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HomeMy WebLinkAboutWI0400468_APPLICATION FOR PERMIT_20190625 North Carolina Department of Environmental Quality—Division of Water Resources APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION In Situ Groundwater Remediation (15A NCAC 02C.0225)/ Tracer Injection (15A NCAC 02C.0229) Do not use this form for the following: • In-situ remediation,tracer, or aquifer test injection wells permitted by rule(ref. 15A NCAC 02C .0217) • remediation systems that reinject treated contaminated groundwater(Non-discharge)(ref. 15A NCAC 02T.1600) Permit Number(to be completed by DWR): WI APPLICATION INFORMATION 1. Project is: [ ]New [X] Modification [ ] Renewal without modification [ ] Renewal with modification 2. If this application is being submitted for Renewal and/or Modification to an existing permit,provide: (a.)Existing permit number WI0400468 Issued Date: 6/20/2017 &Expiration Date: 5/31/2022 For all Renewals, submit a status report including monitoring results of all injection activities to date. For Renewal without modification only,fill out sections I&II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent(if the applicant is not the owner). II. WELL OWNER(S)/PERMIT APPLICANT (generally the responsible party) 1. Name(s): Cintas Corporation 2. Signing Official's Name*: Stephen Koehler Title: Chemical/Environmental Engineer * Signing Official must be in accordance with instructions in Part X on page 5. 3. Mailing address of Permittee/Applicant: 27 Whitney Drive City: Milford State: OH Zip: 45150 4. Telephone number: 513-965-4906 Email: KoehlerS@cintas.org 5. Status(choose one): Individual X Business/Org. Federal State County Municipality III. PROPERTY OWNER(S) (if different than well owners) 1. Name(s): Champion Industries (Roddy Sugg/William Means II) 2. Mailing address: 3765 Champion Blvd City: Winston-Salem State: NC Zip: 27105 3. Telephone number: 336-661-1556 Email: rsugg@championindustries.com IV. PROJECT CONTACT—(generally the environmental/engineering consultant). 1. Name: Bethany Donovan Title: Staff Geologist 2. Company: AECOM 3. Address: 1600 Perimeter Park Drive, Suite 400 4. City: Morrisville State: NC Zip: 27560 5. Telephone number: 919-461-1560 Email: bethany.donovan@aecom.com In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 1 of 6 V. FACILITY INFORMATION 1. Facility name: Former RUS Facility Phone No. if available: 2. Physical address: 3775 Industrial Drive City: Winston-Salem County:Forsyth Zip: 27105 3. Geographic Coordinates: Latitude: 36° 8'58.96" Longitude: -80° 14' 27.55" Reference Datum: WGS94 Accuracy: Method of Collection(i.e.,Google Earth,GPS,etc.): Google Earth 4. Brief description of business: Former industrial laundry and now a paper shredding facility VI. INCIDENT DESCRIPTION 1. Source and date of contamination: The Former RUS facility operated as a dry-cleaning facility from 1968- 1985.Investigations on Site began in 1999 following the discovery of PCE in groundwater on the adjacent property. There is no record of a specific incident leading to the contamination of the nearby soils and groundwater. Four potential sources have been identified during investigations:the former dry-cleaning room, the former interior wash line trenches,the former exterior wastewater basins, and an exterior area on the southwest corner of the facility parking lot. 2. List all contaminants present in soils or groundwater at the site(contaminants may be listed in groups, e.g.,gasoline, diesel,jet fuel,fuel oil, chlorinated ethenes, chlorinated ethanes, metals,pesticides/herbicides, etc): cis-1,2-Dichloroethylene, tetrachloroethene, trichloroethene, vinyl chloride 3. Has LNAPL or DNAPL ever been observed at the site(even if outside the injection zone)? [] Yes If yes, list maximum measured separate phase thickness: feet [X]No If no, list maximum concentration of total VOCs observed at site: 30,545 ppb 4. Agency managing the contamination incident: [] UST Section [x] Superfund Section(including REC Program and DSCA sites) [] DWR Aquifer Protection Section [] Solid Waste Section [] Hazardous Waste Section [] Other: 5. Incident manager's name: Bill Bremen(Registered Site Manager) Phone No.: 919-461-1214 6. Incident number or other incident mgmt. agency tracking number: NONCD-0002431 VII. PERMITS List all applicable permits or construction approvals issued for the facility or incident: 1. Previous or other UIC permits issued by DWR(e.g.,NOIs) WI0400384, WI0400367, WI0400468 2. Other Non-Discharge or NPDES permit issued by DWR: N/A 3. County or DEH subsurface wastewater disposal permits: N/A 4. Hazardous waste management or other environmental permits required by state or federal law: N/A In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 2 of 6 VIII. INJECTION SUMMARY 1. List all proposed injectants/additives. NOTE: Only injectants approved by the epidemiology section of the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/ground-water-approved-injectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919-807-6496) if you wish to get approval for a different additive. However,please note it may take 3 months or longer. Injectant: AquaZVI®Suspension Total Amt. to be injected(gal)/event 23,651 Injectant: PlumeStopTM Suspension Total Amt. to be injected(gal)/event 17,049 Injectant: ORC Slurry Total Amt. to be injected(gal)/event 647 Injectant: Total Amt. to be injected(gal)/event Injectant: Total Amt. to be injected(gal)/event 2. Number of separate injection events: 1 Duration of Event: —30 days 3. Estimated Injection rate per well: 0.1-10 gallons per minute(GPM) 4. Estimated Injection pressure: <50 pounds/square inch(PSI) 5. Temperature at point of injection: ambient air °F 6. Injection will be via: ❑ Existing well(s); Total No.: ; Well Type(DPT,Permanent, etc.): ❑ Proposed well(s); Total No.: 76 ; Well Type(DPT,Permanent, etc.): DPT 7. NC Certified Well Drilling Contractor's Name(if known): NC Well Contractor Certification No.: 8. Date to be constructed if proposed: Summer/Fall 2019 9. Screened interval/Injection interval of injection wells: Depth from 9 to 35 feet below land surface(BLS)(if multiple intervals, indicate shallowest to deepest depth) 10. Well casing(leave blank if Geoprobes®): Type:❑ PVC ❑ Stainless steel ❑ Other: Casing depth: to ft. BLS Type:❑ PVC ❑ Stainless steel ❑ Other: Casing depth: to ft. BLS 11. Grout(leave blank if Geoprobes): Type: ❑ Cement 0x) Bentonite ❑ Other:_ Grout depth: _3 to 5 ft. BLS Type: D) Cement ❑ Bentonite ❑ Other:_ Grout depth: 0 to 3 ft. BLS In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 3 of 6 IX. ATTACHMENTS — provide the following information in separate attachments. The attachments should be clearly identified and presented in the order below to expedite review of the permit application package. 1. INJECTION ZONE—Per 15A NCAC 02C .0225(e)(2), specify the horizontal and vertical portion of the subsurface within which the proposed injection activity will take place and beyond which no violations of groundwater quality standards shall result from the injection as determined by an approved monitoring plan. The determination shall be based on the hydraulic properties of the specified zone. Provide any supporting documentation in a separate attachment. 2. HYDROGEOLOGIC EVALUATION — Per 15A NCAC 02C .0225(e)(3), provide a hydrogeologic evaluation of the injection zone that includes all of the following: (A) Regional and local geology and hydrology; (B) Changes in lithology underlying the facility; (C) Depth to bedrock; (D) Depth to the mean seasonal high water table; (E) Hydraulic conductivity, transmissivity, and storativity, of the injection zone based on tests of site-specific material, including a description of the test(s)used to determine these parameters; (F) Rate and direction of groundwater flow as determined by predictive calculations or computer modeling; and (G) Lithostratigraphic and hydrostratigraphic logs of any existing test and injection wells. 3. INJECTANT INFORMATION—Per 15A NCAC 02C.0225(e)(5),provide information on each injectant as indicated below: (A) MSDS, concentration at the point of injection, and percentage if present in a mixture with other injectants; (B) The source of fluids used to dilute, carry, or otherwise distribute the injectant throughout the injection zone. If any well within the area of review of the injection facility is to be used as the fluid source, then the following information shall be submitted: location/ID number, depth of source, formation, rock/sediment type, and a chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site; (C) A description of the rationale for selecting the injectants and concentrations proposed for injection, including an explanation or calculations of how the proposed injectant volumes and concentrations were determined; (D) A description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; (E) A summary of results if modeling or testing was performed to investigate the injectant's potential or susceptibility for biological, chemical, or physical change in the subsurface; and (F) An evaluation concerning the development of byproducts of the injection process, including increases in the concentrations of naturally occurring substances. Such an evaluation shall include the identification of the specific byproducts of the injection process, projected concentrations of byproducts, and areas of migration as determined through modeling or other predictive calculations. 4. INJECTION PROCEDURE —Per 15A NCAC 02C .0225(e)(6), submit a table with a detailed description of the proposed injection procedure that includes the following: (A) The proposed average and maximum daily rate and quantity of injectant; (B) The average maximum injection pressure expressed in units of pounds per square inch(psi); and (C) The total or estimated total volume to be injected. In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 4 of 6 5. FRACTURING PLAN(if applicable)—Per 15A NCAC 02C.0225(e)(7), submit a detailed description of the fracturing plan that includes the following: (A) Material Safety Data Sheets of fracturing media including information on any proppants used; (B) a map of fracturing well locations relative to the known extent of groundwater contamination plus all buildings, wells, septic systems,underground storage tanks, and underground utilities located within the Area of Review; (C) a demonstration that buildings, wells, septic systems, underground storage tanks, and underground utilities will not be adversely affected by the fracturing process; (D) injection rate and volume; (E) orientation of bedding planes,joints, and fracture sets of the fracture zone; (F) performance monitoring plan for determining the fracture well radius of influence; and (G) if conducted, the results of geophysical testing or pilot test of fracture behavior conducted in an uncontaminated area of the site. 6. WELL CONSTRUCTION DETAILS — Per 15A NCAC 02C .0225(e)(8), submit the following information in tabular or schematic form as appropriate for each item: (A) number and depth of injection wells; (B) number and depth of borings if using multi-level or"nested"well systems; (C) indication whether the injection wells are existing or proposed; (D) depth and type of casing; (E) depth and type of screen material; (F) depth and type of grout; (G) indication whether the injection wells are permanent or temporary"direct push"points; and (H) plans and specifications of the surface and subsurface construction details. 