20070812 Ver 1_07b - LAB RESULTS QUALITY CONTROL RESULTS (2)_20080502

QUALITY CONTROL RESULTS
TestAmerica Tallahassee
Page 123 of 167
12/21./2007
Quality Control Results
Client: Environmental Services, Inc.
Surrogate Recovery Report
8270C Semivolatile Organic Compounds by GCMS - Low Levels
Client Matrix: Solid
Lab Sample ID
640-14341-1
640-14341-2
640-14341-3
640-14341-4
640-14341-5
640-14341-6
640-14341-7
640-14341-8
640-14341-9
640-14341-10
640-14341-11
640-14341-12
640-14341-13
640-1434114
640-14341-15
640-14341-16
640-14341-17
640-14341-18
640-14341-19
640-14341-20
640-14341-21
640-14341-22
640-14341-23
640-14341-24
640-14341-25
640-14341-26
640-14341-27
MB 680-93073/19-A
M B 680-93303/21-A
Client Sample ID
R-1
R-1 b
R-1c
b
R-100
R-1 Dub b
R-1 Dub c
BR-1a
BR-1 b
BR-1c
BR-2a
BR-2b
BR-2c
BR-2 Dub a
BR-2 Dub b
BR-2 Dub c
SA-1 a
SA-1 b
SA-1 c
SA-2 a
SA-2 b
SA-2 c
SA-3 a
SA-3 b
SA-3 c
SA-4 a
SA-4 b
SA-4 0
OTPH
%Rec
OD ..
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
OD
53
85
Surrogate Acceptance Limits
OTPH = o-Terphenyl 29-122
TestAmerica Tallahassee
Jab Number: 640-14341-1
Page 124 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Surrogate Recovery Report
82700 Semivolatile Organic Compounds b GCMS - Low Levels
Client Matrix: Solid
Lab Sample ID
LCS 680-93073120-A
LCS 680-93303122-A
640-14341-20 MS
640-14341-20 MSD
OTPH
Client Sample ID %Rec
53
81
SA-2 b MS OD
SA-2 b MSD OD
Surrogate Acceptance Limits
OTPH = o-Terphenyl 29-122
TestAmerica Tallahassee
Job Number: 640-14341-1
Page 125 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Surrogate Recovery Report
8270C Semivolatile Organic- Compounds by GCMS - Low Levels
Client Matrix: Water
OTPH
Lab Sample ID Client Sample ID %Rec
640-14341-28 EB-1 62
640-14341-29 EB-2 45
Surrogate
OTPH = o-Terphenyl
TestAmerica Tallahassee
Acceptance Limits
44-123
Page 126 of 167
Job Number: 640-14341-1
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Surrogate Recovery Report
8081A 8082 Organchlorine Pesticides & Polychlorinated Biphenyls by Gas Chromatography
Client Matrix: Solid
Lab Sample ID
640-14341-1
640-14341-2
640-14341-3
640-14341-4
640-14341-5
640-14341-6
640-14341-7
640-14341-8
640-14341-9
640-14341-10
640-14341-11
640-14341-12
640-14341-13
640-14341-14
640-14341-15
640-14341-16
640-14341-17
640-14341-18
640-14341-19
640-14341-20
640-14341-21
640-14341-22
640-14341-23
640-14341-24
640-14341-25
640-14341-26
640-14341-27
MB 680-93195/8-A
MB 680-93304121-A
Surrogate
Client sample ID
R-1 b
R-1 c
R-1 Dub
R-1 Dub b
R-1 Dub c
BR-1a
BR-1 b
BR-1c
BR-2a
BR-2b
BR-2c
BR-2 Dub a
BR-2 Dub b
BR-2 Dub c
SA-1 a
SA-1 b
SA-1 c
SA-2 a
SA-2 b
SA-2 o
SA-3 a
SA-3 b
SA-3 c
SA-4 a
SA-4 b
SA-4 c
TCX1
%Rec
41
47
49
49
50
72
82
90
72
41
32
37
72
61
64
55
72
44
36
36
58
63
48
68
72
137
69
68
TCX = Tetrachloro-m-xylene
DCB = DCB Decachlorobiphenyl
TestAmerica Tallahassee
TCX2
%Rec
DCB1
%Rec
49X
57
62
60
60
78
70
94
88
48X
39X
43X
84
67
72
72
69
51
42X
48X
DCB2
%Rec
71
58 75
78
60
75
55
133X
110
91
Acceptance Limits
26-140
50-129
Jab Number: 640-14341-1
Page 127 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Surrogate Recovery Report
8081A 8082 Or anochlorine Pesticides & Polychlorinated Bi hen Is b Gas Chromato ra h
Client Matrix: Solid
TCX1 TCX2 DCB1 DCB2
Lab Sample ID Client Sample ID %Rec %Rec %Rec %Rec
LCS 680-9319519-A 74 103
LCS 680-93304122-A 58 88
640-14341-20 MS SA-2 b MS 60 65
640-1 434 1-27 MS SA-4 c MS 70 54
640-14341-20 MSD SA-2 b MSD 62 66
640-14341-27 MSD SA-4 c MSD 61 47X
Surrogate
Acceptance Limits
TCX = Tetrachloro-m-xylene
DCB = DC8 Decachlorobiphenyl
TestAmerica Tallahassee
26-140
50-129
Page 128 of 167
Job Number: 640-14341-1
12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Surrogate Recovery Report
8081A 8082 Or anochlorine Pesticides & Polychlorinated Bi hen Is b Gas Chromatography
Client Matrix: Water
TCX1 DCB1
Lab Sample ID Client Sample ID %Rec %Rec
640-14341-28 EB-1 71 60
640-14341-29 E8-2 56 16
MB 680-93087112-A 61 69
LCS 680-93087114-A 79 76
Surrogate Acceptance Limits
TCX = Tetrachloro-m-xylene 35-120
DCB = DCB Decachlorobipheny! 14-115
TestAmerica Tallahassee
Page 129 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93073
Lab Sample ID: MB 680-93073119-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 1211312007 1621
Date Prepared: 1211112007 1312
Analysis Batch: 680-93497
Prep Batch: 680-93073
Units: ug/Kg
Job Number: 640-14341-1
Method: 8270C
Preparation: 3550B
Instrument 10: GC/MS SemiVolatiles - K
Lab File ID: k4807.d
Initial Weight/Volume: 30.00 g
Final WeightiVolume: 1.0 mL
Injection Volume: 1 uL
Analyte Result Qual RL
Acenaphthene <6.7 67
Acenaphthylene <63 6.7
Anthracene <63 6.7
