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HomeMy WebLinkAboutWI0400093_Complete File - Historical_20100114Material Safety Data Sheet Magnesium hydroxide MSDS Section 1: Chemical Product and Company Identification Product Name: Magnesium hydroxide Contact Information: Catalog Codes: SLM2437, SLM3811. SLM1663 CAS#: 1309-42-8 RTECS: OM3570000 TSCA: TSCA 8(b) inventory: Magnesium hydroxide CI#: Not available. Synonym: Chemical Name: Not available. Chemical Formula: Mg(OH)2 Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com CHEMTREC (24HR Emergency Telephone), call: 1-80OA24-9300 International CHEMTREC, call: 1-703-527-3887 For non -emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name CAS # % by Weight Magnesium hydroxide 1309-42-8 100 Toxicological Data on Ingredients: Not applicable. Section 3: Hazards Identification Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. I Section 4: First Aid Measures I Eye Contact: Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Serious Skin Contact: Not available. Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious Inhalation: Not available. Ingestion: Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. if the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Serious Ingestion: Not available. I Section 5: Fire and Explosion Data I Flammability of the Product: Non -Flammable. Auto -Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: Not applicable. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: Not applicable. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available. I Section 6: Accidental Release Measures I Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section l: Handling and Storage i Precautions: No specific safety phrase has been found applicable for this product. Storage: No specific storage is required. Use shelves or cabinets sturdy enough to bear the weight of the chemicals. Be sure that it is not necessary to strain to reach materials, and that shelves are not overloaded. Section 8: Exposure Controls/Personal Protection Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit, p. 2 Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivale,t. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Not available. Section 9: Phvsical and Chemical Properties Physical state and appearance: Solid. Odor: Not available. Taste: Not available. Molecular Weight: 58.32 glmole Color: Not available. pH (1% solnlwater): Not available. Boiling Point: Not available. Melting Point: Decomposes. Critical Temperature: Not available. Specific Gravity: 2.36 (Water = 1) Vapor Pressure: Not applicable. Vapor Density: Not available. Volatility: Not available. Odor Threshold: Not available. WaterlOil Dist. Coeff.: Not available. tonicity (in Water): Not available. Dispersion Properties: Not available, Solubility: Very slightly soluble in cold water. Section 10: Stability and Reactivity Data Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Not available. Incompatibility with various substances: Not available. Corrosivity: Non -corrosive in presence of glass. Special Remarks on Reactivity: Not available. Special Remarks on Corrosivity: Not available. Polymerization: No. Section 11: Toxicological Information P. 3 Routes of Entry: Not available. Toxicity to Animals: LD50: Not available. LC50: Not available. Chronic Effects on Humans: Not available. Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: Not available. Special Remarks on other Toxic Effects on Humans: Not available. Section 12: Ecolonical Information Ecotoxicity: Not available. BOD5 and COO: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product. Special Remarks on the Products of Biodegradation: Not available. Section it Disl)osal Considerations I Waste Disposal: Section 14: Transport Information DOT Classification: Not a DOT controlled material (United States). Identification: Not applicable. Special Provisions for Transport: Not applicable. I Section 15: Other Regulatory Information I Federal and State Regulations: TSCA $(b) inventory: Magnesium hydroxide Other Regulations: Not available.. Other Classifications: WHMIS (Canada): Not controlled under WHMIS (Canada). DSCL (EEC): This product is not classified according to the EU regulations. HMIS (U.S.A.): Health Hazard: f Fire Hazard: 0 Reactivity: 0 p. 4 Personal Protection: E National Fire Protection Association (U.S.A.): Health: 1 Flammability: 0 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab coat. Dust respirator. Be sure to use an approvedlcertified respirator or equivalent. Safety glasses. I Section 16: Other Information I References: Not available. Other Special Considerations: Not available Created: 10/10/2005 08:22 PM Last updated: 11 /01 /2010 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab. cam has been advised of the possibility of such damages. P. 5 Material Safety Data Sheet Sodium hydroxide MSDS I Section 1: Chemical Product and Company Identification I Product Name: Sodium hydroxide Catalog Codes: SLS3298, SLS1081, SLS2503, SLS3925, SLS1705 CAS#: 1310-73-2 RTECS: WB4900000 TSCA: TSCA 8(b) inventory: Sodium hydroxide CI#: Not available. Synonym: Caustic Soda Chemical Name: Sodium Hydroxide Chemical Formula: NaOH Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non -emergency assistance, tail: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name CAS # % by Weight Sodium hydroxide 1310-73-2 100 Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available. I Section 3: Hazards Identification I Potential Acute Health Effects: Very hazardous in case of skin contact {corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, of inhalation. The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over -exposure can produce lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. TERATOGENIC. EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to mucous membranes, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage. P. 1 i Section 4: First Aid Measures I Eye Contact: Check for and remove any contact lenses. In case of contact, immediately bush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Gold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti -bacterial cream. Seek medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swaflowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious Ingestion: Not available. I Section 5: Fire and Explosion Data Flammability of the Product: Non-flammable. Auto -Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable, Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: metals Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Slightly explosive in presence of heat, Fire Fighting Media and Instructions: Not available Special Remarks on Fire Hazards: sodium hydroxide + zinc metal dust causes ignition of the latter. Under proper conditions of temperature, pressure and state of division, it can ignite or react violently with acetaldehyde, ally alcohol, allyl chloride, benzene-1,4-diol, chlorine trifluoride, 1,2 dichlorethylene, nitroethane, nitromethane, nitroparafFins, nitropropane, cinnamaldehyde, 2,2-dichloro-3,3-dimethyibutane. Sodium hydroxide in contact with water may generate enough heat to ignite adjacent combustible materials. Phosphorous boiled with NaOH yields mixed phosphines which may ignite spontanously in air. sodium hydroxide and cinnamaldehyde + heat may cause ignition. Reaction with certain metals releases flammable and explosive hydrogen gas. Special Remarks on Explosion Hazards: Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonate prepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, under vacuum distillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrafuren, which can contain peroxides, can p. 2 cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetra hydrobarate liberate hydrogen explosively at 230-270 deg, C. Sodium Hydroxide reacts with sodium salt of trichloropnenoi + methyl alcohol + trichlorobenzene + heat to cause an explosion. I Section 6: Accidental Release Measures I Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. if necessary: Neutralize the residue with a dilute solution of acetic acid. Large Spill: Corrosive solid. Stop leak if without risk. Do not get water inside container. D❑ not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. I Section 7: Handling and Storage Precautions: Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture. Storage: Keep container tightly closed. steep container in a cool, well -ventilated area. Hygroscopic. Deliquescent. I Section 8: Exposure Controls/Personal Protection Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection: Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approvedlcertified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: STEL: 2 (mglrn3) from ACGIH (TLV) [United States] TWA: 2 C E I L : 2 (mglm3) from ❑SHA (PEL) [United States] CELL: 2 (mg/ m3) from NIOSHConsuit local authorities for acceptable exposure limits. Section 9: Physical and Chemical Properties Physical state and appearance: Solid. (Deliquescent solid.) Odor: Odorless. Taste: Not available. Molecular Weight: eta glmole Color: White. p. 3 PH 0% soln1water): 13.5 [Basic.] Boiling Point: 1388'C (2530,4°F) Melting Point: 323°C (613.4'F) Critical Temperature: Not available. Specific Gravity: 2.13 (Water = 1) Vapor Pressure: Not applicable. Vapor density: Not available. Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available, lonicity (in Water): Not available. Dispersion Properties: See solubility in water, Solubility: Easily soluble in cold water. Section 1 U: Stability and Reactivity Data Stability: The product is stable. Instability Temperature: Not available, Conditions of Instability: Incompatible materials, moisture, moist air Incompatibility with various substances: Highly reactive with metals. Reactive with oxidizing agents, reducing agents, acids, alkalis, moisture. Corrosivity: Not available. Special Remarks on Reactivity: Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must be used for this process. Sodium hydroxide solution and octanol + diborane during a work -up of a reaction mixture of oxime and diborane in tetrahyrofuran is very exothermic, a mild explosion being noted on one occassion. Reactive with water, acids (mineral, non -oxidizing, e,g. hydrochloric, hydrofluoric acid, muriatic acid, phosphoric), acids (mineral, oxidizing e.g, chromic acid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, foraldehyde), carbamates (e.g. carbanolate, carbofuran), esters (e.g. butyl acetate, ethyl acetate, propyl formate), halogenated organics (dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (acetone, acetophenone, MEK, MIBK), acid chlorides, strong bases, strong oxidizing agents, strong reducing agents, flammable liquids, powdered metals and metals (Le aluminum, tin, zinc, hafnium, raney nickel), metals (alkali and alkaline e.g. cesium, potassium, sodium), metal compounds (toxic e.g. berylium, lead acetate, nickel carbony#, tetraethyl lead), mitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), nitro compounds (organic e.g, nitrobenzene, nitromethane), acetic anhydride, chlorohydrin, chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrosulfuric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide, chloroethanol, chloroform -methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reacts with formaldehyde hydroxide to yield formic acid, and hydrogen. Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture, Polymerization: Will not occur. I Section 11: Toxicologlcal Information I Routes of Entry: Absorbed through skin. dermal contact. Eye contact, Inhalation. Ingestion. p, 4 Toxicity to Animals: LD50: Not available, LC50: Not available. Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: mucous membranes, upper respiratory tract, skin, eyes. Other Toxic Effects on Humans: Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (corrosive), of ingestion, . Special Remarks on Toxicity to Animals: Lowest Published Lethal Dose: LDL (Rabbit) - Route: Oral; Dose: 500 mg/kg Special Remarks on Chronic Effects on Humans: May affect genetic material. Investigation as a mutagen (cytogenetic analysis) Special Remarks on other Toxic Effects on Humans: Section 12: Ecological Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic. Special Remarks on the Products of Biodegradation: Not available. Section 13: Disposal Considerations Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14: Transport Information f DOT Classification: Class 8: Corrosive material Identification:: Sodium hydroxide, solid UNNA: 1823 PG: II Special Provisions for Transport: Not available. Section 15: Other Regulatory Information Federal and State Regulations: Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide New York release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide Pennsylvania RTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxide Louisiana spill reporting: Sodium hydroxide California Director's List of Hazardous Substances: Sodium hydroxide TSCA 8(b) inventory: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6 kg) Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. p• 5 Other Classifications: WHMIS (Canada): CLASS E: Corrosive solid. DSCL (EEC): R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37139- Wear suitable gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.): Health Hazard: 3 Fire Hazard: 0 Reactivity: 2 Personal Protection: j National Fire Protection Association (U.S.A.): Health: 3 Flammability: 0 Reactivity: 1 Specific hazard: Protective Equipment: Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. Section 16: Omer Information - I References: Not available. Other Special Considerations: Not available. Created: 10/09/2005 06:32 PM Last Updated: 11/0112010 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab. com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages. Material Safety Data Sheet May be used to comply with OSHA 's Hazard Communication Standard, 29 CFR 1910 1200. Standard must be consulted for specific requirements. U.S. Department of Labor Occupational Safety and Health Administration (Non -Mandatory Form) Form Approved OMB No. 1218-0072 IDENTITY (aS Used on Labe! and LiSt) I /Vote: E31ank spaces are not permrttetl. tr any item is not ABC � (Anaerobic 6ioChem) applicable or no information is available, the space most be marked to indicate that. Man u ac urer s name REDOX TECH, LLC L mergency I a ep hone �N um 0 er 8o6-460-0 30 ress um er, nee . City. State and ZIP Gode eleprione NurntieF Tof InIoTmation 919-460-0330 112 Pheasant Wood Court, Morrisville, NC 27560 Date Prapar MAY 2004 gna ure of vreparer op tuna Section II —Hazardous IngretllentsllGentity Information Hazafd o u s C ompononIs (S peci is Chemical Identity, Common Name[s}) OSHA PEL ACGIH TLV Other Limits Recommended % (optional) Mixture of Lactate salts NA NA (0 to 60%) Lactic acid esters NA NA {0 to 98.5%) Phosphate buffer NA NA (0 to 0A%) Ferrous Iron NA NA (0 to 0.1 %) Fatty Acids NA NA (0 to 5%) Section III—PSysicalinhemical Characteristics of ing Point > 100 C Sper;fkc Gravity (H_,O = i) 1.04 Vapor Pressure mm s Lactic acid esters 2.7 mbar, 20 C pH 6.0 to 8.0 vapor Density - Lactic acid esters 3.8 vapors Ion 1191B (Butyl ce a e = No information solubility in water Fully soiuble and miscible Appearance and Oder Light yellow to colorless liquid, slight to mild, characteristic odor Section TV —Fire and Explosion Hazard Data Lactic acid esters: 61 aC (150 2719, closed cup) I Lactic acid esters- 11.5% (100 °C) 111.4% (100 °C) Extingui0ing1916dia water spray, carbon dioxide, dry powder, AFFF, foam Special ire Fignling Proceaures Standard procedures for chemical fires unusual rre and LXplosion Hazards Thermal decomposition can release irritating gases and vapors (epro uce locallye;k Section V—Reactivity Data presence of water, acids and bases u�wuiNou�inq "cr" w'—j Strong oxidants Hazardous Decomposition or uypcoa ucts no known Routesj OT Lntry rn a a ion. Yes, esters only z5KIrl J Yes ingestion Yes Healln hazards fAcare and urwonic)Acid esters: Risk of irritation to eyes. Irritating to respiratory system. May degrease skin. arcinogenicily None No onograp s. No eg U1 a . No Signs and symptoms or txposure Red irritated skin. May cause light-headedness when used in poorly ventilated area without proper vapor mask.. edleal Conditions Generally Aggravated by Exposure Persons susceptible or sensitive to eye and respiratory irritation mergency and Frstrace ores Inhalation: Move to fresh air; Skin: Wash skin immediately with water. Eyes: Flush with water for at least 15 minutes, consult physician; Ingestion: drink water and consult physician. Section recau Ions tor Safe Handling and Use Use safety glasses and latex or nitrile gloves. Work in well ventilated area. as a DISPGsal MethodABC can be disposed as waste water or Iandflied when in compliance with local regulations Precautions to Be -Taken in Handling an onng fay he F Iammable- ❑o not store near ignition sources or at elevated temperatures. Avoid longs storage times, will break down to innocuous products er Precaullons Wear PPE when handling and keep containers tightly closed when stared. Section VII—Control Measures Respiratory Protection (specify yDe) If ventilation inadequate or in confined space, use respirator with filter (DIN 141) en r ion Loralx aus Acid esters have fow vapor pressure (2.7 bpecial Ensure fumes can not reach ignition source mbar at 20°C) Standard HVAC conditions typically adequate mecna"PE;al tGeneraFloor or stand fans ulner ro ec a MiNes PVA, nitrite or latex ye ProTection Safety glasses with side shields VvorvjHygienic FrAclices Do not eat, drink or smoke while handling. Remove/wash contaminated clothing before reuse. Shag Env+ronrrental &-nfrastructure, Inc. Princess Scad Lawrenceville. NJ 08648 609 895.5340 pax: 609,895 1858 aaw Shaw Environmental & Infrastructure, Inc. January 14, 2010 Thomas Slusser NCOENR DWQ APS UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Re. RTB-1 bacterial culture Clear Mr. Slusser, I am sending you this note to confirm that the dechlorinating bacterial cultures BAC-9 marketed by EOS Remediation, LLC and RTB-1 marketed by RedoxTech, LLC are in fact the same culture. The culture (originally SDC-9T"4) is distributed under licensing agreements between the two companies and Shaw Environmental, Inc. Under the terrns of the licensing agreements these companies are allowed to re- name the culture to fit their marketing strategies. SOC-9, RTB-1, and BAC-9 are indeed the same culture. The culture is produced in and shipped from our facility. Please feel free to contact me with any questions (609-895-5356; Rob.steffan@shawgrp.com) Sincerely, Robert Steffan, Ph.D. Director. Biotechnology Development and Applications A Shaw Group Company Material Safety Data Sheet Shaw Environmental, Inc. 17 PRINCESS ROAD LA WRENCEVILLE, N.J. 08648 (609) 895-5340 SECTION 1 - MATERIAL IDENTIFICATION AND INFORMATION Material Name: DHC microbial consortium (SDC-9) MSDS #: ENV 1033 Date Prepared: 10/06/2003 Prepared By: Simon Vainberg CAS #: NIA (Not Applicable) Formula #: NIA Material Description: Non -hazardous, naturally occurring non -altered anaerobic microbes and enzymes in a water -based medium. 24 HOUR EMERGENCY RESPONSE PHONE NUMBER (800)424-9300 SECTION 2 - INGREDIENTS Components % OSHA ACGIH OTHER PEL TLV LIMITS Non -Hazardous Ingredients 100 NIA NIA NIA SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: 100°C (water) Specific Gravity (H2O = 1): 0.9 - 1.1 Vapor Pressure a@ 250C: 24 mm Hg (water) Melting Point: 0°C (water) Vapor Density: NIA Evaporation Rate (H2O = 1): 0.9 - 1.1 Solubility in Water: Soluble Water Reactive: No pH: 6.0 - 8.0 Appearance and Odor: Murky, yellow water. Musty odor. MATERIAL SAFETY DATA SHEET FOR DHC consortium (SDC-9) PAGE 2 OF 4 October 6, 2003 SECTION 4 - FIRE AND EXPLOSION HAZARD DATA Flash Point: NIA Flammable Limits: NIA Extinguishing Media: Foam, carbon dioxide, water Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None SECTION 5 - REACTIVITY DATA Stability: Stable Conditions to Avoid: None Incompatibility (Materials to Avoid): Water -reactive materials Hazardous Decomposition Byproducts: None SECTION 6 - HEALTH HAZARD DATA HEALTH EFFECTS The effects of exposure to this material have not been determined. Safe handling of this material on a long-term basis will avoid any possible effect from repetitive acute exposures. Below are possible health effects based on information from similar materials. Individuals hyper allergic to enzymes or other related proteins should not handle. Ingestion: Ingestion of large quantities may result in abdominal discomfort including nausea, vomiting, cramps, diarrhea, and fever. Inhalation: Hypersensitive individuals may experience breathing difficulties after inhalation of aerosols. Skin Absorption: NIA MATERIAL SAFETY DATA SHEET FOR ❑HC consortium (SDC-9) PAGE 3 OF 4 October 6, 2063 Skin Contact: May cause skin irritation. Hypersensitive individuals may experience allergic reactions to enzymes. Eye Contact: May cause eye irritation. FIRST AID Ingestion: Get medical attention if allergic symptoms develop (observe for 48 hours). Never give anything by mouth to an unconscious or convulsing person. Inhalation: Get medical attention if allergic symptoms develop. Skin Absorption: NIA Skin Contact: Wash affected area with soap and water. Get medical attention if allergic symptoms develop. Eye Contact: Flush eyes with plenty of water for at least 15 minutes using an eyewash fountain, if available. Get medical attention if irritation occurs. NOTE TO PHYSICIANS: All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this material may have occurred. SECTION 7 - SPILL. AND LEAK PROCEDURES Reportable quantities (in Ibs of EPA Hazardous Substances): NIA Steps to be taken in case of spill or release: No emergency results from spillage. However, spills should be cleaned up promptly. All personnel involved in the cleanup must wear protective clothing and avoid shin contact. Absorb spilled material or vacuum into a container. After clean-up, disinfect all cleaning materials and storage containers that come in contact with the spilled liquid. Waste Disposal Method: No special disposal methods are required. The material may be sewered, and is compatible with all known biological treatment methods. To reduce odors and permanently inactivate microorganisms, mix 100 parts (by volume) of ❑HC consortium with 1 part (by volume) of bleach. Dispose of in accordance with local, state and federal regulations. MATERIAL SAFETY DATA SHEET FOR DHC consortium (SDC-9) PAGE 4OF4 October 6. 2993 SECTION 8 - HANDLING AND STORAGE Hand Protection- Rubber gloves. Eye Protection: Safety goggles with side splash shields. Protective Clothing: Use adequate clothing to prevent skin contact. Respiratory Protection: Surgical mask. Ventilation: Provide adequate ventilation to remove odors. Storage & Handling: Material may be stored for up to 3 weeks at 2-4'C without aeration. Other Precautions: An eyewash station in the work area is recommended. While the information and recommendations set forth herein are believed to be accurate as of the date hereof, Shaw Environmental, inc. MAKES NO WARRANTY WITH RESPECT HERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. DOCUMENTS ASSOCIATED WITH THE ORIGINAL PERMIT APPLICATION (MARCH 20, 2008) V. ATTACHMENTS A. HYDROGEOLOGIC DESCRIPTION Regional Geologic Setting The site is located in the Carolina SIate Belt of the Piedmont Physiographic Province. The soil encountered in this area is the residual product of in place chemical weathering of rock presently underlying the site. In general, shallow unconfined groundwater movement within the overlying soils is controlled largely by topographic gradients. Recharge occurs primarily by infiltration along higher elevations and typically discharges into streams or other surface water bodies. The elevation of the shallow water table is transient and can vary with seasonal fluctuations in precipitation. Movement in this water table is generally from higher to lower elevations. The site is located on a flat ridge top which gently slopes to the south and southeast (Figure 1). Site Geology The site is underlain by three distinct lithologic layers. Cross sections were prepared by the former consultant (BPA Environmental & Engineering, Inc.) The location of these cross sections is presented on Figure 2. Cross Sections A -A' to E-E' are presented in Figures 3 to G, respectively. In the vicinity of the plant building, fill material has been estimated to be approximately two to fourteen feet thick. The fill material consists of gravel, silty sand, and coal cinders. The fill material layer, where present, is underlain by a shallow layer of saprolite. Saprolite is the in - place chemical weathering of bedrock beneath the site. This layer ranges from approximately 30 feet thick in the source area to approximately 40 feet thick at the site boundary. The saprolite is underlain by partially weathered rock (PWR). PWR beneath the source area has been estimated to be approximately 35 feet thick and as thick as 140 feet at the site boundary. The PWR is underlain by bedrock which consists primarily of metamorphosed granodiorite or granite. Site Hydrogeology Groundwater of the Piedmont Physiographic Province typically occurs in two hydraulically interconnected zones: the water table and the bedrock aquifers. Shallow and intermediate monitoring wells are screened in the water table aquifer at the site. The water table is considered to be unconfined and is underlain by the bedrock aquifer. For the purposes of this investigation, the unconfined aquifer is described as the shallow and intermediate water table aquifer. The bedrock aquifer is considered to be a semi -confined aquifer, less permeable, and hydraulically connected to the water table aquifer. The deep monitoring wells are screened in the bedrock aquifer. Generally, the site is considered to be a recharge zone for South Buffalo Creek and its tributaries. Water level data for the site is presented in Table I and shown on Figures 7 and 8. Groundwater elevation maps were constructed for the shallow and intermediate water table aquifer. While there is communication between the fractured bedrock and the overlying water table aquifer, groundwater flow in these wells is predominantly determined by the fracture density and orientation, porosity of the material within the fractures, and their connectivity. Consequently, the groundwater flow direction in fractured bedrock is difficult to measure and/or predict. A comparison of seasonal groundwater elevation data recorded between May and October 2006 indicated that the mean seasonal change of groundwater elevations in the shallow monitoring wells at the site was approximately 0.72 feet, approximately 0.69 feet in the intermediate monitoring wells, and approximately 1.21 feet in the deep bedrock wells. The hydraulic conductivity, transmissivity, and specific yield of the aquifer was appropriated from a 72-hour pump test completed in the intermediate aquifer at the Former Burlington Industries site, located at 300 East Meadowview Road which is adjacent to and south of the site. The 72-hour pump test was conducted by Aquaterra, Inc. as part of the RAP prepared for the site. The pump test was conducted in a 6-inch extraction well (MW-7e), which is constructed to a depth of approximately 70 feet bgs. A four -inch stainless steel electrical submersible Grundfos pump was used to pump the aquifer at approximately 18 to 20 gallons per minute. A shallow monitoring well and a deep monitoring well were located adjacent to the extraction well. Several existing monitoring wells were also observed during the test. The data collected from the extraction well was used to determine the hydraulic conductivity and transmissivity of the intermediate aquifer and the drawdown data in the surrounding wells was used to calculate the hydraulic conductivites and transmissivity in the intermediate and bedrock aquifers underlying the site. The hydraulic conductivities were calculated using the Theis Curve matching techniques (Fetter, 1980). The following average hydraulic conductivities are: Intermediate — 295 gpolft2 or 39.44 feet/day Bedrock — 95 gpdit` or 12.7 feet/day The following average transmissivities for the intermediate and bedrock are: Intermediate 5,377 gpolfoot Bedrock 2292 gpolfoot According the USGS, the specific yield is the often same but can be less than the effective porosity. For this reason the effective porosity in the intermediate aquifer is estimated to be approximately 30%. The effective porosity in the bedrock well will be estimated at 0.05% B. INJECTION FLUID COMPOSITION HRCID is a proprietary, environmentally safe polylactic ester specially formulated for slow release of lactic acid upon contact with water in the subsurface environment. Once in place, the HRCS slowly and continuously releases lactic acid. indigenous anaerobic microbes then metabolize the lactic acid generated by the HRC9 and produce hydrogen. Naturally occurring microorganisms capable of reductive dechlorination then use the hydrogen to progressively remove chlorine atoms from chlorinated hydrocarbon contaminants (i.e. convert tetrachloroethene to trichloroethene to dichloroethene to vinyl chloride to ethene). In order to perform the pilot study, an injection permit was obtained from the North Carolina Department of Environment and Natural Resources (NCDENR)-UIC Injection Branch (Permit No. WI0400028, NCDENR letter dated September 16, 2002). Public notice was completed in accordance with ISA NCAC 13C.03060) (NCDENR letter dated April 25, 2002). The Proposed Remedial Action Plan completion Certification form was completed in accordance with 15A NCAC 13C.0306(b)(5)(C) (ECS letter dated April 30, 2002). The HRCS Material Safety Data Sheets are attached. No water supply wells are located within '/ mile from the site. Municipal water at the site will be used for the injection process. C. INJECTION RATIONALE Goals; The goal of injection at the PFG site is to accelerate the biodegradation of chlorinated compounds to non -toxic end products (ethane and ethene) and to provide a chemical barrier at the site boundary. A summary of current and historic groundwater analytical results is included in Table 2. A summary of geochemical parameters is included in Table 3. PCE and TCE concentrations detected in the shallow, intermediate and bedrock wells during the fourth quarter 2006 are shown on Figures 9 through 14. Mr. Evan Kane of the NCDENR requested additional information regarding the injection rationale on February 15, 2005. The response to the additional information request is included in the Appendix for review. On June 4, 2007, ECS resubmitted an injection permit for the use of EOS in the source area and for the use of HRC at the boundary to the Groundwater Protection Unit. In a letter dated June 28, 2007, the Groundwater Protection Unit requested additional information. Based on the additional requested information, Mr. Lee Aiken met with Mr. Peter Pozzo of the Groundwater Protection Unit. Mr. Aiken requested a separation of injection permits which will allow commencement of the HRC injection prior to the EOS injection. A permit for the EOS injection will be submitted under separate cover. In addition Mr. Peter Pozzo of the NCDENR requested a meeting to explain the permit requirements and what information needed to be presented for permit approval. Ms. Carin Kromm and Mr. Mark Brown of ECS, Mr. Lee Aiken of PFG, and Mr. Peter Pozzo and Mr. Qu Qi of the NCDENR UIC Program met on April 17, 2007 to discuss specific issues related to the injection permit. On September 14, 2007 Mr. Randy Cavallier and Mr. Mark Brown of ECS, and Mr. Peter Pozzo and Mr. Qu Qi of the NCDENR UIC Program met to discuss the June 28, 2007 letter. The response to the additional information request is included in the Appendix for review. Reductive Dechlorination HRC(& is used to accelerate the in -situ process biodegradation rates of chlorinated solvents via anaerobic reductive