7. MONITORING PLAN—Per 15A NCAC 02C.0225(e)(9), submit a monitoring plan that includes the following: (A) target contaminants plus secondary or intermediate contaminants that may result from the injection; (B) other parameters that may serve to indicate the progress of the intended reactions; (C) a list of existing and proposed monitoring wells to be used; and (D) a sampling schedule to monitor the proposed injection. Monitoring wells shall be of sufficient quantity and location to detect any movement of injection fluids, injection process byproducts, or formation fluids outside the injection zone. The monitoring schedule shall be consistent with the proposed injection schedule,pace of the anticipated reactions, and rate of transport of the injectants and contaminants. 8. WELL DATA TABULATION — Per 15A NCAC 02C .0225(e)(10), provide a tabulation of data on all existing or abandoned wells within the area of review of the injection well(s) that penetrate the proposed injection zone, including monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's type, depth, and record of construction or abandonment. 9. MAPS AND CROSS-SECTIONS — Per 15A NCAC 02C .0225(e)(11), provide scaled, site-specific site plans or maps depicting the location, orientation, and relationship of facility components including the following: (A) area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site; (B) topographic contour intervals showing all facility related structures, property boundaries, streams, springs, lakes, ponds, and other surface drainage features; (C) all existing or abandoned wells within the area of review of the wells listed in the well data tabulation that penetrate the proposed injection zone; (D) potentiometric surface map(s)that show the direction of groundwater movement, existing and proposed wells; (E) contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, and existing and proposed wells; (F) cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, major changes in lithology, and existing and proposed wells; and (G) any existing sources of potential or known groundwater contamination, including waste storage, treatment, or disposal systems within the area of review of the injection well or well system. In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 5 of 6 X. CERTIFICATION(to be signed as required below or by that person's authorized agent*) NCAC 15A 02C .0211(e)requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor,respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. *If an authorized agent is signing on behalf of the applicant,then supply a letter signed by the applicant that names and authorizes their agent. "I hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate, and complete. I am aware that there are penalties, including the possibility of fines and imprisonment,for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit." Printed Name and Title: See Attached Signature Page(Cintas) Signature: Date: XI. CONSENT OF PROPERTY OWNER(if the property is not owned by the permit applicant) "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C.0200)." Printed Name and Title: See Attached Signature Page(Champion) Signature: Date: Submit TWO hard copies of the completed application package with an electronic version in CD or USB Flash Drive to: Division of Water Resources—UIC Program 1636 Mail Service Center Raleigh,NC 27699-1636 Telephone(919) 707-9129 In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 6 of 6 X. CERTIFICATION(to be signed as required below or by that person's authorized agent*) NCAC 15A 02C .0211(e)requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor,respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. *If an authorized agent is signing on behalf of the applicant,then supply a letter signed by the applicant that names and authorizes their agent. "I hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate, and complete. I am aware that there are penalties, including the possibility of fines and imprisonment,for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit." Printed Name and Title:Stephen Koehler, Chemical/Environmental Engineer Signature: # -- ---- Date:5/30/2019 XI. CONSENT OF PROPERTY OWNER(if the property is not owned by the permit applicant) "Owner"means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C.0200)." Printed Name and Title: Signature: Date: Submit TWO hard copies of the completed application package with an electronic version in CD or USB Flash Drive to: Division of Water Resources—UIC Program 1636 Mail Service Center Raleigh,NC 27699-1636 Telephone(919) 707-9129 In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 6 of 6 CINFAS.. READY FOR THE WORKDAY- . North Carolina Department of Environmental Quality 512 N. Salisbury St. 1636 Mail Service Center Raleigh, NC 27699 1636 May 30, 2019 To whom it may concern, This letter is authorization that Stephen Koehler has signatory authority for the Cintas Former RUS Facility NCDEQ ID No. NONCD0002431 site. Sincerely, p ) Patrick Kneip Director of Chemical/Environmental Engineering Cintas Corporation Cintas Corporation 27 Whitney Drive Milford OH 45150 Office:513.965-4964 www.cintas.com X. CERTIFICATION (to be signed as required below or by that person's authorized agent*) NCAC I5A 02C .0211 (e) requires that all permit applications shall be signed as follows: 1 . for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. *if an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that names and authorizes their agent. "I hereby ceo7if under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate, and complete. I am aware that there are penalties, including the possibility offines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit " Printed Name and Title: Signature: Date: XL CONSENT OF PROPERTY OWNER (if the property is not owned by the permit applicant) "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C .0200). " Printed Name and ' le: U rL-C.I 1""-- t " C.: ,Th 9 C Signature: V Date: 7 / I7 Submit TWO hard copies of the completed application package with an electronic version in CD or USB Flash Drive to: Division of Water Resources — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 707-9129 In-Situ Groundwater Remediation Application Rev. 8-28-2017 Page 6 of 6 Attachments AECOM Application for UIC Permit WI0400468 Modification — Attachments Former RUS Facility NCDEQ ID No. NONCD0002431 Winston-Salem, North Carolina 60602461 June 2019 Cintas Corporation Mason, Ohio Application for UIC Permit W 10400468 60602461 Modification—Attachments Table of Contents 1. Injection Zone 1 2. Hydrogeologic Evaluation 1 2.1 Regional Geology and Hydrology 1 2.2 Site Geology 1 2.3 Site Hydrogeology 2 3. Injectant Information 2 4. Injection Procedure 3 5. Fracturing Plan 3 6. Well Construction Details 3 7. Monitoring Plan 3 8. Well Data Tabulation 4 9. Maps and Cross Sections 4 10. References 4 Prepared for: Cintas Corporation AECOM Application for UIC Permit W 10400468 60602461 Modification—Attachments Tables Table 1 Proposed Injection Summary Table 2 Proposed Injection Point Construction Details Table 3 Proposed Performance Monitoring Plan Table 4 Existing Well Construction Details Figures Figure 1 Site Location Map Figure 2 Site Overview and Injection Monitoring Area Figure 3 Groundwater Potentiometric Map-March 2018 Figure 4 Injection Location Map Figure 5 Saprolite& PWR Isoconcentration Map Figure 6 Cross Section Location Map Figure 7 Cross Section A-A' Figure 8 Cross Section B-B' Acronyms AECOM AECOM Technical Services of North Carolina, Inc. bgs below ground surface cm/s centimeters per second CVOC chlorinated volatile organic compound DPT direct push technology gpm gallons per minute MSDS material safety data sheet msl mean sea level PCE tetrachloroethene psig pounds per square inch gage PWR partially weathered rock ZVI zero valent iron ZVM Mixture of ZVI &aluminum-based Z-LoyTM and Z-LoyTM LA 0/0 percent pm micrometer Prepared for: Cintas Corporation AECOM Application for UIC Permit W 10400468 60602461 Modification—Attachments 1 . Injection Zone A site location map is provided as Figure 1.The map shows the proposed injection zone as stipulated in Title 15A North Carolina Administrative Code 02C.0225(e)(2)and includes an outline of the proposed groundwater monitoring area is shown on Figure 2.The active injections will take place in an area of up to approximately 5,500 square feet. The injections are proposed to be completed from approximately 9 feet below ground surface(bgs)to 35 feet bgs in the saprolite within the vicinity of monitoring well MW-11.The injection zone also includes a sorptive barrier downgradient of the injection area. 2. Hydrogeologic Evaluation 2.1 Regional Geology and Hydrology The Site is located in the Piedmont physiographic province. Both the regional and local landscape of the area is characterized by broad,gently rolling uplands and moderate to steep slopes common to the Piedmont. Geologically, the Site is located in the Milton Belt litho-tectonic province of North Carolina(Brown, 1985). Bedrock in this province is described as a metamorphic complex consisting of biotite gneiss and schist interlayered with mica, amphibolite, and granitic masses. Rocks of these compositions weather to form several distinct lithologic zones. Overlying the competent bedrock are unconsolidated, granular, and porous materials(regolith)that may consist of alluvial deposits, soils, and residual material formed from in-situ physical and chemical weathering of the parent bedrock.The portion of the regolith that is derived from weathered rock, commonly referred to as saprolite, retains much of the relic fabric, texture, and structures of the parent rock(Heath, 1989). Saprolite represents the most extreme weathered condition of the parent bedrock from which it is derived.A transitional zone of partially weathered rock(PWR)is typically found between the saprolite zone and the lower competent bedrock. PWR is typically friable bedrock that retains the parent rock structure, but it has undergone less weathering than saprolite.The transitional zone PWR often is highly fractured and permeable and contains fragments of unweathered rock. Bedrock in this region typically has decreasing fracture density with depth(Heath, 1989). Groundwater aquifer systems in this part of the Piedmont region correspond with the either unconsolidated porous media or fractured, crystalline bedrock.The porous saprolite media typically represents the unconfined or"water table" hydrostratigraphic unit of the regional aquifer. Saprolite and PWR acts as a storage reservoir for groundwater that feeds the underlying fractured bedrock hydrostratigraphic unit. PWR and bedrock units can exhibit unconfined, semi-confined,or even confined hydraulic behavior. Most water supply wells in this region tap the fractured bedrock unit. Supply wells installed in the bedrock aquifer of this region typically yield between 15 and 20 gallons per minute (gpm) (Daniel and Payne, 1990). In groundwater recharge areas of the Piedmont, the water table is usually closer to the ground surface during the winter and spring months and is typically deeper during the drier summer and autumn months. In the Piedmont, shallow groundwater generally flows away from the higher elevation recharge areas and discharges to the stream valleys at lower elevations. 