName: Pace A alyticai Ser.--ices, Inc.
Certification No. 37712
PARAMETERS NOTE: Values should reflect nissotved and colloidal concentrations.
"""
COD oo335 _ .___�.
mg/L
Nitrite (NO2) as N 00615
rpg/L
Pb - Lead mosi uo/L
Coliform: MF Fecal 31516
/100mL
Nitrate (NO3) as N 00620�
_mg/L
Zn - Zinc 01092�- mg/L
Coliform: MF Total 315o4
11 OOmL
Phosvhorus: Total asp 00665
(Note: Use AdPN method for highy turbid samples)
Orthophosphate 7o5o7 _�--_�___,_._-.____
_mg/L
M mg/L
Other (Specify Compounds and Concentration Units):
)issolved Solids:Total 70300 27i>
mglL
Al -Aluminum o1105 20.0�
_mg/L
TSS r 444. mglL �rt�
pH (Lab) 00403 4.6
units
Ba - Barium 01007,�^T`Y,ug/L�
TOC oow
mg/L
Ca - Calcium 00916 _ _ _
_ _ mg/L
Chloride00940i
_Ingl1.
Cd- Cadmium 01027-
ug/L �
Arsenic010o2
ug/L
Chromium: Totaloio34�
yug/L
Grease and Oils 0o552�
eM01
Cu - Copper 01042Y� M
� -rng/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730�
ug!L
Fe -iron 01045
-ug/L
(Specify test and method #. ATTACH 1.A13 REPORT.)
Sulfate 009':5 128
mg/L
Hg - Mercury 71900
_ _ ug/L
Lab Report Attached? ON Yes (1) ❑ No (0)
Specific Conductance 00095 403
faNihes
K- Potassium 00937
_mg/L
VOC 78732: method fr-
�
Total Ammonia onto
mgll,
10ig - Magnesium 00927
mg/L
method r
(Ammonia Nitrogen; NH, as N: Ammonia Nitrogen. Total)
Mn - Manganese 01055�
T
_ ug/L
, method Y
TKN as N 00625 W
mg/L
Ni - Nickel oloe7
_ uglL
method # T
For Remediation Systems Only .. • • •
tr1 :
th.
• ♦ \vh•\ .v ..v \ \�.?, :i•3 vn,, \; � ....,1n• -. {, :\\. •. „\ 4., f\ -0 .. :. wV i:.:?n,- .: :v. v\v-A. Y:: �%,:.,'.L?.,- ....•.:i�>Y:•, .4: �::•\ v :.:.
. t. a.. .. \. \. \i...Z... .a., ..� ... \. .\ -. .a \�.4C.\ :,.. .a .. ...\\.,. ., .\:...<,.. .. .... ....l:x ,..a:->•:RS`:iY:<'..faiA/AY:a-�S..v:",.,�:.:,<'.,.
ti �� . s :\ � ..i � .\^. 5.. .4 .f.: .SARJ .: ..\ ..A .L. �?t�..i :-.ti\:?'3:;r'::4$;^::c;;:�i::<�>��;;`•:�<>\"::; :,,�..
F3? 7 : `a 'rtJ�£ d? i ZieIJ b3' t , : , >" .`:n:.r:. •. �aY' `<• o\�>?:i r ��.�. .. .�.� (. "#�i�tt�t. \ �!'. .t�.._.•��r o.c1..TCi�tas�;;.e: '3'sfi,t'"�>:�.'ek(ns �� .,t;:dz.�Cna\a�s'i"�s�" ,
John .-
Permittee, (or.Authorv2d Agent) Narn:� and Title - Please print or type or P mlffl�t'(o, &'.,_,ized gent) ._
GW-59 Rev. 010
at
of
X

GROUNDWATER QUALITY MONITORING,
COMPLIANCE REPORT FORM
Facility Name: Alchern, Inc
Permit Name (if different):
Facility Address: 8135 Red Road
Rockwell :':t.
NC 78138
or
SUBMIT FORM ON YELLOW PAPER ONLY
County Rowan
act Person: Randall F. Andrews , Telephone; : 910-843-2121
Location/Site Name: MW-3 / Atchem, Inc. No. of wells to be sampled: 3
PERMIT Number:
Expiration Date: 11-30-07
I;on-Discharge
UIC
NPDES
Other WQ0002702
TYPE Or PERMITTED OPERATION BEING MONITORED
N Lagoon
❑ Remediation: infiitration Gallery
❑ Spray Field
❑ Remediation:_
❑ Rolary Distributor
❑ Land Application of Sludge
L ID NUMBER (from Permit): %011-3 � � Date sarnple collected: 10/20/10
Depth: 35 {x, Well Diameter: 2 in.
i to Water Level 82s46:34.70 ft. below measurillCl point Screened interval 25 f, to 35 ft.
wring Point is 808.56 ft. above laid surface Relative M.P. Elevation: 808.`,6µ -it
ne of water pumped/bailed before samp!irg: 0.0 - _gallons
Aes for metals Were collected unfiltered: Q1 YES ❑ NO and field acidified: ❑ YES ❑ NO
Water Source Heat Pump ❑ Other:
FIELD ANALYSES: WAS
PH. 00400: units Temp. 000to: pC • DRY at
time of
Spec. Cond. c0094:�µk4hos sampling,
Odor 000ss: check
Appearance Only enough .eater to collect sample (here:(—,
Date sample analyzed,10-22 to 10-30-10
Laboratory Name: Pace Analytical Services, Inc.
Certification No. 37712
PARAMETERS NOTE: Values should reflect disso€ved and colloidal concentrations,
COD o033:i � �
mg/L
Nitrite (NO2) as N 00,315
mg/L
Pb - Lead o10t;t ug/L
Coliform: MF Fecal 31616�
/10t]n1L
Nitrate (NO,) as N ooe2o
mg/L
Zit - Zinc 010:32 mg/L
Coliform: MF Total 31504
/t00m1-
Phosphorus: Total as P 00665
w �mg/L
(Note: Use MPiq metlyd fcr highly turbid samples)
Orthophosphate 70507
' '�•
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 7(t3o0 2310
mg/L
Al - Aluminum o1lo5 260.0 _ mg/L
TSS = 336 mg/L
pH (Lab) 0040:3 3.6
units
Be - Barium 01007
u ug/L
TOG 0008a
mg/L
Ca - Calcium 00916
mg/L
Chloride C0940
mg/L
Cd - Cadmium 011027
M� J ug/L
�
Arsenic 01ao2
ug/L
Chromium: Total 01034
ug/L
Grease and Oils oo552
mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, I -{PLC)
Phenol 3273'J
110/1-
Fe - iron oto45
ug/L
(Specify test and method N. ATTACH LAB REPORT.)
Sulfate oo945 1480
mg/L
Hg - Mercury 71900
ug/L
Lab Deport Attached? P3 Yes (1) ❑ No (0)
�pecifte Conductance oao95 1630
µmhos
K - Potassium 00937
^. mg/L
VOC 78732: method
Total Ammonia cmlo
mg/L
Mg - Magnesium G0927
and/L
method #
(Am.ttonta Nitrogen; NFI,a:: N; Ammone P!itrogep,lbt2i)
Mn - Manganese 01055
ti ug/L
, method n
TKN as N o0625
mgl_
Ni - Nickel oto67
ug/L
method ;C
For Remediation Systems Only (Attach Lab Reports):
Influent Total VOCs:
mg/L Effluent Total VOCs: mg/L VOC Removal%
t et t t•
,fl � _ .. .w . o - . t _ .� . :�
t < e -
.... : t'J . ati . t .,• e
..
- -it
t a o
o f
w l
� t .., . ° .-
e
a
John D. Reuscher, P.G., Delta Consultants
tit = i 11-5-10
Permute. (or Authorized Agent) Name and Title - Please print
rSfonatule of Permlitee (or Authorized Agent) (Date)
GVU-59 Rev.2/2010

GROUNDWATER QUALIFY MONITORING:
COMPLIANCE REPORT FORM
=acifity Name: Alchem, Inc
'ermit Name (if different):
acility Address: 8135 Red Road
Rockwell ' : ...
SUBMIT FORM ON YELLOW PAPER ONLY
or
NC 28138^^ County Rowan
sct Person: Randall F. Andrews
Location/Site Name: Stream / Alchem, Inc.
Telephone#: [phone]
No, ofwells to be sampled: 3
Number: Expiration Date: 1
haroe UIC
NPDES Other WQ0002702
TYPE OF PERMITTED OPERATION BEING MONITORED
® Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other: _�_
WELL ID -NUMBER (from Permit): Stream
Date sample collected: NA
FIELD ANALYSES:
WAS
Well Depth: NA ft.-
p
Well Diameter: NA,
in.
pH 0os0o: units Temp. 00010:' °C
DRY at
Depth to Water Level 825,16: NA ft. below measuring point
Screened Interval: NA
ft.. t(:• NA ft.
_
Spec. Cond. 00094: ft11A110s
time of
---
Measuring Point is NA _ fr. above land surface
----
Relative M.P. Elevation: NA
--
_ 11.
------- ---�-
Odor aoos5:
sampling,
check
T_ Volume of water pumpedibaile9 before sampling: NA
galions
Appearance Stream was dry at the time of sampling
here:t- :t
Sam fes for metals were collected unfiltered: ❑ YES 071 NO and field acidified: ❑ YES
® NO
LABORATORY INFORMATION .
_
Date sample analyzed: NA _
Laboratory Name: NA
Certification No. NA
PARAMETERS NOTE: Values should reflect dissolved and
colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead oio51 Ug
t"
Coliform: MF Fecal 31616` /100mL
Nitrate (NO3) as N 00620
mg/L
Zn -Zinc oloszT mg/L
Coliform: h9F Total 31504� /100mL Phosphorus: Total as P o0665
mglL
_._mg/L
(Note: Use llPNmethod lo hfgi,lyturbid samptes)
Orthophosphate 70507
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 703oo mg/L
Al - Aluminum 01105
�� TmgIL
pFf (Lab) 004-034 units
Ba - Barium oloo7
_ug/L
T OC 00680 ing/L
Ca - Calcium o09i6
mg/L
Mug/L
Chloride o0940^ mg1L
Cd - Cadmium 01027
Arsenic 01002 ug/L
Chromium: Total 0s034
�ug/L
Grease and Oils 00552� _mg/L
Cu - Copper 01042
�mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32720_ ug/L
Fe - Iron 01045
_ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 0o945` mg/L
Hg - Mercury 71900
_ _ug/L
Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00t95 µMhos
I(- Potassium 00937
—mg/L
VOC 78732: method #
Total Ammonia ooa3o mg/L
Mg - Magnesium 00927
�mg/L
method # ^
(Ammoniz Nitrogen; NH,as V: Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625 mg/L
Ni - Nickel 01067
t1g/L
method #
For Remediation Systems Only (Attach Lab Reports):
Influent Total VOCs:
mg/L Effluent Total VOCs: mg/L VOC Removal%
t t g .
NQ
v�
IFS xx:
John D. Reuscher, P.G., Delta Consultants �• D� l 11-5-10
sir
Permittee (or Authorized Agent) Name and Title- Please p-int or type Signa - 'Permittee (o-i"AUthorized Agent) (Date)
Gl-N-59 Rev.212010 // J

AW
�1 %{ p� / /+ f G Pace Analytical Services, Inc.
.! aceA lalXit.ral 2225 Riverside Dr.
/ smi.pacelaftcom Asheville, NC 28804
(828)254-71 %6
i
November 01, 2010
John Reuscher
Delta Environmental Consultants
8008 Corp. Center Drive
Suite 100
Charlotte', NC 28226
RE: Project: ALCHEM, INC
Pace Project No.: 9280334
Bear John Reuscher:
Pace Analytical Services, Inc.
9800 KinceyAve. Suite =
Huntersville, NC 28078
Enclosed are the analytical results `For samples} received by the laboratory on October 21, 2010.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted, All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely;
i
Kevin Godwin
kevin.godwin@pacelabs,com
Project Manager
Enclosums
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without ilia written consent of Pace Analytical Services, Inc..
[phone]
Page 1 of 35

!fI Pace Analytical Services, Inc. Pace Analytical Services, Inc.
,,Ral ceAnali J� feel 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
-- ) Asheville, NO 28804 Huntersville, NO 28078
4'h'NlpHce18DS.fA11t
[phone] [phone]
CERTIFICATIONS
Project: ALCHEM, INC
Pace Project No.: 9280334
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
North Carolina Drinking Water Certification #: 37712
Connecticut Certification #: PH-0106
North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648
Pennsylvania Certification #: 68-03578
Massachusetts Certification #: M-NCO30
South Carolina Bioassay Certification #: 99030002
New Jersey Certification M NC011
South Carolina Certification #: 99030001
North Carolina Bioassay Certification 4: 9
Virginia Certification #: 00072
REPORT OF LABORATORY ANALYSIS Page 2 of 35
This report shall not be reproduced, except in full,
wieiiGvi t,i& vvriufsn corscnl of "ace Analytical Serviees, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
'PaCeAnaljl ical 2225 Riverside Dr. 9800 Kincey Ave, Suite 100
wavipacolabs.wrn Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
Project: ALCHEM, INC
Pace Project No.: 9280334
Lab ID Sample ID
9280334001
MW-1
9280334002
MW-2
9280334003
MW-3
9280334004
MW-4
9280334005
MW-5
9280334006
'MW-6
9280334007
MW-6D
9280334008
MW-7
9280334009
MW-7D
9280334010
MA-8
9280334011
MW-9
9280334012
IWW-10
n280334013
Agkmf_11
9280334014
MiVv-11 D
9280334015
MW-12
80334016
MW-120
9280334017
WSW-2
9280334018
WSW-SHiRLEY (FORMEP.
ANDERSON)
9280334019
WSW-DANIELS (BARBARA)
9280334020
WSW-SAPAPLES
9280334021
WSW -BEAVER
SAMPLE SUMMARY
Matrix Date Collected Date Received
Water
10/20/10 08:30
10/21/10 14:40
Water
10/2011010:40
10121/10 14:40
Water
10120/1010:15
10121/10 14:40
Water
10/20/10 09:30
10/21/10 14:40
Water
10/20110 09:30
10121/10 14:40
Water
10/20/10 08:00
10/21/10 14:40
Water
10/20/10 08:30
10/21/10 14:40
Water
10/2011012:30
10/21/10 14:40
"later
1012011013:30
10/21/10 14:40
Water
10/20/1013:45
1012111014:40
Wa ter
10/20/10 15! 15
10/21/10 14:40
Water'
1012011014:50
1012111014:40
Water
10/21/1011:00
10121/10 14:40
Waier
10/2111011:30
10/2111014:40
Water
1012,1110 08:30
10/21110 14:40
Water
10/21/10 09:30
10121/10 14:40
Water
10/20/10 09:55
10/21110 14:40
Water
1012011011:00
10/21110 14:40
Water
10120/1012:00
10121/10 14:40
Water
10/20/1011.40
10/21/10 14:40
Water
10/2011011:20
10/21110 14:40
REPORT OF LABORATORY ANALYSIS
This report sha!I not be reproduced, except in full,
without the written consent, of Pace Analytical Services, Inc..
Page 3 of 35

p-V F
e
j-.1�aceAna1Xical
mwepac0abs.com
i
Project: . ALCHEM, WC
Pace Project No.: 9280334
Lab ID Sample ID
9280334001 MW-1
9280334002 tM-2
n230334003 i4G113
9280334004
MW-4
9280334005
mW-6
9280334006
MAI-6 .
9280334007
MW-6D
9280334008
MW-7
9280334009
MW-7D
9280334010
M W-8
9280334011
POW-9
9280334012
row-10
9280334013
MW-11
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
I-iuntersville, NC 28078
[phone]
Analytes
Method Analysts Reported
EPA6010
SHB 1
EPA 120.1
SDH 1
SM 2540C
MLM 1
SM 2540D
MLM 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA6010
SI-IB 1
EPA 120.1
SDI-1 i
SM 2540C
MLM 1
SM 2540D
MLM 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA6010
SI-IB 1
SDH
SM 2640C
MLM 1
SM 2540D
MLM 1
EPA 9D40
MLM 1
EPA 300.0
EWS 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA9040
MLM 1
EPA 300.0
EWS 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA 9D40
MLM 1
EPA 300.0
EWS 1
EPA 9040
HALM 1
EPA 300.0
EWS 1
EPA 9040
MLM 1
EPA 300.0
EWS 1
EPA9040
MLM 1
REPORT OF LABORATORY A.ieALYS IS
This repori shall not be reproduced, except in full.
without the written consent of Pace Analyiieat Services, inc..
nelad .
Page 4 of 35

f.
ff Pace Analytical Services, Inc.
�Jt+t3�pt111{jl+ 2225 Riverside Dr.
UVI� vmwiipacceeelabl..con Asheville, NC 2II804
[phone]
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
i-luntersville, NC 28078
[phone]
Project:
Pace Project No.:
Lab 4D
ALCHEM, INC
9280334
Sample ID
Method
Analysts
Analyses
Reported
EPA 300.0
EWS
1
9280334014
NqW-11D
EPA9040
MLM
1
EPA300.0
EWS
1
9280334015
W1A1-12
EPA 9040
MLM
1
EPA300.0
EWS
1
9280334016
MW-12D
EPA9040
MLM
1
EPA 300.0
E1/\lS
1
9280334017
WSW-2
EPA9040
MLM
1
EPA300.0
EWS
1
9280334018
WSW-SHIRLEY (FORMER ANDERSON)
EPA 9040
MLM
1
EPA 300.0
EWS
1
9280334019
WSW-DANIELS (BARBARA)
EPA9046
MLM
1
EPA 300.0
EWS
1
9280334620
WSW -SAMPLES
EPA'9040
1,01-hh
1
EPA 300.0
EWS
I
9280334021
WSW -BEAVER
EPA9040
MLM
1
EPA300.0
EWS
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced• except in full,
without the written consent of Pace Analytical Services. Inc..
•t,..
held&:
Page 5 of 35

Pace Analytical Services, Inc. Pace Analytical Services, inc.
nal tical 2225 Riverside Dr. 9600 KinceyAve, Suite 100
1 UU Analytical j Asheville, NC 28804 Huntersville. NC 28078
ah+�.pacelabs.corn ,
[phone] [phone]
ANALYTICAL RESULT S
Project: ALCHEM, INC
Pace Project No.: 9280334
Sample: MVV-1
Parameters
Lab ID: 9280334001 Collected: 10/20/10 08:30 Received:
Results Units Report Limit DF Prepared
10/21/10 14:40 Matrix: Water
Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Aluminum
62400 ug/L
10000
100 10/22/1011:15 10/2711016:03 7429.90-5
120.1 Specific Conductance
Analytical Method: EPA 120.1
Specific Conductance
1360 umhos/cm
10.0
1
10/30/10 13:16
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
. 1260 mg/L
25.0
1
'10122110 18:46
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
722 mg/L
8.3
1
10/26/10 19:05
9040 pH
Analytical Method: EPA 9040
PH
4.5 Std. Units
0.10
1
10/22/10 17:41 H6
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
0-4fate
661 mg/L
250
50
10/28/1015:58 14808-79-8
Date: 11/01/2010 01:55 Pis REPORT OF LABORATORY AfillLli_` IS
This report shalt not be reproduced, except in full,
without ttte written consent of Pace Analy'Jcal Services, Inc..
Page 6 of 35

Pace Analytical Services, Inc.
i ce F 1 , nal Racal 2225 Riverside Dr.
jy dt Asheville, NC 28804
vnwtpacelahaccm '
[phone]
ANALYTICAL RESULTS
Project: ALCHEM, INC
Pace Project No.: 9280334
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Fluntersville, NC 28078
[phone]
Sample: MW-2
Parameters
Lab ID: 9280334002 Collected: 10/20110 10:40 Received: 10/21/10 14:40 Matrix: Water
Results knits Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICI
Analytical Method: EPA6010 Preparation Method: EPA 3010
Aluminum
20000 ug/L
100
1 10/22/10 11:15
10/26/10 21:36 7429-90-5
120.1 Specific Conductance
Analytical Method: EPA 120.1
Specific Conductance
403 urnhos/cm
10.0
1
10/30110 13:17
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
276 rng/L
25.0
'1
10/22/10 18:46
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended'Solids
444 mg/L
16.7
1
10/26/10 19:06
9040 pH
Analytical Method: EPA9040
pH
4.6 Std, Units
0.10
1
10/22/10 17:41 HG
30u.0 IC Anions 26 Days
wri'rytieal'M ttrod: EPA 300.0
^.11fate
128 mg/L
25.0
5
10/2811013:14 14808-79-8
Date: 11/0112010 01:55 Pill, REPORT OF LABORATORY ANALYSIS
This report shall riot be reproduced. except in full,
without the written consent of Pace Analytical Services. Inc..
Page 7 of 35

i Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e;
/G}�np /1r1 jt�iJL,rj( 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
/ _.- i i.iLe f al 1 a Asheville. NC 28804 Huntersville, NC 28078
mi pacelabs.com
[phone] [phone]
ANALYTICAL RESULTS
Project: ALCHEM, INC
Pace Project No.: 9280334
Sample: MW-3
Parameters
Lab ID: 9280334003 Collected: 10/20/10 10:15 Received: 10/21/10 14:40 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
6010 MET ICP
Analytical Method: EPA6010 Preparation Method: EPA3010
Aluminum
260000 ug/L
500
5 10/22/10 11:15
10127/1016:52 7429-90-5
120.1 Specific Conductance
Analytical Method: EPA 120.1
Specific Conductance
1630 umhos/crn
10.0
1
10/30/10 13:17
2540C "Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
2310 mg/L
25.0
1
10/22/10 18:47
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
336 mg/L
16.7
1
10/26/10 19:06
9040 pH
Analytical Method: EPA 9040
off
3.6 Sid. Units
0.10
1
10122/10 17:41 H6
300.0 IG unions 28 Days
Analytical Mathud: EPA 300.0
"•-Ifate
1480 rrrg/L
250
50
1012811016:22 14808-79-8
Date: 11/01/2010 01:55 PM REPORT OF LABORATOR ► ANALYSIS
This report shall not he reproduced, except in full,
wiftut Vie written consent of Pace A siytical Services, Inc..
Page 8 of 35