dechlorination processes. The indigenous microorganisms use hydrogen to progressively remove chlorine atoms from chlorinated compounds. Sequential dechlorination occurs from PCE to TCE to dichloroethene (DCE) to vinyl chloride (VC), to ethene. VC will be degraded to ethane as long as the anaerobic/reducing conditions exist. HRC0 slowly releases lactate when hydrated ("food") to the microorganisms residing in the aquifer which then produces the hydrogen. The hydrogen is then available to support the anaerobic conditions which accelerate reductive dechlorination. D. INJECTION PROCEDURE Pilot Study Results and Proposed Injection Procedure A pilot study using HRC9 was completed in November of 2002. HRCO was injected in six injection wells (intermediate and deep wells) located along the site boundary. Information obtained during the pilot study, amended the original injection procedure to allow time between injections in the same well. Injection in the intermediate wells constructed with 30 feet of screen occurred in two 15-foot intervals using straddle packers. For the first injection event, the first phase of injection in the well is followed by a second phase injection approximately one to two days after the first phase injection. Injection of the deep wells constructed with 50 feet of screen occurred in two 25-foot intervals using straddle packers, An average injection rate in the first phase injection of each well was 3.2 Ibslmin. The average injection rate in the second phase injection of each well was 1.2 lbslmin. There was some difficulty with injecting into injection wells IW-3 (intermediate) and IW-6 (deep) and was explained in the field notes as a "tight" formation. After review of the boring logs, it appears that intermediate wells are screened in partially weathered rock and the deep wells are screened in the bedrock. Therefore, the reason for the difficult injection remains unclear. For this project, ECS expects that the injection rates will remain similar to the injection rates observed in the pilot study. For the full scale remediation effort, the manufacturer recalculated their dosage and dose rates based on the movement of the plume over time and increase in concentrations at the border since the pilot study in 2002. The manufacturer now suggests an injection rate of 50 lbslfeet (as shown in the current spread sheet attached) in the intermediate wells, However, the manufacturer considers this rate be too high to inject in one application. Based on the results of the pilot study, HRC® will be injected at a rate of 20 to 25 lbslft in the intermediate wells and 7 lbslft in the bedrock wells at a pressure of less than approximately 150 psi at the wellhead. In order to deliver the amount of product required for treatment of the plume, the HRC@ will be injected in phases approximately 6 months apart. In addition, the pilot study injection wells AV-1 and RV-4 are located approximately 30 feet from injection wells IW-2 and IW-5 and injection wells IW-2 and IW-5 are located approximately 60 feet from injection wells FW-3 and IW-6. Based on the results of the HRC pilot study, the proposed injection wells will be drilled approximately 20 feet apart in the vicinity of the highest concentrations within the plume. The distance will generally increase to approximately 30 feet apart in the lower concentrations on the outer edges of the plume, The proposed treatment area along the barrier wall is approximately 500 linear feet long; therefore, ECS recommended that 38 (19 intermediate and 19 deep) additional injection wells (Plat 1). Injection wells (IW-1 through IW-22 and IW-31 through IW-36) will be installed approximately 20 feet apart in the area with the highest concentrations of TCE. Injection wells (IW-23 through IW-30 and IW-37 through IW-44) will be installed approximately 30 feet apart and located at the two ends of the barrier wall where TCE concentrations are less. The shallow and deep injection well construction details are included in the Appendix. The associated observation wells will be nested together, one shallow and one deep well in the same surface casing (Appendix). Based on the decrease of DO, TCE, PCE and the increase of TOC, the pilot study indicated reducing conditions immediately following HRC8 injection (see Charts in Appendix). It is ECS' opinion that the aquifer will quickly convert to reducing conditions when the entire treatment area is in contact with the injectant, thus beginning the breakdown of chlorinated solvents more effectively. E. MONITORING PLAN For monitoring purposes, the observation wells will consist of two nested well pairs with two wells of different depths in the same boring. A total of 18 additional observation wells (in 9 locations, Plat 1) will be installed approximately 50 feet apart. One nested observation well will have two wells with screened intervals of 25 feet to 35 feet bgs and 45 feet to 55 feet bgs, respectively. The second nested observation well will have two wells with screened intervals of 83 feet to 103 feet bgs and 120 feet to 150 feet bgs, respectively. In order to reduce cost and to not duplicate efforts, existing monitoring wells will be also be used in the observation network. It should be noted that the existing monitoring wells used will not be screened at the same depths as the observation wells, but they will provide concentrations at their specific screened intervals. In the vicinity of monitoring wells MW-22s and MW-23s, OW-51OW-5a and OW-18 and OW-18a will be installed in the intermediate and deeper aquifers, respectively. Monitoring, injection and observation well locations are shown on Plat 1. A Monitoring Plan (Table 4 and Table 5) is attached to this permit application, TABLE 1 SUINMIARY OF HISTORIC AND CURRENT MONITORING WELL .DAI A,4ND DEPTH TO GROUNDWATER MEASUREMENTS Precision Fabrics Group, Inc., Greensboro, North Carolina ECS Project G-6175A Well I.D.ft. Collection Date Depth to Groundwater {ft. TOC} Screened Interval {ft. bgs} Top of Casing Elevation [ft. TOC) Groundwater TOC Elevation () MW-1 10/24/06 30.19 22„37 NM* Nla NINV-2 05/09/06 28.00 '0`35 786.43 758.43 10/24/06 27.21 759.22 MW-3:-,... 05/09/06 28.75 ? l -36 787.70 758.95 10/24/05 2$.26 759.44 A"X-3i 05/09/06 28.50 22-37 787.40 758.90 10/24/06 28.30 759.10 1VINV-6 10/24/06 31.99 90-100 NM* Nla 1VINV-�7 10/24/06 31.99 50-60 NM* Nla MW-8 10/25/06 29.71 50-60 786.95 757.24 _MW-9 05/09/06 27.00 I7-32 786.07 759.07 10/24/06 26.66 759.41 '4IV4'=7T 10/25/06 28.54 17-32 786.22 757.68 MW-12 10/25/06 29.86 18-33 787.07 757.21 MVV713 05/09/06 27.90 50-60 786.86 758.96 10/24/06 27.65 759.21 MW 1.5d 05/09/06 17.95 88-98 776.90 758.95 759.55 10/24/06 17.35 05/09/06 17.85 15-30 776.90 759.05 10/24/06 17.20 759.70 MW-16 10/25/06 19.04 84-99 773.27 754.23 MW-17i . 05/09/06 24.50 70-80 782.28 757.78 10/24/06 23.07 759.21 ININ '-19s 10/25/06 18.47 15-31 773.44 754.97 MW-20 05/09/06 22.40 25-30 775.52 753.12 10/24/06 21.89 753.63 'MIV-201 05/09/06 21.75 60-65 775.59 753.84 10/24/06 21.69 753.90 1INI'-20d 05/09/06 22.20 83-9$ 774.06 751.86 10/24/06 21.95 752.11 M«'-21 05/09/06 19.20 15"30 774.34 755.14 10/25/06 19.98 754.36 MW-21i 05/09/06 22.35 80-100 774,27 751.92 10/25/06 20.39 753.88 MW 21d 05/09/06 20.25 120-150 774.05 753.81 10/25/06 20.39 753.67 TABLE 1 SUMMARY OF HISTORIC AN U t-t'IZREN']' ,LION 1TORLti G %5'ELL DAT. _ . ,.kD DEPTH TO GROUNDWATER MEASUREMENTS Precision Fabrics Group, Inc., Greensboro, North Carolina ECS Project G-6175A '4'+'ell 1.i1. Collection Date Depth to Groundwater (ft. TOC) Screened Interval {ft. hgs} Top of Casing Elevation (ft. TOC) Groundwater Elevation (ft. TOC) A' NY-22d 11/06/02 30.16 95 - 115 781.48 751.32 01/20/03 27.43 754.05 03/31/03 26.37 755.11 06/11/03 24.64 756.84 08/28/03 24.72 756.76 05/09/06 28.65 752.93 10/24/06 28.40 753.08 MW-22f, 11/06/02 29.11 ' -4 - 1 781.35 752.24 01/20/03 26.56 754.79 03/31/03 25.44 755.91 06/10/03 24.20 757.15 08/27/03 23.46 757.89 05/09/06 27.70 753.65 10/24/06 27.32 754.03 AIW-22s. 11/06/02 25.64 18.5 - 33.5 778.13 732.49 01/20/03 23.54 754.59 03/31/03 22.24 755.89 06/11/03 20.30 757.83 08/28/03 19.88 758.25 05/09/06 24.55 753.58 10/24/06 24.31 753.82 MW-23s. 11106J02 ?9.53 20 - 35 782.35 752.82 01 /20Y03 27.47 754.88 03/31/03 26.29 756.06 06/11/03 24,50 757.85 08/28/03 24.01 758.34 05/09/06 NM Nla 10/24/06 27,79 754.56 M'VV-24s 10/24/06 27,72 13-40 ?52.(,1 754.89 ONx-1 11/06/02 29.69 45 - 65 782.37 752.68 01/20/03 27.35 755.02 03/31/03 26.20 756.17 06/10/03 24.85 757.52 08/27/03 24.02 758.35 05/09/06 28.30 754.07 10/24/06 27.87 754.50 TABLE 1 SLM1MARY OF HISTORIC AND a CRRENT MONITORING WELL DAT.. , Is'D DEPTH TO GROUNDWATER MEASUREMENTS Precision Fabrics Group, Inc., Greensboro, North Carolina ECS Project G-6175A Well I.11. Collection Date Depth to Groundwater (ft. TOC) Screened Interval (ft. bgs) Top of Casing Elevation (ft. TOC) Groundwater Elevation (ft. TOC} 0NN'-1 a 1110fi102 29.39 25 _ 31 7R2122 752.83 01/20/03 27.10 755.12 03/31/03 25.94 756.28 06/11/03 24.55 757.67 08/28/03 23.91 758.31 10/24/06 27.51 754.71 11/06/02 27.47 45 - 65 779.81 752.34 01/20/03 25.08 754.73 03/31/03 23.93 755.88 06/10/03 22.16 757.65 08/27/03 21.97 757.84 05/09/06 26.20 753.61 10/24/06 25.91 753.90 OW-2a 11/06/02 27.11 25 - 35 779.57 752.46 01120/03 24.96 754.61 03/31/03 23.79 755.78 06/11/03 23.73 755.84 08/28/03 23,27 756.30 10/24/06 25,81 753.76 OW-3 11/06/02 30.49 120 - 150 782.08 751.59 01/20/03 28.22 753.86 03/31/03 27.05 755.03 06/10/03 28.45 753.63 08/27/03 25.97 756.11 05/09/06 28.65 753.43 10/24/06 28.79 753.29 OW-3a 11/06/02 29.38 83 - 103 781.97 752.59 01 /20Y03 27.47 754.50 03/31/03 26.40 755.57 06/10/03 24.76 757.21 08/27/03 24.51 757.46 1 D'24106 28.24 753.73 OW4 11/06/02 28.11 120 - 150 779.56 751.45 01 /20103 25.95 753.61 03/31/03 24.90 754.66 06/10/03 22.88 756.68 08/27/03 22.95 756.61 05/09/06 27.75 751.81 10/24/06 26.41 753.15 TAB STDMNL4,RY OF IIISTORIC kN_ _ [ RRE'_VT MI ONITOF MEASLT.R Precision Fabrics Group, Inc. ECS Projei Well I.D. Collection Date Depth to Groundwater (ft TOC) Sc OW-4a 11/06/02 27.59 01 /20/03 2497 03/31/03 23.73 06/11/03 22.23 08/28/03 22.14 10/24/06 25.85 IW-1 11/06/02 30.95 10/24/06 28.08 IW-2 11/06/02 29.28 10/24/06 27.46 TW-3 „ :_ _ 11/06/02 28.19 10/24/06 26.70 JW4.:.. 11/06/02 31.76 10/24/06 28.70 IW-5 - 11/06/02 28.95 10/24/06 27.14 IW-6 11/06/02 28.13 10/24/06 26.10 NOTES: MW = Monitoring Well OW = Observation Well TW = Injection Well TOC = Top of Casing NM = Not Measured Nla = Not Applicable * Monitoring Wells top of cas: ft. TOC = Feet below the top of casing TABLE 2 GROUNDWATER ANALYTICAL RESULTS Precision Fabrics Group, Inc. Greensboro, North Carolina ECS Project G-6175A WELL 1D Groundwater Remediation Goals' MW-I MW-2 MW-2 MW-3 Mw-� du MW-3 MW-3i MW-3i MYY " (dup.) MW-6 MW-7 MW-8 MW-8 (dap.) MW-9 MW-9 MW-1I MW-12 Screened Interval(ft.bgs) 33-37 20-35 20-35 21-36 21-36 21-36 22-37 22-37 22-37 90-100 50-60 50-60 50-60 17-32 I7-32 17-32 18-33 Date Sampled t0 WM6 0110P-006 10130✓<tg6 0510912006 511912006 10130C2006 05111912006 10/30/2006 1013012t106 11.0112006 114)1nlf10c, 10125f2006 10/25/2006 05110CD06 IW3012006 10+26Q006 10125120U6 Volatile organic Cum ollml,% ! bl Benzene 1 13QL BQL BQL BQL BQL BQL 3.49 3.62 3.58 BQL BQL BQL BQL BQL BQL BQL BQL Bromodichioromethane NE BQL 1.25 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Sm-Butylbenzene 70 BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL 5.20 BQL BQL BQL Tert-Butylbertzene 70 BQL BQL BQL SQL BQL BQL BQL BQL SQL BQL BQL BQL BQL 8.24 0.70 BQL BQL Carbon tetrachloride 0.3 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Chloroform 70 BQL 11.0 14.5 1.08 1.35 1.57 1.51 2.20 2.09 BQL BQL BQL BQL BQL BQL BQL BQL 1,1-Dichloroethane 70 BQL BQL BQL BQL BQL BQL BQL SQL SQL BQL BQL BQL SQL 1.21 BQL BQL BQL 1,2-Dichloroethane 0.38 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1,1-Dichloroethene 7 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQ1_ BQL 11.2 9.98 1.04 BQL BQL BQL cis-1,2-Dichloroethenc 70 18,000 12.7 BQL BQL BQL BQL 0.590 BQL BQL 610 1,810 BQL BQL 63.0 0.64 BQL BQL trans-1,2-Dichloroethene 100 BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Naphthalene 21 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Tetrachloroethene 0.7 BQL BQL BQL SQL BQL BQL SQL BQL BQL BQL BQL 7.85 4.88 25.7 BQL BQL BQL Toluene 1000 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL 1.1,2-Trichloroethanc 5 BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL Trichloroethene 2.8 21,700 203 232 1.29 2.22 M6 12.6 21.5 19.0 11,400 1,940 1.03 0.85 J 17.3 SQL BQL BQL Vinyl chloride 0.015 BQL BQL BQL B(7L 13L 13L BQL B i. BQ1 BQI_ BQI. BQL. BQI. 1 1.06 BQL BQI. B L Metals { n1) Dissolved Iron NIA BQL BQL BQL BQL BQL 0.117 BQL BQL BQI. BQL BQI. BQL BQL 0.563 BQL BQI- 0.566 Ferrous Iron NIA BQL BQL BQL SQL 1 BQL BQL BQL BQL BQL BQL BQL 1 BQL 1 BQL 0.89 BQL BQL 7.66 Manganese NIA 1.860 0.068 0.094 0.072 0.072 0.533 0.063 0.290 0.309 0AW2 0.105 0.096 0.108 0.990 0.170 U.283 2.970 Innr anics m) Alkalinity -- 210 24.2 28.3 39.9 36.8 33.3 38.9 36.1 39.4 135.0 132.0 81.8 86.9 286 5.7 34.3 113 Carbon Dioxide (CO2) -- 100 106 62.7 79.2 79.2 65.2 70A 66.9 61.0 91.9 98.6 95.0 102.0 52.8 5.85 58.5 127.0 Chloride -- 52.6 74.5 102 214.0 210.0 195 135.0 131 133.0 38.9 27.8 22.4 22.4 8.86 5.79 33.30 14.10 Nitrate Nitrogen 7.26 13.6 11.4 3.6 3.8 5.55 1.34 1,77 1.88 1.84 2.59 2.08 2.78 0.I60 0.244 0.058 0.114 Sulfate -- 83.0 BQL 77 BQL BQL 60.6 BQL 66.8 66A0 80.50 61.40 64.80 62.40 BQL 9.65 72.50 72.50 Sulfide BQL 0.360 0.360 BQL BQL BQL BQL BQL BQL BQL BQL 0.576 0.768 0.720 BQL BQL 0.768 Total Organic Carbon TOC) 4.10 1.14 1 A l 1.61 1.83 2.76 1 1.51 1.64 1 6.39 1.18 3A0 BQL 1.67 1.52 2.43 1.30 1.17 or anics - hferabolic Acids (m) Acetic acid -- NA NA NA NA NA NA NA NA NA NA NA NS NA NA NA NA NA Butyric acid NA NA NA NA NA NA NA NA NA NA NA NS NA NA NA NA NA Lactic acid NA NA NA NA NA NA NA NA NA NA NA NS NA NA NA NA NA Pr ionic acid NA NA NA NA NA NA NA NA NA NA NA NS NA NA NA NA NA Pyruvic acid NA NA NA NA NA NA NA NA NA NA NA NS NA NA NA NA NA McMane. EMone. Ethcpw 1p. bl Ethane NA NA NA NA NA NA NA NA NA NA NA NS NA NA NA NA NA Fthene NA NA NA NA NA NA NA NA NA NA NA NS NA NA NA NA NA Methane NA NA NA NA I NA NA NA NA NA NA NA NS NA NA NA NA NA TABLE 2 GROUNDWATER ANALYTICAL RESULTS Precision Fabrics Group, Inc. Greensboro, North Carolina ECS Project G-6175A WELL ID GroundH•ater Rernediation Goals %M - I MW-11 MW-15s MW-15s du MW-15s MW-15d MW-15d MW-17i MW-171 MW-17i d MW-20 MW-20 MW-20 MW-20i MW-20i MW-20d MW-20d (dup.)( Mw-20d MW-20d du . Screened Interval (ft. bgs) 50-60 50-60 15-30 15-30 15-30 88-98 88-98 70-80 70-80 70-80 25-30 25-30 25-30 60-65 60-65 83-98 83-98 83-98 83-98 Daft Sampled 0 r17,-10w, ]i1+31(200(, S 141 lokir• 05/10/2006 1413112006 05r10:_'0119 ] 110100) 0MV2006 1 Pf)1'2006 11.0112006 05108120D6 1"712006 10127r20D6 05n)8P2006 10r2612006 05108/200 051081-006 10/26/2006 I012612006 1 'nlarik Oryamc Cunt orlyuh ( hi Benzene 1 BQL BQL SQL BQL BQL SQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Bromodichloromethanc NE BQL BQL SQL BQL BQL SQL BQL BQL BQL BQL BQL_ BQL SQL BQL BQL BQL BQL BQL SQL Sec-Bulylbenfene 70 SQL BOIL SQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Ten-Butylbenxene 70 SQL BQL BQL BQL BQL SQL BQL BQL SQL SQL BQL BQL BQ1 BQL BQL BQL BQL BQL BQL Carbon tetrachloride 0.3 BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL 1.37 1.14 BQL BQL BQL BQL BQL 0.91 Chloroform 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2.64 2.45 BQL SQL BQL BQL SQL BQL l,l-Dichloroethane 70 BQL BQL BQL SQL BQL BQL BQL BQL. BQL SQL BQL 1.06 0.98 BQL SQL BQL BQL BQL SQL 1,2-Dichloroethanc 0.38 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.21 1.10 BQL BQL BQL BQL BQL BQL 1,1-Dichloroethene 7 BQL BQL BQL BQL BQL BQL SQL 5.29 10.9 10.5 SQL 5.86 5.16 BQL BQL BQL BQL BQL BQL is-12-Dichloroethenc 70 2,340 520-71 BQL BQL BQL SQL BQL 5.02 4.38 4.46 SQL 1,220 1,040 1,560 BQL 355 379 367 374 ans- 1,2- Dichloroethene 100 BQL BQL BQL BQL BQL SQL BQL BQL BQL SQL BQA 5.84 5.04 BQL BQL BQL BQL BQL BQL Naphthalene 21 BQL BQL SQL BQL SQL SQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Tetrachloroethene 0.7 BQL BQL 1.33 1.44 SQL 3,920 3,700 37.6 34.0 33.2 BQL 15.0 11.9 BQL BQL BQL BQL BQL BQL Toluene 1000 BQI. BQL BQL BQL 74.5 BQL BQL BQL BQL BQL L BQL BQL BQL BQL BQL BQL BQL BQL 1,1,2-Trichlornethanc 5 BQL. BQL BQL BQL SQL BQL BQL BQL BQL BQL 8QL 0.61 0.54 BQL BQL BQL BQL BQL BQL Trichloroethcrrc 2.8 25,3(X) 8,290 SQL BQL BQL BQL BQL 3.55 4.93 4.86 I 1.25 2,580 2,260 3,880 1.86 844 896 1,050 1,070 Vinyl chloudc• 0.015 BQL BQL $ L BQL BQL B L BQL BQI. BQL BQL BQ1. 0.62 o.-55 B L B 1. BQI. 13, BQL BQI. Metals 21wo Dissolved Iron NIA BQL BQL BQL BQL SQL BQL BQL 0.215 BQL BQL BQL SQL BQL BQL BQI SQL BQL Ferrous Iron NIA LBQL B L SQL BQL SQL BQL 8QL BQL BQL BQL BQL SQL BQL 20.18J3 BQL BQL BQL BQL BQL BQL Man anrsc N/A .054 0.035 0.321 364 0.795 8 L B L 0.099 0.260 0.292 0.067 0.168 U.247 0.030 0.016 B L 0.072 0.046 hlurku l.LL % r ywiI Alkalinity 185 72.2 58.8 61.9 54.2 103 103 88.2 82.6 83.6 202 191 181 153 210 109 114 117 114 Carbon Dioxide (CO,) - 141 58.5 44.0 44 4 E8 50.2 57.6 88.0 %.1 98.6 84.5 38.7 33.9 45.8 79.4 88 83.6 68.6 68.6 Chloride 22.4 8.08 12.5 12.5 26.3 29.2 28.9 166 169 170 20.9 66.3 66.3 63.7 25.0 44.9 44.4 44.3 47.4 Nitrate Nitrogen 1.61 0.841 0.961 1.07 1.140 1.56 1.39 7.74 8.90 8.99 0.756 5.05 5.55 4.87 0.237 3.24 3.54 3.37 3.20 Sulfate BQL 27.50 BQL BQL 44.40 BQL 46.80 BQL 54.40 53.30 46.40 49,20 BQL 47.60 BQL BQL 52.90 42.40 Sulfide BQL BQL BQL 0.580 BQL SQL BQL 0.360 BQL BQL BQL BQL BQL 0.360 BQL. BQL SQL BQL BQL Total Organic Carbon (TOO 1.62 1.49 1.49 0.670 1.18 0.520 0.84 1.06 1.04 0.76 1.36 1.37 1.63 O1 680 I.83 0.50 BQL 1.09 BQL Uryanic.% - ifelahulir Aciih 1p rw Acetic acid ?tiA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Butyric acid NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Lactic acid NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Pr ionic acid NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Pvruvic acid NA 'tiA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA kkihanr. F.thonc. Ethene 1 hi ]:thane NA 'tiA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA IEthene NA NA NA NA NA NAt::: 'tiA NA NA tiA tiA tiA NA NA !tiA NA NA NA tiA ,Methane NA 'tiA NA NA NA NA NA NA NA NA 'sA NA NA NA 'tiA NA NA NA NA TABLE 2 GROUNDWATER ANALYTICAL RESULTS Precision Fabrics Group, Inc. Greensboro, North Carolina ECS Project G-6175A WELL ID Groundwater Rernediation Goals" MW-21 MW-21 MW-21i MW-2Ii MW-21d MW-21d Ma-21d MVV-22s MW22s MW-22s MW-22s MW-22s MW-22s MW-22s MW-22i MW•22i MW-22i MW-221 Screened Inter►aI(ft. bgs) 15-30 15-30 80-100 80-100 120-I50 120-150 120-150 18.5-33.5� 18.5-33.5' 18.5-33.5' 18.5-33.5' 18.5-33.5' 18.5-33.51 18.5-33.51 54-74' 54-74' 54-741 54-74' Date Sampled "/09r20n6 IOR512000, 05/1512006 l0/?5f2006 u5MW(ft 11/02/2006 11/02/2006 11/06.r-)002 01/20/2003 03131n003 06/1112003 08/28/2003 051090W 10127,2006 141071?002 01120/2D03 031310003 0611012MI f ularilc orgrrnrc Cum yound,% (p ph1 Benzene 1 BQL BQL BQL BQL BQL BQL- BQL BQL HQL BQL BQL SQL BQL SQL BQL BQL BQI. BQL Bromodichloromethane NE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Sec-Butylbenzene 70 BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Teri-Butylbenzenc 70 BQL _BQL BQL BQL SQL BQL SQL RQL BQL SQL BQI- BQL BQL BQL BQL BQL BQL BQL Carbon tetrachloride 0.3 BQL BQL BQL BQL BQL BQL BQL BQL 4 4 3 3 HQL BQi. BQL 31 40 30 Chloroform 70 BQL BQL BQL BQL BQL BQL BQL BQL 4 3 3 3 BQL BQL BQL 17 15 16 i,l-Dichloroethane 70 BQL BQL BQL BQL SQL SQL SQL BQL SQL BQL BQL BQL BQL BQL SQL BQL I BQL BQL 1,2-Dichloroethanc 0.38 SQL B L BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL I,1-Dichloroethene 7 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 BQL BQL BQL 2 3 2 cis-1,2-Dichloraethcne 70 BQL BQL 25.6 23.0 14.7 29.6 28.4 930 400 260 200 210 420 279 400 730 760 710 trans-1,2-Dichloroethene 100 BQL BQL BQL BQL BQL BQL BQL HQL 2 1 1 2 BQL BQL BQL BQL BQL BQL 3 BQL 3 BQL 4 BQL Naphthalene 21 BQL BQL BQL BQL B L B L BQL SQL BQL BQL BQL BQL Te�trachloroethenc 0.7 BQL BQL BQL 0.88 BQL BQL BQL BQL 10 1 tl 8 8 BQL BQL 230 200 180 170 Toluene 1000 BQL BQL SQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL 1,1,2-Trichioroethane 5 BQL BQL BQL BQI. BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL Trichloroethene 2.8 BQL BQL 102 102 32-9 138 141 3,400 1,600 1,2M 990 940 1,580 1,280 3,700 5,900 6,400 5,000 VinVI chloride 0.015 BQL BQI B L BQl BQI BQl- BQL BQL BQL BQL. BQI SQL. BQI BQI 13Q1 2 B 1. BQI. Dissnl►ed iron N/A BQL BQI. BQ1. 13Q1 0.507 0.107 BQL BQL BQL BQI BQl BQI. BQI. BQL BQI. BQL BQI BQL Ferrous Iron NIA BQL SQL BQL. BQl 0.261 BQI. BQL. BQL BQI.. BQ1. BQL BQL BQI. BQL BQl- BQL BQL. BQL Manganese N: A 0.014 0.052 BQL. BQl 0.212 2.200 1 .A 10 a o127 B l BQI. 1301. 0.023c] 0.13s U.t16H BQL 0 0764 0.(K)52 [1.1"47 norgarric:c ( m) Alkalinity -- 57.8 65.6 73.5 73.7 162 156 116 161 328 317 465 462 102 124 87.1 104 35.0 180 122 41.0 240 127 60.0 250 131 88.0 240 Carbon Dioxide (CO,] -- 79.2 108.0 39.6 58.1 13.2 8.4 25.1 32 53 66 57 119 35.2 Chloride 26.5 22.4 22.9 22.9 27.5 24.7 33.0 100 58 46 40 42 26.1 32.6 Nitrate Nitrogen 3.53 6.16 3.56 4.53 0.308 I.71 4.03 2.9 2 1.9 1,6 1.6 0.988 1.98 7.00 6.10 6.40 6.10 Sulfate BQL 34.50 BQL 34.00 BQL 134.00 76.50 BQL BQL BQL SQL HQL BQL 34.20 BQL BQL BQL BQL Sulfide BQL 0.384 0.528 0.768 BQL 7.92 BQL BQL BQL 0.01 BQL BQL 0.880 BQL BQL BQL SQL BQL Total Or anic Carbon (TOC) BQL 0.65 BQL 3.69 13.6 5.54 5.58 4.9 14.4 6.5 7.5 18.6 3.26 6.78 0.9 10.3 11.2 9.7 C)r ❑nics - Metabolic Acids Ip nr) Acetic acid NA NA NA NA NA NA NA BQL BQI- HQL BQL BQL NA NA NA NA N.A NA Butyric acid NA NA NA NA NA NA NA BQL BQL BQL BQL BQL NA NA NA NA 'ti.A NA Lactic acid - NA NA NA NA NA NA NA BQL BQL BQL BQL BQL NA NA NA NA NA NA Pr ionic acid -- NA NA NA NA NA NA NA BQL BQL BQL BQL BQL NA NA NA NA NA NA Pyru►ic acid - NA NA NA NA 'tiA NA NA H L B L BQL I BQL BQL NA NA NA NA ?tiA NA ifcrhunr. Elhune. E1he'nv (h) Ethane -- NA NA NA NA NA NA NA BQL BQL BQL BQL BQL NA NA NA NA NA N. Ethenc NA NA NA NA NA NA NA BQL BQL BQL BQL BQL NA NA NA NA NA NA Methane NA NA NA NA NA NA NA B L H L B L B L B L NA NA NA NA NA NA TABLE GROUNDWATER ANALYTICAL RESULTS Precision; Fabrics Group, Inc. Greensboro, North Carolina ECS Project G-6175A WELL 1D MW-22i MW-22i I MW 22i NJ%r_22i MW•22d MW-22d MW-22d MW-22d MW-22d MW-22d MW-22d MW-22d MW-23s MW-23s MW-23s MW-23s MW-23s MW-23s MW-23s Groundwater Remediation Goals du d 5crevned Inter►a1(ft.bgs) 54-74' 54.74' 54-741 54-74' 95-115' 95.1151 95-115' 95-115' 95-1151 95-1151 95-115' 95-1152 20-351 20-351 20-351 2D-351 20-35' 20-351 20-35' Date Sampled 08/27R00z n5 h Iflof, 1. 51{6f2pG i0131.+2[>[in � 11ro71'_t1o, n n 1rl 2 003 z GM1.'al '+H>> > 6W11 _Ot�3 > ; Dt,�ill_Oo. z 11812fir'IX�_ t15116120Q6 10130f20[16 11h+7l1g02 �1l24r?(1[13 03 3112003 z 06.1FI_'txl. 08082003 051I6120t]6 10lI712000 1'olaeilc Oreanic Compounds unds ( b) Benzene 1 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Bromodichloromethane NE BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Sec-Butylbenzmc 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL L BQL B L BQL BQL BQL BQL BQL Tert-Butylbenzene 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Carbon tetrachloride 0.3 26 BQL BQL SQL BQL 63 43 43 44 36 BQL BQL BQL BQL SQL BQL SQL BQL BQL Chloroform 70 14 BQL BQL BQL BQL 27 25 27 28 27 SQL BQL BQL BQL BQL SQL BQL BQL BQL 1. 1 -Dichlorocthane 70 BQL BQL SQL SQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL SQL SQL BQL BQL BQL 1,2-Dichloroethane 0.38 BQL BQL BQL BQL BQL BQL BQL 4 4 BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL 1.1-Dichloroethene 7 BQL BQL BQ1- BQL BQL BQL ti 7 7 7 BQL BQL BQL BQL BQL BQL BQL BQL SQL cis-1,2-Dichlorombene 70 600 1070 1020 590 2,300 2,300 2,700 2,800 2,700 2,500 4,030 6,180 BQL BQL SQL SQL BQL 2.88 0.93 trans-l.2-Dichlvroethene 100 5 BQL BQL BQL BQL 12 23 24 27 25 SQL BQL BQL BQL SQL BQL BQL SQL BQL Naphthalene 21 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL SQL BQL BQL SQL Tetrachloroethene 0.7 160 BQL BQL BQL BQL 96 87 76 73 67 BQL BQL BQL 0.6 BQL BQL BQL BQL BQL Toluene 1000 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL 1.1,2-Trichlorodhanc 5 SQL BOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL i richloroethene ? .S - 4,800 5,930 5,6M 4,800 13,000 12,ODO 12,000 11,000 11,000 11.000 8,640 12,300 1.0 BQL BQL BQL BQL 13.5 13.4 Vtn%-I chloride 0-015 BQ1_ BQl_ BQL BQL BQL BQL BQL BQL BQL RQ1. BQL BQ1 BQL BQI. B 1. [301 1 BQL BQ1. qQl. 1levals (pm) Dissolved Iron NIA BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL 0.178 BQL SQL BQI. BQ1 SQL BQl. 1301 Ferrous Iran NIA BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL 0.449 BQL BQL BQL. BQl_ BQL HQL BQI. Maneranesc NIA 0.0196 0.084 0.060 0.021 0.0424 0.465 0.625 1 0.473 0.421 0.611 1.15 0.973 B L BQ1 0.0275 1 1391 0.39U [1.3(17 Inorganics ( m) Alkalinity 119 130 139 127 128 118 133 154 142 166 194 169 298 301 265 169 305 441 390 Carbon Dioxide(CD_) 57.0 105.0 88.0 91.9 40 39.6 70.4 40 31 13 96.8 117.0 40 60 48 70 101 123 135 Chloride 220 169 162 162.0 440 420 410 360 360 320 230 274.0 20 23 25 25 21 BQL 2.63 Nitrate N i trogm -- 6.50 3.88 3.60 3.58 6 4.1 3.8 3.1 3 2.9 2.0 1.66 0.27 0.41 0.46 0.5 0.38 0.098 0.121 Sulfate - BQL BQL SQL 75.20 BQL BQL BQL BQL BQL BQL BQL 11.10 BQL BQL BQL BQL BQL BQL 34.00 Sulfide -- BQL BQL BQL BQL 0A I I BQL IBQL o.05-1 0.04 0.05 0.380 SQL BQL BQL BQL BQL BQL 0.360Total Or,anic Carbon (TOC) 6.4 0.680 0.820 0.83 1.1 8 4.9 3.8 3.9 5-2 2.49 1.38 4319.1 7 L52L 12.4 L45 2.57 U '-:amc's - .Mclabo/4 .acid! Acetic acid NA NA NA NA NA NA NA NA NA NA NA tiA NA NA NA NA NA NA !tiA Bu c acid NA NA NA NA NA NA NA NA NA NA NA NA NA 'tiA NA NA NA NA NA Lactic acid - NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Pr ionic acid NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Pvruvic acid NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA ethane. Ethane, £Mery (pph) Ethane NA NA NA NA NA NA NA NA NA 'tiA NA NA NA NA NA NA NA NA Lthene tiA N.A NA NA NA NA N.A 'tiA NA NA ti;1 NA NA NA NA NA!tiA NA NA 'dethanc t'A NA NA '.tiA ?tiA NA tiA NA 'tiA NA NA N.A tiA MA tiA NA NA NA TABLE 2 GROUNDWATER ANALYTICAL RESULTS Precision Fabrics Group, Inc. Greensboro, North Carolina ECS Project G-6175A WELL ID Groundwater Remediation Goals- MW-24s MW-24s (duin.) OW-1 ow-1 OW-1 OW-1 OW-1 ow -I OW-1 ow -la ow -la OW -la OW -la ow -la ow -la OW -Ea OW-2 OW-2 OW-2 OW-2 45-65 06110/2003 Screened Interval (ft. bgs) 17-32 17-32 45-65 45-65 45-65 45-65 45-65 45.65 45-65 25-35 25-35 25-35 25-35 25-35 25-35 25-35 45-65 45-65 45-65 Date Sampled 10/31coon 10!31(2006 1110?[2M2 0112012003 03/31/2003 ftllof)M3 118r270003 05t1e,/2006 1013t112D06 111071200: OIf-M-12 H13 03.131!2M3 06/11/2003 M2912003 05/16/2006 1012712f1or I MO-002 01/2012003 03131/2003 I ularile Urewjic C•urry undc ! hJ Benzene l BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL Bromodichloromethanc NE BQL SQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Sec-Butylbenzwe 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Tcn-Butylbenzene 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQl- SQL BQL BQL Carbon tetrachloride 0.3 BQL BQL BQL I 2 0.9 0.9 BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL 15 12 BQL Chloroform 70 BQL SQL BQL 3 3 2 2 BQL 0.68 BQL BQL BQL BQL BQL BQL BQL BQL 32 22 25 1,1-17ichloroethane 70 BQL BQL BQL BOL SQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL B L BQL BQL BQL BQL l,2-Dichloroethane 0.38 SQL SQL BQL BQL SQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL 3 BQL BQL 1,1-Dichloroethene 7 SQL BQL BQL L BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL 7 7 $ cis-1,2-Dichloroethene 70 BQL BQL 45 BQL BQL BQL BQL BQL 9.56 BQL BQL BQL BQL SQL 1.84 BQL 1,700 2,000 2,300 2.100 trans-1,2-Dichloroethene 100 SQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 10 9 j5 Naphthalene 21 BQL BQL BQL BQI. 2 BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQI- BOL Tetrachloroethene 0.7 BQL BQL 140 150 150 99 92 110 5.03 14 3 2 0.9 0.6 BQL BQL BQL 10U 94 95 Toluene 1000 BQL BQL Bpi BQL BQL BQL BQL BQL SQL. BQL BQL BQL BQL BQL 0.550 BQL BQL SQL BQL BQL. -Trichloroethane 5 BQL BQL BQI. BQI. 6 BQL BQL BQI. BQI- B L BQL BQL BQL BQL BQL BQL BQL BQL BQL Sloroethene [T,,h 2.8 BQL BQL 790 6 5 4 4 17.7 43.5 BQL BQL BQL 0,5 SQL 0.9 8.53 7a0[i 9,800 12,000 9,5(10 inv1 chloride [i.fll5 SQL BQL B(71_ SQi }3Q! BQl BQI- BQ1. BQ[. BQL BQI. BQL. BQI. BQI. ft[1[. SQI. B 1- 3 BQI. SQL. Alerals ( no Dissolved iron N.'A BQL BQL BQL BQL BQl. BQL BQI. BQI BQ1 BQ1- BQL BQL BQL BQ1. BQL. BQI. BQL fl-5x{ '-4 % ''-2 Ferrous Iron N.'A 13QL BQL BQL BQL BQL BQL BQ1 BQI BQl- BQI. BQL BQL BQL BQL E1Q1. BQL. BQL BQL 4.48 2.48 Manganc�sc N;A 0-249 0.130 i1.654 0.373 0.286 0.220 0.171 (1-111 f1-116 o.8?� 1.24 1.43 1.(x, 1) 2.h5 I-?40 0.0562 1.8" 4.53 928 Inur�arrics {p m} Alkalinitv 78.8 78.9 177 171 157 199 111 184 187 297 427 435 465 520 492 its 194 ;i9 449 Carbon Dioxide (M) 109 100 77 70 79 136 57 132 91.9 41 48 40 75 48 106 7.1 87.1 36 44 70 198 198 Chloride 20.2 15.8 56 56 55 49 46 63.8 58.9 43 34 30 30 30 SQL SQL 190 200 210 180 Nitrate Nitro ert 5.75 7.29 2 2.7 3.4 2.4 2.6 2.26 1.42 0.33 0.37 BQL 0,3 0.24 0.151 0.311 4.9 0.64 0.54 0.32 lfate 35.00 41.00 BQL BQL SQL BQL BQL BQL 41.20 BQL BQL BQL BQL BQL BQL 68.40 BQL BQL BQL BQL p!S,ufide BQL BQL BQL BQL BQL 0.07 BQL 0.540 SQL SQL 0.01 0.1 0.2E BQL 0.760 BQL BQL BQL 0.07 BQL tal Or anic Carbon TOC} 1.42 1.32 2.4 13.6 4.R 5 3.3 1.14 LSO 9.9 22.5 13-3 5.1 6.3 2.01 2.78 1.S 17.7 64 156 Organics - Metabolic Acids (r nr) Acetic acid NA NA SQL- BQL BQL BQL BOIL <1.00 BQL BQI BQL BQ1. BQL BQL BQI, BQL BQL 1 4,7 44 100 Bu c acid -- NA NA BQL BQL BQL BQL BQL <1.00 BQi. BQL BQL BQL BQL BQL SQL BQL BQL. BQL 37 34 Lactic acid -- NA NA BQL BQL BQL SQL BQL <25.00 BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Pr ionic acid NA NA BQL SQL BQL BQL BQL <1.00 BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL 35 130 Pvruvic acid NA NA BQL BQL BQL B L B L <10.00 B L B L BQL BQL BQL B L B L B L BQL f3Ql- BQI- BQL. I.Vethanc. Elhayw. Ethane yh/ Ethane NA NA 27 BQL SQL BQL BQI 669-7 T 6.290 29 BQL BQL BQL BQL 0.170 BQL BQL BQL BQL BQL Ethene NA NA 25 BQL BQL BQL BQL 0.160 0-150 27 BQL BQL BQL BQL 0.230 0.031 BQL BQL BQL SQL Methane DNA NA 7.4 BQL BQL BQL BQL 1.7 2.1 11 SQL SQL BQL S L 2.8 1.5 S.b B L B L 73 TABLE 2 GROUNDWATER ANALYTICAL RESULTS Precision Fabrics Group, 1 nc. Greensboro, North Carolina ECS Project G-6175A WFL-L I Gtoundwater Remediation Goals OW-2 du .l OW-3 OW-3 OW-3 OW-3 OW-3 aw-3 d OW-3 OW-3a OW-3a OW-2 OW-2 OW-2OW-2a OW-2a {1K-2a OW-2a OW-2a OW-2a MV-2a Screened Interval (ft.bgs) 45-65 45-65 45-65 45-h5 25-35 25-35 25-35 25-35 25.35 25.35 25-35 120-150 120-150 120-150 120-150 120-150 120-150 120-150 83-103 83.103 Date Sampled 081270003 05115/2006 051162006 11/01/2006 11.0612002 01/212003 0410112003 W11/2003 08128I2003 05+15i'2006 10/27/2006 11107r2002 01i2012003 013112003 OW1012003 08127I2003 08R712003 to to 2006 It107r2W 0If?0.?003 1 olarilc• Organic Co ands (e& Benzene Beene 1 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Bromodichloromethane NE BQL BQL HQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Sec-Butylberizcne 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL SQL SQL BQL BQL Tert-Butylbenxem 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL Carbon tetrachloride 0.3 BQL BQL BQL BQL BQL 6 5 6 5 BQL BQL BQL 17 13 4 BQL BQL BQL BQL 24 Chloroform 70 21 BQL BQL SQL BQL 7 6 6 6 BQL BQL BQL 16 15 I 8 8 BQL BQL 12 1, 1 -Dichloroethane 70 BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL SQL BQL SQL BQL 13QL BQL 1.2-Dichloroethanc 0.38 BQL BQL SQL SQL BQL BQL 0.9 0.8 BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL 1,1-Dichloroethenc 7 7 BQL BQL HQL BQL BQL 0.7 0.6 0.5 BQL BQL BQL 4 4 5 6 6 BQL BQL BQL. cis-1,2-Dichloroethene 70 1,900 1,740 1,790 910 950 620 370 350 350 506 468 940 1,200 1,800 1,600 1,500 1,400 2,520 400 330 trans-l.2-Dichloroethene 100 16 BQL BQL BQL BQL BQL 2 6 3 BQL BQL BQL 6 7 11 14 14 BQL BQL BQL Naphthalene 21 BQL BQL BQL BQL BQL SQL BQL BQL BQL SQL BQL BQL BQL BQL BQI. BQL BQL BQL BQL- BQL -Letrachloraethenc 0.7 82 BQL BQL BQL BQL 19 14 15 13 BQL BQL BQL 100 95 89 78 77 250 370 Toluene 1000 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL SQL BQL BQL BQL BQL BQL BQL 1,1,2-Trichloroethane 5 BQL BQL BQL BQL BQL BQL HQL BQL BQL BQL BQL BQL BQL BQL BQL BQL HQL BQL SQL BQL Trichloroethene 2.8 9,100 7,900 8,300 5,820 3,400 2,300 1,300 1,400 1,400 1,960 2,410 6,400 7,500 11,000 7,300 7,100 7,000 5.660 4,100 3.800 Vinyl chlnride 0.015 BQL BQL B L BQL B L B L EIL B L BQ1_ B L B L BQl- B L 13QL BQ[ BQL BQI. BQl I L3Q1 BQ1 17r1a1s ( mj Dissol-ed [Ton NIA 3.90 6.25 6.24 SQL SQL BQL BQL SQL BQL BQL BQL BQL BQL 0.245 1.18 0.419 0 34: 1.01 BQL BQL 17errOUS Iron NIA 12-1 10.4 7.13 4.11 HQL BQL HQL BQL SQL BQL BQL I BQL BQL 0.7 2.11 1.19 1.32 2.49 BQL BQL Manganese NIA 9.10 4.29 4.15 3.34 0.719 0.655 0.226 0.0391 0.0714 1.05 I.R3 0.01 15.30 22.10 27.80 31.40 32.00 2.53 B L wlw Inorganics Ippni1 Alkalinity 483 232 2 100 74-9 135 163 211 211 61.9 177.0 115 256 327 515 0.613 580 138 145 132 Carbon Dioxide (C(D,} 108 246 179 142 40 22 119 70 79 35.2 117.0 44 50 40 88 0.07 0.07 109 40 32 Chloride 190 148 154 117 200 14 i00 120 90 12.2 67.3 1,900 1,400 1,500 1,400 1 1 1,080 460 380 'citrate Nitrogen BQL 0.119 0.134 SQL 7.9 3.3 2.9 3 3 0.815 1.05 5.4 1.5 1.1 0.34 BQL 0.0027 0.466 9.7 9.4 Sulfate -- BQl_ BQL BQL 59.00 BQL BQL BQL BQL BQL SQL 149.00 SQL BQL BQL HQL BQL BQL 63.00f�Rj BQL Sulfide L0.11%, BQL BQL BQL BQL 300 SQL BQL BQL 0.52$ BQL BQL BQL BQL BQL SQL BQL BQLSQL Total Or ganic Carbon (TOC) 161 1-58 1.4!