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Home My WebLink AboutWQ0036723_Regional Office Historical File Pre 2018 (3)Town of Mooresville NORTH CAROLINA NCDENR-DWQ Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699 ROCKY RIVER W.W.T.P TELEPHONE (704) 662-8470 FAX (704) 662-8473 POST OFFICE BOX 878 MOORESVILLE, NC 28115 RECEIVED/NCDENR/DWR JAN 2 8 2019 0 1/7/ �9WQROS OORESVILLE REGIONAL OFFICE Subject: 2018 Annual Sludge Report, WQ0036723 Distribution of Class A Residuals Following is the information requested to accompany our Class "A" Annual report. 1) Facility - Rocky River Wastewater Treatment Facility 369 Johnson Dairy RD. Mooresville, N.C. 28115 Phone: 704-663-2840 2) Responsible official and facility contact — Larry Hendren, Bio-solids Coordinator P.O. Box 878 Mooresville, NC 28115 Phone: 704-799-4063 3) Class "A" dried biosolids were distributed under Town of Mooresville permit # WQ0036723 4) (Part A) and (Part B) Distribution of Class "A" Residuals for 2017 were transported to, Joe Hampton in Mt. Ulla, NC, and Doug Carrigan in Mooresville, NC. Total = 363.11 dry metric tons (See Attached Hauling Summary Sheets). Laboratory data from quarterly TCLP analyses have been included in this report. 5) (Part C) I certify, under penalty of law that the above information is, to the best of my knowledge and belief, true and accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Prepared by: Larry Hendren, Bio-solids Coordinator Reviewed by: Jamie Levis, WWTP Plant Manager Signature:.8, -c�-_� l -^1 - Zo l C� Date Signatu / 5L— Date Town of Mooresville 2018 Hauling Summary Sheet DATE TONS TRANSPORTER DESTINATION COMMENTS 4/1/2018 11.5 Garrin Klutz Farm Mt. Ulla 1 Load 4/29/2018 19.8 Garrin Klutz Farm Mt. Ulla 2 Loads 4/30/2018 10.8 Garrin Klutz Farm Mt. Ulla 1 Load 5/2/2018 54.4 Garrin Klutz Farm Mt. Ulla 5 Loads 7/18/2018 60.4 Garrin Klutz Farm Mt. Ulla 5 Loads 7/19/2018 61.7 Garrin Klutz Farm Mt. Ulla 5 Loads 10/22/2018 32.4 Carrigan Farms Mooresville 8 Loads 10/23/2018 29.6 Carrigan Farms Mooresville 8 Loads 10/24/2018 28.9 Carrigan Farms Mooresville 8 Loads 10/25/2018 28.1 Carrigan Farms Mooresville 8 Loads 11/29/2018 30.1 Carrigan Farms Mooresville 8 Loads 11/30/2018 34.4 Carrigan Farms Mooresville 10 Loads 11/30/2018 11.7 Town of Mooresville Carrigan Farms - Mooresville 2 Loads Total tons 413.71 Avg. % solids 0.9675 Dry tons 400.3 Conversion factor 0.907184 Metric tons 375.31 Dry metric tons 363.11 Calculation: Dry metric tons= total tons * avg.% solids* conversion factor TOWN OF MOORESVILLE CLASS A BIOSOLID PELLETS. eC21VED1NCDENR1DWR UTILIZATION AGREEMENT DISTRIBUTED UNDER NC DWQ PERMIT # WQ0036723 JAN 2 8 7.01y I. CONTACT INFORMATION THIRD PARTY INFORMATION Name Doug Carrigan Mailing Address 1261 Oak Ridge Farm Highway _Mooresville, NC 28115 Phone Number 704-664-1450 or 704-662-2014 Email doug0c� arriganfarms.com WQR05 MOORESVILLE REGIONAL OFFICE TOWN OF MOORESVILE INFORMATION Larry Hendren (Permittee Designee) P.O. Box 878, Mooresville NC 28115 704-799-4063 lhendren@mooresvillenc.gov II. DESCRIPTION This is pelletized material produced from the heat treatment of residuals from municipal wastewater. This product meets the standards for a Class A biosolid product according to the EP.A's 40 CFR Part 503 regulations. III. RESTRICTIONS Residual land application is prohibited except in accordance with the instructions on this Utilization Agreement: 1. If the residuals are likely to adversely affect a threatened or endangered species listed under section 4 of the Endangered Species Act or its designated critical habitat 2. If the application causes prolonged nuisance conditions 3. If the land fails to assimilate the bulk residuals or the application causes the contravention of surface water or groundwater standards 4. If the land is flooded, frozen, or snow-covered, or is otherwise in a condition such that runoff of the residuals would occur 5. Within the 100 year flood elevation, unless the bulk residuals are injected or incorporated within a 24- hour period following a residuals land application event 6. During a measurable precipitation event (i.e. greater than 0.01 inch per hour), or within 24 hours following a rainfall event of 0.5 inches or greater in a 24-hour period 7. If the soil pH is not maintained at 6.0 or greater, unless sufficient amounts of lime are applied to achieve a final soil pH of at least 6.0, or if an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for the specified crop 8. If the land does not have an established vegetative cover unless the residuals are incorporated or injected within a 24-hour period following a residuals land application event 9. If the vertical separation between the seasonal high water table and the depth of residuals application is less than one foot 10. If the vertical separation of bedrock and the depth of residuals application is less than one foot 11. Biological Residuals shall not be stockpiled for more than 30 days prior to distribution 12. The Third Party accepting the residuals shall provide the Permittee with all other nutrient applications (i.e. organic and/or inorganic fertilizers) 13. it copy of this Utilization Agreement shall be maintained at the site when bulk residuals are being applied 14. The residuals shall be prevented from entering any public or private water supply source (including wells) and any surface waters (e.g. streams, lake, river, wetland) 15. Residuals should be land applied at agronomic rates © 2016 Town of 1tifooresville 16. Submission of Soil Samples prior to distribution of product 17. The Permittee shall not distribute bulk residuals to any person or entity known to be applying residuals contrary to the condition of the signed Utilization Agreement IV. SETBACKS Applicable setbacks in accordance with 15A NCAC 02T .1108(b): Description of Setback Setback by type of application (feet) Cake Residuals Private or public water supply 100 Surface Waters (streams — intermittent and perennial, perennial waterbodies, and wetlands) 25 Surface water diversions (ephemeral streams, waterways, ditches 0 Groundwater lowering ditches (where the bottom of the ditch intersects the SH 0 Wells with exception to monitoring wells 100 Bedrock outcrops 0 V. APPLICATION RATES Application Rates should not exceed the calculated nitrogen requirements based on the Realistic Yield Expectation for a particular crop and the predominant soil series within the application area. This product has a North Carolina Fertilizer label of 5% Nitrogen —1 % Phosphorus — 0% Potassium ratio, but given that it is generated from aerobically digested residual biosohds it is assumed that a 30% mineralization rate (Organic Nitrogen to Plant Available Nitrogen) is used to calculated the Plant Available Nitrogen (PAN). The PAN listed below should be used along with other nutrient application to determine agronomic rates. NUTRIENT RANGES Percent Solids: 94-98% Total Nitrogen: 60-112 lbs/ton Ammonia Nitrogen: 3-6 lbs /ton Nitrate/Nitrite Nitrogen: 0 - 0.01 lbs/ton PAN: 13-40 lbs /ton Total Phosphorus: 20-28 lbs/ton (as PtiOsl Approximate Density:15 - 20 lbs/ft3 Total Potassium: 0lbs/ton (as K V. AGREEMENT Third Party (Printed Name) Larry Hen , Town of Mooresville Date T1=4d Party (Signature) ate /O-16-19, 0 2016 Town of Mooresville I n PR_ISM ©V LABORATORIES, INO Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe i P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 01/16/2018 Prism Work Order: 8010222 Case Narrative 01 /07/2019 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a revised report and supersedes the original report dated 2/1/2018. The calculations for SAR and PAN have been added to the case narrative. This is a revised report and supersedes the original revised report dated 03/27/18. The SAR and PAN calculation worksheets have been added to the report. Analysis note for SAR: SAR = [ Na ] / SQRT { ( [Ca] + [Mg] j / 2' } SAR = [ 124/23 ] / SQRT { ( [126/201 + [59.6/12.21) / 2 } SAR = 2.2 Concentrations for Na, Ca, and Mg are expressed in milliequivalents per liter, and SQRT designates taking the square root of the operand in parentheses. PAN Equation = • 0. 3 * (TKN — Ammonia) + 0: 5 * (Ammonia) + Nitrate —Nitrite PAN Equation = 0.3 * 449700 — 1890) + 0.5 * (1'890) + 5.62 PAN = 15000 Equation uses Mineralization Rate (MR) for Aerobically Digested Solids (0.3) 34 ) + �50•�2 I! This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 -Toll Free Number: 1-800/529-6364 - Fax: 704/526-0409 Page 1 of 17 Please call if you have any questions relating to this analytical'report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager r(kD 66a-1) Reviewed By Terri W. Cole Project Manager Data Qualifiers Key Reference: B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 1 Ox the MB. CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 2 of 17 I Full -Service Analytical & P R I S M Environmental Solutions �r%UIBONATOXIE3, INC Sample Receipt Summary 01/07/2019 Prism Work Order: 8010222 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received Class A 8010222-01 Solid 01/16/18 8:30 01/16/18 12:55 Samples were received in good condition at 4.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041626-0409 Page 3 of 17 r Full -Service Analytical & LJP R_ I S M Environmental Solutions 7ueoanTOslEs ING Laboratory Report 01 /07/2019 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8010222-01 P. O. Box 878 Prism Work Order: 8010222 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 01/16/18 08:30 Time Submitted: 01/16/18 12:55 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 16000 mg/kg dry 1600 330 20 *Calculation 1/22/18 10:49 CLB [CALL] Solids 97.0 % by 0.100 0.100 1 *SM2540 G 1/22/18 14:16 TJY P8A0320 Weight Ammonia as N 1900 mg/kg dry 9.6 2.4 1 *SM4500-NH3 C 1/18/18 14:00 BMS P8A0246 Nitrate/Nitrite as N 6.6 mg/kg dry 6.2 0.57 1 *SM4500-NO3 F 1118/18 10:02 CLB P8A0226 pH 6.2 pH Units 1 *9045D 1/17/18 13:33 EGC P8A0220 Phosphorus -Total 11000 mg/kg dry 260 37 100 *SM4500-P F 1/19/18 9:20 CLB P8A0225 -- Total Kjeldahl Nitrogen 50000 mg/kg dry 5200 1100 20 *351.2 1/22/18 10:49 CLB P8A0239 Microbiological Parameters Fecal Coliforms 0.5 MPN/g dry 0.2 1 *SM9221 E 1/16/18 14:07 EGC P8A0222 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 *1311 1/24/18 8:30 JAB P8A0331 TCLP Extraction Complete N/A 1 *1311 ZHE 1/26/18 9:00 ANG P8A0378 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 1/24/18 16:29 JAB P8A0344 Arsenic 0.22 mg/L 0.050 0.016 1 *6010D 1/26/18 13:21 JAB P8A0399 Barium 22 mg/L 5.0 0.0040 1 *60101) 1/26/18 13:21 JAB P8A0399 Cadmium 0.081 mg/L 0.025 0.00075 1 *6010D 1/26/18 13:21 JAB P8A0399 Chromium 2.2 mg/L 0.25 0.0018 1 *6010D 1/26/18 13:21 JAB P8A0399 Lead BRL mg/L 0.050 0.0040 1 *6010D 1/26/18 18:52 JAB P8A0399 Selenium 0.42 mg/L 0.10 0.028 1 *6010D 1/26/18 13:21 JAB P8A0399 Silver BRL mg/L 0.25 0.0020 1 *6010D 1/26/18 18:52 JAB P8A0399 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00086 1 *8081B 1/29/18 18:41 JMC P8A0353 Dieldrin BRL mg/L 0.00050 0.000070 1 *8081B 1/29/18 18:41 JMC P8A0353 Endrin BRL mg/L 0.00050 0.000075 1 *8081B 1/29/18 18:41 JMC PBA0353 gamma-BHC BRL mg/L 0.00050 0.000065 1 *8081B 1/29/18 18:41 JMC P8A0353 Heptachlor BRLCCV mg/L 0.00050 0.000085 1 *8081B 1/29/18 18:41 JMC P8A0353 Heptachlor Epoxide BRL mg/L 0.00050 0.000065 1 *8081B 1129118 18:41 JMC P8A0353 Methoxychlor BRLCCV mg/L 0.00050 0.00020 1 *8081B 1/29/18 18:41 JMC P8A0353 Toxaphene BRL mg/L 0.025 0.00037 1 *8081B 1/29/18 18:41 JMC P8A0353 Surrogate Recovery Control Limits Decachlorobiphenyl 29 % 13-186 Tetrachloro-m-xylene 25 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 *8270D 1/29/18 19:26 JMV P8A0411 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 1/29/18 19:26 JMV P8A0411 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 *8270D 1/29/18 19:26 JMV P8A0411 2-Methylphenol BRL mg/L 0.050 0.0018 1 *8270D 1/29/18 19:26 JMV PBA0411 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 Free Number: 1-800/629-6364 Fax: 704/626-0409 Page 4 of 17 -Toll - G R Full -Service Analytical 8 I S M ^-1 Environmental Solutions �,'I.AeORATORIES ING Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 01 /07/2019 Client Sample ID: Class A Prism Sample ID: 8010222-01 Prism Work Order: 8010222 Time Collected: 01/16/18 08:30 Time Submitted: 01/16/18 12:55 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID --, 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 '8270D 1/29/18 19:26 JMV P8A0411 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 '8270D 1/29/18 19:26 JMV P8A0411 -- Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 '8270D 1/29/18 19:26 JMV P8A0411 Hexachloroethane BRL mg/L 0.050 0.0017 1 '8270D 1/29/18 19:26 JMV P8A0411 Nitrobenzene BRL mg/L 0.050 0.0026 1 '8270D 1/29/18 19:26 JMV P8A0411 Pentachlorophenol BRL mg/L 0.25 0.0012 1 '8270D 1/29/18 19:26 JMV P8A0411 _ Pyridine BRL mg/L 0.25 0.0010 1 '8270D 1129/18 19:26 JMV P8A0411 Surrogate Recovery Control Limits 2,4,6-Tdbromophenol 44 % 43-140 2-Fluorobiphenyl 44 % 44-119 2-Fluorophenol 42 % 19-119 _ Nitrobenzene-d5 41 % 44-120 SE Phenol-d5 30 % 11-52 Terphenyl-d14 44 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 '8260B 1/27/18 2:15 KDM P8A0420 1,2-Dichlorcethane BRL mg/L 0.025 0.00066 1 '8260B 1/27/18 2:15 KDM P8A0420 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 '8260B 1/27/18 2:15 KDM P8A0420 Benzene BRL mg/L 0.025 0.00048 1 '8260B 1/27/18 2:15 KDM P8A0420 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 '8260B 1/27/18 2:15 KDM P8A0420 Chlorobenzene BRL mg/L 5.0 0.00062 1 '8260B 1/27/18 2:15 KDM P8A0420 Chloroform BRL mg/L 0.30 0.00076 1 '8260B 1127/18 2:15 KDM P8A0420 - Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 '8260B 1/27/18 2:15 KDM P8A0420 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 '8260B 1/27/18 2:15 KDM P8A0420 Trichloroethylene BRL mg/L 0.025 0.00078 1 '8260B 1/27/18 2:15 KDM P8A0420 Vinyl chloride BRL mg/L 0.020 0.00097 1 '8260B 1/27/18 2:15 KDM P8A0420 Surrogate Recovery Control Limits 4-Bromofluorobenzene 95 % 80-124 Dibromofluoromethane 98 % 75-129 Toluene-d8 95 % 77-123 Total Metals Calcium 130 BH, B mg/L 0.10 0.010 1 '60101) 1/25/18 17:27 JAB P8A0256 Magnesium 60 mg/L 0.10 0.0086 1 '6010D 1123/18 12:09 JAB P8A0256 Sodium 120 B mg/L So 1.8 100 '60101) 1/23/18 12:02 JAB P8A0256 Aluminum 9100 mg/kg dry 2.6 0.76 1 '6010D 1/26/18 0:08 JAB P8A0395 Mercury 0.25 mg/kg dry 0.057 0.0064 3 '74716 1/29/18 14:10 JAB P8A0418 _ . SAR Soil Preparation Complete g 1 '2-78-054 1/19/18 9:20 JAB P8A0238 SAR Percent Moisture Complete % by 0.100 0.100 1 '2-78-054 1/23/18 15:20 JAB P8A0333 Weight Arsenic 1.2 mg/kg dry 0.26 0.032 1 '6010D 1/26/18 13:21 JAB P8A0395 - Sodium Absorption Ratio 2.2 [blank] 0.30 0.016 1 '2-78-064 1/25/18 16:69 JAB P8A0256 Cadmium 0.41 mg/kg dry 0.26 0.0069 1 '6010D 1/26/18 0:08 JAB P8A0395 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC Phone: 704/629-6364 Free Number: 1-800/529-6364 Fax: 28224-0643 Page 5 17 -Toll - 704/626-0409 of f' PG Full -Service Analytical & !'P R I S M Environmental Solutions 'LAwO Tanim ma Laboratory Report 01 /07/2019 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8010222-01 P. O. Box 878 Prism Work Order: 8010222 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 01/16/18 08:30 Time Submitted: 01/16/18 12:55 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Calcium 9700 mg/kg dry 10 0.24 1 *6010D 1/26/18 0:08 JAB P8A0395 Chromium 11 mg/kg dry 0.26 0.043 1 *6010D 1/26118 0:08 JAB P8A0395 Copper 160 mg/kg dry 52 4.7 100 *6010D 1/25/18 15:22 JAB P8A0395 Lead 6.8 mg/kg dry 0.26 0.048 1 *6010D 1/26/18 0:08 JAB P8A0395 Magnesium 1800 mg/kg dry 2.6 0.24 1 *6010D 1/26118 0:08 JAB P8A0395 Molybdenum 5.9 mglkg dry 0.52 0.016 1 *6010D 1126/18 0:08 JAB P8A0395 Nickel 8.7 mg/kg dry 0.52 0.019 1 *6010D 1/26/18 0:08 JAB PSA0395 Potassium 2700 mg/kg dry 1300 47 100 *6010D 1125/18 15:22 JAB P8A0395 Selenium 2.4 mglkg dry 0.52 0.12 1 *6010D 1/26/18 0:08 JAB P8A0395 Sodium 990 mg/kg dry 16 0.51 1 *6010D 1/26/18 0:08 JAB P8A0395 Zinc 360 mg/kg dry 260 9.3 100 *6010D 1/25118 16:22 JAB P8A0395 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041526-0409 Page 6 of 17 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Date/Time 8010222-01 P8A0239 0.05 g 25 mL 01/18/18 10:00 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 8010222-01 P8A0246 1.09 g 50 mL 01/18/18 12:00 Prep Method: SM4500-PB5 Lab Number Batch Initial Final Date/Time 8010222-01 P8A0225 1 g 50 mL 01/18/18 7:08 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 8010222-01 P8A0320 30 g 30 g 01/22/18 14:16 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 8010222-01 P8A0331 100 g 2000 mL 01/23/18 14:08 8010222-01 P8A0378 12.5 g 250 mL 01/25/18 15:45 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8010222-01 P8A0399 10 mL 50 mL 01/26/18 10:20 8010222-01 P8A0399 10 mL 50 mL 01/26/18 10:20 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 8010222-01 P8A0344 20 mL 30 mL 01/24/18 10:10 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 8010222-01 PBA0353 200 mL 10 mL 01/25/18 11:00 Prep Method: 3610C MS Lab Number Batch Initial Final Date/Time 8010222-01 P8A0411 200 mL 1 mL 01/29/18 11:30 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 8010222-01 P8A0420 1 mL 10 mL 01/26/18 11:46 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 8010222-01 P8A0256 50 mL 50 mL 01/19/18 9:20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 -Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 7 of 17 Prep Method: 3050E Lab Number Batch Initial Sample Extraction Data Final Date/Time 8010222-01 P8A0395 1.99 g 50 mL 01/23/18 9:40 8010222-01 P8A0395 1.99 g 50 mL 01/23/18 9:40 8010222-01 P8A0395 1.99 g 50 mL 01/23/18 9:40 Prep Method: 7471B Lab Number Batch Initial Final Date/Time 8010222-01 P8A0418 0.65 g 50 mL 01/29/18 11:42 Prep Method: SAR 2-78-064 Lab Number Batch Initial Final Date/Time 8010222-01 P8A0238 250 g 250 g 01/18/18 9:20 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 8010222-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/626-0409 Page 8 of 17 _ �' 1 Full-�._�r;lce Atsiytical c. S Enviicnrltental Solutions t 4COAA7061CS. I11C 4,19 Springbrook Road • Charlotte, NC 28217 Phone 704/529-6364 • Fax: 7041525-0409 t Client Company Name: )Q�.[� b/ o"OtZ e Report To/Contact Name: aR tt/�tl Reporting Address:.:--SfpD, 9_4V C.HAIN OF CUSTODY RICLEC®RD PAGE OF JR-QUOTE K TO EN/{SURE PROPER- �BILLING: Project Name: & A ��a � 51 la�� Short Hold Analysis: as (No) UST Project: Yes) (r 'Please ATTACH any project specific reporting (QC LEVF�i III IV) provisions and/or QC Requirements Invoice To: JEW& ag MODS441R L Address: Samoles INTACT upon aiiival7 Received ON INET :CE'' PROPER. PRESERVATIVES indicated? Received WITHIN HOLDING rIUES? CUSTODY SEALS INTACT? VOLATILES ruc'd'hROUT HEADSPACE PROPER CONTAINERS used^ TEMP. Therm ID:_I Li.1-_i1 Uusarved ' l O ti PI%one: 4--&174—J Fax (Yes) (No): Purchase Order No./Billing Reference 1 O SE -FILLED IN BY CLIENTISAMPLING PERSONNEL Email Address: - Raqudsled Cua Date ❑ 1 Day ❑ 2'ba�s ❑ 3 Days 134 Days ❑ 5 Days Certification: N)=LAC_ 90l)FL PAC EDD Type: PDF ✓EtCe(_ Other dust Be "'Working Days" ❑ &9 Days andard l0 days O e- Site Location Name: pprov Samples received after 14:00 will be processed next business day.' Turnaround time is based on business days, excluding weekends and holidays. SIC - OT IA :R i Water.Chlorinated: YES_ NC! e/ Site Location Physical Address: (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES_ id0_ RENDERED BY PRISM LABORATORIES. INC. TO CLIENT) TIME MATRIX SAMPLE CONTAINER ANALYSIS REQUE C✓.t.b °hhy 'aj �'.iieJ •/ PRESERVA- {� •)' PRISM CLIENT SAMPLE DESCRIPTION DATE COLLECTED COLLECTED MILITARY SOIL, WATER OR TES f oaNY `K \ ` \ + %� REMARKS N � �. +, LAB ID NO. `TYPE SIZE HOURS SLUDGE) SEE BELOW NO. e c '/ o �y� {�/� tic SO9� pyr'Q, .i i I • �I i I _ l I 11 - Sampler's Signature �1 -~` �J�Y\rLCr Sampled By (Print Name) �—�+ r �� t-�Pr iCH v1 Affiliation. Upon relinquishing, this Chain oi-bustody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for an changes after analyses have been initialized. rngWshedHy:jS`yrcaWre►: r ii nalComme Is: I Sile.4irivel'iiuie: Re y:( ignagrray Oat lltild¢iyltiosir>i AdditioTt 1 Re_T q n. y:'(r:8 . ,pro Received Or. ( ignatuie) Date Site Dr_panure ?ime' Rec�Nk'dfcrPnsm Ln ratgries al ' / � Field ?aci Fee: I41 �,Y ate`" - r (.1� 1 ti ! hlremu' IT S ODYSEALS ORTRANSPORTATIO TO R. CO �rtup;NO. 0 ! hIcthad.arSNprne NOTE: ALL SAMPLE C00I:ERSBHOULDBETAPF�SH DRAT SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. %Sldsm J7 Fed E;,r O UPS ❑land-0errvered Field Service O Olhar LAND ILL j� o r �❑ NC O SC ❑ NC O SC I n NO ❑ SC I ❑ NCO CIMIKINGWATER, �`� '{tlG l3 SG p NC ❑ SC I ZINC CIS C I ❑ NC F❑ SC I O❑TNC O SC *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Ca_ p VOA = Volatile Organics Analysis (Zero Head Space) Full -Service Analytical & �1"ARNI OF CUSTODY RECORD Environmental Solutions PAGE OFQUOTE #TO ENSURE PROPER BILLING, PRISM 1L1aORATOME:S. INC, 449 Springbrook Road • Charlotte, NC 28217 Project Name: l /y �i S LIST Phone 704/529-6364 • Fax: 704/525-0409 4 Short Hold Analysis., ( UST PPG (Yes) 0 Client Company Name: D - �tiV� `Please ATTACH any prcda specific reporting (QC LEV501 Ill i r qt 1 10-1 provisions and/or QC Requirements y Invoice To: t9tH1E1, �- ��+��b Report To/Contact Name: �- Reporting Address: o• ab -9,V Address: AAhes15%il , iVriIsaPf �E,SS NO NIA Samptes INTACT upon arnval"� Receiver ON %NE?ICF? _/l PROPER PRESERVATIVES utdiraled' Received WITHIN 1 IOLDING T IMES^: CUSTODY STEALS INTACT? VOLA TILES rec'd PI/OIJI HEADSoACE•/ PROPER CiIi!-U-1ILI,- u.ed" 'tc^.%P' 'Ir�_rru IU_I iLt� +/ _ULs�,y_d: t_I _f � � _ � -• "; � fe_ Phone: a2H AbO-32z Fax (YGS)(No): Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: ul�' EDD Type: PDF � FJtcel Other Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days "Working Rush Wooc Mdust BePre-Appr Certification: NELAC DoD / FL NC y Days" ❑ 6-9 Days ❑ Standard 10 days O SC OTHER N/A Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Tumaround time Is based on business days, excluding weekends and horidays. Water Chlorinated: YES_ NO r� (SEE REVERSE FOR TERMS 6 CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES O RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) TIME MATRIX SAMPLE CONTAINER •it'd A14ALYS15REt1UESTED ' / ' PRISM CLIENT SAMPLE DESCRIPTION DATE COLLECTED COLLECTED MILITARY (SOIL, WATER OR PRESERVA- TILES ; ; D� Al • (3 U � / REMARKS LAB ID NO. *TYPE NO. SIZE r HOURS SLUDGE) SEE BELOW C-� f � I I 1 Sampler's Signaturot C._ — � � -c��- Sampled By (Print Name) �� t e -& iz s� Affiliation Upon relinquishing, this Chain of &study Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for ,anyr#anges after analyses have been initialized. RetinRulshed y: (5- nalura d RecoNod"•(Signawre) - oala .. t.41 doryvHnurs Additional Comments: • ! �=,i.M,�I::�Tr.�ri , —. — JI1 Rellm u ed 6 S; n re "Ved B nature Date _ r `:il.i De,arlum Tiosa: RotinqulshadByy(Signalura) Rracalle• or Prism otrbrabdh'� ate/r - I Or, �,.I0:11`f j i-ielJ Tecn Fee: --- '--i - ---------- �, —° /. -:�' ::� •._�/��/tf�J �c� .�� 6J,`, 4. — jvko Pill � II j roile q.,: Me:Had vt Sntpraenl: t t37E ALLSArdPLE COOLERS SHOULD HE TAPED SH WITH CUSTODY U ALS FOR TRANSPORTAT1014 TO THE LABORATORY. COC Group Ido. j �. P L SAMPLESARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT THE LABORATORY. -Fed-Ear Pq Feld Service O Oihea N ""T: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: ❑NC❑SCI ❑NC ❑SC I ❑NC ❑SC 113NC ❑SC C ❑SC IaCNC0SC � ❑❑NC ❑SC ❑❑NC ❑SCI ❑❑NC ❑SC ❑----- ❑- - ❑- j *CONTAINER TYPE CODES: A=Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Main Office: 449 Springbrook Road 'JD Full Service Analytical and P.O. Box 240543 91smEnvironmental Solutions Charlotte, NC 28224-0543 _ :N: )fldl =11EF INC, Phone: 7041529-6364 1/800/529-6364 Fax: 7041525-0409 www.prismlabs.com Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Numberl 8010222 1 Sample Namel Class A Na: Sodium (mg/L) Equivalent weight: 23 Ca: Calcium (mg/L) Equivalent weight: 20 Mg : Magnesium (mg/L) Equivalent weight: 12 Milli Equivalent (ME) = mg/L / Equivalent weight Nam /L . Cam /L Mg(mg/L) 120.0 1 130.0 60.0 Na (ME) Ca ME M ME 5.22 6.50 5.00 SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power SAR = 2.2 (From mg/L entered above) Calculated By: Page 11 of 17 Main Office: f Full 9otvieu Analytical and 449 Springbrook Road ' PI t ISM I Envlroumoulal Solutions P.O. Box 240543 Charlotte; NC 28224-0543 Phone: 7041529-6364 118001529-6364 Fax:7041525-0409 www.prismiabs.com Plant Available Nitrogen Sample Numberl 8010222 Sample Name . Gass A Mineralization Rate TKN NH3 NOX rnalkg Mg/kg ma/kg 0.3 50000 1900 5.6 PAN 15,000 lmgikg Calculated By:_ MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mglkg sd GfD- / sc) �so Page 12 of 17 . �ESs ANALWICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 8010222 LABORATORY REPORT NUMBER 1801F47 DATE January 30, 2018 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aatnick(aaxs-inc.com - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Tne), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # TL-E87582, NELAP certified laboratory # E87582 , - AIHA-LAP,LLC Laboratory 0:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Ewa mination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.78 142,13 or toll fee al 883.315.4243 Page 1 of 5 Page 13 of 17 Full -Service Analytical & Environmental Solutions �n �`� -1' IAaeMTOP�IN6 . SUBCONTRACT ORDER Certili NELAC USACE Prism Laboratories, Inc. NCj SC Other 8010222 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457.8177 Fax: 704-525-0409 Fax: NA Project Manager. Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample ED: 8010222-01 Solid Sam led:01/16/18 08.30 Herbicides TCLP (Sub) 01/23/18 08:30 Canlofaers Supplied.- L I141�- 1455 i It 8-11 ? Released By Date Received By Date Page 1 of 1 Page 2 of 5 C Page 14 of 17 Analytical Environmental Services, Inc Date: 30-Jan-18 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1801F47 Tag Number: 8010222-01 Project Name: 8010222 Collection Date: 1/16/2019 8:30:00 AM Lab ID: 1801F47-OOIA Matrix: Solid Analyses Result Qual MDL Reporting Limit Units BatchID DF Date Analyzed Analyst HERBICIDES,TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Siivex) BRL 0.030 0.20 mg/L 254629 1 010C1018 18:54 EI 2,4-D BRL 0.051 0.20 mg/L 254629 1 01/29/201818:54 EI Surr: DCAA 76.4 0 50.4-133 %REC 254629 1 01129=1813:54 EI Qnaltfrers: a Mblue exceeds maximum contaminant level E Istim tted value abotK quantitation range BRL Mat Detected at MDL S Spike Recovery oucido limits due to matrix H Holding times for preparation or analysis exceeded > Greater than Result value N Ana lyie wd VELAC certified J Estimated value detected below Reporting Limit B Analyte detected in the associated method blank < Lets thin Result value Page 3 of 5 Page 15of17 6Fix: m r1c,11 IL AES S�rt,crs,lrrc. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. 2. Carrier: FeclE:t Q UPS ❑ USPS❑ Client❑ Courlcr❑ Othei AES Work Order Number: 1801F47 nntailc f,Cfeap:' .a :Sa.V. ' Comments Shipping container/cooler received in good condition? o damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? o . Custody seals intact on shipping container? Temperature blanks present? o Cooler temperature(s) within limits of 0-6eC? (See item 13 and 14 for temperature recordings,] �J ® Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? o' Chain of Custody signed, dated, and timed when relinquished and received? r Sampler name and/or signature on COC? Were all samples received within holding time? D t TAT marked on the COC?} If no TAT indicated, proceeded with standard TAT per Terms & Conditions. LIM 13. Cooler I Temperature 1.7 °C Cooler 2 Temperature 14. Cooler 5 Temperature °C Cooler 6 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 2t, 25. 26. °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 7 Temperature °C Cooler 8 Temperature °C 1 certify that I have completed sections 1-15 (dated initials), TD 1/22/18 —,;6 [nmments Were sample containers intact upon receipt? o Custody seals present on sample containers? e Custody seals intact on sample containers? n Do sample container labels match the COC? Q ® Q incomplete info ❑ illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? no oall of the samples listed on the COC received? samples received but not listed on COC ID samples listed on COC not received ❑ Was the sample collection date/time noted? e, Did we receive sufficient sample volume for indicated analyses? o' Were samples received in appropriate containers? u Were VOA samples received without headspace (< 1/4" bubble)? o Were trip blanks submitted? ©' listed on COC ❑ not listed on COC ❑ 27. Comments: 1 certify that I have completed sections 16-27 (dated initials). TR 1/22/18 This soclion only applies to samples where pH can be checked at Samnle Recaint. von N„ nl/n Details Comments 28. Have containers needing chemical preservation been checked? ` o 29.1 Containers meet preservation guidelines? 30, Was pH adjusted at Sample Receipt? 0 W ' Nate: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Colitorms, VOCs and Oil & Grease/TPH. TR 1/22/18 CD1 certify that I have completed sections 28-30 (dated initials). 01) Checklist 6.9.17 Rev 2 ; LOckeds.; I Page 4of5 1 Analytical Environmental Services, Inc ^.lient: Prism Laboratories Project Name: 8010222 Workorder: 180047 Date: 30-Jan-18 ANALYTICAL QC SUMMARY REPORT BatchID: 254629 Sample ID: h1B-254629 Client ID: Units: mg/L Prep Date: 01/25/2018 Run No: 361892 SampleType: M'BT.X TestCode: HERBICIDES, TCLP SW1311/8151A BatchID: 254629 Analysis Date: 01/29/2018 Seq No: 7992513 Analyte Result RPT Limit SPK value SPK WWI %REC Low Limit High Limit RPD WWI 0/.RPD RPD Limit Qual 2,4,5-TP (Silver;) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.3993 0 0.5000 79.9 50.4 133 Sample ID: LCS-254629 Client ID: Units: mg/L Prep Date: O1/2512018 Run No: 361892 SampleType: LCS TestCode: HERBICIDES, TCLP Sw1311/8151A BatchID: 254629 Analysis Date: O1129/2018 Seq No: 7992514 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qua] 2,4,5-TP (Silvea) 0.3603 0.20 0.5000 72.1 49.1 119 2,4-D 0.4093 0.20 0.5000 81.9 50.9 129 Surr: DCAA 0.3997 0 0.5000 79.9 50.4 133 Samplc7D: 1801F45-001AYIS Client ID: Units: mg/1. Prep Date: 01/2.5/2018 Run No: 361892 SampleType: ,VIS TestCode: HERBICIDES,TCLP SW1311/8151A BatchID:254629 Analysis Date: 01/29/2018 Seq No: 7992516 Analyte Result RPT Limit SPK value SPK Ref Val O REC Low Limit High Limit RPD WWI 0/,RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.3844 0.20 0.5000 76.9 48.2 125 2.4-D 0.4881 0.20 0.5000 97.6 44.5 139 Surr: DCAA 0.4134 0 0.5000 82.7 50.4 133 Qualifinz: > Greater thin Re 11-lee < Les than Result value, B Analytedeletmdiatheassociated method blank ERL Isetow reporting limit E Estiro[ed (value ab-.q=. t Wim range) H Holding times rorprepa tim or analysis emeeded J Esli,uted value deteetud bclnw Repertipy Limit N Amlym not NELAC ccniLed R RPD outside limits due to matrix CD Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix v 0 Page 5 of 5 v PRISM LABORATORIES INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 04/30/2018 Prism Work Order: 8040569 Case Narrative 05/23/2018 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a Revised Report and supercedes the original laboratory report dated 05/18/2018. Correction made to units on PAN calculation sheet. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. i Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit PD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 1 of 16 .PRISM �� IAW.A70.M%INC. " lient Sample ID Class A Full-Servico Analytical $ Environmontal Solutions Lab Sample ID Matrix 8040569-01 Solid Samples were received in good condition at 2.0 degrees C unless otherwise noted. Sample Receipt Summary 05/23/2018 Date Sampled Prism Work Order: 8040569 Date Received 04/30/18 04/30/18 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240W - Charlotte, NC 28224-0543 Phone: 704/529.6384-Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 2 of 16 r� �L R C M I Full -Service Analytical s JEnvironmental Solutions LABORATOR Town of Mooresville/RR WWTP .ttn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 05/23/2018 Client Sample ID: Class A Prism Sample ID: 8040569-01 Prism Work Order: 8040569 Time Collected: 04/30/18 08:00 Time Submitted: 04/30/18 12:19 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 9700 mg/kg dry 1500 330 20 `Calculation 5/9/18 9:11 CLB [CALL] % Solids 97.7 % by 0.100 0.100 1 'SM2540 G 4130118 14:55 TJY P8E0002 Weight Ammonia as N 220 mg/kg dry 9.5 2.4 1 'SM4500-NH3 C 518118 14:08 BMS 138E0162 Nitrate/Nitrite as N BRL mg/kg dry 5.1 1.4 1 'SM4500-NO3 F 519118 9:11 CLB P8E0174 pH '6.4 pH Units 1 •9045D 511118 16:35 CBP P8E0035 Phosphorus -Total 12000 mgikg dry 260 37 100 'SM4500-P F 518/18 10:31 CLB PSE0084 Total Kjeldahl Nitrogen 32000 mg/kg dry 6100 1100 20 '351.2 514118 8:21 CLB PSE0071 Microbiological Parameters Fecal Coliforms BRL MPN/g dry 0.2 1 'SM9221 E 4/30/18 13:00 BMS P8E0024 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 '1311 5/8118 7:20 MMR PSE0134 TCLP Extraction Complete N/A 1 '1311 ZHE 5115/18 9:00 ANG P8E0322 TCLP Metals '^ercury BRL mg/L 0,010 0.000030 1 '7470A 5110/18 11:26 JAB P8E0192 genic BRL mg/L 0.10 0.016 1 '6010D 519/18 17:11 JAB PBE0148 Barium BRL mg/L 5.0 0.0040 1 '6010D 519/18 17:11 JAB P8E0148 Cadmium BRL mg/L 0.025 0.00075 1 '6010D 5/9/18 17:11 JAB P8E0148 Chromium BRL mg/L 0.25 0.0018 1 '601OD 519/18 17:11 JAB P8E0148 Lead BRL mg/L 0.050 0.0040 1 '6010D 519/18 17:11 JAB P8E0148 Selenium BRL mg/L 0.10 0.028 1 '6010D 519/18 17:11 JAB P8E0148 Silver BRL mg/L 0.25 0.0020 1 `6010D 5/9/18 17:11 JAB P8E0148 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00086 1 '80818 5110/18 22:14 JMV P8E0139 Dieldrin BRL mg/L 0.00050 0.000070 1 '8081B 5110/18 22:14 JMV P8E0139 Endrin BRL mg1L 0.00050 0.000075 1 '8081B 5110118 22:14 JMV P8E0139 gamma-BHC BRL mg1L 0.00050 0.000065 1 '8081B 5110118 22:14 JMV PBE0139 Heptachlor BRL mg/L 0.00050 0.000085 1 '8081 B 5/10118 22:14 JMV P8E0139 Heptachlor Epoxide BRL mg/L 0.00050 0.000065 1 '8081 B 5/10/18 22:14 JMV P8E0139 Methoxychlor BRL mg/L 0.00050 0.00020 1 '8081B 5110118 22:14 JMV P8E0139 Toxaphene BRL mg/L 0.025 0.00037 1 '8081B 5110/18 22:14 JMV P8E0139 Surrogate Recovery Control Limits Decachlorobiphenyl 221 % 13-186 SE Tetrachloro-m-xylene 164 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 '8270D 5111/18 14:32 JMV P8E0208 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 '8270D 5/11118 14:32 JMV PBE0208 ,-Dinitrotoluene BRL mg/L 0,050 0.0014 1 '8270D 5/11/18 14:32 JMV P8E0208 2-Methylphenol BRL mg/L 0.050 0.0018 1 '8270D 5/11/18 14:32 JMV P8E0208 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240W - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041626-0409 Page 3 Of 16 n Laboratory Report I n n I Full -Service Analytical & ' V' Environmental Solutions 05/23/2018 ®: ueowaonies v+a Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A kttn: Whitney Munroe Prism Sample ID: 8040569-01 P. O. Box 878 Prism Work Order: 8040569 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 04/30/18 08:00 Time Submitted: 04/30/18 12:19 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methylphenol BRL mg/L 0.050 0.0016 1 '8270D 5/11/18 14:32 JMV P8E0208 Hexachlorobenzene BRL mg/L 0.060 0.0013 1 '82701) 5111118 14:32 JMV P8E0208 Hexachlorobutadiene BRL mg1L 0.050 0.0021 1 '8270D 5/11/18 14:32 JMV P8E0208 Hexachloroethane BRL mg/L 0.050 0.0017 1 '8270D 5/11/18 14:32 JMV PBE0208 Nitrobenzene BRL mg1L 0.050 0.0026 1 '8270D 5/11118 14:32 JMV P8E0208 Pentachlorophenol BRL mg/L 0.26 0.0012 1 '82701) 5/11118 14:32 JMV P8E0208 Pyridine BRL mg/L 0.25 0.0010 1 '82701) 5111/18 14:32 JMV P8E0208 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 29 % 43-140 SE 2-Fluorobiphenyl 29 % 44-119 SE 2-Fluorophenol 38 % 19-119 Nitrobenzene-d5 30 % 44-120 SE Phenol-d5 26 % 11-52 Terphenyl-d14 32 % 50-134 SE TCLP Volatile Organic Compounds by GCIMS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 '826013 5/16/18 15:07 KDM P8E0333 1-Dichloroethane BRL mg/L 0.025 0.00066 1 '8260B 5/16/18 15:07 KDM PBE0333 „4-Dichlorobenzene BRL mg1L 0.38 0.00050 1 '82608 5/16/18 15:07 KDM PBE0333 Benzene BRL mg/L 0.025 0.00048 1 '826013 5/16/18 15:07 KDM PBE0333 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 '8260B 5116/18 15:07 KDM P8E0333 Chlombenzene BRL mg/L 5.0 0.00062 1 '8260B 5116/18 15:07 KDM P8E0333 Chloroform BRL mg/L 0.30 0.00076 1 '8260B 5/16/18 15:07 KDM P8E0333 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 '8260B 5116/18 15:07 KDM P8E0333 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 '826013 5116/18 15:07 KDM P8E0333 Trichlorcethylene BRL mg/L 0.025 0.00078 1 '82608 5116/18 15:07 KDM PBE0333 Vinyl chloride BRL mg/L 0.020 0.00097 1 '8260B 5116118 15:07 KDM P8E0333 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 95 % 77-123 Total Metals Aluminum 15000 mg/kg dry 61 7.6 10 '6010D 514/18 14:50 JAB P8E0073 Mercury BRL mg/kg dry 0.30 0.029 15 '7471 B 517118 12:56 JAB P8E0114 BAR Soil Preparation Complete g 1 '2-78-054 5/4/18 11:00 MMR P8E0089 SAR Percent Moisture Complete % by 0.100 0.100 1 '2-78-054 517/18 10:40 MMR P8E0131 Weight Arsenic 2.0 mglkg dry 0.51 0.031 1 '60101) 5/3/18 14:59 JAB P8E0073 Sodium Absorption Ratio 2.3 [blank] 0.30 0.016 1 '2-78-054 5/8I18 9:48 JAB PBED104 Cadmium 0.42 mg/kg dry 0.25 0.0068 1 '60100 613/18 14:69 JAB PBE0073 'Icium 10000 mg/kg dry 10 0.23 1 '6010D 513/18 14:59 JAB 138E0073 -alcium, SAR 220 mg/L 1.D 0.10 10 °6010D 518118 9:48 JAB P8E0104 Chromium 14 mglkg dry 0.25 0.043 1 '6010D 5/3118 14:69 JAB 138E0073 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc, 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.CSQ Phone: 7041629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041625-0409 Page 4 of 16 p R I S n n I Full -Service A Soluli l 'v' Environmontal Solutions LAGOMTd X& .a Town of Mooresville/RR WWTP >ttn: Whitney Munroe P. O, Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 05/23/2018 Client Sample ID: Class A Prism Sample ID: 8040569-01 Prism Work Order: 8040669 Time Collected: 04/30/18 08:00 Time Submitted: 04/30/18 12:19 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Copper 180 mg/kg dry 5.1 0.46 10 •6010D 514118 14:50 JAB 138E0073 Lead 7.5 mglkg dry 0.25 0.047 1 `6010D 5/3118 14:59 JAB 138E0073 Magnesium 2200 mg/kg dry 2.5 0.24 1 `6010D 513/18 14:59 JAB 138ED073 Magnesium, SAR 130 mg/L 1.0 0.086 10 160101) 5/8/18 9:48 JAB P8E0104 Molybdenum 7.1 mglkg dry 0.51 0.015 1 "6010D 513118 14:59 JAB PSE0073 Nickel 10 mg/kg dry 0.51 0.018 1 '6010D 513118 14:59 JAB PBE0073 Potassium 2900 mglkg dry 13 0.46 1 '6010D 513118 14:69 JAB P8E0073 Selenium 3.2 mglkg dry 0.51 0.12 1 '6010D 6018 14:59 JAB PBE0073 Sodium 800 mglkg dry 15 0.60 1 '6010D 5/3/18 14:59 JAB PBE0073 Sodium, SAR 170 mg/L 5.0 0.18 10 '6010D 518/18 9:48 JAB POE0104 Zinc 320 mg/kg dry 25 0.91 10 '6010D 614118 14:50 JAB PBE0073 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc, 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number:1-800152M364 - Fax: 7041525-0409 Page 5 of 16 Sample Extraction Data Prep Method: 351.2 1 ab Number Batch Initial Final DateMme .40569-01 PBE0071 0.05 g 25 mL 05/03/18 9:00 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 8040569-01 P8E0162 1.08 g 50 mL 05/07/18 10:50 Prep Method: SM4500-PBS Lab Number Batch Initial Final DateMme 8040569-01 P8E0084 1 g 50 mL 0510811E 6:15 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final DateMme 8040569-01 P8E0002 30 g 30 g 04/30/18 14:55 Prep Method: 1311 Lab Number Batch Initial Final DateMme 8040569-01 P8E0322 25 mL 500 mL 05/14/18 14:30 804056MI P8E0134 100 g 2000 mL 05/07/18 14:12 Prep Method: 3010A Lab Number Batch Initial Final Datelrme 8040669-01 P8E0148 10 mL 50 mL 05/08/18 8:55 :p Method: 7470A Lab Number Batch Initial Final Date/Time 8040569-01 P8E0192 20 mL 30 mL 05/09118 14:00 Prep Method: 3510C GC Lab Number Batch Initial Final Date/rime 8040569-01 P8E0139 200 mL 10 mL 05/08/18 8:45 Prep Method: 3510C MS Lab Number Batch Initial Final DatelTme 8040569-01 PBE0208 200 mL 1 mL 05/10/18 8:37 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 8040569-01 P8E0333 1 mL 10 mL 05/15/18 14:04 Prep Method: 3010A Lab Number Batch Initial Final Datefrime 8040569-01 P8E0104 50 mL 50 mL 05/04/18 11:00 8040569-01 P8E0104 50 mL 50 mL 05/04/18 11:00 Prep Method: 3050E . ab Number Batch Initial Final Datel'rime ..040569-01 P8E0073 2.01 g 50 mL 05/03/18 8:45 804056MI P8E0073 2.01 g 50 mL 05/03/18 8:45 This report should not be reproduced, except in Its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240W - Charlotte, NC 28224-0543 Phone: 704/52M364 - Toll Free Number: 1-8001629-6364 - Fax: 7041526-0409 Page 6 of 16 Sample Extraction Data Prep Method: 7471B Lab Number Batch Initial Final Datelrme 40569-01 PBE0114 0.61 g 50 mL 05/07/18 8:30 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final DatelTime 8040569-01 P8E0089 250 g 250 g 05/03/18 11:00 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 8040569-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Spdngbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: l$00/529-8364- Fax: 7041525-0409 Page 7 of 16 � �j I Full -Service R i SService Analytical g�, Environmental Solutions LABORATORIES, ING 449 Springbrook Road • Charlotte, NC 28217 Phone 7041529-6364 • Fax: 704/52"409 Client Company Name: � 10(uV& Report To/Contact Name: Mlll n&-- Reporting Address: P. 0. ooruiht- f✓ "115" CHAIN OF CUSTODY RECORD PAGE.." OF,��IUOTEii 7�D ENSURE PR ER BILLING. Project Name: Qj"s 0 R 6 e. Short Hold Analysis: a (No) UST Project: (Yes N •Please ATTACH any project specific reporting (QC I EVE611 III 1V) provisions and/or QC Requirements Invoice To: Tom- OF moond b kk, Address: c USE ONLY vEy NO WA Samples INTACT upon arrival? /� _ Received ON WET ICE? f DO RROPER,PRESERVATIVES indicated? T 0 Received WITHIN HOLDINGTI1uIES? tI ctf CUSTODY SEALS INTACT? � VOLATILES reed W/OUT HEADSPACE? PROPER'CONTAIT�S.uj ed? TEMP: Therm ID _ Observed: Corri -0 °C Phone:104-64o S-46 Fax (Yes) (No):` Purchase Order No./Billing Reference Email Address: "a TO BE FILLED IN BY CLIENTISAMPLING PERSONNEL Requested Due Date ❑ 1 Day ❑ 2 eys ❑ 3 Days Cl 4 Days ❑ 5 Days Certification: NELAC DoD FL NC EDD Type: PDF Excel Other "Working Days" ❑ 6-9 Days�Slandard 10 days ❑ Pre WorkMust Be SC OTHER NIA Site Location Name: Samples received after 14:00 will a moeessed next business day. Water Chlorinated: YES �NO" Site Location Physical Address' Turnaround time Is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES_ NO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) TIME I CLIENT DATE `COLLECTED ' SAMPLE DESCRIPTION COLLECTED MILITARY MATRIX (SOIL, WATER OR SAMPLE CONTAINER j PRESERVA- *TYPE TIVES ANALYSIS REQUESTED `�6?/'3�yC�' REMARKS PRISM I NO. SIZE ! DLAN80 ID i I HOURS SLUDGE) SEE BELOW I DO P I .601 i I I l 1n 1 f i 1 i ' � i� i► I �� I L 1 , II I I I i 7 I ; Sampler's Signature i`�e�cirv--� Sampled By (Print Name) �cr -� n kfe• Affiliation Upon relinquishing, this Chain o stody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be PRISM USE • NLY submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. R inshad By. (Signature) Recery: (Slanaturo) Oap. MilitaryiHourN Additional Comments: Site Arrival Time: RBllnq ,-he By (Signatu By. (Signature) to 1 VVi V O It Site Site Departure Time: Relfn ed S . (Signature) Received.Wrism Laboratories By. D t �? rYt�il YID Feld Tech Fee: Ob Mileage: tvl Ihod or Ipmont• OTE, ALL SAM PLE COOLERS SFI ULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. IfOC G No. SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. �1 O Fad Et O UPS ❑ HanddeliverBd dsm Field Service ❑ Other + NPDES; UST: I GROUNDWATER: j DRINKING VYATER: f_ SAID WASTE: j RCRA: CERCLA LANDFILL ;OTHER: ❑NC❑SC E, ❑SC❑NC ❑SC ❑NC ❑SC i)qNC ❑SC ! ❑NCr1SC: [INC ❑SC, ❑NC ❑SC ❑NC ❑SC ❑ I ( ❑ I ❑ _. _ ❑ ❑_ ❑ ❑ ❑ A — A—— n — n1..-.- r — l•1...... 0 — DI....47... TI — T 11— 1 ;—A d•. ./nA — %/ Inf;ln r%m *.— Ano1-1. 17— W ri Qn... PRISM Full -Service Analytical & Environmental Solutions 449 Springbrook Road - Charlotte, NC 28217 Phone 704/529-6364 • Fax: 704/525-0409 Client Company Name: t7WtA. 6� OPNiP.�,tw�� Report To/Contact Name: % tNr► �'� Reporting Address: -O • g _ stu __ g. p n, � % dA _ _ CHAIN OF CUSTODY RECORD PAGE � OF O— QUOTE 0 TO ENSURE PR ER BILLING: Project Name: doze, Short Hold Analysis: � (No) UST Project: es) O *Please ATTACH any pro ect specific reporting (QC LEVE01 III ) provisions and)or QC Requirements InvoiceTo; rot", --op- AA&0l�dN�� Address: Y�6 NO N/A CO Samples INTACT upon arrival?' — Received ON WET ICE? / PROPER•PRESERVATNES indicated? T Reoeived WITHIN HOLDING -TIMES? a CUSTODY. SEALS INTACT.? �_ d •VOLATIL'ES redd,WlO,UT REAOSPACE? PROPER.CONTANERS used? _. �� TEMP: Thttnn ID: t r� Obse'rvedZ °C / Corr. L-- °C r-none:-t�-t—s-ZX w Fa xtres)tivo): Purchase Order No.Billing Reference Email Address: VJT%U% faa-F OQ!'*++LW - Ac. mA TO BE FILLED 1N BY CLIENUSAMPLING PERSONNEL Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days EDD Type: PDF ✓Excel Other "Working Days" ❑ 6-9 Day>tStandard 10 days ❑ RushWork Must Be Certification: NELAC DOD FL NC Site Location Name: Samples received after 14:00 will be processed next business day. Site OTHER NIA Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NOV (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES NO_ i TIME MATRIX CLIENT DATE i COLLECTED (SOIL, { SAMPLE CONTAINER —. __ — PRESERVA- _4p ANALYSIS REQUESTED .' .. Q!' REMARKS PRISM LAB SAMPLE DESCRIPTION COLLECTED ; MILITARY WATER OR { HOURS SLUDGE) *TYpE SEE BELOW ; NO. ; SIZE TNES QJ. !' Q 0 ID NO. B,�o,,, t I ,. i `l Sampler's Signature �� I Sampled By (Print Name) %--'n �'� �F r,C, C-C v\ Affiliation TOt+w�-i .o o• Upon relinquishing, this Chain of OZIstody is your authorisation for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been InItIa4ed.PRISM USE ONLY Jlqd, ea e : (s�gnemrel Rece : (Si, ature) at � 3��:�' ltaryrHo Additional Comments: SiteAnivafTmae: Rellnqukhed By: (51 1 oeiv y. ignature a ' Site Departure Time: Resin s eedd y: tSignatuie) Received F%P.T=m Ulboralortes By T Dat �. � 1I TT al � I �. A Field Tech Feu: Mileage: 'Mfithud o ipment-- NOTE: ALL SAMPLE COOLERA SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. UQG Group No. SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. j� f Ilia., ❑ tQL�, ��j Lt ❑ Fed Ex UPS O Hand delivered Prism Field Service - Olher 1 NF'Ut.7: UST: GKVUNDWAIEK: I UKINKING WATER: S I WASTE: RCRA: CERCLA I LANDFILL OTHER: I ❑ NC ElSCI ❑ Mr, ❑ SC ❑ NC ❑ SC El NC El SC NC ❑ SC ! ❑ NC Cl SC ❑ NC Cl SC i ❑ NC ❑ SC. [INC ❑ SC *rnNTAwFR i .. F CnnFS• A = Amhar t : = (:IPar r;= (;lacc P = Plastic• n = TPtlnn-i inwd (ni. _ 0A = Vnlatile nroanit•_S Annivsis (Zero Head Soacel ')RIGINAL Main Office: 449 Springbrook Road PR Full Sorvlrt, Analytical and P.O. Box 240543 I ! {f � %� t j 1 EnvironrnoWal Solutions Charlotte, NC 28224-0543 - I1;.onaTO I Phone:704/529-6364 118001629-6364 Fax:704/525-0409 www.prismiabs.com Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Numberl 8040569-01 Sample Namel Class A Nam /L Cam /L M m /L Na: Sodium (mg/L) Equivalent weight: 23 1 173 223 130 Ca: Calcium (mg/L) Equivalent weight: 20 Mg : Magnesium (mg/L) Equivalent weight 12 Na ME Ca (ME) I Mg (ME] 7.52 11.15 10.83 Milli Equivalent (ME) = mg/L / Equivalent weight SAR= Na Milli Equivaleni/(0.5 X (Ca Milli Equivalent+ Mg Milli equivalent)]0.5 power SAR = 2.27 (From mg/L entered above) '7 Calculated By: � 31� (r )�-19co Page 10 of 16 Main Office: Full Sorvico Analytical and 449 Springbrook Road Envlronmunlal Solutiono P.O. Box 240643 INC Charlotte, NC 28224-0543 Phone: 7041529.6364 118001529-6364 Fax: 7041525-0409 www.prism[abs.com Plant Available Nitrogen Sample Numberl 8040569-01 1 Sample Name Class A Mineralization Rate TKN NH3 NOX mg/kci mp/kta mglkq 0.3 32200 223 2.3 PAN Surface 9,707 mg/kg MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mg/kg Page 11 of 16 ACCESS ANALYTJCAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 8040569 LABORATORY REPORT NUMBER 1805073 DATE May 07, 2018 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL•E87582, NELAP certified laboratory # E87582 AIIIA-LAP,LLC Laboratory 1D:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SCINC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page Page 12 of 16 Full - ,I I O J I Envir o men Analytical s _ J v � f l=nvironineninl Solutions .. a: '•`'` innonntonMs,uic. ��, o�SUBCONTRACT ORDER Cerii(i o NELAC= USACE Prism Laboratories, Inc. C SC_ Other 8040569 N SENDI G LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. P. O. Box 240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax:704-525-0409 Analytical Environmental Services, Inc. 3080 Presidential Parkway Atlanta, GA 30340 Phone :(770) 457-8177 Fax: NA Project Manager: Tern W. Cole _ _ - --• - Analysis Due Expires Laboratory ID Comments C ted:04/30/18 08:00 Sample 1D: 8040569-01 Solid Sam P - Herbicides TCLP (Sub) 05/07/18 08:00 Containers Supplied: I II Id d64e, (l�s r:,-1 f) Rcicased 13)• Dnie Reccivcd By U ne Page 1 of 1 Page Page 13 of 16 Analytical Environmental Services, Inc Date: 7-May-18 Client: Prism Laboratories Client Sample ID: Class A Lab Order 1805073 Tag Number: 8040569-01 Project Name: 8040569 Collection Date: 4/30/2018 8:00:00 AM Lab ID: 1805073-OOIA Matrix: Solid Analyses y Result Qual MDL Reporting Limit Units BatchID DT Date Analyzed Analyst HERBICIDES, TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.030 0.20 ing/L 260118 1 05/04/2018 14:38 UH 2,4-D BRL 0.051 0.20 mg/L 260118 1 05/04/201814:38 UH Suit: DCAA 63.5 0 504-133 %REC 260118 1 05/00201814:38 UH Qnalifiers: • Value exceeds maximum conlominaw level E Esungmd value above quonntanon rmge BRL Not Detected at MDL 5 Spike Recovery outside limits due to niamx H Holding times for pmparalion or analysts "ctedcd > Greater thon Result value N Anolyie not NELAC cortirwil 1 Eslnnated value dotwtcd below Reporting Limit B An tlyle dclecicd in dte assoeimed method binnL• < Less than Result value Page P Page 14 of 16 (:r : ) AXA(Xl'Itat. r L''\'VIk0\.1trx-r I. Ai:S SIZILVICES. t.NC. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. AES Work Order Number: 1805073 2. Carrier: FedEx 0 UPS ❑ USPS[, Client❑ Courier[] Othei Yes No N/A 3. 4. S. 6. 7. 8. 9. 10. 11. 12. Clear Save as Shipping container/cooler received in good condition? a damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? ;o Custody seals intact on shipping container? e Temperature blanks present? • 77 Cooler temperature(s) within limits of 0-9'C? [See item 13 and 14 for temperature recordings.] O o Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (CDC) present? o Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? o Were all samples received within holding time? o it TAT marked on the CDC? • If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13 Cooler I Temperature 0.4 oC Cooler 2 Temperature oC Cooler 3 Temperature 14. Cooler 5 Temperature oC Cooler 6 Temperature oC Cooler 7 Temperature 15. Comments: 16. 17 18. 19. 20. 21. 22. 23. 24. 25 26. V.. Ain MIA oC Cooler 4 Temperature DC oC Cooler 8 Temperature oC I certify that I have completed sections 1-15 (dated initials). AJJ 5/1/18 Were sample containers intact upon receipt? p Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the CDC? .°® O ® incomplete info ❑ illegible [] no label ❑ other ❑ Are analyses requested indicated on the CDC? • Were all of the samples listed on the CDC received? ® Q sam les received but not listed on CDC P samples listed on CDC not received _ Was the sample collection date/time noted? o Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? a Were VOA samples received without headspace (<1/4" bubble)? i Were trip blanks submitted? listed an CDC ❑ not listed on CDC ❑ 27. Comments: This section only applies to samples where pH can be checked at Sample Receipt. I certify that 1 have completed sections 16-27 (dated initials). PJM 5/02/18 28. Have containers needing chemical preservation been checked?' 