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HomeMy WebLinkAboutWI0400091_Monitoring (Report)_20080929wsO�o�o9/ �ry�-tea Quarterly HiSOC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Trigon I Kleinfelder Project No. 042-08-018 P.Q. Box 18846 • Zip 27419-8846 - 313 Gallimore Dairy Road • Greensboro, NC 27409 • p 336.668.0093 • f 336.668.3868 September 26, 2008 Mr. Qu Qi Aquifer Protection Section — UIC Staff DENR — Division of Water Quality 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Reference: Quarterly RiSOC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Trigon I Kleinfelder Project No. 042-0$-0I$ Dear Mr. Qi: Trigon I Kleinfelder, Inc. is pleased to provide our quarterly monitoring report for the Underground Injection Control (UIC) Permit for treatment of groundwater with the HiSOC system at the referenced site. This report summarizes our field activities, observations, and includes the analytical results of the groundwater samples. Should you have any questions or require additional information, please do not hesitate to contact Chris Hay at your convenience. Very truly yours, TRIGON I KLEINFELDER, INC. CL Christopher W. Hay, Environmental Group anager CWHIGGL:cas jAshar60420lpmjccls12009\0I SV4208018.doe Gail G. Licayan, P.E. Project Professional RECEIVED I DENR 11)WQ jjgiPropriWo Section SEP 29 2008 www.trigoneng.com Ms. Beth Money, Gilbarco Sept=ber26, 2008 7300 West Friendly Avenue, Greensboro, North Carolina Trigon j Meinfelder Project No. 042-08.018 GILBARCO Greensboro, North Carolina Groundwater Incident Nos. 12960 And 15123 SITE INFORMATION Address: Contact: Telephone: Latitude and Longitude: Risk Classification: Land Use Category: LAND OWNERSHIP Name: Address: Telephone: Attention: RELEASE INFORMATION September 26, 2008 7300 West Friendly Avenue Greensboro, North Carolina Ms, Beth Money 336.547.5130 36.0901°N, 79.9282 °W Low Commercial G ilbarco 7300 West Friendly Avenue Greensboro, North Carolina 27420 336.547.5130 Ms. Beth Money Cause of Release: Release from a 1,000 gallon diesel UST and four 550 gallon gasoline USTs was discovered in November and December 1994. The quantity released is unknown. ENVIRONMENTAL CONSULTANT Name: Trigon I Kleinfelder, Inc. Address: Post Office Box 18846 Greensboro, North Carolina 27419-8846 Telephone: 336.668.0093 Attention: Mr. Christopher W. Hay Seal and Si►iq�tifying Registered Engineer 1, Gail , 5 �Pd Engineer for Trigon i Kleinfelder, Inc., do certify that the information contained itls���� i orrat and accurate to the best of my knowledge. _ rtL . Gail G. Registeree ��; • • �gineer No. 031532 11111111101 TRuGoN I KLmaiLDER, INC. Page i Ms. Beth Money, Gilbarco September26, 2008 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinielder Project No. 042-08-018 TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................................. I 2.0 GROUNDWATER MONITORING ACTIVITIES...............................................................................2 3.4 GROUNDWATER ANALYTICAL RESULTS....................................................................................3 4.0 RiSOC INSTALLATION AND MONITORING..................................................................................4 5.0 CONCLUSIONS AND RECOMMENDATIONS.................................................................................5 TABLES 1 Groundwater Elevation Data 2 Aquifer Characteristics Field Analysis Summary 3 Summary of Groundwater Sample Results 4 Historical Summary of Groundwater Sample Results 5 Estimated Dissolved Hydrogen Concentrations at Injection Wells 6 Estimated Hydrogen Consumption FIGURES 1 Site Location Map 2 Site Plan 3 Groundwater Potentiometric Surface Map 4 Total VDCS Concentrations September 4, 2408 5 Total Chlorinated Hydrocarbons September 4, 2008 APPENDICES A Laboratory Report and Chain -of -Custody Document B Total VOC Graphs TRic,oN I KLENFELDEk NC. Page ii Ms. Beth Money, Gilbarco September 26, 2008 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 042-08-018 1.0 INTRODUCTION The subject site is located at 7300 West Friendly Avenue in Greensboro, Guilford County, North Carolina (Figure 1). There are currently two open groundwater incidents (Incident Nos. 12960 and 15123). The incidents have a commingled plume and are being treated with the same corrective action plan. A pump and treat system is currently operating at the site. The system consists of four recovery wells, an oil -water separator, and an air stripping system. A drastic and sudden increase in the concentration of methyl ten -butyl ether (MTBE) was detected in the laboratory analysis of groundwater samples from MW-32 during the August 2006 sampling event. Because of the MTBE levels detected in monitoring well MW-32, the well was resampled on November 1, 2006. Similar levels of contaminants were detected in the subsequent laboratory results. In order to collect additional information and assess the potential origin of the MTBE, monitoring well MW-32 was evacuated over a period of eight hours on December 7. 2006. The well was evacuated using a vacuum truck with Aggressive F1uidNapor Recovery and twenty-four gallons of petroleum impacted groundwater were removed. An additional groundwater sample was collected from MW-32 following the evacuation of the well. Monitoring well MW-32 and two nearby wells (MW-7 and MW-28) were sampled on December 14, 2006. Laboratory analytical results from the December 14, 2006 sampling event determined MTBE levels in monitoring wells MW-7 and MW-28 were below laboratory detection limits. The MTBE concentration From the groundwater sample collected from MW-32 on December 14, 2006 was consistent with the previous laboratory results. In January 2008, Trigon I Kleinfelder submitted a CAP Addendum recommending the use of HiSOC and iSOC technology to degrade the chlorinated and petroleum hydrocarbons in groundwater at the site. This technology will work in concert with the existing groundwater recovery system and supplement the ability of the system to contain the contaminant plume within the property limits and reduce contaminant levels. The HiSOC system was installed in June of 2008 and began operating on June 13, 2008. The baseline sampling event was conducted on June 5, 2008. The purpose of this report is to summarize the quarterly monitoring of the HiSOC system performed on September 4, 2008. TFuGON I KLEMMMER, INC. Page 1 Ms. Beth Money, Gilbarco September 26, 2009 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 042-48-018 2.0 GROUNDWATER MONITORING ACTIVITIES Static water levels were measured in the existing monitoring wells on -site on September 4, 2008. Groundwater samples were collected from ten of the monitoring wells (MW-7, MW-11, MW-13, MW-13D, MW-14, MW-23D, MW-24, MW-25, MW-42, and MW-45) and analyzed for VOCs by EPA Methods 601 and 602, isopropyl ether, methyl tert-butyl ether, ethylene dibromide, and xylenes. Field parameters including oxidation-reduction potential (ORP), pH, conductivity, dissolved oxygen, and temperature of representative groundwater samples were also recorded from each monitoring well sampled. Groundwater elevations in the existing monitoring wells were used to determine the groundwater flow direction, average hydraulic gradient, and plume orientation. Table 1 provides a summary of monitoring well construction details and the groundwater elevations measured on September 4, 2008. The monitoring well locations are shown on Figure 2. The static water levels measured on September 4, 2008 between monitoring wells MW-32 and MW-45 indicate a horizontal groundwater flow gradient of 0.04 feet per foot to the northwest. A groundwater flow map of the shallow aquifer based on the September 4, 2008 groundwater elevations are shown on Figure 3. Free product was not observed in any of the monitoring wells during the sampling event. Based on data provided in the October 1996 Corrective Action Plan, the surfcial aquifer has an average hydraulic conductivity of 0.09 feet per day. The average groundwater velocity is estimated to be 0.01 feet per day (4 feet per year), based on the average groundwater gradient from the September 4, 2008, water level measurements and an estimated effective porosity of thirty percent. Groundwater samples were collected from monitoring wells MW-7, MW-Il, MW-13, MW-13D, MW-14, MW-23D, MW-24, MW-25, MW-42, and MW-45 using disposable polyethylene bailers. The wells were purged of three well volumes of water or until they were bailed dry. Groundwater purged from the monitoring wells was disposed of in the on -site groundwater recovery system. Groundwater samples were collected and placed in laboratory prepared containers. The samples were maintained on ice until delivered to Pace Analytical Laboratories in Huntersvilie, North Carolina. TwooN j KLEiNFELn£Ii, INC. Page 2 Ms. Beth Money, Gilbarco September 26, 2008 7300 West Friendly Avenue. Greensboro, North Carolina Trigon I Kleinfeldcr Project No. 042-08-018 3.0 GROUNDWATER ANALYTICAL RESULTS The groundwater field analysis generally indicates that the subsurface environment is within acceptable limits for biodegradation to occur. The field measurements recorded on September 4, 2008 are summarized in Table 2, which includes the preferred conditions for natural biodegradation of chlorinated compounds within the groundwater plume. Conductivity is recorded for quality control and sampling consistency. Volatile organic compounds were detected at levels above the respective North Carolina groundwater quality standards established in 15 NCAC, Subchapter 2L (2L Standards) in six of the ten monitoring wells sampled. The analytical results are summarized in Table 3 and a historical summary of groundwater sampling results is presented in Table 4. A chain -of -custody document was maintained throughout the collection and transportation process and is included in Appendix A with the laboratory report. Historical total volatile organic compound concentrations for each monitoring well sampled are shown in individual graphs included in Appendix B. The individual graphs of the total VOC concentration for each monitoring well indicate MW-7, MW-11, MS-13, MW-13D, MW-23D, and MW-24 generally have trends of decreasing contaminant levels. Other graphs of contaminant concentrations indicate the total VOCs levels remain fairly consistent (MW-14, MW-42, and MW-45). The trend of rising contaminant concentrations are of concern in monitoring well MW-25. Total VOCs concentrations detected during the September 4, 2008 sampling event are shown on Figure 4. The current hydrogen injection phase of the corrective action plan targets the reduction of chlorinated hydrocarbon contaminant levels in the groundwater. The oxygen injection phase will target the reduction of petroleum hydrocarbons. The volatile organic compounds targeted during the hydrogen and oxygen injection phases of the corrective action plan are separated in Table 4 by a double line. Total chlorinated hydrocarbons concentrations detected from the groundwater samples collected September 4, 2008 are ' shown on Figure 5. TRIGoN `KLEINFELt]ER, INC. Page 3 Ms. Beth Money, Gilbareo September 26, 2008 7300 West Friendly Avenue, Greensboro, North Carolina THgon I Meinfelder Project No. 042-08-01 & 4.0 HiSOC INSTALLATION AND MONITORING Trigon j Kleinfelder applied for a permit from the Underground Injection Control (UIC) Program for the installation of a hydrogen and oxygen delivery system for remediation of contaminants in groundwater at the site. A permit dated March 20, 2008 was issued for the site (Injection Well Permit W10400091). The permit is effective through April 30, 2010. Installation of the injection equipment was initiated on April 9 through April 11, 2008. The existing protective casings were removed from monitoring wells MW-7, MW-10, MW-23D, MW-29, and MW-34. Ten inch diameter PVC casings were installed to a depth of five feet below ground surface adjacent to the monitoring well locations to hold the hydrogen cylinders. Six to ten inches of gravel was placed in the