+ {l,44 8.4 r1.r1 $.7 5.9 4.[l 4-2[1 3.4h l.] 61 228 351 0.438R 0-4574 37.6 3.6 f)r ani['.s-;tlrrnhulir.9rklctPpn;l Acetic acid 52 < 1.00 NA 2A BQL BQL BQL 13QL BQl_ < 1.00 BQL BQL 26 100 35t1 28 55 78.0 BQL BQl- Butyric acid 34 <1.00 NA BQL BQL BQL BQL BQL BQL <1.00 SQL BQL BQL 1A 11 44 41 2.8 BQL BQL Lactic acid -- BQL <25.00 NA BQL BQL SQL HQL SQL BQL <25.00 BQL BQL BQL 54 SQL BQL BQL BQL BQL BQL Pr ionic acid -• 118 <1.00 NA BQL BQL BQL BQL SQL BQL <1.00 BQL BQL 6.8 78 280 145 132 15.0 BQL BQL Tyruvic acid BQL I < 10.00 NA B L A BQL I BQl_ I BQL BQL I SQL 10.00 BQL BQl- SQL HQL BQL BQL. BQL B L B L B L ilclhanc°. Ethane. 1irh,nu (pphj Ethane BQL 0.280 NA 0.054 BQL BQL BQL BQL BQL 0.170 0.032 BQL HQL S 9(] BQi. BQL Fthene BQL 0.680 NA 0.310 BQL BQL BQL BQL BQL 0.530 0.240 BQL BQL BQL BQL BQI- BQL 1.(HK1 BQL BQl- l+ ethane -� BQL 500 NA 420 9A BQi. BQL BQL BQL 14 1.5 BQL BQL BQL BQI- 720 690 13.{>i3c1 BQL BQL- TABLE Z GROUNDWATER ANALYTICAL RESULTS Precision Fabrics Group, Inc. Greensboro, North Carolina ECS Project G-6175A WELL 1D Groundwater Remediation Goats' OW-3a OW-38 OW-3a OW-3a OW-3a OW4 OW4 OW4 OW4 DW4 (dup.) OW-4 OW-4 OW4 OW-4a OW-4a OW-4a OW-4a OW4a Screened Interval (ft. bgs) 83-103 83-103 83.103 83-I03 83-103 120-150 120-150 120-150 120-150 120-150 120.150 120-150 120.150 83-103 83-103 83-103 83-103 83-103 Date Sampled 03131ON" Oh.16'2WO 08r2712(X)3 0506r2006 1013112006 11/0702002 (11/ 2CM3 OVOU-7003 1)6J10l2M3 (WI012003 08127r2003 05r16r2W6 10.111 200t' 11070-602 011270-00; n4101r2003 (16/1112003 0wSr2ow I'olarile Organic C•onr xrnds ( b) Benzene l BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL Bromodichloromethane NE BQL BQL BQL BQL BQL SQL BQL SQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL Sec-Butylbenzene 70 BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL Teri-Butylbenxene 70 BQL BQL BQL SQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Carbon letrachloride 0.3 31 24 22 BQL BQL SQL 18 13 BQL BQL BQL BQL BQL BQL 36 23 29 27 Chloroform 70 11 12 11 BQL BQL BQL 20 17 17 17 16 BQL BQL BQL 21 18 21 17 1,1-Dichloroethane 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1,2-Dichloroethane 0.38 BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL $QL 5 5 BQL I.1-Dichloroethcne 7 1 1 BQL BQL BQL BQL 12 11 8 lI 9 BQL BQL BQL 12 9 11 10 cis-1,2-Dichlorocthene 70 300 290 270 332 255 3,700 3,800 3,700 3,500 3,700 3,200 3,010 2,640 3,500 3,500 3,300 3,300 3,400 trans-1,2-Dichloroethcne 100 1 2 BQL BQL BQL BQL 19 17 17 1K 20 BQL BQL BQL 17 14 17 23 Naphthalene 21 BQL BQL BQL SQL BQL BQL BQL BQL BQI- BQI- BQL BQL BQL BQL BQL BQL BQL BQL Tetrachloroethenc 0.7 360 320 300 270 125 BQL 89 86 90 89 78 BQL BQL BQL 100 82 90 79 Toluene 1 L100 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQI_ BQL SQL SQL BQL BQL 1,1,2-Trichloroethane 5 BQL BQL BQL BQL BQI. BQI. BQL BQL_ BQL BQL BQI- BQI_ BQL BQL BQL BQl- BQL BQL. Trichlornethenc 2.8 3,900 3,100 3,200 3,180 3,300 12,000 14,000 12,000 10,000 12,0(10 10,000 8,960 9,9""0 13,000 15,000 13,0ikI 12,000 13,000 rml chloride 0A,15 BQI BQI- BQI. BQL J BQL BQL I BQI- I BQL I BQL BQL BQL 1301- BQL w), BQI- BQL- 13QI BQL 1Llcfals op-) Dissolved Iron NIA BQL BQL BQL BQL BQL BQL 0.31 1 1.18 1.24 0.504 0.720 BQL RQ1- BQL 0.104 BQL BQL Ferrous Iron NIA BQL BQL BQL 0.120 BQL BQL 0.35 BQL BQL BQL 0.37 1.56 0.793 BQL BQL BQL BQL BQL klan ancse NIA 0.0265 0.0342 0.0348 0.021 0.017 0.0477 2,02 4.6 7,99 7.68 8.18 3.26 4.60 POI 1.19 1.76 0.618 0.513 Inorgaincs ( nt Alkalinity 120 142 123 105 103 158 243 312 388 411 384 351 305 108 132 138 134 108 Carbon Dioxide (CO2) 44 53 35 61.6 33.4 44 66 66 44 40 35 119 75.2 75.2 75.2 75.2 75.2 75.2 Chloride - 370 320 300 257 294 170 190 180 140 i40 150 12.8 142.0 160 180 160 180 160 Nitrate Nitrogen -- 10 9.5 9.7 6.57 7.39 3.3 1.1 0.87 0.52 0.63 0.28 0.377 0.263 4.2 2.8 2.8 3.1 3.6 Sulfate -- BQL BQL BQL SQL 51.20 BQL SQL BQL BQL BQL BQL BQL 40.20 BQL BQL BQL BQL BQL Sulfide -- BQL 0.06 BQL BQL BQL BQL 0,09 BQL 1.95 0.95 0.05 BQL 9.36 BQL BQL BQL 0.04 0.1 Total Organic Carbon [TDC) 4.2 3.3 4.4 BQL Q.53 1.8 41.8 93.9 104 91.2 220.9 8.56 7.16 I 10.8 7 4-7 5.6 ( rgunic s - Mcfabolic Acids ( pi) Acetic acid BQL BQL ]? I.[►I} BQL BQL 11 63 1211 I20 5" 8.00 7.9 BQI. BQI. BQI_ SQL BQL Butyric acid BQL BQL 17 < 1.00 BQL BQL BQL BQL 20 19 23 1.50 BQL BQL. BQL BQL BQL BQL Lactic acid BQL BQL BQL <25.00 SQL BQL SQL SQL BQL BQL BQL <25.00 BQL BQL BQL BQL BQL BQL Propionic acid -- BQL BQL 25 < 1.00 BQL BQL 5.1 16 58 57 74 6.00 BQL BQL BQL BQL BQL BQL Pvruvic acid BQL BQL B L <10.00 BQL BQL 13L BQL BQL BQL BQL <10.00 BQL BQL BQL BQL BQL BQL Afethaw. F.rhane. Enccnr ( 6) Ethane -- BQL BQL BQL 0.120 0-032 BQL BQ1- BQI BQI- BQL BQI- 0.670 0.240 BQL BQl BQL BQL BQL Lthene -- BQL BQL BQL 0.180 0.098 BQL, BQL BQL BQI BQL BQL 1.800 0,880 BQL BQl- BQL BQL BQL Methane B l_ BQL BQL 42-0 6.0 7.2 BQL SQL BQI- BQL 27 I'M) 870 BQI- B01 BQL BQL. BQL TABLE x GROUNDWATER ANALYTICAL RESULTS Precision Fabrics Group, Inc. Greensboro, North Carolina ECS Project G-6175A WELL 31) Groundwater Remediation Goals"1-IX[I OW-4a QW a d fW-3 IW� IW-S IW-6 Trip Blank Trip Blank Trip Blank Trip $laMTripBlank:Trip Blank Equipment Blank-1 Equipment Blank-2 Equipment Blank-3 Equipment Blank-4 Equipment Blank-5 F.quirmew Blank-n Fqulpment Blank -- Screened Interval (ft. bgs) 83.103 83.103 40-70 100-150 100-150 100-150 NIA NIA NIA NIANIA NIA NIA NIA NIA NIA N .A ti A Date Sampled OSi28l2IXIJ I[tr+ �n Itn161200i II n7120[12 11�07i2[lOj 41rIm �[ar? IiS1?Sn_00[5 106/2006 10R712006 Iq/3[s.n i IA)112006 7. n 1[s+-s Ititb 10/26/2006 10/2712006 10/3012006 101311200r 1 1451 '1,+,r• It o. 'thin 1 o1wile Organic Compnrinds (h) Benzene 1 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL SQL BQL Bromodichloromethane NE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Sec-Butylbenzene 70 BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL Tert-Butylbenzene 70 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL Carbon tetrachloride 0.3 28 BQL SQL SQL BQL BQL BQL BQL BQL BQL SQL BQL BQL SQL BQL BQL BQL BQL BQL Chloroform 70 19 BQL BQL BQL BQL BQL 2.33 BQL SQL BQL BQL BQL 0.93 SQL 0.75 BQL 0.56 0.52 BQL 1,1-Dichloroethane 70 BQL BQL BQL SQL B L BQL BQL BQL BQL 8QL 8QL BQL BQL BQL BQL BQL BQL BQL BQL 1,2-Dichloroethane 0.38 BQL 8QL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL SQL BQL 1.1-Dichloroethene 7 11 BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL BQL BQL BQL BQL SQL BQL BQL BQL cis-1,2-Dichloroethene 70 3,100 2,230 3,900 2,300 4,000 4,3 BQL BQL BQL SQL BQL BQL BQL BQL BQL BQL SQL BQL BQL trans-1,2-Dichloroethene 100 23 BQL BQL BQL BQL BQL. BQL BQL BQL BQL BQL SQL BQL BQL BQL 13QL BQL BQL SQL Naphthalene 21 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Tetrachloroethene 0.7 83 BQL BQL SQL BQL BQL BQL BQL SQL SQL BQL SQL SQL BQL BQL BQL BQL BQL SQL Toluene 1000 BQL I BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SQL BQL 1,1,2-Trichloroethane 5 BQL BQL. BQL. BQL BQL 8QL BQL BQL 8QL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Trichloroethene 2.8 11,000 10,100 13,000 9,800 15,000 13,000 BQL 1.02 BQL BQL BQL SQL SQL BQL BQL BQL BQL BQL BQL �'im 1 chloride 0.015 BQ1. BQI. SQ1 BQL RQ! BQI.-BQl B L BQL 13Q1. BQL B L BQ[ BQl BQL BLit 13Q1. B i RQl 4leials (m) Dissolved Iron N..A BQL BQL BQI. BQL- BQI. BQI. NIA NIA NiA NIA N A NIA BQI. BQl BQL I BQI, I BQL I BQL BQI. Ferrous Iron N. A BQI, 0.158 0.64 BQL BQL SQL NIA NIA NIA NIA NIA NIA BQI. BQI. BQl BQI- BQL BQI. BQ Man Ur sc N A o,54: 0,417 01 19) MM94 13L 0.0353 N: A NIA N/A I NIA J N, A J NIA I BQI- B L BQL BQL BQL BQI. BQL 1n0rg(.fP6 _s (ppn+l Alkalinity 128 98.8 109 119 174 133 NA NA NA NA NA NA 5.05 2.02 1.01 1.01 2.85 1.90 3.80 Carbon Dioxide (CQ,] -- 75.2 75.2 76 33 BQL 38 NA NA NA NA NA NA 2.90 1.67 1.94 1.68 1.67 1.67 BQL Chloride -- 160 132 200 960 300 190 NA NA NA NA NA NA SQL BQL BQL BQL 1.02 BQL BQL Nitrate Nitrogen -- 3.6 8.11 4.2 3.3 3A 2.9 NA NA NA NA NA NA BQL BQL 0.210 0.226 BQL 0.062 BQL Sulfate -- BQL 44.40 BQL BQL BQL BQL NA NA NA NA NA NA BQI. BQL BQL BQL BQL BQLJ BQL Sulfide 0.01 1BQL TBQL BQL 0,11 BQL NA NA NA NA NA NA BQL BQL BQL SQL BQL BQL Total Dr anic ('arbnn TQC) 5.3 2.11 1.8 1.3 1.8 1.4 NA NA NA NA NA NA NA B L BQL B L B L S L Rj Organic - Alcrahulic Acids (a tn) Acetic acid BQI. 3.8 BQL BQL BQL BQL 'tiA NA NA NA NA NA NA NA NA NA NA ;tiA NA Butyric acid BQL BQL BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NA NA NA Lactic acid -- BQL BQL BQL SQL BQL BQL NA NA NA NA NA NA NA NA NA NA NA NA NA Pro ionic acid -- BQL BQL SQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NA NA NA Pvruvic acid -- B L B L B L B . $ L B L NA NA NA NA NA NA NA NA NA NA NA NA NA ,1k rhane. Elharre . Erlu ne r h/ Ethane - I§Q-]---1 0.047 1 BQL I BQL I SQL I BQL I NA NA I NA I NA NA NA NA NA NA NA NA NA NA Ethene BQL 0.190 BQL BQL BQL BQL NA NA NA NA NA NA NA NA NA NA NA NA NA Methane 13L 170 8A 7.9 BQL BQL NA NA NA NA NA NA tiA NA NA NA NA NA NA TABLE 3 GEOCHEMICAL MEASUREMEN'r5 Precision Fabrics Croup, Inc., Greensboro, North Carolina ECS LLP Pro ect 09-6175A BEFORE 511:L1. 11Ul{[JNG :iH'i'Elt Date li F-11 ITemperaturelConductkili ('elsius Uissol►ed O, HeDoa (ttt5lrnt) rt► I lml'} pll T'emperalurc "{:elsius Cunducti►itr twSlsnt) Uissulred 0, rn III ReUux 4nfV) M 1V-1 I U 24 2111k,1 6.32 20.4 0.722 12.6 4.U1 6.32 21.4 0.006` 51.3#9� 2t,97` 6.36 2U.K 0.670 4-8 36.9 6.36 20.3 11-723 9.2 1I%V-2 10 _'-i 2 lien• IT. 11) 223 f1.41 50.8 48.1 6.09 22.2 0-63I i? 0 _tl 1 11 25 2u07' [r.7? 21-6 1.4116 5.2 - 19.8 6.19 22.0 t1.695 15.0 -- a? 8 h 1 r-3 10- 24; 2006' 5.66 1 & 1 0.555 41.4 77 6.70 18.7 0.996 78.7 174.3 11:2512007' 5.92 18-0 0.546 25.1 63.9 6.34 18.3 0.732 43.1 41.11 M ►V-31 111 _'4 21111r,• [,.3 17.' (l-55k S.4 44 1} 18.1 0.666 7.3 196 ] ,t 1111 ]• 634 ] x.3 U.SX4 13.0 40 ] i, i4 18.0 0.682 11.1 38.2 M -6 RV2412MA-1 6.9 1 19.9 1 I bs i 1 36.1 9.7 6.51 1 20.2 1 0.718 1 12.3 28.2 1'25'2007• 6-35 12.4 1 4-093• 1 76.0 37.2 1 7-25 18.5 1 0-661 20.2 149.1 NI W-7 Ili -14.2n{if) r).3-4 '-I1'_ I1.SU1 20 40.5 11 6.23 20-4 0.52 34.0 46-3 11. _' 200- r, '-I 19 h I1.105 1 (1. L40 9 6 39 I-o.5 11,5118 1 16.1 163.2 h111'-8 11 (1 24 2f0r)1 n 53 15.7 0.347 57.3 39.7 1 6.50 i5.7 U.344 67.5 31 fl 2, 200-f If.-i2 1 15.5 1 0.349 49.5 33.0 7.54 15-1 0.35 59.2 86.3 h1 WD I [1 24 21)"" 6.49 19.4 U.641 3.5 29.7 6.55 1$.9 0.05 51.9 203 1 _'1_'ul1 536 19.9 0.099 4-5 83.3 5.93 19.3 U-1186 8-9 629 M u 2.1 2nlx,` 7i 21) 9 11 1 x! 43.9 72 5.70 21.0 0 Ix4 41.2 7i.r1 11 '� 2111;•. i 9r1 2I12 111xx 17.7 u3.7 5.93 20.1) a IX2 ]6.5 '7,7 M W-12 1u 24 2fl+in"R sa 15.6 u.42 26 26.5 0.48 15.5 0.387 26.2 2ik o 11 '5 20U7'' 15.9 1p 314 12 27.4, r018 14 2 0.36 5 i.i 211.21 11 M W-13 IIu2412006' h,xX 19 r, 11.- 711 h 15.8 0.71 19,t, I,$' i'Y 1 1 X J1,2512[i07• 48 13.i, I] I151 47.5 -_'3.2 6.h2 i f1.l 0 U8n 21 .'12 2 7 j h1H'-ISs Ill _'4:21}[l6• 11.5 17.6 fl -1 55.5 2=1 9 n 42 17.9 0 252 if,.3 13 3 11.25211117• 6.I5 16.4 i1.1f2 48.3 47.r, r+.57 16-6 f1 s] 40.2 24.7 Ai 11'-15d 10 -4 2006' 7.1'1 1? 113x 15 z y n x_' 18.3 0 ilk: i1.1 111.K _ 11.25 21)07' 7 23 ki,.3 (1 3X2 14.0 _ k t.3 h.76 17.0 0 21 - 1.3.7 t 5.36 h1 W-171 Io-14 21n1r+• 0.5U 17.0 I)9I=r r+1 r, 2i,14 (..2X I7.f+ U.9 U.944 i4f, 41.7 11.25.2007• n.SX 16.5 1).X92 in ] 26.7 n 33 17.3 _ 53 39.1 M W-20s I 24 2f1t16• 10.nr+ I=J.3��ij 2Xx :1 3.S n=11 I'1.0 1164n :5I_'S _'llti7• i.i4 19.6 33.6 w4.'o '1 o 18.6 0.0'J8 ?l19 164.4 AI1V-20i II] 24 _'i1136• F1.35 1(7 5 0 41 1 X7.6 43. t f, I,[, 19.5 f).S52 11 25 21 i11;• i xt, 144 a 194" i.g 16n.8 n.71 IB.0 i1.524 44.f1 16.8 M W-20d l0 24 21111r,• 1 2 q 2,+11" n 4x 19._' 114xt 514-1 i ; n 14.3 If 1,2 ri 59 18.8 (1.481 1 K. i 11,48 - 71).5 21.8 - ] i+.11 1r 3 _ 27 X M W-21 s 111 25 21Ifif) h.3x 17.5 [1 1", 4S 2 39.9 I+ it, Ix.2 If.3ryn 5[,.9 .3X.6 11. 25 2I1fi7• b. t,� in.�] rt 234 79.9-14'l.6 6Ufl 15.x I1. i69 49.7 2.8 ht W-21 i III 25 -Inm' Of, 17 3 11.114 1i X 2_' ' 6 rr2 17.0 11.11 h h i.2 21.4 1 i" 17.5 f1.45h 2 5 ?U r1 6 74 Ih.S 11.3110 58 13 n 10 25 200f, x.vrJ 17 ? 0.47X 13 -4 l ltx [+ !, 72 17-2 0.459 70.2 16.2 - h1 W-22s 11.0612002 6M4 19.7 U.686 0.63 149 6.17 19.3 0.694 3.65 192.3 01/20/2003 6.55 19.5 0.839 2.07 3 6.53 19.5 0.796 2.5 54 03/31/2003 610 19.5 1.07 1.3 72 6.77 19.3 0.857 3.33 94 6/11/2003 6.85 19.5 0.905 1.17 18 6.86 19.8 0.889 2.05 42 08/28/2003 7.14 19-5 0.988 0.75 102 7.04 19.5 0.893 4,40 104 10,124/2006*11i 6.31 211.1 0.787 8.IU _ 39.5 1 6.65 1 20.2 0.014 76.9U 17 II 25 2(K}7' 6 5ir I 20 4 11.261 X.' 25.7 1 o.95 19.1 n.35=Y 62.o 3.8 h1 W- 31 II:06.2002 .15 18.3 0.699 1.08 -176 6.37 18.9 [1.850 0.90 24-5 6.44 19.1 0.722 0.83 139 6.37 19.7 0.951 1.10 171 0313112003 6.38 19.3 1.36 0.33 172 6A3 19.0 1.18 U.95 122 1ul/20/20U3 06/10/2003 6A3 19.7 0.844 3.19 217 6.45 20.1 1.11 3.75 179 007/2003 6.77 1 19.4 0.770 101 187 6.62 19.4 OMS 2.97 178 1012412006-0,17.01 I8.8 0.766 67.80 11.6 6.61 19,1 0.778 45.80 182 6 1/2512007' 7.00 18.6 0.782 7-1 3.8 7.U9 18.4 0.792 IS.! u.k h1 W-22d - 1 1,(*/20021 6.40 1 18.4 1.43 4.33 iO3 6.30 18.6 1.61 4A5 117 01/20/2003 6.36 18.6 1.56 1.22 83 6.41 18.7 1.72 U.74 105 03/31/2003 6-59 19.2 1.69 0.45 I15 6.57 18.9 1.68 3.51 135 06/11/2003 6.57 19,2 1.57 1.68 78 8.25 19.4 0.184 1.94 90 08128/20U3 6.89 18.9 1.32 0.25 75 613 19.5 1.24 OA9 52 10/2412006*1 7.38 18.75 0110 76 9 11.8 7.45 19-07 0.225 78.6 147-4 r1.25 2007' 8.03 18 5 iw42 47.5 b4.7 7.20 18.8 0.148 35.5 6.5 M W-23s II/D612002 6.65 19.0 0.002 0.41 40.5 h.52 19.6 o.592 4.55 66-5 01/20/2003 6.45 19.3 0.572 0.72 157 6.35 19.5 0.578 1.57 164 W5112003 0.89 M5 1.070 1.30 72 6.77 19.3 0.857 3.33 94 0611112D03 6.62 20.1 0.584 0.75 72 6.75 19.6 0,555 1.29 too OMS12003 6.90 19.5 0.598 0.49 76 6.94 26.0 0.595 1.73 102 IU12412006 6.49 19.5 i 0.814 2.00 28.2 6.57 i9-7 0.728 19.00 25.2 01/2512007 6.67 19.52 0.758 6.8 19 6.78 19.36 0.725 47.6 12.8 NIW-24s 3 u 24 2nU6' r1.24 19-0 0.455 17-10 45.2 0.27 19.1 0.384 58-90 43.3 II 25 2U1i7' 6.711 IN 5 0.439 24.7 149.3 O] I 18.6 1 0.435 3U.6 34A TABLE 3 GEOCIIEMICAL MEASUREMENTS Precision FAbrics Group, Inc., Greensburg, North Carolina EC S LLP Project 09-6175A BEFtlRE 11' 1,L PC R(JNG AFTER NVELL PURGING Date cr>tperuturc pit p1l "Celsius ['unducti►it► llissuls[[I C], {trtSlcnt) wail HeDoxL11"C't t[tll } _ fernPcrnture lsius C ojlducd'�il% [ntSIctnj INSSo red C1. tut ,/1} Rehu► Ilnl 1 OW-1 II.Ut,,2002 6.29 19,7 U-531 0-62 73.7 o.28 19-4 U.515 .3.14 -43 0112W2003 6.14 19-6 0.531 0.50 135 6.34 19.1 0.526 2.05 98 03/31/2003 6-94 1916 0.488 0.59 265 6.65 19.4 0.513 1 J6 244 oo/IO/2003 6.65 20.0 0,487 1.54 202 6.62 20.3 OA83 1.95 181 08/27/2003 6.8 19.5 0.487 1.18 215 6.80 19.8 0.478 4- l4 2U2 1 U124/2006* 6.75 19.2 0.619 66.30 16.5 6,67 19A 0.644 61.10 59 id.25.2007" ,.Is 19.0 0-037 40.2 3.6 7,15 17.8 0.635 42.3 5.6 OW -la 11*612002 7.2 19.7 0,767 0.69 -71.7 6.78 19.3 0.714 2.25 123.5 01/20/2003 6.94 19.5 0.991 0.33 20 6.95 20.0 0.830 0.70 54 03'31/2003 7.07 19.6 0.868 0.22 3 7.L0 19.4 0.914 0.24 73 06A 1/2003 6.97 19.5 0.869 0.23 56 7.10 19.7 0.895 0.27 -11 08128121103 7.3 19,2 O.943 0.16 37 7.28 19-4 0,948 0.44 46 V U; 24120[ la' 4.71 19.4 1.090 3.00 17 6.74 19. 5 0.985 17.90 14.7 +11 25'{rl!'• t,.x4 ICo. 5 I f123 9.4 6.89 19-7 0-949 36.6 [,.+ -- OW-2 1l.fu+.2002 t,.15 18.6 U.S92 i_. 200 5.48 18.5 0.895 2-47 182-5 01/20/2003 6.55 19.1 0.962 0.95 22 6-33 19-2 1.10 0.88 8 03131/2003 6.74 18.9 1.15 0.51 -77 6.67 18.9 1-2k 0.53 -30 06/10/2003 6.45 19.8 1-99 0.41 -89 1 6.63 20.6 1.62 0.57 48 08/27/2003 6.72 19.1 l .54 010 -132 6.76 20.2 1.53 0.36 - I (it) 10124/2006* 6.18 19.14 0.112 %.80 66.8 6.10 19.53 0.09 57.3 52.3 01/25/2007* b.69 18.9 0.020* 53.8 19 6.52 18.6 1.014 13.K 27.8 D -a 11106i2UU2 6.22 18.8 1.32 3.15 146.5 6.18 18.5 1.23 1.50 154 01/20/2003 6.43 19.5 0.943 0.85 46 6.47 19.3 0.960 1.37 57 03/31/2003 6.64 1 19.3 0.773 1.03 34 6,60 19.5 0.775 U.52 86 116/1112003 6.72 19.1 0.893 1.54 -44 6.56 19.3 0-913 1.30 Il u812812003 0.88 19.0 0.892 1.85 114 6.97 19.3 1.20 2.15 128 10. 242006* 6.35 19.3 0.701 98.6 38.5 7.38 18.6 0.061 87.4 -21A U1 25`200746.31 1 19.11 1 IOV 3.11 44.1 [,.[,1 19-2 _ OW-3 111)b2(nl' r+'t) 19. 1) 4.28 12.15 -15ii - 1.9.2 5.77 12.03 29 01/2W2003 S._14 19.3 3.38 1.69 -300 7.06 18.8 5.00 1-42 -118 03/31/2003 7.31 19.1 4,27 0.30 -237 T25 18.4 3.79 0.68 -215 06/10/2003 7,6•t 20.8 3.79 0.35 -233 6m 19.8 5.19 0.36 -90 u8/27/20U3 t+.93 19.7 4.91 0.31 -170 6.68 19.3 5.42 0.31 -109 10/24/2006' 7.07 MO 3-739 47-80 -4-1 6.96 19.5 3 2 7.00 -71-4 11/2512007• 7{17 19.0 3.25] 3-0 -4.1 6.94 1" 3.170 4.1 42 O%V-3a I1,U6,2UU2 11.36 M2 3-82 7.42 -151 8.54 18.7 2.15 4.10 -43.5 01/20/200.1 8.47 18.9 0.815 1 0.21 -272 6.88 1 19.3 1 1.520 j 0.87 -78 03/31/2003 7.46 18.8 1.25 OA6 -76 &64 18.7 1.49 1.01 169 06/10/2003 6.94 19.3 0.623 0.32 145 6.82 20.0 1.25 0.92 l35 08/27/2003 7.13 19.5 O.652 0.55 151 7.03 19.8 0.930 1.66 122 10.'2412006* 7.09 19.0 0.662 35.30 6.4 6.78 18.9 0.698 13.40 156.5 11 25 2007* 9.64 19-1 (J.176 6.1 -152.7 7.ol 19 2 0.597 8.9 03 ❑W 4 1 1 /06/2002 I {1.05 18.7 1.20 4 64 -205 6.68 18.7 i .mt 1.91 -10 u1/20/2003 7.06 18.6 0.954 U.24 -80 6.74 181 I.Il 0.80 -25 1)3/31/2003 7,10 191 0.981 0.21 -160 6,91 18.7 1.27 0.38 .78 (WIO/2003 6.97 19.3 1.15 0.25 -185 6.96 19.5 1.26 0.39 -246 08/27/2003 7.49 19.0 L.17 0.16 -223 7.22 19.5 1.19 0.59 -202 1(I124/2006' 1 6.96 19.9 1.192 19.43 3.2 6.68 19,1 1 1-097 45.0 70.8 11 'S 2UU7•• �.14 Ito 1l 1 1K2 3.'1 8.(1 t,.�5 14.1 ! ]91 32.5 lo.1 O W-4a I I U6.2002 1).25 19,2 0.900 1.16 -141 5.1J2 18.3 U.7YU I.95 97.5 U1:2o.;2UO3 6.42 19.2 0.783 0.93 -225 6.21 18.7 0.786 0.60 •44 U3131i2003 6.67 19.3 0.768 0.20 -157 6.49 19.5 0.792 0,43 -l6 0611;2003 0-56 19.2 0,766 0.65 -197 6.49 19.4 0.773 0.51 -96 U'i 2S 1903 6-65 19.0 0.732 0.55 84 6.57 19.6 0.744 0.74 8 10 24,U6** 9-82 19.1 0.267 92.5 -163.2 6.84 193 0.064 66.50 -142.6 }1 25 2ut17• x-27 19-3 0.470* 1.8 -73.9 6.96 19.15 0.076 5-2 1.9 I W-1 ! I1h 211f+2 h.2N 19 7 U.9M, 5.0' 113.5_JL {,.14 14 h i1.8Uh1 9.ii7 FRiiin. i1V-2 I 19.1 0004 -'.24 kl!!.5 t,,13 1`1.6 1.1111 1 _'] 142.5 1 W-3 I I flh. 2002 5 92 1 1).4 11.(0 5 70 154 6.09 19.5 11,K45 i ! 91 I1►'-4 1 I.nt+ 2UO2 37 ?iJ I _ ?. 71, �.12 k61.3 o.41 ail.? 3 a? 1 UI r l 3 1►V-5 l ut+ 2uf12 1 d2 211.1 1 3- 3.53 Ui.5 K.1] 20.2 1.32 4 1n n,S 1W-6 ll U6,?un2 6.SS 20.4 O.Iu}2 2.72 83 6.5f1 19.9 1y,885 '_-tik n1.3 ReDox - Oxidation/Roduction Pcaential mgll - milligrams per tiler tppmj mSJctn s microscimens per centimeter mV - millivoils h1W - Monnaring Well OW = Observation Well 1W - Injection Well * = Unstabilized reading • " Dissolved oxygen is in % Saturation TABLE 4 REMEDIATION SCHEDULE Month/Year Scope of Services November/December Submit Injection Permit and Obtain Approval 2007 Drilling - Injection Well/Observation Well Installation January/February Investigative Derived Waste Containment & Disposal 2008 Laboratory Services — Waste Disposal Sampling ECS Field Services/Project Mana ement HRC0 - Supply March 2008 HRC® - Injection ECS Field Services/Project Mana ement April 2008 HRC9 - Injection, if necessary ECS Field Services/Project Management Laboratory Services — Post -Injection Groundwater Sampling — (includes monitoring wells and observation wells in the vicinity of June 2008 the injection area) Investigative Derived Waste Containment & Disposal ECS Field Services/Project Management Laboratory Services — Post -Injection Groundwater Sampling — (includes monitoring wells and observation wells in the vicinity of September 2008 the injection areas) Investigative Derived Waste Containment & Disposal ECS Field Services/Project Management October/November HRC® - Injection, if necessary 2008 ECS Field Services/Project Management Laboratory Services — Post -Injection Groundwater Sampling — (includes monitoring wells and observation wells in the vicinity of December 2008 the injection areas) Investigative Derived Waste Containment & Disposal ECS Field Services/Project Management Laboratory Services — Post -Injection Groundwater Sampling — (includes monitoring wells and observation wells in the vicinity of March 2009 the injection areas) Investigative Derived Waste Containment & Disposal Laboratory Services — Post -Injection Groundwater Sampling — (includes monitoring wells and observation wells in the vicinity of June 2009 the injection areas) Investi ative Derived Waste Containment & Disposal Laboratory Services — Post -Injection Groundwater Sampling — September 2009 (includes monitoring wells and observation wells in the vicinity of the injection areas) Investigative Derived Waste Containment & Disposal Laboratory Services — Post -Injection Groundwater Sampling — December 2009 (includes monitoring wells and observation wells in the vicinity of the injection areas) Investigative Derived Waste Containment & Disposal Laboratory Services — Post -Injection Groundwater Sampling — (includes monitoring wells and observation wells in the vicinity of March 2010 the injection areas) Investigative Derived Waste Containment & Disposal Laboratory Services — Post -injection Groundwater Sampling — (includes monitoring wells and observation wells in the vicinity of June 2010 the injection areas) Investigative Derived Waste Containment & Disposal UD r 10, TABLE 5 PROPOSED ANALYSES FOR EXISTING, MONITORING, INJECTION AND OBSERVATION WELLS (Pre- and Post -injection) Precision Fabrics Group 301 East Meadowview Road Greensoro, North Carolina ECS Project 09,6175B b o., a U .� u ° ❑ ° i. v m p ° S d p o •a v .0 a „ P0 ° C Q a o as n e+ Z d w q e PaUd p r� d emu V i ��srr iG G O 10 L .stl+ ar64 a 4! O titer C W 'n ow V G" 41 � v ,Sample ED Location Injection Wells -Boundary (see Plat 1) Not Sampled Monitoring Wells Boundary MW-20 30 X X X X X x X X X X X X MW-20i 65 X X X X X X X X X X X X MW-20d 98 X X X X k X X X X X X X MW-21 30 X X X X X X X X X x X h MW-21i 100 X X X X X X X X X X X X MW-22s 33.5 X X X X X X X X X X X X MW-22i 74 X X X X X X X X X X X X MW-22d 115 X X X X X X X X X X X X MW-23s 35 X X X X X X X X X X X X -24s 32 X X X X X X X X X X X X Observation Wells -Boundary (See Plat 1) OW-1 65 X X X X X X X X X X X X OW -la 35 X X X X X X X X X X X X OW-2 65 X X X X X X X X X X X X OW-2a 35 X X X X X X X X X X X X OW-3 150 X X X X X X x X X X X X OW-3a 103 X X X X X X X X X X X X OW-4 150 X X X X X X X X X X X X OW-4a 103 X X x X X X X X X X X X 0W-510W-5a through OW- 41OW-44a -- X X x X X X X X X X X X VOCs Metabolic Acids = acetic acid, butyric acid, lactic acid, proprionic acid, and pyruvic acid. Light Hydrocarbons = ethane, ethene, and methane BGS = Below Ground Surface icy ", �.� ^' 14 E 12 10 x 0 5 a (D 4 N 2 N 6 0 CHART 1 Concentration of Dissolved oxygen Vs. Time CN 0 Cr) co 0 0 0 0 0 0 oa v a o to a `C) i CD CAD C) r C] Q 0 CD r Date OW-1 �- OW-1 A OW-2 OW-2A OW-3 -� OW-3A OW-4 OW-4A a, 60000 50000 � 40000 30000 �v 20000 U 10000 D U CHART 2 TCE Concentrations Vs.Time Ctl Cn to �t t'7 u7 CO QD 0 o a o 0 0 0 a 0 0 0 0 0 o 0 0 0 0 L L LO r o r Q r- Q r- o r - OW-4A OW-4 --- OW-3A .- OW-3 OW-2A OW-2 OW-lA -- OW-1 v m 11 /01 /2002 03/01/2003 07/0112003 11 /01 /200 3 03/01/2004 07/01 /2004 11 /01/2004 03/01 /2005 07/01 /2005 11 /01/2005 0 3/01 /2006 0 7/01 /2006 111011200E Concentration in (uglf) srvw�Cnm--1COCDCD ooC)oCDCDooCDCD C) CD CD 0 CD CD a CD C7 CD C7 0 0 0 0 0 0 0 0 *:E :*****:� 1 N N W W 0 m 0 0 n C) � w C s Concentration in (mg/1) -� N W A U1 M �1 O O O O O O O O O O O O O O O 11161 /2002 6310 112663 67/61/2663 1110112663 6310112a64 67/61/2664 v 11/61/2664 mf-O63/41/2665 07/61/2665 ARM UN1111,19 67161 /2666 11161 /2006 o0000000 0 0 0 0 (D 0 r. 0 � C SECTION V. APPENDIX RESPONSE TO COMMENTS February 15, 2006, Revised May 2007 .tune 28, 2007 ED HRC Design So are for Barrier Treatment Regenesrs Technical Support USA (949) 366-bQOO wwn.teWiesss com Site Name: Precision Fabrics Group Location: Upgradient Bamer (PWR,) Consultant: ECS, Lid Site Conceptual ModellExtent of Plume Requiring Remediatron LefVIi of bamet (inte r sectrag " tkw% direct"i Depth to wntaminated zone Thickness of Conlarrrnalad saturated zone Aquifer soil type (gravel sane nifty sand sill day etr Effective porosity Hydraulic conductivity Hydraulrr gradient Seepage velocity 8-8E-03 lcmlsec 0,583 Jfvday Dissolved Phase Electron Donor Demand Contaminant Contaminant Stoichlometry Conc (mg1L) Mass (11") conWa (wtlw0 Tetrachloroethene (PCE . T rrchloroethene (TCE ) as, 1.2•01chloroethene IDCE I Vinyl Chloride (VC) 1 1 1- T nchloroethane (TCA ) 1.1-Drchlorochloroethane (DC A; User added also add stoichrometrrc demand Isee pull -down; User added, also add stoichiometnc demand (see pull -down 1 008 4.90 20.7 9.10 543.88 21.9 1.90 113.56 24.2 0,00 0.00 31.2 0-00 0.00 22.2 0-00 0.00 24.7 0.00 0.06 0-0 0.00 0.D0 0-0 - pult-down menu Competing Electron Acceptors: CEA CEA Stoich. (wtw) Conc (mg►L) Mass (IMn) e a /H Oxygen Demand Nitrate Demand Bioavarlable Manganese Demand Broavailable }ion Demand Satiate Demand Microbial Demand Factor Safety Factor Liferspan for one application Injection Spacing and Dose: Number of rows in barrier Spacing within rows Effective spacing perpendicular to flow (ft) Total number of HRC injection locations Minimum required HRC application rate (lb/ft) Number of HRC delrvery points lad)ust as necessary for site HRC application rate in lbsA (adfust as necessary for site) Corresponding amount of HRC per point (lb) Number of 30 lb HRC buckets per injection point Total number of 30 Ib buckets Total amount of HRC (lb) HRC unit cast (5Ab) Total Material Cost Shipping and Tax Estimates in US Dollars 5aie" Tax rate 0 0000 Total Material Cost Shinano of HRC (Call far Quote) 5-00 298.83 8,0 6-50 388A6 12.4 9-30 555.83 27.5 3-90 233.09 55.9 25.00 1 494.17 12.0 3 Recommend 14x 2 Recommend 1-4x 1 Year(s) 1 23 ft on Center 23.0 Max = 15 ft- Tighten SpacM 22 points 45.9 22 459 1377 45.9 11 1010 30,300 5 525 159,075 159.075 May 2005 rmovr a rrgri Pw~ car Rparesc Tad, Suppw to confirm I Length of each injection point (ft) 70 Design and Regulatory tssue6 c Total length for direct push for project (ff) 1.540 Groundwater monifoung and reporttng Esbmateo daily irrstallalron rate (ft per day 300 for pustr 150 lot dnlliN 300 Other 5 Estimated points per day (10 to 30 is typical for direct push) 43 Other 5 Required number of days 6 Other Mcbftatrcnurdemob0a3tron Cost for nnlechon subcontractor - OthF t early raie for rgecbon suboor0irasicy C7ther 5 Tota+ iJertion subcontractor cost for appGcalron C)the Total InssaftOmtVwIkvbacs Teen:-A*&jnL iJbtm@X3 i.w 159,075 Total Project Cast S 159,075 Last Revised: HydrogRL4en Release Compound (HRO) Nt4TEL SAFETY DATA SHEET (MSDS) February 10, 2004 Section 1 - Material Identification Supplier: CW REGENESIS 1011 Calle Sombra San Clemente, CA 92673 Phone: 949.366.8000 Fax: 949166.8090 lrnnail: info(EvxeQenesis.com Chemical Name: Propanoic acid, 2-[2-[2-(2-hydroxy-l-oxopropoxy)-1- oxopropoxy[-1-oxopropoxyj-1,2,3-propanetriyi ester Chemical Family: Organic Chemical Hydrogen Release Compounds' (E RC4) Trade Name: Glycerol tripolylactate and Glycerol Product Use: Used to remediate contaminated soil and groundwater (environmental applications) Section 2 -- Chemical Identification CAS# Chemical 201167-72-8 Glycerol Tripolylactate 56-81-5 Glycerol 50-21-5 Lactic Arad Section 3 - Physical Data Melting Point: Not Available (NA) Boiling Point: Not Determined (ND) Flash Point: ND Density: 1.3 g/ec Rrgrrirsis - HHC h4SDS Section 3 — Physical Data (cont) Solubility: Acetone and ❑MSO Appearance: Viscous amber gelfiiquid Odor: Not detectable Vapor Pressure: None Section 4 - Fire and Explosion Hazard Data Extinguishing Media: Carbon Dioxide, Dry Chemical Powder or NVater may be used to keep exposed containers cool. For large quantities involved in a fire, one should ►wear full protective clothing and a NIOSH approved self contained breathing apparatus with full face piece operated in the pressure demand or positive pressure mode as for a situation where lack; of oxygen and excess heat are present. Section 5 - Toxicological Information Mav be harmful by inhalation, ingestion, or skin absorption. May cause irritation. To the best of our knowledge, the Acute Effects: chemical, physical, and toxicological properties of the glycerol tripolylact.ate have not been investigated. Listed below are the toxicological information for glycerol and lactic acid. MA8050000 RTECS#: Glycerol Irritation data: SKID'-RBT 500 MG/7AR MLD 85JCAE-,207,1986 EYE-RBT 126 MG MLD EYE-RBT 500 MG124H MLD SKN-RBT 5MG124H SEV EYE-RBT 750 UG 5EV J_E( +eratiarss'NSDS',H C MSDS Pagc BIOFX* 9-411970 WCAE-,207,1986 853CAE-,656,86 AJOPAA 29,1363,46 Rcgcnes:s - HRC MSDS Section 5 - Toxicological Information (cont) ORL-MUS LD50:4090 MGIKG NIIRDN 6,215,1992 FRZKAP (6),56,1977 FEPRA7 4,142,1945 SCU-RBT LD50:100 MG/KG RCOCBS 56,125,1987 ORL-RAT LD50:12600 MG1KG A.RZNAD 26,1581,1976 IHL- ARZNAD 26,1579,1978 RATLC50:>578MG/M3/1HBI0 NIIRDN 6,215,1982 F7X*9.411970 IPR-RAT LD50: dAPMA8 39,583,1950 4420 MG/KG DMIDJAP 31,276,1959 1VN-RAT LD50: 5566 MG/KG B10FX* 94/1970 IPR-MUS LD50: 9700 MGIKG NIIRDN 6,215,1982 Toxicity data: SCU-MUS LD50: 91 MG/KG FMCHA2-,C252,91 IVN-MUS LD50: 4250 MGIKG FMCHA2-,C252,91 ORL-RBT LD50: 27 GM/KG FAUNAU 40,144,67 SKN-RBT LD50:>IOGMIKG JIHTAB 23,259,41 IVN-RBT LD50: 53 GMIKG FMCHA2-,C252,91 ORJ -GPG LD50: 7750 MGIKG JTHTAB 23,259,1941 ORL-RAT LD50:3543 MG/KG SKN-RBT LD50>2 GM/KG ORL-MUS LD50: 4875 MG/KG ORL,GPG LD50: 1810 MG/KG ORL-QAL LD50: >2250 MG/KG Behavioral (headache), gastrointestinal (nausea or vomiting), Target Organ data: Paternal effects (spermatogenesis, testes, epididymis, sperm duct), effects of fertility (male fertility index, post -implantation mortality). RTECS#: OD2800000 Lactic acid Only selected registry of toxic effects of chemical substances (RTECS) data is presented here. See actual entry in RTECS for complete information on lactic acid and glycerol. POpuationsiMSMHRC MSDS Page 3 kcgertcsi� - HR( MSM Section 6 - Health Hazard Data Handling: Avoid continued contact ►sith skin. Avoid contact with eyes. In any case of any exposure which elicits a response, a physician should tr consulted immediately. First Aid Procedures Remo■•e to fresh air. If not breathing give artificial respiration. Inhalation: In case of labored breathing give oxygen. Call a physician. No effects expected. Do not give anything to an unconscious Ingestion: person. Call a physician immediately. Flush with plenty of water. Contaminated clothing ma) be Skin Contact: washed or dn' cleaned normally. NVash ryes with plenty of Hater for at least 15 minutes lifting I:ye contact: both upper and lower lids. Call a physician. Section 7 - Reactivit-• Data Conditions to Avoid: Strom, oxidizing agents, bases and acids Hazardous