29.ContEpHadjustedat rs meet preservation guidelines? It 30. Was Sample Receipt? u D Lu CD ' Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & GreasefrPH. CT! 1 certify that I have completed sections 28-30 (dated initials). Checklist 6.9.17 Rev 2 rn Locked PJM 5/02/18 Page 4 of 5 Analytical Environmental Services, Inc Date: 7-May-18 Client; Prism Laboratories ANALYTICAL C SUMMARY REPORT' Project Name: 80405G9 W'orkorder: 1805073 BatchID: 260118 Sample iD: MB-260118 ClientlD: Units; mg/L Prep Date: 05/0312018 Run No: 369542 SampleType: MBLK TestCode. HERBICIDES,TCLP SW131118151A Batch)[1): 260118 Analysis Date: 05/04/2018 Seq No: 8186724 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual r tsNvex) BKL 0.20 2,4-D BRL 0.20 Sun: DCAA 0.3280 0 0.5000 65.6 504 133 Sample 11): LCS-260118 Client ID: Units: mg/L Prep Date: 05/03/2018 Run No: 369542 SampleType: LCS TestCode: HERBICIDES,TCLP SW131118151A BatchID:260118 Analysis Date: 05/04/2018 Seq No: 8186725 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual L,4,n-1 r (Jllvex) 03468 0.20 0.5000 69.4 49.1 119 2.4-D 03771 0.20 0.5000 754 50.9 129 Surr: DCAA 03366 0 0.5000 67.3 50.4 133 Sample ID: 1804R35-OOIBMS Client 1D: Units: mg(L, Prep Date: 05/03/2018 Run No: 369542 SampleType: NiS TestCode: HERBICIDES,TCLP Sw131118151A BatchID: 260118 Analysis Date: 05/04/2018 Seq No: 8186727 Analyte Resull RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual ,.4,3-1 r (snvex) 02996 0.20 0.5000 59.9 48.2 125 2.4-D 03250 0.20 0.5000 65.0 445 138 Surr: DCAA 0 2927 0 0.5000 58.5 50.4 133 cncamr uan rtezwr value BRL Below reporting limit J EslinWed oalue deleded below Reporting Lttnit RptLtm RepuumgLimit c Less than Result value E Estimated (talue above quantization range) N Analyte, not NELAC ccnirred S Spike Recovery ouistde limits due to matrix B Analyze detected in the associated mothod blank H Holding limes for preparation or analysis exceeded R RPD outside limits due to matrix Page 5 of 5 s/✓ 'PRISM PRI I Full -Service Analytical & Environmental Solutions tABMTCFIESS INC. Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cart No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 07/16/2018 Prism Work Order: 8070199 Case Narrative 08/03/2018 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a Revised Report and supercedes the original laboratory report dated 08/01/2018. Fecal coliform result has been recalculated and corrected. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 1 Ox the MB. MC Sample concentration too high for recovery evaluation. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlofte, NC 28224-0543 Phone: 7041529.6364 - Toll Free Number. 1-8001529-6364 - Fax: 704152"409 Page 1 of 16 iPRISM J R I S M 1 2 lService Analytical r � Environmental solutions Sample Receipt Summary 08/03/2018 Prism Work Order: 8070199 Client Sample ID Lab Sample ID Matrix Daterrime Sampled Date/Time Received Class A 8070199-01 Solid 07/16/18 6:35 07/16/18 11:10 Samples were received in good condition at 2.4 degrees C unless otherwise noted. This report should not be reproduced, except In its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629.6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 2 of 16 PRISM r I Full -Service Analytical s ! Environmental tal Solutions +�-•.. -.. V30M:CR�F .i T Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 08103/2018 Client Sample ID: Class A Prism Sample ID: 8070199-01 Prism Work Order: 8070199 Time Collected: 07/16/18 06:35 Time Submitted: 07/16/18 11:10 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Datefrime ID General Chemistry Parameters Plant Available Nitrogen 3700 mglkg dry 390 85 5 *Calculation 7127118 20.10 CLB [CALC] Solids 97.0 % by 0.100 0.100 1 *SM2540 G 7/17/18 15:40 BJC P8G0248 Weight Ammonia as N 1700 mglkg dry 10 2.5 1 *SM4500-NH3 C 7127118 20:10 BMS P8G0433 Nitrate/Nitrite as N BRL mg/kg dry 5.2 1.4 1 *SM4500-NO3 F 7/17/18 7:51 CLB P8G0218 pH 6.3 pH Units 1 *9045D 7/16/18 16:17 CBP PBG0228 Phosphorus -Total 14000 mg/kg dry 260 57 100 *SM4500-P F 7119/18 8:27 CLB P8G0221 Total Kleldahl Nitrogen 11000 mglkg dry 1300 280 5 *351.2 7/18118 10:28 CLB P8130230 Microbiological Parameters Fecal Coliforms 2 MPN/g dry 0.2 1 *SM9221 E 7116/18 13:64 BMS PBG0280 TCLP Extraction by EPA 1311 TCLP Extraction TCLP Extraction TCLP Metals Complete Complete N/A NIA 1 1 *1311 *1311 ZHE 7/20/18 7:35 7130118 9:39 MMR KDM P8G0281 P8G0465 Mercury BRL mg/L 0.010 0.000030 1 *7470A 7120118 15:16 JAB P8G0301 Arsenic BRL mg/L 0.10 0.016 1 *6010D 7/23118 14:21 JAB P8G0307 Barium BRL mg/L 5.0 0,0040 1 *6010D 7/23/18 14:21 JAB P8G0307 Cadmium BRL mg/L 0.025 0.00075 1 *6010D 7123118 14:21 JAB PBG0307 Chromium BRL mg/L 0.25 0.0018 1 *6010D 7/23/18 14:21 JAB PBG0307 Lead BRL mg/L 0.050 0.0040 1 *6010D 7/23/18 14:21 JAB P8G0307 Selenium BRL mg/L 0.10 0.028 1 *6010D 7/23118 14:21 JAB P8G0307 Silver BRL mg/L 0.25 0.0020 1 *6010D 7/23/18 14:21 JAB P8G0307 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00017 1 *8081B 7/30118 13:11 JMV P8G0414 Dieldrin BRL mg/L 0.00050 0.000014 1 *8081B 7/30118 13:11 JMV P8130414 Endrin BRL mg/L 0.00050 0.000016 1 *8081B 7/30118 13:11 JMV P8130414 gamma-BHC BRL mg/L 0.00050 0.000013 1 *8081B 7/30/18 13:11 JMV P8G0414 Heptachlor BRL mg/L 0.00050 0.000017 1 *8081B 7/30/18 13:11 JMV P8G0414 Heptachlor Epoxide BRL mg/L 0.00050 0.000013 1 *8081B 7130118 13:11 JMV P8G0414 Methoxychlor BRL mg/L 0.00050 0.000039 1 *8081B 7/30/18 13:11 JMV P8130414 Toxaphene BRL mg/L 0.025 0.000074 1 *80816 7130118 13:11 JMV P8130414 Surrogate Recovery Control Limits Decachlorobiphenyl 18 % 13-186 Tetrachloro-m-xylene 5 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 *8270D 7126118 11:17 JMV P8G0380 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 7126118 11:17 JMV P8G0380 2,4-Dinitrotoluene BRL mg/L 0.050 0,0014 1 *8270D 7126118 11:17 JMV P8G0380 2-Methyiphenol BRL mg/L 0.050 0.0018 1 *82700 7/26118 11:17 JMV P8130380 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629.6364-Toll Free Number: 1-8001529-6364 - Fax: 704/625-0409 Page 3 of 16 P R I S� �I{ I Full -Service Analytical s � �,i/ � Environmental Solutions . „aE:we Laboratory Report 08/03/2018 Town of Mooresville/RR WWTP Attn: Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Client Sample ID: Class A Prism Sample ID: 8070199-01 Prism Work Order: 8070199 Time Collected: 07/16/18 06:35 Time Submitted: 07/16/18 11:10 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methylphenoi BRL mg/L 0.050 0.0015 1 '8270D 7126118 11:17 JMV PBG0380 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 "827013 7/26/18 11:17 JMV P8G0380 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 `8270D 7/26118 11:17 JMV P8G0380 Hexachloroethene BRL mg/L 0.050 0.0017 1 '8270D 7126/1811:17 JMV P8G0380 Nitrobenzene BRL mg/L 0.050 0.0026 1 '8270D 7/26118 11:17 JMV P8G03BO Pentachlorophenol BRL mg/L 0.25 0.0012 1 '8270D 7126118 11:17 JMV P8G03B0 Pyridine BRL mg/L 0.25 0.0010 1 '8270D 7/26118 11:17 JMV P8G0380 Surrogate Recovery Control Limits 2,4,6-Tdbromophenol 34 % 43-140 SE 2-Fluoroblphenyl 28 % 44-119 SE 2-Fluorophenol 28 % 19-119 Nitrobenzene-d5 32 % 44-120 SE Phenol-d5 26 % 11-52 Terphenyl-d14 34 % 50-134 SE TCLP Volatile Organic Compounds by GClMS 1,1-Dichloroethylene BRL mg/L 0.035 0.000083 1 `826013 7/27118 18:12 KDM P8G0468 1,2-Dichloroethane BRL mg/L 0.025 0.000066 1 '8260B 7127118 18:12 KDM P8G0468 1,4-Dichlorobenzene BRL mg/L 0.38 0.000050 1 `8260B 7127118 18:12 KDM P8G0468 Benzene BRL mg/L 0,025 0.000048 1 `826013 7/27118 18:12 KDM P8G0468 Carbon Tetrachloride BRL mg/L 0.025 0.00011 1 '8260B 7127/18 18:12 KDM P8G0468 Chlorobenzene BRL mg/L 5.0 0.000062 1 '8260B 7/27/1 a 18:12 KDM P8G0468 Chloroform BRL mg/L 0.30 0.000076 1 `6260B 7127118 18:12 KDM P8G0468 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.00024 1 `82608 7127118 18:12 KDM P8G0468 Tetrachloroethylene BRL mg/L 0.035 0.000098 1 '826013 7/27118 18:12 KDM P8GO468 Trichloroethylene BRL mg/L 0.025 0.000078 1 `8260B 7/27118 18:12 KDM P8G0468 Vinyl chloride BRL mg/L 0.010 0.000097 1 '8260B 7/27118 18:12 KDM P8G0468 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 99 % 77-123 Total Metals Aluminum 20000 mg/kg dry 52 7.6 10 •6010D 7/24/18 12:31 JAB PSG0303 Mercury 0.63 mglkgdry 0.31 0.029 15 •7471B 7/18118 14:13 JAB P8G0245 SAR Soil Preparation Complete g 1 '2-78-054 7/24/18 13:40 MMR P8G0362 SAR Percent Moisture 81.1 % by 0.100 01100 1 •2-78.054 7125118 13:45 MMR P8G0393 Weight Arsenic 2.0 mg/kg dry 0.52 0.031 1 •6010D 7/23118 12:35 JAB P8G0303 Sodium Absorption Ratio 1.6 [blank] 0.30 0.016 1 `2-78-054 7126118 0:37 JAB P8G0369 Cadmium 0.65 mg/kg dry 0.26 0.0069 1 •60101) 7123118 12:35 JAB P8G0303 Calcium 25000 mglkg dry 100 2.4 10 •6010D 7124118 12:31 JAB PBG0303 Calcium, SAR 260 B mg/L 0.10 0.010 1 '6010D 7126118 0:37 JAB PBG0369 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364-Toll Free Number: 1.8001529-6364- Fax: 7041525-0409 Page 4 of 16 Fu31-Service Analytical & Environmental Solution❑ �.. 'U RATORIEa MG Laboratory Report 08/03/2018 Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Client Sample ID: Class A Prism Sample ID: 8070199-01 Prism Work Order: 8070199 Time Collected: 07/16/18 06:35 .Time Submitted: 07/16/18 11:10 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Datelrime ID Chromium 24 mg/kg dry 0.26 0.043 1 '6010D 7/23118 12:35 JAB PBG0303 Copper 330 mglkg dry 5.2 0.47 10 •6010D 7124118 12:31 JAB PSG0303 Lead 14 mglkg dry 0.26 0.048 1 `6010D 7/23118 12:35 JAB PBG0303 Magnesium 2600 mglkg dry 2.6 0.24 1 "60101) 7123118 12:35 JAB PSG0303 Magnesium, SAR 76 mg/L 0.10 0.0086 1 "6010D 7126118 0:37 JAB PBG0369 Molybdenum 8.5 mg/kg dry 0.52 0.015 1 *6010D 7123/18 12:35 JAB P8G0303 Nickel 16 mglkg dry 0.52 0.019 1 `6010D 7123118 12:36 JAB POG0303 Potassium 3000 mglkg dry 13 0.46 1 '60101) 7123118 12:35 JAB P8G0303 Selenium BRL mg/kg dry 5.2 1.2 10 '6010D 7/24/18 12:31 JAB PBG0303 Sodium 850 mglkg dry 15 0.61 1 '6010D 7123118 12:35 JAB PBG0303 Sodium, SAR 110 B mg1L 0.50 0.018 1 •6010D 7126118 0:37 JAB PSG0369 Zinc 620 mglkg dry 26 0.92 10 '6010D 7124/18 12:31 JAB P8G0303 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 -Toll Free Number: 1-8001529-6364 - Fax: 70N625-0409 Page 5 of 16 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final DatelTime 8070199-01 P8G0230 US g 25 mL 07/17/18 9:25 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 8070199-01 P8G0433 1.02 g 50 mL 07/26/18 13:00 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 8070199-01 P8G0221 1 g 50 mL 07/18/18 11:00 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 8070190-01 P8G0248 30 g 30 g 07/17/18 15:40 Prep Method: 1311 Lab Number Batch Initial Final Daterrime 8070199-01 P8G0281 100 g 2000 mL 07/19/18 14:15 8070199-01 P8G0465 25 g 500 mL 07/26/18 8:34 Prep Method. 3010A Lab Number Batch Initial Final Date/Time 8070199-01 P8G0307 10 mL 50 mL 07/20/18 9:55 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 8070199-01 PBG0301 20 mL 30 mL 07/20/18 9:50 I' Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 8070199-01 P8G0414 1000 mL 10 mL 07/26/18 9:48 Prep Method: 3610C MS Lab Number Batch Initial Final Date/Time 8070199-01 P8G0380 200 mL 1 mL 07/25/18 9:27 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 8070199-01 P8G0468 10 mL 10 mL 07/27/18 8:41 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 807019MI 08G0369 50 mL 50 mL 07/24118 13.40 8070199-01 PBG0369 50 mL 50 mL 07/24/18 13:40 8070199-01 PSG0369 50 mL 50 mL 07/24/18 13:40 Prep Method: 30500 Lab Number Batch Initial Final Datemme 8070199-01 PBG0303 2 g 50 mL 07/20/18 9:00 This report should not be reproduced, except in its entirely, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 704/529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041525-0409 Page 6 of i 6 Sample Extraction Data Prep Method: 3050E Lab Number Batch Initial Final Daterrime 8070199-01 P8G0303 2 g 50 mL 07/20/18 9:00 Prep Method: 7471 B Lab Number Batch Initial Final Daternme 8070199-01 PBG0245 0.6 g 50 mL 07/18/18 9:05 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/rime 8070199-01 P8G0362 260 g 250 g 07/23/18 13:40 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 8070199.01 Herbicides TCLP (Sub) This report should not be reproduced, except In Its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 7041529-6364 - Toll Free Number: 1-8001629.6364 - Fax: 7041525.0409 Page 7 of 18 CHAIN OF CUSTODY RECORD /PRISM I Full -Service Analyticel & i NO WA � Environmental SolutionC PAGE OF 07% QUOTE N TO ENSURE PROP BILLINGt r} Samp:us 14ITACT upon, envoi? r »- 4.9 Springbrook Road • Charlotte, NC 28217 Project Name: 1 Recal%vd ON WET ICE? , �. 00 Phone 7041525-6364 • Fax: 7041525,0408 Short Hold Analysis: OP (No) UST Project: (Yes)-" PROPER FRESERVAVVES ins ,.alcd7 N Client Company Name: t3ia+bl aGiil�DMl2du - 'Please ATTACH any project specific reporting (QC LEVER III IV) Received Wrrl-IIN HOLDl14 T hiES? provisions andlor QC Requirements CUSTODY SEAI,S I`dTACT Report TolContaCt Name: rb-P, Invoice To: TOVA� or AowxAat VOLATILES wc'o IA1 OUT HEADSPACE� Reporting A t�.a. Address: PROPER 06W> `1 �i ' %� TEMP. Them- Phone.�- WO-XAC(p Fax (Yes) (No): Purchase Order No.lBilling Reference TO BE FILLED IN BY CLIEN7/SAR�PLIiVG PERSONNEL Email Address: Wvs,LrXI fa1CI�+�Y►�oCtite aiC . �$1/ Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days Q 5 Days EDO Type: PDF � Excel _Other �— 'Working n Rush work Must Be Certification: NELAC DoD FL NC Days" 6-9 D aysiandard 10 days ❑ Pre -Approved Sc OTHER NIA Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address* Turnaround time Is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ 140� (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BYPRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES teo NO_ TIME ( MATRIX SAMPLE CONTAINER ANALYSIS}1EST6of CLIENT DATE COLLECTED (SOIL, PRESERVA- +�+�� PRISM SAMPLE DESCRIPTION COLLECTED MILITARY j WATER OR *TYPE rnE5 I` , ! REMARKS LAB HOURS SLUDGE) SEE 13ELOW NO. I SIZE y,,y �.� O�j�®'� ID NO. �L `'"''�j'�' 11 I i I Sampler's Signature - Sampled By (Print Name) 1- -V- r. !-A,?„r V-e r-, 1 Affiliation lA ytlt� Upon relinquishing, this Chain of Oustody Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted In writing to the Prism Project Manager. There will he ckarges for any changes after analyses have been initialized. R 1 nulshedB (Scaature day {S?gr. rre £ilea, ours AdditionalCOmments: Relin I +By.IS ra vedBy (Signature) iy - ata try :7 �L_.Fyb Tw— VOr /S 1 Relin ' ed By: (Signature) Recaitia �r nx+I.z w-alorles ' Data r pp 1 Lo Uwe oe of ftipmem NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED allUT isTUDY SEALS FOR TRANSPORTATION TO THE LABORATORY. WC Gioup Ne. SAMPLESARENOTACCEPTEDAND VERIFIE13 AGAINST CDC UNTIL RECEIVED ATTHELABORATORY. } Tj� [) Q Fed Ex O UPS O Hand -delivered risrrr Field Service D DES'UST GROUNDWATER: DRINKING WATER: ,`SO TD WASTE: RCRA: ; CERCLA LANDFILL OTHER: I NC O SCI ❑ NC ❑ SC I ❑ NC O SC ❑ NC ❑ SC %ANC ZI SC ❑ NC O SC r LING ❑ SC El NC R SC ❑ NC ❑ SC ❑ ❑ ❑_ s J U _ El _ 0 *CONTAIN. (PE CODES: A = Amber C = Clear I G= Glass P = Plastic; TL = Teflon -lined Ca, DA = Volatile Organics Analysis (Zero Head Space) Site A, fival Time. ! skC F7eparture Turn l 1 Field Tech Fee. 1 EgS :E7E-QET-rg '7ERj14SONS M CHAIN�� ti I. .' rt Fu0-Service ^nzlyno:al & :r^taPAGry PRISM I En4ir:Ls OF.2 QUOTE iETOENSURE PROPER a1LLIlmO; SWnrp'c. iRii11C7 i1pOn8r.r 71'7 r Project Name 5 pce3C1 s�ne:C� YrrC7 f„i o 441 1 Springorocy Road • Charlot-te, MC 2821'r Pt"drsr'wR PRESS ..PP:TIveS nc+ sn_r=, Ptter+s 70-31529.63�t • Fax: 7041625-0409 Short Hold Analysis: ee ) (No) UST Project: ( s) - r k raf:.r=pVU1TYItiW^LDit.G Ttf«fi�S� Client Company Name: �bV4w'/�OQ[Lt`i 4_ Please ATTACH any project specific reporting (QC LEVE !F Ill i1� B, provisions and/or QC Requirements - - _ . �` sUC t 4iiV r F.F41.8 "+t tA(' f a r� CS Report To/Contact Name: ttl' (fie-- ';OWiitF' d' ftCl,1i N-AD:�P,C:F`% Invoice To: �f$�^,� ,c 's �L�_ Reporting Address: ,1• Address P .^•I =rt _. ;.:,,,.{Y'. _ SA.[ _ iFR:Y: T,.,�r,1r+ �Ei �`y :)b;erMi:�7. V Phone:i-r a-3lo Fax (Yes) (No): Purchase Order No./Billing Reterence TO BE FILLED IN BY CLIENTISAMPLiNG PERSONNEL Email Address: W(btitt 1 u v Reque,led Due Date ❑ 1 Day ❑ 2 Days Q 3 Days U 4 Days 0 5 Days Certification: NELAC 'DOD FL NC—Z EDD Type: PDF Excel other rwaf,,, Days" Ll 8-9 Days)k9tandard 10 days ❑Rushh Work t Be ScPre-ApprOTHER NIA Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround lime Is based on business days, excluding weekends and holidays_ Water Chlorinated: YES.__,_ NO_V' (SEFE REVERSE FOR ENDERS BY PRISM LABOS RATOR ES, INC. TO CLLIE& CONDITIONS NnSERVICES Sample Iced Upon Collection: YES V NO TiME MATRIX SAMPLE CONTAINER ANALYSIS REQUESiED CLIENT DATE COLLECTED (SOIL, PRESERVA- X I PRiSM SAMPLE DESCRIPTION I COLLECTED MILITARY WATER OR s — til REMARKS I LAB HOURS SLUDGE) SEE BELOW ! NO' SIZE TIVES��'�CJ�' ID NO. Sampler's Signature'Ac ,�.� +-iw - r'l Sampled By (Print Name) t-�P re, Affiliation — l L�IiWt-- Upon relinquishing, this Chai—� q g, rFaltustody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been Initialized. RoUnq Is ey F.'-��r. �^.,rar ' R„c= .. Ny is�C r� �:= nrnsaryr;rour: Additional Comments: Resingts... -ad 6} i-:fps j R ed By, (Signatur )� Rafe i t taW:r Pn Reh quished By: IS Al As � e.� ignahir, r Rac.srrrdj'+,*,: rr ,;:::+:: �,. •'�" _ � pnsr<� r I � � _` d � ' �y Method of Shipment N TE: ALI, SAMPLE COOLERS SHOULD BE TAPED 5 T wITH'C TIDY EALS FOR TRAN$POR'rAffd4TO THE LABORATORY. G 'C SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEFVEDATTHE LABORATORY. ❑ Fed Ex O UPS O Handdeltvered Prism Field Service ❑ O;nar I NP >~S: UST GROUNDWATER: I DRINKING WATER: SOLID WASTE: RCRA: CERCLA i LANDFILL OTHER: I WNC ❑ SC CI NC ❑ SC El NC ❑ SC j ❑ NC ❑ SC `E'NC ❑ SC ❑ NC CI SC ❑ NC ❑ SC ❑ NC ❑ SC I ❑ NC ❑ SC ❑ _.__. ❑ ❑ ❑ . — ❑ ❑ .... ❑ ❑ ' ❑ °CONTAIN► YPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Ca -)A = Volatile organics Analysis (Zero Head Space) Main Office: rush vioa snafytleN aid 449 Springbrook Road nviromn"gi4l Safutic;tc P.O. Box240543 Chariotte, NC 28224-0543 Phone: 704/529-6364 118001529-0364 Fax: 704152&4409 www.prismlabs.com Plant Available Nitrogen Sample Number 8070199-01 1 Sample Namel class A Mineralization Rate TKN Nli3 NOX m_C /L mglL. MRIL 0.3 11200 1680 0 PAN Surface 3,700 ro lkg MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mg/kg Calculated. B�,.r,' = °- f _ fr' y V S7� Page 10 of 16 Main Office: 449 Springbrook Road P I Full Sar=ka• Aualytical ::nd P.O. BOX 240643 Enviranm.:ntal Solution: Charlotte, NC28224-0643 " Phone: 7041629-6364 118001629-6364 Fax: 7041526-0409 www.prismlabs.com Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Humberl 807019g-01 Sample Namel Class A Na m: /I.} Ca.(riN& Mom L� Na : Sodium (mg/L) Equivalent weight: 23 (�113 252 75.7 Ca: Calcium (mg/L) Equivalent weight: 20 Mg : Magnesium (mg/L) Equivalent weight: 12 Na._,(ME� C-A-on Mg,(ME) 491 12.6 6.31 Milli Equivalent (ME) = mg/L / Equivalent weight SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power I SAR = 1.60 (From mg/L entered above) Calculated By, Page 11 of 16 44' AcasS ANAL�71CAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cale PROJECTID 8070199 LABORATORY REPORT NUMBER 1807F77 DATE July 26, 2018 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIl•]A-LAP,LLC Laboratory ID:100671 for Industrial Hyglene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative ofAES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803 781.4243 or toll Fee at 883.315.4243 Page Page 12 of i 6 ,e PRIS Full Service Analytical & yq. Environmental Solutions ".�•�.-;-. 't�titiW}L314.'UE:i MC. j klF-1Z SUBCONTRACT ORDER Certifi tiNELAC IISACE Prism Laboratories, Inc. C V SC_ Other 8070199 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc, P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA ProJect Manager, Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample 1D: 8070199-01 Solid Sampledo07116118 06s35 Herbicides TCLP (Sub) 07/23/18 06:35 Contalners Supplied. � Released By Date cccived By _ Dale - fWcasca .iy Date Received By Date Page 1 of 1 Page Page 13 0f 16 Analytical Environmental Services, Inc Date: 26-7u1-18 Client: Prism Laboratories Client Sample ID: Class A Lab Order 1807F77 Tag Number. 8070199-01 Project Name: 8070199 Collection Date: 7/16/2018 6:35:00 AM Lab ID: 1807F77-OOIA Matrix: Solid Analyses y Result Qual MDL Reporting Units BetchID DF Dato Analyzed Analyst Limit HERBICIDES, TCL? SW131118151A (SW3510C) 2,4,5-TP (SilveX) BRL 0.030 0,20 mglL 264460 1 07/25/2018 13:48 UH 2,4•D BRL 0.051 0.20 mriL 264460 1 07/25/.Z018I3:48 UH Surr: DCAA 63.7 0 50.4-133 %REC 264460 1 07/2512018 13:48 UH Quali6en: ' `.il.r. s tc'm msxirn„a conlom;!:anl level H Y.o'x :.a;; t.et:rc °ot p.,Wn%cr w analyus exceeded N AC —,i 1 B An-!,gc dcma:J e,o, sai7...a7 r-:,_;,:ji ank Es!i:xrca .x:ros5ovc quxiila3,v,rz�;:¢ S 5p, , i.c;o" Iy wside linulstsJr ::, r:u,;•t Mull value J [,q-;:!d value du:eted Inr„ Re:+e�tirg trmil Page Page 14 of 16 ;NE-S�1 n,us�rlc n, '4f:t9-innN ttE s"J tl 1. Client Name: Access Analocal, inc, INC Clear Save as SAMPLE/COOLER RECEIPT CHECKLIST 2. Carrier: FedEx © UPS ❑ USPS❑ Client El Courier❑ Other Yes No N/A 3. a. 5 6 7. 8 9, 10. 11. i2. AES Work Order Number: 18071`77 nefane Shipping container/cooler received in good condition? o damaged ❑ leaking ❑ other[] Custody seals present on shipping container? o Custody seals intact on shipping container? o Temperature blanks present? o < Cooler temperatures) within Limits of 04C? (See item 13 and 14 for temperature recordings.] Q `lJ Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (CDC) present? o Chain of Custodysigned, dated, and timed when relinquished and received? o signature & date only Sampler name and/or signature on CDC? o. Were all samples received within holding time? o TAT marked on the COC? a If no TAT indicted, proceeded with standard TAT per Terms & Conditions. pj 13. Cooler 1 Temperature 4.3 °C Cooler 2 Temperature 14. Cooler 5 Temperature °C Cooler 6 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler3Temperature oC Cooler 4 Temperature °C °C Cooler 7 Temperature °C Cooler 8 Temperature °C 1 certify that 1 have completed sections 1-15 (dated initials). MI 7/18119 Yes No N/A Ontalis jr--re Were sample containers intact upon receipt? a Custody seals present on sample containers? o Custody seals intact on sample containers? o Do sample container labels match the COC? J ® 0 incomplete info f_[ illegible iJ no label ❑ other ❑ Are analyses requested indicated on the COC? a Were all of the samples listed on the CDC received? � ® 0 samples recelved but not listed on COC t samples listed on COC not received ! i Was the sample collection date/time noted? o Did we receive sufficient sample volume for indicated analyses? o Were samples received in appropriate containers? no Were VOA samples received without headspace (< 1/4" bubble)? —9 o Were trip blanks submitted? o ilsted on COC ❑ not listed on COC [_ 27. Comments: This section only applies to samples where pH can be t certify that I have completed sections 16-27 (dated initialsl. AU 7/18/18 checked at Sample Receipt, Yes No N/A Details Comments La. nave comamers need mg cnemrcat preservation oeen cnecKeoe - o 29, Containers meet preservation guidelines? 1 0 1 o cQ 30.I Was pH adjusted at Sample Receipt? _ I o N 'Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as California, VOCs and 011 & Grease/TPH. c. I certify that J have completed sections 28-30 (dated initials). O Checklist 6.9.17 Rev 2 Locked A.0 7/18/18 = Page 4 of 5 Analytical Environmental Services, Inc Date: 26-7ui-18 Client,. Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 8070199 Workorder: 1807F77 BOOM: 264460 _ Sample ID: MB-264460 Client ID:� Units: mglL Prep Date: 07/2512018 Run No: 376124 SampleType: MBLK TestCode: 1tERBICIDES,TCLP SWI31118151A Batchll):264460 Analysis Date: 07/25/2018 SegNo: 9365919 "X-dyte Result RP'r Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Quat 2,4,5-TP(Si!vex) BRL 0.20 2,4-1) BRL 0.20 Surr: DCAA 0.3454 0 0.5000 69.1 50.4 133 ! sample tu: Le6-264460 Client lll: Units: mg/L Prep Date: 07/25/2018 Run No: 376124 SampleType: LCS TestCode: IJERBICIDMTCLP SWIS1118151A BatchID:264460 Analysis Date: 0712512018 SegNo: 8365920 Analytc Result RPT Limit SPK value SPK Ref Val _ tr/eREC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2; I.S; ; P (Silvcx) 0.4206 0.20 0.5000 84_1 -A 49.1 119 2. }-D 0.4666 0.20 0.5000 93.3 509 129 Surf: DCAA 0.3866 0 0.5000 77.3 50.4 133 ! sample 1u: 1807N77-001AMS Client ID: ClassA Units: mg/L Prep Date: 07/25/2018 Run No: 376124 j SampleType: MS i TestCode: BERBICIDE$TCLP SWI311/8151A 13atchtD:264460 Analysis Date: 0717-V2018 SegNo: 8365922 Analyze Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qua! 2,4,5-TP (Silvex) 0.4484 0.20 0.5000 89.7 482 125 -1 2.4-D 0.4935 0.20 0.5000 98_7 44.5 138 Surr: DCAA 0.2960 0 0.5000 59.2 50.4 133 (-0 Qusllfeua; � Greater tban kesuN value NTILL Bclosv reporting limit J Estimated value demcted WN ur Rap., tT rmn,G.nit Q Rpt Lim Rcpordnu Limit IJ < Lers thm Rc aA value E Estimated (valu.. above gt:mt::zlicn trngc) N Anil:;enotNUACcerdfied S Spike Rordvery outside [imim due to matrix B Aneiyte datecud in dre auatiated method blank Ti 1`103ing times fat preparation or analysis exceeded R RPD outside limits due to matrix Page 5 of 5 tDR, ISM VLABORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 10/08/2018 Prism Work Order: 8100149 Case Narrative 10/26/2018 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a Revised Report and supercedes the original laboratory report dated 10/25/18. SAR and PAN calculation sheets are now attached. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager A LLICV recovery (125%) is greater than the upper control limit (120%). Low results might have a high bias. B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 10x the MB. DM Sample diluted and RL increased due to the matrix. MC Sample concentration too high for recovery evaluation. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/626-0409 Page 1 of 16 / P�. Full -Service Analytical & L.cI,F ! Im Environmental Solutions ✓ LABORATORIES ING Sample Receipt Summary 10/26/2018 Prism Work Order: 8100149 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received Class A 8100149-01 Solid 10/08/18 8:05 10/08/18 12:40 Samples were received in good condition at 3.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/626-0409 Page 2 of 16 Laboratory Report ',,{9 u 'n\ //�' Full -Service Analytical s 10/26/2018 E I 1 I S 1 Y 1 Environmental Solutions �IABORATORIF.$ INC Town of Mooresville/RR WIMP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8100149-01 P. O. Box 878 Prism Work Order: 8100149 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/08/18 08:05 Time Submitted: 10/08/18 12:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 3900 mg/kg dry 3200 930 20 *Calculation 10/18/18 8:13 CLB [CALL] % Solids 95.3 % by 0.100 0.100 1 *SM2540 G 10/17/18 16:42 TJY P8J0357 Weight Ammonia as N 1400 mg/kg dry 10 2.5 1 *SM4500-NH3 C 1019/18 16:56 BMS P8J0171 Nitrate/Nitrite as N BRL mg/kg dry 5.2 1.4 1 *SM4500-NO3 F 10/17/18 9:21 CLB P8J0296 pH 6.4 pH Units 1 *9045D 10/12/18 16:49 CBP P8J0279 Phosphorus -Total 12000 mg/kg dry 260 58 100 *SM4500-P F 10/16/18 7:41 CLB P8J0260 Total Kjeldahl Nitrogen 12000 mg/kg dry 10000 3100 20 *361.2 10/18/18 8:13 CLB P8J0308 Microbiological Parameters Fecal Coliforms 5 MPN/g dry 0.2 1 *SM9221 E 10/8/18 13:28 BMS P8J0169 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 *1311 10/12/18 8:45 MMR P8J0220 TCLP Extraction Complete N/A 1 *1311 ZHE 10/19/18 10:30 KDM P8J0395 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 10/16/18 16:27 MMR PSJ0277 Arsenic BRL mg/L 0.050 0.0031 1 *6010D 10/15/18 14:37 JAB P8J0230 Barium BRL mg/L 5.0 0.00080 1 *6010D 10/15/18 14:37 JAB P8J0230 Cadmium BRL mg/L 0.025 0.00015 1 *6010D 10/15/18 14:37 JAB P8J0230 Chromium BRL mg/L 0.25 0.00036 1 *6010D 10/15/18 14:37 JAB P8J0230 Lead BRL mg/L 0.050 0.00080 1 *6010D 10/15/18 14:37 JAB PBJ0230 Selenium BRL mg/L 0.050 0.0056 1 *6010D 10/15/18 14:37 JAB PBJ0230 Silver BRL mg/L 0.25 0.00039 1 *6010D 10/15/18 14:37 JAB P8J0230 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00017 1 *8081B 10/15/18 16:26 JMC P8J0249 Dieldrin BRL mg/L 0.00050 0.000014 1 *8081B 10/15/18 16:26 JMC P8J0249 Enddn BRL mg/L 0.00050 0.000015 1 *8081B 10/15/18 16:26 JMC P8J0249 gamma-BHC BRL mg/L 0.00050 0.000013 1 *8081B 10/15/18 16:26 JMC P8J0249 Heptachlor BRL mg/L 0.00050 0.000017 1 *8081B 10/15/18 16:26 JMC P8J0249 Heptachlor Epoxide BRL mg/L 0.00050 0.000013 1 *8081B 10/15/18 16:26 JMC P8J0249 Methoxychlor BRL mg/L 0.00050 0.000039 1 *8081B 10/15/18 16:26 JMC P8J0249 Toxaphene BRL mg/L 0.025 0.000074 1 *8081 B 10/15/18 16:26 JMC P8J0249 Surrogate Recovery Control Limits Decachlorobiphenyl 30 % 13-186 Tetrachloro-m-xylene 29 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 *8270D 10/16/18 18:37 JMV PBJ0264 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 10/16/18 18:37 JMV P8J0264 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 *8270D 10/16/18 18:37 JMV P8J0264 2-Methylphenol BRL mg/L 0.050 0.0018 1 *8270D 10/16/18 18:37 JMV P8J0264 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/626-0409 Page 3 of 16 Laboratory Report R I Full-Serviceiroen Analytical Environmental Solutions s �.-, L" S TORIES. ING 10/26/2018 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8100149-01 P. O. Box 878 Prism Work Order: 8100149 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/08/18 08:05 Time Submitted: 10/08/18 12:40 Parameter Result Units Report MDL Limit Dilution Factor Method Analysis Analyst Date/Time Batch ID 3/4-Methylphenol 0.36 mg/L 0.050 0.0016 1 *82701) 10/16/18 18:37 JMV P8J0264 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 *8270D 10/16/18 18:37 JMV P8J0264 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 *8270D 10/16/18 18:37 JMV P8J0264 Hexachloroethane BRL mg/L 0.050 0.0017 1 *8270D 10/16/18 18:37 JMV P8J0264 Nitrobenzene BRL mg/L 0.050 0.0026 1 *8270D 10/16/18 18:37 JMV P8J0264 Pentachlorophenol BRL mg/L 0.25 0.0012 1 *8270D 10/16/18 18:37 JMV P8J0264 Pyridine BRL mg/L 0.25 0.0010 1 *8270D 10/16/18 18:37 JMV P8J0264 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 57 % 43-140 2-Fluorobiphenyl 51 % 44-119 2-Fluorophenol 39 % 19-119 Nitrobenzene-d5 49 % 44-120 Phenol-d5 32 % 11-52 Terphenyl-d14 58 % 50-134 TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *8260B 10/19/18 17:57 KDM P8J0397 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 *8260B 10/19/18 17:57 KDM P8J0397 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *8260B 10/19/18 17:57 KDM P8J0397 Benzene BRL mg/L 0.025 0.00048 1 *8260B 10/19/18 17:57 KDM PBJ0397 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *8260B 10/19/18 17:57 KDM P8J0397 Chlorobenzene BRL mg/L 5.0 0.00062 1 *8260B 10/19/18 17:57 KDM P8J0397 Chloroform BRL mg/L 0.30 0.00076 1 *8260B 10/19/18 17:57 KDM P8J0397 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *8260B 10/19/18 17:57 KDM P8J0397 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *8260B 10/19/18 17:57 KDM P8J0397 Trichloroethylene BRL mg/L 0.025 0.00078 1 *8260B 10/19/18 17:57 KDM P8J0397 Vinyl chloride BRL mg/L 0.020 0.00097 1 *8260B 10/19/18 17:57 KDM P8J0397 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 93 % 77-123 Total Metals Aluminum 22000 DM mglkg dry 520 76 100 *6010D 10/23/18 18:23 JAB P8J0276 Mercury 0.62 mg/kg dry 0.062 0.0059 3 *7471B 10/23/18 11:01 MMR P8J0414 SAR Soil Preparation Complete g 1 *2-78-054 10/16/18 12:15 MMR P8J0289 SAR Percent Moisture 74.8 % by 0.100 0.100 1 *2-78-054 10/17/18 16:54 MMR P8J0322 Weight Arsenic BRLDM mg/kg dry 52 3.2 100 *6010D 10/23/18 18:23 JAB P8J0276 Sodium Absorption Ratio 0.80 [blank] 0.30 0.016 1 *2-78-054 10/24/18 11:29 JAB P8J0285 Cadmium BRLDM mg/kg dry 26 0.70 100 *6010D 10/23/18 18:23 JAB P8J0276 Calcium 19000 DM mg/kg dry 1000 24 100 *60101) 10/23/18 18:23 JAB P8J0276 Calcium, SAR 47 B mg/L 0.10 0.010 1 *6010D 10/24/18 11:29 JAB P8J0285 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/525-0409 Page 4 of 16 C� PPC 1 Full -Service Analytical & I S M Environmental Solutions ® LABORATORIEj INa Laboratory Report 10/26/2018 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 8100149-01 P. O. Box 878 Prism Work Order: 8100149 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/08/18 08:05 Time Submitted: 10/08/18 12:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chromium 29 DM mg/kg dry 26 4.3 100 *6010D 10/23/18 18:23 JAB P8J0276 Copper 270 DM mg/kg dry 52 4.7 100 *6010D 10/23/18 18:23 JAB P8J0276 Lead BRLA, DM mg/kg dry 26 4.8 100 *6010D 10/23/18 18:23 JAB P8J0276 Magnesium 2900 DM mg/kg dry 260 24 100 *6010D 10/23/18 18:23 JAB 138J0276 Magnesium, SAR 12 mg/L 0.10 0.0086 1 *60101) 10/24/18 11:29 JAB P8J0285 Molybdenum BRLDM mg/kg dry 52 1.5 100 *6010D 10/23/18 18:23 JAB P8J0276 Nickel BRLDM mg/kg dry 52 1.9 100 *6010D 10/23/18 18:23 JAB P8J0276 Potassium 3800 DM mg/kg dry 1300 47 100 *6010D 10/23/18 18:23 JAB P8J0276 Selenium BRLDM mg/kg dry 52 12 100 *6010D 10/23/18 18:23 JAB P8J0276 Sodium BRLDM mg/kg dry 1600 51 100 *6010D 10/23/18 18:23 JAB P8J0276 Sodium, SAR 23 B mg/L 0.60 0.018 1 *601013 10/24/18 11:29 JAB P8J0285 Zinc 670 DM mg/kg dry 260 9.3 100 *6010D 10/23/18 18:23 JAB P8J0276 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 5 of 16 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Date/Time 8100149-01 P8J0308 0.05 g 25 mL 10/17/18 10:35 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 8100149-01 PBJ0171 1.05 g 50 mL 10/09/18 13:00 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 8100149-01 P8J0260 Prep Method: Solids, Dry Weight Lab Number Batch 1 g Initial 50 mL Final 10/15/18 10:57 Date/Time 8100149-01 P8J0357 30 g 30 g 10/17/18 16:42 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 8100149-01 P8J0395 12.5 g 250 mL 10/18/18 16:30 8100149-01 P8J0220 100 g 2000 mL 10/11/18 15:46 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8100149-01 P8J0230 50 mL 50 mL 10/12/18 11:05 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 8100149-01 P8J0277 20 mL 30 mL 10/16/18 9:15 Prep Method: 3610C GC Lab Number Batch Initial Final Date/Time 8100149-01 P8J0249 1000 mL 10 mL 10/15/18 8:59 Prep Method: 3610C MS Lab Number Batch Initial Final Date/Time 8100149-01 P8J0264 200 mL 1 mL 10/16/18 9:12 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 8100149-01 P8J0397 1 mL 10 mL 10/19/18 11:01 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 8100149-01 P8J0285 50 mL 50 mL 10/16/18 11:52 8100149-01 P8J0285 50 mL 50 mL 10/16/18 11:52 Prep Method: 3060B Lab Number Batch Initial Final Date/Time 8100149-01 P8J0276 2.02 g 50 mL 10/16/18 8:20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/526-0409 Page 6 of 16 Sample Extraction Data Prep Method: 7471E Lab Number Batch Initial Final Date/Time 8100149-01 P8J0414 0.61 g 50 mL 10/23/18 7:35 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 8100149-01 PSJ0289 250 g 250 g 10/15/18 12:15 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 8100149-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/625-0409 Page 7 of 16 GMAIN ®F GUbTUDY RECORD ONLY n Full -Service Analytical 8 - ' V I Environmental Solutions =� I I PAGE I of a QUOTE # TO ENSU PROPER BILLING* YES NO N/A � € .._.... r. LABORATORIES INC. O Samples INTACT upon arrival? o 449 Springbrook Road •Charlotte, NC 28217 Project Name: IGSS Received ON WET ICE? � Phone 7041529-6364 • Fax: 704/525-0409 ll Short Hold Analysis: 'iris (NO UST Pr ect: (Yes) O) PROPER PRESERVATIVES indicated? Please ATTACH a Client Company Name: 1. D�� 1 t7'2Sv1�i� an ro specific reporting QC LE II ill 1 Received WITHIN HOLDING TIMES?to p g ( � Report To/Contact Name: Z• - provisions and/or QC Requirements CUSTODY SEALS INTACT? 1 Invoice _Fp1AA I- 1y �aU{7S k VOLATILES t1 Reporting Address:O naqv To: reed W/OUT HEADSPACE? - Address: PROPER CONTAINERS used? II _ TEMP: Therm ID: J4cl, Observed: L °C / Corr. T - 2 -C Phone dd -G�0' $�D Fax (Yes) (No): E Email Address:: wrv�w'lYL eC1c�i.rn^ct=r2�,iilll ��' - hg Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL EDD Type: PDF_Excel^Other Requested Due Date ❑ 1 Day ❑2 D ys Q 3 Days ❑ 4 Days O 5 Days Certification: NELAC DOD FL NC Site Location Name: "Working Days" ❑ 6-9 Days Standard 10 days ❑ P CIA Work Must Be SC �3 i ER N/A Samples received after 14:00 will be processed next business day. Site Location Physical Address: —ice'_ Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NIOL/'- (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES ✓NO_ CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY MATRIX (SOIL, WATER OR SAMPLE CONTAINER PRESERVA- TIVES"1- p ANALYSIS REQUES�EO' . y �R` 7 fL,�'h��js$` �u / ,a / o / �� rs�,�' / REMARKS IA', PRISM LAB *TYPE H IRS SLUDGE) SEE BELOW NO. SIZE / �Q 4J� 3 v� ID NO. /� j� 0,1llSS P 0 $ D1L ei I i i i p9 f i r I Sampler's Signatu�a � Sampled By (Print Name) ,R ( Affiliation j Upon relinquishing, this Chain f Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be Owges for any changes after analyses have been initialized. PRISP4 USE ONLY R In u c B , is.gnalure Receive By; (Slgnety Date Mirdary/Hours Additional Comments: Site Arrival Time: Re q '- "•d r3y (Sig tea e/ ! ed 6y; (Signature] Data Site Departure Time: Reli ed By: (Signature) Received For,Prism LaboraI es By: J Date Field Tech Fee: - ( 11 L-io Mileage: Method al SNpmentt NOTE: ALL SAMPLE COOLERS SHOULD BE' SHUT WRH CUSTODY SEALS FOR TRRR. }}}NNNSP RTATION TO THE ORATORY.' roup No. COC G SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE {IAHORATORY. > q ❑ Fed Ex El UPS ❑ Hand -delivered Priam Field Service ❑ Olhrir I v� / Li ,NPDES: UST: GROUNDWATER. DRINKING WATER: 1\S9 LID WASTE: RCRA: CERCLA LANDFILL OTHER: 9VC El SC ElNC ❑ SC iEl NC El SC ❑ NC ❑ SC �( NC ❑ SC I ❑ 1, ❑SCI ❑ NC ❑SCI ❑ NC ❑ SCI ❑ NC ❑ SC ❑ ❑ ❑ ❑ I. ❑ - ❑ ❑ ❑ ❑ nolr�lntA l `CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) CHAIN OF CUSTODY RECORD Rv' I n n I FullAnalytical & Environmental Solutions PAGE -a OF � QUOTE # TO ENSURE PROPER BILLING: ma's •s-- •�." LViORATORIE$ INC 449 Springbrook Road • Charlotte, NC 28217 Project Name: Phone 7041529-6364 Fax: 704/525-0409 Short Hold Analysis: (Yes) (Nor UST Pro t. (Yes) (NO) *Please ATTACH any project specific reporting (QC LEVEL 1 II 111 IV) Client Company Name: �iw� a� �U�i)�:2-'�►1 provisions and/or QC Requirements Report To/Contact Name: JWA, At �n ylnun rt 2. Invoice To: Reporting Address: X P. 9 Address: Oe[iSL��_ 21 l `i Samples INTACT upon arrival? Received ON WET ICE? PROPER PRESERVATIVES indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? VOLATILES reed W/OUT HEADSPACE? PROPER CONTAINERS used? TEMP: Therm ID: I0-T-1 Observe YES NO N/A 1 l� o r 0) m 1' cc/ Corr E� Phone :':01{- 00 3.tp Fax (Yes) (No): Purchase Order No./Billing Reference Email Address: but1O. r,- CaaJl."f1At'ma14 - oa. j is Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days EDD Type: PDF_Excel Other Rush Work Must Be "Working Days" ❑ 6-9 Days ❑Standard 10 days ❑ Pre -Approved Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays�6 (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Certification: NELAC DoD FL NC� SC OTHER N/A Water Chlorinated: YES_ NO17' RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES NO CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIMES AN IS REQUESTED i r % - / REMARKS �� f PRISM LAB ID NO. `TYPE SEE BELOW NO. SIZE • a g Q��D Soil TS—� J Oc .. Sampler's Signature Sampled By (Print Name) c-t Affiliation _D &UA - Upon relinquishing, this Chain kfbustody is your authorization for Prism to proceed with the an (yses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Re squish By: (Signature) Re c' Y-(signature Date itirylHalrrs Additional Comments: SHeArrival Time: /M Relin d By>(Si_ a re) Recdiu®d'By: Signature) Date Sue Departure Time: 0 �ry 12�1 Field Tech Fee: _ oralode-'By. Date Relin ed By: (Signatu Received For Prism ab' %j'- to - 3' I $ l 2 r1 V Mileage: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TJIANSPORTATION TO LABORATORY. COC.Group No. SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT TH LABORATORY. �xy tU - ' oo I 1 ❑ Fed Ex ❑ UPS ❑ Hand -delivered Prism Field Service O Other V ES: UST: GROUNDWATER: DRINKING WATER: S LID WASTE: RCRA: CERCLA LANDFILL OTHER: SEE REVERSE ;NC❑SC El NC El SIC El NC ❑SC I ❑NC US C INC ❑SC ❑NC❑SCI ❑NC El El NC El SC ❑NC ❑SIC CONDITIONS n ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑- nolrtnlAl 'CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Main Office: 449 Spring brook Road Full and meat P.O. Box 43 roY Environmental Solutions l Solt , NC 28 Charlotte, NC 28224-0543 Ird Phone: 7041529-6364 11800/529-6364 Fax: 7041525-0409 www.prismiabs.com Sodium Absorption Ratio The amount of exchangeable sodium ions versus the amount of exchangeable calcium & magnesium ions in a given material. Sample Numberl 8100149-01 Sample Namel Class A Nam `/L Cam %L M rrt-- /L Na: Sodium (mg/L) Equivalent weight: 23 23.4 1 47.4 1 12.4 Ca: Calcium (mg/L) Equivalent weight: 20 Mg : Magnesium (mg/L) Equivalent weight: 12 Na (ME)," Ca M Mg (ME) 1:02 2:.37 1:03 Milli Equivalent (ME) = mg/L / Equivalent weight SAR= Na Milli Equivalent/[0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0.5 power SAR = 0.8 (From mg/L entered above) Calculated By: le /G& Page 10 of 16 Main Office: � %� Full Service Analytical and 449 Springbrook Road ' m V I Environmental Solutions P.O. Box 240543 .` iRbrlRl.it:ir c-uer_ Charlotte! NC 28224-0543 Phone: 7041529.6364 1/8001529-6364 Fax: 704/525-0409 www.prismiabs.com Plant Available Nitrogen Sample Number 8100149-01 1 Sample Namel Class A Mineralization Rate TKN NH3 NOX mg/k4 m_ _g �� 0.3 12000 1400 1 1.7 PAN 3,900 imgflkg MR(TKN-NH3)+ 0.5(NH3)+NOX = PAN mg/kg Calculated [3}/;��%_�-t� Page 11 of 16 9�. ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECTID 8100149 LABORATORY REPORT NUMBER 1810954 DATE October 18, 2018 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - All-IA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative ofAES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll tee at 883.315.4243 Page Page 12 of 16 1�710y�q S M IFull-Service Analytical 8 Environmental Solutions SUBCONTRACT ORDER Ccrt fc;man: NEL/1C._ USACF. Prism Laboratories, Inc. NC SC .other. 8100149 N1A SENDING LAB611AT0riY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta,'GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA Project Manage: Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample 1D: 8100149 Ol Salid Sompled:10/08/18 08:05 C`l 5 Herbicides TCLP (Sub) 10/15/18 08:05 Containers Supplied: 161.i6 Released By Dwe Received By Date Page 1 of 1 Page Page 13 of 16 Analytical Environmental Services, Inc Date: 18-Oct-18 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1810954 Tag Number: 8100149-01 Project Name: 8100149 Collection Date: 10/8/2018 8:05:00 AM Lab 1D: 1810954-OOIA Matrix: Solid Analyses y Result Qual MDL Reporting Limit Units BatchID DF Date Analyzed Analyst HERBICIDES, TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.030 0.20 nn /L 268729 1 10/16/2018 15:56 HB 2,4-D BRL 0.051 0.20 mE/L 268729 1 10/16/201815:56 HB Surr: DCAA 87 0 50.4-133 a/oREC 268729 1 10/16/2018 15:56 HB Qunlirrem • Value exceeds maximum contaminant level E Estimated value above quamiiation range DRL Not Detected at MDL S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded > Greater than Result value N Analyte not NELAC cerulied J Estimated value detected below Reporting Limit 9 Analyfe defected in the associated method blank < Less than Result value ' Page Page 14 of 16 A cA1., rrr nt. Clear Save as I AF,%JEN-VIRONMENTAL SERVICES.INC. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. AES Work Order Number: 1810954 2. Carrier: FedEx ❑i UPS ❑ USPS❑ Client❑ Courier❑ Othei Yes No N/A Details Comments 3. 4. 5 6. 7. 8. 9. 10. 11. 12. Shipping container/cooler received in good condition? o damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? s Custody seals intact on shipping container? • Temperature blanks present? 0 J-9 Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature recordings.) Q ® Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? •. Were all samples received within holding time? •�E TAT marked on the COC? 1• —R If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 0.5 °C Cooler 2 Temperature oC Cooler 3 Temperature °C Cooler 4 Temperature 0C 14. Cooler 5 Temperature °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C 15. Comments: certify that I have completed sections 1-15 (dated initials). AJJ 10/10/18 Yes No N/A Details Comments 16. 17. 18. 19. 20. 21. 22. 23- 24. 25. 26. Were sample containers Intact upon receipt? a Custody seals present on sample containers? o Custody seals intact on sample containers? o Do sample container labels match the COC? Q Q ® incomplete info ❑ Illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? o all of the samples listed an the CDC received? Q® O samples received but not listed on CDC ElWere samples listed on COC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? o. Were VOA samples received without headspace (< 1/4" bubble)? o Were trip blanks submitted? • listed on CDC ❑ not listed on COC ❑ 27. Comments: This section only applies to samples where pH can be 28. 29. W 30. u? I certify that 1 have completed sections 16-27 (dated initials). AP 10/10/18 m ' Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. 1 certify that I have completed sections 28-30 (dated initials). AP 10/10/18 (Sl O Checklist 6.9.17 Rev 2 Locked HIM Page 4 of 5 Analytical Environmental Services, Inc Client: Prism Laboratories Project dame: 8100149 Workorder: 1810954 Date: 18-Oct-I8 ANALYTICAL QC SUMMARY REPORT BatchID: 268729 Sample ID: MB-268729 Client 1D: Units: mg/L Prep Date: 10/15/2018 Run No: 382404 SampleType: MBLK TestCode: HERBICIDES, TCLP SWI311/8151A BatchID: 268729 Analysis Date: 10/16/2018 Seq No: 8530650 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.3772 0 0.5000 75.4 50.4 133 Sample ID: LCS-268729 Client ID: Units: mg/L Prep Date: 10/15/2018 Run No: 382404 SampleType: LCS TestCode: HERBICIDES, TCLP SWI311/8151A BatchlD: 268729 Analysis Date: 10/16/2018 Seq No: 8530651 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.5181 0.20 0.5000 104 49.1 119 2.4-D 0.4757 0.20 0.5000 95.1 50.9 129 Surr: DCAA 0,4876 0 0.5000 97.5 50A 133 Sample ID: 1810954-001AVIS Client ID CLASS A Units: mg/L Prep Date: 10/15/2018 Run No: 382404 SampleType: MS TestCode HERBICIDES,TCLP Sw1311/8151A BatchlD:268729 Analysis Date: 10/16/2018 Seq No: 8530653 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.4125 0.20 0.5000 2.4-D 0.4034 020 0.5000 Surr: DCAA 0.4065 0 0.5000 pj Qualifiers: - Greater than Result value CD BRL Below reporting limit 8 1 Estimated value deteckel below Reporting Limit p Rpt Lim Reporting Ltmu 1 82.5 482 125 807 44.5 138 813 50A 133 e Less than Result value E Estimated (value above quantitation range) N Analyte not NELAC certified S Spike Recovery outside limits due to matrix B Amdyte delecled in the associated method blank H Holding limes for prepamtian or analysis rxceedcd R RPD outside limits due to matrix Page 5 of 5 RECENSDINCDENRIDWR: FEB IS 2020 WQROS fife _ORP—SVILLEREGIONALOFFI Town of Mooresville NORTH CAROLINA rPVF FEB 0 3 2020 I10131%1RTION PROCESSING UNiT ROCKY RIVER W.W.T.P �%� TELEPHONE (704) 6624470 FAX (704) 662-8473 POST OFFICE BOX 878 MOORESVILLE, NC 28115 Q\Sc,�a�� Q� Annual Class A Report, W'0036723 Rocky River Wastewater Treatment Facility MooresAle, N.C. 28115 Town of Mooresville NORTH CAROLINA NCDENR-DWQ Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699 ROCKY RIVER W.W.T.P TELEPHONE (704) 662-8470 FAX (704) 662-8473 POST OFFICE BOX 878 MOORESVILLE, NC 28115 01/28/20 Subject: 2019 Annual Sludge Report, WQ0036723 Distribution of Class A Residuals Following is the information requested to accompany our Class "A" Annual report. 1) Facility - Rocky River Wastewater Treatment Facility 369 Johnson Dairy RD. Mooresville, N.C. 28115 Phone: 704-663-2840 2) Responsible official and facility contact — Larry Hendren, Bio-solids Coordinator P.O. BOX 878 Mooresville, NC 28115 Phone: 704-799-4063 3) Class "A" dried,biosolids were distributed under Town of Mooresville permit # WQ0036723 4) (Part A) and (Part B) Distribution of Class "A" Residuals for 2019 were transported to, Joe Hampton in Mt. Ulla, NC, Doug Carrigan in Mooresville, NC, Chad Swim in Mooresville, Rob Bailey in Mooresville, and Scott Goodman in Kannapolis. Total = 656.09 dry metric tons (See Attached Hauling Summary Sheets). Laboratory data from quarterly TCLP analyses have been included in this report. 5)(Part C) I certify, under penalty of law that the above information is, to the best of my knowledge and .belief, true and accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Prepared by: Larry Hendren, Bio-solids Coordinator Reviewed by: Jamie Levis, WWTP Plant Manager Signature l - 2$- Z O Date c Signature: - 2 Date Town of Mooresville 2019 hauling Summary Sheet DATE _ TONS _ TRANSPORTER DESTINATION COMMENTS _ 3/19/2019 47.8 Town of Mooresville Carrigan Farms- g Loads Mooresville 3/20/2019 t 45.5 Town of Mooresville Carrigan Farms- 7 Loads Mooresville 3/24/2019 21.5 Garin Klutz Farm Mt. Ulla 2 Loads 3/28/2019 15.0 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 3/31/2019 10.4 Garin Klutz Farm Mt. Ulla 1 Load 4/17/2019 11.3 Town of Mooresville Carrigan Farms- 2 Loads Mooresville 4/29/2019 29.0 Town of Mooresville Carrigan Farms- 5 Loads Mooresville 4/30/2019 32.2 Town of Mooresville Carrigan Farms- 5 Loads Mooresville 5/8/2019 18.4 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 5/16j2019 21.8 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 6/20J2019 30.0 Town of Mooresville Carrigan Farms- 5 Loads Mooresville 6/24/2019 38.1 Town of Mooresville Carrigan Farms- 6 Loads Mooresville 6/26/2019 30.9 Town of Mooresville Carrigan Farms- 5 Loads Mooresville 7/3/2019 19.8 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 7/10/2019 28.6 Town of Mooresville Carrigan Farms- 5 Loads Mooresville 7/11/2019 17.9 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 7/15/2019 13.7 Town of Mooresville Carrigan Farms- 2 Loads Mooresville 7/22/2019 28.7 Town of Mooresville Carrigan Farms- 5 Loads Mooresville 8/14/2019 5.7 Chad Swim Mooresville 2 Loads 8/19/2019 24.4 Town of Mooresville AFH Farm 4 Loads Mooresville 8/20/2019 6.1 Town of Mooresville AFH Farm 1 Load Mooresville 8/26/2019 19.1 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 9/4/2019 19.7 Town of Mooresville AFH Farm 3 Loads Mooresville 9/4/2019 12.4 Town of Mooresville Carrigan Farms- 2 Loads Mooresville 9/10/2019 19.9 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 9/10/2019 5.7 Town of Mooresville AFH Farm 1 Load Mooresville 9/18/2019 12.6 Town of Mooresville Carrigan Farms- 2 Loads Mooresville 9/18/2019 12.8 Town of Mooresville AFH Farm 2 Loads Mooresville 9/25/2019 6.8 Town of Mooresville Carrigan Farms- 1 Load Mooresville 9/25/2019 6.7 Town of Mooresville AFH Farm 1 Load Mooresville 9/26/2019 6.8 Town of Mooresville Carrigan Farms- 1 Load Mooresville 10/1/2019 4.2 Chad Swim Mooresville 1 Load 10/9/2019 6.4 Town of Mooresville AN Farm 1 Load Mooresville 10/9/2019 6.7 Town of Mooresville Carrigan Farms- 1 Load Mooresville 10/15/2019 12.1 Town of Mooresville Carrigan Farms- 2 Loads Mooresville 10/15/2019 17.4 Town of Mooresville AFH Farm 3 Loads Mooresville 10/24/2019 12.0 Town of Mooresville Carrigan Farms- 2 Loads Mooresville 10/28/2019 23.3 Town of Mooresville Carrigan Farms- 4 Loads Mooresville 11/19/2019 17.9 Town of Mooresville Carrigan Farms- 3 Loads Mooresville 11/20/2019 21.7 Town of Mooresville Carrigan Farms- 4 Loads Mooresville 12/12/2019 11.8 Melton Hauling Scott Goodman 2 Loads Kannapolis Total tons 752.80 Avg. % solids 0.96 Drytons 723.21 Conversion factor 0.907184 Metric tons 682.93 Dry metric tons 656.09 Calculation: Dry metric tons= total tons * avg.% solids* conversion factor PRISM ' UUMRATORIE$ INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WVVTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 02/11/2019 Prism Work Order. 