�, Pace Analytical Services, Inc. Pace Analytical Services, Inc.
/�.�y j��n4��+�� 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
/ `o j't Asheville, NC 28804 Fluntersville, NC 28078
t vnn�pacelahs.conr
[phone] [phone]
QUALITY CONTROL DATA
Project: ALCHEM, INC
Pace Project No.: 9280334
QC Batch: MPRP/7281 Analysis Method: EPA 6010
QC Batch Method: EPA 3010 Analysis Description: 6010 MET.
Associated Lab Samples: 9280334001, 9280334002, 9280334003
METHOD BLANK: 515876
Matrix: Water
Associated Lab Samples: 9280334001, 9280334002,
9280334003 .
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Aluminum
uglL
ND
100
IW26/1020:2
LABORATORY CONTROL SAMPLE:
515877
Spike
LCS
LCS
Parameter
Units
Conc.
Result
% Rec
Aluminum
ug/L
5000
4720
94
MATRIX SPIKE SAMPLE:
515878
9280295001
Spike
MS
Parameter
Units
Result
Conc.
Result
.aminurn
ug/L
103000 5000
105000
SAMPLE DUPLICATE: 515879
Parameter
Aluminum
Date: 11/01/2010 01:55 PV
9280295002 Dup
Units Result Result RPD
ug/L 10200 10100 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analyticaf Services, Inc..
Qualifiers
% Rec
Limits Qualifiers
80-120
MS % Rec
% Rec Limits Qualifiers
48 75-125 MO
Max
RPD Qualifiers
20
Page 27 of 35

m Pace Analytical Services, Inc. Pace Analytical Services, Inc.
la
/�r�ryhltr; � 2225 Riverside Dr. 9800 KinceyAve. Suite 100
ri�}1�1,L�tac}'olaica Asheville, NC 28804 Huntersville, NC 28078
QUALITY CONTROL DA` A
Project: ALCHEM, INC
Pace Project No.: 9280334
[phone] [phone]
QC Batch: WET/14294
Analysis Method:
EPA 120.1
QC Batch Method: EPA 120.1
Analysis Description:
120.1 Specific Conductance
Associated Lab Samples: 9280334001, 9280334002,
9280334003
METHOD BLANK: 520557
Matrix: Water
Associated Lab Samples:' 9280334001, 9280334002,
9280334003
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Specific Conductance
umhoslcm
ND 10.0
10/30/10 13:11
LABORATORY CONTROL SAMPLE:
520558
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
S 'f Co d t n e
umhoslcm
1410 1410
100 90-110
pea Ic 11 uc d c
SAMPLE DUPLICATE: 520559
9279975001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
_pecific Conductance ulnhos/cm ND ND 20
SAMPLE DUPLICATE: 520560
9280071004 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Specific Conductance umhoslcm 134 132 2 20
Date: 11/01/2010 01:55 PM
REPORT OF LABORATORY ANAP(SIS
This report shall not be reproduced, except in full,
without the written consent of Pace AnalyticalServicas, I
p� 5
rG Lela;
Pape 28 of 35

y Pace Analytica§ Services, Inc. Pace Analytical Services, Ina
e
a�G ���f t /f`� ! 2225 Riverside Dr. 9800 I<incey Ave. Suite 100
/J VAw".pacelahscom Asheville, NO 28804 1-!untersville, NO 280-18
[phone] [phone]
QUALITY CONTROL DATA
Project: ALCHEM, INC
Pace Project No.: 9280334
QC Batch: WET/14195 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 9280334001, 9280334002, 9280334003
METHOD BLANK: 516735 Matrix: Water
Associated Lab Samples: 9280334001, 9280334002, 9280334003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids rng/L ND 25.0 10/22/10 18:44
LABORATORY CONTROL SAMPLE: 516736
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 244 98 80-120
SAMPLE DUPLiCAT E: 516737
Parameter
.al Dissolved Solids
Date: 11/01/20 10 01:55 PM
928024200*1 Dup
Units Result Result
mg/L 58.0 67.0
Max
RPD P.PD Qualifiers
14 10 D6
'REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
:(roFc
"be
Page 29 of 35

Pace Analytical Services, Inc. Pace Analytical Services, inc.
c /� t7a (` 7¢ cal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
? !-Ir I !y t lr f Asheville, NC 28804 Fluntersville, NC 28078
�nnipacalaDs.cwn
( [phone] [phone]
i
QUALITY CONTROL DATA
Project: ALCHEM, INC
Pace Project No.: 9280334
QC Batch: WET/14227
ota
Analysis Method:
SM 2540D
QC Batch Method: SM 2540D
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 9280334001, 9280334002,
9280334003
METHOD BLANK: 518087
Matrix: Water
Associated Lab Samples: 9280334001, 9280334002,
9280334003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Total Suspended Solids mg/L•
ND 2,5 10/26/10 19:03
LABORATORY CONTROL SAMPLE: 618088
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
T 1 S ded Solids rrig/L
250 224
90 80-120
aspen ,
SAMPLE DUPLICATE: 5.18089
92802-16001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Aal Suspended Solids mg1L 4080 4190 3 10
Date: 11/0112010 01:55 PM REPORT OF LABORATORY ANALYSIS Page 30 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
:`helk',

pr..
vnrrvpacelabscom
i
Project: ALCHEM, INC
Pace Project No.: 9280334
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WET/14188 Analysis Method: EPA 9040
QC Batch Method: EPA 9040 Analysis Description: 9040 pFl
Associated Lab Samples: 9280334001, 9280334002, 9280334003, 9280334004, 9280334005, 9280334006, 9280334007. 9280334008,
9280334009, 9280334010, 9280334011, 9280334012, 9280334013, 9280334015, 9280334016, 9280334017,
9280334018, 9280334019, 9280334020, 9280334021
SAMPLE DUPLICATE: 516205
9280334006 Dup Max
Parameter Uriits Result Result RPD RPD Qualifiers
pH Std. Units 3.8 3.8 0 20 H6
SAMPLE DUPLICATE: 516206
9280334020 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH - Std. Units 6.8 6.8 . 0 20 FI6
Date: 11/01/2010 01:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
-nela6-
Page 31 of 35

�f o Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aAnal�iicaf 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
-." �nnal (laica Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: ALCHEM, INC
Pace Project No,: 9280334
QC Batch: WET/14189 Analysis Method: EPA9040
QC Batch Method: EPA 9040 Analysis Description: 9040 pl-1
Associated Lab Samples: 9280334014
SAMPLE DUPLICATE: 516207
9280306001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pla Std. Units 9.7 9.7 0 20 1-16
Date: 11/01/2010 01:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
.without the written consent of Pace Analytical Services, MO..
Page 32 of 35

c / F Pace Analytical Services, Inc. Pace Analytical Services, Inc.
ceAnalt tica� 2225 Riverside Dr. 3800 Kincey Ave. Suite 100
/// t� as.cvm Asheville. NO 28804 Fluntersville, NO 28078
rnlnhpacje7h
[phone] [phone]
QUALITY CONTROL DATA.
Project: ALCHEM, INC
Pace Project No.: 9280334
QC Batch: WETA/8436
Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 9280334001, 9280334002,
9280334003, 9280334004, 9280334005, 9280334006, 9280334007, 9280334008,
9280334009
METHOD BLANK: 517196
Matrix: Water
Associated Lab Samples: 9280334001, 9280334002,
9280334003, 9280334004, 9280334005, 9280334006, 9280334007, 9280334008,
9280334009
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Sulfate
mg/L
ND 5.0 10/26/10 20:19
LABORATORY CONTROL SAMPLE:
517197
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Sulfate
mg/L
30 30.9 103
MATRIX SPIKE SAMPLE:
517198
9279858002 Spike Ms.
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Sulfate
mg/L
ND 30 25.4
85
MATRIX SPIKE SAMPLE:
517200
9279858003 Spike MS
MS % Rec
Parameter
Units.
Result Conc. Result
% Rec Limits Qualifiers
Sulfate
mg/L
ND 30 13.6
45 Mo
SAMPLE DUPLICATE: 517199
9279855002 Dup
iJiax
Parameter
Units
Result Result RI'D
RPD Qualifiers
Sulfate
mg/L
ND ND
SAMPLE DUPLICATE: 517201
9279858003 Dup
Max
Parameter
Units'
Result Result RPD
RPD Qualifiers
Sulfate
mg/L
ND ND
Date: 11/01/2010 01:55 PM
REPORT OF LABORATORYANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
jQ�j ypC J�Ct
L HCac i
Page 33 of 35

r
Ill,-Pace
�e Pace Analytical Services, Inc. Pace Analytical Services, Inc.
1��ff!l�1L�! 2225 Riverside Or. 9800KinceyAve. Suite100
rral�lp cjelaabts.com Asheville, NC 28804 Fluntersvilte, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: ALCI-IEM, INC
Pace Project No.: 9280334
QC Batch: WETA/8437 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 9280334010, 9280334011, 9280334012, 9280334013, 9280334014, 9280334015, 9280334016, 9280334017,
9280334018,9280334019,9280334020,9280334021
METHOD BLANK: 517202
Matrix: Water
Associated Lab Samples:
9280334010, 9280334011,
9280334012, 9280334013, 9280334014,
9280334015, 9280334016, 9280334017
9280334018,9280334019,9280334020,9280334021
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Sulfate
mg/L
ND 5.0
10/27/10 08:53
LABORATORY CONTROL SAMPLE: 517203
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Sulfate
mg/L
30 31.8
106
MATRIX SP!)<F SAMPLE:
517204
9280334010 Spike
MS
MS % Rec
Parameter
Units
Result Conc.
Result
% Rec Limits
Sulfate
mg/L
38.8 30
51.3
42
MATRIX SPIKE SAMPLE:
517206
9280334011 Spike
MS
MS % Rec
Parameter
Units
Result Conc.
Result
% Rec Limits
Sulfate
mg/L
ND 30
12.7
42
SAMPLE DUPLICATE: 5*17205
Parameter
Sulfate
SAMPLE DUPLICATE: 617207
Parameter
Sulfate
Date: 1110112010 01:55 PM
�280334010
Unity- Result
mg/L• 3II.8
9280334011
Units Result
mg/L ND
Dup rfiax
Result RPD RPD Qualifiers
38.2 2
Dup Max
Result RPD RPD Qualifiers
ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
wilhout the written consent of Pace Analytical Services, Inc..
,'� R elac
Qualifiers
MO
Qualifiers
MO
Page 34 of 35

ceAnalgical 0
j tmnvpowlahs.cora
QUALIFIERS
Project: ALCHEM, INC
Pace Project No.: 9280334
DEFINITIONS
Pace Analytical Services, Inc.
2225 Riverside Dr -
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
I-luntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is NELAP accredited. Contact your Pace Pik for the current list of accredited analytes.
IALYTE QUALIFIERS
DE The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H6 Analysis initiated more than 15 minutes after sample collection.
Mo Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
Date: 11/01/2010 01:55 PM REPORT OF LABORATORY ANALYSIS Page 35 of 35
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
-nela :

PaceAnalyfical"
w•vw.ezcolahs.com
'CHAIN-01F-CUSTODY f Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
ration A Section a
quIred Client Informalion; Roquirod Project information;
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invoice Information:
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E
N
-.
SI3NATURE o{SAf.1PLER: r „� � �✓1f
DATE Signed
(MMIDDA'Y): ��� �Q

Analytical Client lime: L �� Project
Received:tlntersville ❑Asheville ❑ Eden
wrier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Cornmerciar-Ci Pace Other Optional
Istody Sea[ on Cooler[Box Present: ❑ yes Ej no Seals intact: ❑ yes ❑ no Prof. Due.Date:
Proi. Name:
icking Material: []Bubble Wrap ❑Bubble Bags ❑-None ❑Other
ermometer used: IR Gun: T809 Type of ice: et Blue None ❑, s pies on ice, cooling process has begun
rn r, rr%rrarfinn Farfnrr Acid / Sniitrant n C
p•:
irrected Cooler iem G
np should be above freezing to VC
Biological 'issue is Frozen: Yes No
Comments:
D d Initialls ff p o examining
co e i"'-�`
ain of Custody Present:
fees 0No
DNA
1.
ain of Custody Filled Out:
� ONo
ON/A
2.
ain of Custody Relinquished:
-E&�. ON.
❑N/A
3.
mpler Name & Signature on COC:
ONo
❑NIA
4,
moles Arrived within Hold Time:
-2< ONo
❑IVA
5.
ort Hold Time Analysis (<72hr):
6Yes ONo
❑NIA
6.
sh Turn Around Time Requested:
dNo
❑,
ON/A
7,
`ficient Volume:
,Yes
I res ONo
ON/A
g.
rrect Containers Used:
e Containers Used:
_, ❑No
,Y -ONo
E
❑N1A
ON/A
italners Intact:
❑Yes ONo
/A
10.
Bred volume received for Dissolved tests
❑Yes ONo
ON/A
11,
nple Labels match COC:
-Includes date/time/ID/Analysis Matrix:
OY ❑No
/
ON/A
12•
ontainers needing preservation have been checked.
:ontainers needing preservation are found to be in
ipliance with EPA recommendation.ples
ptions: VOA. coliform. TOC, O&G, WI-DRO (muter)
nples checked for dechlorination:
, wss ❑No
ONo
❑Yes ❑No
I_;Y(,s ONo
ON/A
ONJA
tt
llnitial
ONIA
13.
a
when completed
14.
�dspace in VOA Vials ( >6mm):
❑Yes ONtr
ON/A
'15,
Blank Present:
Blank Custody Seals Present
:e Trip Blank Lot ## ('if purchased):
❑Yes nNo
❑Yes ONo
_
' <A �
✓-
❑NIA
16.
;n? lgotification/ Resolution: Field Data Required? Y / N
Person Contacted: DateMme:
Dmments/ Resolution:
€JRF Review: Date: i��l 1� SRF Review Date: /�071 JU
>: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEFINiZ
ification Office (i.e out of hold, incorrect preservative, out of temp, incorrect containers)
F-CHR-CS-003-rev.01

+
C)
ODD
1�0
......
FEET
i L
I
............
4 -
P'o .ny
mw-9
............ -------
m�-7p:
xv-1
vs
ij
mv-lzb
I tea.
0
El"'v
�pv'ty
P,.p y 1
0
iJ
SHALLOW MOMIORINIG WELL
DEEP MOK11TORING WELL
WATER- SUPPLY L
FENCE uNE
RAILROAD IRACKS
V.
MONITORING WELL LOCATION MAP C149D OR [PD5EO8 5096P
:
ALCHEM, INC. daunt ne
ROCKWELL, NORTH CAROLINA jUA7E- MEV.
EDEH L-9 .tea"%� 110/27/06 07/06/101

APPENDIX D
GW-59A AND GW-59 FORMS

GW-59A COMPLIANCE REPORT FORM eaeryllit # W�`lr�._.
(Submit nNe wich ruotritoriug period (Pith GW-59 forms.)
Enter date monitoring results were due. ( Will this monitoring report (GW-59 and GW-59A)
YES
O
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
NO
iF the answer to question 1 or 2 Is "YES", list In the space provided below the well Identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged easing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the mrsiver is "Yes ", contact dre Regional Once for guidanmr .
4
Are any monitored constituents equal to or above. the established standards?
YES
NO
If the answer to question 4 is 'NO", skip to section 8.
If the answer to question 4 Is "YES" list the affected wells individually with constituents) and concentration(s)
exceeding standards in the space provided below.,
5
For the constituents Identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years).
r
rr
G
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE If the answer is "NO", monitoring wells may be improperly
located, contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
if the answer to question 7 is "NO", contact the Regional Office within 9t1 days. all evaluation 8may be
m ;erred to determine the Impact the waste dlsn9ml system is having at the review and comiWance
bounor&s surrounding this facility. Fallure to do so may sublect the nermidee to a Notice of V1214tlon.
lames. and/or og aides.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above Information was evaluated and the information submitted in this
report (Compliance Report GW-59A) Is true and complete to the best of my knowledge.
^ /
3Si1nature of Permittee (or Authorized Agent) Date
\:�&.tt' o�-A�10A'S✓1t..
€AV-59A 12/8/21103

TER QUALITY MONITORING:
E REPORT FORM
Name: fe la
Name (if different): O
Address: '9/3.S
- MMI I rVKM tJN Lcztvw rArCK UNL7
♦
or Type
County
act Person: _ ,as,, Telephone#: 211— 79dF
Location/Site Name:_/4tt% —/ fl(',.�'t� . L� s �c,- No. of wells to be sampled: _3
PERMIT Number: Expiration Date:
Non -Discharge UIC
NPDES Other 4 tVgQo�
TYPE QF PERMITTED OPERATION BEING MONITORED
IR'Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
L ID NUMBER (from Permit): l3'! G✓ E` pate sample collected: ©f lG FIELD ANALYSES: _
Depth: ft. Welt Diameter: in. ``'�� pH 4 J 9 units Temp. ��Z°C
i to Water Level: la',Q ft_ below measuring point Screened Interval: , _ft. to �Cp ft. Spec. Cond. 4 ;Z 70 uMhos
luring Point is 905, 58
ft. above land surface Relative M.P. Elevation ._�,,,,—_6ft. Odor Ivan e-
ne of water pumpedibailed before sampling_ �^ /S gallons Appearance (V e4;!,,--
sample analysed: &fj._;� — 3/i
COD
Coftrm: MF Fecal
mg/I
/100m]
Coliform: MFTotal
/loom]
(Note: Use MPN method torhighly turbid samples)
Dissolved Solids: Total
mg/I
pH (when analyzed) , l.e units
TOC
mg/I
Chloride
mg/I
Arsenic
mg/I
Grease and Oils
mg/I
Phenol
mg/1
Sulfate LZ2_____mgll
Specific Conductance �! 7 70
uMhos
Total Ammonia
mg11
- (Ammonia Nitrogen:-Ntiias N: Amfronia Nitrogen: Total) "
---
TKN as N
mg/I
❑ NO and field acidified: EYES ❑ NO
_ Laboratory Name: 7a..cE ,��g �.�-�-(Ca� t�2 nC. Certification No.-_ '7W r�
and colloidal concentrations.
Nitrite (NO2) as N mg!! Pb - Lead mg/I
Nitrate (NO;) as N mg/I Zn - Zinc mg/I
Phosphorus: Total as P
mg/1
Orthophosphate
mg/I
Other (Specify Compounds and Concentration Units):
Al - Aluminum ?i mg/I
7
Ba - Barium
mg/I
�/
G7!
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total
mg/I
Cu - Copper
mg/I
ORGANICS: (by GC, GCIMS, HPLC)
Fe - Iron
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Hg - Mercury
mg/I
Report_ Attached? ❑ Yes (1) ❑ No (0)
K - Potassium
mg/I
VOC method #
Mg - Magnesium
mg/1
, method #
Mn - Manganese
_mg/I
method #
Ni - Nickel
mg/I
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
i that the laboratory analytical data
'�� d imprisonment for knr
..,� _
Permittee (orAuthor¢ed Agent) Name and Title - Please print or type
GW-59 Rev.1/2007
VOC
at
of
N1

NDWATER QUALITY MONITORING:
TYINFORM Tp� ION- please Prtntc(eanyorType
Name:
Name (if different):
Address: g% s- r
51J1IM1 I t-UKM UN Yta_t-Uw t'Ht•tK UNLI
County
act Person:Telephone#: �yi�t'• r2.7� l `u t1
Location/Site Name: j?1�TNo. of wells to be sampled:_
L ID NUMBER (from Permit): 0.
Depth:
h to Water Level: f 5 , S ft. below measuring point
During Point is :.''. 7 ft. above land surface
Tie of water pumped/bailed before sampling: , q,3
sample analyzed:y21c—AWID - 01i/!0
AMETERS NOTE: Values should reflect
dissolv(
COD
mg/I
Coliform: MF Fecal
/loom[
Coliform: MF Total
/loom)
(Note: use ldPN method wr highly turbid samples)
Dissolved Solids: Total //1Q
mg/t
pH (wheri analyzed) S b
units
TOC
mg/I
Chloride:
mgA
Arsenic
mg/I
Grease and Oils
mg/I
Phenol
mg/I
Sulfate _ 3
-- mg/l
Specific Conductance
µMhos
Total Ammonia
mg/l
(Ammoj1 a Nitnoden, NK,as N: Ammonia Nitrogen: Total)'"-
- -
TKN as N
mg/I
For Remediation Systems Only (Attach Lab Reports):
W.0-
ittee (or Authorized Agent) Name and Title - Please print or type
GW 59 Rev. 1/2007
RMIT Number: Expiration Date: .%t/_5G
n-Discharge UIC
IDES Other Q�J0 7a
'PE OF PERMITTED OPERATION BEING MONITORED
L" Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
Date sample collected: oZ ,2/J 'O FIELD ANALYSES:
Well Diameter: nZ in. pH 41}q units Temp.
Screened Interval: 0"25 ft. to-aLft. Spec. Cond. i;2 -2- µMhos
Relative M.P. Elevation:71aiz-
ft. Odor do
gallons // Appearance 0-ka.�'-
JO and field acidified:Gr ES ❑ NO
1' e- i�trl�tt Laboratory Name--
colloidal concentrations.
Nitrite (NO2) as N mg/I Pb:- Lead
Nitrate (NO3) as N mg/l Zn - Zinc
Phosphorus: Total as P mgA
Certification No. 37 i`, !9
mg/I
mg/1
Orthophosphate
mgA
Other (Specify Compounds and Concentration Units):
Al - Aluminum 3., r �7 mgA
..1 S .5 . _-> rr .
Ba - Barium
mgA
/q-e- (,d. 5- e ked)4 ., {�
Ca - Calcium
Mg/I
Cd - Cadmium
mg/I
Chromium: Total
mgA
Cu - Copper
mg/1
ORGANICS: (by GC, GC/MS, HPLC)
Fe - Iron
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Hg - Mercury
mg/I
Report Attached? ❑ Yes (1) ❑ No (0)
K - Potassium
mg/I
VOC method #
Mg - Magnesium
mgll
, method #
Mn - Manganese
mg/f
method #
Ni - Nickel
mgA
method #
Influent Total VOCs:
Effluent Total VOCs:
VPC Removal%
at
Of.
u