bottom of each casing, Excavations were completed for installation of twenty-four inch square, steel well vaults and the vaults were set in concrete flush with the ground surface. Protective vaults were also installed adjacent to the existing above grade protective covers for monitoring wells MW-14D, MW-I5, MW-16, MW-24, and MW-43D. The 15 inch by 24 inch PVC protective vaults were installed over the cylinder casings. Vents were installed in the protective vaults to allow hydrogen to be released in the case of a leak from the delivery system. The HiSOC equipment from InVentures was installed at the site in ten existing monitoring wells (MW-7, MW-10, MW-141), MW-15, MW-16, MW-23D, MW-24, MW-29, MW-34, and MW-43D) on June 13, 2008. Within each injection well is a HiSOC unit and filter. Hydrogen is supplied from a compressed gas cylinder with a regulator and gauge connected to the HiSOC unit by Parflex tubing and a support cable. Four foot grounding rods were installed and connected to the regulator assembly of the gas cylinders. The HiSOC installation locations are shown on the figures in orange. In anaerobic bioremediation applications, the HiSOC supersaturates the treatment well with dissolved hydrogen, typically at a concentration of 1 to 4 parts per million (ppm) depending on the immersion depth of the HiSOC unit in groundwater. The dissolved hydrogen concentration achieved in the injection well depends on the height of the water column in the well. Each atmosphere of pressure allows for a maximum of approximately 1.6 ppm of dissolved hydrogen. Table 5 estimates the dissolved hydrogen concentrations in each of the injection wells. These concentrations are estimated based on the approximate pressure at the installation depth of the HiSOC based on the depth of the water column in TwooN j KLEiNFELDFR, bTc. Page 4 Ms. Beth Money, Gilbarco September 26, 2008 7300 West Friendly Avenue, Greensboro, north Caoline Trigon I Kleinfelder Project No. 042-08-018 the injection wells, The calculation is made with the assumption that 1.6 ppm of hydrogen is dissolved in the groundwater per atmosphere of pressure. Hydrogen is infused from the HiSOC into the treatment well at a typical rate of 28 standard cubic centimeters per minute or approximately 1.4 cubic feet per day. The hydrogen consumption in each of the injection wells is tracked to estimate the remaining service life of the hydrogen cylinders. Table 6 shows the recorded hydrogen cylinder pressures and estimates a date for each injection well that the cylinder should be replaced. It is anticipated that the hydrogen cylinders will be replaced prior to the next quarterly monitoring event scheduled for December 2008. The HiSOC produces a convection current in the well with a designed release bubble from the top of the HiSOC to distribute dissolved hydrogen rich water throughout the screened interval. A curtain of hydrogen rich water disperses around the well into the adjacent groundwater forming a treatment zone allowing enhanced bioremediation to degrade the target contaminants. Following installation of HiSOC units in monitoring wells MW-10 and MW-29, the HiSOC units were found to be flooded. The HiSOCs were removed and the units were dried for a period of two weeks prior to re -installation. Otherwise the hydrogen delivery system has been in continuous operation since June 13, 2008. 5.0 CONCLUSIONS AND RECOMMENDATIONS The groundwater potentiometric map indicates that the groundwater flow direction at the site is from the southeast to the northwest under a gradient of 0.04 feet per foot as measured between MW-32 and MW-45, Contaminant levels in monitoring wells MW-7, MW-11, MW-13, MW-13D, MW-23D, and MW-24 have decreased when compared to the groundwater contamination levels during the baseline sampling event in June 2008. Groundwater contaminant levels in monitoring wells MW-14, MW-42, and MW-45 remained consistent with the baseline levels and monitoring well MW-25 showed an increase. These four wells have relatively low chlorinated hydrocarbon levels and were not significantly different than their historical averages. Groundwater aquifer characteristics monitored during the sampling event indicate suitable conditions for biodegradation of chlorinated hydrocarbons exist at the site. Based on a comparison of the aquifer characteristics during the baseline sampling event, the monitoring wells that Truooh I KLENFELDER, LNc. Page 5 Ms. Beth Money, Gilbareo 7300 West Friendly Avenue, Greensboro, North Carolina September 26, 2008 1 K1einfelder PrajectNo, 042-08-018 showed a significant decrease in chlorinated hydrocarbon levels (MW-7, MW-11, MW-23D, and MW- 24) also showed improved biodegradation conditions. Corrective action monitoring will be conducted on a quarterly schedule and the next event should be scheduled for December 2008. During the next sampling event, we recommend the following wells are sampled: MW-7, MW-13, MW-13D, MW-14, MW-16, MW-231), MW-24, MW-25, MW-42, and MW-45. Monthly system checks should also be conducted during the next quarter to monitor the rate of hydrogen consumption of the HiSOC delivery system. Copies of this report have been mailed to the Guilford County Department of Environmental Health in Greensboro, North Carolina and the UIC Program in Raleigh, North Carolina. TRiGoIv { KLEiNw-LD M. INc. Page 6 Ms. Beth Money. G iibarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE I: GROUNDWATER ELEVATION DATA September 26, 2008 Trigon I Kleinfelder Project No, 042.08-018 Well ID Total Depth (feet TUC) TOC Elevation (feet) Date Water Level Measured Static Water Level (feet TOC) Groundwater Elevation (feet) MW-7 29.9 861.19 09/04/08 7.47 853.72 MW-10 33.6 860.36 09/04/08 9.78 850.58 MW-11 25.1 859.26 09/04/08 15.95 843.31 MW-12 16.8 851.50 09/04/08 11.24 840,26 MW-12D 27.0 851.06 09/04/08 11.29 839.77 MW-13 24.2 861.29 09/04/09 16.39 844.90 MW-13D 39.4 860.40 09/04/09 15.93 844.47 MW-14 24.8 859.32 09/04/08 22.17 837.15 MW-14D 41.0 859.26 09/04/08 22.80 836.46 MW-15 25.2 857.71 09/04/08 15.79 841.92 MW-16 35.2 863.60 09/04/08 30.64 832.96 MW-23D 57.1 860.90 09/04/08 17.60 843.30 MW-24 58.8 858.81 09/04/08 23.63 835.18 MW-25 168.9 861.47 09/04/08 25.61 835.86 MW-27 44.0 862.74 09/04/08 14.71 848.03 MW-28 23.8 861.54 09/04/08 9.94 851.60 MW-29 18.8 861.13 09/04/08 5.22 855.91 MW-30 73.4 862.28 09/04/08 16.78 845.50 MW-31 19.0 861.73 09/04/08 11.83 849.90 MW-32 19.6 861.76 09/04/08 10.49 951.27 MW-33 21.0 861.77 09/04/08 16.21 845.56 MW-34 21.0 860.45 09/04/08 15.30 845.15 MW-40 29.7 860.62 09/04/08 11.33 849.29 MW-41 20.3 860.52 09/04/08 9.95 850.57 MW-42 35.0 865.32 09/04/08 32.21 833.1I MW-43D 53.0 865.47 09/04/08 32.71 832.76 MW44 28.5 NM 09/04/08 18.83 --- MW-45 36.2 861.79 09/04/08 29.94 831.85 Notes: feet TOC = feet below top of well casing TRIGON I KLEINFELDEP,1NC. Page I of 6 Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 2: AQUIFER CHARACTERISTICS FIELD ANALYSIS SUMMARY September 26, 2008 Trigon I Kleinfelder Project No. 042-08-018 Monitoring Well Sample ©ace Temperature (°C) pH Conductivity (mSlem3] DissolvedRedox Oxygen (mV) Preferred Conditions a 200C 5<pH<9 --- <0.5 mg/L <50 mV MW-7 09/04/08 18.99 8.14 0.293 0.60 -232.3 MW-11 09/04/08 18.45 7.03 0.350 3.09 -28.4 MW-13 09/04/08 1997 6.76 0.431 1.41 245.1 MW-13D 09/04/08 19,10 7.22 0.455 1.56 -149.7 MW-14 09/04/08 16.48 6.99 0.185 9.28 115.7 MW-23D 09/04/08 18.33 8.07 0.598 0.49 -425.6 MW-24 09/04/08 15.93 7.81 0.611 0.58 -185.3 MW-25 09/04/08 15.55 9.25 0.258 <0.69 -223.1 MW-42 09/04/08 15.25 8.03 1.567 4.11 8,9 MW45 09/04/08 1 14.28 J 8.24 1 0.483 1 2.43 1 -66.7 Notes: Redox = oxidation-reduction potential °C = degrees Celsius mSlcm3 = millisiemens per cubic centimeter mg/L = milligrams per liter, analogous to parts per million mV = millivolts Conductivity is measured for consistency in groundwater sample collection. TRIGON i KLEINFELDER, INC. Page 2 of 6 Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 3: SUMMARY OF GROUNDWATER SAMPLE RESULTS September 26, 2008 Trigon I I{leinfelder Project No. 042-0"18 Parameter NCGS 2L Standard Analytical Results Sample ID MW-7 1 MW-1 I MW-13 MW-13❑ MW-14 MW-23D MW-24 MW-25 MW42 MW45 Collection Date 09/04/08 1 09/04/08 09/04/08 09/04/08 09/04/08 09/04/08 09/04/08 09/04/08 09/04/08 09/04/08 Volatile Organic Comp) u►ads by EPA Method 6011602 (pg/l} Tetrachloroethene 0.7 BDL BDL BDL BDL 50 BDL 1,430 18.7 5.7 BDL Trichloroethene 2.8 BDL BDL BDL BDL BDL BDL 51.7 5.2 BDL BDL cis- 1,2-❑ichloroethene 70 1,190 BDL 67.9 15.2 BDL 5.3 349 33.2 BDL BDL Vinyj Chloride 0.015 BDL BDL BDL 3.1 BDL BDL BDL BDL BDL BDL Total Chlorinated H drocarbons 1,I90 0 68 18 50 5 1,831 57 6 0 Benzene 1 BDL BDL BDL BDL BDL BDL 253 BDL BDL BDL Eth ]benzene 550 788 BDL BDL BDL BDL BDL. BDL BDL BDL BDL Total X lenes 530 873 BDL BDL BDL BDL BDL BDL BDL BDL BDL MTBE 200 BDL BDL BDL 17.6 BDL 19.3 BDL 3 BDL BDL Diisopropyl ether 70 BDL BDL BDL BDL BDL BDL 60.3 4.8 BDL BDL Na hthalene 21 301 BDL BDL BDL BDL BDL BDL BDL BDL BDL Total Petroleum Hydrocarbons 1,962 0 0 18 0 19 313 8 0 0 Total VOCs 3,152 0 68 36 50 25 2,144 65 6 0 Notes: NCGS 2L Standard = North Carolina Groundwater Standard BDL = Below Detection Limits gg11= Micrograms per liter, analogous to parts per billion BOLD = Concentration exceeds the NCGS 2L Standard MTBE = Methyl-tert-butyl ether TRtGON I KLEINFELDER, INC. Page 1 of 1 M5. Beth Money, Gilbarcn 7300 West Friendly Avenue. Greensboro, North Carolina TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS September 26, 2008 Trigon I Kleinfelder Project No. 042.08-018 Sam le ID Chlorinated Hydrocarbons Hydrocarbons Total Chlorinated Petroleum Hydrocarbons 'Dotal Petroleum Total VDC CoBcetion Date Tetrachloroetheste Trichloraetbeoe cis 1,2-Dichloroetlterte l,l•Dicblaroethene Vinyl Chloride l,I-Dichlaraetttane l,2-Dichioroethane trans-1,2- Dichloroethme l,l.l-Trichloraethanc Benzene ntuenr T Ethylbenune Total ]{yleaes MTBE biisapropyi ether NaphthaleneHydrocarbons NCGS 2L Sid 0.7 2.9 70 7 t 0.015 1 70 1 0.38 S00 200 1 1,000 550 1 530 1 200 70 21 MW-7 M27190 790 190 BDL SDL BDL BDL BDL BDL 59 1,039 650 5,300 1,500 5,700 BDL SDL BDL 13,150 14,189 01/14/92 SDL 360 BDL SDL BDL BDL BDL BDL BDL 360 480 3,900 21100 7,100 BDL BDL SDL 13,580 13,940 03/11/98 BDL BDL BDL 3S4 SDL BDL BDL BDL 238 592 468 8,9I0 2,200 8,990 SDL BDL BDL 20.579 21.170 05/25/99 BDL SQL BDL 723 BDL BDL BDL BDL 347 1,070 253 21280 2,290 10,800 SDL SDL BDL 15,623 16.693 04)VJ03 BDL BDL BDL SDL SDL BDL BDL BDL 88 88 BDL 220 2,400 5,71)0 SDL 60 SDL 8.380 8,468 065(04 SDL BDL 1,300 SDL BDL BDL BDL BDL BDL 2,300 BDL l t0 1,800 3,800 SDL SDL 520 6,230 8.530 08116/05 BDL I BDL 1,100 BDL SDL BDL BDL BDL BDL 2,100 SAL BDL 1,600 390I0 SDL BDL 520 5,140 7,240 08/25M6 BDL BDL 2,000 14 BDL SDL BDL 1.3 14 21030 1.7 23 370 380 11 3.3 82 $71 2,901 IV14106 3.6 4 2,100 570 BDL 15 SOL 5.1 13 2.711 4.1 39 1,300 19660 BDL SDL 440 3,443 6,154 06/05/08 BDL BDL 1.750 BDL BDL BDL SDL BDL BDL 1,750 BDL BDL I,040 1,280 BDL BDL 401 2.721 4,471 09/04/08 BDL BDL 11190 SDL BDL SDL BDL BDL BDL 1,190 BDL BDL 783 873 SDL BDL 301 1,962 3,152 MW-8 (abandoned) 09/27M 13DL BDL SDL SDL BDL BDL SAL BDL BDL 0 BDL BDL SDL 1 SDL BDL BDL I i 01/1V92 BDL BDL SAL BDL BDL BDL SDL BDL BDL 0 BDL BDL BDL SDL SDL BDL BDL 0 0 05/15/92 BDL BDL SDL BDL BDL BDL BDL BDL BDL 0 SDL BDL BDL BDL BDL BDL SDL 0 0 MW-9 (abandoned) 09/27/90 10 2 SDL SDL BDL BDL SDL BDL BDL 12 2 BDL BDL BDL BDL BDL BDL 2 14 O1/14/92 BDL BDL BDL BDL BDL BDL SDL BDL BDL 0 SDL BDL BDL BDL BDL BDL SDL 0 U 05/15/92 SDL BDL SDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 MW-10 09127M 76 140 BDL SDL BDL BDL SAL BDL 140 356 2,900 66 BDL 670 BDL BDL SDL 3.636 3,992 01/14/92 BDL 78 BDL 110 SDL BDL SDL BDL BDL 198 2,900 BDL BDL 120 BDL BDL SDL 3,020 3,219 03/1IM BDL SDL BDL 13.9 BDL BDL BDL BDL SDL 14 234 BDL SDL BDL BDL BDL SDL 234 248 05/26/99 SAL BDL BDL BDL BDL BDL SDL BDL BDL 0 36 BDL BDL BDL BDL BDL BDL 36 36 10/10/02 5.9 2.3 SDL 4,4 BDL BDL SDL BDL 7.3 20 220 8.5 16 71 29200 16 BDL Z,532 2,551 04/22/03 3.2 1.3 BDL BDL BDL BDL SDL BDL 2,6 7 47 SQL