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HomeMy WebLinkAboutWI0400091_Monitoring (Report)_20091002°RnTF ICY p 2 LWJ FCL EINFEL DER �� J- Bright People. Right Solutions. RECEIVED I DENR r DWQ AQUIPcP vPnTrr-T1pN gPUICN OCT 4 2 2009 c�c Quarterly HiSOC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Kleinfelder Project No. 97746 wi n`��p°91 ('KL EINFEL,DER Bright People. Hight Solutions. September 18, 2009 Fife No. 977461 GS009R167 Mr. Qu Qi Aquifer Protection Section — UIC Staff ❑ENR — Division of Water Quality 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Reference: Quarterly HiSGC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Kleinfelder Project No. 97746 1 GS009R Dear Mr. Qi: Kleinfelder is pleased to provide our quarterly monitoring report for the Underground Injection Control (U1C) Permit for treatment of groundwater with the HiSQC system at the referenced site. This report summarizes our field activities, observations, and includes the analytical results of the groundwater samples. Should you have any questions or require additional information, please do not hesitate to contact Chris Hay at your convenience. Very truly yours, KLEINFELDER SOUTHEAST, INC. 000 �-O Christopher W. Hay, E.I. Environmental Group Manager Gail G. Licayan, P.E. Project Professional CWHIGGL:cas 313 Galhmore Dairy Road, Greensboro, NC 27409 p 1 336.668,0093 f 1336 668-3868 GILBARCO Greensboro, North Carolina Groundwater Incident Nos. 12960 And 15123 SITE INFORMATION Address: Contact: Telephone: Latitude and Longitude Risk Classification: Land Use Category: LAND OWNERSHIP Name: Address: Telephone: Attention: RELEASE INFORMATION September 30, 2009 7300 West Friendly Avenue Greensboro, North Carolina Ms. Beth Money 336,547.5130 36.0901 ON, 79.9282 °W Low Commercial Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina 27420 336.547.5130 Ms. Beth Money RECEIVED ! DENR I DVVR AOUIF�a 0Rf17f'TInN 0,F(710N OCT 0 2 2009 Cause of Release: Release from a 1,000-gallon diesel UST and four 550-gallon gasoline USTs was discovered in November and December 1994. The quantity released is unknown. ENVIRONMENTAL CONSULTANT Name: Kleinfelder Southeast, Inc. Address: Post Office Box 18846 Greensboro, North Carolina 27419-8846 Telephone: 336.668.0093 Attention: Mr. Christopher W. Hay Seal and ",g�WjHr,e of Certifying Professional Engineer �ZH C A R a ��f� i, Gail Geis�r<q,;��i�ssional Engineer for Kleinfelder do certify that the information contai aed. his re s�&orrect and accurate to the best of my knowledge. SEAL Gail G 4,i�,a RegisteVll a Engineer No. 031532 I01111$1110\0 97746 i GS009R167 Page i September 30, 2099 Copyright 2009 Kleinfelder TABLE OF CONTENTS 1.0 INTRODUCTION......................................................................................................1 2.0 GROUNDWATER MONITORING ACTIVITIES........................................................1 3.0 HiSOC INSTALLATION AND MONITORING...........................................................2 4.0 GROUNDWATER ANALYTICAL RESULTS............................................................4 5.0 CONCLUSIONS AND RECOMMENDATIONS... ...................................................... 5 TABLES 1 Groundwater Elevation Data 2 Estimated Dissolved Hydrogen Concentrations at Injection Wells 3 Estimated Hydrogen Consumption 4 Aquifer Characteristics Field Analysis Summary 5 Summary of Groundwater Sample Results 6 Historical Summary of Groundwater Sample Results FIGURES 1 Site Location Map 2 Site Plan 3 Groundwater Potentiometric Surface Map 4 Total VOCs Concentrations 5 Total Chlorinated Hydrocarbons APPENDICES A Laboratory Report and Chain -of -Custody Document B Total VOC Graphs 977461 GS009R167 Page ii September 30, 2009 Capynght 2009 Kleinfeider 1.0 INTRODUCTION The subject site is located at 7300 West Friendly Avenue in Greensboro, Guilford County, North Carolina (Figure 1). There are currently two open groundwater incidents (Incident Nos. 12960 and 15123). The incidents have a commingled plume and are being treated with the same corrective action plan. A pump and treat system is operating at the site, The system consists of four recovery wells, an oil -water separator, and an air stripping system. In January 2008, Kleinfelder submitted a CAP Addendum recommending the use of HiSOC and iSOC technology to degrade the chlorinated and petroleum hydrocarbons in groundwater at the site. This technology will work in concert with the existing groundwater recovery system and supplement the ability of the system to contain the contaminant plume within the property limits and reduce contaminant levels. The HiSOC system was installed in June of 2008 and began operating on June 13, 2008. The baseline sampling event was conducted on June 5, 2008. The purpose of this report is to summarize the quarterly monitoring of the HiSOC system performed on September 2, 2009. 2.0 GROUNDWATER MONITORING ACTIVITIES Static water levels were measured in the existing monitoring wells on -site on September 2, 2009. Groundwater samples were collected from twelve of the monitoring wells (MW-7, MW-11, MW-13, MW-13D, MW-14, MW-14D, MW-23D, MW-24, MW-25, MW-42, MW-43D, and MW-45) and analyzed for VOCs by EPA Methods 601 and 602, isopropyl ether, methyl tert-butyl ether, ethylene dibromide, and xylenes. Field parameters including oxidation-reduction potential (ORP), pH, conductivity, dissolved oxygen, and temperature of representative groundwater samples were also recorded from each monitoring well sampled. Groundwater elevations in the existing monitoring wells were used to determine the groundwater flow direction, average hydraulic gradient, and plume orientation. Table 1 provides a summary of monitoring well construction details and the groundwater elevations measured on September 2, 2009. The monitoring well locations are shown on Figure 2. The static water levels measured between monitoring wells MW-32 and MW-45 indicate a horizontal groundwater flow 977461 GS009R167 Page 1 of 6 September 30, 2009 Copyright 2009 Kleinfelder gradient of 0.04 feet per foot to the northwest. A groundwater flow map of the shallow aquifer based on the September 2, 2009 groundwater elevations are shown on Figure 3. Free product was not observed in any of the monitoring wells during the sampling event. Based on data provided in the October 1996 Corrective Action Plan, the surficial aquifer has an average hydraulic conductivity of 0.09 feet per day. The average groundwater velocity is estimated to be 0.01 feet per day (4 feet per year), based on the average groundwater gradient from the September 2, 2009 water level measurements and an estimated effective porosity of thirty percent. Groundwater samples were collected from monitoring wells MW-7, MW-11, MW-13, MW-13D, MW-14, MW-14D, MW-23D, MW-24, MW-25, MW-42, MW-43D, and MW-45 using disposable polyethylene bailers. The wells were purged of three well volumes of water or until they were bailed dry. Groundwater purged from the monitoring wells was disposed of in the on -site groundwater recovery system. Groundwater samples were collected and placed in laboratory prepared containers. The samples were maintained on ice until delivered to Pace Analytical Laboratories in Huntersville, North Carolina. 