:51.1k l I rUKM UN Yl--U tVV rHt'tK U1VLT
GROUNDWATER QUALITY MONITORING:
• • • •
tlft§tQNaF=iAiNFO, .. iATIONP.,�?QCl?S$1NG.11Nlir
Yt;>�+?-''..a.:'9E,:L c.:J't•.a3'^' �5.-,ram',^,: •La':. .,`:.i;:Y �: �r'.. ,�.'}:�
COMPLIANCEREPORT FORM
s�7i rsfaviccitrr:aRA1:E[CiH NC27 Q9 s7Z<Fiiorie'81s'Z332Y7:'`
FACILITY INFORMATIONl Please PdntCleartyorType
PERMIT Number:
EX iradon Date: %/ ?oOG
Facility Name: f�%!>?i �. G.�+C•
Non -Discharge
U1C
Permit Name (if different):
NPDES
Otherlrl • 000a70v2__
Facility Address: a:. J3 i2E_c.Q
TYPE PF PERMITTED OPERATION
BEING MONITORED
NC 22213 R
County
9 lagoon
❑ Remediation:'lnfiltration Gallery
❑ Spray Field
❑ Remediation:
Contact Person:
Telephone#: - )-ri-7'?o
❑ Rotary Distributor
❑ Land Application of Sludge
Well Location/Site Name: Mw--3 14 iCfwvy�, . LAr--
No. of wells to be sampled: 5
❑ Water Source Heat Pump ❑ Other:
(Ron Pe`mil
5AMPLING INFORMATION.
WELL ID NUMBER (from Permit): ?Y74U ­ Z 5
Date sample collected: olU tU
FIELD ANALYSES:
If WELL
WAS
Well Depth: .3` " ft.
Well Diameter: 2 in.
pH units
Temp. j �=� °C
DRY at
Depth to Water Level: :? . D ft. below measuring point
Screened Interval:;` .S ft. to 3S
ft. Spec. Cond. 14,
(e 6 µMhos
time of
sampling,
Measuring Point is G�S�ft. above land surface
Relative M.P. Elevation: b� S ft.
Odor A) o *_e
check
olume of water pumped/bailed before sampling: (('r $ gallons
Appearance /Uvcla _
here: ❑
Samples for metals were collected unfiltered: YES ❑ NO
and field acidified: RYES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: 149�_ 114D -, JJ � a
Laboratory Name:
Certification No. _ 77 i
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/l
Nitrite (NO2) as N mg/I
Pb - Lead
mg/I
Coliform: MF Fecal /100ml
Nitrate (NO3) as N� mg/I
Zn - Zinc
mg/I
Coliform: MF Total
/100ml
Phosphorus: Total as P
mgA
(Note: Use MPN mearod for highly turbid samples)
Orthophosphate
mg/l
Other (Specify Compounds and Concentration Units):
Dissolved Solids: Total 9G mg/I
At - Aluminum%
mg/1
�J?3• hzy ,�
J r.
pH (when analyzed) � �mg/I/S
units
Ba -Barium
tT1 ��!•
TOC
mg/I
Ca - Calcium
mg/l
Chloride
mg/l
Cd - Cadmium
mg/1
Arsenic
mg/1
Chromium: Total
mg/1
Grease and Oils
mg/1
Cu- Copper
mg/l
ORGANICS: (by GC, GC/MS, HPLC)
Phenol
mg/I
Fe - Iron
mg11
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate _ 1,970
mg/l
Hg - Mercury
mgll
Report Attached? ❑ Yes (i) ❑ No (o)
Specific Conductance �, G
µMhos
K - Potassium
mg/l
VOC method #
Total Ammonia
mg/1
Mg - Magnesium
mg/I
method #
(Amrrnnia N;vogen: N:idas'N: Anvnortia Nitrogen. Toil)
- Mn - Manganese
mg/I
- - , method # - - -
TKN as N
nigh
Ni - Nickel
mg/l
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs:
Jc}�.1�. n� LX;t:CStii 6 • 13 Q 1 i ce' Jr�HQ.t dam_ iC�lX AAA 1
Permidee (or Authorized Agent) Marne and Tdle - Please print or type J
GW-55 Rev.112007
Effluent Total VOCs: mg/L VOC Removal%

SUBMIT FORM ONY.ELLM PAPER ONLY
)UNDWATER QUALITY MONITORING:
{siourOFY11A9Et 'QU.-1tJF,.G131VI/17iONPROCESSINGAJNIT'
11PLIANCE REPORT FORM
f • • •
.1G:`�i:;i'.t =v�!: r✓-};<: �•::e-••:L'.�-�.!. !i 4;•:. .r. C.;
sare�nle=si Rvlce 4' Ra EiGy� NC:27fi98= sir a ►a ►e ' 119 733 _22
<.1.. 1
LITY INFORMATION
Please FrintClearly orType
PERMIT Number: Expiration Date: // X AW
tyName: �rl�=/E/r1
j_�✓L? .
Non -Discharge UtC-
A Name (if different):
NPDES Other glj006•�-70071
ty Address:
TYPEERMITTED OPERATION BEING MONITORED
e,kWeA
Nei3.Q
County UL-!�Zd1Lagoon
❑Remediation: Infiltration Gallery
`
{�
_
G
❑ Spray Field ❑ Remediation:
act Person: -J"OA
e Siri fC:
Telephone#: 4VL _0279 � / OF
❑ Rotary Distributor ❑ Land Application of Sludge
Location/Site Name:
��
lr, -wn , -Ac,
No, of wells to be sampled: -
❑ Water Source Heat Pump ❑ Other:
t
[from Pe m$t
..r ti,'i ..�.
LL ID NUMBER (from Permit):+^ea� Date sample collected: 1r20 ^
Well Depth: /.rf+ - ft. Well Diameter: NSF in.
Depth to Water Level: All+ ft. below measuring point Screened Interval: _AZ -ft. to eft.
Measuring Point is A?A ft. above land surface Relative M-P. Elevation: _ft.
Volume of water pumped/bailed before sampling: 0 gallons �/-
Samples for metals were collected unfiltered: CIYES ❑ NO and field acidified: R ES ❑ NO
FIELD ANALYSES: G
pH 7i ` 7 units Temp. ' 1 `T / °C
Spec. Cond. �-? µMhos"
Odor IJc zE
Appearance ��4r
1t ln[Gt-1-
AS
DRY at
time of
sampling,
check
here: D
LABORATORY INFORMATION
Date sample analyzed: �t G — �i /,�Q
Laboratory Name: �LZLe ,l- r lrie�G< ( i! 4�666eJ
-L+ - Certification
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
`
COD mg/l
Nitrite (NO2) as N mg/I
Pb - Lead mg/I
Coliform: MF Fecal /100ml
Nitrate (NO3) as N mg/I
Zn - Zinc mg/I
Coliform: MF Total /100ml
Phosphorus: Total as P mg/I
(Note: Use MPN melnod for highly turbid samples)
Orthophosphate mg/I
Other (Specify Compounds and Concentration Units):
Dissolved Solids: Total mg/I
Al - Aluminum - O. 93 mg/i
r�`r+ rrtGJ/
pH (when analyzed) fe 24 units
Be - Barium mg/1
�7}S
i� ze-l- s /! el:t 157: 4 4e
TOC mg/I
Ca - Calcium mg/l
Chloride mg/l
Cd - Cadmium mg/I
Arsenic mg/I
Chromium: Total mg/I
Grease and Oils m911
Cu - Copper .-mg/I
ORGANICS: (by GC, GC1MS, HPLC)
Phenol mg/I
Fe - Iron mg/l
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate % -7S_ mg/I
Hg - Mercury mg/I
Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance /r eo µMhos
K - Potassium mg/I
VOC method #
Total Ammonia mg/I
Mg - Magnesium mg/1
method #
(Ammonia Nltroyen: NK as N: Aaunonia Nitrogen: 7otv)- --Mn
- Mang2neSe mg/l
f176tilOa # - -
TKN as N mg/1
N! - Nickel mg/I
method #
For Remediation Systems Only - • • •
1 certify that. to the best of my knw[ledge and belief the information submitted in this report is Vue, accurate. and comp�e e, and }hat the laboratory artalyUce(ttatavas produced usin' p, oved methods of analysis by a'
OWO ceded laboratory. 1 am a !rare chat there are sign (cant penalties forsubmitting false information. including the possibility of Imes and imprisonment for knovhng violations.
iitiee (or Authorized Agent) NSrrte and Tale - Please print or type
GW-59 Rev.1/2007

_�, aceArralyticaf
WwWi18CelO6S.�R1
r
March 03, 2010
John Reuscher
Delta Environmental Consultant
8008 Corp. Center Drive
Suite 100
Charlotte, NC 28226
RE: Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Dear John Reuscher:
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 KincoyAve. Suile 100
Huntersvilie, NC 28076
Enclosed are the analytical results for sample(s) received by the laboratory on February 22, 2010.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report:
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Paco Analytical Services, Inc..
.1..3 6t
(704)07"092
Page 1 of 16

aCeAnalytical
'rwrW.fJ000IeDS.0071
r
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Asheville Certification IDs
Florida/NELAP Certification M E87648
Pennsylvania Certification f#: 68-03578
Louisiana/LELAP Certification It: 03095
North Carolina Wastewater Certification M 40
2225 Riverside Dr. Asheville, NC 28804
North Carolina Drinking Water Certification M 37712
West Virginia Certification A 356
North Carolina Bioassay Certification #i: 9
Virginia Certification M 00072
New Jersey Certification 11: NC011
Tennessee Certification it. 2980
Massachusetts Certification A M•NCO30
South Carolina Certification #: 99030001
Connecticut Certification #: PH-0106
South Carolina Bioassay Certification 0: 99030002
REPORT OF LABORATORY ANALYSIS
'ibis report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 16

Pace Analytical Services, Inc.
2225 Riverside Dr.
Pace Analytical Services, Inc.
98001CnceyAve. Suile100
mv.pecelebsosm
Asheville. NO 28804
Huntersvilie, NO 28078
1
[phone]
[phone]
i
SAMPLE SUMMARY
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Lab ID
Sample ID
Matrix
Date Collected
Date Received
9263743001
MW-1
Water
02120/10 12:15
02/22/10 08:00
9263743002
MW-2
Water
02/20/10 10:50
02122/10 08:00
9263743003
MW-3
.Water
02/20/10 08:40
02/22/10 08:00
9263743004
STREAM
Water
02/20/10 14:26
02122/10 08:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, Inc..
{Cl','
Page 3 of 16

11ceAl7al Q Paco Analytical Services, Inc. Pace Analytical Services, Inc.
Irral 2225 Riverside Or. 9800 KinceyAve. Suite 100
uwwpecefa6s.com Asheville, NC 28804 Huntersville. NC 28078
[phone] [phone]
SAMPLE ANALYTE COUNT
Project; ALCHEM, INC- ROCKWELL, NC
Pace Project No., 9263743
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
9263743001'
MW-1
EPA6010
EWS
1
EPA6010
EWS
1
EPA 120.1
SDH
1
SM 2540C
LEP
1
SM 2640D
LEP
1
EPA 9040
LEP
1
ASTM D516-90
SHI3
1
9263743002
MW2
EPA6010
EWS
1
EPA6010
EWS
1
EPA 120.1
SDH
1
SM 2540C
LEP
1
SM 2540D
LEP
1
EPA9040
LEP
1
ASTM D516-90
SHB
1
9263743003
MW3
EPA6010
EWS
1
EPA6010
EWS
1
EPA 120.1
SDH
1
SM 2640C
LEP
1
SM 2540D
LEP
1
EPA 9040
LEP
1
ASTM D516-90
SHB
1
9263743004
STREAM
EPA6010
EWS
1
EPA6010
EWS
1
EPA 120.1
SDH
1
SM 2540C
LEP
1
SM 2540D
LEP
1
EPA9040
LEP
1
ASTM D616-90
SHB
1
REPORT OF LABORATORY ANALYSIS Page 4 of 16
This report sliall not be reproduced, except in full,
without the written consent of Paco Analytical Services, Inc..
a,I..ccun

q,, Pace Analytical Services, Inc_ Pace Analytical Services, Inc.
11!;aceAnalytical 2225 Riverside Dr. 9800 KinceyAve. Suite 100
wtvrv.�aMfabS.tern Asheville, NC 28604 iiuntemville, NC 28078
I [phone] [phone]
ANALYTICAL RESULTS
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Sample: MW1
Lab iD: 9263743001 Collected: 02/20/10 12:16
Received: 02/22/10 08:00 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method:
EPA 3010
Aluminum
8050 ug/L 1000
10
02/24/10 13:25 02/26/10 13:37 7429.90-5 03
6010 MET ICP, Dissolved
Analytical Method: EPA 6010 Preparation Method:
EPA 3010
Aluminum, Dissolved
6580 ug/L 1000
10
03/01/10 13:32 03/02/10 10:20 7429-90-5 D3
120.1 Specific Conductance
Analytical Method: EPA 120.1
Specific Conductance
1370 umhoslem . 10.0
1 •
03/01/10 14:48
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
1190 mg/L 20.0
1
02126/1013:34
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
24.1 mg1L 2.5
1
02/25/10 10:13
9040 pH
Analytical Method: EPA 9040
pH
4.6 Std. Units 0.10
1
02124/10 15:44 H3,116
ASTM D516-90 Sulfate Water
Analytical. Method: ASTM D516-90
Sulfate
749 mg1t. 150
30
03101/10 15:54 14S08.79-8
Date: 03/0312010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 5 of 16
This report shall not be reproduced, except In full,
without tho written consent of Pace Analytical Services, Inc..
.tt4y
.'neiacT

Paco Analytical Services, Inc, Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Ktncay Ave. Suite 100
whW..pacelabs.conr Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Sample; MW-2
Lab ID: 926374.3002 Collected: 02/20/10 10.:50 Received:
02/22/10 08:00 Matrix: Water
Parameters
Results Units Report Limit DF Prepared
Analyzed CAS No. Qual
6010 MET top
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Aluminum
677 ug/L 100 1 02/24/10 13:25 02/2511016:22 7429-90-5
6010 MET 1CP, Dissolved
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Aluminum, Dissolved
272 ug1L 100 1 03/01/10 13:32 03101/10 2.1:06 7429.90-5
120.1 Specific Conductance
Analytical Method: EPA 120.1
Specific Conductance
148 umhoslem 10.0 1
03/01/10 14:49
2540C Total Dissolved Solids
Analytical Method: SM 2540C
Total Dissolved Solids
116 mg/L 20.0 1
02/26110 13:34
2540D Total Suspended Solids
Analytical Method: SM 25400
Total Suspended Solids
19.2 mg/L 4.2 1
02/25/10 10:13
9040 pH
Analytical Method: EPA9040
pH
5.0 Sid. Units 0.10 1
02/24/10 15:44 113,H6
ASTM D516-90 Sulfate Water
Analytical Method: ASTM 0516-90
Sulfate
32.1 mg/L 5.0 1
03/01/1014:48 14808-79.8
Date: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 6 of 16
This report shall not be reproduced, except in full, .
without the written consent of Pace Analytical Services, Inc..
v�.irieiae:

aceAnalytical
"` www.pacmobs.00m
i
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Price Analytical Services, Inc,
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: MW-3
Lab ID:.9263743003 Collected: 02/20/10 08:40 Received:
02122110 Matrix: Water
Parameters
Results Units Report Limit DF Prepared
Analyzed CAS No. Qual
6010 MET iCP
Analytical Method: EPA 6010 Preparation Method. EPA 3010
Alun inum
272000 ug/L 500 5 02/24/10 13:25 02/26/10 12:26 7429.90-5 03
6010 MET ICP, Dissolved
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Aluminum, Dissolved
258000 ug1L 500 5 03/01/10 13:32 03/0211014:40 7429-90-5 D3
120.1 Specific Conductance
Analytical Method: EPA 120.1
Specific Conductance
2920 umhos/om 10.0 1
03101/1014:49
2540C Total Dissolved Solids
Analytical Method: SM 25400
Total Dissolved Solids
3490 mg/L 20.0 1
0212611013:34
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
93.2 mg1L 4.2. 1
02125/10 10:13
9040 pH
Analytical Method: EPA 9040
PH
3.5 Std. Units 0.10 1
02/24/10 15:44 H3,H6
ASTM 0516-90 Sulfate Water
Analytical Method: ASTM D516-90
Sulfate
1970 mg/L 150 30
03/01/10 15:57 14808.79-8
Date: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 7 of 18
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without the written consent of Pace Analytical Services. Inc..

e /�,,�J fo Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aCGA lalXicat 2225 Riverside Dr. 9800 KinceyAve. Suite 100
wnwpacelebScem Asheville, NO 28804 Huntersviile, NO 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Sample: STREAM
Parameters
Lab ID: 9263743004 Collected: 02/20/10 14:25 Received: 02/22/10 08:00 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Atuminum
937 ug/L 100 1 02/2411013:25
02/25/1016:30 7429-90-5
6010 MET ICP, Dissolved
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Aluminum, Dissolved
5660 ug/L 100 1 03101/10 13:32
03/01/10 21:20 7429-90-5
120.1 Specific Conductance
Analytical Method: EPA 120.1
Specific Conductance
.126 urnhos/cm 10.0 1
03/01/1014:49
2540C Total Dissolved Solids
Analytical Method: SM 25400
Total Dissolved Solids
346 mg/L 20.0 1
02/26/1013:35
2540D Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
24.2 mg/L 4.8 1
02/25/10 10:14
9040 pH
Analytical Method: EPA 9040
pH
6.3 Std. Units 0.10 1
02/24/10 15:44 H3,116
ASTM D51 &90 Sulfate Water
Analytical Method: ASTM D516-90
Sulfate
175 mg/L 30.0 10
03/01/10 16:06 14808.79.8
Date: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 8 of 16
This report steal( not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�piyivye�

Analytical
Pace Analytical Services, Inc.
2225 Riverside Dr.
Pace Analytical Services, Inc.
98001(incey Ave. Suite 100
Vv wwPeJ�'laftoom
Asheville, NO 28804
Huntersviite, NO 28078
f
[phone]
[phone]
QUALITY CONTROL DATA
Project: ALCHEM, INC- ROCKWELL, NO
Paco Project No,: 9263743
QC Batch: MPRP/5865 Analysis Method: EPA 6010
QC Batch Method: EPA 3010 Analysis Description: 6010 MET
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
METHOD BLANK: 406055 Matrix: Water
Associated Lab Samples: 9263743001. 9263743002, 9263743003, 9263743004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum ug/L ND 100 0212511015:06
LABORATORY CONTROL SAMPLE: 406056
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Aluminum uglL 5000 4630 93 80-120
MATRIX SPIKE SAMPLE: 406057
92635960'15 Spike MS Ms % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Aluminum ug/L 803 6000 5480 94 75-125
SAMPLE DUPLICATE: 406058
Parameter
Aluminum .
ug/L
Units
926359SID16 Dup Max
Result Result RPD RPD Qualifiers
103 102 1 20
Date: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 9 of 16
This report shall not be reproduced, except In lull,
- without the written consent of Pace Analyll al Services, Inc..