Benzo[a]anthracene <6.7 6.7
Benzo[a]pyrene <6.7 6.7
Benzo[b]fluoranthene <6.7 6.7
Benzo[g,h,i]perylene <6.7 67
Benzo[k]fluoranthene <6.7 6.7
Chrysene <6.7 6.7
Dibenz(a,h)anthracene <6.7 6.7
Fluorene <6.7 6.7
Fluoranthene <6.7 6.7
Indeno[1,2,3-cd]pyrene <6.7 6.7
Naphthalene <6.7 6.7
Phenanthrene <6.7 6.7
f yrene <6.7 6.7
Surrogate % Rec Acceptance Limits
o-Terphenyl 53 29 - 122
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 130 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Lab Control Spike - Batch: 680-93073 Method: 8270C
Preparation: 35508
Lab Sample ID: LCS 680-93073120-A Analysis Batch: 680-93497 Instrument ID: GCIMS SemiVolatiles - K
Client Matrix: Solid Prep Batch: 680-93073 Lab File 1D: k4808.d
Dilution: 1.0 Units: ug/Kg Initial Weight/Volume: 30.01 g
Date Analyzed: 12113/2007 1644 Final Weight[Volume: 1.0 mL
Date Prepared: 12111/2007 1312 Injection Volume: 1 uL
Analyte Spike Amount Result % Rec. Limit Qual
Acenaphthene 66.6 35.5 53 36 - 110
Acenaphthylene 66.6 33.8 51 34 - 110
Anthracene 66.6 33.6 50 38-111
Benzo[a]anthracene 66.6 39.7 60 44 - 116
Benzo[a]pyrene 66.6 40.2 60 41-110
Benzo[b]fluoranthene 66.6 41.2 62 40- 112
Benzo[g,h,i]perylene 66.6 35.8 54 37 - 119
Benzo[k]fluoranthene 66.6 42.4 64 42 - 115
Chrysene 66.6 43.8 66 46 - 110
Dibenz(a,h)anthracene 66.6 34.9 52 36- 115
Fluorene 66.6 34.5 52 35 - 110
Fluoranthene 66.6 39.7 60 41 - 110
Indeno(1,2,3-cd]pyrene 66.6 33.0 50 35 - 126
Naphthalene 66.6 35.2 53 36 - 110
Phenanthrene 66.6 36.7 55 38 - 110
Pyrene 66.6 41.5 62 41-111
Surrogate % Rec Acceptance Limits
o-Terphenyl 53 29 - 122
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 131 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank - Batch: 680-93303
Lab Sample ID: MB 680-93303121-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/19/2007 1820
Date Prepared: 12/13/2007 1259
Analysis Batch: 680-94176
Prep Batch: 680-93303
Units: ug/Kg
Job Number: 640-14341-1
Method: 8270C
Preparation: 3550B
Instrument ID: GCIMS Semivolatiles - D
Lab File ID: d7946.d
Initial Weighl/Volume: 30.01 g
Final Weight/VOume: 1 mL
Injection Volume: 1 uL
Analyte Result Qual RL
Acenaphthene <6.7 6.7
Acenaphthylene <6.7 6.7
Anthracene <6.7 6.7
Benzo[a]anthrace ne <6.7 6.7
Benzo[a]pyrene <6.7 6.7
Benzo[b]fiuoranthene <6.7 6.7
Benzo[g,h,i]perylene <6.7 6.7
Benzo[k]fluoranthene <6.7 6.7
Chrysene <6.7 6.7
Dibenz(a,h)anthrace ne <6.1 6.7
Fluorene <6.7 6.7
Fluoranthene <6.7 6.7
Indeno[1,2,3-cd]pyrene <6.7 6.7
Naphthalene <6.7 6.7
Phenanthrene <6.7 6.7
Pyrene <6.7 6.7
Surrogate % Rec Acceptance Limits
o-Terphenyl 85 29 - 122
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestArnericaTallahassee Page 132 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Lab Control Spike - Batch: 680-93303 Method: 8270C
Preparation: 3550B
Lab Sample ID: LCS 680-93303122-A Analysis Batch: 680-94176 Instrument ID: GCIMS Semivolatiles - D
Client Matrix: Solid Prep Batch: 680-93303 Lab File ID: d7947.d
Dilution: 1.0 Units: ug/Kg Initial Weight/Volume: 30.00 g
Date Analyzed: 12119/2007 1842 Final WeightNolume: 1 mL
Date Prepared: 12/13/2007 1259 Injection Volume: 1 uL
Analyte Spike Amount Result % Rec. Limit Qual
Acenaphthene 66.7 54.4 82 36 - 110
Acenaphthylene 66.7 53.2 80 34 - 110
Anthracene 66.7 57.6 86 38-111
Benzo[a]anthrace ne 66.7 58.3 87 44 - 116
Benzo]a]pyrene 66.7 58.1 87 41 -110
Benzo[b]fluoranthene 66.7 59.5 89 40 - 112
Benzo[g,h,i]perylene 66.7 57.2 86 37 - 119
Benzo[k]fluoranthene 66.7 59.2 89 42 - 115
Chrysene 66.7 56.9 85 46 - 110
Dibenz(a,h)anthracene 66.7 57.6 86 36 - 115
Fluorene 66.7 59.4 89 35 - 110
Fluoranthene 66.7 58.0 87 41 -110
Indeno[1,2,3-cd]pyrene 66.7 55.7 84 35- 126
Naphthalene 66.7 51.5 77 36 - 110
Phenanthrene 66.7 56.5 85 38 - 110
Pyrene 66.7 56.2 84 41-111
Surrogate % Rec Acceptance Limits
o-Terphenyl 81 29 - 122
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 133 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Matrix Spike/ Method: 82700
Matrix Spike Duplicate Recovery Report - Batch: 680-93303 Preparation: 3550B
MS Lab Sample ID: 640-14341-20 Analysis Batch: 680-94258 Instrument ID: GUMS Semivolatiles - D
Client Matrix: Solid Prep Batch: 68 0-93303 Lab File ID: d7978.d
Dilution: 10 Initial Weight/Volume: 30.14 g
Date Analyzed: 12120/2007 1430 Final Weight/Volume: 1 mL
Date Prepared: 1211312007 1259 Injection Volume: 1 uL
MSD Lab Sample ID: 640-14341-20 Analysis Batch: 680-94258 Instrument ID: GC/MS Semivo latiles - D
Client Matrix: Solid Prep Batch: 68 0-93303 Lab File ID: d7979.d
Dilution: 10 Initial WeightNolume: 30.12 g
Date Analyzed: 12120/2007 1453 Final Weight/Volume: 1 mL
Date Prepared: 12/13/2007 1259 Injection Volume: 1 uL
% Rec.
Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual
Acenaphthene 72 89 36 - 110 17 50
Acenaphthylene 94 104 34 - 110 10 50
Anthracene 59 95 38-111 26 50
Benzo[a]anthracene -91 -7 44 - 116 27 50 F F
Benzo[a]pyrene -107 -32 41 -110 23 50 F F
Benzo[b]fluoranthene -235 -125 40 - 112 23 50 4 4
Benzo[g,h,i]perylene -98 -3 37 - 119 35 50 F F
Benzo[k]fluoranthene -45 38 42 - 115 33 50 F F
Chrysene -114 -26 46 - 110 27 50 F F
Dibenz(a,h)anthrace ne 165 181 36 - 115 10 50 F F
Fluorene 88 104 35 - 110 15 50
Fluoranthene -171 -61 41 -110 29 50 4 4
Indeno[1,2,3-cd]pyrene -84 -7 35 - 126 27 50 F F
Naphthalene 76 87 36 - 110 13 50
Phenanthrene 1 45 38 - 110 22 50 F
Pyrene -116 -19 41 -111 30 50 F F
Surrogate MS % Rec MSD % Rec Acceptance Limits
o-Terphenyl 0 D 0 D 29 - 122
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmericaTallahassee Page 134 of 167 12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93087
Quality Control Results
Job Number: 640-14341-1
Method: 8081A 8082
Preparation: 3520C
Lab Sample ID: MB 680-93087112-A Analysis Batch: 680-93295 Instrument ID: GC SemiVolatiles - J
Client Matrix: Water Prep Batch: 680-93087 Lab File ID: j110012.d
Dilution: 1.0 Units: ug/L Initial Weight/Volume: 1000 mL
Date Analyzed: 12111/2007 1633 Final Weight/Volume: 10 mL
Date Prepared: 12/10/2007 1445 Injection Volume: 2 uL
Column ID: PRIMARY
Analyte Result Qua] RL
PCB-1242 <1.0 1.0
PCB-1248 <1.0 1.0
PCB-1254 <1.0 1.0
PCB-1260 <1.0 1.0
Surrogate % Rec Acceptance Limits
Tetrachloro-m-xylene 61 35 - 120
DCB Decachlorobiphenyl 69 14-115
Lab Control Spike - Batch: 680-93087
Lab Sample ID: LCS 680-93087114-A Analysis Batch: 680-93295
Client Matrix: Water Prep Batch: 680-93087
Dilution: 1.0 Units: ug1L
Date Analyzed: 12!1112007 1719
Date Prepared: 12/1012007 1445
Analyte Spike Amount Result
PCB-1260 10.0 8.27
Surrogate % Rec
Tetrachloro-m-xylene 79
DCB Decachlorobiphenyl 76
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 135 of 167
Method: 8081A_8082
Preparation: 3520C
Instrument ID: GC SemiVolatiles - J
Lab File ID: j110014A
Initial WeightfVolume: 1000 mL
Final WeighWolume: 10 mL
Injection Volume: 2 uL
Column ID: PRIMARY
% Rea Limit Qual
83 58 - 124
Acceptance Limits
35 - 120
14-115
12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Method Blank -Batch: 680-93195 Method: 8081A8082
Preparation: 3550E
Lab Sample ID: MB 680-9319518-A Analysis Batch: 680-93447 Instrument ID: GC SemiVolatiles - M
Client Matrix: Solid Prep Batch: 680-93195 Lab File ID: m112011.d
Dilution: 1.0 Units: ug1Kg Initial WeightNolume: 30.01 g
Date Analyzed: 12/1212007 1502 Final WeightNolume: 10 mL
Date Prepared: 12/1112007 1800 Injection Volume: 2 uL
Column ID: PRIMARY
Analyte Result Qual RL
PCB-1242 <33 33
PCB-1248 <33 33
PCB-1254 <33 33
PCB-1260 <33 33
Surrogate % Rec Acceptance Limits
Tetrachloro-m-xylene 69 26 - 140
DCB Decachlorobiphenyl 110 50 - 129
Lab Control Spike - Batch: 680-93195 Method: 8081A_8082
Preparation: 35508
Lab Sample ID: LCS 680-9319519-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/12/2007 1521
Date Prepared: 12/11/2007 1800
Analyte
PCB-1260
Surrogate
Tetrachloro-m-xylene
DCB Decachlorobiphenyl
Analysis Batch: 680-93447
Prep Batch: 680-93195
Units: ug/Kg
Instrument ID: GC SemiVolatiles - M
Lab File ID: m112012.d
Initial Weight/Volume; 30.01 g
Final WeightNolume: 10 mL
Injection Volume: 2 uL
Column ID: PRIMARY
% Rec. Limit Qual
78 53 - 133
Acceptance Limits
26 - 140
50 - 129
Spike Amount Result
333 259
% Rec
74
103
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerfcaTallahassee Page 136 of 167
1.2/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93195
MS Lab Sample ID
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MSD Lab Sample ID
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
640-14341-27
Solid
2.0
12112/2007 1805
12111/2007 1800
640-14341-27
Solid
2.0
12/1212007 1825
12/1112007 1800
Analyte
PCB-1260
Surrogate
Tetrachloro-m-xylene
DCB Decachlorobiphenyl
Analysis Batch: 680-93447
Prep Batch: 680-93195
Analysis Batch: 680-93447
Prep Batch: 680-93195
% Rec.
MS MSD
72 59
MS%Rec
70
54
Limit
53 - 133
MSD % Rec
61
47
Calculations are performed before rounding to avoid round-off errors in calculated results.
Job Number: 640-14341-1
Method: 8081A 8082
Preparation: 3550E
Instrument ID: GC SemiVolatiles - M
Lab File ID: m112020.d
Initial Weight/Volume: 30.06 g
Final Weight/Volume: 10 mL
Injection Volume: 2 uL
Column ID: PRIMARY
Instrument ID: GC SemiVolatiles - M
Lab File ID: ml1202U
Initial Weight/Volume: 30.05 g
Final WeightiVolume: 10 mL
Injection Volume: 2 uL
Column ID: PRIMARY
RPD RPD Limit MS Qual MSD Qual
20 50
Acceptance Limits
26 - 140
X 50 - 129
TestAmerica Tallahassee Page 137 of 167 12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93304
Lab Sample ID: MB 680-93304121-A Analysis Batch: 680-93715
Client Matrix: Solid Prep Batch: 680-93304
Dilution: 1.0 Units: ug/Kg
Date Analyzed: 12114/2007 2044
Date Prepared: 12113/2007 1830
Analyte Result
PCB-1242 <33
PCB-1248 <33
PCB-1254 <33
PCB-1260 <33
Surrogate % Rec
Tetrachloro-m-xylene 68
DCB Decachlorobiphenyl 91
Lab Control Spike - Batch: 680-93304
Lab Sample ID: LCS 680-93304122-A Analysis Batch: 680-93715
Client Matrix: Solid Prep Batch: 680-93304
Dilution: 1.0 Units: ug/Kg
Date Analyzed: 12/1412007 2103
Date Prepared: 12/1312007 1830
Analyte Spike Amount Result
PCB-1260 333 261
Surrogate % Rec
Tetrachloro-m-xylene 58
DCB Decachlorobiphenyl 88
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 138 of 167
Quality Control Results
Job Number: 640-14341-1
Method: 8081A 8082
Preparation: 3550E
Instrument ID: GC SemiVolatiles - M
Lab File ID: m114041.d
Initial Weight/Volume: 30.01 g
Final Weight/Volume: 10 mL
Injection Volume: 2 uL
Column ID: PRIMARY
RL
33
33
33
33
Acceptance Limits
26 - 140
50 - 129
Method: 8081A_8082
Preparation: 35508
Instrument ID: GC SemiVolatiles - M
Lab File ID: m114042.d
Initial WeightNolume: 30.03 g
Final Weight/Volume: 10 mL
Injection Volume: 2 uL
Column 1D: PRIMARY
% Rec. Limit Qual
78 53 - 133
Acceptance Limits
26 - 140
50 - 129
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93304
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
640-14341-20
Solid
1.0
12/15/2007 0352
12/1312007 1830
640-14341-20
Solid
1.0
12115/2007 0412
12113/2007 1830
Analyte
PCB-1260
Surrogate
Tetrachloro-m-xylene
DCB Decachlorobiphenyl
Analysis Batch: 680-93715
Prep Batch: 680-93304
Analysis Batch: 680-93715
Prep Batch: 680-93304
% Rec.