3.0 HiSOC INSTALLATION AND MONITORING Kleinfelder applied for a permit from the Underground Injection Control (U1C) Program for the installation of a hydrogen and oxygen delivery system for remediation of contaminants in groundwater at the site. A permit dated March 20, 2008 was issued for the site (Injection Well Permit W10400091). The permit is effective through April 30, 2010. Installation of the injection equipment was initiated on April 9 through April 11, 2008. The existing protective casings were removed from monitoring wells MW-7, MW-10, MW-23D, MW-29, and MW-34. Ten -inch diameter PVC casings were installed to a depth of five feet below ground surface adjacent to the monitoring well locations to hold the hydrogen cylinders. Six to ten inches of gravel was placed in the bottom of each casing. Excavations were completed for installation of 24-inch square, steel well vaults and the vaults were set in concrete flush with the ground surface. Protective vaults were also installed adjacent to the existing above grade protective covers for monitoring 977461 GS009R167 Page 2 of 6 September 30, 2009 Copyright 2009 Kleinfe}der wells MW-14D, MW-15, MW-16, MW-24, and MW-43D. The 15-inch by 24-inch PVC protective vaults were installed over the cylinder casings. Vents were installed in the protective vaults to allow hydrogen to be released in the case of a leak from the delivery system. The HiSOC equipment from InVentures was installed at the site in ten existing monitoring wells (MW-7, MW-10, MW-14D, MW-15, MW-16, MW-231D, MW-24, MW- 29, MW-34, and MW-431D) on June 13, 2008. Within each injection well is a HiSOC unit and filter. Hydrogen is supplied from a compressed gas cylinder with a regulator and gauge connected to the HiSOC unit by Parflex tubing and a support cable. Four -foot grounding rods were installed and connected to the regulator assembly of the gas cylinders. The HiSOC installation locations are shown on the figures in orange. On May 13, 2009 the HiSOC equipment was removed from monitoring well MW-10 and installed in monitoring well MW-25. The hydrogen cylinder was placed on the existing concrete well pad and a protective cover was constructed around the well and above ground protective well casing. The protective cover includes three sides and a top made of dimensional lumber, roofing paper, and asphalt shingles. The east side of the enclosure is open. A new grounding rod was installed. Other details of the HiSOC installation at MW-25 are substantially the same as described for the initial installation. In anaerobic bioremediation applications, the HiSOC supersaturates the treatment well with dissolved hydrogen, typically at a concentration of 1 to 4 parts per million (ppm) depending on the immersion depth of the HiSOC unit in groundwater. The dissolved hydrogen concentration achieved in the injection well depends on the height of the water column in the well. Each atmosphere of pressure allows for a maximum of approximately 1.6 ppm of dissolved hydrogen. Table 2 estimates the dissolved hydrogen concentrations in each of the injection wells. These concentrations are estimated based on the approximate pressure at the installation depth of the HiSOC based on the depth of the water column in the injection wells. The calculation is made with the assumption that 1.6 ppm of hydrogen is dissolved in the groundwater per atmosphere of pressure. Hydrogen is infused from the HiSOC into the treatment well at a typical rate of 28 standard cubic centimeters per minute or approximately 1.4 cubic feet per day. The hydrogen consumption in each of the injection wells is tracked to estimate the 977461 GS009R167 Page 3 of 6 September 30, 2009 Copyright 2009 Kleinfelder remaining service life of the hydrogen cylinders. Table 3 shows the recorded hydrogen cylinder pressures and estimates a date for each injection well that the cylinder should be replaced. It is anticipated that the hydrogen cylinders will be replaced prior to the next quarterly monitoring event scheduled for December 2009. The HiSOC produces a convection current in the well with a designed release bubble from the top of the HiSCC to distribute dissolved hydrogen rich water throughout the screened interval. A curtain of hydrogen rich water disperses around the well into the adjacent groundwater forming a treatment zone allowing enhanced bioremediation to degrade the target contaminants. 4.0 GROUNDWATER ANALYTICAL RESULTS The groundwater field analysis generally indicates that the subsurface environment is within acceptable limits for biodegradation to occur. The field measurements recorded on September 2, 2009 are summarized in Table 4, which includes the preferred conditions for natural biodegradation of chlorinated compounds within the groundwater plume. Conductivity is recorded for quality control and sampling consistency. Volatile organic compounds were detected at levels above their respective North Carolina groundwater quality standards established in 15 NCAC, Subchapter 2L (21- Standards) in each of the twelve monitoring wells sampled. The analytical results are summarized in Table 5 and a historical summary of groundwater sampling results is presented in Table 6. Chain -of -custody documents were maintained throughout the collection and transportation process and are included in Appendix A with the laboratory report. Historical total volatile organic compound concentrations and chlorinated volatile organic compound concentrations for each monitoring well sampled are shown in individual graphs included in Appendix B. The individual graphs of the total VOC concentration for each monitoring well indicate MW-7, MW-13, MW-13D, MW-14, and MW-42 generally have trends of decreasing contaminant levels. The graphs of MW-11 and MW-43D show a decrease when compared to the previous sampling event but have previously shown increases. The graphs of MW-14D, MW-23D, and MW-24 appear to have decreasing trends; however, the most recent concentrations showed an 977461 GS009R167 Page 4 of 5 September 30, 2009 Copyright 2009 Kleinfelder increase. The graph of contaminant concentrations in MW-25 and MW-45 indicates the total VOCs level to be increasing. The increase in contaminant levels in monitoring wells MW-23D, MW-24, and MW-25 is impacted by increases in cis-1,2-dichloroethene and vinyl chloride which are degradation components of tetrachloroethene. Monitoring well MW-24 also showed a rebound in the tetrachloroethene concentration. Total VOCs concentrations detected during the September 2009 sampling event are shown on Figure 4. The current hydrogen injection phase of the corrective action plan targets the reduction of chlorinated hydrocarbon contaminant levels in the groundwater. The oxygen injection phase will target the reduction of petroleum hydrocarbons. The volatile organic compounds targeted during the hydrogen and oxygen injection phases of the corrective action plan are separated in Table 6 by a double line. Total chlorinated hydrocarbons concentrations detected during the September 2009 sampling event are shown on Figure 5. Historical chlorinated hydrocarbon contaminant levels generally follow the trends of total VOCs in the wells that are sampled during this hydrogen phase. The trend of rising tetrachloroethene contaminant concentrations has been of concern in monitoring well MW-25. However, during this sampling event, the tetrachloroethene concentration decreased in comparison to the previous sampling event. 5.0 CONCLUSIONS AND RECOMMENDATIONS The groundwater potentiometric map indicates that the groundwater flow direction at the site is from the southeast to the northwest under a gradient of 0.04 feet per foot as measured between MW-32 and MW-45, Groundwater aquifer characteristics monitored during the sampling event indicate suitable conditions for biodegradation of chlorinated hydrocarbons generally exist at the site. Both the total chlorinated hydrocarbons and total petroleum hydrocarbons contaminant levels in monitoring wells MW-7, MW-11, MW-13, MW-14, and MW-42 have decreased when compared to the groundwater contamination levels during the baseline sampling event in June 2008. Monitoring wells MW-14D and MW-43D were not sampled during the June baseline sampling event; however, contaminant levels in both wells have decreased since their most recent sampling in 2006. Groundwater contaminant levels in monitoring wells MW-13D, MW-23D, MW-24, MW-25, and MW-45 showed an increase. Of these wells, 97746 l GS009R167 Page 5 of 6 September 30, 2009 Copyright 2009 Kleinfelder only MW-25 and MW-45 show an increase in tetra chloroethene since the baseline sampling event. A comparison of total chlorinated hydrocarbons in the ten monitoring wells sampled since the baseline sampling event in June 2008 and the ,June 2009 event indicated a reduction by 52 percent. With the rebound of the tetrachloroethene concentration in MW-24 and the degradation components in MW-23D, MW-24, and MW-25, the September 2009 reduction in total chlorinated hydrocarbons is 35 percent. Corrective action monitoring will be conducted on a quarterly schedule and the next event should be scheduled in December 2009. During the next sampling event, we recommend the following wells are sampled: MW-7, MW-13, MW-13D, MW-14, MW-14D, MW-15, MW-23D, MW-24, MW-25, MW-42, MW-43D, and MW-45. Monthly system checks should also be conducted during the next quarter to monitor the rate of hydrogen consumption of the HiSOC delivery system. Copies of this report have been mailed to the Guilford County Department of Environmental Health in Greensboro, North Carolina and the UIC Program in Raleigh, North Carolina. 