11!aXAnaljdical N
wwrvpocalobs.com
t
i
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
Paco Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28004
[phone]
QUALITY CONTROL DATA
QC Batch: MPRP/5875 Analysis Method: EPA6010
QC Batch Method: EPA 3010 Analysis Description: 6010 MET Filtered
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
METHOD BLANK: 406899 Matrix: Water
Associated Lab Samples: 9263743001, 9263743002; 9263743003, 9263743004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Aluminum, Dis;�oived ug/L ND 100 03/01/10 20:51
Pace Analytical Services, Inc.
9800 Kincey Ave, Suite 100
Huntersville, NC 28076
[phone]
LABORATORY CONTROL SAMPLE: 406900
Spike LCS LCS % Rea
Parameter Units Conc. Result % Rec Limits Qualifiers
Aiuminum, Dissolved ug/L 5000 4400 86 80-120
MATRIX SPIKE SAMPLE: 406901
9263743001 Spike MS MS % Rea
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Aluminum, Dissolved ug/L 6580 5000 10300 76 76-125 D3
SAMPLE DUPLICATE: 406902
9263743002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Aluminum, Dissolved ug/L 272 259 5 20
Date: 03/03/2610 05:21 PM REPORT OF LABORATORY ANALYSIS Page 10 of 16
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
,� acto`v

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytieal 2225 Riverside Dr. 9800 KlnceyAve. Suite 100
www.pacolabsoont Asheville, NC 28804 Huntersvil(e, NC 28078
[phone] [phone]
E
QUALITY CONTROL DATA
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
QC Batch: . WET/11574 Analysis Method: EPA 120.1
QC Batch Method: EPA 120.1 Analysis Description: 1201 Specific Conductance
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
METHOD BLANK: 408828 Matrix: Water
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Specific Conductance umhostem NO 10.0 03/01/1014:40
LABORATORY CONTROL SAMPLE: 408829
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Specific Conductance umhos/cm 1410 1420 101 90-110
SAMPLE DUPLICATE: 408830
Parameter
Specific Conductance
Units
umhos/cm
9263096004 Dup
Result Result
154 162
Max
RPD RPD Qualifiers
1 20
Date: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 11 of 16
This report shall not be reproduced, except in full,
without the written consent of face Analytical Services, Inc..

a Pace Analytical Services, Inc.
aC� 2225 Riverside Dr.
awwrpaaelabs.00m Asheville, NO 28804
[phone]
1
QUALITY CONTROL DATA
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No.: 9263743
QC Batch: WET111556 Analysis Method: SM 2540C
QC Batch Method: SM 25400 Analysis Description: 264OCTotal Dissolved Solids
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
METHOD BLANK: 407951 Matrix: Water
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 20.0 02/26/10 13:33
Pace Analytical Services, Inc.
9800 KtnceyAve. Suite 100
Huntersville, NO 28078
[phone]
LABORATORY CONTROL SAMPLE: 407962
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 242 97 80.120
SAMPLE DUPLICATE: 407963
9263743001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg1L 1196 1190 0 20
Date: OW03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 12 of 16
-This report shall not be roproduced, except in lull,
without the written consent of Pace Analytical Services, Inc..

o Paco Analytical Services, Inc,
�ce /t „a/t yj cal 2225 RiversideNC8 04
"" v 1`U�l �i}�'ln�6sV.comt Asheville, NC 28fl04
[phone]
QUALITY CONTROL DATA
Project: ALCHEM, INC- ROCKWELL, NO
Pace Project No,: 9263743
QC Batch: WET111521 Analysis Method: SM 2540D
QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
METHOD BLANK: 406644 Matrix: Water
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg1L ND 2.5 02/26/10 09:45
LABORATORY CONTROL SAMPLE: 406645
Parameter Units
Total Suspended Solids mg1L
SAMPLE DUPLICATE: 406646
Parameter
Total Suspended Solids
Units
mg/L
Spike LCS LCS
Cone. Result % Rec.
250 244 98
9263688002 Dup
Result Result RPD
II1,2 84.7
Paco Analytical Services, Inc.
98001CInceyAve. Suite100
Huntersvilie, NC 28078
[phone]
% Rec
Limits Qualifiers
80.120
Max
RPD Qualifiers
4 20
Dale: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 13 of 16
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalidical
t twhepscidabs.corn
I
Project: ALCHEM, INC- ROCKWELL,.NC
Pace Project No,: 9263743
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch: WETM1524 Analysis Method: EPA9040
QC Batch Method: EPA 9040 Analysis Description: 9040 pl-i
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
Pace Analytical Services, Inc.
9800 KfnceyAve. Suite 100
liuntersville, NC 28078
[phone]
SAMPLE DUPLICATE: 406659
9263715001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH Std. Units 8.7 8.7 0 20 1.16
SAMPLE DUPLICATE: 406660
Parameter
pH
9263745005
Units Result
Sid. Units' 4.9
Dup Max
Result RPD RPD Qualifiers
4.9 0 20 H6
Date: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 14 of 16
This report shall not be reproduced, except in full,
without the Notion consent of Pace Analytical Services, Inc..

a
Pace Analytical Services, Inc.
Analytical
'Ca
2225 Riverside Dr.
wvnvpocolo
Asheville, NC 26804
[phone]
QUALITY CONTROL DATA
Project: ALCHEM, INC- ROCKWELL, NC
Pace Project No,: 9263743
QC Batch: WETA/6842 Analysis Method: ASTM D516-90
QC Batch Method: ASTM D516-90 Analysis Description: ASTM D516-90 Sulfate Water
Associated Lab Samples: 9263743001, 9263743002, 9263743003, 9263743004
METHOD BLANK: 408766 Matrix: Water
Associated Lab Samples: 9263743001, 9263743002, 9263743003. 9263743004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 5.0 03/0111014:45
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
408767
Spike LCS
LCS
% Rec
Parameter
Units
Cone. Result
% Rec
Limits
Qualifiers
Sulfate
mg/L
20 20.0
100
90.110
MATRIX SPIKE SAMPLE:
408768
9263743001 Spike
MS
MS
1A Rec
Parameter
Units
Result Cone.
Result
% Rec
Limits Qualifiers
Sulfate
mg/L
749 20
768
95
75-125
MATRIX SPIKE SAMPLE: 408770
9263745010 Spike MS MS `10 Rec
Parameter Units Result Cone. Result % Rec Limits Qualifiers
Sulfate mg/L 104 20 123 98 76-125
SAMPLE DUPLICATE: 408769
9263743002
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
Sulfate mg/L
32.1
31.8
1 20
SAMPLE DUPLICATE: 408771
9203745011
Dup
Max
Parameter Units
Result
Result
RPD RPD Qualifiers
Sulfate mg/L
ND
ND
20
Date: 03/03/2010 05:21 PM REPORT OF LABORATORY ANALYSIS Page 15 of 16
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without the written consent of Pace Analytical Services, Inc..
n CA.

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ALCHEM, IN
5135 RE® R®
ROCKWELL, NC 28138
D E C E 0 W E
AUG - 4 2009
NC 7Ff�l� MRQ
DWQ -Aquifer Protection

a I
ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
wolcott—[e-mail]
ANNUAL RESIDUAL REPORT
I-q-4 d
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
3/3/2008
20 TONS
6%
3
3/4/2008
20 TONS
6%
3
3
3/5/2008
20 TONS
6%
3
I
3/6/2008
20 TONS
6%
3
3/7/2008
20 TONS
6%
3
RTOnMp
3/10/2008
20 TONS
6%
3
w�
3/11/2008
20 TONS
6%
3
a.a
3/12/2008
20 TONS
6%
3
3/13/2008
20 TONS
6%
3
0
3/14/2008
20 TONS
6%
3
3/17/2008
20 TONS
6%
3
3/18/2008
20 TONS
6%
3
3/19/2008
20 TONS
6%
3
�L.
3/20/2008
20 TONS
6%
3
��^ I
V
3/21/2008
20 TONS
6%
3
3/24/2008
20 TONS
6%
3
3/25/2008
20 TONS
6%
3
3/26/2008
20 TONS
6%
3
fCk
TOno
3/27/2008
20 TONS
6%
3
3/28/2008
20 TONS
6%
3

0 ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
[e-mail]
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
3/31/2008
20 TONS
6%
3
,a OM4/1/2008
20 TONS
6%
3
• I
4/2/2008
20 TONS
6%
3
4/312008
20 TONS
6%
3
2 J
4/4/2008
20 TONS
6%
3
T ocd
4/7/2008
20 TONS
6%
3
C00_ 27
4/8/2008
20 TONS
6%
3RT
I
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4/9/2008
20 TONS
6%
3
-/
4/10/2008
20 TONS
6%
3
RE In, on n%
4/1 112008
20 TONS
6%
3
4/14/2008
20 TONS
6%
3
• O
®
4/15/2008
20 TONS
6%
3
4/16/2008
20 TONS
6%
3
3
4/17/2008
20 TONS
6%
3
4/18/2008
20 TONS
6%
3
4/21/2008
20 TONS
6%
3
VV
4/22/2008
20 TONS
6%
3
R.1- 00prM
4/23/2008
20 TONS
6%
3
4/24/2008
20 TONS
6%
3
4/25/2008
20 TONS
6%
3

E ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
wolcott—[e-mail]
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
/
4/28/2008
20 TONS
6%
3
,Z
4/29/2008
20 TONS
6%
3
4/30/2008
20 TONS
6%
3
5/1/2008
20 TONS
6%
3
5/2/2008
20 TONS
6%
3
® ®&
5/512008
20 TONS
6%
3
kTO DD -17
516/2008
20 TONS
6%
3
5/7/2008
20 TONS
6%
3
5/8/2008
20 TONS
6%
3
�71
J�
5/912008
20 TONS
6%
3
5/12/2008
20 TONS
6%
3
5/13/2008
20 TONS
6%
3
s�
5114/2008
20 TONS
6%
3
5/15/2008
20 TONS
6%
3
'11612008
20 TONS
6%
3
5/19/2008
20 TONS
6%
3
5/20/2008
20 TONS
6%
3
n, f
5/21/2008
20 TONS
6%
3
5122/2008
20 TONS
6%
3
/ c)Cow��
5123/2008
20 TONS
6%
3

0ALCHEM, INC
8135 RED RD
ROCKWELL, NC 28138
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
Phone:[phone]
Fax: [phone]
E-mail:
[e-mail]
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
j /LAGOON # f�
SAMPLING PORT
PH
C)er 1
5/26/2008
20 TONS
6%
3
1 Z
5/27/2008
20 TONS
6%
3
d
rw
lV
5/28I2008
20 TONS
6%
3MOW
'
Lf
5/29/2008
20 TONS
6%
3
5/30/2008
20 TONS
6%
3
6/2/2008
20 TONS
6%
3
6/3/2008
20 TONS
6%
3
�Q
6/4 - 6113
REACTOR DOWN
6/16/2008
20 TONS
6%
3
R• 70
6/17/2008
20 TONS
6%
3
6/18/2008
20 TONS
6%
3
U
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6/19/2008
20 TONS
6"/,
3
I rZ2-IRD, RIM
b/201,30.Q�>•�
_ 20 TONS"`
U7 V
6/23/2008
20 TONS
6%
1
6/24/2008
20 TONS
6%
I
qn
IV
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6/2S/2008
20 TONS
6%
1
03 v
r
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6/26/2008
20 TONS
6%
1
6/27/2008
20 TONS
6%
1
/
7
6/30/2008
20 TONS
6%
1
n• `
7/1/2008
20 TONS
6%
I
P ,
r

0 ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
[e-mail]
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
7/2/2008
20 TONS
6%
QQ O
7/3/2008
20 TONS
6%
B G
y�ao
7/812008
7/9/2008
20 TONS
20 TONS
6%
6%
1
n�L�®JJ
7.1012008
20 TONS
6%
LP
7/11/2008
20 TONS
6%
Z
7/14/2008
20 TONS
6%
1
7/IS/2008
20 TONS
6%
I
7/16/2008
20 TONS
6%
1
®
7/17/2008
20 TONS
6%
1
9
7118/2008
20 TONS
6%
1
7/21/2008
20 TONS
6%
1
3
7/22/2008
20 TONS
6%
1
7/23/2008
20 TONS
6%
I
h O
CJ
7/24/2008
20 TONS
6%
7/25/2008
20 TONS
6%
1
—
7/28/2008
20 TONS
6%
i
7/29/2008
20 TONS
6%
7I30/2008
20 TONS
6%
I
7/31/2008
20 TONS
6%
1

ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
[e-mail]
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
8/I/2008
20 TONS
6%
I
j 02-
8/4/2008
20 TONS
6%
I
8/5/2008
20 TONS
6%
I
S
9
I/`lJ
8/6/2008
20 TONS
6%
I
8/7/2008
20 TONS
6%
I
i
8/8/2008
20 TONS
6%
1
-3.yD
8/ 1 1 /2008
20 TONS
6%
1
I
8/12/2008
20 TONS
6%
I
T6c)10 /
8/13/2008
20 TONS
6%
0
8/14/2008
20 TONS
6%
1
8/15/2008
20 TONS
6%
���,
(iiJ
8/18/2008
20 TONS
6%
I
E
Dd /; 3
8/19/2008
20 TONS
6%
I
�./ o
8120/2008
20 TONS
6%
I
© -.4i
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.( "P
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8/21/2008
20 TONS
6%
1
i
4
T-0©/1
8/22/2008
20 TONS
6%
I
.r D / +
I
8/25/2008
20 TONS
6%
I
8/26/2008
20 TONS
6%
1
TOb 11
1�
8/27/2008
20 TONS
6%
il�v,
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8/28/2008
20 TONS
6%
1
)'
1,
P' a

ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
wolcott,[e-mail]
ANNUAL RESIDUAL REPORT
Purposes NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
/% ro
8/29/12008
20 TONS
6%
1
T-000 12-2-
9/1/2008
20 TONS
6%
3
9/2/2008
20 TONS
6%
1
9/3/2008
20 TONS
6%
1
I 2-5
9/4/2008
20 TONS
6%
1
-o V I z- `
915/2008
20 TONS
6%
CFO 1 Z-7
9/8/2008
20 TONS
6%
1
9I9/2008
20 TONS
6%
1
DD /2-9
9/10/2008
20 TONS
6%
1
I , D
9/1 112008
20 TONS
6%
1
9/12/2008
20 TONS
6%
2
9115/2008
20 TONS
6%
1
9/ 16/2008
20 TONS
6%
1
9/17/2008
20 TONS
6%
I
a. ' ©1�C
J
9/18/2008
20 TONS
6%
1
9/19/2008
20 TONS
6%
1
9/22/2008
20 TONS
6%QMO
1
3a
9/23/2008
20 TONS
6%
1
R
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9/24/2008
9/25/2008
20 TONS
20 TONS
6%
6%
1
I
.3 y
;,7`�

ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
ANNUAL RESIDUAL REPORT wolcott,[e-mail]
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
f f
9/2612008
20 TONS
6%
1
.`
jV0 r ,l
lJ(�
9/29/2008
20 TONS
6%
1
3
9/30/2008
20 TONS
6%
1
�DD j
101112008
20 TONS
6%
1
45
10/212008
20 TONS
6%
1
� V /
10/3/2008
20 TONS
6%
1
I
10/612008
20 TONS
6%euolup
1
10/7/2008
20 TONS
6%
1
I Uo /
10/8/2008
20 TONS
6%
y
10/9/2008
20 TONS
6%
I
1
10/10/2008
20 TONS
6%
1
10/13/2008
20 TONS
6%
1
10/14/2008
20 TONS
6%
1
1011 S/2008
20 TONS
6%
% /,
10/16/2008
20 TONS
6%
1
10/17/2008
20 TONS
6%
1
10/2012008
20 TONS
10/21/2008
20 TONS
EEE
I
20 TONS
10/23/2008
20 TONS
6%
I
w) 0

0 ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
[e-mail]
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
/j
j
10124/2008
20 TONS
6%
I
a
�, 3_
le 2-
20 20 TONS
6%
I
7.05
�_
oQ / &3
10/28/2008
20 TONS
6%
I
PSG30/2008
29/2008
El
20TONS
6%
I
k-tUO!i
20 TONS
6%
/CD� `
10131/2008
20 TONS
6%
I
nrOO/ 7
1 1/312008
20 TONS
6%
RT00/
1 1/4/2008
20 TONS
6%
1
6.90
%J
9�
1 1/5/2008
20 TONS
6%
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1 1/6/2008
20 TONS
6%
I
I I/712008
20 TONS
6%
I
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D/ 6
1111012008
20 TONS
6%
1
6.95
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11/11/2008
20 TONS
6%
1
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11 / 12/2008
20 TONS
6%
I
6
1111312008
20 TONS
6%
I ,
1 1/14/2008
20 TONS
6%WO
I
7
11/17/2008
20 TONS
6%
1
6.89
p
11/18/2008
20 TONS
6%
1
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11/19/2008
20 TONS
6%
F®
11/20/2008
20 TONS
6%
I
41 PO

ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
ANNUAL RESIDUAL REPORT wolcott—[e-mail]
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
1% o �s
6c
1 1/21/2008
20 TONS
6%
1
1
2
kTDn
1 1/24/2008
20 TONS
6%
1
11125/2008
20 TONS
6%
I
6.89
12/1/2008
20 TONS
6%
I
12/2/2008
20 TONS
651.
1
6.99
I
12/3/2008
20 TONS
6q,
I
I
I
I
1214/2008
20 TONS
6%
j� G3
12/S/2008
20 TONS
6%
12/8/2008
20 TONS
6%
O
12/9/2008
20 TONS
6%
12/10/2008
20 TONS
6%
I
I
12/11/2008
20 TONS
6%
12/12/2008
20 TONS
6%
12/15/2008
20 TONS
6%
I
I
7.02
�s
12/1612008
20 TONS
6%
12117/2008
20 TONS
6%
I
I
ZE112/1812008
20 TONS
6%
I
2/19/2008
20 TONS
6%
I
I
12/22/2008
20 TONS
6%
I
3, V.2 3 4
_ 1
�7��j
�--W
12/29/2008
20 TONS
6%
I
6.89
q. 0'f
0/

ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
ANNUAL RESIDUAL REPORT wolcott,[e-mail]
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
r
IC
12/30/2008
20 TONS
6%
1
1/2/2009
20 TONS
6%
I
115/2009
20 TONS
6%
1
/�
I
1/6/2009
20 TONS
6%
I
6.92
1/7/2009
20 TONS
6%
1
1/8/2009
20 TONS
6%
I/912009
20 TONS
6%tunol
1
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1/12/2009
20 TONS
6%
I
6.89
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1/13/2009
20 TONS
6%
1
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I/14/2009
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6%
1
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6%
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1/16/2009
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6%
1
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1/19/2009
20 TONS
6%
1
1/20/2009
20 TONS
6%
1
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1/21/2009
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6%
1
6.89
1- 3,70
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II22/2009
20 TONS
6%
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1/23/2009
20 TONS
6%
1
�I
1/2612009
20 TONS
6%ann
1
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1/27/2009
20 TONS
6%
1
I
1/20/2009
20 TONS
6%
1
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a

ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
ANNUAL RESIDUAL REPORT wolcott—[e-mail]
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
PM 0 22.
1/29/2009
20 TONS
6%
1
6.75
1/30/2009
20 TONS
6%
�n
,
9
E213/2009
20 TONS
6%
�!2
20 TONS
6%
1
2/4/2009
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6%
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2/5/2009
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6%
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2/6/2009
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6%
%� 22
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2/912009
20 TONS
6%
1
2/10/2009
20 TONS
6%
I
3
2/1 I/2009
20 TONS
6%
1
6.96
2/12/2009
20 TONS
6%
1
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2/13/2009
20 TONS
6%
1
2 33
2/16/2009
20 TONS
6%
1
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2/17/2009
20 TONS
6%
I
7.10
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2/18/2009
20 TONS
6%
2/19/2009
20 TONS
6%
I
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2/20/2009
20 TONS
6%
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2/23/2009
20 TONS
6%
1
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2/24/2009
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6%
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6.98
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2/25/2009
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6%
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ALCHEM, INC
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLUF
/ti/� ,-1
(JC.b-
3/26/2009
20 TONS
tp 2
3/27/2009
20 TONS
2 j_
3/30/2009
20 TONS
Q�-/�i /
3/3112009
20 TONS
20 TONS
(iV
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4/2/2009
20 TONS
T/v1
1 C �2 P
4/3/2009
20 TONS
�O
4/6/2009
20 TONS
Q
4/7/2009
20 TONS
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4/8/2009
20 TONS
�2 7
4/9/2009
20 TONS
V027 r/
4/10/2009
20 TONS
F
rnrZ73
4/13/2009
20 TONS
6
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4/14/2009
20 TONS
6
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4/15/2009
20 TONS
6
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4/16/2009
20 TONS
6'
4/17/2009
20 TONS
6!
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4/20/2009
20 TONS
6,
2
4/21/2009
20 TONS
6'
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4/22/2009
20 TONS
69
8135 RED RD
ROCKWELL, NC 28138
Phone: [phone]
Fax: [phone]
E-mail:
wolcott—[e-mail]
RIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
6%
2
6%
2
6%
2
6%
S%
S%
i%
2
2
2
2
7.10
%
2
r
%
%
2
2
7. I I
,
%
%
2
2
vo
2
2
7.05
6
2
6
2
2
'
2
2
' 2
6.98
`99 )

aALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
[e-mail]
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
DATE
BAUXITE USED
% SLURRIED OUT
LAGOON #
SAMPLING PORT
PH
LAGOON PH
4/23/2009
20 TONS
6%
2
4/24/2009
20 TONS
6%
2
O On S-3
4/27/2009
20 TONS
6%,
2
Zncbll�
4/28/2009
20 TONS
6%
2
J
Vls `
4/29/2009
20 TONS
6%
2
v�
4/30/2009
20 TONS
6%
2
2� l
5/1/2009
20 TONS
6%
2
0p (�
5/4/2009
20 TONS
6%
2
CQD
5/5/2009
20 TONS
6%
2
6.89
5/6/2009
20 TONS
6%
2
�m r
�r7
G
5/7/2009
20 TONS
6%
2
5/8/2009
20 TONS
6%
2
029
5/11/2009
20 TONS
6%
2
Z9 v
7(f'S
5/12/2009
20 TONS
6%
2
U 2
5/13/2009
20 TONS
6%
2
6.92
5/14/2009
20 TONS
6%
2
OU2 9/ /
5/15/2009
20 TONS
6%
2
9 -
5/18/2009
20 TONS
6%
2
99
5/19/2009
20 TONS
6%
2
5/20/2009
20 TONS
6%
2
WE