BDL BDL 11100 2.9 BDL 1,150 1,157 06r30104 BDL BDL 9.1 BDL BDL SDL BDL SAL BDL 8 22 SDL 2.8 5.8 770 2.8 BDL 903 8l2 05/16/05 BDL SDL BDL SDL SDL SDL BI7L SAL BDL 0 43 BDL BDL BDL 680 SDL SAL 723 723 09124/06 BDL SDL 3 BDL BDL BDL BDL SDI. BDL 3 8.1 I BDL BDL SOL 360 4.3 SDL 372__J 375 MW-il OW0104 2.1 3 1.4 SDL SAL BDL BDL BDL BDL 7 SDL BDL BDL BDL 4.1 BDL BDL 4 11 08/15/05 5 3.6 9.7 BDL SDL SDL BDL BDL BDL 18 BDL 130L BDL BDL 2.2 BDL BDL 2 21 08/24/06 4.9 2.5 5.2 BDL SDL BDL BDL BDL BDL 13 SDL SDL BDL BDL 4.4 SDL SDL 4 17 06/05/08 6.8 1.5 5.0 BDL SDL BDL BDL BDL BDL 13 BDL BDL BDL BDL BDL BDL BDL 0 13 09/04/08 SDL BDL BDL BDL SDL BDL BDL SDL BDL 0 BDL BDL BDL BDL BDL SDL J SDL 0 0 MW-12 09/27/90 BDL BDL BDL BDL BDL 3DL BDL BDL BDL 0 SDL SOL SDL SAL BDL BDL BDL 0 0 01/14/92 BDL BDL BDL 130L SAL BDL BDL SDL SDL 0 SDL SDL BDL BDL SDL BDL BDL 0 0 03111/" BDL SDL BDL BDL SDL SDL BDL SDL BDL 0 BDL BDL BDL SDL SDL SDL BDL 0 0 03126/99 SDL BDL BDL BDL SDL BDL BDL SDL BDL 0 BDL BDL BDL BDL BDL SDL BDL 0 0 06/30/04 SDL SDL BDL BDL SDL BDL BDL SDL BDL 0 BDL BDL SDL SDL SDL SDL BDL 0 0 08/15/05 BDL SDL BDL BDL BDL BDL BDL SDL BDL 0 BDL BDL BDL SDL SDL BDL BDL 0 0 08/24/06 30L SDL BDL BDL SDL SDL BDL SDL BDL 0 SDI. BDL SAL BDL SDL 8DL BDL 0 0 mW-12D 09/27/90 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 SDL BDL BDL BDL SAL BDL BDL 0 0 01/14/92 BDL BDL BDL BDL SDL BDL BDL SDL BDL 0 SDL BDL BDL BDL SDL BDL SDL 0 0 03/11/98 SDL BDL BDL BDL BDL BDL BDL 8DL SDI. 0 BDL SDL BDL BDL SOL BDL BDL 0 0 O26/99 SDL BDL BDL BDL SDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL SDL SDL 0 0 06/30/04 SDL SDL BDL SDL BDL SDL BDL BDL SDL 0 SDL BDL BDL BDL SAL BDL SDL 0 0 08/15/03 BDL BDL BDL BDL BDL BDL BDL BDL SDL 0 SAL BDL BDL SOL BDL BDL BDL 0 0 08/24/06 SDL SDL BDL BDL BDL SDL SDL BDL BDL 0 BDL EIDL BDL BDL SDL I BDL BDL 0 0 Notes. All units measured in µ81L BDL - Selow Detection Limits NCGS 2L Std. - North Carolina Groundwater Standard BOLD - Concentration exceeds the 21, Grotmdwaier Quality Standard MTBE - Methyl -ten buryl ether TRIGON I XLEINFELDER, INC. Fagc I of 4 Ms. Beth Money, Gilbarco 7300 West Fnendly Avenuer Greensboro, North Camliaa TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS September 26. 2008 Tsigon I Kkinfelder Project No. 042-09-010 Sam le ID Chlorinated S drocmi-buns Petroleum Hydrocarbons Collection Date Teunchl noethrne Trichlorvethene cis-i,2-Aichlttsvetheste 1,1-pichloroethenr Vinyl Chloride 1.1-Dichlorcethane 1,2-D chlnroethanc tratus-1,2- Dichloroethane l,l,l-Trichloraethane Total Chlorinated ry drocarbons Brturnc Talueae Ethylbcnzenr Total Xylencs MT13E Diisopropyl ether NaphthnIenr Hydrocarbons Tatai Petroleum Total VOCs NCGS 2L Sid. D.7 2.9 70 7 0.015 70 0,38 ]00 200 -- 1 I.D00 550 530 200 70 21 MW-13 09/26/90 2 SOL BDL SDL BDL BDL BDL BDL BDL 2 SOL BDL 13DL BDL BDL BDL BDL 0 2 01/14/92 130 36 BDL BDL BDL SOL BDL BDL BDL 166 SDL BDL SOL BDL BDL SDL SOL 0 166 05/15/92 130 20 SDL SDL SOL SDL BDL BDL BDL 150 SOL BDL BDL BDL SOL SDL SDL 0 150 03/11/98 2.5 4.7 BDL SDL BDL BDL SDL BDL SDL 7 SDL SDL SDL BDL BDL SDL BDL D 7 05126+99 4.2 1S BDL SDL BDL BDL BDL BDL BDL 19 BDL BDL SDL BDL BDL BDL SDL 0 19 06/30/04 BDL 6,5 140 BDL BDL SOL SOL BDL BDL 147 SOL BDL BDL BDL 13 SDL BDL 13 160 02/13/05 BAL SOL 110 SDL BDL BDL BDL SDL BDL i10 BUL BDL SDL SDL BDL BDL BDL"41'1 08124/06 SDL 2.9 Ito BDL BDL BDL BDL 1.1 SDL 114 BDL SOL BAL SAL 34 SDL SQL 06/05/08 BDL BDL 94.7 SDL SOL SDL SDL BDL BDL 95 6.4 BDL SDL SDL BDL SDL SDL MUM SDL SDL 67.9 SDL BDL SOL SOL SDL SDL 68 BDL BDL BDL BDL BDL BDL SDLmw-13D 06/30/04 BDL SDL 18 BDL 15 BAL B➢L SpL BDL 2D 1.1 HDL BDL BQL 26 lI BDL 0105105 BDL BAL 37 SDL 1.4 SDL SOL SDL SDL 38 SDL SOL BDL SDL 20 L3 SDL 21 60 08f24106 BDL SDL 30 SDL 1.3 BDL SOL SDL SDL 31 BDL SQL BDL SDL 19 BDL SDL 19 50 06/05/08 BDL SDL 21.6 SDL 3-2 SOL SDL SDL SOL 25 SDL SDL 3.0 3.6 I2.5 1.7 SDL 21 46 09/04/08 SDL SDL 152 SDL 3.1 BDL BDL SDL SDL 18 BDL SDL BDL I SDL 17.6 BDL SOL l8 36 MW-14 09/26190 1,300 BDL SDL BDL BDL BDL BDL SDL SDL 1,3D0 BDL SDL BDL BDL BDL BDL BDL 0 1,300 01/34/92 1,400 13DL BDL BDL SDL SOL Ho SDL 100 1,680 BDL 60 SOL 100 SDL SDL BDL 160 1,940 03/31/98 80 SDL BDL BDL BDL BDL BDL SOL BDL 80 BDL SDL SDL SDL BDL BDL SOL 0 80 05/25/99 67 SDL BDL BDL BDL BDL BDL SDL SOL 67 BDL SOL BUL BDL SOL SOL SOL 0 67 04122/03 lie SOL SDL SQL BDL SOL SOL BDI. BDL 110 1.1 1.7 SDL 1.9 BDL BDL SOL 5 115 06/30/04 80 SDL BDL SDL BDL BDL BDL SOL BDL 80 SDL SOL BDL SOL BDL SDL BDL D 80 08+16/05 58 BDL BDL SDL BDL SOL BDL SOL SOL 58 BDL SOL SDL SOL BDL SDL SOL 0 58 OIV24106 46 9DL BDL SQL SDL BDL BDL SDL SDL 46 SOL SDL SDL BDL BDL SDL BDL 0 46 06/05/08 54.0 SOL BDL SDL BDL SDL SDL SDL BDL 54 SOL SOL SOL SOL BDL SAL SDL 0 54 09/04/08 S(LO SDL SOL BDL BDL SOL BDL SOL BDL 50 SDL SOL BDL SDL BDL SOL BDL 0 50 14W-1411 09/27/90 110 3 BDL 58 SOL 5 SOL SAL 20 196 45 1 BDL 5 BDL BDL BpL 51 247 01/14/92 20D SDL BDL BDL SAL SOL BDL SDL BDL 200 65 3 SDL BDL BDL SOL BDL 68 268 05/15/92 56 BpL SDL 2.1 SDL SOL BDL SDL BDL 58 4.7 SOL SOL BDL BDL SDL BDL 5 63 MOM 210 SDL BDL 23 SDL 13DL BDL SDL 13 246 220 BDL BDL BDL BDL SOL BDL 220 466 03/1i/98 35.4 SDL BDL I" BDL SOL SOL 13DL BDL 46 5.6 SAL BDL BDL BDL BAL BDL 6 05/25/99 2W BDL BDL 25 BDL SOL SOL SDL BDL 226 67 BDL BDL SDL BDL BDL SQL 67 10/10/02 79 2.8 SDL 4 SDL 4.2 SDL SDL BDL 90 U BUL SOL BDL 11 29 SDL 48 04/27/03 40 SDL BDL 1.2 SDL BDL SDL SDL BDL 41 SDL BDL BDL HDL BDL 1.8 BDL 2 K78 06/30/04 29 SQL 3.0 3.5 SDL 2.2 BDL SDL SDL 35 BDL SOL BDL BDL 3.3 BDL SDL 3 08/16/05 55 1.8 15 3.3 SOL BDL BDL BDL SOL 75 5A BDL BDL BDL 3.2 7,3 SAL 16 08/24/06 47 2 17 1.4 BDL 13DL B➢L SDL BDL 67 1.3 BDL SDL SDL 2.4 6A SDL 10 MW-15 09/27/90 SDL SDL SDL SOL BDL BDL BDL SOL BDL 0 SDL SDL BDL BDL SDL BDL SDL 0 0 011141W SDL BDL BDL SDL BDL SOL BDL SOL BDL 0 SDL BDL BDL SDL SOL BDL SDL 0 0 Will/" BDL SDL BDL BOIL BDL SOL SDL SDL SOL 0 SDL BDL BDL SDL SDL BDL BDL 0 0 05/25/99 4.9 3 BpL BDL BDL SOL SDL BDL SOL 8 BUL BDL BDL SDL SOL BDL BDL 0 8 10/10/02 13 7.8 SDL SOL BDL 1.4 BDL SDL SOL 22 SDL SOL BAL SOL 29 BDL SOL 29 SI 04/22/03 11 5 SDL SOL BDL 1.4 BOL SOL BDL 17 SDL BDL BDL SOL 17 BDL BDL 17 34 06/30/04 7.5 3.9 8fi SDL BDL Sp1 BDL BDL BDL 97 SDL BAL SDL SDL 18 BDL BDL l$ 115 08/16/05 68 '_.3 47 SDL SDL SDL SQL BDL BDL 56 SDL SDL BDL SAL 15 SDL SDL IS 7l 08/24/06 5.5 5 48 SDL SOL SDL BDL BDL SDL 59 BDL BDL BDL SDL 8 BDL BDL 1 8 67 Notts, All units measured in pg/L 8DL - Below Detection Limits NCGS 2L Sol. -'forth Caroline Groundwater Standard BOLA - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl-tert butyl ether TRIGON I KLEINFELDER, LNIC. Page 2 of 4 September 26, ZOOS Tnpn I Klemfelder Project No. 042-08-418 Ms. Beth Money. Gilbareo 7300 Weal Fnendly Avenue, Ca msboro, North Casolum TABLE 4: HISTORICAL SL WMARY OF GROUNDWATER SAMPLE RESULTS Sam to 10 Chlorinated 11 drocarbana 1 11 Petroleum H drocarboaa Collection Date Tetrachloroethene Trichloroethcne cis-1,2-Dichloroethene 1,1-Dichlorvethene Vinyl Chloride 1,1-DidhiarMedwne 1,2-DiAloroethane trms-1,2 Dichlormhane ],1,1-Trichloreethane TotaIChlortasted Hvdrocar6nna Benzene Toiuert EthyFbenxette Total Xylenes MTBE Diisoprovyle0w Naphthalene TatalPetroleam Hydrocarbons TotalVRCs NCGS 2L Std 0 7 2.8 70 7 0.015 70 0.38 WO 200 1 1,000 550 530 200 70 21 MW-I6 09/26M BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL B➢L BDL BDL BDL BDL 0 0 03/11M 1.9 BDL BDL BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 0S/02,199 2.4 BDL BDL BDL BDL BDL 13DL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 1011WO2 I2 3.8 BDL 1.8 BDL BDL BDL BDL BDL 28 BDL BDL BDL BDL BDL BDL BDL 0 28 041221❑3 46 9.6 BDL 3.6 BDL BDL BDL BDL BDL 58 BDL BDL BDL BDL 36L BDL BDL 0 58 0&30104 31 7.6 24 27 BDL 1 BDL BDL BDL. 66 BDL BDL BDL BDL BDL BDL BDL 0 66 08/15/05 3p 4,4 BAL l.8 BDL BDL BDL BDL B➢L 36 BDL BDL BDL SAL BDL 17 BDL t7 53 08125106 1 36 7.4 31 2.9 BDL BDL BDL BDL BDL 77 BDL BDL BDL BDL SAL BDL BDL 0 77 NSW-17 abandoned 01r03106 09/26/90 1 BDL 9DL BDL BDL BDL BDL BDL BDL I BDL BDL BDL BDL BDL BDL BDL ❑ 1 01/14N2 BDL 3 BDL BDL BDL BDL BDL BDL BDL 3 SDL BDL BDL BDL BDL BDL BDL 0 3 03/11/98 BDL BDL BDL BDL I BDL BDL I BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06102199 BDL 8DL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 D6r30104 BDL 8DL BDL BDL BDL BDL BDL BDL BDL 0 SQL BDL BDL BDL 17 BDL BDL 17 17 MW-23D D9127/90 BDL 2 BDL BDL BDL 5 5 BDL BDL 12 1 BDL BDL BDL BDL BDL BDL t 13 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 05/15/92 BDL 2.2 BDL BDL BDL 5.3 BDL 8DL BDL $ 45 BDL BDL BDL BDL BDL BDL 45 53 09/09r'uY' 1-9 63 BDL 54 BDL 65 2 BDL BDL 22 6,3 BDL BDL BDL BDL BDL BDL 6 28 03/11/98 2.5 25 BDL I4 BDL 29 BDL BDL 4 13 7.1 3.7 BDL BDL BDL BDL BDL 11 24 05/26/99 BDL 4.1 BDL 24 BDL 5.7 2.6 BDL BDL 15 3.1 BDL BDL BDL BDL BDL BDL 3 18 06/30/04 BDL BDL 200 BDL BDL BDL BDL BDL BDL 200 BDL BDL DDL BDL 500 12 BDL 512 712 08/15/05 BDL BDL 280 BDL BDL BDL BDL BDL BDL 2.80 BDL BDL BDL BDL 310 BDL BDL 310 590 OV24106 BDL 11 340 BDL 1.9 BDL BDL BDL BDL 343 1.8 BDL BDL BDL 310 9.1 BDL 321 664 0610510B BDL 3DL 166 BDL BDL BDL BDL BDL BDL 166 BDL BDL 20.2 23.6 209 BDL BDL 252 418 09,04108 BDL 3DL 53 BDL BDL BDL BDL BDL BDL 5 BDL BDL BDL BDL 193 BDL BDL !9 25 MW-24 09,27190 630 28 BDL 60 BDL BDL BDL BDL BDL 718 1,5W SO BDL 8o BDL BDL BDL 1.660 2.379 01/14/92 3,8DD 110 BDL 200 BDL BDL 56 BDL 80 4,246 l,800 260 BDL 340 BDL BDL BDL 2,400 6,646 05/1519l- 1,40D 25 BDL 4 9 BDL BDL BDL 3DL BDL 1,430 W100 ISO BDL BDL BDL BDL BDL 1,980 3.410 091,09192 2170D HDL BDL BDL BDL BDL BDL BDL 100 2,800 2,500 150 BDL 150 BDL 3DL BDL 2,8DO 5.600 03/11/96 IX" 3DL BDL BDL BDL BDL BDL BDL BDL 1230 1,920 BDL BDL SDL BDL BDL BDL 1.920 3,150 05/25/99 637 BDL BDL BDL BDL BDL BDL BDL BDL 637 1,510 SAL BDL BDL BDL BDL BDL 1,510 2,147 10gWD2 I,ODD 68 BDL 31 BDL 11 2.5 BDL 49 2.117 1,700 16 14 1 27 180 530 BDL 2,454 4,572 04/22/03 640 24 BDL 17 BDL 64 BDL BDL 18 689 500 64 BDL 63 81 ISO BDL 774 1.463 0&130104 870 BDL 37O BDL BDL BDL BDL BDL BDL 1,240 780 BDL BDL BDL 74 200 BDL 554 1,794 09/16/05 1,300 62 570 BDL BDL BDL BDL BDL BDL 1,932 4I0 BDL BDL BDL 69 170 BDL 659 2,591 081241D6 2,200 84 770 15 BDL 6.4 1.2 1.„ 55 3.083 660 4.8 BDL 104 78 160 56 919 4.002 06/05/08 1,840 BDL $45 DDL BDL BDL BDL BDL BDL 2,185 210 BDL BDL BDL 351 140 BDL 405 2.790 09/04/08 1,430 51.7 349 BDL BDL BDL BDL BDL BDL 1.831 253 BDL BDL BDL BDL 603 BDL 313 2,144 M-W-25 03/11/98 8,9 3.5 BDL BDL BDL BDL BDL BDL BDL 12 BDL BDL BDL. BDL BDL BDL BDL 0 12 0512a'99 10 3.6 BDL BDL BDL BDL BDL BDL BDL 14 BDL BDL BDL 3DL BDL BDL BDL 0 14 06/34/04 &1 3.5 9.9 BDL BDL BDL BDL BDL BDL 22 BDL BDL BDL BDL BDL 44 BDL 4 26 08/16/05 17 3.9 31 BDL BDL BDL BDL BDL BDL 52 BDL BDL BDL BDL 3.6 BDL 3DL 4 56 081251D6 20 4.8 51 BDL BDL BDL BDL BDL BDL 76 BDL BDL BDL BDL 1.8 43 BDL 6 82 0"5108 11.7 3.2 235 BDL BDL BDL BDL BDL BDL 38 BDL BDL 13 BDL 22 4.2 BDL 8 46 ❑ ,104108 19.7 5.2 33 2 BDL BDL BDL BDL BDL BDL 57 BDL BDL BDL BDL 3 4.8 BDL 8 65 MW--26 4bandokled0P03106 07/01/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL D BDL BDL BDL BDL BDL BDL. BDL 0 0 08/15/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 NIW-27 10110102 BDL BDL BDL 82L BDL BDL BDL BDL BDL 0 23 2 47 18 23 BDL BDL 72 72 07/01/04 BDL BDL BDL BDL BAL BDL BDL BDL BDL 0 5.4 27 34 7.9 11 BDL 17 78 78 0SI16/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 12 4 ! ISO 34 3 5 BDL 30 264 264 11/01/06 BDL BDL BDL 3DL BDL BDI, BDL BDL BDL 0 6.2 24 38 3.1 BDL BDL 16 66 66 Notes: All units meastmd in }iWL BDL - Below Detection Limits NCGS 2L Sid. - Noah Carolitw Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MT BE - Methyl-tert butyl ether TRIGON I KLUNFELAEF, INC. Page 3 of 4 Ms. Beth Money, Gtsbarca 7300 West Friendly Avenue, Greensboro. North Carolina 'CABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS September 26, 2008 Trigon I Kleinfrlder Project No. 042-08.018 Sample ID Chlorinated Hydrocarbons Petroleum HydrKarbow Collection Date Truachloroethetu Trictilaroethrne cis l,2-Dichloroethrne 1,1-Dichloroethene 4'inylChloridr l,l-Dichlmoerhene 1-DichloroeOtane trans-1,2- Dichloroethaar I, I, 