977461 G5009R167 Page 6 of 6 September 30, 2009 Copydght 2009 Kleinfelder TABLES TABLE 1: GROUNDWATER ELEVATION DATA Well ID Total Depth (feet TOC) TOC Elevation (feet) Date Water Level Measured Static Water Level feet TOC Groundwater Elevation feet MW-7 29.9 861,19 09/02/09 6.21 854.98 MW-10 33.6 857,68 09/02/09 8.71 848,97 MW-11 25.1 859.26 09/02/09 14.99 844.27 MW-12 16.8 851.50 09/02/09 11.37 840.13 MW-12D 27.0 851.06 09/02/09 11.26 839.80 MW-13 24.2 861.29 09/02/09 16.05 845.24 MW-13D 39.4 860.40 09/02/09 15.49 844.91 MW-14 24.8 859.32 09/02/09 22.31 837.01 MW-14D 41.0 859.26 09/02109 22.51 836.75 MW-15 25.2 857.71 09/02/09 15.65 842.06 MW-16 35.2 863.60 09/02/09 30.26 833.34 MW-23D 57.1 860.90 09/02/09 17.45 843.45 MW-24 58.8 858,81 09/02/09 23.25 835.56 MW-25 168.9 861 A7 09/02/09 25,71 835,76 MW-27 44.0 862.74 09/02/09 12.76 849,98 MW-28 23.8 861.54 09/02/09 7.35 854.19 MW-29 18.8 861.13 09102M9 4.45 856.68 MW-30 73A 862.28 09/02/09 21,58 840.70 MW-31 19.0 861.73 09/02/09 9.91 851.82 MW-32 19.6 861.76 09/02/09 8.86 852.90 MW-33 21.0 861.77 09/02/09 14.28 847.49 MW-34 21.0 860.45 09/02/09 flooded --- MW-40 29.7 860.62 09/02/09 11.11 849.51 MW-41 20.3 860.52 09/02/09 8.83 851.69 MW-42 35.0 865.32 09/02/09 31.25 834.07 MW-43D 53.0 865.47 09/02/09 32.31 833.16 MW-44 28.5 NM --- --- --- MW-45 36.2 861.79 09/02/09 29.33 832.46 Notes: feet TOC = feet below top of well casing NM = Not measured 977461 GS009R167 Page 1 ❑f 1 September 30, 2009 Copyright 2009 Kleinfelder TABLE 2: ESTIMATED DISSOLVED HYDROGEN CONCENTRATIONS AT INJECTION WELLS Well ip Total Depth (feet TOC) TOC Elevation ftet) Bottom Elevation (feet) pate Water Level Checked Level Static Water Le (feet vel Groundwater Elevation (feet) Depth of Water (feet) Estimated Dissolved Hydrogen Concentration (ppm) MW-7 29.9 861.19 831.29 09/02/09 6.21 854.98 23.69 2.7 MW-10 33.6 860.36 826.76 09/02/09 8.71 851.65 24.89 2.8 MW-14D 41.0 859.26 818.26 09/02/09 22.51 836.75 18.49 2.5 MW-15 25.2 857.71 832.51 09102/09 15.65 842.06 9.55 2.1 MW-16 35.2 863.60 828.40 09/02/09 30.26 833.34 4.94 1.8 MW-23D 57.1 860.90 803.80 09/02/09 17.45 843.45 39.65 3.5 MW-24 58.8 858.81 800.01 09/02/09 23.25 835.56 35.55 3.3 MW-29 18.8 861.13 842.33 09/02/09 4.45 856.68 14.35 2.3 MW-34 21.0 860.45 839.45 09/02/09 0.50 859.95 20.50 2.6 MW-43D 53.0 865.47 812.47 09/02/09 32.31 833.16 20.69 2.6 Notes: feet TOC = feet below top of well casing ppm = parts per million Hydrogen concentrations are estimated based on a saturated hydrogen content of 1.6 ppm per atmosphere. 97746 1 GS009R167 Page 1 of 1 September 30, 2009 Copyright 2009 Kleinfelder TABLE 3: ESTIMATED HYDROGEN CONSUMPTION Date Water Original Cylinder Estimated Volume Estimated Date Injection Date Hydrogen Cylinder Level and Pressure on of Hydrogen Days Elapsed Average Hydrogen Cylinder Must be Cylinder Cylinder Since Cylinder Use per bay Well I❑ Pressure 9121Q9 Remaining {cubic Changed Based on Installed Pressure Installation (psilday) (psi) (psi) feet) Pressure Recorded MW-7 07/28/09 2,000 09/02/09 1,000 96 36 27.8 10/04109 MW-14D 07/28/09 1,900 09/02/09 1.100 111 36 22.2 10/17/09 MW-15 07/28/09 2,000 09/02/09 1,350 129 36 18.1 11/10/09 MW-16 07/28/09 1,900 09/02/09 900 90 36 27.8 09l30109 MW-23D 03/27/09 1,900 09l02109 1.200 121 159 4.4 05/09/10 MW-24 07/28/09 2,000 09/02/09 1,450 138 36 15.3 11/29/09 MW-25 07/28/09 2,100 09/02/09 1,150 105 36 26.4 10/11/09 MW-29 07/28/09 2,200 09/02/09 1,700 148 36 13.9 12/26/09 MW-34 05/13/09 2,000 09/02/09 700 67 112 11.6 10/23/09 MW-43D 05/13/09 1,900 09/02/09 0 0 112 17.0 08/27/09 Notes: psi = pounds per square inch All hydrogen cylinders must be replaced prior to the cylinder pressure falling below 50 psi. 97746 1 GS009R167 Page 1 of 1 September 30, 2009 Copyright 2009 Kleinfelder TABLE 4: AQUIFER CHARACTERISTICS FIELD ANALYSIS SUMMARY Monitoring Well Sample p Date Temperature ° [ C } pH Conductivity {rnSlcm} Dissolved Oxygen m jL Redox (mV) Preferred Conditions a 200C 5<pH<9 --- <0.5 mg1L <50 mV MW-7 09/02/09 18.50 8.22 0.237 2.03 54.1 MW-11 09/02/09 18.08 6.24 0.232 0.89 164.9 MW-13 09/02/09 19.81 6.19 0.420 3.65 139.5 MW-13❑ 09/02/09 18.15 6.25 0.440 1.09 83.0 MW-14 09/02/09 15.88 7.06 0.167 6.77 76.2 MW-14D 09/02/09 16.29 6.71 0.265 1.49 -20.2 MW-23D 09/02/09 18.34 7.15 0.909 0.44 -163.3 MW-24 09/02/09 15.83 6.80 0.538 1.00 -86.6 MW-25 09/02/09 15.91 8.08 0.244 0.92 -100.8 MW-42 09/02/09 14.96 7.27 1.125 7.43 68.6 MW-43❑ 09/02/09 15.45 6.99 0.298 0.66 -13.1 MW-45 09/02/09 14.47 7.33 0.467 3.74 22.4 Notes: Redox = oxidation-reduction potential °C = degrees Celsius mSlcm = millisiemens per centimeter mg/L = milligrams per liter, analogous to parts per million mV = millivolts Conductivity is measured for consistency in groundwater sample collection. 97746 1 GS009R167 Page 1 of 1 September 30, 2009 Copyright 2009 Kleinfelder TABLE 5: SUMMARY OF GROUNDWATER SAMPLE RESULTS Parameter NCGS 2L Standard Anaiytical Results Sample ID MW-7 MW-11 MW-13 MW-13D MW-14 MW-14D MW-23D MW-24 MW-25 MW-42 MW-43D MW-45 Collection Date 09/02/09 09J02/09 09/02109 09/02/09 09/02/09 09/02/09 09/02/09 09/02/09 09/02/09 09M2109 09/02/09 09/02/09 Volatile Organic Compounds by EPA Method 6011602 IL Tetrachloroothene 0.7 BDL 4.4 BDL BDL 23.8 27.1 BDL 946 24.8 3.4 337 2.4 Trichloroethene 2.8 BDL 2.3 BDL BDL BDL 1.4 BDL 127 7.9 BDL 11.4 1.1 cis- 1,2-Dichlaroethene 70 556 BDL 47.6 16.7 BDL 8.8 140 760 60.1 BDL 99.4 BDL 11-Dichloroethene 7 6.3 BDL BDL BDL BDL BDL BDL 9.7 1.6 BDL 119 BDL Vinyl Chloride 1 0.015 1 27.3 BDL BDL 5.3 BDL BDL 23.5 121 BDL BDL BDL BDL 1,1-Dichloroethane 1 70 7.8 BDL _ BDL BDL SDL 6DL BDL 6-2 1.1 BDL It7t BDL Total Chlorinated Hydrocarbons 597 7 48 22 24 37 164 1,970 96 3 466 4 Benzene 1 BDL BDL 1.2 BDL BDL 1.8 2.7 537 BDL BDL 3 BDL Toluene 1,000 6.1 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Eth ibenzene 550 519 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Total X lenes 530 468 BDL BDL BDL BDL BDL BDL 13.7 BDL BDL BDL BDL MTBE 200 BDL BDL 3.6 23.1 BDL 1.3 317 77.5 8.9 BDL 16.7 SQL Diisopropyl ether 70 BDL BDL BDL BDL BDL 2.9 6.4 165 9.1 BDL 29.9 BDL Naphthalene 21 288 BDL BDL BDL BDL BDL BDL 15.5 BDL BDL BDL BDL Chloromethane 2.6 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 3.8 BDL Dichloroditluoromethane 1,400 8.7 BDL BDL BDL BDL BDL 8DL BDL BDL BDL BDL 8DL Trichlorotluoromethane 2,100 8DL BDL BDL BDL BDL BDL BDL 32 BDL BDL 3.7 BDL Total Petroleum Hydrocarbons 1,290 0 5 1 23 0 6 325 841 18 0 57 0 Total VOCs 1,887 7 52 1 45 24 43 490 2,811 114 3 523 4 Notes: NCGS 2L Standard = North Carolina Groundwater Standard BDL = Below Detection Limits pg1L = Micrograms per liter, analogous to parts per billion BOLD = Concentration exceeds the NCGS 2L Standard MTBE = Methyl -tent -butyl ether 97746 j GS009R167 Page 1 of 1 September 30. 