ALCHEM, INC
8135 RED RD Phone: [phone]
ROCKWELL, NC 28138 Fax: [phone]
E-mail:
ANNUAL RESIDUAL REPORT [e-mail]
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
REACTION #
36
DATE
5/21/2009
BAUXITE USED
20 TONS
% SLURRIED OUT
6%
LAGOON # SAMPLING PORT LAGOON PH
PH
2
36
5/22/2009
20 TONS
6 %
2
30
5/25/2009
20 TONS
6%
2
- -7�/�2 h
/ (/V JlJ
5/26/2009
20 TONS
6%
2
vc
5/27/2009
20 TONS
6%
2
7.10
2
J
�^
�7-/�V 3 /
/ V
5/28/2009
5/29/2009
611/2009
20 TONS
20 TONS
20 TONS
6%
6%
6%
2
2
2
6/2/2009
20 TONS
6%
2
3 (D
6/3/2009
20 TONS
6q`
2
1 631 f
2
6/4/2009
6/5/2009
20 TONS
20 TONS
6%
6%
2
2
6.78
10
a
6!8/2009
20 TONS
6%
2
6/9/2009
20 TONS
6%
2
6/10/2009
20 TONS
6%
2
2
/
� l
6/11/2009
20 TONS
6%
6.89
6/12/2009
20 TONS
6%
2
3
6/15/2009
20 TONS
6%
2
6/16/2009
20 TONS
6%
2
r� 6/17/2009 20 TONS 6% 2
Aq.21
3 i 9)

ALCHEM, INC
8135 RED RD
ROCKWELL, NC 28138
ANNUAL RESIDUAL REPORT
Purpose NCDENR
SURFACE DIPOSAL PERMIT REQUIREMENT
Date: 3/08 - 6/09
Phone:[phone]
Fax:[phone]
E-mail:
Wolcott—[e-mail]

ALCHEM, INC
rAUG - 4 2009
f�C-L�F�lr� Pr�RO
DWG} - A Lifer Protection
LAGOON PH
'• s READINGS
ATT.- PEGGY FINLEY
8135 RE® R®
ROCKWELL, NC 28138

Date:
ALCHEMQPhatneter wo►�'luheet
Analyst: ���,�j'
pH Analysis
r�l:hratinn Cal. check
:at. Time Buffer 1.� ,
Buffer 2
Buffer 3
*pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sam led♦
Ti
Time Anal
d♦ pH Result S.U. '
Temperati
f
Lagoon 1
1.10 �V—
(:
Lagoon 2
u G f:;-V P
.Y,
I-as�
Solid
Comment
*If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommendeddrift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Wor et
fLf"j
y Analyst:
PH Analysis
Comments
;al. Time c anorauu,.
Buffer 1
Buffer 2
Buffer 3
*pH check buffer 3 must be within t 0.1 pH
units of the standards true value.
Sample
Time Sam led ♦
Time Anal zed ♦
pH Result S.U.
_
Temperate
Lagoon l
Lagoon 2
IS
u ►
r�a.r-�
_
IJ
Solid
Comment
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 f 0.1 pH units of the ffers frog value) end of the day.
Calibration drift check is recommended three times daily (for a full workday)morning, mid day

Date:
ALCHEM Paramete( Worl—heet
Analyst:
pH Analysis
Cal. Time
Calibufferration
B1
Cration
Balib
%.B411ufferbra3tio Cal. check
I, � GL.
it Ls'
I. cs
*pH check buffer 3 must be within ± 0.1 pH units of the standards true value.
Sample
Time Time Analyzed
It S.U.
Temperaturt
Lagoon
Lagoon 2
Is
Ir P
Solid
Comment
+If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer 93 ± 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.
P
of

ALCHEM Par me er ( or �et
Date:
3 — Analyst:
pH Analysis
Cal. Time
Calibration
Calibration
Calibration Cal.
'
Buffer 1
Buffer 2
Buffer 3
IG.O3
`1 ul
•nH check buffer 3 must be within ± 0.1 pH units of the standards true value.
♦If sample is measured direcay m me suuuu U,.,y W»v�-- -- - -
Indicates a recommended drift check. (use Buffer #3 ± 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCH M Parameter Worksheet
Date: 9 Analy ; • r
pH Analysis
*pH check buffer 3 must be within t 0.1 pH units of the standards true value.
♦ If sample is measured directly to the stream only uuic 41MIY4w ­ ..,.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHE Parameter W rkssheAf---
Date: Analyst: •�J��71/" �y,
pH Analysis
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Commenu
Cal. Time
jID
._,s ,a.—, V ..ff
� Z mvicr he within t 0.1 nH units
of the standards true value.
r--
Sample
Time sampled*
Time Analyzed ♦
pH Result S.U. f
Temperature
Comment
Lagoon 1
I . bC
• 3�
��� • j
Lagoon 2
\�
a j.Cc"
SC,n
,c)
S.��
�G
Solid
Sam le
Time Sam led
Time Anal zed
H Result S.U.
Tern erature
Grams of sample
®If sample is measured directly in the stream onry trmc uualy—u Wuu— uv.w�•���•
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

^� ALCHEM Para eter Workshy
Date:
r �^ ` Analyst: !lS?� .✓
pH Analysis
Cal. Time
cauorauou
Buffer 1
%,ulu,auvu
Buffer 2
�..���.-.
Buffer 3
q.o`
st)Pol
-I •aA
*pH check buffer 3 must be within t 0.1 pH units of the standards true value.
*If sample is measured arrecuy in me sueaiu WHY LIAL&V w.. j —.. -•- -- --------
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Para etY)&_U_W
Workshe
Date: y
i
Anal st:
�
pH Analysis
d. Time
c:auomtion
Buffer 1
%-alluiau—
Buffer 2
.,...-.._-
Buffer 3
b.'Ob
LV 0k
10• DDL
I ,O d
'vH check buffer 3 must be within t 0.1 pH units of the standards true value.
•If sample is measured directly in me sa=n uuly u...V a....,........ _._ -- --- --
indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Param ter WO
ksheet
Dat
e: lY r Analyst:'
Cal. Time
pH Analysis
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
'pH check buffer 3 must be within t 0.1 pH units of the standards true value.
♦ If sample is measured directly to the stream umy uuw a'Q-jV ,,, ...,,.... -- -_.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

� ALCHEM Parameter Worksh , t
`1 Date: � b� Analyst:
pH Analysis
check
Cal. Time caiiorauou I
RufFer 1 I Buffer
W.'30 1 qx)k I ib.C- 1-6-1
•pH check buffer 3 must be within ± 0.1 pH units of the standards true value.
♦If sample is measured directly in the stream vuq U11W -.-j— --•- -- --- - -
Indicates a recommended drift check. (use Buffer #3 ± 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHE Parameter Works eet
Date: _ I. Analyst: fW � 0
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
*pH check buffer 3 must be within t U. l pH units or me sranoaras rruc vuiun.
Sample
Time Sam led ♦
Time Analyzed ♦
pH Result S.U.
Temperature
Comment
Lagoon 1
C
Lagoon 2
S�eat�,
1JU \dCA"r
S4►��
Np WO der
Solid
Sample
Time Sampled
-Time Analyzed
JH Result S.U.
Temperature
Grams of sample
♦ if sample is measured directly in the stream only time anaiyzea wouio oe recomea.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter WorAsheet
Date: Analyst:✓ LdA
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
LA 'Dk
L.Ox
*pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sampled*
Time Analyzed♦
pH Result S.U. '
Temperature
Comment
Lagoon 1
9 z )'0
% -� i}
)'1. 3 C
Lagoon 2
g
No,
Nt \dc4e'
NO 1ok r
Kin V14e:
Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
♦ If sample is measured directly in the stream. only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 10.1 pH units of the buffers true value)
Calibrdtion`drift deck is recommended three times daily (for a full workday) morning, mid -day, end of the day.

6 `� o ALCHEM Paramete�rks eet
s
Date: I — Analyst:
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal, check
Comments
*pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sam led♦
Time Anal zed♦
pH Result S.U.
Temperature
Comment
Lagoon 1
L
Lagoon 2
L a,300n.
S+Zfa'r-\
I�C, � r
SQ��d
Na
K R 146
INC ���Pr
Solid
Sample
Time Sam led
•Time Anal zed
pHResultS.U.
Temperature
Grams of sample
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Worksheet
Date: — i — d� Analyst: (,c Jj
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
JU,00
401
i0`.oi
I
spH check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sampled*
Time Anal zed♦
pH Result S.U. '
Temperature
Comment
Lagoon 1
Lagoon 2
Cc a
10 i 04
5 �-e o v\
A-r
Q �d
No Wal et-
R A�'td
No Wo-ker
. Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Tempe re
Grams of sample
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

-1 ALCHEM Parameter Worksheeett
Date: ' d 1 Analyst: fi OiYn 1 p X V
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
1Z
•pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sampled*
Time Analyzed♦
pH Result S.U.
Temperature
Comment
Lagoon 1
q'
Lagoon 2
NU `Nat er
Sated
No Wa-Aer-
cle Acid
It w4or
Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicites a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Wo(rksheet'f
Date: 11 - �o — b Analyst:_ �_IJ_ Om I '1.�.�1 r to 'et
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
0
,,02
-pH check butter 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sampled*
Time Anal ♦
pH Result S.U.
Temperature
Comment
Lagoon 1
= yD�.`
Lagoon 2
[[''--`` C��f
hb i -er
S� eav\
No W Aer
SanC�
D V �4er
N 1jer
Solid
Sample
Time Sampled
-TimeAnalyzed
H Result S.U.
Temperature
Grams of sample
•rr sampie is measures airecuy to the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter W%ork�sh tt
Date: —.I L 3 - o i J Lc.ceJ�% Analyst:_
pH Analysis
Cal. Time
Calibration
Buffer I
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
)o.o3
-7.o,,j
r a ..ua ve n.u.w z v.1 pn unub ur me manuaras true value.
Sample
Time Sampled*
Time Analyzed#
pH Result S.U.
Temperature
Comment
Lagoon 1
Lagoon 2
`�
NO14/44t "
I a l,an 3
9 :35
3 41
�°l.�
S + ea m
IAA-�r
Sad
go W44fr
T_
Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
•. —.r., Aa sucaauiw uuwuy nl we aueam only time analyzed wouia tie recorded.
Indicates a recommended drift check. (use Buffer #3 t 0' I pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

i ALCHEM Parameter Worksheet
Date: ! - Analyst:_ lica-r-
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
j0 °os
14,01
io,d ►
7,6 f
r • -••-.� .••.. •u�„ w ,nu,w x v. a pn UUIth Ur Ule s=dards we value.
Sample
Time Sampled*
Time Analyzed#
pH Result S.U.
Temperature
Comment
Lagoon 1
Lagoon 2
No Idc-I'Pr
� a Di7 h
10:36-
3•qO
27.E
SA ea r�
l
p W a+Pr
16.60
14.50
solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
arc
._--..r._ ......-.......w ....w.,� u — a U Uuqnuw .e aaalyLW wouUe recoruca.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Worksheet
Date• I —� - `1 A
Analyst:
pH Analysis
Cal. Time
Calibration
Iii
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
yy //fi�tt
yyBuffer
tsaa vuvvn uuaacs j inua uw wlunn 2 u.l pn units oI the stanQaras true value.
Sample
Time Sampled ♦
Time Anal ♦
pH Result S.U.
Temperature
Comment
Lagoon
C
Lagoon 2
00 r P�
t3
I° i0
3.NI4�7.��
Q11b
i' a's
`1 •55
.27. jE
Fle A
No Wo��r
Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
. as -ij vie nm"umu uuwuy in Lao JUCam omy time anatyzea wouia be recor(tea.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

s� _ �7 ALCHE Parameter orks
Date: d 2 © I Analyst: ,uil,
pH Analysis
Cal. Time
Calibration
Buffer I
Calibration
Buffer 2
Calibration.
Buffer 3
Cal. check
Comments
va vuw Vu 1 111ua1 uc w 1111 = v.1 pri units oI me standards true value.
Sample
Time Sam led ♦
Time Analyzed ♦
pH Result S.U.
Temperature
Comment
Lagoon 1
;5&
.3. IYd
Lagoon 2
Aio �1t�P�
La Iwrt 3
5}-Va IVY
qo' waker
aq,q
&aV,
Ur Ael 6
X, VVa4e r
Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
• it sample is measured directly to the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Par ete; Workshee
Date: rl6 - — Analyst:�r
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
r.............v, u,ua, w wa,uw = u. t pri UHIL5 vi tnc sumaards true value.
Sample
Time Sampled ♦
Time Analyzed#
pH Result S.U.
Temperature
Comment
Lagoon
Lagoon 2
La Q bri 3
3
s-re4 m
W. 55
& . b
o c A e't
NL Vjder
Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
.aa aaauNw w uaw—w uiiwuy in we stream only time analyzed would be Iecorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

^ i� ALCHE Parameter Worksheet
Date: I d - AS— 01 Analyst: LL�
PH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
�.L)
-PH cnecK nutter s must be wrtnm t U.1 pH units of the standards true value.
Sample
Time Sam led♦
Time Anal zed♦
pH Result S.U. '
Temperature
Comment
Lagoon 1
Lagoon 2
<'Aral"
q ,. qo
gib A
Solid
Sample
Time Sampled
-Time Analyzed
pH Result S.U.
Temperature
Grams of sample
*If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

Q ALCHEMM Parameter Worksheet
Date: u Analyst:,) jLe J� � �a�
pH Analysis
Cal. Time
Calibration
Buffer I
Calibration
Buffer 2a
Calibration
Buffer 3
Cal. check
Comments
q,3V.0
j�•�
'pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sampled
Time Anal zed♦
pH Result S.U. '
Temperature
Comment
Lagoon 1
Lagoon 2
LQ Spot.
Aro
3.3 ►
j�.�
84-4
1� z�
�; .05
11, i
sc"J
A.
A 6
Solid
Sample
Time Sampled
-Time Analyzed
PH Result S.U.
Tem erature
Grams of sample
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 f 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Works eet
Date: y — t Analyst:
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
'pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sam led ♦
Time Analyzed#
pH Result S.U.
Temperature
Comment
Lagoon 1
3.q)
Lagoon 2
S'
sAea_rY%
1D:�s
14. 4-1
Aci
T
Solid
Sample
Time Sampled
-Time Analyzed
VH Result S.U.
Temperature
Grams of sample
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Worlsheet
a4'
Date: r a 6 Analyst; J z"z'
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
*pH check buffer 3 must be within ± 0.1 pH units of the standards true value.
Sample
Time Sampled*
Time Analyzed♦
pH Result S.U.
Temperature
Comment
Lagoon 1
Lagoon 2
3.31
t_
Scnci
Solid
Sample
Time Sampled
Time Analyzed
pH Result S.U.
Temperature
Grams of sample
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer 93 ± 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

�1
Datej "� I- ©`;
ALCHEM Parameter Worksheet
Analyst: jA1Y�-�'z
pH Analysis
Cal. Time Calibration
Buffer 1
Calibration Calibration Cal. check
BufferBuffer Comments
*pH check busier 3 must be within ± I
0.1 pH units of the standards tine value
Sample Time Sampled ♦ y
P Time Analyzed* ♦ pH Result S.U. Temperature
Lagoon 1 Comment
Lagoon 2 �G 3 . `: 3
Pr
1.3u 13.39 1 i 3.S
ttrc� � /up
G'�5
% i he W4,-r
Sample Time c , , Solid
led Time Analyzed
pH Result S T T -r
of
♦If sample is measured dhr_ ,.y :.,_
only time
Indicates a reco_ min_ ended dnft�check�euse Buffer #3 ± am 0.1 PHa11-11 would be recorded.
Calibration drift check is recommended three times daily (for a fulltworkday) morning, mid -day, end of the day.

ALCHEM Parameter Worksheet
Date: 3-1 E — 0
Analyst:��5j�
PH Analysis
Cal. Time Calibration Calibration
Buffer 1 Buffer 2
Calibration
Cal. check
Buffer 3
Comments
� I' iS �•� f 10-�:�.
(.ate
*pH check buffer 3 must be within ± 0.1 pH units of the standards true value.
Sample Time Sam led♦
Lagoon 1
Time Analyzed ♦
pH Result S.U. Temperature
Lagoon
1i;ap
SAA
SIG {�Qi�°r
N 0 "a+�< <
Alo Wo�er
Sample Time Samnlr i T Solid
--- e i . im j rinaly,ed H Result S.U. I Trim,._
of
♦If sample is measurPrl :_ _I
directly ��� the stream only time analyzed would be r orce ded
Indicates a recommended drift check. (use Buffer #3 ± 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

`� ALCHEM Parameter Worksheet
Date: J -� Analyst:-Ip,ll ,1,0
PH Analysis
Time
'PH check buffer 3 must be within t 0.1 PH units of the standards true value.
Indicates a recommended drift check. (use Buffer #3 t 0.1 PH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

y ALCHEM Parameter W(orksheet
Date: "7 ' 7 - O� Analyst: ud l.,%
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
+nH check hi=.";
muct L..
n 1
- — ••.. 1.. uu..a V. wv Jl41N141LL3 Ul11Z value.
Sample
Time Sampled ♦
Time Analyzed ♦
pH Result S.U.
Temperature
Comment
Lagoon 1
LID
Lagoon 2
A aler
L aicon .3
1,�.: 3 0
3.49
1� 5
Ao Wa4er
'jcan�
1,2:'40
11.5i7
%e A c, �a
B Ida4r
Solid
Sample
Time Sam led
•—Time Analyzed
PH Result S.U.
Temperature
Grams of sam le
•rfcamnln i —A A:.e
.1.. .1 _
- __1 ._ ...___.-•• •••....q ....uv 0u 1 vuq uluo 4llnlyLCO WOU10 De recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM{ Parameter Worksheet
Date: 1'du Analyst:
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
]�.oa
'pH check buffer
3 must he with;.
+ n t
•••-• -- �•� � .,� uuc raiuc.
Sample
Lagoon 1
Lagoon 2
Time Sam led♦
Time Analyzed +
0 Wa+4
pH Result S.U. '
Temperature
Comment
-ci5ov , 3
q: jc
3. ya
;,• z�r-,
0 WQer
Solid
Sam le
Time Sam led
•Time Anal zed
H Result S.U.
Tern erature
Grams of sample
♦If sample is measured dimrtly
;. th.. �t.e .
uG IODUrUeu.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

:Date: - �T "
ALCHEM Parameter W,{orksheeett
Analyst:_ J/t P� J
PH Analysis
Cal. Time
Calibration
Buffer I
Calibration
B/u�ffer 2
Calibration
Buffer 3
Cal. check
Comments
yJ1 �y�j
q.ff. L
*nR rhrAlr hnff
r 2 . + tie
.., __ ^ •••.... _ ...I NI, ullna vI LIM bUMUUMS true value.
Sample
I Time Sampled ♦
Time Analyzed ♦
pH Result S.U.
Temperature
Comment
Lagoon 1
p WCt. e
Lagoon 2
°40
�i-c
Water
w4ef"
Solid
Sample
Time Sampled
Time Analyzed
H Result S.U.
Tern erature
Grams of sample
♦Tfcamnlr ism _A Ai.e
.f„
-- ----- -- '- ---------- .-.J .I...L. —1-14A WILY uulc a1jGjyleU WOUIO De rec ordea.
Indicates a recommended drift check. (use Buffer #3 ± 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

Date: 5'� 8- d Is
:al. Time
Calibration
Calibradc
Buffer 1
I Buffer')
1 D:15
Nate77C7
ALCHEM Parameter Worksheet
Analyst:- 'w O
pH Analysis
Calibration Cal. check
Buffer 3
O.
'pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Comments
macates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

Date: b - - 0 9
Time
J • 9� I iA,at I IcD.o.-?_
ALCHEgM Parameter Worksshheet
Analyst: J'U'-'.k
pH Analysis
Calibration Cal. check
Buffer 3
1. C.X
'pH check buffer 3 must be within t 0.1 pH units of the standards true value.
Comments
utalcates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Worksheet
t ,1�
Dale: (D- 5 > Analyst: .CQIA 3 .� -1cJLV
PH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
-
Comments
jl`.w;�
�•oi
�a•oa.
l.ot
'PH check buffer
3 must be within
± 00.1 nH unitc
of thn
....e .7.._
Indicates a recommended drift check. (use Buffer #3 t 0.1 PH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

yr ALCHEM Parameter Worksheet
n A
Date �- -D VVV Analyst. j • 1,Q
PH Analysis
Cal.
ro.ca
'pH check buffer 3 must be within t 0.1 pH units of the standards true value.
- - -- -- -—���u unrr cneck. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

{ Date: ALCHEM Parameter Wor�kssheet
4Analyst
:_
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
14,o (
JUO0 L
-?, o�L
*pH check buffer
3 must be within
t 0.1 nH unite
nfrtia &M.,,r...a......_
....I.._
Sample
Lagoon 1
Time Sam led♦
,
Time Mal zed♦
Flo Wale r
pH Result S.U. '
Temperature
Comment
Lagoon 2
i
No W cat '-r
L oh 3
101 i5
r�
i Ullaler
ID., qo
t R =o
Ac-d
woe
Wof
Solid
Sam le
Time Sam led
•Time Analyzed
H Result S.U.
Temperature
♦If sample is meacurnA dirnrrt.,
:., ��a ....e.,._ ,._...:�_
_ELEA
Indicates a r,....J' ""_ aualy"u wuu,u oe recoraea.
ecommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Works�heeet
Date: _ Analyst: �llLicyt ' JZ'1l
pH Analysis
Cal, Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
*pH check check buffer 3 must be within t 0.1 pH units of the standards true value.
Sample
Time Sam led ♦
Time Analyzed +
pH Result S.U.
Temperature
Comment
Lagoonl
Lagoon 2
Ali) Wa4er
Surd
I C°. 50
i4 , -1
P-% A ��
No II a4cr
Solid
Sample
I Time Sampled
I -TimeAnalyzed
I pH Result S.U.
I Temperature
Grams of sample
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day

ALCHEameter W� et
Date:____ 'C _ D Analyst:14
pH Analysis
Cal. -Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
q;oo
y .ol
l0•�2
`i.o l
eDH Check buffer
I meet by with;n
.- n i ct
r•• .•••••+ v ury 0 WA QJu3 nU0 VaIUC,
Sample
Lagoon 1
Time Sam led a
Time Analyzed ♦
pH Result S.U. '
Temperature
Comment
Lagoon 2
La oo►� 3
S 4a r+n •
S ar'dt4.0'7
q, yp
o U` r
3 7S
i q. 01
fit i d
Sample
Time Sam led
o
Solid
Time Analyzed
H Result S.U.
Tern erature Grams of sam le
♦IfsamDle is measured directly
in thn ct.
i...
�______-I
--- -, •••• v .•• icu Q Yzwuutu uc recomea.
Indicates a recommended drift check, (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) moming, mid -day, end of the day.