9020168 Case Narrative 02/28/2019 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Analysis note for SAR: SAR = [ Na ] / SORT { ([Ca] + [Mg]) / 2 ) SAR = ( 79.5/23 ] / SORT { ([142/20] + [87.5/12.2]) / 2 ) Concentrations for Na, Ca, and Mg are expressed in milliequivalents per liter, and SORT designates taking the square root of the operand in parentheses. PAN Equation = 0.3 * (TKN — Ammonia) + 0.5 * (Ammonia) + Nitrate —Nitrite PAN = 0.3 * (21000 — 1400) + 0.5 * (1400) + 8.7 PAN = 67=fl �- Equation uses Mineralization Rate (MR) for Aerobically Digested Solids (0.3) Please call if you have any questions relating to this analytical report Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager i Reviewed By Terri W. Cole Project Manager This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - charlotte, No 28224-OM 7-1 Phone: 7041529-6364 -Toll Free Number, 1-8001629.6364-Fax:704/526.0409 Page 1 of 15 Data Qualifiers Key Reference: BH MB greater than one half of the RL, butthe sample concentrations are greater than 10x the MB. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detectionlimit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to. the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364- Toll Free Number: 1-800/629-6364- Fax; 704IS26-0409 Page 2 of 15 I S M I Full -Service al Solutions s I i Environmental Solutions Sample Receipt Summary 02/28/2019 Prism Work Order: 9020168 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received Class A 9020168-01 Solid 02/11/19 7:03 02/11/19 13:30 Samples were received in good condition at 3.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041629-6364 -Toll Free Number: 1-800/629-6364 - Fax: 704/52"409 Page 3 of 15 if �q GGG Full -Service Analytical 8 Environmental Solutions 3 UBOgATOgIP$ING Town of Mooresville/RR WIMP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 02/28/2019 Client Sample ID. Class A Prism Sample ID: 9020168-01 Prism Work Order: 9020168 Time Collected: 02/11/19 07:03 Time Submitted: 02/11/19 13:30 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 6700 mglkg dry 1600 460 10 'Calculation 2115119 11:63 CLB iCALC] % Solids 96.8 % by 0.100 0.100 1 'SM2640 G 2121/19 9:50 KBS PBB0364 Weight Ammonia as N 1400 mglkg dry 9.7 2.4 1 'SM4500-NH3 C 2114119 15:31 BMS P9150236 Nitrate/Nitrite as N 8.7 mg/kg dry 6.2 1.4 1 'SM4500-NO3 F 2115119 11:63 CLB P980262 pH 6.3 pH Units 1 '9045D 2116119 17:00 CBM P980328 Phosphorus -Total 12000 mg/kg dry 260 58 100 'SM4500-P F 2/21/19 8:29 CLB P980298 Total Kjeldahl Nitrogen 21000 mglkg dry 6200 1500 10 '351.2 2113119 9:06 CLB 1`9130195 Microbiological Parameters Fecal Col'lforms BRL MPNlg dry 0.2 1 'SM9221 E 2/11119 13:39 BMS P9130205 TCLP Extraction by EPA 1311 TCLP Extraction TCLP Extraction TCLP Metals Complete Complete N/A NIA 1 1 '1311 '1311 ZHE 2113119 7:20 2/19119 9:50 MMR TBL P980208 P980322 Mercury BRL mg/L 0.010 0.000030 1 '7470A 2113119 13.44 MMR P9B0213 Arsenic BRL mg/L 0.10 0.016 1 '6010D 2113/19 15:14 JAB P9130217 Barium BRL mg/L 5.0 0.0040 1 '6010D 2/13119 15:14 JAB P9B0217 Cadmium BRL mg/L 0.025 0.00076 1 '6010D 2113119 15:14 JAB PDB0217 Chromium BRL mg/L 0,25 0.0018 1 '6010D 2113H9 15:14 JAB PBB0217 Lead BRL mg/L 0.050 0.0040 1 '6010D 2/13/19 16:14 JAB P9B0217 Selenium BRL mg/L 0.10 0.028 1 '6010D 211311915:14 JAB POB0217 Silver BRL mg/L 0.26 0.0020 1 '6010D 2113119 15:14 JAB PBB0217 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00086 1 '80818 2121119 21:09 ZRC P9130295 Dieldrin BRL mg/L 0.00050 0.000070 1 '8081B 2/21/19 21:09 ZRC P980295 Enddn BRL mg1L 0.00050 0.000075 1 •8081 B 2/21119 21:09 ZRC 1`960295 gamma-SHC BRL mg/L 0.00050 0.000065 1 '8081B 2/21119 21:09 ZRC P960295 Heptachlor BRL mg/L 0.00050 0.000085 1 '8081B 2/21/19 21:09 ZRC P9130295 Heptachlor Epoxide BRL mg/L 0.00050 0.000065 1 '8081 B 2/21119 21:09 ZRC P9130295 Methoxychlor BRL mg/L 0.00050 0.00020 1 •8081B 2/21119 21:09 ZRC P960295 Toxaphene BRL mg/L 0.025 0.00037 1 •8081B 2121/19 21:09 ZRC PSB0295 Surrogate Recovery Control Limits Decachlorobiphenyl 15 % 13-186 Tetrachloro-m-xylene 14 % 40-134 SE TCLP Semivolatile Organic Compounds by GCIMS 2,4,5-Trichiamphenol BRL mg/L 0.25 0.0016 1 '8270D 2/13119 20:58 JMV P9B0223 2,4,6-Tdchlorophenol BRL mg/L 0.10 0.0018 1 '8270D 2113/19 20:58 JMV P980223 2,4-Dinitrotoluens BRL mg/L 0.050 0.0014 1 '8270D 2/13/19 20:58 JMV P960223 2-Methylphenol BRL mg/L 0.050 0.0018 1 '8270D 2/13119 20:58 JMV PSB0223 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240M - Charlotte, NC 28224-0543 Phone: 704/629-6364-Toll Free Number..l-8001529-6364- Fax: 7041626-0409 Page 4 of 15 �r PR i S M I Full -Service Analytical s //r�ey� Environmental Solutions WG Laboratory Report 02/28/201 9 Town of Mooresville/RR WWTP Project Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample 1D: 9020168-01 P. 0. Box 878 Prism Work Order: 9020168 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 02/11/19 07:03 Time Submitted: 02/11/19 13:30 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Daterrime ID 3/4-Methylphencl BRL mg/L 0.050 0.D015 1 '8270D 2113118 20:58 JMV P9B0223 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 '82700 2113/19 20:58 JMV P9B0223 Hexachlorobutadiene BRL MA 0.050 0.0021 1 '8270D 2113/19 20:58 JMV P960223 Hexachlorcethane BRL mg/L 0.050 0.0017 1 '8270D 2113/19 20:58 JMV P960223 Nitrobenzene BRL mg/L 0.050 0.0026 1 '8270D 2113/19 20:58 JMV P960223 Pentachlorophenol BRL mg/L 0.25 0.0012 1 '8270D 2113119 20:58 JMV PSB0223 Pyridine BRL mg1L 0.25 0.0010 1 '82700 2113/19 20:58 JMV P9130223 Surrogate Recovery Control Llmlts 2,4,6-Tribromaphenol 20 % 43-140 SE 2-Fluorobiphenyl 20 % 44-119 SE 2-Fluorophenol 24 % 19-119 Nitrobenzene-d5 19 % 44-120 SE Phenol-d5 19 % 11-52 Terphenyl-d14 22 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 '8260B 2119119 20:45 KDM P9130356 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 '8260B 2119/12 20:45 KDM P980356 1,4-Dichlombenzene BRL mg/L 0.38 0.00050 1 '8260B 2119/19 20:45 KDM P9130356 Benzene BRL mg/L 0.025 0.0004E 1 '8260B 2/19119 20:45 KDM P9B0356 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 '8260B 2/19/19 20:45 KDM P9B0356 Chlorobenzene BRL mg/L 5.0 0.00062 1 '8260B 2119/19 20:45 KDM P9B0356 Carbon disulfide BRL mg/L 0.050 0.00075 1 •8260B 2/19/19 20:45 KDM PSB0356 Chloroform BRL mg/L 0.30 0.00076 1 '8260B 2/19119 20:45 KDM P9BD356 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 '8260B 2119/19 20:45 KDM P9130356 Tetrachloroethylene BRL mg/L 0.036 0.00098 1 '8260B 2119/19 20:45 KDM P9B0356 Trichloroethylene BRL mg/L 0.025 0.00078 1 '8260B 2119/19 20:45 KDM PSB0356 Vinyl chloride BRL mg/L 0.020 0.00097 1 '8260B 2119119 20:45 KDM P9130356 Total Metals Aluminum 9600 mg/kg dry Mercury 0.22 mg/kg dry SAR Soil Preparation Complete g SAR Percent Moisture 88.4 % by Weight Arsenic 1.6 mglkg dry Sodium Absorption Ratio 1.3 [blank] Cadmium 0.30 mg/kg dry Calcium 8900 mglkg dry Surrogate Recovery Control Limits 4-Bromofluorobenzene 92 % 80-124 Dibromofluoromethans 85 % 75-129 Toluene-d8 98 % 77-123 5.2 0.76 1 '6010D 2/18/1916:40 JAB P980293 0.062 0.0069 3 '7471B 2121119 16:11 MMR P980366 1 '2-78-054 2/19/19 8:50 MMR P9B0294 0.100 0.100 1 •2-78.064 2120119 9:00 MMR P9130321 1.0 0.063 2 '6010D 2120119 21:28 JAB PSB0293 0.30 0.016 1 `2-78-054 2/20119 22:21 JAB PSB0320 0.26 0.0069 1 '6010D 2M8/19 16,40 JAB P9B0293 10 0.24 1 '6010D 2/18M9 16:40 JAB P9130293 This report should not be reproduced, except In its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 7041629-6364- Toll Free Number: l-800/629-6364- Fax; 7041626-0409 Page 5 of 15 Laboratory Report �, n I �.��..-fib ", R I S Full -Service Analytical 8 ' � I Environmental Solutions 02128/2019 `� W60gATOR1E5 LNG Town of Mooresville/RR VWV(P Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 9020168-01 P. O. Box 878 Prism Work Order: 9020168 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 02/11/19 07:03 Time Submitted: 02/11/1913:30 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DateTme ID Calcium, SAR 140 mg/L 6.0 0.50 50 `6010D 2/20M9 22:21 JAB PBS0320 Copper 120 mg/kg dry 0.52 0.047 1 '60101) 2/18119 16:40 JAB PSB0293 Lead 6.6 mg/kg dry 0.26 0,048 1 '6010D 2118/19 16:40 JAB PSB0293 Magnesium 2100 mglkg dry 2.6 0.24 1 •6010D 2/18119 16:40 JAB PSB0293 Magnesium, SAR 88 mg/L 5.0 0.43 50 '6010D 2120/19 22:21 JAB P9130320 Molybdenum 8.4 mg/kg dry 0.62 0.016 1 "6010D 2118/19 16:40 JAB P9B0293 Nickel 7.3 mglltvq dry 0.62 0.019 1 '6010D 2/18/19 16:40 JAB P9B0293 Potassium 2900 BH mglkg dry 13 0.46 1 '6010D 2M8119 16:40 JAB P9B0293 Selenium 2.2 mg/kg dry 0.52 0.12 1 •6016D 2118H9 16:40 JAB P9130293 Sodium 760 mg/kg dry 31 1.0 2 '6010D 2120119 21:28 JAB PSB0293 Sodium, SAR 80 mg/L 25 0.90 5o •6010D 2120119 22:21 JAB P9B0320 Zinc 280 mg/Itq dry 26 0.92 10 •6010D 2119/19 17:06 JAB P980293 This report should not be reproduced, except In its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NO 28224-0543 Phone: 704/629.6364 -Toll Free Number: 1-8001629.6364 - Fax: 7041626-0409 Page 6 of 15 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final DateMme 9020168-01 P9B0195 O.05 g 25 mL 02/12/19 1200 Prep Method: SM4600-NH3 B Lab Number Batch Initial Final DatelTime 9020168-01 P9B0236 1.07 g 50 mL 02/14/19 9:06 Prep Method: SM4500-PBS Lab Number Batch initial Final Date/Time 9020168-01 P9B0298 1 g 50 mL 02/18/19 10:39 Prep Method: 1311 Lab Number Batch Initial Final Datefrime 9020168-01 PSB0208 100 g 2000 mL 02/12/19 14:50 9020168-01 P9B0322 12.5 g 250 mL 02/18/19 15:45 Prep Method: 3010A Lab Number Batch Initial Final DatelTime 9020168-01 P9B0217 10 mL 50 mL 02/13/19 9:20 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 9020168-01 F`00213 20 mL 30 mL 02/13/19 8:40 Prep Method: 3510C GC Lab Number Batch Initial Final Date/rime 9020168-01 P9130295 200 mL 10 mL 02/18/19 9:20 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 9020168-01 PSB0223 200 mL 1 mL 02/13/19 11:52 Prep Method: 6030E Lab Number Batch Initial Final Date1Time 9020168-01 P9B0356 1 mL 10 mL 02/19/19 12:13 Prep Method:3010A Lab Number Batch Initial Final Date/Time 9020168-01 PSB0320 50 mL 50 mL 02/19/19 8:50 9020168-01 PSB0320 50 mL 50 mL 02/19/19 8:50 Prep Method: 3050E Lab Number Batch Initial Final Date/Time 902016"1 P980293 2 g 50 mL 02/18/19 8:20 9020168-01 P9B0293 2 g 50 mL 02/18/19 8:20 9020168-01 PgB0293 2 g 50 mL 02/18/19 8:20 9020168-01 PSB0293 2 g 50 mL 02/18/19 8:20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529.6364 - Toll Free Number 1-8001629-6364 - Fax: 704/525.0409 Page 7 of 15 Sample Extraction Data Prep Method: 7471 B Lab Plumber Batch Initial Final DatelTime SD20168-01 P9B0366 0.6 g 50 mL 02121/19 9:10 Prep Method: SAR 2-78-064 Lab Number Batch Initial Final DatelTme 9020168-01 P930294 250 g 250 g 02/18/19 8:20 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 9020168-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number.,1-8001629-6364 - Fax: 704152"409 Page 8 of 15 ®Q S M IFull-Service Analytical & Environmental Solutlons R 449 Springbrock Road • Charlotte, NC 28217 Phone 7041529-6364 Fax:704152"409 Client Company Name: 0 viA pfL iv 10Oca-a-lk- Report To/Contact Name: vL^w— Reporting Address: P, 0 . OX 8N AkO�%'At. tic, mils- Phone•-4J60'3 —� CHAIN OF CUSTODY RECORD PAGE OF QUOTE D TO ENSURE P OPER e1LLING: Project Name: R.'u � c$� Short Hola Analysis: lies (No) UST ProjecN es) 10 *Please ATTACH any pro ct specific reporting (QC LIe1l I I iII IV) provisions and/or QC Requirements Invoice To: �OrAAti Gr- MOor&4k Address: Samples, INTACT upon arrival? Recelved ON W& ICE? PROPER,PRESERVATNES indicated? Received WITHIN' HOLDING' TIMES? CUSTODY SEALS' INTACT? V.OLATILES reed W10UT HEADSPACE? PROPER7-CONTAINEI2S. used? TEMP: ,Therm ID L'L 'r'! .,Observe u*) r M . _ ( es) (No). Purchase Order No./Billing Reference ErTta11 Address: tl1)1V�W 6't'�fgsµ {e, rtG • qpV TO BE FILLED IN BY CLIENTiSAMPLING PERSONNEL Requested Due Date O 1 Day O 2 Days U 3 Days O 4 Days O 5 Days EDD Type: PDF Excelel Other •Working Days" 17 6-9 Daystandard 10 Rush Work Must Be Certification: NELAC DOD FL NC days O Pre Approved Site Location Name: Samples received after 14:00 will be processed next business day. SC OTHER NIA Site Location Physical Address: Turnaround time is based on business days, excluding weeltends and holidays. Water Chlorinated: YES NO1_ (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YEZZNO CLIENT TIME + MATRIX DATE COLLECTED (SOIL, SAMPLE CONTAINER _�_.__ i i PRESERVA- AqLYSIS REQUESTED :�j .{Ti \tlti�',/ PRISM *TYPE NO. SIZE SAMPLE DESCRIPTION COLLECTED MILITARY I WATER OR j T1VE3 QYY REMARKS �� LAB HOURS SLUDGE) SEE BELOW i t oy� .�j' eb ID NO. az o soy �_ -KI.o c i I I I ! I _ f i , , I I i I ? i i Sampler's Signature � Sampled By (Print Name) 4�Aee t �h cq ' Affiliation t4AA / Upon relinquishing, this Chain o ustody Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted In writing to the Priam Project Manager. There will be charg for any changes after analyses have been Initlajlzqd. • (Signaluro Reoe ( Ignalum) _ Dale Additional Comments: t � �MWInlymours 7Sa!e!!lTime:Retinqulshed Y: (8 m) oety By. ( gnalure) D�'/�.h,,-...i'�rflO��ls i : v Rermquu y(SlpnaluroL, Raoelved or PrismLeboraled Dal �-I '•"^I'` FieidTechFee: 1 �3 3a 8a&o / nqv Mileage: NOWSMipment: N •ALLSAMP coOLE s S PEO S u N cuSTOD S S FOR NSPOR A ON TO E LAIIORA RY ap No. SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST CDC UNTIL RECBVED AT E LABORATORY. f 00 Fed Ex UPS O Haltddalivered Prism Field Service Q Other 6 O O ��201 NPDES: II UST: GRO NDWATER: DRINKING WATER: SO ID WASTE: RCRA: jj CERCLA LANDFILL OTHER: •' aNCOSCI ❑5C I O�NC ❑SC I ANC ❑SC ❑SC I OONCOSCI OSC I (3NC OSCI OOSC ' ❑nTz ❑ONC 13 3INC v��C •CONTA • ; '--,TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cal k = Volatile Organics Analysis (Zero Head Space) Of `'AL � ' B S Full -Service Analytical & Environmental Solutions LABORATORIES INC 449 Springbrook Road • Charlotte, NC 28217 Phone 704/529.6364 Fax: 70�41525-0409 I O Client Company Name: WA,4Z /V\WrISAJ1- Report To/Contact Name: AAllWiVnem M"Pk- Reporting Address: P.-0r 6y, _ JJ�tmtleaallt�,�... 7.$1t� CHAIN OF CUSTODY RECORD PAGE __'IP— OF �` QUOTE 0 TO E@BSURE-PROPER BILLING; Project Name: _il� aliQ'Cibt.A") Short Hold Analysis: es (No) U— ST Proj ct (Yes) (QVO *Please ATTACH any pro-IM specific reporting (QC LEVEC)I III IV) provisions and/or QC Requirements Invoice To: -rk44-, of IADOC� Address: YES NO NIA r Samples INTACT upon. arrival? / Received ON WET ICE? �_ _16 o PROPER PRESERVATIVES indicated?_ r Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? ll VOLATILES redd,WiOUT HEADSPACE? PROPER'CONTAINERS used? TEMP: Therm ID,' / - / Observed. 7 � °C !Carr elC rnone: •nri—LgNb-5 A6w I-ax (Yes) (No): Purchase Order No./Billing Reference Email Address: TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL EDD T yp e: PDF ✓ ExCel_Other � Requested Due Date O i Day O 2 Days ❑ 3 Days 04Rush Certification: NELAC DOD FL NC Working Days" ❑ 6 9 Daysstendard 10 days ❑ Wark Must ae Pre -Approved Site Location Name: Samples received after 14:00 vn'll be processed next business day. Sc OTHER N/A Site Location Physical Address: Tumamund time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO_-__ (SEE REVERSE FOR TERMS 8 CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES_ NO TIME MATRIX SAMPLE CONTAINER ANALYSIS REQUESTED PRISM CLIENT SAMPLE DESCRIPTION DATE COLLECTED COLLECTED MILITARY (SOIL, WATER OR PRESERVA- `TYPE I NO. SIZE TIVES ' REMARKS •,' `, LAB ID NO. i HOURS �,0 SLUDGE)i SEE BELOW I '. 4% eLes {a - I i-I9 5oi1 d1 I i ' I i ! { I I I �I I I SampiePs Signature Sampled By (Print Name) \At4 „c\c-L Affiliation Upon relinquishing, this Chain of Custody Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been Initialized. e q Ia ed ignaNre) Recelve : (Signature) ` Date N111tarylHours Additional Comments: Site Arrival rme: Relinquished By: ig [ure) ROcalVed By. (Signature) oaf ry \�/ Site Departure Time' �(i (� �, ,lt�I Resin Is y: (signatur8) Res For Prism Laborato Data 1 l l k i `� I V•N I QA [ Field Tech Fee: Mileage:ALLSA WIMhoMShipment NOTE: MPLE COD RS SHOULD BE TA SHUT WITH CUSTODY SEALS FO TRA SPORTATION TO LABORATORY C up No. I SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COG UNTIL RECEIVED AT HE LABORATORY. r �� l s$ I I N O Fed Ex ❑ UPS ❑ Hand -delivered �r(sm Feld Service ❑ Other ��01 NPDES: UST. TER: D i,SS-ENC0SCION �NKING CATER: IONC ❑ SCNC El SC ONC ❑ SCC❑CSC [INCNC O SC I LI C ❑ SCIO I I l7 11 ❑ *CONTAr, — -YPE CODES: A= Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap ' "- = Volatile Organics Analysis (Zero Head Space) ut (tutivrl- AcCE55 ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT E D 9020168 LABORATORY REPORT NUMBER 1902B08 DATE February 18, 2019 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES. PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory 9 98016, NCDENR certified lab 9 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, hictols, PCI11 Asbestos, Grnvimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examinafion. - Local support services For this project tire provided by Access Analytical, Inc. Access Analytical is a representative oFAES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or loll fee at 883.315.4243 Page 0 6page 11 of 15 �- 1 � }� I Environmental Analytical s �] Environmental Solutions t �o2ft SUBCONTRACT ORDER Certiiitaiioi • NL:LAC LFSACE•� Prism Laboratories, Inc. NC SC Other 90207168 N/A SE, NDING LABOR&TORY: RLTCE1i/1NG LABORATORY: Frism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte„ NC 28224-0543 Atlanta, GA30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA Project Manager: Ten!W. Cole Analysis Due Expires Laboratory ID Comments SatnpleID: 902016S-01 Solid Sampled:02111/1907:03 ? ?" Herbicides TCLP (Sub) 02118/19 07:03 'antat rsSuppliad: x L k r inr- Re dex 2-13-I01 lt?•01 Released By Date Received By Date Released By crate Raccivod By Date Page 1 of I Page Page 12 of 15 Analytical )Environmental Services, Inc Date: IB-Feb•19 Client: Prism Laboratories Client Sample 1D: CLASS A Lab Order 19021308 Tag Number: 9020168-01 Project Name: 9020168 Collection Date: 2/11/2019 7:03:00 AM Lab ID: 19021508-001A Matrix: Solid Analyses y Result Qua] MDL Reporting Units nits BatchlD DF Date Analyzed Analyst HERBICIDES, TCLP SWJ311/8151A (SWW3510C) 2,4,5-17(Silvex) BRL 0.030 020 mgjL 274527 1 02/15201917:35 HB 2,4 D BRL 0.051 020 mg/L 274527 1 02/15201917:35 HB Surr. DCAA 62.9 0 494-120 %RFC 274527 1 02/T5201917:35 HB Quallumv. ° Vnlue exceeds maximum contnnunan level BRL Not Deleacd at MDL JI Holding fines for jampamfien nr nnalys. excecdcd N Analyle not NELAC eoairled a Analyle detected in the assoctawd method blank E Eshmased %alue alim cliamranon range S Sprhe Rcmvey omside [units due to main, > Greater than Result value J Esumaled tnlue delecmd below Reporting Luwt Less ihm+Rusulc ai je Page I Page 13 of 15 A�,�In-ncnt. At=S IStrt,'Rets lac Al SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. 2, Carrier: FeclEx Loo ups ❑ usps❑ Client❑ Courier❑ Othet 3. 4. S. 5. 7. S, 9. 10. 11 12. V— M- hI/A AES Work Order Number. 1902BOS Clear Save as shipping container/cooler received In good condition? o damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? b o Custody seals intact on shipping.00ntainer? Temperature blanks present? o Cooler temperature(s) within limits of D-6°C? [See item 33 and 14 for temperature recordings.] ® py Cooling initiated for recently collected samples / Ice present ❑ Chain of Custody (COC) present? o Chain of Custody signed, dated, and timed when relinquished and received? o Sampler name and/or signature on CDC? Were all samples received within holding time? o TAT marked on the COC? o If no TAT Indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 2.0 °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C 14, Cooler 5 Temperature °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 9 Temperature °C 15 Comments: I certify that 1 have completed sections 1-15 (dated initials). AP 2/13119 V.. Wn rd/A ...:�. 16. 17 is. 19. 20. 21. 22. 23_ 24. 25. 26. 27. Comments: This section only applies to samples Where pH can be I certify that I have completed sections 16-27 (dated initials). HB 2/13/2019 checked at Sample Receipt. yes No N/A natan. Were sample containers Intact upon receipt? o Custody seals present on sample containers? o. Custody seals Intact an sample containers? o Do sample container labels match the CDC? ® ® Incomplete info ❑ illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the CDC? o Were all of the samples listed on the CDC received? Was the sample collection date/time noted? 0 on 0 0 samples received but not listed on COC � 1.1 samples listed on CDC not received n Did we receive sufficient sample volume for indicated analyses? o Were samples received In appropriate containers? o Were VOA samples received without headspace (<1/4° bubble)? tisted on CDC n not listed on CDC ❑ Were trip blanks submitted? 2& Have containers needing chemical preservation been checked? v 29, Containers meet preservation guidelines? a 30. Was pH adjusted at Sample Receipt? o rvure: uena+n analyses require cnermcal preservation out must oe enecKW In the laboratory and not upon Sample Receipt such as Collforms, VOCs and Oil & GreaswTPH. certify that I have completed sections 29-30 (dated initials). HB 2/13/2o19 Checklist 6.9.17 Rev 2 Locked Page 4 of 5 Analytical Environrnental Services, Inc Date: 18-Feb-19 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 9020168 Workorder. 1902B08 BatchID• 274627 Sample ID: NIB-274527 Client 1D: Units: mg/L Prep Date: 02/95/2019 Run No: 391204 SampleType: MBLK TestCode: HMBYCMM TCLP SWI31119151A BatchlD: 274527 Analysis Date: 02/15/2019 Seq No: 8754609 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD WWI a/oRPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2.4-D BRL 0.20 Surr: DCAA 0.3190 0 0.5000 63.8 49.4 120 Sample TD: LCS-274527 Client TD: Units: mg/L Prep Date: OV15/2019 Run No: 391204 SamplcType: LCS TestCode: HERBrctDES.TCLP Swt311/8151A BatchfD:274527 Analysis Date: 02/1512019 Seq No: 8754610 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2.4,5-TP (Silvex) 03618 0.20 0.5000 72.4 49 120 2.4-D 03924 0.20 0.5000 76.5 50.9 120 Surr: DCAA 0.3595 0 0.5000 719 494 120 Sample TD: 002B62-002BATS Client ID: Units: mg/L. Prep Date: 02115/2019 Run No: 391204 SampleType: MS TestCode: HERBICIDES,TCLP MUMMA BatchID: 274527 Analysis Date: 02/15/2019 Seq No: 8754613 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4.5-TP (Silvex) 03537 020 0.5000 70.7 48.2 120 2A-D 03570 0.20 0.5000 714 45 130 Surr: DCAA 03639 0 0.5000 72.8 49.4 120 Qualifirs- Grcale, than Result salue BRL Belowrepnni.ghmit f Estimmed valuodeteaed bclowRepurting Limit Rpt Lim Reporting Limit < Less than Resultvalue E animated (value above quantilation range) N Analyze not NELAC certified S Spike Recovery outside limits due to matrix 9 :tndyte dctated in the associated metirod hlenk H Holding omesfor preparation or mnlysis exceeded R RPD outside limits due tomatsix Page 5 of 6 P I C% M ' " i-, K.- �.� LABORATORIEa INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 04/22/2019 Prism Work Order. 9040345 Case Narrative 5/8119 16:29 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Analysis note for SAR: SAR =[Na]/SQRT(([Ca]+[Mg])/2) SAR = [ 100/23 ] /SQRT (([240/20] + [150/12.2]) / 2 ) SAR = 1.3 Concentrations for Na, Ca, and Mg are expressed in milliequivalents per liter, and SQRT designates taking the square root of the operand in parentheses. PAN Equation = 0.3 * (TKN — Ammonia) + 0.5 * (Ammonia) + Nitrate —Nitrite PAN = 0.3 * (25000 — 1900) + 0.5 * (1900) + 2.6 PAN = 7900 mg/kg Equation uses Mineralization Rate (MR) for Aerobically Digested Solids (0.3) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224.0543 Phone: 704/529-6364 - Toll Free Number. 1-8001529.6364- Fax: 7041526.0409 Page 1 of 15 Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. r Terri W. Cole Project Manager Data Qualifiers Key Reference: DM Sample diluted and RL increased due to the matrix. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference i Reviewed By Terri W. Cole Project Manager Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364- Toll Free Number..1-8001529-6364- Fax: 7041625-0409 Page 2 of 15 PrjR I MTOPI Full -Service Analytical & ,.,:' V' Environmental Solutions ,awIABO1Eg ING Sample Receipt Summary 05/08/2019 Prism Work Order: 9040345 Client Sample ID Lab Sample ID Matrix DatelTme Sampled Date/Time Received Class A 9040345-01 Solid 04/22/19 8:42 04/22/19 11:33 Samples were received in good condition at 3.4 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 26224-0543 Phone: 7041929-6364 - Toll Free Number: 1-8001629.6364 - Fax: 7041526-040S Page 3 of 15 �. `� I S I Y I I Full-Service Analytical s Environmental Solutions L 00RANQP A INC Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 05/08/2019 Client Sample ID: Class A Prism Sample ID: 9040345-01 Prism Work Order. 9040345 Time Collected: 04/22/19 08:42 Time Submitted: 04/22/1911:33 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Datemme ID General Chemistry Parameters Plant Available Nitrogen 7900 mglkg dry 70 30 20 *Calculation 517119 9:26 CLB ICALCI % Solids 96.9 % by 0.100 0.100 1 'SM2640 G 511119 16:19 KBS P9E0019 Weight Ammonia as N 1900 mglkg dry 10 2.6 1 'SM4500-NH3 C S12/19 16:15 BMS PSE0026 Nitrate/Nitrite as N BRL mg/kg dry 6.2 1.4 1 'SM4500-NO3 F 4/26/19 9:02 CLB P9D0467 pH 6.2 pH Units 1 •9045D 4/24119 16:35 CBM PSD0461 Phosphorus -Total 12000 mglkg dry 520 160 100 •SM4500-P F 4125119 8:20 CLB PSD0424 Total Kjeldahl Nitrogen 25000 mg/kg dry 210 94 20 '361.2 617119 9:25 CLB P9D0542 Microbiological Parameters Fecal Coliforms BRL MPN/g dry 0.2 1 'SM9221 E 4/22119 12:45 BMS P9130398 TCLP Extraction by EPA 1311 TCLP Extraction TCLP Extraction TCLP Metals Complete Complete N/A NIA 1 1 •1311 '1311 ZHE 4/23119 7:10 4/24119 9:00 MMR TBL P9D0368 PSD0410 Mercury BRL mg/L 0.010 0.00016 1 '7470A 4/23/19 15:26 MMR P9D0386 Arsenic BRL mg/L 0.10 0.030 1 '6010D 4123/19 22:59 JAB P9D0388 Barium BRL mg/L 5.0 0.010 1 '6010D 4/23119 22:69 JAB P9D0388 Cadmium BRL mg/L 0.025 0.0020 1 '6010D 4/23119 22:59 JAB PSD0388 Chromium BRL mg/L 0.25 0.015 1 '6010D 4123119 22:59 JAB PSD0388 Lead BRL mg/L 0.050 0.020 1 '60100 4123119 22:59 JAB P9D0388 Selenium BRL mg/L 0.15 0.063 1 '6010D 4/23119 22:69 JAB P900388 Silver BRL mg/L 0.25 0.0045 1 '6010D 4/23119 22:59 JAB PGD0388 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00090 1 '8081B 4/25/19 13:33 ZRC P9D0417 Dieldrin BRL mg/L 0.00050 0.000068 1 `80816 4/25119 13:33 ZRC PSD0417 Endrin BRL mg/L 0.00050 0.000068 1 '8081B 4/26119 13:33 ZRC PSD0417 gamma-BHC BRL mg/L 0.00050 0.000030 1 '8081B 4/25119 13:33 ZRC PSD0417 Heptachlor BRL mg/L 0.00050 0.000065 1 '8081B 4/25119 13:33 ZRC P9D0417 Heptachlor Epoxide BRL mg/L 0.00050 0.00011 1 '8081B 4125/19 13:33 ZRC P9D0417 Methoxychlor BRL mg/L 0.00050 0.000090 1 '80818 4125119 13:33 ZRC PSD0417 Toxaphene BRL mg/L 0.025 0.0018 1 '8081B 4125119 13:33 ZRC PBD0417 Surrogate Recovery Control Limits Decachlorobiphenyl 12 % 13-186 SE Tetrachloro-m-xylene 11 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichloraphenol BRL mg/L 0.25 0.0040 1 '8270D 4/25/19 14:04 JMV P9D0433 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0044 1 '82700 4/25/19 14:04 JMV PSD0433 2,4-Dinitrotoluene BRL mg/L 0.012 0.0032 1 '8270D 4126119 14:04 JMV P9D0433 2-Methylphenol BRL mg/L 0.050 0.0019 1 '8270D 4/25/19 14:04 JMV PSD0433 This report should not be reproduced, except In Its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: l-8001629.6364- Fax: 704162541409 Page 4 of 15 PR i S M I Euviron lea Analytical s Laboratory Report i Environmental Solutions 05/08/2019 . U00fUTOi11E51NG Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 9040345-01 P. O. Box 878 Prism Work Order. 9040345 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 04/22/19 08:42 Time Submitted: 04/22/1911:33 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DatefTlme ID 3/4-Methylphenol BRL mg/L 0.050 0.0025 1 `8270D 4125/19 14:04 JMV P9D0433 Hexachlorobenzene BRL mg/L 0.020 0.0041 1 '82701) 4/25/19 14:04 JMV 139D0433 Hexachlorobutadiene BRL mg1L 0.050 0.0028 1 '8270D 4/25119 14:04 JMV P9D0433 Hexachloroethane BRL mg/L 0.050 0.0023 1 •8270D 4/25119 14:04 JMV P9D0433 Nitrobenzene BRL mg/L 0.050 0.0024 1 '8270D 4/25/19 14:04 JMV P9D0433 Pentachlorophenol BRL mg/L 0.25 0.0033 1 `8270D 4/25/19 14:04 JMV P9D0433 Pyridine BRL mg1L 0.25 0.0023 1 •8270D 4/25/19 14:04 JMV PSD0433 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 33 % 43-140 SE 2-Fluorobiphenyl 33 % 44-119 SE 2-Fluorophenol 39 % 19-119 Nitrobenzene-d5 31 % 44-120 SE Phenol-d5 28 % 11-52 Terphenyl-d14 35 % 50-134 SE TCLP Volatile Organic Compounds by GClMS 1,1-Dichloroethylene BRL mglL 0.035 0.00083 1 •8260B 4/24/19 23:13 KDM P9D0439 1,2-Dichloroethane BRL mg/L 0.025 0.00086 1 '8260B 4/24/19 23:13 KDM P9D0439 1,4-Dichlorobenzens BRL mg/L 0.38 0.00050 1 •8260B 4124/19 23:13 KDM PSD0439 Benzene BRL mg/L 0.025 0.00048 1 •8260B 4/24119 23:13 KDM P9D0439 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 •8260B 4124/19 23:13 KDM P9D0439 Chlorobenzene BRL mg/L 5.0 0.00062 1 *82603 4124/19 23:13 KDM PSD0439 Chloroform BRL mg/L 0.30 0.00076 1 '8260B 4124119 23:13 KDM PSD0439 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 •8260B 4/24119 23:13 KDM P900439 Tetrachloroethylene BRL mg/L 0.035 0.00096 1 '8260B 4124/19 23:13 KDM P9D0439 Trichloroethylene BRL mg/L 0.025 0.00078 1 •8260B 4124/19 23:13 KDM P91)0439 Vinyl chloride BRL mg/L 0.020 0.00097 1 '82608 4/24/19 23:13 KDM P9D0439 Surrogate Recovery Control Limits 4-Bromofluorobenzene 95 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 95 % 77-123 Total Metals Aluminum 11000 mgfkg dry Mercury 0.59 DM mglkg dry SAR Soil Preparation Complete g SAR Percent Moisture 81.6 % by Weight Arsenic 1.4 mglkg dry Sodium Absorption Ratio 1.3 [blank] Cadmium BRL mglkg dry Calcium 9900 mglkg dry Calcium, SAR 240 mg/L 26 5.7 1 '6010D 4126119 15:36 JAB PSD0478 0.52 0.18 10 '7471B 0/19 16:32 MMR P9E0005 1 -2-78 054 4126119 10:00 MMR P91)0462 0.100 0.100 1 '2-78-064 4129119 10:06 MMR P9D0494 1.0 0.14 1 •6010D 4126119 16:36 JAB PSD0478 0.30 0.016 1 •2-78-064 4126/1916:43 JAB PSD0479 0.52 0.035 1 `6010D 4126/19 15:36 JAB PSD0478 100 27 1 '6010D 4126119 16:36 JAB P9D0478 0.10 0.010 1 '60101) 4126119 16:43 JAB P011479 This report should not be reproduced, except in Its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 7041629-6364 - Toll Free Number 1-8001629-6364- Fax: 70W626-0409 Page 5 of 15 1PR ISM I Fun -Service Analytical Environmental Solutions ER80RAToaES I.C. Town of Mooresville/RR VWVTP Attn: Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 05/08/2019 Client Sample ID: Class A Prism Sample ID: 9040345-01 Prism Work Order: 9040345 Time Collected: 04/22/19 08:42 Time Submitted: 04/22/19 11:33 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Copper 140 mg/kg dry ' 26 3.5 10 Lead 6.0 mg/kg dry 1.0 0.17 1 Magnesium 2200 mg/kg dry 26 2.4 1 Magnesium, SAR 160 mg/L 0.10 0.0086 1 Molybdenum 6.6 mg/kg dry 1.0 0.13 1 Nickel 8.7 mg/kg dry 1.0 0.31 1 Potassium 2700 mg/kg dry 100 11 1 Selenium 2.1 mg/kg dry 1.0 0.29 1 Sodium 510 mg/kg dry 100 14 1 Sodium, SAR 100 mg/L 0.60 0.018 1 Zinc 250 mg/kg dry 100 15 10 '6010D 4130119 12:16 JAB P9D0478 '6010D 4/26/19 15:36 JAB PSD0478 '6010D 4126/1915:36 JAB PSD0478 '6010D 4126/19 16:43 JAB PSD0479 '6010D 4/26/1916:36 JAB P9D0478 '601013 4126119 15:36 JAB PSD0478 '6010D 4126/1915:36 JAB 139D0478 '6010D 4126119 15:36 JAB P9130478 '6010D 4/2811915:36 JAB P9D0478 '6010D 4/26M916:43 JAB P9DD479 '6010D 4130/1912:16 JAB PSD0478 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529.8384 -Toll Free Number:1.8001529-6364 - Fax: 704/525-0409 Page 6 of 15 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Datefrime 9040345-01 PSD0542 0.05 g 25 mL 04/30119 SAS Prep Method: SM4600-NH3 B Lab Number Batch Initial Final Date/Time 9040345-01 P9E0026 1.01 g 50 mL 05/02/19 8:56 Prep Method: SM4600-PBS Lab Number Batch Initial Final Date/Time 9040345-01 PSD0424 1 g 50 mL W24/19 10:27 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Daterrime 9040345-01 PSE0019 30 g 30 g 05/01/19 16:19 Prep Method: 1311 Lab Number Batch Initial Final Datemme 9040345-01 PSD0410 12.6 g 250 mL 04/23/19 15:25 9040345-01 PSD0368 100 g 2000 mL 04/22/19 14:35 Prep Method: 3010A Lab Number Batch Initial Final DatefTme 9040345-01 P91)0388 10 mL 50 mL 04/23/19 10:35 Prep Method: 7470A Lab Number Batch Initial Final Datelrime 9040345-01 P9D0386 20 mL 30 mL 04/23/19 9:05 Prep Method: 3610C GC Lab Number Batch Initial Final Date/71me 9040345-01 P91)0417 200 mL 10 mL 04/24/19 9:15 Prep Method: 3610C MS Lab Number Batch Initial Final Date/Time 9040345-01 P9D0433 200 mL 1 mL 04/25/19 8:43 Prep Method: 6030B Lab Number Batch Initial Final Date/11me 9040345-01 P900439 1 mL 10 mL 04/24119 7:46 Prep Method: 3010A Lab Number Batch initial Final DatefTime 9040345-01 P91)0479 50 mL 50 mL 04/26/19 10:05 9040345-01 P91)0479 50 mL 50 mL 04/26/19 10:05 Prep Method: 3060B Lab Number Batch Initial Final DateMme 9040345-01 P9D0478 2 g 50 mL 04/26/19 8:10 9040345-01 PSD0478 2 g 50 mL 04/26/19 8:10 This report should not be reproduced, except in fts entirety, without the written consent of Prism Laboratories, lnc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 29224-0643 Phone: 7041529.6364-Toll Free Number. 1-800/629-6364 - Fax: 704JS26-0409 Page 7 of 15 Sample Extraction Data Prep Method: 74716 Lab Number Batch Initial Final Date/rime 9040345-01 P9E0005 0.8 g 50 mL 05/01/19 8:55 Prep Method: SAR 2 78-054 Lab Number Batch Initial Final DateMme 9040345-01 PSD0462 250 g 250 g 04/25/19 10:00 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 9040345-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc, 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-OM Phone- 7041529-6364 -Toll Free Number. 1-8001629-6364 - Fax; 704/625-0409 Page 8 of 15 x` RISM .,...,_ IABOAATOnIee.INC. Full -Service Analytical & Environmental Solutions 449 Springbrook Road •Charlotte, NC 28217 Phone 70M529 8384` Fax: 7041525-0409 Client Company Name: ®►w` o BfP. Q1,L. Report To/Contact Name: Wn tAA- Reporting Address: .-2.dl CHAIN OF CUSTODY RECORD PAGE OF j2_1QUOM S TO eNs PROPER BILLINGS Project Name: Gas (T L� SI > Short Hold Analysis: es (No) UST Project: (Yes) O *Please ATTACH any project specific reporting (QC LEVE121II ill provisions and/or QC Requirements vv Invoice To: Tow, or- Meoc"Ak, Address: YES NO N/A Samples INTACT upon amval7 T Received ON*ET ICE? _ O PROPER; PRESERVATIVES;Indic3ted7 RecelvedWITHIN'HOLDINGTIMES? pl CUSTODY� SEALS INTACT?. VOLATILES:rec d WiOUf HEADSPACE? ll f1 G PROPER CONTAINEwused? trio): Purchase Order No./Billing Reference Email Address:tJJUbatAI'YO rmort6dV► %tii0-, a V TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Requested Due Date 01 Day O 2 Days O 3 Days O 4 Days O 5 Days Certification: NELAC DOD FL NC I/ EDD Type: PDF Excel Other 'Working Days' O 6-9 Days�tandard 10 days p Rush Work Must Be Site Location Name: Pre -Approved Samples received after 14:00 will be processed next business day. Turnaround time Is based business days, SC OTHER NIA T Site Location Physical Address: on excluding weekends and holidays. Water Chlorinated: YES NO V (SEE REVERSE FOR TERMS 8 CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. To CLIENT) Sample Iced Upon Collection: YES NO_ CLIENT SAMPLE DESCRIPTION t � DATE COLLECTED TIME COLLECTED MILITARY MATRIX {SOIL, SAMPLE CONTAINER PRESERYA- ANb �� o REMARKS PRISM LAB 4TYPE WATER OR NO. SIZE TiVES \� ID NO. HOURS SLUDGE) SEE BELOW V� �0 Q 6011 Q I I I _ , M - >l **V `I i, • • • �� Sampler's Signature Sampled By (Print Name) 1' w. 1I8 Affiliation Te tn,, Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted In writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. PRISM USE ONLY Rol ulahod By: IS lureRace N y: 8l9nawre) ` ueZ2 s m Additional Comments: Site ArrivalTime: C-Of�rw ! Rel ed By: (Signs coly y: Igde u ) ate I W� V'0 6"t Site Departure Time: ION Yti?it0�$ R•Iinquished . ( gnelvro) � ,-^ Racalvad P en ey: pale +J Field Tech Fee: ,J r J /Z, `��—. 7 2�'�n 8�i1Ax" Mileage: a NOTE: ALL SA OLD BE TAPE 9 T CU IOR TRANSPORTATION TO THE LABORATORY. C C Grcu o. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RE09WEDATTHELABORATORY. ❑ Fed Ex O UPS O Hand -delivered ><;sm Fleld Service Q Olhar NPDES, UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: j E aOf SC ❑ NC ❑ SC ❑ NC ❑ SC I ❑ NC ❑ SC �VC ❑ SC I ❑ NC ❑ SC I NC ❑ SC NC ❑ SC I U NC ❑ SC ❑ ❑ ❑ ------ - — ❑ ❑ ❑ o I o 'CONTR1"01? TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -tined Car +1^4 = Volatile Organics Analysis (Zero Head Space) 0 JAL 3 1 I FullService Analytical Environmental Solutions LABORATORIES INO. 449 Springbrook Road • Charlotte, NC 28217 Phone 7041529..63�6•4 Fax:7041525-0409 Client Company Name: f0 ag. Mnwr&A key Report To/Contact Name: S uArbiL Reporting Address: vi11� G �$1 is Ph 1—b(on-3-41. CHAIN OF CUSTODY RECORD PAGE LT?= OF _-74wOTE i TO ENSURE PROPER OILLMO.- Project Name:(bits� t✓ Short Hold Analysis: es (No) UST Project: DW O *Please ATTACH any project specific reporting (QC LEVE� 10 IU provisions and/or QC Requirements '� InvoicaTa• _ f �Of 46_%m& oAg4 Address: Samples INTACT, upon arrival? V Received ON WET ICE7 PROPE'RPRESERVATIVES indicaleil?" Received WITHIN;HOLDING'TIMES? CUSTODY SEALSI INTACT? VOLATILES raddiW/OUT HEADSPACE7k,, �- .-_Observed: one. Fax (Yes) (No). Purchase Order NoJBIIUng Reference Email Address: roils It 0 TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL v%c.• Requested Due Date O 1 Day 132 Days O 3 Days 134 Days Q 5 Days EDD Type: PDF_Excel�Other Certification; NELAC DoD FL NC Be _ "Working Days" O 6-9 Days standard 10 days 0 orr& ppro ed Site Location Name: Samples received after 14:00 will be processed next business day. SC OTHER NiA Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES NC (SEE REVERSE FOR TERMS i CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENn Sample Iced Upon Collection: YES NO TIME MATRIX SAMPLE CONTAINER t A\NALYSM REQUESTED CLIENT DATE COLLECTED (SOIL, PRES�ERVA• ` , I PRISM TYPE SEE BELOW NO. SIZE SAMPLE DESCRIPTION COLLECTED MILITARY HOURS WATER OR SLUDGE) TI /�j'>v f A�' REMARKS , : � `C` � f LAB ID NO. De, A K I�a�l 08= oa S °i l I i Sampler's Signature4wyp 18ampled By (Print Name) 44W..-, Affiliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be char for any changes after analyses have been initialized. he y; gnat ) ace y g7ne rue ere ~ I Dora Additional Comments: : site ArtivaI Time: ., nqula eo y (Sim 9 I Iwtray s, eturel Dete I ' 'Site,DapartureTime: RelingWshe y: Sign7 aturek,7l Flea ey. D Feld Tech Fee - � ' Bd enL'" O SAMPLE COOLERS SHOULD BET SHUT U PORrAT ON TO THE ORATORY. C C ro NO. i ge: • Mileaip SAMPLES ARE NOT ACCEPTED AND VERIFH?DAGAINST CDC UNTI E ATTHELABORATORY. 0 D Fed Ex UPS 0 Hand -delivered rvice Pdam Field Se0 Olher �� J NPDES: UST GROUNDWATER: DRINKING WATER: II SO -LID WASTE: RCRA: CERCLA LANDFILL OTHER: NC ❑ SC j.JgNC Q SC ' QNC Q SC I aNC Q SC I Q NC Q SC I Q NC 0 SC O NC CI SCI QQ NC ❑ SC I O NC ❑ SC I a ' D o ❑ *CONTi" "�- TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Ca , • 7A = Volatile Organics Analysis (Zero Head Space) 0 IAL ACCESS la NALWICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 9040345 LABORATORY REPORT NUMBER 1904N72 DATE April 30, 2019 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aainick@axs-inc.com - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, POVI Asbestos, Gravimctric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc: Access Analytical is a representative ofAES serving client in the SCINC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883 315 4243 Page A 49;Pagel 1 of 15 PRII Enil rcinmee Analytical s Environmeniai Solutions ". LtoCiLtit6n1FAR:,�. 1ga�N'la SUBCONTRACT ORDER CertiAca 'or p NELAC_ iJSACE Prism )Laboratories, Inc. N SC Otitsr 9040345 N1 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3090 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA ProjectManager: Teiri W. Cole Analysis Due Expires Laboratory ID Comments Samp]e ID; 9040345-01 Solid Sompled:04l22119 08:42 j f.l '�S J Aif Herbicides TCLP (Sub) roe 04129/19 08.42 q.z7 0 Y�L3��4 � �fCo,Qq Released By Date Received By Dntc Rcicascd By Date Rcceived By Date Pace I of 1 Page Page 12 of 15 Analytical Environmental Services, Inc Dates 30-Apr-19 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1904N72 Tag Number: 9040345-01 Project Name: 9040345 Collection Date: 422/2019 8:42:00 AM Lab ID: 1904N72-001A Matrix: Solid Analyses Result Qual MDL ReportingLimit Units BatchID DF Date Analyzed Analyst HERBICIDES, TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.030 0.20 mg/L 278276 1 04129201917:39 HB 2,4-D BRL 0.051 020 meAL 278276 1 0429201917.39 HB Sun-. DCAA 549 0 49.4-120 %REC 278276 1 0429/201917:39 HB Qualiaers %blue exceeds maximum comattinam level E Esnmmed value above iltiamnahon range BRL Not Dclected at MDL S Spike Recovery outside limits due to main% H Holding times far preparation or analysis mceedcd > Grewerthan Result calve N Analvte rim NELAC certified J Estimated calve detected below Reporting Limit B Analyte detected in the associated mnhod blank < Less than Result calve Page Page 13 of 15 f:l AhmixricAii. JENVIRONIiUMMAL ABS SEtevi s.we. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. 2. Carrier: FedEx Q UPS ❑ USPS❑ Client❑ Courier❑ Othei 3. 4. 5. 6. 7. B. 9. 10. IL 12. vnc rd. N /A AES Work Order Number: 1904N72 Clear camas Shipping container/cooler received In good condition? v damaged D leaking ❑ other[] ............... Custody seals present on shipping container? o Custody seals intact on shipping container? o Temperature blanks present? Cooler temperature(s) within limits of 000 {See item 13 and 14 for temperature recordings.] ® ® Cooling Initiated for recently collected samples / Ice present ❑ Chain of Custody (CDC) present? o Chain of Custody signed, dated, and timed when relinquished and received? a SIGNATURE & DATE ONLY Sampler name and/or signature on CDC? o Were all samples received within holding time? o TAT marked on the COC? o If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 4.8 14, CoolerSTemperature 15. Comments; 16. 17 Is. 19. 20. 21. 22. 23. 24. 25, 26. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). MJ 4/23/19 vex ni torn Were sample containers intact upon receipt? o Custody seals present on sample containers? o Custody seals intact on sample containers? o Do sample container labels match the COC? Co 0 ® incomplete Info Lj Illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? o Were all of the samples listed on the COC received? E) ® ® samples received but not listed on COC samples listed on COC not received ❑ Was the sample collection date/time noted?. o o Did we receive sufficient sample volume forindicated analyses? Were samples received in appropriate containers? o Were VOA samples received without headspace (< 1/4" bubble)? o Were trip blanks submitted? © listed on CDC ❑ not,listed on COC ❑ 27. Comments; This section only ap Ilas to samples where pH can be I certify that I have completed sections 16-27 (dated InItlaIs). EW 4/23/19 checked at Sample Receipt. Yes No N/A Details 28. � 29. 30. Have containers needing chemical preservation been checked? * o• Comments Containers meet preservation guidelines? o. Was pH adjusted at Sample Recelpt7 0 Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. j I certify that I have completed sections 28-30 (dated initials). EW 4/23/19 O Checklist 6.9.17 Rev 2 Locked Page 4 of 5 Analytical Environmental Services, Tne Date: 30-Apr-19 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 9040345 Workorder: 1904N72 I3abchil): 278278 Sample 1D: MB-.278276 Client TD: Units: mg/L Prep Date: 04/29/2019 Run No: 397006 SamplcType: MBLK TestCode: HERRICIDES,TCLP SW1311ISI5IA BatchlD: 278276 Analysis Date: 04/29/2019 Seq No: 8892500 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.2532 0 0.5000 50.6 49.4 120 Sample TD: LCS-278276 Client ID: Units: mg/L Prep Date: 04/29/2019 Run No: 397006 SamplcType: LCS TestCode: 1+ERBICIDES,TCLP SW13111815IA BatchID: 278276 Analysis Date: 04/29/2019 Seq No: 8892501 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qua] 2.4,5-TP (Silvex) 0.2692 0.20 0.5000 53.8 49 120 2.4-D 02681 0.20 0.5000 53.6 50.9 120 Surr: DCAA 02668 0 0.5000 53.4 494 120 Sample ID: 1904N72-OOIAMS Client lD CLASS A Units: mglL Prep Date: 04/29/201.9 Run No: 397006 SamplcType: MS TestCode. JlERBICIDES. TCLP SW13111815tA BatchlD: 278276 Analysis Date: 04/29/2019 Seq No: 8892503 Analyle Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4.5-TP (Silvex) 02807 0.20 0.5000 56 1 48.2 120 2,4D 02704 0.20 0.5000 54.1 45 130 Surr: DCAA 0.2613 0 0.5000 52.3 49.4 120 -0 Quallrme= n Greater than Result value < Less thanResultvalue a Analyle defected mthe assneiated method blank ca CD BRL Below repoilin6 Itmrt E Eslimaled (volue above quanllialion range) H Holdinglimes for preparation or onalyais exsxoded —'' J Estimated voluo defected below Reporting Limit N Anolyto not NELAC cetiaed K RPD otusidellmitsdueto matrix 01 0 Rpt Uto Reporting Limit S Spike Recovery oulsido limits due to matrix Page 5 of 5 _"PRISM _ 'LABOAATOA0% INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 NC certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 07/08/2019 Prism Work Order: 9070083 Case Narrative 7/29/19 13:59 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Analysis note for SAR: SAR =[Na]/SQRT{([Ca]+[Mg])/2} SAR = [ 180/23 ] / SQRT { ([280/20] + [100/12.2]) / 2 } SAR = 2.4 Concentrations for Na, Ca, and Mg are expressed in milliequivalents per liter, and SQRT designates taking the square root of the operand in parentheses. PAN Equation = 0.3 * (TKN — Ammonia) + 0.5 * (Ammonia) + Nitrate —Nitrite PAN = 0.3 * (13000 — 1700) + 0.5 * (1700) + 5.6 PAN = 4296 mg/kg Equation uses Mineralization Rate (MR) for Aerobically Digested Solids (0.3) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number. 1.8001529-6364 - Fax: 704152W409 Page 1 of i 6 Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. i Terri W. Cole Project Manager Data Qualifiers Key Reference: r Reviewed By Terri W. Cole Project Manager DM Sample diluted and RL increased due to the matrix. SE Surrogate recovery outside the QC limits due to emulsion. SR Surrogate recovery outside the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the wriften consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364- Toll Free Number l-8001629-8364- Fax: 704/625.0409 Page 2 of 16 Full -Service Analytical '�RRISY Environmental Solutions "ueanvoac6 wa Sample Receipt Summary 07/29/2019 Prism Work Order: 9070083 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received Class A 9070083-01 Solid 07/08/19 8:31 07/08/19 12:50 Samples were received in good condition at 0.5 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlofte, NC 28224-0543 Phone: 704152M364 - Toll Free Number: 1-800152M364 - Fax: 7041626-MS Page 3 of 16 A Laboratory Report �P'R I S I tl L I Fullironmee Analytical 8 Environmental Solutions 07/29/2019 "IM1B WORiE%1N Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 9070083-01 P. 0. Box 878 Prism Work Order: 9070083 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/08/19 08:31 Time Submitted: 07/08/19 12:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DateMme 1D General Chemistry Parameters Plant Available Nitrogen 4200 mg/kg dry 1600 710 10 `Calculation 7126119 8:26 BMS ICALCI % Solids 95.7 % by 0.100 0.100 1 `SM2640 G 7112119 14:30 KBS P9G0186 Weight Ammonia as N 1700 mglkg dry 10 2.6 1 'SM4500-NH3 C 7126119 8:26 BMS P9G0380 NitratelNitrite as N 6.6 mg/kg dry 6.2 1.4 1 *SM4600-NO3 F 7/22/19 10:16 CLB P9G0324 PH 6.8 pH Units 1 '9045D 7/9119 12:34 CBM P9G0138 Phosphorus -Total 14000 mglkg dry 1000 320 200 •SM4500-P F M4119 10:24 CLB P9130216 Total Kjeldahl Nitrogen 13000 mglkg dry 6200 2400 10 •361.2 7/19/19 14:06 BMS PSG0213 Microbiological Parameters Fecal Coliforms 62 MPN/g dry 0.2 1 `SM9221 E 718119 13:06 BMS P9130156 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 '1311 ZHE 7/11/19 7:15 TBL P9G0154 TCLP Extraction Complete NIA 1 *1311 7117/19 7:30 MMR P9G0245 TCLP Metals Mercury BRL mg/L 0.010 D.00016 1 '7470A 7118119 14:21 MMR P9G0276 Arsenic BRL mg/L 0.10 0.030 1 '601OD 7/17/19 12:45 JAB PSGO249 Barium BRL mg1L 5.0 0.010 1 *60101) 7/17119 12:45 JAB P9130249 Cadmium BRL mg/L 0.025 0.0020 1 `6016D 7117119 12:45 JAB P9G0249 Chromium BRL mg/L 0.25 0.015 1 -6010D 7/17/19 12:45 JAB P9G0249 Lead BRL mg/L 0.050 0.020 1 "6010D 7/17/19 12:45 JAB P9G0249 Selenium BRL mg/L 0.15 0.063 1 '6010D 7/17119 12:45 JAB P9130249 Silver BRL mg/L 0.25 0.0045 1 *601OD 7117/19 12:45 JAB P9G0249 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00090 1 *80813 7/23/19 18:25 ZRC P9G0347 Dleldrin BRL mg/L 0.00050 0.000068 1 '8081B 7123119 18:25 ZRC P9G0347 Endrin BRL mg/L 0.00050 0.000068 1 '8081 B 7/23119 18:25 ZRC POG0347 gamma-BHC BRL mg1L 0.00050 0.000030 1 '8081B 7123/19 18:25 ZRC P9G0347 Heptachlor BRL mg/L 0.00050 0.000065 1 18081B 7123/19 18:26 ZRC P9G0347 Heptachlor Epoxide BRL mg/L 0.00050 0.00011 1 *8081 S 7123119 18:26 ZRC P9120347 Methoxychlor BRL mg/L 0.00050 0.000090 1 '8081 B 7/23119 18:25 ZRC PSG0347 Toxaphene BRL mg/L 0.025 0.0018 1 '8081B 7123/19 18:25 ZRC P9G0347 Surrogate Recovery Control Limits Decachlorobiphenyl 23 % 13-186 Tetrachloro-m-xylene 35 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0036 1 '8270E 7/17/19 16:24 JMV P9G0254 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0045 1 •8270E 7/17119 16:24 JMV P9G0254 2,4-Dinitrotoluene BRL mg/L 0.012 0.0042 1 '8270E 7/17/19 16:24 JMV P9G0254 2-Methylphenol BRL mg/L 0.050 0.D024 1 '8270E 7/17/19 16:24 JMV PSG0254 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041629-6364 - Toll Free Number. 1-80WS29-6364 - Fax: 7041625-0409 Page 4 of 16 ,R I S I Y E I Funmeo Analytical s Environmental Solutions ,,, MBO 10--&INC Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 07/29/2019 Client Sample ID: Class A Prism Sample ID: 9070083-01 Prism Work Order: 9070083 Time Collected: 07/08/19 08:31 Time Submitted: 07/08/19 12:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DateTme ID 3/4-Methylphenol BRL mg/L Hexachlorobenzene BRL mg/L Hexachlorobutadiene BRL mg/L Hexachloroethane BRL mg/L Nitrobenzene BRL mg/L Pentachlorophenol BRL mg/L Pyridine BRL mg/L TCLP Volatile Organic Compounds by GC/MS 0.050 0.0025 1 '8270E 7/17/19 16:24 JMV PSG0254 0.020 0.0039 1 '8270E 7/17119 16:24 JMV P9130254 0.050 0.0045 1 '8270E 7/17/19 16:24 JMV PSG0264 0.050 0.0037 1 '827DE 7117119 16:24 JMV PSG0254 0.050 0.0038 1 '8270E 7117119 16:24 JMV PSG0254 0.25 0.011 1 '8270E 7/17/19 16:24 JMV P9130254 0.25 0.0016 1 '8270E 7/17119 16:24 JMV P9G0254 Surrogate Recovery Control Limits 2,4,6-Tdbromophenol 54 % 43-140 2-Fluorobiphenyl 51 % 44-119 2-Fluorophenol 50 % 19-119 Nitrobenzene-d5 43 % 44-120 SR Phenol-d5 38 % 11-62 Terphenyl-d14 51 % 50-134 1,1-Dichloroethylene BRL mg/L 0.035 0.0035 1 '8260D 7/12119 22:10 KOM P9GO179 1,2-Dichlorcethane BRL mg/L 0.025 0.0041 1 '8250D 7112119 22:10 KDM P9G0179 1,4-Dichlorobenzene BRL mg/L 0.38 0.0042 1 '8260D 7/12119 22:10 KDM P9130179 Benzene BRL mg/L 0.025 0.0034 1 '8260D 7/12119 22:10 KDM P9G0179 Carbon Tetrachloride BRL mg/L 0.025 0.0055 1 '8260D 7/12/19 22:10 KDM PSGO179 Chlorobenzene BRL mg/L 5.0 0.0034 1 '8260D 7/12/19 22:10 KDM P9G0179 Chloroform BRL mg/L 0.30 0.0048 1 '8260D 7/12119 22:10 KDM PSGO179 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0078 1 '8260D 7/12119 22:10 KDM P9G0179 Tetrachloroethylene BRL mg/L 0.035 0.0031 1 '8260D 7/12119 22:10 KDM P9G0179 Trichloroethylene BRL mg/L 0.025 0.0046 1 •8260D 7/12/19 22:10 KDM PSGO179 Vinyl chloride BRL mg/L 0.010 0.0041 1 '8260D 7/12119 22:10 KDM PSGO179 Surrogate Recovery Control Limits Total Metals Aluminum 22000 mg/kg dry Mercury 0.41 DM mglkg dry SAR Soil Preparation Complete g SAR Percent Moisture 77.3 % by Weight Arsenic 3.5 mg/kg dry Sodium Absorption Ratio 2 4 [blank] Cadmium BRL mglkg dry Calcium 13000 mglkg dry Calcium, SAR 280 mg/L 4-Bromonuorobenzene 102 % 60-124 Dlbromofluoromethane 108 % 75-129 Toluene-d8 102 % 77-123 270 68 10 '6010D 711511912:19 JAB HG0165 0.26 0.090 5 '7471B 7116119 11:22 MMR P9G0232 1 '2-78-054 7/16119 13:00 MMR PSGO225 0.100 0.100 1 '2 78-054 7117119 13:15 MMR P9G0239 1.1 0.14 1 '6010D 7111119 14:48 JAB P9130166 0.30 0.016 1 '2-78-054 7126119 8:36 JAB P9130238 0.53 0.036 1 '6010D 7111/19 14:48 JAB POG0165 110 28 1 '6010D 711611912:27 JAB P9G0165 10 0.10 10 '6010D 7125M9 8:36 JAB PSG0238 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number; 1-8001629.6364- Fax: 7041626.0409 Page 5 of 16 " R I S n � I Fun -Service Analytical s _. 