2009 Copyright 2009 Hleinielder TABLE 6: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample ID Chlorinated H drocarbana Total Chlorinated Hydrocarbons Petroleum hydrocarbons Total Petroleum Hydrocarbons Total VOCs Cailectlan pate Tetra chloroethene Trichloroelhene cis 12 Oichloroethene 1,1 Dichloraethene Vinyl Chloride 1,1- Dkhloroethane 1,2 Dichloroelhane trans-1,2 pichloroethane 1,1,1- Trichioroethane Benzene Toluene Ethylhenzene TotalXylenes MTBE Diisopropylether �2�;nj NCGS 2L Std. 0.7 2.8 70 7 0.015 70 0.38 100 200 i 1,ODD 550 530 200 70 MW-7 09/27/90 790 190 SOL BDL SOL SDL SDL BDL 59 1,039 650 5,30D 1,500 5,700 SOL SDL BDL 13.150 14,199 01/14/92 SOL 360 SDL SDL SOL 8131- BDL BDL BDL 360 480 3,900 2100 7,100 SDL BDL SDL 13.580 13.940 owl1198 SOL SDL SOL 354 SDL BDL BDL BDL 238 592 468 8.920 21200 8.990 SDL BDL SOL 20,578 21.17D 05/25/99 BDL 6DL SOL 723 SDL BDL SOL SDL 347 1.070 253 2,280 2,290 10.800 BDL BDL BDL 15,623 16.693 D412n3 BDL SAL BDL BDL BDL SOL SQL SOL 86 88 SOL 220 2,400 5,700 SOL 60 BDL 8,380 8.468 M30104 SOL BDL 2,3D0 BDL BDL SOL SDL BDL BDL 2,300 SDL 110 1,800 3,800 BDL BDL 520 6,230 8,530 08/16/05 BDL BDL 2,1D0 BDL BDL SDL 8DL BDL BDL 2.100 SDL SQL 1,600 3,020 SDL SDL 1 520 5.140 7,240 D8125106 SDL BDL 2,000 14 SDL BDL SOL 1.5 14 2,030 1.7 23 370 380 11 3.3 82 871 2,901 12114l06 3.6 4 2.100 670 BDL 15 BDL 5.1 13 2,711 4.1 39 1,300 1,660 SOL SDL 440 3.443 6.154 06/05/08 SDL SOL 1,750 SDL BDL SQL SDL SDL SDL 1.750 SAL SDL 1,040 1.200 SQL BDL 401 2,721 4,471 09/04/08 BDL SDL 1,190 SDL BDL BDL SDL BDL BDL i,190 BDL SOL 788 en BDL BDL 301 1.952 3.152 01105/09 BDL SDL 798 BDL BDL BDL SDL BDL $DL 798 SOL BDL 643 598 SDL SDL 30B 1.549 2,347 03/05/09 BQL SAL 935 BDL BDL SDL SAL SOL BDL 935 SDL SQL 749 723 BDL SOL 384 1,B55 2.791 OW24109 BDL BDL 634 BDL BDL BDL BDL SDL SDL 631 SDL SDL 589 526 SOL SDL 210 1,325 1.956 09102/09 SQL BDL 556 6-3 27.3 7.0 SAL BDL 8DL 597 BDL 6-1 519 468 SOL SOL 1 288 1.290 1.8871 MW-8 (abandoned) 09/27190 SDL BDL BDL SOL SDL BDL SAL SOL BDL 0 SOL SDL BQL 1 SDL BOL BDL 1 1 01/14/92 BDL BDL BDL SOL BDL BDL BDL SDL SDL 0 SOL SDL SDL BDL SOL BDL BDL 0 ❑ 05/15/42 SOL BDL BDL BDL SDL BDL SOL SDL BDL 0 BOL SOL BDL SOL SDL SOL BDL 0 0 MW-9 (abandoned) 09/27/90 10 2 SOL SOL BDL BDL BDL SOL BDL 12 2 SOL BDL BDL BDL BDL BDL 2 14 011141W BDL BDL SDL SOL SDL BDL BDL SDL BDL 0 BOL BDL BDL SDL SDL BDL BDL 0 0 0"5/92 SOL SDL SDL SOL SOL SDL SOL BDL SDL ❑ SDL BDL SDL BDL BDL SOL BDL 0 0 MW-10 09/27/90 76 140 SOLMSDL SDL BDL SDL BDL 140 356 2,900 fib BDL 670 SDL SOL BDL 3.636 3,992 01/14/92 BDL 78 SOLSDL BDL BDL BDL BDL 198 2,900 SOL SOL 120 SDL SDL BDL 3.020 3.218 03J71/98 SDL SDL BDLSOL SOL SDL SOL BDL 14 234 SOL BDL BDL BDL BDL SDL 234 248 05126M BDL SOL BDLSDL BDL BOL SDL BDL 0 36 BQL SDL BDL SOL BDL BDL 36 36 SD/10102 5.9 2.3 BDLSDL SDL BDL BDL 7.3 20 220 9.5 16 71 2,200 16 BDL 2,532 2.551 04/22/03 3.2 1.3 BDLBDL SOL $DL SDL 2.6 7 47 SOL BDL BDL 1,1Do 2.9 SDL 1.150 1,157 06130/04 BDL BDL 8.1BDL BDL BDL BDL BQL 8 22 BDL 2.8 5.8 770 2.8 BQL 803 812 081161❑5 BQL SDL SDLBDL BDL BDL BDL SOL 0 43 BDL SAL BDL 680 SDL BDL 723 723 OEV24106 BDL BDL 3 BDL SDL BDL BDL BDL SAL 3 8A SDL SOL SDL 360 4.3 SOL 372 375 MW-11 06WI04 2.1 3 1.4 SDL BDL SOL SOL BDL SOL 7 SOL SOL SDL BDL 4.1 SOL BDL 4 11 08115.105 5 3.6 9.7 SDL BDL SDL SDL SDL BDL 18 SOL SDL SDL BDL 2.2 SOL SOL 2 21 08/24/06 4.9 2.5 5.2 SOL BDL BDL BDL SDL SDL 13 SOL BDL SDL BDL 4.4 BDL BDL 4 17 W05108 6.8 1.5 5.0 SDL BDL BDL BDL BDL SOL 13 SDL SOL SOL BDL BDL BDL BDL 0 13 091D4108 BDL SDL SDL SDL BDL BDL SDL BDL SDL 0 BDL BDL BDL BDL SDL SOL SOL 0 0 01/05/09 2.7 1.6 2.6 SpL SDL SDL SDL BDL BDL BDL BDL SDL BDL 1.1 SOL SDL 1 8 03/MO9 1.3 BDL 1.5 SDL BDL BDL BDL BDL BDL 3 SDL SQL SOL BDL SDL SDL BDL ❑ 3 06/24/09 1 6.6 1.6 4.7 1 BDL SOL BDL SOL BDL SOL 13 BDL BDL SDL SDL BDL SAL SOL 1 14 ❑9102109 4.4 2.3 BDL BDL BDL BDL BDL BDL BDL 7 SDL SDL SOL SDL SDL SOL BDL I 0 7 MW-12 09/27/90 SOL SOL BDL SOL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL SOL BDL BDL 0 0 01/14/92 SDL BDL BDL SOL BDL BDL SAL SOL BDL ❑ BDL SDL SOL BDL SDL BDL SOL 0 ❑ 03/11.'98 SOL BDL BDL SDL SOL BDL SOL BDL BDL 0 SOL BDL BDL BDL BDL SOL BDL 0 0 05/26/99 SDL BDL BDL BDL BDL SDL SOL SDL BOL 0 SOL BDL SDL SDL BDL SOL SOL 0 ❑ DBW04 BDL BDL BDL SOL BDL BDL BDL SDL BDL ❑ SDL BDL SOL SDL SOL SDL BDL 0 ❑ OB115/05 BDL BDL BDL SOL SDL BDL SOL SAL SDL ❑ SDL SDL SDL BDL SDL SOL SDL ❑ 0 08/24/06 BDL SOL $OL BDL SDL BDL SOL BDL SDL 0 SDL BDL BDL SDL SOL BDL SDL 0 0 Notes: All units measured In micrograms per liter, pglL ' Total Petroleum Hydrocarbons and Total VOCs include chloromethane, dichlorodMuoromethene, and Vic hloronuoromelhane values (see Table 5). BDL - Below Detection Limits NCGS 21- St& - North Carolina Groundwater Standard BOLD - Concentration exceeds the 21 Groundwater quality Standard MTBE - Methyl -tart butyl ether 97746 J GS009R167 Copyright 2009 Klein}elder Page 1 of 5 September 30, 2009 TABLE 6: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample ID Chlorinated H drocarhons Total Chlorinated Hydrocarbons Petroleum Hydrocarbons Total Petroleum Hydrocarbons Total VOCs Collection Date Tetrachloroethene Tnchloreethene cis 1,2 Dfchloroethene 1,1 Vinyl Chloride Dichloroethene Dichichloroethane =m0larle 1.2- trans 1,2 Dichloroethane 1,1.1- Trichloroelthane Benzene Toluene Ethylbenzene TotalXylene8 MTBE Diisopropylether Naphthalene NCG52LSid, 0.7 2.8 70 7 0.015 70 0,38 100 200 1 1,000 550 530 200 70 21 MW-12D 09/27/90 BDL SOL SOL BDL SOL SOL BDL BDL BDL 0 BDL SOL SOL SDL BDL BDL SOL 0 0 01/14/92 BDL BDL SOL BOL BDL BDL SOL SOL SOL 0 BDL SOL BDL SOL BDL SOL SOL 0 0 03/11/98 BDL SOL BDL SOL BDL SOL SOL SOL BDL 0 BOL SOL SOL SOL BDL SOL SOL 0 0 0512669 BDL BDL BDL SOL BDL SOL SOL SDL BDL 0 BDL SOL BDL SDL BDL SOL BDL 0 ❑ 06/30/04 SOL BDL BDL SOL SDL BDL SOL SOL SOL 0 BDL SOL SOL 8DL BDL BDL SOL 0 0 08/15105 BDL BDL SOL SOL BDL SOL BE SOL SOL 0 8DL SOL SOL 8DL BDL SOL SOL 0 0 08/24/06 SOL BDL SOL SOL BDL BDL SOL BDL SOL 0 BDL SOL BDL I SOL BDL t SOL I SOL H 0 H 0 MW-13 09/26/90 2 BDL BDL BDL BDL SDL BDL SOL SOL 2 SOL SOL SOL BDL BDL SOL SOL 0 2 01I14192 130 36 SOL BDL BDL SOL BOL BDL SOL 166 BDL SOL SOL BDL BDL BDL BDL 0 166 05/15M 130 20 BDL BDL BDL SOL BOL BDL BDL 150 SOL SOL SOL SDL 8DL BDL SOL 0 150 03l1148- 2.5 4.7 SDL BDL SOL SOL BDL BDL SOL 7 BDL SOL BDL SDL BDL SOL SOL 0 7 05/26PA 4.2 15 SOL BDL SOL SOL BDL BDL SOL 19 BDL SOL BDL BDL BDL SOL BDL 0 19 06/30/04 BDL 6.5 140 BDL SOL SOL SOL BOL BDL 147 SDL SOL BDL SOL 13 BDL BDL 13 160 08/16/05 BDL BDL 110 BDL BDL SOL SOL SDL BDL 110 SOL SOL BDL SDL BDL SDL SOL 0 110 08/24/06 BDL 2.9 110 SOL BDL SOL SAL 1.1 BDL 114 SDL BDL BDL BDL 5.4 SOL BDL 5 119 M05/08 BDL SOL 94.7 SOL BOL SOL SOL SOL BDL 95 6.4 SOL SDL SOL SOL BOL BDL 6 101 09/04/08 SOL SOL 67.9 SOL BOIL BDL SOL SOL SOL 68 BDL BDL BOL SAL SOL BDL BDL 0 68 01/05/09 SOL BDL 66.7 SOL SOL SOL SOL SDL BDL 69 3.2 SOL SDL SOL 52 BDL BDL B 77 03105M BDL BDL 119 SOL SDL BDL BOL BDL SOL 119 SOL SOL BDL SOL It SOL BDL 3 12-2 06/24/69 SDL BDL 812 SOL SOL 8DL BDL BDL BDL 69 BDL BDL BDL SOL SOL SOL SOL 0 69 09/02/09 SAL BOL 47.6 BDL SOL BAL SOL SOL BDL 48 1.2 BDL SDL BOL 3.6 BDL BDL 5 52 MW-13D 06/30/04 SAL BDL 18 SOL 1.5 SDL SDL 60L SDL 20 1.1 BDL BDL SOL 26 1.1 BDL 28 48 OW15105 SOL BDL 37 SOL 1.4 BDL BDL BDL SOL 38 SOL BDL SDL SOL 20 1.3 SDL 21 60 08l24106 SOL BDL 30 SOL 1.3 SOL BDL BOL SOL 31 SAL BOL BDL SOL 19 SOL BDL 19 50 06I05108 BOL BDL 21.6 BDL 3.2 SOL BDL DDL SOL 25 SDL BDL 3.0 3.6 12.5 1.7 SOL 21 46 0910410B SOL BDL 15.2 BDL 3.1 BDL BDL BDL BDL 1B SOL BDL BDL BDL 17.6 BDL B0L 18 36 01/05/09 BDL BDL 17.4 BOL 4.2 BDL SDL BDL SOL 22 SOL BDL BDL SOL 16.3 1 A BDL 17 39 03/05/09 BDL BDL 14.6 SOL 3.4 SOL SDL BDL SOL 1B SOL BDL SOL SOL 13.4 BDL SOL 13 31 ❑6124109 BDL SOL 19.2 9.4 4.1 SOL SOL BDL SOL 33 SOL BOL SOL BDL 20.2 BDL 8DL 20 53 09/02/09 BDL SOL 16.7 SDL 5.3 SDL SOL BDL BDL 22 SOL BDL SOL SOL 23.1 BDL BDL 23 45 MW-14 09/26/90 1,300 SOL BDL SOL SDL BDL SOL SOL BDL 1,300 BDL SOL SOL SOL BDL BOL SOL 0 1,300 01/14/92 1,400 BDL BDL SDL SOL SOL 18O SDL 100 1.680 BDL 60 SOL 100 BDL BDL SDL 760 1,1140 03111M 80 BDL BDL SOL BDL SOL SOL SDL BDL BO BDL SOL SOL BOL BDL BDL SDL ❑ 80 05/25/99 67 BDL SOL BDL SOL SOL BDL SOL BDL 67 SDL BDL BDL BDL BDL BOL BDL 0 67 04/22/03 110 DDL BDL SOL SOL BDL SOL SOL SOL 110 1.1 1.7 BDL 1.9 SDL BDL BDL 5 115 06/30/04 BO BDL SDL SOL SOL SOL BDL SOL SOL 