1•Trichloroethane Total Chim rina ted Hydraptrbona Brume Toluene Ethylbenzette Total7iyleoes [rfTBE Diisaprapylesher Naphthalene Hydrocarbons Total Petroleum Totalr'ilCr NCGS 2L Std. 0.7 2.8 70 7 0.015 70 0.38 l0D 200 -- 1 1.000 550 530 1 2DO 70 21 MW-28 IO110M2 Bpi. BDL BDL BDL BDL I BDL I BDL t BDL BDL 0 to 2.2 45 22.5 BDL 2.3 BDL 82 82 07/01/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 95 51 1 SW 1,065 BDL BDL 490 3,191 3,191 081t5105 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 210 78 2,3W 750 BDL BDL 740 4,078 4.078 0"i% BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 170 56 2,500 1,200 BIIL BDL SO0 4,726 4,726 12IL4106 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 100 BDL 2,500 530 BDL BDL 940 4,070 4.070 MW-29 01/01/04 23 BDL 280 BDL 813L BDL BDL BDL BDL 303 BDL 8DL 21 BDL BDL BDL BDL 21 324 OIVI5105 39 4.2 29 BDL BDL BAL BDL BDL BDL 72 BDI. BDL BDL BDL BDL BDL BDL 0 72 0&25M6 5 2.2 38 BDL BDL BDL BDL BDL BDL 45 BDL BDL BDL BDL BDL BDL BDL 0 45 MW-30 07/01/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL 2,200 BDL BDL 2,2OD 2.200 MIME BDL BDL 200 43 77 SAL BDL BDL BDL 320 74 SAL 58 BDL SID BDL BDL 642 962 08/25/06 BDL BDL 23 2.3 16 BDL BDL BDL BDL 42 U 23 1$DL 2.6 2 1 1,500 1 13 1 BDL JL 1,541 J 1.582 MW-3t MUM BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL 1 320 2,600 1 7,9t10 BDL BDL BDL- 10.820 10,820 0412n3 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL 310 t,800 4,6W BDL BDL BDL 6,710 6,710 07/01/04 BDL BDL 53 BDL BDL BDL BDL BDL BDL 53 18 94 590 1,3" BDL BDL 400 2452 2,505 OW15105 BDL BDL 48 BDL BDL BDL BDL BDL BDL 48 BDL 67 1,100 I'm BDL BDL 750 3,407 3,455 11/01/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL 1,700 Wo BDL BDL 720 2,810 2.810 MW-32 07/01/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL 29O BDL BDL 790 290 08/15/05 BDL BDL BDL B➢L BDL BDL BDL I BDL I BDL 0 BDL F BDL BDL I BDL I ISO I BDL I SAL 180 ISO 081251% BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 1,4W 280 190 600 I 15,000 32 160 17,662 17,66: 11/01/06 BDL BDL BDL BDL BDL BAL BAL BDI. BDL 0 1,400 320 340 900 MOW BDL BDL 22.960 22.%0 121t4106 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 1,5W 3,700 1,700 Blom 16,0110 BDL 1,1W 32,000 32.000 .MW-33 1W10102 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06/30/04 BDL BDL 1.6 BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 08/15/05 SQL BDL 5.6 BDL BDL BDL 8DL SAL BDL 6 BDL BDL_ BDL BDL BDL BDL SAL 0 6 08/25/06 BDL BDL 5.7 BDL BDL BDL BDL $DL 8DL 6 BDL BDL BbL BDL BDL BDL BDL 0 6 4iW-34 04127JO3 BDL 100 8DL 15 BDL 72 BDL BDL BDL 122 BDL BDL BDL BDL BDL BDL BDL 0 122 07/01/04 BDL 130 63 6.3 BDL 7.4 BDL SAL BDL 207 SDi, BDI, BDL BDL BDL BDL BDL 0 207 08/16/05 BDL 9O 37 BDL BDL BDL BDL $DL BDL 127 8DL BDL BDL BDL BDL BDL BDL 0 127 081/5/06 BDL 59 24 4.8 BDL 2.3 BDL SAL BDL 90 BDL BDL BDL BDL BDL BDL BDL 0 90 uw-40 IIMUM BDL BDL BDL BDL BDL BDL BDL SAL BDL 0 250 230 280 552 BDL BDL 130 1,442 11 1,442 MW-41 04/22/03 BDL BDL BDL BDL BDL BDL BDL BDL I BDL 11 0 11 7.100 J 6,600 1 2,400 1 10,900 1 BDL I BDL I BDL 11 27.000 27,ODO 07/08/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 7,OD9 6,600 2,600 13,309 BDL 520 770 30,790 30,790 09/15/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 5,40D 4,900 2,500 9,700 BDL 230 780 23,310 23,510 OM106 BDL BDL BDL BDL BDL BDL BDL B➢L BDL0 3,100 3,WO I,000 2900 BDL 6.4 16 10.022 10,072 MW-42 01/10/06 36.0 BAL 7.5 6.1 BDL 1.6 BDL BDL BDL 51 BDL BDL BDL BDL BDL BDL 3.2 3 54 W8125106 27.0 BDL 4.7 3.5 BDL L5 BDL BDL BDL 37 BDL BDL BDL BDL BDL BDL BDL 0 37 OW05108 53 BDL BDL BDL BDL BDL BDL BDL BDL 5 BDL BDL BDL BDL BDL BDL BDL 0 5 09/04/08 5.7 BDL. 8DL BDL BDL BDL BDL BDL BDL 6 fl BDL J BDL J BDL BDL BDL BDL BDL 0 6 MW-4311 01110106 3" 12.0 110 42.0 8DL 6.8 BDL BDL BDL 561 11 4,8 1 BDL BDL BDL 36.0 68.0 BDL 109 670 MW-l4 0411 J107 BDL 2.1 BDL BDL BDL BDL BDL BDL IBDL 2 BDL t BDL I BDL BDL J BD1. I BDL BDL 0 2 MW-43 09/13/07 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 OW05108 1.2 BDL BDL BDL BDL BDL BDL BDL BDL 1 BbL BDL BDL BDL BDL BDL BDL 0 1 OW05109 1.2 BDL BDL BDL BDL BDL BDL BDL BDL 1 BDL BDL BDL BDL BDL BDL BDL 0 1 MUM BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BAL BDL BDL BDL BDL BDL BDL 0 0 Notes: All units measured in pgIL BDL - Below Detection Limits NCGS 2L Std. - North Carolina Groundwater Standard BOLD - Coaeantratiaa exceeds the 2L Groundwater Quality Standard MTBE - Melltyl-tort butyl ether TR1GOW I KLEINFELDER- L\C. Page 4 of 4 Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 5: ESTIMATED DISSOLVED HYDROGEN CONCENTRATIONS AT INJECTION WELLS September 26, 2008 Trigon t Kieinfelder Project No. 042-08-018 Well 1D Total Depth (feet TUC) TOC Elevation (feet) Bottom Elevation (feet} Date Water Level Checked Static Water Level (feet TUC) Groundwater Elevation (feet] Depth of Water (feet) Estimated Dissolved Hydrogen Concentration (ppm) M W-7 29.9 861.19 831.29 9/4/2008 7.47 853.72 22.43 2.7 M W-10 33.6 860.36 826.76 9/4/2008 9.78 850.58 23.82 2.7 MW-14D 41.0 859.26 818.26 9/4/2008 22.80 836.46 18.20 2,5 MW-15 25.2 857.71 832.51 9/4/2008 15.79 841.92 9.41 2.0 M W-16 35.2 863.60 828.40 9/4/2008 30.64 832.96 4.56 1.8 MW-23D 57.1 860.90 803.80 9/4/2008 17.60 843.30 39.50 3.5 MW-24 58.8 858.81 800.01 9/4/2008 23.63 835.18 35.17 3.3 MW-29 18.8 861.13 842.33 9/4/2008 5.22 855.91 13.58 2.2 MW-34 21.0 860.45 839.45 9/4/2008 15.30 845.15 5.70 1.9 MW-43D 53.0 865.47 812.47 9/4/2008 32.71 832.76 20.29 2.6 Notes: feet TOC = feet below top of well casing ppm = parts per million Hydrogen concentrations are estimated based on a saturated hydrogen content of 1.6 ppm per atmosphere. TRIGON I KLEINFELDEP, INC. Page I of l Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 6: ESTIMATED HYDROGEN CONSUMPTION September 26, 2008 Trigan I Klcinfcldcr Project No. 042-08-018 Injection Well I❑ Date Hydrogen Cylinder Installed Original Cylinder Pressure (psi) Date Water Level and Cylinder Pressure Recorded Cylinder Pressure on 09104108 Estimated Volume of Hydrogen Remaining (cubic feet} Days Elapsed Since Cylinder Installation Hydrogen Use per Day - Since Installation (psi/day) Estimated Date Cylinder Must be Changed Based on Pressure MW-7 8/8/2008 2,000 09/04/08 1,200 115 27 29.6 10/11/2008 M W-10 9/4/2008 2,100 09/04/08 2,100 191 0 68.5 10/3/2008 MW-14D 9/4/2008 2,000 09/04/08 2,000 191 0 25.9 11/16/2008 MW-15 8/8/2008 2,100 09/04/08 1,300 118 27 29.6 10/14/2008 MW-16 8/8/2008 2,100 09/04/08 450 41 27 61.1 Flooded M W-23 D 6/ 13/2008 2,050 09/04/08 600 56 83 4.8 12/16/2008 M W-24 9/4/2008 2,100 09/04/08 2,100 191 0 18.5 12/21 /2008 M W-29 8/8/2008 2,100 09/04/08 0 0 27 77.8 Flooded M W-34 6/ 13/2008 2,050 09/04/08 450 42 83 7.2 10/22/2008 MW-43D 9/4/2008 2,050 09/04/08 2,050 191 0 25.9 11/18/2008 Notes: psi = pounds per square inch All hydrogen cylinders must be replaced prior to the cylinder pressure failing below 50 psi. TRIGON R MINFELDER, INC. Page 1 of I Ms. Beth Money, Gilbmco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 5: ESTIMATED DISSOLVED HVDROCEN CONCENTRATIONS AT INJECTION WELLS September 26, 2008 Trigon i Klein felder Pralect No. 042-08-018 Well I D Total Depth (feet TOC) TOC Elevation (feet) Bottom Elevation [feet} Date Water Level Checked Static Water Level (feet TUC} Groundwater Elevation (feet} Depth of Water (feet) Estimated Dissolved Hydrogen Concentration (ppm) M W-7 29.9 861.19 831.29 9/4/2009 7.47 853.72 22.43 2.7 M W-10 33.6 860.36 826.76 9/4/2008 9.78 850.58 23.82 2.7 M W-14D 41.0 859.26 818.26 9/4/2008 22.80 836.46 18.20 2.5 MW-15 25.2 857.71 832.51 9/4/2008 15.79 841.92 9.41 10 MW-16 35.2 863.60 828.40 9/4/2008 30.64 832.96 4.56 1.8 MW-23❑ 57.1 860.90 803.80 9/4/2008 17.60 843.30 39.50 3.5 MW-24 58.8 858.81 800.01 9/4/2008 23.63 835.18 35.17 3.3 M W-29 18.8 861.13 842.33 9/4/2008 5.22 855.91 13.58 2.2 MW-34 21.0 860.45 839.45 9/4/2008 15.30 845.15 5.70 1.9 MW-43❑ 53.0 865.47 812.47 9/4/2008 32.71 832.76 20.29 2.6 Notes: feet TOC = feet below top of well casing ppm = parts per million Hydrogen concentrations are estimated based on a saturated hydrogen content of I.6 ppm per atmosphere. TRIMN I KIXINFELDER, INC. Page I of I Ms_ Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 6: ESTIMATED HYDROGEN CONSUMPTION September 26, 2008 Trigan I Kleinfelder Project No_ 042-08-018 Injection Well ID Date Hydrogen Cylinder Installed Original Cylinder Pressure (psi) Date Water Level and Cylinder Pressure Recorded Cylinder Pressure on 09104108 Estimated Volume of Hydrogen Remaining (cubic feet) Days Elapsed Since Cylinder Installation Hydrogen Use per Day -Since Installation (psi/day) Estimated Date Cylinder Must he Changed Based ❑n Pressure MW-7 8/8/2008 2,000 09/04/08 1,200 115 27 29.6 10/11/2008 M W-10 914/2008 2,100 09/04/08 2,100 191 0 68.5 101312008 MW-14D 9/4/2008 2,000 09/04/08 2,000 191 0 25.9 11/16/2008 M W-15 8/8/2008 2,100 09/04/08 1,300 118 27 29.6 10/ 14/2008 M W-16 8/8/2008 2,100 09/04/08 450 41 27 61.1 Flooded MW-23D 6/13/2008 2,050 09/04/08 600 56 83 4.8 12/16/2008 MW-24 9/4/2008 2,100 09/04/08 2100 191 0 18.5 12/21/2008 MW-29 8/8/2008 2,100 09/04/08 0 0 27 77.8 Flooded MW-34 6/13/2008 2,050 09/04/08 450 42 83 7.2 10/22/2008 MW-43D 9/4/2008 2,050 09/04/08 2,050 191 0 25.9 11/18/2008 Notes: psi = pounds per square inch All hydrogen cylinders must be replaced prior to the cylinder pressure falling, below 50 psi. TRIGON I KLEINFELDER, INC. Page 1 of 1 I a . 0 I r _Ip)Ch"� 7), 411 A J 141) t 1. _n q 9 oil 40' 4%1p tip 9 �01 \J 0 L IV ><­'7��ti PersJmmqn Gi .900 Ch X & �7 rj BM FIGURE I SITE LOCATION MAP Gilbarco 7300 West Friendly Avenue TRIGON, Greensboro, North Carolina DATE: 6.13-2008 1 SCALE I'-2.000' GREENSBORO, NORTH CAROLINA SOURCE: 1951 (PROTORMSEV 1994) USON TOPOGRAPHIC MAP, GUILFORD QUADRANGLE PROJECT NO: 042-08-018 NSW-45 i111.1r� NIkl-43i1 MW-4Z MW-12S) . W-12 MW-14 -2S llll-14D ATE TATIO TANI{ MW 41 ill►.�ii i4W-13D MW40 Q� 3 RW-2 RW-3❑ NiV4-11 �NnV-13 NM-23D MW-34 A 1 Il _ MW-31 � MW-28 R W MW-32 MW 33 MW-27 MW-30 MW-44 EXISTING PARKING EXISTING PARKING LEGEND EXISTING BUILDING IMV-7 INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION FIGURE 2 RW-3 ❑ RECOVERY WELL LOCATION 17AT SITE PLAN Gilbarco 7300 West Friendly Avenue TRIGDN Greensboro, North Carolina DATE: 1-2-20GS SCALE.: V - 100' - GREENSBORO, NORTH CAROLINA DRAWN BY. CWH PROJECT NO: 042-08.019 EXISTING PARKING i MW-45 831.85 '!$, 835 16 832.96 t86 3.2.7MW-42 833.11 MW-12D 839.77 941,92 811) MW-14 835.18 840.25 835 w 944 )1►� -3 4 845.15 8i0 f LEGEND fj m .-7 INJECTION WELL LOCATION 8".72 AND GROUNDWATER ELEVATION MW-14 MONITORING WELL LOCATION 837•I5 AND GROUNDWATER ELEVATION ❑ RW-3 RECOVERY WELL LOCATION 84� GROUNDWATER CONTOUR LINE NOTE: GROUNDWATER ELEVATIONS WERE RECORDED SEPTEMBER 4, 2008. MONITORING WELLS MW-13D AND MW-23D ARE SCREENED BELOW THE WATER TABLE AND WERE NOT USED TO GENERATE THE GROUNDWATER CONTOURS, 855 EXISTING BUDDING $48.03 SUS ]Ili'-10 NW-13 850.58 4 844.4 V1'-3 MW-11 1 mv►'-T � 843.31 853.72 %M.29 843.30 ]IVS'-30 845.50 NM-44 M 33, W 845.56 850 8--95 EXISTING PARKING EXISTING PARKING LEGEND fir !ln INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION 50 WITH TOTAL VOCs CONCENTRATION (ug/L) 0 RNV-3 RECOVERY WELL LOCATION 1.1100—/_\ TOTAL vacs ISOCONCENTRATION LINE NOTE: SAMPLES COL.LECrED ON SEPTEMBER 4, 2005. MW-45 0 AV ,INV.43 MW-42 1111.�a 1M.16 jww 2I44 !1H -15 MW-12D 50 11l1 _ I40 65 MW-12 -41 1!'-1 DU[3 3� RW-3 36 MW-13 MW 40 MW-11 6$ !i!1' 0 3,152 ) I!► -23D RW-2 fl 25 L !n► -34 -31MW-x8 EXISTING BUILDING MW-30 MW-44 NORTH EXISTING PARIUNG FIGURE 4 TOTAL VOCs CONCENTRATIONS SEPTEMBER 4 2008 Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina DATE: 9.25.2009 SCALE: I'- 100' DRAWN BY: CWH PROJECTNO 042-OMIS �MWdS Q I -a D AOI NM-42 6 Ni 1; Mw-12D MW-14 1' 1 KW-12 5D MW-25 SUB �57 ATIO �1��-iafl -\ ATE TANK 1VFW-4I is �i11'-U3 MFV-13 !4iW-13 �LI 000 RW-3 68 -40 MW-11 RW-2 0 TNI523D 5 1 190 r %IN -34 Nf" �SVS'-28 RW-4 MW-3I ❑ � MW_33� MW�2 L MW-27 KW-30 MWW 44 EXISTING PARKING EXISTING LEGEND EXISTING PARKING BUILDING INJECTION WELL LOCATION 'NW-14 MONITORING WELL LOCATION s0 WITH TOTAL CHLORINATED HYDROCARBONS CONCENTRATION (ug/L) ❑ RW-3 RECOVERY WELL LOCATION FIGURE S 4,11111l�\ TOTAL CHLORINATED HYDROCARBONS ISOCONCENTRATION LINE TOTAL CHLORINATED HYDROCARBONS 1C SEPTEMBER 4 2008 Gilbarco NOTE. SAMPLES COLLECTED ON SEPTEMBER 4, 200s.77300 West Friendly Avenue 11TR1 Greensboro, North Carolina m.t BATE: 9.17.2008 5CAL.E 1' R IW GREENSBORO, NORTH CAROLINA DRAWN BY- CWH FRD7sCTNO: 042-08.018 APPENDIX A aceAnalytrcal r WWWpacalaba.