None known Poh-merezation: Further Information: Hydrolyses in Hater to form Lactic Acid and Glycerol. Section 8 - Spill, Leak or Accident Procedures After Spillage or Neutralization is not required. This material may be burned in a Leakage: chemical incinerator equipped with an afterburner and scrubber. La►►s and regulations for disposal ►an• widely by locality. Observe all applicable regulations and laws. This material, ma} Disposal: be disposed of in solid waste. Material is readily degradable and hydrolyses in several hours. No requirement for a reportable quantity (CERCLA) of a spill is known. J:,Operations'MMSIHRC MSDS raer 4 Regencs)s - HRC MSDS Section 9 - Special Protection or Handling Should be stored in plastic lined steel, plastic, glass, aluminum, stainless steel, or reinforced fiberglass containers. Protective Gloves: Vinyl or Rubber Eyes: Splash Goggles or Fuli Face Shield Area should have approved means of a,ashing eyes. Ventilation: General exhaust. Storage: Store in cool, dry, ventilated area. Protect from incompatible materials. Section 10 - Other Information This material Rill degrade in the environment by hydrolysis to lactic acid and glyeeroL Materials containing reactive chemicals should be used only by personnel with appropriate chemical training. The information contained in this document is the best available to the supplier as of the time of writing. Some possible hazards have been determined by analogy to similar classes of material. No separate tests have been performed on the toxicity of this material. The items in this document are subject to change and clarification as more information becomes available. JA0PcrationslMSDS\HRC MSDS Page 5 Response to Letter from U1C Program dated February 15, 24106 Revised Mav 2007 Bullet No. 1: Results from several wells indicate aqueous concentrations of 1% of the solubility limit of TCE in water. These high concentrations indicate the possibility of DNAPL at the site. What testing has been done to document for the presence or absence of DNAPL: on site, especially in the areas proposed for additional injections. Response No. 1: EC5 collects groundwater samples from the bottom of the monitoringlobservation wells using a bailerlperistaltic pumplGrundfost pump (depending on the depth of the well) in order visually inspect for potential DNAPL and to get the most representative sample of the surrounding groundwater aquifer. During recent groundwater monitoring events (March 2006, October 2006, and January 2007), DNAPL was not ►isually observed in the Mailer or purge water. While this does not prase that DNAPL does not exist at the site, further investigation for DNAPL would not be feasible or practical at the point of implementing the Remedial Action Plan. In lieu of additional DNAPL assessment, the injected substrate that makes up HRCO and DNAPL, if any, sorbs to the aquifer matrix in the treatment area causing a reduction in DNAPL mobility. While the sorption of the HRC& is temporary, the DNAPL is then consumed by the microorganisms as the ferments and as the HRC* produces lactic acid. Because the movement of this particle is restricted by its sorption onto the aquifer matrix, the water quality will eventually improve in the treatment area and remain unchanged outside the treatment area. Bullet No. 2: Given that enhanced bioremediation such as that proposed is generally contraindicated in suspected areas of DNAPL or at very high concentration of chlorinated solvents, additional injection of carbon substrates may cause further degradation of groundwater quality at the site. Rule 15A NCAC 2C .0213{a)(2XA) requires that substances used for in situ remediation not be injected at appoint where their injection would further degrade the existing quality of groundwater. Furthermore, additional injections, if unsuccessful, may complicate future efforts to remediate groundwater at this site. Please explain how you will achieve compliance with 15A NCAC 2C (a)(2XA) and how the remaining organic substrates and their by-products will be addressed if they are not removed by effective reductive dechlorination. Response to Bullet No. 2: The monitoring wells and existing and newly installed observation wells will he sampled for eight consecutive quarters so that the progress of the remedialion technology can be evaluated. The monitoring wells and the observation wells will he monitored for natural attenuation parameters (i.e., alkalinity, carbon dioxide, dissolved and ferrous iron, manganese, chloride, nitrate, sulfate, sulfide, and total organic carbon) and geochemical parameters (dissolved oxygen, conductivity, reductionloxidatian porential, pH, and turhiditv). Regenesis has recommended that each of the observation wells also be anahzed for metabolic acids (i.e., acetic acid, hutvric acid, lactic acid, proprionic acid. and Pyruvic acid) and light hvdrocarhonx (methane, ethane, and ethane). When Response to Letter from U1C Program dated F ehruar► 15, 2006 Re►7sed May 2007 the acids and light hydrocarbons are present in the groundwater, reducing conditions exist. the HRC is slowly releasing the lactic acid used as the 'food and chlorinated compounds are being dechlorinated. Regular quarterly monitoring after injection Kill identify problems in the HRC(§ remediation cell. If the degradation of the chlorinated compounds is incomplete, the reaction may stall at the production of cis-1,2-dichloroethane (cis-1,2-DCA). This generally indicates the lack of a .flourishing Dehalococcoides sp. (DHQ microorganism population. In this case the DHC microorganism can be injected to augment and allow the reductive dechlorination reaction to continue. Dverwhelming the system with ' food " will allow the reaction to quickly convert to methanogenisis conditions and a spike in the methane concentrations will be observed in the monitoring data. Because HRC is designed to release slowly in the remediation cell, methoangenisis rarely occurs but stays in sulfate reducing conditions in the remediation cell. If methanogenisis conditions do occur, it will generally decrease the pH of the cell. A buffer solution will then be added to the system to lower the pH and convert the system back to sulfate reducing conditions. According to Regensis personnel, this situation rarely, if at all, has occurred in over 600 world wide applications. Bullet No3: Results submitted to date indicate the occurrence of anaerobic conditions in some wells, yet indicate only limited reductive dechlorination was observed. Please submit more recent results, including natural attenuation parameters, to document the extent to which anaerobic respiration had caused reductive dechlorination and consumption of the organic substrate. Response to Bullet No. 3: Three additional groundwater monitoring events were conducted in 2006 (Tables 2 and 3 in the injection permit application). When comparing the results of analyses from 2003 and 2006, there are significant changes in the groundwater chemistry, immediately following the pilot study injection of HRC! in the boundary wells. Charts depicting concentrations over time have been prepared to highlight these trends over time. The chlorinated hydrocarbons, PCE and TCE have generally decreased over time. Total organic carbon (TOC) increased significantly in boundary observation wells immediately following the HRC9 injection. Dissolved oxygen also decreased immediately following the injection. The reductionloxidation (redox) potential appears to decrease in four of the eight observations wells immediately following HRC® injection. The redox potential appeared to increase from baseline conditions. The reason for the increase is unclear, based on the TOC and DO results, reducing conditions appear to be present in the vicinity of the pilot study. Furthermore, it is ECS' opinion that the pilot study cell was a small treatment area xvithin a very large plume and with hull of the dosage rate applied; it is likely that the treatment cell was overwhelmed bt° chlorinated solvents entering the cell _from the source area. Because the source it -ill be treated concurrendv, the amount of neN chlorinated Response to Letter from UIC Program dated Februsr% 15. 2006 Revised Ma► 2007 compounds in the HRC remediation cell will he reduced, thus enhancing the degradation of the chlorinated compounds at the boundary. It should be noted that 11U from the last twe sampling events uVre measured in Saturation rather than milligrams per kilogram lmglk-g). Table 3 hers been corrected to reflect this modification. Concerns regarding the use of EDS in the bedrock aquifer will he addressed in a separate permit application. Bullet No. 4: What injection rates, volumes, and f-equencies will be used for the proposed injection operation, and how do these parameters compare with those used for the pilot test? Please demonstrate how the proposal injection rates, volumes, and frequencies were revised from the pilot study such that minimal energy (hydrogen) will be diverted toward methanogenesis and that this energy source will be released slowly enough to promote complete dechlorination of the target chlorinated compounds. Response to Bullet No. 4 : The HRC was injected at an approximate rate of 15.5 pounds per foot Obslft) in the intermediate wells and 7 lbslfoot in the bedrock wells during the pilot study. These rates appear to be approximately half of the manufacturer's suggested rate of 25 lbsf (per phase) in the intermediate wells and 12 lbslfoot in the bedrock wells. The suggested manufacturer's dose rate is based on the oxygen and sulfate demand, the competing electron acceptors, and the concentrations of the contaminants in groundwater at the PFG site. While the lithology at the site is taken into account, the aforementioned factors are used in the mass balance calculation of the dose rate (See the attached mass balance calculations for HRC}. During the pilot study, HRC was injected through packers, which isolated hay -of the screen of each well at 15-foot and 25 foot intervals in the intermediate and bedrock injection wells, respectively. With the exception of injection wells IW-3 and IW-6, the intermediate injection '",ells required approximately 15 to 20 minutes per 15 foor interval. The bedrock injection wells required approximately 30 minutes to an hour per 25 foot interval. For this reason, the rates, the injection rate in the intermediate wells will be increased to approximately 20 to 25 lbs f but likely remain 7 lbs l in the bedrock wells. During the pilot study, half the chosen HRCCV dose was injected into wells I H =3 (intermediate) and 1 W-6 (bedrock) most likely due to the tightness of the formation andlor the fractures in this location. In this case, a packer will be used to isolate 5- to 10 foot .screened intervals to ensure that the most amount of HRC9 is injected as possible. Since a lower dose rate will likely be used, a potential third application may be required in the slom, accepting wells. Response to better from MC Program dated Februar% 15, 2006 Revised Ma► 2007 In addition, the pilot study injection wells IW-1 and 1W--4 are located approximately 30 feet from injection u ells IW-2 and IW-5 and injection %Vlls IW- 2 and IW-5 are located approximately 60 feet from injection wells IW-3 and IW-6. Based on the results of the HRC pilot study, the proposed injection wells in the source and the boundary areas will be drilled approximately 20 feet apart in the vicinity of the highest concentrations within the plume. The distance will generally increase to approximately 30 feet apart in the lower concentrations an the outer edges of the plume. Based on the decrease of DO and the increase of TOC, the pilot study indicated reducing conditions immediately following HRCV injection. It is ECS: opinion that the aquifer will quickly convert to reducing conditions when the entire treatment area is in contact with the injectants, thus beginning the breakdown of chlorinated solvents more effectively. Response to letter from LTC Program dated June 28, 2007 In a telephone con►vrsadon between Ms. Carin 8romm of ECS and Mr. Peter Pouo on August 1, 2007.it was agreed that items 1, 3, 4, 5, b, and 7 are related to the potential use of EUS in the source area. All questions regarding the source area mill be addressed in a separate injection permit application. Question No. 1: Please provide an original signature page for this application (Note: each application requires a new signature page. The April 2, 2007 signature page is not adequate). Response No. 1: .4 new original signature page will be provided with this application. Question No. 2: The hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection including a description of the test(s) used to determine these parameters as required on page 5 section A.(3) of the permit application. Response No. 2: The hydraulic conductivity, transmissivity, and specific yield of the aquifer was appropriated from a 72-hour pump test completed in the intermediate aquifer at the Former Burlington Industries site, located at 300 East Meado-wview Road which is adjacent to and south of the site. The 72-hour pump test was conducted by Aquaterra, Inc. as part of the RAP prepared for the site. The pump test was conducted in a 6-inch extraction well (Mil'-7e), which is constructed to a depth of approximately 70 feet bgs. A four - inch stainless steel electrical submersible Grundfos pump was used to pump the aquifer at approximately 18 to 20 gallons per minute. A shallow monitoring well and a deep monitoring well -Kvre located adjacent to the extraction well. Several existing monitoring wells were also observed during the test. The data collected ,from the extraction well was used to determine the hydraulic conductivit , and transmissivity of the intermediate aquifer and the drawdown data in the surrounding wells was used to calculate the hydraulic conductivites and transmissivity in The intermediate nd bedrock aquifers underlying the site. The hydraulic conductivities were calculated using the Theis Curve matching Techniques (Fetter, 1980). The following average hydraulic conductivities are: Intermediate - 295dlfi' or 39.44 feetlday Bedrock - 95 gpolfr or 12. 7 feetlday The following average transmissivities far the intermediate and bedrock area Intermediate 5,377 gpolfoor Bedrock 2292gsdffoot According the USGS, the specific yield is the often same but can be less than the effective porosity. For this reason the effective porosity in the intermediate aquifer is estimated to be approximatey, 30•1a The effective porosity in the bedrock well will be estimated at 0.05% Response to letter from U1C Program dated ,tune 28, 2007 (question No. 7: Explain why half the manufacturers recommended dose of injection was applied during the pilot test. Please explain why you are proposing half of the manufacturers recommended dose of HRC9) for the full-scale application. Response No. 7: It is unclear why ha jof the manufacturers recommend dose rate was used during the pilot study. The personnel involved in this project at ECS PFG, and the 1HSB REC program are no longer employed with these companies or agencies. Currently, the manufacturer's dose rate for the intermediate zone is 50 lbslfoot. Because the manufacturer considers this dose rate to too high to deliver in one application, the1, recommended deliver), of the full 5011bs/foot in two 25 lbslfoot phases, approximately six months apart. H'hile two phases are planned for the majority of the intermediate wells, existing injection well IW-3, which is known from the pilot study to be slow accepting, may require a third dose to deliver the full 50 lbslfoot that is recommended. Similarly, injection IW-6 located in the bedrock may require a second dose. It is possible that a small amount of the proposed injection wells may be slow accepting due the specific lithology of that well location. In this instance, the dose rate will be reduced and the HRC Kill be delivered in phases. During the pilot study, the remaining two intermediate injection wells accepted the HRC well at a dose rate of 15.5 lbslfoot and will likely accept the higher dose rate of 25lbs1foot in the two separate phases. JOB NAME,: PRECISION FABRICS GROUP, INC JOB NUM13ER G--6175B WELL NUMBER: IW-8 LOCATION- GREENSBORO, NORTH CAROLINA CONCRETE - LOCKABLE CAP. GROUT- 6-INCH DIA. BOREHOLE-- 2-INCH DIA. SCH. 80 PVC RISER 6.25-INCH DIA. .188 GALVANIZED RISER 95.0 FT. c_ 2-INCH DIA. SCH. 80 PVC SCREEN (.04-INCH SLOTS) a BENTONITE SEAL 9 (93-98 FT.) SAND PACK - BOTTOM CAP - COVER ASSEMBLY WITH REMOVABLE STEEL COVER DEPTH TO BASE OF GROUT 93.0 FT. if NOTE. ALL PVC JOINTS ARE FLUSH THREADE❑ CSLLP DEPTH TO TOP OF SAND 98.0 FT. TOTAL DEPTH OF WELL 150.0 FT. SCREENED INTERVAL 100.0 -150.0 FT. TOTAL DEPTH OF BOREHOLE 150.0 FT, PROPOSED TYPE III MONITORING INJECTION WELL CONSTRUCTION DIAGRAM JOB NAME: PRECISION FABRICS GROUP, INC. JOB NUMBER: G-6175B WELL NUMBER: OW-3 & OW-3A LOCATION: GREENSBORO, NORTH CAROLINA OW-3A OW-3 COVER ASSEMBLY WITH REMOVABLE STEEL COVER GROUND SURFACE ;: •,..ti CONCRETE LOCKABLE CAP GROUT DEP TO TOTAL B—INCH D1A- BOREHOLE BASE OF DEPTH OF GROUT BOREHOLE 77.0 FT. 150.0 FT- 2—INCH DIA. SCH. 40 PVC RISER & 11 .0 FT. DEPTH TO TOP OF SAND °❑ o0 81.0 & 118.0 FT. ,. TOTAL — BENTONITE SEAL DEPTH °° ° ` - — OF WELL {77-0-81 A FT. °a o t 103.0 & 150.0 FT. (113.0-118.0 FT-) SAND PACK SCREENED 2—INCH DIA. SCH. 40 PVC SCREEN — INTERVAL (01—INCH SLATS} 83-0-103.0 FT. 120.0-150.0 FT. BOTTOM CAP PROPOSED NESTED NOTE: ALL PVC JOINTS ARE OBSERVATION TYPE II FLUSH THREADED giLP WELL DIAGRAM C�ARDLII�TAk- JOB NAME: PRECISION FABRICS GROUP. INC. JOB NUMBER: G-6175B WELL NUMBER: OW-2 & OW — 2A LOCATION: GREENSBORO, NORTH CAROLINA OW-2 OW—ZA r COVER ASSEMBLY WITH REMOVABLE STEEL COVER GROUND SURFACE \�r\fir\l r�l lr�l r\1�\��\ CONCRETE "• '' LOCKABLE CAP GROUT oo DEPTH TO TOTAL 6—INCH DIA. BOREHOLE BASE OF DEPTH OF GROUT 26BOREHOLE .0 FT, 65.0 F"T- 2—INCH DIA. SCH. 40 PVC HENTONITE SEAL (28.0-33.0 FT.) (58.0--63.0 FT.) SAND PACX 2—INCH DIA. SCH. 40 PVC SCREEN (01—INCH SLOTS) BOTTOM NOTE: ALL PVC JOINTS ARE FLUSH THREADED giLP C'AROLINAS & 58Ll FT. I DEPTH TO TOP OF SAND 33.0 & 63.0 FT. TOTAL DEPTH OF WELL 35.0 & 65.0 FT. SCREENED INTERVAL 25.0— 35.0 FT. 45.0-65.0 FT. PROPOSED NESTED OBSERVATION TYPE II WELL DIAGRAM . too 1 1 ATTACHMENT H 1'125DG Scale �: -- T - h -- Approximate Property Boundary ` SOURCE: GREENSBORO, NC 7.5 MINUTE TOPOGRAPHIC QUADRANGLE, 2002 ERM, NC Inc ERM TOPOGRAPHIC SITE LOCATION MAP 301 E MEADOWVIEW ROAD GREENSBORO, NORTH CAROLINA Figure 1A Higglrns S:6. 1►i+��s • 3 � ffAlkr ALve r J I of Avo Approximate Property Boundary SOURCE: Microsoft Corporation (circa 2009) F _ I pC3- i i NOT TO SCALE I SITE LOCATION MAP Figure ERM, NC PC 301 E MEADOWVIEW ROAD 1 ERINI GREENSBORO, NORTH CAROLINA .. 0i e I .r • . - i LAP r w�aC T JW 1 1 �i1W-18 PATTON AVENUE •� �. ww-f ++ Mw-1 + uw*171 jrf ww-5 I 4 mw—H —325 ; y7�M'-3 W 535 mw 11W-1� +mw-8 � LIw12 ++AIW-251 \ AiW—S35 YY1 11 •� WW-2 +5 Alw-2& 271 W*-245 uw-z3s • •RIW-1fi �• W1-22i .• MW-1 WW-2211 '�•�, '4 0 �-2fl �1rw-225 1 ww-210 .. —201 MEgpOWV,L,W 1�0 4 0 WALE W PFE7 ❑ ss so Boa PKFAE UM PLAN } E M NC, PC ABMC`4 O RUP 2A ERM moo, NORTH CAROB NA i few-1a PATTON AVENUE r rr r MYt�l7! A 4 � W-9 —325�e.,,.,, ] �fl,itr ■ Mw A11Y-1 \i\ Mw12 ffIIW-251 MW—;S O •\ MM� ] 1 •\ • Mw—T4 261 g 1Mw-245 >- -271 I..K. fAPW=235 /• i /MW-1a mw-19% uwAf1Y�,2?2i --�•�, 4 A1W-211 ~,___, • fWW-2�' i S"Mw-21 D • —201 LEGFND WADQ WWE' ROAD DRAINAGEMACHINERY PIT AREA FLOOR DRAINAGE LINE SCALE m rW 0 27 50 100 POTENTIAL SOURCE AREAS 1 cum REIEM4AL ACTION PLAN ERNE NC, PC PRECISION FABRICS GROUP 2B GREENSBORO. NORTH CAROLINA .. $ Y i - 14 % • 6 PFC ,1WRES.OIr<. T 30 JC/ PATTON AVENUE A W-1 J MOM ` YAW-13 J - 25 wv-• 5ry_dd _ 1 �. -335 A11Y_} B 12 YAY_25i ww- uw-1 �--+, uw-2 L_ _2 s -245 *AM-zss • mw -16 •�' �• ❑ ►W►r-21i � omw- lw-21D _ of ROAC SCALE N FM CROSS SUCIiax LOCATMN MAP LAN MM K� PC PRE P s � 3 CREENSRMO, NOWM CAS 44A A V) Q v7 M Iq r� rfl n •- n] 010 � cv 7M 779 75B ms IM in M pB fi,a11D. in 54.7 678 ssa eso In 2N 3M 4" sm m LEGEND BEDROCK QUARTZ (FRACTURED) 1 FILACTUREZONE SAPROLCI'k HIGH TRANSMI.SSIVITY P%VR 52,3 TCE CONCENTRATION ZONE(FRAC11TRED) (NS/L) PARTIALLY v WATER LEVEL NS NOTSANIPLFD %i'EATHERE D ROCK = IBB Boo 900 7000 7769 ERM NC, PC FR%l A' ED1,000 µg/ L TCE CONCENTRATION CONTOUR ®10,000 jig/ L TCE CONCENTRATION CONTOUR . 50,000 ugl L TCE CONCENTRATION CONTOUR CROSS SECTION A - A' PRECISION FABRICS GROUP GREENBORO, NORTH CAROLINA In m 30 4w 5M m 7M ] 00 pg/ L TCE CONCENTRATION CONTOUR . SM Rg/ L TCE CONCENTRATION CONTOUR LEGEND BEDROCK (QUARTZ (FRACTURED) —/#— FRACTUREZONE SAPRDLITE HIGH TRANSML%tVM PWR 52.3 TY:ECC�NCEN7RATTON ZONE{FRACTURED� (µg/L) PARTIALLY w WATER LEVEL NS NOTSAMPLED �} ERM NC, Inc. WEATHERED ROCK — LR M CROSS SECTION B-B' PRECISION FABRICS GROUP GREENBORO, NORTH CAROLINA 13 C ne (oo m ry r+y [V (V CV CV rn ._. ------------ rig iM - 721 esa - - ti lie c• 7- 06 ►at SQL see HS - A� fa• 1.000 u81 L TCE cse CONCFNTRAT[ON CONTOUR +p 2w 3" AN SN NO vw aM sM 5,OW µg/ L TCE 1O CONCENTRATION CONTOUR LEGEND Q s�rc w Y(� 6 F7 BEDRCICY (QUARTZ (FRACTURED) FRAC `URE ZONE HIGH TRANSMLS'SIV[TY PWR a �a irXi E7 SAPRO�LiTF 52.3 pg/ CO�NCF �7Tt;117O� ZntiE(rTWCTL�REii) (µ81L) CROSS SECTION Cam' 11AR114I.LY T WATTiR LFVFL NS M'rl-SA-Ml'LE17 �) ERM NC, Inc. PRECISION FABRICS GROUP WEATHERED ROCK — I R N 1 GREENBORO, NORTH CAROLINA F(IIZNII It 5aprolite- Unsaturated Zone - Primarily silty sands and clays. No substantial residual contaminant mass has been indentlfied in the unsaturated zone. Partially Weathered Rock (PWR)- Encountered at 20' BGS in unsaturated zone - Very dense- low hydraulic conductivity Fractured Quartz Zone- Embedded within the PWR at an approx. depth of 40' BGS. Composed of clean, angular, quartz pebbles. Bulk of contaminant mass present in this zone. Generally less than 5' thick. Transition Zone- Between PWR and competent bedrock. Highly fractured, relatively high transmissivity zone. Allows for rapid contaminant transport. Competent Bedrock- Groundwater flow entirely through fractures. Aquifer testing indicates much lower hydraulic conductivity than transition zone. Some contaminant transport through diffusion. ERM NC, Inc SITE CONCEPTUAL MODEL PRECISION FABRICS GROUP GREENSBORO, NORTH CAROLINA SITE CONCEPTUAL MODEL - PLAN VIEW FaulVFracture Zone - Fault or fracture providing vertical flow•path to transition zone Contaminant Plume - Primary contaminant is TCE. Plume is longer than wide. Primary Source Area - (2) ZODO- gallian TCE ASTs formerly in use at the facility (1964 to early 1980s) Groundwater Flow Direction - Groundwater flow at the site is primarily to the south I=igu re i NW-15S (NS) J ' TmmPr Pyrkrrle - A {36�) 5 (NS l 0.76) 0 ON 44:3S MW-24Si (NS) --� UW-19si ~�hf r8lC moils 1 11'iL'.7dplyylcK' Htl1M} � �I I LEGEND ,N- E XISTING SHALLOW MON170RING WELL LOCATION I (30.100) TCE CONCE N TRA 11ON IN ugn IJULY niII f CE ISOCONCENf RAC ION LINE - - .- an T!t]CHLOROE{ HENE IN THE SHAU.OW AQUIFER ERM NC, Inc PREMION FAMCS GROUP 301 EAST MEAWWVMW DUn R M GREENS SMG. NORTH CAROUNA -171 �n rWk a� Trs+irr phi "� ag r'L (X440) ' f u •� [7.3I0 _ 271 % I3•a00} �J J' rorlf +a1c W"Ck)wvicw Rnsd {716} LEGEND N rMSTING TRANSITION ZONE MONITORING WELL LOCATION (30.tOO) TCE CONCENTRATION IN uyL (DULY nIII TCE ISOCONCEN TRA T ION LINE r� TRICHLORCIETHENE I N THE INTERMEDIATE AQUBMR h EIZM NC, Incrr MSION FABRICS GROUP g 301 EAST M -AWN" ew DRIVE Eli M GRffi4sBORp, NORTH CAROIINA MW- I Jso — 4nd r�ilc� p are-�ry� omw- ti it I _g fi O 0 y f + C ,1 II r ° 11 �r�1\ -- {N57ziD Mrv-zoo I Meadow��cK Road �—_�L 0 LEGEND N E xi STING DEEP MONITORING WELL LOCATION I (ao,Ino) ICE CONCENTRAIiON IN VL (Julr a0+1) TCE ISOCONCENINAiION LINE TRICHLOROFMENE IN THE BEEP AQUIM PREaSIOERM NC, Inc MI FAST E�WW FABRICS OUP 10 ERM ORMNSBORO, NORTH CAROURA y Urn murk a� -IW12 (758.7 756 1 $A MH• 41 mw-155 (759.52) MW-ad) [758.60) 57-98} Idw-3i{758.99} , TSl W�� T 2 ' _4 B-3 om' Sh _1Q (NM; =724S, 755 - �� 1 - a , �. (754,79) Y •s \ AIW-t85, ` - F W ?ale 21� 3 (751 1< 7Nraih�Wvlcu Rood 754 20 LEGEND I f157,751 GROUNDWATER ELEVATION IN FEE I IM1SL NOTE: GROUNDWATER ELEVATION DATA COlLECTEO BETWEEN JULV $g AND 75. 2011 c� POTEN ROMEMC SURFACE MAP - SHAUOW AQUff;ER �J ERM NC, Inc PRBCIssaN FABRICS GROUP M, EAST aEEnnoWvIEw DRIVE 11 ERM GREMNS80RO, NORTH CAROLINA - -- aRtl r'�'►er�rkrrrg (758.96 �759.20) �. r 759 0 e(756.79) _ t (757.51)4' . • 757 4 40 r 755 271 75 [3.M 7 •s t-� -- - ---- 211 I --�- ---. {753.62) Mu&%-OL-m R"d - LEGEND {753.06} 1752.4) GROUNDWATER ELEVATION IN FEET MSL NOTE: GROUNDWATER ELEVATION DATA COLLECTED BETWEEN JULY 13 AND 13. 2011 POTENIIOME:TRIC SURFACE MAP - OnM MEDIAT!~ AQUEZER ERM NC, Inc e1 EMION FABIUCE GROUP 12 301 UST &WADOWVMW DRSVL ER M GREENSBORO, MATH CAROLJNA ww-750 (759.34) a x �ri• l'r4ck $ 59 - "d Trailer p$y���R Y s'1 (758.71 ) 57-5 � F5$ f a \ 757- L' � f �� f••♦ r � 7 za 756 — 7 C y � r f % 4 �\ ` 754 MH r ^R 754 "+ . r�YY-18 7 (753.84) s 210 YW-200 1 N Aleadnµ vieµ• Rind (753 ram.•' 753 LEGEND EM.25) GROUNDWATER ELEVAVON IN PEP M51 SCA�c NOTE L'.FiOUNDNfAf ER EL VAiIGN DATA COL LEGTEp BE h+lEEN 7LilY 13 AND +8. 201+ P 70 4P POMr MOMFMIC SURFACE MAP - DEEP AQUIFER PRECISION FABRICS GROUP ERM NC, Inc 301 EAST MRAWWVXEW DRIVE 13 E R M GREMBO$O+ NORTH CAROL NA MW-�2S ®r f Mw-3IS 1 MW-3i I Mw-3 y yi 0f r N I r plw-1 Mw-335/Li� 1 of3-1 I �Mw-z -359' IW-' ' l w_ ` �1 j` "L 7 r AIA � � —3 ire - A 1 iw— 1 0fwit7 [ r ll� I , 1w_�i,_�� omw-36S . 1 l BMW--38� ;. LEGEND PROPOSED INJECTION WELI LOQATION ` / X%7 EXISTING SFsALLOW MONI IORING WELL LOCATIONTCE ISOCONCENTRAT{ON LINEESTIMATED RADIUS OF INFLUENCEE%IS71NG PILOT TEST WELL TO BE USER AS RNP PINJECTION WELL DURING FULL SCALE AL IGAl IONPROPOSER MQNITORING WELL LOCATION FROPOSP-D NEW [NJECnON WELL LOCATION MAP ERM NC, Inc ?RECISION FAARICSGROUP �� 301 EAST W,%DOWVMW DRIVE F R N7 GREMNSWRO. NORTH CAROLD" eru_injecuon tquipment �:.CnemoVC:-uwu d/,4a/um I = I jun RETURN LINE TO TANK GAUGE 300_500 GAL. GATE VALVE GATE VALVE POLY TANK T P T PUMP TOTALIZER TRAILER MOUNTED GATE VALVE (PRESSURE RELIEF VALVE) HIGH PRESSURE FLEXIBLE LINE FE VALVE UNION 17 INJECTION WELL INJECTION EQUIPMENT SCHEMATIC ERM NC, Inc IN-SrrU BIOREMEDIATION TREATMENT SYSTEM 15 PRECISION FABRICS GROUP (PFG) FACILITY ERM GREENSBORO, NORTH CAROLINA wwo �I w-a w,z ®w YW-18 �---- - YW-15S W--4*Ww —9 V _1 —32S mw-3 B �i 1 —335 ,. O9-2 emw a5 25t �`` Ills �1W-271 YW-24SO dM-23S MW-195o ' AQN 211 _ FrCinf ['rate �2�21� A1W— 4. lfradowvicry ko d �,1 7tW2 i I SOLE iN FEET a Yo W � SITE LAYOUT MAP Flcu r ERA+I NC, InC PRS=ON FABRICS GROUP � PAS T ST NPADOWVMW DRIVE E *r GREEIiSBORO, yORTH CAROLDIA SOURCE AREA PRECISION FABRICS GIEOUI' - _ - .13Li11.Ai G •S.ti. ti.S.S. ti of tiftifti•:ti:t�ti:S:{:yti�{�ti�:.titirtilL�ti:ti�tijti.ti: y.ti.ti.y.y.y.ti.y.S.y.S..,..,.y.y.y..y.y.S.y. S.q.ti.y.y.y.y.S. {r :rtirtifti�ti:�:Sr V ERM SITE CONCEPTUAL MODEL - PLAN VIEW Saprolite- Unsaturated Zone - Primarily silty sands and clays. No substantial ® FaulyFracture Zone - Fault or residual contaminant mass has been indentified in the unsaturated zone. fracture providing vertical flowpath to transition zone Partially Weathered Rock (PWR)- Encountered at 20' BGS in unsaturated Contaminant Plume -Primary zone - Very dense- low hydraulic conductivity contaminant is TCE. Plume is Fractured Quartz Zone- Embedded within the PWR at an approx. depth of 40' longer than wide. BGS. Composed of clean, angular, quartz pebbles. Bulk of contaminant mass Primary Source Area - (2) 2,000- present in this zone. Generally less than 5' thick. gallon TCE ASTs Formerly in use at Transition Zone- Between PWR and competent bedrock. Highly fractured, the facility (1964 to early 1980s) relatively high transmissivity zone. Allows for rapid contaminant transport. Competent Bedrock- Groundwater flow entirely through fractures. Aquifer testing mwww�* Groundwater Flow Direction - indicates much lower hydraulic conductivity than transition zone. Some Groundwater Flow at the site is contaminant transport through diffusion.primarily to the south ERM NC, Inc SITE CONCEPTUAL MODEL I Figure PRECISION FABRICS GROUP GREENSBORO, NORTH CAROLINA 3 0 9 � Mw-6 Mw-7 1 r no Mw-33S/(W-1 39 OB-1 08-4 0 L FORMER DRUM - STORAGE AREA---, IW-2 1 1 - • OB-%2 L L FORMER s UNDERGROUND 1 PIPING TO TICE � L STORAGE TANKS rL LEGEND _ l 0 PILOT TEST INJECTION WELL PILOT TEST OBSERVATION WELL i n (B EXISTING MONITORING WELL SCALE IN EEzr FlGU RE PILOT Tarr AREA LAYOUT EItM NC, Inc 301 B hffiAnOwvfw DROM 4 ERM OR NSBORO, NORTH CAROLM ti MW-7 0 Mw-1 1W-2 (37.700/2.380) MW-33S/1W-1 (55,200/3,130)g • OB-2 08-1 (61,000/6,520) D/18,000) • OB-3 (75,300/[500) OB-4 (39,800/16,200) LEGEND a PILOT TEST INJECTION WELL PILOT TEST OBSERVATION WELL [� EXISTING MONITORING WELL (100/52) BASELINE TCE CONCENTRATION (MARCH 2O10)1 MARCH 2O11 TCE MICROGRAMS PER LITER NS NOT SAMPLED IN SCALc ' FIGURE TCE CONCENTRATION IN = KU)IT TEST AREA SRM NC. IxtC 30I E MEADOVVV]EW DRIVE 5 (EREENSBORO, NORTH CAROUNA 100,000 90,000 80,000 70,000 J a 60,000 C O tti 50,000 d O U w 40,000 U 30,000 20,000 10,000 0 3/1/2010 Figure S - Bioremediation Pilot Test Data t-OB-1 tOB-2 —Ar-OB-3 fOB-4 ■ Injection 4/20/2010 619/2010 7/29/2010 9/17/2010 11/6/2010 12/26/2010 2/14/2011 Time MW-32S X ® � x MW-31 S MW-3i 0 MW-3 MW—] MW-335 ®0013-2 0 B-4 03-3 S�rA�T • 0 %W-2 0� Mw-3ss f lMO- 25S l �o x mw 9 LEGEND a / 0 SOURCE AREA CHARACTERIZATION WELL LOCATION y ' EMSTINO SRLLLOW MONITORING WELL LOCATION t SOURCE AREA CHARAC TaWATION WEU [.CxArnON MAP PRECLSION FABRICS GROW ERA�I NC, Inc301 BASF MA WVLEw DRIVE ERM GR WSBORO, NORTH CAROLINA *WW12 PAW-15S (759.52) (7w-40 \ °< (75e.sa) x �w-s ` {759.12} -32S( 0.14) � 759� .f. `m -3 57.98) Mrw3i({5589) 8.89} 09-2 0,% -3 O _ r + emw 758-70 � (Nm) } -N 7591 1 4 25S i1 (757.37) 1' . �...:,� yMr_36� _ 757 757.4 `� Q 7' 756 l »v ve7 y y r r i ` W-27S rn (755.39) - (7N�iW-24S* .01 .000 235 a ■ {75M 54 755 I'� 4 �+�� .I I' i f� POP i I (754.78) I{a b4 - ww-19s® 244. _ 1T} Mraduwvicw T;q� 754 LEGEND (7'.12 M GROUNDWATER ELEVATION IN FEET MSL s[x[ w F-t HOTS OROUNOWATER ELEVAMN OATH CO L Fe'-7'F+7 BETWEEN JULY 13 AND 19. 2Q11 a xa w aso r� PO'TEi+MOM MC SURFACE MAP - SHALLOW AQUIFER �J $ItM NC, Inc PREaS ION FABFUCS GROUP g 301 EAST NW.ADOWVMW DR1vE ERM GR7MfSBORO, NORTH CAROUNA _J 755 9.20) 1 759 02) 757 1 u� 757 Nk % ` t \l 1, �!t 271 �(75ass) Nor a �a .a �211 {753.az] f hf�oyYy "� KO� ��MF-20i__ LEGEND (753.08) (752.25) GROUNDWATER ELEVATION IN FEET NSL _ ir.�E v =E_« NOTE GROUNDWATER ELEVATION DATA C.OLLECrM BETWEEN JULY 13 AM 19. 2011 PQTENMOMEMC SURFACE MAP - UnU MEDIATE AQUUq R EIz1VI NC, IncPREMION FAMCS GROUP 301 Ease &H Amwrlffw DRrVE BRM GREENSB RO, r1MM CAROL NA W#-1'2D (759.34) 75s � 59 {758.71} AIrW— V. r j 7 57.6 4 � 757 r U� �TTVVVl e1y r•� \� �r cir MAL �. refX, yrg r x 754 (753.84) 4� +vnt -- 1dW-210 AM-= Mesdowvi,:,p (753.3$} 50) 753 LEGEND V32.25) GROUNOWATER ELEVATM IN FEET LIST SCALE IN Fur NOTE: GROUN(MATER ELEVArK)N DATA COLLECTED 9ETwEEN 3uLr 13 AND 18, 2011 0 70 W an POTENT'IOMEMC SURFACE MAP - DEEP AQUWM ERM IY Inc 3°N FABMCS aROUP �� `-'+ 301 BAST MLIXOWVMW DWYB ERM GRBBt1SBOR0. NORTH CAROLINA (NS) S 1 3� .. 1-27S 41) WW-24S X ww-195e (NS) -21S* -20 LEGEND Fiasnmo sKALLow momToFtimr. WELL LocAna44 (30, 1 OD) TcE comciENTRATom IN uA (jLLY 2a 11) L- r — TC9 ISOCONC4NTFtATION LINE TRICHLOROMHEn IN THE SHAU.OW AQUMM ERM NC, Inc PRBMION FABRWS GROUP, 1 EAST hCEADOVIVMW DRIVE ERM 30I GREMiSWRO NORM CAKO[MqA � a f �w i -21 - -�_ ---- ---__ {zaa LEGEND ti ® EWSTING TRANSITION ZONE MONITORING WELL LOCATION (30.I0D) TCE CONCENTRATION IN LP- {JLILY 7011) TCE ISODONCENTRATM LINE MUCHWPOMUENE IN nffl M ER AEDiATE AQUm3R ERiN NC, ��.` YRWMON PABWCS GROUP 7 301 EAST IMBADOWV EW DRM ESRM GREENSBORO, NORTH CAROLINA v -1 ) rllk d s o �• Y,Ei. ' V. 1EIE 000 _ s e �d l _ ra�r - -zto 4 vo 11-dmr,mp,R.Q (NS) LEGEND ti ® ewsnkc DFEp YowroRwG wELL LocnnoN (30.100) TCE CONCENTRAnON K ug& puLY 2o1S} :.hi •ti 'E'T TCE LSOCONCENMA71ON UNE 20 w eo �hy TRICHLOROET HENE IN THE DEEP AQUIPM t l N�+ y�C PRBMION FABRICS GROUP �� ■ 30t EASTI�AOOWVffiW DRIVE ERM GRMSBOR0. NORTH CAROE24A M�25 ' 1 ® MW-3 T 5 MW-3i' f ® MW-3 M 0 T �S'o.o 6 1 + 03 A 0 I ®Mw-z ' 0 �c 0 ` 354 lw • f 0 I f )w-- Q n • y �I —14 r Y� �� IW 'r Q 0 'Lptfr lw—TQi _/ t -o� IW— T # p r r %W-365 I ` ` IWp-1 2� LEGEND PROPOSED INJECTIoN WELL LOCATION ExsTm SHALLOW moNITORING WELL LOGinON —. .