Date: q' ib' ALCHEM Parameter Worksheet
Analystji4 i
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
Oo
10.o2
T 02
�nH n6nr4 tinFFn.
2 ..,....• 1.e . :•G:...L
n .
-- ••• . — Y.. u.•w va u-aW iyai lib uuG Value.
Sample
Time Sampled*
Time Analyzed♦
pH Result S.U.
Temperature
Comment
Lagoon 1
Lagoon 2
1�2'•35
3.8
j44 o�
I_a on 3
l 2 . Sa
3, 75
Shea r •,
�liv W�'�
c
acid
NO Wa4r_
Solid
Sam le
Time Sam led
Time Anal zed
H Result S.U.
Temperature
Grams of sample
♦If sample is meacurrrl Air•.��L,
;n �tia �..o.,... ,...i...:�_
___'-._-' --
..
_ _
. nv4.0 UtV lGVVIUGU.
Indicates a recommended drift check. (use Buffer 43 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

/" d,3 ALCHE�(M Parameter Worksheet
Date: q� AlAnalyst: I.2041 �
PH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
*PH check buffer
3 must be within
t 0 1 nH nnitc
of fl a ara...;­AI
.. _ .._'.._
lndtcates a recommended drift check. (use Buffer #3 t 0.1 PH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

p ALCHEM��,,��P��arrame((ter Workksshheet
Date: ��" O Analyst4- 4k �},,,, w,,Q /
pH Analysis
Cal. Time
Calibration
Buffer I
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
o I
l0' O:L
?. 01
.•.. .. },aa wuu Ui ulc DLa11udxus true valve.
Sample
Time Sam led ♦
Time Analyzed
pH Result S.U.
Temperature
Comment
Lagoon 1
lq.as
Lagoon 2
01
1-a on 3 y-
q_ E5
3,1Co
19.O
�ifea M
o L41Ar
S qn0
io: io
3.17
Iq.oi
Rix `j
NO wa�er
Solid
Sample
Time Sam led
Time Anal zed
2HResultS.U.
Temperature
Grams of sample
•tFC9TnIn nA A:_e
-- -----.-� �••ww 1" .,,V Ou"441 wuy uiue anaryzea wouta oe recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

Date: I C) -2+0
Cal. Time Calibratio
Buffer I
ra:140.��
Buffer 2
tt>.(Dq
ALCH7z=�r
Analyst:
PH Analysis
Calibration I Cal. check
Buffer 3
r1.o I
'PH check buffer 3 must be within t 0.1 pH units of the standards true value.
Comments
inatcates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Worksh et
Date: , I �— Gs,
Analyst:
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
D b5
I .-)J-
10.0
•nH rhrr4 E,nff
r 1 ... r l.e . :.�:_
_.. n .
_ --
• - •••••..• ..........I" .,. v. r Pu uww- u1 Ulu slanaaras true value.
Sample
Time Sam led ♦
Time Analyzed ♦
pH Result S.U,
Temperature
Comment
Lagoon 1
Lagoon 2
tiaJoD,-, 3 T
ID
R.o3
,���� •�,
r �
<r8q
e�2
s air
0 :'40
H Result S.U. Tern erature Grams of sample
Solid
Sam le
Time Sam led
Time Anal zed
♦ If sample is meacurert riirr
rl
- .".. "a�yavu wuulu oe recoraee.
Indicates a recommended drift check, (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

bat
ALCHEM Parameter Worksheet
Analyst:
PH Analysis
�al. Time Calibration Calibration
Calibration Cal. check
Buffer 1 Buffer2
Buffer3 Comments
'PH check buffer 3 must be within t 0.1 pH units of the standards true value
Sample
Lagoon 1
Time Sam led♦ I Time Anal zed♦
Y
pH Result S.U. '
Temperature Comment
Lagoon 2
" fD
3 •Yy
1q.0 l
t5
5.3$
/q.03
fir' a Y
2 =1U
44 d
0-
Act
Sam le
P
Solid
Time Sampled rlm e ,
zed PHRes
b U
Temperasure Grams ofsamole
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.
V
1

S ALCHEM Parameter Workshheeeet
Date: 1�.— — Analyst:_ �_jI'.,&
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
I
9.01
Io - ot0
z 2-
••••.•••• � .. Yu uuiu ui u,c sunuaras true value.
Sample
Time Sampled
Time Analyzed ♦
pH Result S.U.
Temperature
Comment
Lagoon 1 ,
Lagoon 2
L con 3
0
►,j . 0
q. o :L
L
Z
s�hd
.2:ss
3.q_I
, -0
174 t td
U4,14er-
Solid
Sam le
Time Sam led
Time
pH Result S.U.
—Temperature
Grams of sample
♦rffaTnlP i eA A:.e
'---•--r•- •_ •••^�•�• ••••w.y u• "1''"I'll uwy WHO analyZCa would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

i q ^ ALCHEM Parameter Workkshheet
Date: Analyst d Ijz,a7
PH Analysis
Cal. Time
Calibration
Buffer 1
Cal. check
Comments
tCalibration#Calibration
•PH check buffer
3 must be within
t o.l nH units
of rhr
Indicates a recommended drift check. (use Buffer #3 10.1 PH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter /Works%eJet
`�
Date: 1 Anal ys7lL.¢0yt�,.r.�
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal, check
Comments
a '. oo
L{ .off
jO .t) �c
o
•c �,
'oH check buffer
i muct he urirhin
+n t ..v
•• — • r• • ••• — uw awuuaius Lrue value.
Sample
Lagoon 1
Lagoon 2
Time Sam led♦
Time Analyzed*
3C)
pH Result S.U.
�1
Temperature
i4•��
Comment
czrr.
' �o
Na �Ic�r
x 1Vt
'P� C"
a °.s (D
I�D Wgjer
Solid
Sample Time Sampled Time Analyzed H Result S.U. Tern erature Grams of sam le
If sample is mrac rP i 1
r rl..
- -- ---••--•v ••• •••W J-11 vuq uu,c a,1a1yzea would be recorded.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Worksheet
Date: Analyst• � _. ���
PH Analysis
Calibration Calibration Calibration I Cal, check
Buffer I Buffer Buffer3 Comments
_%%t' L1.�k I (c)ze I i.a4- 1 -T,Oi
'pH check buffer 3 must be within t 0,1 pH units of the standards true value.
Lnuicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ci ALCHEM Parameter Worksheet
Date: ' �� �' Analystj �a
PH Analysis
Cal. Time
Calibration
Calibration
Calibration
Cal, check
—
Comments
Buffer 1
Buffer 2
Buffer 3
$PH check buffer
3 must be within
t 0.1 off unirc
of rhP eta d ­io
t_ _i_
Indicates a recommended drift check. (use Buffer #3 t 0.1 PH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

Date: A---o�
Time
Buffer 1
�o,o(e
ALCHEM Parameter Worksheet
Analyst:, A.19 � L_, J
PH Analysis
Calibration Cal. check
Buffer 3
'PH check buffer 3 must be within t 0.1 PH units of the standards true value.
indicates a recommended drift check. (use Buffer #3 t 0.1 PH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.
-1 0

ALCHEM Parameter Worksheet
Analyst: /Lela - �i_ -
PH Analysis
Buffer 1 Buffer 2 I Buffer 3
"PH check bul%r 3 must be within t 0.1 PH units of the standards true value.
Lnuicates a recommended drift check. (use Buffer #3 t 0.1 PH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

a p ALCHEM Parameter Worksh/ne}ett
Dace:_ _ ' �` -` Analyst:J�
PH Analysis
Cal. Time Calibration Calibration Calibration Cal, check
Buffer 1 Buffer 2 Buffer 3 Comments
*pH check buffer 3 must be within t 0.1 pH units of the standards true value. --
u,uicares a recommended drift check. (use Buffer #3 # 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

Date:- 9-6 "G q
Time
Xis 1 H.1:)`
ALCHEM Parameter Worksheet
_ Analyst�il.t'A _JL'
pH Analysis
ilibration Calibration Cal. check
iffer 2 Buffer 3 Comments
D .c i I Z ,1 1 I
'pH check buffer.) must be within t o.I pH units of the standards true value.
♦ If sample is measured directly in the stream only time analyzed would be recorded.
Indicates a recommendeddrift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) moming, mid -day, end of the day.

Date: '
ALCHEM Parameter Worksheet
Analystd n A A _j,, x
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
'A.01
Colo
tic)
-r.a1
'pH check buffer
3 must be with;
t o 1
to . pH units of the standards true value.
Sample
Time Sam led ♦
Time Analyzed ♦
pH Result S.U. '
Temperature
Comment
Lagoon I a
Lagoon 2
t
.L�.7
97
MASI
'io
it.(n�
J.lo ,� t
uo I� :
Solid
Time
Grams of sample
♦lfSamDle IS RIPASurPli rilrertiv.n ♦6n...o.,... I _i...:__ _
-••y ....... w—j— n U'U VG IGVUIUeu.
Indicates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the, day.

ALCHEM Parameter Worksh e
Date: J' 1 Analyst._ !t I
pH Analysis
Cal. Time
Calibration
Calibration
Calibration
Cal. check
Comments
Buffer I
Buffer 2
Buffer 3
"nR A—L-
�- � — Nz, ulna ui me stanaaros true value.
tnotcates a recommended drift check. (use Buffer #3 t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Wporksh-(e�ett
Date: `_� bQ Analyst:_ '� 1�
pH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
fD :00
LA
I ID -O Le
i -0
r=. d 11AU31 VG WlNllll = V.1 prr Vnit$ or me standards true value.
Sample
Time Sam led ♦
Time Analyzed ♦
pH Result S.U.
Temperature
Comment
Lagoonl
Lagoon 2
0 '.35
LA
�« o�'3 r
io '.4io
3.51
j-�rec=r�
10`60
tcr
RYR A c 6
j �, O
No YJa�er
Solid
Sample
Time Sampled:.
::Tithe Analyzed
H Result S.U.
Temperature
Grams of sam le
is
�If a ..In ..J J:
•1. .L_
• •• +•••.•11 " w......w u AwuY H= =NC. iuvwll Vllly Ulne analyzed woula oe recoroca.
Indicates a recommended drift check. (use Buffer O t 0.1 pH units of the buffers true value)
Calibration drift check is recommended three times daily (for a full workday) morning, mid -day, end of the day.

ALCHEM Parameter Worksheet
Date: r.1 Analyst n a�..k ,� L,.�s 4
PH Analysis
Cal. Time
Calibration
Buffer 1
Calibration
Buffer 2
Calibration
Buffer 3
Cal. check
Comments
Q:oC)
4-01
J©,D(O
Z .c6-
T.0a-
'pH check buffer
3 must be within
t 0.1 nH units
nfehr
Calibration drift check is recommended three time s�daily (for a full or day) morning, mid -day, end of [fie day.
U_V

Analytical and Consulting Chemists
(DXFORD
1316 South Fifth Street
DATE RECEIVED 0 9 -1 1- 9 8 Wilmington, N.C. 28401
�b®ratories DATE REPORTED 0 9- 2 2- 9 8 [phone]
9 8 W 6 4 5 7 Fax [phone]
no. RECEIVED
PAGE 1 OF 1 MNATER QUA-ITY 8ECTION
Cf d 1�
ALCHEM INC P.O. # Mon-Oischarp
8135 RED ROAD f'e►miign�
ROCKWELL, NC 28138
ATTENTION: RANDALL ANDREWS
SAMPLE DESCRIPTION: TCLP METALS - SAND
1. RESULTS FOR THIS SAMPLE.
2. OXFORD LABORATORIES ROUTINE DETECTION LIMIT
3. NORTH CAROLINA LANDFILL MAXIMUM
4. EPA MAXIMUM CONTAMINANT LEVEL
5. MATRIX SPIKE %:RECOVERY
RESULTS
1
RESULTS: ON TCLP LEACHATE
Arsenic, as As, PPM
BDL
Barium, as Ba, PPM
.256
Cadmium, as Cd, PPM
BDL
Chromium, as Cr, PPM
BDL
Lead, as Pb, PPM
BDL
Mercury, as Hg, PPM
BDL
Selenium, as Se, PPM
BDL
Silver, as Ag, PPM
BDL
pH @ 5 % Sample
3.5
Extraction Fluid Used
1#1
NOTE: BDL = BELOW DETECTION LIMIT
2 _ 3
0.005
0.5
0.020
10.0
0.005
0.1
0.010
0.5
0.010
0.5
0.0005
0.02
0.005
0.10
0.010
0.50
4 5
5.0
101
100.0
92.2
1.0
86.7
5.0
93.5
5.0
80.6
0.2
97.3
1.0
89.8
5.0
82.1
KEN SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 9 -1 1- 9 8 Wilmington, N.C. 28401
DATE REPORTED 0 9- 2 2- 9 8 [phone]
9 8 W 6 4 5 7 Fax [phone]
RECEIVED
PAGE 1 OF 1 !(U,TER QUALITYSECTION
f Syi..° tr t Ot i t6
ALCHEM INC P ' O ' # Baia-Dscha,9e
813 5 RED ROAD f'eiTitift<tlg
ROCKWELL, NC 28138
ATTENTION: RANDALL ANDREWS
SAMPLE DESCRIPTION: TCLP METALS - SAND
1. RESULTS FOR'THIS SAMPLE
2. OXFORD LABORATORIES ROUTINE DETECTION LIMIT
3. NORTH CAROLINA LANDFILL MAXIMUM
4. EPA MAXIMUM CONTAMINANT LEVEL
5. MATRIX SPIKE % RECOVERY
RESULTS: ON TCLP LEACHATE
Arsenic, as -As, PPM
Barium, as Ba, PPM
Cadmium, as Cd, PPM
Chromium, as Cr, PPM
Lead, as Pb, PPM
Mercury, as Hg, PPM
Selenium, as Se, PPM
Silver, as Ag, PPM
pH @ 5 % Sample
Extraction Fluid Used
NOTE: BDL = BELOW DETECTION LIMIT
RESULTS
1
2
3
4
5
BDL
0.005
0.5
5.0
101
.256
0.020
10.0
100.0
92.2
BDL
0.005
0.1
1.0
86.7
BDL
0.010
0.5
5.0
93.5
BDL
0.010
0.5
5.0
80..6
BDL
0.0005
0.02
0.2
97.3
BDL
0.005
0.10
1.0
89.8
BDL
0.010
0.50
5.0
82.1
3.5
#1
�C�II.-Ox
KEN SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
(DXFORD 1316 South Fifth Street
DATE RECEIVED 0 9 -1 1- 9 8 Wilmington, N.C. 28401
�gborat®GIes DATE REPORTED 0 9 - 2 2- 9 8 [phone]
9 8 W 6 4 5 7 Fax [phone]
nc. RECEIVED
PAGE 1 OF 1 1NA T ER QUALITY SECTION
QLs 2 ce 6
ALCHEM INC P.O. # Edon -Discharge Permdnq
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: RANDALL ANDREWS
SAMPLE DESCRIPTION: TCLP METALS - SAND
1. RESULTS FOR THIS SAMPLE
2. OXFORD LABORATORIES ROUTINE DETECTION LIMIT
3. NORTH CAROLINA LANDFILL MAXIMUM
4. EPA MAXIMUM CONTAMINANT LEVEL
5. MATRIX SPIKE % RECOVERY
RESULTS
1
RESULTS: ON TCLP LEACHATE
Arsenic, as As, PPM
BDL
Barium, as Ba, PPM
.256
Cadmium, as Cd, PPM
BDL
Chromium, as Cr, PPM
BDL
Lead, as Pb, PPM
BDL
Mercury, as Hg, PPM
BDL
Selenium, as Se, PPM
BDL
Silver, as Ag, PPM
BDL
pH @ 5 % Sample
3.5
Extraction Fluid Used
#1
2_ 3
0.005
0.5
0.020
10.0
0.005
0.1
0.010
0.5
0.010
0.5
0.0005-0.02
0.005
0.10
0.010
0.50
4 5
5.0
101
100.0
92.2
1.0
86.7
5.0
93.5
5.0
80.6
0.2
97.3
1.0
89.8
5.0
82.1
NOTE: BDL = BELOW DETECTION LIMIT
KEN SMITH, SENIOR ANALYST

C)XFORD
®b®rat®roe$
nc.
AL.CHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYS
Analytical and Consulting Chemists
1316 South Fifth Street
Wilmington, N.C. 28401
DATE RECEIVED 0 9- 0 2- 9 8 [phone]
DATE REPORTED 0 9-14- 9 8 Fax [phone]
98W6311
PAGE 1 OF 1
SAMPLE DESCRIPTION: SAND - TCLP METALS
1. RESULTS FOR THIS SAMPLE - SAND
2. DETECTION LIMIT
3. NC LANDFILL MAXIMUM
4. EPA MAXIUMUM CONTAMINANT LEVEL
5. MATRIX SPIKE % RECOVERY
RESULTS
1
2
3
4
5
RESULTS: ON TCLP LEACHATE
Cadmium, as Cd, PPM
BDL
0.005
0.1
1.0
93.5
Lead, as Pb, PPM
BDL
0.010
0.5
5.0
88.2
Copper, as Cu, PPM
BDL
0.005
*
*
102
Nickel, as Ni, PPM
.013
0.005
*
*
119
Zinc, as Zn, PPM
.209
0.005
*
109
pH @ 5% Sample
3.5
X
X
X
X 1
Extraction Fluid Used
#1
X
X
X
X
NOTE: BDL.=BELOW DETECTION LIMIT
* UNKNOWN
4K; MITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
Wilmington, N.C. 28401
DATE RECEIVED 0 9- 0 2- 9 8 [phone]
DATE REPORTED 0 9 -14 - 9 8 Fax [phone]
98WF311
PAGE 1 OF 1
AL.CHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYS
SAMPLE DESCRIPTION: SAND - TCLP METALS
1. RESULTS FOR THIS SAMPLE - SAND
2. DETECTION LIMIT
3. NC LANDFILL MAXIMUM
4. EPA MAXIUMUM CONTAMINANT LEVEL
5. MATRIX SPIKE % RECOVERY
RESULTS: ON TCLP LEACHATE
Cadmium, as Cd, PPM
Lead, as Pb, PPM
Copper, as Cu, PPM
Nickel, as Ni, PPM
Zinc, as Zn, PPM
pH @ 5 90 Sample
Extraction Fluid Used
NOTE: BDL.=BELOW DETECTION LIMIT
* UNKNOWN
RESULTS
1 2 3 4 5
BDL
0.005
0.1
1.0
93.5
BDL
0.010
0.5
5.0
88.2
BDL
0-.005
*
102
.013
0.005
*
*
119
.209
0.005
109
3.5
X
X
X
X
#1
X
X
X
X
K MITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
Wilmington, N.C. 28401
DATE RECEIVED 0 9- 0 2- 9 8 .[phone]
DATE REPORTED 0 9 -14 - 9 8 Fax [phone]
98W6311
PAGE 1 OF 1
AL.CHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
SAMPLE DESCRIPTION: SAND - TCLP METALS
1. RESULTS FOR THIS SAMPLE - SAND
2. DETECTION LIMIT
3. NC LANDFILL MAXIMUM
4. EPA MAXIUMUM CONTAMINANT LEVEL
5. MATRIX SPIKE % RECOVERY
RESULTS: ON TCLP LEACHATE
Cadmium, as Cd, PPM
Lead, as Pb, PPM
Copper, as Cu, PPM
Nickel, as Ni, PPM
Zinc, as Zn, PPM
pH @ 5 % Sample
Extraction Fluid Used
NOTE: BDL.=BELOW DETECTION LIMIT
* UNKNOWN
RESULTS
1
2 3 _ 4 5
BDL
0.005
0.1
1.0
93.5
BDL
0.010
0.5
5.0
88.2
BDL
0.005
*
*
102
.013
0.005
*
*
119
.209
0.005
*
*
109
3.5
X
X
X
X
#1 '
X
X
X
X
4K; MITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
Wilmington, N.C. 28401
DATE RECEIVED 0 9- 0 2- 9 8 [phone]
DATE REPORTED 0 9- 1 4- 9 8 Fax [phone]
98Wf311
PAGE 1 OF 1
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
SAMPLE DESCRIPTION: SAND - TCLP METALS
1, RESULTS FOR THIS SAMPLE - SAND
2. DETECTION LIMIT
3. NC LANDFILL MAXIMUM
4. EPA MAXIUMUM CONTAMINANT LEVEL
5. MATRIX SPIKE % RECOVERY
RESULTS: ON TCLP LEACHATE
Cadmium, as Cd, PPM
Lead, as Pb, PPM
Copper, as Cu, PPM
Nickel, as Ni, PPM
Zinc, as Zn, PPM
pH @ 5 9b Sample
Extraction Fluid Used
NOTE: BDL.=BELOW DETECTION LIMIT
* UNKNOWN
RESULTS
1 2 3 4. 5
BDL
0.005
0.1
l.0
93.5
BDL
0.010
0.5
5.0
88.2
BDL
0.005
*
*
102
.013
0.005
*
*
119
.209
0.005
*
*
109
3.5
X
X
X
X
#1
X
X
X
X
dG�I -
K MITH, SENIOR ANALYST