2.2 Site Geology The Site is underlain by varying thicknesses of fine-grained saprolite that overlays a fractured,felsic schist bedrock. Soils(i.e., residuum)and saprolite at the Site are generally described as mottled orange/brown/gray micaceous sandy silt and clayey silt.The residual soil and saprolite unit is very thin on the northeast portion of the Site,where competent bedrock was encountered at a depth of 7 feet bgs at monitoring well MW01d.The saprolite unit thickens toward the western portion of the Site(ENVIRON, 2000;AECOM Technical Services of North Carolina, Inc. [AECOM], 2012). Depth to competent bedrock within the Cintas property boundary varies from approximately 7 feet bgs at monitoring well MW01d to 56 feet bgs at monitoring well MWO4d(ENVIRON, 2000). Depth to competent bedrock on off-site Prepared for: Cintas Corporation AECOM 1 Application for UIC Permit W 10400468 60602461 Modification—Attachments properties investigated during the Remedial Investigation ranges from 40 feet bgs at wells MW10d and MW14d to 100 feet bgs at well MW08d. In the Piedmont region the surface of competent bedrock often has a localized undulating pattern. On the Champion property southwest of the Cintas property the bedrock generally slopes in the western direction. In the area of the proposed injections near MW-11 the bedrock surface elevation is approximately 835 feet mean sea level (msl).The deepest extent of the saprolite zone that is targeted by these injections ranges approximately from 845 feet msl to 855 ft msl. 2.3 Site Hydrogeology Within the Cintas property boundary, groundwater is encountered at depths ranging from 12 to 28 feet bgs and the water table surface is found primarily in the saprolite hydrostratigraphic unit.On the east and northeast sections of the Cintas property,the saprolite unit is not saturated due to very shallow bedrock in these areas.Within the Champion property boundary, groundwater is encountered at depths ranging from 7 to 14 feet bgs and the water table surface is found within the saprolite hydrostratigraphic unit. Potentiometric elevations for shallow wells on the Champion property ranged from 873.71 to 868.59 feet msl during the most recent monitoring event in March 2018.The general groundwater flow on the Site is generally to the south/southeast towards Leak Fork Creek.The water level gauging data from the March 2018 monitoring event were used to produce the groundwater potentiometric map shown in Figure 3 for the Saprolite hydrostratigraphic unit. Using the March 2018 data for wells ART-02 and MW-11,the general hydraulic gradient of the site is calculated to be 0.027 feet per foot. Using the March 2018 data for wells PMW-3 and MW-11,the hydraulic gradient of the Champion property injection area is calculated to be 0.020 feet per foot. While aquifer tests have not been performed at the Site, several tests were conducted at a nearby site.The analogous site is located approximately 1.5 miles away. Slug Tests were conducted on both sites in monitoring wells that were screened in similar lithologies to the Saprolite unit logged at the Former Rental Uniform Service facility (sandy silt or clayey silt). At the nearby site, rising head permeability tests within the shallow Saprolite layer, a sandy silt, resulted in K values ranging from 4.45x10-4 centimeters per second(cm/s)to 5.92x10-4 cm/s(or 1.26 to 1.68 feet per day).The results of the slug testing correspond to a moderate silty sand and lithologic borings recorded at both sites that indicate saprolitic textures/Saprolite similar to the unit that will be affected by the proposed injection. 3. Injectant Information In this modification AECOM proposes to inject AquaZVI®(an aqueous suspension of colloidal zero valent iron [ZVI]) upgradient of Leak Fork Creek within the MW-11 hot spot area.AquaZVI®contains 40% colloidal ZVI with particles less than 5 micrometers(pm) in diameter. AECOM plans to inject 18,000 pounds(1,348 gallons)of AquaZVl°as a 6% by volume suspension (a total injected volume of approximately 23,650 gallons when mixed with water for injections).AquaZVI®stimulates chemical reduction processes and dechlorinates tetrachloroethene(PCE)and its daughter products. PlumeStopTM will be injected to install a sorptive barrier. PlumeStopTM consists of 75%water, less than 25% colloidal activated carbon that is less than 2.5 pm, and proprietary additives.AECOM plans to inject 9,600 pounds(1,136 gallons)of PlumeStopTM as an aqueous suspension that is approximately 6.6% PlumeStopTM by volume(a total injected volume of approximately 17,050 gallons when mixed with water for injections). The purpose of PlumeStopTM is to reduce the concentration of dissolved chlorinated volatile organic compounds(CVOCs)downgradient of the AquaZVI®injections through adsorption onto activated carbon.The PlumeStopTM barrier is intended to work in combination with the AquaZVl®to quickly and permanently reduce CVOC mass flux into the nearby Leak Fork Creek. An Oxygen Release Compound(ORC®)barrier will be installed between Leak Fork Creek and the sorptive barrier. ORC®is comprised of 60-70% magnesium hydroxide, 30-40% magnesium peroxide, less than 3% dipotassium phosphate, less than 3%monopotassium phosphate, and less than 1% magnesium oxide.The ORC®barrier exists to provide dissolved oxygen to treated groundwater before entering the creek.Approximately 1,600 pounds of ORC®will Prepared for: Cintas Corporation AECOM 2 Application for UIC Permit W 10400468 60602461 Modification—Attachments be mixed with water to create approximately 650 gallons of a 25%ORC®slurry.The material safety data sheets for AquaZVl®, PlumeStopTM, and ORC®are included in Appendix A. Municipal water will be used for dilution for the proposed injection concentrations. ZVI, PlumeStopTM and ORC®have previously been piloted at the site within the same aquifer during the Phase II and Phase III injection activities and were detailed in the Phase II/III Preconstruction Report(AECOM,2015)and Phase II/III Construction Completion Report(AECOM, 2016). Small scale injections of PlumeStopTM and ORC®,ZVM(zero valent iron(ZVI)and aluminum-based products(Z-Loy TM and Z-LoyTM LA))were completed under NCDEQ DWR UIC permit numbers W10400384&W10400367.The goal of the PlumeStopTM and ORC®injections was to decrease VOC concentrations in surface water of Leak Fork Creek downgradient of the Site(immediately downgradient of the MW- 10 cluster). The primary goal of the ZVM injections was to reduce the concentrations of PCE in the vicinity of the MW- 03 hotspot,which is was an upgradient source of contaminant flux to the PlumeStopTM application area. Following the injections, concentrations of PCE and its daughter products decreased in the vicinity of MW-03 and in the porewater and surface water samples collected in Leak Fork Creek downgradient of the injection area. The injections described above are proposed for treatment of the target zone with dimensions of approximately 5,500 square feet in area and up to 25 feet in thickness within the Champion parking lot near monitoring well MW-11. Assuming an effective porosity of approximately 20%,the proposed injection volume represents approximately a 10% displacement. Vendor assumptions are included in Appendix B. 4. Injection Procedure Table 1 summarizes the injection plan. Figure 4 shows the proposed injection locations.There will be three different injection phases during this proposed injection plan: a phase to inject AquaZVl®, a phase to inject PlumeStopTM and a phase to inject ORC.AECOM estimates the three injection phases will take approximately 30 days to complete.All three injection phases will be completed using direct push technology(DPT)injection methods.The injection flow rates are expected to range from 0.1 to 10 gpm. It is expected that the injection pressure will be approximately 50 pounds per square inch gage(psig). However,the injection rate, amount and pressure will vary depending on field conditions. 5. Fracturing Plan A fracture plan is not needed as there will be no fracturing during these phases. 6. Well Construction Details Approximately seventy-six DPT injection points are being proposed for this scope.Table 2 summarizes the proposed construction details for the temporary DPT points.The points will be advanced up to 35 feet bgs depending on the inferred thickness of the saprolite at the planned locations.Additional borings may be added within the general injection area to achieve distribution of the proposed injection reagents at the intended depth, if necessary. Additionally, up to three pore water wells will be installed on site.The porewater wells will be stainless steel push samplers that placed into the Leak Fork Creek sediments immediately adjacent to the injection zone for monitoring. Locations of the porewater wells will be determined at a future date. 7. Monitoring Plan The primary contaminant on-site is PCE. Prior to the injections,AECOM will complete a site-wide groundwater monitoring event within the 60 days prior to the injections that will serve as the baseline monitoring event for the proposed injection activities.AECOM also proposes to conduct four quarterly performance groundwater monitoring events to evaluate injection effectiveness. Finally, a larger sampling event will occur one year after the injection program that will provide a more comprehensive evaluation of all Phase IV activities. Details of these events are summarized in Table 3. Prepared for: Cintas Corporation AECOM 3 Application for UIC Permit W 10400468 60602461 Modification—Attachments 8. Well Data Tabulation See Table 4. 9. Maps and Cross Sections See Figures 1 through 8. 10. References AECOM,2012. Combined Phase l and Phase ll Remedial Investigation Report, Former Rental Uniform Services Facility. AECOM, October 5,2012. AECOM,2015. Preconstruction Report Phase II/Ill Injections for Groundwater Remediation. AECOM, February 2015. AECOM,2016. Construction Completion Report-Phase II and Phase III Injections for Groundwater Remediation and Phase I Progress Update. AECOM,July 2016. Daniel, C.C., Ill, and Payne, R.A., 1990. Hydrogeologic unit map of the Piedmont and Blue Ridge provinces of North Carolina: U.S. Geological Survey Water—Resources Investigation Report. Brown, Philip M., et al., 1985. Geologic Map of North Carolina. Developed by the North Carolina Department of Natural Resources and Community Development, Division of Land Resources, North Carolina Geological Survey. Philip Brown—Chief Geologist. ENVIRON, 2000. Comprehensive Site Assessment/Corrective Action Plan, Former Rental Uniform Services Site. ENVIRON International Corporation. May 2000. Heath, Ralph C.,1989. "The Piedmont Ground-Water System." Presented in Ground Water in the Piedmont: Proceedings of a Conference on Ground Water in the Piedmont of the Eastern United States. October 16- 18, 1989. Published by Clemson University, Clemson, South Carolina. Prepared for: Cintas Corporation AECOM 4 Application for UIC Permit W 10400468 60602461 Modification—Attachments Tables Prepared for: Cintas Corporation AECOM Table 1 Proposed Injection Summary UIC Permit WI0400468 Modification Cintas-Former RUS Facility Estimated Estimated Estimated Estimated Estimated Number of Estimated Average Estimated Injection Injection Total Volume Maximum Average Daily Maximum Daily Injection Phase Composition Method Duration Injection of Injection Maximum Injection Average Daily Daily Rate Injection Injection (days) Points (gallons) Pressure(psi) Rate(gpm) m Quantity(gal) Quantity(gal) ) (gpm) (9 ) 6.0%AquaZVI® AquaZVI® DPT 16 40 23,651 50 1.0 10 