� TCE 15000NCENTRATION UNE g +j i \ 7S ! I EST"uRAYEDRA01V50FIFFLUET+CE � �� ./` 0 EwSTING PILOT TEST WELL TO BE usED AS AN INJECTION WELL DURING FULL -SCALE RPPLFGTION 9 PROPOSED MONITORNG WELL LOCATION PROPOSED NEW INJEMON WELL LOCAT[ON MAP 4 ERM NC, Inc MECUION FABRICS GPJXT 14 30) FAST MPADOWVERI DRIVE ERM GRPFNSBOAO. NORT}I CAROLINA ��"'����.�, _� .'� •� � :fir '� � -��_ € }JVA. ■ _ �,j p prep i •;fit r� J: }-.e `' ;4. �4 �y' t� i _ _-- A ° 5, a� GRE;ENSBORD N. C. 36019-A7-iF-021951 - 1. D14A 5O56 in SE —SERIES V842 W-Me S' 25370' CAM 2-1-2010 SHEET NUMBm 1 cr 1 PFG SITE GREENSBORO, nc LOCATION MAP REDOX TECH, LLC "0 Q%ok pave, Cmy. NC 27513 Pl o 91M794140 Fu: 919-07&0150 ATTACHMENT H FIGURES rrrgEr�kr CNsg 1 l M u [7 SfO ! r3.00n} yy $4.61 M�adowvfew Road------- (�al LEGEND E)U5r NG TRAINSMON ZONE MONITORING WELL LOCATIGN (A100) TCE CONCENTRATION IN k9k [LILY 2011 ScAu ,a F9T - — TCE ISOCONCENTRATGN UNE 0 20 {C as L TRICHLOROMIELIE IN TIM LVTERMGDIAT@ AQUU:ER Flxar ERM NC ISC PRECISION FABRICS GROUP h r 301 BAST MEADOWYIBW DRIVE 7 E•RM GR ENSBORO. NORTH CAROLINA aw -ale 0 ol IN y r f . C. IN 1 -01 (Ns) d' -- -� rnnr Cair'--.b1iY�2T0 ww-ZDD 0 0. 1 i LEGENO f 1 EX15TING DEEP MONITORING WELL LOCATION I (XIOQ) TCE CONCENTRAT40N IN yqk IJULY Zp111 SGIi >w :EST --- TCE ISOCONCENTRAn ON LINE u zo 4o ea TR[aMOROEMENE IN THE DEEP AQUUER ERM NC, Inc MEM90N FABRICS GROUP 10 301 PASTMPAOOWVMY DRIvH ER -NI GREENSBORO, NORTH CAROLWA �rw—l�s (759, 52) 44W12 (758.; )75s �0, , \\ %W-3 { 758.89} a� �-235 (w754, 754 (754,78)' __ LIW-195 i 22S F+ti,, Ro 754 753.49}- (75�3)lfeudo". N —20 LEGEND I f752231 GROUNDWATER ELEVATION IN FEET hM NOTE: GROUNDWATER ELEVATION DATA COLLECTED BETWEEN .WLY 1] ANO 13. 2011 POTEN-ROME [RIC SURFACE M" - SHALLOW AQLnFER ERM NC. IncPROMIONPA UCSGROUP 301 P1kn&IEADOWVMW OPIVU ERM GREM45BOR0, NORTH CAROLINA 757 _ N41111 Ml1I. r %W-1 r� (758.96) $W 759 .L 9.20) a .02) Q� 0 251 (1515 4151 \' �1757 J ' 1 755 ` ` �J 7 �,„ a y• 754 {r2l l 753 62) M�dnwvicw kox -iABY 2C L {753.V9} LEGEND [752.25] GROUNDWATER ELEVATION IN FEET MSL NOTE: GROUNDWATER ELEVATION DATA COLLECTED 9ETWEEN 3ULY 13 AND 18, 2011 POT=OMETRIC SURFACE MAP - NTERAeD1A•TE AQUWER ERM NC Inc PRECISION FABRICSGRWP I�12 301 Parr DOwvEEw DRIVE EiLm GREENSBORO. NORTH r►Qry WA ot\ 0 0 u 75 �r \t wx r � 754la {F � , a :`•k (753.84) ~� milt --- ILIW-210 hIW—xOn - Meado"d,Rod (753,38) - (753.50) t 753 _�G£4fl �752 25i c;RQUNDWAMR ELEVATION !N FEET BISL 5Cxf ref NOT£; GROUNDWATER ELEVATION DATA COLLECTEO BETWEEN JOLT 13 AND T6, 2011 POMMOMFMC SURFACE MAP - DEEP AQUIFER .. ERM NC Inc1 PRMSXON PABRICS GROUP i r 301 EAST MP�IOOWVlMW DRIVE RM GREM;SBORO. NORTH CAROCAIA uw-r�o (75134) r%4 4Gd r+3rltrq•� 'i55 (758.71) 57.8 � r � �- 757 , C . MW�42S ' � X'}� MW 1 }� -31 S ' MW-3i a Mw-3 1 Mw-1 _ 1w _ MW- 0 j 08 1 0� 1 8 I 3 QS-3 �Jrf2a l �G f iW— 1 ilfi Ile- y r v • t�i -r4 r , �yw ��Y���e 1 -_ _ 5V -- ` Iw1 r� t v rv ,2., i %W-38 - l LEGEND v PROPOSED INJECTION WELL LOCATION _ 1100 ® E70 STING SWALLOW MONITORING WELL LOOATIGN TCE ISOCONCENTRATION UNE � A ESTIhAATEO RADIUS OF INRUENCE 1 � - O EXIS ING PILOT TEST WELL TO BE USED AS AN INJECTION WELL DURING FULL SCALE APPLICATION 'r I� PROPOSED MONTORING WELL LOCATION PROPOSED NEW INJECTION WELL LOCATION MAP ERM NC Inc PRKMION PAMUCS GROUP 14 �rr / 301 EAST MEADOWVMW DRIVE E� ■1 GRMV38ORO. NORTH CAROUNA �iChematic.UWI; b/25/uu 1=i JGu ICT.Wel A RETURN LINE TO TANK GATE VALVE (PRESSURE RELIEF VALVE) 300-500 GAL. GATE VALVE T GATE VALVE POLY TANK PUMP TOTALIZER y TRAItER MOUNTED HIGH PRESSURE FLEXIBLE LINE E fE VALVE UNION INJECTION WEI1. INJECTION EQUIPMENT SCHEMATIC FIGURE , ERM NC, Inc IN -SITU BIOREMEDIATION TREATMENT SYSTEM 15 ERM PRECISION FABRICS GROUP (PFG) FACILITY GREENSBORO, NORTH CAROLINA Expandable locking cap with lock Concrete apron (.3 feet square X 4 inches deep) Top of Casing (TOC) Elevation: feet M 2' Depth to top of bentonite: 31 feet Depth to first slot of screen: 35 feet Borehole diameter 6 1A inches Manhole with bolt down lid Ground Surface Elevation: feet reit1011tlM Type Expansive cement grout (95% Type I Portland cement, 5% sodium bentonite powdeO Number of Bags Unknown Weight of Bags 100 Ibs RISER PTPF Type PVC Diameter 2 inch Length 35 ft n-ANEW" Type Hydrated sodium bentonite Size Medium Number of Bags l Weight of Bags 50 Ibs TyRe PVC Screen Slot 0.010inch Diameter 2 inch Length 10 feet 2$ feet below FILTER SAND 1'- TOC Type Silica Size Medium Number of Ba s 6 _ Weight of Bags 50 lbs Depth to last slot off screen: 45 feet Boring depth `Not to scale 45 feet Well construction measurements are rounded to nearest 0. l font All measurements are From below land surface [BLS] Elevations are from a surveyed datum Groundwater gauging date: 2/2 1l21010 r% Notes Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Grundfos Pump Drilling StardEnd Date 2010/2/20 Well Construction Start/End Date 2010/2/20 KI 4ppr• ERM PROJECT WHSI ,SITE It FIGURE 16 CA B CA B 107830 Dwg Dare: Re>rfsion 0 Precision Fabrics Group Dbservation Greensboro, North Carolina Well�� � Construction Detail ERM NC, INC 1130 Sites Court Raleigh, North Carolina PH: (919) 2334501 FAX: (919) 233-4505 Expandable locking cap with lock Concrete apron (3 feet square X 4 inches deep) Manhole with bolt down lid Top of Casing (TOC) Elevation: feet I ?' Depth to top of bentonite. 31 feet Depth to first slot of screen: 35 feet Borehole diameter 6 1/8 inches 27 feet below ❑ TOC Depth to last slot off screen: 45 feet Baring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0.1 foot All measurements are from below land surface (BLS) Elevations are from a surveyed datum Groundwater gauging date: 2/21/2010 Ground Surface Elevation: feet GROUT Type Expansive cement grout (95% Type I Portland cement, 5% sodium bentonitepowder) Number of Bags Unknown Weight of Bags 100 lbs RtSFR PTPF Type PVC Diameter 2 inch Length 35 ft WFi i_ SFAT Type Hydrated sodium bentonite Size Medium Number of Bags 1 Weight of Bags 50 Ibs SLOTTED SCREEN Type PVC Screen Slot 0.010 inch Diameter 2 inch Length 10 feet FILTER SAND Type Silica Size Medium Number of Ba s 6 Wei ht 01'Bags 50lbs Notes Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Grundfos Pump Drilling Start/End Date 2010/2/20 Well Constriction StartlEnd Date 201W2120 Dwn: Appr= ERAI PROJECT #1HSI SITE # FIGURE 17 C4B CAB 107830 Dwg Date: Revision 9127110 0 Precision Fabrics Group Observation OB—Greensboro, North Carolina Fr ruction Derail ERM NC, INC 1130 Situs Court Raleigh, North Carolina PH: (919) 2334501 FAX: (919) 2334505 Expandable locking cap with lock Concrete apron C 3 feet square X 4 inches deep} -- Manhole with bolt down lid Top of Casing (TOC) Elevation: feet 12' to tot) of bentonite: 31 feet Depth to first slot of screen: 35 feet Borehole diameter 6 118 inches 28 feet below TOC Depth to last slot off screen: 45 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0.1 foot All measurements are from below land surface (BLS) Elevations are from a serve ed datum Ground Surface EIevation: feet GROUT Type Expansive cement grout (95% Type I Portland cement, 5% sodium bentonite pawder) Number of Bags Unknown Weight of Bags 100 lbs RTgFR PTPF. Type PVC Diameter 2 inch Length 35 ft WFr T_ SFAT Type Hydrated sodium bentonite Size Medium Number or Bags I Weigh L of Bags 50 lbs SL(iTTFD SCRFF.N Type PVC Screen Slot 0.010 inch Diameter 2 inch Length 14 feet FTT TFR SAND Type Silica Sire Medium Number of Bags 6 Weight of Bags 50 lbs Notes Well Type Observation Well Drilling Contractor Geologic Exploration Driller Namc Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Gntndfos Pump Drilling Start/End Date 201012120 Well Construction Start/End Tate 201012120 .7 Groundwater gauging date: 2/2112010 Dw►r. Appr: ERAI PROJECT NIHSI.SITE # FIGURE 18 NC INCCAA C B 07830 r 1130 Situs Court Dwg Date: 9 7/1 # Re►-ision a Precision Fabrics Group Greensboro, North Carolina observation well Constructing Raleigh, North Carolina PH: (919) 2334501 FAY: 2334505 �g-7 (919) Detail Concrk [3 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0, l foot All measurements are from below land surface (BLS) Elevations are From a surveyed datum Groundwater gauging date: 2/21/2010 Dwn: Appr: ERAI PROJECT WHSI SITE # CAB CAB 107830 Dwg Date: Revision 9127110 11 Precision Fabrics Group O $r3 Greensboro, North Carolina Surface n: Feet grout and m bentonite Notes Well Type Observation WeII Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist Name Robert f.aumann Drilling Method Air Rotary Development iIiethod Grundfos Pump Drilling Start/End Date 201.0/2120 Well Construction Start/End Date 2010/2/20 FIGURE 19 ERM NC, INC 1130 Situs Court Raleigh, North Carolina Observation Well PH: (919) 233-4501 ( "Instructiorr Detail FAX: (919) 233-4505 Concre (3 feet *Not to scale Well construction measurements are rounded to nearest 0 All measurements are from below land surface (BLS) Elevations are From a surveyed datum Groundwater gauging date: 2/21/2010 Boring depth 45 feet l foot Surface n: feei grout and m bentonite Notes Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist dame Robert Laumann Drilling Method Air Rotary Development Wetbod Grundfos Pump 1 Drilling Start/End Date 201012120 Well Construction Start/End Dale 201012120 Djvn rlppr. C 8 F. RM PROJECT #IHS1 SITE # 107830 FIGURE 20 E � INCC18 ' 1130 Situs Court Raleigh, North Carolina PH: (919) 233-4501 Drvg Dale: 9127110 Revisiwi 0 Precision Fabrics Group Greensboro, North Carolina Observatiom Weit D O D_4 Construction FAX: (919) 233-4505 Detail Depth to top of bentonite: 29 feet Depth to top of send: 31 feet Depth to first slot of screen: 35 feet Borehole diameter. 6'/." Depth to last slot of screen: 45 feet Own: Appr: AOD I 8H Dwg Date: Revision 7/11/2011 0 Boring depth: 45 feet ERM PROJECTft 0138869 Precision Fabrics Group Greensboro, North Carolina GROUT: Type: Expansive cement grout (95% Type I Portland cement, 5% sodiurn ber+tonite powder) RISER PIPE: Type- PVC Diart-Aler 2 t h ID Lengh 3S h WELL SEAL: Type, Hydrated sodium t�entorite Size- htediurn SLOTTED SCREEN Type PVC Size: 4.010 D-arre:e- 2 inch Leno:h- loft FlLTE1 SAND Type: Spica Sand Size; 20-d0 Wel i Type: Drtllirg Contfactor: Dnller Name- Geo"isls Name Drillirg MwtxA, Development Method: DrAirg Stagy End Date: Well Construction Start End date: Minmoring Well Geologic Explornor,. Johnny Bur* Ch"S Means Par Rotary Pumping 201 VV09.201 V7110 201 I;TM9-2011;7110 FIGURE 21 ERM NC, Inc 1130 Situs Court Raleigh, North Carolina Monitoring PH: (919) 233-4501 Well PAX: (919) 233-4505 Depth to top of bentonite: 29 feet Depth to tap of sand: 31 feel Depth to first slot of screen: 35 feet Borehole diameter. 6'•�' Depth to last slot of screen: 45 feet ❑wn: Appr: AOD BH Dwg Date: 7/11/2011 Revision 0 MW-35S Boring depth. 45 feet ERM PROJECT # 0138869 Precision Fabrics Group Greensboro, North Carolina GROUT: Type- Expansive cement grout (95% Type I Parttand cement. 5% sodium bentonile powder) RISER PIPE: Type• PVC Dian-7tFx: 2 inch 0 Lenq:h 35 f1 4YELL SEAL: Tyne Hydraled sodium bemrx ke Site: hirxiiurn SLOTTED SCREEN Type: PVC Size: 0.010 Deamaler 2 inch Leng:h 10 P. FILTER SAND Ty,,m: Silica sand sire: 20-40 Vlell Type: Drilling Con:raruor Dnllw Name- Geot Ism Name ❑nlliny hlettxxl: Oeystopmem Method Drilling Star• --End Date: Well Corstaiclipr Star' End Date: Monitoring Well Geokgfc Explorwior. Johnny Burr Chas Moans Air Rotary Pumping 20111M1 201117r i 0 2011 V09-201 V71 l 0 FIGURE 22 ERM NC, Inc 1130 Situs Court Raleigh, North Carolina Monitoring PH: (919) 2334501 Well FAX: (919) 233-4505 Depth to top of bentonite. 29 feet to top of sand: 31 Feet Depth to first slot of screen: 35 feet Borehole diameter B'/," Depth to last slot of screen: 45 feet ❑wn: Appr: AOD I BH Dwg Date: 777sion 7/11/2011 0 M W-345 Boring depth: 45 feet ERM PROJECT # 0138869 Precision Fabrics Group Greensboro, North Carolina GROUT. Type Expansive cement grout (95% Type I Portland cement. 5% sodium bentomte pawd(-1 RISER PIPE: Type- PVC Diansew 2 inc)i ID Length 35 h WELL SEAL: Type- Hydrated sac9tim ben:onile Size. Medium SLOTTED SCREEN Type: PVC Size: 0.010 D4ame?er 2Irch Lengl.h' 10 f1 FILTER SAND Typo: Silica Sand Size' 20-40 Well Type: Drilling Canvac[or: Dnller Name' Gaokxyisls Name. Drilling hletlUd. Development Method: Drilling Start. -End Date. Well OwslniGlion Start End Date' Nbnhoring Well C.eo;cgic Exploration Johnny Burr Chris Adeans Air Rotary Fumping 201 VV09-201117E 10 201 1;7109.201 V7310 FIGURE 23 ERM NC, Inc 1130 Situs Court Raleigh, North Carolina Monitoring PH: (919) 233-4501 Well FAX: (919) 233-4505 Depth to tap of bentonite: 29 feet Depth to top of sand-- 31 feet Depth to first slot of screen. 35 feet Borehole diameter- h '/:' Depth to last slot of screen: 45 feet Boring depth. 45 feet GROUT- Type: Expansive cement grout (95% Type I Pordand cemenk. 5% sodium beMonile powder) RISER PIPE: Type- PVC Dwrrxf?rV 2inch ID Lengh 3511 WELL SEAL: Type: Hydrated sodium bewor lte Size: Medium SLOTTED SCREEN Type: PVC size: 0,010 Diameter 2 inch Length 10 tt FILTER SAND Type; Silica Sand Size: 20-40 Neil Type: Dniting Cors;maor: Dnliw Name: Geologists Narnm Dri5ing Mctfuxi- Deveioprnent Method: Drilling Start End Date: Wall Corsin,ction Start End Cale: Monitoring Shell Geologic Explora;ior Jdnnny Burr Chns Means Air Rntary Pumping 2011M'D9 201 1; 7110 2011iVM201 VV10 Dwn: Appr: ERM PROJECT # FIGURE 24 ERM NC, Inc AOD BH 0138869 1130 5itus Court Dwg Date: Revision Raleigh, North Carolina 7/11/2011 0 Precision Fabrics Group Monitoring PH: (919) 233-4501 MW-37S Greensboro, North Carolina Well FAX: (919) 2334505 Expandable locking cap with lock Concrete apron Manhole with bolt down lid (3 feet square 3{ 4 inches deep} Top of Casing (TOC) Elevation; feet 31' Depth to top of bentonite: 31 feet Depth to first slot of screen: 35 feet Borehole diameter 5 1/8 inches Ground Surface EIevation: feet GROUT Type Expansive cement grout (95% Type l Portland cement, 5% sodium bentonitepowder) Number of Bags Unknown Weight of Ba s 100 lbs RISFR PIPE Type PVC Diameter 2 inch Length 35 R WFt.i. SFAI. Type Hydrated sodium bentonite Size Medium Number of Bags 1 Weight of Bags 50 Ibs Si.0TTFr) SCRFFN Type PVC Screen Slot 0.010 inch Diameter 2 inch Length 10 feet 28 feet below FILTER SAND 12' TOC Type Silica j - Size Medium ill Number of Ba s b Wei1ThtofBags 50lbs Depth to last slot off screen: 45 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0.1 foot All measurements are from below land surface (BLS) Elevations are from a surveyed datum Groundwater gauging date: 2/21/2010 Dwn: CA .•i ppr: CA 8 I Divg Date: Revision Typical (IW-2) ERN PROJECT #IHSI SITE # Precision Fabrics Group Greensboro, North Carolina Notes Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Grundfos Pump Drilling Start/End Date 201012I20 . Well Construction Start/End Date 201012l20 J FIGURE 25 ERM NC, INC 1130 Situs Court Raleigh, North Carolina PH: (919) 233-4501 FAX: (919) 233-4505 Observation Well Construction Detail Expandable locking cap with lock Concrete apron (3 feet square X 4 inches deep) Manhole with bolt down lid Ground Surface Top of Casing (TOC) Elevation: fee[ Elevation: feet 12, to ton of bentonite: 31 feet Depth to first slot of screen: 35 feet Borehole diameter 6 118 inches 28 feet below SZ roc Depth to last slot oft screen: 45 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0.1 foot All measurements are from below land surface (BLS) Elevations are from a surveyed datum Groundwater gauging date: 2/21/2010 GROUT Type Expansive cement grout (95% Type I Portland cement, 5% sodium bentonitepowder) Number of Bags Unknown Weight of Bags 100 lbs RiSFR PiPF Type PVC Diameter 2 inch Len th 35 ft WELL SEAL Type Hydrated sodium bentonite Size Medium Number of Bags 1 Weight of Bags 50 lbs SLOTTED SCREFN Type PVC Screen Slot 0.010 inch Diameter 2 inch Length 10 feet FILTER SAND Type Silica Size Medium Number of Ba s 6 Weight of Bags 50 lbs Notes Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Gmndfos Pump Drilling Start/End Date 201012120 Well Construction StartlEnd Date 2010/2/20 Dwtr: Appr. ERM PROJECT #1HS1 SITE # FIGURE I C•i8 CAB 107830 Dwg Date: Revising 9127110 0 Precision Fabrics Group Observation �y Greensboro, North Carolina well IW—G Construction Detail ERM NC, PC 1130 Situs Court Raleigh, North Carolina PH: (919) 233-4501 FAX: (919) 2334505 Expandable locking cap with lock Concrete apron (3 feet square X 4 inches deep) Top of Casing (TOC) Elevation: feet 2' Depth to top of bentonite: 31 feet Depth to first slot of screen. 35 feet Borehole diameter 5 1/8 inches Manhole with bolt down lid Ground Surface / Elevation: feet GROTIT Type Expansive cement grout (95% Type I Portland cement, 5% sodium bentonitepowder) Number of Bags Unknown Weight of Bags 100 lbs 1r1I.M2,201a21 Type PVC Diameter 2 inch 1 Len th 35 fi Type Hydrated sodium bentonite Size Medium Number of Bags l Weight of 13a s 50 lbs SLOTTED SCREEN TvDe PVC Screen Slot 0.010 inch Diameter 2 inch Length 10 feet 27 feet below FILTER SAND i TOC Type Silica Size Medium Number of Bags G Weight of Bags 50 lbs Depth to last slot off screen; 45 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0.1 foot All measurements are From below land surface (BLS) Elevations are from a surveyed datum Groundwater gauging date: 2/21/2010 Notes Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Grundfos Pump Drilling Start/End Date 201012120 Well Construction Start/End Date 201012120 D)vn: CAB Appr: CA ERM PROJECT #/HSI SITE # 107830. FIGURE I ERM NC, PC 1130 Situs Court Raleigh, North Carolina PH: (919) 233-4501 FAY: 233-4505 Divg Date: 9127110 Revision Precision Fabrics Group Greensboro, North Carolina Observation well Co►s&ucdon O$_1 (919) Detail Expandable locking cap with lock Concrete apron [3 feet square X 4 inches 7dccp)Top of Casing (T Elevation: feet h to tap ofbentonite: 31 feet Depth to first slot of screen: 35 feet Borehole diameter 6 1/8 inches Manhole with bolt down lid Ground Surface Elevation: feet 6ROUT Type: Expansive cement grout (95% Type I Portland cement, 5% sodium bentonitepowder) Number of Bags Unknown Weight of Bags 100 lbs RISER PIPE Tyve PVC Diameter 2 inch Length 35 ft WF1_1. GF.AT. Type Hydrated sodium bentonite Size Medium Number of Bags 1 Weight of Bags 50 lbs 5LOTTED SCREEN Type PVC Screen Slot 0.010 inch Diameter 2 inch Length 10 feet 28 feet below FILTER SAND l ' ❑ TOC Type Silica Size Medium Number of Ba s 6 Weight of Bags 50 lbs Depth to last slot off screen: 45 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0.1 foot All measurements are from below land surface (BLS) Elevations are from a surveyed datum Nntec I I Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Grundfos Pump Drilling StaWE-nd Date 201012/20 Well Construction Start/End Date 2010/2/20 Groundwater gauging date: 2/21/2010 Dwn. Appr: ERM PROJECT WHSI SITE # FIGURE I CAR CA 107830 ERAII NC, .PC &vg Date: Revision 1130 Situs Court 0 D Precision Fabrics Group 06servurion Raleigh, North Carolina Greensboro, North Carolina well PH: (919) 233-4501 O$_2 Construction FAX: (919) 233-4505 Retail Expandable locking cap with lock Concrete apron Q feet square X 4 inches deep) Top of Casing (TOC) ILievation: feet a 0 Depth to top of bentonite: 3 l feet Depth to first slot of screen: 35 feet Borehole diameter 6 118 inches Manhole with bolt down lid r Ground Surface Elevation: feet CI RO11T Type Expansive cement grout (95% Type I Portland cement, 5% sodium bentonitepowder) Number of Bags Unknown Wei ht of Ba s 100 lbs RiRFR PiPF Type PVC Diameter 2 inch Length 35 ft WFt t GFAi. Type Hydrated sodium bentonite Size Medium Number of Bags 1 Weight of Bas 50lbs SLOTTFDSCREEN Type PVC Screen Slot 0.010 inch Diameter 2 inch Length 10 feet F 29 feet below FILTER SAND 12, V TOC Type Silica Size Medium Number of Ba s 6 Weight o f Ba s 50 lbs Depth to last slot off screen: 45 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0. l foot All measurements are from below land surface (BLS) Elevations are from a surveyed datum Groundwater gauging date: 2/21/2010 Natec I I Well Type Observation Well Drilling Contractor Geologic Exploration DrillerName Terry Watkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Grundfos Pump Drilling Start/End Date 2010/2/20 Well Construction StartlEnd Date 2010/2/20 Dwtt: (AB Appr: C is ERM PROJECT #IHSI SITE # 107830 FIGURE I EPM NC, PC 1130 Situs Court Raleigh, North Carolina Dwg pale: Revision Observation 9 7/10 Precision Fabrics Group Greensboro, North Carolina well Construction PH: (919) 233-4501 FAX: 2334505 ^ B_3 V (919) Detail Expandable locking cap with lock Concrete apron (3 feet square X 4 inches 7deep)Top of Casing (T Elevation: feet Depth to top cif bentonite: 31 feet Depth to first slot of screen: 35 feet Borehole diameter 6 118 inches Manhole with bolt down lid Ground Surface Elevation: feet rH i61Um Type Expansive cement grout (95% Type I Portland cement, 5% sodium bentonitepowder) Number of Bags Unknown Weight of Bags 100 lbs RISER PIP£ Type PVC Diameter 2 inch Length 35 ft WFEL GFAi. Type Hydrated sodium bentonite Size Medium Number of Bags l Weight of Bags 50 lbs Type PVC Screen Slot 0.010 inch Diameter 2 inch Length 10 feet 28 feet below FILTER SAND I'- TOC Type 'Silica Size Medium Number of Bags 6 Weight of Bags 50 lbs Depth to last slot off screen: 45 feet Boring depth *Not to scale 45 feet Well construction measurements are rounded to nearest 0. l foot All measurements are from below land surface (BLS) Elevations are from a surveyed datum Groundwater gauging date: 2/21/2010 Nntec Well Type Observation Well Drilling Contractor Geologic Exploration Driller Name TerryWatkins Geologist Name Robert Laumann Drilling Method Air Rotary Development Method Grundfos Pump Drilling StartlEnd Date 201012/20 Well Construction StartlEnd Date 2010I2120 Dwn. Appr., ERM PROJECT #1H.SI .SITE # FIGURE 1 CAB CAB 107830 Dwg Date: Revision # 0 Precision Fabrics Group Observation Greensboro, North Carolina well O$-4 Construction Detail ERM NC, PC 1130 Situs Court Raleigh, North Carolina PH: (919) 233-4501 FAX: (919) 233-4505 1 Depth to top of bentonite: 29 feet Depth to tap of sand: 31 feet Depth to first slat of screen: 35 feet Borehole diameter: 6 %' Depth to last slat of screen: 45 feet Own: Appr' AOD I El 1 Dwg Date: Revision 7/1112011 0 GRouT Type: Expansive rament grout (95% Type I Partiand camera, 5% sodium bentonBe powder) RISER PIPE: Type: PVC Diameter 2 inch ID Length 35 h WELL SEAL Type- Hydrated sodium herl:onite Size' Med -urn SLOTTED SCREEN Type: PVC Size: 0.010 Diameter 2 inch Length 10 tt FILTER SAND Type: Silica Sand Size: 20-40 Well Type: Drilling Contractor: Drillrr Name: Guolog ss Na" Drilling Method' Development Method: Drilling Start End Date: Well Construction Start End Date: Boring depth: 45 feet Monitoring watt Geo"ic ExploraLa- jolinny Burr Chris Means Alt Rotary Pumping 20 t 117;D9-201 V7110 201 VVWL-201 1I7i 10 ERM PROJECT # FIGURE 1 ERM NC, Inc 0138869 1130 situs Court Raleigh, North Carolina Precision Fabrics Group Monitoring PH: (919) 233-4501 Greensboro, North Carolina Well FAX: (919) 233-4505 Depth to top of bentonite: 29 feet Depth to top of sand: 31 feet Depth to first slot of screen- 35 Beet Borehole diameter 6 %" Depth to last slot of screen: 45 feet ❑wn: Appr: ADD I BH Dwg Date: Revision 7/11/2011 0 MW-35S Boring depth: 45 feet ERM PROJECT # 0138869 Precision Fabrics Group Greensboro, North Carolina GROUT - Type, Expansive cement grout (95% Type i Portland cement, 5% sodium benlonite posudef) RISER PIPE: Type: PVC Diameter: 2 inch ID Length 35 n WELL SEAL: Type- Hydrated sodium ben:onite Size: Medium SLOTTED SCREEN Type' PVC Size: 0.010 Orameter 2 inch Length- 1011 FILTER SAND Type: Silica Sand Size- 20-40 Well Type: Monitoring Well D illir+g Contractor Geologic Exploration Dnller Name Johnny Burr Geo"isas Name Chris Moans Dnli" Moll -CA: Air Rotary DevokiWent Method: Pumping Drilling StarvEnd Oate- 201117J09-201 V7110 Welt Construction Start End Date- 2011/7109-201 Will FIGURE 1 ERM NC, Inc 1130 sites Court Raleigh, North Carolina Monitoring PH: (919) 233-4501 Well FAX: (919) 233-4505 1 Depth to top of bentonite: 29 feet to top of sand: 31 feet Depth to first slot of screen. 35 feet Borehole diameter 6 '/a" Depth to last slot of screen: 45 feet Own: Appr: AOD I 8H Dwg Date: Revision 7/11/2011 0 MW-345 GROUT Type: Expansive cement grout (95% Type I Portland cement. 5% sodium bentonite powder) RISER PIPE- Type- PVC D+aniaw- 2 inch Id Length 35 h WELL SEAL- Type Hydrated sodium bewonite Sipe- Medium SLOTTED SCREEN Type: PVC Size- 0.01C Diameter- 2 rrch Lengib- 10 h FILTER SAND Type Stirs Sand Size: 2040 Well Type: Drilling Contractor Driller Name: Geologists Name: Drilling AAelhod Developrnent Method: Drilling StarllEnd Date: Well Construction Stan End Date: Boring depth: 45 feet Monitoring Well GeohVic EVIarstior Johnny Burr Chris Means Air Rotary Pumping 201117A)9.201117110 201117109-20t 1I7! 10 ERM PROJECT# FIGURE 1 ERM NC, Inc 0138869 1130 situs Court Raleigh, North Carolina Precision Fabrics Group Monitoring PH: (919) 233-4501 Greensboro, North Carolina Well FAX: (919) 233-4505 Depth to top of bentanite- 29 feet Depth to top of sand- 31 feet Depth to first slot of screen 35 feet Borehole diameter 6 1/:' Depth to last slot of screen: 45 feet Dwn: Appr: ROD I BH Dwg Date: Revision 7/11/2011 0 MW-37S Boring depth: 45 feet ERM PROJECT # 0138869 Precision Fabrics Group Greensboro, North Carolina GROUT: Type: Ecparsive r_ement grout (95�� Type I Portland cement, 5°S Sodium bentnnite powder) RISER PIPE Type r'VC Dwnater- 2 inch 10 Length 35 ft WELL SEAL: Type Hydrated sodium ben:orite Size: Medium SLOTTED SCREEN Type PVC Size: 0 010 Diameter 2 ir%ch Length 1011 FILTER SAND Type: Silica sand Size: 20-40 Well Type- Drillirg Contractor- Driller Name- Geait kis Name: Drilling Method - Development Method: Drillirg Start(End Date: Well Con5trurtion Start End Date - Monitoring Weil Geolc+jic Exptoratior Johnny Burr Ctvis Mears An Rotary Pumping 201 V710&201117110 201117109-201 117110 FIGURE 1 ERM NC, Inc 1130 situs Court Raleigh, North Carolina Monitoring PH: (919) 233-4501 Well FAX: (919) 233-4505 DOCUMENTS ASSOCIATED WITH THE ORIGINAL PERMIT APPLICATION (MARCH 20, 2008) _'•{ it 1 i � [ i �:. r4 fy � _• ti r } I p { 1► l '� 1f { is Ll F. xJ 4� Y ' u 10 ay TIElip AP �s-�•'• M1 µ- _ - 1 r. �-1- .. ... rt fir -_ .iP 1 iV -�iice, �/ � � .�• �f �.. ,' - •r I i �-7 w ,l �• a.. r,. r"r � - i y ti � r ` � �' .' r'•T fir, lk - ``- Rf. •�� E �*�. � - it . .. lk _ { Ski r. ■- r w a a p I w� 4 ! • r `•f 14.iJf . i Ar ul - �� � �' "` .'' ir* �� "-' ■'_ 4`` F . r •' •ice - - : ter± . fir. �►, � 1 SCALE (IN ter),_-- - - FIGURE 1 1000 2000 ��- SITE LOCATION MAP 200Q v PRECISION FABRICS GROUP, INC. 301 E. MEADOWVIEW ROAD REFERENCE: USGS TOPOGRAPHIC MAP LP GREENSBORO, NORTH CAROLINA GREENSBORO, NC QUADRANGLE - DATFLD 14ri1 PRnTnRV.VTgPn I QQ4 CAROLINAS ECS PROJECT G-6175B EXPLANATION OF GEOLOGIC CROSS SECTION m MW-18 LQ+ ATIU FhN AV AE : 6. �. FILL - GRAVEL, CLAY, SILTY SAND .. AND COAL CINDERS, SCALE (IN FEET) 60 120 WW-t5d MW-I5s Q-{� SAPROLITE - CLAY, CLAYEY SILT, SANDY SILT AND SILTY SAND. NOTE; SAND CONTENT GENERALLY INCREASES WITH DEPTH. JNW-17i N 120 PARTIALLY TO MODERATELY WEATHERED ROCK - SILT ` SAND MIXED WITH SMALL PIECES OF WEATHERED RLA Mw-5 AND WHITE GRANITE OR PINK AND WHITE GRANITE. REFERENCE: ASPHALT PAVING NOTE: TOP OF PARTIALLY WEATHERED ROCK IS MW cl� �� w-q' WHERE GREATER THAN 50 BLOWS/6 INCH MATERIAL LOCATIOPLAN AND WELL NS NS PROVIDED BY O W-13 ENCOUNTERED. BPA ENVIROMENTAL & RES Vatic ' �Z �� 0" BEDROCK - METAMORPHOSED GRANODIOR'TE OR ENGINEERING, INC. x MW-3i CGRANnE. m -6 M W-3 E TO MW-7 SOFTFSIER MONFRlNG WELL BCONCRETE Mw-I BvmDING DOUBLE CASED MONITORING WELL H MT WS 1� -2 DEC 12 MW-10 = SCREENED INTERVAL w GFALOGIC CONTACT {I]ASIiEI7 WHERE INFERRED) M W-12 WATER TOWER V _ WATER •TABLE^ (NOVEMBER 1999) PRECISION FABRICS GROUP, INC. VVwJJ TD TOTAL DEPTH ASP T METAL PAVING BUILDING ,a s =E Mw-1I LLP METAL CAROLINAS BUILDING D. W-14 FIGURE 2 LOCATION OF CROSS Mw-24% A' SECTIONS ado PRECISION FABRICS GROUP, c� Mw-z3s GREENSBORO, NC � E AJ MW-16 Mw-z2i mvd,-19s ry -Ai PROJECT NO. G-6175B T MW-21d MW-22d MW-2I9 MW-22s MW-21s e - -2Dd W-wi E' BRAWN BY/DATE -2D-+ D. A 60 120 ;PHALT PAVING WI0-2 15 07 v CHECKED BY/BATE SCALE IN FIST l3 FILENAME: 6175BFIG3 t NW A BOO Mw_9 MW-13 MW 780 mw-155 �� _• �.� � ° r 1uI9V-15d 7{"" 760 iv=siFr= '�= 36 FT.•. 740 700 680 -p :, 03 FT. rho _, 0 rw 12❑ 180 MV-7 Mw-1 mw-Z •'�-• .p'.a •,-11: �►'-•9. i•■••fir. 0',^, ��.+',� —�- SCALE (IN FEET) SE 60 120 A' 900 120 0 REFERENCE: 780 SITE PLAN AND WELL LOCATIONS PROVIDED BY BPA ENVIROMENTAL & ENGINEERING, INC. - 760 110 I�9' 111�`L 720 W 700 jE1 IV- s w LLP CAROLINAS TD - 100 FT. FIGURE 3 686 GEOLOGIC CROSS SECION A -A' PRECISION FABRICS GROUP, INC. GREENSBORO, NC escs 300 3k 420 480 540 660 W 720 780 840 WO M 1,020 PROJECT NO. G-6175B DISTANCE IN FEET DRAWN BY/DATE WIO-2/15/07 CHECKED BY/DATE FILENAME: 6175BFIG3 12 Luu, z 0 F C SCALE (IN FEET) NW 5E 60 120 B B' 800 800 120 p MW-g MW-12 MW-lI - REFERENCE: 780 780 SITE PLAN AND WELL MW-20d LOCATIONS PROVIDED BY A IQN S HPA ENYIROME NTAL - ENGINEERING. INC. 760 760 TD �.33 FT. TA 32 :..;.: ';µ•• �1 N S • ' ''� '"''' w 740 •� ' - • 7411 ta .�` , a. :,- fir. - 4 ::•� .`vim`/���j}~ ....'; ' ,'.. • w ': :r � :+ `� ..] 41, giLLP .1 7DO 700 CAROLINAS FIGURE 4 680 - 480 GEOLOGIC CROSS 71) 99 Fr- SECION B-B' PRECISION FABRICS GROUP, INC. GREENSBORO, NC 660 0 b0 120 180 240 N0 360 420 480 w 600 660 720 781) 8440 DISTANCE 1H FEET PROJECT NO. G-6175D DRAWN BY/DATE WIO-2/15/07 CHECKED BY/DATE { FILENAME: 6175BFIG NE w E SCALE (IN FEET) D D' 60 120 E El UK) 8i]0 8IH] Mimi 120 O MW-22d NSW-23s MW-24s m w-14 REFERENCE: 780 l.4w-2?3 713U M 1V-20d 780 780 MW-16 MW-19s MR+-21d MW 20d SITE PLAN AND WELL LOCATIONS O S PROVIDED BY SPA ENVIROMENTAL & =;ti -�_. RI ENGINES G N INC. 76 0 • �'. 7G0 .•1,r •.,;• 7G0 7G0 `r. S TD — 35 lo _ C 'TD 4d = OfD, .1 r• 740 740 h W LQ 740 — 740 Lia a w ?