= r September 16, 2008 Ms. Gail Licayan Trigon/Kleinfelder, Inc. 313 Gallimore dairy Rd Greensboro, NC 27409 RE: Project: G I LBARCO 042-08-018 3264 Pace Project No.: 9227199 Pace Analytical Services, Inc. 2225 Riverside Or. Asheville, NC 26804 (826)264-7176 Pace Analytical Services. Inc. 9800 Kincey Ave. Suite 100 kuntersville. NC 28078 Dear Ms. Licayan: Enclosed are the analytical results for sample(s) received by the laboratory on September 05, 2008. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Bonnie McKee bonnie.mckee@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. wittlout the written consent of Pace Analytical Services. Inc,. (704)875-9092 Page 1 of 19 r. .1)'VaceAnalytical Jwww.�acelabs.com I Project: GILBARCO 042-08-018 3264 Pace Project No.: 9227199 Pace Analytical Services. Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 CERTIFICATIONS Pace Analytical Services, Inc. 98DO Kinney Ave. Suite 100 Huntersville, NC 28078 Charlotte Certlflcatlon Ills Connecticut Certification Number PH-0104 North Carolina Field Services Certification Number. 5342 Pennsylvania Certification Number- 68-00784 North Carolina Wastewater Certification Number: 12 West Virginia Certification Number, 357 North Carolina prinking Water Certification Number: 37706 Virginia Certification Number: 00213 Louisiana/LELAP Certification Number: 04034 Tennessee Certification Number: 04010 Kentucky UST Certification Number: 84 South Carolina prinking Water CerL Number: 990060003 New Jersey Certification Number, NCO12 South Carolina Certification Number. 990060001 Flodda/NELAP Certification Number E87627 (704)875.9092 Asheville Certification JDs Connecticut Certification Number: PH-0106 Pennsylvania Certification Number: 68-03578 Massachusetts Certification Number: M•NC030 North Carolina 9loassay Certification Number: 9 West Virginia Certification Number: 356 North Carotina Wastewater Certification Number: 40 Virginia Certification Number: 00072 North Carolina Ofting Water Certification Number: 37712 Tennessee Certification Number: 2980 New Jersey Certification Number: NCO11 South Carolina Bioassay Certification Number: 99030002 Louisiana/LELAP Certification Number 03095 South Carolina Certification Number: 99030001 Flohda/NELAP Certification Number: E87648 Eden Certification IDs Virginia Drinking Water Certification Number: 00424 North Carolina Drinking Water Certification Number: 37738 North Carolina Wastewater Certification Number: 633 REPORT OF LABORATORY ANALYSIS This report rhatl not be reproduced, except in full, without the written consent of pace An aIyticai Services, Inc.. nel Page 2 of 19 ,2 aceAnalytical .. wwwpacelabs.com i� i Project GILBARCO 042-0B-018 3264 Pace Project No.: 9227199 Lab Id Sample ID 9227199001 MW-7 9227199002 MW-11 9227199003 MW-13 9227199004 MW-13D 9227199005 MW14 9227199006 MW-23❑ 9227199007 MW-24 9227199008 MW-25 9227199009 MW-42 9227199010 MW-45 Pare Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 28804 [828]254.7176 SAMPLE SUMMARY Matrix Date Collected Date Received Water 0910410616:06 0910510813.14 Water 0910410811:37 09/051081314 Water 0 9104/0 8 11 :04 0910510813:14 Water 0910410811:35 09/0510813:14 Water 0910410813:30 09/05/0813:14 Water 09104/0811:14 09105/0813:14 Water 0910410816:37 091051081314 Water 091041081417 09105/0813:14 Water 0910410814:50 09105/0813:14 Water 0910410614:56 09105/0813:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written can sent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvwlle, NC 28078 [704]875-9092 Page 3 of 19 x ace Analytical ww•,v.pacelat7s.cnm i Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Sutie 100 Huntersville, NC 28076 (704)875-9092 Project: GILBARCO 042-08-018 3264 Pace Project No.. 9227199 Analytes Lab ID Sample ID Method Analysts Reported 9227199001 MW-7 EPA6011602 PPM 40 9227199002 MW-11 EPA 6011602 PPM 40 9227199003 MW-13 EPA6011602 PPM 40 9227199004 MW-13❑ EPA6011602 PPM 40 9227199005 MW-14 EPA6011602 PPM 40 9227199006 MW-23D EPA 6011602 PPM 40 9227199007 MW-24 EPA6011602 PPM 40 9227199008 MW-25 EPA601/602 PPM 40 9227199009 MW-42 EPA6011602 PPM 40 9227199010 MW-45 EPA601/502 PPM 40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written can sent of Pace Analytical Services, Inc.. Page 4 of 19 e laceAnalytical w^pecefebs.= Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pats Ana lyticaI Sanricoo. Inc. 9800 Kincey Ave. Suite 100 Huntersville. NO 28075 (704)875-9092 Project: GILBARCO 042-08-018 3264 Pace Project No.. 9227199 Sample: MW7 Lab Ill: 9227199001 Collected: 09/04/06 16:06 Received: 09105/08 13:14 Matrix: Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS Na, Qual 6011602 Volatlles Analytical Method: EPA 6011602 Benzene ND uglL 50.0 50.0 50 09112/08 15:24 71-43-2 Bromodichloromethane ND uglL 50.0 50.0 50 09/12/08 15:23 75-27-4 Bromoform N❑ uglL 50.0 50.0 50 09112/08 15:23 75-25-2 Bromomethane ND uglL 50.0 50.0 50 09/12/08 15:23 74-83-9 Carbon tetrachloride NO uglL 50.0 50.0 50 09/12/08 15:23 55-23-5 Chlorobenzene NO uglL 50,0 50.0 50 09112/0815:23 108-90-7 Chloroethane NO uglL 50.0 50,0 50 09112/0815:23 75-00-3 Chloroform NO uglL 50.0 50.0 50 0911210815:23 67-66-3 Chloromethane NO qg L 100 100 50 09/12108 15,23 74-87-3 ❑ibromachloromethane NO uglL 50.0 50.0 50 09/12/0816 23 124-48-1 1,2-Dibromoethane (EDB) ND ug)L %0 50.0 50 09112/08 15:23 106-93-4 1,2-Dichlerobenzene NO uglL 50.0 50.0 50 09/12/08 15,23 95-50-1 1,3-Dichlorobenzene NO uglL 50X 50.0 50 09/12/08 15:23 541-73-1 1,4-Dichlorobenzene ND uglL 50,0 50,0 50 0911210815:23 106-46-7 Dichlorodiflucromethane ND ug1L 50.0 50.0 50 0911210815:23 75-71-8 1,1-❑lchloroethane ND uglL 50.0 50.0 50 09)1210815:23 75-34-3 1,2-Dlchloroethane NO uglL 50.0 50.0 50 OW1210815:23 107-06-2 1,1-❑ichiorcethene ND uglL 50.0 50,0 50 09112/0815:23 75-35-4 cis-1,2-Dichloreethene 1190 ug1L 50.0 50,0 50 091121081523 156-59-2 trans-1,2-Di chicroethene NO uglL 50,0 50,0 50 09112/0815:23 156-50-5 1,2-Oichloropropane ND uglL 50,0 50.0 50 09/12/08 15:23 78-87-5 cis-1,3-Dichloropropene NO uglL 50.0 50.0 50 0911210815:23 10061-01-5 trans-1,3-Dichloropropene ND uglL 50.0 50.0 50 0911210815:23 10051-02-6 Diisopropyl ether ND uglL 50.0 50.0 50 09/12/08 15:24 108-20-3 Ethylbenzene 788 uglL 50.0 50.0 50 09/1210815:24 100-41-4 Methylene Chloride N❑ uglL 100 100 50 09/12/08 15:23 75-09-2 Methyl -tent -butyl ether N❑ ug1L 50.0 50.0 50 09/12108 15'24 1634-04-4 Naphthalene 301 uglL 100 100 50 091121081524 91-20-3 1,1,2,2-Tetrachloroethane ND ug1L 50.0 50,0 50 0911210815:23 79-34-5 Tetrachloroethene N❑ ug1L 50,0 50.0 50 09/12108 15:23 127-18-4 Toluene NO uglL 50.0 50,0 50 09/1210815:24 108-88-3 1,1,1-Trichloroethane NO uglL 50.0 50.0 50 09/12/0815:23 71-55-6 1,1,2-T6chloroethane NO uglL 50.0 50.0 50 09112/0815:23 79-00-5 Trichloroethene NO uglL 50.0 %0 50 09112/0815:23 79-01-6 Trichlorofluoromethane ND uglL 50.0 50.0 50 09/1210815:23 75-89-4 Vinyl chtoride ND uglL 50.0 50.0 50 09/12/08 15:23 75-01-4 Xylene (Total) 873 ug1L 100 100 50 09/12/08 15:24 1330-20-7 m&p-Xylene 873 ug1L 100 100 50 09112/08 1524 1330-20-7 o-Xylene N❑ uglL 50.0 50.0 50 0911210815:24 95-47-6 1-Chloro-3-fluorobenzene (5) 105 % 55-137 50 09/12/08 15:23 625-98-9 Date: 09/1612008 01:09 PM REPORT OF LABORATORY ANALYSIS Page 5 of 19 This report sha11 not he reproduced, except In full, without the written consent of Pars Analytical Services, Inc.. aceAnalytiical"' wwwp800MUMM I Project: GILBARCO 042-08-018 3264 Pace Project No.: 9227199 Pace Analytical Services, Inc. 2226 Riverside Dr. Asheville, NC 28804 (828)254-7178 ►cLf1,'��LFI�I�.���11t�? PaceAna lyticai Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 20078 (704)875-9092 Sample: MW-11 Lab lO: 9227199002 Collected: 09104/0811:37 Received: 0910510813:14 Matrix: Water Report Parameters Results Units Limit MOL OF Prepared Analyzed CAS No. Oual 6011602 Volatlles Benzene 6romodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chbroform Chioromethane D ibro much loromethan e 1,2-Dibromoethane (EOB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Di ch lorodiflu o ro metha n e 1,1-Dichloroethene 1,2•Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1.2-Dichloroethene 12-Dichloropropene cis-1,3-Dichloropropene trans- l,3-Dichloropropene Dilsopropyi ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1,1,2,2-Tetrachloroethane Tetra ch loroethene Toluene 1,1,1-Trichloroethene 1,1,2-Trichloroethene Triohloroethene Th ch Io rofl uo rome thane Vinyl chloride Xylene (Total) m&p-Xylene o-xylene 1-Chia ro-3-fluombenzene [S) Date: 09116/2008 01:09 PM Analytical Method: EPA 6011602 NO uglL 1.0 1.0 1 09/12/08 16:05 71.43.2 NO uglL 1.0 1.0 1 09/12/08 16:05 75-27-4 NO ug1L 1.0 1.0 1 0911210816:05 75-25-2 ND ug/L 1.0 1.0 1 09/12/08 1&05 74-83-9 ND uglL 1.0 1.0 1 0911210816:05 56-23-5 NO uglL 1.D 1.0 1 09112J0816:05 108-90-7 ND uglL 1.0 1.0 1 09112/0816,05 75-00-3 NO uglL 1.0 1.0 1 09/12/08 16:05 67-66-3 ND uglL 2.0 2.0 1 09112/08 16:05 74-87-3 ND ug1L 1.0 1.0 1 0911DOS 16:05 124-48-1 NO uglL 1.0 1.0 1 09/12/05 46:05 106-93-4 NO uglL 1.0 1.0 1 09/12/08 16:05 95-5D-1 NO uglL 1.0 1.0 1 09/12108 i6:05 541-73-1 NO uglL 1.0 1,0 1 0911210816:05 106-46-7 ND ug)L 1.0 1.0 1 09112/0816:05 75-71-8 NO uglL 1.0 1.0 1 09/12/08 16:05 75-34-3 ND uglL 1.0 1.0 1 09/1210816:05 107-06.2 NO uglL 1.0 1.0 1 0911210816:05 75-35-4 NO uglL 1.0 1.0 1 09/12/08 16:05 156-59-2 ND ug1L 1.0 1.D 1 09MV0816:05 156-6D-5 ND ug1L 1.0 1.0 1 091121D8 16:05 78-87-5 NO uglL 1.0 1.0 1 OW12/0816:05 10061-01-5 NO ug/L 1.0 1.0 1 09112/0816:05 1ID061-02-6 ND ug1L 1.0 1.0 1 09112J08 16:05 108-20-3 ND uglL 1.0 1.0 1 09/12/08 16:05 100-41-4 NO uglL 2.0 2.0 1 09112J08 16:05 75-09-2 N❑ ug1L 1.0 1.0 1 09MV0816:05 1634-04-4 NO ug1L 2.0 2.0 1 09/12/08 16:05 91.20.3 NO ugl>_ 1.0 1.0 1 0911210816:05 79-34-5 NO ug& 1.0 1.0 1 0911210816:05 127-18-4 NO uglL 1.0 1,0 1 09112/0816:05 108-88-3 NO ug)L 1.0 1.0 1 09112J08 18:05 71-55-6 ND uglL 1.0 1.0 1 09/12/08 16:05 79-00-5 ND uglL 1.0 1,0 1 09/12/08 16:05 79-01-6 N❑ ug1L 1.0 1.0 1 09/12108 16:05 75-69-4 NO ug1L 1.0 1.D 1 0911210816:05 75-01-4 NO uglL 2.0 2.0 1 09/12/08 1605 1330-20-7 NO ug1L 2.0 2.0 1 09112J08 16:05 1330-20-7 NO ug)L 1.0 1.0 1 09112/08 16:05 95-47-6 104 % 65-137 1 09/12/08 16:05 625-98-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6of19 aceAnalyfical www.pacslebs.mm Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 20804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kin may Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GILBARCD 042-08-018 3264 Pace Project No.: 9227199 Sample: MW-13 LabID-. 