MS MSD
55 59
MS % Rec
60
65
Limit RPD
53 - 133 5
MSD % Rec
62
66
Calculations are performed before rounding to avoid round-off errors in calculated results.
Job Number: 640-14341-1
Method: 8081A 8082
Preparation: 35508
Instrument ID: GC SemiVolatiles - M
Lab File ID: m114063.d
Initial Weight/Volume: 30.19 g
Final Weight/Volume: 10 mL
Injection Volume: 2 uL
Column ID: PRIMARY
Instrument ID: GC SemiVolatiles - M
Lab File ID: m114064.d
Initial WeightfVolume: 30.45 g
Final WeightlVolume: 10 mL
Injection Volume: 2 uL
Column to! PRIMARY
RPD Limit MS Qual MSD Qual
50
Acceptance Limits
26 - 140
50 - 129
TestAmericaTatlahassee Page 139 of 167 12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93138
Lab Sample ID: MB 680-93138118-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12112/2007 0234
Date Prepared: 12110/2007 1406
Analysis Batch: 680-93371
Prep Batch: 680-93138
Units: mg/Kg
Quality Control Results
Job Number; 640-14341-1
Method: 6010B
Preparation: 3050B
Instrument ID: ICPIAES
Lab File ID: NIA
Initial WeightNolume: 1.00 g
Final WeightNolume: 100 mL
Analyte Result Qual RL
Arsenic <1.0 1.0
Barium <1.0 1.0
Cadmium <0.50 0.50
Chromium <1.0 1.0
Iron <10 10
Lead <0.50 0.50
Selenium <2.5 2.5
Lab Control Spike - Batch: 680-93138
Lab Sample ID: LCS 680-93138119-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/12/2007 0239
Date Prepared: 12/10/2007 1406
Analysis Batch: 680-93371
Prep Batch: 680-93138
Units: mg/Kg
Method: 60108
Preparation: 3050E
Instrument ID: ICPIAES
Lab File ID: NIA
Initial WeightNolume: 1.00 g
Final WeightNolume: 100 mL
Analyte Spike Amount Result % Rec. Limit
Arsenic 200 186 93 75 - 125
Barium 200 197 98 75 - 125
Cadmium 5.00 4.81 96 75 - 125
Chromium 20.0 19.9 99 75 - 125
Iron 109 110 101 75 - 125
Lead 50.0 47.8 96 75 - 125
Selenium 200 181 91 75 - 125
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 140 of 167
Qual
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93140
Lab Sample ID: MB 680-93140120-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 12112/2007 0001
Date Prepared: 12110/2007 1412
Analysis Batch: 680-93370
Prep Batch: 680-93140
Units: ug/L
Job Number: 640-14341-1
Method: 6010B
Preparation: 3005A
Total Recoverable
Instrument ID: ICPIAFS
Lab File ID: NIA
Initial WeightNolume: 50 mL
Final Weight/Volume: 50 mL
Analyte Result Qual RL
Arsenic <10 10
Barium <10 10
Beryllium <4.0 4.0
Cadmium <5.0 5.0
Chromium <10 10
Iron <50 50
Lead <5.0 5.0
Selenium <10 10
Lab Control Spike - Batch: 680-93140
Lab Sample ID: LCS 680-93140121-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 12112/2007 0006
Date Prepared: 12110/2007 1412
Analysis Batch: 680-93370
Prep Batch: 680-93140
Units: ug/L
Method: 60108
Preparation: 3005A
Total Recoverable
Instrument ID: ICP/AES
Lab File ID: NIA
Initial WeightNolume: 50 mL
Final WeightNolume: 50 mL
Analyte Spike Amount Result % Rec. Limit
Arsenic 2000 2010 100 75 - 125
Barium 2000 2060 103 75 - 125
Beryllium 50.0 51.6 103 75 - 125
Cadmium 50.0 51.0 102 75 - 125
Chromium 200 208 104 75 - 125
lron 1000 1020 102 75 - 125
Lead 500 507 101 75-125
Selenium 2000 2010 101 75 - 125
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 141 of 167
Qual
12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93199
Lab Sample ID: MB 680-93199/21-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed; 12/17/2007 0920
Date Prepared: 12/1112007 0829
Analysis Batch: 680-93808
Prep Batch: 680-93199
Units: mg/Kg
Quality Control Results
Job Number: 640-14341-1
Method: 6010B
Preparation: 3050B
Instrument ID: ICPIAES
Lab File ID: NIA
Initial Weight/Volume: 1.00 g
Final Weight/Volume: 100 mL
Analyte Result Qual RL
Arsenic <1.0 1.0
Barium <1.0 1.0
Cadmium <0.50 0.50
Chromium <1,0 1.0
Iron <10 10
Lead <0.50 0.50
Selenium <2,5 2.5
Lab Control Spike - Batch: 680-93199
Lab Sample ID: LCS 680-93199122-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/1612007 2125
Date Prepared: 12111/2007 0829
Analysis Batch: 680-93808
Prep Batch: 680-93199
Units: mglKg
Method: 6010E
Preparation: 3050B
Instrument ID: ICP/AES
Lab File ID: NIA
Initial Weight/Volume: 1.00 g
Final Weight/Volume: 100 mL
Analyte Spike Amount Result % Rec. Limit
Arsenic 200 179 89 75- 125
Barium 200 184 92 75 - 125
Cadmium 5.00 4.40 88 75 - 125
Chromium 20.0 19.1 96 75 - 125
Iron 109 106 97 75 - 125
Lead 50.0 45.6 91 75 - 125
Selenium 200 171 85 75 - 125
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 142 of 167
Qual
12/21/2007
Client: Environmental Services, Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93199
MS Lab Sample ID: 640-14341-8
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12116/2007 2143
Date Prepared: 12111/2007 0829
Analysis Batch: 680-93808
Prep Batch: 680-93199
MSD Lab Sample ID: 640-14341-8
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 1211612007 2148
Date Prepared: 12111/2007 0829
Analyte
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Selenium
Analysis Batch: 680-93808
Prep Batch: 680-93199
% Rec.