�, w z x a z x o - _ Lu 720 el 14, CSLLP - -'. -'• CAROLINAS _I - - 8n 680P(Sr—REENED 101 M 690 ;•�;::':680 FIGURE E TD = 9B,75 rr. GEOLOGIC CROSS rag 100 �+- SECION D-D' AND E-E' = 1S0 . PRECISION FABRICS GROUP, TD ' k15 � INC. sE,u Gso tNrRvAl = is Fr.) GREENSHOROr NC G 110 230 350 48p SGO 624 — 5 S 0 120 240 36fl 4SU D157APNCE IN FEET DISTANCE IN FEET PROJECT NO. G-6175B DRAWN BY/DATE WIO-2/15/07 CHECKED BY/DATE FILENAME: 6175BFIG3 LEGEND - - - - - = APPROXIMATE PROPERTY LINE = FENCE ■ = SHALLOW MONITORING WELL s = INTERMEDIATE MONITORING WELL % = DEEP MONITORING WELL = GROUNDWATER CONTOUR LINE - - = INFERRED CONTOUR LINE = GROUNDWATER FLOW DIRECTION (769.10) = GROUNDWATER ELEVATIONS (10/24/ Nu = NOT MEASURED / NW-1 WAS NOT USED TO CALC' GROUNDWATER FLOW DIRECTION Q° 0 Mill STOCKHAUSEN 0 4 1[W 14 + m + {7 55- 7) ■ + -24S 89) PRECISIPN FABRICS GROUP, INC. `NEW ADDMON(760 {7sn.97) im 4 Y11-15D brw--195■ -] WW-4 (758-70 0 1 v -17i A PHALT PA IGNG + + zrv-23sw \\ 7 mw SCALE (IN FEET) lw 75 15❑ r--- 1 150 0 REFERENCE: SITE PLAN AND WELL LOCATIONS PROVIDED BY BPA ENVIROMENTAL & + I ENGINEERING, INC. 4 75) , + _�0 755.04) (755,90) -21 x Vw-21 9 44 1[1f-lo % 1rw-18 Ix ASPHALT PA G 1[rr-a + s■ 1�r--i2 44 x x f �� A 4 - x x x x K - x DO STREET mcLLP CAROLINAS FIGURE 7 GROUNDWATER ELEVATIONS IN THE SHALLOW WATER TABLE AQUIFER PRECISION FABRICS GROUP, INC. GREENSBORO. NC PROJECT NO. G-6175B DRAWN BY/DATE WIO-2/15/07 CHECKED BY/DATE FILENAME: 6175BFIG 3 1 LEGEND = APPROXIMATE PROPERTY LINE FENCE = SHALLOW MONITORING WELL s = INTERMEDIATE MONITORING WELL % = DEEP MONITORING WELL = GROUNDWATER CONTOUR LINE - - = INFERRED CONTOUR LINE = GROUNDWATER FLOW DIRECTION (757.24) = GROUNDWATER ELEVATIONS (10/24/06) " = NOT MEASURED MW-7 WAS NOT USED TO CALCULATE GROUNDWATER FLOW DIRECTi 41 STOCKHAUSEN 1iM-18 ti DOS \1: a PRECISION x GROUP, INC. ADDITION 1 j --158 l ~i till 5{76 1) I l[11-15D l[lf-4 -17i (759.97) (780.09) 1 lx A HALT PAVING r ii11-17+ + l(W—\24S�S � , A ASPHALT PARKING 3S + -Eli x cb +� 60>fw 12 l % x f AA Q.. rrAA In All - x % � x x - x x x STREET 19) SCALE (IN FEET) 75 150 150 O REFERENCE: SITE PLAN AND WELL LOCATIONS PROVIDED BY BPA ENVIROMENTAL & ENGINEERING, INC. 6 N*S A EELP CAROLINAS FIGURE 8 GROUNDWATER ELEVATIONS IN THE INTERMEDIATE WATER TABLE AQUIFER PRECISION FABRICS GROUP, INC+ GREENSBORO. NC PROJECT NO. G-6175B DRAWN BY/DATE IYIO-02/15/07 CHECKED BY/DATE FILENAME: 6175BFIG4 LEGEND --------- = APPROXIMATE PROPERTY LINE FENCE = SHALLOW MONITORING WELL ti = INTERMEDIATE MONITORING WELL % = DEEP MONITORING WELL = ISOCONCENTRATION CURVE = INFERRED ISOCONCENTRATION CURVE = NOT SAMPLED AS PART OF THIS INVESTIGATION (25 7) = PCE CONCENTRATIONS (ppb) (HQL) = BELOW QUANTIFATION LIMIT Ppb = PARTS PER BILLION=UG% ug/L = MICROGRAMS PER LIT Q 0 STOCKHAUSEN 0 brW-18 ti D0YLB I `i 4 I� i. I STREET lrly-24S ($QL ASPHALT PARKING /ef 1 lnr-m 0 (BQi MW-22D % MW 221 lfw`m • l -9 L] • l2w- (BQL) ASPHALT PAVING PRECISION FABRICS GROUP, INC. ADDMON ! r xwRB % MW-12 (BQL) H11-11 • (BQI RL =1�16: td �A (8QL)liN'-215' 0 �VW--221i� 0 1IW-19S a+� (NS) i SCALE (IN FEET) 75 150 150 O REFERENCE: SITE PLAN AND WELL LOCATIONS PROVIDED BY BPA ENVIROMENTAL & ENGINEERING, INC. N+ s mcsL`P CAROLINAS FIGURE 9 PCE CONCENTRATIONS IN THE SHALLOW WATE TABLE AQUIFER PRECISION FABRICS GROUP, INC. GREENSBORO. NC PROJECT NO. G-6175B DRAWN 13Y/DATE UBS/08-01-06 CHECKED BY/DATE FILENAME: 6175AFIG5 LEGEND - - - - = APPROXIMATE PROPERTY LINE -- = FENCE • = SHALLOW MONITORING WELL '• INTERMEDIATE MONITORING WELL % = DEEP MONITORING WELL A = MONITORING WELLS ARE DESTROYED -z = ISOCONCENTRATION CURVE' INFERRED ISONCONCENTRATION CUR rvs = NOT SAMPLED AS PART OF THIS INVESTIGATION 34.0 = PCE CONCENTRATION (ppb) 4 BQL = BELOW QUANTITATION LI S ppb = PARTS PER BILLION= L ug/L = MICROGRAMS PER R Q 0 111 STOCKHAUSEN M I fill-1U +-� UT=� . ASPHALT \ PARKING + + if gas ■ )Dm+ 0 IM-3 lflf-R• + (BQL)lill-ml li\:;2-%o1 + - BQL) - PRECISION FABRICS i) GROUP, INC. • 0 mw-2 (0+68)xv 81i 1 ■ 10 NEW ADDITION -1 20 NW-11 iill-6 • A j lid 15 D ■s lilt -18.5 • `d I 5 ]ill--4(NS) Ix -17i 34,0) E- 1 1¢ W lilt-1B 1+ mr-18 x HALT PAVI G I` x % 1 I + �`■ -12 x " 5 �x lx � 4 x Dp 5ET SCALE (IN FEET) 75 150 150 0 REFERENCE: SITE PLAN AND WELL. LOCATIONS PROVIDED BY BPA ENVIROMENTAL & ENGINEERING, INC. Ir ,s EcsLLP CAROLINAS FIGURE 10 PCE CONCENTRATIONS IN THE INTERMEDIATE WATER TABLE AQUIFER PRECISION FABRICS GROUP, INC. GREENSBORO, NC PROJECT NO. G-6175B DRAWN BY/DATE MBS/08-01-06 CHECKED BY/DATE FILENAME: 617 5AF'I G 6 LEGEND - - - - - = APPROXIMATE PROPERTY LINE -- = FENCE • = SHALLOW MONITORING WELL s = INTERMEDIATE MONITORING WELL ti = DEEP MONITORING WELL NS = NOT SAMPLED AS PART OF THIS INVESTIGATION :3.700) = PCE CONCENTRATION (PPB) ���� BQL = BELOW QUANTITATION LIMITS P� ppb = PARTS PER BILLION = ug/L 6'R ug/L = MICROGRAMS PER LITER 4R�a WE ll STOCKHAUSEN Q O ME lilt-18 (NS)% o " /+ SCALE (IN FEET) + 75 150 1n►-14 ti + + 15❑ O - + REFERENCE: + ASPHALT \ PARKING SITE PLAN AND WELL LOCATIONS PROVIDED BY bfW-23S\ BPA ENVIROMENTAL & m'-22Dti( L) ENGINEERING, INC. lilt-22i i E w-3 lilt-s mw-P\ t itN_ N LS s li►-zD + _ BQQ MR-20DBQQ w PRECISION Q ull-1 FABRICS " GROUP, INC. i fill-9 iiM-21i W + \ -2 NEW ADDITION ` -15S lit►-11 A fill-15D \d lill-195\ EgLLP 5: lill-4 E- 1" -17i W CAROLINAS l � 1 �s� e ti l" ASPHALT PAVING FIGURE 11 ww l PCE CONCENTRATIONS + \ Y"-12 ` IN THE FRACTURED BEDROCK PRECISION FABRICS GROUP, 1" INC. GREENSBORO, NC PROTECT NO. G-6175B DRAWN BY/DATE MBS/08-01-06 _ CHECKED 13Y/DATE STREET FILENAME: 6175AF1G7 LEGEND - - - - - = APPROXIMATE PROPERTY LINE — — FENCE • = SHALLOW MONITORING WELL S = INTERMEDIATE MONITORING WELL % = DEEP MONITORING WELL = ISOCONCENTRATION CURVE = INFERRED ISOCONCENTRATION CURVE Ns = HOT SAMPLED AS PART OF THIS INVESTIGATION (21,700) = BQL = PCE CONCENTRATION (PPB) , BELOW QUANTITATION LIMITS �� ppb = PARTS PER BILLION = ug/L 1�4 ug/L = MICROGRAMS PER LITER 4LAy,� I 710 Q O 0 inr-18 ti SCALE (IN FEET) 75 150 15❑ O + lnr-14 % + REFERENCE: SITE PLAN AND WELL bfW-245 (B LOCATIONS PROVIDED BY + ASPHALT \ BPA ENVIROMENTAL & PARKING * ENGINEERING, INC. + mw10 - j NW-10 d mw-m 100 N (-S � S 1[ll- �LIVV 2, (1.2 , .. lq w mw_ mw-2 , + gyp, (2 ! J00 (2. ] -20�" "f7 + -20 21.700) IO a IC WW- I tr INC. 17. NEW ADDITION 1 i5s �nr-ii Q l NW-5 {�pl 1w-15D [ % �NSJS' CARCLINAS lMW-4 E- I% -171 LIO w FIGURE 12 TCE CONCENTRATIONS ASPHALT PAVING `% IN THE SHALLOW WATE] inr-8 TABLE AQUIFER + s'i ilW-12 l PRECISION FABRICS GROUP, (BQL) INC. x x GREENSBORO, NC PROJECT NO. G-6175B y DRAWN BY/DATE I NRR/08-01-06 1, CHECK BY/DATE x FILENAME: 6175AP IG8 LEGEND - - - - - = APPROXIMATE PROPERTY LINE = FENCE ■ = SHALLOW MONITORING WELL = INTERMEDIATE MONITORING WELL % = DEEP MONITORING WELL A Z(8,290) = TCE CONCENTRATIONS (ppb) ' = ISOCONCENTRATION CURVE �O = INFERRED ISOCONCENTRATION CU} NS = NOT SAMPLED AS PART OF THIS INVESTIGATION BQL = BELOW QUANTITATION LIMITS ppb = PARTS PER BILLION = ug/L ug/L = MICROGRAMS PER LITER Q O it'll STOCKHAUSEN 0 1rw-1a ti mll 1tW-14 ti„+ + \(N3 uw- s + ASPHAL\ PARKING + PRECISION FABRICS GROUP, INC. NEW ADDITION 1 -15s % hfw-5 YR-15D •b 11W-4 (NS) x -17I f fq7 Rl 1[II'-11 • + NW-23S• 40 VW-201 hfw-2a MY-20 A 4 0 BQL 1I11-21 :D 1[R-19S • F. (NS) Q W 11 >rw-18 ASPHALT PAVING l x yww-8 ( I IL x x l` l l% I■ 4 r x - x � x y x � * x S'TRF'ET SCALE (IN FEET) 75 150 �—mo� 4 150 ❑ I ZIA 91:4 ZI �@ Uej 3 SITE PLAN AND WELL. LOCATIONS PROVIDED BY BPA ENVIROMENTAL & ENGINEERING, INC. N H S S UJ A 93LLP CAROLINAS FIGURE 13 TCE CONCENTRATIONS IN THE INTERMEDIATE WATER TABLE AQUIFER PRECISION FABRICS GROUP, INC. GREENSBORO, NC PROJECT NO. G-0175B DRAWN BY/DATE NRR/Oa-ol-OS CHECKED BY/DATE FILENAME: 6175AFIGP LEGEND - - - = APPROXIMATE PROPERTY LINE FENCE • = SHALLOW MONITORING WELL S = INTERMEDIATE MONITORING WELL DEEP MONITORING WELL NS = NOT SAMPLED AS PART OF THZS,,, INVESTIGATION (I1,400)= TCE CONCENTRATIONS (ppb)Ppb = PARTS PER BILLION = ug/L BQL = BELOW QUANTITATION LIMITS ug/L = MICROGRAMS PER LITER ¢Y� Q° 0 Ell STOCKHAUSEN �OYLE uw-l0 +;_ • mw- 1{w- w + - 11,400) 1I11-1 + 0 l -155 ww-5 Yw-15D •d {BQL} 1<w_4 -171 i (KS)MW-14 % PRECISION FABRICS GROUP, INC. ADDMON • + ww-m ASPHALT PARKING + + Hw-23S 0 uw-22D % ) lilt-221 K- • 1(w-80 {1,05 } a BQL „ lnr-as � uw-2li -2 ❑ w I y„ ASPHALT PAVING {} I I„ Y + 50 MW-12 `y x x 5 jx lx `� I l �r l f�' r y x - 4 •� r STREET SCALE (IN FEET) 75 150 SITE PLAN AND WELL LOCATIONS PROVIDED BY BPA ENVIROMENTAL & ENGINEERING, INC. CAROLINAS FIGURE 14 TCE CONCENTRATIONS IN THE FRACTURED BEDROCK PRECISION FABRICS GROUP, INC. GREENSBORO, NC PROJECT NO. G-6175B DRAWN BY/DATE NRR/06-01-06 CHECKED BY/BATE FILENAME: 6175AFIG 10 WJb WOO 93 ERM NC, INC. December 21, 2012 David Goodrich UIC Program - Aquifer Protection Section North Carolina DENR - DWQ 1636 Mail Service Center Raleigh, NC 27699-1635 Phone (919) 733-3221 Subject. Injection Event Record Precision Fabrics Group (PFG) Greensboro, North Carolina UIC Permit Number WI0400093 Dear Mr. Goodrich: 8000 Corporate Center Drive Suite 200 Charlotte, NC USA 28226 704541-8345 Please find attached an injection event record for the referenced injection of Anaerobic BioChem (ABC) into the subsurface at the Precision Fabrics Group facility in Greensboro, North Carolina. The ABC was injected to treat volatile organic compound impacted groundwater. Please call if you have any questions. Sincerely, ram' Ed Hollifield, P.G. Project Manager Attachment - Injection Event Record RECEIVEDIDENHWO DEC 2 7 20$2 Aquifer Protection Sedon INJECTION EVENT RECORD North Carolina Department of Environment and Natural Resources -- Division of Water Quality Permit Number WID400093 1. Permit Information Precision Fabrics Group, Inc. Permittee Precision Fabrics Group (PFG) Facility Name 301 East Meadowview Road Greensboro, NC 27406 Facility Address 2. Injection Contractor Information ERM NC, Inc. Injection Contractor 1 Company Name Street Address 8000 Corporate Center Drive Charlotte NC 28226 City State Zip Code 704 678-0140 Area code --- Phone number 3, Well Information Number of wells used for injection 12 IW-1,0-2, os-411W-%!W-5, IW-4, rW-11, IW-12, Well names IWS, IW-101 M-9,1W-71 Iw-6 Were any new wells installed during this injection event? ❑ Yes ❑ No If yes, please provide the following information: Number of Monitoring Wells Number of Injection Wells Type of Well installed (Check applicable type): ❑ Bored ❑ Drilled ❑ Direct -Push ❑ Hand -Augured ❑ Other (specify) Please include hvo copies of form +GW-I b for each vCl1H1G RNAMell installed. t Were any wells abandoned during this injection event? ❑ Yes ❑■ No If yes, please provide the following information: Number of Monitoring Wells Number of Injection Wells Please include h4,o copies of the GW-30 far each well abandoned. 4. Injectant Information Anaerobic BioChern (ABC) Injectant Type 1,100 Ih ABC in 600 gal per location Concentration If the injectant is diluted please indicate the source dilution fluid. Total Volume Injected 7 , 200 gals Volume Injected per well 6Q0 gals 5. Injection History Injectiondates)419/10712/l /10, 10/5/12 Injection number (e.g, 3 of 5) 3 of 4 Is this the last injection at this site? ❑ Yes 0 No I DO HEREBY CERTIFY THAT ALL THE INFORMATION ON THIS FORM IS CORRECT TO THE BEST OF MY KNOWLEDGE AND THAT THE INJECTION WAS PERFORMED WITM THE STAND S LAID OUT I THE PERMIT. z z46tfE__ 4elza b Z. 5I t, 9 XT 0 RF, UF 90ECTI UT CONTRACTOR DA THE t, Submit the on nai f rm to the Division of Water Quality within 30 days of injection. A ail Service Center, Raleigh, NC 27699-1635, Phone No. 919-733-3221 Form UIC-IER Rev. 07/09 ;n NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Charles Wakild, P.E. Dee Freeman Governor Director Secretary March 9, 2012 Lee Aiken, Director of Manufacturing Services Precision Fabrics Group, Inc. P.O. Box 214448 Greensboro, NC 27420 Ref; Issuance of Injection Permit WI0400093 Precision Fabrics Group, Inc. Facility 301 Fast Meadowview Road Greensboro, Guilford County, North Carolina. Dear Mr. Aiken; In accordance with the application received on February 2, 2012, and the supporting data received February 20, 2012 and March 1, 20I2, we are forwarding permit number WI0400093, This permit is to inject Anaerobic BioChem (ABC), Dehalococcoides bacteria (DHC), and Magnesium Hydroxide or Sodium Hydroxide for the enhanced bioremediation of chlorinated solvents at the facility referenced above. This permit shall be effective from the date of issuance until February 28, 2014, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII — MONITORING AND REPORTING REQUIREMENTS, Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. Please note that the permit requires the construction of a new deep monitor well near the location of existing well MW-36S, and the inclusion of this well and existing well MW-22D in the quarterly monitoring program, You will need to notify (his office by telephone 48 hours prior to initiation of operation of the facility. In order to continue: uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. Please contact me at 919-807-6352 or at david.goodrich@ncdenr.gov if you have any questions about your permit. Best Regards, David Goodrich, L.G. I lydrogeologist �L. L3d tVJII hll lbiil, Yl k1jaLULl-..]�N��lI tl b& 111,Lk �-•I tn. Janet MacDonald, Division of Waste Management-Superfund Section Beau Hodge, PG, ERM NC, PC, 1 130 Situs Court, Suite 250, Raleigh, NC 27606 W10400093 Permit File AuulrER t,Kvk0INN sLu j 04 1636 Mail Service Center, Raleigh, North Carolina 27699.1635 Location_ 512 N Sallsbury St., Raleigh, North Carolina 27664 One Phone' 919.8Q7-B4ti41FAX, 919-807.6496 N tliCarolina Internet: mm.nmateraualfty.ore An fpual Opporllm41 Affvmalive AeIon Employer atu }� �" 111 Goodrich, David From: Knight, Sherri Sent: Monday, March 12, 2012 4 28 PM To: Goodrich, David Subject: RE: WSRO Comments on Precision Fabrics injection permit WI0400093 I have read the staff report and concur with the requested information. Sherri Knight, PE. NC DENR Winston-Salem Regional Office Division of Water quality, Aquifer Protection Section 585 Waughtown Street Winston-Salem, NC 27107 Voice: t336j 771-5280 FAX: (336) 771-4632 E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Goodrich, David Sent: Monday, March 12, 2012 1:30 PM To: Knight, Sherri; Wang, Shuying Subject: WSRO Comments on Precision Fabrics Injection permit WI0400093 Sherri, We received your office's comments on the Precision Fabrics Injection Permit. However, they did not include your signature. Could you send me a brief message confirming your approval of the comments? Thank you! Regards, David Goodrich Office Telphone Number: (919) 807-6352 Aquifer Protection Section Main Number: (919) 807-6464 Fax Number: (919) 807-6496 Goodrich, David From: Goodrich, David Sent: Thursday, March 01, 2012 9:32 AM To: 'Beau Hodge' Subject: RE: Injections at the Precision Fabrics Group Site Mr. dodge: Thank you for clarifying the situation for me. The permit application package appears to be missing Figures 3, 4, and 5 (and possibly others). Attachment H begins with Figure 9. Please send me these Figures electronically or by mail at your earliest convenience. Thank you. Regards, David Goodrich Aquifer Protection Section Central Office Office Telphone Number: (919) 807-6352 Aquifer Protection Section Main Number: (919) 807-6464 Fax Number: (919) 807-6496 From: Beau Hodge fmailto:Beau. Hodge@erm.coml Sent: Wednesday, February 29, 2012 8:50 AM To: Goodrich, David Cc: Aiken, Lee Subject: RE: Injections at the Precision Fabrics Group Site The new permit is intended to replace the original remediation strategy. The original strategy was a barrier approach with the 44 wells and was never performed. ERM revised the approach to a source area remediation with the well designation as stated in the recently submitted report. Sorry for any confusion and thank you for the prompt response on the application. Beau Hodge, PG ERM NC, Inc. 1130 Situs Court, Ste 250 Raleigh, NC 27606 Phone: (919) 233-4501 Cell: (919) 802-1558 One Planet, One Company, ERM From: Goodrich, David[mailto:david.goodrichC&ncdenr.gov] Sent: Wednesday, February 29, 2012 8:38 AM To: Beau Hodge Subject: Injections at the Precision Fabrics Group Site Mr. Hodge: Goodrich, David From: Goodrich, David Sent: Thursday March 01. 2012 2:56 PM To: 'Allison Dugan' Subject: RE. Figures for Infections at the Precision Fabrics Group Site Dear Ms. Dugan: Thank you and Mr. Hodge for your rapid response to my request. I will be In contact if I need anything further, Regards, David Goodrich Aquifer Protection Section Central Office Office Telphone Number: (919) 807-6352 Aquifer Protection Section Main Number: (919) 807-6464 Fax Number: (919) 807-6496 From: Allison Dugan [mailto:Ailison,DuganPaerm.com] Sent: Thursday, March 01, 2012 1:07 PM To: Goodrich, David Cc: Beau Hodge Subject: Figures for Injections at the Precision Fabrics Group Site Dear Mr. Goodrich: Beau Hodge asked me to forward to you the attached figures you requested that were missing from the Permit Application for PFG. Please let me know if you need any additional information. Beau will follow up with you this afternoon to answer any additional questions you may have. Thank you Allison Dugan ERM NC, Inc (919) 2334501 This electronic mail message may contain information which is (a) LEGALLY PRIVILEGED, PROPRIETARY IN NATURE, OR OTHERWISE PROTECTED BY LAW FROM DISCLOSURE, and (b) intended only for the use of the Addressee (s) names herein. If you are not the Addressee (s). or the person responsible for delivering this to the Addressee (s), you are hereby notified that reading. copying, or distributing this message is prohibited. If you have received this electronic mail message in error, please contact us immediately at (704) 541-8345 and take the steps necessary to delete the message completely from your computer system. Thank you. ERM NG, Inc- To: Goodrich, David Cc: Knight, Sherri; Jennifer Byrd Subject: RE: MSDS Sheets for the Precision Fabrics Injection Permit David, I have attached the MSDS sheets for the materials you requested. Please let me know if this is sufficient or if we need to send by mail. Beau Hodge, PG ERM INC, Inc. 1130 Situs Court, Ste 250 Raleigh, NC 27606 Phone: (919) 233-4501 Cell: (919) 802-1558 One Planet, One Company, ERM From: Goodrich, David mailto:david, oodrich ncdenr. ov Sent: Monday, February 20, 2012 10:38 AM To: Beau Hodge Cc: Knight:, Sherri Subject: MSDS Sheets for the Precision Fabrics Injection Permit Mr. Hodge: The Aquifer Protection Section is in receipt of the application for an injection permit at the Precision Fabricsfacility in Greensboro, NC. In order to perform our review, we need Material Safety Data Sheets far each of the proposed injectant substances (ABC, Dehalococcoides bacteria, and Magnesium Hydroxide and / or Sodium Hydroxide (both, if it is undecided which hydroxide chemical will be used). Thank you for your assistance. Regards, David Goodrich Aquifer Protection Section Central Office Office TeIphone Number: (919) 807-6352 Aquifer Protection Section Main Number: (919) 807-6464 Fax Number: (919) 807-6496 This electronic mail message may contain information which is (a) LEGALLY PRIVILEGED. PROPRIETARY IN NATURE, OR OTHERWISE PROTECTED BY LAW FROM DISCLOSURE, and (b) intended only for the use of the Addressee (s) names herein. If you are not the Addressee (s), or the person responsible for delivering this to the Addressee (s), you are hereby notified that reading, copying, or distributing this message is prohibited. If you have received this electronic mail message in error. please contact us immediately at (704) 541-8345 and take the steps necessary to delete the message completely from your computer system. Thank you. ERM NC, Inc. Goodrich, David From: Wang, Shuying Sent: Tuesday, February 21, 2012 5:15 PM To: Beau.Hodge@erm.com Cc: Knight, Sherri; Goodrich, David Subject: RE: MSDS Sheets for the Precision Fabrics Injection Permit Hi Mr, Hodge, Your application does show concentrations of VOCs decreasing after two injection events of ABC and DHC. However, there is no data to show whether the injection had any negative impact on groundwater in transition zone and bedrock. Although it is unlikely that the injection had any affects on deeper wells because of the distance between deeper wells and the injection wells and the limited injection area, I would like to have a copy of the last groundwater monitoring report prepared after the completion of the pilot injection to look at if it should be concerned. Could you pass me a copy of the report? If this message is not clear, please call me at 336-771-S287. Thank you! Shuying Wang Hydrogeologist NC DENR Winston-Salem Regional Office Division of Water Quality, Aquifer Protection Section 585 Waughtown Street Winston-Salem, NC 27107 Voice: (336) 771-5000 FAX: (336) 771-4631 or 771-4632 shuyl ng . wa nQ@ncdenr.gov http.ZZpo rta I. ncd e n r.o rp,lwe b/wglaps E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties. **************** From: Knight, Sherri Sent, Tuesday, February 21, 2012 11:34 AM To: Wang, Shuying Subject: FW: MSDS Sheets for the Precision Fabrics Injection Permit Sherri Knight, PE NC DENR Winston-Salem Regional Office Division of Water Quality, Aquifer Protection Section 585 Waughtown Street Winston-Salem, NC 27107 Voice: (335) 771-5280 FAX: (335) 771-4532 E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Beau Hodge mailto,Beau. Hod a erm.com Sent: Monday, February 20, 2012 11:33 AM Goodrich, David From: Beau Hodge [Beau.Hodge@erm.com] Sent: Wednesday. February 29, 2012 8:50 AM To: Goodrich, David Cc: Aiken, Lee Subject: RE: Injections at the Precision Fabrics Group Site The new permit is intended to replace the original remediation strategy. The original strategy was a barrier approach with the 44 wells and was never performed_ ERM revised the approach to a source area remediation with the well designation as stated in the recently submitted report. Sorry for any confusion and thank you for the prompt response on the application. Beau Hodge, PG ERM NC, Inc. 1130 Situs Court, Ste 250 Raleigh, NC 27606 Phone: (919) 233-4501 Cell: (919) 802-1558 One Planet, One Company, ERM Frorrt: Goodrich, David fmailto:david.goodrichOncdenr.gov] Sent: Wednesday, February 29, 2012 8:38 AM To: Beau Hodge Subject: Injections at the Precision Fabrics Group Site Mr, Hodge: I am drafting the new injection permit for the subject facility in Greensboro. The original injection permit, issued on March 27, 2008, allowed the injection of HRC into 44 injection wells. It is unclear as to whether these proposed injections were ever performed. The documents associated with the current permit submission make reference to a pilot tests on two injection wells in April of 2010 and December of 2010. The eleven injection wells proposed in the current permit application have the same name designations as the originally - proposed wells. Please inform me as to whether the originally -proposed injections were ever performed, or if the new permit is intended to "replace" the original remediation strategy. Thank you. Regards, David Goodrich Aquifer Protection Section Central Office Office Telphone Number: (919) 807-6352 Aquifer Protection Section Main Number: (919) 807-6464 Fax Number: (919) 807-6496 Ake NCDENR North Carolina Department of Environment and Uovernor Director February 14, 2012 Lee Aiken -- Director of Manufacturing Services Precision Fabrics Group, Inc. PO Box 214448 Greensboro, NC 27420 Dear Mr. Aiken: Natural Resources Subject: Acknowledgement of Application No. W10400093 Precision Fabrics Group, Inc. Greensboro Facility Injection In situ Groundwater Remediation Well (51) System Guilford County Secretary The Aquifer Protection Section acknowledges receipt of your permit application and supporting documentation received on February 2, 2012. Your application package has been assigned the number listed above, and the primary reviewer is David Goodrich. Central and Winston-Salem Regional Office staff will perform a detailed review of the provided application, and may contact you with a request for additional information. To ensure maximum efficiency in processing permit applications, the Aquifer Protection Section requests your assistance in providing a timely and complete response to any additional information requests. Please note that processing standard review permit applications may take as long as 60 to 90 days after receipt of a complete application. If you have any questions, please contact David Goodrich at (919) 807-6352 or david.goodrich@ncdenr.gov. Sincerely, a Ok �'&a'u for Debra J. Watts Groundwater Protection Unit Supervisor cc: Winston-Salem Regional Office, Aquifer Protection Section Beau Hodge, P.G. R.S.M. -- ERM NC, PC Permit File WI0400093 1636 Mail Service Center, Ralegh, North Carolina 27699.1636 Location: 512 N. Salisbury St., Raleigh, NoM Carolina 27604 Phone: 919-807A4641 FAX: 919-807.6495 Internet www.nmatercualHy.om One NorlhCarolina An Equal Opponunily k Afl9rmative Aaron Er l)"r DOCUMENTS ASSOCIATED WITH THE ORIGINAL PERMIT APPLICATION (MARCH 20, 2008) �LdP GgRQL-INA>S ECS CAROLINAS, LLP _ _ Geotechnical • Construction Materials Environmental Mr. Qu Qi NCDENR - Division of Water Quality LUC Program 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Reference: Injection Well Diagrams Precision Fabrics Group, Inc. Facility 301 East Meadowview Road Greensboro, Guilford County, North Carolina Site ID# NONCD 000 1020 ECS Project 09.61755 Dear Mr Qu Qi: March 11, 2008 ECS Carolinas (ECS) is pleased to submit the following injection well diagrams and explanation per our recent telephone conversation. The site is the Precision Fabrics Group, Inc. (PFG) textile manufacturing facility located at 301 East Meadowview Road in Greensboro, North Carolina. During our telephone conversation, there was some confusion as to the number and construction of the proposed injection wells installed or to be installed at the site. The attached Injection Well Diagrams (intermediate and Deep) should clarify the proposed well installation for the pending injection permit. Currently, there are three intermediate depth (70 feet deep) injection wells (IW-1, IW-2 and IW-3) and three deep (150 feet deep) injection wells installed at the site. The existing wells were installed as part of a HRC injection pilot study (UIC Permit No. WI0400028). ECS has proposed to install an additional 19 intermediate depth and 18 deep injection wells for a total number of 43 injection wells. As indicated on the Plat included with the injection permit application, the new intermediate depth injection wells will be designated IW-7, IW-9, IW-12, NV-14, IW-16, IW-18, IW-20, IW-22, NV-24, AV-26, NV-28, IW-30, IW- 32, IW-34, IW-36, IW-38, IW-40, IW-42,and IW-44. The new deep injection wells will be designated IW-8, IW-10, AV-13, IW-15, IW-17, 1W-19, IW-21, IW-23, IW-25, IW-27, IW-29, IW-31, IW-33, IW-35, AV-37, IW-39, IW-41and IW-43. Please note the use of packers in the proposed injection wells. In order to get a more uniform distribution of the HRC injectant across the entire screened interval, ECS proposes the use of packers to inject % of the product in the lower half of the screen and %: in the upper half. MAR 13 2008 4811 Koger Boulevard ■ Greensboro, NC 27407 • (336) 856-7150 • Fax (336) 856-7160 Injection Permit Well Diagrams Precision Fabrics Group Facility Greensboro, North Carolina ECS Project 09.671 SB March 11, 2008 We are pleased to have the opportunity to offer our services and look forward to working with PFG and the NCDENR on this project. We appreciate your timely attention to this injection permit request. If you have any questions or comments concerning the contents of the enclosed documents or other related topics, please feel free to contact us. Respectfully submitted, ECS CAROLINAS, LLP eallje�5kl- Randy H. avallier Project Geologist Attachments: Proposed Intermediate Type III Injection Well Construction Diagram Proposed Deep Type III Injection Well Construction Diagram JOB NAME: PRECISION rABRICS GROUP, INC. JOB NUMBER: G-6175B l►1A11Wt$j� --_Iof.a LOCATION: GREENSBORO, NORTH CAROLINA GROUND SURFACE CONCRETE LOCKABLE CAP GROUT 6—INCH DIA. 2—INCH DIA. SCH. 80 PVC RISER 5—INCH DIA. .188 GALVANIZED RISER 35.0 FT. 2—INCH DIA. SCH. 80 PVC SCREEN (04—INCH SLOTS) — BENTONITE SEAL (33-38 FT.) — PACKER SAND PACT{ IQ r,mw f)3i NOTE: ALL PVC JOINTS ARE FLUSH THREADED COVER ASSEMBLY WITH REMOVABLE STEEL COVER DEPTH TO BASE OF GROUT 33.0 FT. )EPTH TO TOP OF SAND 38.0 FT. TOTAL DEPTH OF BOREHOLE 70.0 FT. TOTAL DEPTH OF WELL 70.0 FT. INJECTION INTERVAL — _ 40.0-54.0 SCREENED INTERVAL 40.0-70.0 FT. _ INJECTION INTERVAL 55.0-70.0 rc &LP CAROLINAS PROPOSED INTERMEDIATE TYPE III MONITORING INJECTION WELL CONSTRUCTION DIAGRAM JOB NAME: PRECISION i ABRICS GROUP, INC. J013 NUMBER: G--6175B vain l""W31:1043 LOCATION: GREENSBORO, NORTH CAROLINA COVER ASSEMBLY WITH REMOVABLE STEEL COVER GROUND SURFACE ° .: �'• '_;e':. CONCRETE LOCKABLE CAP DIA. BOREHOLE �� N �. TO \/ �\OF Is 80 ` f I GROUT IN" 's DIA. .188 GALVANIZED RISER r Fr. 2-INCH DIA. SCH. 80 PVC SCREEN (.04-INCH SLOTS) BENTONITE SEAL (93-98 FP.y PACKER SAND PACK BOTTOM NOTE: ALL PVC JOINTS ARE FLUSH THREADED DEPTH TO TOP OF SAND 98.0 FT. 11 1 TOTAL DEPTH OF BOREHOLE 150.0 FT. TOTAL DEPTH OF WELL 150.0 FT. _ ..: T INJECTION INTERVAL, 100.0-125.0 SCREENED INTERVAL 100.0-150.0 FT. INJECTION INTERVAL —_ 126.0-150.0 CAROLINAS PROPOSED DEEP TYPE III MONITORING INJECTION WELL CONSTRUCTION DIAGRAM ECS CARGNAS, LLP E§7 LIGeotechnical - Construction Materials - Environmental CAROLIHAS To: QU ❑i NCDENR-DWQ (UIC Program) 1636 Mail Service Center Aquifer Protection Section Raleigh, NC 27699-1636 We are sending you the following items via: FedEx Priority LETTER OF TRANSMITTAL Date; 12-11-07 TProject No. 09:6175B Re: Precision Fabrics Group, Inc. 301 East Meadowview Road Greensboro, NC DE[' 1 Z Zuti, COPIES DATED I DESCRIPTION 2 11-20-07 1 Revised Application for Permit to Construct Wells for Injection These are transmitted as checked below: x For your use As requested REMARKS Attached is our report for the above referenced site. Please sign below indicating that you have received our report. For questions or comments regarding this report, please contact Randy Cavallier. III ' �a Cathy L. r Environ " tal Administrative Assistant Received bv: Date: 4911 Koger Boulevard - Greensboro, NC 27407 - (336) 856-7150 - Fax (336) 856-7160 Michael F. Easley. Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Nature! Resources December 14, 2007 LEE AIKEN PRECISION FABRICS GROUP, INC.. 301 MEADOWVIEW ROAD GREENSBORO, NC 27406 Subject: Acknowledgement of Application No. W10400093 Precision Fabrics Group Injection in situ Groundwater Remediation Well (5I) Guilford County Dear MR AIKEN: Coleen H. Sullins Director Division of Water Quality The Aquifer Protection Section of the Division of Water Quality (the Division) acknowledges receipt of your permit application and supporting materials on December 12, 2007. This application package has been assigned the number listed above and will be reviewed by Qu Qi. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions, please contact Qu Qi by phone at (919) 715-6935 or by email at qu.gil'a,ncmail.net. If the reviewer is unavailable, you may leave a message, and they will respond promptly. Also note that the Division has reorganized. To review our new organizational chart, go to hM-�Lh2o.enr.state.nc.us/documents/dwq Mchart. df. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT. Sincerely, C IZWL �..f I For Debra J. Watts Supervisor cc: Winston-Salem Regional Office, Aquifer Protection Section Permit Application File W10400093 Randy Cavallier - FCS Carolinas, LLP, 4911 Koger Blvd., Greensboro, NC 27407 Aquifer Protection Section 1636 Mail Service Center Internet' www.ncwatUguali1y.,QM Location: 2728 Capital Boulevard An Equal OpportunilylAffimative Action Ernpbyer 50% Recycledil0% Post Consumer Paper N?; Carolina Xaturally Raleigh. NC 27699-1636 Telephone: (919) 733-32-11 Raleigh, NC 27604 Fax 1; (919) 715-0588 Fax 2. (919)715-6048 Customer service: (877) 623-6748 AQUIFER PROTECTI.ON SECTION` APPLICATION REVIEW REQUEST FORM FFB } 5 2012 Date: Febrauary 14, 2012 a: ❑ Landon Davidson, ARO-APS ❑ David May, WaRO-APS ❑ Art Barnhardt, FRO-APS ❑ Charlie Stehman, WiRO-APS ❑ Andrew Pitner, MRO-APS X Sherri Knight, WSRO-APS ❑ Jay Zimmerman, RRO-APS David Goodrich, Land Application Unit $ n 7 - 6 Y 9 6 Telephone: (g 19) 7+.'mH-(Y2 $ g!� 7 - 6 3 S z. Fax: (919) DE S E Mail: david.goodrich@ncdenr.gov i A. Permit Number: W10400093 j B. Owner: Precision Fabrics Group, Inc. C. Facility/Operation: Precision Fabrics Group Greensboro Facility ' X Proposed ❑ Existing X Facility X Operation D. Application: 1. Permit Ttpe: ❑ Animal ❑ Surface Irrigation ❑ ❑ Recycle ❑ I/E Lagoon X ❑ U1C - (5A7) open loop geothermal For Residuals: ❑ Land App. ❑ D&M ❑ 503 ❑ 503 Exempl Reuse ❑ H-R Infiltration GW Remediation (ND) 5I Inj. wells ❑ Surface Disposal ❑ Animal Z. Project Type: Q New ❑ Major Mod. ❑ Minor Mod. ❑ Renewal X Renewal w/ Mod. E. Comments/Other Information: ❑ I would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: X Return a Completed APSARR Form. - Please comment ❑ Attach Well Construction Data Sheet, ❑ Attach Attachment B for Certification by the LAPCU. ❑ Issue an Attachment B Certification from the RO.