80 BOL SOL BDL BDL 8DL SDL BDL 0 80 08/16/05 58 BDL BDL BDL SOL BDL BOL SOL SOL 58 SDL SOL SOL SOL SDL SOL BDL 0 58 08/24/06 46 BDL SDL SOL BDL BDL BDL BDL SOL 46 BDL SOL BOL BOL BOL SOL BOL 0 46 06/05/08 54.0 BDL SDL BDL SOL SOL BDL SOL SDL 54 BDL BDL BDL BDL SDL SDL SDL 0 54 09/04/08 50.0 BOL SDL BDL SOL SOL BDL SDL SOL 50 SOL BDL SDL SOL SDL SOL BDL 0 50 01/05/09 29.9 BDL SOL BDL SOL SOL BDL SOL SOL 30 SOL BDL SOL SDL BDL SOL BDL 0 30 03/05/09 32 SDL BDL BOL SOL BDL BDL SOL SOL 32 SOL BDL BDL BDL SDL BDL SDL q 32 0&24/09 31.2 SOL BDL SDL SOL BDL BDL BDL SOL 31 SOL BOL BDL BDL SOL SOL BDL ❑ 31 OW02/09 23.8 BOL BDL BDL BDL SOL BDL BDL SOL 24 SOL BOL SDL EL BDL SOL SOL 0 24 M W-140 09/27/90 110 3 BDL 58 BDL 5 BDL SDL 20 196 45 1 SOL 5 SOL SOL SOL 51 247 01/14/92 200 SOL SOL SDL SOL SDL SOL BDL BDL 200 65 3 SOL SOL SDL BOL SOL 68 268 05/15/92 56 BDL SOL 2.1 BDL BDL SOL BDL BDL 58 4.7 SDL SOL BDL SOL SOL SOL 5 63 09/09/92 210 BDL SOL 23 BOL BDL SOL BDL 13 246 220 BDL SOL SOL BDL SOL BDL 220 466 Notes: All units measured in micrograms per liter, ggIL 'Total Petroleum Hydrocarbons and Total VOCs include chlommethane. dchlorodifluoromethane, and trichlorofluaromethane values (see Table 5). SOL - Below Detection Limits N C G S 2L Sid. - North Carolina Groundwater Standard SOLD - Concentration exceeds the 21 Groundwater Quality Standard MTBE - Methyl -tart butyl ether 97746 J G5009R167 Page 2 of 5 September 30. 2009 Copyright 2009 Kleinfelder TABLE 6: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample ID Chlorinated H drocar6ens Total Chlorinated Hydrocarbons Petroleum Hydrocarbons Total Petroleum Hydrocarbons Total VOCs Collection Date Tetrachloroethene Trichloroethene rts-1,2 Dichlaroethene 1.1 Vinyl Chloride Dichloroethene 1,1- Dichbroethane 1,2- Dichloroethane trans-1.2- Dichloroethane 1,1,1- Trichbreethane Benzene Toluene Ethylbenzene Total Xylenes MTBE Diisopropyl ether Naphthalene NCGS 2L Std. 0.7 2.8 70 7 0.015 70 0.38 100 200 5 1.000 550 530 200 70 21 MW-140 (Continued) 03/11i98 3S.4 BDL BDL 10.6 SOL SOL SOL BDL SDL 46 5.8 BDL BDL BDL BDL BDL SOL 6 52 05/25/99 201 SOL BDL 25 SOL SOL SOL SOL BDL 226 67 BOL BDL BDL BDL SOL BDL 67 293 10/10102 79 2.8 BDL 4 BDL 4.2 BDL SOL BDL 90 8.3 SOL SDL SOL 11 29 SDL 48 138 04/22/03 40 BDL BDL 1.2 SOL SOL SOL BDL BOL 41 BDL SOL SOL BDL SOL 1.8 SOL 2 43 06/30/04 29 BDL 3.0 3.5 SOL 2.2 SOL BDL BDL 35 BDL BDL SDL SOL 3.3 BDL SOL 3 38 08/16/05 55 1.8 15 3.3 SOL SOL SOL BDL BDL 75 5.4 SOL SOL BDL 3.2 7.3 SOL 15 91 08/24/06 47 2 17 1.4 SOL BDL BDL SOL BDL 67 12 SOL SOL SOL 2.4 6.4 BDL 10 78 031271D9 10.6 SOL 1.0 BDL BDL BDL SOL BDL BDL 12 BDL SOL SOL BDL SOL SOL SOL 0 12 06/24109 11.7 SDL BDL 130L SOL SOL SQL BDL SOL 12 SOL SOL BDL SOL SOL BDL SOL 0 12 09/02/09 27.1 1.4 8.8 SOL BDL SOL SOL SOL BDL 37 1.8 SOL BDL BDL 1.3 2.9 BQL 6 43 MW-15 09/27/90 BDL SOL SDL SOL BDL SOL SQL BDL BDL 0 SOL SOL BDL SOL BDL BDL SQL 0 0 01/14/92 BDL BDL SOL SOL SOL BDL BDL SOL SOL 0 SOL SOL SOL BDL SOL BDL BDL 0 0 03/11/98 SOL SDL SDL SOL BDL BDL BDL BDL BDL 0 BDL SOL SOL SOL SOL SOL BDL 0 0 05125/99 4.9 3 SDL SOL SOL BDL BDL SDL BDL 8 BOL SOL SOL SOL SOL BDL SQL ❑ 8 10/10/02 13 7.8 SDL SOL BOL 1.4 SOL BDL BDL 22 BDL SOL BDL SOL 29 SOL SOL 29 51 04/22/03 11 5 SOL SOL SOL 1.4 BDL BDL BDL 17 BDL SOL BDL BDL 17 SOL BDL 17 34 06/30/04 7.5 3.9 Bfi BDL SDL SDL SOL BDL BOL 97 BDL SDL BOL BOL 18 60L BDL 18 115 06/16/05 6.B 2.3 d7 SOL SOL SDL BDL SOL BDL 56 BpL SOL BDL SOL 15 SDL BDL 15 71 O8/24106 5.5 5 48 BDL SOL SOL SDL BDL SOL 59 BDL SOL SOL SOL a BDL SOL 8 U 67 MW-16 09/26/90 BDL BDL SOL BDL BDL SOL BDL BDL SOL 0 BDL SOL SOL SOL SOL BDL SDL 0 0 01/14/92 SOL BDL SOL BDL SOL SDL BDL BDL BDL 0 SOL SOL SOL SOL BDL BDL SOL ❑ 0 03/11/98 1.9 BDL BDL BDL SOL BDL SOL BDL BDL 2 SOL SOL BDL SOL SOL SDL BDL ❑ 2 06/02199 2.4 BDL SOL BDL SDL SOL BDL BDL SOL 2 SOL SOL SOL SOL SOL BDL SOL 0 2 10/10/02 22 3.8 SQL 1.8 SOL SDL SOL SDL SOL 26 SDL SOL SOL SDL SOL SDL SDL 0 28 D4/22/03 46 8.6 SOL 3.6 SOL SOL SOL BDL BDL 58 BDL SOL SOL BDL SOL 13DL BDL ❑ 58 06/30/04 31 7.fi 24 2.7 SOL 7 SOL BDL BDL 66 BDL BDL BDL BOL SOL BDL BDL ❑ 66 D8116/05 30 4A BDL 1.8 BDL SOL SDL SOL SOL 36 SOL SOL SOL SOL BDL 17 BDL 17 53 OB125/06 36 7.4 31 2.9 SDL SDL BDL SOL SDL 77 SOL SOL SOL SOL BDL SOL BOL 0 77 MW-17 (abandoned 01/03106) OW26190 i SOL BDL BDL SOL SOL SOL SOL BDL 1 BDL SOL SOL SOL SOL SOL BDL 0 1 01114/92 SQL 3 SOL BOL SOL SOL SOL SOL SOL 3 BDL SOL BDL SOL SOL 8DL BDL 0 3 03/11/98 BDL BDL BDL SDL BDL SOL BDL BDL BDL 0 BDL BDL SOL SOL BDL SOL BDL 0 0 ❑8102199 SOL BDL SOL SDL BDL SOL SDL SDL SOL ❑ BDL BOL SOL SOL SOL BDL SOL 0 0 06130/04 SOL BDL BDL SOL SOL SOL BDL BDL SOL 0 BDL SOL SOL SOL 17 SDL SOL 17 17 MW-23D 09127/90 SOL 2 BDL SOL BDL 5 5 SOL SOL 12 1 SOL SOL SOL SOL BDL SOL 1 13 01/14/92 BDL BDL BDL BDL BDL BDL BDL SDL BDL 0 BDL BDL SOL BDL SOL BDL BDL 0 0 05/15/92 BDL 2.2 BDL SOL SOL 5.3 SOL SOL SOL 8 45 BDL SOL SOL BDL BDL BDL 45 53 09/09/92 1.9 6.3 BOL 5.4 BOL 6.5 2 SOL SOL 22 6.3 SOL BOL SOL BDL SOL BDL 6 29 03/11/98 2.5 2.5 BDL 1.4 BDL 2.9 SOL SOL 4 13 7.1 3.7 SOL SOL BDL SOL BDL 11 24 05/26/99 SOL 4.1 BDL 2.4 BDL 5.7 216 BDL SOL 15 3.1 SOL BDL SOL SDL BDL BDL 3 18 06/301D4 BDL BDL 20O SOL BOL BDL SOL SOL SOL 20❑ SOL SOL BDL SOL 500 12 SOL 512 712 08/15/05 SQL BDL 280 SOL BOL SOL SOL SOL SDL 280 BDL BDL SDL BDL 31D BDL BDL 310 590 OB124106 BDL 1.1 340 SOL 1.9 BDL BDL SOL SDL 343 1.0 SOL SOL BDL 310 9.1 BDL 321 66.4 06/05*8 SOL SOL 166 BDL SDL SOL BDL SOL SOL 166 SOL BDL 20.2 23.6 208 SOL BDL 252 418 09/04108 BDL SOL 5.3 BDL SDL BDL SOL SOL SOL 5 BDL BDL BDL SOL 19.3 BDL BDL 19 25 Notes: All units measured in micrograms per liter, NgIL ' Total Petroleum Hydrocarbons and Total VOCs include chimomethane, dichloroddluorc metha ne, and trichlorolluoromelhane values (See Table 6). BDL - Below Detection Limits N C G S 2L Std. - North Carolina Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl-tert butyl ether 977461 GS009R1 B7 Page 3 of 5 September 30, 2009 Copyright 2009 Kleinlelder TABLE 6: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample ID Chlorinated N drocerbons Total Chlorinated Hydrocarbons Petroleum Hydrocarbons Total Petroleum hydrocarbons Total VOCs Collection Date Tetrachloroethene Trichloroethene cis-1,2 Dichloroethene 1.1- Dichloroethene vinylCh"e 1,1 Dichloroethane 1,2 Dichloroethane trans-1,2• Dichloroethane 1,1,1- Tdchloroethane Benzene Toluene Ethylbenzene Total Xylenes MTBE Diisopropylether N;phalene NCGS 2L Std. 0.7 2,8 70 7 0.015 70 0.38 100 200 1 1,000 550 530 200 70 1 MW-23D (Continued) 01/05/09 BDL SDL 15.3 BDL BOL BDL BDL SOL BDL 15 I BDL I BDL SOL I SOL 1 37.6 SOL I BDL 1 38 53 03/05109 SOL SOL 173 SOL 19.4 1 A BDL BDL SOL 194 1.7 BDL SOL SOL 194 SOL SOL 196 389 06/24/09 SOL SOL 107 BDL BDL SOL SOL BDL SOL 107 SOL BDL SOL SOL 331 SOL SOL 331 438 09/02/09 BOIL SOL 140 BOL 23.5 SOL BOL SOL BDL 164 2.7 SOL BDL BDL 317 6,4 SOL 326 490 MW-24 09/27/90 630 28 BDL 6D SOL SOL BDL SOL SOL 718 11500 80 SOL 80 SOL BDL SOL 1.660 2,378 01/14/92 3,860 110 BDL 200 SOL SOL 56 BDL 80 4,246 1,800 260 SOL 340 BDL BDL SOL 2,400 6.646 06/15/92 1,400 25 BDL 4,9 SOL SOL SOL SOL SOL 1,430 1,80D 180 BDL BDL BDL SOL BDL 1,980 3.410 09109192 2,700 SOL BDL BDL BDL BDL BDL SOL 100 2,800 2,500 150 SOL 150 BDL SOL SOL 2.800 5.600 03/11/98 1,230 BDL SDL BDL BDL SOL BDL SOL BDL 1,230 1,920 SOL BDL BDL SOL BDL SOL 1,920 3,150 05/25/99 637 SOL SOL SOL BDL SOL BDL BDL SOL 637 1,510 SDL SOL BDL BDL SOL BDL 1,510 2.147 10/10/02 2,000 68 SOL 31 SOL 11 2.5 BDL 4.9 2,117 1,700 16 1,4 27 180 630 BDL 2,454 4,572 D4122103 640 24 SOL 17 SDL 6A BDL BDL 1.8 689 500 6.4 SOL 6,3 81 180 SOL 774 1,463 06/30/44 87D BDL 370 BDL BDL BDL BDL BDL SOL 1,240 280 BDL SOL SOL 74 260 SOL 554 1,794 08/16/05 1,3D0 62 570 SDL BDL SOL SDL BDL SOL 1,932 420 BDL SOL SOL 69 170 SOL 659 2,591 08/24/06 2,200 84 770 15 BDL 6.4 1.2 1.2 5.5 3.083 660 4,8 SOL 10.4 78 160 5.6 919 4,002 06/05/08 1,940 BDL 545 SOL BDL BDL BAL SOL SOL 2,385 210 SDL SOL SOL 561 140 SOL 405 2,-M 09/04/08 1,430 51.7 349 SOL BDL SOL SOL SDL BDL 1,831 253 SOL SOL