MS MSD
83 84
89 91
83 84
88 94
82 1060
86 89
76 76
Limit
75 - 125
75-125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 143 of 167
Quality Control Results
Job Number: 640-14341-1
Method: 6010B
Preparation: 30508
Instrument ID: ICPIAFS
Lab File ID: NIA
Initial Weight/Volume: 1.08 g
Final WeightNolume: 100 mL
Instrument ID: ICPIAES
Lab Fife ID: NIA
Initial Weight/Volume: 1.08 g
Final WeightNolume: 100 mL
RPD RPD Limit
0 20
2 20
1 20
4 20
10 20
3 20
0 20
MS Qual MSD Qual
4
4
12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Method Blank -Batch: 680-93141 Method: 7470A
Preparation: 7470A
Lab Sample 1D: MB 680-93141120-A Analysis Batch: 680-93296 Instrument ID: LEEMANI
Client Matrix: Water Prep Batch: 680-93141 Lab File ID: NIA
Dilution: 1.0 Units: ug/L Initial Weight/Volume: 50 mL
Date Analyzed: 12111/2007 1144 Final WeightA/olume: 50 ML
Date Prepared: 12110/2007 1424
Analyte Result Qual RL
Mercury <0.20 0.20
Lab Control Spike - Batch: 680-93141 Method: 7470A
Preparation: 7470A
Lab Sample ID: LCS 680-93141121-A Analysis Batch: 680-93296 Instrument ID: LEEMAN1
Client Matrix: Water Prep Batch: 680-93141 Lab File ID: NIA
Dilution: 1.0 Units: ug/L Initial Weight/Volume: 50 mL
Date Analyzed: 1211112007 1147 Final Weight/Volume: 50 mL
Date Prepared: 12110/2007 1424
Analyte Spike Amount Result % Rec. Limit Qual
Mercury 2.50 2.44 98 80 - 120
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 144 of 167
12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93247
Lab Sample 1D: MB 680-93247118-B
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12112/2007 1019
Date Prepared: 12111/2007 1149
Analysis Batch: 680-93475
Prep Batch: 680-93247
Units: mg/Kg
Analyte
Mercury
Result
X0.020
Lab Control Spike - Batch: 680-93247
Lab Sample ID: LCS 680-93247119-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/1212007 1022
Date Prepared: 12/1112007 1551
Analysis Batch; 680-93475
Prep Batch: 680-93247
Units: mg/Kg
Analyte
Mercury
Qual
Spike Amount Result % Rec
0.125 0.120 96
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 145 of 167
Quality Control Results
Job Number: 640-14341-1
Method: 7471A
Preparation: 7471A
Instrument ID: LEEMAN1
Lab File ID: NIA
Initial Weight/Volume; 1.00 g
Final Weight/Volume: 50 mL
RL
0.020
Method: 7471A
Preparation: 7471A
Instrument ID: LEEMANI
Lab File ID: NIA
Initial Weight/Volume: 1.00 g
Final WeighWolume: 50 mL
Limit Qual
80 - 120
12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Method Blank - Batch: 680-93249 Method: 7471A
Preparation: 7471A
Lab Sample ID: MB 680-93249123-A Analysis Batch: 680-93642 Instrument ID: LEEMAN1
Client Matrix: Solid Prep Batch: 680-93249 Lab File ID: NIA
Dilution; 1.0 Units: mg/Kg Initial Weight/Volume: 1.00 g
Date Analyzed: 12/1312007 1607 Final WeightNolume: 50 mL
Date Prepared: 12/11/2007 1159
Analyte Result Qual RL
Mercury <0.020 0.020
Lab Control Spike - Batch: 680-93249 Method: 7471A
Preparation: 7471A
Lab Sample ID; LCS 680-93249124-A Analysis Batch: 680-93642 Instrument ID: LEEMANI
Client Matrix: Solid Prep Batch: 680-93249 Lab He ID: NIA
Dilution: 1.0 Units: mg/Kg Initial Weight/Volume: 1.00 g
Date Analyzed: 12/1312007 1609 Final Weight/Volume: 50 mL
Date Prepared: 12/1112007 1159
Analyte Spike Amount Result
Mercury 0.125 0.121
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93249
% Rec. Limit
97 80 - 120
Method: 7471A
Preparation: 7471A
Qual
MS Lab Sample ID: 640-14341-20
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/13/2007 1723
Date Prepared: 12/11/2007 1159
MSD Lab Sample ID: 640-14341-20
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/13/2007 1726
Date Prepared: 12/11/2007 1159
Analysis Batch: 680-93642
Prep Batch: 680-93249
Analysis Batch; 680-93642
Prep Batch: 680-93249
% Rec.
Analyte MS MSD Limit
Mercury 108 118 80 - 120
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmericaTallahassee Page 146 of 167
Instrument ID: LEEMAN1
Lab File ID: NIA
Initial Weight/Volume: 1.04 g
Final Weight/Volume: 50 mL
Instrument ID: LEEMANI
Lab File ID: NIA
Initial WeightNolume: 1.04 g
Final Weight/Volume: 50 mL
RPD RPD Limit MS Qual MSD Qual
6 20
12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93651
Lab Sample ID: MB 680-9365111
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 12/14/2007 1049
Date Prepared: NIA
Analyte
Fluoride
Lab Control Spike - Batch: 680-93651
Lab Sample ID: LCS 680-9365112
Client Matrix: Water
Dilution: 1A
Date Analyzed: 12/14/2007 1049
Date Prepared: N/A
Analyte
Fluoride
Quality Control Results
Job Number: 640-14341-1
Method: 340.2
Preparation: NIA
Analysis Batch: 680-93651 Instrument ID: No Equipment Assigned
Prep Batch: NIA Lab Fite ID: NIA
Units: mglL Initial Weight/Volume: 50 mL
Final Weight/Volume: 50 mL
Result Qual RL
X0.20 0.20
Method: 340.2
Preparation: NIA
Analysis Batch: 680-93651 Instrument ID: No Equipment Assigned
Prep Batch: NIA Lab File ID: NIA
Units: mg1L Initial Weight/Volume: 50 mL
Final Weight/Volume: 50 mL
Spike Amount Result % Rec. Limit Qual
6.23 6.56 105 85 - 115
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerfcaTallahassee Page 147 of 167
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93682
Lab Sample ID: MB 680-9368011-A
Client Matrix: Solid
Dilution: 11.0
Date Analyzed: 12114/2007 1133
Date Prepared: NIA
Date Leached: 12113/2007 1613
Analysis Batch: 680-93682
Prep Batch: NIA
Units: mg/Kg
Leachate Batch: 680-93680
Analyte Result
Fluoride-S <4.0
Lab Control Spike]
Lab Control Spike Duplicate Recovery Report - Batch: 680-93682
LCS Lab Sample ID: LCS 680-9368012-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
LCSD Lab Sample ID
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Solid
1.0
12/1412007 1133
NIA
12/13/2007 1613
LCSD 680-93680!3-A
Solid
1.0
12114/2007 1133
N/A
12113/2007 1613
Analyte
Fluoride-S
Analysis Batch: 680-93682
Prep Batch: NIA
Units: mg/Kg
Leachate Batch: 680-93680
Analysis Batch: 680-93682
Prep Batch: NIA
Units: mg/Kg
Leachate Batch: 680-93680
% Rec.