(i)XFORD
CEborat®91es
nc.
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYS
Analytical and Consulting Chemists
1316 South Fifth Street
Wilmington, N.C. 28401
DATE RECEIVED 0 9- 0 2- 9 8 [phone]
DATE REPORTED 0 9 -14 - 9 8 Fax [phone]
98W6311
PAGE 1 OF 1
SAMPLE DESCRIPTION: SAND - TCLP METALS
1. RESULTS FOR THIS SAMPLE - SAND
2. DETECTION LIMIT
3. NC LANDFILL MAXIMUM
4. EPA MAXIUMUM CONTAMINANT LEVEL
5. MATRIX SPIKE % RECOVERY
RESULTS
1
RESULTS: ON TCLP LEACHATE
Cadmium, as Cd, PPM
Lead, as Pb, PPM
Copper, as' Cu, PPM
Nickel, as Ni, PPM
Zinc, as Zn, PPM
pH @ 5 96' Sample
Extraction Fluid Used
NOTE: BDL.=BELOW DETECTION LIMIT
* UNKNOWN
2 3 4 5
BDL
0.005
0.1
1.0
93.5
BDL
0.010
0.5
5.0
88.2
BDL
0.005
*
*
102
.013
0.005
*
*
119
.209
0.005
*
*
109
3.5
X
X
X
X
#1
X
X
X
X
4K; MITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8- 1 2- 9 8 Wilmington, N.C. 28401
DATE REPORTED 0 8- 3 1- 9 8 [phone]
9 8W5 9 4 8 Fax [phone]
PAGE 1 OF 1
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
SAMPLE DESCRIPTION: #3 SAND
1. #3 SAND AS RECEIVED
2. #3 SAND DRY BASIS
RESULTS
1 2
RESULTS: WT/WT
Cadmium, As Cd, PPM <.200 <.278
Copper, -as Cu, PPM 1.60 2.23
Lead, as Pb, PPM 1.23 1.71
Nickel, as Ni, PPM .525 .730
Zinc, as Zn, PPM 3.40 4.73
Total Solids, wt % 71.88 X
�ry►�d�F
N SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 - 12- 9 8 Wilmington, N.C. 234013-9793
DATE REPORTED 0 8 - 3 1- 9 8 (910) Fax [phone]
98VT5948
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
SAMPLE DESCRIPTION: #3 SAND
1. #3 SAND AS RECEIVED
2. #3 SAND DRY BASIS
t
RESULTS: _WT/WT
Cadmium, As Cd, PPM
Copper, a.s Cu, PPM
Lead, as Pb, PPM
Nickel, as Ni, PPM
Zinc, as Zn, PPM
Total Solids, wt %
PAGE 1 OF 1
RESULTS
1 2
<.200 <.278
1.60 2.23
1.23 1.71
.525 .730
3.40 4.73
71.88 X
E SMITH, SENIOR ANALYST

(DXFORD
®b®rat®ries
nc.
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 - 12 - 9 8 Wilmington, N.C. 28401(910) 763-9793
DATE REPORTED 0 8 - 3 1- 9 8 98W5948 Fax [phone]
SAMPLE DESCRIPTION: #3 SAND
1. #3 SAND AS RECEIVED,
2. #3 SAND DRY BASIS
RESULTS: WT/WT
Cadmium, As Cd, PPM
Copper, as Cu, PPM
Lead, as Pb, PPM
Nickel, as Ni, PPM
Zinc, as Zn, PPM
Total Solids, wt %
PAGE 1 OF 1
RESULTS
1 2
<.200
< . 2 7 8
1.60
2.23
1.23
1.71
.525
.730
3.40
4.73
71.88
X
1EAN SMITH, SENIOR ANALYST

(DXFORD
abwat®roes
nc.
Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 -12 - 9 8 Wilmington, N.C. 28401
DATE REPORTED 0 8 - 31- 9 8 [phone]
9 8 W 5 9 4 8 Fax [phone]
PAGE 1 OF 1
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
SAMPLE DESCRIPTION: #3 SAND
1. #3 SAND AS RECEIVED
2. #3 SAND DRY BASIS
RESULTS
1 2
RESULTS: WT/WT
Cadmium, As Cd, PPM <.200 <.278
Copper, as Cu, PPM 1.60 2.23
Lead, as Pb, PPM 1.23 1.71
Nickel, as Ni, PPM .525 .730
Zinc, as Zn, PPM 3.40 4.73
Total Solids, wt % 71.88 X
1AN SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 -12 - 9 8 Wilmington, N.C. 284013-9793
DATE REPORTED 0 8 - 3 1- 9 8 (910) Fax [phone]
98W5948
PAGE 1 OF 1
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYS
SAMPLE DESCRIPTION: #3 SAND
1. #3 SAND AS RECEIVED.
2. #3 SAND DRY BASIS
RESULTS
1 2
RESULTS: WT/WT
<.200 <.278
Cadmium, as Cd, PPM
1.60 2.23
Copper, as Cu, PPM
1.23 1.71
Lead, as Pb, PPM
Nickel, as Ni, PPM
.525 .730
3.40 4.73
Zinc, as Zn, PPM
Total Solids, wt % 71.88 X
EN SMITH, SENIOR ANALYST

G)XFORD
_ . , rato;
_..
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYS
Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 -1 2- 9 8 Wilmington, N.C. 28401(910) 763-9793
DATE REPORTED 0 8 - 3 1- 9 8 98W5950 Fax [phone]
SAMPLE DESCRIPTION: #3 SAND
1. 43 SAND AS RECEIVED
2. #3 SAND DRY BASIS
RESULTS: WT/WT
Aluminum, as Al, PPM
Total Solids, wt
PAGE 1 OF 1
RESULTS
1 2
8610 11200
71.88 X
2
K N SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 -12 - 9 8 Wilmington, N.C. 284013-9793
DATE REPORTED 0 8 - 3 1- 9 8 (910) Fax [phone]
98W5950
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
SAMPLE DESCRIPTION: #3 SAND
1. #3 SAND AS RECEIVED
2. #3 SAND DRY BASIS
RESULTS: WT/WT
Aluminum, as Al, PPM
Total Solids, wt %
PAGE 1 OF 1
RESULTS
1 2
8610 11200
71 . 88 K
K N SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 -12 - 9 8 Wilmington, N.C. 28401
DATE REPORTED 0 8 - 31- 9 8 [phone]
9 8 W 5 9 5 0 Fax [phone]
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYS
SAMPLE DESCRIPTION: #3 SAND
1. #3 SAND AS RECEIVED
2. #3 SAND DRY BASIS
RESULTS: WT/WT
Aluminum, as Al, PPM
Total Solids, wt
PAGE 1 OF 1
RESULTS
1 2
8610 11200
71.88 X
2
K N SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
Wilmington N.C. 23401
DATE RECEIVED 0 8 -1 2- 9 8 (910) 3-9793
DATE REPORTED 0 8 - 3 1- 9 8 Fax [phone]
98W5950
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYE
SAMPLE DESCRIPTION: #3 SAND
1. 43 SAND AS RECEIVED
2. #3 SAND DRY BASIS
RESULTS: WT/WT
Aluminum, as Al, PPM
Total Solids, wt %
PAGE 1 OF 1
RESULTS
1 2
8610 11200
71.88 X
2
K N SMITH, SENIOR ANALYST

Analytical and Consulting Chemists
1316 South Fifth Street
DATE RECEIVED 0 8 -1 2- 9 8 Wilmington, N.C. 284013-9793
DATE REPORTED 0 8 - 3 1- 9 8 (910) Fax [phone]
98W5950
ALCHEM INC
8135 RED ROAD
ROCKWELL, NC 28138
ATTENTION: WAYNE DRYS
SAMPLE DESCRIPTION; #3 SAND
1. #3 SAND AS RECEIVED
2. #3 SAND DRY BASIS
RESULTS: WT/WT
Aluminum, as Al, PPM
Total.Solids, wt %
PAGE 1 OF 1
RESULTS
1
2
8610 11200
71.88 X
K N SMITH, SENIOR ANALYST'

Facsimile Cuwer Page
NC DENR
DWQ-Groundwater Section
P.O. BoX 29578 Raleigh NC 27626-0578
2728 Capital Blvd. Raleigh, NC 27504
Phone: [phone]
Fax: [phone]H or [phone]
Company:. - - - - - - - Phone:
Phote: Date:
Fax: Wages including i.hi.s cover page: - - -
Comments:
1 � IM5"(�7

Fac
NC DENR
DWQ-Groundwater Section
P.Q. 33ox 29578 Rateigh NC 27626-0578
2728 Capital Blvd. Raleigh, NC 27604
Phone: [phone]
Fax.: [phone] or [phone]
To Frow.,
ozu an - - '- - - - _.. _ . _ _ .... , .. Phone:.. r�
P y:.._
Phone:
Date:
Pax: a — Oh5C7. Pages including €his cover page:-- --
J
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Comments: YO
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d� '�0
'J.:

'imilLa'ver Page
NC DEN
DWQ-Groundwater Section
P.Q. 33ox 29578 Raleigh NC 27626-0578
2728 Capital 131vd. Raleigh, NC 27604
phone: [phone]
Fax: [phone] or [phone]
To '" From;
Company: - • - - - - - - -.. _ ......... = .. , . _ Phone:
Phone: gate: . x
Fax: ,0 — C��. Pages including yhis cover page: —=2 =
fI ments: /�r►��
6 M50

Facslmfl—eO
NCD.ENR
DWQ-Groundwater Section
P.Q. 13OX 29578 Raleigh NC 27626-0578
2728 Capital Blvd. Raleigh, NC 27604
Phone: [phone]
Fax: [phone] or [phone]
TO. From;
Phone:
Company:—
7
Phone: Date: IA
Fax: Pages including -,,,.his cover page:
Comments- A'e

I CSI-Mile Q���r F
NC DES
DWQ.Groundw-ater Section
P.O. Box, 29578 Raleigh NC 27626-0578
2728 Capital Blvd. Raleigh, NC 27604
Phone: [phone]
Fax: [phone] or [phone]
To fri From;
Company:
Phone:.
Phone:
Date:
Fax: Pages including phis cover page: - -
x4c ze
lily!

ti a^s / -
GROUNDWATER SECTION GW #
;DIVISION OF ENVIRONMENTAL MANAGEMENT
RECORM OF WASTE DISPOSAL PERMIT APPLICATION ION RE74104V
REVIEW SY`
FACILITY NAME �—
LOCATION I r-:?< r
TYPE OF DISPOSAL SYSTEM (LAGOON, ETC.)
DESCRIPTION 0F.FACILITY_ e --f
SIZE OF IMPOUNDMENT (FT SQ.)
DATE 1-24A17i-7 4 FIELO IINV TIGATION? (Y/N) .-•—
yCOUNTY
-DESIGN CAP. (GPD)
'A.c V;c,'& .-
WOR SIZE OF APPLICATION AnEA
w Rl SOU t°: MUN. SLUDGE- MUN. W. WATER: ---- .PRIMAAY
IND. SLUDGE
-- --1ND, WELL WATER -- ___.OTHERS:
nlQ-rANCE FRgM WASTE SOURCE TO NEAREST: STREAM - Fr., WELL — 1*'�' FT -
FOR WELL. TYPE ®F USE TH PUMP RATE ('r.�ST_)
WHAT DESIGN CoNDI ONS W(L EDUCFII CREASE CHANCE OF GW CON AMINAT1C7i �:
WHAT NA T URAt= SITE CONDITIONS WILL REDUCEAWSBEASE3HANCE OF GW CONTAWNATION: Le2' —"
DEPTH TO: BEDROCK FT., SEASONAL HIGH W.T. FT., ANNUAL W.T. FLUX
SURFICIAL AQUIFER TESIAN, AQUIFER
SECONDARY TERTIARY
GEN. LITHOLOGY - -
A$EASUF.ED LJ MEASURED
HYD. COND. _..- FTJOAY Lj ESTIMATED F )DAY [] ESTIMATED'
THICKNESS FT.
PR
NO, OF MONITER WELLS. DPQSED`, UP------._... _ DOWN FJ(1ST1NG: U1' DOWN r �:
cr+ r
FROM WORKSHEET: SITE NUMERICAL DESCRIPTION-
T 1 2 3 4 5 _._ 6 6A 6B
SITE GRADE (HYDROGEQL.) a SITUATION GRADE .
PROPOSED SAMPLING SCHEDULE & PARAMETER(S):+4;^`
HAVE THERE BEEN ANY EXCEEDANCES OFTFIE GROUNDWATER STANDARDS? YES �r NO
HAS ANY ENFORCEMENT ACTION BEEN TAKEN? YES NO _ �� DATE OF A'n ION:
BRIEF SUMMARY OF ENFORCEMENT.ACTION TAKEN:
REMARKS/ RECOMMENDATIONS (Continue on reverse, if necesssry):
HYD. REGIONAL SUPERVISOR
GW-48 Revised 0024

f
,- GROUNDWATER SECTION GW
DIVISION OF ENVIRONMENTAL MANAGEMENT
RECCRO bP WASTE DISPOSAL lsr=RUlr T APPLICA TION RSVIEvV
REVIEW BY'
FACILITY NAj5M
LOCATION
TYPE OF DISPOSAL SYSTEM (LAGOON, ETC.)
-_ DESCRIPTION OF
SIZE OF IMPOUNDMENT (FT. 80.) .
W�A, R : MUN. SLUDGE-
DATE�di rlEt i� P�lV�1`(C,A'ildN?.(Y1N) �?
- - CCUNTY -~
3 ,O -s DESIGN CAP. (02FD)
WCR SIZE OF APPLICATION AREA -
MUN. W. WATER: -PRIMARY
. PRIMARY
I�DGE —IND. WELL WATER
- — -. OTHERS: -- .. ,
SECONDARY
TERTIARY
DISTANCE FROM WASTE SOURCETO NEAREST: STREAM FT., WELL FT -
FOR WELL: TYPE OF USE 05PTH PUMP RATE (EST-)
WHAT DESIGN CONDI ONS WIL EDUCEII CS5AS5 CHANCE OF GW CONTAMINATION' �= � - �� ^ `-• �`' ® �
WHAT NA T URAt: SITE CONDITIONS WILL REDUC C;JE=AS HANCE OF GW CONTAM;NA710N:
FT., SEASONAL HIGH W.T. � FT., ANNUAL W.T. FLUX
DEPTH TO: BEDROCK
SURFICIAt AQUIFERBEDROCKJARTESIAN AOUIFEA :t =:;
4
GEN. LITHOLOGY MEASURED
HYD. COND. ._..__ FTJ1)AY HESTIMATE
THICKNESS _ " Fr.
NO, OF MONITER WELLS. F'ROPOSlmI7: UP
O KSHE=T SITE NUMERICAL DESCRIPTIONm
-
IT
MEASURE
D FTJl7,',Y ® ESTIMATED'
DOWN ...m ; EXISTING: U DOWN-,_-.- -;
� n
FROM W R--
T I 2 3 4 5 6 6A 6B
SITE GRADE(HYDROGEOW _F SITUATION GRADE -
PROPOSeO SAMPLING $CHeDULE & PARAMETER($): mow`
.,.- 4--
HAVE THERE BEEN ANY EXCEEDANCES OF THE GROUNDWATER STANDARDS? YES -✓ NO
HAS ANY ENFORCEMENT ACTION BEEN TAKEN? YES NO _. - DATE OF A TION: f
BRIEF SUMMARY OF ENFORCENIENT-ACTION TAKEN: 1
REMARKS[ RECOMMENDATIONS (Continue on reverse. ifi necessary):
HYp. RlrGIONP,L SUP�r�V1SOt�
GW-48 Revised a4094
m

GRQUN®WATER SIeOTtOra GW #e
DIVISION OF ENVIRONMENTAL MANAGEMENT
RECC9RO OF WASTE DISPOSAL PERM -IT APPLICA T ION REVI-1
REVIEW Sy a e.-� DATE 12,&l'lo 9 FIELD IN TIGATION? (YIN) `
FACILITY NAME e_ °" COUNTY 4­0
LOCATION 913<
TYPE OF DISPOSAL SYSTEM (LAGOON, ETC.)-•° DESIGN CAP. (GPD)
DESCRIPTION OF FACILITY °`f'
ra raa � s�aZf & i �`h
SIZE OF IMPOUNDMENT (FT. SQ.) WOR SIZE OF APPLICATION AREA
W��RCE: MUN, SLUDGE- MUN. W. WATER: —PRIMARY PRIMARY SECONDARY TERTIARY
— IND. SLU0(3E -- INO. WELL WATER -- — OTHERS:
DISTANCE FROM WASTE SOURCE TO NEAREST: STREAM Ff., WELL " �� FT -
FOR WELL: TYPE OF USE TH PUMP RATE (EST-)
t
WHAT DESIGN CONDITj ONS WIL EDUCE/I CR5ASS CHANCE OF GW CONTAMINATIC7?�: I"
;' � •d � .
WHAT NA T URAtSITE CONDITIONS WILL REDUC C;; S HANCE OF GW CONTAMINATION:
DEPTH TC: SEDROCK
FT., SEASONAL HIGH W.T- Fi`., j:NNUAL W.T. FLUX
SURFICIAL AQUIFER BEDROCKIARTESIAN AQUIFER
GEN. LITHOLOGY -- _ MEASURED
® MEASURED HYD. COND. _..-_FTJDAY ® ESTIMATED FTlf�'+Y ®ESTIMATED?
�� N
THICKNESS FT.
NO. OF MONITER WELLS: PROPOSED: up_ DOWN ,® ; EXITING: LIP_ — DOWN
(01
FROM WORKSHEET: SITE NUMERICAL DESCRIPTION-
T 1 2 3 4 5 6 6A 66
SITE GRADE (HYDROGEOL.) a L�J� SITUATION GRADE
PROPOSED SAMPLING SCHEDULE & PARAMETER(S): `-
HAVE THERE BEEN ANY EXCEEDANCES OF THE GROUNDWATER STANDARDS? YES NO
HAS ANY ENFORCEMENT ACTION BEEN TAKEN? YES NO DATE OF A:` TION:
BRIEF SUMMARY OF ENFORCEMENT -ACTION TAKEN:
r.
REMARKS/ RECOMMENDATIONS (Continue on reversa, if necessary):--
HYD. REGIONAL SUPERVISOR
GW-48 Revised 04194

GROUNDWATER SECTION GW It f / �29
DIVISION OF ENVIRONMENTAL MANAGEMENTS
RECORD OF WASTE DISPOSAL PE;;MI T AFPLIC.A i IdN REVIEW
REVIEW ®Y t)ATE 1.2,11011, FIELD I AVWIGATION? (YIN) !-.-•—
FAC:ILI7Y NAME COUNTY
LOCATION I 0.5-r
TYPE OF DISPOSAL SYSTEM (LAGOON, ETC.) `D DESIGN CAP. (GPD)
DESCRIPTION OF FACILITY
A•M��.arj'� �6a,Cs t/" ��m-f`8�-"3gr �'}�'%�'. BrbAl✓.LPG!'` ,
SIZE OF IMPOUNDMENT (FT. 80.) WOR SIZE OF APPLICATION AflEA
W R : MUN. SLUDGE- MUN. W. WATER: PRIMARY SECONDARY TERTIARY
-- IND. SLUDGE IN0. WELL WATER OTHERS: — '
DISTANCE FROM WASTE SOURCE TO NEAREST: STREAM Fr., WELL — 14Z FT.
FOR WELL: TYPE OF USE WTH PUMP RATE (EST_)
WHAT DESIGN COND►�ONS WIL EOUCE/I CREASE CHANCE OF GW CONgAMINATION'
WHAT NA T URAE SITE CONDITIONS WILL RFDUC CREAS HANCF OF GW C4NTAMEivATION:
FT., SEASONAL HIGH W_T._ _ ANNUAL W.T. FLUX
DEPTH TO: SEDROCK —`
SURFIOIAL AQUIFERBEDROCKJAhTESIAN AQUIFER
4
GEN. LITHOLOGY AIEASUF,ED MEASURED" `-
HYD. COND. — FTJI)AY ESTIMATED FTJD;1Y ®ESTIMATED ?
THICKNESS FT.
NO, OF MONITER WELLS. PROPOSED: UP - _ DOWN
1=RnM WnRKSHFFT� SITI= NUMERICAL DESCRIPTIONw ✓
5 6 6A 66
SITE GRADE (HYDROGEOL.) $F5 SITUATION GRADE= -
PRiOPOSI=D SAMPLING SCHEDULE & PARAME7ER(S):
.x"
HAVE THERE BEEN ANY EXCEEDANCES OF THE GROUNDWATER STANDARDS? YES �_� NO
HAS ANY ENFORCEMENT ACTION BEEN TAKEN? YES NO DATE OF A. `;TICN:
BRIEF SUMMARY OF ENFORCEmiI NT ACTION TAKEN:
J ,
REMARKS/ RECOMMENDATIONS (Continue on reverse, if necessarY):
v
HYD. REGIONAL SUPERVISOR
GW-48 Revised 04/94