1,478 10,000 Suspension 6.7% PlumeStopTM PlumeStopTM DPT 6 16 17,049 50 1.0 10 2,842 10,000 Suspension ORC 25%ORC Slurry DPT 8 20 647 50 1.0 10 81 647 Notes -Injection pressures,durations,volumes,and concentrations are approximate and may change due to conditions encountered in the field Table 2 Proposed Injection Point Construction Details UIC Permit WI0400468 Modification Cintas-Former RUS Facility Proposed Injection Number of Injectant Installation Total Depth (ft Injection Interval Locations Injection Points Method bgs) (ft bgs) ZVI-1 through ZVI-40 40 AquaZVI® DPT 32 9-32 PS-1 through PS-16 16 PlumeStopTM DPT 35 10-35 ORC-1 through ORC-20 20 ORC® DPT 35 10-35 Notes -Injection depths are estimated and may change based on conditions encountered in the field -ft bgs:feet below ground surface -DPT:Direct Push Technology drilling/injection method -All points will be abandoned with tremie grouting techniques following injection activities Table 3 Proposed Performance Monitoring Plan UIC Permit WI0400468 Modification Cintas-Former RUS Facility Sampling Frequency Well ID Baseline Event Quarterly Events Annual Events (Within 60 days prior to (Month 1,3,6&9 Post- Month 12 Post- Tentative Schedule injection) Injection) Injection) Monitoring Wells MWO1d x MWO2 x MWO2d x MWO3 x x MWO4 x MWO4d x MWO5 x MWO6 x MWO7s x x MWO7d x MWO8 x MWO8d x MWO9 x MW10s x x x MW10 x MW 10d x MW11 x x x M W 12s(r) x MW12 x x x MW 12d x MW13 x MW 13d x MW14 x MW 14i x MW 14d x MW15s x MW15 x MW15d x MW16 x MW 16d x MW17 x MW18 x ART-1 x x ART-2 x x ART-3 x x PMW-1 x x PMW-2 x x PMW-3 x x TPMW-4 x TPMW-5 x Pore Water SPW-04b x x x SPW-05 x x x SPW-06 x x x SPW-07 x x x SPW-09 x x x SPW-17* x x x SPW-18* x x x SPW-19* x x x Surface Water SWG-3 x x x SWG-4 x x x SWG-5 x x x SWG-6 x x x SWG-7 x x x Notes Sampling events to occur prior to injections and during Month 1,Month 3,Month 6,Month 9 and Month 12 post-injection. *Up to three additional porewater sample locations have been proposed and locations will be decided on during a later date Table 4 Existing Well Construction Details UIC Permit WI0400468 Modification Cintas-Former RUS Facility WELL CONSTRUCTION DETALS Well Date Drilling TOC Elev. Total Well Depth Screen Interval Number Installed Well Materials Method (ft, msl (ft, bgs) ) (ft, bgs) I (ft, msl) 9 ) MW-10 10/27/11 2" PVC HSA 879.18 38 841.18 33-38 MW-10s 11/07/11 2" PVC HSA 879.18 15 864.18 10-15 PMW-03 01/25/15 2" PVC HSA 880.99 36 844.99 31-36 MW-11 10/24/11 2" PVC HSA 880.05 35 845.37 25-35 MW-12s(r) 05/22/12 2" PVC HSA 879.78 22 857.78 17-22 MW-12 10/27/11 2" PVC HSA 879.79 50 829.79 40-50 SPW-06 2008 1/4"SS NA 872.38 2.5 869.88 0.5-2* SPW-07 2008 1/4"SS NA NS NS NS 0.5-2* SPW-09 2008 1/4"SS NA NS NS NS 0.5-2* Abbreviations: ft-feet HSA-hollow stem auger TOC-top of casing SS-1/4"Stainless Steel Henry Samplers bgs-below ground surface NA-Not Applicable msl-mean sea level PVC-polyvinyl chloride NS-Not Surveyed Porewater samplers were installed just below the stream bed and varied at each location Application for UIC Permit W 10400468 60602461 Modification—Attachments Figures Prepared for: Cintas Corporation AECOM ta67/m y .\,4.,0,'(,",„'_''_,\__,,,....,..,-i_.,-..-,t-..—;._o.-._p...,'.,_c;,, t�1,47 t�- ` 7 \ `�ssfY; , rj • tpi r ell `'ti ' '\t•s 1ri 4.(,:,.A..r::A',f...-... �iit ‹, -,,, ,,• , . _''` � • .i; -! 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NitNy.,..-• •, i 1 ,, u, o ` -� t ' ' . . )4V/\ \*\, '' ' 10,,i, , r___.,,., b. - III, i j,,,.:r.:_ ..... s :' Illy! --N -. _ f t* --', x' 'i, '� i 1, 4,%vJ--,.i.lik ski,.'- -t1..t4..6../,A1-1i qkrft. o Fairgrords 1t i ti ,t i i,l f it l w _ 4A: /1. ,-' E,.;a.` i 1 ' ' 1'1 p: 1 r �,' ‘ + �Kl��'sr'1!1gyp rP !;�I�► IItCopynght®2013 a"_tiomal_Geograp ie'S'ocety;i cubed-cc z �I Map Location N , Winton-Salem, NC (1983) i (WL w USGS Topographic Quadrangles j W �� E 0 2,000 4,000 � ° :_, o FeetS a UIC Permit Modification Cintas-Former RUS Facility ACOM 3775 Industrial Drive,Winston-Salem, NC Site Location Map Project No.:60602461 Date: 05-20-19 Figure: 1 x o, • Cinte N , /. . MW07s I - �� LL MWO74 I 4141 //w _ . ��. MWO7d FB-0 c� 1 . I I ®MP-2 MW02d lc sar FB-08 S MW02 ' ' • ♦ I 4 I4FB-02 x • �\\• ON' a FB-10 U • �, • I FB-011 r,,. a MP-1 ' I co ' `, ' Champion Industries, Inc. ,.,f;�i �- • FB-03 A MW12s ♦ / MWO3 ifi MW12s(R).�AMW12 i A ,\ f 1 \,4 MW12d - - DPT-G, 101 FB-05 . . . . �4 ' Oe FB-11 , . —et eC I I4 PMW-1 _ ��I ,� ,t. DPT-GW102 i O\ Proposed Area of Injection t �/ w To SPW-12 DPT-GW10 ce .4 PMW 3fr Q iv, � ` C ZC7 j' ', •1� ♦ DPT-GW105 i / 16 PMW-2 Q z b _ ;. f ` • '.f TPMW-4 PS-2 ®PS-3A / w Z ` rT S 3`"' p6_4ce 7 SW-04 • .. i♦:+ - Oe DPT-GW101J-1, 5 ®Ps-� > 2 0 .4I ,� PS-60�S-5A O Z F , SWG-1 --- i ,,•♦'\.. /,. DPT-GW107 INJ-2 INJ 3 w O z \__ 0, ; Ai, ♦♦♦ Oe /MW10d TP W-5 1- p • • M 10 CO O �` F°rk i DPT-GW110 `. / MW19 W Legend S DPT-GW111© e 0, ♦♦♦ / / z a — - - — Cintas Property Boundary • \� • �� ' o O ♦♦ DPT-GW106 SWC��. F Adjacent Property Boundary \, :.NIW11 DPT-GW109 ••�• �, i OSWG 9 t — Stream (Surveyed) N SWG-2 SWG-4 ♦♦ ♦ y a - Proposed Injection Monitoring Area ` n �• e ��, SWG-7 O S -02 0 •) ZVI-1 ZVI Injection Location(Phase II ) \``\ ` / �\ ,�• DPT-GW108,_ PW-06 SPW�5 SWG-3° SP_W-fl� �� \ SWG-10 • �, .) ORC-1 ORC Injection Location(Phase II ) _/_ �WG_5 • SPW-07 w .) PS-1 Saprolite PiumestopTM Injection — — ` -♦� ® 0 RI-GW19 m Location(Phase III ) •♦ • // ' wPWR PlumestopTM Injection Wet \♦♦♦ ,� SWGJ JINJ1 (Phase III) ` � ♦ � � ♦. / o o FB-05 Fracture Boring Injection Points(Phase IV) ' / RI-GW20 0 • U o)\ ® SPW-04 • z N MW-01 Abandoned Monitoring Wet ` SW-03 ' o 1•� N t3 MW-02 Type II Groundwater Monitoring Wet \ I \ N &.z MW-02d Type III Groundwater Monitoring Wet I• \ (n o a�I.25 O TPMW-4 Temporary Performance Monitoring Well Notes \ = o CD °M ART-1 Existing Wets,pH Adjustment and 1. Aerial photograph obtained from C co c 0 u) ITS J0 Carbon Substrate Injection Locations(Phase I ) NC dated 2010. 0 OneMap, DPT-GW12 0 \ �, oz ART-2 Existing Observation Wets 2. Cintas property boundary is from Pyatt Boundary MW15 ! \ v > ; • FF ® MP-1 Groundwater Monitoring Point (Piezometer) Survey (2000). The remaining surveyed features �� MW15d = ce L o,, (inclusive of sampling locations, wets, streams, etc.) - 'a I- 0 6 RI-GW20 Groundwater DPT Sampling Location(2011,2012) O 41)E mo are based on Regional Land Surveyors, Inc. surveys MW15s \ m ii co a __ DPT-GW12 Groundwater DPT Sampling Location(2018) dated March 2012, June 2012, and July 2012. 7-" 0 SW-05 Surface Water Sample Location 3. Adjacent property boundaries estimated from Forsyth (t)60 0 120 E w = o L , -0 Z �a ;• SWG-1 Surface Water Sample Location(2018) County GIS data (not surveyed). \ McGee Industrial Park —=- a Sti 03 ,., rn£ 0 SPW-1 3 Sediment Pore Water Sample Location 4- 2018 Surface Water Sample locations are based on field 1"-120' 0_ c N. o Jg measurements(not surveyed). = V c~ o_ I Legend I 0 - Cintas Property Boundary PMW-2 Performance Monitoring Well Location I I — / — — Adjacent Property Boundary 0 TPMW-4 Temporary Performance Monitoring Well �" tiii' • —XX— Fence 5 PMW-2-Groundwater elevation at I I a O O MWO6 r LL 875.38 monitoring well(ft.) —— —— —— —— —— 1 s NM rTITI Stream(Surveyed) 871 ��� Groundwater equipotential I MWO5 S La 5 MW-03 Type II Groundwater Monitoring Well contour(ft.,dashed where inferred) a — Estimated groundwater flow direction I I 894.77 0 SPW-13 Sediment Pore Water Sample Location / 0 ®MP-2 Groundwater Monitoring Point(Piezometer) NM Not Measured I L QMW-12d Type III Groundwater Monitoring Well s 1 ❑� MW04d tkMW04 872.82 0 • ®ART-1 Existing Wells, pH Adjustment and 1880.20 Carbon Substrate Injection Locations(Phase I) I I Cintas Corporation L Notes: I 1.Groundwater elevations measured on 03/19/2018 for all site 25 0 50 I wells except SPW wells. I 2 ��� MW07s 3 2.Wells MW-04d and MW-07d not used to develop contours. 1"=50' 875.04 I 45 I I \ i� [1 MW07d I I \ c /�� 874.32 88i 09 IL gc �' I I ::NM 2 Q MW02 Q 8z I MW02d 879.73 E oa I ART 1 ART-2 879.26 / 879.34 879.88 i M 0 z ®M 1 w LL MW12s MW12 / NM 0 :Li oI NM865.46 / Nv MW12d .`MW03 l i x _ 878.08 865.30 ART-3-—— —— — "— —`—11 0 Q c MW12s(R) `878.37 879 vre z / / PMW-1 878 — Q �_ _�� PMW 31 ` 877.92 Q c: 873.71,• Z a SPW-12 / Z LL \ � / / a , PMW2 0 F \ Champion I lustries, Inc. 874.86 /TPMW-4 873.10 /� / L.L. % / \ MW10d 8's N'N -872.21 �� TPMW-5O f LL \• �6'" <0 / MW10s a ` O \ 4�L \ 8721 872.79 S. \/ /� SMW11 I \ / // ?4 .— LT. 868.59 0 0- Co- may S ` Sty l d' c',O/I \ O I E N 0 o 2 F �A�� ream _ '�� SPW-06 \ SPW-0 a� az �// _—— �; 0 I \ NM, �, oL Ramp \ _'�6— \.. c 0 as C \ ,/ 1 \ ��� _ o \ , 1 Champion Industries, Inc. V ;co n `\ \ / \ \ 5 o LL \_. i \ \ ( SPW-04(B) �� \ \ice I �NM .L N o wa \ \ . Cfl w = .� .. .. u O _.0 • \ 1 \ \ ,_ r -0 Z I \ d rn c U .a ,i \ tv ;11I \ U c o JLL ` 5 U M 1 c x Champion Industries Inc. x 41 , . • CV ' /I \` O E CV o 0 rvIn (7) / \, . /''` • '' '\ ' Q / WO ._ /� ♦ / ♦♦/ a) • / o \ ♦ ♦ N / a . , ♦ / ♦ . • / Q \ /' ♦♦•�// cis ♦♦ . N N \. / cIs ♦♦ . Pt. N \ • , oc a) / Champion Industries Inc. Pk< / 0 N N 0 • / p u_ Champion Industries Inc. Parking Lot N L a) Parking Lot < ♦/ a) ® N Is, ZV _29 Pk< X NA'N ,7s .05 o �< \ /7;-AS `o ZVI-16 ZVI-30 ��s oO �<a) E a) ZVI-17 ZVI-31 0 c . ZVI-1 0 0 �< s_ `�a) CD, 118 ZVI-32 < Q./o ZVI-2 0� / / 16.02 \ZVI-19 ZVI-33 < gisA, ZVI-3 0 z PS- - o �NN a o . ZVI 20 ZVI- < ��s <<// ZVI-4ki-X N 0 34 N aM 0PS 2 ZVI-21 ZVI- ��s GAS — O W11 ZVI-5 0 35N _ ORC-1 o A C,P' 0 o , PS-3 ZVI-22 _ N / w ZVI-6 o ZVI 36 GP5 , )RC-2 PS-4 0 - A z ZVI-23 oZVI-37N �� ORC-3 ZVI-7 0 N.. A, ORC-4 N oPS-5 ZVI-24 oZVI-38 GP ZVI-8o V O RC-5 PS-6 ® - GP5 0 o ZVI-25 oZVI 39 o .ORC-6 PS- - o ZVI-9 GP5 / 0 o ZVI-26 o ZVI-40 oORC-7 ZVI-10 � PS-8 0 00RC-8 0 o ZVI-27 0 ZVI-11 0O RC-9 PS- • o _ ® ZVI 28 a U ORC-10 ZVI-12 2 SPW-09 0 a___, 0 / 1- PS-1 I- NORCI2 SPW-06 z , ZVI-13 Legend PS-1 / �w � ZVI- z 6 0)zi Proposed AquaZVI Injection Location ORC-13 0 4 / 0 CO o PS-12 o o a� .�� Proposed PlumeStop Injection Location \ ZVI_ — • N 0_LL Proposed ORC Injection Location \ O RC- ' O RC-15 PS-13 • co-� 0 0 co 0 = 0 J PS-14 , •� � o � �: SW-06 Surface Water Sample Location \ 7� OORC-16 , C Ca .0 o o� Approximate Tree Line Location O LI- ~ �L 0 PS-15 0 nco - 2 N o -wLwLwLwL- Approximate Water Line Location \ N o0 OR - o SPW-07 M w D - -.As- - Approximate Gas Line Location W .� (0 Cl)o \ OR OoRC-19 l- L _ �, 0 F—F—F- Approximate Fiber Optic line Location O o Q z * P S-1 6 VERIFY PRINTED 2 c •� Cfl -(7), . : a o — — Leak Fork Creek / SCALE +� O (n Q BAR IS ONE INCH ON U. = 0 •U ORC-20 ORIGINAL DRAWING �U 0 1„ 1 Z IF NOT ONE INCH ON a c V 5 0 10lEe THIS SHEET ADJUST �... LO ww co c �.� \ SCALE ACCORDINGLY 0 = N- .O ow as No m ma ift, X Legend Abbreviations ♦ • J=Estimated value ♦ ♦ ♦ lin N _ Cintas Property Boundary ♦ • O N ug/L=Micrograms per liter ♦♦ �, CD - - Adjacent Property Boundary PWR=Partially weathered rock ♦♦ , L - -XX- Fence DPT=Direct push technology •'♦ •, z - - - Stream (Surveyed) ♦ Q Stream (Unsurveyed) •♦ , ' ' PCE Iso-contour(Dashed Where Inferred) 0, /\ Piedmont Triad ,� ■ c \ Investment Properties LL S MW-03 Type II Groundwater Monitoring Well - ♦ \ \ ` Q SPW-13 Sediment Pore Water Sample Location ♦ \ \ ,% CD ®MP-2 Groundwater Monitoring Point(Piezometer) \ % 0 ®MW-12d Type III Groundwater Monitoring Well \ ii.c.