9227199003 Collected: 09/04108 11:04 Received: 09/05/08 13:14 Matrix; Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6 01 /602 volatiles Analytical Method: EPA 6011602 Benzene NO ug/L 5.0 5.0 5 0911210817:28 71-43-2 Bromodichforomethane ND ug/L 5.0 5.0 5 09112/0817:28 75-27-4 Bromoform NO ug)L 5.0 5.0 5 09/12/08 17:28 75-25-2 Bromomethane NO ugJL 5.0 5.0 5 09112/0817,28 74-83-9 Carbon tetrachloride NO ug1L 5.0 5.0 5 09/12/08 17:28 56.23.5 Chlorobenzene ND ugIL 5.0 5.0 5 09/12/08 17:28 108-90-7 Chlorcethane ND ug/L 5.0 5.0 5 09/12/08 17-28 75-00-3 Chloroform ND ug/L 5.0 5.0 5 0911=817:28 67-66-3 Chloromethane ND ug1L 10.0 10.0 5 09112/0817:28 74-87-3 ❑ibromochloromethane ND ug/L &0 5.0 5 09/12/08 17.28 12448-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 5.0 5 09/12108 17:28 106-93-4 1,2-0ioWorobenzene N❑ ug/L 5,0 5.0 5 09112/0817:28 95-50-1 1,3-Dichlorobenzene NO ug1L 5.0 5.0 5 09112/0817:28 541-73-1 1,4-Dichlorobenzene ND ugIL 5.0 5.0 5 09/12/08 17:28 106-46-7 Dichlorodlfluoromethane ND ugIL 5.0 5.0 5 09/1210817:28 75-71-8 1,1-Dichloroethane ND ug/L 5.0 5.0 5 0911210817:28 75-34-3 1,2-Dichloroethane ND ug/L 5.0 5.0 5 0911210817,28 107-08-2 1,1-Dichloroethene ND ug/L 5.0 5.0 5 09112/0817:28 75-35-4 cis-1,2-Dichloroethene 67.9 ugIL 5.0 5.0 5 0911210817:28 156-59-2 trans-1,2-Dichloroethene ND ug1L 5.0 5.0 5 09/12/08 17:28 156-60-5 1,2-Dichloropropane NO ugJL 5.0 5.0 5 09112/08 17:28 78-67-5 cis- 1,3-Dichloropropene ND ug/L 5.0 5.0 5 0911210817:28 10061-01-5 trans-1,3-Dichloropropene ND ugJL 5.0 5.0 5 09/1210817:28 10061-02-6 Diisopropyl ether ND ug/L 5,0 5.0 5 09/12/08 17:28 108-20-3 Ethylbenzene ND ug/L 5.0 5.0 5 0911210817:28 100-41-4 Methylene Chloride ND ug1L 10.0 10.0 5 09/12/08 17:20 75-09-2 Methyt-tert-butyl ether NO ug1L &0 5.0 5 09112/08 17:28 1634-04-4 Naphthalene ND uglt- 10.0 1 DA 5 09/12/08 17:28 91-20-3 1,1,2,2-Tetrachlorcethane NO ug/L 5.0 5.0 5 09112/091728 79-34-5 Tetrachloroethene NO ug/L 5.0 5,0 5 09/12/081728 127-18-4 Toluene ND ug/L 5.0 5,0 5 09/12108 17:28 108-88-3 1,1,1-Tdchloroethane ND ug/L 5.0 5,0 5 09/12/08 17:28 71-55-6 1,12-Trichloroethane ND ug/L 5.0 5.0 5 0911210817728 79-00-5 Trichlorcethene ND ug/L 5.0 5.0 5 09/12/08 17:28 79-01-6 Trichlorofluoromethane ND ug1L 5.0 5.0 5 0911210817-28 75-69-4 Vinyl chloride NO ug)L 5.0 5.0 5 09112J08 17:28 75-01-4 Xylene (Total) NO ug/L 10.0 10.0 5 09/12/08 17:28 1330-20-7 m&p-%ylene NO ugJL 10.0 10.0 5 09/1210817:28 1330-20-7 o-Xylene ND ugIL 5.0 5.0 5 09/12/08 17:28 95-47-6 1-Chloro-34uorobenzene (S) 95 % 65-137 5 09/12/08 17:28 625-98-9 Date: 09116t2008 01:09 PM REPORT OF LABORATORY ANALYSIS Page 7 of 19 This report shall not be reproduced. except in full, without the written consent of P.ace Analytical Services, Inc.. aceAnalylical't www.paoelaRccam Project: GILBARCC 042-08-018 3284 Pace AnatyticaI Sary Ices, Inc. 2225 Rlverslde Dr. Asheville. NC 28804 ANALYTICAL RESULTS (828)254-7178 Pace Analytical Services, Inc. 9800 Klncey Aye. Suite 100 Huntersville. NC 28078 Pace Project No.: 9227199 Sample: MW-13D Lab ID: 9227199DD4 Collected: 09/04/08 11:35 Recelved: 09/05/08 13:14 Matrix: Water Report (704)875-9092 Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6011602 Volatiles Analytical Method: EPA 601/602 Benzene ND uglL 1.0 1.0 1 09112JO8 18:09 71-43-2 Bromodichloromethane NO uglL 1.0 1.0 1 09MV0818:09 75-27-4 Bromoform NO uglL 1.0 1,0 1 09/1214818:09 75-25-2 Bromomethane ND uglL 1.0 1.0 1 09/12/08 18:09 74-83-9 Carbon tetrachloride ND ug1L 1.0 1.0 1 09/12/08 18:09 56-23-5 Chlorobenzene NO uglL 1.0 1.0 1 09/12/08 18:09 108-90.7 Chioroethane ND uglL 1.0 1.0 1 09/12/08 18:09 75-DD-3 Chloroform NO ug1L 1.0 1.0 1 09112I08 18:09 67-66-3 Chloromethane ND uglL 2.0 2.0 1 09112/0818,09 74-87-3 Dibromochloromethene NO uglL 1,0 1.0 1 09/12/0818:09 124-48-1 1,2-Dibromoethane (EDB) ND uglL 1.0 i.D 1 09/12/08 18:09 106-93-4 12-Dichlorobenzene NO uglL 1.0 1.0 1 0911210818:09 95-50-1 1,3-Dichlorobenzene NO uglL 1.0 1.0 1 0911210818:D9 541-73-1 1.4-Dichlorobenzene NO ug1L 1.0 1.0 1 09/12/0818:09 106-46-7 Dichlorodifluoromethane NO uglL 1.0 1.0 1 0911210818:09 75-71-8 1,1-Dichloroethene ND ug)L 1.0 1.0 1 09/12/0818:09 75-34-3 1,2-Dichloroethane ND uglL 1.0 9.0 1 0911210818:09 107-06-2 1,1-Dichloroethene NO ug1L 1.0 1.0 1 09/12/08 18:09 75-35-4 cis-1.2•Dichloroethene 15.2 uglL 1,0 1.0 1 0911?JO618:09 156-59-2 trans-1,2-Dichloroethene ND uglL 1A 1.0 1 0911210818:09 156-60-5 1,2-Dichloropropane NO uglL 1.0 1.0 1 09/1210818:09 78-87-5 cis- 1,3-❑ichloropropene NO ug1L 1.0 1.0 1 09/12/0818:09 10061-01-5 trans-1,3-Dichloropropene NO ug1L 1.D 1.0 1 09/1210818:09 10061-02-6 Dlisopropyl ether NO ug1L 1.0 1.0 1 09/12/08 18:09 108-2D-3 Ethylbenzene NO uglL 1.D 1.0 1 0911210816:09 100-41-4 Methylene Chloride ND uglL 2.0 2.0 1 09112I08 18:09 75-09-2 Methyl -tent -butyl ether 17.6 uglL 1.0 1.0 1 09/12/08 18:09 1634-04.4 Naphthalene ND ug1L 2.0 2.0 1 09MZ08 18:09 91-20-3 1,1,2,2-Tetrachloroe thane ND ug1L 1.0 1.0 1 09112/08 18:09 79-34-5 Tetrachloroethene ND uglL 1.0 1.0 1 09/12/08 18,09 127-18-4 Toluene N❑ uglL 1.0 1.0 1 09/12/08 18:09 108-88-3 1,1,1-Tirchloroethane NO uglL 1.0 1.0 1 0911210816:09 71-55.6 1,1,2-Trichloroethene ND uglL 1.0 1.D 1 0911210818:09 7MO-5 Tdchloroethene NO ug1L 1.D 1.0 1 09112/0818:09 79-01-6 Trich lorofl u oro methane NO uglL 1.D 1.0 1 09/12/08 18:09 75-69-4 Vinyl chloride 3.1 ug1L 1.D 1.0 1 09112/08 18:09 75-01-4 Xylene (Total) NO ug1L 2.0 2.0 1 09112/08 18:09 1330-20-7 m&p-Xylene NO ug1L 2.0 2.0 1 09/12/08 18:09 1330-20-7 o-Xylene ND uglL 1.0 1.0 1 09112/08 18:09 95.47-6 1-Chlora-3-fluorobenzene (S) 94 °% 65-137 1 09/12/08 18:09 625-98-9 Date: 09/16/2008 01:09 PM REPORT OF LABORATORY ANALYSIS Page 8 of 19 This report shall not be reprodured, except In full. without the written consent of Pace Analytical Services, Ino.. aceAnalytical www.pacelabs.com Pace Analytic* I Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace AnaWlcai Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GILBARCQ 042-08-018 3264 Pace Project No.: 9227199 Sample: MW-14 Lab ID: 9227199005 Collected: 09/04/08 l&30 Received: 09/05/08 13:14 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6011602 Volatlles Analytical Method: EPA 601J602 Benzene ND ugJL 1.0 1.0 1 091121081&51 71-43-2 Bromodichlaromethane N4 ug/t_ 1.0 1,0 1 09112/0818:50 75-27-4 Bromoform N❑ ugJL 1.0 1.0 1 09/12108 18:50 75-25-2 Bromemethane ND uglL 1.0 1,0 1 09/1210816:50 74-83-9 Carbon tetrachloride ND uglL 1.0 1.0 1 09/12/08 18:50 56-23-5 Chlorobenzene ND uglL 1,0 1.0 1 09112J08 18:50 108-90-7 Chloroethane ND uglL 1.0 1.0 1 09/12J08 18:50 75-00-3 Chloroform NO ug1L 1.0 1.0 1 09/12/08 18:50 67-66-3 Chloromethane ND uglL 2.0 2.0 1 09112/081&50 74-87-3 Dibromochloromethane ND uglL 1.0 1.0 1 09112/08 18:50 124-48-1 1,2-Dibramoethane (EDB) NO uglL 1.0 1.0 1 09/12/08 18:50 106-93-4 1,2-Dichlorobenzene NO ugJL 1.0 1.0 1 0911210818:50 95-50-1 13-Dichlorobenzene NO uglL 1.0 1.0 1 0911210818:50 541-73-1 1,4-Dichlorobenzene NO ugJL 1.D 1.0 1 09J1210818:50 106-46-7 Dichlorodifluoromethane NO ugJL 1.0 1.0 1 09112/0818:50 75.71-8 1,1-Dichloroethene ND ugJL 1.0 1,0 1 09/12/08 18:50 75-34-3 1,2-Dichlaroethane NO uglL 1.0 1.0 1 09/12/08 18:50 107-0&2 1,1-Dichloroethene ND uglL 1.0 1.0 1 0911210B 1&50 75-35-4 cis- 1,2-Dichloroethene ND uglL 1.0 1.0 1 09/12/08 1&50 156-59-2 trans- l,2-Di chloroethene ND uglL 1.0 1.0 1 091121081&50 156-60-5 1,2-Dichloropropane NO uglL 1.0 1.0 1 09/1210818:50 78-87-5 cis-1,3-Dichloropropene ND ugJL 1.0 1.0 1 09/1210818:50 10061-01-5 trans-1,3-D!chi oropropene ND ugJL 1.0 1.0 1 09/1210818:50 10061-02-6 Diisopropyl ether NO uglL 1.0 1,0 1 09112J08 18:51 108-20-3 Ethylbenzene NO ugJL 1.0 1.0 1 09/1210818:51 1DD41-4 Methylene Chloride Nil ugJL 2.0 2.0 1 09/12/08 18:50 75-09-2 Methyl-tert-butyl ether NO uglL 1.0 1.0 1 09112JOB 18:51 1634-04-4 Naphthalene ND uglL 2.0 2.0 1 09112/0818:51 91-20-3 1.1,2,2-Tetrachleroethane ND uglL 1.0 1.0 1 09112/0818:50 79.34-5 Tetrachlorcethene 50.0 ugJL 1.0 1.0 1 09M210818:50 127-18-4 Toluene ND uglL 1.0 1.D 1 09112J0818:51 108-88-3 1,1,1-Trichloroethane ND ugJL 1.0 1.0 1 09/12J0818:50 71-55-6 111,2-Trichloroethane ND uglL 1.0 1.0 1 0911210818:50 79-00-5 Trichloroethene ND ugJL 1.0 1.0 1 09112J081&50 79-01-6 Tdchlorofl uo ro methane NO uglL 1 A 1.0 1 09/12/08 18:50 75-69-4 Vinyl chloride NO uglL 1.0 1.0 1 09112/08 1&50 75-01-4 Xylene (Total) ND uglL 2.0 2.0 1 09/12108 18:51 133D-20-7 m&p-Xylene ND uglL 2.0 2.0 1 09/12/0818:51 1330-20-7 o-Xylene NO uglL 1.0 1.0 1 09112/0818:51 95-47-6 1-Chloro-3-fluorobenzene (S) ill % 65-137 1 09/12108 18:50 625-98-9 Date: 09/16/2008 01:09 PM REPORT OF LABORATORY ANALYSIS Page 9 of 19 This report shall not be reproduced, except in full, without the written consent of Pace Anal ytlral Services, Inc.. aceAnalytical wwwPaDwabs.car+ t Project: GILBARCG 042-08-018 3264 Pace Project No.: 9227199 Pa ce An a lyticall Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Klncey Ave. Sulte 100 Huntersville, NC 28078 (704)875-9092 Sample: {YAW-23D Lab ID: 9227199006 Collected: 09/04/08 11:14 Received: 09/05/08 13:14 Matrix: Water Report Parameters Results Units Limit MOL OF Prepared Analyzed CAS No, Qua] 6011602 Volatiles Analytical Method: EPA 6011602 Benzene NO uglL 1.0 1.0 1 09/15/08 15:55 71-43-2 Bromodichloromethane NO ug& 1.D 1.0 1 0911510815:55 75-27-4 Bromoform NO uglL 1.0 1.0 1 0911510815:55 75-25-2 Bromomethane NO uglL 1.0 1.0 1 09115/08 15:55 74-83-9 Carbon tetrachloride NO uglL 1.0 1.D 1 09115/08 15:55 56-23-5 Chlorobenzene NO uglL 1.0 1.0 1 09115/08 15:55 108-90-7 Chlorcethane NO uglL 1.0 1.0 1 09/15/08 15:55 75-DO-3 Chloroform NO uglL 1.0 1.0 1 09/15/08 15:55 67-66-3 Chloromethane NO uglL 2.0 2.0 1 09/15108 15:55 74-87-3 Dibromochlorornethane NO uglL 1.0 1.0 1 09/15/08 15:55 124-48-1 1,2-Oibromoethane (EDB) NO uglL 1 A 1,0 1 09/15/08 15:55 106-93-4 1,2-Dichlorobenzene ND ug1L 1.0 1.0 1 09/15/08 15:55 95-50-1 1,3-Dichi orvbenzene NO uglL 1.0 1.0 1 0911510815:55 541-73-1 1,4-Dichlorobenzene NO ug1L 1.0 1.0 1 09115/01315:55 106-46-7 Diohlorodifluoromethane NO ug1L 1.0 1.0 1 09115/0815:55 75-71-8 1,1-Dichloroethene NO ug/L 1.0 1.0 1 0911510815:55 75-34-3 1,2-Dichloroethane NO ug1L 1.0 1.0 1 09/1510815:55 107-06-2 11-Dichloroethene NO ug1L 1.0 1.D 1 0911510815:55 75-35-4 cis-1,2-Dlchloroethene 5.3 uglL 1.0 1.0 1 0911510815:55 156-59-2 trans-1,2-Dichloroethene NO uglL 1.0 1.D 1 09115/0815:55 156-6D-5 1,2-Dichloropropene NO ug/L 1,0 1.0 1 0911510815:55 78-87-5 cis-1,3-Dichloropropene NO uglL 1,0 1.0 1 09115/0815:55 10061-01-5 trans-1.3-Dichioropropene ND uglL 1.0 1.0 1 G9115/08 15:55 10061-02-6 Oiisopropyl ether NO uglL 1.0 1.0 1 09/15/08 15'55 108-20-3 Ethylbenzene NO ug1L 1.0 1.0 1 0911510B 15:55 100-41-4 Methylene Chloride NO uglL 2.0 2,0 1 09115/08 15:55 75-09-2 Methyl -tent -butyl ether 19,3 uglL 1.0 1.0 1 OW15108 15:55 1634-04-4 Naphthalene NO uglL 2.0 2.0 1 09/1510815:55 91-20-3 1,1,22-Tetrachioroethane ND ug)L 1.0 1.0 1 09/15/08 15:55 79-34-5 Tetra ch loroethene N❑ uglL 1.D 1.0 1 09/15/08 15:55 127-18-4 Toluene ND uglL 1,0 1.0 1 09/15/08 15:55 108-88-3 1,1.1-Trichloroethana ND uglL 1,0 1.0 1 09/15/08 15:55 71-55-6 1,1,2-Trichioroethane N❑ uglL 1.0 1.0 1 09115/0815:55 79-00-5 Trichicroethene NO uglL 1.0 1.0 1 0911510815:55 79-01-6 Trichiarofluoromethane NO ug1L 1.0 1 A 1 09/15/08 15:65 75-69-4 Vinyl chloride NO ug1L 1.0 1.0 1 09/15/08 15:55 75-01-4 Xylene (Total) ND uglL 2.0 2.0 1 0911510815:55 1330-20-7 m&p-Xylene NO uglL 2.0 2.0 1 0911510815:55 1330-20-7 o-Xylene NO uglt 1.0 1.0 1 09/15108 15:55 95-47-6 1-Chloro-3-fluarobenzene (S) 93 % 65-137 1 D9115108 15:55 625-98-9 Date; 09116/2008 0 1:0 9 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, with aut the written onnsent of Pace Anal Services. Inc._ Page 10 of 19 aceAnalytical NM1vn!p8eallabs, earrn Pane Analytical Services, Ine. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntarsville. NC 28078 (704)875-9092 project: GILBARCO 042.08-018 3264 Pace Project No.: 9227199 Sample: MW-24 Lab Id: 9227199007 Collected: 09/04/08 16:37 Received: 09/05/08 13:14 Matrix: Water Report Parameters Results Units Limit MDL DP Prepared Analyzed CAS No. Qua[ 6011602 Volatiles Analytical Method: EPA601/602 Benzene 253 ugiL %0 50.0 50 09/12/08 20:14 71-43-2 Bromodichloromethane ND ugiL 50.0 %0 50 09/12/08 20:14 75-27-4 Bromoforrn ND ug1L 50.0 50.0 50 09/12108 20:14 75-25-2 Bromomethane ND ug1L 50.0 50.0 50 09/12/08 20:14 74-83-9 Carbon tetrachloride ND ugiL 50.0 50.0 50 09/12/08 2 0: 14 56-23-5 Chlorobenzene ND ug1L 50.0 50.0 50 09/12/08 20:14 108-90-7 Chloroethane ND ug1L 50.0 %0 50 09/12/08 20,14 75-00-3 Chloroform NO ug1L 50,0 50.0 50 09/12/08 20:14 67-68-3 Chloromethene ND ug1L 100 100 50 09/12/08 20:14 74-87-3 Dlbromochloromethane NO ugiL 50.0 50.0 50 09/12/08 20:14 124-48-1 1,2-Dibromoethane(EDB) N❑ ugiL 50.0 50.0 50 09/1210820:14 106-93-4 1,2-Dichlorobenzene ND ugiL 50.0 50.0 50 0911210820:14 95-50.1 13-Dichlorobenzene ND ugiL 5U 50.0 50 0911210820:14 541-73-1 1,4-❑ichlorobenzene N❑ ugiL 50.0 50.0 50 0911210820:14 106-46-7 Dichlorodifluoromethane ND ugiL 50A 50.0 50 09/12108 20:14 75-71-8 1,1-Dichloroethane ND ugiL 50.0 50.0 50 0911210820:14 75-34-3 1,2-Dichloroethane NO ugiL 50.0 SU 50 0911210820:14 107-06-2 1,1-Dlchloroethene ND ugiL 50.0 50.0 50 09/12@820:14 75-35.4 cis- 1.2-Dichleroethene 349 ugiL 50.0 50.0 50 09/12/08 20:14 156-59-2 trans-1,2-Dichloroethene ND ugiL 50.0 %0 50 0911210620:14 156-60-5 1,2-Dichloropropane ND ug1L 50.0 50.0 50 09MV08 20:14 78-87-5 cis-1,3-Dichlorapropene ND ug1L 50.0 50.0 50 09/12/08 20:14 10061-01-5 trans-1,3-Dichloropropene ND ug1L 50.0 50 0 50 09/12/08 20:14 10061-02-6 Dilsopropyi ether 60.3 ugiL 50.0 50.0 50 09/12/08 20:14 108-20-3 Ethylbenzene ND ug1L 50.0 50.0 50 09/12/08 20:14 1 OD-41.4 Methyiene Chloride N❑ ugiL 100 100 50 09/12/08 20:14 75-09-2 Methyl-tert-butyl ether NO ug1L 50.0 50.0 50 09/12/08 20:14 1634-04-4 Naphthalene NO ugiL 100 100 50 09/12/08 20:14 91-20-3 1.1,2,2-Tetrachloroethane NO ugiL 50.0 50,0 50 0911210820:14 79-34-5 Tetra ch loroeth ene 1430 ugiL 50.0 50.0 50 09/12/08 20:14 127-18-4 Toluene NO ugiL 50.0 50,0 50 09/12/08 20:14 108-6 -3 1,1,1-Trichloroethane NO ugiL 50.0 %0 50 D9112108 20:14 71-55-6 1,1,2-Trichloroethane NO ugiL 50.0 50.0 50 09/12/08 20:14 79-OD-5 Trichioroethene 51.7 ugiL 50.0 50.0 50 09/12/08 20:14 79-01-6 Trichlorofluoramethane ND ugiL 50.0 50.0 50 09/12/08 20:14 75-694 Vinyl chloride ND ugiL 50.0 50.0 50 09/12/08 20:14 75-01-4 Xylene (Total) N❑ ug1L 100 100 50 09/12/08 20:14 133D-20-7 m&p-Xylene N❑ ugiL 100 100 50 09/12/08 20:14 133D-20-7 o-Xylene N❑ ug1L 50.0 50.0 50 09112108 20:14 95-47-6 1-Chloro-3-fluorobenzene (S) 105 % 65-137 50 09/12/08 20:14 625-98-9 Date: 0911&2008 01,09 PM REPORT OF LABORATORY ANALYSIS Page 11 of 19 This re part shall not he reproduced, except in full, without the written consent of Pace An alytical Services, inc.. -inmG; aceAnalytical www.pacelebs.com Project: GiLBARCO 042-08-018 3264 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 ANALYTICAL RESULTS [828]264.7176 Pace Analytical 5arvice>s. Inc. 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 Pace Project No.: 9227199 Sample: MW-25 Lab ID: 9227199008 Collected: 09/04108 14:27 Received: 0910510E 13:14 Matrix, Water Report Parameters Results Llnlls Limit MDL OF Prepared Analyzed 6011602 Volatlles Analytical Method: EPA 6011602 (704)875-9092 CAS No. Qual Benzene ND uglL 1.0 1.0 1 09112/08 20:55 71-43-2 Bromodichloromethane ND uglL 1.0 1.0 1 09/12/08 20:55 75-27-4 Bromoform NO ug1L 1.0 1.0 1 09/12/08 20:55 75-25-2 Bromornethane NO uglL 1.0 1,0 1 09/12/0820:55 74-83-9 Carbon tetrachloride ND uglL 1.0 1.0 1 09/12/08 20:55 56-23-5 Chlorobenzene ND uglL 1.0 1.0 1 09112108 20:55 108.90-7 Chloroethane ND uglL 1.0 1.0 1 09/12/08 20:55 75-00-3 Chloroform ND uglL 1.0 1.0 1 09/12/08 20:55 67-66-3 Chloromethane ND ug1L 2.0 2.0 1 09112/08 20:55 74-87-3 Dibromochloromethane ND uglL 1.0 1.0 1 09/12/08 20:55 124-48-1 1,2-Dibromoethane (EDB) NO uglL 1.0 1.0 1 09/12/08 20:55 106-93-4 1,2-Dichlorobenzene NO uglL 1.0 1.0 1 09112/08 20:55 95-50-1 1,3-Dichlorobenzene NO uglL 1.0 1.0 1 09112/08 20:55 541-73-1 1,4-Oichtorobenzene ND uglL 1.0 1.0 1 091121D8 20:55 106-46-7 Dichlorodifluoromethane NO ug1L 1.D 1.0 1 09/12/08 20:55 75-71-8 1,1-Dichloroethane ND uglL 1.0 1.0 1 091121D820-55 75-34-3 1,2-Dichloroethane ND uglL 1.0 1.0 1 0911210820:55 107-06-2 1,1-Dichloroethene NO ugli. 1.0 1.0 1 0911210820:55 75-354 cis•1,2-DichIoroethene 33.2 uglL 1.0 1.0 1 09/12/08 20:55 156-59-2 trans- 1,2-D!chi oroethene ND uglL 1.0 1,0 1 09/12/08 20:55 155-60-5 1,2-Dichloropropane ND uglL 1.0 1.0 1 09/12/08 X 5 5 78-87-5 cis- 1,3-Dichloropropene ND ug1L 1.0 1.0 1 09/1210820:55 10061-01-5 trans-1,3-Dichloroprope ne ND ugli. 1.0 1.0 1 09112/08 20:55 10061-02-6 Dllsopropyl ether 4,8 ug1L 1.D 1.0 1 09/12/08 20:55 108-2D-3 Ethylbenzene NO uglL 1.0 1.0 1 09/12/08 20:55 100-41-4 Methylene Chloride NO uglL 2.0 2.0 1 09/12/08 20:55 75-09-2 Methyl -tent -butyl ether 3.0 uglL 1,0 1 A 1 09/12/08 20:55 1634-04-4 Naphthalene ND uglL 2.0 2.0 1 09/12/08 2D:55 91-20-3 1,12,2-Tetrachloroethane NO uglL 1,0 1.0 1 0911210820:55 79-34-5 Tetrachloroethene 18.7 uglL 1.0 1.0 1 09/12/08 20:55 127-18-4 Toluene ND ug1L 1 A 1,0 1 09f12108 20:55 108-88-3 1. 1, 1 -Tdchloroethane ND ug1L 1.0 1,0 1 09/12/0820:55 71-55-6 1, 1,2-Trich loroethane ND ug1L 1.0 1,0 1 0911210820:55 79-00-5 Thchleroethene 5.2 ug1L 1.0 1.0 i 09/12/08 20:55 79-01-6 Tdchlorofluoramethane NO uglL 1.0 1 A 1 09112/08 20:55 75-89-4 Vinyl chloride NO uglL 1.0 1.0 1 0911210820:55 75-01-4 Xylene (Total) NO uglL 2,0 2.0 1 09/12/08 20:55 1330-20-7 m&p-Xylene NO uglL 2.0 2.0 1 09/12/08 20:55 1330-20-7 o-Xylene ND uglL 1.0 1.0 1 09/12108 20:55 95-47-6 1-Chloro-3-fluorobanzene(S) 106 % 65-137 1 09112/0820:55 625-98-9 Date: 09/16120DO 01:09 PM REPORT OF LABORATORY ANALYSIS Page 12 of 19 This report shall not be reproduced, except in fu11. wlttsout the written consent of Pace Analytical Services, Inc. acMnalytical r wwwpsaslabs.enm Project: GILBARCO 042-08-018 3264 Pace Analytical Sorylces, Inc. 2225 Riverside Dr. Asheville, NC 28804 {828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc, 9800 KIncey Ave. Suite 100 Huntersville, NC 28078 Pace Project No.: 9227199 Sample: MW-42 Lab ID: 9227199009 Collected: 09104/08 14:50 Reoeived 09/05/08 13:14 Matrix: Water (704)875-9092 Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6011602 VolatiIas Analytical Method: EPA6011602 Benzene NO uglL 1.0 1.0 1 09/12/08 21:37 71-43-2 Bromodich loro methane NO u911- 1.0 1.0 1 09/12/08 21:36 75-27-4 Bromoform NO uglL 1.0 110 1 09/12/08 21:36 75-25-2 Bromomethane NO ug1L 1.0 1.0 1 09/12/08 21:36 74-83-9 Carbon tetrachloride NO ug)L 1.0 1.0 1 09112/08 21:36 56-23-5 Chlorobenzene NO ug& 1.0 1.0 1 09112108 21:36 108-91 -7 Chtoroethane NO uglL 1.0 1.0 1 09/12/08 21:36 75-00-3 Chloroform NO uglL 1.0 1.0 1 09/12/08 21:36 67-66-3 Chloromethane NO uglL 2.0 2.0 1 09/12/08 21:36 74-87-3 Dibromochloromethane NO uglL 1.0 1-0 1 09M2108 21:36 124-48-1 1,2-Dibromoethane (EDB) NO uglL 1.0 1.0 1 09/12/08 21:36 106-93-4 1,2-Dichlorobenzene NO uglL 1.0 1.0 1 0911210821:36 95-50-1 1,3-Dichlorobenzene NO ug1L 1.0 1.0 1 09112/0821-36 541-73-1 1,4-Dichic robenzene NO uglL 1.0 1.0 1 09112M821:36 106-4&7 Dichlorodifluoromethane NO uglL 1.0 1.0 1 0911V0821:36 7&71-8 1.1-Dichloroethane NO uglL 9.0 1.0 1 09112/06 21:36 75-34-3 1,2-Dichloroethane NO ug1L 1.D 1.0 1 09/12/08 21:36 107-06-2 1,1-Dichloraethene NO ug1L 1.0 1.0 1 09/12/08 21:36 75-35-4 cis-1,2-Dichloroethene NO uglL 1.0 1.0 1 0911210821:36 156-59-2 trans- l,2-Dichloroethene N❑ ug1L 1.0 1.0 1 09/12/08 21:36 156-60-5 1,2-Dichloropropane N❑ uglL 1.0 1.0 1 09/1210821:36 78-87-5 Cis- 1.3-Di chi oro pro pe ne ND uglL 1.0 1.0 1 09112/08 21:36 10061-01-5 trans-1,3-Dichlaropropene NO uglL 1.0 1.0 1 09112J0821,36 10061-02-6 ❑iisopropyl ether NO uglL 1.D 1.D 1 09/12/08 21-.37 108-20-3 Ethylbenzene NO uglL 1.0 1.0 1 09/12/08 21:37 100-41.4 Methylene Chloride NO uglL 2.0 2.0 1 09/12/00 21:35 75-09-2 Methyl-tert-butyl ether NO uglL 1.0 1.0 1 09/12108 21:37 1634-04.4 Naphthalene NO uglL 2.0 2.0 1 09/12108 21:37 91-20-3 1,1,2,2-Tetrachloroethane ND uglL 1.0 1.0 1 0911210821:36 79-34-5 Tetra ch loroethe ne 5.7 uglL 1.0 1.0 1 09/12/08 21:36 127-18.4 Toluene ND ug1L 1.0 1.0 1 09/12/08 21.37 108-88-3 1.1,1-Tdchlaroethane ND ug1L 1.0 1.0 1 09/12/08 21:36 71-55-6 1,12-Trichloroethane N❑ uglL 1.0 1.0 1 0911210821,36 79-00-5 Trichloroethene N❑ uglL 1.0 1.0 1 09/12/0821:36 79-01-6 Trichlorofluoromethane N❑ ug1L 1.0 1.0 1 09/12/08 21:36 75-69A Vinyl chloride NO uglL 1.0 1.0 1 09/12/08 21:36 75-01-4 Xylene (Total) NO uglL 2.0 2.0 1 09/12/08 21:37 1330-20-7 m&p Xylene NO uglL 2.0 2.0 1 09/12/08 21:37 1330-20-7 o-Xylene NO ug1L 1.D 1.0 1 09/12/08 21:37 95-47-6 1-Chloro-3-fluorobenzene (S) 107 % 65.137 1 09112f08 21:36 625.98-9 Date: 09/16/2006 01 09 PM REPORT OF LABORATORY ANALYSIS Page 13 of 19 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. T.n' 6 m aceAnaIXical www.paeelaba.vom Pace Analytical Services. Inc. 2225 Riverside Or. Asheville, NC 28804 (628)254-7175 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 }4ncey Ave. 5uRe 100 kuntersvllle, NC 20078 (704)875.9092 Project: GI1-BARC0 042-08-018 3264 Pace Project No.: 9227199 Sample: MW-45 Lab ID: 9227199010 Collected: 09/04/08 14:56 Received: 09/05/08 13:14 Matrix: Water Report Parameters Results Units Limit MOIL DF Prepared Analyzed CAS No. 4ual 6011602 Volatiles Analytical Method: EPA 6011502 Benzene ND uglL 1.0 1.0 1 09/12100 22:19 71-43-2 Bromodichloromethane ND uglL 1.0 1.0 1 09/12/08 22:18 75-27-4 Bromoform NO ugIL 1.0 1.0 1 09/12/08 22:18 75-25-2 Bromomethane NO ug1L 1.0 1.0 1 09112/08 22:18 74-83-9 Carbon tetrachloride NO ug1L 1.0 1.0 1 09/12/08 22:18 56-23-5 Chlorobenzene NO ug1L 1.0 1.0 1 09/12/08 22:18 108-90-7 Chlorcethane NO ug/L 1.0 1.0 1 09112108 22:18 75-00-3 Chloroform NO uglL 1.0 1,0 1 0911210822:18 67-66-3 Chloromethane NO uglL 2.0 2.0 1 09/12108 22:18 74-87-3 Dibromochloromethane ND ugIL 1.0 1.0 1 09/12/08 22:18 124-48-1 1,2-Dibromoethane(EDB) NO ug1L 1.0 1.0 1 0911210822:18 106-93-4 1,2-Dichlorobenzene NO ugIL 1.0 1.0 1 09/1210822-18 95-50-1 1,3-Dichlorobenzene Nil ugIL 1.0 1.0 1 0911210822:18 541-73-1 1,4-Dichlorobenzene NO ugIL 1.0 1.0 1 09/12/08 22:18 106-46-7 Dichlorodifluoromethane ND ug1L 1.0 1.0 1 09/12/08 22:18 75-71-8 11-Dichloroethane NO ug/L 1.0 1.0 1 09/12/08 22:18 75-34-3 1,2-Dichloroethane NO ug/L 1.0 1.0 1 09/12/08 22:18 107-DS-2 1,1-❑ichlorcethene NO ugIL 1.0 1,0 1 09/12/08 22:18 75-35-4 cis- 1,2-Dichloroethene NO uglL 1.0 1,0 1 0911210822AS 156-59-2 trans-1.2-Dichloroethene NO uglL 1.0 1.0 1 09/12/08 22,18 156-60-5 12-Dichloropropane NO uglL 1.0 1.0 1 09/12/08 22:18 78-87-5 cis- 1,3-Dichloropropene N❑ ug1L 1.0 1.0 1 0911210822:16 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 1.0 1 09112/08 22: 10 10061-02-6 Diisopropyl ether NO uglL 1.0 1.0 1 09/12/08 22:19 108-20-3 Ethylbenzene NO uglL 1.0 1.0 1 09112/08 22:19 100-41-4 Methylene Chloride NO ugIL 2.0 2.0 1 09/12/08 22:18 75-09-2 Methyl -tent -butyl ether ND uglL 1.0 1.0 1 0911210822:19 1634-04-4 Naphthalene NO uglL 2.0 2.0 1 09/12/08 22:19 91-20-3 1,1,2,2-Tetrachloroethane NO ug/L 1.0 1.0 1 0911210822:18 79-34-5 Tetra chi oroethene NO ugIL 1.0 1.0 1 09/12/08 22:18 127-18-4 Toluene NO uglL 1.0 1.0 1 09/12/08 22:19 108-68-3 1,1,1-Tdchloroethane NO uglL 1.0 1.0 1 09/12/08 22:18 71-55-6 1.1,2-Tdchloroethane NO uglL 1.0 1.0 1 09/12/08 22:18 79-OD-5 Trichloroethene NO uglL 1.0 1.0 1 09/12/0822:18 79-01-6 Trlchlorotluoromethane NO uglL 1.0 1.0 1 09/12108 22:18 75-69-4 Vinyl chloride NO uglL 1.0 1.0 1 09/12108 22:18 75-01-4 Xylene (Total) NO uglL 2.0 2.0 1 09/12108 22:19 133D-20-7 m&p-Xylene NO ug1 2.0 2.0 1 09/12/08 22:19 1330-20-7 o-Xylene NO ugIL 1.0 1.D 1 09/12/08 22:19 95-47-6 1-Chlorc-3-flucrobenzene (5) 91 °% 65-137 1 09/12/08 22:18 625-98-9 Date: 09/1612008 01:09 PM REPORT OF LABORATORY ANALYSIS Page 14 of 19 This report shell not be reproduced, except in Full, without the written mnsentof Pace Analytical Services, Inc.. Pace Analytical Services, Inc. Pace Analytical Services. Inc. aeeAnalXical 2225 Riverside Dr, 9800 Kmcey Ave. Suite 100 Ww Pcutaacom Ashevrlle, NC 28604 Huntersville, NC 28078 Project: GILBARCO 042.08-018 3264 Pace Project No.: 9227199 CC Batch: GCV12456 (828)254.7176 QUALITY CONTROL DATA Analysis Method. EPA 6011602 ❑C Batch Method: EPA 8011602 Analysis Description. 6011602 GCV Water Associated Lab Samples: 9227199001. 9227199002, 9227199003. 9227199004, 9227199005, 9227199006, 9227199007, 9227199008, 9227199009,9227199010 METHOD BLANK: 166951 Matrix: Water Associated Lab Samples: 9227199001, 9227199002. 9227199003. 9227199004. 9227199005. 9227199006. 9227199007. 