'v I I Environmental Solutions A Town of Mooresville/RR WWTP Attn: Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 07/29/2019 Client Sample ID: Class A Prism Sample 1D: 9070083-01 Prism Work Order: 9070083 Time Collected: 07/08/19 08:31 Time Submitted: 07/08/19 12:50 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Daterrime Analyst Batch ID Copper 190 mglkg dry 27 3.6 10 `6010D 7116/19 12:19 JAB P9G0165 Lead 3.6 mglkg dry 1.1 0.18 1 `601OD 7/11/19 14:48 JAB PSGO165 Magnesium 2100 mglkg dry 27 2.4 1 *6010D 7111119 14:48 JAB P9G0165 Magnesium, SAR 100 mg1L 1.0 0.086 10 '6010D 7126/19 8:36 JAB PSG0238 Molybdenum 11 mg/kg dry 1.1 0.13 1 •6010D 7111119 14:48 JAB P9130165 Nickel 11 mglkg dry 1.1 0.32 1 •6010D 7/11119 14:48 JAB PSGO165 Potassium 2000 mglkg dry 110 11 1 `6010D 7111/19 14:48 JAB P9G0165 Selenium 3.2 mglkg dry 1.1 0.29 1 '6010D 7/11/19 14:48 JAB P9130165 Sodium 760 mglkg dry 110 14 1 '6010D 7116119 12:27 JAB P9G0165 Sodium, SAR 180 mglL 6.0 0.18 10 '6010D 7/25/19 8:36 JAB POG0238 Zinc 330 mg/kg dry 110 1s 10 '6010D 7116/19 12:19 JAB P91310165 This report should not be reproduced, except in its entirety, without the w(itten consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: l-8001629.6364- Fax: 7041625-0409 Page 6 of 16 Fun -Service Analytical Environmental Solutions *," IT.,'� UBDnATONEE. ING Town of Mooresville/RR WWTP Attn: Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 07/29/2019 Client Sample ID: Class A Prism Sample ID: 9070083-01 RE1 Prism Work Order. 9070083 Time Collected: 07/08/19 08:31 Time Submitted: 07/08/1912:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DateTme ID TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 '1311 7/23/19 7:50 MMR PBG0342 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240M - Charlotte, NC 28224-0543 Phone: 7041629.6364- Toll Free Number..l-8001629-6364- Fax: 7041525-0409 Page 7 of 16 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Datelilme 9070083-01 P9G0213 0.05 g 25 mL. 07/15/19 11:17 Prep Method: SM4600-NH3 B Lab Number Batch Initial Final Date/Time 9070083-01 P9G0380 1.02 g 50 mL 07/24/19 9:54 Prep Method: SM4500-PBS Lab, Number Batch Initial Final Datelfime 9070083-01 P9130216 1 g 50 mL 07/15119 10:10 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final DateTme 9070083-01 PSG0186 -30 g 30 g 07/12/19 9:00 Prep Method:1311 Lab Number Batch Initial Final DateMme 9070083-01 P9G0154 12.6 g 260 mL 07/10/19 13:00 9070063-01 PSG0245 160 g 2000 mL 07/16/19 14:20 9070D83-01RE1 P9G0342 100 g 2000.mL 07/22419 15:20 Prep Method: 3010A Lab Number Batch Initial Final Date/Tune 9070083-01 POG0249 10 mL 50 int. 07/17/19 920 Prep Method: 7470A Lab Number Batch Initial Final DateTme. 8070083-01 P8G0276 20 mL 30 mL 07/18%19 8:40 Prep Method: 3610C GC Lab Number Batch Initial Final Date/Tune 9070083-01 P9G0347 200 mL 10 mL 07/23/19 10:10 Prep Method. 3610C MS Lab Number Batch Initial Final DateTme 9070083-01 P900254 200 ML 1 mL 07/17/19 9:30 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 9070083-01 P9G0179 1 mL 10 mL 07/12/19 10:36 Prep Method: 3010A Lab Number Batch Initial Final DateTme 9070083-01 POG0238 50 mL 50 mL 07/16/19 13:05 9070083-01 PSGO238 50 .mL 50 mL 07/16/19 13:05 Prep Method: 3090E Lab Number Batch Initial Final Data/Time 9070083-01 P9G0165 1A •g $0 mL 07/11/19 8:55 This report should notbe reproduced, except in Its entirety, without the written consent of Prism Laboratories,. Inc. 449 Springbrook Road - P.O., Box 240543 -Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number 14001629-6164- Fax: 7041525-M9 Page 8 of 16 Sample Extraction Data Prep Method: 3050E Lab Number Batch Initial Final DatelTime 9070083-01 POG0165 1.96 g 50 mL 07/11/19 8:55 9070083-01 POG0165 1.96 g 50 mL 07/11/19 8:55 Prep Method: 7471 B Lab Number Batch Initial Final Date/Time 9070083-01 PSG0232 0.6 g 50 mL 07/16/19 8:30 Prep Method: SAR 2-78-064 Lab Number Batch Initial Final Date/Time 9070083-01 PSG0225 250 g 250 g 07/15/19 12:55 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Humber Analysis 9070083-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number. 1.8001529.6364 - Fax: 7041626-0409 Page 9 of 16 PR I I Full -Service Analytical Environmental Solutions �-. LReORATORI'c$ IN4 449 Springbrook Road • Charlotte, NC 282117 Phone 7041629-6364 • Fax: 7041525-0409 Client Company Name: ut Report To/Contact Name: Reporting Address C. 1 I Phone: _M" 3 28'l1Fax (Yes) (No): Email Address: MkA A rk e. 0 EDD Type: PDF Excei_Other. Site Location Name: Site Location Physical Address: CLIENT DATE SAMPLE DESCRIPTION I COLLECTED PM J��R� OF CUSTODY RECORD RD PAGE_.._L OF a QUOTE #TO ENSURE P OPER BILLING: YES NO NIA Sampies,INTACTupon arrival? Project Name: al 4-,.s S IiAbl Q Received ON WET ICE? O Short Hold Analysis: (No) UST Project: es) ( O PROPER PRESERVATIVES indicated? / o *Please ATTACH any pro ect specific reporting (QC LE II lil I� Received WITHIN HOLDING TIMES? / prOVislons and/or --Q�C- Requirements 1- CUSTODY SEALS INTACT? Invoice To: t o Wag_ M D6(i�$VI� tK . VOLATILES-reed WIOUT HEADSPACE? IL Address: PROPER CONTAINERS used? TEMP: Therm ID T-J Observed,(;Lt "C / Corr.�__°C Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Requested Due Date D 1 Day 0 2 Days 13 3 Days 0 4 Days 0 5 Days Certification: NELAC DOD_ FL NC !% "Working Days" 136-9 Days Standard 10 days O p �!gW-rk dust Be $C OTHER NIA Samples received Sher 1"0 will `belprocessed next business day. Turnaround time Is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO (SEE REVERSE FOR TERMS S CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES___- NO_ 71ME MATRIX SAMPLE CONTAINER COLLECTED (SON, _I PRESERVA- MILITARY HOURS WATER OR SLUDGE) *TYPE SEE BELOW NO. SIZE TNES 10 931 PRISM ' REMARKS LAB j ID NO. Sampler's Signature !V'VVv `r /(/` 1 Sampled By (Print Name) ff ?J �W I Affiliation 10 KAJ Upon relinquishing, this Chain of Custody Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted In writing to the Prism Project Manager. There will be charges for angee after analyses have been initialized. Ro nqu shed : (Signature) Recowncl (51gnature) Date In auto Additional Comments: Yi1,tin` Date ,I-P rlo�is" Ra qulsh y: (S gn u a Racelved R gna ) Rclinquls Slgna e) mI 7Prlsm Lnbarato 1es Dot gab Phad at Shl nt: NOTE ALL SAMPLE COOLERS SHOULD BE TAP' KCU5TODY EALS FORTtANSPORTATION TITHE LABORATORY. COG Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED ATTHE LABORATORY. ❑ Fed Ex 17 UPS O Hand -delivered dsm Field Service O other. _ IUNTER• DRINrJNG WATER: S ID WASTE: CLA I LANDFILL ICl NC ❑ SCI ❑ NC ❑ SC ❑ NC❑ SC ❑ NC ❑ SCD NNC ❑ SC ❑ C ❑ SC❑ N ❑ ❑ ❑ O ❑ I ❑ `CONTAI"I=P TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap vnA = Volatile Organics Analysis (Zero Head Space) C VAL A /o.-RISM I Full -Service Analytical Environmental Solutions -- LAWRATORIM 111C, 449 Springbrook Road • Charlotte, NG 28217 Phone•7041529-6364 Fax:704152"409 Client Company Name: 1 QiM-, n�- !v ►yww4k Report To/Contact Nape: Reporting Address: .O . a Al x8! S" Phono.!h6—1'0(P0— 3 z t(o Fax (Yes) (No : Email Address: �u ,nnoprP.6u1�,1RC_ 4t1V EDD Type: PDF ✓ Excel Other Site Location Name: Site Location Physical Address: CHAIN OF CUSTODY RECORD PAGE 2 OF a QUOTE d To I NSUr1bria PROPEIL R BLINGS — Project Name: 0i a4S di a'i Short Hold Analysis: (Yes (No) UST Project: (Yes) NO *Please ATTACH any project specific reporting (QC LEVE0 III IV) provisions and/or QC Requirements Invoice To: TDuA, aF- M Address: Purchase Order No./Billing Reference Requested Due Date O t Day ❑ 2 O 3 Days O 4 Oays 0 8 Days "Working Day6" O 6-9 Days Bard to days Ll Pus P rkMust Be Samples received after 14,00 will be processed nag business day. Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS 6 CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) LAB USE ONLY YES NO NIA ccSamples IiJTACT upon arrival? Received ON.WET•ICE? O PROPER PRESERVATIVESilndicated?' r Received. WITHIN HOLDING TIMES? CUSTODY:SEALSIINTACT? VOLATILES^redd WIOUT HEADSPACE? LL PROPER CONTAINERS ? iuse TEMP Therm TheIDT :ObservedD,!f_ 'C.iCc.n°C TO BE FILLED IN BY CLIENTISAMPLING PERSONNEL Certification: NELAC DoD Fes„_ NC ✓ Sc OTHER NIA Water Chlorinated: YES_ NOYESS_ — Sample Iced Upon Collection: _V'NO_ CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIMES %` ANALYSIS RECUESTED / ✓ tL , �`�,�/�' REMARKS i �` �`'` �` PRISM I LAB `TYPE SEE BELOW NO. SIZE I aA W Pr g_ 0851 5Dt1 r 61 Sampler's Signature Mo iYU- I Sampled By (Print Name) _1 4%1T J d'UZ *VV\ I Affiliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for changes after analyses have been Initialized. SAMPLES ARE NOTACCEPTED AND VERIFIED ❑ Fed Ex D UPS O Hand -delivered "OPrism Field Service O COC UNTIL RECEMM AT THE LABORATORY. '�1MO1"6 Additional Comments: Me, ��1 f�sl �fGAf 0300%3 011 &., K)1Ji,� !Site Arrival Time: Site Departure Time: Field Tech Fee: Mileage: ❑ NC O SC ❑ NC ❑ SC I O 14C ❑ SC ❑ NC ❑ SC '• NC ❑ SC O NC ❑ SC ❑ NC ❑ SC 1 O NC O SC ❑ NC 13 SC ' ❑ ❑ O __-- — ..... ❑ — ---_ ._— I ❑ ❑ ❑ —_ ❑ ❑ *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cain, "—' Volatile Organics Analysis (Zero Head Space) Of AL ACCESS ANALYnCAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECTID 9070083 LABORATORY REPORT NUMBER 1907820 DATE July 15, 2019 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential'Drivc, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - A1HA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCI41 ,asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 4 cc;Page 12 of 16 Full-Service.t-RIS I Environmental Solutions tnoanmomcs:ec /QD'7 if"a SUBCONTRACT ORDER Certification: NELAC_ USACE Prism Laboratories, Inc. N0,L SC_ Other _ 9070083 N/ SPENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. P. O. Box 240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax: 704-525-0409 Project Manager. Terri W. Cole Analytical Environmental Services, Inc. 3090 Presidential Parkway Atlanta, GA30340 Phone :(770) 457-8177 Fax: NA Analysis Due F_xpires Laboratory ID Comments Sample ID: 9076093-01 Solid Sampledt07108/19 08:31 C R 5 s L ' Herbicides TCLP (Sub) 07/15/19 08:31 Containers suppllc t �--- Released By Dote eceived By r5aic Rck-mcd By Due Rccc vcd By Date Poge I of I Pag Page 13of16 Analytical Environmental Services, Inc Date: is-jul-19 Client. Prism Laboratories Client Sample ID: CLASS A Lab Order 1907820 Tag Number. 9070083-01 Project Name: 9070083 Collection Date: 7/8/2019 8:31:00AM Lab ID: 1907820-OOIA Matrix: Solid Analyses Result Quai MDL ReportingLimit Units SatchYD DF Date Analyzed Analyst HERBICIDES, TCLP SWI311/8151A (SW3510C) 2,4,5 TP (Silvex) BRL 0.030 0.20 mp1L 281962 1 07/120019 20:07 HB 2,4-D BRL 0.051 0.20 mgJL 281862 1 07/12/2019 20:07 HB Surr: DCAA 589 0 49.4-120 %REC 281862 1 07JI212019 20:07 HB Qoaiirterst \Slue exceeds maximum contaminant level E Estimated value obovc quantization range BRL Not Detected at MDL S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded > Greater han Result value N Anahne not NELAC ceaillled J Estimated value detected below Reponiro; Limit B Analvte dneved in the associated method blank < Les than Result value Page Page 14 of 16 AxAm rim. EA971tOIvM m r.V . AF.S ScR-,zers.l%C. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical/ Inc. 2. Carrier: Fedfx Q UPS ❑ USPS❑ Client❑ Courier[—] Othei AES Work Order Number: 1907820 WC rdI N/e nor�n� Clear Save as Shipping container/cooler received In good condition? o - damaged ❑ leaking ❑ other❑ ............. Custody seals present on shipping container? o Custody seals intact on shipping container? o Temperature blanks present? o Cooler temperature(s) within limits of 0.6°C? [See item 13 and 14 for temperature recordings.) ® ® Cooling initiated for recently collected samples J ice present ❑ Chain of Custody (COC) present? no Chain of Custody signed, dated, and timed when relinquished and received? .a Sampler name and/or signature on COC? Were all samples received within holding time?91=lf TAT marked on the COC? no TAT Indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler I temperature 2.1 aC Cooler 2 Temperature 14. Cooler 5 Temperature aC Cooler 6 Temperature 15. Comments: is. 17. 18. 19. 20, 21. 22. 23. 24. 25. 26. aC Cooler 3 Temperature aC Cooler 4 Temperature aC aC Cooler 7 Temperature aC Cooler 8 Temperature °C certify that I have completed sections 1-IS (dated initials). MJ 7/10/19 Vow alw �Ilfl Were sample containers intact upon receipt? e3 Custody seals present on sample containers? o Custody seals Intact on sample containers? o Do sample container labels match the COC? 80 ® incomplete info ❑ illegible ❑ no label r l other CJ Are analyses requested Indicated on the CDC? o Were all of the samples listed on the COC received? Was the sample collection date/time noted?CO) Q ® �.J 0 samples received but not listed on COC ED samples listed on COC not received ❑ Did we receive sufficient sample volume for indicated analyses? o Were samples received in appropriate containers? no Were VOA samples received without headspace (< 1/4" bubble)? ff a. Were trip blanks submitted? o listed on COC ❑ not listed on COC ❑ 27. Comments: This section only applies to samples where pH can be 28 29. 30. m I certify that I have completed sections 16-27 (dated initials). AP 7/10/19 Note: Certain analyses require chemical preservation but must be checked In the laboratory and not upon Sample Receipt such as Collforms, VOCs and Oil & Grease/TPH. 1 certify that I have completed sections 28-30 (dated initials). AP 7/10/19 00 Checklist 6.9,17 Rev 2 rn Locked Page 4 of 5 Analytical Environmental Services, Inc Date: 15-Jul-I9 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 9070083 Warkorder: 1907820 BatchlA: 281852 Sample 1D: NIB-281862 Client ID: Units: mg/L Prep Date: 07/11/2019 Run No: 402616 Sampltjfype: MBLK TestCode: t1ERBICIDES,TCLP SWI31118151A BatchTD:281862 Analysis Date: 07/12/2019 Seq No: 9037028 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2.4-D BRL 0,20 Surr: DCAA 0.3287 0 0.5000 657 49.4 120 Sample ID: LCS-281862 Client 1D: Units: mg/L Prep Date: 07/11/2019 Run No: 402616 Sampljype: LCS TestCode: HERBICIDES, TCLP SWI31118151A MOM: 281862 Analysis Date: 07/IV2019 Seq No: 9037029 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val a/oRPD RPD Limit Qual 2,4,5 TP (Silvex) 0.3438 0.20 0.5000 68.8 49 120 2.4-D 0.3778 0.20 0.5000 75.6 50.9 120 Surr: DCAA 0.3687 0 0.5000 73.7 49.4 120 Sample ID: 1907665-t101BMS ClientlD: Units: mg/L Prep Date: 07/1112019 Run No: 402616 SampleType: MS TestCode: HERBICIDES, TCLP SWI311/9151A Batch[D: 281862 Analysis Date: 07/12/2019 Seq No: 9037030 Analyte Result RPT Limit SPK value SPK Ref Val a/oREC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2.4.5-1'P (Silvex) 02964 020 0,5000 59.3 482 120 2.4-D 03277 0.20 0.5000 655 45 130 Surr: DCAA 03017 0 0.5000 603 494 120 Qnnliaera. I Greater than Result value BRL Belowrepmmnghtmt 1 ]isumaad value dci Tlcd belotc Repotting Limn Rpl Lim Rupurting Linn( Lees than Result value E Fslimated (value above quaniitalion range) N Analyte not XELAC cenifitd S Spike Recovery outside limits due to matrix R Analyto detected in the associated method blank H Holding times for preparation or analysis exceeded R RFD outside limils due to marix Page 5 of 5 PRISM UWORATCRIEA INQ Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37736 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 10/07/2019 Prism Work Order: 9100089 Case Narrative 10/23/19 15:25 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Analysis note for SAR: SAR =[Na]/SQRT {([Ca]+[Mg])/2} SAR = [ 115123 ] / SQRT {([298/20] + [68/12.2]) / 2 ) SAR = 1.6 Concentrations for Na, Ca, and Mg are expressed in milliequivalents per liter, and SQRT designates taking the square root of the operand in parentheses. PAN Equation = 0.3 * (TKN — Ammonia) + 0.5 * (Ammonia) + Nitrate —Nitrite PAN = 0.3 * (22000 — 1400) + 0.5 * (1400) + 2.6 PAN = 6700 mg/kg Equation uses Mineralization Rate (MR) for Aerobically Digested Solids (0.3) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041626-0409 Page 1 of 16 Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager DM Sample diluted and RL increased due to the matrix. ECV Ending CCV above the. QC limit. Analyte not detected down to the MDL. No further action taken. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 2.40543 - Charlotte, NC 28224-0543 Phone:.7041529-6364-Toll Free Number: 1.8001629-6364-Fax: 704/526-0409 Page 2 of 16 pA P R I S M I Full -Service Analytical & f Environmental Solutions `"�a 1A80M 0A)M ING Sample Receipt Summary 10/23/2019 Prism Work Order: 9100089 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received Class A 9100089-01 Solid 10/07/19 9:14 10/07/19 12:50 Samples were received in good condition at 2.5 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Spring brook Road -P.O. Box 240M -Charlotte, INC 28224-0643 Phone: 7041529.6364-Toll Free Number: 1-8001529.6364-Fax:7041526-0409 Page 3 of 16 /.rr:r��.R 1 S � �j I EuviService Analytical s / V � Environmental Solutions � IABOgAM.1ra I.C. Town of Mooresville/RR WWTP Attn: Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 10/23/2019 Client Sample ID: Class A Prism Sample ID: 9100089-01 Prism Work Order. 9100089 Time Collected: 10/07/19 09:14 Time Submitted: 10/07/1912:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DateTme ID General Chemistry Parameters Plant Available Nitrogen 6700 mg/kg dry 790 420 10 'Calculation 10/18/19 15:10 CLB [CALL] % Solids 95.9 % by 0.100 0.100 1 'SM2640 G 10/10/19 12.19 EDV P9J0187 Weight Ammonia as N 1400 mglkg dry 9.6 2.4 1 'SM4500-NH3 C 10N8119 16:10 BMS 139J0299 Nitrate/Nitrite as N BRL mg/kg dry 5.2 1.4 1 'SM4500-NO3 F 10/11/19 9:24 CLB P9J0161 PH 6.2 pH Units 1 '9045D 1018119 16:23 CBM PSJ0134 Phosphorus -Total 14000 mg/kg dry 520 160 100 'SM4500-P F 10/16/19 9.24 CLB P9J0242 Total Kjeldahl Nitrogen 22000 mglkg dry 2600 1400 10 •361.2 1019/19 7:67 CLB 139J0116 Temperature 21.1 pH Units 1 '9045D 1018119 16:23 CBM PSJ0134 Microbiological Parameters Fecal Coliforrns TCLP Extraction by EPA 1311 390 MPNIS dry 0.2 1 'SM9221 E 1017/19 13:10 BMS PBJ0130 TCLP Extractlon Complete NIA 1 '1311 ZHE 10/9119 6:52 TBL PBJ0120 TCLP Extraction Complete NIA 1 '1311 10/9119 7:20 EDV P9J0127 TCLP Metals Mercury BRL mg/L 0.010 0.000034 1 '7470A 1019119 13:03 mmr PSJ0145 Arsenic BRL mg/L 0.10 0.030 1 '6010D 10/11/19 20:53 JAB P9J0180 Barium BRL mg/L 5.0 0.010 1 '6010D 10/11/19 20:53 JAB P9J0180 Cadmium BRL mg/L 0.025 0.0020 1 '6010D 10/11/19 20:53 JAB P9J0180 Chromium BRL mg/L 0.25 0.015 1 '601OD 10/11/19 20:53 JAB P9J0180 Lead BRL mg/L 0.050 0.020 1 '6010D 10/11/19 20:53 JAB P9J0180 Selenium BRL mg/L 0.15 0.063 1 '6010D 10/11/19 20:53 JAB P9J0180 Silver BRL mg/L 0.25 0.0045 1 '601OD 10/11/19 20:53 JAB PSJ0180 TCLP Organochlorine Pesticides by GCIECD Chlordane BRL mg/L 0.0025 0.00090 1 '8081B 10/11/19 18:34 NMB P9J0187 Dieldrin BRL mg/L 0.00050 0.000068 1 '6081B 10/11/19 18:34 NMB PSJ0187 Endrin BRLECV mg/L 0.00060 0.000068 1 '8081B 10/1V1918:34 NMB P9J0187 gamma-BHC BRL mg/L 0.00050 0.000030 1 '8081B 10/11/19 18:34 NMB P9J0187 Heptachlor BRL mg/L 0.00050 0.000065 1 '8081B 10/11/19 18:34 NMB 139J0187 Heptachlor Epoxide BRL m9tL 0.00050 0.00011 1 '8081B 10/11/19 18:34 NMB P9J0187 Methoxychlor BRLECV mg/L 0.00050 0.000090 1 '8081B 10/11/19 18:34 NMB P9J0187 Toxaphene BRL mg/L 0.025 0.0018 1 '8081B 10/11/19 18:34 NMB PSJ0187 Surrogate Recovery Control Limits Decachlorobiphenyl 74 % 13-186 Tetrachloro-m-xylene 60 % 40-134 TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0036 1 '8270E 10/10/19 17:45 JMV P9J0162 2.4,6-Trichlorophenol BRL mg/L 0.10 0.0045 1 '8270E 10/10/19 17:45 JMV PSJ0162 2,4-Dinitrotoluene BRL mg/L 0.012 0.0042 1 '8270E 10/10/19 17:45 JMV PSJ0162 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc, 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 -Toll Free Number. 1.8001529-6364 - Fax: 7041625-0409 Page 4 of 16 Laboratory Report Analytical & PRISM I Environmental Solutions 10/23/2019 .---� unowlaniEs. iNc Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 9100089-01 P. O. Box 878 Prism Work Order: 9100089 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/07/19 09:14 Time Submitted: 10/07/19 12:50 Parameter Result Units Report MDL Limit Dilution Factor Method Analysis Analyst Date>Tme Batch ID 2-Methylphenol BRL mg/L 0.050 0.0024 1 `8270E 10/10/19 17:45 JMV PSJ0162 3/4-Methylphenol BRL mg1L 0.050 0.0025 1 '8270E 10/10/19 17:45 JMV P9J0162 Hexachlorobenzene BRL mg/L 0.020 0.0039 1 '8270E 10/10/19 17:45 JMV P9J0162 Hexachlorobutadiene BRL mg/L 0.050 0.0045 1 '8270E 10/10/19 17:45 JMV P9J0162 Hexachloroethane BRL mg/L 0.050 0.0037 1 '8270E 10/10/19 17:46 JMV P9J0162 Nitrobenzene BRL mg/L 0.050 0.0038 1 '8270E 10/10/19 17:45 JMV PSJ0162 Pentachlorophenol BRL mg/L 0.25 0.011 1 '8270E 10/10/19 17:45 JMV P9J0162 Pyridine BRL mg1L 0.25 0.0016 1 '8270E 10/10/19 17:45 JMV PSJ0162 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 46 % 43-140 2-Fluorobiphenyl 43 % 44-119 SE 2-Fluorophenol 48 % 19-119 Nitrobenzene-d5 40 % 44-120 SE Phenol-d5 34 % 11-52 Terphenyl-d14 47 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.0035 1 `8260D 10/11/19 13:52 KDM P9J0168 1,2-Dichloroethane BRL mg/L 0.025 0.0041 1 `8260D 10/11/19 13:52 KDM P9J0158 1,4-Dichiorobenzene BRL mg/L 0.38 0.0042 1 '8260D 10/11/19 13:52 KDM P9J0158 Benzene BRL mg/L 0.025 0.0034 1 `8260D 10/11/19 13:52 KDM P9J0158 Carbon Tetrachloride BRL mg/L 0.025 0.0055 1 •8260D 10/11/19 13:52 KDM 139J0158 Chloroberizene BRL mg/L 5.0 0.0034 1 '8260D 10/11/19 13:52 KDM P9J0158 Chloroform BRL mg/L 0.30 0.0048 1 '8260D 10/11/19 13:52 KDM P9J0158 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0078 1 `8260D 10/11/19 13:52 KDM P9J0158 Tetrachlorcethylene BRL mg/L 0.035 0.0031 1 '8260D 10/11/19 13:52 KDM P9J0158 Tdchloroethylene BRL mg/L 0.025 0.0046 1 '8260D 10/11/19 13:52 KDM PSJD158 Vinyl chloride BRL mg/L 0.010 0.0041 1 '8260D 10/11/19 13:52 KDM P9J0158 Surrogate Recovery Control Limits 4-Bromofluoroberrzene 107 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 100 % 77-123 Total Metals Aluminum 28000 mg/kg dry 260 57 10 •6010D 10/16/19 14:64 JAB P9J0176 Mercury 0.78 DM mg/kg dry 0.16 0.064 3 '74718 10/10/19 13.20 mmr P9JD166 SAR Soil Preparation Complete g 1 '2-78-054 10/10/19 14:50 MMR PSJ0146 SAR Percent Moisture 67.6 % by 0.100 0.100 1 •2-78-064 10/11/19 14:60 MMR P9J0178 Weight Arsenic 3.8 mg/kg dry 1.0 0.14 1 '6010D 10114/19 16:17 JAB P9J0176 Sodium Absorption Ratio 1.6 [blank] 0.30 0.016 1 '2-78-054 10/22/19 8:42 JAB P9J0177 Cadmium BRL mg/kg dry 0.52 0.035 1 '6010D 10/14/19 15:17 JAB P9J0176 Calcium 22000 mg/kg dry 1000 270 10 '6010D 10M5119 14:64 JAB 139J0176 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041629.6364-Toll Free Number: 1-8001529-6364-Fax:704/525-0409 Page 5 of 16 ,t.r�,R I S M I Fun -Service Anatyutio s r. Environmental Solutions .-+-, uBonnToaJes uac Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 10/23/2019 Client Sample ID: Class A Prism Sample ID: 9100089-01 Prism Work Order: 9100089 Time Collected: 10/07/19 09:14 Time Submitted: 10/07/19 12:50 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor WWI ime ID Calcium, SAR 300 mg/L 10 Copper 270 mglkg dry 26 Lead 8.4 mglkg dry 1.0 Magnesium 2000 mg/kg dry 26 Magnesium, SAR 68 mg/L 1.0 Molybdenum 8.6 mglkg dry 1.0 Nickel 11 mglkg dry 1.0 Potassium 2600 mg1kg dry 100 Selenium 4.7 mglkg dry 1.0 Sodium 940 mg/kg dry 100 Sodium, SAR 110 mg/L 1.0 Zinc 510 mg/kg dry 100 0.10 10 •6010D 10/15/19 8:46 JAB P9J0177 3.6 10 •6010D 10116119 14:64 JAB PSJ0176 0.17 1 '6010D 10/14119 16:17 JAB PDJ0176 2.4 1 *60100 10/14119 16:17 JAB P9J0176 0.086 10 '6010D 10/15119 8:46 JAB P9J0177 0.13 1 •6010D 10/14/19 16:17 JAB P9J0176 0.31 1 •6010D 10/14/19 16:17 JAB P9J0176 11 1 •6010D 10/14/19 16:17 JAB PSJ0176 029 1 •6010D 10/14/19 15:17 JAB PSJ0176 14 1 `6010D 10/16/19 16:02 JAB PSJ0176 0.036 2 '60101) 10/21/19 23:14 JAB PSJ0177 15 10 °6010D 10116119 14:64 JAB PSJ0176 This report should not be reproduced, except in Its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041626-0409 Page 6 of 16 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Date/Time 9100089-01 P9J0116 0.05 g 25 mL 10/08/19 9:50 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 9100089-01 PSJ0299 1.09 g 50 mL 10/18/19 8:47 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 9100089-01 P9J0242 1 g 50 mL 10/15/19 11:20 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 9100089-01 P9J0157 30 g 30 9 10/09/19 14:22 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 9100089-01 P9J0127 100 g 2000 mL 10/08/19 14:35 9100089-01 P9J0120 12.5 g 250 mL 10/08/19 12:00 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 9100089-01 P9J0180 10 mL 50 mL 10/11/19 10:40 Prep Method: 7470A Lab Number Batch Initial Final DatelTme 9100089-01 P9J0145 20 mL 30 mL 10/09/19 8:40 Prep Method: 3510C GC Lab Number Batch Initial Final Datefrime 9100089-01 PSJ0187 200 mL 10 mL 10/11/19 8:41 Prep Method: 3610C MS Lab Number Batch Initial Final Datemme 9100089-01 P9J0162 200 mL 1 mL 10/10/19 8:27 Prep Method: 5030E Lab Number Batch Initial Final DateMme 9100089-01 P9J0158 1 mL 10 mL 10/11/19 9:29 Prep Method: 3010A Lab Number Batch Initial Final Date/Tme 9100089-01 139J0177 50 mL 50 mL 10/10/19 14:50 9100089-01 P9J0177 50 mL 50 mL 10/10/19 14:50 9100089-01 P9J0177 50 mL 50 mL 10/10/19 14:50 Prep Method: 3050B Lab Number Batch initial Final Date/Time 9100089-01 PSJ0176 2 g 60 mL 10/10/.19 8:11 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240M - Charlotte, NC 282244943 Phone: 704/529.6364 - Tog Free Number.,1-8001529-6364 - Fax: 7041525-0409 Page 7 of 16 Sample Extraction Data Prep Method: 3060B Lab Number Batch Initial Final DatefTims 9100089-01 P9J0176 2 g 50 mL 10/10/19 8:11 9100089-01 PSJO176 2 g SD ,ml- 10/10/19 8:11 Prep Method: 7471 B Lab Number Batch Initial Final DateTme 9100089-01 P9J0166 0.6 g 50 mL 10/10/19 9A3 Prep Method: SAR 2 78-064 Lab Number Batch Initial Final DateNme 9100089-D1 P9J014e 250 g 250 g 10109/19 14:60 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 9100089-01 Herbicides TCLP (Sub) This report should not be reproduced, except in Its entirety, without the written consent of Prism Laboratories, Inc: 449 Springbrook Road -P.O. Box 240643:• Charlotte, NC,28224-0643 Phone: 7041529.6364 -Toll Free Number. 1.800/529-6364- Fax: 704/6254 MOS Page 8 of 16 LPRISM i Full -Service Analytical & Environmental Solutions & �= LAEORMOR1ES IHG 440 Springbrook Road - Charlotte, NC 28217 Phone 7041529-6364 - Fax: 7041525.0409 Client Company Name: -d+un- WAD &C464,11e. Report To/Contact Name: t co AuArl�e_ Reporting Address: $ AA pftwidq 1..AJC,'.RI IS - CHARM OF CUSTODY RECORD PAGe_J_ OF —I;'— QUOTE 1) TO,,ENSURE PROPER BILLINGr Project Name: aAa^� / / pU,,4 S1} khe— Short Hold Analysis: a (No) UST Project: s) b 'Please ATTACH any protect specific reporting (QC LEVE�I III IV) provisions and/or- -QC� Requirements -r Invoice To: IIrt , 01-MDLs+re&1Ae_ Address: Samples INTACT upon arrival? Received ON WET ICE? PROPER PRESERVATIVES indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? VOLATILES redd W/OUT HEADSPACE? -PROPER CONTAINERS used? TEMP: Therm 10-tiI —1k Observed: Y NO NIA 7 0 0) a Email Address: VJfK! !JC @ (Yes) (No): Email Address: WMuI't��I'V1C truSrlllt ItC- Purchase Order No./Billing Reference • L?� TO BE FILLED IN BY CLIENTISAMPLING PERSONNEL EDD Type: PDF ✓ Other Requested Due Date ❑ 1 Day ❑ 22 /Days ❑ 3 Days LI 4 Dayss ❑ 5 Days "Working Be Certification• NELAC_- - DOD FL NC 1/ Days ❑ 6-9 Days pffSlandard 10 days ❑ P er SApWprovedust Site Location Name: ' s Samples received after 14:00 will processed next business day. SC� OTHER N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO_ (SEE REVERSE FORTERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) I Sample Iced Upon Collection: YES____ NO, CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER 1 PRESERVA- J. ANALYSIS R�QUESTED c ��• PRISM 'TYPE NO. SIZE SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR TIVES (T�jQ1r yv; ��'MAS IDI O HOURS SLUDGE) SEE BELOW 00,19 Sampler's Signaturef(� NzY\ .a o Sampled By (Print Name) 1 r `o�:I *''E irm"', Affiilation T WM Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted In writing to the Prism Project Manager. There will be c es for any changes after analyses have been initialized. Relinyursned a(v: (Signature) ' . A YY: Re ve 6 (S' Date t/ety ours Additional Comm nts' site Arrival Time: Re adayn ro R ived By: (signature) Data ' "— v a�-1 `S�t Site Departure Time: Re a By: (Sign ur Racetvcd For Prlsrn Laberotories By. Date-1 l } Q p Field Tech Fee: �0 J" I � /rise �eLFA� lO o� Tilr Mileage: Method cf Shlpment: NOTE: ALL SAMPLE COOLERS SHOULD BETAPEO SHUT wiTH cU oO R ATI T LABORATORY. cur. Group No. SAMPLES ARE NOTACCEPTEDAND VERIFIEDAGAINST COCUNTIL RECEIVED ATTHELABO TORY. 1 ` VV [� O Fad Ex O UPS O Hand�re ellved pram Field Service ❑ Olhar -� 'ODES: UST GROUNDWATER DRINKING WATER: SO ID WASTE: RCRA: CERC -A LANDFILL OTHER: ' IC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC I 1 ❑ NC ❑ SC C ❑ SC ❑ NC ❑ SC I❑ NC ❑ SC I ❑ NC ❑ SC I ❑ NC ❑ SC ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ IT AlmOO TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Car —^L= Volatile Organics Analysis (Zero Head Space) C NAL ffe f -II SM ...�v.�:e. LABORATORIES. INC Full -Service Analytical & Environmental Solutions 449 Springbrook Road - Charlotte, NC 28217 Phone 7041529.6364 • Fax: 704152"409 Client Company Name: sv4,%. aF iAcrYY. Alt Report To/Contact Name: w h 1 iT' "- Reporting Address: M•uexe�ilk,_.\J Pn GGD -3 j OL U C tr"�ilEN OF CUSTODY RECORD PAGE A OF � QUOTE # TO ENSURE PROPER BILLING: a Project Name: e�Ss 14 Short Hold Analysis: "Please ATTACH any provisions and/or QC Invoice To: Address: I (No) UST Project: (Yes) specific reporting (QC LEVEeI I III NO N/A Samples INTACT upon arrival?!&S arrival? t-�' Recolved ON WETICE? ✓ � Q 0 CD OROPER'PRESERVATIVES indicated? 1/ _ CD Received WITHIN -,,HOLDING TIMES? I� N .S CUSTODY SEALS � od VOLATILES rec'd WfQUT HEADSPACE? PROBER CONTAINS used? TEMP: ThermlD:• to Observed�2+�—`C;GCorr1S 9C one.�r — Fax (Yes) (No): Purchase Order No./Billing Reference Email Address: _ $ri'LMot1'4Al to C gall TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Requested Due Date Q 1 Day ❑ 2 Days Q 3 Days Q 4 Days ❑ 5 Days EDD Type: PDF ✓ Excei_Other "Working Days" Q 6-9 Days)tandard 10 days Rush Wory ust Be f;eltiflcatlOnidELAC DOD FL NC - ' V Q d Site Location Name: Samples received after 14:00 will be processed next business day. SC_ OTHER N/A Site Location Physical Address: Turnaround time Is based an business days, excluding weekends and holidays. Water Chlorinated: YES_ NO_ (SEE DERED BY P SM LABORATORIES, IRSE FOR TERMS & N CSCNSERVICES RENDEREDT RDEN ; Sample Iced Upon Collection: YES_ NO TIME MATRIX SAMPLE CONTAINER ANALYSIS REQUESTED CLIENT SAMPLE DESCRIPTION DATE COLLECTED COLLECTED MILITARY (SOIL, WATER OR PRESERVA- TIVES y(. / lJ" �/ �REMARKS PRISM � "TYPE HOURS SLUDGE) SEE BELOW NO. SIZE S'.' �r`��/ J ID NO. lJt r � '? ^ 1 I 0 el / W 50 l' I , i Sampler's Signature 41-411 r Sampled By LV_kN+4kkd (Print Name) Afriliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted In writing to the Prism Project Manager. There will be charges for any changes after analyses have been Initialized. e ellnqul Is _ (SlgnorumJ ece ; (Sign. D n ��` pia r aura ry Additional Comments: Site Arrival Time: Relinqu y (Si um Re y: (SlgnaWre) �7 9'.l � � Date � ��; Site Departure Time: Relinqurs By: (Signature) Received For Prism Laboralodos By: Date I / si 01I lire(/ �t� Field Tech Fee: .) [j� J` _ \ Method of Shipment NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPOERTANON TO THELABORATORY. COC Group No. Mileage: I I I SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT THE LABO RY. / 1017adgx ❑ UPS O O Hand•delivered dsm Field service Other � ��0� NPDES; I UST: GROUNDWATER: DRINKING WATER: " SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: ❑NC❑SC ❑NC ❑SC ❑NC ❑SC I ❑NC ❑SC �X{NC ❑SC ❑NC❑SC ❑NC ❑SC+❑NC ❑SC QNC ❑SC I❑ '0 I❑ I❑ In ' ❑ ❑ El . In 'CONTAINER TYPE CODES: A =Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Car = Volatile Organics Analysis (Zero Head Space) 0 IAL 0 ACCESS ,,@ ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 9100089 LABORATORY REPORT NUMBER 1910899 DATE October 15, 2019 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 ALMA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative ofAES serving client in the SCINC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883315.4243 Page Page 11 of 16 .'PRISM g. R I S M 1m Full -Service Analytical �•_ �'"Environental Solutions �" -' - , uno:raMIMI a SUBCONTRACT ORDER IqI(DgqC� Cenificatiow NL-LAC_ USACE Prism Laboratories, Inc. NC xi SC Other 9100089 N/A_ SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. 0. Box 240543 3080 Presidential Par",ay Charlotte, NC 28224-0543 Atlanta, GA 303,10 Phone: 800-529-6364 Phone :(770) 457-S177 Fox:104-525-0409 Fax: NA Project Manager. Terri W. Cole Analysis Due Expires Laboratory ID Comments SamplelD: 9100089-01 Solid Sampled:101D4119 09:14 �� 5 Herbicides TCLP (Sub) 10119119 09:14 4 Released Bp I?:ar Received Sy �! Hale Released By hate Received 13% Bate Nwe I o1 I Pays I Page 12 of 16 Analytical Environmental Services, Inc Date: 15-Oct-19 Client: Prism Laboratories Project: 9100099 Case Narrative Lab ID: 1910899 Sample Receiving Non-conformance: Sample information, on the Chain ofCustody (COC), did not match that on the container label. On the COC, collection date is listed as 10/07/19 whereas, on the label, it is 10/04/19. Sample logged in according to the COC. Page page 13 of 16 Analytical Environmental Services, Inc Date: 15-Oct-I 9 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1910899 Tag Number: 9100089-01 Project Name: 9100089 Collection Date: 10/7/2019 9:14:00 AM Lab ID: 1910899-OOIA Matrix: Solid Analyses Result Qual MDL Reporting Units BatchlD DF Date Analyzed Analyst Limit HERBICIODI✓S, TCLP SW1311/8151A 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr: DCAA 79.8 Quoliaess: ' Value exceeds maximum conteminont level BRL Not Detected at MDL H Holdings:mes for preparation or analysis exceeded N Analyle not NELAC eeni0ed B Analyle detected in the associated method blank (SW3510C) 0.030 0.20 MA 286382 I 101151201913:24 HB 0.051 0,20 mg/L '286392 1 10/15/201913:24 HB 0 49.4-120 %REC 286382 1 10/15fl01913:24 HS E Estimated value above quanlimian range S Spike Rcpovety outside limits due to matrix > Greater than Result % line J Estimated value dewed below Reporting Limit < Less than Result value Page Page 14 of 16 AFS IAN,%vricnt. smXaENVIAtNVI CES, r\C.At SAMPLE/COOLER RECEIPT CHECKLIST 1. CllentName: Access Analytical, Inc. 2. Carrier: fedEx Q uPs ❑ uSPs❑ Orient❑ Courier❑ other Ves Nn NIB hn�oile 3, 4, S. 8, 7. 8. 9, 10, IL 12 Clear Save as AES Work order Number. 1910899 Shipping container/cooler received in good condition? o damaged leaking ❑ other❑ Custody seals present on shipping container? e Custody seals intact on shipping container? o Temperature blanks present? o Cooler temperature(s) within limits of 04C? [See item 13 and 14 for temperature recordings.] Q ® (0, Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? no Chain of Custody signed, dated, and timed when relinquished and received? o Sampler name and/or signature on COC? o Were all samples recelved within holding time? a TAT marked on the COC? a1 if no TAT indlcated, proceeded with standard TAT per Terms & Conditions. 13 Cooler 1 Temperature 0.4 °C Cooler 2Temperature °C Cooler 3 Temperature °C Cooler Temperature °C 14, Cooler5Temperature °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C 15 Comments- 1 certify that I have completed sections 1-1S (dated initials). MDP 10/9/19 v— Nn N/A 16. 17 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. Comments. This section only applies to samples where pH can be I certify that i have completed sections 16-27 (dated initials). MDP 10/9/19 checked at Sample Receipt, vex Nn N/A nos ii� Were sample containers intact upon receipt? 6 '.......... — Custody seals present on sample containers? o Custody seals Intact on sample containers? o Do sample container labels match the COC? ®o ® ® incomplete info ❑ Illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? o Were all of the samples listed on the COC received? 0 samples received but not listed on COC samples listed on CDC not received [] Was the sample collection date/time noted? no Did we receive sufficient sample volume for Indicated analyses? o Were samples received in appropriate containers? o Were VOA samples received without headspace (<1/O bubble)? g o Were trip blanks submitted? FR— o listed on CDC ❑ not listed on COC ❑ 28. Have containers needing chemical preservation been checked? • o 29. 30. Containers meet preservation guidelines? o o Was pH adjusted at Sample Receipt? .mote: t enam anaiyses require cnemicai pressrvation out must be checKeo in the laboratory and not upon Sample Receipt such as Colifomis, VOCs and Oil & GreaserrPH. I certify that I have completed sections 28-30 (dated initials). MDP 10/9/19 Checklist 6.9.17 Rev 2 Locked Page 5 of 6 Anaiyticai Environmental Services, Inc Date: 15-Oct-19 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name, 9100099 Workoi-der: 1910899 BatchlD- 286382 Sample TD: MB-286382 Client TD: Units: mg/L Prep Date: 10/14/2019 Run No: 409240 SampleType: MBLK TestCode: HERBICIDEs,TCLP SW1311/8t51A BatchID:286382 Analysis Date: 10/15/2019 Seq No: 9206470 Analyte Result RPT Limit SPK value SPK Ref Val a/oREC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qua] Z,4,5-T1'(S11VCx) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.3725 0 0,5000 74.5 49.4 120 Sample ID: LCS-286382 Client 1D: Units: mg/L Prep Date: 19/1412019 Run No: 409240 SampleType: LCS TestCode: HERBICIDES, TCLP SW1311/8151A BatchTD: 286382 Analysis Date. 10/15/2019 Seq No: 9206472 Analyte Result RPT Limit SPK value SPK RefVal "AREC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4.a-1 r (buvex) 03549 0.20 0.5000 71 0 49 120 2.4-D 03745 020 0.5000 749 509 120 Surr: DCAA 03807 0 0.5000 761 494 120 Sample 16. 1910899-001ANIS Client TD: CLASSA Units: mg/L Prep Date: 10114/2019 Run No: 409240 Sample Type: MS TestCode: IiERBICIDES,TCLP SW1311/8151A Batch[D: 286382 Analysis Date: 10/15/2019 Seq No: 9206479 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qua] Z,4,5=1 P (Silvcx) 04017 020 0.5000 80.3 482 120 2.4-D 04140 0.20 0.5000 82.8 45 130 Surr: DCAA 04053 0 0.5000 81.1 494 120 Qoatincral > Greater than Result value a Lesr than Result value ca CD BRL Belowrcpoxrutg hmil E Estimated (value above quantitation range) s ) Eslinmted wlue detected below Reporting Limit N Anolyienot NELACcmiritei p Rpt Lim R poning Limit S Spike Recovery outride limits due to matrix 1 () R Analyte detected in the associalcd method blmxk H Holding times ror preparadon or analysis exceeded R RPD outsidelielilsduelomalrix Page 6 of 6 TOWN OF MOORESVILLE CLASS A BIOSOLID PELLETS UTMIZ A.TION AGREEMENT DISTRIBUTED UNDER NC DWQ PERMIT # WQ0036723 I. CONTACT INPogm Yow THIRDPARTY TOWN OF MOORESVILE VF® T14b AA�� lLGINFORMATION Name i1G w4 Larry Hendren 6 Q Ad � 5"� VY (Permittee Designee) Mailing Address , . jP.O. Box 878, Mooresville NC 28115 Laedl, 704-799-4063 Phone Number 7441— ✓raj-. �d Email a.E) Zjnt A49-A_ arF_Sjri+�-lit wY. lhendrcn@rnooresviUenc.gov II . DESCRIPTION This is pelletized material produced from the heat treatment of residuals from municipal wastewater. This product meets the standards for a Class A biosolid product according to the EPA's 40 CFR Part 503 regulations. III. RESTRICTIONS Residual land application is prohibited except in accordance with the instructions on this Utilization Agreement: 1. If the residuals are likely to adversely affect a threatened or endangered species listed under section 4 of the Endangered Species .Act or its designated critical habitat 2. If the application causes prolonged nuisance conditions 3. I£ the land fails to assimilate the bulk residuals or the application causes the contravention of surface water or groundwater standards 4. If the land is flooded, frozen, or snow-covered, or is otherwise in a condition such that runoff of the residuals would occur 5. Within the 100 year flood elevation, unless the bulk residuals are injected or incorporated within a 24- hour period following a residuals land application event 6. During a measurable precipitation event (Le. greater than 0.01 inch per hour), or within 24 hours following a tainfill event of 0.5 inches or greater in a 24-hour period 7. If the soil pH is not maintained at 6.0 or greater, unless sufficient amounts of lime are applied to achieve a final soil pH of at least 6.0, or if an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for the specified crop 8. If the land does not have an established vegetative covet unless the residuals are incorporated or injected within. a 24-hour period following a residuals land application event 9. If the vertical separation between the seasonal high water table and the depth of residuals application is less than one foot 10. If the vertical separation of bedrock and the depth of residuals application is less than one foot 11. Biological Residuals shall not be stockpiled for more than 30 days prior to distribution 12. The Third Party accepting the residuals shall provide the Pettsiittee with all other nutrient applications (ie. organic and/or inorganic fertilizers) 13. A copy of this Utilization Agreement shall be maintained at the site when bulk residuals are being applied 14. The residuals shall be prevented from entering any public or private water supply source (including wells) and any surface waters (e.g. streams, lake, river, wetland) 15. Residuals should be land applied at agronomic rates 0 2016 Town of Mooresville 16. Submission of Soil Samples prior to distribution of product 17. The Permittee shall. not distribute bulk residuals to any person or entity known to be applying residuals contrary to the condition of the signed Utilization Agreement IV. —SETBACKS Applicable setbacks in accordance with 15A NCAC 02T .1108(b): Description of Setback Setback by type of application (feet) Cake Residuals Private or public water supply 100 Surface Waters (streams — intermittent and perennial, perennial waterbodies, and wetlands) 25 Surface water diversions(ephemeral streams, waterways, ditches 0 Groundwater lowering ditches (where the bottom of the ditch intersects the S 0 Wells with exception to monitatingwells 100 Bedrock outcrops 0 V. ARRUCATION RATES Application Rates should not exceed the calculated nitrogen requirements based on the Realistic Yield Expectation for a particular crop and the predominant soil series within the application area. This product has a North Carolina Fertilizer label of 51/o Nitrogen —1% Phosphorus — 0% Potassium ratio, but given that it is generated from aerobically digested residual biosolids it is assumed that a 30% mineralization rate (Organic Nitrogen to Plant Available Nitrogen) is used to calculated the Plant Available Nitrogen (PAN). The PAN listed below should be used along with other nutrient application to determine agronomic rates. NUTRIENT RANGES Percent Solids: 9_ 4-98% Total Nitrogen: 22-1001bs/ton Ammonia Nitrogen: 0.4-61bs/ton Nitrate/Nitrite Nitrogen: 9 - 0.01 Is/ton PAN: 7-401bs/ton Total Phosphorus: 20-28 Ibs/ton (as 2201 Total Potassium: V. AGREEMENT 0-81bs/ton (as K�0) •R`� A CL Hen en Town�ofMoo=esviIIMDte' Approximate Density:15 - 20 lbs/fO This Par (P . ted Name) r J Q d Party (Signature) Date 0 2016 Town of Mooresville TOWN OF MOORESVILI.E CLASS A BIOSOLID PELLETS UTILIZATION AGREEMENT' DISTRIBUTED UNDER NC DWQ PERMIT # WQ0036723 I_ CONTACT INFORMATION THIRD PARTY TOWN OF MOORESVILE INFORMATION INFORMATION Name ` Larry Hendren 0tPJ (Permittee Designee) Mailing Address s4gkeP.O. Boa 878, Mooresville NC 28115 704-799-4063 Phone Number Retail c� +��r o.'a � lhendren@mooresvillenc.gov II . DESCRIPTION This is pelletized material produced from the heat treatment of residuals from municipal wastewater. This product meets the standards for a Class A biosolid product according to the EPA's 40 CFR Part 503 regzalations. III. RESTRICTIONS Residual land application is prohibited except in accordance with the instructions on this Utilization Agreement: 1. If the residuals are likely to adversely affect a threatened or endangered species listed under section 4 of the Endangered Species Act or its designated critical habitat 2. If the application causes prolonged nuisance conditions 3. If the land fails to assimilate the bulk residuals or the application causes the contravention of surface water or groundwater standards 4. If the land is flooded, frozen, or snow-covered, or is otherwise in a condition such that runoff of the residuals would occur 5. Within the 100 year flood elevation, unless the bulk residuals are injected or incorporated within a 24- hour period following a residuals land application event 6. During a measurable precipitation event (i.e. greater than 0.01 inch per hour), or within 24 hours following a rainfall event of 0.5 inches or greater in a 24-hour period 7. If the soil pH is not maintained at 6.0 or greater, unless sufficient amounts of lime are applied to achieve a final soil pH of at least 6.0, or if an agronomist provides information indicating that the pH of the soil, .residuals and lime mixture is suitable for the specified crop 8. If the land does not have an established vegetative cover unless the residuals are incorporated or injected within a 24-hour period following a residuals land application event 9. If the vertical separation between the seasonal high water table and the depth of residuals application is less than one foot 10. If the vertical separation of bedrock and the depth of residuals application is less than one foot 11. Biological Residuals shall not be stockpiled for more than 30 days prior to distribution 12. The Third Party accepting the residuals shall provide the Permittee with all other nutrient applications (Le. organic and/or inorganic fertilizers) 13. A copy of this Utilization Agreement shall be maintained at the site when bulk residuals are being applied 14. The residuals shall be prevented from entering any public or private water supply source (including wells) and any surface waters (e.g. streams, lake, river, wetland) 15. Residuals should be land applied at agronomic rates © 2016 Town of Mooresville 16. Submission of Soil Samples prior to distribution of product 17. The Permittee shall not distribute bulk residuals to any person or entity known to be applying residuals contrary to the condition of the signed Utilization Agreement IV. SETBACKS Applicable setbacks in accordance with 15A NCAC 02T .1108(b): Description of Setback Setback by type of application (feet) Calve Residuals Private or public water supply 100 Surface Waters (streams — intermittent and perennial, perennial waterbodies, and wetlands) 25 Surface water diversions e hemeral streams, waterways, ditches 0 Groundwater lowering ditches (where the bottom of the ditch intersects the S 0 Wells with exception —to monitoring wells 100 Bedrock outcrops 0 V. APPLICATION RATES Application Rates should not exceed the calculated nitrogen requirements based on the Realistic Yield Expectation for a particular crop and the predominant soil series within the application area. This product has a North Carolina Fertilizer label of 5% Nitrogen —1 % Phosphorus — 0% Potassium ratio, but given that it is generated from aerobically digested residual biosolids it is assumed that a 30% mineralization rate (Organic Nitrogen to Plant Available Nitrogen) is used to calculated the Plant Available Nitrogen (PAN). The PAN listed below should be used along with other nutrient application to determine agronomic rates. NUTRIENT RANGES Percent Solids: 94-98% Total Nitrogen: 22-100 lbs/ton Ammonia Nitrogen: 0.4-61bs/ton Nitrate/Nitrite Nitrogen: O - 0.01 lbs/ton PAN: 7-40 lbs /ton Total Phosphorus: 20-28 lbs/ton (as PION Total Potassium: V. AGREEMENT 0-81bs/ton (as I4C O� tot Larry Hen Town of Mooresville Date Approximate Density:15 - 20lbs/ft3 A0 Pf-94;leo Third Party (Printed Name) Third Pax ignat =e) Date © 2016 Town of Mooresville TOWN OLD MOORESVILLE CLASS A BIOSOLID PELLETS UTILIZATION AGREEMENT DISTRIBUTED UNDER NC DWQ PERMIT # WQ0036723 I. CONTACT TNFORMATI0--N THIRD PART` I�NF TION Name �r Mailing Address 116 -0 ✓ e n t4S J /- Phone Number a - - .34' 7 Email TOWN OF MOORESVILE INFORMATION Larry Hendren (Permittee Designee) P.O. Box 878, Mooresville NC 28115 704-799-4063 lhendren@mooresvMcnc.gov II . DESCRIPTION This is pelletized material produced from the heat treatment of residuals from municipal wastewater. This product meets the standards for a Class A biosolid product according to the EPA's 40 CFR Part 503 regulations. III. RES'T'RICTIONS Residual land application is prohibited except in accordance with the instructions on this Utilization Agreement- 1 , If the residuals are likely to adversely affect a threatened or endangered species listed under section 4 of the Endangered Species Act or its designated critical habitat 2. If the application causes prolonged nuisance conditions 3. If the land fails to assimilate the bulk residuals or the application causes the contravention of surface water or groundwater standards 4. If the land is flooded, frozen, or snow-covered, or is otherwise in a condition such that runoff of the tesiduals would occur 5. Within the 100 year flood elevation, unless the bulk residuals are injected or incorporated within a 24- hour period following a residuals land application event 6. During a measurable precipitation event (i.e. greater than 0.01 inch per hour), or within 24 hours following a rainfall event of 0.5 inches or greater in a 29-hour period 7. If the soil pH is not maintained at 6.0 or greater, unless sufficient amounts of lime are applied to achieve a final soil pH of at least 6.0, or if an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for the specified crop 8. If the land does not have an established vegetative cover unless the residuals are .incorporated or injected within a 24-hour period following a residuals land application event 9. If the vertical separation between the seasonal high water table and the depth of residuals application is less than one foot 10. I£ the vertical separation of bedrock and the depth of residuals application is less than one foot 11. Biological Residuals shall not be stockpiled for more than 30 days prior to disttibution 12. The Third Party accepting the residuals shall provide the Peamittee with all other nutrient applications (Le. organic and/or inorganic fertilizers) 13. A copy of this Utilization Agreement shall be maintained at the site when bulk residuals ate being applied 14. The residuals shall be prevented from entering any public or private water supply source (including wells) and any surface waters (e.g. streams, lake, river, wetland) 15. Residuals should be land applied at agronomic rates 0 2016 Town of MooxesvMe 16. Submission of Soil Samples prior to distribution of product 17. The Pennittee shall not distribute bulk residuals to any person or entity known to be applying residuals contrary to the condition of the signed Utilization Agreement IV. SETBACKS Applicable setbacks in accordance with 15A NCAC 02T .1108(b): Description of Setback Setback by type of application (feet) Cake Residuals Private or public water supply 100 Surface Waters (streams - intermittent and perennial, perennial waterbodies, and wetlands) 25 Surface water diversions (ephemeral streams, waterways, ditches 0 Groundwater lowering ditches (where the bottom of the ditch intersects the S 0 Wells with exception to monitoring wells 100 Bedrock outcrops 0 V. APPLICATION RATES Application Rates should not exceed the calculated .nitrogen requirements based on the Realistic Yield Expectation for a particular crop and the predominant soil series within the application area. This product has a North Carolina Fertilizer label of 5% Nitrogen -1 % Phosphorus - 0% Potassium ratio, but given that it is generated from aerobically digested residual biosolids it is assumed that a 30% mineralization rate (Organic Nitrogen to Plant Available Nitrogen) is used to calculated the Plant Available Nitrogen (PAN). The PAN listed below should be used along with other nutrient application to determine agronomic rates. NUTRIENT RANGES Percent Solids: 49 ° o Total Nitrogen: 22-100 lbs /ton Ammonia Nitrogen: 0.4-6 lbs/ton Nitrate/Nitrite Nitrogen: 0 - 0.01 lbs/ton PAN: 7-40 lbs /ton Total Phosphorus: 20-28 lbs/ton (as P20si Total Potassium: V. AGREEMENT 0-8lbs/ton (as &,) �;►� -- ,fir ! ,�►� , � � +, ■ + to k"i+i Town ofMooresville Date - Approximate Density:15 - 20 lbs/fe Third Party (Printed Name) Third Party (Signature) Date 0 2016 Town of Mooresville Jan Feb Mar Apr Daily Dryer Log May Jun Jul Aug Sept Oct Nov Dec m ��- E!"W NI U d 0 Q Z tw J 0 ON° V QNi lNn {a W N FN� O lY0 ° 10- v W N Fes-\ p lfl 00 V 01 Cn A W Ni FAru N M 0. Q 1 2 qj N N— J J �1 -3 " .9tj N L N Qi �J ty 9J O Q rTa are DUO OSWin: m Q C' pp a. Q 0 r ra (� o O a Q j� J Jz G `� 0. N ID 00 D Ln lz rAa �1 e,JW.a O l�n N V� JU C} 00 VI. 3 d J� O oG� �ap3 .h -v K rj� y pV1 N �r �� 6°n QW �O 10 O , �f p O1�Vn4i 3 _ Or �jQ 3 3 .