* * Remember that you will be responsible for coordinating site visits and reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: "'A Date: FORM: APSARR 07/06 Page 1 of 1 AQUIFER PROTECTION SECTION — GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT Date: 2/22/2012 Permittee(s):_Precision Fabrics Group, Inc Permit No.: WI0400093 To: APS Central Office County: Guilford Central Office Reviewer: David Goodrich Project Name: Precision Fabrics Regional Login No: L GENERAL INFORMATION 1, This application is (check ai that apply): ❑ SFR Waste Irrigation System ❑ UIC Well(s) ❑ New ® Renewal ❑ Minor Modification ® Major Modification ❑ Surface Irrigation ❑ Reuse ❑ Recycle ❑ High Rate Infiltration ❑ Evaporation/Infiltration Lagoon ❑ Land Application of Residuals ❑ Attachment B included ❑ 503 regulated ❑ 503 exempt ❑ Distribution of Residuals ❑ Surface Disposal ❑ Closed -loop Groundwater Remediation ® Other Injection Wells (including in situ remediation) Was a site visit conducted in order to prepare this report? ❑ Yes or ® No. a. Date of site visit: b. Person contacted and contact information: c. Site visit conducted by: d. Inspection Report Attached: ❑ Yes or ❑ No, 2. Is the following information entered into the RIMS record for this application correct? ® Yes or ❑ No. If no, please complete the following or indicate that it is correct on the current application. For SFR Treatment Facilities: a. Location: b. Driving Directions: c. USGS Quadrangle Map name and number; d. Latitude; Longitude: Method Used (GPS, GoogleTM, etc.}; e. Regulated Activities 1 Type of Wastes (e.g., subdivision, food processing, municipal wastewater): For UIC Injection Sites: (If multiple sites either indicate which sites the information applies to, copy and paste a new section into the document for each site, or attach additional oases for each site a. Location(s): b. Driving Directions: c. USGS Quadrangle Map name and number: d. Latitude: Longitude: Method Used (GPS, GoogleTM, etc.) APS-GPU Regional Staff Report (Sept 09) Page 1 of 6 Pages AQUIFER PROTECTIVir SECTION — GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT IV INJECTION WELL PERMITAPPLICATIONS (Complete these two sections for all systems that use injection wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat pump injection wells.) Description of Well(s) and Facilities —View, Renewal, and Modification 1. Type of injection system: ❑ Heating/cooling water return flow (5A7) ❑ Closed -loop heat pump system (5QW5QW) ® In situ remediation (5I) ❑ Closed -loop groundwater remediation effluent injection (5U'Non-Discharge") ❑ Other (Specify: _ - 2. Does system use same well for water source and injection? ❑ Yes ® No 3. Are there any potential pollution sources that may affect injection? ® Yes ❑ No What is/are the pollution source(s)? Onsite surficial surfactant sumo. What is the distance of the injection well(s) from the pollution source(s)? >200 ft. 4. What is the minimum distance of proposed injection wells from the property boundary? ft. S. Quality of drainage at site: ® Good ❑ Adequate ❑ Poor C. Flooding potential of site: ® Low ❑ Moderate ❑ High 7, For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ❑ Yes ® No. Attach map of existing monitoring well network if applicable, If No, explain and recommend any changes to the groundwater monitoring program: Groundwater_ monitoring data from your two reports emailed me on February 22.2012 indicates that the plume may have remobilized if it had ever been stabilized (see table below; the wells are donwgradient wells). To monitor weather the proposed injections really have any adverse impact on migration of the plume in bedrock or downgradient, please include one of deep wells into the proposed quarterly sampling plan. In addition, it looks to be necessary to install another deep well at the Iocation of existing MW-36S. Well ID TCE Concentration (µgo) July 2009 July 2010 ugust 2011 MW-20I 2 274 716 MW-21I 124 164 200 MW-22I 2840 2670 5670 MW-20D 738 630 1060 MW-22D 6190 10700 11900 APS-GPU Regional Staff Report (Sept 09) Page 4 of 6 Pages AQUIFER PROTECTIUi-4 SECTION - GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT 8. Does the map presented represent the actual site (property lines, wells, surface drainage)? ® Yes or ❑ No. If no or no map, please attach a sketch of the site. Show property boundaries, buildings, wells, potential pollution sources, roads, approximate scale, and north arrow. Injection Well Permit Renewal and Modification Only: 1. For heat pump systems, are there any abnormalities in heat pump or injection well operation (e.g. turbid water, failure to assimilate injected fluid, poor heating/cooling)? ❑ Yes ❑ No. If Yes, explain: 2. For closed -loop heat pump systems, has system lost pressure or required make-up fluid since permit issuance or last inspection? ❑ Yes ❑ No. If yes, explain: 3. For renewal or modification of groundwater remediation permits (of any type), will continued/additional/modified injections have an adverse impact on migration of the plume or management of the contamination incident?-❑ Yes ❑ No. If yes, explain: Unlikely, but need to monitor 4. Drilling Contractor: Name: Geologic Exploration. Inc. Address: NC Certification number: 2401 5, Complete and attach NEW Injection Facility Inspection Report, if applicable I! E VAL UA TION A ND RECOMMENDATIONS 1. Provide any additional narrative regarding your review of the Application: 2. Attach new Injection Facility Inspection Form, if applicable 3. Do you foresee any problems with issuance/renewal of this permit? ❑ Yes ® No. If yes, please explain briefly, 4. List any items that you would like APS Central Office to obtain through an additional information request. Make sure that you provide a reason for each item: Item Reason APS-GPU Regional Staff'Report (Sept 09) Page 5 of 6 Pages AQUIFER PROTECTIbri SECTION - GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT 5. List specific Permit conditions that you recommend to be removed from the permit when issued. Make sure that you provide a reason for each condition: Condition Reason Submit a copy of each To evaluate if injections have any adverse impacts on groundwater quarterly monitoring quality or plume migration. report during first two years of proposed fall scale injection to WSRO A couple of deep wells See explanation in Section IV Item 7 should be included in quarterly monitoring plan 6. List specific special conditions or compliance schedules that you recommend to be included in the permit when issued. Make sure that you provide a reason for each special condition: Condition Reason 7. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office; ❑ Hold, pending review of draft permit by regional office; ❑ Issue upon receipt of needed additional information; Issue; ❑ Deny. If deny, please state reasons: 8. Signature of report Preparers); Signature of APS regional superv.aul . Date: VI. ADDITIONAL INFORMATION AND SITE MAP (Sketch ofsite showln2 house and waste irrigation system, spray or drip field , location of wells), and/or other relevant information- SHOW NORTH ARROW) APS-GPU Regional Staff Report (Sept 09) Page 6 of 6 Pages AQUIFER PROTECTION SECTION APPLICATION REVIEW REQUEST FORM Date: Febrauary 14, 2012 To: ❑ Landon Davidson, ARO-APS ❑ Art Barnhardt, FRO-APS ❑ Andrew Pitner, MRO-APS ❑ Jay Zimmerman, RRO-APS 'ECEIVEfJ `C '.3eat. of EkR FEB 5 2012 ❑ David May, WaRO-APS ❑ Charlie Stehrnan, WiRO-APS X Sherri Knight, WSRO-APS From: David Goodrich, Land Application Unit 2j ❑ 7 - 9 `i y 6 Telephone: (919) 7+0*+,&2 $6 2- L 3S z Fax: (919) 7t56048 E-Mail. david.goodrich@ncdenr.gov A. Permit Number: WI0400093 B. Owner: Precision Fabrics Group, Inc. C. Facility/Operation: Precision Fabrics Group Greensboro_ Facility X Proposed ❑ Existing X Facility X Operation D. Application: 1. Permit Type: ❑ Animal ❑ Surface Irrigation ❑ Reuse ❑ H-R Infiltration ❑ Recycle ❑ 1/E Lagoon X GW Remediation (ND) 51 Inj. wells ❑ UIC - (5A7) open loop geothermal For Residuals; ❑ Land App. ❑ D&M ❑ Surface Disposal ❑ 503 ❑ 503 Exempt ❑ Animal 2. Project Type: ❑ New ❑ Major Mad. ❑ Minor Mod. Q Renewal X RenewaI w/ Mad. E. Comments/Other Information: ❑ 1 would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: X Return a Completed APSARR Form. - Please comment ❑ Attach Well Construction Data Sheet. ❑ Attach Attachment B for Certification by the LAPCU. ❑ Issue an Attachment B Certification from the RO.* * Remember that you will be responsible for coordinating site visits and reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person i sted above. RO-APS Reviewer: -i Date: 7 FORM: APSARR 07/06 Page 1 of i 10 7 North Carolina Department of Health and Human Services Division of Public Health - Epidemiology Section Occupational and En►•iran mentaI Epidemiology Branch 19121 Vlail Service Center • Raleigh, North Carolina 1-7699-19l? Telephone:919-707-5900 Fax: 919-870-4807 Michael F. Easley, Governox Dempsey Benton, Secretsuy January 18, 2008 MEMORANDUM TO: Qu Qi Underground Injection Control Program Agiufer Protection Section FROM: Luanne K. Williams, Pharm.D., Toxicologist Medical Evaluation and Risk Assessment Unit Occupational and Environmental Epidemiology Branch North Carolina Department of Health and Human Services Lcah Devlin, DDS, )AP" State Health Director SvC - 1 SUBJECT: Use of a Biological Product BAC-9® to Enhance Biodegradation of Groundwater Contaminated with Chlorinated Compounds I am writing in response to a request for a health risk evaluation regarding the use of use of a biolotical product SAC-9 ® to enhance biodegradation of groundwater contaminated with chlorinated compounds. Based upon my review of the information submitted, I offer the following health risk evaluation: PRECAUTIONS DURING APPLICATION 1. The microorganisms in SAC-9'V are naturally found in soil. These microorganisms are not ordinarily associated with infection in healthy humans (except through an existing wound). However, these microorganisms may cause infection in the young, the aged, and immunocompromised such as individuals with AIDS, cancer, hepatitis, or with individuals following dialysis or surgical procedures, In addition. some of the ingredients within the BAC-9 V product have been known to cause eye, skin, and lung irritation. North Corolirro Public Health Zr,kP —, hea[ihler and vafer Noah Coruliw EYCryWg rp lre rydAy. [YZryNvdy Location: 5505 Sir Forks Rat. 3"' Floor, Roam 1-2-DI • Raleigh, NC 27h09 An Equal Oppoduaty Empinyer 2. Also, be aware that mixing potassium with some of the metal and acid ingredients listed in the product have been reported to be possibly explosive. Care should be taken to review the MSDS sheets for each ingredient listed to ensure that there would be no explosive hazard. 3. If the products are released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking, or mixing), then it is imperative that proper personal protective equipment be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. 4. Persons working with this product should at least wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. Again, consult with an industrial hygienist to ensure proper protection. 5. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should never be permitted in the application area during or immediately following application. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 6. The Material Safety Data Sheets should be followed to prevent adverse reactions and injuries. 7. Access to the area of application should be limited to the workerss applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. S. Efforts should be made to prevent contamination of existing or future wells and surface water that may be located near the application area. Please do not hesitate to call me if you have any questions at (919) 707-5912. cc: Dr. Robert Steffan Shaw Environmental, Inc. 17 Princess Road Lawrenceville, NJ 08648 Mr. Gary Birk Ms. Susan Bostian EOS Remediation, Inc. 1101 Nowell Road Raleigh, NC 27607 w ~� IL North CaroUt12 Department of Health and Hurnart Services Division of Public Health ■ Epidemiology Section 1912 N129 Service Center + Raleigh, Nora Carolina 2 7699-1912 Tel 919-733-3410 a Fax 919-733-9555 Michael F. EaAey, Govcrnar November 4, 2004 MEMORANDUM TO: Evan Kane Underground Injection Control Program Aquifer Protection Section FROM: Luanne K. Williams, Pharm.D., Toxicologist U� Medical Evaluation and Risk Assessment Uni Occupational and Environmental Epidemiology Branch North Carolina Department of Health and Human Services Carmcn !Tooker Odom. Seerceaq SUBJECT: Use of ABC@ by Redox Tech, LLC and KB-1TM Culture by SiREM Laboratories and Bio-Dechlor INOCULUM to Enhance Biodegradation of Groundwater Contaminated with Chlorinated Solvents I am writing in response to a request for a health risk evaluation regarding the use of ABCO by Redox Tech, LLC and KB-1 M Culture by Solutions Industrial & Environmental Services and Bio-Dechlor INOCULUM to enhance biodegradation of groundwater contaminated with chlorinated solvents. Based upon my review of the information submitted, I offer the following health risk evaluation: PRECAUTIONS DURING APPLICATION 1. Some effects or hazards reported to be associated with the chemicals proposed for use are as follows: Exposure can cause burns on the skin, eyes, nose and throat and cause dizziness, lightheadedness, and loss of consciousness. Can be significantly absorbed through the skin and lungs (New Jersey Department of Health and Senior Services Hazardous Substance Fact Sheet, Micromedex TOMEs Plus System CD-ROM Database, Volume 62, 2004). The chemical is highly flammable. It will be easily ignited by heat, sparks, or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. The vapors will spread along ground and collect in low confined areas (sewers, basements, and tanks). The storage containers for the chemical should be kept well closed. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated (Hazardous Substances Data Bank Micromedex TOMES Plus System CD-ROM Database, Volume 62, 2004). I* Lrxaoon: 2728 Capital Boulevirci 9 Parkcr Lincoln Building 6 Ralugh, N.C. 27604 An Equal Clppom pity Employer Precautions should be taken to prevent explosions to protect on -site workers, nearby residents, and off -site workers. Liberates toxic hydrogen sulfide on contact with acids. Reacts violently with carbon, diazonium salts, n-dichloromethyiamine; o-nitroaniline diazonium salt, and water. Based on testing and method used to produce the microorganisms (grown in a mineral salt medium), the microorganisms are not likely to be pathogenic. These microorganisms are not ordinarily associated with infection in healthy humans (except through an existing wound) (Madigan MT, Martinko JM, and Parker Jack 2003. Brock Biology ofMicroorgan isms, Tenth Edition. Pearson Education, Inc.). However, these microorganisms may cause infection in the young, the aged, and immunocomprom.ised such as individuals with AIDS, cancer, hepatitis, or with individuals following dialysis or surgical procedures. In order to provide an additional margin of safety, it is recommended to maintain an aerobic zone around the treatment zone, which should minimize the survival of the obligate anaerobes outside the treatment zone. 2. If the products are released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then it is imperative that proper personal protective equipment be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. Persons working with this product should at least wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. Again, consult with an industrial hygienist to ensure proper protection. 4. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should never be permitted in the application area during or immediately following application. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. The Material Safety Data Sheets should be followed to prevent adverse reactions and injuries. 6_ Access to the area of application should be limited to the workers applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. 7. According to the information submitted, the area is served by a public water supply. Based upon injections of the product at several sites, the approximate maximum distance of travel is estimated to be 25 feet. Two unnamed tributaries to Belmont Lake are located approximately 100 feet from the pilot test injection area. Belmont Lake is located approximately 130 feet downstream of the full-scale injection. Due to the shallow depth to groundwater at the injection site, it is possible that the injected fluid could migrate into the unnamed tributaries to Belmont Lake. Nearest residence is greater than 1,500 feet and nearest workplace is 600 feet. Because of the potential risks associated with the use of this product and the proximity of supply wells and surface waters, efforts should he made to prevent contamination of existing or future wells and nearby surface waters near the application area. Please do not hesitate to call me if you have any questions at (919) 715-6429, cc: -Mr. Mike Ranck, Underground injection Control Program, Aquifer Protection Section -Mr. Jerry Prasser, ERM NC, PC, 8000 Corporate Center Drive, Suite 200 Charlotte, NC 28226 -Mr. Bob Gorham, The Tuscarora Corporation, 2442 Sunset Avenue Rocky Mount, NC 27804 -Mr. David Sordi, Ingersoll-Rand, 70 North Street, Torrington, CT 06790 -Mr. John Haselow, Redox Tech, LLC, 1006A Morrisville Parkway Morrisville, NC 27560 -Mr. Phil Dennis, Operations Manager, SiREM Laboratories, 130 Research Lane, Suite 2, Guelph, Ontario Canada, N I G 5G3 North Carolina Department of Health and Human Services Division of Public Health + Epidemiology Section 1912 Mail Service Center • Raleigh, North Carolina 27699-1912 Tel 919-707-5900 • Fax 919-870-4810 A{ichad F. 1:.1'lLv, Governin March 8, 2007 MEMORANDUM r 13111]1111 f Ionker Odom. Secretafy RECEIVED ! DEHR, D'AQ AQUIPPR PPnTcr'T1CjN �FC710N TO: QU Q1 N1MIR 16 2007 Underground Injection Control Program Aquifer Protection Section FROM: Luanne K. Williams, Pharm.D., Toxicologists Medical Evaluation and Risk Assessment Unit Occupational and Environmental Epidemiology Branch North Carolina Department of Health and Human Services SUBJECT: Use of non -biological products magnesium hydroxide and calcium carbonate to increase the pH of groundwater at the Southern States Chemical Company in Wilmington, NC l am writing in response to a request for a health risk evaluation regarding the use of non - biological products including magnesium hydroxide and calcium carbonate to increase the pH of groundwater at the Southern States Chemical Company in Wilmington, NC. Based upon my review of the information submitted, I offer the following health risk evaluation: Some effects or hazards reported to be associated with the chemicals proposed for use are as follows: Exposure can cause irritation of eyes, nose, throat and skin as well as nausea, vomiting, hypotension, ECG changes, CNS depression, respiratory depression and paralysis (Micromedex TOMEs Plus System CD-ROM Database, Volume 71, 2007). If the products are released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. Persons working with this product should at least wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. Again, consult with an industrial hygienist to ensure proper protection. l.�,raunn: 75❑5 tiix Fs,rlaa ltn,i�1, yi.t lQut�r, itc,rtm Dl ■ Ra10g1k, \ G ?7609 Ali lignal Oplitsrnuiity I'm ployer 4. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should never be permitted in the application area during or immediately following application. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. The Material Safety Data Sheets should be followed to prevent adverse reactions and injuries. G. Access to the area of application should be limited to the workers applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. According to the information submitted, the Southern States Chemical Company is currently using bottled water but has five water supply wells located 2,000 feet from the proposed injection area. These supply wells are currently being used to process, toilet flushing, and hand washing. During the injection period and prior to confirmation sampling that the drinking water is safe, it is recommended to not use the groundwater for drinking or cooping at the site. Once it is determined that the pH is between 6.5 to 8.5 then, drinking water samples should be collected from these water supply wells. These samples should be analyzed for contaminants of concern in soil and groundwater and pH should be tested as well. If these wells are to be used for drinking or cooking, please forward the results of this sampling to me so a drinking water health evaluation can be done. The levels found will be compared to our health -based drinking water levels or North Carolina Public Health Goals. S. According to the information submitted, a county raw water line passes the site along US Highway 421. Measures should be taken to prevent the contaminants found in soil and groundwater from contaminating this water line or any private or public water supply wells. Also, the ea.stem portion of the site is adjacent to the northeast Cape Fear River. Measures should be taken to prevent contamination of this water body. Please do not hesitate to call me if you have any questions at (919) 707-5912. cc: Mr, Joseph Rossabi, Redox Tech, LLC, 200 Quade Drive, Cary, NC 27513 Mr. Barry Culp, RMT North Carolina, Inc., 30 Patewood Drive Suite 100, Patewood Plaza One, Greenville, SC 29615-3535 RECEIVED i DEAR I DWQ AQUIFFR ppnYFrr+nnl RFC110M North Carolina Department of Health and Human Sery icE-MAY 1) 5 2009 Division of Public Health a Epidemiology Section Occupational and Environmental Epidemiology Branch 1912 Mail Service Center. Raleigh, North Carolina 27699-1912 Tel 919-707-594Q • Fax 919-8704810 Beverly Eaves Perdue, Governor L =-er IYL Cmsler, Secretary April 30, 2009 MEMORANDUM TO: Thomas Slusser Aquifer Protection Section Division of Water Quality FROM: Kenneth Rudo, Ph.D. Toxicologist �4m t' MERA/OEEB Division of Public Health THROUGH: Mina Shehee, Ph.D, Supervisor MERAIDEEB 0 Division of Public Health Jeffrey P. Engel, NLD. State Health Director SITB.IECT: Health Risk Evaluation Groundwater Remediation Using Sodium Hydroxide and Calcium Chloride This review is provided in response to a request for a health risk evaluation regarding the use of sodium hydroxide and calcium chloride. These compounds are to be used to enhance the remediation of groundwater contaminated with hydrofluorosilicic acid. The following information is provided regarding precautions during use: 1) Sodium Hydroxide — chemical is hazardous in cases of ingestion, inhalation, skin and eye contact and may be an irritant or corrosive. The amount of damage depends on length of contact. Skin contact can produce inflammation and blistering characterized by scaling, redness, itching and occasionally, blistering. Eye contact may produce inflammation characterized by redness, watering and itching and severe contact may result in blindness or corneal damage. inhalation may produce irritation to the respiratory and GI tract and severe exposure may result in lung damage, choking or death. Please see the instructions in the MSDS sheet for this chemical in regards to first aid treatment if exposed and the exposure controls and personal protection when using sodium hydroxide. 2) Calcium Chloride — chemical may cause irritation from eye contact, may be a skin irritant characterized by scaling, itching, reddening and occasionally blistering. May be hazardous upon ingestion and inhalation exposure. Please see the instructions in the MSDS sheet for this chemical in regards to exposure controls and personal protection when using calcium chloride. kunh CPali dyHrslile Vaddrg fa,,hrakbwm"d S4FCr North Caroiino Erc�Tw}Ne. EVeryeliy. Ewg6ady. Location. 5505 Six Forks Road, 2'j Floor, Room ❑-1 • Raleigh, N.0 27609 RECENED I DENR I DWQ AQU{Er-R-vRnrFr.TjrW sFirTION MAY 4 v 2909 3) For both chemicals store and use in well ventilated areas. Do not store near heat, spark, or flame. To minimize exposure access to the area of mixing and application should be limited to those required to work with the 2 chemicals. All persons involved in the handling and use of these 2 chemicals should be familiar with the MSDS information and the information in this memo. Please see the MSDS sheet for both chemicals in regards to first aid measures to take upon exposure. 4) Eating, drinking, smoking, handling contact lenses, and applying cosmetics should never be permitted in the application area during or immediately following application. After handling, wash hands and face thoroughly with soap and water before eating, drinking or smoking. 5) Based on the information provided by Mr.Slusser on the use of these chemicals in the remediation process, well water contamination should not be expected in a manner that would pose an increased health risk upon personal well water use. However, measures should be taken to better identify any nearby private drinking water wells based on the incomplete information provided to OEEB. In the event that wells are found within 500 feet of the remediation area, steps should be taken to prevent contamination of these nearby wells. Central Filas: APS SWP 02/14/12 Permit Number W10400093 Permit Tracking Slip Program Category Status Project Type iJl Vtii.0 Vvi_kUi .,. IL:I._... -Ili i, IIIG�v,J4 f.iii4 Permit Type Version Permit Classification Injection In situ Groundwater Remediation Well (51) Individual Primary Reviewer Permit Contact Affiliation david.goodrich Beau Fudge Coastal SW Rule Permitted Flow Facili Facility Name Precision Fabrics Group, Inc. Greensboro Facility Location Address 301 E Meadowview Rd Greensboro NC 27406 Owner Owner Name Precision Fabrics Group Inc Dates/Events Scheduled Orig Issue App Received Draft initiated Issuance 03/20/08 02ro2/12 Regulated Activities Groundwater remediation Outfall NUU G M P R S 1130 Situs Ct Raleigh NC 27606 MajorfMinor Region Minor Winston-Salem County Guilford Facility Contact Affiliation Owner type Non -Government Owner Affiliation Lee Aike n 301 Meadowview Rd Greensboro Public Notice Issue NC 27406 Effective Expiration Requested/Received Events RO staff report received ^� RQ staff report requested Waterbody Name Stream index Nuinbet Current Class Subbasin DOCUMENTS ASSOCIATED WITH THE ORIGINAL PERMIT APPLICATION (MARCH 20,2008) [Fwd. Re: [Fwd: REC Project Audits - Preci---- Fabrics Group & 0... Subject: [Fwd: Re; [Fwd: REC Project Audits - Precision Fabrics Group & Overcash Machine Shop]] From: Stephen Berry <Steplien.BerryCilcmail.net> Date: Mon, 1 I Feb 2008 09:24:24 -0500 To: Qu QI <QU.QICa ncmail.net> Ott Oi, Here is the information I spoke about; ------- Original Message ---- ---- Subject:Re: [FNN,d: REC Project Audits - Precision Fabrics Group & Overeash Machine Shop] Date:Thu, 07 Feb 2008 13:37:25 -0500 From:Kim T. Caulk <Kim.Caulk a ncmail.net> To: Stephen. Berry(g)Wmai I.net References:<47A7224A.3040603(a),ncntai 1.net> Stephen: The meeting is scheduled for Wed., Feb. 20 at 10 am. I have a meeting, wl other Superfund Section folks to discuss the situation on 2112 at I pm. No rush, but when you get a chance, give me a call and we can discuss things as well. Kim Kim T. Caulk wrote: Stephen: Last Friday, I forgot to copy you on the a -mail (below) that was sent to the REC regarding the project audit for the above sites. i ant waiting on them to set up a meeting to discuss the audit findings. When I hear back from thent and a meeting is scheduled. I will let you know so we Cali touch base. Kiln _w_--- Original Message-------- Subject:REC Project Audits - Precision Fabrics Group & Gvercash Machine Shop Date:Fri, 01 Feb 2008 09:40:42 -0500 From, -Kim T. Caulk <Kim.Caulk(q?ncmaii.net> To: Mark Brown <smbrown pmecslimited.com>, Stephen Gosselin <sgosselin rr,ecslimited.com> Mr. Brown & Mr. Gosselin: i of5 2/11/2008 10:27 AM [Fwd: Re: 1Fwd: REC Project Audits - Prec"-- Fabrics Group & ❑... have completed my review of your responses to the REC Project Audits for the Precision Fabrics Group Site and the Overcash Machine Shop Site. Be aware that the Branch has not made any final decisiom regarding the audit findings. The following comments to your responses are provided: Precision Fabrics Grou l . Item 1 of your December 12, 2007 response to my November 13. 2007 project audit letter states "ECS accepted the Remedial Action plan (RAP) prepared at the time by PBA and :acknowledged that at some time in the future, the source areas and off -site contamination would have to be addressed". At the time ECS agreed to implement the RAP as it was designed, 1 cannot find any indication or acknowledgment that the source area and off -site contamination was to be addressed. The RAP that ECS reviewed and agreed to implement only discusses remediation of contamination at the site boundary. After I mentioned this concern during our - May 2, 2005 meeting, ECS indicated in a June 10, 2005 ECS letter that the source area would be addressed. Furthennore, the rest of the plume is not mentioned. The REC Rules require the RSM to ensure a certified RAP is prepared that demonstrates the planned remedial action will nicet itGs for the entire plume, which includes the source area, contamination at the site boundary-. contamination between the source area and the site boundary, and off -site contamination. I cannot find a certified RAP or certified RAP Addendum in the public file that meets this requirement. 2. Item 2 of your response states "laboratory analysis of the soil samples did not detect targeted compounds above the Inactive Hazardous Sites Branch Remediation Goal (RG)". Be aware there Lire two remedial goals for soil, which are the "health -based" RG and the "protection of- -groundwater" RG_ Therefore, for this statement you need to clarify which RG was not exceeded. ,Nlso, there seems to be conflicting infortnation between the November 17, 2000 RI Report and the January 8, 2002 RAP and your comments regarding the soil contarination above RGs. 'ro support your conclusions, you need to provide a table that summarizes the soil sample location and depth and the soil contaminant concentrations for all of the field and laboratory data performed for the soil investigation, a site map showing the soil sample locations, and appropriate cross -sections of the soil contamination with respect to the: water table. This information needs to clearly indicated the location of residual soil contaminant concentrations (in mg/kg) for both inetals and organics that exceeded values of 20 times the corresponding groundwater remediation _Foals (in mg/1) as discussed in the REC Program Implementation Guidance and the location of the tramples that were found to be leaching contaminants based on the TCLP analyes. The information also needs to indicate the location of soil contamination in excess of "health -based" RGs. 3. The AA for the Precision Fabrics Group Site was executed on November 18, 1997. therefore, all source areas should have been fully defined so that all non -groundwater retnediation, which includes soil contamination and DNAPLs, could be completed by November 18, 2005 as required by the REC Rules. 4. The RSM approved, certified January 8, 2002 RAP that is in the public file included plans for geophysical surveys and packer tests to evaluate bedrock fractures at the injections wells. Therefore, performance of these surveys and tests should have been addressed because they were part of the approved remedy. Be aware that the Underground Injection Control (UIC) Prograrn has asked the REC Program for this data as part of their review of the UIC permits that you are still requesting. u 2/11/2008 10:27 AM 1Fwd; Re: [Fwd: REC Project Audits - Preci—'^^ Fabrics Group & 0... 5. Comments 5 and 6 of my November 13, 2007 letter concerned the delays inn submitting a prc-construction report , failure to submit a construction completion report, the delays in obtaining UIC permits, and failure to implement full groundwater remediation. The Administrative lgreement (AA) was executed on November 18, 1997, and, therefore, in accordance with the REC Rules, full groundwater remediation should have been initiated within 2 years of completion of the remedial investigation (based on the RI completion for this site no later than November 18, 2002). 