9227199008, 9227199009.9227199010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1-Trichloroethane uglL NO 1.0 09/1210810:33 1,1.2.2-TetrachIaroethane uglL ND 1.0 09/1210810:33 1,1,2-Trichiaroethane uglL N❑ 1.0 0911210810:33 1,1-Dichloroethane uglL ND 1.0 09/12/0810:33 1,1-Dichloroethene ug1L ND 1.0 09112/0810:33 1,2-Dibromoethane (EDB) uglL ND 1.0 09112/0810,33 1,2-Dlchlorobenzene uglL NO 1.0 09/1210810:33 1.2-Dichloroethane uglL ND 1.0 09/1210810:33 1,2-❑ichloropropane uglL N❑ 1.0 09/1210B 10:33 1,3-Dichlarobenzene uglL N❑ 1.0 0911210810,33 1,4-Dichlarobenzene ug1L NO 1.0 09/12/0810:33 Benzene ug1L ND 1,0 09/1210810:33 Bromodichioromethane uglL ND 1,0 09112/0810.33 Bromoform ug1L ND 1.0 09/1210810:33 Bromomethane uglL ND 1.0 09/12/08 10 33 Carbon tetrachloride uglL N❑ 1.0 09/12/08 10:33 Chlorobenzene ug1L NO 1.0 0911210810:33 Chloroethane uglL ND 1.0 091121081033 Chloroform uglL ND 1.0 0911210810:33 Chloromethane ug1L ND 2.0 09112/0810:33 cis -1.2-Dichloroethene ug1L ND 1.0 09/12108 10:33 cis-1,3-DichIoropro pen e ug)L N❑ 1.0 0911210810:33 Dibromochloromethane uglL ND 1,0 0911210810:33 Dichlorodifluoromethane uglL ND 1.0 09112)081033 Dilsopropyl ether ug1L ND 1.0 09/12/08 10:33 Ethylbenzene ug1L ND 1.0 0911210810'33 rn&p-Xylene ug1L ND 2A 09112/0810:33 Methyl-tert-butyl ether uglL ND 1.0 09/12/08 10:33 Methylene Chloride uglL NO 2.0 09112/08 10:33 Naphthalene uglL NO 2.0 0911210810:33 o-Xylene uglL ND 1.0 0911210810:33 Tetrachloroethene uglL ND 1.0 09/1210810:33 Toluene uglL ND 1.0 0911210810,33 trans-1,2-Dichloroethene uglL ND 1.0 0911210810:33 trans-1,3-Dichi oroprope ne uglL ND 1.0 0911210810.33 Trichloroethene uglL N❑ 1.0 09112/081033 Trichlorofluoromethane uglL ND 1.0 09/12/08 10733 Vinyl chloride ug1L NO 1.0 09/12/06 10:33 Xylene (Total) uglL ND 2.0 09/12/08 10,33 1-Chloro-3-fiuorobenzene (5) °% 106 65.137 0911210E 10 33 Date: 09/16/2006 01 09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, nchouI the written consent of Para Analytical Services, Inc.. •= (704)675-9092 Page 15 of 19 ace Analytical www.pace6lias.00m Project: GtLBARCO 042-08-018 3264 Pace Project No.: 9227199 Pa ce Ana lyticall Servlcea, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Ps a* Analytic* I Sarvlaas, Inc. 9800 Kincey Ave. Suite 100 Huntersvllle, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 166952 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,11-Trichloroethane uglL 20 25.6 128 41-138 1,1.2.2-Tetrachloroethane uglL 20 22.9 114 8-184 1,1,2-Trichioroethane uglL 20 23.1 116 39-136 1,1-Dichlorcethane uglL 20 26A 132 47-132 M-Dichlorcethene uglL 20 23.1 115 28-167 1,2-Dlbromoethane (EDS) ug1L 20 23.5 117 5D-150 1,2-Dichlorobenzene uglL 20 22.8 114 1-208 1,2-Dichloroethane uglL 20 27.0 135 51-147 1,2-0101oropropane uglL 20 27.9 139 44-156 1,3-❑Ichlorobenzene ug1L 20 22.5 112 7.187 IIA-Dichlorobenzene uglL 20 22.9 114 42-143 Benzene uglL 20 21.7 108 39-150 Bromodichloromethane ug1L 20 28A 142 42-172 Bromoform ug1L 20 23.0 115 13-159 Bromomethane ug1L 20 23.2 116 1.144 Carbon tetrachloride uglL 20 25.9 130 43-143 Chlorobenzene ug/L 20 23.3 117 38-150 Chlorcethane ug/L 20 23,9 120 46-137 Chloroform ug/L 20 25.2 126 49-133 Chloromethane ug/L 20 25.7 128 1-193 cis- 1,2-1)ichloroethene q/L 20 25.6 128 38-155 cis-1,3-Dichloropropene ug/L 20 25.8 129 22.178 Dibromochioromethane ug/L 20 24.0 120 24-191 Dichlorodifluoromethane ug/L 20 21.6 108 48-157 Diisopropyi ether ug/L 20 21.3 106 89-108 Ethylbenzene uglL 20 19.6 98 32-160 m&p-Xylene ug1L 40 40.7 102 82-115 Methyl-tert-butyl ether uglL 20 20.0 100 88-110 Methylene Chloride uglL 20 27.6 138 25-162 Naphthalene uglL 20 19.4 97 50-150 o-Xylene uglL 20 19.2 95 91-110 Tetra ch loroeth ene uglL 20 23.2 116 26-162 Toluene ug1L 20 20.1 100 46-148 trans-1,2-Dichloroethene ug1L 20 26.8 134 38-155 trans-1,3-Dichloropropene uglL 20 24.6 123 22-178 Trichloroethene uglL 20 25.6 128 35-146 Tdchlorofluoromethane ug/L 20 25.7 128 21-156 Vinyl chloride ug1L 20 23.2 116 28-163 xylene (Total) uglL 60 59.9 1 D0 5D-150 1-Chloro-3-fluorobenzene (S) % 114 65-137 MATRIX SPIKE SAMPLE: 166958 9227199010 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits 1,1.1-Trichloroethane uglL NO 20 15.4 82 41-138 1,1.2,2- Tetra chi oroethane uglL N❑ 20 24.0 120 8484 1,1,2-Trichloroethane ug1L ND 20 21.3 107 39-136 Date: 09116l2D08 01.09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent or Pare Ana IyticaI Servlces, Inc.. y e11G�4, Qualifiers Page 16 of 19 (I�IaoeAnalytical www.pacWabs.c= Project: GILBARCO D42-08-018 3264 Pace Project No.: 9227199 Pace Analytical Services, Ino. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kin coy Ave. Suite 100 Huntersvilie, NC 28078 (704)875-4092 MATRIX SPIKE SAMPLE: Parameter 166958 Units 9227199010 Result Spike Cone. MS Result MS % Rec % Rec Limits Qualifiers 1,1-Dichloroethane ugIL NO 20 19.7 99 47-132 1,1-Dichloroethene ugIL NO 20 19.3 96 28-167 1,2-Dibromoethane (EDB) ug/L NO 20 22.1 111 50-150 1,2-Dichlorobenzene ug/L ND 20 20A 1D2 1-208 1,2- Diehl oroethane ug/L NO 20 19.1 95 51-147 1,2-Dichloropropane ug/L NO 20 22.1 11i 44-156 1,3-Dichlorobenzenc ug/L NO 20 19.8 99 7-187 1,4-Dichlorobenzene ug/L NO 20 19.7 98 42-143 Benzene ugfL NO 20 21.7 109 39-150 Bromodi ch loro methane ug/L NO 20 23,8 119 42-172 Bromoform ugIL ND 20 22A 114 13-159 Bromomethane uglL ND 20 13.6 68 1-144 Carbon tetrachloride ug/L ND 20 19.6 98 43-143 Chiorobenzene ug/L ND 20 22.0 110 38-150 Chloroethane ugIL N❑ 20 20.5 102 46-137 Chloroform ug/L NO 20 19,0 95 49-133 Chloromethane ug/L NO 20 23,9 120 1-193 cis- I,2- Diehl oroethane ug/L ND 20 11.2 56 38-155 cis- 1,3-Dlchloropropene ug/L ND 20 16.9 85 22-175 DibromochlDromethane ugfL N❑ 20 21.2 108 24-191 Dichlorodifluoromethane ugIL ND 20 22.2 111 48-157 Diisopropyl ether ug/L NO 20 19.5 98 89-108 Ethylbenzene uglL N❑ 20 19.8 99 32-160 m&p-Xylene ug/L IN 40 41A 103 82-115 Methyl-tert-butyl ether ugIL NO 20 20.6 103 88-110 Methylene Chloride ug1L ND 20 23.1 115 25-162 Naphthalene ug/L NO 20 20.5 102 50-150 o-Xylene ug/L NO 20 20.0 100 91-110 Tetrachlaroethene ug/L NO 20 20.7 104 26-162 Toluene ug/L NO 20 20,5 102 46-148 trans-1,2-Dichloroethane uWL NO 20 19.4 97 38-155 trans-1,3-Dichloropropene ug/L N❑ 20 21.9 110 22-178 Trichloroethene ug/L NO 20 20.2 101 35-146 Trichlorofluoromethane ug/L NO 20 21.5 107 21-156 Vinyl chloride ug/L NO 20 21,9 110 28-183 1-Chloro-3-fluorobenzene (5) % 102 65-137 SAMPLE DUPLICATE: 166957 Parameter 9227199002 Oup Units Result Result RPD Max RPD Qualifiers 1,1,1-Trlchloroethane uglL ND NO 0 30 1,1,2,2-Tetrachloroethane ugIL NO ND 0 30 1,1,2-Trichloroethane ug/L NO ND 0 30 1,1-Dichloroethane ug/L NO ND 0 30 1,1-t)ichioroethene ug/L NO N❑ a 30 1,2-Dibromaethane {EDB} ug/L ND NO 0 30 1,2-❑ichlorobenzene ug/L N❑ NO 0 30 Date: 09/16/2008 01:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in lull, without the written consent of Pace Analytical Services, Inc.. Page 17 of 19 /7 1 ace Analytical .. ww oacr!±abs com i Project: GILBARCO 042-08-018 3264 Pace Project No.: 9227199 SAMPLE DUPLICATE: 166967 Parameter Units 1,2-D1Chloroethane ug1L 1,2-Dichloropropane ug1L 1,3-Dichlorabenzene ug1L 1,4-Dichlorabenzene uglL Benzene uglL BromodichlDromethane uglL Bromoform uglL Bromomethane ug1L Carbon tetrachloride ug1L Chlorobenzerie ug1L Chloroethane uglL Chloroform uglL Chloromethane uglL cis-1,2-0ichIoroethene uglL cis-1.3-❑ichIoropropene uglL Dibromochloromethane uglL Dichlorodifluoromethane uglL Diisopropyl ether uglL Ethylbenzene uglL m&p-Xylene uglL Methyl-tert-butyl ether uglL Methylene Chloride uglL Naphthalene ug/L o-Xylene uglL Tetrachloroethene ug1L Toluene uglL trans-1,2-Dichloroethene uglL trans-1,3-❑ichloropropene uglL Trichlloroethene ug/L Trichlorofluorornethane uglL Vinyl chloride ug1L Xylene (Total) ug1L 1-Chloro-3-fiucrobenzene (S) % Date: 09/1612008 01:09 PM PaceAnalytical Services, Inc. 2225 Riverside Dr. Asheville, NC 20B04 [828]254-7176 QUALITY CONTROL DATA 9227199002 Result ❑up Result ND ND ND NO ND ND ND N❑ ND ND ND ND N❑ ND ND N❑ ND ND ND ND ND ND ND NO NO ND ND ND ND ND ND NO N❑ ND ND ND ND ND ND ND NO ND NO ND ND ND N❑ ND NO ND NO ND NO ND NO ND ND ND ND ND NO NO NO ND 104 97 RPD REPORT OF LABORATORY ANALYSIS This report shall not oe reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. T cap o rr Max RP❑ 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 a 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 0 30 a 30 0 30 0 30 0 30 0 30 0 30 0 30 7 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Page 18 of 19 aceAnalytical wwwpacelacs.rnm I QUALIFIERS Project: GILBARCO 042-08-018 3264 Pace Project No. 9227190 DEFINITIONS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 Pace Analytical Sorvices, Inc. 9a0p Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL- Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydraxine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. Date: 09/16/2008 01:09 PM REPORT OF LABORATORY ANALYSiS Page 19 of 19 This report shall riot be reproduced, except In full, without the written consent of Pa re Analytical Services, Inc.. . acre. ��riefac �: �eAnalytrral CHAIN -OE -CUSTODY 1 Analytical Request Document The Chain& -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section 6 Section C Required client IniwTr"on: Required Project Inforrm0on: invoice fnformatiorn: Page i Of 7 Company. Trlgordl(leinfeider, Inc. Repocl To: Gail Licayan AtlanliOn: Gail Licayan Address: 313 Gallimore Dairy Rd Copy Tor company Name, TrionlKleinfelder, Inc. Greensboro, NC 27409 Address: 313 Gallimore Dairy Rd, Greensbao, NC Email To: gfiIkleinfeider.curn Purchase Order No. Pace Ouote Reference. Phone: 336 66MG93 I re. Client Project ID: GILBARC0 042-08-018 Pace Project Manager McKee, Bonnie t� Requeslad Owe UstarTAT: 10 Default Container Order Number 3264 Pace Prvrile d: North Carolina I F ri MATR+x CODE 8 u COLLECTED x Preservatives .. -..9 Wwr DW y O WN.r WT - W. Ww' WW 7j S m V w SAMPLE ID 51. 3 ! a ON a One Character per box pro. [A z o-9 r • -) START END �' oe,. oT $ample Ida n1U7S be unique T1— Ts $ u� O [[n77 w a agg u T [Sf rq o o v 6 C _ F < q TIME DATE TRNE 4 O f 6 ore oC �+w-7 WT to q C x Im bAw-11 WT c 11137 1 x in Mw-13 WT G ' r x an MW-130 WT G Z x MW-14 WT fm x MW-23D WT -Gi. G x MW-24 WT G x MW-25 WT G x MW�$ WT G a x VW-45 wr G x 41 N A4VV- - - £� �'GIrS lGIrTf '57,5" ra U C a ttl � 9 PRINT Name of SAMPLER: SIGNATURE of SAMPLER: DATE Slated: z w ❑ r UU h� APPENDIX B TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-7 25,000 20,000 I oPo0 5,000 0 0/ 01, 0& 12v or '06' )9j 0& s Date TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-11 to 15 S ollp Q9 Date w TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-13 Will 140 120 w C� 40 KC 0 00 of a" o,? 09,'o-r oT o�> o& os Date TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-13D 70 60 50 40 30 RE 10 Date b ❑ C7 7 'S A� t� Y TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-14 2,000 l . wO 1,400 1,200 o 1 800 r 600 400 200 0 9p 9f 9� 9� 9� 9� 96 9> A� 99 QD Qf O� O� O� �]Ir I > Date TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-23D 800 700 500 m_ 400 v MQ c4 300 200 100 0 '��o, ✓� ��a, ��, �� f�a, f�., '��o, fir, �`�o, f� ' f' J� ✓� ✓' , �' , �' Date TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-24 1 s . It `% ��' ter, f ✓ Da to 7,000 6,000 5,000 n 0 4,000 m 0 H 3,000 2,000 111 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-25 m x() (A) w 40 V u 20 El fir, Jar, J' J�J�o, �� ? J�o, Jar, 9� 9� a0 ar a� a� aQ a� a� O) O� Date TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-42 .c 50 40 20 10 0 o� olp Elate N TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-45 o� of ay Date r TRIGON SERVICES ■ GEOTECHNICAL ENGINEERING ■ CONSTRUCTION MATERIALS ENGINEERING/TESTING ■ SPECIAL INSPECTIONS ■ FORENSIC ENGINEERING ■ ENVIRONMENTAL DUE DILIGENCE/PHASE I AUDITS ■ GEOTECHNICAL AND ENVIRONMENTAL DRILLING ■ GROUNDWATER INVESTIGATIONS/REMEDIATION • SITE CIVIL DESIGN ENGINEERING • LAND PLANNING/DEVELOPMENT ENGINEERING ■ STREAM AND WETLAND DELINEATION/PERMITTING ■ WATER RESOURCE ENGINEERING • WATER AND WASTEWATER ENGINEERING ■ STORMWATER MANAGEMENT/PERMITTING/SPCC • TANK INTEGRITY TESTING ■ HEALTH AND SAFETY CONSULTING ■ REGULATORY COMPLIANCE ENGINEERING/STRATEGIES ■ WASTE MINIMIZATION STUDIES ■ AIR QUALITY CONSULTING • ATMOSPHERIC DISPERSION MODELING ■ SOURCE TESTING AND CONTINUOUS EMISSIONS MONITORING ■ INDOOR AIR QUALITY/INDUSTRIAL HYGIENE ■ ASBESTOS AND LEAD -BASED PAINT INSPECTIONS OFFICE LOCATIONS Greensboro Charlotte Raleigh Raleigh North Carolina North Carolina North Carolina North Carolina 336.668.0093 704.598.1049 Design and Construction Environmental 919.755.5011 91.9.861.7775 Wilmington North Carolina 910.256.9300