\ Res aft Q B ART-1 Existing Wells,pH Adjustment and , `� ♦♦ois 1.1 on MN aft am, • Q Carbon Substrate Injection Locations(Phase I) `•• RI-GW07 MW08d ♦ •♦ ``♦ Q ART-2 Existing Observation Wells •` MW 8s 4 •<1 •0 8 , RI-GW08 •, S PMW-2 Performance Monitoring Well Location •\ �• •<1 .0 MW000 ,� �• OTPMW-4 Temporary Performance Monitoring Well / 111 • • ,� • `` t SW-06 Surface Water Sample Location • \ ��� _ __� x • a) elDPT GW109 DPT Groundwater Samples \ RI-GWO' 11/11 x ``• t 4 FB-04 Fracture Boring Injection Points \ • am ss Proposed Target Injection Area \ - `� _ _ t ,♦♦ ` CO Notes: I S U 1. Surface water samples not used for contours. RI-GW 1 0 L 2. Groundwater and surface water samplescollected in March I O O D° 2018. DPT groundwater samples collected in April 2018. L - - 3. Results are in micrograms per liter(ug/L). O O MWO6S r HSVE I • G RI-GW 1 4. PMW-3,TPMW-4,TPMW-5, INJ-1, INJ-2,and INJ-3 were N installed January 25-27,2015 r I n 3.0 MW05 o DPT-GWO I i 'J- 3.0 1 _,, . -i/f,N I i RI-GW11 1 iii NO"), �/ 7 1 RI-GW13 I L To •♦ ��N / RI-GW03•see �- �- - a eo / Q ♦ Former McGee MWO4� M9 04d RI-GW16 Cl) "S N Industrial Park 12.2 Z 0 N�♦ / 0 1 : Cintas Corporation RI-GW14 O f \•♦♦ I a ti SW-05/4) _ I I Ce a 0 SPW9.0 O3 \ ,• �p MW07 100 �I o • I MW07s 23.4 J Z a S. II MW07d 7.9 FB-09 1 W Q 1 • / 4 MW02 1 x 2 M®2 61.9 / eO 1 Z O I ` FB-08 MVVO2d � RI-GW151 O (� li x 1 O 1 ART-1, �FB-02 I MW02d l V II <1 .0 0 61 .9 w FB-101 x O a I �1 FB-01 FB-04 1 4 4��.5 J 1 r e MP-1 / W > SW-08/Lu � FB-03� NS B-07 x 0 / I V 2 SPW-16 MW12s FB-0 ,.MW03 <20 , i i x �RI-GW09 a �` MW12 42 '-` ART-3 <2.0 I I O I MW12s(R) MW12d DPT-GW101 II I 0FB-05 -- I Y XY= _ j x=� _ Y YY ctCe I Lu I % <1 .0 < 1 .0 OB 332 (26') FB-11 PMW-1 I a / ,� DPT-GW10 B<1 .0 �� ♦ 640 (27') 015 w D I • SPW-12 DPT-GW1 �3 • I I \ 0 354 27' 80\ \ \ O�SPMW-3 C.6 I �. DPT-G 105w 927 �33') �� 1,520 �) S J %� 13.9 1') PMW-2 0 MW17 a `� ♦v Champion Industries, Inc. TPMW-4 97•9 Ce I MW18 <1 .0 a <1 .0 L1 240 S / S Q j ♦ SW-04 ::: �I �, 14.9 PT-G DPT-GW104e o •,_=__ 18.3 J (25 ) 86.8 15' TPMW-5 N ♦♦♦ �, 35 ) ( ) MW10d .370 2 DPT-GW111 - J I ♦ DPT-GW110 DPT-GW106 MW10 / Q I • �� 59.3 (27') I 690 (25') �0 529 (35')'16.7 2 ) MW10s I .• 9)'� Z MW11 O 11 11 ♦♦ 9 DPT-GW 109 c j II / \ high ♦ 2,800 (25') z II "vdy •♦♦ �0�. 1 ,550 (39') SW-02 II S2 ♦♦ / 4.9 11 ch II II II 1 �A'-i.A. ♦♦, �* SPW-09 DPT-®108 S64W-05 / zI' dike ♦♦ •`K NS 2,570 (25�) SPW-O6 259 �v I ♦♦ `` 5,570 (33 ) / U N Y ti oO I •♦ `` - ` '� SPW-07 RI-GW19 Champion Induslies, Inc. zN cO :% SW-07/ • � .. ... ...% 1 �O� o� SPW-15 •�♦ ` 14.5� , '� \ • SPW-04B NS I N� a w ♦..`` _ _ __ RI-GW20 ADD SPW-04 <1.0 �w • • • • • � � � � � = O J2 . . . . . . . . . .♦ v cn O NU ♦♦♦ , C CU .i. >C Co ma MW15 DPT-GW129 4, \ 1 0o U <1 .0 cc) Ow MW15sSS S MW15d % i .V = j CO CO Um <1 .0 <1 .0 % 1 'i w co Q \ % ` 1 O � - O av VERIFY PRINTED • 2 E ._ co 2(1 �S�W-01 / ♦1 LO U BAR IS ONELINCH ON ,<1 • AZA MW09 S '- O ORIGINAL DRAWING S <1 .0 z SD U O -�- • • I 20 0 40 1 �--+ a co a) 6 IF NOT ONE INCH ON SP;02 0(t) THIS SHEET ADJUST 1"=40' a .O o c SCALE •ACCORDINGLY • ` I� V - ♦` I• •� nollt♦ x / ICD I N I— , o RI-GW18e_-i/ I I O \ U / 1 1a / e�, sve \ 114 LL CO \ �aQp \\\ \ I 1 I J \‘ .,\ I \ I \ I OD x I r� ��1` \ 1 0 —ri \ I I I �g _ _ co 1 \ \ MW08s MW08d 0 I v Lo \\ p 1 \ 1 m ............0___ � S MWO8 fl wQ \ir nLi yU B' / I \ \ I •7 0� N I x��x�sx��sx�ax — — — — — g I MW14•; W14d o 1 \ I °M II RI(1)-BG01 A / my I \ 1 r RI-GW12 / c� MW14i — — — / MW05 a)i2 I ` ie I R-GW11 MW01d �� �� \ �' I MW04d RI(1)-SB21 / 0 I 1 / Z jai I \ I / I I MWO4 �W N i O. D ♦ I L Cintas / Q a, \ I �. SPW-13 Corporation � � � r1 / z Fe-og / 0 o MWO2• / I I / B 0' FB-02 .J \cn — _ ` I 4 FB-11 MWO2d V /J A•T-1 r L.u — _ / 1 FL-011 , _pRT-2 / 0 o I aMW12s MW03 03� FB-04 0 MW12 F:. 1.y' FB-07 \ OZ I MW12s(R) _ DPT-GW10 / F' 'i , �xtmx xr�xr»x�m. / 2 N/ghw I \\\ MW12d eDPT-GG 102 /: B-11 — .... U LLi ay 5 II I DPT-GW103 0 / / / fW 2 ry e �i Ramp �\\ DPeGW105 MW17 �I A DPT-GV/104 /Lu 0 0 a ��\\ DPT-GW107 re MW10d1%, 7 V z �jgh� \<<o�� D•' GW1 o DPT-GW110 A MW10 '7MW10s / a6 ays2 \ ,OD MW11 DP GW109 eDPT-G 06 j. / 'z FI/f �••sf/gd/h / —\ DPT-G 108 �J\SPW-OS / cn z Legend \\ ,\\ ,,,,/, RI-GW19 / ,G RI-GW20 \ / Cintas Property Boundary \ 1 �i Adjacent Property Boundary \ 1 \ / Hz —x—X— Fence \ MW15 i 0'%) \ 6 — — — Stream (Surveyed) Mw15s. .' ']MW15d / CV 0 6 Stream (Unsurveyed) I \\ NO o 00 S MW03 Type II Groundwater Monitoring Well A' ', \ MWO9.• / Z Cr) No Q MW12d Type III Groundwater Monitoring Well I / o a E9 ART Groundwater Remediation Well I \ /O m ai ®ART-3 \ To s0 (Inactive) a¢ \ I \ U) CO Jo ®RI-GW20 Groundwater DPT Sampling Location \ I \ ±' Nw ®SPW-05 Pore Water Sample Location / 5 o \ c m0 ®DPT-GW109 DPT Groundwater Samples \\ I •\ / O li " o� o5 a FB-04 Fracture Boring Injection Points \ I \ IP cts - dj co W6 A A' Cross Section Transect A-A' j \ // Ce •L co oWB— — — —B' Cross Section Transect B-B' \ / p w p 1 LL 0 y9h tij9h m E . co 60 0 120Et. S2( S2( \ \ /bk \ \ / i -a Z �C3 SO`f �O� \ \ RI-GW21 -�MW16d CO U hbo hbo \ \ MW16 / I CD a R 1"=120' /'�a� ��a� B t 0 c N- o JLL • •• 940— A n� —940 O i z (SOUTHWEST) PAVED PARKING LOT (NORTHEAST) a 930— PAVED PARKING LOT 930 '� LL CINTAS BUILDING N 0 o m a 920— N c-9 o o 4- —920 cC < g 2 910— ' 910 L ct 1 U M M O ct CD O o m < � 900— I- o o LO op 2 m LL —900 m Ln �, -0 < m LL - - SAPROLITE (894.77) '0 LEAKS ',70 �' FORK ■ 03 890— o 0 co wE C —890 cl Y¢ 2 2 2 vE0 O� : PWR (883.94) T =o o PP _ _ 1(879.88) (879.73� — ,W 880— (878.37) (879.34) IV _ ' —880 E co 872.63 — (869.92) (872.21) ( V (878.08)f _ Ir = ' 61.9_ owi 870 —=- - r7, 164 - _ <20 _ I 870 ae <1 = P R = 0 = SAPROLITE I t F IAT' — I Q it 860— I I -860 Q I / I W 0 SAPROLITE <2.0 / (879.26) W I 0 a_ 850 <1 = / / 61.9 ' —850 W F (869.55) _ (873.22) ' co 1970 _ _ �� BRco i W 0 ' 840— 1 —840 0 s I \ PWR U �' PWR 0 830— 0 7 —830 zo I 7 I W II I 820 —820 o En z BR \ / 810— / —810 N ‘ (872.21) 334 f D800— _ Q� �� 0. ONO 'S. woo800 a0 ?� i MASSIVE BEDROCK o zsa 790 —/I(FEW WATER-BEARING 790 C.) 0) °'a VERTICAL SCALE: 1"=20' `4..., % ► FRACTURES) Z O -b� HORIZONTAL SCALE: 1"=80' a. _ BR E N zu, VERTICAL EXAGGERATION: 4x 0.7 o °U 780 780 (/) ca yQ 0 -Io Legend Abbreviations = o W — Asphalt/Concrete Paving DPT Direct Push Technology C c •w Q 0o Groundwater Monitoring Well 1afr; -w-- FB/RI Soil Boring PCE Concentration (ug/L) in ft. msl Feet mean sea level O li tiPCE Perchloroethene (Tetrachloroethene) O fA 56.7 Groundwater Well Screen SAPROLITE Saprolite (includes residuum V n a) co Groundwater Potentiometric Elevation and local fill material) Note ;_ w ._ co w W t873 88� (ft. msl) March 19,2018 PCE Isoconcentration in L 0 or) COW 70 — — — Micrograms per Liter (ug/L) 1.Groundwater samples collected from monitoring wells O d o u_o in March 2018.Groundwater samples collected from E . (Dashed Where Inferred) PWR Partial) Weathered Rock PWR �a f Fracture Boring(FB) 7 Groundwater Equipotential Surface y ( ) DPT points in April 2018. +, O <6 - (ft. msl) (Dashed Where Inferred) p 0 2.Depth of PWR and bedrock between wells ART-2 E L- a f Fracture Intervals — Line of Lithologic Contact and ART-3 is estimated from directpush boringL Z �d Historic PCE Groundwater Sample Dashed Where Inferred O rn E v Results (Dates Vary) ( ) BR Bedrock (Biotite Gneiss and Schist) DPT-GW14 (ENSR, 2008) that encountered d 2 Lo N ci m probe refusal at depth of 59 ft. bls. 0 O •o L co m O 2a 114 iz U) 2 a a a B' B (NORTHWEST) (SOUTHEAST) -o Y U 940- -940 N 0 U 930- -930 a ce 0 920- -920 pin gm'N N i Qm z 910- -910 O iri co co (° iE W =� 900- - o 0 0 -900 Vm LARGE BEDROCK E0 OUTCROP IN STREAM CI N 1- 0 - 0 0 i N 2 °U ASSUMED CONTINUOUS a a PAVED DRIVE -890 co 2wl -1- v v LEAK FORK (879.25) Tii PAVED PARKING LOT PAVED PARKING LOT _ �880 WO 2 2 2 880 M e—STORMWATER PIPE a0 — PAVED PATTERSON (872.79) in DRIVE AVENUE — _ _ — y -870 9 870- (865.88) — — — — — — — SAPROLITE m N SAPROLITE — — (859.57) SAPROLITE — — — -- SAPROLITE Z w 860 t —• - — — — — — — — d (865.88) -860 0 I 0 (874.56) PWR W 850- PINK 850 F 41 (868.59) , 5 _(872.63) VW. a 840- ALTERNATING ZONES OF _ P/ I E -840 UI PWR/BR (859.59) PWR AND FRACTURED - (877.37) D ROCK FROM 830' - 845' (865.46)- PWR U ml 830 ms1 -830 w iY 11 0 z 820 MASSIVE BEDROCK II -820 w BR Z(NO FRACTURESING I I ' -810 810- (872.21) II Zw 334 o - II 800- (859.58) (865.30 BOREHOLE ABANDONED II -800 <7 BR BR WITH GROUT AND BENTONITE- 790- FROM 60-100 FT. BLS •Uoo -790 N 0 NI H 780 780 z O N U O 1- VERTICAL SCALE: 1"=30' a W HORIZONTAL SCALE:1"=120' m a VERTICAL EXAGGERATION: 4x z a O co N A'r a) 0) oU -o Legend Abbreviations a 0 o Historic PCE Groundwater Sample DPT Direct Push Technology C �? F * Results (Dates Vary) Asphalt/Concrete Paving ft. msl Feet mean sea level G 4m Groundwater Monitoring Well f DPT Soil Boring t> o o PCE Perchloroethene (Tetrachloroethene) C ca o q� PCE Concentration (ug/L) in 0 L.I.o? Well Screen 56.7 Groundwater SAPROLITE Saprolite (includes residuum '++ In 6a73$$ Groundwater Potentiometric Elevation and local fill material) Noterein = Qj co W i ( ) (ft. msl) March 19,2018 PCE Isoconcentration in 1.Groundwater samples collected from monitoring wells Ce . (.0 o' Cr 70 — - - Micrograms per Liter (ug/L) in March 2018.Groundwater samples collected from L -7 c0 wo V Groundwater Equipotential Surface p PartiallyWeathered Rock PWR O _ (Dashed Where Inferred) ( ) DPT points in April 2018. ca o g- - (ft. msl) (Dashed Where Inferred) (9 air) 2.Depth of PWR and bedrock between wells ART-2 �, mo General Direction of Vertical and ART-3 is estimated from direct push boring li o j Hydraulic Flow Gradients at - - Line of Lithologic Contact DPT-GW14 (ENSR, 2008) that encountered , -0 Z mE Multi-Depth Well Clusters (Dashed Where Inferred) BR Bedrock (Biotite Gneiss and Schist) probe refusal at depth of 59 ft. bls. U U ym Ln N J U c N- o MUci0 Application for UIC Permit W 10400468 60602461 Modification—Attachments Appendix A Material Safety Data Sheet Documents Prepared for: Cintas Corporation AECOM REGENESIS SAFETY DATA SHEET Technology-Based Solutions for the Environment 1. Identification Product identifier PlumeSTOP® Other means of identification None. Recommended use Soil and Groundwater Remediation. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name Regenesis Address 1011 Calle Sombra San Clemente,CA 92673 Telephone 949-366-8000 E-mail CustomerService@regenesis.com Emergency phone number CHEMTREC°at 1-800-424-9300(International) 2. Hazard(s) identification Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Not classified. Label elements Hazard symbol None. Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC) 3. Composition/information on ingredients Mixtures Chemical name CAS number Water 7732-18-5 >75 Colloidal activated carbon <_2.5 7440-44-0 <25 Pm Proprietary additives <2 Composition comments All concentrations are in percent by weight unless otherwise indicated. 4. First-aid measures Inhalation Move to fresh air.Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water.Get medical attention if irritation develops and persists. Eye contact Rinse with water.Get medical attention if irritation develops and persists. Ingestion Rinse mouth.Get medical attention if symptoms occur. Most important Direct contact with eyes may cause temporary irritation. symptoms/effects, acute and delayed PlumeSTOP® SDS US 923801 Version#:01 Revision date:- Issue date:26-February-2015 1 /6 Indication of immediate Treat symptomatically. medical attention and special treatment needed General information If you feel unwell, seek medical advice(show the label where possible). Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Carbon dioxide, alcohol-resistant foam, dry chemical,water spray, or water fog. Unsuitable extinguishing None known. media Specific hazards arising from During fire, gases hazardous to health may be formed. Combustion products may include: carbon the chemical monoxide, carbon dioxide, sodium oxides, metal oxides. Special protective equipment Use protective equipment appropriate for surrounding materials. and precautions for firefighters Fire fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Use water spray to keep fire-exposed containers cool. General fire hazards This material will not burn until the water has evaporated. Residue can burn. When dry may form combustible dust concentrations in air. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away.Avoid contact with spilled material. For personal protection, protective equipment and see section 8 of the SDS. emergency procedures Methods and materials for This product is miscible in water. containment and cleaning up Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading.Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery,flush area with water. Small Spills:Wipe up with absorbent material (e.g. cloth,fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains,water courses or onto the ground. 7. Handling and storage Precautions for safe handling Avoid contact with skin and eyes.Avoid prolonged exposure. Observe good industrial hygiene practices.Wash thoroughly after handling.Wear appropriate personal protective equipment(See Section 8). Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials(see Section 10 including any incompatibilities of the SDS). Protect from freezing. 8. Exposure controls/personal protection Occupational exposure limits US.OSHA Table Z-3(29 CFR 1910.1000) Components Type Value Form Colloidal activated carbon TWA 5 mg/m3 Respirable fraction. <_2.5 pm (CAS 7440-44-0) 15 mg/m3 Total dust. US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Colloidal activated carbon TWA 2.5 mg/m3 Respirable. <_2.5 pm (CAS 7440-44-0) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour)should be used.Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. PlumeSTOP° SDS US 923801 Version#:01 Revision date:- Issue date:26-February-2015 2/6 Individual protection measures,such as personal protective equipment Eye/face protection Wear approved chemical safety goggles. Skin protection Hand protection Rubber, neoprene or PVC gloves are recommended.Wash hands after handling. Other Avoid contact with the skin.Wear suitable protective clothing. Respiratory protection Not normally needed. In case of insufficient ventilation,wear suitable respiratory equipment. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable)or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aqueous suspension. Color Black. Odor Odorless. Odor threshold Not available. pH 8- 10 Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Flash point Not flammable. Evaporation rate Not available. Flammability(solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit-lower Not available. (%) Flammability limit-upper Not available. (%) Explosive limit-lower(%) Not available. Explosive limit-upper(%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 1 - 1.2 Solubility(ies) Solubility(water) Miscible Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Contact with incompatible materials. Keep from freezing. Incompatible materials Strong oxidizing agents.Water reactive materials. PlumeSTOP° SDS US 923801 Version#:01 Revision date:- Issue date:26-February-2015 3/6 Hazardous decomposition Combustion may produce: carbon oxides. products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact Prolonged or repeated skin contact may result in minor irritation. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Not expected to be acutely toxic. Components Species Test Results Colloidal activated carbon <_2.5 pm (CAS 7440-44-0) Acute Inhalation LC50 Rat >8500 mg/m3, air Oral LD50 Rat >2000 mg/kg, (Female) Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1%are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC,ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity- Not classified. single exposure Specific target organ toxicity- Not classified. repeated exposure Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil Expected to be temporarily highly mobile in soil. Other adverse effects None known. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user,the producer and the waste disposal company. PlumeSTOP° SDS US 923801 Version#:01 Revision date:- Issue date:26-February-2015 4/6 Waste from residues/unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues.This material and its container must be disposed of in a safe manner(see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue,follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not established. Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations All components are listed on or exempt from the U.S. EPA TSCA Inventory List. This product is not known to be a"Hazardous Chemical'as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List(40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard-No Delayed Hazard- No Fire Hazard- No Pressure Hazard-No Reactivity Hazard- No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313(TRI reporting) Not regulated. Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs) List Not regulated. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations US. Massachusetts RTK-Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Colloidal activated carbon 52.5 pm (CAS 7440-44-0) US. Pennsylvania Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. PlumeSTOP° SDS US 923801 Version#:01 Revision date:- Issue date:26-February-2015 5/6 US.California Proposition 65 Not Listed. International Inventories Country(s)or region Inventory name On inventory(yes/no)* Australia Australian Inventory of Chemical Substances(AICS) Yes Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical No Substances(EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances(ENCS) No Korea Existing Chemicals List(ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States&Puerto Rico Toxic Substances Control Act(TSCA) Inventory Yes *A"Yes"indicates this product complies with the inventory requirements administered by the governing country(s). A"No"indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 26-February-2015 Revision date - Version# 01 Further information HMIS®is a registered trade and service mark of the American Coatings Association (ACA). HMIS®ratings Health: 0 Flammability: 0 Physical hazard: 0 NFPA ratings 0 0 .0 Disclaimer Regenesis cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user's responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use.The information in the sheet was written based on the best knowledge and experience currently available. PlumeSTOP° SDS US 923801 Version#:01 Revision date:- Issue date:26-February-2015 6/6 REGENESIS SAFETY DATA SHEET Technology-Based Solutions for the Environment 1. Identification Product identifier PlumeSTOP®Nutrients Other means of identification None. Recommended use Soil and Groundwater Remediation. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name Regenesis Address 1011 Calle Sombra San Clemente, CA 92673 Telephone 949-366-8000 E-mail CustomerService@regenesis.com Emergency phone number CHEMTREC®at 1-800-424-9300(International) 2. Hazard(s) identification Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Not classified. Label elements Hazard symbol None. Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s)not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR 1910.1200. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Do not rub eyes. Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if symptoms occur. Most important Dusts may irritate the respiratory tract, skin and eyes. symptoms/effects, acute and delayed Indication of immediate Treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. PlumeSTOP®Nutrients SDS US 931709 Version#:01 Revision date:- Issue date:07-January-2016 1 /6 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide(CO2).Apply extinguishing media carefully to avoid creating airborne dust. Unsuitable extinguishing None known. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Use water spray to cool unopened containers.Avoid dust formation. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during protective equipment and clean-up. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at emergency procedures levels exceeding the exposure limits. For personal protection, see section 8 of the SDS. Methods and materials for Avoid the generation of dusts during clean-up. Collect dust using a vacuum cleaner equipped with containment and cleaning up HEPA filter. This product is miscible in water. Stop the flow of material, if this is without risk. Large Spills:Wet down with water and dike for later disposal. Shovel the material into waste container. Following product recovery,flush area with water. Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains,water courses or onto the ground. 7. Handling and storage Precautions for safe handling Minimize dust generation and accumulation. Provide appropriate exhaust ventilation at places where dust is formed. Practice good housekeeping. Conditions for safe storage, Store in original tightly closed container. Store in a well-ventilated place. Store away from including any incompatibilities incompatible materials(see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) Components Type Value Form PlumeSTOP®Nutrients PEL 5 mg/m3 Respirable fraction. (as dust) 15 mg/m3 Total dust. US. OSHA Table Z-3(29 CFR 1910.1000) Components Type Value Form PlumeSTOP®Nutrients TWA 5 mg/m3 Respirable fraction. (as dust) 15 mg/m3 Total dust. 50 mppcf Total dust. 15 mppcf Respirable fraction. US.ACGIH Threshold Limit Values Components Type Value Form PlumeSTOP®Nutrients TWA 3 mg/m3 Respirable particles. (as dust) 10 mg/m3 Inhalable particles. Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Ensure adequate ventilation, especially in confined areas. Local exhaust is suggested for use, controls where possible, in enclosed or confined spaces. PlumeSTOP®Nutrients SDS US 931709 Version#:01 Revision date:- Issue date:07-January-2016 2/6 Individual protection measures,such as personal protective equipment Eye/face protection Wear safety glasses with side shields(or goggles). Unvented,tight fitting goggles should be worn in dusty areas. Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Skin protection Other Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation, use MSHA/NIOSH approved dust respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Solid. Form Powder. Color White. Odor Odorless. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Flash point Not available. Evaporation rate Not available. Flammability(solid, gas) The product is non-combustible. Upper/lower flammability or explosive limits Flammability limit-lower Not available. (%) Flammability limit-upper Not available. (%) Explosive limit-lower(%) Not available. Explosive limit-upper(%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility(water) Completely soluble. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. PlumeSTOP®Nutrients SDS US 931709 Version#:01 Revision date:- Issue date:07-January-2016 3/6 Possibility of hazardous No dangerous reaction known under conditions of normal use.Ammonia fumes may be released reactions upon heating. Conditions to avoid Contact with incompatible materials. Excessive heat. Incompatible materials Strong oxidizing agents. Bases. Hazardous decomposition Ammonia fumes may be released upon heating. products 11. Toxicological information Information on likely routes of exposure Inhalation Dust may irritate respiratory system. Skin contact Dust or powder may irritate the skin. Eye contact Dust may irritate the eyes. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Dusts may irritate the respiratory tract, skin and eyes. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Not expected to be acutely toxic. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1%are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC,ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. NTP Report on Carcinogens Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity- Not classified. single exposure Specific target organ toxicity- Not classified. repeated exposure Aspiration hazard Not an aspiration hazard. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Mobility in soil This product is completely water soluble and will disperse in soil. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential)are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. PlumeSTOP®Nutrients SDS US 931709 Version#:01 Revision date:- Issue date:07-January-2016 4/6 Waste from residues/unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues.This material and its container must be disposed of in a safe manner(see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue,follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is not known to be a"Hazardous Chemical"as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. CERCLA Hazardous Substance List(40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard-No Delayed Hazard- No Fire Hazard- No Pressure Hazard-No Reactivity Hazard- No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313(TRI reporting) Chemical name CAS number %by wt. Ammonium sulfate 7783-20-2 40-50 Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs) List Not regulated. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations US. Massachusetts RTK-Substance List Ammonium sulfate(CAS 7783-20-2) US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Pennsylvania Worker and Community Right-to-Know Law Ammonium sulfate(CAS 7783-20-2) US. Rhode Island RTK Not regulated. PlumeSTOP®Nutrients SDS US 931709 Version#:01 Revision date:- Issue date:07-January-2016 5/6 US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s)or region Inventory name On inventory(yes/no)* Australia Australian Inventory of Chemical Substances(AICS) No Canada Domestic Substances List(DSL) No Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical No Substances(EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances(ENCS) No Korea Existing Chemicals List(ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS) United States&Puerto Rico Toxic Substances Control Act(TSCA) Inventory No *A"Yes"indicates this product complies with the inventory requirements administered by the governing country(s). A"No"indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 07-January-2016 Revision date - Version# 01 HMIS®ratings Health: 1 Flammability: 0 Physical hazard: 0 NFPA ratings 0 1 .0 Disclaimer Regenesis cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user's responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use.The information in the sheet was written based on the best knowledge and experience currently available. PlumeSTOP®Nutrients SDS US 931709 Version#:01 Revision date:- Issue date:07-January-2016 6/6 REGENESIS SAFETY DATA SHEET Technology-Based Solutions for the Environment 1. Identification Product identifier AquaZVI Other means of identification None. Recommended use Remediation of contaminants in soil and groundwater. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name Regenesis Address 1011 Calle Sombra San Clemente, CA 92673 USA General information 949-366-8000 E-mail CustomerService@regenesis.com Emergency phone number For Hazardous Materials Incidents ONLY(spill, leak,fire, exposure or accident), call CHEMTREC 24/7 at: USA, Canada, Mexico 1-800-424-9300 International 1-703-527-3887 2. Hazard(s) identification Physical hazards Not classified. Health hazards Not classified. OSHA defined hazards Not classified. Label elements Hazard symbol None. Signal word None. Hazard statement The mixture does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information Contact with acids liberates very toxic gas. 3. Composition/information on ingredients Mixtures Chemical name CAS number Iron, powders 7439-89-6 30-50 Iron(ll)sulfide 1317-37-9 0-2 Composition comments All concentrations are in percent by weight unless otherwise indicated. Components not listed are either non-hazardous or are below reportable limits. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical attention if symptoms occur. AquaZVl SDS US 942500 Version#:02 Revision date: 12-April-2018 Issue date: 15-February-2018 1 /6 Most important Direct contact with eyes may cause temporary irritation. symptoms/effects, acute and delayed Indication of immediate Treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Use extinguishing agent suitable for type of surrounding fire. Unsuitable extinguishing None known. media Specific hazards arising from During fire, gases hazardous to health may be formed. Combustion products may include: carbon the chemical oxides, iron oxides, sulfur oxides. Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards This material will not burn until the water has evaporated. Residue can burn. When dry may form combustible dust concentrations in air. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. For personal protection, see section 8 of the SDS. protective equipment and emergency procedures Methods and materials for Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is containment and cleaning up possible.Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery,flush area with water. Small Spills:Wipe up with absorbent material (e.g. cloth,fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains,water courses or onto the ground. 7. Handling and storage Precautions for safe handling Observe good industrial hygiene practices. Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials(see Section 10 including any incompatibilities of the SDS). 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour)should be used.Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures,such as personal protective equipment Eye/face protection Wear safety glasses with side shields(or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Skin protection Other Wear suitable protective clothing. Respiratory protection In case of insufficient ventilation,wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. AquaZVl SDS US 942500 Version#:02 Revision date: 12-April-2018 Issue date: 15-February-2018 2/6 General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Viscous metallic suspension. Color Dark gray. Odor Slight. Odor threshold Not available. pH 7-8 (When mixed with water) 10(As shipped) Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Flash point Not available. Evaporation rate Not available. Flammability(solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit-lower Not available. (%) Flammability limit-upper Not available. (%) Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility(water) Not available. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 3000 cP(77°F(25°C)) Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Contact with acids will cause evolution of heat. Chemical stability Material is stable under normal conditions. Possibility of hazardous Contact with acids liberates very toxic gas. Can react with some acids with the evolution of reactions hydrogen. Conditions to avoid Contact with incompatible materials.Avoid drying out product. May generate combustible dust if material dries. Incompatible materials Strong oxidizing agents. Strong acids. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Inhalation Spray mist may irritate the respiratory system. For dry material: Dust may irritate respiratory system. Skin contact May cause mild skin irritation upon prolonged and excessive contact. AquaZVl SDS US 942500 Version#:02 Revision date: 12-April-2018 Issue date: 15-February-2018 3/6 Eye contact Direct contact with eyes may cause temporary irritation. Ingestion May cause discomfort if swallowed. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Not expected to be acutely toxic. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1%are mutagenic or genotoxic. Carcinogenicity Not classifiable as to carcinogenicity to humans. IARC Monographs.Overall Evaluation of Carcinogenicity Not listed. NTP Report on Carcinogens Not listed. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity- Not classified. single exposure Specific target organ toxicity- Not classified. repeated exposure Aspiration hazard Not an aspiration hazard. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability The majority of components in this product are inorganic compounds that are not biodegradable. No data is available for the organic components. Bioaccumulative potential No data available. Mobility in soil No data available. Other adverse effects None known. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues/unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues.This material and its container must be disposed of in a safe manner(see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue,follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. AquaZVl SDS US 942500 Version#:02 Revision date: 12-April-2018 Issue date: 15-February-2018 4/6 IMDG Not regulated as dangerous goods. Transport in bulk according to Not established. Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is not known to be a"Hazardous Chemical"as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List(40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not regulated. Superfund Amendments and Reauthorization Act of 1986(SARA) SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous No chemical SARA 313(TRI reporting) Not regulated. Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs) List Not regulated. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations US. Massachusetts RTK-Substance List Not regulated. US. New Jersey Worker and Community Right-to-Know Act Not listed. US. Pennsylvania Worker and Community Right-to-Know Law Not listed. US. Rhode Island RTK Not regulated. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs,tit.22,69502.3, subd. (a)) Iron, powders(CAS 7439-89-6) International Inventories Country(s)or region Inventory name On inventory(yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes AquaZVl SDS US 942500 Version#:02 Revision date: 12-April-2018 Issue date: 15-February-2018 5/6 Country(s)or region Inventory name On inventory(yes/no)* Europe European Inventory of Existing Commercial Chemical No Substances(EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances(ENCS) No Korea Existing Chemicals List(ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) Taiwan Taiwan Chemical Substance Inventory(TCSI) Yes United States&Puerto Rico Toxic Substances Control Act(TSCA) Inventory Yes *A"Yes"indicates this product complies with the inventory requirements administered by the governing country(s). A"No"indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 15-February-2018 Revision date 12-April-2018 Version# 02 HMIS®ratings Health: 1 Flammability: 1 Physical hazard: 0 NFPA ratings 1 1 O Disclaimer Regenesis cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user's responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use.The information in the sheet was written based on the best knowledge and experience currently available. AquaZVI SDS US 942500 Version#:02 Revision date: 12-April-2018 Issue date: 15-February-2018 6/6 Application for UIC Permit W 10400468 60602461 Modification—Attachments Appendix B REGENESIS — Injection Design Summaries Prepared for: Cintas Corporation AECOM 4 REGENESIS Project Information AquaZVl®Application Design Summary Cintas-Frmr RUS City,State PCE South Area Field App.Instructions PCE South Area Application Method Direct Push Prepared For: Spacing Within Rows(ft) 8 AECOM Spacing Between Rows(ft) 15 Input special application instructions here as needed. Target Treatment Zone(TTZ)Info Unit Value Application Points 40 Treatment Area ft2 4,800 Areal Extent(square ft) 4,800 Top Treat Depth ft 9.0 Top Application Depth(ft bgs) 9 Field Mixing Ratios Bot Treat Depth ft 32.0 Bottom Application Depth(ft bgs) 32 AquaZVl Concentrate per Pt(Ibs) Vertical Treatment Interval ft 23.0 AquaZVl to be Applied(Ibs) 18,000 450 Treatment Zone Volume ft3 110,400 AquaZVl to be Applied(gals) 1,348 Mix Water per Pt(gals) Treatment Zone Volume cy 4,089 AquaZVl Mix% 6% 558 Soil Type --- saprolite Volume Water(gals) 22,303 AquaZVI Mix Volume per Pt(gals) Porosity cm3/cm3 0.33 AquaZVl Mix Volume(gals) 23,651 591 Effective Porosity cm3/cm3 0.20 Treatment Zone Pore Volume gals 272,530 Treatment Zone Effective Pore Volume gals 165,170 Fraction Organic Carbon(foc) g/g 0.005 Soil Density g/cm3 1.67 Soil Density Ib/ft3 104 Soil Weight lbs 1.2E+07 Hydraulic Conductivity ft/day 1.0 Hydraulic Conductivity cm/sec 3.53E-04 Prepared by:DaP62196 Volume per vertical ft(gals) Hydraulic Gradient ft/ft 0.017 Date: 1/2/2019 26 GW Velocity ft/day 0.09 Technical Notes/Discussion 3 AquaZVl rows upgradient of 31 Plumestop/AquaZVI final downgradient GW Velocity ft/yr row Contaminant Demand and Dosing Unit Value Dissolved Phase Mass lbs 11 Sorbed Phase Contaminant Mass lbs 107 Assumptions/Qualifications In generating this preliminary estimate,Regenesis relied upon professional judgment and site specific information provided by others. Using this information as input,we performed calculations based upon known chemical and geologic relationships to TTZ Groundwater Mass Flux L/day 443 generate an estimate of the mass of product and subsurface placement required to affect remediation of the site. Contaminant Mass Flux through TTZ lb/yr 2 REGENESIS developed this Scope of Work in reliance upon the data and professional judgments provided by those whom completed Applied Dose into TTZ Pore Volume g/L 8 the earlier environmental site assessment(s). The fees and charges associated with the Scope of Work were generated through REGENESIS'proprietary formulas and thus may not conform to billing guidelines,constraints or other limits on fees. REGENESIS does Application Dosing not seek reimbursement directly from any government agency or any governmental reimbursement fund(the"Government"). In any circumstance where REGENESIS may serve as a supplier or subcontractor to an entity which seeks reimbursement from the AquaZVl to be Applied lbs 18,000 Government for all or part of the services performed or products provided by REGENESIS,it is the sole responsibility of the entity seeking reimbursement to ensure the Scope of Work and associated charges are in compliance with and acceptable to the Government prior to submission. When serving as a supplier or subcontractor to an entity which seeks reimbursement from the Government,REGENESIS does not knowingly present or cause to be presented any claim for payment to the Government. 4 REGENESIS Project Info PlumeStop®Application Design Summary Cintas-Frmr RUS PCE South Area(MW-11) Winston-Salem,NC PlumeStop Technical Notes/Discussion PCE South Area(MW-11) Barrier Length(ft) 130 Prepared For: Spacing Within Barrier(ft) 8 AECOM Number of Lines 1 Target Treatment Zone(TTZ)Info Unit Value Application Points 16 Barrier Length ft 130 Application Method Direct Push Top Treat Depth ft 10.0 Top Application Depth(ft bgs) 10 Bot Treat Depth ft 35.0 Bottom Application Depth(ft bgs) 35 Vertical Treatment Interval ft 25.0 PlumeStop to be Applied(Ibs) 9,600 PSTOP Injection Concentration(mg/L) Treatment Zone Volume ft3 26,000 PlumeStop to be Applied(gals) 1,136 4,551 Treatment Zone Volume cy 963 In Situ Chemical Reduction-AquaZVl Soil Type --- saprolite AquaZVl to be added to PlumeStop(Ibs) 0 Porosity cm3/cm3 0.33 AquaZVl to be added to PlumeStop(gals) 0 Effective Porosity cm3/cm3 0.20 PlumeStop+AauaZVl Volume Totals Treatment Zone Pore Volume gals 64,183 Mixing Water(gal) 15,912 Treatment Zone Effective Pore Volume gals 38,899 Total Application Volume(gals) 17,049 Treatment Zone Pore Volume liters 242958 Injection Volume per Point(gals) 1066 Treatment Zone Effective Pore Volume liters 147247 Anaerobic Bioremediation-HRC Fraction Organic Carbon(foc) g/g 0.005 HRC Application Points 16 Soil Density g/cm3 1.67 HRC to be Applied(Ibs) 0 Soil Density Ib/ft3 104 HRC per point(Ibs) 0 Soil Weight lbs 2.7E+06 Total Application Volume(gals) 0 Hydraulic Conductivity ft/day 1.0 Injection Volume per Point(gals) 0.0 Hydraulic Conductivity cm/sec 3.53E-04 Bioaugmentation-BDI Plus Hydraulic Gradient ft/ft 0.017 BDI Plus Application Points 16 GW Velocity ft/day 0.09 BDI Plus to be Applied(Liters) 0 GW Velocity ft/yr 31 BDI Plus per point(Liters) 0.0 Sources of Hydrogen Demand Unit Value Assumptions/Qualifications Dissolved Phase Contaminant Mass lbs 0 downgraient row Sorbed Phase Contaminant Mass lbs 0 Competing Electron Acceptor Mass lbs 48 In generating this preliminary estimate,Regenesis relied upon professional judgment and site specific information provided by others. Using this information as input,we performed calculations based upon known chemical and geologic relationships to generate an estimate of the Total Mass Contributing to H2 Demand lbs 48 mass of product and subsurface placement required to affect remediation of the site. Stoichiometric H2 Demand lbs 3 REGENESIS developed this Scope of Work in reliance upon the data and professional judgments provided by those whom completed the Stoichiometric HRC Demand lbs 140 earlier environmental site assessment(s). The fees and charges associated with the Scope of Work were generated through REGENESIS' proprietary formulas and thus may not conform to billing guidelines,constraints or other limits on fees. REGENESIS does not seek Application Dosing Unit Value reimbursement directly from any government agency or any governmental reimbursement fund(the"Government"). In any circumstance where REGENESIS may serve as a supplier or subcontractor to an entity which seeks reimbursement from the Government for all or part of PlumeStop to be Applied lbs 9,600 the services performed or products provided by REGENESIS,it is the sole responsibility of the entity seeking reimbursement to ensure the Scope of Work and associated charges are in compliance with and acceptable to the Government prior to submission. When serving as a supplier or subcontractor to an entity which seeks reimbursement from the Government,REGENESIS does not knowingly present or cause to be presented any claim for payment to the Government. Prepared by: DaP62196 Date: 1/2/2019 4 REGENESIS Project Info ORC®Application Design Summary Cintas-Frmr RUS Winston-Salem,NC Saprolite Aquifer Field App Instructions Saprolite Aquifer Barrier Length(ft) 130 Prepared For: Spacing Within Barrier 6.5 AECOM Number of Lines 1 Input special application instructions here as Target Treatment Zone(TTZ)Info Unit Value Application Points 20 needed. Barrier Length ft 130 Application Method Direct Push Top Treat Depth ft 10.0 Top Application Depth(ft bgs) 10 Bot Treat Depth ft 35.0 Bottom Application Depth(ft bgs) 35 Vertical Treatment Interval ft 25.0 ORC Advanced to be Applied(Ibs) 1,600 Field Mixing Ratios Treatment Zone Volume ft3 26,000 ORC Advanced per point(Ibs) 80 Water per Pt(gals) Treatment Zone Volume cy 963 Percent Slurry 25% 29 Soil Type --- saprolite Volume Water(gals) 575 ORC Advanced per Pt(Ibs) Porosity cm3/cm3 0.33 Volume ORC Advanced(gals) 72 80 Effective Porosity cm3/cm3 0.20 Total Application Volume(gals) 647 Total Volume per Pt(gals) Treatment Zone Pore Volume gals 64,183 Injection Volume per Point(gals) 32 32 Treatment Zone Effective Pore Volume gals 38,899 Fraction Organic Carbon(foc) g/g 0.005 Technicas/Discussion dill Soil Density g/cm3 1.67 Soil Density lb/ft3 104 Soil Weight lbs 2.7E+06 Hydraulic Conductivity ft/day 1.0 Hydraulic Conductivity cm/sec 3.53E-04 Hydraulic Gradient ft/ft 0.017 GW Velocity ft/day 0.09 GW Velocity ft/yr 31 Sources of xyg Value Dissolved Phase Contaminant Mass lbs 6 Sorbed Phase Contaminant Mass lbs 1 In generating this preliminary estimate,Regenesis relied upon professional judgment and site specific information provided by others. Using this information as input,we performed calculations based upon known chemical and geologic relationships to generate an estimate of the Reduced Metals(Fe2+and Mn2+)Mass lbs 16 mass of product and subsurface placement required to affect remediation of the site. BOD mass equivalent lbs 3 COD mass equivalent lbs 11 Total Mass Contributing to 02 Demand lbs 36 REGENESIS developed this Scope of Work in reliance upon the data and professional judgments provided by those whom completed the ,Stoichiometric Demanc Value I earlier environmental site assessment(s). The fees and charges associated with the Scope of Work were generated through REGENESIS' Stoichiometric 02 Demand lbs 24 proprietary formulas and thus may not conform to billing guidelines,constraints or other limits on fees. REGENESIS does not seek Stoichiometric ORC Advanced Demand lbs 242 reimbursement directly from any government agency or any governmental reimbursement fund(the"Government"). In any circumstance where REGENESIS may serve as a supplier or subcontractor to an entity which seeks reimbursement from the Government for all or part of Application Do Value 'the services performed or products provided by REGENESIS,it is the sole responsibility of the entity seeking reimbursement to ensure the Scope of Work and associated charges are in compliance with and acceptable to the Government prior to submission. When serving as a supplier or subcontractor to an entity which seeks reimbursement from the Government,REGENESIS does not knowingly present or cause to ORC to be Applied lbs 1,600.0 be presented any claim for payment to the Government. Prepared By: DaP62196 Date: 1/2/2019 About AECOM AECOM is built to deliver a better world. We design, build, finance and operate infrastructure assets for governments, businesses and organizations in more than 150 countries. As a fully integrated firm, we connect knowledge and experience across our global network of experts to help clients solve their most complex challenges. From high-performance buildings and infrastructure, to resilient communities and environments, to stable and secure nations, our work is transformative, differentiated and vital. A Fortune 500 firm, AECOM companies have annual revenue of approximately US$18 billion. See how we deliver what others can only imagine at aecom.com and @AECOM. AECOM 1600 Perimeter Park Morrisville, NC 27560 USA T:919.461.1100 F:919.461.1415 aecom.com