LCS LCSD Limit
100 102 75 - 125
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 148 of 167
Job Number; 640-14341-1
Method: 340.2
Preparation: NIA
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weightolume: 50 mL
Final WeightlVolume: 50 mL
Method: 340.2
Preparation: NIA
RL
4.0
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightfVolume: 50 ML
Final Weight/Volume: 50 mL
Instrument ID: No Fquipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 50 mL
Final WeighWolume: 50 mL
RPD RPD Limit LCS Qual LCSD Qual
2 30
12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Job Number: 640-14341-1
Matrix Spike/ Method: 340.2
Matrix Spike Duplicate Recovery Report - Batch: 680-93682 Preparation: N/A
MS Lab Sample ID; 640-14341-25 Analysis Batch: 680-93682 Instrument ID: No Equipment Assigned
Client Matrix: Solid Prep Batch: NIA Lab File ID: NIA
Dilution: 1.0 Initial Weight/Volume: 50 mL
Date Analyzed: 1211412007 1133 Final Weight/Volume: 50 mL
Date Prepared: NIA
Date Leached: 12113/2007 1613 Leachate Batch: 680-93680
MSD Lab Sample ID: 640-14341-25 Analysis Batch: 680-93682 Instrument ID: No Equipment Assigned
Client Matrix: Solid Prep Batch: NIA Lab File ID: NIA
Dilution: 1.0 Initial Weight/Volume: 50 mL
Date Analyzed: 12/14/2007 1133 Final WeightlVolume: 50 mL
Date Prepared: NIA
Date Leached: 12/1312007 1613 Leachate Batch: 680-93680
% Rec.
Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual
Fluoride-S 62 76 75 - 125 21 30 F
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 149 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank - Batch: 680-93684
Lab Sample ID: MB 680-9368111-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 1211412007 1324
Date Prepared: N/A
Date Leached: 12113/2007 1617
Analysis Batch: 680-93684
Prep Batch: NIA
Units: mglKg
Leachate Batch: 680-93681
Analyte Result
Fluoride-S <4.0
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93684
LCS Lab Sample ID: LCS 680-9368112-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
LCSD Lab Sample ID
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Solid
1.0
12/1412007 1324
NIA
12/1312007 1617
LCSD 680-9368113-A
Solid
1.0
12114/2007 1324
NIA
12/13/2007 1617
Analyte
Fluoride-S
Analysis Batch: 680-93684
Prep Batch: NIA
Units: mg/Kg
Lear-hate Batch: 680-93681
Analysis Batch: 680-93684
Prep Batch: NIA
Units: mg/Kg
Leachate Batch: 680-93681
% Rec.
LCS LCSD Limit
96 100 75 - 125
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 150 of 167
Jab Number: 640-14341-1
Method: 340.2
Preparation: NIA
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 50 mL
Final WeightNolume: 50 mL
Method: 340.2
Preparation: NIA
RL
4.0
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 50 mL
Final WeightNolume: 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 50 mL
Final WeightNolume: 50 mL
RPD RPD Limit LCS Qual LCSD Qual
4 30
12/21/2007
Quality Control Results
Client: Environmental Services, Inc. Jab Number: 640-14341-1
Matrix Spike/ Method: 340.2
Matrix Spike Duplicate Recovery Report - Batch: 680-93684 Preparation: NIA
MS Lab Sample ID: 640-14341-17 Analysis Batch: 680-93684 Instrument ID: No Equipment Assigned
Client Matrix: Solid Prep Batch: NIA Lab File ID: NIA
Dilution: 1.0 Initial WeightlVolume: 50 mL
Date Analyzed: 12/14/2007 1324 Final Weight/Volume: 50 mL
Date Prepared: NIA
Date Leached: 1211312007 1617 Leachate Batch: 680-93681
MSD Lab Sample ID: 640-14341-17 Analysis Batch: 680-93684 Instrument ID: No Equipment Assigned
Client Matrix: Solid Prep Batch: NIA Lab File ID: NIA
Dilution: 1.0 Initial WeighUVolume: 50 mL
Date Analyzed: 12/14/2007 1324 Final Weight/Volume! 50 mL
Date Prepared: NIA
Date Leached: 12113/2007 1617 Leachate Batch: 680-93681
% Rec.
Analyte MS MSD Limit RPD RPD Limit MS Qual MSD Qual
Fluoride-S 56 55 75 - 125 1 30 F F
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 151 of 167 12/21/2007
Client: Environmental Services, Inc.
Method Blank - Batch: 680-93323
Lab Sample ID: MB 680-9332311-B
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 1211412007 0511
Date Prepared: 12/1212007 1300
Analyte Result
Cyanide, Amenable <0.50
Cyanide, Total <0.50
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93323
Analysis Batch: 680-93525
Prep Batch: 680-93323
Units: mg/Kg
Qual
LOS Lab Sample ID: LOS 680-9332312-B Analysis Batch: 680-93525
Client Matrix: Solid Prep Batch: 680-93323
Dilution: 1.0 Units: mg/Kg
Date Analyzed: 12114/2007 0512
Date Prepared: 12/12/2007 1300
LCSD Lab Sample ID: LCSD 680-9332313-B
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/1412007 0513
Date Prepared: 12/1212007 1300
Analyte
Analysis Batch: 680-93525
Prep Batch: 680-93323
Units: mg1Kg
% Rec.
LCS LCSD Limit
Cyanide, Total 102 99 85 - 115
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 152 of 167
Quality Control Results
Job plumber: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightfVolume: 10.00 g
Final Weight/Volume: 200 mL
Method: 9012A
Preparation: 9012A
RL
0.50
0.50
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.00 g
Final Weight/Volume: 200 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightfVolume: 10.00 g
Final WeightAlofume: 200 mL
RPD RPD Limit LOS Qual LCSD Qual
3 30
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93323
MS Lab Sample ID: 640-14341-1
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12114/2007 0515
Date Prepared: 12112/2007 1300
Analysis Batch: 680-93525
Prep Batch: 680-93323
MSD Lab Sample ID: 640-94341-1
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12114/2007 0516
Date Prepared: 12112/2007 1300
Analyte
Cyanide, Total
Analysis Batch: 680-93525
Prep Batch: 680-93323
% Rec.