� eip 44 'O N N 0 Y C-� ` y V) m Z C v m A YEAR_ aC)( Jan Feb Mar Apr (Daily Dryer Log May Jun Jul Aug Sept Oct Nov Dec Date Feed rate ibs/hr 8AM 413M 12AM Time Temp %DS Initials Time Temp %DS Initials Time Temp %DS Initials 1 °qfo 9� /SY 2 s� v i �a 66 � �$ M d ' �o/ l . . 0CJ 0% a-S� ��, 1" Pat 1 a a o 5G, t q ? 11 / !ffi' 12 0 2 7019, qq 6 I.Z, L,o 11�. 4,14 03 Pp 1 cl 7 ?.1% `7'S 1151 1°I% 7 8 9230- - -0 g-1-;2KO& 147 S ° ell `% Ctq ID —1�"SS 3: s ` 3 % s's 1 c/ 1-7 Z. 'H S 4;44- 1Z0- f2 /0 Iq G 1 a7 clef 7- q -Ay 1� 10- 2ZZ cz 'W oo 1 1-7 °7g •�o Q 11 Z3oa It os, / `I t qq "/. C-k T S 15 1 99 Y, L,tj � . 12 'q• Dq f( �,Jr, O t X 13 �7.�-i Obi=10 61Z 0 9 % ~%' q 14 AIV O'(ts' 114 Irf KI . - i+OW i4x0em 197 9q!• 121q 1f 7�j 9' . y rlCSyY 16 17 7A,;b 3l�l� ti q d4 ° �{ 'S1: o-0 O 1gG' o Z9 'r L`�1 / • 1 ?, W'`,XTY 18 Z 3'Z.S �: i /197. '�"/ ��o Limit • r ' q!' 19 1z3vo 3C0.0 118-0.. 1179% j q?r qq ,f 21 1 qq, / ;� 4 7 9% •.r 22 Qeoo olf tail" .o -3S IL2 ! q y ozrROL / 24 Z2.C: 0Z55 q9°lc U qqj 1q . qq .r 3-KZS- 25 26400 27 .2 200 c�0 0801 0 1!S 19 i . a7` co '• . ` y:3 m y:v� � 1 7' 19V '.. 99 /, ciof*/. I -r5 A- . S is 1147 7' I C[g 1q4 RQ`. `, 5ld o ZYT s 151k 28 29 30 2200 O D 7ss 03 iti ;. ° o Jtp:o0 ti:3 9lo° 6�ii q' , +0 MN 12 0 `7 1 • 9 ®o r� lsi 31 YEAR Q 'O `l Daily Dryer Log Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec Date Feed rate Ibs/hr 8AM 413M 12AM Time Temp %DS Initials Time Temp %DS Initials Time Temp %DS Initials 1 zz-m %t'os Lg % 9gc'1� L a - .1 7' �• a Z 1% ` qq' . f� `�X. Y 3 2275 75 /r?6 g9`/n TSY 12 117 cr% IS 003r- 197* at ta/!jG 4 : �:3�P�+ 1 99/ S Iti uy C' q% /-, 5 ;j?S Ir:r3IV '. 11.0 mn ! /' I Z oZ Iti 1 17% ISY 6 S bi 5 5 Q .7? 7 Y M I ei 74 % .' 1 1 5 ass B ass ► sj' 7 237> 09 14 0A t'11V 3q a A0. M fitd X. 7qy- ST s I j5q 1M 1!7 d 11 o I: Prw� 41' P� o p% i` q 10 V !09-A,,,%q9/ /SY 97° 9,97,o 11 A300 -6 -. 45A I g' R114 nzy q:05 tNa" 961-A Pr. Ob I Ll ( °�' gm/o i&;% 12 w 17' Y� 3 'WS 190 9g l� - 11y 9G Tory" 13 ?-LCo o1',# 5 o /117 '71 19il ®. 12 o 9,107, 15Y 14 2 Z 0 0 :00 4q L :OD l q& qqL •. 15 Z2 to -a V iO 1510 0 M q y. 11 S Z j 91 y 9% i S:Y 16 ,A :a. P°�s5. Gss 1 �55 O 5 `18/a &I 17 ZZS6 0 'i' : 1 sj % -7 9 yli L, '50 gio pis O 76 5 y t 1970 i `✓ y 18 22 8o 0*755 )q'7 91 -f ' om- 1 19 AA b72 41$ 1, 'm l M 1 � &`' � 12,Oq 19 5 20 aL. YO 01a-.1 tovi ` ;do � �-7 21 a3 yQ a d 0M A ° "(0 M# /aop 22 �00 0rA-3 I C17 1bM M4,3S"7 `1 �% Cis•- 23 o �'.AAI ' 7 a Q ` 24 O sr:-/3 1 S" 41/j Z S ;03 m 1 S' 120.3 A G 25 2250 ?,,30Affi, 'I jg 9 9 �/6 —ART N%ob lq(o' '/, 1155 IR 6 q9'r isy- 26 =5sl? 0 t I, 01'1 d 41 ISOM 19 11 2 q ro Ps Y 27 )D 61 'Al1000 `ly To 1(2 OA let , 'Yo l 196 g % 28 ,: V-O I or6go tq-14 )?' 10a qi oD Pig. 197 177. &A 'a 1Z 29 la I- W6 0 2zY5 �: to 1_g7 V?- 'z ��ae ' <48 '� Yo,� L'N ia%� • . F31 Z7-W SS;� 11-e I T Z io4 /�� `yr/ 1213 4 IN YEAR XWIR Jan Feb Mar Daily D, yer Log Apr May Jun Jul Aug Sept Oct Nov Dec Date Feed rate Ibs/hr BAM 4PM 12AM Time Temp %DS Initials Time Temp Initials Time Tepmy p Initials o%�DyS p%DS F43 11 ;taff- 0�70 A- N N dV1 30P14 5 alll-IC' lJo 641 R Ass t3 << t„44 M elm % ff i u ; 6 9A&L :BVWxj 7 �i tzo� 0 19 $ �9 g 7 �-#� �. 4 ..sr / !o ' S' �� S ! ! 1 i ro ' � 1 S 8 D •� q 0 9% 1 _S rq9 9 70�. yy 9 10 - 11 71 S0 6Z0 at�c� 16 s o b 06 t/ VOL qq / �Cp �l d4i . -ir10160 /► t p -cSl I° r ?° /� Arf- I Z O i 1,15S 14 G l 4 6 � `17 `/ I `S l 5 Y 12 -;k3 S'O O 1Rp o A P11`' O 3142 ° -? °(a ; �U JqT IS' . 13 14 a4Oo D I dg ? `S 1R?` `, = 1 Q� Mt► M a R'7 �6 7`- �16 do is l 7kA5( 'CA — ,S 207 9 s/ 17 UV q-7 ° -7°d I I-$ M I ° .18 q00 o$at/ C07 0 a r^ h ors 19 z BC �c°� i4)7" TR /a 1 3a.1rM 20 21 22 23 24 Z4 c6 3G 3 teoo 4'; 10. `! a� 9? I9 ` LOW P. 1 d aJ `3SI ' ° R °l y'� i co ;Jr2�r'7 q.tjGpMItyt: �» a M 11 ° h 17l 9't , h o . i S'2 Z© 11(. 1 r ct 2 ©o 7 lo 15, /5'/ �Sy 26 ov OIL(gA L CA71° -1° 3 M tq., q� MM 2 B 2 t 7 o t s Y 27 3?00 ,T-*,. o � g 5w' '/v 4_jA : o o 0. 4° Z� J ©(. 1 15 Zs 00 Z5 9ja srs 9 i s -r 191 q m 5. 29 300 :Do M �f° -1 p !% �0 M Iqy� -7Il q 07 19 V 71' 30 3 boo 0 75S t ?5; 91V0 TP Pligrld—m 9, I i q s qG 31 ' , Dwa kv ."t-6�&ce- +� WN U YEAR �b` 1 `i�llo�iK �3K►J * lfr7VAM rLuwj 'WwvA,� aiv - r IC/ Daily Dryer Log Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec Date Feed rate Ibs/hr 8AM 4PM 12AM Time Temp %DS Initials Time Temp %DS Initials. Time Temp %DS Initials 1 3 v Iy Ig$° al° pt�,N 33SPM � .� t2o5 IR5 97'�a [SY 2 00 ONO LW O ifm t" 15Y 3 17WO 10111°l(o' 4,106 FR a-'lWA LAso 4 97%, L "ov rn) 911' 1209 1 etc s 6 7 3�eea�o TOf 3 7;�� 07ib 151 Igo ! B% 57 tl'r L� � e i;W M y:ug5 -6 qq' 1 1 0 F 9 y° 7% q� /, q'i ,7, Iy S I1.5-, llq o I�jR6 Z00 j. C 18% % - 15�/; 57 15 Y 8 3 $'O`D g �. O 0 % �% 7 nlr � 1 1-41 1' !� ( e o q1 014 MPH 159 Zoo q 60/' Is 9 �dv 08oZ$" .° S° AW : 1 7 ` 7-16 IK5 2©1 6 7. .5 16 `)-C� 6 I �&Q 1°J f/ Tito /A OlV % 12Oy Z00 f �o l 5 1 11 36,b b at, 15'0- 1 -1 .:111 % � � S v r � ! 4 17 n� �� I I L 3 lie Y. /5 12 346o-n $ : o0 /5 4148 'CL, IV, t 160' 97 % I CY 8 1767.0 15 13 3S0.0 0805 1 n q 'T 1111.20 m 1931 S.. Q 7m/ j S 14 15 S,TSdrO 013 g s6 �94 1 11,16 `i VY6 "L:6`I Al;D3c� y:l 9 r 19 `� q.i/ % '�!� I20.(7 4ylo Dfy�� 201 OFF r17 V. 15j 17 3 %ao . 1600 q.v- 97 L-K ':oS I gS 0)7 V. L-fq 201 % .5 Y 18 19 38 Q r3 '1106r, �s�os I `14 s' 977. 7.7'�� L:-N L� q-, 3:5�' /? s c `�S 17 °�. '1'7 �7,1 sty � C73 �1 yG 2Q 1 � ��° 9 7 Y. /Sv s 7ro L 10 7° 115'�l n C% /sy 21 3 (7t7 OZ I AM 7 t 3% 0 +n. 17 O 9 "7 `/i I Z 01 2 O I %% l S. 22 JM60 23 3.Vd) -0'7j� I iUO° O 7 `4 �7 tP& 3.3 3 MM Ic� y a;0 I q7 c201 I Rx" - r 15 24 3ao0 0%2a, j-a �ii8� ��p� / ; i o r I.�' �l 26 Y_a)� rg�;®y ��7 yg"/r`.� c,- .03 Ig d q16'; it 19�1 9 7a� 15 28 4(aoo 70 i..Uta it: o t r, NPIF 6 % -7 S I -K 2 00 7/o 29 07g1 fjA V GC 3 �t'. V.'l?A tc66 9 x 7a K I?- Z J I 1-by 30 "00 lal Ae uY4 y --o Pm l,C r ° m- 31 3'1cro YEARS 0 / / Jan Feb Mar Apr Daily Dryer Log May Jun Jul Sept Oct Nov Dec a i+ �+, t `.� Le.6g�i'ifl'.a�l'litll►��._�<I3:�7 .® e ` " % �� . `■"t:77 a ��a��.�a��^'!'�l��t � + �33r ® •' mEmrmm • V�aE&Il ® UMa.CM 0la2. 0i ' LLi1 PWft=EWA ..- I- NUM ;, s: �F�r7 •► � IS��'�'a��J�T�{a�� ' Leta � m � W-M M, m sUmmiA ► ► �' .E"'�' r.. MEN' YEAR Z0l f Jan Feb Mar Daily D, Ver Log Apr May Jun Jul Aug Sept Oct Nov Dec Date Feed rate Ibs/hr 8AM 413M 12AM Time Temp %DS Initials Time Temp %DS Initials Time Temp %DS Initials 1 3Z,00 o s5 I4K R-7'/ OT :i0 r., q40 q.17, ql-2 R77, s 2 7a0 �0 758 95 9S°o 05 l S6 a--- Ad' 12a 1 "1 3" 'Zo (o 2jQ0 q f, ° 0 gM 3-H'7P^ JJV R -K) ? 4 3700 IQ 7 9 &tZ Old 4fayft4 11 ° q d ad!0 4'- S 137 ; o0 7 1?% 3.�9 171 77'/ '-k 1,200 a0Q q7'. 6 131r.00 16x1-c 11 `9�'%,. Z,}z. :/m r►! q' 017% 3' IN-2-2 2oa °d 5Y 7 3`900 . . 0 7 N1 $' 9'7 � i f 1 ci t�1 �. O e r S 8 3� L��° 7 . , 15 1"1 • d 9 316W ail tew 1' ;: l d 13 9° 0 5 Y 10 ' (�c o.Z t 1 `� 31 M1, ., gphmt '/. 11 1,3600 014; 1 halo 3 s n 19V 7 :! Q *TXT 12 376c, 0000 1194 4tioyo- 3:54 Owl 97% try 13 37. o o 7So 1913 ° R 7%- TP 0:oAM 1 3" 177 %, `T 12 1 y 14SI 14 37570 1150 1 9(07/- Af- M 100 '/. ITZT 1 I S19 1418 1*o / Sr 15 '1$b 5 M 7°1a `'!.,11)m o CPS V. O 1 q 75ea 1 16•.. 77 1 1 S° g1tl N:0 c % ffQ14 121 Z 200 9 7 % I SY 17 77 099, KV qI °l°0,14A, y=1 -o ° �3a 18 310 0141 1j5 7 o 19 38,MC2, V , 17 '% Ili • �' � '� 11151 ° '� %� 20 Z'Oto0 -q 1. i�p I °l �} ` � �1 9:7,2 v%% 19ta' .g 7 Ya 21 3'oc S Pg QV4 H.0-711m 7'/, 22 3S 6- °1'2 N:03 04F `TES' 1200 1�ryer oF� ISY 23 341 0 1 4-1 is,56 a7•n/ . 53 ► `'1 � ✓� t 5Y' 24 Z`33o t., -Or 19 '/D t : ; Y T° C1I °lo tS ', 1" 25 `��i30 0 k�du ; '/ 11717 26 3''i3io I. I'll Sjqq7'. 27 S130 CjI g' , y;e9 6? -- v S. i��. 61 A f 28 3 �r :'js 1 9 1 O q '/• 11 �fZaa 2� -1 7 �p SY 29 021414 0103 W �1 �1i 40 m" & fJ 1 S 30 U otblaftft ow 4ys t 5-0 cJK- 31 YEAR �O 19 Jan Feb Mar Apr Daily Dryer Log May Jun Jul Aug Sept Oct Nov Dec 092ei �i�; �iO r E! ' "O ® .ate I:o '♦ ��'� �� ®f.•�'.� �� ® ' ' " '' = � • • ' ' % ,�.� .: it � ; �! Q� r��, � = ` ®_' m, I �- `Jii A 9Sil`lL� ■l`��, m FFIWA5�fm - 3 7i Mrl" NA % �Evilrim � �� Z M=-MMM OMM I Y , , I I fAV MUMa +� ., 1. * m MOMIM Is �MA-= �� i�a� m ��r/mil/�'��-� or Z)a0 & PO }daS Bny inr unr AeW Sod aaA,(3 AlieCl AV aeW qaj uer 2fd3,k Q U 0 tw .0 L �m ca a :2 '�emmommoo��eeeee�ee��ee� a C— i AS, Non -Discharge Branch Upload/Submittal Form a NORTH CAROLINA Environmenral Quality Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other issues. ............................................................................................................................................................................................................................................................................................................... Name* Jamie Levis Email Address* jlevis@mooresvillenc.gov Project Information Application Type* O New O Renewal O Annual Report Permit Type* O Wastewater Irrigation O Other Wastewater O Closed -Loop Recycle O Single -Family Residence Wastewater Irrigation Is a paper copy of the application being submitted?* *Yes 0NoON/A Permit Number* WQ0036723 Applicant/Permittee* Town of Mooresville Phone Number* 704-662-8341To O Modification (Major or Minor) O Additional Information O Other O High -Rate Infiltration O Reclaimed Water O Residuals O Other: Applicant/Permittee 369 Johnson Dairy Rd, Mooresville, NC 28115 Address * Facility Name* Rocky River Wastewater Treatment Facility Please provide comments/notes on your current submittal below. For new and modification permit applications, a paper copy may be required, If you have any questions about what is required, please contact the reviewer or Tessa Monday. If a paper application is required, be advised, applications accepted for pre -review until both the paper and electronic copies have been received. The paper copy shall include the following: o Application Form o All relevant attachments (calcs, soils report, specs, etc.) o One full-size engineering plan set o One 11x1r engineering plan set o One extra set of specifications o Fee (if required) Railing address: By U.S. Postal Service ----------- --- - - ----- ; By Courier/Special Delivery: -- --- ---- --- --------- -------------- Division of Water Resources Division of Water Resources -- Non-Discharge Branch ------------ ---------------------------------------------------- ; Non -Discharge Branch 1617 Mail Service Center -------------------------------------------- 1 Att: Nathaniel Thornburg, 911 Floor, Office #942W --ry,�".--------- Raleigh, NC 27699-1617 512 N. Salisbury St. For questions or problems contact Tessa Monday at tessa.monday@ncdenr.gov or 919.707.3660. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form, Engineering Plans, Specifications, Calculations, Etc.) CLASS AANNUAL REPORT STATE.pdf 28.57MB Upload only 1 PDF document. Multiple documents must be combined into one PDF file. * p By checking this box I acknowledge that I understand the application will not be accepted for pre -review until the paper copy (if required) and fee (if required) have been received by the Non -Discharge Branch. I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Signature* Submission Date Is filled in automatically once submitted. r Town of Mooresville NORTH CAROLINA NCDENR-DWQ Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699 ROCKY RIVER W.W.T.P TELEPHONE (704) 662-8470 FAX (704) 662-8473 POST OFFICE BOX 878 MOORESVILI t1EPX-di5'NCDENR/DWR FEB 2 6 2018 WQROS 02MAWSVILLE REGIONAL OFFICE Subject: 2017 Annual Sludge Report, WQ0036723 Distribution of Class A Residuals Following is the information requested to accompany our Class "A" Annual report. 1) Facility - Rocky River Wastewater Treatment Facility 369 Johnson Dairy Rd. -- Mooresville, N.C. 28115 Phone: 704-662-8470 1 2) Responsible official and facility contact — Tom Wynn, Operations Supervisor P.O. BOX 878 Mooresville, NC 28115 Phone: 704-799-4054 3) Class "A" dried biosolids were distributed under Town of Mooresville permit # WQ0036723 4) (Part A) and (Part B) Distribution of Class "A" Residuals for 2017 were transported to, Joe Hampton in Mt. Ulla, NC (SSUID 001), Mike Bowers in Troutman, NC (SSUID 002) and Jeremy Wayne in Davidson, NC (SSUID 003). Total = 568.98 dry metric tons (See Attached Hauling Summary Sheets). Laboratory data from quarterly TCLP analyses have been included in this repo 5) (Part C) I certify, under penalty of law that the above informatiolG�Jv� 'and belief, true and accurate and complete. I am aware that there are sigh rt� G �lse information, including the possibility of fines and imprisc Prepared by: Tom E. Wynn, Operations Supervisor Reviewed by: Jamie Levis, WWTP Plant Manager Sig. �- -�' 2 .Z eS Date Signature Date Town of Mooresville H,c!u,llqg'Summary$heet A -kjlkl`-ilj� A �� --A 0 �0 —ba �NIAAPOA 3/9/2017 13 Gurin Klutz Farm Mt Ulla: I load ri K u ar n m F .-21bad' s 16i5 rrin . ija 4.: loadst '8/-i`9"""/2"ibD- il.b: 6-arrin KjqT4,F#rm,, Mt Ola! `2 loads: b 6aKriO k(Uf4:F rM,2 Mt;, Ulla 3, (00ds 3/26/20,17 41. 0' Garrift KILitf, FathIr Mt:l I VIIA 4- . lbaft- 4/12/2017 i;3.b %rriR Kfu4'farm. ,Mt 0414. 6/2/ rd 0&fff Farm - 3,3.5 Gprrin z'Farm mt,ulla` lloads: 6/4/2017 13-D GarriO.K(Uti-Taft mt. UIIA 'I load' 17 fg.., 5 Garri Kl'uti-.Fapfti mt-uflEf 2 loads; 7124/ZQ17 8,.3 'Mike e',,'lBbw'eTs. Troutman 4 loads,,. -7/29/2017 33.0 Garrih, Klutz -Farm Mt. Ulla_ 3 loads,- _,$/1;9/2017 41,0. Gaedin Klutz farm Mt,.,Ulla. 4 loads 8/20/2017 25.0 GarriKKIOtz Farm Mt.Ulla.. '2 loads 8/21/20,17- 20.5 'da:rrin-Klutz. Farm mtulla 2-loads 8/8/2017 4.7 Town of PlooilrosVillle, Mt.`Ulla' .1 load 8/24/2017 14.0 Town b.fMooresville Mt.,Ulla 3 loads 4/Z5/2017 41 Town of Mooresville' Mi.,-Ulla '8/2-6/2017 8.2 Town of Mooresville MtUI'La 2 load I s 8/17/21017 8Jy Town of Mo-oresville, Mi.Aiwa 2. Pads ,8/29/2017 AA Town of Mooresville; Mt Ulla I [bad 8/81/2017 13 Town of Mooresville: W U Ila Ifoad 9/1/1017 3. 1 'town of Mooresville loi.blla 5/2,/2017, 4.0 Town of Mooresville, Mt. U.11a I load.: 9/4/2017' 4.2- Tqwp of M66resville MT,- Ulla -d 91612017- 3A, Tpwn,(?f Mooresville Mt. Ulla .11 -d 9/7/n17 AA Town of Mooresville : Mt: UO'l 1, loa�d 0/8/2017 IS ToWrf of Mooresville mt..Ofla I load 9/10/2017 4.2 Town of Mooresville Mt: Ulla iiod 9/11/2017 ZO: Town 0 Mooresville Mt Ulla 1 toad 9/13/2617 4.4 Town of Mooresville Mt. Ulla Ilload 9/14/2617 4 ToWn.of MobyesVlfie mt. Ulla -4 110d 9/17-/2017 -4,b, Town of Mooresville mt. ull'a I lo6d 5/19/2011 4.0 Town Of Mooresville Mt. Ulla .1 load 9/0/2917 41.3- TpWh.of Mooresville- mt. Ulla, 1 Wd :9/12/2017 3.3 Town of MbbtesVllle mt. ullzf lload 9/23/20I7 316 TomVp'.Q.fM0.0tesville- Mt QUA -1joad ,9/25/20117 3A-. ,T,OWri'bf Modres-villd mt. ulla, 1 load 9/26/2,017 5;,,0 ToWn,of Mooresville. ille mt. UIIA 1.1oad 9/283/12017 :A Town of Mooresville, Mt Ulla 1 load 10/1 2 /2, Ui 7' 5.0-- Town'd' oresvillle: Mt,.Ulla I load: 10/4/201.7 4-3 'Townbf Mooresville. Mt-:Ulla I load.: 4. fown-of-Mb-ores'illie-, a�- - 'Mt, Lill' - i - load: Town, of Mt Ulla 10/8/2Q17 4.8 wn� f Mooresville,. Town o, mt Ulla. 7._ Town; -of Mooresville. Mt Ulla:2 loads. 10/13 61-7, 4:.0 Town of Mooresville, Mt ,Ulla, 1 load. 1d/15/2017:44 'Town., qfMooresville` M , t;,Uila, 104 10/,17/,20i7I 4,.6 Town b o resvq.6� mt4,.ull8 1 load 17 4-5 Town -0- rps�illb 5 mt. Wa i load p 10f20/2P17 4.5 Town Of Mod re - sVi I I Mt Ulla 1 load 10/21/2t 17 4.6 Town of mpof6s4illi'q: Mt. la,, I I oa d 41127/2017 .43 'Town Of Mpqte9016,,, W,Vlfa., 10/28/2017 4.01 T6Wh of Mooresville: mt.,Ullg 1 load 1-1/1/20:17,' 4.2 Town of M66,resVjlj& __..,MtUllA I - load. 3.8 T6Wh bFIVId6rdWild mt. U118 load-, 11/5/201-1 4.8 Town of MOOt�esville Mt.,Ul,Ia load.' 11/7/2Q17 4.0 ,'Moo.resV.. il Town 6f16 . MtUlla I load,: 11/10/2:017 17 Town of Mooresville- mt. Ulla 1 load. 11/12/2017, 3.8 Town of-m6o,resvilfe Mt. Ulla -!'load 1 1/14/-20-17- 4.6 Town of Mooresville Mt; Ulla I load 1:1/16/2617- !'own of Mooresville Mt. Ulla 1 .16 ad 11/17/2017 3° g Town of Mooresville Mt. Ulla i-load 11/20/2017 440 Town of Mooresville Mt.. Ulla 1 load 11/22/2017 41 Town of Mooresville Mt,. Ulla ,load 1 1/2 %7, 1 603 :Carolina Seeding 1 moorgsvflte 14 load's TOtal*fons 64-0 Avg..% solids :6.04 2 Pry tons 00i Conv,ersion f4dor 6e 907124 M'e#it tons, 546;6 Dry rnc,�trfi: tons 5512s0 Dryton total tons 099.1 640-.61 0.942. Metric tons: =total tons, *' conve;rsion factor' 58fi.6 =fi46,.V,:-0;907184:% DrV ni6tric tohs .=;.m,ett.Je-t6hS- *.a.v-9,.'% s6fids 552.6 586.6 �,0.942 Town of Mooresville 2017 Hauling Summary Sheet DATE,,; TONS. TRANSPORTER `„ DESTINATION, :, COMMENTS, 3/9/2017 13 Garrin Klutz Farm Mt. Ulla 1 load 3/12/2017 17 Garrin Klutz Farm Mt. Ulla 2 loads 3/13/2017 16.5 Garrin Klutz Farm Mt. Ulla 2 loads 3/19/2017 17.0 Garrin Klutz Farm Mt. Ulla 2 loads 3/24/2017 30.0 Garrin Klutz Farm Mt. Ulla 3 loads 3/26/2017 41.0 Garrin Klutz Farm Mt. Ulla 4 loads 4/12/2017 13.0. Garrin Klutz Farm Mt. Ulla 1 load 6/2/2017 21.0 Garrin Klutz Farm Mt. Ulla 2 loads 6/3/2017 33.5 Garrin Klutz Farm Mt. Ulla' 3 loads 6/4/2017 13.0 Garrin Klutz Farm Mt. Ulla 1 load 6/27/2017 19.5 Garrin Klutz Farm Mt. Ulla 2 loads 7/24/2017 8.3 Mike Bowers Troutman 4 loads 7/29/2017 33.0 Garrin Klutz Farm Mt. Ulla 3 loads 8/19/2017 41.0 Garrin Klutz Farm Mt. Ulla 4 loads 8/20/2017 25.0 Garrin Klutz Farm Mt. Ulla 2 loads 8/21/2017 20.5 Garrin Klutz Farm Mt. Ulla 2 loads 8/23/2017 4.7 Town of Mooresville Mt. Ulla 1 load 8/24/2017 14.0 Town of Mooresville Mt. Ulla 3 loads 8/25/2017 4.2 Town of Mooresville Mt. Ulla 1 load 8/26/2017 8.2 Town of Mooresville Mt. Ulla 2 loads 8/27/2017 8.3 Town of Mooresville Mt. Ulla 2 loads 8/29/2017 4.1 Town of Mooresville Mt. Ulla 1 load 8/31/2017 3.3 . Town of Mooresville Mt. Ulla 1 load 9/1/2017 3.7 Town of Mooresville Mt. Ulla 1 load 9/2/2017 4.0 Town of Mooresville Mt. Ulla 1 load 9/4/2017 4.2 Town of Mooresville Mt. Ulla 1 load 9/6/2017 3.4 Town of Mooresville Mt. Ulla 1 load 9/7/2017 4.4 Town of Mooresville Mt. Ulla 1 load 9/8/2017 3.5 Town of Mooresville Mt. Ulla 1 load 9/10/2017 4.2 Town of Mooresville Mt. Ulla 1 load 9/11/2017 2.0 Town of Mooresville Mt. Ulla 1 load 9/13/2017 4.4 Town of Mooresville Mt. Ulla 1 load 9/14/2017 4.1 Town of Mooresville Mt. Ulla 1 load 9/17/2017 4.0 Town of Mooresville Mt. Ulla 1 load 9/18/2017 4.0 Town of Mooresville Mt. Ulla 1 load 9/20/2017 4.3 Town of Mooresville Mt. Ulla 1 load 9/22/2017 3.7 Town of Mooresville Mt. Ulla 1 load 9/23/2017 3.6 Town of Mooresville Mt. Ulla 1 load 9/25/2017 3.8 Town of Mooresville Mt. Ulla 1 load 9/26/2017 5.0 Town of Mooresville Mt. Ulla 1 load 9/28/2017 3.4 Town of Mooresville Mt. Ulla 1 load 10/2/2017 5.0 Town of Mooresville Mt. Ulla 1 load 10/4/2017 4.3 Town of Mooresville Mt. Ulla 1 load 10/5/2017 4.8 Town of Mooresville Mt. Ulla 1 load 10/7/2017 3.0 Town of Mooresville Mt. Ulla 1 load 10/8/2017 4.8 Town of Mooresville Mt. Ulla 1 load 10/11/2017 7.9 Town of Mooresville Mt. Ulla 2 loads 10/13/2017 4.0 Town of Mooresville Mt. Ulla 1 load 10/15/2017 3.0 Town of Mooresville Mt. Ulla 1 load 10/17/2017 4.0 Town of Mooresville Mt. Ulla 1 load 10/18/2017 4.5 Town of Mooresville Mt. Ulla 1 load 10/20/2017 4.5 Town of Mooresville Mt. Ulla 1 load 10/21/2017 4.6 Town of Mooresville Mt. Ulla 1 load 10/27/2017 4.3 Town of Mooresville Mt. Ulla 1 load 10/28/2017 4.0 Town of Mooresville Mt. Ulla 1 load 11/1/2017 4.2 Town of Mooresville Mt. Ulla 1 load 11/3/2017 3.8 Town of Mooresville Mt. Ulla 1 load 11/5/2017 4.8 Town of Mooresville Mt. Ulla 1 load 11/7/2017 4.0 Town of Mooresville Mt. Ulla 1 load 11/10/2017 3.7 Town of Mooresville Mt. Ulla 1 load 11/12/2017 3.8 Town of Mooresville Mt. Ulla 1 load 11/14/2017 4.6 Town of Mooresville Mt. Ulla 1 load 11/16/2017 3.7 Town of Mooresville Mt. Ulla 1 load 11/17/2017 3.9 Town of Mooresville Mt. Ulla 1 load 11/20/2017 4.0 Town of Mooresville Mt. Ulla 1 load 11/22/2017 4.3 Town of Mooresville Mt. Ulla 1 load 12/11/2017 60.3 Carolina Seeding Mooresville 14 loads Total tons 646.6 Avg. % solids 0.942 Dry tons 609.1 Conversion factor 0.907184 Metric tons 586.6 Dry metric tons 552.6 Calculation: Dry metric tons= total tons * avg.% solids* conversion factor SM ORATORIE$ INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 01/09/2017 Prism Work Order: 7010095 Case Narrative 01 /25/2017 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. i Project Manager Data Qualifiers Key Reference: � � � � �^' �2%1 _'"' �_ � Reviewed By Terri W. Cole Project Manager BH MB greater than one half of the RL, but the sample concentrations are greater than 10x the MB. CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. M Matrix spike outside of the control limits. MC Sample concentration too high for recovery evaluation. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. "9 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/526.0409 Page 1 of 14 Sample Receipt Summary ®I ` n n Full -Service Analytical 8 n J' V' I environmental Solutions 01/25/2017 T.,4.'IABOB TORIEr, ING Prism Work Order: 7010095 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 7010095-01 Solid 01/09/17 01/09/17 Samples were received in good condition at 1.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 2 of 14 J Laboratory Report X® I n Full -Service Analytical & ' ' V' Environmental Solutions 01/25/2017 -'-��.i'�''-RATORIE$ ING Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 7010095-01 P. O. Box 878 Prism Work Order: 7010095 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 01/09/17 10:00 Time Submitted: 01/09/17 12:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID ' General Chemistry Parameters ! Plant Available Nitrogen 17000 mg/kg 7500 870 100 *Calculation 1/19/17 9:14 CLB [CALC] I % Solids 91.3 % by 0.100 0.100 1 *SM2540 G 1/10/17 16:09 JLB P7A0124 Weight Nitrate/Nitrite as N BRL mg/kg dry 5.5 0.60 1 *SM4500-NO3 F 1/18/17 11:04 CLB P7A0138 PV 6.1 pH Units 1 *9045D 1/9117 14:06 BMS P7A0091 Phosphorus -Total 11000 mg/kg dry 270 130 100 *SM4500-P F 1/11/17 10:36 CLB P7A0097 Total Kjeldahl Nitrogen 62000 mg/kg dry 27000 3100 100 *351.2 1119117 9:14 CLB P7A0145 ,Ammonia as N 1400 mg/kg dry 220 85 40 *SM4500-NH3 G 1/13117 11:09 CLB P7A0156 Microbiological Parameters Fecal Coliforms 2600 MPN/g dry 0.2 1 *SM9221 E 119/17 12:50 BMS P7A0113 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 *1311 ZHE 1/11/17 9:00 ANG P7A0127 TCLP Extraction - Complete N/A 1 *1311 1/11/17 13:55 JAB P7A0130 TCLP Extraction Complete N/A 1 *1311 1/12/17 6:55 JAB P7A0130 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 1/13/17 11:53 JAB P7A0158 Arsenic BRL mg/L 0.050 0.012 1 *6010D 1/12117 21:50 bgm P7A0143 Barium BRL mg/L 5.0 0.0065 1 *6010D 1/12/17 21:50 bgm P7A0143 Cadmium BRL mg/L 0.025 0.00065 1 *6010D 1/12/17 21:50 bgm P7A0143 Chromium BRL mg/L 0.25 0.0038 1 *6010D 1/12/17 21:50 bgm P7A0143 Lead BRL mg/L 0.050 0.0080 1 *6010D 1/12117 21:50 bgm P7A0143 - Selenium 0.11 mg/L 0.10 0.022 1 *6010D 1/13117 18:56 bgm P7A0143 Silver BRL mg/L 0.25 0.00050 1 *6010D 1/12/17 21:50 bgm P7A0143 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.000094 1 *8081B 1/20117 15:36 JMC P7A0167 Dieldrin BRL mg/L 0.00060 0.000014 1 *8081 B 1/20/17 15:36 JMC P7A0167 Endrin BRL mg/L 0.00050 0.000015 1 *8081B 1/20/17 15:36 JMC P7A0167 gamma-BHC BRL mg/L 0.00050 0.000013 1 *8081B 1/20/17 15:36 JMC P7A0167 Heptachlor BRL mg/L 0.00050 0.000017 1 *8081B 1/20/17 15:36 JMC P7A0167 - Heptachlor Epoxide BRL mg/L 0.00050 0.000013 1 *8081B 1/20/17 15:36 JMC P7A0167 Methoxychlor BRLCCV mg/L 0.00050 0.000039 1 *8081B 1/20/17 15:36 JMC P7A0167 Toxaphene BRL mg/L 0.025 0.000074 1 *8081B 1/20/17 15:36 JMC P7A0167 Surrogate Recovery Control Limits Decachlorobiphenyl 32 % 13-186 Tetrachloro-m-xylene 31 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 *8270D 1/16/17 17:43 JMV P7A0165 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 1/16/17 17:43 JMV P7A0165 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 *8270D 1/16/17 17:43 JMV P7A0165 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/626-0409 Page 3 of •14 ®AR's Full -Service Analytical ® r Environmental Solutions LABORATORIES INC Laboratory Report 01 /25/2017 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 7010095-01 P. O. Box 878 Prism Work Order: 7010095 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 01/09/17 10:00 Time Submitted: 01/09/17 12:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 2-Methylphenol BRL mg/L 0.050 0.0018 1 *8270D 1/16/17 17:43 JMV P7A0165 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 *8270D 1/16/17 17:43 JMV P7A0165 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 *8270D 1/16/17 17:43 JMV P7A0165 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 *8270D 1/16/17 17:43 JMV P7A0165 Hexachloroethane BRL mg/L 0.050 0.0017 1 *8270D 1/16/17 17:43 JMV P7A0165 Nitrobenzene BRL mg/L 0.050 0.0026 1 *8270D 1/16/17 17:43 JMV P7A0165 Pentachlorophenol BRL mg/L 0.25 0.0012 1 *8270D 1/16/17 17:43 JMV P7A0165 Pyridine BRL mg/L 0.25 0.0010 1 *8270D 1/16/17 17:43 JMV P7A0165 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 26 % 43-140 SE 2-Fluorobiphenyl 25 % 44-119 SE 2-Fluorophenol 12 % 19-119 SE Nitrobenzene-d5 24 % 44-120 SE Phenol-d5 8 % 11-52 SE Terphenyl-d14 25 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *8260B 1/12/17 18:57 KDM P7A0161 1,2-Dichlorcethane BRL mg/L 0.025 0.00066 1 *8260B 1/12/17 18:57 KDM P7A0161 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *8260B 1112/17 18:57 KDM P7A0161 Benzene BRL mg/L 0.025 0.00048 1 *8260B 1/12/17 18:57 KDM P7A0161 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *826013 1/12/17 18:57 KDM P7A0161 Chlorobenzene BRL mg/L 5.0 0.00062 1 *826013 1/12/17 18:57 KDM P7A0161 Chloroform BRL mg/L 0.30 0.00076 1 *8260B 1/12/17 18:57 KDM P7A0161 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *8260B 1/12117 18:57 KDM P7A0161 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *8260B 1112/17 18:57 KDM P7A0161 Trichloroethylene BRL mg/L 0.025 0.00078 1 *8260B 1112/17 18:57 KDM P7A0161 Vinyl chloride BRL mg/L 0.020 0.00097 1 *82608 1/12/17 18:57 KDM P7A0161 Total Metals Aluminum 6800 mg/kg dry Mercury 0.88 mglkg dry SAR Soil Preparation Complete g SAR Percent Moisture 81.8 % by Weight Arsenic, 1.2 mg/kg dry Sodium Absorption Ratio 1.6 [blank] Cadmium 0.32 mg/kg dry Calcium 180 mg/L Surrogate Recovery Control Limits 4-Bromofluorobenzene 105 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 101 % 77-123 2.8 0.81 1 *6010D 1/17/17 3:12 bgm P7A0182 0.063 0.0034 3 *7471B 1/11/17 13:02 JAB P7A0121 1 *2-78-054 1/13/17 13:00 JAB P7A0150 0.100 0.100 1 *2-78-054 1113/17 13:00 JAB P7A0183 0.28 0.034 1 *6010D 1/17/17 3:12 bgm P7A0182 0.30 0.016 1 *2-78-054 1/17/17 2:16 bgm P7A0174 0.28 0.0074 1 *6010D 1/17/17 3:12 bgm P7A0182 1.0 0.086 10 *6010D 1/17/17 2:16 bgm P7A0174 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/626-0409 Page 4 of 14 Laboratory Report I S n � ' V' Full -Service Analytical & Environmental Solutions 01/25/2017 6--_ '•LABORATOPIE$ ING Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 7010095-01 P. O. Box 878 Prism Work Order: 7010095 Mooresville, NC 28115 . Sample Matrix: Solid Time Collected: 01/09/17 10:00 Time Submitted: 01/09/17 12:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Calcium 9300 mg/kg dry 110 2.6 10 •601OD 1/21117 0:22 bgm P7A0182 Copper 120 mg/kg dry 0.55 0.060 1 •6010D 1/17117 3:12 bgm P7A0182 ,Lead 5.6 mg/kg dry ' 0.28 0.051 1 •6010D 1/17117 3:12 bgm P7A0182 Magnesium 1300 mg/kg dry 2.8 0.26 1 '6010D 1/17117 3:12 bgm P7A0182 Magnesium 69 mg/L 1.0 0.0070 10 *6010D 1/17/17 2:16 bgm P7A0174 Molybdenum 3.8 mg/kg dry 0.66 0.016 1 *60101) 1/17/17 3:12 bgm P7A0182 - Nickel 6.7 mg/kg dry 0.56 0.020 1 `6010D 1117/17 3:12 bgm P7A0182 Potassium 2200 mg/kg dry 140 6.0 10 '6010D 1121/17 0:22 bgm P7A0182 Selenium 3.0 mg/kg dry 0.56 0.13 1 '6010D 1/17/17 3:12 bgm P7A0182 Sodium 610 mg/kg dry 17 0.64 1 '6010D 1117/17 3:12 bgm P7A0182 Sodium 99 mg/L 5.0 0.18 10 '6010D 1117/17 2:16 bgm P7A0174 Zinc 240 mg/kg dry 28 0.99 10 '6010D 1/21/17 0:22 bgm P7A0182 I ' This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 14 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final Date/Time 7010095-01 P7A0145 0.05 g 25 mL 01/12/17 9:36 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 7010095-01 P7A0097 1 g 50 mL 01/10/17 8:39 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 7010095-01 P7A0124 30 g 30 g 01/10/17 15:09 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 7010095-01 P7A0127 25 g 500 mL 01/10/17 15:00 7010095-01 P7A0130 1000 mL 1000 mL 01/11/17 13:55 7010095-01 P7A0130 1000 mL 1000 mL 01/11/17 13:55 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7010095-01 P7A0143 10 mL 50 mL 01/12/17 9:00 7010095-01 P7A0143 10 mL 50 mL 01/12/17 9:00 ' Prep Method: 7470A Lab Number Batch Initial Final Date/Time 7010095-01 P7A0158 20 mL 30 mL 01/13/17 7:52 Prep Method: 3510C GC Lab Number Batch Initial Final DatelTime 7010095-01 P7A0167 200 mL 10 mL 01/13/17 9:20 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 7010095-01 P7A0165 200 mL 1 mL 01/13/17 8:55 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 7010095-01 P7A0161 1 mL 10 mL 01/12/17 9:42 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7010095-01 P7A0174 50 mL 50 mL 01/13/17 13:10 7010095-01 P7A0174 50 mL 50 mL 01/13/17 13:10 Prep Method: 3050E Lab Number Batch Initial Final Date/Time 7010095-01 P7A0182 1.98 g 50 mL 01/16/17 7:55 7010095-01 P7A0182 1.98 g 50 mL 01/16/17 7:55 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629.6364-Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 6 of 14 Sample Extraction Data Prep Method: 7471E Lab Number Batch Initial Final Date/Time 7010095-01 P7A0121 0.63 g 50 mL 01/11/17 8:45 Prep Method: SAR 2-78-064 Lab Number Batch Initial Final Date/Time 7010095-01 P7A0150 250 g 250 g 01/12/17 13:00 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 7010095-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/626-0409 Page 7 of 14 CHAIN OF CUSTODY RECORD r RFull-Service Analytical I YES; NO N/A d.PAGE_ .... . _' i.aiaoraa naies { Environmental Solutions MG. OF _ (iUOYE # TO ENSURE PROP R BILLING: S Samples INTACT upon arrival? 149 Springbrool(Road • Charlotte, NC 28217 Phone 7041529-6364 • Pax: 7041525-0409 Project Name: �� bia Short Hold Analysis: (No) UST Project: es) Recelved ON WET ICE? PROPER PRESERVAl IVES Indicated? _ /]�- 00 �— Name: * Please ATTACH any pr a specific reporting (QC LEV I 1 III IV)� Received WITfIIN HOLDING TIMES? _ to a Client Company P D ntl� provisions and/or QC Requirements CUSTODY SEALS INTACT? Report To/Contact Name: I Invoice To: T(IttNl pw /v td7��e— VOLATILES reed. WfOUT HEADSPACE?' ' Reporting Address: p ®• VX S Address: PROPER CONTAINERS used?, TEMP Therm ID: I 06servetl i ; °C / Co r'.� • °G Phone:10%1@0— 3 29� Fax (Yes) (No): Purchase Order No./Billing Reference Email Address: IRjPKMl veJ3i0 , Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days E®D Type: PDF�xcel_Other "Wonting Days" ❑ 6-9 Days tandard 10 days ❑ Prle Apprrovedust Be Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Certification: NELAC DoD FL NC SC OTHER N/A Water Chlorinated: YES_ NO YES I/ IV®_ RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: p p CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUD1GE) SAMPLE CONTAINER PRESERVA-°y T1VES ANALYSIS R QUESTED • �� a� y `� 6 -�/ REMARKS � �7� \ � � Q ©0 D PRISM LAB ID NO. •TYPE SEE BELOW NO. SIZE A- lelacv Sampler's Signature- b� �' Sampled By (Print Name) �1�P� ��°�� Affiliation Upon relinquishing, this Chain of CustodyA your authorization for Prism to proceed with the analyses as requested above. Any changes must submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. be Re I uish B Si nat r 9 Y� ( s RA�%-- By: ign lure) Relinquished By: (Signa�ure) Recelved By: (Signature) gate _ a Cis--.. ` % ~1/ Received By: (Signature) Date R eived For Prism boratories By: Da _ Milltary/Hours _ Additional Comments: site Arrival Time: iS WT&LRelinquished 1.... v :Site,DepartUre Time: Vol fO ® Field`Tech Fee: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CU�9'r Y SEALS FOR TRANSPORTATI N TO THE LABORATORY. COG Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC Ur-1 RECEIVED AT THE LABORATORY. ❑ Fed Ex ❑ UPS ❑ Hand -delivered 0 Prism Field Service ❑ Other U TER LANDFILL❑ DRINKING �C ❑ NC ❑ SC ❑ NC ❑ SC I El NC ❑ SC ❑ NC N ❑ SCE I ❑ NBC ❑ SC L3 NC ❑ SC NC SC 0 NC ❑ SC n n II"' ,.. *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) y I Full -Service Analytical R Environmental Solutions P8 I S M 2 LADORATORIE S, INC. 449 Springbrook Road • Charlotte, NC 28217 Phone 7041529-6364 • Fax: 704/525-0409 Client Company Name: 7o—.-4& /v 10ecm%% �_ Report To/Contact Name: "rilg— Reporting Address .®, Box iMoor sable_, N C- 2SI15 CMAIN OF CUSTODY RECORD PAGE �OF �/eQU�OTE # TO ENSURE PROPER BILLING: Project Name: �l �g� Short Hold Analysis: ( es (No) UST Project: s) ( O *Please ATTACH any pr ect specific reporting (QC LEVE 1 III IV) provisions and/or QC Requirements p Invoice To: Address: " Samples INTACT upon arrival?'' YES'' ''NO N/A _ j2 Received ON WET ICE? rn PROPER PRESERVATIVES.Indicated? rn Received WITHIN HOLDING•TIMES? CUSTODY SEALS'INTACT? _ _ V.OLATILES reed W/OUT HEADSPACE? PROPER' _ CONTAINERS used?;, TEMP .Therm, ID_ Obse(ved a . r °C / C$Ir: �• C Phone. "'I—We0-36.(p Fax (Yes) (No): Email Address: Ybe&6, Frviveww EDD Type: PDF_Excel _Other Site Location Name: Purchase Order No./Billing Reference Requested Due Date ❑ 1 Day ❑ 2 Da s ❑ 3 Days ❑ 4 Days ❑ 5 Days "Working Days" ❑ 6 9 Days tandard 10 days ❑ Rush Be Pre -Approved Samples received after 14:00 will be processed next business day. TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Certification: NELAC Do® FL NC e/ SC OTHER_ N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Water Chlorinated: YES_ NO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) I Sample Iced Upon Collection: YES V NO CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TNES ANALYSIS REQUESTED SLR REMARKS PRISM LAB ID NO. *TYPE SEE BELOW NO. SIZE lil�S !Ai J1 V C a Sampler's Sign fur= 1�� Sampled By (Print Name) / L L�'�'t Affiliation Upon relinquishing, this Chain of Custod Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. / II Relinq fished By: (Sig ature) r Recei : (Signature) Date �_ `--'-- r` `17 Military/Hours Additional Comments: .. _e rPival'nme:, JIM RelinquishedBy: (Signaturq I Received By: (Signature) Date AV -Sr 'Site'Departure Tme: - Relished By: (Signatu Recei For P Ism Laboratories By: iDat�j _ Me od of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH STODY SEALS FOR TRANSPORTATION TO THE LABORATORY. COG Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC NTIL RECEIVED AT THE LABORATORY. _ t' f� �/ `"" I `:Field Tech Fee - r Mdeagei ❑ Fed Ex ❑ UPS Cl Hand -delivered ❑ Prism Field Service O Other NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL �' OTHER: ❑NC❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC r ❑ - ❑ - ❑ - ❑ ❑ ❑ ❑ ❑ n 'fir"7f;SP,!r;t *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) ` ACC s ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECTID 7010095 LABORATORY REPORT NUMBER 1701712 DATE January 17, 2017 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, AES Project Manager, Access Analytical aainick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, lnc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed. to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 5 I Page 10 of 14 i:, ih r Rr—,!, Full-Service Analytical & PI S M I Environmental Solutions t �NFLA80RATORISS, INC. - SUBCONTRACT ORDER Certificatio : NELAC_ USACE Prism Laboratories, Inc. NCSC_ Other 7010095 NJA SENDli 1G LABORATORY: RECEIVLNG LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax-, 704-525-0409 Fax: NA Project Manager: Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample ID: 7010095-01 Solid Sampled:01/09/1710:00 �,�„l. 21� "1i Herbicides TCLP (Sub) 01/16/17 10:00 Containers Supplied: 1/1/ /7 i/,, P 1eleased/By I Date tceeervea by r Lint" 1Jate Released By Date Received By Date Released By Date Received By Date Page 2 of 5 Q Page 11 of 14 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1701712 Tag Number: 7010095-01 Project Name: 7010095 Collection Date: 1/9/2017 10:00:00 AM Lab 11D: 1701712-001A Matrix: Solid Analyses Result Qual MDL Reporting Units BatchID DF DateAnalyzed Analyst Limit HERBICIDES, TCLP SW1311/8151A 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr: DCAA 83.9 Qualifiers: " Value exceeds maximum contaminant level BRL Not Detected at MDL H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank (SW3510C) 0.064 0.20 mg/L 236276 1 01/16/201716:16 AW 0.076 0.20 mg/L 236276 1 01116/201716:16 AW 0 50.1-132 %REC 236276 1 01116/201716:16 AW E Estimated value above quantitation range S Spike Recovery outside limits due to matrix > Greater than Result value r Estimated value detected below Reporting Limit < Less than Result value Page 3 of 5 Page 12of14 Analytical Environmental Services, Inc. Sample/Cooler Receipt Checklist Client XXo 9 lam✓ Work Order Number 4iJJ"— Checklist completed by Signa a Date Carrier name: FedEx _ S _ Courier _ Client ^ US Mail _ Other Shipping container/cooler in good condition? Yes ✓ No _ Custody seals intact on shipping container/cooler? Yes J No _ Custody seals intact on sample bottles? Yes _ No _ Container/Temp Blank temperature in compliance? (0°56°C)* Yes �� No _ O Not Present _ Not Present _ Not Present Cooler #1 !i Cooler #2 Cooler #3 Cooler #4 Cooler#5 Cooler #6 / Chain of custody present? Yes . No Chain of custody signed when relinquished and received? Yes No Chain of custody agrees with sample labels? Yes No _ Samples in proper container/bottle? Yes No _ Sample containers intact? Yes v No Sufficient sample volume for indicated test? Yes !/ No All samples received within holding time? Yes v No _ Was TAT marked on the COC? Yes V No _ Proceed with Standard TAT as per project history? Yes _ No _ Not Applicable Water - VOA vials have zero headspace? No VOA vials submitted Yes — No _ Water - pH acceptable upon receipt? Yes _ No _ Not Applicable / Adjusted? Checked by Sample Condition: Good Other(Explain) (For diffusive samples or AIHA lead) Is a known blank included? Yes _ No _ See Case Narrative for resolution of the Non -Conformance. * Samples do not have to comply with the given range for certain parameters. \\Aes server\1\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Sample_Cooler Reeipt Checklist Revl.rtf Page 4 of 5 Page 13of14 Analytical Environmental Services, Inc Date: 17-7an-17 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 7010095 Workorder: 1701712 BatchID: 236276 Sample ID: MB-236276 Client ID: Units: mg/L Prep Date: 01/13/2017 Run No: 334354 SampleType: 1V1BLK TestCode: HERBICIDES, TCLP SW131119151A BatchID: 236276 Analysis Date: 01/16/2017 Seq No: 7291256 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-1P (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.4083 - 0 0.5000 81.7 50.1 132 Sample ID: LCS-236276 Client ID: Units: mg/L Prep Date: 01/13/2017 Run No: 334354 SarnpleType: LCS TestCode: IrERBICIDES,TCLP SW1311/8151A BatchID: 236276 Analysis Date: 01/16/2017 Seq No: 7291257 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.4267 0.20 0.5000 85.3 50.7 117 2,4-D 0.4614 0.20 0.5000 92.3 50.1 119 Surr: DCAA 0.4588 0 0.5000 91.8 50.1 132 Sample ID: 1701712-OOIAMS Client ID: CLASS A Units: mg/L Prep Date: 01/13/2017 Run No: 334354 SampleType: MS TestCode: HERBICIDES, TCLP SW1311/8151A BatchID: 236276 Analysis Date: 01/16/2017 Seq No: 7291259 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.4444 0.20 0.5000 2,4-D 0.4759 0.20 0.5000 Surr: DCAA 0.4294 0 0.5000 JQ)j Qualifiers: > Greater than Result value to (D BRL Below reporting limit r Estimated value detected below Reporting Limit O Rpt Lim Reporting Limit 88.9 46.3 95.2 43.3 85.9 50.1 < Less tlmn Result value E Estimated (value above quantitatiou mngc) N Analyte not NELAC certified S Spike Recovery outside limits due to matrix 126 132 132 B Analyte detected in the associated method blank H Holding times for preparation or analysis exceeded S. RPD outside limits due to matrix Page 5 Of 5 PRISM .rtr"LABORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cent No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 10/17/2016 Prism Work Order: 6100344 , Case Narrative 02/21 /2017 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: This is a Revised Report and supercedes the original laboratory report dated 11/08/2016. Correction made to the PAN calculation. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager / �1 Reviewed By Terri W. Cole Project Manager Data Qualifiers Key Reference: A Result is based on a single replicate due to matrix interference. CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. D RPD value outside of the control limits. L2 LCSD recovery outside of the QC limits. LCS recovery within the limits. No further action taken. MC Sample concentration too high for recovery evaluation. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041626-0409 Page 1 of 18 Full -Service Analytical $ Environmental Solutions OR TORIESJI Sample Receipt Summary 02/21 /2017 Prism Work Order: 6100344 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 6100344-01 Solid 10/17/16 10/17/16 Samples were received in good condition at 3.2 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/529-6364 -Toll Free Number: 1-8001629-6364 - Fax: 704/525-0409 Page 2 of 18 SFun -Service Analytical Environmental Solutions 1A8ORATORIE$ INC. Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 02/21 /2017 Client Sample ID: Class A Prism Sample ID: 6100344-01 Prism Work Order: 6100344 Time Collected: 10/17/16 08:30 Time Submitted: 10/17/16 13:35 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 12000, mg/kg dry 1700 230 100 'Calculation 10/26/16 8:26 CLB [CALC] % Solids 92.5 % by 0.100 0.100 1 'SM2540 G 10/25/16 16:46 JLB 136J0462 Weight Nitrate/Nitrite as N BRL mg/kg dry 5.4 0.59 1 'SM4500-NO3 F 10/21/16 7:32 CLB P6J0366 pH 6.6 pH Units 1 •90451) 10/19/16 10:44 EGC P6J0335 Phosphorus -Total 12000 mg/kg dry 540 260 200 'SM4500-P F 10/20/16 6:34 CLB P6J0303 Total Kjeldahl Nitrogen 39000 mg/kg dry 5400 610 20 *361.2 10/25/16 8:25 CLB P6J0406 Ammonia as N 1900 mg/kg dry 540 210 100 'SM4500-NH3 G 10/24/16 8:18 CLB P6J0397 Microbiological Parameters Fecal Coliforms TCLP Extraction by EPA 1311 BRL MPN/g dry 0.2 1 'SM9221 E 10/17/16 13:52 EGC P6J0316 TCLP Extraction Complete N/A 1 *1311 ZHE 10/25/16 9:30 ANG P6J0414 TCLP Extraction Complete N/A 1 *1311 11/1/16 7:30 JAB P6J0552 TCLP-Metals Mercury BRL mg/L 0.010 0.000030 1 '7470A 11/2/16 7:04 JAB P61<0021 Arsenic BRL mg/L 0.050 0.012 1 '6010D 11/1/16 20:01 bgm P61<0023 Barium BRL mg/L 5.0 0.0065 1 '6010D 11/1/16 20:01 bgm P61<0023 Cadmium BRL mg/L 0.025 0.00065 1 '6010D 11/1/16 20:01 bgm P61<0023 Chromium BRL mg/L 0.25 0.0038 1 '6010D 11/1/16 20:01 bgm P61<0023 Lead BRL mg/L 0.050 0.0080 1 '6010D 11/1/16 20:01 bgm P61<0023 Selenium BRL mg/L 0.10 0.022 1 '6010D 11/1/16 20:01 bgm P61<0023 Silver BRL mg/L 0.25 0.00050 1 `6010D 11/1/16 20:01 bgm P61<0023 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.000094 1 *8081B 11/2/16 17:37 JMC P61<0029 Dieldrin BRL mg/L 0.00050 0.000022 1 '808113 11/2/16 17:37 JMC P61<0029 Endrin BRL mg/L 0.00050 0.000020 1 '8081B 11/2/16 17:37 JMC P61<0029 gamma-BHC BRL mg/L 0.00050 0.000013 1 *80816 11/2/16 17:37 JMC P61<0029 Heptachlor BRL mg/L 0.00050 0.000015 1 '8081B 11/2/16 17:37 JMC P61<0029 Heptachlor Epoxide BRL mg/L 0.00050 0.000018 1 `8081B 11/2/16 17:37 JMC 1361<0029 Methoxychlor BRLCCV mg/L 0.00050 0.000033 1 `8081B 11/2/16 17:37 JMC P61<0029 Toxaphene BRL mg/L 0.025 0.00032 1 '8081B 11/2116 17:37 JMC P6K0029 Surrogate Recovery Control Limits Decachlorobiphenyl 45 % 13-186 Tetrachloro-m-xylene 51 % 40-134 TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 `8270D 11/2/16 10:16 JMV P61<0028 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 '8270D 11/2/16 10:16 JMV P61<0028 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 `8270D 11/2/16 10:16 JMV P61<0028 2-Methylphenol BRL mg/L 0.050 0.0018 1 '8270D 11/2/16 10:16 JMV P61<0028 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 18 P Full -Service Analytical Environmental Solutions Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 02/21 /2017 Client Sample ID: Class A Prism Sample ID: 6100344-01 Prism Work Order: 6100344 Time Collected: 10/17/16 08:30 Time Submitted: 10/17/16 13:35 Parameter Result Units Report MDL Dilution Method _ Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methyl phenol BRL mg/L 0.050 0.0015 1 *8270D 11/2/16 10:16 JMV P61<0028 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 *8270D 1112/16 10:16 JMV P61<0028 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 *8270D 11/2/16 10:16 JMV P6K0028 Hexachloroethane BRL mg/L 0.050 0.0017 1 *8270D 11/2/16 10:16 JMV P61<0028 Nitrobenzene BRL mg/L 0.050 0.0026 1 *8270D 11/2/16 10:16 JMV P61<0028 Pentachlorophenol BRL mg/L 0.25 0.0012 1 *8270D 11/2/16 10:16 JMV P61<0028 Pyridine BRL mg/L 0.25 0.0010 1 *8270D 11/2/16 10:16 JMV P61<0028 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 2 % 43-140 SE 2-Fluorobiphenyl 61 % 44-119 2-Fluorophenol 8 % 19-119 SE Nitrobenzene-d5 55 % 44-120 Phenol-d5 7 % 11-52 SE Terphenyl-d14 63 % 50-134 TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.000083 1 *8260B 10/27/16 6:24 KDM P6J0482 1,2-Dichloroethane BRL mg/L 0.025 0.000066 1 *8260B 10/27/16 6:24 KDM PGJ0482 1,4-Dichlorobenzene BRL mg/L 0.38 0.000050 1 *8260B 10/27/16 6:24 KDM P6J0482 Benzene BRL mg/L 0.025 0.000048 1 *8260B 10/27/16 6:24 KDM P6J0482 Carbon Tetrachloride BRL mg/L 0.025 0.00011 1 *8260B 10/27/16 6:24 KDM P6J0482 Chlorobenzene BRL mg/L 5.0 0.000062 1 *8260B 10/27/16 6:24 KDM P6J0482 Chloroform BRL mg/L 0.30 0.000076 1 *826013 10/27/16 6:24 KDM P6J0482 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.00024 1 *8260B 10/27/16 6:24 KDM P6J0482 Tetrachloroethylene BRL mg/L 0.035 0.000098 1 *8260B 10/27/16 6:24 KDM P6J0482 Trichloroethylene BRL mg/L 0.025 0.000078 1 *8260B 10/27/16 6:24 KDM P6J0482 Vinyl chloride BRL mg/L 0.010 0.000097 1 *8260B 10/27/16 6:24 KDM P6J0482 Surrogate Recovery Control Limits 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 129 % 75-129 Toluene-d8 93 % 77-123 Total Metals Aluminum 10000 mg/kg dry 2.7 0.78 1 *60101) 10/21/16 1:01 bgm P6J0329 Mercury 0.48 A mg/kg dry 0.066 0.0036 3 *7471B 10/28/16 15:27 JAB P6J0510 SAR Soil Preparation Complete g 1 *2-78-054 10/27/16 14:00 JAB P6J0500 SAR Percent Moisture Complete % by 0.100 0.100 1 *2-78-054 11/1/16 16:00 JAB P6K0031 Weight Arsenic 1.7 mg/kg dry 0.27 0.032 1 *6010D 10/21/16 1:01 bgm P6J0329 Sodium Absorption Ratio 1.6 [blank] 0.30 0.016 1 *2-7M64 10/28/16 17:27 bgm P6J0501 Cadmium 0.36 mglkg dry 0.27 0.0071 1 *6010D 10/21/16 1:01 bgm P6J0329 Calcium 10000 mg/kg dry 11 0.24 1 *6010D 10/21/16 1:01 bgm 136J0329 Calcium 120 mg/L 1.0 0.085 10 *6010D 10/27/16 20:42 bgm 136J0501 Copper 170 mg/kg dry 11 0.96 20 *6010D 10/21/16 15:37 bgm P6J0329 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/526-0409 Page 4 of 18 �E l� I Full -Service Analytical s Environmental Solutions =.� LABORATORM Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 02/21 /2017 Client Sample ID: Class A Prism Sample ID: 6100344-01 Prism Work Order: 6100344 Time Collected: 10/17/16 08:30 Time Submitted: 10/17/16 13:35 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Lead 8.4 mglkg dry 0.27 0.050 1 `60101) 10/21/16 1:01 bgm P6J0329 Magnesium 2000 mg/kg dry 2.7 0.26 1 '6010D 10/21/16 1:01 bgm PGJ0329 Magnesium 60 mg/L 1.0 0.0070 10 '6010D 10/27/16 20:42 bgm P6J0501 Molybdenum 6.6 mg/kg dry 0.63 0.016 1 '6010D 10/21/16 1:01 bgm P6J0329 Nickel 9.9 mg/kg dry 0.63 0.019 1 '6010D 10/21/16 1:01 bgm P6J0329 Potassium 2100 mglkg dry 270 9.6 20 '6010D 10/21/16 15:37 bgm P6J0329 Selenium 3.0 mg/kg dry 0.63 0.13 1 '6010D 10/21/16 1:01 bgm P6J0329 Sodium 660 mglkg dry 16 0.62 1 *6010D 10/21/16 1:01 bgm 126J0329 Sodium 85 mg/L 5.0 0.18 10 "6010D 10/28/16 17:27 bgm P6J0501 Zinc 320 mg/kg dry 53 1.9 20 •6010D 10/21/16 15:37 bgm P6J0329 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 5 of 18 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final Date/Time 6100344-01 P6J0406 o.b5 g 25 mL 10/24/16 10:00 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 6100344-01 P6J0303 1 g 50 mL 10/18/16 10:02 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 6100344-01 P6J0462 30 g 30 g 10/25/16 16:45 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 6100344-01 P6J0552 100 g 2000 mL 10/31/16 15:30 6100344-01 P6J0414 25 g 500 mL 10/24/16 16:00 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6100344-01 P6K0023 10 mL 50 mL 11/01/16 12:10 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 6100344-01 P61<0021 20 mL 30 mL 11/01/16 9:30 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 6100344-01 P61<0029 200 mL 10 mL 11/01/16 13:50 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 6100344-01 P6K0028 200 mL 1 mL 11/01/16 13:35 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 6100344-01 P6J0482 10 mL 10 mL 10/26/16 9:20 Prep Method: 3010A Lab Number Batch Initial Final Date/Tlme 6100344-01 P6J0501 50 mL 50 mL 10/27/16 15:00 6100344-01 P6J0501 50 mL 50 mL 10/27/16 15:00 6100344-01 P6J0501 50 mL 50 mL 10/27/16 15:00 Prep Method: 3060B Lab Number Batch Initial Final Daterrime 6100344-01 P6J0329 2.03 g 50 mL 10/19/16 9:05 6100344-01 P6J0329 2.03 g 50 mL 10/19/16 9:05 Prep Method: 7471 B Lab Number Batch Initial Final Date/Time This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. r ' 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 6 of 18 Sample Extraction Data Prep Method:7471B Lab Number Batch Initial Final Date/Time 6100344-01 P6J0510 0.6 g 50 mL 10/28/16 9:42 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 6100344-01 P6J0500 250 g 250 g 10/26/16 14:00 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 6100344-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/626-0409 Page 7 of 18 CHAIN OF CUSTODY RECORD . -.." Full -Service Analytical & ISNA I Environmental Solutions PAGE LOF UOTE # TO ENSURE PROP BILLING: YES NO oD N/A � . .,..."'-, LABORATORIES, INC. *bn ( Samples 'INTACT;upon arrival? _ .:., ��/�) Project Name: ��5 lair Received ON;WET ICE?.,. _ _ 00 449 Springbrook Road • Charlotte, NC 28217 Short Hold Analysis: t NO ST Project: es Phone 704/529-6364 • Fax: 704/525-0409 y ) ( ) 1 �N/( *Please ATTACH any pi t specific reporting (QC LEVEVI INII IV) PROPER PRESERVATIVES indicated? — Received WITHIN HOLDING TIMES? ®CXp&�1d4Q� Client Company Name: A�� provisions and/or QC Requirements aa _ CUSTODY SEALS 'INTACT? , Report To/Contact Name: u11rh$, Invoice L To: /0� m� /" �� `� VOLATILES reed VWOUT HEADSPACE? � Reporting Address: ® ax aLov Address: s PROPERCONTAINERS'ud? r j� p p 11V\BdCt9VP_r AJC, .rI, 911 TEMP: Therm ID: �I—� I'L! Observed 3 --6 PC / Corr: IC Phone: °�"��® -_AWWO ax (Yes) (No): Purchase Order No./Billing Reference 6,Af At-, �5 TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: ,f1�M��® •mat • Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC DOD FL NC EDD Type: PDF_Excel Other Rush work Must Be Yp "Working Days" ❑ 6-9 Daystandard 10 days ❑ Pre -Approved Site Location Name: Samples received after 14:00 will be processed next business day. SC OTHER NIA Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO (SEE REVERSE FOR TERMS $ CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES NO CLIENT DATE TIME COLLECTED MATRIX SAMPLE CONTAINER PRESERVA- ANALYSIS R UESTED �6 PRISM SAMPLE DESCRIPTION COLLECTED MILITARY (SOIL, WATER OR TIVES ? O yC REMARKS LAB *TYPE NO. SIZE ID NO. HOURS SLUDGE) SEE BELOW o �y s o� �s A' �b �.3}M -Soil �loir� Sampler's Signa re Sampled By (Print Name) Affiliation , • Upon relinquishing, this dhain of Custody is your authorization for P is It proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be cha es for any changes after analyses have been initialized. Relin uis d By, (Signature Receive : (Sig na re C �" Date _ Military/Hours Additional Comments: `p-�� Vol Aewo Relinquished By: (Sig r Received By: ( Ignature) Dale Qn' , Relinquished By: (SI e) Received For Pris borat s B Date y Y .G.