15A NCAC 13C .0306(b)(4)(C) and .0306(b)(5)(p) of the REC Rules also require a lire -construction report and construction completion report be prepared and certified prior to full iill plern entation of groundwater remediation. On November 21, 2002 a letter was issued from the Branch (J. Powers to S. Gosselin) providing concurrence that ECS had met deadline for implementation of groundwater remediation because the groundwater remediation pilot study had begun. The letter also reminded ECS that the above documents were due prior to full implementation of groundwater remediation_ Over five years have passed since the Branch issued kite November 21. 2002 letter. Therefore, please review the November 21, 2002 letter, the deadline requirements established in the executed AA for implementation of groundwater cmediation, and the documents required by the REC Rules and provide your interpretation of when full groundwater remediation was to be initiated and when the above required documents were to be submitted to the Branch. 0. Your responses to comments 7 & 8 of my November 13, 2007 letter have been reviewed. I have no further comments. Overcash Machine Shop 1. Section 111. paragraph B of the .tune 9, 2006 Administrative Agreement states "the Remediator shall submit quarterly letter progress reports on or before the 15th day of January, April, July, and October of each year that this Agreement is in effect." My November 14, 2007 utter stated "review of the Fite indicates no quarterly status reports have been received since the V\ was executed, since my October 18, 2006 Warning of Violation letter was issued, or since the .tune 14, 2007 letter was received from ECS. Subsequently, on November 27, 2007, 1 received a document (Remedial Investigation Work Plan and Report), but no explanation as to why quarterly status reports were not submitted as required by the AA. ?. The R1 workplan portionof the document received November 27, 2007 does not include certification in accordance with .0306(b). �. The RI work plan portions of the document received November 27, 2007 does not include all of the components required by .030G(g). 4. The document received November 27. 2007 appears to include a remedial investigation (RI) report and includes site assessment activities performed in May 2007, prior to submittal of a certified RI work plan to the Branch. Pursuant to 15A NCAC 13C .0306(b)(4)(A), RSM certification of remedial investigation work plans prepared in accordance with Paragraph (g) shall occur rp i r to implementation. 5. The RI Report included in Appendix E of the RI Work Plan does not include all ol- thc 3 of 4 2/11/2008 10:27 AM [Fwd: Re: [Fwd.- REC Project Audits - Preci-inn Fabrics Group & 0_ components required by .0306(h). 6. The Letter of Transmittal with the document received on November 27, 2007 includes a request for an "expeditious review of the report". Apparently, this request was made in an effort to have the Site closed by the Branch. For sites in the REC Program, the Branch does not review these documents unless a technical audit is perforated. The procedures for submitting RSM certified RI reports and completion statements are discussed during REC training and are included in the REC Program Implementation Guidance. In the REC Program, a "no further action" (NFA) is only issued after receipt of a Remedial Action Completion Report that includes a Remedial Action Completion Certification statement from the RSM. The Remedial Action Completion Report must clearly demonstrate the site cleanup has been completed and specific cleanup levels have been achieved, For sites that undergo rernediation, a letter requesting an NFA determination is also required in accordance with 130A-310.7(c). I t1t, i i a i c indicated that ECS would like to have a meeting to discuss the prejcct audits. I meeting is held, I would give a brief overview of the REC; Program and you would then have an opportunity to discuss any or all of the above comments and potential REC Rule violations and provide any additional int0rmation that you may have, Please call me as soon as possible if you still request a meeting. Regards, Kim T. Caulk, P.G. Inactive Hazardous Sites Branch - REC Program NCDENR - Division of Waste Management 401 Oberlin Road, Suite 150 Raleigh, North Carolina 27605 Phone: (919) 508-8451 Fax: (919) 733-4811 e-mail: kim.caulkCncmail.net Kim T. Caulk, P.G. Inactive Hazardous Sites Branch - REC Program NCDENR - Division of Waste Management 401 Oberlin Road, Suite 150 Raleigh, North Carolina 27605 Phone: (919) 508-8451 Fax: (919) 733-4811 e-mail: kim.caulka@ncmail.net Stephen Berry NC DENR Winston-Salem Regional office Division of Water Quality, Aquifer Protection Section 585 Waughtown Street Winston-Salem, NC 27107 4 of 5 2/11/2008 10:27 AM North Carolina Dexter R. Matthews, Director November 13, 2007 Mr, Stephen J. Gosselin ECS Carolinas, LLP 8702 Red oak Boulevard, Suite A Charlotte, North Carolina 28217 FMA NCDENR Department of Environment and Division of Waste Management Re: REC Project Audit Precision Fabrics Group, Inc. Greensboro, Guilford County, NC Site ID No.: NONCD 000 1020 Dear Mr. Gosselin: Natural Resources Michael F. Easley, Govemor William G. Ross Jr., Secretary I am in the process of performing a technical audit of the project files and associated reports that have been submitted by ECS Carolinas, LLP (ECS) to the Registered Environmental Consultant (REC) Program of the Inactive Hazardous Sites Branch (Branch) for the Precision Fabrics Group (PFG) Site (Site). Be aware that I am not familiar with all technical aspects of the REC Program projects because oversight of the remedial activities is the responsibility of the Registered Site Manager (RSM). My review thus far has identified potential REC Rule violations for the Site. In order for me to complete this review, please provide any responses that you may have to the following comments: On May 5, 2005, 1 sent a letter to you regarding the project status and potential REC Rule violations that we had discussed during our May 2, 2005 meeting. Page 19 of the January 8, 2002 RECIRSM approved remedial action plan (RAP) states "the objective of the remedial action is to provide on -site containment of the solvent contaminated groundwater ...... the preliminary remediation goal is to significantly reduce the contaminant concentrations of the ground water leaving the PFG site and the ultimate goal is to reduce the contaminant concentrations to a level that meets current guidelines." In addition, a February 22, 2002 ECS letter states "based on our review of the RAP, ECS agrees to implement the remedial action as proposed". Item 1 of my May 5, 2005 letter requested you to explain how the planned remedial action for all of the contaminated soil and groundwater will provide protection of human health and the environment, including the attainment of cleanup levels as required by 15A NCAC 13C .0306(l)(3)jA) and as further discussed in the REC Program Implementation Guidance (Guidance). Your June 10, 2005 response states "ECS again agrees to implement the proposed remedial action as stated in the RAP, and concurs that the proposed remedial technology will be an adequate, in -situ method to remediate impacted groundwater and in turn will aid in the protection of human health and the environment. it should be noted that no receptors have been identified as a result of the past releases at the PFG property. There are no groundwater intakes in the surrounding area. The only deviation from the original remedial design that ECS and PFG would recommend is groundwater remediation in the source area in conjunction with the barrier wall configuration near the property boundaryYour June 10, 2005 letter further states "it was understood that the remedial action which was proposed (HRCTM injection for groundwater remediation only in a barrier wall configuration) was a sufficient means to remediate impacted groundwater beneath the site, in conjunction with containing impacted groundwater to the subject site". Be aware that the entire groundwater contaminant plume must be remediated to meet the water quality standards of 15A NCAC 2L. Neither the REC approved RAP, which ECS agreed to implement, nor your June 10, 2005 response explain how the remedial goals of the entire groundwater contaminant plume, particularly at the general source area and the area between the general source area and the Site boundary, will be met nor does the RAP or response demonstrate how human health and the environment will be protected using the selected remedial altemative. In addition, receptors have no bearing on whether or not the remedial goals for the groundwater must be met. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-84001 FAX 919-715-3605 I Internet http:llwastenotnc.org An Equal Opportunity I Affirmative Action Employer - Printed on Dual Purpose Recycled Paper ECS1Precision Fabrics Group Site REC Project Audit November 13, 2007 Page 2 Your June 10, 2005 letter states "with regard to the soil contamination identified at the subject site, which is located either beneath the building or is capped with concrete andlor asphalt, ECS agrees .... that no remediation of the soil is necessary Your June 10, 2005 letter also states "the average depth of groundwater beneath the site is 25 to 30 feet bgs. It is not practical to believe that limited extent of soil contamination is contributing to the impacted groundwater in a 'source area" manner. Furthermore, it is not feasible nor cost effective to attempt to remediate impacted soils given the extensive groundwater remediation that will occur in the vicinity of the soil contamination (impacted groundwater source area) as well as downgradient of the soil contamination (barrier wall)", According to Section 2.6.1 of the January 8, 2002 RAP, contaminants were detected in several soil samples at concentrations that were 20 times the groundwater remedial goals. The RAP also indicates that two soil samples were tested using TCLP analyses and found to be leaching contaminants to groundwater. In addition, the fact that groundwater is already contaminated is an indication that contaminants have leached into the groundwater and "protection of groundwater' remedial goals for soil have been exceeded. Therefore, it appears that the remedial alternative selected for the soil contamination will not meet the soil remedial goals as it is proposed. According to 15A NCAC 13C .0308(a), it is the RSM's responsibility to ensure that the Department's cleanup standards for all media are met when a remedial action plan is approved by the RSM. The procedures for establishing remedial goals are provided in Appendix D of the REC Program Implementation Guidance. Furthermore, in accordance with 15A NCAC 13C .0306(1), the RSM is required to prepare and certify a RAP that ensures all sources of contamination, including contaminated soil and any dense non -aqueous phase liquids (DNAPLs), are remediated and remedial goals for all media are met. As indicated in the REC Program Guidance, the only exception to meeting "protection of groundwater clean up standards is for the REC to demonstrate that it is technically impracticable to meet these standards. Any technical impracticability case that would leave contamination in place and is taus a containment remedy requires our concurrence per 15A NCAC 13C .0306(i), It is the RSM's responsibility to ensure a complete RAP is prepared and concurrence is obtained. 3. The Branch is concerned that the contaminant source area(s) has not been completely identified. Contaminated soil exists at the Site, no active soil remediation appears to have been performed at the facility, and the average depth to groundwater beneath the Site is between 25 and 30 feet below ground surface. This would indicate that there could be significant contamination within the soil column (the vadose zone/soil above the water table), which is contributing to the groundwater contamination. In addition, the concentrations of chlorinated solvents in the groundwater, which are several orders of magnitude higher that the 15A NCAC NC 2L groundwater quality standards, suggest that DNAPLs may be present beneath the Site. Information received from the Division of Water Quality indicates the issue regarding DNAPLs has been and continues to be a major concern of the Underground Injection Control (UIC) Program as well. Therefore, knowing that soil contamination exists above the water table and given the size of the groundwater contaminant plume (over 1,150 feet long by 525 feet wide) and the contaminant concentrations in the groundwater, it is likely that a specific source area has not been identified. In accordance with 15A NCAC 13C .0306(e) and (f), it is the RSM's responsibility to ensure that all source areas of contamination have been identified and the extent of contamination in each media is fully defined so an appropriate remedial alternative can be chosen. The January 8, 2002 RAP proposed geophysical surveys and packer tests to evaluate bedrock fractures at the injection wells that were installed for a pilot test at the Site. These surveys and tests can be and typically are beneficial to gain a better understanding of subsurface conditions for the final remedial design. However, based on correspondence submitted since the RAP was approved, either the geophysical surveys and packer tests were not included in the Preconstruction report required by 15A NCAC 13C .0306{m) or no information has been provided for the public record to explain why the surveys tests were not conducted even though they were proposed in the approved RAP. Item 3 of my May 5, 2005 letter requested information regarding why no preconstruction report was submitted for approximately 2.5 years following implementation of a groundwater remediation pilot study, which began November 2002. The Branch wanted to know the reason for the delay because, according to the schedule in the RAP, submittal of the preconstruction report was anticipated within 6 to 8 months after the pilot study began and a construction completion report was anticipated approximately 11 months after the pilot study began. You were reminded of these reporting requirements in a November 21, 2002 letter from the Branch. To date, no explanation for the delay in submitting the preconstruction report has been provided and a construction completion report for full implementation of groundwater remediation as required by 15A NCAC 130 .0306(n) still has not been received 5 years after the pilot study began. 6. Following my May 5, 2005 letter regarding concerns about the project status, a certified Report of Reductive Dechlorination Pilot Testing document (Pre -construction Report) with Remedial Design Completion Certification was received on ,tune 28, 2005. The report recommended additional injection activities and expanding the remedial actions to include the general ECS/Precision Fabrics Group Site November 13, 2007 REC Project Audit Page 3 source area in addition to the Site boundary. However, according to a progress report received December 21, 2005, a LAC permit was not requested from the UIC Program until October 18, 2005 four months following submittal of the Preconstruction Report. In addition, in a February 15, 2006 letter, the UIC Program requested additional groundwater monitoring data for a UIC permit application from ECS. According to your progress report received April 13, 2006, the groundwater sampling requested by the UIC Program was not scheduled until May 2006. The file indicates that it was September 13, 2006 before a report of findings was prepared. Delays such as these could add up and not only reduce the effectiveness of the remedial efforts already initiated at the Site boundary, but also lead to violations of the REC Rule deadlines of 15A NCAC 13C .0302(h), Explanation is needed for the delays in requesting the U1C permit and performing the needed groundwater sampling. 7. As indicated in my May 5, 2005 letter, remedial action progress reports are required following implementation of groundwater remediation on a quarterly basis, and all progress reports must be certified and include the document components required by 15A NCAC 13C .0306(o). Your June 10, 2005 letter states "ECS acknowledges that we did not submit quarterly reports following the post HRCTM injection episodes Subsequent to that acknowledgement, progress reports were received December 21, 2005, April 13, 2006, and September 18, 2006. This schedule still was not quarterly. In addition, review of these three reports and progress reports subsequently received by the Branch on February 5, 2007 and May 4, 2007 indicates none of the reports include the components required by 15A NCAC 13C .0306(o). 8. According to the REC Administrative Agreement that was executed on November 21, 1997, the commencement of the implementation of groundwater remediation was due November 18, 2002. We met on May 2, 2005 to discuss the Branch's concerns regarding the remedial efforts at the Site and compliance with the REC Rules. Review of information submitted to this office indicates groundwater remediation still has not been fully implemented and required documents have not been received on schedule and those that have been submitted are incomplete. No explanation has been provided. Finally, your June 10, 2005 response letter indicates "through several correspondences and telephone conversations with John Powers of the NCDENR all parties were in agreement with the Remedial Action Plan (RAP)". We find no correspondence in our files to suggest the Branch agreed with the RAP. As indicated in the REC Program Guidance, explained during REC training, and required by the REC Rules, certification, approval, and implementation of a RAP is the responsibility of the RSM. The Branch does not approve RAPS for Sites undergoing remediation in the REC Program. The Branch only becomes familiar with the technical aspects of an REC project when an audit is performed. Please provide any responses that you may have to the above itemized issues by December 13, 2007, If you have any questions or would like to have a meeting to discuss this letter and the project, please contact me at (919) 508-8451. Sincerely, Kim T. Caulk REC Program Inactive Hazardous Sites Branch Superfund Section cc: Mr. Mark Brown, ECS Mr. Wallace Kale, Precision Fabrics Group Mr. Peter Pozzo, UIC Program Y DIVISION OF WATER QUALIT AQUIFER PROTECTION SECTION March 20, 2008 MEMORANDUM TO: DEBRA WATTS —� 2� FROM: QU QI RE: Recommendation for the Issuance of UIC Permit WI0400093 I have reviewed the subject permit application, and I am recommending the permit be issued with the following comments: 1. Site Overview: Groundwater at the site is impacted by chlorinated solvents, primarily trichloroethene (TCE) and tetrachloroethene (PCE). The groundwater contamination occurred in both saprolite aquifer and bedrock aquifer. The proposed injection area is near property line — down gradient from the source area. The source area remediation is going to be separated under another permit. The previous pilot test was to inject HRC in November 2002 under UIC permit WI0400028. After the injection, favorable geochemical conditions were observed, but the reduction of contaminant concentrations was not observed, probably because of missing monitoring events and low injection dosage. Site geology: Soils encountered at the site are generally saprolite (30 to 45 feet thick) made of clay, clayey silt, sandy silt and silty sand. Sand content increases with depth. Below the saprolite is the partially weathered rock with a thickness about 30 to 50 feet. This layer is underlain by bedrock which is mainly metamorphosed granodiorite or granite. The groundwater table varies from 20 feet to 30 feet below the grade across the area. 2. Injection: The proposed injectant is HRCTM to stimulate in situ biodegradation. The dosage is increased from the pilot test. The proposed injection will occur in forty four injection wells: twenty two of them are shallow wells (8 to 16 feet) and twenty two are deep wells (16 to 20 feet). A total of 3000 gallons of HRC will be applied during first injection event and 1600 gallons for the second event six months later. 3. Monitoring: Total of forty monitoring wells will be sampled quarterly for VOC, metabolic acids, alkalinity, CO2, chloride, nitrate, ferrous iron, dissolved total iron, manganese, sulfide and total organic carbon. 4. Epidemiology: Dr. Luanne Williams provided a risk evaluation of HRC, and did not identify any risks that would prohibit injection. 5. Regional Office Comments: The Winston-Salem Regional Office provided a review of the application and site inspection and raised the concern about the bedrock injection. The injectant HRC does not require to be diluted and therefore the total volume of the injectant is small knu chasing water is needed). The poten..... of pushing contaminants further away from the site is very low. l have explained this to the regional staff and did not receive any further comments. Please let me know if you have any questions, comments, or concerns about issuing this permit. AQUIFER PROTECTION REGIONAL STAFF REPORT Date: 02/04/2008 To: Aquifer Protection Central Office Central Office Reviewer: Ou Oi Regional Login No: County: Guilford Permittee: Precision Fabrics Group, Inc Project Name: Precision Fabrics Group, Inc Application No.: WI0400093 I. GENERAL INFORMATION 1. This application is (check an that apply): ® New ❑ Renewal ❑ Minor Modification ❑ Major Modification ❑ Surface Irrigation ❑ Reuse ❑ Recycle ❑ High Rate infiltration ❑ Evaporation/Infiltration Lagoon ❑ Land Application of Residuals ❑ Attachment B included ❑ 503 regulated ❑ 503 exempt ❑ Distribution of Residuals ❑ Surface Disposal ❑ Closed -loop Groundwater Remediation ® Other Injection Wells (including in sim remediation) Was a site visit conducted in order to prepare this report? ® Yes or ❑ No. a. Date of site: visit: 0112912IX18 b. Person contacted and contact information: Randy Cavallier, ECS Carolina. LLP ; 336-856-7154 c. Site visit conducted by: Stephen Berry & Shuying Wang d. Inspection Report Attached: ❑ Yes or ® No. 2. Is the following information entered into the BIMS record for this application correct? ® Yes or ❑ No. If no, please complete the following or indicate that it is correct on the current application. a. Location(s): 30I E. Meadowview Road b. Driving Directions: From WSRO, I44W: Exit S Elm -Eugene St, Turn North: Turn East on E Meadowview Rd: Facility on North side of road. c. USGS Quadrangle Map name and number: UNKNOWN d. Latitude: 36.039776 Longitude: 79.7852 IV. INFECTION WELL PERMIT APPLICATIONS (Complete these two sections for all systems that use injection wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat pump injection wells,) Description Of Well(S) And Facilities — New, Renewal, And Modification 1. Type of injection system: ❑ Heating/cooling water return flow (5A7) ❑ Closed -loop heat pump system (5QM15QW) ® In situ remediation (5I) ❑ Closed -loop groundwater remediation effluent injection (5LP'Non-Discharge") ❑ Other (Specify: 2. Does system use same well for water source and injection? ❑ Yes ® No 3. Are there any potential pollution sources that may affect injection? ® Yes ❑ No FORM: WI0400093 APSSRR AQUIFER PROTECTION REGIONAL STAFF REPORT What is/are the pollution source(s)? Surficial Surfactant Sump up gradient. What is the distance of the injection well(s) from the pollution source(s)? 120ft ft. In the event of an exceptional flood event and a coinciding spill of surfactants held above gradient, there is a potential for surface contamination of all down gradient existing and proposed wells, albeit a highly unlikely occurrence. 4. What is the minimum distance of proposed injection wells from the property boundary? --20 ft. 5. Quality of drainage at site: ® Good ❑ Adequate ❑ Poor 6. Flooding potential of site: ® Low ❑ Moderate ❑ High 7. For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters. etc,) adequate? ❑ Yes ® No. Attach map of existing monitoring well network if applicable. If No, explain and recommend any changes to the groundwater monitoring program: Ideally, the contamination plume would be better defined: off -site monitor wells are needed: The frequency of monitor events is adequate; DO levels need to be in ppm, not % saturation as documented in the application. 8. Does the map presented represent the actual site (property lines, wells, surface drainage)? ® Yes or ❑ No. If no or no map, please attach a sketch of the site. Show property boundaries, buildings. wells, potential pollution sources, roads. approximate scale, and north arrow. Iniection Well Permit Renewal And Modification Only: 1. N/A 2. For renewal or modification of groundwater remediation permits (of any tone). will continued/additional/modified injections have an adverse impact on Nation of the plume or management of the contamination incident? ® Yes ❑ No. If Yes. explain: S.Wang has reservations regarding injection of HRC into bedrock aquifer. 3. Drilling contractor: Name: Geologic Exploration. Inc Address: Unknown Certification number: 2580 2 AQUIFER PROTECTION REGIONAL STAFF REPORT 4. Complete and attach Well Construction Data Sheet. Please refer to the permit application for full size schematics ka .�Yk NV.�mtW f �YNY� a+hi� •M f•.� ��Y9d �-.ice rta N..fe � '' rarrcx �:5. tS. C[ iNL�QQY �S�+ti fe�aNYN CIPiN9Cfafc NOIm� GYVM� i.1c�N. WR�e, aR[M [IJYAi�a r r Nra r map 7--- 1jNdr:.N.Nra 1 � a-NeN e. a _ nac Nude iYwrcnu'0`�" ,a JK:J uo[f�idpWLY mycnoDN — n`rynm' CAR T:pE 7 P8dPD5q NESI1:0 cAfEoI.7HAti V. EVALUATION AND RECOMNIENDATIONS I[Y ,DytQ -nix n S LU 9OLLYMM90 SYNI'f0lfY7 � WOf0a91 �pr:L fy� +r oo-N r.n .rNcn n-r w�c fNR1�'] xyyaN ]7Nom'+gy�� couY70"- re 6:ci9-� L%RI1:1X �Of ]NI '.cvx� L�Slr] yWSL•afd ].�� Cu 1. Provide any additional narrative regarding your review of the application.: 2. Attach Well Construction Data Sheet - if needed information is available 3. Do you foresee any problems with issuancelrenewal of this permit? 0 Yes ® No. If yes, please explain briefly. NIA 4. List any items that you would like APS Central Office to obtain through an additional information request. Make sure that you provide a reason for each item: Item Reason List on permit under Section IV (A) (1) Responses to 2/15/6 letter infer Injection Fluid Data, all fluids to be injected the use of other injectants (i.e., Response to Bullet 2 states 46...DHC microorganisms can be injected" and that " A buffer solution will then be added..."). These injectants should be approved by OEES and listed under section IV (A)(l ); 5. List specific Permit conditions that you recommend to be removed from the permit when issued. Make sure that you provide a reason for each condition: FORM: WI0400093 APSSRR 3 AQUIFER PROTECTION REGIONAL STAFF REPORT Condition Reason Bedrock Injections should To inject HRC into deep bedrock aquifer is not recommended be avoided (per Shuying unless more detailed investigation and analysis on the deep Wang's request) i bedrock aquifer system have been conducted. 5. List specific special conditions or compliance schedules that you recommend to be included in the permit when issued. Make sure that you provide a reason for each special condition: Condition Reason None 7. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office; ❑ Hold, pending review of draft permit by regional office; ® Issue upon receipt of needed additional information; Issue; ❑ Deny. If deny, please state reasons: 8. Signature of report preparer(s): Signature of APS regional supervisor; Date: 04 & Y ADDITIONAL REGIONAL STAFFREV1EW ITEMS None FORM: W10400093 APSSRR 4 Existing Monitoring Wells on EAST side of property SOUTH property line (looking west) sou (look WI0400093_PFG, Inc SOUTHEAST corner of PFG, Inc. property AQUIFER PROTECTION SECTION APPLICATION REVIEW REQUEST FORM Date: December 14, 2007 ❑ Landon Davidson, ARO-APS ❑ David May, WaRO-APS ❑ Art Barnhardt, FRO-APS ❑ Charlie Stehman, WiRO A4PS ❑ Andrew Pitner. MRO-APS ® Sherri Knight, WSRO-APS ❑ Jay Zimmerman, RRO-APS ff � t`om: u Qi , Groundwater Protection Unit r Telephone: (919) 715-6935 Fax: (919) 715`0588 E-Mail: gu.gi(a-), ncmail.net A. Permit Number: W10400093 B. Owner: Precision Fabrics Groug C. FaciliLv/Operation: _Precision Fabrics Grout ® Proposed ❑ Existing ❑ Facility ❑ Operation 1). _application: 1. Permit Type: For Residuals ❑ Animal ❑ Surface Irrigation ❑ Reuse ❑ H-R Infiltration ❑ Recycle ❑ I/E Lagoon ❑ GW Remediation (ND) ® UIC - (51) in -situ groundwater remediation ❑ Land App. ❑ D&M ❑ Surface Disposal ❑ 503 ❑ 503 Exempt ❑ Animal 2. Project Type: ® New ❑ Major Mod. ❑ Minor Mod. ❑ Renewal ❑ Renewal wl Mod. E. Comments/Other Information: ❑ I would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: ® Return a Completed Form APSARR. ❑ Attach Well Construction Data Sheet. ❑ Attach Attachment B for Certification by the LAPCU. ❑ Issue an Attachment B Certification from the RO*. * Remember that you will be responsible for coordinating site visits, reviews. as well as additional information requests with other RO APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: Date: FORM: APSARR 02/06 Page I of 1 STAXtNorth C ~d •" � Departu of Health and Human Services Division of Public Health - 1912 Mail Service Center ■ Raleigh, North Carolina 27699-1912 -� �• 2728 Capital Boulevard a (919) 733-3421 ■ Courier 56-32-00 Ann F. Wolfe, M.D., M.P.H., Director August 1, 2000 CD MEMORANDUM CM o n � n TO: Mark Pritzel Underground Injection Control Program — r- Groundwater Section r. FROM: Luanne K. Williams, Pharrn.D., Toxicologistio,", Medical Evaluation and Risk Assessment Unit —� Occupational and Environmental Epidemiology Branch y -c�� d SUBJECT: Health Risk Evaluation Regarding the Use of Glycerol Tripolylactate, a Hydrogen Release Compound, Used to Enhance In Situ Biodegradation Rates for Chlorinated Compounds Detected in Groundwater at Fairchild Industrial Products Company in Winston-Salem, North Carolina I am writing in response to Qore, Incorporation's request for a health risk evaluation regarding the use of Glycerol Tripolylactate, a hydrogen release compound, to enhance in situ biodegradation rates for chlorinated compounds detected in the groundwater at Fairchild Industrial Products Company in Winston-Salem, North Carolina (see enclosed letter dated April 10, 2000). Based upon my review of the information submitted, I offer the following health risk evaluation: WORKER PRECAUTIONS DURING APPLICATION Some effects reported to be associated with the product proposed to be used are as follows: eye, skin, nose, throat, and lung irritation. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. Ever),Wjere. Evep),Day. Every&dy. F-19 Asi Equal Oppormijity,l,4frmalive.tetian Employer �`� Mark Pritzel Memo August 1, 2000 Page Two 4, Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. OTHER PRECAUTIONS 1, Access to the area of application should be limited to the workers applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. 2. According to the information submitted with the letter dated April 10, 2000, municipal water is available to the application area, and there are no known public water supply welts located within 1,500 feet of the site. However, two private water supply wells are reported to be located approximately 1,200 and 1,500 feet southwest of the site, respectively. Qore, Inc. has reported that with an initial lactic acid groundwater concentration of 5,000 and 1,000 ppm, the concentration would be diluted to 1 ppm at 45.93 and 41.34 feet, respectively. It appears that impact to the closest wells is unlikely; however, it is recommended that the Groundwater Section review the data and determine likelihood of potential impact to these wells. 3. According to the information submitted, an unnamed tributary of Salem Creek is located near the proposed application area. It is recommended to contact Ms. Dianne Reid «.ith the Water Quality Section at (919) 733-5083 extension 568 to determine if this product or process could impact these water bodies. If you have any questions, contact me at (919) 715-5429. LKW:mbf c: Mr. John Sealey, Fairchild Industrial Products Company Mr. Kim Caulk, Qore Property Sciences Dr. Steve Koenigsberg, Ph.D., Regenesis (manufacturer) Ms. Dianne Reid, Water Quality Section