BDL BOL 60.3 SOL 313 2,144 01/05/09 1,610 78.4 517 SOL SOL BDL BDL SOL SOL 2,205 280 BOL SOL SOL 70.9 116 BDL 467 2.672 03105/09 11250 BDL 466 BDL BDL SDL BDL SDL BDL 1,716 117 BDL BDL BDL 8131- BOL BDL 117 1,833 06/24/09 484 BDL 119 BDL BDL SOL SOL SAL BDL 603 SOL BDL BOL SOL SDL BDL SOL 0 603 091D2109 946 127 760 9.7 121 6.2 BDL BDL BDL 1,970 537 BDL BOL 13,7 77.5 165 15.5 841 2,811 MW-25 03/11/98 8.9 3.5 BDL BOL BDL SOL BDL BDL SDL 12 SOL SOL BOL BDL SDL SOL SOL 0 12 05126199 10 3.6 SOL BDL SOL BDL BDL SOL SOL 14 SOL SOL SOL SOL SOL SOL BDL 0 14 06/30/04 8.1 3.5 92 BDL SOL SOL SOL BDL BDL 22 SOL SOL SOL SOL SDL 4,4 SOL 4 26 0811"5 17 3.9 31 BDL BDL BDL SOL BDL SDL 52 SOL SOL BDL SOL 3.6 SOL SOL 4 56 OW25106 20 4.8 51 SOL BDL SOL SOL 9DL SOL 76 SOL BDL SOL SOL 1,8 4.3 BDL 6 82 06/05/08 11.7 3.2 23.5 BDL SOL SOL BDL SOL GDL 38 SOL BDL 1.3 SOL 2.2 4.2 BDL 8 46 09/04/08 1&7 5.2 33.2 SOL SOL SOL BDL BOL SDL 57 BDL I SDL I SOL SOL 3 4,8 SOL 8 65 01/05109 2M 615 46.6 1.1 SOL 1.1 SOL BDL BDL 78 BDL SDL SOL SOL 4,8 6.2 BOL 11 89 03/05/09 24.9 0.3 51 1.1 BDL BDL SOL SDL BDL 85 SDL SOL SOL BDL 4,8 BDL SDL 5 90 0&24109 30.8 7.4 54.7 2,4 BDL BDL BDL SOL SOL 95 SQL SOL BDL BDL 5,9 6.9 BDL 13 108 09/02109 24.0 7.9 60.1 1.6 SOL 1 A BDL BDL SDL 96 SOL SOL SOL SOL 8.9 9.1 SOL 18 114 MW-26 (abandoned 01/03106) 07/01/04 BDL BDL SOL SOL SOL SOL SOL BDL SOL 0 BOL SOL SOL SOL BDL SOL BDL 0 0 OB115105 BDL SOL SOL BDL BDL SOL SOL BDL I SOL U 0 BDL I SOL I BDL I 8131L I SOL I SOL I SOL L0 0 MW-27 10/10/02 SDL BDL SDL SDL BDL BDL SOL I SDL T BDL 0 2.3 2 1 47 1 18 1 2,3 1 SOL I BDL H 72 11 72 07/01/04 OOL SOL SOL BDL SOL SOL BDL BDL BDL 0 5.4 2.7 34 7.9 11 BDL 17 78 78 08/16/05 BDL SOL SOL SDL BDL SOL BDL SDL SOL 0 12 4.1 180 34 3.5 SOL 30 264 264 11/01/06 BDL BDL SDL SOL SDL SOL SDL SDL SOL ❑ 5.2 2,4 38 3.1 BDL SOL 16 66 66 MW-28 10/10/02 SOL BDL SDL BDL 8131 SOL SOL SOL SOL 0 10 2.2 45 22.5 BDL 2,3 BDL 82 82 07/01/04 SOL SOL SOL SOL SOL BDL SOL SDL BDL 0 95 51 4,500 1,OE5 BDL BDL 480 3,191 3.191 08/15/05 BDL SOL BDL SOL BDL SOL SOL BDL BDL 0 210 78 2,3D0 750 SOL SOL 740 4,078 4,076 08/25/06 SOL SOL SOL SOL SOL SOL BDL SOL SOL 0 170 56 2,500 1,200 BDL SOL 800 4.726 4,726 12/14/06 SOL BDL BDL BDL BOL SOL SOL SOL SOL 0 100 BDL 2,500 530 SDL SOL 940 4,070 4,070 MW-29 07/01/04 23 8131- 2110 BDL BDL SOL BDL BDL SOL 303 SOL BDL 21 BDL SOL SOL BDL 21 324 08/15/05 39 4.2 29 SOL SDL 8DL SOL SOL SOL 72 SOL SDL SDL BDL SOL BDL BDL 0 72 08/25/06 5 2.2 38 BDL SOL BDL SOL A BDL BOL H 45 a SOL I BDL I SOL I SOL BDL BDL BDL 11 0 45 Notes: All units measured in micrograms per liter, u911- ' Total Petroleum Hydrocarbons and Total VOCs include chioromethane, dichloroddluoramethane, and Vic hlorofluoromethane values (see Table 5). BOL - Below ➢election Limits NCO 2L Std. - North Carolwla Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl -ten butyl ether 97746 1 GS009R167 Page 4 of 5 September 30, 2009 Copyright 2W09 Kleintelder TABLE B: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample ID Chlorinated Hf drocarbona Total Chlorinated Hydrocarbons Petroleum Hldrocar6ons Total Petroleum Hydrocarbons Total VOCs Collecton pate Tetrachioroethene Trichloroethene '2 DichlorWhene 1'1 DrchbMethene Vinyl Chloride 1,1 Dichloroelhane 1,2 Dichloroethane trans 1,2 Oichloroethane 7,1,1 Thchl 'roethane Benzene Toluene =E1hy0-nzene Total Xyienes I MTBE I Diisopropyl other I Naphthalene NCGS 2L Std. 0.7 2.8 70 7 0.015 70 0.38 100 200 1 1.000 550 53D 200 70 21 MW-30 071011❑4 SOL SOL SOL BDL BOL BDL BDL BDL BDL 0 SOL SOL SOL BDL 2,200 BDL 80L 2,200 2,200 08/16/05 BDL SOL 200 43 77 BDL BDL BDL BDL 320 74 SOL 58 BDL 510 SOL SOL 642 962 0B125106 SOL SAL 23 2.5 i6 BDL SOL BDL SOL 42 23 L SOL 2.6 2 1,500 13 SOL 1,541 1,582 MW-31 1Oil 0/02 SOL BDL SOL SOL SOL SOL SOL BDL SOL 0 SOL 320 2,600 7,900 SAL BDL 8DL 10.820 10,620 D4122JG3 SOL SOL SOL BDL SOL SOL SOL SOL SOL 0 SOL 310 1300 4,600 SOL SOL SOL 5.710 6,710 07/01/04 SOL SAL 53 BDL SOL BDL SOL BDL BDL 53 18 84 590 1,360 SOL SOL 400 2.462 2,505 00/15/05 8DL BDL 48 BDL SOL SOL BDL SOL BDL 48 SOL 67 1,100 1,490 SOL BDL 750 3.407 3,455 11/01/06 SOL SOL SOL SOL SOL 8DL SOL BDL BDL 0 SOL BOL 1,700 390 SDL BDL 720 2.810 2,810 MW-32 07/01/04 BDL SOL SOL BDL BDL BDL SOL BOL SOL 0 SOL SOL SOL SOL 290 L BDL BDL 290 290 08/15/05 SOL SOL SOL $DL SOL SOL SOL SOL SOL 0 SOL SOL SOL SOL 1B0 L SOL SOL 180 180 08/25/06 SOL SOL BDL SOL SOL SOL BOL SOL SOL 0 1,400 280 190 600 15,000 32 160 17,662 17.662 1 V01106 SOL BOL SOL SOL SOL BDL SOL BDL SOL 0 1,400 320 340 900 20,000 8DL SOL 22,960 22,980 12l14/06 SOL SOL BDL SOL SOL SOL SOL SDL SOL ❑ 1.500 3.700 1,700 8,000 16,000 SOL 1,100 32,000 320❑0 M W •33 10/10/02 SOL SOL SOL BDL SOL BDL BDL SOL SOL 0 SOL BDL BDL SOL SOL SOL BDL 0 0 06/30/04 BDL SOL 1.6 BDL SOL BOL SOL SOL BDL 2 SOL BDL SOL SOL SAL BDL SOL 0 2 ❑6i5/05 SOL BDL 5.6 SAL BDL BDL BDL SOL SAL 6 BDL SOL SOL SAL BDL SOL SOL 0 6 ❑8125106 SOL BDL 5.7 SOL SOL BDL SOL SOL BDL 6 SOL SOL BDL SOL SOL SOL BDL 0 6 MW-34 G4122103 SOL 100 BDL 15 SOL 7.2 SOL SOL SOL 122 SOL SOL BDL SOL BDL SOL BDL 0 122 07/01/04 BOL 130 63 6.3 SOL 7.4 BDL SOL BOL 207 BDL BDL BDL SOL SOL SOL BDL G 207 ❑8116/05 SOL 90 37 SOL BDL $DL SOL SOL SOL 127 BDL BDL BDL SAL SOL SOL SOL 0 127 08/25/06 SOL 59 24 4.8 BDL 2.3 SOL SOL BDL 90 SOL SAL SOL BDL SOL BDL BDL 0 90 M W -40 11101*6 SOL SOL BOL SOL SOL BDL SOL SOL BDL 0 250 230 280 652 BDL SOL 130 1,442 1.442 MW-41 04)22J03 SOL SOL SOL BDL SOL BDL BDL SOL BDL 0 7,200 6,600 2,400 10,800 SOL SOL BDL 27,0D0 27.000 07/08/04 SOL BDL BDL BDL BOL SOL SOL BDL SOL 0 7,000 6,600 2,600 13,300 SOL 520 770 30,790 30.790 06/16/05 SOL SAL SOL SOL BDL SOL SDL SOL SOL 0 6,400 4,900 2,500 9,700 SOL 230 780 23.510 23.510 08/24/06 BDL SOL SOL SOL SOL BDL 9DL BDL BDL 0 3,100 3.000 1,000 2,900 BDL 6.4 16 10,022 1❑,022 M W -42 011101D6 36.0 SOL 7.5 6.1 BDL 1.6 SOL BOL BDL 51 BDL SOL SOL SOL BDL SOL 3.2 3 54 08/25/06 27.0 SOL 4.7 3.5 SOL 1.5 BDL BDL BDL 37 SOL BDL SOL SOL SOL SOL BDL 0 37 06/05/08 5.3 SOL BDL SOL SOL SOL SOL BDL SOL 5 SOL SOL SOL SOL BDL SOL BDL 0 5 09/04/08 6.7 SOL SOL SOL SOL SOL SOL BDL SOL 6 BDL BDL SOL SOL BDL SOL SOL ❑ 6 01105/09 5.3 BDL 80L BDL SOL BDL BDL BDL SOL 5 BDL BOL SOL SOL BDL SOL BDL ❑ 5 03/05/09 2.7 SOL SOL SOL BDL B➢L BDL SOL SOL 3 BDL SOL BDL SOL SOL SOL BDL 0 3 06/24/09 3.1 BOL BOL SDL BRL BDL SDL BDL BDL 3 BDL BDL BDL BDL SOL SDL BDL Q 3 D9102/09 3.4 BDL SOL BDL BDL BDL SOL SOL $➢L 3 BDL BDL BDL BOL BDL SOL BDL 0 3 MW-43D 01/10/06 390 12.0 110 42.0 SOL 6.8 BOL I SDL f SOL H 567 1 4.8 1 BDL I BDL BOL 1 36.0 1 68.0 1 BOL 109 670 03/27/09 BOL SOL BDL 9.3 BDL BDL 1.6 BDL 1.2 12 9.0 BDL 7.5 SOL 3.6 SOL 4.4 25 37 0674109 381 11A 114 SOL BDL BOL SOL SOL SOL 507 BDL SOL SOL SOL 13.6 BDL SOL 14 520 09/02/09 337 11A 99A 13.9 BDL 3.9 SOL SOL SOL 466 3 BOL SOL SOL 167 29.9 SOL 57 523 MW-04 04/11/07 BDL 2.1 SOL BOL BDL SOL SOL BOIL SOL 2 SOL SOL SOL BDL BDL SOL BDL ❑ 2 M W -45 09/13/07 SOL SOL SOL SOL SOL SOL BDL SOL BDL 0 SOL BDL SOL SOL SAL SOL SOL ❑ 0 06/05/08 1.2 SOL SOL SOL BDL SOL SOL SOL SOL 1 BDL SOL 8DL SOL BDL SOL BDL 0 1 09/041❑B BDL BDL BDL SOL SOL SOL SOL BDL SOL 0 SOL SOL BDL SOL BOL SOL SOL ❑ 0 01105/69 1.4 1.2 SOL SOL SOL SOL BDL BDL SOL 3 BDL BDL BDL SOL SOL SOL SOL ❑ 3 U051❑9 1.3 BDL BDL SOL SOL BOL SOL SOL SOL 1 BOL SOL BOL SOL SOL BDL SOL 0 1 06/24/09 1.8 SOL BDL SOL SOL SOL SOL SOL BOL 2 SOL SOL BDL BDL BDL SOL SOL 0 2 ❑91021Q9 2A 1.1 BDL SOL SOL SOL SOL SOL SOL 4 BDL BDL BDL 8➢L BDL BDL SOL 0 4 Notes: All units measured in micrograms per liter, pg/L 1 Total Petroleum Hydrocarbons and Total VQCs include chioromethane, dichloroditluoromethane, and trichlorotluoromethane values {see Table 5). BDL - Below Detection Limits NCGS 2L Sid. - North Carolina Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl-terl bulyl ether 97746 1 GS009R167 Page 5 of 5 September 30, 2009 Copyright 2DD9 Kleintelcor FIGURES KL EINFEL DER Bright People. Right Solutions. 313 GALLIMCRE OA;HY ROM GREENSBORO, NORTH CAROLINA PHONE: 336.888.OD93 FIGURE 1 SITE LOCATION MAP GilbarCO 7300 West Friendly Avenue Greensboro, North Carolina DATE: 9-17.2009 USGS 7,5' TOPOGRAPHIC MAP. APPROVFD BY: SCALE: V = 2.000' 1� L_ MW-45 �r •.