MS MSD Limit RPD
107 108 85-1115 1
Calculations are performed before rounding to avoid round-off errors in calculated results.
Job Number: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighiNolume: 10.02 g
Final Weight,/Volume: 200 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.02 g
Final WeightfVolume: 200 mL
RPD Limit MS Qual MSD Qual
30
TestAmerica Tallahassee Page 153 of 167 12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93479
Lab Sample ID: MB 680-93479/1-B
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 1211712007 0839
Date Prepared: 12/13/2007 1201
Analysis Batch: 680-93723
Prep Batch: 680-93479
Units: mg/K9
Analyte Result
Cyanide, Amenable X0.50
Cyanide, Total X0.50
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93479
LCS Lab Sample ID: LCS 680-9347912-B Analysis Batch: 680-93723
Client Matrix: Solid Prep Batch: 680-93479
Dilution: 1.0 Units: mglKg
Date Analyzed: 12/1712007 0839
Date Prepared: 12/1312007 1201
LCSD Lab Sample ID
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
LCSD 680-9347913-6
Solid
1.0
12/1712007 0840
12/1312007 1201
Analysis Batch: 680-93723
Prep Batch: 680-93479
Units: mglKg
% Rec.
LCS LCSD Limit
Cyanide, Total 103 104 85 - 115
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 154 of 167
Job Number: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.00 g
Final Weight/Volume: 200 mL
Method: 9012A
Preparation: 9012A
RL
0.50
0.50
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 10.00 g
Final Weight/Volume: 200 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 10.00 g
Final WeightNolume: 200 mL
RPD RPO Limit LCS Qual LCSD Qual
1 30
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Matrix Spike!
Matrix Spike Duplicate Recovery Report - Batch: 680-93479
MS Lab Sample ID: 640-14341-11
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/17/2007 0843
Date Prepared: 12113/2007 1201
Analysis Batch: 680-93723
Prep Batch: 680-93479
MSD Lab Sample ID: 640-14341-11
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12117/2007 0844
Date Prepared: 1211312007 1201
Analyte
Cyanide, Total
Analysis Batch: 680-93723
Prep Batch: 680-93479
% Rec.
MS MSD Limit RPD
114 113 85-1115 0
Calculations are performed before rounding to avoid round-off errors in calculated results.
Job Number: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.04 g
Final Weight/Volume: 200 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.04 g
Final Weight/Volume: 200 mL
RPD Limit MS Qual MSD Qual
30
TestAmericaTallahassee Page 155 of 167 12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch. 680-93765
Lab Sample ID: MB 680-9376511-B
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 1211812007 1311
Date Prepared: 1211712007 1132
Analyte Result
Cyanide, Amenable <0.50
Cyanide, Total <0.50
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93765
Analysis Batch: 680-93982
Prep Balch: 680-93765
Units: mg/Kg
Qual
LCS Lab Sample ID: LCS 680-93765/2-B Analysis Batch: 680-93982
Client Matrix: Solid Prep Batch: 680-93765
Dilution: 1.0 Units: mg/Kg
Date Analyzed: 12/18/2007 1311
Date Prepared: 1211712007 1132
LCSD Lab Sample ID: LCSD 680-9376513-B
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12118/2007 11311
Date Prepared: 12117/2007 1132
Analyte
Analysis Batch: 680-93982
Prep Batch: 680-93765
Units: mg/Kg
% Rec.
LCS LCSD Limit
Cyanide, Total 96 96 85 - 115
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 156 of 167
Quality Control Results
Job Number: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.00 g
Final WeightNolume: 200 mL
Method: 9012A
Preparation: 9012A
RL
0.50
0.50
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 10.00 g
Final Weight/Volume: 200 mL
Instrument ID; No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 10.00 g
Final Weight/Volume: 200 mL
RPD RPD Limit LCS Qual LCSD Qual
1 30
12/21/2007
Quality Control Results
Client: Environmental Services, inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93765
MS Lab Sample ID; 640-14341-21
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 1211812007 1311
Date Prepared: 12117/2007 1132
Analysis Batch: 680-93982
Prep Batch: 680-93765
MSD Lab Sample ID: 640-14341-21
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12118/2007 1311
Date Prepared: 12/17/2007 1132
Analyte
Cyanide, Total
Analysis Batch: 680-93982
Prep Batch: 680-93765
% Rec.
MS MSD Limit RPD
100 107 85 - 115 7
Calculations are performed before rounding to avoid round-off errors in calculated results.
Job Number: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.04 g
Final Weight/Volume: 200 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 10.04 g
Final Weight/Volume: 200 mL
RPD Limit MS Qua] MSD Qual
30
TestAmerica Tallahassee Page 157 of 167 12/21/2007
Client: Environmental Services, Inc.
Method Blank -Batch: 680-93847
Lab Sample ID: MB 680-9384711-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 1211812007 1311
Date Prepared: 12/1812007 0646
Analysis Batch: 680-93983
Prep Batch: 680-93847
Units: mg/L
Analyte Result
Cyanide, Amenable <0.010
Cyanide, Total <0.010
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93847
LCS Lab Sample ID: LCS 680-9384712-A Analysis Batch: 680-93983
Client Matrix: Water Prep Batch: 680-93847
Dilution: 1.0 Units: mg1L
Date Analyzed: 12/18/2007 1311
Date Prepared: 12/1812007 0646
LCSD Lab Sample ID
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Analyte
LCSD 680-9384713-A
Water
1.0
12/1812007 1311
12/1812007 0646
Analysis Batch: 680-93983
Prep Batch: 680-93847
Units: mg/L
% Rec.
LCS LCSD Limit
Cyanide, Total 96 94 85 - 115
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results,
TestAmerica Tallahassee Page 158 of 167
Quality Control Results
Job Number: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 50 mL
Final WeightNolume: 50 mL
Method: 9012A
Preparation: 9012A
RL
0.010
0.010
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 50 mL
Final Weight/Volume: 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 50 mL
Final Weight/Volume: 50 mL
RPD RPD Limit LCS Qual LCSD Qual
2 20
12/21/2007
Client: Environmental Services, Inc.