� ® 91 " IS Method of Shipment: NOTE: A SA LE COOLERS SHOULD BE TAPED SHUT WITH CUS DY SEALS OR TRANSPORTATION TO THE LABORATORY. COC Group No. SAMPLES ARE NOTA//�CEPTED AND VERIFIED AGAINST COC UN RECEIVED AT THE LABORATORY. / ❑ Fed Ex ❑ UPS El Hand delivered ®Prism Field Service ❑ Other LO J Li ❑ SC ❑ NC ❑ SC I ❑ NC ❑ SC ❑ NC ❑ SC NC ❑ SC ❑ NC ❑ SC I ❑ NC ❑ SC I ❑ NC ❑ SC I ❑ NC ❑ SC *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) MEMEMM Site Arrival Time: Site,Departure Time` Field "Tech Fee: Mileage; '-SEE REVERSE FOR'- . TERMS 8: CONDITIONS Nroone: 'rvi--weFd---1--qtp tax (ves) (Ivo): Purchase Order No./Billing Reference Email Address: @LMlRI�� ` • �, 2 • > Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days EDD Type: PDF_Excel Other "Working Days" ❑ 6-9 Days Standard 10 days ❑ Pre-ApprovedhWrk Must Be Site Location Name: Samples received aker 14:00 will he processed next business day. TO BE FILLED IN BY CLIENT/SAMPLING PERSONN Certification: NELAC DoD FL NC If SC OTHER NIA Site Location Physical Address: Tumaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Water Chlorinated: YES_ NO_ Sample Iced Upon Collection: YES NO CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIVES ANALYSIS UES5D . ' ® e REMARKS �� P _ � PRISM LAB ID NO. *TYPE SEE BELOW NO. SIZE exss °fir Mane, b Sampler's Signa(ur Sampled By (Print Name) /c,,i'1/t' L ;t/a/' Affiliation d Upon relinquishing, this Chain of Cus dy is your authorization for Prism to lkroceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for apy changes after a al es have been initialized. I' quI ed y: (Sign ture) Received By: (Signature Date c p�q Relinquished B SI n lure Received B Si n e U V/ q Y e ) Y� ( 9 ) Date Military/HoursAdditional Comments: l /V_\T/ • 'SltoAlnval time :Site gepzrture Time Relinquished By: (Signature) Received For,P,fifs La orl Date �� j / g `� _< ' /g5 (G®/ P®p Method of Shipment NOTE: ALL SAM COOLERS SHOULD BE TAPED SHUT WIT STODY SEALS FOR TRANSPORTATION TO THE LABORATORY. COC Group No. SAMPLES ARE NOTAC�CEPTEDAND VERIFIED AGAINST NTILRECEIVEDATTHE LABORATORY. , ❑ Fad Ex ❑ UPS ❑ Hand -delivered PPrism Field Service ❑ Other ,) , lU NPDES: I UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC �NC ❑ SC ❑ NC ❑ SC LING ❑ SC ❑ NC ❑ SC LING ❑ SC Field fecti Fee Mileage. ❑___ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ I *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 6100344 LABORATORY REPORT NUMBER 161 OG89 DATE November 07, 2016 Primary Data Review By Chris Pafford Project Manager, AES Secondary Data Review By Ashley Amick Project Manager, Access Analytical aamick(d,)axs-inc. com PLEASENOM - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDIIEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regardnig this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 9 Page 10 of 18 SUBCONTRACT ORDER CertiftWIoELAC_USACE Prism Laboratories, Inc. SC_ Other 6100344 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone:800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA Project Manager: Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample ID: 6100344-01 Solid! Samplcd:10/17/16 08:30 Herbicides TCLP (Sub) 10/24/16 08:30 Containers Supplied.• ('Oh eased By Me Received By Date Released By Dale Received By �3 Released By Date Received By Date Released By Date Received By Date Page 2 o Page 1 of 1 Page 11 c .... .... - i _. _ , . _ _ .. _ . _._. ..,.... .d _, T.. ....... .... . ... �P ism 4 - L180RATORIKINQ Full -Service Analytical & Environmental Solutions NOW SUBCONTRACT ORDER Certific : NELAC_ USACE Prism Laboratories, Inc. SC_ Other 6100344 SENDING LABORATORY: RECEIM11+1G LABORATORY: Prism Laboratories, Inc. P. O. Box 240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax: 704-525-0409 Project Manager: Terri W. Cole Analytical Environmental Services, Inc.. 3080 Presidential Parkway Atlanta, GA 30340 Phone :(710) 457-8177 Fax: NA Analysis Due Expires Laboratory ID Comments HOMESample ID: 6100344-01 Solid Sampled:10/17/16 08:30 Herbicides TCLP (Sub) Containers Supplied: 10/24/16 08:30 Released By Date Received By Date Released By Date Received By Date age 3 of 9 Page 1 of 1 Page 12 of 18 Analytical Environmental Services, Inc Date: 7-Nov-16 Client: Prism Laboratories Project: 6100344 Case Narrative LabID: 161OG89 Sample Receiving Nonconformance: Insufficient sample was received on 10/20/16 @ 09:15 AM for TCLP Herbicides analysis. Additional sample was received on 10/28/16 @ 10:20 AM. Page 4 of 9 Page 13of18 Analytical Environmental Services, Inc Date: 7-Nov-16 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1610G89 Tag Number: 6100344-01 Project Name: 6100344 Collection Date: 10/17/2016 8:30:00 AM Lab ED: 1610G89-OOIA Matrix: Solid Reporting Analyses Result Qua[ MDL Units BatchID DF Date Analyzed Analyst Limit HERBICIDES,'TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.064 0.20 rng/L 232093 1 11/03/2016 14:46 AW 2,4-D BRL 0.076 0.20 mg/L 232093 1 11/03/2016 14:46 AW Surr: DCAA 85.4 0 50.1-148 %REC 232093 1 11/03/2016 14:46 AW Qualifiers: ' Value exceeds maximum contaminant level BRL Not Detected at:vlDL H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated value above quantitation range S Spike Recovery outside limits due to matrix > Greater than Result value J Estimated value detected below Reporting Limit < Less than Result value Page 5 of 9 Page 14 of 18 Analytical Environmental Services, Inc. Sample/Cooler Receipt Checklist Client M` S S 7 N M Work Order Number Checklist completed by(�� Signature Date Carrier name: FedEX!/ UPS Courier Client US Mail Other Shipping container/cooler in good condition? YesV Custody seals intact on shipping container/cooler? Yes Custody seals intact on sample bottles? Yes _ Container/Temp Blank temperature in compliance? (0°_<6°C)* Yes Cooler #1 d �6C Cooler #2 Cooler #3 Cooler #4 Chain of custody present? Yes V Chain of custody signed when relinquished and received? Yes -V Chain of custody agrees with sample labels? Yes Samples in proper container/bottle? Yes Sample containers intact? Yes V Sufficient sample volume for indicated test? Yes _ All samples received within holding time? Yes Was TAT marked on the COC? Yes _ Proceed with Standard TAT as per project history? Yes Water - VOA vials have zero headspace? No VOA vials submitted V No _ Not Present _ No _ Not Present _ No Not Present No Cooler#5 Cooler #6 Not Applicable No Water - pH acceptable upon receipt? Yes _ No _ Not Applicable V Adjusted? Checked by Sample Condition: Good / Other(Explain) (For diffusive samples or AMA lead) Is a known blank included? Yes _ No _ See Case Narrative for resolution of the Non -Conformance. No _ No _ No No _ No No No No V No — Yes _ * Samples do not have to comply with the given range for certain parameters. \\Aes server\l\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Sample Cooler Recipt_Checklist Revl.rtf Page 6 of 9 Analytical Environmental Services, Inc, Sample/Cooler Receipt Checklist Client (� Mss V N Work Order Number o C �� r' �b 0 1- Checklist completed by-ftl(AaQ V to ( �k g UP Signature Date Carrier name: FedEx V UPS _ Courier _ Client _ US Mail Other Shipping container/cooler in good condition? Yes `V Custody seals intact on shipping container/cooler? Yes V/ Custody seals intact on sample bottles? Yes _ Container/Temp Blank temperature in compliance? (0°56°C)* Yes 0 c✓ Cooler 41 Cooler #2 Cooler #3 Cooler 44 _ V Chain of custody present? Yes I Chain of custody signed when relinquished and received? Yes Chain of custody agrees with sample Iabels? Yes _d/ Samples in proper container/bottle? Yes Sample containers intact? Yes d Sufficient sample volume for indicated test? Yes All samples received within holding time? Yes Was TAT marked on the COC? Yes Proceed with Standard TAT as per project history? Yes dA Water - VOA vials have zero headspace? No VOA vials submitted No _ Not Present No _ Not Present _ No _ Not Present V No _ No No No _ No _ No _ No _ No _ No No _ Yes Water - pH acceptable upon receipt? Yes _ No _ Adjusted? Checked by Sample Condition: Good Other(Explain) (For diffusive samples or ARIA lead) Is a known blank included? Yes _ See Case Narrative for resolution of the Ilion -Conformance. Cooler#5 Cooler 46 Not Applicable _ No _ Not Applicable No * Samples do not have to comply with the given range for certain parameters. \\Aes server\I\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Sample Cooler Recipt Checklist Rev1 stf Page 7of9 Page 16 of 18 Analytical Environmental Services, Inc Date: 7-Nov-16 Client: Prism Laboratories Project Name: 6100344 Dates Report Lab Order: 161 OG89 Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date Prep Date Analysis Date 1610G89-001A CLASS A 10/17/2016 8:30:OOAM Solid HERBICIDES, TCLP Leached 10/28/2016 11/2/2016 1:30:OOPM 11/03/2016 Analytical Environmental Services, Inc Client: Prism Laboratories Project Name: 6100344 Workorder: 161 OG89 Date: 7-Nov-16 ANALYTICAL QC SUMMARY REPORT BatchID: 232093 Sample ID: MB-232093 Client ID: Units: mg/L Prep Date: 11/02/2016 Run No: 328981 SampleType: MBLK TestCode: HERBICIDES, TCLP SWI311/8151A BatchID: 232093 Analysis Date: 11/03/2016 Seq No: 7140934 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 13RL 0.20 2,4-D BRL 0.20 Sun-: DCAA 0.3844 0 0.5000 76.9 50.1 148 Sample ID: LCS-232093 Client ID: Units: mg/L Prep Date: 11/02/2016 Run No: 328981 SampleType: LCS TestCode: HERBICIDES, TCLP SW1311/8151A BatchID: 232093 Analysis Date: 11/03/2016 Seq No: 7140938 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.3852 0.20 0.5000 77.0 52.5 126 2,4-D 0.4045 0.20 0.5000 80.9 50.5 132 Surr: DCAA 0.4275 0 0.5000 85.5 50.1 148 Sample ID: 1611034-001CMS Client ID: Units: mg/L Prep Date: 11/02/2016 Run No: 328981 SampleType: MS TestCode: HERBICIDES, TCLP SW1311/8151A Batc11ID: 232093 Analysis Date: 11/03/2016 Seq No: 7141921 Analyte Result IRPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP(Silvex) 0.4095 0.20 0.5000 8L9 49.4 131 2,4-D 0.4535 0.20 0.5000 90.7 44.1 137 Surr: DCAA 0.6910 0 0.5000 138 50.1 148 0) Qualifiers: > Greater than Result value (D BRL Below reporting limit Qp 7 Cstimated value detected below Reporting Limit 0 Rpt Lint Reporting Limit -n co < Less than Result value E Estimated (value above quamitation range) N Analyte not NELAC certi5ed S Spike Recovery outside limits due to matrix B Analyte detected in the associated method blank H Holding tunes for preparation or analysis exceeded R RPD outside limits due to matrix Page 9 of 9 PRISM -71 �� ORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 02/20/2017 Prism Work Order: 7020388 Case Narrative 03/03/2017 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: rG66a-l# Reviewed By Terri W. Cole Project Manager BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 1 of 5 Sample Receipt Summary O I S Full -Service Analytical & Environmental Solutions 03/03/2017 :'LABORATORIES, ING Prism Work Order: 7020388 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 7020388-01 Solid 02/20/17 02/20/17 Samples were received in good condition at 1.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/52"409 Page 2 of 5 ®®® Orr] 1I®—� I S „ ,® Full -Service Analytical s i ■ l I � I Environmental Solutions - — ,_.1."mil SOAATOAIES INC. Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 03/03/2017 Client Sample ID: Class A Prism Sample ID: 7020388-01 Prism Work Order: 7020388 Time Collected: 02/20/17 07:40 Time Submitted: 02/20/17 11:55 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters % Solids 94.4 % by 0.100 0.100 1 *SM2540 G 2/23/17 16:41 JLB P7B0461 Weight Microbiological Parameters Fecal Coliforms 0.4 MPN/g dry 0.2 1 *SM9221 E 2/20/17 12:29 EGC P7130383 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041625-0409 Page 3 of 5 Sample Extraction Data Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 7020388-01 P7130461 30 g 30 g 02/23/17 16:41 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/625-0409 Page 4 of 5 CHAIN OF CUSTODY RECORD Full -Service Analytical & LO Environmental Solutions PAGE OF J_ QUOTE # TO ENSURE PROPER BILLING: .- . � YES ;�,JvC LABOFAT6FIE5,INC, r /� l 44.9 Springhrook Road • Charlotte, NC 28217 Project Name: G �'� sS V7 Phone 704/529-5364 Fax: 704152l5-0409 Short Hold Analysis: (Yes) (No) UST Project: (Yes) (NO) *Please ATTACH any project specific reporting (QC LEVEL 111 Ill IV) Client Company Name• l provisions and/or QC Requirements Report To/Contact Name: p Invoice To: I/+ �e� �- 1�1ii,E'r+�tii�LL Reporting Address: �i� fi `. � � Address: Phone: rt _tGwu tax (Yes) (No): Purchase Order No.18illing (deference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: Requested Due Date ® 1 Day 6Days El 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC ®o® FL NC Ir''•� EDD Type: PDF=EXCel_Other "Working Days" 0 6-9 Days ® Standard 10 days ❑ Be Site Location Name: Pre-ApprovedhWorkust Samples received after 14:00 will be processed next business day. SC OTHER N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Water Chlorinated: YES_ No RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES N® TIME MATRIX SAMPLE CONTAINER 1'�( ANALYSIS REQUESTED CLIENT DATE COLLECTED (SOIL, PRESERVA- REMARKS PRISM LL AB SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR "TYPE NO. SIZE TIVES 4� 1 HOURS SLUDGE) SEE BELOW ,ry Sampler's Signat Sampled By (Print Name) t LilivA- Affiliation �' ar�✓'� Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charg2.sf9rAny changes after analyses have been initialized. - ` Rel'nquishe, By: (Signature) -m Re ce' d (Sign lure) Date MilitarylHours Additional Comments: SiteFlrnvalTi_ ime . Re quished ey: (Si t re) R eived By: ignature) Date r =Sde Dopartuie Tirne;�; Relinqui' ed By: (Si ature) ,Retleiv l For Prism L oratories By: a, Date %a Fleld Tech Fee Method of Ship ent: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTO S S FOR TRANSPORTATI N TO THE LABORATORY. y,, C C Group No. r tVllieagc •' - SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL CEIVED AT THE LABORATORY/ l7 Ped F� ❑ UPS ❑ Hand -delivered VP.sn Field Service ❑ Other NPDES: UST: G UNDWATER: DRINKING WATER:SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: ®NIC ®NC ®SC ®SC ®NC ❑SC I C ®SC 0NC®SC I UNC ®SC ®NC LISCI El NC ®SC ° ®NC El El "CONTAINER TYPE CODES: A =Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA= Volatile Organics Analysis (Zero Head Space) t P.ISM ,. - a' LABORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cart No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 04/10/2017 Prism Work Order: 7040189 Case Narrative 04/26/2017 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: PAN Equation = 0.3 * (TKN - Ammonia) + 0.5 * (Ammonia) + Nitrate -Nitrite Equation uses Mineralization Rate (MR) for Aerobically Digested Solids (0.3) Analysis note for SAR: SAR=[Na]/SQRT{([Ca]+[Mg])/2} Concentrations for Na, Ca, and Mg are expressed in milliequivalents per liter, and SQRT designates taking the square root of the operand in parentheses. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager t6na-'s Reviewed By Terri W. Cole Project Manager This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/626-0409 Page 1 of 10 Data Qualifiers Key Reference: BH MB greater than one half of the RL, but the sample concentrations are greater than IN the MB. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference Results reported.to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529.6364 -Toll Free Number: 1-800/529-6364 - Fax: 704/626-0409 Page 2 of 10 Full -Service Analytical & Environmental Solutions I ORATORIE Sample Receipt Summary 04/26/2017 Prism Work Order: 7040189 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 7040189-01 Solid 04/10/17 04/10/17 Samples were received in good condition at 2.4 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 3 of 10 r Ism S m Fun -Service Analytical s V' Environmental Solutions /RPR -osxroniEE, INC. Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Laboratory Report 04/26/2017 Project: Class A Dried Sludge Client Sample ID: Class A Prism Sample ID: 7040189-01 Prism Work Order: 7040189 Sample Matrix: Solid Time Collected: 04/10/17 08:45 Time Submitted: 04/10/17 13:05 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Daterrime ID General Chemistry Parameters Plant Available Nitrogen 16000 mg/kg dry 1600 360 40 *Calculation 4118/17 6:53 CLB [CALC] % Solids 96.1 % by 0.100 0.100 1 *SM2540 G 4/12/17 16:07 JLB P7100208 Weight Nitrate/Nitrite as N BRL mg/kg dry 5.2 0.57 1 *SM4500-NO3 F 4/17/17 10:12 CLB P7D0233 pH 6.4 pH Units 1 *9045D 4110/17 14:29 BMS P7130120 Phosphorus -Total 9300 mg/kg dry 260 37 100 *SM4500-P F 4119/17 7:64 CLB P7D0263 Total Kjeldahl Nitrogen 50000 mg/kg dry 5200 1100 20 *351.2 4/18/17 6:63 CLB P7100152 Ammonia as N 2900 mg/kg dry 210 66 40 *SM4500-NH3 G 4/17/17 6:66 CLB P7D0197 Microbiological Parameters Fecal Coliforms BRL MPN/g dry 0.2 1 *SM9221 E 4/10/17 14:06 BMS P7D0154 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 *1311 4/18/17 6:35 JAB P7D0250 TCLP Extraction Complete N/A 1 *1311 ZHE 4/19/17 7:45 ANG P7D0271 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 4/18/17 13:27 JAB P7D0256 Arsenic BRL mg/L 0.050 0.012 1 *6010D 4/20/17 15:02 bgm P7D0266 Barium BRL mg/L 5.0 0.0065 1 *6010D 4/20/17 15:02 bgm P7D0266 Cadmium BRL mg/L 0.025 0.00065 1 *6010D 4/20/17 15:02 bgm P7D0266 Chromium BRL mg/L 0.25 0.0038 1 *6010D 4/20/17 15:02 bgm P7D0266 Lead BRL mg/L 0.050 0.0080 1 *6010D 4/20/17 15:02 bgm P7D0266 Selenium 0.15 mg/L 0.10 0.022 1 *6010D 4/20/17 15:02 bgm P71010266 Silver BRL mg/L 0.25 0.00050 1 *6010D 4/20/17 15:02 bgm P7D0266 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00047 1 *8081B 4/25/17 21:21 JMC P7D0354 Dieldrin BRL mg/L 0.00050 0.000070 1 *8081B 4/25/17 21:21 JMC P7D0354 Endrin BRL mg/L 0.00050 0.000075 1 *808113 4/25/17 21:21 JMC P7D0354 gamma-BHC BRL mg/L 0.00050 0.000065 1 *8081B 4/25117 21:21 JMC P7D0354 Heptachlor BRL mg/L 0.00050 0.000085 1 *8081B 4/25/17 21:21 JMC P7D0354 Heptachlor Epoxide BRL mg/L 0.00050 0.000065 1 *8081 B 4/25/17 21:21 JMC P7D0354 -- Methoxychlor BRL mg/L 0.00050 0.00020 1 *8081B 4/25/17 21:21 JMC P7D0354 Toxaphene BRL mg/L 0.025 0.00037 1 *8081B 4/25/17 21:21 JMC P7D0354 Surrogate Recovery Control Limits Decachlorobiphenyl 15 % 13-186 Tetrachloro-m-xylene 17 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 *8270D 4/21/17 11:19 JMV P7D0293 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 4/21/17 11:19 JMV P7D0293 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 *8270D 4/21/17 11:19 JMV P7D0293 2-Methylphenol BRL mg/L 0.050 0.0018 1 *8270D 4/21/17 .11:19 JMV P7D0293 i This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 10 { Laboratory Report ISMFull -Service Analytical s ' V' Environmental Solutions 04/26/2017 ...� r�LrlEORATORIE$ INC Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 7040189-01 P. O. Box 878 Prism Work Order: 7040189 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 04/10/17 08:45 Time Submitted: 04/10/17 13:05 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 *8270D 4/21/17 11:19 JMV P7D0293 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 *8270D 4/21/17 11:19 JMV P7D0293 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 *8270D 4/21/17 11:19 JMV P7D0293 Hexachloroethane BRL mg/L 0.050 0.0017 1 *8270D 4/21/17 11:19 JMV P7D0293 Nitrobenzene BRL mg/L 0.050 0.0026 1 *8270D 4/21117 11:19 JMV P7D0293 Pentachlorophenol BRL mg/L 0.25 0.0012 1 *8270D 4/21/17 11:19 JMV P7D0293 Pyridine BRL mg/L 0.25 0.0010 1 *8270D 4/21/17 11:19 JMV P7D0293 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 55 % 43-140 2-Fluorobiphenyl 49 % 44-119 2-Fluorophenol 31 % 19-119 Nitrobenzene-d5 48 % 44-120 Phenol-d5 23 % 11-52 Terphenyl-d14 54 % 50-134 TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *8260B 4/21/17 17:42 KDM P7D0344 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 *8260B 4/21117 17:42 KDM P7130344 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *8260B 4/21/17 17:42 KDM P7D0344 Benzene BRL mg/L 0.025 0.00048 1 *8260B 4/21/17 17:42 KDM P700344 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *826013 4/21/17 17:42 KDM P7D0344 Chlorobenzene BRL mg/L 5.0 0.00062 1 *826013 4/21/17 17:42 KDM P7D0344 Chloroform BRL mg/L 0.30 0.00076 1 *8260B 4/21/17 17:42 KDM P7D0344 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *8260B 4/21/17 17:42 KDM P7D0344 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *8260B 4/21/17 17:42 KDM P7D0344 Trichloroethylene BRL mg/L 0.025 0.00078 1 *8260B 4121/17 17:42 KDM P7D0344 Vinyl chloride BRL mg/L 0.020 0.00097 1 *8260B 4/21/17 17:42 KDM P7D0344 Surrogate Recovery Control Limits 4-Bromofluorobenzene 115 % 60-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 102 % 77-123 Total Metals Aluminum 5400 mg/kg dry 2.6 0.77 1 *60101) 4/24/17 21:55 bgm P7D0229 Mercury 0.59 mg/kg dry 0.069 0.0033 3 '747113 4117117 12:28 JAB P7130230 SAR Soil Preparation Complete g 1 *2-78-054 4/13/17 9:40 JAB P7D0179 SAR Percent Moisture 81.2 % by 0.100 0.100 1 *2-78-054 4/17/17 10:26 JAB P7D0246 Weight Arsenic 0.96 mg/kg dry 0.26 0.032 1 *60101) 4/24/17 21:55 bgm P7130229 Sodium Absorption Ratio 1.4 Iblank] 0.30 0.016 1 *2-78-054 4/17/17 21:26 bgm P7D0209 Cadmium 0.28 mg/kg dry 0.26 0.0070 1 *60101) 4/24/17 21:55 bgm P7130229 Calclum 190 mg/L 1.0 0.10 10 *6010D 4/17/17 21:26 bgm P7D0209 Calcium 7700 mg/kg dry 100 2.4 10 *60101) 4124117 22:04 bgm P7130229 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/625-0409 Page 5 of 10 Laboratory Report ®R I SM1 EnviFull-Service Analytical s 04/26/2017 Environmental SolutionsR Town of Mooresville/RR VWVTP Attn: Whitney Munroe P. 0. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Client Sample ID: Class A Prism Sample ID: 7040189-01 Prism Work Order: 7040189 Time Collected: 04/10/17 08:45 Time Submitted: 04/10/17 13:05 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chromium 7.7 mg/kg dry 0.26 0.043 1 *6010D 4/24/17 21:66 bgm P71010229 Copper 110 mg/kg dry 0.62 0.047 1 *6010D 4124/17 21:65 bgm P7D0229 Lead 4.9 _ mg/kg dry 0.26 0.048 1 *6010D 4/24/17 21:56 bgm P7D0229 Magnesium 1600 mg/kg dry 26 2.4 10 *60101) 4124/17 22:04 bgm P7130229 Magnesium 87 mg/L 1.0 0.086 10 *6010D 4/17/17 21:26 bgm P7D0209 Molybdenum 3.6 mg/kg dry 0.62 0.015 1 *6010D 4/24/17 21:56 bgm P71010229 Nickel 6.4 mg/kg dry 0.62 0.019 1 *6010D 4124117 21:55 bgm P71010229 Potassium 1600 mg/kg dry 130 4.7 10 *60101) 4/24/17 22:04 bgm P71010229 Selenium 3.1 mg/kg dry 0.62 0.12 1 *6010D 4124/17 21:56 bgm P7D0229 Sodium 670 BH mg/kg dry 16 0.51 1 *6010D 4/24/17 21:65 bgm P7D0229 Sodium 93 BH mg/L 5.0 0.18 10 *6010D 4/17/17 21:26 bgm P7D0209 Zinc 230 mg/kg dry 26 0.93 10 *6010D 4/24117 22:04 bgm P7D0229 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/626-0409 Page 6 of 10 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final Date/Time ' 7040189-01 P7D0152 0.05 g 25 mL 04/11/17 10:55 Prep Method: SM4600-PBS Lab Number Batch Initial Final Date/Time i 7040189-01 P7D0263 1 g 50 mL 04/18/17 10:20 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 7040189-01 P7D0208 30 g 30 g 04/12/17 16:07 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 7040189-01 P7D0271 12.5 g 250 mL 04/18/17 15:00 7040189-01 P7D0250 100 g 2000 mL 04/17/17 14:10 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7040189-01 P7D0266 10 mL 50 mL 04/18/17 11:20. Prep Method: 7470A Lab Number Batch Initial Final Date/Time 7040189-01 P7D0256 20 mL 30 mL 04/18/17 10:40 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 7040189-01 P7D0354 200 mL 10 mL 04/21/17 8:30 Prep Method: 3610C MS Lab Number Batch Initial Final Date/Time 7040189-01 P7D0293 200 mL 1 mL 04/19/17 10:30 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 7040189-01 P7D0344 1 mL 10 mL 04/21/17 16:10 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7040189-01 P7D0209 50 mL 50 mL 04/13/17 11:00 7040189-01 P71)0209 50 mL 50 mL 04/13/17 11:00 Prep Method: 3050E Lab Number Batch Initial Final Date/Time 7040189-01 P7D0229 2 g 50 mL 04/17/17 8:10 7040189-01 P7D0229 2 g 50 mL 04/17/17 8:10 Prep Method: 7471B Lab Number Batch Initial Final Date/Time 7040189-01 P7D0230 0.63 g 50 mL 04/17/17 9:05 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 Toll Free Number: 1-800/629-6364 Fax: 704/525-0409 Page 7 of 10 - - Prep Method: SAR 2-78-064 Lab Number 7040189-01 Sample Extraction Data Batch Initial Final Date/Time P7D0179 250 g 250 g 04/12/17 9:40 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 10 Full -Service Analytical & I CHAIN OF CUSTODY RECORD ,k - I Environmental Solutions PAGE ` OF; QUOTE # TO ENSURE PROPER BILLING: .... ,....-, - ' LA80RATORIES, INC. /� j � J,1 �ia9 Springbrook Road • Charlotte, NC 25277 Project Name: L--eis � ��6 t.r Phone 704/529-6364 • Fax: 7041525-0409 Short Hold Analysis: es (No) UST Project. (Yes) T *Please ATTACH any project specific reporting (QC LEVE Itll III IV) Client CompanyName: Pzv provisions and/or QC Requiremegts Re ort To/Contact Name: Invoice To: I "Vt - °i 6ote t,ke, Reporting Address: (�.• �� oX Address: Phone: -lo'j—L.40 -3:)-'� Fax (Yes) (No): Purchase Order No./Billing Reference Email Address: Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days EDD Type: PDF L Excel Other Rush Work Must Be yp _ _ "Working Days" ❑ 6-9 Days tandard 10 days ❑ pre -Approved Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS It CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Certification: NELAC DOD FL NC SC OTHER NIA Water Chlorinated: YES_ li Sam on Collection: YES NO " p e I Iced Upon CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIVES ANALYSIS REQUESTED .� �� O �J i® v rC REMARKS rl� �u _y�Y %�V�� !\ jq PRISM LAB ID NO. TYPE SEE BELOW NO. SIZE cab Sampler's Signatur al_,_ Sampled By (Print Name) Affiliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be u submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Re inqui('sh/f,ed' By: (Signature) Re d By: (Signature) '6D.ate 1 MilitarylHouts Additional Comments 5lte Arrival Time Relinquished By: (S' n lure) Received By: (Signature) Date 7F ff I $tte Departure i Ime' `IJVD FteldTech.Fee Relinquish ed.B • (Signature) ReceivedFy�-n' Lab tones y: Date -7 l3wt U ivllleage Method of'Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT W STODY SEALS FOR TRANSPORTATION TO THE LABORATORY. CDC Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST SPC UNTIL RECEIVED AT THE LABORATORY. '7 Q ❑ Fed Ex ❑ UPS ❑ Hand -delivered !®,Prism Feld Service ❑ Other (U �I NPDES: I UST: I GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: •� >NC ❑ SC ❑ NC El El SC ❑ NC ❑ SC ❑ NC El SC El NC ❑ SC ❑ NC El SC ❑ NC ❑ SC I ❑ NC ❑ SC I o ❑ ❑ El 1-1NC ❑ ❑ ❑ P « *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) CHANN OF CUSTODY RECORD ISM ToFull-Service Analytical & ° o '.- Environmental Solutions PAGE' orn auoTE a o EmsunE PnoPs BILLONG: � � � { YES NO NIA ,0 Samples INTACT upon,arnval O IN ."'+"LABORATORIES G r Project Nam®: } P�'`"'� Reserved ON WET ICES Temp 449 Springbrook Road a P.O. Box 24OW a Charlotte, MC 28224-OS43 � PROPER PRESERVATIVES indicated? N Phone: 704/529-6364 v Fax: 704/525-0409 Short Bold Analysis. (Yes) (No) LIST Project: (Yes) (NO) -- p) Client Company Name " � Ua ;ti�11� "Please ATTACH any project specific reporting) (SRC LEVEL l it III tin Cieco(ved WITHIN HOLDING TIMES? � 1$ r bu1rZ� provisions and/or OC Requirements CUSTODY SEALS INTACT? • a Report To/Contact NaPvt®: L'v VOLATILES rem d WlOUT, HEADSPACE? Reporting Address: t : c i5a- �d Invoice To: — - a Address: PROPER•GONTAINEFiS used? -1 r Phone: '401 Fax (Yes) (No): Purchase Orcl®r NO./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PEAS®NNEi. Email e) (N®) i8 Address Requested Due Date C1 1 Day U 2 Days U 3 Days a 4 Days U 5 Drays i€' Certification: NELAG USACE FL _ NC EDO Type: PDP—tExcel®Other "Working Days" Cl 6-9 Days 9 Standard 10 days Ct Rush pork dust BePre-SC OTHER N/A Site Location Name. Samples received after 15:00 will be processed next business clay. Site Location Physical Address: Turnaround time Is basod on business days, excluding weekends and holidays, Water Chlorinated: YES® NO (SEE REVERSE FOR TERMS if CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES NO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) p TIME MATRIX SAMPLE CONTAINER ANALYSES REQUESTED CLIENT DATE COLLECTED (SOIL, _ PRESERVA° PRISM SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR "TYPE TIVEa� ;! �L i \ �':. ° �l ,°�:� �' REUARKS LAB FLOURS SLUDGE) SEE BELOW N®. SIZE / -, �a / \ � � j. � � I® N®. k i Sampler's Signature �` Sampled By (Print Name) 1'� 10� �� Affiliation 0 � Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Relinquished By: (Signature) Received By: (Signature) Date 4-10-17 MilitaryMours 1054 Additional Comments Relinquished By: (Sign u e) Received By: (Signature) Date` -ram g Relinquished By: (Signature) Received For Prjsr9LabvcrieVy: Date �a I` al 1/ y-y� ISN I J' 1 -� 1 1a &LL / t Method of Shipment-. NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CODY BEAUS FOR TRANSPORTATION TO THE LABORATORY COC Grou No Wil• 51te Arrival 711ne; Site Departure rime: :Field Teeh Gee: SAMPLES ARE NOT CCACCEPTED AND VERIFIED AGAINST C06b TIL RECEIVED AT THE LABORATORY. ❑ Fed Ex ❑ UPS - ❑ Hand -delivered Prism Field Service ❑ Other 1 • NYDIES. UST: (GROUNDWATER: DRINitINCa WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: �NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC' ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC *CONTAINER TYPE CODES: A = Amber C = Clear G = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) iY —I. Proi, I R'' - I S) M F�� ;- LABORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 07/24/2017 Prism Work Order: 7070400 Case Narrative 08/09/2017 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. i Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 10x the MB. MC Sample concentration too high for recovery evaluation. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 1 Of 17 t� ®I n n Full -Service Analytical & Ile,>i Environmental Solutions --- n I v' �" LABORATORIES, ING Sample Receipt Summary 08/09/2017 Prism Work Order: 7070400 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 7070400-01 Solid 07/24/17 07/24/17 Samples were received in good condition at 2.1 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041626-0409 Page 2 of 17 "j' I I Fun -Service Analytical s �` Environmental Solutions i-s-- 1�� LABORATORIES, [NC. Laboratory Report 08/09/2017 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 7070400-01 P. O. Box 878 Prism Work Order: 7070400 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/24/17 11:15 Time Submitted: 07/24/17 11:52 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Datefrime ID General Chemistry Parameters Plant Available Nitrogen 4500 mg/kg dry 1600 360 40 *Calculation 8/2/17 10:24 CLB [CALL] % Solids 96.2 % by 0.100 0.100 1 *SM2540 G 8/1/17 16:38 JLB P7H0034 Weight Nitrate/Nitrite as N BRL mg/kg dry 5.2 0.57 1 *SM4500-NO3 F 7/25/17 10:14 CLB P7G0371 pH 6.5 pH Units 1 *9045D 7/25/17 13:27 SLS P7G0392 Phosphorus -Total 14000 mg/kg dry 260 37 100 *SM4500-P F 7/31/17 11:35 CLB P7130466 Total Kjeldahl Nitrogen 13000 mg/kg dry 6200 1100 20 *351.2 812/17 10:24 CLB P7G0479 Ammonia as N 2200 mg/kg dry 210 66 40 *SM4500-NH3 G 7/28/17 9:22 CLB P7G0411 Microbiological Parameters Fecal Coliforms 2 MPN/g dry 0.2 1 *SM9221 E 7/24/17 12:23 BMS P7130387 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 *1311 811/17 7:00 JAB P7G0488 TCLP Extraction Complete N/A 1 *1311 ZHE 8/3/17 8:30 ANG 1371-10070 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 8/1/17 15:51 JAB P7110014 Arsenic BRL mg/L 0.050 0.012 1 *6010D 8/1/17 21:05 JAB P7110015 Barium BRL mg/L 5.0 0.0065 1 *6010D 8/1/17 21:05 JAB P7110015 Cadmium BRL mg/L 0.025 0.00065 1 *6010D 8/1/17 21:05 JAB P71-10015 Chromium BRL mg/L 0.25 0.0038 1 *6010D 8/1/17 21:05 JAB P7110015 Lead 0.11 mg/L 0.050 0.0080 1 *6010D 8/1117 21:06 JAB P7H0015 Selenium BRL mg/L 0.10 0.022 1 *6010D 8/1/17 21:05 JAB P7110015 Silver BRL mg/L 0.25 0.00050 1 *6010D 8/1117 21:05 JAB P7110015 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0,00047 1 *8081B 8/7/17 21:17 JMC P7110053 Dieldrin BRL mg/L 0.00050 0.000070 1 *8081B 8/7/17 21:17 JMC P7110053 Endrin BRL mg/L 0.00050 0.000075 1 *8081B 8/7/17 21:17 JMC P7110053 gamma-BHC BRL mg/L 0.00050 0.000065 1 *8081B 8/7/17 21:17 JMC 1371-10053 Heptachlor BRL mg/L 0.00050 0.000085 1 *808113 8/7/17 21:17 JMC P7110053 Heptachlor Epoxide BRL mg/L 0.00050 0,000065 1 *8081B 8/7/17 21:17 JMC P7110053 Methoxychlor BRL mg/L 0.00050 0.00020 1 *8081B 8/7/17 21:17 JMC P7110053 Toxaphene BRL mg/L 0.025 0.00037 1 *8081B 8/7/17 21:17 JMC P7110053 Surrogate Recovery Control Limits Decachlorobiphenyl 34 % 13-186 Tetrachloro-m-xylene 22 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichloraphenol BRL mg/L 0.25 0.0016 1 *8270D 8/1/17 18:18 JMV P7GO486 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 8/1/17 18:18 JMV P7G0486 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 *8270D 8/1/17 18:18 JMV P7G0486 2-Methylphenol BRL mg/L 0.050 0.0018 1 *8270D 8/1/17 18:18 JMV P7G0486 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/625-0409 Page 3 of 17 Laboratory Report P"® I S Fun -Service Analytical & n Environmental Solutions 08/09/2017 /`---Oi-TORles INC Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 7070400-01 P. O. Box 878 Prism Work Order: 7070400 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/24/17 11:15 Time Submitted: 07/24/17 11:52 Parameter Result Units Report MDL Limit Dilution Factor Method Analysis Date/Time Analyst Batch ID 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 *8270D 8/1/17 18:18 JMV P7G0486 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 *8270D 8/1/17 18:18 JMV P7G0486 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 *8270D 8/1/17 18:18 JMV P7G0486 Hexachloroethane BRL mg/L 0.050 0.0017 1 *8270D 811/17 18:18 JMV P7G0486 Nitrobenzene BRL mg/L 0.050 0.0026 1 *8270D 8/1/17 18:18 JMV P7G0486 Pentachlorophenol BRL mg/L 0.25 0.0012 1 *8270D 8/1/17 18:18 JMV P7G0486 Pyridine BRL mg/L 0.25 0.0010 1 *8270D 8/1/17 18:18 JMV P7G0486 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 51 % 43-140 2-Fluorobiphenyl 46 % 44-119 2-Fluorophenol 36 % 19-119 Nitrobenzene-d5 42 % 44-120 SE Phenol-d5 26 % 11-52 Terphenyl-d14 55 % 50-134 TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *8260B 8/3/17 15:11 KDM P71-10083 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 *8260B 8/3/17 15:11 KDM P71-10083 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *8260B 8/3/17 15:11 KDM P71-10083 Benzene BRL mg/L 0.025 0.00048 1 *8260B 8/3/17 15:11 KDM P71-10083 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *8260B 8/3/17 15:11 KDM P71-10083 Chlorobenzene BRL mg/L 5.0 0.00062 1 *8260B 8/3/17 15:11 KDM P71-10083 Chloroform BRL mg/L 0.30 0.00076 1 *8260B 8/3117 15:11 KDM P71-10083 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *8260B 813/17 15:11 KDM P71-10083 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *8260B 8/3/17 15:11 KDM P71-10083 Trichloroethylene BRL mg/L 0.025 0.00078 1 *826013 8/3/17 15:11 KDM P71-10083 Vinyl chloride BRL mg/L 0.020 0.00097 1 *8260B 8/3/17 15:11 KDM P71-10083 Surrogate Recovery Control Limits 4-Bromofluorobenzene 108 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 97 % 77-123 Total Metals Aluminum 11000 mg/kg dry 2.6 0.76 1 *6010D 811/17 22:00 JAB P7G0450 Mercury 0.76 mg/kg dry 0.29 0.028 15 *7471B 814117 15:02 JAB P7H0093 SAR Soil Preparation Complete g 1 *2-78-054 611117 11:02 JAB P7G0489 SAR Percent Moisture 78.5 % by 0.100 0.100 1 *2-78-054 8/3117 13:25 JAB P7H0076 Weight Arsenic 1.6 mg/kg dry 0.26 0.031 1 *6010D 811/17 22:00 JAB P7G0450 Sodium Absorption Ratio 1.6 [blank] 0.30 0.016 1 *2-78-054 8/1117 21:50 JAB P71-10016 Cadmium 0.46 mglkg dry 0.26 0.0069 1 *6010D 8/1/17 22:00 JAB P7G0450 Calcium 17000 mg/kg dry 210 4.7 20 *6010D 8/1/17 14:43 JAB P7G0450 Calcium 190 mg/L 0.10 0.010 1 *6010D 811/17 21:50 JAB P71-110016 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 17 Full -Service Analytical & Laboratory Report Environmental Solutions 08/09/2017 - J-'PRISM _._._._;�� . L OF-ORIE$ INC. Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Client Sample ID: Class A Prism Sample ID: 7070400-01 Prism Work Order: 7070400 Time Collected: 07/24/17 11:15 Time Submitted: 07/24/17 11:52 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chromium 15 mg/kg dry 0.26 0.043 1 '6010D 8/1/17 22:00 JAB P7130450 Copper 190 mg/kg dry 10 0.93 20 '6010D 8/1117 14:43 JAB P7G0450 Lead 9.9 mg/kg dry 0.26 0.048 1 '6010D 8/1/17 22:00 JAB P7G0450 Magnesium 1900 mg/kg dry 2.6 0.24 1 '6010D 811/17 22:00 JAB P7G0450 Magnesium 64 mg/L 0.10 0.0086 1 "6010D 8/1/17 21:60 JAB P71-10016 Molybdenum 3.6 mg/kg dry 0.51 0.016 1 '6010D 8/1/17 22:00 JAB P7G0450 Nickel 10 mg/kg dry 0.51 0.019 1 '6010D 8/1/17 22:00 JAB P7G0450 Potassium 2300 mg/kg dry 260 9.3 20 '6010D 811/17 14:43 JAB P7130450 Selenium 3.0 mg/kg dry 0.51 0.12 1 '6010D 8/1/17 22:00 JAB P7130450 Sodium 720 mg/kg dry 15 0.61 1 '6010D 8/1/17 22:00 JAB P7130450 Sodium 92 B mg/L 10 6.36 20 '6010D ' 8/1/17 21:42 JAB P71-110016 Zinc 420 mg/kg dry 51 1.8 20 '6010D 8/1/17 14:43 JAB P7G0450 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 17 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final Date/Time 7070400-01 P7G0479 0.05 g 25 mL 08/01/17 8:10 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 7070400-01 P7G0466 1 g 50 mL 07/31/17 6:00 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 7070400-01 P71-10034 30 g 30 g 08/01/17 16:38 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 7070400-01 P7G0488 100 g 2000 mL 07/31/17 13:00 7070400-01 P71-10070 12.5 g 250 mL 08/02/17 15:00 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7070400-01 P71-10015 10 mL 50 mL 08/01/17 11:35 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 7070400-01 P7110014 20 mL 30 mL O8/01/17 8:55 Prep Method: 3610C GC Lab Number Batch Initial Final DatelTime 7070400-01 P71-10053 200 mL 10 mL 08/03/17 8:15 Prep Method: 3680A Lab Number Batch Initial Final Date/Time 7070400-01 P7G0486 200 mL 1 mL 08/01/17 11:05 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 7070400-01. P71-10083 1 mL 10 mL 08/03/17 10:02 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7070400-01 P71i0016 50 mL 50 mL 08/01/17 12:15 7070400-01 P71-10016 50 mL 50 mL 08/01/17 12:15 7070400-01 P71-10016 50 mL 50 mL 08/01/17 12:15 Prep Method: 3050B Lab Number Batch Initial Final Date/Time 7070400-01 P7G0450 2.02 g 50 mL 07/28/17 7:55 7070400-01 P7G0450 2.02 g 50 mL 07/28/17 7:55 Prep Method: 7471 B Lab Number Batch Initial Final Date/Time This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 17 Sample Extraction Data Prep Method: 7471 B Lab Number Batch Initial Final Date/Time 7070400-01 P71-10093 0.64 g 50 mL 08/04/17 9:55 Prep Method: SAR 2.78-054 Lab Number Batch Initial Final Date/Time 7070400-01 P7G0489 250 g 250 g 07/31/17 11:02 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 7070400-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toil Free Number: 1.800/629-6364 - Fax: 7041525-0409 Page 7 of 17 c 9CMAIN OF CUSTODY RECORD. r • ' �I en, I i Full -Service Anaiyticai & Environmental Solutions PAGE--L QUOTE # TO ENSURE PROP I! BILLING: t, y t A80RKrORIFS, INC. j J Lq '' Project Name: i.0 $ { I�C� �I L'l�i e •WU Rec 1 ^^-if t.;.ri; gtfrook goad •Charlotte, NC 28217 P;ior;r; 70<i!5?.9.6364 •Fax; 704/525.0409 Short Hold Analysis: �e No UST Project: s O Y � ( ) J ( ) ) I'RC �/ ff i'� 10c�'L�iSVt�l� *Please ATTACH any project specific reporting (QC LEVE�II III IV) .::. Client Company Name: CW G IV "rint?v kw)nV-- provisions and/or QC Requirements p q` ^fit 1`.::� Report To/Contact Name: "'V%- 0 Invoice To: � � %y'�e`-*r�s'•��$,. of Reporting Address: �'• L3 i3, Address: ,,..... e�r�c Phone: -N7"1' V4U-- 5-:&Y Fax (Yes) (No): ylt6lfi /\C Purchase Order No./Billing Reference it $ TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: INr�Z(� ,(j, jytp �;L71d • - Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days F_DD Type: PDF L/"Excel_Other "Working Must Be Certification: NELAC DOD V� FL NC Days" ❑ 6-9 DaysX tandard 10 days ❑ Pe-ApprovedrlhWork Sc OTHER N/A Site Location Name: Samples received after 14:00 will be processed next business day. Water L-f Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE OR TERMS & CONDITIONS SERVICES R ERSE Chlorinated: YES_ NO "No REND D BYFPR SM LABORATORIES, INC. TO C�LIENT)ING Sample Iced Upon Collection: YES CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- ANALYSIS REQUESTED ry�c ,°� PRISM SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR TIVES L' n REMARKS �i� LAB `TYPE HOURS SLUDGE) SEE BELOW NO. SIZE ob \�' �v ID NO. L��t�sS Pr �y .i �ae� olne, C� f r? _ Cat d Sampler's Signature Sampled By (Print Name) Affiliation Upon relinquishing, this Chain of Custody is your authorization for PrisM- proud with the analyses as requested above. Any changes must be ' submitted in Writing to the Prism Project Manager. There will be ch ges for any, hanges after analyses have been initialized. L a.:. Relinquished By: (Signaturre)),� Re /. ed By: Signature) Dat �'� Military/Hours s Additional Comments: : Slte Hrnval Time Reli qui hed By: ( g lure) Received•By: (Signature) Date `j7i i .� �/'�1I / 'ohi 'Departure l;lme:; . ..Cytl Relinquis�ed-Bg�(Signature Received For Pris� Laboratories By: Da e tJl I`�'\Q�,p(' Flelii-TeittPF2e'. a ' ss•-r''li2-11�. / f its �J (/ % IUlileage;. Method of Shlpm�C- NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTATION -TO THE LABORATORY. COG Group o.� .,.�'' SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. �7 `C�Fed Ex CI UPS ❑Hand-0elivered rism Field Service ❑Other 0cu-;vc) DRINKING❑ SOLID ILL I OTHER: F❑ NNC ❑ SC El NC ❑ SC ❑ NC El SC ❑ NC SCATER. ❑ NC El SC ❑ NBC ❑ SC ❑ NC El 9 NC SC 1 ❑ NC ® SC . . "CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) PRIZiFull -Service Analytical ik Environmental Solutions :' ..._ LABORATORIES, INC. 449 Springbrook Road • Charlotte, NC 28217 Phono 704/529-6364 • Fax: 704/525-0409 1+ Client Company Name: ��'�l �F fv�trlVi 51;4 Report To/Contact Name: Ld1(bN&i \ Reporting Address: tr CHAIN OF CUSTODY RECORD PAG& OF QUOTE # TO ENSURE PROPER BILLING: . - .. YES NO . NIA a Samples INITA. T upon arrivr l Project Name: �� + 1 �ItcG� I aelvedC)N NEI'ICE+ _;%_ CF) Short Hold Analysis: (Ye) (No) UST Project: (Ye ( O PROPER PRESRRVATIVES Indicated? ✓_ _ N *Please ATTACH any project specific reporting (QC LEVEL 1 II 111 IV) Receive'dWITHIN HOLDING, TIMES? provisions and/or QC Requirements C6S70D`C-SE-AL"S LNTACT? / 0- Invoice To: 1666^P1-c�- N1,bcrqft,1 VOLATILESrec'd':1N/OUTHEADSPACE? Address: PROPER 0ONTAINER TEMP l tie rm ID / K used?:. .:Observed: Z �(j °C l on °CI Phone: -Joli— W0•- 1:IW Fax (Yes) (No): Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC DOD �L NC EDD Type: PDF� Excel —Other "Working Days" CI 6-9 Days�Standard 10 days ❑ Rush Work Must Be Pre -Approved SC OTHER N/A Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO_ (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES NO CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- ANALYSIS R QUESTED � � PRISM 'TYPE SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR TIVES p REMARKS ` li './ : LAB ID NO. HOURS SLUDGE) SEE BELOW NO. SIDE ~ ' 1 --------------- Sampler's Signature Sampled By (Print Name) Affiliation ��ItiL Upon relinquishing, this Chain of Custody is your authorization for Prism to proctfd ith the analyses as requested above. Any changes must be submitted in Writing to the Prism Project Manager. There will be charges foraoy cha ges after analyses have been initialized. Relin Ish d B : ( ignalure) v Received B Y(Signature) Dale Military/Hours �, i �� . Additional Comments: Site Airivnl Time; ,A- Wy1_VUV1VLq1_ Relinquished By: (Sig t g},� Received By: (Signalµre) Date I Site Departure Time: Relinquished ReceiyvedorPrismLabor'riesBy: D� MI�5) I�I FieICI�TechFee: y/(Slign/at�yrge)/ eta, 9 MO 9 Pb) itAileage: Method'of Shiprpdbt: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. COC Group o. I i i� SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. % /\`-]�I' %�/A A �Qy se', �I Ao(J I _;I Fi d Ex ❑ UPS ❑ Hand -delivered Prism Field Service ❑ Other f lJ j f e1 _ o NPDES.- UST: G OUNDIVATER: DRINKING WATER: SOLID WASTE: RCRA: RCLA LANDFILL OTHER: del $ ❑NC❑SC ❑NC ❑SC oNC ❑SC I ElNC �CE ❑SC NC ❑SC ®NC❑SC ®NC ❑SC ®NC ❑SC oNC ❑SC 0 "CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) ACC ESS ANA%`11CI L-, INC.. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT E D 7070400 LABORATORY REPORT NUMBER 1707J80 DATE August 03, 2017 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick(a. axs-ine. c om - Unless otherivise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, CA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, CA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative ofAES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to yourlocal Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Pag Page 10 of 17 R I S M fay_t-'i -?e"LABDRATDRIES INC. Full -Service Analytical & 1_70 Environmental Solutions SUBCONTRACT ORDER CertVC NELAC_ USACB_ Prism (laboratories, Inc. SC_ Other 7070400 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. 0. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA Project Manager: Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample ID: 7070400-01 Solid Sampled:07/24/1711:15 Herbicides TCLP (Sub) 07/31/17 11:15 Containers Supplied. $eL 140k5S �•�� Re] By Date Fed 7l2 ill IN Released By Date Reccived By Date Date Released By Date Received By Page 1 of 1 Pag Page 11 of 17 c Full -Service Analytical & Environmental Solutions 1-4a-41,3 f SUBCONTRACT ORIDEiB Cetji nc NELAC USACE Prism Laboratories, Inc. SC Other 7070400 — SENDING LABORATORY: RECIEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. 0. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA Project Manager Terri W. Cole Analysis Due Expires Laboratory ID Comments ID:7070400-01 Solid Sampled:07/l4/1711:15 Herbicides TCLP (Sub) Containers Supplied 5 oZ 411aSS iar i" 07/31/1711:15 Feacv- _ 7 s : r s Lam. �J Relcased By Date Received By Date Page 1 of 1 12 of 17 i Analytical Environmental Services, Inc Date: 4-Aug-17 Client: Prism Laboratories Project: 7070400 Case Narrative Labi®: 1707J80 Insufficient sample volume was received on 7/25/17 for TCLP Herbicides analysis. Client sent in more sample on 7/28/17. Pag Page 13 of 17 Analytical Environmental Services, Inc Date: 3-Aug-17 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1707J80 Tag Number: 7070400-01 Project Name: 7070400 Collection Date: 7/24/2017 11:15:00 AM Lab ID: 1707J80-001A Matrix: Solid Reporting Analyses Result Qual A4DL Units BatchlD DF Date Analyzed Analyst Limit HERBIICIDES,'TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.030 0.20 mg/L 246282 1 08/03/201714:08 AW 2,4-D BRL 0.051 0.20 ing/L 246282 1 08103/201714:08 AW Surr: DCAA 61.3 0 50.1-132 %REC 246282 1 08/03/2017 14:08 AW Qualifiers: " Value exceeds maximum contaminant level BRL Not Detected at MDL H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank E Estimated value above quantization range S Spike Recovery outside limits due to matrix > Greater than Result value J Estimated value detected below Reporting Limit < Less than Result value Pag Page 14 of 17 II"LP0�Al1ENVIiSiS';RyICPb;INI ..: 1. CilentName: Access Analytical, Inc. SAMPLE/COOLER RECEIPT CHECKLIST 2. Carrier: FedEx Q UPS ❑ USPS❑ Client❑ Courier❑ Othel Va4 Nn N/A 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. AFS Work Order Number: 1707.l80 nm.n. r.,..,..,e - Shipping container/cooler received in good condition? e; damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? o Custody seals intact on shipping container? s Temperature blanks present? Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature recordings.] i ✓ Cooling Initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? e _ Chain of Custody signed, dated, and timed when relinquished and received? e_ sampler name and/or signature on COC? o Were all samples received within holding time? :P: TAT marked on the COC? e; If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 0.3 14. Cooler5Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3 Temperature eC Cooler 4Temperature °C eC Cooler 6 Temperature eC Cooler 7 Temperature eC Cooler 8 Temperature eC I certify that I have completed sections 1-15 (dated initials). TR 7/25/17 Ves Nn N/A r.,.,,..,.- Were sample containers intact upon receipt? ®; Custody seals present on sample containers? o. Custody seals Intact on sample containers? 0 e: Do sample container labels match the COC? 0 0 0 Incomplete info ❑ illegible ❑ no label ❑ other ❑ Are analyses requested Indicated on the COC? e Were all of the samples listed on the COC received? 0 0 samples received but not listed on COC ❑ samples listed on COC not received ❑ Was the sample collection date/time noted? o: . Did wexeceive sufficient sample volume for indicated analyses? _ Were samples received In appropriate containers? e• Were VOA samples received without headspace.(<1/4" bubble)? o; Were trip blanks submitted? IllsteclonCOC ❑ not listed on COC ❑ 27. Comments: This section only applies to samples where pH can be I certify that 1 have completed sections 16-27 (dated Initials). Al 7/25/17 checked at Sample Receipt. Yes No N/A Details Comments 28. Have containers needing chemical preservation been checked? ° all 29. Containers meet preservation guidelines? - 30. Was pH adjusted at Sample Receipt?1 0 1 0 1o. (a ' Note. Cortain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Collforms, VOCs and Oil & Grease/TPH. AI 7 25 1 (D I certify that i have completed sections 28-30 (dated initials). / / 7 p Checklist 6.9.17 Rev 2 - Page 6 of 8 $IANAzYHCAL r ' ��lARtitr? 1 iiVtesifi; rtaQ. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. 2. Carrier: FedEx Q UPS ❑ USPS ❑ Client❑ Courier❑ Other 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Vac Nn N/A i Y AES Work Order Number: 1707JBO Y nwtallc Comments Shipping container/cooler received In good condition? • damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? o: _ Custody seals intact on shipping container? •; _ Temperature blanks present? ®. Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature recordings.] ® Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? • Chain of Custody signed, dated, and timed when relinquished and received? ' e Sampler name and/or signature on COC? •. Were all samples received within holding time? TAT marked on the COC? o. If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 0.3 °C Cooler 2 Temperature 14. Cooler 5 Temperature °C Cooler 6 Temperature 15. Comments: r, °C Cooler 3 Temperature °C Cooler 4Temperature °C °C Cooler 7 Temperature °C Cooler 8 Temperature °C 1 hP k i certify that I have completed sections 1-15 (dated Initials). PM 7/28/17 Yes No N/A Details Comments Were sample containers intact upon receipt? ®: Custody seals present on sample containers? • Custody seals Intact on sample containers? e: Do sample container labels match the COC? 0 C) incomplete Info ❑ Illegible ❑ no label ❑ other El Are analyses requested indicated on the COC? o; _ Were all ofthe samples listed on the COC received? ; Q.: " ` samples received but not listed on COC ❑ samples listed on COC not received ❑ Was the sample.coilection date/time npted? •' ' Did we receive sufficient sample volume for indicated analyses? o; Were samples received in appropriate containers? o; _ Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? ® listed on COC ❑ not listed on COC ❑ 27, Comments: This section only applies to samples where pH can be checked at Sample. Receipt. f I certify that I have completed sections 16-27 (dated initials). PM 7/28/17 Details Comments f 28. Have containers needing chemical preservation been checked? �: 29, 1 Containers meet preservation guidelines? o -U 30. Was pH adjusted at Sample Receipt? _ _ o rQ Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. I certify that I have completed sections 2H-30 (dated initials). PM 7/28/17 vrty=� .. : Checklist 6.9.17 Rev 2� g� Yi O a Page 7 of 8 i Yes No N/A Analytical Environmental Services, Inc Client: Prism Laboratories Project Name: 7070400 Workorder: 1707J80 Date: 3-Aug-17 ANALYTICAL. QC SUMMARY REPORT Batch1l): 246282 Sample ID: NIE-246282 Client ID: Units: mg/L. Prep Date: 08/02/2017 Run No: 349004 SampleType: NIBLK TestCode: HERBICIDES, TCLP SW131118151A BatchID: 246282 Analysis Date: 08/03/2017 Seq No: 7667896 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.2722 0 0.5000 54.4 50.1 132 Sample ID: LCS-246282 Client ID: Units: mg/L Prep Date: 08/02/2017 Run No: 349004 SampleType: LCS TestCode: HERBICIDES, TCLP SW1311/8151A BatchlD: 246282 Analysis Date: 08/03/2017 Seq NTo: 7667897 Analyte Result RPT Limit SPK value SPIC Ref Val . %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.3724 0.20 0.5000 74.5 50.7 117 2,4-D 0.3343 0.20 0.5000 66.9 50.1 119 Sum DCAA 0.2849 0 0.5000 57.0 50.1 132 Sample ID: 1707N95-001B3MS Client ID: Units: mg/L Prep Date: 08/02/2017 Run No: 349004 SampleType: NIS TestCode: HERBICIDES, TCLP SW1311/8151A BatehlD: 246282 Analysis Date: 08/03/2017 Seq No: 7667899 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.3634 0.20 0.5000 72.7 46.3 126 2,4-D 0.3159 0.20 0.5000 63.2 43.3 132 Surr: DCAA 0.2844 0 0.5000 56.9 50.1 132 -D Qualifiers: Greater than Result value < Less than Result value B Analyte detected in the associated method blank fD BRL Below reporting limit E Estimated (value above quantitation range) H Holding times for preparation or analysis exceeded �I J Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside limits due to matrix Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix 1-jj Page 8 of 8 ism IFull-Service Analytical Environmental Solutions 'LABORATORIES, INC. Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 10/16/2017 Prism Work Order: 7100308 Case Narrative 11 /02/2017 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: W-0. 4_1� M, _� � k �, � Reviewed By Terri W. Cole Project Manager B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 1 Ox the MB. CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. D RPD value outside of the control limits. L1 LCS recovery outside of the QC limits. LCSD recovery within the limits. No further action taken. MC Sample concentration too high for recovery evaluation. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 14 1- I Full -Service Analytical s Environmental Solutions LABORATORIES ING Sample Receipt Summary 11/02/2017 Prism Work Order: 7100308 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 7100308-01 Solid 10/16/17 10/16/17 Samples were received in good condition at 3.9 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/625-0409 Page 2 of 14 r �, I SM Fun -Service Analytical s Environmental Solutions ,4 LABORATORIES INC. Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 11 /02/2017 Client Sample ID: Class A Prism Sample ID: 7100308-01 Prism Work Order: 7100308 Time Collected: 10/16/17 08:19 Time Submitted: 10/16/17 12:35 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 9700 mg/kg dry 4000 840 50 *Calculation 10/31/17 14:10 CLB [CALC] % Solids 96.0 % by 0.100 0.100 1 *SM2540 G 10/24/17 15:25 TJY P7J0482 Weight Ammonia as N 1700 mg/kg dry 11 2.6 1 *SM4500-NH3 C 10/31/17 14:10 BMS P7J0591 Nitrate/Nitrite as N BRL mg/kg dry 5.3 0.58 1 *SM4500-NO3 F 10/19/17 8:28 CLB P7J0332 pH 6.8 pH Units 1 *9045D 10/17/17 13:54 BMS 127J0296 Phosphorus -Total 12000 mg/kg dry 260 38 100 *SM4500-P F 10/24/17 8:10 CLB P7J0407 Total Kieldahl Nitrogen 31000 mg/kg dry 13000 2800 50 *361.2 10/23/17 8:18 CLB P7J0334 Microbiological Parameters Fecal Coliforms BRL MPN/100 2 1 *SM9221 E 10/16/17 13:30 BMS P7J0291 mL TCLP Extraction by EPA 1311 TCLP Extraction TCLP Extraction TCLP Metals Complete Complete N/A N/A 1 1 *1311 *1311 ZHE 10/19/17 7:30 JAB 10/27/17 9:00 ANG P7J0321 P7J0535 Mercury BRL mg/L 0.010 0.000030 1 *7470A 10/19/17 16:39 JAB P7J0345 Arsenic BRL mg/L 0.050 0.016 1 *6010D 10/19/17 17:41 JAB P7J0346 Barium BRL mg/L 5.0 0.0040 1 *6010D 10/19/17 17:41 JAB P7J0346 Cadmium BRL mg/L 0.025 0.00075 1 *6010D 10/19/17 17:41 JAB P7J0346 Chromium BRL mg/L 0.25 0.0018 1 *6010D 10/19/17 17:41 JAB P7J0346 Lead BRL mg/L 0.050 0.0040 1 *6010D 10/23/17 14:53 JAB P7J0346 Selenium BRL mg/L 0.10 0.028 1 *6010D 10/19/17 17:41 JAB P7J0346 Silver BRL mg/L 0.25 0.0020 1 *6010D 10/19/17 17:41 JAB P7J0346 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00047 1 *8081B 10/31/17 12:58 JMC P7J0464 Dieldrin BRL mg/L 0.00050 0.000070 1 *8081B 10/31/17 12:58 JMC P7J0464 Endrin BRL mg/L 0.00050 0.000075 1 *8081B 10/31/17 12:58 JMC P7J0464 gamma-BHC BRL mg/L 0.00050 0.000065 1 *808113 10/31/17 12:58 JMC P7J0464 Heptachlor BRL mg/L 0.00050 0.000085 1 *8081B 10/31/17 12:58 JMC P7J0464 Heptachlor Epoxide BRL mg/L 0,00050 0.000065 1 *8081B 10/31/17 12:58 JMC P7J0464 Methoxychlor BRL mg/L 0.00050 0.00020 1 *8081B 10/31/17 12:58 JMC P7J0464 Toxaphene BRLCCv mg/L 0.025 0.00037 1 *8081B 10/31/17 12:58 JMC P7J0464 Surrogate Recovery Control Limits Decachlorobiphenyl 30 % 13-186 Tetrachloro-m-xylene 47 % 40-134 TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 *8270D 10/25/17 17:15 JMV P7J0471 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 10/25/17 17:15 JMV P7J0471 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 *8270D 10/25/17 17:15 JMV P7J0471 2-Methylphenol BRL mg/L 0.050 0.0018 1 *8270D 10/25/17 17:15 JMV P7J0471 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1.800/529-6364 - Fax: 704/526-0409 Page 3 of 14 q Laboratory Report PR I I tl 1 I EnviService Analytical & ronmental Solutions 11/02/2017 - I Envi"�•-ORATORIEr I c Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 7100308-01 P. O. Box 878 Prism Work Order: 7100308 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/16/17 08:19 Time Submitted: 10/16/17 12:35 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DatelTime ID 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 *8270D 10/25/17 17:15 JMV P7J0471 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 *8270D 10/25/17 17:15 JMV P7J0471 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 *8270D 10/25/17 17:15 JMV P7J0471 Hexachloroethane BRL mg/L 0.050 0.0017 1 *8270D 10/25/17 17:15 JMV P7J0471 Nitrobenzene BRL mg/L 0.050 0.0026 1 *8270D 10/25/17 17:15 JMV P7J0471 Pentachlorophenol BRL mg/L 0.25 0.0012 1 *8270D 10/25/17 17:15 JMV P7J0471 Pyridine BRL mg/L 0.25 0,0010 1 *8270D 10/25/17 17:15 JMV P7J0471 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 69 % 43-140 2-Fluorobiphenyl 72 % 44-119 2-Fluorophenol 44 % 19-119 Nitrobenzene-d5 69 % 44-120 Phenol-d5 30 % 11-52 Terphenyl-d14 67 % 50-134 TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *8260B 10/31/17 13:17 KDM P7J0597 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 *8260B 10/31/17 13:17 KDM P7J0597 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *8260B 10/31/17 13:17 KDM P7J0597 Benzene BRL mg/L 0.025 0.00048 1 *8260B 10/31/17 13:17 KDM P7J0597 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *8260B 10/31/17 13:17 KDM P7J0597 Chlorobenzene BRL mg/L 5.0 0.00062 1 *8260B 10/31/17 13:17 KDM P7J0597 Chloroform BRL mg/L 0.30 0.00076 1 *8260B 10/31/17 13:17 KDM P7J0597 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *8260B 10/31/17 13:17 KDM P7J0597 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *82608 10/31/17 13:17 KDM P7J0597 Trichloroethylene BRL mg/L 0.025 0.00078 1 *8260B 10/31/17 13:17 KDM P7J0597 Vinyl chloride BRL mg/L 0.020 0.00097 1 *8260B 10/31/17 13:17 KDM 137J0597 Surrogate Recovery Control Limits 4-Bromofluorobenzene 106 % 80-124 Dibromofluoromethane 107 % 75-129 Toluene-d8 95 % 77-123 Total Metals Aluminum 13000 mg/kg dry 26 7.6 10 *60101) 10/24/17 17:30 JAB P7J0403 Mercury 0.46 mg/kg dry 0.21 0.020 10 *7471B 10/17/17 13:01 JAB P7J0282 SAR Soil Preparation Complete g 1 *2-78-054 10/25/17 12:10 JAB P7J0422 SAR Percent Moisture 79.0 % by 0.100 0.100 1 *2-78-054 10/27/17 14:00 JAB P7J0546 Weight Arsenic 2.1 mg/kg dry 0.26 0.031 1 *60101) 10/23/17 18:28 JAB P7J0403 Sodium Absorption Ratio 1.8 B [blank] 0.30 0.016 1 *2-78-054 10/26/17 18:21 JAB 137J0494 Cadmium 0.38 mg/kg dry 0.26 0.0069 1 *60101) 10/23/17 18:28 JAB 137J0403 Calcium 14000 mg/kg dry 100 2.4 10 *6010D 10/24/17 17:30 JAB 137J0403 Calcium 330 B mg/L 0.10 0.010 1 *6010D 10/26/17 18:21 JAB 137J0494 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 4 of 14 Laboratory Report �%®® I C � /� EnviService Analytical s 11/02/2017 /' r (� V �/ Environmental Solutions ..�.. LABORATORIES,- Town of Mooresville/RR VWVTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid t Client Sample ID: Class A Prism Sample ID: 7100308-01 Prism Work Order: 7100308 Time Collected: 10/16/17 08:19 Time Submitted: 10/16/17 12:36 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chromium 15 mg/kg dry 0.26 0.043 1 *601OD 10/23/17 18:28 JAB P7J0403 Copper 200 mg/kg dry 5.1 0.46 10 *6010D 10/24/17 17:30 JAB P7J0403 Lead 9.9 mg/kg dry 0.26 0.048 1 *601013 10/23/17 18:28 JAB P7J0403 Magnesium 1500 mg/kg dry 2.6 0.24 1 *6010D 10/24/17 14:37 JAB P7J0403 Magnesium 74 mg/L 0.10 0.0086 1 *6010D 10/25/17 18:21 JAB P7J0494 Molybdenum 6.2 mg/kg dry 0.51 0.015 1 *6010D 10/23/17 18:28 JAB P7J0403 Nickel 9.9 mg/kg dry 0.61 0.018 1 *6010D 10/23/17 18:28 JAB P7J0403 Potassium 1600 mg/kg dry 130 4.6 10 *6010D 10/24/17 17:30 JAB P7J0403 Selenium 3.0 mg/kg dry 0.51 0.12 1 *6010D 10/23/17 18:28 JAB P7J0403 Sodium 140 B mg/L 50 1.8 100 *6010D 10/26/17 18:16 JAB P7J0494 Sodium 760 mg/kg dry 15 0.50 1 *6010D 10/24/17 14:37 JAB P7J0403 Zinc 440 mg/kg dry 26 0.92 10 *6010D 10/24/17 17:30 JAB P7J0403 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 14 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final Date/Time 7100308-01 P7J0334 0.05 g 25 mL 10/19/17 10:15 Prep Method: SM4500-NH3 B Lab Number Batch Initial Final Date/Time 7100308-01 P7J0591 1 g 50 mL 10/31/17 14:10 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 7100308-01 P7J0482 30 g 30 g 10/24/17 15:25 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 7100308-01 137J0321 100 g 2000 mL 10/18/17 14:35 7100308-01 P7J0535 12.5 g 250 mL 10/26/17 16:00 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7100308-01 P7J0346 10 mL 50 mL 10/19/17 9:25 7100308-01 P7J0346 10 mL 50 mL 10/19/17 9:25 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 7100308-01 P7J0345 20 mL 30 mL 10/19/17 9:35 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 7100308-01 P7J0464 200 mL 10 mL 10/25/17 9:03 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 7100308-01 P7J0471 200 mL 1 mL 10/25/17 11:00 Prep Method: 6030B Lab Number Batch Initial Final Date/Time 7100308-01 P7J0597 1 mL 10 mL 10/31/17 9:21 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 7100308-01 P7J0494 50 mL 50 mL 10/25/17 13:35 7100308-01 P7J0494 50 mL 50 mL 10/25/17 13:35 7100308-01 P7J0494 50 mL 50 mL 10/25/17 13:35 Prep Method: 3050B Lab Number Batch Initial Final Date/Time 7100308-01 P7J0403 2.05 g 50 mL 10/23/17 8:55 7100308-01 P7J0403 2.05 g 50 mL 10/23/17 8:55 7100308-01 137J0403 2.05 g 50 mL 10/23/17 8:55 7100308-01 P7J0403 2.05 g 50 mL 10/23/17 8:55 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 6 of 14 Sample Extraction Data Prep Method: 7471B Lab Number Batch Initial Final Date/Time 7100308-01 P7J0282 0.59 g 50 mL 10/17/17 9:30 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 7100308-01 P7J0422 250 g 250 g 10/23/17 12:10 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 7100308-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 -Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 7 of 14 s j Full -Service Analytical & f : 1 M I Environmental Solutions . _..,..,. ...._ 1-4eOFATORIES, INC. 449 Springbrook Road ^ Charlotte, NC 28217 Phone 7041529-6364 Fax: 7041525-0409 Client Company Name: -T-0 MAV ct— MWUA1 k- Report To/Contact Name: _ I Reporting Address: ?-0 flZc m®diled'A\e, Mc. "III CHAIN ®F CUSTODY RECORD PAGE OF - QUOTE # TO ENSURE SsP��ROPS ILLING: Project Name: IDS A-rN 4 S I Short Hold Analysis: es (No) UST Project: S NO 'Please ATTACH any project specific reporting (QC LEV I 1 III IV) provisions and/or QC Requirements Invoice To: Mkh- Op- MIN - Address: Phone: ^�' A --W b®—a20V Fax (Yes) (No): Purchase Order No./Billing Reference Email Address: 6 8 Tft Q 'Z ^ rADWWA4 if%e .a I& TO BE FILLS® IN BY CLIENT/SAMPLING PERSONNEL a Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification, NELAC ®®® FL IVC�_ EDD Type: PDF_Excel_Other yp Rush Work Must Be "Working Days" ❑ 6-9 Days ❑Standard 10 days ❑ Pre -Approved SC OTHER N/A Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Water Chlorinated: YES_ NO — RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES NO CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PR - ': ANALYSIS R UES D REMARKS PRISM "TYPE NO. size SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR TIVES TIVES ®� ` v ID NO. HOURS SLUDGE) SEE BELOW �o ��q O'k 0, '1 K. 0.. Sampler's Signature �s Sampled By (Print Name)!P� Affiliation a• Upon relinquishing, this Chain of bustody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been Initialized. 1 ° Rel' is d By: Signature c nature) MilltarylHours �� Received By: Date �®�t Additional Commerits: SlteArnv2fTime �I�yvu..� 9 ReVic0shed By: (Sig tur) Received By: ( Ignature) Date :Site;D:e(�aiture Ti.me..., Relinquished By: nature) Received For is La 9iatories By: l/ Date Fiyld Tech Fee: / 1 1--• •_ (.-�...._. i Method Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED �11� ��..,�fl" f � /_.J�®1 �s'i�V® �oC Mileage. 'i, r!I/� SHUT WITH CU TOD E L FOR O of I N TO THE LABORATORY. CDC Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RE ENED AT THE LAB RATORY. a 7A ❑ Fed Ex ❑ UPS ❑ Hand -delivered XPrism Field Service ❑ Other NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA. CLANDFILL OTHER:: ❑NOL3 ❑❑NC ❑SC LlNO ❑SC ❑❑NC ®ERCLA El I ❑❑NC El QNC❑SC NO ❑SC ❑NC ❑SC El ❑SC ❑ "CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) „1 ,;• l �g ISN I Environrnerta! Solutions r�~e <. ... _,. L;a60RATOn1£S, INC. 449 Springbrook Road • Charlotte, NC 28217 Phone 704/529-636+4 • Fax:7041525-0409 Client Company Name: OWK Report To/Contact Name: d Reporting Address: .0 b A91 �u t kZ a4f A _ K "',,fitp€° sa %� 1 PAQsC-.2— OF QUOTE It TO ENSURE P ®a'aR BILLING: _ Project Name: Short Hold Analysis: s (NO) UST Project: Y ) NO *Please ATTACH any protect specific reporting (QC LEV III III provisions and/or QC Requirements Invoice To: ow, a�'AA Address: Phone:'J0'J—b 0®,'>l=ax (lies) (N®): Purchase Order No./Billing Reference n4t TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: ° WhOongQke. , K Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ® 5 Days Certification: NELAC DOD FL NC EDD !Type: PDF_Excel _Other "Working Days" ❑ 6-9 Days^standard 10 days ® Rush Work Must Be Pre -Approved Site Location Name: Samples received after 14:00 will be processed next business day. Sc OTHER� N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ No (SEE REVERSE FOR TERMS E CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES N® CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- N TpANALYSIS PRISM SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR 'TYPE TIVES ®�� REMARKS LAB HOURS SEE BELOW NO. SIZE �" NO. p �S°LUDGE) ``ID Y U'� l B0 A Sampler's Signature Sampled By (Print Name) L"-e e%A Affiliation Upon relinquishing, this Chain of Custody is your autho6zation for Prism to proceed with the analyses as requested above. Any changes must be 1, � � t p, am submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized.�c sXs Relin uished By: ( ignature) Received • Signature Date Military/Hours ,,- Additional Comments: S «/ rrival Tme� WV Relin ui ed y: (Signet re) Received By: (Signature) Date �+i4 '' SItF Depantge Time.- - Relinquished By: (Signature) i`j Received F Pri m L oratorie By, jjD/ate _ r I � D :Field `'ech ee �QV��_ i �11>leage Method of Shipment NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH �CUST LS FORT S O ATION TO THE LABORATORY. COC Group No SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTILi ECEIVED AT TH LABORATORY.��,,�� AA l 71 o ❑ Fed Ex ❑ UPS ❑ Hand -delivered Prism Field Service ❑ Other NPDES: I UST: GRO NDINATER: ®RINKING@WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: ®CBI ' ❑NC❑SC ❑NC ❑SC ❑NC CIS ❑NC ❑SC ❑NC ❑SC ❑NC®SC ❑NC ❑SC ®NC ❑SC ❑NC ®SC *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) AI` E 5 tip_ ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECTID 7100308 LABORATORY REPORT NUMBER 171OF58 Primate Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: DATE October 24, 2017 Secondary Data Review By Ashley Amick Project Manager, Access Analytical aamick@axs-ine.com Unless otherwise noted, all analysis on this report performed atAnalytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCIDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page I Page 10 of 14 a ,z ~ se Full -Service Analytical & e Environmental Solutions I M I LABORANRtES, ING SUBCONTRACT ORDER Celtificat' n: NELAC_ I SACE_ Prism Laboratories, Inc. N V SC_ Other 7100308 N/ SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA Project Manager: Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample JD.-7100308-01 Solid Sampled:10/16/1708:19 Herbicides TCLP (Sub) 10/23/17 08:19 Containers Supplied; Lf1k e6 -1, • c i co -1? -0 4-1 Released By Date Received By Date Page 1 of 1 Page I Page 11 of 14 Analytical Environmental Services, Inc Date: 24-Oct-17 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 171OF58 Tag Number: 7100308-01 Project Name: 7100308 Collection Date: 10/16/2017 8:19:00 AM Lab ID: 171OF58-OOIA Matrix: Solid Analyses y Result Qual NNiDL Reporting Units I3atch7D DF Date Analyzed Analyst Limit HERBICIDES, TCLP SW1311/3151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.030 0.20 mg/L 250150 1 10/20/2017 18:14 EI 2,4-D BRL 0.051 0.20 mg/L 250150 1 10/20/2017 18:14 El Surr: DCAA 77.4 0 50.1-132 %REC 250150 1 10/20/2017 18:14 EI Qualifiers: Value exceeds maximum contaminant level BRL Not Detected at MDL H Holding times for preparation or analysis exceeded N "alyte not NELAC certified B Analyte detected in the associated method blank E Estimated value above quantitation range S Spike Recovery outside limits due to matrix > Greater than Result value Estimated value detected below Reporting Limit < Less than Result value Page Page 12 of 14 ANALYTfCAL `: ENVIRON6IENTAL ES SERVICES, INC. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc 2. Carrier: FedEx Q UPS ❑ USPS❑ Client Courier❑ Othei 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Clear Save a, , AES Work Order Number: 171OF58 Shipping container/cooler received in good condition? ©` - - damaged ❑ leaking ❑ other❑ w u nnencs Custody seals present on shipping container? .o. Custody seals intact on shipping container? o. Temperature blanks present? ®.. Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature Cooling initiated for recently collected samples / ice recordings.] present ❑ Chain of Custody (COC) present? o, Chain of Custody signed, dated, and timed when relinquished and received? o Sampler name and/or signature on COC? ®, Signed and dated. Were all samples received within holding time? �j TAT marked on the COC? e If no TAT indicated, proceeded with standard TAT per Terms & Conditions. Q 13. Cooler 1 Temperature 1.1 14. Cooler 5 Temperature 1S. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). AU 10/17/17 checked at Sample Receipt. yes Mn N/A °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C cc Cooler 6 Temperature °C Cooler 7 Temperature cc Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). TR 10/17/17 Were sample containers intact upon receipt? wuunen[s Custody seals present on sample containers? o• Custody seals intact on sample containers? 0, Do sample container labels match the COC? (D 0 0 incomplete info ❑ illegible ❑ no label ❑ other ❑ . Are analyses requested indicated on the COC? o. Were all of the samples listed on the COC received? 0 C 0 samples received but not listed on COC ❑ samples listed on COC not received ❑ Was the sample collection date/time noted? o: Did we receive sufficient sample volume for indicated analyses? 0 Were samples received in appropriate containers? o. Were VOA samples received without headspace (< 1/4" bubble)? m, Were trip blanks submitted? ®` listed on COC ❑ not listed on COC ❑ tea. nave containers neeamg cnemical preservation been checked? * f -D 29. Containers meet preservation guidelines? 0) 30. Was pH adjusted at Sample Receipt? ®, (D ' Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as CDliforms, VOCs and Oil & Grease/TPH. W I certify that I have completed sections 28-30 (dated initials). Oh Checklist 6.9.17 Rev 2 Locked t' s AU 10/17/17 Page 4 of 5 Analytical )Environmental Services, Inc Client: Prism Laboratories Project Nance: 7100308 Workorder: 171 OP58 Date: 24-Oct-17 ANALYTICAL QC SUMMARY REPORT BatchIlD: 250150 Sample ID: rvIB-250150 Client ID: Units: mg/L Prep Date: 10/19/2017 Run No: 354929 SampleType: N1BLK TestCode: HERBICIDES, TCLP SWI311/8151A BatchID: 250150 Analysis Date: 10/2012017 Seq No: 7813977 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.2823 0 0.5000 56.5 50.1 132 Sample ID: LCS-250150 Client ID: Units: ing/L Prep Date: 10/19/2017 Run No: 354929 SampleType: LCS TestCode: HERBICIDES, TCLP Sw1311/8151A BatchID: 250150 Analysis Date: 10/20/2017 Seq No: 7813978 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.3524 0.20 0.5000 70.5 50.7 117 2,4-D 0.4362 0.20 0.5000 87.2 50.1 119 Surr: DCAA 0.3768 0 0.5000 75.4 50.1 132 2,4,5-TP (Silvex) 0.3652 0.20 0.5000 73.0 46.3 126 2,4-D 0.4465 0.20 0,5000 89.3 43.3 132 Surr: DCAA 0.4489 0 0.5000 89.8 50.1 132 B Analyte detected in die associated method blank Qualir-r : > Greater than Result value < Less than Resultvalue (T (D BRL Below re ortinb limit ! E Estimated (value above quantization range) H Holding times for preparation or analysis exceeded I Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside limits due to matrix O Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix A Page 5 of 5 ROCKY RIVER W.W.T.P TELEPHONE (704) 662-8470 Town of Mooresville FAX (704) 662-8473 NORTH CAROLINA POST OFFICE BOX 878 MOORESVILLE, NC 28115 NCDENR-DWQ Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699 O1/26/17 RECEIVEDINCDENRIDWR EB 13 2017 Subject: 2016 Annual Sludge Report, WQ0036723 Distribution of Class A Residuals Following is the information requested to accompany our Class "A" Annual report. 1) Facility - Rocky River Wastewater Treatment Facility 369 Johnson Dairy Rd. Mooresville, N.C. 28115 Phone: 704-662-8470 2) Responsible official and facility contact — Tom Wynn, Biosolids Coordinator P.O. BOX 878 Mooresville, NC 28115 Phone: 704-799-4054 WQROS MOORESVILLE REGIONAL OFFICE 3) Class "A" dried biosolids were distributed under Town of Mooresville permit 4 WQ0036723 4) (Part A) and (Part B) Distribution of Class "A" Residuals for 2016 were transported to, NCDA & CS Piedmont Research Station (SSUID 001), Water & Sewer Authority of Cabarrus County (SSUID 002), and CMS Landfill ( SSUID 003) Total tons = 485.6 (See Attached Hauling Summary Sheets). Laboratory data from quarterly TCLP analyses have been included in this report. 5) (Part C) I certify, under penalty of law that the above information is, to the best of my knowledge and belief, true and accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. - p Prepared by: Tom E. Wynn, Biosolids Coordinator Sign e• Z '0- t 7 Date Reviewed by: Jamie Levis, Envir. Compliance Supervisor Signature / , J 7 Date Town of Mooresville 2016 Hauling'Summary Sheet DATE TONS TRANSPORTER DESTINATION COMMENTS 4/22/2016 27.6 SYNAGRO BFI LANDFILL 4/23/2016 20.6 SYNAGRO BFI LANDFILL 4/25/2016 79.9 SYNAGRO BFI LANDFILL 7/20/2016 125.4 SYNAGRO BFI LANDFILL 10 loads 7/21/2016 40.2 SYNAGRO BFI LANDFILL 3 loads 8/11/2016 9.2 SYNAGRO WSACC Water Sewer Authority Cabarrus Co. 8/12/2016 8.7 SYNAGRO WSACC 8/29/2016 3.6 Town of Mooresville WSACC 9/9/2016 16.1 SYNAGRO WSACC 2loads 9/13/2016 17.0 SYNAGRO WSACC 2loads 9/14/2016 7.7 SYNAGRO WSACC 9/20/2016 16.1 SYNAGRO WSACC 2loads 10/7/2016 7.3 SYNAGRO WSACC 10/8/2016 9.1 SYNAGRO WSACC 10/20/2016 15.6 SYNAGRO WSACC 2loads 10/22/2016 8.1 SYNAGRO WSACC 10/28/2016 17.1 SYNAGRO WSACC 2loads 11/4/2016 17.3 SYNAGRO WSACC 2loads 11/8/2016 18.2 SYNAGRO WSACC 2loads 12/28/2016 20.8 NC Depf Agar- NC Dept Agr 2 loads I U I AL 485. b 2G• 8 M LABORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 VA Certification No. 460211 DoD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307 Project: Class A Dried Sludge Lab Submittal Date: 01/11/2016 Prism Work Order: 6010158 Case Narrative 01/27/2016 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager A Analyzed outside of hold time. BH MB greater than one half of the RL, but the sample concentrations are greater than 10x the MB. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525.0409 Page 1 of 9 PR I V n � Full -Service Analytical ' V � Environmental Solutions __ LABORATORIES.INC. Sample Receipt Summary 01 /27/2016 Prism Work Order: 6010158 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 6010158-01 Solid 01/11/16 01/11/16 Samples were received in good condition at 5.3 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 9 Full -Service Analytical & PR I S Environmental Solutions ' - LABORATORIES,Wa Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid ort !'�rlif C'/hCv�kq�a 2016 _ _.,omits. Parameter Result . Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters l Plant Available Nitrogen 9100 mg/kg 1600 600 20 Calculation 1/18/16 11:40 CLB ICALCj % Solids 96.4 % by 0.100 0.100 1 *SM2540 G 1/20/16 15:42 JLB P6A0313 Weight Nitrate/Nitrite as N 5.2 mg/kg dry 6.2 0.67 1 *SM4500-NO3 F 1/14/16 10:31 CLB P6A0178 pH 6.1 pH Units 1 *9045D 1/16116 12:63 EGC P6A0228 Phosphorus -Total 12000 mg/kg dry 260 67 100 *SM4500-P F 1/20/16 8:49 CLB P6A0253 Total Kjeldahl Nitrogen 30000 mg/kg dry 5200 2100 20 *351.2 1M5/16 11:36 CLB P6A0187 Ammonia as N 7 2100 mg/kg dry 100 23 20 *SM4500-NH3 G 1/18/16 11:40 CLB P6A0222 Microbiological Parameters Fecal Coliforms BRLA MPN/g dry 1 1 *SM9221 E 1/12/16 9:25 EGC P6A0175 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 *1311 ZHE 1/19/16 9:00 ANG P6A0249 TCLP Extraction Complete N/A 1 *1311 1/20/16 7:00 JAB P6A0264 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 1/20/16 13:40 JAB P6A0281 Arsenic BRL mg/L 0.050 0.0035 1 *6010C 1120/16 18:15 bgm P6A0289 Barium BRL mg/L 5.0 0.0035 1 *6010C 1/20/16 18:15 bgm P6A0289 Cadmium BRL mg/L 0.025 0.00050 1 *6010C 1/20/16 18:15 bgm P6A0289 Chromium BRL mg/L 0.25 0.0030 1 *6010C 1/20/16 18:15 bgm P6A0289 Lead BRL mg/L 0.050 0.0065 1 *6010C 1/20/16 18:15 bgm P6A0289 Selenium BRL mg/L 0.10 0.016 1 *6010C 1/20/16 18:15 bgm P6A0289 Silver BRL mg/L 0.25 0.0010 1 *6010C 1/20/16 18:15 bgm P6A0289 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.00034 1 *8081B 1/21/16 13:29 JMC P6A0262 Dieldrin BRL mg/L 0.00050 0.000022 1 *8081B 1/21/16 13:29 JMC P6A0262 Endrin BRL mg/L 0.00050 0.000020 1 *8081B 1/21/16 13:29 JMC P6A0262 gamma-BHC BRL mg/L 0.00050 0.000013 1 *8081B 1/21/16 13:29 JMC P6A0262 Heptachlor BRL mg/L 0.00050 0.000015 1 *8081B 1/21/16 13:29 JMC P6A0262 Heptachlor Epoxide BRL mg/L 0.00050 0.000018 1 *8081B 1/21/16 13:29 JMC P6A0262 Methoxychlor BRL mg/L 0.00050 0.000033 1 *8081B 1/21/16 13:29 JMC P6A0262 Toxaphene BRL mg/L 0.025 0.00016 1 *8081 B 1/21/16 13:29 JMC P6A0262 Surrogate Recovery Control Limits Decachlorobiphenyl 38 % 13-186 Tetrachloro-m-xylene 34 % 40-134 SE TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0023 1 *8270D 1/25/16 18:45 JMV P6A0290 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0026 1 *8270D 1/25/16 18:45 JMV P6A0290 2,4-Dinitrotoluene BRL mg/L 0.050 0.0019 1 *8270D 1/25/16 18:45 JMV P6A0290 2-Methylphenol BRL mg/L 0.050 0.0021 1 *8270D 1/25/16 18:45 JMV P6A0290 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 3 of 9 p Full -Service Analytical & P R I S Environmental Solutions l _ . -.. .-rr"�LABORATOFIES ING Laboratory Report 01/27/2016 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 6010158-01 P. O. Box 878 Prism Work Order: 6010158 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 01/11/16 07:30 Time Submitted: 01/11/16 16:30 - - Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methylphenol BRL mg/L 0.050 0.0019 1 *8270D 1/25/16 18:45 JMV P6A0290 Hexachlorobenzene BRL mg/L 0.050 0.0019 1 *8270D 1/25/16 18:45 JMV P6A0290 Hexachlorobutadiene BRL mg/L 0.050 0.0026 1 *8270D 1/25/16 18:45 JMV P6A0290 Hexachloroethane BRL mg/L 0.050 0.0025 1 *8270D 1/25116 18:45 JMV P6A0290 Nitrobenzene BRL mg/L 0.050 0.0024 1 *8270D 1/25/16 18:45 JMV P6A0290 Pentachlorophenol BRL mg/L 0.25 0.0025 1 *8270D 1/25/16 18:45 JMV P6A0290 Pyridine BRL mg/L 0.25 0.0021 1 *8270D 1/25/16 18:45 JMV P6A0290 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 40 % 43-140 SE 2-Fluorobiphenyl 42 % 44-119 SE 2-Fluorophenol 17 % 19-119 SE Nitrobenzene-d5 44 % 44-120 Phenol-d5 12 % 11-52 TerphenyW14 47 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *826013 1/19/16 16:28 KDM P6A0275 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 *826013 1/19/16 16:28 KDM P6A0275 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *826013 1/19/16 16:28 KDM P6A0275 Benzene BRL mg/L 0.025 0.00048 1 *8260B 1/19/16 16:28 KDM P6A0275 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *826013 1/19/16 16:28 KDM P6A0275 Chlorobenzene BRL mg/L 5.0 0.00062 1 *826013 1/19/16 16:28 KDM P6A0275 Chloroform BRL mg/L 0.30 0.00076 1 *8260B 1/19/16 16:28 KDM P6A0275 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *8260B 1/19/16 16:28 KDM P6A0275 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *8260B 1/19/16 16:28 KDM P6A0275 Trichloroethylene BRL mg/L 0.025 0.00079 1 *8260B. 1/19/16 16:28 KDM P6A0275 Vinyl chloride BRL mg/L 0.020 0.00097 1 *8260B 1/19/16 16:28 KDM P6A0275 • Surrogate Recovery Control Limits 4-Bromofluorobenzene 91 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 94 % 77-123 Total Metals Aluminum 11000 mg/kg dry 26 3.5 10 *6010C 1/18116 19:27 bgm P6A0189 Mercury' 0.66' mg/kg dry 0.062 0.0040 3 *7471B 1114/16 12:12 JAB P6A0190 SAR Soil Preparation Complete g 1 *2-78-054 1/20/16 8:30 JAB P6A0288 SAR Percent Moisture 81.6 % by 0.100 0.100 1 *2-78-054 1/20/16 8:40 JAB P6A0383 Weight Arsenic 2.6 mg/kg dry 2.6 0.58 10 *6010C 1/18/16 19:27 bgm P6A0189 Sodium Absorption Ratio 1.3 [blank] 0.30 0.016 1 `2-78-054 1/20/16 18:54 bgm P6A0287 Cadmium 0.29 mg/kg dry 0.26 0.0056 1 *6010C 1116/16 20:10 bgm P6A0189 Calcium 110 BH mg/L 1.0 0.085 10 *6010C 1/20/16 18:54 bgm 126A0287 Calcium 9500 mg/kg dry 100 6.7 10 *6010C 1/18/16 19:27 bgm P6A0189 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/525-0409 Page 4 of 9 Laboratory Report Full -Service Analytical & �I Environmental : LAEOR TORIES, INC. Solutions 01/27/2016 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 6010158-01 P. O. Box 878 Prism Work Order: 6010158 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 01/11/16 07:30 Time Submitted: 01/11/16 16:30 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Copper 160 mg/kg dry 5.2 0.90 10 *6010C 1118/16 19:27 bgm P6A0189 Lead 8.0 mg/kg dry 0.26 0.027 1 *6010C 1/16116 20:10 bgm P6A0189 Magnesium 1900 mg/kg dry 26 2.8 10 *6010C 1/18/16 19:27 bgm P6A0189 Magnesium 61 mg/L 1.0 0.0070 10 *6010C 1/20/16 18:54 bgm P6A0287 Molybdenum 4.5 mg/kg dry 0.52 0.023 1 *6010C 1/16116 2DA0 bgm P6A0189 Nickel 9.5 mg/kg dry 0.52 0.049 1 *6010C 1/16116 20:10 bgm P6A0189 Potassium 3100 mg/kg dry 130 13 10 *6010C 1/18/16 19:27 bgm P6A0189 Selenium 6.6 mg/kg dry 5.2 0.38 10 *6010C 1118/16 19:27 bgm P6A0189 Sodium 560 mg/kg dry 160 4.6 10 *6010C 1/18/16 19:27 bgm P6A0189 Sodium 67 mg/L 6.0 0.074 10 *6010C 1120/16 18:54 bgm P6A0287 Zinc 310 mg/kg dry 26 0.32 10 *6010C 1/18/16 19:27 bgm P6A0189 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 5 of 9 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final Date/Time 6010158-01 P6A0187 0.05 g 25 mL 01/14/16 11:00 Prep Method: SM4500-PB5 Lab Number Batch Initial Final Date/Time 6010158-01 P6A0253 1 g 50 mL 01/19/16 11:30 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 1 6010158-01 P6A0313 30 g 30 g 01/20/16 15:42 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 6010158-01 P6A0249 25 g 500 mL 01/18/16 16:00 6010158-01 P6A0264 100 g 2000 mL 01/19/16 14:10 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6010158-01 P6A0289 10 mL 50 mL 01/20/16 11:45 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 6010158-01 P6A0281 20 mL 30 mL 01/20/16 8:30 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 6010158-01 P6A0262 200 mL 10 mL 01/20/16 12:45 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 6010158-01 P6A0290 200 mL 1 mL 01/21/16 8:45 Prep Method: 6030E Lab Number Batch Initial Final Date/Time 6010158-01 P6A0275 1 mL 10 mL 01/19/16 8:54 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6010158-01 P6A0287 50 mL 50 mL 01/20/16 8:30 6010158-01 P6A0287 50 mL 50 mL 01/20/16 8:30 Prep Method: 3050E Lab Number Batch Initial Final Date/Time 6010158-01 P6A0189 2 g 50 mL 01/14/16 8:30 6010158-01 P6A0189 2 g 50 mL 01/14/16 8:30 Prep Method:7471B Lab Number Batch Initial Final Date/Time I 6010158-01 III P6A0190 0.6 g 50 mL 01/14/16 9:00 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 6 of 9 Sample Extraction Data Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 6010158-01 P6A0288 250 g 250 g 01/19/16 8:30 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 6010158-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041626-0409 Page 7 Of 9 ""''PRISM Full -Service Analytical & -' Environmental Solutions -LABORATORIES. INC. 449 Springbrook Road • Charlotte, NC 26217 Phone 7041529-6364 Fax: 704/525-0409 Client Company Name: eL M Lf�d Report To/Contact Name: UT) Mt. A' Vd i l� Reporting Address: , bDA- wCi&mi� VCR 1 1S Phone:'''(-Q, )-.-.3-22(�) Fax (Yes) (No): Email Address: 0jy`tU-)r_0C�(r MOD-?54. k1C its EDD Type: PDF L/ Excel Other. Site Location Name: Site Location Physical Address: TIME CLIENT DATE COLLECTED SAMPLE DESCRIPTION COLLECTED. MILITARY HOURS p jq MATRIX (SOIL, WATER OR SLUDGE) CHAIN OF CUSTODY RECORD , • PAGEOF OUO4E N YO ENSURE PROPER 616LING: ' YF$ NO N/A ' 137 Samples IWACT upon arrival?. c/ O Project Name: CJ S YT ri Cc I L4 v Recelved oPV WET ICES 00 Short Hold Analysis: �) (NO) UST Project"'(Yes) O PROPER PRESERVATIVES IrdlCat d� �_ — - IC *Please ATTACH any p ct specific reporting (QC LEV_E[vl"11 III IV Received WITHIN HOLDING TI�Ata a provisions and/or QC Requirements C.USTODY;SEALS INTACT? __ Invoice To: ► u>tiL1 b �= M ! oe� i� VOLATILES.roc d N1rt1UT tiEADSPACE? _ PROPER CONTAINERS used Address: TEMP:'. Therm ID'_ Observed: �1-�; °O Cor-5 °C, Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Requested Due Date ❑ 1 Day ❑ 2 Days El Days ❑ 4 Days ❑ 5 Days Certification: NELAC DOD FL NC it "Working Days" ❑ 6-9 Days�Standard 10 days ❑ Pre-ApprovedhWrk Must Be SC OTHER N/A Samples received after 14:00 will be processed next business day. Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ N® (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES •'✓NO_ SAMPLE CONTAINER ANALYSIS REQUESTED PRESERVA- PRISM *TYPE TIVES ,� ,° a �s, rlc / REMARKS LAB SEE BELOW NO. SIZE ID NO. 4 Sampler's Signature I e ! : rJ� r� Sampled By (Print Name),?) �P) LF L/n�,Le Affiliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. R linquished By: (Signature) R rued By: (Signature Date Military/Hours r'rti�v elinquis d By (S' nature) Recelved By: (Signatup) Dale 310 Relinqu hed By: (Signs e) 1 ed Fot Pris aboralories By: Dat Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTO Y SEALS FOR TRANSPORTATION TO THE LABORATORY. C C Graup No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL R CEIVED AT THE LABORATORY. ❑ Fed Ex ❑ UPS ❑ Hand -delivered Ir sm Field Service ❑ Other N� UST: GROUNDWATER: DRINKING WATER: SOLID ❑SCE ❑ R ❑ SC ❑ NC L❑ SC ❑ LANDFILL SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC Ell — El — LI El — [ L3 — L3 — L3 _� 0 El *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Additional Comments: J'Ct. r ,vi)1/SiimI Ski 47 0/ o40 McK.;rk F Site Arrival Time: Site Departure Time:: . Field Tech Fee: Mileage: �� tJr I' i` Ai.. CHAIN OF CUSTODY RECORD Fu!!-Service Analytical & I S Environmental Solutions PAGE! OF � QUOTE # TO ENSURE PROPER BILLING: M I LABORATORMS, I VC. 449 Springbrook Road - Charlotte, NC 28217 Project Name: l� Ga t-, • cZ Phone 704/529.6364 •Fax: 7041525-0409 Short Hold Analysis: (!e) (No) UST Proj® t: (yes) O �' tla.-c' as l � *Please ATTACH any project specific reporting (QC LEVEg011 111 1 Client CompanyName: provisions and/or QC Requirements Report To/Contact Name: '+ ti.v ,�IG✓tY�� 7 ^ Invoice To: Gmt;,.� a% /VEyseA'y")t: i �. Reporting Address: . e )% Xc Address: on- agI15- Phone: Fax (Yes) (No): Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: 111 '' dL4,+` a Yet %a? u'(Irti EIC5 Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC DOD FL NC EDD Type: PDF L Excel Other "Working Days" ❑ 6-9 Days Siandard 10 days ❑ Rush work Must Be SC OTHER NIA Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO� (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES YES Sl@ Iced U On COII@C$lon: r^' iV® RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sampie p TIME MATRIX SAMPLE CONTAINER ANALYSIS R&QUES7413 CLIENT DATE COLLECTED (SOIL, PRESERVA- y �` -�i PRISM `t `, -. REMARKS LAB SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR *TYPE NO. SIZE TIVES . ID NO. HOURS SLUDGE) SEE BELOW I IF \,y l�° 3 ,. Sampler's Signature � � o �- Sampled By (Print Name) / �� / � a�e�—��-� Affiliation Upon relinquishing, this Chain of Custody is our authorization for Prism to proceed with the analyses as requested above. An changes must be q 9r Y Y P Y q Y 9 submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Relinquisryhed B : (Signature) �I 1 Re eiv tl By; Si t t Military/Hours Additional Comments Site An+ua.l Time 7 �� W Relinquis d By: (Signat Gj Received By: (Sign ure) Date Jd t Site DO)7artUre Tlrt3e Al( A—s/ 0.al/ 1 itid Tech Fee Relinq ' e By: (Signatur _ Rec . -For Pri aboratories By: Date A� YN/ 7 ° Jq V1ticaae '' Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTO Y SEALS FOR TRANSPORTATION TO THE LABORATORY. COO Group No.��a SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL R CEIVED AT THE LABORATORY. ❑ Fed Ex ❑ UPS ❑ Hand -delivered rism Field Service ❑ Other TER. ATER. A LANDFILL OTHER: L❑ NC❑SC❑ ❑ NC ❑ CNG ❑ NC ❑ SC ❑ NI.0 ❑ SC ❑ NC ❑ SCIAS�011) ❑SCWASTE ❑ NC SC NC El SC ® NC ❑ SC ❑ rI ❑ ❑ *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) I Im T 'LABORATORIES, INC, Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cart No. 37735 VA Certification No. 460211 DOD ELAP: L-A-B Accredited Certificate No. L2307 ISO/IEC 17025: L-A-B Accredited Certificate No. L2307 Project: Class A Dried Sludge Lab Submittal Date: 04/18/2016 Prism Work Order: 6040352 Case Narrative 05/06/2016 This data package contains the analytical results for the project identified above and includes a Case Narrative,_ Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager B Analyte is found in the associated blank at a concentration >1/2 RL. BH MB greater than one half of the RL, but the sample concentrations are greater than 1 Ox the MB. CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. MC Sample concentration. too high for recovery evaluation. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041626-0409 Page 1 Of 16 �i� I n %� Full -Service Analytical ' V' Environmental Solutions .SAT 7' L BOFATOFIES ING Sample Receipt Summary 05/06/2016 Prism Work Order: 6040352 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 6040352-01 Solid 04/18/,16 04/18/16 Samples were received in good condition at 4.2 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 16 iiirrrggq Laboratory Report I Analytical & --- _ Environmental Solutions 05/06/Full-Service _ , _-_ --_ _-- -� 6/2016 LABOHATOBIEa ING - _ ---- Q o Town of Mooresville/RR VWVTP Project: Class A Dried Sludge p J Attn: Whitney Munroe P. O. Box 878 R I Mooresville, NC 28115 Sample Matrix: Solid q P Dilution- mleillu, Parameter Result Units Report MDL Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 16000 mg/kg 3000 360 40 *Calculation 5/2116 11:32 CLB ICALCI % Solids 96.7 % by 0.100 0.100 1 *SM2540 G 4/21/16 10:34 SLS P6D0374 Weight Nitrate/Nitrite as N BRL mg/kg dry 5.2 0.57 1 *SM4500-NO3 F 4/22/16 8:43 CLB P6D0398 pH 6.4 pH Units 1 *9045D 4/21116 10:59 EGC P6130382 Phosphorus -Total 11000 mg/kg dry 260 120 100 *SM4500-P F 4/29/16 6:29 CLB P6D0452 Total Kjeldahl Nitrogen 55000 mg/kg dry 10000 1200 40 *361.2 5/2/16 11:32 CLB 1300528 Ammonia as N 2900 mg/kg dry 100 40 20 *SM4500-NH3 G 4/21/16 8:13 CLB P6100335 Microbiological Parameters Fecal Coliforms TCLP Extraction by EPA 1311 0.4 MPN/g dry 0.2 1 *SM9221 E 4/18/16 13:00 EGC PSD0317 TCLP Extraction Complete N/A 1 *1311 4/22116 7:15 JAB P6D0389 TCLP Extraction Complete N/A 1 *1311 ZHE 4/22/16 8:00 ANG P6D0392 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 4/22/16 15:19 JAB P6D0406 Arsenic BRL mg/L 0.050 0.0035 1 *6010D 4/22116 21:52 BGM P61)0417 Barium BRL mg/L 5.0 0.0035 1 *6010D 4/22/16 21:52 BGM P6D0417 Cadmium BRL mg/L 0.025 0.00050 1 *6010D 4/22/16 21:52 BGM P6D0417 Chromium BRL mg/L 0.25 0.0030 1 *6010D 4/22/16 21:52 BGM P6D0417 Lead BRL mg/L 0.050 0.0065 1 *6010D 4/22116 21:52 BGM P6D0417 Selenium BRL mg/L 0.10 0.016 1 *6010D 4/22/16 21:52 BGM P6D0417 Silver BRL mg/L 0.25 0.0010 1 *6010D 4122/16 21:52 BGM P6D0417 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.000094 1 *8081B 4126/16 13:50 JMC P6D0463 Dieldrin BRL mg/L 0.00050 0.00011 5 *8081B 4/27116 10:42 JMC P6D0463 Endrin BRL mg/L 0.00050 0.00010 5 *8081B 4/27/16 10:42 JMC P6D0463 gamma-BHC BRL mg/L 0.00050 0.000065 5 *8081B 4/27/16 10:42 JMC P6D0463 Heptachlor BRL mg/L 0.00050 0.000075 5 *808113 4/27/16 10:42 JMC P6D0463 Heptachlor Epoxide BRL mg/L 0.00050 0.000090 5 *8081B 4/27/16 10:42 JMC P6D0463 Methoxychlor BRLCCV mg/L 0.00050 0.00016 5 *8081B 4/27/16 10:42 JMC P6D0463 Toxaphene BRLCCV mg/L 0.025 0.00032 1 *8081B 4/26/16 13:50 JMC P6D0463 Surrogate Recovery Control Limits Decachlorobiphenyl 50 % 13-186 Tetrachloro-m-xylene 51 % 40-134 TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0023 1 *8270D 4/27/16 0:47 JMV P6D0471 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0026 1 *8270D 4/27/16 0:47 JMV P6D0471 2,4-Dinitrotoluene BRL mg/L 0.050 0.0019 1 *8270D 4/27/16 0:47 JMV P6D0471 2-Methylphenol BRL mg/L 0.050 0.0021 1 *8270D 4/27/16 0:47 JMV P6D0471 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 16 iRI S M A Full -Service Analytical '�1 Environmental Solutions iI / I.O.ATORIE$ INO Town of Mooresville/RR VWVTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 05/06/2016 Client Sample ID: Class A Prism Sample ID: 6040352-01 Prism Work Order: 6040352 Time Collected: 04/18/16 08:00 Time Submitted: 04/18/16 12:44 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methylphenol 0.21 mg/L Hexachlorobenzene BRL mg/L Hexachlorobutadiene BRL mg/L Hexachloroethane BRL mg/L Nitrobenzene BRL mg/L Pentachlorophenol BRL mg/L Pyridine BRL mg/L TCLP Volatile Organic Compounds by GC/MS 0.050 0.0019 1 *8270D 4/27/16 0:47 JMV P61010471 0.050 0.0019 1 *8270D 4/27/16 0:47 JMV P6DO471 0.050 0.0026 1 *8270D 4/27/16 0:47 JMV P6D0471 0.050 0.0025 1 *8270D 4/27/16 0:47 JMV P6D0471 0.050 0.0024 1 *8270D 4/27/16 0:47 JMV P6D0471 0.25 0.0025 1 *8270D 4/27116 0:47 JMV P6D0471 0.25 0.0021 1 *8270D 4/27116 0:47 JMV P6D0471 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 70 % 43-140 2-Fluorobiphenyl 56 % 44-119 2-Fluorophenol 30 % 19-119 Nitrobenzene-d5 56 % 44-120 Phenol-d5 22 % 11-52 Terphenyl-d14 74 % 50-134 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *8260B 4/23/16 23:18 KDM P61)0435 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 *8260B 4/23/16 23:18 KDM P6D0435 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *8260B 4/23/16 23:18 KDM P6D0435 Benzene BRL mg/L 0.025 0.00048 1 *8260B 4/23/16 23:18 KDM P6D0435 . Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *8260B 4/23/16 23:18 KDM P6D0435 Chlorobenzene BRL mg/L 5.0 0.00062 1 *8260B 4/23/16 23:18 KDM P6D0435 Chloroform BRL mg/L 0.30 0.00076 1 *8260B 4/23/16 23:18 KDM P6D0435 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *8260B 4/23/16 23:18 KDM P6D0435 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *8260B 4/23/16 23:18 KDM P6D0435 Trichloroethylene BRL mg/L 0.025 0.00078 1 *8260B 4/23/16 23:18 KDM P6D0435 Vinyl chloride BRL mg/L 0.020 0.00097 1 *8260B 4/23/16 23:18 KDM P6D0435 Surrogate Recovery Control Limits Total Metals 4-Bromofluorobenzene Dibromofluoromethane Toluene-d8 105 % 104 % 92 % 80-124 75-129 77-123 Aluminum * ^ cxc fry 1300 mg/kg dry 260 75 100 *601013 5/3/16 16:14 BGM P6D0381 Mercury BRL mg/kg dry 0.021 0.0012 1 *7471B 4/20/16 12:02 JAB P6D0338 SAR Soil Preparation Complete g 1 *2-78-054 4/26/16 7:30 JAB P6D0519 SAR Percent Moisture 80.1 % by 0.100 0.100 1 *2-78-054 4/28/16 8:40 JAB P6D0529 Weight Arsenic 2.2 mg/kg dry 0.26 0.031 1 *6010D 4/21/16 20:42 bgm P6D0381 Sodium Abs orption Ratio 1.3 [blank) 0.30 0.016 1, *2-787054 5/4/16 0:67 BGM 136130497 Cadmium / 0.51 mg/kg dry 0.26 0.0069 1 *60101) 4/21/16 20:42 - bgm P6D0381 Calcium 12000 mg/kg dry 10 0.24 1 *601011) 4/21/16 20:42 bgm P6D0381 Calcium 190 BH, B mg/L 1.0 0.085 10 *6010D 5/4/16 0:67 BGM P6D0497 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/625-0409 Page 4 of 16 Laboratory Report Full -Service Analytical s 05/06/2016 Environmental Solutions LiB0-Towes, lNa Town of Mooresville/RR VWVTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 6040352-01 P. O. Box 878 Prism Work Order: 6040352 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 04/18/16 08:00 Time Submitted: 04/18/16 12:44 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Copper J B�,H mg/kg dry 51 4.6 100 *6010D 513116 16:14 BGM P6D0381 Lead slid �a„ /�211'0 �8.4�' mg/kg dry 0.26 0.048 1 *6010D 4/21/16 20:42 bgm P6D0381 Magnesium 2100 mg/kg dry 2.6 0.24 1 *6010D 4/21/16 20:42 bgm P6D0381 Magnesium 99 mg/L 1.0 0.0070 10 *6010D 5/4116 0:57 BGM P6D0497 Molybdenum tr 12 mg/kg dry 0.51 0.016 1 *6010D 4/21/16 20:42 bgm P6D0381 Nickel ®�` 9.7 mg/kg dry 0.51 0.018 1 *6010D 4/21/16 20:42 bgm P6D0381 Potassium 2600 mg/kg dry 13 0.46 1 *6010D 4121/16 20:42 bgm P6D0381 Selenium / 6.0 mg/kg dry 0.61 0.12 1 *6010D 4121/16 20:42 bgm P61010381 Sodium 830 mg/kg dry 15 0.50 1 *6010D 4/21116 20:42 bgm P6D0381 Sodium 88 mg/L 6.0 0.074 10 *6010D 5/5/16 0:46 bgm P6D0497 Zinc �- 340 mg/kg dry 260 9.2 100 *6010D 513/16 16:14 BGM P6D0381 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road -,P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 5 of 16 Sample Extraction Data Prep Method: 351.2 Lab Number Batch Initial Final Date/Time 6040352-01 P6D0528 0.05 g 25 mL 04/28/16 11:00 Prep Method: SM4600-PBS Lab Number Batch Initial Final Date/Time 6040352-01 P6D0452 1 g 50 mL 04/25/16 11:38 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 6040352-01 P6D0374 30 g 30 g 04/21/16 10:34 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 6040352-01 P61D0389 100 g 2000 mL 04/21/16 13:50 6040352-01 P6D0392 25 g 500 mL 04/21/16 15:00 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6040352-01 P61)0417 10 mL 50 mL 04/22/16 12:00 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 6040352-01 P61D0406 20 mL 30 mL 04/22/16 8:50 Prep Method: 3610C GC Lab Number Batch Initial Final Date/Time 6040352-01 P6D0463 200 mL 10 mL 04/25/16 12:50 6040352-01 P6D0463 200 mL 10 mL 04/25/16 12:50 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 6040352-01 P61D0471 200 mL 1 mL 04/26/16 9:40 Prep Method: 6030B Lab Number Batch Initial Final Date/Time 6040352-01 P6D0435 1 mL 10 mL 04/22/16 9:20 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6040352-01 P6D0497 50 mL 50 mL 04/26/16 7:30 6040352-01 P6D0497 50 mL 50 mL 04/26/16 7:30 6040352-01 P6D0497 50 mL 50 mL 04/26/16 7:30 Prep Method: 3050E Lab Number Batch Initial Final Date/Time 6040352-01 P6D0381 2.02 g 50 mL 04/21/16 9:50 6040352-01 P61D0381 2.02 g 50 mL 04/21/16 9:50 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/525-0409 Page 6 of 16 Sample Extraction Data Prep Method: 7471B Lab Number Batch Initial Final Date/Time 6040352-01 P6D0338 0.59 g 50 mL 04/20/16 8:05 Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 6040352-01 P6D0519 250 g 250 g 04/25/16 7:30 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 6040352-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 7 of 16 CnMAIN OF CUSTODY RECORD IN Fuil-Ser;icr Analytical Environmental Solutions YEb NO N/A .. ,:'. LABORATORIES, INC. PAGE OF QUOTE 0 TO ENSURE P OPER BILLING: /d 111 Samples INTgCTupon armai? .,_. Q 449 Springbraok Road •Charlotte, NC 28217 Phone 7041529-6364 • Fax: 704/525-0409 Project Name: Gp S.S rf aJ� Short Hold Analysis: (YY) (No) UST Project: (Yes) ( ) Recelyed ON WET PROPER PRESERVATIVES Indicated? 00 a) gg �a `/gg *Please ATTACH any protect specific reporting (QC LEVE h 1 III IV Received N1ITNIN HOLDING TIIVIE�? Client Company Name: ,0 Zy� o JU t3 I G1 `fyV provisions and/or QC Requirements l !i (US10DY SEALS INTACI , '' rl Report To/Contact Name: it •''III Invoice Yo:/ �G�'`Z'�� Lt VOLATILES recd WIOUT HEADSPACEv Reporting Address: P 0_ _�ti� �(,. aS- Address: :PROP.ER-CONTAINERS used? _ 2.0 �RbrlYS'LI(!L'� Ci 11> TENiP ThzrrrilD;_ Observed 7°d or :41 Phone: P"l — 41eV9 Fax (Yes) (No): ., Purchase Order No./Billing Reference I TO BE FILLED IN 13Y CLIENT/SAMPLING PERSONNEL Email Address: Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC ®®® FL NC EDD Type: PDF_Excel Other "Working Days" ❑ 6-9 Days standard 10 days ❑ Pre-ApprovedhWrk Must Be SC OTHER NIA Site Location Name: Samples received after 14:00 will be processed next business day. - Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES NO (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample iced Upon Collection: YES CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- ANALYSIS REQUES ED PRISM • rypE NO. SIZE SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR TfVES y W -� REMARKS ��® LAB ID NO. HOURS SLUDGE) SEE BELOW vLj� Sampler's Signature Sampled By (Print Name) iir b?sd ✓ " Affiliation Upon relinquishing, this Chan of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be chjlgel for any changes after analyses have been initialized. Reli quished By: (Signature) Reeve By: (Sig lure) Da a Mildary/Hours Additional Comments: �. Site Arnval Time - . Relinquished By: (Sign rved B . (' nature) Date ] [1 : Site 602rture Time Relinquished Field Tech Fee It 1 1 °' - ::.. ' = Mltoage: .. Method of Ship L SAMPLE COOLERS SHOULD BE TA T 1 CUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. COC uP N �/�3� SA ES ARE NOT ACCEPTED AND VERIFIED AGAINSC UNTIL RECEIVED AT THE LABORATORY. { ❑ Fe F�c O UP ❑Hand -delivered rrism Field Service ❑Other .1�(� /LI/f,) •�� /%y N E UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: ' NC❑SC El NC ❑SC ❑NC El SC ❑NC El SC I ❑NC ❑SC ❑NC❑SC ❑NC ❑SC ❑NC ❑SC El NC ❑SC *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) { i t Full -Service Analytical & x Environmental Solutions RISM I Sri,. "LABORATORIES, INC. 449 Springbrook Road • Charlotte, NC 28217 Phone 7041529-636 • Fax: 7049/5,25-0409 1, Client Company Name: Report To/Contact Name: VV►� Reporting Address: CHAIN OF CUSTODY RECORD t ,) YFS' NO NIA. (O PAGE _ OP =�®DOTE #1TO ENSURE PROPERR, BILLING: Samples INTACT upon qrnvah � Project Name: G t �Zs "' )1 UGC Received. ON WET Short Hold Analysis: es (No) UST Project: es) O PROPERPRCSERVA7IVES Indicated? _ _ N *Please ATTACH any pr ' ct specific reporting (QC LEVEV 11111 IV) Received WITHIN HQI DING 1IMES, _ provisions and/or QC Requirements CUSTODY.SEALS INTACT? Invoice To: -�6V1_t a� VOLATILES reed OOUT HEADSPACE? Address: PROPELS CONTAINERS used? TEMP: Therm ID.:; 'r' Observed: Phone: 104 — WOO--. aJV Fax (Yes) (No): �. �vi)IrL' Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: tn�1�Iti81rd' ��' 'LiS Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC DOD FL NC t EDD Type: PDF_Excel_Other "Working Days" • 9 6-9 Day�andard 10 days ❑ Rush Work Must Be Pre -Approved SC OTHER NIA Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NOZ (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES l/NO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) I CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESS A = ANALYSIS R' QUES�D REMARKS PRISM LAB *TYPE NO. SIZETIVET SAMPLE DESCRIPTION COLLECTED MILITARY WATER O; . 