$i- MW-42 MW-12b r - - MW-12 MW-14 SUB STATIaNJ RW- WATER —Y TANK Syr Y� MW-41 N MW-13b G A MW-11 MW-13 MW-qp j' i RW-3 RW-2 I EXISTING PARKING ISTING IRKING EXISTING PARKING M W-45 832.46 A� 835 833.34 e� 833.16 MW-42 842.06 834.07 MW-12 835 W-13 837.01 835-76 ~ SUB 835 �Y•' 836.75 Rmac- TAiJi{ MW-10 8'10 MW-41 F 848-9� MW-130 851.69 N 844.91 y- MW-40 RW-3 1 845 9-51 -2 ❑ 1. 98 MW-11 850 gs= $44-27 843.45 858.68 r M W-28 856 RW-4 864.19 Mw-33 M W-31$. 847.49 851.82 64r, M W-32 862.90 MW-27 MW-30 849-98 ` 840-70 4 MW-44 855 LEGEND EXISTING INJECTION WELL LOCATION AND BUILDNO r 854.98 GROUNDWATER ELEVATION MW-14 MONITORING WELL LOCATION AND 837-01 GROUNDWATER ELEVATION RW-7 RECOVERY WELL LOCATION M-,- GROUNDWATER CONTOUR LINE NOTES- GROUNDWATER ELEVATIONS WERE RECORDED SEPTEMBER 2, 2W9 w - 839 80 • -1F -1F mac- �- -iF �F �F --AF -JI-- 845 J� MW-13 845.24 856 85a EXISTING PARKING MONITORING WELLS MW-13D, MW-23D, AND MW-25 ARE SCREENED BELOW THE WATER TABLE AND WERE NOT USED TO GENERATE THE GROUNDWATER CONTOURS EXISTING PARKING M W-45 4 , MW-42 3 2.811 M W-14 24 43 may,. �W BOL LEGEND r. INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION} WITH 31 TOTAL VOCS CONCENTRATION (uq/L) RW-7 RECOVERY WELL LOCATION 1 D0� TOTAL VOCs ISOCONCENTRATION LINE NOTE: SAMPLES COLLECTED ON SEPTEMBER 2. 20M lT4 4$�MW-120 MW-12 Mr STATI WATER TANK MW-10 MW-41 ¢ MW-13D 45 fMW-13 RW-3 MW-40 MW-11 SQL •r �W ] R W-2 1.887 438 1.000 100 MW-28 BOL M W-31 RW-4 10.000 MW-27 EfI TNG BUILDNO MW-30 `f MW-44 EY.ISTING PARKING r' �l MW-45 sr s MW-42 466 3 �{1() MW-12D yr MW-14 1,g70 MW-12 24 Sue L x —� 96 I ATIONJ T 37 R WATER �w TANK i3GL F MW-10 MW-430 MW-41 ¢ 22 �RW-3 c MW-13 -40 MW-11 ■ 48 ..., ,i Rw 2 591 7 •� ` 164 MW-28 -RW d MW-31 MW-32 MW-33 MW-2 �4 i i MW-30 41 MW-4 EXISTING PARKING EXISTING PARKING EXISTING LEGEND BUILDNG ',. INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION WITH 31 TOTAL CHLORINATED HYDROCARBONS CONCENTRATION (ug/L) 0 RW-7 RECOVERY WELL LOCATION TOTAL CHLORINATED HYDROCARBONS ISOCONCENTRATION LINE FIGURE 5 TOTAL CHLORINATED HYDROCARBONS NOTE: SAMPLES COLLECTED ON SEPTEMBER 2, 2009 JCL EINFEL DER t Frieno 73ee sbor Friendly Avenue Bright People. Right Solutions. Greensboro, North Carolina APPROVED By 313 GALLIMORE DAIRY ROM DATE: 7-31-2009 SCALE: 1' = 100' GREENSBORO. NORTH CAROLINA PHONE: 336-SG6.0093 (/!6 /�_1^p DRAWN BY: GGL v y PROJECT NO! 9774fi APPENDIX A e aceAnalylical www.peCMW&.COM Pace Analytical Services, Inc. 2225 Riverside Or. Asheville, NC 2a804 Pace Analytical Services, Inc, 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 September 14, 2009 Ms. Gail Licayan Trigon/Kleinfelder, Inc. 313 Galiimore Dairy Rd Greensboro, NC 27409 RE: Project: GILBARCO 97746 Pace Project No.: 9252397 (828)254--7176 Dear Ms. Licayan: Enclosed are the analytical results for sample(s) received by the laboratory on September 03, 2009. The results relate only to the samples included in this report_ Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Bonnie McKee bonnie.mckee@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS (704)875-9092 Page 1 of 21 This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. aceAnalytical. www.pecelabscarr t Project GILBARCC 97746 Pare Project No.: 9252397 Charlotte Certification IDs Connecticut Certification #: PH-0104 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana/LELAP Certification #: 04034 New Jersey Certification #: NC012 North Carolina Drinking Water Certification #: 37706 West Virginia Certification #: 357 Pace Analytical Services, Inc. 2225 Riverside Or. Ashevllle. NC 28804 (828)254-7176 CERTIFICATIONS North Carolina Wastewater Certification #: 12 Pennsylvania Certification #: 68-00784 South Carolina Certification #: 990060001 South Carolina Drinking Water Cent. #: 990060003 Tennessee Certification #: D4010 Virginia Certification #: 00213 North Carolina Field Services Certification #: 5342 REPORT OF LABORATORY ANALYSIS Pace Analytical Services, ]no. 9800 Kin ceyAve . Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 21 This report shall not he reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. aceAnalytical 2225 Riverside Rr. www.pacews.eam Asheville. NC 28804 (82$)254-7176 SAMPLE SUMMARY Project. Pace Project No.: GILBARCO 97746 9252397 Lab lR Sample ID Matrix Date Collected Rate Received 9252397001 MW-7 Water 09/02/09 1404 M03109 13:38 9252397002 MW-11 Water 09/02/09 09:37 09/03/09 13:38 9252397003 MW-13 Water 09/02/09 09:10 09/03109 13:38 9252397004 MW-131) Water 09/02/09 09:06 09/03/09 1138 9252397005 MW-14 Water 09/021091120 0910310913:38 9252397006 MW-23❑ Water 09/02/09 09:03 09/03/09 13:38 9252397007 MW-24 Water 09/0210912:56 09103/0913:38 9252397000 MW-25 Water 09/0210913:00 09103/0913:38 9252397009 MW42 Water 09102M914:52 0910310913:38 9252397010 MW-43D Water 09102/0914:48 09/03/0913:38 9252397011 MW-45 Water 09/02/0915:05 09/03/0913:38 9252397012 MW-14Q Water 09/02/0913:12 09/03/0913:38 REPORT OF LABORATORY ANALYSIS This report shall riot be reproduced, except in full. without the written consent of Paacee Analytical Services, Inc.. la t. Pace Analytical Services, Inc. 9800 Kin cey Ave. Smote 100 Huntersville, MC 28078 (704)875-9092 Page 3 of 21 aceAnalydrcal wuNpq(" +abs.cam Project: GILBARCO 97746 Pace Project No-: 9252397 Pace Analytical Services, Inc. 2225 Riverside Or. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 913M Kincey Ave. Suite 100 Huntersville, NC 28078 (7041875-9092 Lab ID Sample I❑ Method Analysts Analytes Reported 9252397001 MW-7 SM 6200B MCK 43 9252397002 MW11 SM 6200B MCK 43 9252397003 MW-13 SM 6200B MCK 43 9252397004 MW-13❑ SM 6200B MCK 43 9252397005 MW-14 SM 62008 MCK 43 9252397006 MW-23❑ SM 6200E MCK 43 9252397007 MW-24 SM 6200B MCK 43 9252397008 MW-25 SM 6200B MCK 43 9252397009 MW-42 SM 6200B MCK 43 9252397010 MW-43D SM 6200B MCK 43 9252397011 MW45 SM 6200B MCK 43 9252397012 MW-14D SM 62008 MCK 43 REPORT OF LABORATORY ANALYSIS This report shall act De reproduced, except in Full, without the written consent of Pace Analytical Services, Inc.. Page 4 of 21 aceAnalytiea! www.p&ow8b&wM Pace AnalyticaI Services, Inc. 2225 Riverside ❑r, Asheville, NC 28804 (828 y254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. suite 100 Huntersville, NC 28078 {7041875-9092 Project: GILBARCO 97746 Pace Project No.: 9252397 Sample: MW-7 Lab ID: 9252397001 Collected: D9102109 14,04 Received: 09/03/09 13:38 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 601/602 Volatiles by SM 6200 Analytical Method: SM 6200B Benzene NO ug/L 5.0 5.0 5 09/10/09 10:24 71-43-2 BromOdiohloromethane NO uglL 5.0 5.0 5 09/10/09 10:24 75-27-4 Bromoform NO ug/L 5.0 5.0 5 D9110109 10:24 75-25-2 Bromomethane NO ugIL 5.0 5.0 5 09/10/09 10:24 74-83-9 Carbon tetrach#oride N❑ uglL 5.0 5.0 5 09110/09 10.24 56-23-5 Chlorobenzene NO uglL 5.0 5.0 5 09110109 10:24 108-90-7 Chloroethane NO uglL 5.0 5.0 5 09/10/09 10:24 75-00-3 Chloroform ND uglL 5.0 5.0 5 09110/09 10:24 67-66-3 Chloromethane ND uglL 5.0 5.0 5 09/10/09 10:24 74.87-3 Dibromochloromethane NO uglL 5.0 5.0 5 09/10/09 10:24 124-48-1 1,2-Dibromoethane (EDB) NO ug/L 5.0 5.D 5 09/10/09 1D:24 105-93-4 1,2-Dichlorobenzene NO ug/L 5.0 5.0 5 09/10109 10:24 95-50-1 1,3-Dichlorobenzene NO ug/L 5.0 5.0 5 09110/0910:24 541-73-1 1,4-Dichlorobenzene N❑ ug1L 5.0 5.0 5 09110/0910:24 106-46-7 Dichlorodifluoromethane 8.7 ugIL 5.0 5.0 5 09/10/09 10:24 75-71-8 1.1-Dichloreethane 7.8 ug/L 5.0 5.0 5 09/10/09 10:24 75-34-3 1,2-Dichioroethane NO ugIL 5.0 5.0 5 09/10/09 10:24 107-06-2 1,1-Dichiomethene 6.3 ug1L 5,0 5,0 5 D9110109 10:24 75-35-4 cis-1,2-Dichloroethene 556 ugIL 5.0 5.0 5 09/10/09 10:24 156.59-2 trans-1,2-Dichloroethene ND uglL 5.0 5.0 5 09/10/09 10:24 156.60-5 1,2-Dichloropropane NO ug/L 5.0 5.0 5 09/10109 10:24 78-87-5 cis-1,3-Dichloropropene N❑ ug/L 5.0 5.0 5 09/10/09 10:24 10061-01.5 trans-1,3-Dichloropropene ND ug/L 5.0 5.0 5 09/10/09 10:24 10061-02-6 Diisopropyl