FT.
f d ✓ �-'
GROUNDWATER SECTION GW # !
:DIVISION OF ENVIRONMENTAL MANAGEMENT
RECOFjO OF WASTE DISPOSAL P(=qW T APPLICA T ICK REVIEW
REVIEW UY
FACILITY NAME
LOCATION I
TYPe OF DISPOSAL SYSTEM (LAGOON, ETC.)
DESCRIPTION OF FACILITY
SIZE OF IMPOUNDMENT (FT. SQ.) .
WASTE,$O lR : MUN. SLUDGE-
DATE i.�%i7l�i' � PIEL O Iigvl STIGATION? (YIN) '—
COUNTY
(DESIGN CAP. (GPD)
WOR SIZE OF APPLICATION f-SiF-A
MUN. W. WATER:
V IND SLU17GE -- INO. WELL WATI_R
. _ PRIMARY —SECONDARY
— _- - _OTHERS: — -�
TERTIARY
DISTANCE FROM WASTE SOURCE TO NEAREST: STREAM Fr., WELL "' d"C FT.
FOR WELL: TYPE. OF USE TH PUMP RATE (i=ST_)
WHAT CESICN C®IVDI�ONS WIL EDUCFII ^CRE SE CHANCE OF GW CON AMINATIC : 9f ��
d'' Greed h °$ �'' /m .
WHAT( NATURAL: SITE CONDITIONS WELL RE/DUC CIS! AS HANCE OF GW CONTAMINATION:
FT., P..NNUAL W.T. FLUX --FT-
DEPTH TC' SEDROCK FT., SEASONAL HIGH W.T. _ _�--
SURFICIAL AQUIFER BF-TE. AQUIF�FRI,. y-
GEN. LITHOL06Y mEASUFED
HYD- CONO. --- FTJDAY HESTIMATED
TH10KNESS
NO. OF MONITER WELLS: F'AOPOSED: UP _ __
FROM WORKSHEET: SITE NUMERICAL DESCRIPTION-
- - LJ MEASUREU-
FT li�:yY ESTIMATED
- (ni
DOWN ; EXISTING: Uti DOWN
T t 2 3 4 5.-. 6 6A 6B
GRADEa
SITE GRADE (HYDADGEOL.) _[ SITUATION
PROPOSED SAMPLING SCHEDULE & PARAMET'M(S):
HAVE THERE BEEN ANY EXCEEDANCES OF THE GROUNDWATER STANDARDS? YES NO —�
HAS ANY ENFORCEMENT ACTION -BEEN TAKEN? YES NO DATE OF ATION: f
BRIEF SUMMARY OF ENFORCEMENT.ACTION TAKEN:
REMARKS/ RECOMMENDATIONS (Continue on reverse. If necessary):
HYD. REGIONAL SUPERVISOR
GW-48 Revised 04J94

DIVISION OF WATER QUALITY
GROUNDWATER SECTION
December 30, 1998
MEMORANDUM
To: Kim Colson
Water Quality Section
Through: Bob Cheek i C'
From: Brian Wootton
Subject: Alchem, Inc.
Wastewater Recycle System
Rowan County
Permit No. WQ0002702/GW98150
Joe Pearce: SERG Review Engineer
The Groundwater Section has reviewed the subject permit renewal/modification request for
the continued operation of the recycle system and modification to "mix the sand by product, which
is a result of Bauxite mixing with Sulfuric Acid at a high temperature with clay".
Groundwater sampling results obtained from the two (2) existing downgradient monitor wells
indicate there have been no exceedances 2L Groundwater Standards since groundwater sampling
commenced. The parameters TSS, SO4, and TDS may be omitted from the groundwater sampling
program. The upgradient monitor well, MW-1 (a potable well), is also sampled separate from this
permit. Groundwater Samples obtained from this well have had exceddances of 2L Groundwater
Standards for Sulphate (SO4) and TDS. The high concentrations of these parameters are most likely
coming from a source upgradient of monitor well MW-1 and not the downgradient lined lagoons
associated with this permit. Since this well (MW-1) is also being sampled separate from this permit,
the requirement for the continuation of sampling of this well is not necessary as a condition in this
permit. Also the installation of another new upgradient monitor well is not necessary, since
background concentrations have been established.
in the water supply well (MW-I) separate However, the owner of the Alchem, Inc. this
l have
to address the problem of the 2L exceedanc
permit.
Based upon the Groundwater Section's review of the subject permit application and
supporting documentation, the Groundwater Section makes the following recommendations:

DMSION OF WATER QUALITY
GROUNDWATER SECTION
December 30, 1998
MEMORANDUM
To: Kim Colson
Water Quality Section
Through: Bob Cheek V Z-' ` G
From: Brian Wootton 095W
Subject: Alchem, Inc.
Wastewater Recycle System
Rowan County
Permit No. W00002702/GW98150
Joe Pearce: SERG Review Engineer
The Groundwater Section has reviewed the subject permit renewal/modification request for
the continued operation of the recycle system and modification to "mix the sand by product, which
is a result of Bauxite mixing with Sulfuric Acid at a high temperature with clay".
Groundwater sampling results obtained from the Groundwater (2) existing Standards sdowngradient ince groundwaterltor 'Wells
sampling
indicate there have been no exceedances 2L
commenced. The parameters TSS, SO4, and TDS may be omitted from the groundwater sampling
program. The upgradient monitor well, MW-1 (a potable well), is also sampled separate from this
permit. Groundwater Samples obtained from this well have had exceddances of 2L Groundwater
Standards for Sulphate (SO4) and TDS. The high concentrations of these parameters are most likely
coming from a source upgradient of monitor well MW-1 and not the downgradient lined lagoons
associated with this permit. Since this well (NIW-1) is also being sampled separate from this permit,
the requirement Tor the continuation of sampling of this well is not necessary as a condition in this
permit. Also the installation of another new upgradient monitor well is not necessary, since
background concentrations have been established. Roin the water uesowner of the Alchem, Inc. pply well (NIW-1) separate this
l have
to address the problem of the 2L exceeda
permit.
Based upon the Groundwater Section's
s the following recommendations:
application an
supporting documentation, the Groundwater Section make
1

rY
DIVISION OF WATER QUALITY
GROUNDWATER SECTION
December 30, 1998
MEMORANDUM
To: Kim Colson
Water Quality Section
Through: Bob Cheek �C'
From: Brian Wootton
Kam`
Subject: Alchem, Inc.
Wastewater Recycle System
Rowan County
Permit No. W00002702/GW98150
Joe Pearce: SERG Review Engineer
The Groundwater Section has reviewed the subject permit renewal/modification request for
the continued operation of the recycle system and modification to "mix the sand by product, which
is a result of Bauxite mixing with Sulfuric Acid at a high temperature with clay".
Groundwater sampling results obtained from the two (2) existing downgradient monitor wells
indicate there have been no exceedances 2L Groundwater Standards since groundwater sampling
commenced. The parameters TSS, SO4, and TDS may be omitted from the groundwater sampling
program. The upgradient monitor well, MVJ-1 (a potable well), is also sampled separate from this
permit. Groundwater Samples obtained from this well have had exceddances of 2L Groundwater
Standards for Sulphate (SO4) and TDS. The high concentrations of these parameters are most likely
coming from a source upgradient of monitor well MW-1 and not the downgradient lined lagoons
associated with this permit. Since this well (NW-1) is also being sampled separate from this permit,
the requirement for the continuation of sampling of this well is not necessary as a condition in this
permit. Also the installation of another new upgradient monitor well is not necessary'I have
, since
background concentrations have been established.
edances in the water supply well (MW-1) separatell
to address the problem of the 2L exce of this
permit.
-Based upon the Groundwater Section's
review
makes the followsubject recompermit
mendationon and
supporting documentation, the Groundwater Section
1

DMSION OF WATER QUALITY
GROUNDWATER SECTION
December 30, 1998
MEMORANDUM
To: Kim Colson
Water Quality Section
Through: Bob Cheek V Z2 C'
From: Brian Wootton��
Subject: Alchem, Inc.
Wastewater Recycle System
Rowan County
Permit No. W00002702/GW98150
J.oe Pearce: SERG Review Engineer
The Groundwater Section has reviewed the subject permit renewal/modification request for
the continued operation of the recycle system and modification to "mix the sand by product, which
is a result of Bauxite mixing with Sulfuric Acid at a high temperature with clay".
Groundwater sampling results obtained from the two (2) existing downgradient monitor wells
indicate there have been no exceedances 2L Groundwater Standards since groundwater sampling
commenced. The parameters TSS, SO4, and TDS may be omitted from the groundwater sampling
program. The upgradient monitor well, N4W-1 (a potable well), is also sampled separate from this
permit. Groundwater Samples obtained from this well have had exceddances of 2L Groundwater
Standards for Sulphate (SO4) and TDS. The high li n 1 andsof n t the dparameters are most likely
owngradient lined lagoons
coming from a source upgradient of monitor we
associated with this permit. Since this well (NfW-1) is also being sampled separate from this permit,
the requirement for the continuation of sampling of this well is not necessary as a condition in this
permit. Also the installation of another new upgradient monitor well is not necessary, since
background concentrations have been established. However, the owner of the Alchem, Inc. will have
to address the problem of the 2L exceedances in the water supply well NW-1) separate of this
permit.
Based upon the Groundwater Section's review of the subject permit application and
supporting documentation, the Groundwater Section makes the following recommendations:

DMSION OF WATER QUALITY
GROUNDWATER SECTION
December 30, 1998
MEMORANDUM
To: Kim Colson
Water Quality Section
Through: Bob Cheek 13- G'
From:
Brian Wootton
Subject: Alchem, Inc.
Wastewater Recycle System
Rowan County
Permit No. W00002702/GW98150
Joe Pearce: SERG Review Engineer
The Groundwater Section has reviewed the subject permit renewal/modification request for
the.continued operation of the recycle system and modification to "mix the sand by product, which
is a result of Bauxite mixing with Sulfuric Acid at a high temperature with clay".
Groundwater sampling results obtained from the two (2) existing downgradient monitor wells
indicate there have been no exceedances 2L Groundwater Standards since groundwater sampling
m
comenced. The parameters TSS, SO4, and TDS may be omitted also om the groundwater sepaate sampling
a fromthis
program. The upgradient monitor well, MVJ-1 (a potable well),sampled
permit. Groundwater Samples obtained from this well have had exceddances of 2L Groundwater
Standards for Sulphate (SO4) and TDS. The high concentrations of these parameters are most likely
coming from a source upgradient of monitor well MW-1 and not the downgradient lined lagoons
associated with this permit. Since this well (N ff-1) is also being sampled separate from this permit,
the requirement for the continuation of sampling of this well is not necessary as a condition in this
permit. Also the installation of another new upgradient monitor well is not necessary, since
background concentrations have been established. However, the owner of the Alchem, Inc. will have
to address the problem of the 2L exceedances in the water supply well (MW-1) separate of this
permit.
Based upon the Groundwater Section's review
s the subject permit
recommendationon an
supporting documentation, the Groundwater Section make

* 1. Existing monitor wells, MW-1 and MW-2, depicted on Attachment A, shall be sampled
February and July for the following parameters.
Water Level pH
Aluminum
nfor the
2. The measurement of water levels must be each well shall be made
easured from the prior to surveyed point the
ng
parameters. The depth to water inea
top of the casing.
3. The results of the sampling and analysis must be received on Form GW-59 (Groundwater
Quality Monitoring: Compliance Repoi: Form) by the Groundwater Section, Permits and
Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on or before the last working
day of the month following the sampling month.
4. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in
15ANCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary for
the disposal system individually permitted after December 31, 1993 is established at either
(1) 250 feet from the waste disposal area, or (2) within 50 feet of the property boundary,
whichever is closest to the waste disposal area. An exceedance of Groundwater Quality
Standards at or beyond the Compliance Boundary is subject to immediate remediation action
in addition to the penalty provisions applicable under General Statute 143- 215.6A(a)(1).
In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the
disposal system midway between the Compliance Boundary and the perimeter of the waste
disposal area. Any exceedance of standards at the Review Boundary shall require remediation
action on the part of the permittee.
5. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall
be provided.
*Denotes different language than the shell document.
cc: Barbara Christian
Permit Files
2

*1. Existing monitor wells, MW-1 and MW-2, depicted on Attachment A, shall be sampled
February and July for the following parameters: r
Water Level pH
Aluminum
2. The measurement of water levels must be made prior to sampling for the remaining
parameters. The depth to water in each well shall be measured from the surveyed point on the
top of the casing. -
3. The results of the sampling and analysis must be received on Form GW-59 (Groundwater
Quality Monitoring: Compliance Report Form) by the Groundwater Section, Permits and
Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on or before the last working
day of the month following the sampling month.
4. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in
15ANCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary for
the disposal system individually permitted after December 31, 1983 is established at either
(1) 250 feet from the waste disposal area, or (2) within 50 feet. of the property boundary,
whichever is closest to the waste disposal area. An exceedance of Groundwater Quality
Standards at or beyond the Compliance Boundary
uunderbject to Generalimmediate ute 143 215 t6A(a)(1)
in addition to the penalty provisions applicable
In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the
disposal system midway between the Compliance Boundary and the perimeter of the waste
disposal area. Any exceedance of standards at the Review Boundary shall require remediation
action on the part of the permittee.
quality monitoring, as deemed necessary by the Division, shall
5. Any additional groundwater
be provided.
*Denotes different language than the shell document.
cc: Barbara Christian
Permit Files
2

Existing monitor wells, MW-1 and MW-2, depicted on Attachment A, shall be sampled
February and July for the following parameters:
Water Level pH
Aluminum
2. The measurement of water levels must be made prior to sampling for the remaining
parameters. The depth to water in each well shall be measured from the surveyed point on the
top of the casing.
3. The results of the sampling and analysis must be received on Form GW-59 (Groundwater
Quality Monitoring: Compliance Report Form) by the Groundwater Section, Permits and
Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on or before the last working
day of the month following the sampling month.
4. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in
15ANCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary for
the disposal system individually permitted after December 31, 1983. is established at either
(1) 250 feet from the waste disposal area, or (2) within 50 feet of the property boundary,
whichever is closest to the waste disposal area. An exceedance of Groundwater Quality
Standards at or beyond the Compliance Boundary is subject to immediate remediation action
in addition to the penalty provisions applicable under General Statute 143- 215.6A(a)(1).
In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the
disposal system midway between the Compliance Boundary and the perimeter of the waste
disposal area. Any exceedance of standards at the Review Boundary shall require remediation
action. on the part of the permittee.
5. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall
be provided.
*Denotes different language than the shell document.
cc: Barbara Christian
Permit Files
2

*1. Existing monitor wells, MW-1 and MW-2, depicted on Attachment A, shall be sampled
February and July for the following parameters:
Water Level pH
Aluminum
2. The measurement of water levels must be made prior to sampling for the remaining
parameters. The depth to water in each well shall be measured from the surveyed point on the
top of the casing.
3. The results of the sampling and analysis must be received on Form GW-59 (Groundwater
Quality Monitoring: Compliance Report Form) by the Groundwater Section, Permits and
Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on or before the last working
day of the month following the sampling month.
4. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in
15ANCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary for
the disposal system individually permitted after December 31, 1983 is established at either
(1) 250 feet from the waste disposal area, or (2) within 50 feet of the property boundary,
whichever is closest to the waste disposal area. An exceedance of Groundwater Quality
Standards at or beyond the Compliance Boundary is subject to immediate remediation action
in addition to the penalty provisions applicable under General Statute 143- 215.6A(a)(1).
In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the
disposal system midway between the Compliance Boundary and the perimeter of the waste
disposal area. Any exceedance of standards at the Review Boundary shall require remediation
action on the part of the permittee.
5. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall
be provided.
*Denotes different language than the shell document.
cc: Barbara Christian
Permit Files
2

I. Existing monitor wells, MW-1 and MW-2, depicted on Attachment A, shall be sampled
February and July for the following parameters:
Water Level pH
Aluminum
2. The measurement of water levels must be
be measu�ed from thr to e sgrveyed poinfor t the
aining
parameters. The depth to water m each well s
top of the casing.
3. The results of the sampling and analysis must be received on Form GW-59 (Groundwater
Quality Monitoring: Compliance Report Form) by the Groundwater 2�626 0578 on or beforelthe P mits and
working
Compliance Unit, P.O. Box 29578 Raleigh, N.C.
day of the month following the sampling month.
4. The COMPLIANCE BOUNDARY for the disposal system is specified by.regulations in
15ANCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary for
the disposal system individually permitted after December 31, 1983 is established at either
(1) 250 feet from the waste disposal areaor ,
within 5 . 0 feet of the property An exceodance o Groundwater Quality
whichever is closest to the waste disposal area
Standards at or beyond the Compliance Boundary is subject to immediate remediation action
in addition to the penalty provisions applicable under General Statute 143- 215.6A(a)(1).
In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the
disposal system midway between the Compliance Boundary and the -perimeter of the waste
disposal area. Any exceedance of standards at the Review Boundary shall require remediation
action on the part of the permittee.
5. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall
be provided.
*Denotes different language than the shell document.
cc: Barbara Christian
Permit Files
PA

ALCHEM, INC
8135 RED ROAD
ROCKWELL, NC 28138
704.279.7908 fax [phone]
ga1y_23;01-4
NCDENR-DWQ
PERMIT NO WQOO 163 3 8
Enclosed are the three copies of the Bauxite Residuals Report for Permit
WQ0016338. If you have any questions or would like to discuss this further
please do not hesitate to call me at 704-279-7908 or e-mail me at:
[e-mail]
Thanks you,
Patty Fry
Office Manager
Alchem, Inc
D FE; C071 1 1 E
AUG - 3 2010
JUL 29
Z010

elil-ol e n 0 n e
UG - 3 2010
FINAL REPORT OF ANALYSES
Pam Hester
D'ii/_Q.-!-`;;tait2r Protection
July 12, 2010
TBL Laboratory
Client Project
Name
Alchem
P.O. Box 589
Client Project
Number TBL-21522
Lumberton, NC
28359
PO Number
E1 Project Number e14792
Sample #
Sample ID
Sand Residuals
Sample Matrix
SS
Sample Type
Date Received
07/02/2010
Date Sampled
06/30/10
Time Sampled 1400
Time Received
1035
Delivered by
FedEx .
Sampler
Received by
RLC
E1 Sample
# 14792
Parameter
Result
Result
Unit Dilution
DL
Method
Date
As Received
Dry Basis
Sodium
69.4
118
mg/Kg 50
0.8
EPA 200.8
07/07/2010
Magnesium
713
1208
mg/Kg 50
0.8
EPA 200.8
07/07/2010
Alurninum
Phosphorus
20124
26.0
34108
mg/Kg 2000
0.08
EPA 200.8
07/07/2010
Calcium
43076
44.1
73010
mg/Kg 1
mg/Kg 500
0.8
2.0
EPA 200.8
07/07/2010
Chromium
12.7
21.5
mg/Kg 1
0.08
EPA 200.8
EPA 200.8
07/07/2010
07/07/2010
Manganese
Nickel
10.9
18.5
mg/Kg 1
0.08
EPA 200.8
07/07/2010
Copper
4.95
2.48
8.39
mg/Kg 1
0.08
EPA 200.8
07/07/2010
Zinc
4.20
mg/Kg 1
0.08
EPA 200.8
07/07/2010
Arsenic
36.8
0.367
62.4
0.622
mg/Kg 50
0.08
EPA 200.8
07/07/2010
Selenium
< 0.08
< 0.136
mg/Kg 1
mg/Kg 1
0.08
0.08
EPA 200.8
EPA 200.8
07/07/2010
07/07/2010
Silver
Cadmium
< 0.08
< 0.136
mg/Kg 1
0.08
EPA 200.8
07/07/2010
Barium
0.220
31.6
0.373
mg/Kg 1
0.08
EPA 200.8
07/07/2010
Lead
55.6
mg/Kg 50
0.08
EPA 200.8
07/07/2010
Mercury
7.78
0.098
13.2
0.166
mg/Kg 1
0.08
EPA 200.8
07/07/2010
Solids
59.0
mg/Kg 1
0.02
EPA 7471A
07/08/2010
pH, as received
9.31
%
SU
SM2540G
07/12/2010
EPA 9045C
07/07/2010
Ken Smith, Laboratory Director
TBL-21522 Report.doc Compiled by
NC Certifications: DW 37788 and DWQ DENR 604
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