Duplicate - Batch: 680-93847
Lab Sample ID: 640-14341-29
Client Matrix: Water
Di4ution: 1.0
Date Analyzed: 12118/2007 1311
Date Prepared: 12118/2007 0646
Analysis Batch: 680-93983
Prep Batch: 680-93847
Units: mg1L
Analyte
Cyanide, Amenable
Cyanide, Total
Sample Result/Qual
<0.010
<0.010
Quality Control Results
Job Number: 640-14341-1
Method: 9012A
Preparation: 9012A
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 50 mL
Final Weight/Volume: 50 mL
Result RPD Limit
<0.010
0.000830 NC 20
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 159 of 167
Qual
12/21/2007
Quality Control Results
Client: Environmental Services, Inc,
Method Blank -Batch: 680-93191
Lab Sample ID: MB 680-9319111-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/11/2007 1226
Date Prepared: 12111/2007 0629
Analyte Result
Cyanide, Weak Acid Dissociable <0.50
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93191
Analysis Batch: 680-93253
Prep Batch: 680-93191
Units: mg/Kg
LCS Lab Sample ID: LCS 680-9319112-A Analysis Batch: 680-93253
Client Matrix: Solid Prep Batch: 680-93191
Dilution: 1.0 Units: mWK9
Date Analyzed: 12/1112007 1226
Date Prepared: 12/1112007 0629
LCSD Lab Sample ID: LCSD 680-9319113-A Analysis Batch: 680-93253
Client Matrix: Solid Prep Batch: 680-93191
Dilution: 1.0 Units: mglKg
Date Analyzed: 12/1112007 1226
Date Prepared: 12/1112007 0629
% Rec.
Analyte LCS LCSD Limit
Cyanide, Weak Acid Di ssociable 105 101 75 - 125
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 160 of 167
Job Number: 640-14341-1
Method: SM 4500 CN I
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 1.00 g
Final Weight/Volume: 50 mL
RL
0.50
Method: SM 4500 CN I
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File 1D: NIA
Initial WeightNolume: 1.01 g
Final Weight/Volume: 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: /VIA
Initial Weight/Volume: 1.01 g
Final Weight/Volume: 50 mL
RPD RPD Limit LCS Qual LCSD Qual
5 30
12/21/2007
Client: Environmental Services, Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93191
MS Lab Sample ID: 640-14341-2 Analysis Batch: 680-93253
Client Matrix: Solid Prep Batch: 680-93191
Dilution: 1.0
Date Analyzed: 12/1112007 1226
Date Prepared: 12111/2007 0629
MSD Lab Sample ID: 640-14341-2 Analysis Batch: 680-93253
Client Matrix: Solid Prep Batch: 680-93191
Dilution: 1.0
Date Analyzed: 12111/2007 1226
Date Prepared: 12111/2007 0629
% Rec.
Analyte MS MSD Limit
Cyanide, Weak Acid Dissociable 94 92 75 - 125
Duplicate - Batch: 680-93191
Lab Sample ID: 640-14341-12 Analysis Batch: 680-93253
Client Matrix: Solid Prep Batch: 680-93191
Dilution: 1.0 Units: mg/Kg
Date Analyzed: 12/11/2007 1226
Date Prepared: 12111!2007 0629
Analyte Sample ResulUQual
Cyanide, Weak Acid Dissociable <1.6
Result
0.242
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 161 of 167
Quality Control Results
Job Number: 640-14341-1
Method: SM 4500 CN I
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 1.02 g
Final WeightNolume: 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 1.03 g
Final Weight/Volume: 50 mL
RPD RPD Limit MS Qual MSD Qual
4 30
Method: SM 4500 CN I
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 1.02 g
Final Weight/Volume: 50 ML
RPD Limit Qual
NC 30
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank -Batch; 680-93200
Lab Sample ID: MB 680-9320011-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/1112007 1234
Date Prepared: 12111/2007 0834
Analyte Result
Cyanide, Weak Acid Dissociable <0.50
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93200
Analysis Batch: 680-93256
Prep Batch: 680-93200
Units: mglK9
Qual
LCS Lab Sample ID: LCS 680-9320012-A Anaiysis Batch: 680-93256
Client Matrix: Solid Prep Batch: 680-93200
Dilution: 1.0 Units: mg/Kg
Date Analyzed: 12/1112007 1234
Date Prepared: 1211112007 0834
LCSD Lab Sample ID: LCSD 680-9320013-A
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/1112007 1234
Date Prepared: 12/11/2007 0834
Analyte
Analysis Batch: 680-93256
Prep Batch: 680-93200
Units: mglKg
% Rec.
LCS LCSD Limit
Cyanide, Weak Acid Dissociable 100 102 75 - 125
Calculations are performed before rounding to avoid round-off errors in calculated results.
7estAmerica "Tallahassee Page 162 of 167
Job Number: 640-14341-1
Method: SM 4500 CN i
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 1.00 g
Final WeightNolume: 50 mL
RL
0.50
Method: SM 4500 CN I
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 1.01 g
Final WeightNolume: 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 1.01 g
Final WeightNolume: 50 mL
RPD RPD Limit LCS Qual LCSD Qual
2 30
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 680-93200
MS Lab Sample ID: 640-14341-21
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12111/2007 1234
Date Prepared: 12/1112007 0834
Analysis Batch: 680-93256
Prep Batch: 680-93200
MSD Lab Sample ID: 640-14341-21
Client Matrix: Solid
Dilution: 1.0
Date Analyzed: 12/1112007 1234
Date Prepared: 12/1112007 0834
Analyte
Cyanide, Weak Acid Dissociable
Analysis Batch: 680-93256
Prep Batch; 680-93200
% Rec.
MS MSD Limit RPD
103 99 75 - 125 5
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 163 of 167
Job Number: 640-14341-1
Method: SM 4500 CN I
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 1.00 g
Final WeighWolume: 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume: 1.01 g
Final Weight/Volume: 50 mL
RPD Limit MS Qua] MSD Qual
30
12/21/2007
Quality Control Results
Client: Environmental Services, Inc.
Method Blank - Batch: 680-93202
Lab Sample ID: MB 680-9320211-A
Client Matrix: Water
Dilution; 1.0
Date Analyzed: 12/1112007 1236
Date Prepared: 12/11/2007 0836
Analyte Result
Cyanide, Weak Acid Dissociable <0.010
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-93202
Analysis Batch: 680-93257
Prep Batch: 680-93202
Units: mg/L
Qual
LCS Lab Sample ID: LCS 680-9320212-A Analysis Batch: 680-93257
Client Matrix: Water Prep Batch: 680-93202
Dilution: 1.0 Units: mg/L
Date Analyzed; 12/11/2007 1236
Date Prepared: 1211112007 0836
LCSD Lab Sample ID: LCSD 680-93202/3-A
Client Matrix: Water
Dilution: 1.0
Date Analyzed: 12111/2007 1236
Date Prepared: 12/1112007 0836
Analyte
Analysis Batch: 680-93257
Prep Batch: 680-93202
Units: mg/L
% Rec.
LCS LCSD Limit
Cyanide, Weak Acid Dissociable 100 97 85 - 115
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tallahassee Page 164 of 167
Job Number: 640-14341-1
Method: SM 4500 CN i
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial Weight/Volume: 50 mL
Final WeightNolume: 50 mL
RL
0.010
Method: SM 4500 CN I
Preparation: SM 4500 CN I
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeighWolume: 50 mL
Final Weight/Volume: 50 mL
Instrument ID: No Equipment Assigned
Lab File ID: NIA
Initial WeightNolume; 50 mL
Final Weight/Volume: 50 ML
RPD RPD Limit LCS Qual LCSD Qual
3 30
12/21/2007
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