1 g„ g ID NO. SLUDGE SEE BELOW '4�jHOURS -4 IY il" a:0® SDI +-,r� Sam �t�rr �a �c c - Affiliation Sampler's Signature r. pled By (Print Name) a Upon relinquishing, this Chain of ustody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges:for an changes after analyses have been initialized. Reli uish d By: (Sig alure) Received'8y: (Signa re) Date MililarylHour Additional Comments: Rell q he By: ,(Signa re) R calved By ignature) D to Relinquishe : (Signa re) - beeived For Prism Laboratories By: Dale 4I / �p �a 0-1 Zis lc /27�yx L-J ',µ+apt- / Pbi =13 : NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT wrrH CUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. COG Group No, a / -y l p/ SAMPLES ARE NOTACCEPTED AND VERIFIED AGAINST COG UNTIL RECEIVED AT THE LABORATORY. Not ,/ �� K, � YA ❑ Hand -delivered , Prism Field Service ❑ Other ZA NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: V C❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC❑SC ❑NC ❑SCIO❑ NC ❑SC ❑❑ NC SC *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Site Arrival Time: Site Departure Time: Field Tech Fee: Mileage: ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 6040352 LABORATORY REPORT NUMBER 1604G60 DATE April 27, 2016 Primary Data Review By Secondary Data Review By 6JCPK"AAA-) Chantelle Kanhai Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com. - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 7 Page 10 of 16 . ISM�WO IFuli-service Analytical & E-i Environmental Solutions RATORIES RIG SUBCONTRACT ®ItD]CR Certifi ion •. NELAC_ USACE_ Prisru Laboratories, Inc. trC SC Other 6040352 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc, P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Pax: NA Project Manager: Terri W. Cole Analysis Due Expires Laboratory ID Comments Sample ID: 6040352-01 Solid Sampled:04/18/16 08:00 NS10 - T sl TLCP vol/semi 8260/8270 methods Herbicides TCLP (Sub) 04/25/16 08:00 Contabrers Supplied• K/gall v By Released By Date Received By Date Page 2of7 Released By Date Received By Date Paae 11 of 16 Ana1'1tiCal Environmental Services, Inc Date: 27-Apr-16 Client: Prism Laboratories Project: 6040352 Case Narrative Lab ID: 1604G60 Sample was analyzed for only TCLP Herb, per Angela Martin via email oa 4/21/16. Page 3 of 7 Page 12 of 16 Analytical Environmental Services, Inc Date: 27-Apr-16 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 1604G60 Tag Number: 6040352-01 Project Name: 6040352 Collection Date: 4/18/2016 8:00:00 AM Lab ID: 1604G60-001A Matrix: Solid Analyses Result Qual MDL ReportingLimit Units BatchID D)C Date Analyzed Analyst HERBICIDES, TCLP SW1311/8151A (SW3510C) 2,4,5-TP (Silvex) BRL 0.064 0.20 ing/L 223037 1 04/26/2016 20:45 AW 2,4-D BRL 0.076 0.20 mg/L 223037 1 04/26/2016 20:45 AW Surr: DCAA 1.01 0 50.1-148 %uREC 223037 1 04/26/2016 20:45 AW Qualifiers: * Value exceeds maximum contaminant level BRL Not Detected at MDL H Holding times for preparation or analysis exceeded N Analyto not NELAC certified B Analyte detected in the associated method blank E Estimated value above quantitation range S Spike Recovery outside limits due to matrix > Greater than Result value J Estimated value detected below Reporting Limit < Less than Result value Page 4 of 7 Page 13 of 16 Am>dytical Eiii,ironmental 5en,k-es, Inc. Sample/Cooler Receipt Checklist (`� n .Client Work Order Number Checklist completed by,nk Signature Date Carrier name: kedEy c/ UPS Courier Client. US Mail Other Shipping container/cooler.in good condition? Yes No _ Custody seals intact on shipping container/cooler? Yes _ No Custody seals intact on sample bottles? Yes ` No Coutainer/Temp-Blank temperature in compliance? (0°56°C)-Yes No _ Not Present Not Present Not Present _tom Cooler #I L 1 Cooler #2 Cooler 43 Cooler #4 Cobler#5 Chain of custody present? Yes / No Chain of custody signed when relinquished and received? Yes t/ No _ D Chain of custody agrees with sample labels?. Yes tZ No Samples in proper container/bottle? Yes No _ Sample containers intact? Yes s/ No _ Sufficientsample volume for indicated test? Yes No _ All sannples received within holding timer les No p 4/10 Was TAT marked on the COC? Yes _ No Proceed with Standard -TAT as per project history? Yes Z/ No Water - VOA vials have zero headspace? No VOA vials submitted ✓ Yes Water � pH acceptable upon receipt? Yes _ No •_ D Cooler #6 Not Applicable No —. Not Applicable Adjusted? Checked'by p Sample Condition: Good Other(Explain) (For diffusive samples 'or AIHA lead) -Is a known blank included? Yes _ No _ See Case Narrative for resolution of (lie Non -Conformance. 1 * Samples do not have to comply «zth the given range for certain parameters. \1Aes server111Saniple Receiptllvly DocumentslCOCs and pH' Adjustment SheetlSample. Cooler_Recipt Checkl.ist_ReQV5 of.7 Page 14 of 16 Analytical Environmental Services, Inc Date: 27-Apr-16 Client: Prism Laboratories Project Name: 6040352 Dates Report Lab Order: 1604G60 Lab Sample ID Client Sample ID Collection Date Matrix Test Name 1604G60-001A CLASS A 4/18/2016 8:00:OOAM Solid HERBICIDES, TCLP Leached TCLP Date Prep Date Analysis Date 04/20/2016 4/25/2016 11:00:OOAM 04/26/2016 �-i T m cn - m 1 cn Page 6 of 7 0 1 Analytical Environmental Services, Inc Date: 27-Apr-16 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 6040352 `\'orkorder: 1604G60 BatchlIB: 223037 Sample ID: 1VIB-223037 Client ID: Units: mg/L Prep Date: 04/25/2016 Run No: 315493 SampleType: MBLK TestCode: HERBICIDES,TCLP SW1311/8151A BatchID:223037 Analysis Date: 04/26/2016 SegNo: 6790499 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 2,4-D Surr: DCAA BRL 0.20 BRL 0.20 0.3782 0 0.5000 75.6 50.1 148 ample ID: LCS-223037 Client ID: Units: mg/L Prep Date: 04/25/2016 Run No: 315493 ampleType: LCS TestCode: HERBICIDES, TCLP SW1311/8151A BatchID: 223037 Analysis Date: 04/26/2016 Seg No: 6790500 �nalyte Result RPT Limit SPK value SPI{ Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 2,4-D Surr: DCAA 0.4324 0.20 0.5000 86.5 52.5 126 0.4088 0.20 0.5000 81.8 50.5 132 0.4300 0 0.5000 86.0 50.1 148 ample ID: 1604G59-002AM5 Client ID: Units: mg/L Prep Date: 04/25/2016 Run No: 315493 ampleType: MS TestCode: 11ERBICIDES,TCLP SW1311/8151A BatehID:223037 Analysis Date: 04/26/2016 SegNo: 6790504 lnalyte Result RPT Limit SPK value SPK Ref Val DAREC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 2,4-D Surr: DCAA 0.3885 0.20 0.5000 77.7 49.4 131 0.3874 0.20 0.5000 77.5 44.1 137 0.4132 0 0.5000 82.6 50.1 148 W Qualifiers: > Greater than Result value < Less than Result value B Analyte detected in the associated method blank CD BRL Below reporting limit E Estimated (value above quantitation range) H Holding times for preparation or analysis exceeded J Esthvnted value detected below Reporting Limit N Analyte not NELAC certified R RPD outside limits due to matrix page 7 of 7 00 Rpt Linr Reporting Limit S Spike Recovery outside limits due to matrix /."V LABORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. O. Box 878 Mooresville, NC 28115 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 FL NELAC Cert No. E87519 VA NELAC Cert No. 460211 Project: Class A Dried Sludge Lab Submittal Date: 07/18/2016 Prism Work Order: 6070282 Case Narrative 08/05/2016 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager A No duplicate with this batch BH MB greater than one half of the RL, but the sample concentrations are greater than 1 Ox the MB. D RPD value outside of the control limits. MC Sample concentration too high for recovery evaluation. MI Matrix spike outside of the control limits. Matrix interference suspected. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 1 of 16 R ISM Full -Service Analytical & Sample Receipt Summary ' + -- "' Environmental Solutions 08/05/2016 ��-�_�-LABORwTOflIES ING Prism Work Order: 6070282 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 6070282-01 Solid 07/18/16 07/18/16 Samples were received in good condition at 3.6 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte; NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1.800/529-6364 - Fax: 704/525-0409 Page 2 of 16 I SM Fun -Service Analytical s Environmental Solutions LABORATORIES ING Laboratory Report 08/05/2016 Town of Mooresville/RR VWdTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 6070282-01 P. O. Box 878 Prism Work Order: 6070282 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/18/16 08:30 Time Submitted: 07/18/16 13:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General'Chemistry Parameters Plant Available Nitrogen 4900 mg/kg 780 93 20 *Calculation 7/28/16 9:53 EGC [CALC] % Solids 96.0 A % by 0.100 0.100 1 *SM2540 G 7/21/16 16:51 JLB P6G0378 Weight Nitrate/Nitrite as N BRL mg/kg dry 5.2 0.57 1 *SM4500-NO3 F 7/22/16 8:46 CLB P6G0367 pH 6.3 pH Units 1 *9045D 7119/16 8:34 BMS P6G0293 Phosphorus -Total 3600 mg/kg dry 260 120 100 *SM4500-P F 7126/16 11:55 EGC P6G0392 Total K]eldahl Nitrogen 16000 mg/kg dry 2600 300 10 *361.2 7/28/16 9:53 EGC P6130381 Ammonia as N 1300 mg/kg dry 100 40 20 *SM4500-NH3 G 7/21/16 8:62 EGC P6G0333 Microbiological Parameters Fecal Coliforms BRL MPN/g dry 0.2 1 *SM9221 E 7/18/16 14:11 EGC P6G0314 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 *1311 7/26/16 6:50 JAB P6G0410 TCLP Extraction Complete N/A 1 *1311 ZHE 7/26/16 9:00 ANG P6G0411 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 *7470A 7/26/16 13:40 JAB P6G0420 Arsenic BRL mg/L 0.050 0.0035 1 *6010D 7/27/16 17:44 bgm P6G0429 Barium BRL mg/L 5.0 0.0035 1 *6010D 7127/16 17:44 bgm P6G0429 Cadmium BRL mg/L 0.025 0.00050 1 *6010D 7/27/16 17:44 bgm P6G0429 Chromium BRL mg/L 0.25 0.0030 1 *6010D 7/27/16 17:44 bgm P6G0429 Lead BRL mg/L 0.050 0.0065 1 *6010D 7/27/16 17:44 bgm P6G0429 Selenium BRL mg/L 0.10 0.016 1 *6010D 7/27/16 17:44 bgm P6G0429 Silver BRL mg/L 0.25 0.0010 1 *6010D 7127/16 17:44 bgm P6G0429 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.000094 1 *8081B 7/26/16 16:02 JMC P6G0427 Dieldrin BRL mg/L 0.00050 0.000022 1 *8081B 7/26/16 16:02 JMC P6G0427 Endrin BRL mg/L 0.00050 0.000020 1 *8081B 7/26/16 16:02 JMG P6G0427 gamma-BHC BRL mg/L 0.00050 0.000013 1 *8081B 7/26/16 16:02 JMC P6G0427 Heptachlor BRL mg/L 0.00050 0.000015 1 *8081B 7/26/16 16:02 JMC P6G0427 Heptachlor Epoxide BRL mg/L 0.00050 0.000018 1 *8081B 7/26/16 16:02 JMC P6G0427 Methoxychlor BRL mg/L 0.00050 0.000033 1 *8081B 7/26/16 16:02 JMC P6G0427 Toxaphene BRL mg/L 0.025 0.00032 1 *8081B 7/26/16 16:02 JMC P6G0427 Surrogate Recovery Control Limits Decachlorobiphenyl 76 % 13-186 Tetrachloro-m-xylene 65 % 40-134 TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 *8270D 7126116 19:59 JMV P6G0424 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 *8270D 7126/16 19:59 JMV P6G0424 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 *8270D 7/26/16 19:59 JMV P6G0424 2-Methylphenol BRL mg/L. 0.050 0.0018 1 *8270D 7/26/16 19:59 JMV P6G0424 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 3 of 16 Laboratory Report Full -Service Analytical & I S M I Environmental solutions 08/05/2016 1 LABORATORIES, ING Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 6070282-01 P. 0. Box 878 Prism Work Order: 6070282 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/18/16 08:30 Time Submitted: 07/18/16 13:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methylphenol BRL mg/L 0.050 0.0015 1 *8270D 7/26/16 19:59 JMV P6G0424 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 *8270D 7/26/16 19:59 JMV P6G0424 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 *8270D 7/26/16 19:59 JMV P6G0424 Hexachloroethane BRL mg/L 0.050 0.0017 1 *8270D 7/26116 19:59 JMV P6G0424 Nitrobenzene BRL mg/L 0.050 0.0026 1 *8270D 7/26/16 19:59 JMV P6G0424 Pentachlorophenol BRL mg/L 0.25 0.0012 1 *8270D 7/26/16 19:59 JMV PsG0424 Pyridine BRL mg/L 0.25 0.0010 1 *8270D 7/26116 19:59 JMV P6G0424 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 47 % 43-140 2-Fluorobiphenyl 41 % 44-119 SE 2-Fluorophenol 24 % 19-119 Nitrobenzene-d5 37 % 44-120 SE Phenol-d5 17 % 11-52 Terphenyl-d14 44 % 50-134 SE TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.00083 1 *8260B 7/27/16 0:03 KDM P6G0437 1,2-Dichloroethane BRL mg/L 0.025 0.00066 1 *8260B 7/27/16 0:03 KDM P6G0437 1,4-Dichlorobenzene BRL mg/L 0.38 0.00050 1 *8260B 7/27/16 0:03 KDM P6G0437 Benzene BRL mg/L 0.025 0.00048 1 *8260B 7/27/16 0:03 KDM P6G0437 Carbon Tetrachloride BRL mg/L 0.025 0.0011 1 *8260B 7/27/16 0:03 KDM P6G0437 Chlorobenzene BRL mg/L 5.0 0.00062 1 *826013 7/27/16 0:03 KDM P6G0437 Chloroform BRL mg/L 0.30 0.00076 1 *826013 7/27/16 0:03 KDM P6G0437 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.0024 1 *82606 7/27/16 0:03 KDM P6G0437 Tetrachloroethylene BRL mg/L 0.035 0.00098 1 *8260B 7/27/16 0:03 KDM P6G0437 Trichloroethylene BRL mg/L 0.025 0.00078 1 *8260B 7/27/16 0:03 KDM P6G0437 Vinyl chloride BRL mg/L 0.020 0.00097 1 *8260B 7/27/16 0:03 KDM P6G0437 Surrogate Recovery Control Limits 4-Bromofluorobenzene 88 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 81 % 77-123 Total Metals Aluminum 8000 mg/kg dry 2.6 0.77 1 *6010D 7/27/16 1:38 bgm P6G0369 Mercury 0.45 mg/kg dry 0.060 0.0033 3 *7471B 7/25116 12:57 JAB P6G0398 SAR Soil Preparation Complete g 1 *2-78-054 7/26/16 8:10 JAB P6G0399 SAR Percent Moisture 79.7 % by 0.100 0.100 1 *2-78-054 7128/16 10:15 JAB P6130464 Weight Arsenic 1.7 mg/kg dry 0.26 0.032 1 *6010D 7/27116 1:38 bgm P6G0369 Sodium Absorption Ratio 1.1 [blank] 0.30 0.016 1 *2-78-054 8/3/16 15:34 bgm P000423 Cadmium 0.39 mg/kg dry 0.26 0.0070 1 *60101) 7/27/16 1:38 bgm P6G0369 Calcium 8900 mg/kg dry 10 0.24 1 *6010D 7127/16 1:38 bgm P6G0369 Calcium 96 mg/L 1.0 0.086 10 *6010D 8/3/16 15:34 bgm P6G0423 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 -Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 4 of 16 Laboratory Report ,,, I n n V "LABORATORIES, ING Fun -Service Analytical s Environmental Solutions ' 08/05/2016 Town of Mooresville/RR WWTP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 6070282-01 P. O. Box 878 Prism Work Order: 6070282 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 07/18/16 08:30 I— Time Submitted: 07/18/16 13:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Copper 170 mg/kg dry 10 0.95 20 '6010D 7/28/16 13:47 bgm P6G0369 ' Lead 7.6 mg/kg dry 0.26 0.049 1 '6010D 7/27/16 1:38 bgm PSG0369 Magnesium 2000 mg/kg dry 2.6 0.25 1 '60101) 7/27/16 1:38 bgm P6G0369 Magnesium 69 mg/L 1.0 0.0070 10 '6010D 8/3/16 15:34 bgm 136G0423 Molybdenum 4.1 mg/kg dry 0.52 0.015 1 '6010D 7/27116 1:38 bgm P6G0369 Nickel 8.6 mg/kg dry 0.62 0.019 1 •6010D 7/27/16 1:38 bgm 126G0369 Potassium 2100 mg/kg dry 260 9.4 . 20 '6010D 7/28/16 13:47 bgm P6G0369 Selenium 3.3 mg/kg dry 0.62 0.12 1 '6010D 7/27/16 1:38 bgm 136G0369 Sodium 620 mg/kg dry 16 0.61 1 '6010D 7/27/16 1:38 bgm P6G0369 Sodium 56 BH mg/L 5.0 0.074 10 '6010D 8/3/16 15:34 bgm P6G0423 Zinc 270 mg/kg dry 52 1.9 20 '60101) 7128116 13:47 bgm 136G0369 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 16 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Date/Time 6070282-01 P6G0381 0.05 g 25 mL 07/27/16 9:30 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 6070282-01 P6G0392 1 g 50 mL 07/25/16 10:05 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final DatelTime 6070282-01 P6G0378 30 g 30 g 07/21/16 16:51 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 6070282-01 P6G0411 25 g 500 mL 07/25/16 14:30 6070282-01 P6G0410 100 g 2000 mL 07/25/16 14:40 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6070282-01 P6G0429 10 mL 50 mL 07/26/16 10:10 Prep Method: 7470A Lab Number Batch Initial Final DatelTime 6070282-01 P6G0420 20 mL 30 mL 07/26/16 8:12 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 6070282-01 P6G0427 200 mL 10 mL 07/26/16 13:40 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 6070282-01 P6G0424 200 mL 1 mL 07/26/16 13:05 Prep Method: 6030B Lab Number Batch Initial Final Date/Time 6070282-01 P6G0437 1 mL 10 mL 07/26/16 8:20 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6070282-01 P6G0423 50 mL 50 mL 07/26/16 8:55 6070282-01 P6G0423 50 mL 50 mL 07/26/16 8:55 Prep Method: 3050B Lab Number Batch Initial Final Date/Time 6070282-01 P6G0369 1.99 g 50 mL 07/22/16 7:50 6070282-01 P6G0369 1.99 g 50 mL 07/22/16 7:50 Prep Method: 7471B Lab Number Batch Initial Final Date/Time 6070282-01 P6G0398 0.62 g 50 mL 07/25/16 9:23 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/626-0409 Page 6 of 16 Sample Extraction Data Prep Method: SAR 2-78-054 Lab Number Batch Initial Final Date/Time 6070282-01 P6G0399 250 g 250 g 07/25/16 8:10 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 6070282-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/526-0409 Page 7 of 16 CHAIN Environmental Analytical ®F CUSTODY RECORD .�x P R9 R Environmental Solutions PAGE lJ----OF QUOTE # TO ENSURE ROPER BILLING: ." LABORATORIES, INC. - cc' li 449 Sprirrrat�rook Road ^Charlotte, NC T821'T Project Name: /I. di- 3 9 = � ) Phone 704/529-6364 • Fax: 704/525-0409 Short Hold Analysis: eS) (NO) UST Projec . es) (NO) �•—�-- � f�f��L ,�`�� *Please ATTACH any pr ' c specific reporting (QC LEVEL 1 11 III ICY) Client Company Name: t? t,w,, c provisions and/or QC R uirements Deport To/Contact Name: _ Q )l I d%w fv� wed Invoice To: t V {- Gt• ri v�- Jr - Reporting Address: 1,1� &4 ',S-4. Address: Phone: W, .ti — �r — 3-' WFax (Yes) (No): Purchase Order No./Billing Reference Email Address: kli��BA�hTt? + i 5-- 0 �'�• "e Je-vi.S Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days Ell Days ❑ 5 Days EDD Type: PDF ✓EXcel_Other "Working Days" ❑ 6-9 Daystandard 10 days ❑ Rush Work Must Be Pre -Approved Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Certification: NELAC ®o® FL NC �- SC OTHER N/A Water Chlorinated: YES_ NO Sample Iced Upon Collection: YES VINO_ CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIVES ANALYSIS fj(=QUESTED s `r �� ° 1 REMARKS � /� o 4�i�a g;,• a �% PRISM LAB ID NO. *TYPE SEE BELOW NO. SIZE r Sampler's Sign re Sampled By (Print Name) � �r��tl�/ Affiliation D�,, , Upon relinquishing, this Chain of Cus ody is your authorization for Prism to proceed with the analyses as requested above. Any changes must bed submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. g k R linq�,hredB9{y-(Signature Receiv BY: (Signature) Date l // • J� lJ'l• i' � - �� V_" °'+"Sf'�' � �/� �A/ Relinquished By ig ature) Received By: (Signature) Date Relinquished,By;,(Signalu e)// Received or ris b ones By: Data Meth "d of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT wJTXCUSTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. CDC Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAW, T,90C UNTIL RECEIVED AT THE LABORATORY. ❑ Fed 6c ❑UPS ❑ Hand -delivered Prism Field Service ❑ Other Milit Additional Comments lteArn SvalTime: � •gyp° �pp L.(..^'� fvl �.52s�na /'� P' V Site Departure Ime }} _ 7 r%� � - Field Teeh ! ee Mileage — 4 DRINNLANDFILL GROUNDWASOLID WAST: RC: CERCA 1LI L❑SCI OTHER: R? •� IN C ❑SCI ❑ NC ❑ SC El NO ❑ SCTER. ❑ CATER. ❑ NO El SCE ® NC El SC o NC ❑ NO El SCI NO ❑QI NC LI SC *CONTAINER TYPE CODES: A =Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Full -Service Analytical & 4j` I Environmental Solutions . • LABORATORIES, MG. 449 Springbrook Road - Charlotte, NC 28217 Phone 704/529.6364 • Fax: 7041525-0409 Client Company Name: Report To/Contact Name: A m x20 Vv 1(re, Reporting Address: ,fin n 561 81% CHAIN OF CUSTODY RECORD � PAGE OF.=_-�. OUOTE # TO ENSURE _ROPEj�R BILLING: Project Name: t A,S S /A-�L`� (i Short Hold Analysis: esp (No) UST Proje` : -(Yes) (NO) "Please ATTACH any prblLrdt specific reporting (QC LEVEL I If III IV) provisions and/or QC Requirements Invoice To: Address; e YES NO - NIA CD Samples.INTACT upon arrival?. O Received ON WET ICE? O� s:. PROPER. PRESERVATIVES incUcaled? _ Recflivecl WITHIN 1iOLDING:TIMES? _cc OUSTODY SEALS INTACT.?;.. ;VoLxrii_Et reddiVVIOWT HF_AIDSPACE?. PROPER. CONTAINERS.used? -.- TEMPi.THerm.ID, _� Observed::°C;lCorr:��v °C Phone:--gC'vr-L'�ti " 3,2SWax (Yes) (No): Purchase Order No./Billing Reference Email Address: WiNU Arrs Q'ZI aI'd 2,�vt� i' .- t�C - Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days EDD Type: PDF i.� Excel Other "Working Days" ❑ 6-9 Days ❑ Standard 10 days ❑ RushWokust Be Site Location Name: Samples received after 14:00 will be processed next business day. Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) I TO BE FILLED IN BY CLIENTISAMPLING PERSONNEL Certification: NELAC DOD FL NC !� SC OTHER _ N/A Water Chlorinated: YES_ NO Sample Iced Upon Collection: YES NO CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIVI ANALYSIS �2UES,TED t a ih y / REMARKS .CHOURS fit; 7Wj PRISM LAB ID NO. •TYPE SEE BELOW NO. SIZE LL e Sampler's Signatu a r—� 1LeM 0 2 1 z 4 Ns Sampled By (Print Name) dt 6C/��/V Affiliation YrJ4��✓ Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be a submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Reinquis edgy: Signature) Relinquished By: (Sign t r Received(Signature)•�Daate�� +, Received By: (Signature) Date Military/Hours Additional Comments: : Site Arrival -Time : - X, A"s •-- Site.Depa'rture Time:. Relinquished By: (Sign lure) Received F P m Labo ries D_ateJ - I., -I ��! I V%'L ` Field'Tech Fee:. Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WIT STODY SEAES FOR TRANSPORTATION TO THE LABORATORY. COC Group No. •L�f•;• f SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST C NTIL RECEIVED AT THE LABORATORY. n K A� EULE}��Li r ❑ Fed Ex O UPS ❑ Hand -delivered rism Field Service ❑Other ! 7J I �;rNP&3E5: UST: GKOUNUINATER: DRINKING WATEK: SULIU VVAS I E: K(Ur, t:EK(:L.A LMNU 'ILL U I t1EK: jV) cSi ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ❑NC❑SC ❑NC ❑SC ❑NC ❑SC ❑NC ❑SC ) *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 6070282 LABORATORY REPORT NUMBER 1607G40 DATE August 02, 2016 Primate Data Review By Secondary Data Review By Chantelle Kanhai Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aatni ck(a), ax s-inc. c o m - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 7- Page 10 of 16 1 Full -Service Analytical & Environmental Solutions S RM SUBCONTRACT ORDER Certifi atio NELAC_ USACE Prism Laborato+•les, Iite' SC_ Other 6070282 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Analytical Environmental Services, Inc. P. O. Box 240543 3080 Presidential Parkway Charlotte, NC 28224-0543 Atlanta, GA 30340 Phone: 800-529-6364 Phone :(770) 457-8177 Fax: 704-525-0409 Fax: NA Project Manager: Terri W. Cole Analysis Due Expires Laboratory ID Comments NOW ?sY P 3Yr�E 4 Sample ID: 6070282-01 solid 03:30 y s Herbicides TCLP (Sub) 07/25/16 08:30 Coniaineis Supplied: V Q G& . `II7/�.o l d Re]ewed By Date . Received By Date Released By IDate Received By Date Page 11 of 16 I 9YK Ism I Full -Service Analyticaf & Environmental Solutions eB! T i;i5�' LAWRATORIE$ING SUBCONTRACT ORDER Certification: NELAC_ USACE_ Prism Laboratories, Inc. NC SC_ Other 6070282 Nhl SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. P. O. Box 240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax:704-525-0409 Project Manager: Terri W, Cole Analytical Environmental Smices, Inc. 3080 Presidential Parkway Atlanta, GA 30340 Phone :(770) 457-8177 Fax: NA Analysis Due Expires Laboratory ID Comments Sample ID: 6070282-01 Solid Sampled:07/18/16 08.30 ::;; :i; i;}:r. :;:_^:::,;; TCLPvol/semi 3260/8270 method§ Herbicides TCLP (Sub) 07/25/16 08:30 Containers Supplied: — *- E,�-?, YIQ� 7/ 1 7/( 0 Released By Date Received By Date Released By Date Received By Date �k 27ho Cyr3J Page 12 of 16 Analytical Environmental Services, Inc Date: 2-Aug-16 Client: Prism Laboratories Client Sample ID: CLASS A Lab Order 16071340 Tag Number: 6070282-01 Project Name: 6070282 Collection Date: 7/18/2016 8:30:00 AM Lab ID: 1607G40-001A Matrix: Solid Analyses Result Qual MDL Reporting Units BatchlD DF Date Analyzed Analyst Limit HERBICIDES, TCLP SWI311/8151A 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr: DCAA 95.4 Qualifiers: ` Value exceeds maximum contaminant level BRL Not Detected.at hOL H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank (SW3510C) 0.064 0.20 mg/L 227374 1 07/29/2016 20:03 AW 0.076 0.20 ing/L 227374 1 07/29/2016 20:03 AW 0 50.1-148 %REC 227374 1 07/29/2016 20:03 AW E Estimated value above quantitation range S Spike Recovery outside limits due to matrix > Greater than Result value J Estimated value detected below Reporting Limit < Less than Result value Page 4 of 7 Page 13 of 16 Analytical DIVil•onni entai Services, Inc. Sanlple,'Cooler Receipt Checklist 1f IQ LL clicill --_.—..._--------.- •� Work OrderNumber Checklist cons lletzd b �`��✓"Uv _ _ t ��,1-� Carrier PcdEx PS name: L __ C(1nTier _ Clicnt ._- US \•tail _ Other — Shihpin�" container,'cooler in Mood condition? Yes '/ No Not Present Custody seals iw( ict nr, shipping containcniitoler? Y"es -Z \b Not Pres(nt Custody soak int2-t I ,n sah:;,le l,otlles? Yes \o -- Not Pres( nl / Conminer!1'emp L lool, lcntperaunc in cntr.�?liancc? (U° _ii"C 1" 1'rs ✓ �n Cooler ;,I (_C"oalel `' - - --- Cooler `'_i _ Cooler4`4 — (.oi:ler .Chain of cusii cil, i-i'c�Cnt: Yes Chain of custo(A- : hmCd \ •lien relinquished and received:' Yes (// No Chain of'custody ;;erers %%-i;h santpie lahclti? Yes V No SalllpleS ill proper tic? Yes o I Sample container: intarr' Yes No Sufficient.'ampk o ('•n:: ! r iadirticci lc-x. Yes ✓ \o — rt�i S:i Ill ples ricer, ed \l ilhin ho I d i ng ti I11 e'.1 Yes I z \0 AY illark x of l'le n0c•".' i 1'es \li 1/ Proceed with Sum -lard TA as per p.ro ecl hlsiol\•? Yes \o \Ut a.7f Ii:11'le ' Water - VOA vial, ha\�f Zcro headspace? No VOA vials sulmlttled ✓_ Yes -- NL) Water- pi-l'accep:ahle upon receipt? Yes � N0 'Not App Icnblc Adjusted? Checked liv Santple Cunt}ilior.- Good ,// //' Other(L'-xplaut)_. — --- ,- -- lF or di flllsk e .ill plc (.IT .= II'IA le'!df IS a known blank 11c'uAod:' Yes -- CVO 5�cc <-a,c• \a •I-:u° .e i:n� rc:olu[iur• ol'the �'on-(:'ortfnrr::;llc( Page Analytical Environmental Services, hic. Sample/Cooler Receipt Checklist Client \ p{ i SyY1 Work Order Number Checklist completed by 22 Its Signature Date Carrier name: FedEs /UPS _ Courier-- Client— US tmail _ Other -- Shipping container/cooler in good condition? Yes V No Custody seals intact on shipping container/cooler? Yes ✓ No Custody seals intact on sample bottles? Yes _ No _ Container/Temp Blank temperature in compliance? (0°<6°C)- Yes ✓ No Cooler # 1 _ � Cooler #2 Cooler #3 Cooler #4 Chain of custody present? Yes ✓ No Chain of custody signed when relinquished and received? Yes V No Chain of custody agrees with sample labels? Yes ✓ No Samples in proper containerlbottle? Yes - No Sample containers intact? Yes t/ No Sufficient sample volume For indicated test? Yes V� No All samples received within holding time? Yes No Was TAT marked on the COC? Yes _ No _✓ Proceed with Standard TAT as per project history? Yes _V' No Water - VOA vials have zero liendspace? No VOA vials submitted Yes roo-26q-3 Not Present _ Not Present _ Not Present Cooler#S Cooler 46 Not Applicable_ No iVater - pH acceptable upon receipt? Yes No — Not Applicable / Adjusted? Checked by Sample Condition: Good ✓ Other(Explain)_� (Tor diffitsive samples or A1HA lead) Is a known blank included? Yes No See Case Narrative for resolution of the Non -Conformance. Samples do not have to comply with the given range for certain parameters. \\Aes_server\l\Sample Receipt\\ply Documents\COCs and pH Adjustment SlreetlSample_Cooler Recipt_Cliecklist_Revl.rt Page Analytical Environmental Services, Inc Date: 2-Aug-16 Client: Prism Laboratories ANALYTICAL QC SUMMARY REPORT Project Name: 6070282 Workorder: 1607G40 )BatchID: 227374 2,4,5-IT (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.4140 0 0.5000 82.8 50.1 148 2,4,5-TP (Silvex) 0.4929 0.20 0.5000 98.6 52.5 126 2,4-D 0.4477 0.20 0.5000 89.5 50.5 132 Surr: DCAA 0.5721 0 0.5000 114 50.1 148 2,4,5-TP (Silvex) 0.4719 0.20 0.5000 94.4 49.4 131 2,4-D 0.4454 0.20 0.5000 89.1 44.1 137 Surr: DCAA 0.5270 0 0.5000 105 50.1 148 Qualifiers: > Greater than Result value < Less than Result value B Analyte detected in the associated method blank _ CD BRL Below reporting limit E Estimated (value above quantitation range) H Holding times for preparation or analysis exceeded - 0) r Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside limits due to matrix Page 7 of 7 Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix ,PIRS M I ._...-'i 'LABORATORIES, INC. Full -Service Analytical & Environmental Solutions Town of Mooresville/RR WWTP Whitney Munroe P. 0. Box 878 Mooresville, NC .28115 NC Certification No. 402 NC Drinking Water Cent No. 37735 SC Certification No. 99012 Project: Class A Dried Sludge Lab Submittal Date: 10/17/2016 Prism Work Order: 6100344 Case Narrative 11 /08/2016 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Terri W. Cole Project Manager Data Qualifiers Key Reference: Reviewed By Terri W. Cole Project Manager A Result is based on a single replicate due to matrix interference. CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. SE Surrogate recovery outside the QC limits due to emulsion. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 18 +� ®' S n n Full -Service Analytical & t n_ ' V' Environmental Solutions I.ABO-R1ES, INC. Sample Receipt Summary 11/08/2016 Prism Work Order: 6100344 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received Class A 6100344-01 Solid 10/17/16 10/17/16 Samples were received in good condition at 3.2 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/52"409 Page 2 of 18 �. ®� Fun -Service Analytical s Environmental Solutions LA90PATORIES ING Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Laboratory Report 11 /08/2016 Client Sample ID: Class A Prism Sample ID: 6100344-01 Prism Work Order: 6100344 Time Collected: 10/17/16 08:30 Time Submitted: 10/17/16 13:35 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Plant Available Nitrogen 11000 mglkg 1600 210 100 "Calculation 10/26/16 8:25 CLB ICALCI % Solids 92.5 % by 0.100 0.100 1 "SM2540 G 10/25/16 16:45 JLB P6J0462 Weight Nitrate/Nitrite as N BRL mg/kg dry 5A 0.59 1 'SM4500-NO3 F 10/21/16 7:32 CLB P6J0366 pH 6.5 pH Units 1 '9045D 10/19/16 10:44 EGC P6J0335 Phosphorus -Total 12000 mg/kg dry 640 260 200 'SM4500-P F 10/20/16 6:34 CLB P6J0303 Total Kjeldahl Nitrogen 39000 mg/kg dry 6400 610 20 *361.2 10/26/16 8:25 CLB P6J0406 Ammonia as N 1900 mglkg dry 540 210 100 'SM4500-NH3 G 10/24/16 8:18 CLB P6J0397 Microbiological Parameters Fecal Coliforms BRL MPN/g dry 0.2 1 'SM9221 E 10/17/16 13:52 EGC P6J0316 TCLP Extraction by EPA 1311 TCLP Extraction Complete N/A 1 `1311 ZHE 10/25/16 9:30 ANG P6J0414 TCLP Extraction Complete N/A 1 *1311 11/1/16 7:30 JAB P6J0552 TCLP Metals Mercury BRL mg/L 0.010 0.000030 1 `7470A 11/2/16 7:04 JAB P61<0021 Arsenic BRL mg/L 0.050 0.012 1 "6010D 11/1/16 20:01 bgm P61<0023 Barium BRL mg/L 5.0 0,0065 1 '6010D 11/1/16 20:01 bgm P6K0023 Cadmium BRL mg/L 0.025 0.00065 1 '6010D 11/1/16 20:01 bgm P6K0023 Chromium BRL mg/L 0.25 0.0038 1 `6010D 11/1/16 20:01 bgm P6K0023 Lead BRL mg/L 0.050 0.0080 1 '6010D 11/1/16 20:01 bgm P61<0023 Selenium BRL mg/L 0.10 0.022 1 `6010D 1111/16 20:01 bgm P6K0023 Silver BRL mg/L 0.25 0.00050 1 '6010D 11/1/16 20:01 bgm P61<0023 TCLP Organochlorine Pesticides by GC/ECD Chlordane BRL mg/L 0.0025 0.000094 1 '8081B 11/2/16 17:37 JMC P61<0029 Dieldrin BRL mg/L 0.00050 0.000022 1 `8081B 1112/16 17:37 JMC P61<0029 Endrin BRL mg/L 0.00050 0.000020 1 '8081B 11/2/16 17:37 JMC P61<0029 gamma-BHC BRL mg/L 0.00050 0.000013 1 '8081B 11/2/16 17:37 JMC P61<0029 Heptachlor BRL mg/L 0.00050 0.000015 1 '8081B 11/2/16 17:37 JMC P61<0029 Heptachlor Epoxide BRL mg/L 0.00050 0.000018 1 '8081 B 11/2/16 17:37 JMC P61<0029 Methoxychlor BRLCCv mg/L 0.00050 0.000033 1 '808113 11/2/16 17:37 JMC P6K0029 Toxaphene BRL mg/L 0.025 0.00032 1 '80818 11/2/16 17:37 JMC P61<0029 Surrogate Recovery Control Limits Decachlorobiphenyl 45 % 13-186 Tetrachloro-m-xylene 51 % 40-134 TCLP Semivolatile Organic Compounds by GC/MS 2,4,5-Trichlorophenol BRL mg/L 0.25 0.0016 1 `8270D 1112/16 10:16 JMV P61<0028 2,4,6-Trichlorophenol BRL mg/L 0.10 0.0018 1 `8270D 11/2/16 10:16 JMV P6K0028 2,4-Dinitrotoluene BRL mg/L 0.050 0.0014 1 '8270D 11/2/16 10:16 JMV P61<0028 2-Methylphenol BRL mg/L 0.050 0.0018 1 '8270D 11/2/16 10:16 JMV P61<0028 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/625-0409 Page 3 of 18 ISM Full -Service Analytical �®�"/yp(�[�, j Environmental Solutions " --.T-E$ ING Laboratory Report 11 /08/2016 Town of Mooresville/RR VWVfP Project: Class A Dried Sludge Client Sample ID: Class A Attn: Whitney Munroe Prism Sample ID: 6100344-01 P. O. Box 878 Prism Work Order: 6100344 Mooresville, NC 28115 Sample Matrix: Solid Time Collected: 10/17/16 08:30 Time Submitted: 10/17/16 13:35 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3/4-Methyl phenol BRL mg/L 0.050 0.0015 1 `8270D 11/2/16 10:16 JMV P61<0028 Hexachlorobenzene BRL mg/L 0.050 0.0013 1 `8270D 11/2/16 10:16 JMV P61<0028 Hexachlorobutadiene BRL mg/L 0.050 0.0021 1 '8270D 11/2/16 10:16 JMV P61<0028 Hexachloroethane BRL mg/L 0.050 0.0017 1 '8270D 11/2/16 10:16 JMV P61<0028 Nitrobenzene BRL mg/L 0.050 0.0026 1 `8270D 11/2/16 10:16 JMV P61<0028 Pentachlorophenol BRL mg/L 0.25 0.0012 1 '8270D 11/2/16 10:16 JMV P61<0028 Pyridine BRL mg/L 0.25 0.0010 1 '8270D 11/2/16 10:16 JMV P61<0028 Surrogate Recovery Control Limits 2;4,6-Tribromophenol 2 % 43-140 SE 2-Fluorobiphenyl 61 % 44-119 2-Fluorophenol 8 % 19-119 SE Nitrobenzene-d5 55 % 44-120 Phenol-d5 7 % 11-52 SE Terphenyl-d14 63 % 50-134 TCLP Volatile Organic Compounds by GC/MS 1,1-Dichloroethylene BRL mg/L 0.035 0.000083 1 '8260B 10/27/16 6:24 KDM P6JO482 1,2-Dichloroethane BRL mg/L 0.025 0.000066 1 '8260B 10/27/16 6:24 KDM P6JO482 1,4-Dichlorobenzene BRL mg/L 0.38 0.000050 1 '8260B 10/27/16 6:24 KDM P6J0482 Benzene BRL mg/L 0.025 0.000048 1 '8260B 10/27/16 6:24 KDM P6JO482 Carbon Tetrachloride BRL mg/L 0.025 0.00011 1 '8260B 10/27/16 6:24 KDM P6JO482 Chlorobenzene BRL mg/L 5.0 0.000062 1 '8260B 10/27/16 6:24 KDM P6JO482 Chloroform BRL mg/L 0.30 0.000076 1 '8260B 10/27/16 6:24 KDM P6JO482 Methyl Ethyl Ketone (2-Butanone) BRL mg/L 10 0.00024 1 '8260B 10/27/16 6:24 KDM P6JO482 Tetrachloroethylene BRL mg/L 0'.035 0.000098 1 '8260B 10/27/16 6:24 KDM P6JO482 Trichloroethylene BRL mg/L O.D25 0.000078 1 '8260B 10/27/16 6:24 KDM P6JO482 Vinyl chloride BRL mg/L 0.010 0.000097 1 '8260B 10/27/16 6:24 KDM P6JO482 Total Metals Surrogate 4-Bromofluorobenzene Dibromofluoromethane Toluene-d8 Recovery 104 % 129 % 93 % Control Limits 80-124 75-129 77-123 Aluminum 10000 mg/kg dry 2.7 0.78 1 '60101) 10/21/16 1:01 bgm P6J0329 Mercury 0.48 A mg/kg dry 0.065 0.0036 3 '7471B 10/28/16 16:27 JAB P6J0510 SAR Soil Preparation Complete g 1 '2-78-054 10/27/16 14:00 JAB P6JO500 SAR Percent Moisture Complete % by 0.100 0.100 1 '2-78-054 11/1/16 16:00 JAB P61<0031 Weight Arsenic 1.7 mglkg dry 0.27 0.032 1 '601011) 10/21/16 1:01 bgm P6J0329 Sodium Absorption Ratio 1.6 [blank] 0.30 0.016 1 '2-78-054 10/28/16 17:27 bgm 136J0501 Cadmium 0.36 mg/kg dry 0.27 0.0071 1 '6010D 10/21/16 1:01 bgm P6J0329 Calcium 10000 mg/kg dry 11 0.24 1 •6010D 10/21/16 1:01 bgm P6J0329 Calcium 120 mg/L 1.0 0.085 10 `6010D 10/27/16 20:42 bgm P6J0501 Copper 170' mg/kg dry 11 0.96 20 `60101) 10/21/16 15:37 bgm P6JO329 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 4 of 18 f.Y I S I Full -Service Analytical lo—( ' Environmental Solutionss ^ I LABORATORIES - Laboratory Report 11 /08/2016 Town of Mooresville/RR WWTP Attn: Whitney Munroe P. O. Box 878 Mooresville, NC 28115 Project: Class A Dried Sludge Sample Matrix: Solid Client Sample ID: Class A Prism Sample ID: 6100344-01 Prism Work Order: 6100344 Time Collected: 10/17/16 08:30 Time Submitted: 10/17/16 13:35 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Lead 8.4 mg/kg dry 0.27 0.050 1 *6010D 10/21/16 1:01 bgm P6J0329 Magnesium 2000 mg/kg dry 2.7 0.26 1 *6010D 10/21/16 1:01 bgm P6J0329 Magnesium 60 mg/L 1.0 0.0070 10 *6010D 10/27/16 20:42 bgm P6J0501 Molybdenum 5.6 mg/kg dry 0.53 0.016 1 *6010D 10/21/16 1:01 bgm P6J0329 Nickel 9.9 mg/kg dry 0.53 0.019 1 *6010D 10/21/16 1:01 bgm P6J0329 Potassium 2100 mg/kg dry 270 9.6 20 *6010D 10/21/16 15:37 bgm P6J0329 Selenium 3.0 mg/kg dry 0.53 0.13 1 *6010D 10/21/16 1:01 bgm P6J0329 Sodium 650 mg/kg dry 16 0.52 1 *6010D 10/21/16 1:01 bgm P6J0329 Sodium 85 mg/L 5.0 0.18 10 *6010D 10/28/16 17:27 bgm P6J0501 Zinc 320 mg/kg dry 53 1.9 20 *6010D 10/21/16 15:37 bgm, P6J0329 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041625-0409 Page 5 of 18 Sample Extraction Data Prep Method: 361.2 Lab Number Batch Initial Final Date/Time 6100344-01 P6J0406 0.05 g 25 mL 10/24/16 10:00 Prep Method: SM4500-PBS Lab Number Batch Initial Final Date/Time 6100344-01 P6J0303 1 g 50 mL 10/18/16 10:02 Prep Method: Solids, Dry Weight Lab Number Batch Initial Final Date/Time 6100344-01 P6J0462 30 g 30 g 10/25/16 16:45 Prep Method: 1311 Lab Number Batch Initial Final Date/Time 6100344-01 P6J0552 100 g 2000 mL 10/31/16 15:30 61100344-01 P6J0414 25 g 500.mL 10/24/16 16:00 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6100344-01 P61<0023 10 mL 50 mL 11/01/16 12:10 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 6100344-01 P61<0021 20 mL 30 mL 11/01/16 9:30 Prep Method: 3610C GC Lab Number Batch Initial Final Date/Time 6100344-01 P61<0029 200 mL 10 mL 11/01/16 13:50 Prep Method: 3610C MS Lab Number Batch Initial Final Date/Time 6100344-01 P61<0028 200 mL 1 mL 11/01/16 13:35 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 6100344-01 P6J0482 10 mL 10 mL 10/26/16 9:20 Prep Method: 3010A Lab Number Batch Initial Final Date/Time 6100344-01 P6J0501 50. mL 50 mL 10/27/16 15:00 6100344-01 P6J0501 50 mL 50 mL 10/27/16 15:00 6100344-01 P6J0501 50 mL 50 mL 10/27/16 15:00 Prep Method: 3050B Lab Number Batch Initial Final Date/Time 6100344-01 P6J0329 2.03 g 50 mL 10/1.9/16 9:05 6100344-01 P6J0329 2.03 g 50 mL 10/19/16 .9:05 Prep Method: 7471 B Lab Number Batch Initial Final Date/Time This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/625-0409 Page 6 of 18 Sample ExtractionData Prep Method: 7471B Lab Number Batch Initial Final Date/Time 6100344-01 P6J0510 0.6 g 50 mL 10/28/16 9:42 Prep Method: SAR 2-78-064 Lab Number Batch Initial Final Date/Time 6100344-01 P6J0500 250 g 250 g 10/26/16 14:00 Subcontracted Analyses The following analyses were subcontracted to Analytical Environmental Services, Inc. Lab Number Analysis 6100344-01 Herbicides TCLP (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/626-0409 Page 7 of 18 Full -Service Analytical & Environmental Solutions LABORATORIES, INC. 449 Springbrook Road - Charlotte, NC 28217 Phone 704/529-6364 - Fax: 704/525-0409 Client Company Name: :ISo"uAf_ Report To/Contact Name: udl Reporting Address:p� a �g CHAIN OF CUSTODY RECORD PAGE OF DOTE 0 TO ENSURE PR07R BILLING: Project Name:s Short Hold Analysis: e ) (No) '—UST Project: es *Please ATTACH any p t ing specific report(QC LEVi I II1H IV) provisions and/or QC Requirements.J e g� Invoice To: I -9,A A ,40_ Address: Phone: -M"t"Ut90 -32StgFax (Yes) (No): Purchase Order No./Billing Reference �j�nlA ,'ot ��t ��o B1�f TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email Address: •� - Requested Due Date O 1 Day ❑ 2 Days ❑ 3 Days O 4 Days ❑ 5 Days Certification: NELAC DOD FL NC "'� EDD Type: PDF_Excel_Other "Working Days" ® 6-9 DaysXS-tandard 10 days ® Must Be Pre-ApprovedhWok Site Location Name: Samples received after 14:00 will be processed next business day. $C ®TITER N/A — Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. dater Chlorinated: YES_ MO (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES NO T TIME COLLECTED MATRIX SAMPLE CONTAINER PRT A�� ANALYSIS R UESTED ® PRISM CLIENT SAMPLE DESCRIPTION COLLECTED WATER OR VES ® ,� ® A REMARKS LAB *TYPE NO. SIZE a ID NO. HOURS SLUDGE) SEE BELOW s �0�' Cad Pr [ lb a 3c4M ""SoA ��n "`�✓ Sampler's Signa re Sampled By (Print Name) Affiliation Upon relinquishing, this h-in of Custody is your authorization for P ism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charqes for any changes after analyses have been initialized. Relin uIs d By (Signature Receive : (Signs re) C �` Date _ MilitaryMours Additional Comments ' SlteArnvallttnp - Relinquished By: (Sig r Received By: ( ignature) Dale �'4s Vol A7 'Site Departure I - Relinquished By: (SI e) Received For Pris borat s B Dale �1 .[•U! �� `Field Tech Fee. i r �- 1)�' ��}J� Mileage. Method of Shipment: NOTE: A L SA LE COOLERS SHOULD BE TAPED SHUT WITH GUSJ9DY SEALS OR TRANSPORTATION TO THE LABORATORY. COC Group No. NOT SAMPLES ARE NOT A CEPTED AND VERIFIED AGAINST COC UN RECEIVED AT THE LABORATORY. ( l J L� ❑ Fed Ex ❑ UPS El Hand -delivered Field Service ❑ Other ` ES: UST: GRouNDwATER: DRINKING MIATER: ST WAS E• CERCLA LANDFILL ® SC ❑ NC ❑ SC El NC LI SC ® NC LIEC NC ❑SCl_10 ®NRC ®SC I NC ®SC ®NC ®SC ®NC ®SC I D ® 13 ❑ ❑ ❑ ❑ ❑ ❑ "1 1 1 IAi *CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Full -Service Analytical & PRISM Environmental Solutions _ LAaOn ATOnIIIS, INC. 449 Springbrook Road • Charlotte, NC 28217 Phone 704/529-6364 • Fax: 1704/525-0409 Client Company Name: ® m!PI AA& g t `ik- Report To/Contact Name -_A^ ��ro'L A Reporting Address: �, t) .� OZC CHAIN OF CUSTODY RECORD PAGE6"\ OF jg!!, QUOTE # TO ENSURE PROPER BILLING Project Name: olos A - Short Hold Analysis: s (No) UST Project: �es) O *Please ATTACH any project specific reporting (QC LEV II III IV) provisions and/or QC Requirements Pr�� AAA Invoice To: 7AWA. '9 t- i` we6Xt- Address: YES NO ' N/A10O Samples INTACT upon"a&ival? .:. p <: Received ON'WET ICE? 0) PROPER PRESERVATIVES.indlcated? O Received WITHIN HOLDING,TIMES? GUSTgDY SEAL5 INTACT ': VOLATILES reed W101-IT HEADSPACE7 r PROPCR LONTAINERS used? r h rnone: rax(ves) (No): Purchase Order No./Billing Reference Email Address: PWMr taRequested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days EDD Type: PDF Excel -Other "Working Days" ❑ 6-9 Days Standard 10 days ❑ Rush re h Work Must Be Site Location Name: roved Samples received after 14:00 will be processed next business day. TO BE FILLED IN BY CLIENT/SAMPLING PERSONIIIF,,L Certification: NELAC DOD FL NC If SC OTHER N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays, (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) hater Chlorinated: YES_ N® Sample Iced Upon Collection: YES NO CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY HOURS MATRIX (SOIL, WATER OR SLUDGE) SAMPLE CONTAINER PRESERVA- TIVES ANALYSIS �9 UESTIRD o REMARKS PRISM LAB ID NO. `TYPE SEE BELOW NO. SIZE ass A- S6t1 Sampler's Signa Lr Sampled By (Print Name) Affiliation ) I' Upon relinquishing, this Chain of Cust9dy is your authorization for Prism to roceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after a al es have been initialized. - 0 i Iqul ed y:(Sign lure) Received By: Slgnat�) Date c�( �1%"U MditarylHoure Additional Comments: •_ siteAi•rval Timei�:�•;..`.?.` Relinquished By Sign lure) Received B(Signature) Y Date %V\iil ..Site ,DepartureTime, Relinquished By: (Signature) Received For Is orl Date ` /`•�, I ( 4) LA r Cdi '�FleldI Method of Shipment: NOTE: ALL SAM COOLERS SHOULD BE TAPED SHUT WIT USTODY SEALS FOR TRANSPORTATION TO THE LABORATORY. COC Group No. SAMPLES ARE NOT AC EPTED AND VERIFIED AGAINST NTIL RECEIVED AT THE LABORATORY. �]y / , %%,,Il V l L(� r�Wl I Styr �' ❑ Fed Ex ❑UPS O Hdnd-delivered Prism Field Service ❑ Other l V ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SCTER: I O NC Ll S ATER: y& NC ❑SCE I ❑❑ NBC ❑ SC NC ❑ SC I ❑ NC LANDFILL❑ SC ❑ NC ❑ SC O, /S Tech fee. . �. El -- ❑ ❑ LI 'CONTAINER TYPE CODES: A = Amber C = Clear G= Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte NC 282240543 ATTENTION Terri W. Cole PROJECT ID 6100344 LABORATORY REPORT NUMBER 161OG89 Prunary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: DATE November 07, 2016 Secondary Data Review By Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDIIEC certified laboratory # 98016, NCDENI2 certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative ofAES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 9 Page 10 of 18 Full-Service Analytical & Environmental Solutions SENDING LABORATORY: Prism Laboratories, Inc. P. 0. Box 240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax:704-525-0409 Project Manager: Terri W. Cole lellldel;�119 SUBCONTRACT ORDER Certifi fo ELAC_ USACE Prism Laboratories, Inc. C SC_ Other 6100344 RECEIVING LABORATORY: Analytical Environmental Services, Inc. 3080 Presidential Parkway Atlanta, GA 30340 Phone :(770) 457-8177 Fax: NA Analysis Due Expires Laboratory ID Comments M-11 Sample ID: 6100344-01 Solid Sampled:10/17/16 08:30Ml- Herbicides TCLP (Sub) 10/24/16 08:30 FLY--) Containers Supplied: Tv7, (oh-1 //'� li teased i3y Vate Received By Date Relcascd By Dale Received By Released By Date Received By Date Flage 2 o Page 1 of 1 Ism "LASORATORIS S, INC. Full -Service Analytical & Environmental Solutions jvo&g� SUBCONTRACT ORDER Certific t: NEL_ Otherher ACE Prism Laboratories, Inc. SCC 6100344 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. P, O. Box240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax:704-525-0409 ProjectManager: Terri W. Cole Analytical Environmental Services, Inc., 3080 Presidential Parkway Atlanta, GA 30340 Phone :(770) 457-8177 Fax: NA Analysis Due Expires Laboratory ID Comments Sample ID: 6100344-01 Solid Sampled:10/17/16 08:30 Herbicides TCLP (Sub) Containers Supplied: 10/24/16 0830 Released By Date . Received By Date Released By Date Received By Date Page 3 of 9 Page 1 of 1 Pagel of 18 Analytical Environmental Services, Inc Date: 7-Nov-16 Client: Prism Laboratories Project: 6100344 Case Narrative Lab ID: 161OG89 Sample Receiving Nonconformance: Insufficient sample was received on 10/20/16 @ 09:15 AM for TCLP Herbicides analysis. Additional sample was received on 10/28/16 @ 10:20 AM. Page 4 of 9 Page 13 of 18 Analytical Environmental Services, Inc Date: 7-Nov-16 Client: Prism Laboratories Client Sample 11): CLASS A Lab Order 1610G89 Tag Number: 6100344-01 Project Name: 6100344 Collection Date: 10/17/2016 8:30:00 AM Lab 1m: 1610G89-OOIA Matrix: Solid Analyses Result Qua[ MDL Reporting Units BatchID DF Date Analyzed Analyst Limit HERBICIDES, TCLP SW1311/8151A 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr: DCAA 85.4 Qualifiers: ' Value exceeds maximum contaminant level BRL Not Detected at MDL H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank (SW3510C) 0.064 0.20 mg/L, 232093 1 11/03/201614:46 AW 0.076 0.20 -g/L 232093 1 11/03/201614:46 AW 0 50.1-148 %REC 232093 1 11/03/201614:46 AW E Estimated value above quantitation range S Spike Recovery outside limits due to matrix > Greater than Result value J Estimated value detected below Reporting Limit < Less than Rauh value Page 5 of 9 Page 14 of 18 / Adjusted? Sample Condition: Good �d Other(Explain) (For diffusive samples or A1HA lead) Is a known blank included? See Case Narrative for resolution of the Non -Conformance. Analytical Environmental Services, Inc. Sample/Cooler Receipt Checklist Client" Work Order Number Checklist completed by m! r an 1 d 1N t cp Signature Date Carrier name: FedExl9 UPS Courier Client US Mail Other Shipping container/cooler in good condition? Yes Custody seas intact on shipping container/cooler? Yes Custody seals intact on sample bottles? Yes Container/Temp Blank temperature in compliance? (0°:56°C)* Yes 6 Ci Cooler #1 Cooler 92 Cooler #3 Cooler 94 Chain of custody present? Yes v/ Chain of custody signed when relinquished and received? Yes @! Chain of custody agrees with sample labels? Yes Samples in proper containerlbottle? Yes V Sample containers intact? Yes Sufficient sample volume for indicated test? Yes _ All samples received within holding time? Yes Was TAT marked on the COC? Yes _ Proceed with Standard TAT as per project history? Yes Water - VOA vials have zero headspace? No VOA vials submitted V Water - pH acceptable upon receipt? Yes _ No _ Checked by No _ Not Present _ No _ Not Present _ No Not Present No _ Cooler#5 Cooler #6 No No _ No _ No _ No No y No _/ No V No _ Yes _ Not Applicable _ No Not Applicable 0/ Yes No * Samples do not have to comply with the given range for certain parameters. \\Aes_server\1\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Sample Cooler Recipt Checklist Revl.ttf Page 6 of 9 h Analytical Environmental Services, Inc. Sample/Cooler Receipt Checklist Client evms'y p rn Work Order Number I iQ l o C ® 9 Checklist completed by f waq 1.0 1 Signature Date Carrier name: FedEx e/ UPS _ Courier _ Client _ US Mail J Other Shipping container/cooler in good condition? Yes `r No _ Custody seals intact on shipping container/cooler? Yes V No Custody seals intact on sample bottles? Yes _ No Container/Temp Blank temperature in compliance? (0156'C)* Yes No 0C, Cooler #1 ' • Cooler #2 Cooler #3 Cooler 44 V Not Present _ Not Present _ Not Present V Cooler#5 Cooler 46 Chain of custody present? Yes No Chain of custody signed when relinquished and received? Yes !/ No _ Chain of custody agrees with sample Iabels? Yes1 No _ Samples in proper container/bottle? Yes `" No _ Sample containers intact? Yes No _ Sufficient sample volume for indicated test? Yes `r No _ All samples received within holding time? Yes No _ V Was TAT marked on the COC? Yes _ No Proceed with Standard TAT as per project history? Yes _V/ No _ Not Applicable Water - VOA vials have zero headspace? No VOA vials submitted Yes _ No Water - pH acceptable upon receipt? Yes _ No _ Not Applicable V / Adjusted? Checked by Sample Condition: Good I/ Other(Explain) (For diffusive samples or A HA lead) Is a known blank included? Yes _ No See Case Narrative for resolution of the Non -Conformance. 4 Samples do not have to comply with the given range for certain parameters. \Wes server\I\Sample Receipt\My Documents\COCs and pH Adjustment Sheet\Saniple_Cooler Recipt Checklist Revl.rtf Page 7 of 9 Page 16 of 18 Analytical Environmental Services, Inc Date: 7-Nov-16 Client: Prism Laboratories Project Name: 6100344 Dates Report Lab Order: 161 OG89 Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date Prep Date Analysis Date 161OG89-001A CLASS 10/17/2016 8:30:DOAM Solid HERBICIDES, TCLP Leached 10/28/2016 11/2/2016 1:30:OOPM 11103/2016 v CD v Page 8 of 9 0 Analytical Environmental Services, Inc Client: Prism Laboratories Project Name: 6100344 Worl(order: 161 OG89 Date: 7-Nov-16 ANALYTICAL QC SUMMARY REPORT BatchID: 232093 Sample ID: MB-232093 Client ID: Units: mg/L Prep Date: 11/02/2016 Run No: 328981 SalnpleType: NBLK TestCode: HERBICIDES, TCLP SW1311/8151A BatchlD: 232093 Analysis Date: 11/03/2016 Seq No: 7140934 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val 0/.RPD RPD Limit Qual 2,4,5-TP (Silvex) BRL 0.20 2,4-D BRL 0.20 Surr: DCAA 0.3844 0 0.5000 76.9 50.1 148 Sample ID: LCS-232093 Client ID: Units: mg/L Prep Date: 11/02/2016 Run No: 328981 SalnpleType: LCS TestCode: HERBICIDES, TCLP SW1311/8151A BatchID: 232093 Analysis Date: 11/03/2016 Seq No: 7140938 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.3852 0.20 0.5000 77.0 52.5 126 2,4-D 0.4045 0.20 0.5000 80.9 50.5 132 Surr: DCAA 0.4275 0 0.5000 85.5 50.1 148 Sample ID: 1611034-001CMS Client ID: Units: mg/L Prep Date: 11/02/2016 Run No: 328981 SampleType: MS TestCode: HERBICIDES,TCLP SW1311/8151A BatchID: 232093 Analysis Date: 11/03/2016 Seq No: 7141921 Analyte Result RPT Limit SPK value SPK Ref Val %REC Low Limit High Limit RPD Ref Val %RPD RPD Limit Qual 2,4,5-TP (Silvex) 0.4095 0.20 0.5000 2,4-D 0.4535 0.20 0.5000 Surr: DCAA 0.6910 0 0.5000 IR W Qualifiers: > Greater than Result value (D BRL Below reporting limit CC) 7 Bstinwted value detected below Reporting Limit O Rpt Lim Reporting Limit 00 81.9 49.4 131 90.7 44.1 137 138 50.1 148 < Less than Result value B Estimated (value above quantitation range) N Analyte not NELAC certified S Spike Recovery outside limits due to matrix B Analyte detected in the associated method blank H Holding tunes for preparation or analysis exceeded R RPD outside limits due to matrix Page 9 of 9