ether NO ug1L 5.0 5.0 5 09/10/09 10:24 108-20-3 Ethylbenzene 519 ug1L 5.0 5.0 5 0 9110/0 9 1 D: 24 100-41-4 Methylene Chloride NO uglL 10.0 1 D.0 5 09/10/09 10:24 75-09-2 Methyl-tert-butyl ether NO ug/L 5.0 5.0 5 09/10/09 10:24 1634-04-4 Naphthalene 288 uglL 10.0 10.0 5 09110/0910:24 91-20-3 1,1,2,2-Tetrachloroethane NO ugIL 5.0 5.0 5 09/10/09 10:24 79-34-5 Tetrachloroethene N❑ ugIL 5.D 5.0 5 09/1010910*24 127-18-4 Toluene 6.1 ugJL 5.0 5.0 5 09/10/09 10:24 108-88-3 1.1,1-TrichIoroethane N❑ uglL 5.0 5.0 5 09/10/0910.24 71-55-6 1,1.2-Trichloroethane ND uglL 5.0 5.0 5 09/10/09 10:24 79-00-5 Trichloroethene N❑ ug1L 5.0 5,0 5 09/10/09 10,24 79-01-6 Tri ch lorofluorom ethane ND ug/L 5.0 5.0 5 09/10/09 10:24 75-69-4 Vnyl chloride 27.3 ugIL 5.0 5.0 5 09/10/09 10:24 75-01-4 Xylene (Total) 468 ug1L 10.0 10.0 5 09/10109 10:24 1330-20-7 m&p-Xylene 447 ug1L 10.0 10.0 5 09110/0910:24 1330-20-7 o-Xylene 21.5 ug1L 5.0 5.0 5 09/10/09 10:24 95-47-6 4-Bromofluorobenzene (S) 100 % 70-130 5 09/10/09 10:24 460-00-4 Dibromofluoromethane (S) 102 % 70-130 5 09/10/09 10:24 1868-53-7 1,2-Dichioroethane-d4 (S) 102 % 70-130 5 D9110109 10:24 17060-07-0 Toluene-d8 (S) 96 % 70-130 5 09/10/09 10:24 2037-26-5 Date: 09/14/2009 09:56 AM REPORT OF LABORATORY ANALYSIS Page 5 of 21 This report shall not be reproduced, except in full, without the written consent of Pace rAnalytical Services, Inc.. 16h11..� aceAnalytical www.pecewbscom I Project: GILBARCO 97746 Pace Project No.: 9252397 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-11 Lab ID: 9252397002 Collected: 09/02/09 09:37 Received: 09/03/09 13:38 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 601/602 Volatiles by SM 6200 Analytical Method: SM 6200B Benzene NO uglL 1.0 1.0 1 0911110913:26 71-43-2 Bromodichloromethane NO uglL 1.0 1.0 1 09/11/09 13.26 75-27-4 Bromoform NO uglL 1.0 1.0 1 09/11/09 13:26 75-25-2 Bromomethane NO uglL 1.0 1.0 1 09/11/09 13:26 74-83-9 Carbon tetrachloride NO uglL 1.0 1.0 1 09/11/09 13:26 56-23-5 Chlorobenzene NO ug1L 1.0 1.0 1 09111/0913:25 108-90-7 Chloroethane NO uglL 1.0 1.0 1 09/11/09 13:26 75-00-3 Chloroform ND uglL 1.0 1.0 1 09/11/09 13:26 67-66-3 Chloromethane NO uglL 1.0 1.0 1 09111/0913:26 74-87-3 Dibromochloromethane NO uglL 1.0 1.0 1 09/11/0913:26 124-48-1 1,2-Oibromoethane (EDB) NO uglL 1.0 1.0 1 09/11/09 13:26 106-93-4 1.2-Dichlorobenzene NO uglL 1.0 1.0 1 09111/0913:26 95-50-1 1.3-Dichlorobenzene NO uglL 1.0 1.0 1 09/11/09 13:26 541-73-1 1,4-Dichlorobenzene NO uglL 1.0 1.0 1 09/11/09 13:26 106-46-7 Dichlorodifluoromethane NO uglL 1.0 1.0 1 09111/0913:26 75-71-8 1,1-Dlchloroethane NO ug1L 1.0 1.0 1 09/11109 13:26 75-34-3 1,2-Dichlorcethane NO uglL 1.0 1.0 1 09/11/0913:26 107-06-2 11-Dichloroethene NO ug1L 1.0 1.0 1 0911110913:26 75-35-4 cis-1,2-Dichloroethene NO ug1L 1.D 1.0 1 0911110913:26 156-59-2 trans-1,2-Dichforoethene NO uglL 1.0 1.0 1 09111/0913:26 156-60-5 1,2-Dichloropropane NO ug1L 1.0 1.0 1 09111/0913:26 78-87-5 cis-1,3-Dichloropropene ND ug1L 1.0 1.0 1 09/11/09 13:26 10061-01-5 Vans-1,3-Dichloropropene ND uglL 1.0 1.0 1 09/11/09 13:26 10061-02-6 Diisopropyl ether NO uglL 1.0 1.0 1 09/11/09 13:26 108-20-3 Ethylbenzene NO uglL 1.0 1.0 1 09/11109 13:26 100-41-4 Methylene Chloride NO uglL 2.0 2.0 1 09/11/09 13:26 75-09-2 Methyl-tert-butyl ether NO ug1L 1.0 1.0 1 09/11/09 13:26 1634-04-4 Naphthalene NO ug1L 2.0 2.0 1 09/11/0913:26 91-20-3 1,1,2,2-Tetrachlaroethane NO uglL 1A 1.0 1 09/11/0913,26 79-34-5 Tetrachloroethene 4.4 ug1L 1.0 1.0 1 09/11109 13:26 127-18-4 Toluene ND uglL 1.0 1.0 1 09/1110913:26 108-88-3 1,11-Trichioroethane NO uglL 1.0 1.D 1 09/11109 13:26 71-55-6 1,1,2-Trichloroethane NO ug1L 1.0 1.0 1 09/1110913:26 79-00-5 Trichloroethene 2.3 uglL 1.0 1.0 1 0911110913:26 79-01-6 Tfthlorofluoromethane ND uglL 1.0 1.0 1 09/1110913:26 75-59-4 Vinyl chloride ND uglL 1.0 1.0 1 09/11109 13:26 75-01-4 Xylene (Total) NO uglL 2A 2.0 1 09/11/09 13:26 1330-2D-7 m&p-Xylene ND uglL 2.0 2.0 1 09/11/09 13:26 1330-20-7 o-Xylene NO ug1L 1.0 1.0 1 09111/0913:26 95.47-6 4-Bromofluorobenzene (S) 97 % 70-13D 1 09/11109 13:26 460-00-4 Dibromafluoromethane (S) 101 % 70-130 1 09/11/09 13:26 1868-53-7 1,2-DicNoroethane-d4 (S) 103 % 70-130 1 09/11/09 13:26 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 09/11/09 13:26 2037-26-5 Date: 09/14/2009 09:56 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduewd, except in full, without the written consent of Race Analytical Services, Inc.. Page 6 of 21 aceAnalWical wwwpecabbloom Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 [828]254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Project: GILBARCC 97746 Pace Project No.: 9252397 Sample_ NW-13 Lab ID: 9252397003 Collected: 09/02/09 09:10 Received: 09/03/09 13:38 Matrix: Water Report Parameters Results Units Limit MOIL OF Prepared Analyzed CAS No. Qual 6011602 Volatiles by SM 6200 Analytical Method: SM 6200B Benzene 1.2 ug/L 1.0 1.0 1 09/10109 11.11 71-43-2 $romodichloromethane NO ug/L 1.0 1.0 1 09/10109 11A1 75-27-4 Bromoform NO ug/L 1.0 1.0 1 09110/09 11:11 75-25-2 Bromomethane NO ug/L 1.0 1.0 1 09/10/09 11:11 74-83.9 Carbon tetrachloride N❑ ug/L 1.0 1.0 1 09/10/09 11:11 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 09/10/09 11:11 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 09/10/09 11,11 75-00-3 Chloroform ND ug/L 1.0 1.0 1 0911010911:11 67-66-3 Chloromethane NO ug/L 1.0 1.0 1 09110109 11;11 74-87-3 Dibromochloromethane ND uglL 1.0 1.0 1 0911010911.11 124-48-1 1.2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 09/10/09 11:11 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 09/10109 11:11 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1.0 1 091101091111 541-73-1 1,4-Dichlorobenzene NO ug/L 1.0 1.0 1 091101D911.11 106-46-7 Dichlorodifluoromethane NO ug/L 1.0 1.0 1 09/10/09 11:11 75-71-8 1,1-Dichloroethane ND ug/L 1.0 I.0 1 09/10/09 11:11 75-34-3 12-Dichloroethane NO ug/L 1.0 1.0 1 0911D10911:11 107-06.2 11-Dichloroethene ND ug/L 1.0 1.0 1 09110/09 11:11 75-35-4 cis-1,2-Dichloroethane 47.6 ug/L 1.0 1.0 1 0911010911:11 156-59-2 trans-1,2-Dichloroethane ND uglL 1.0 1A 1 09/10/0911:11 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 09/10/09 11:11 78-87-5 ds-1,3-DichlorDpropene N❑ ug/L 1.0 1.0 1 09/1010911:11 10061-01-5 trans-1.3-Dichloropropene NO ug/L 1.0 1.0 1 09/10/09 11:11 10061-02-6 Diisopropy! ether ND ug/L 1.0 1.0 1 09/10/09 11:11 108-20-3 Ethylbenzene N❑ ug1L 1.0 1.0 1 09/10/09 11:11 100-41-4 Methylene Chloride NO ug/L 2.0 2.0 1 09/10109 11:11 75-09-2 Methyl -tort -butyl ether 3.6 ug/L 1,0 1.0 1 09/10/09 11:11 1634-04-4 Naphthalene NO ug/L 2.0 2.0 1 09110/0911:11 91-20-3 1,1,2,2-TetrachIoroethane ND ug/L 1.0 1.0 1 09/1010911:11 79-34-5 Tetrachloraethene NO ug/L 1.0 1.0 1 09/10/09 11:11 127-18-4 Toluene NO uglL 1.0 1.0 1 09/10/09 1111 108-88-3 1,1.1-Trichloroethane NO ug/L 1.0 1.0 1 09/10/09 11:11 71-55-6 1,1.2-Trichloroethane ND ug/L 1.0 1.0 1 09/10/09 11,11 79-00-5 Trichloroethene N❑ ug/L 1.0 1.0 1 09/10/09 11:11 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 09/10/09 11:11 75-69-4 Vinyl chloride ND ug/L 1.0 1.0 1 09/10/09 11,11 75-01-4 Xylene (Total) NO ug/L 2.0 2.0 1 09110/09 11:11 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 09/1010911:11 1330-20-7 o-Xylene NO ug/L 1.0 1,0 1 09/10/09 11:11 95-47-6 4-Bromofluorobenzene (S) 92 % 70-130 1 09/10/09 11:11 460-00-4 Dibromofluoromethane (S) 102 % 70-130 1 09/10/09 11;11 1868-53-7 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 09/10/09 11:11 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 09/10/09 11:11 2037-26-5 Date: 09/14/2009 09:56AM REPORT OF LABORATORY ANALYSIS Page 7 of 21 This report shall not be reproduced, except in lull. without the written can sent of Pace Analytical Services, Inc. :�J .iG10>L.rc aceAnalytical wwwpeoele68.WM Pace Analytical Services, Inc. 2225 Riverside Dr - As h eyi I to, NC 28804 (B28)254-7175 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kin cey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GILBARCO 97746 Pace Project No.: 9252397 Sample: MW-13D Lab ID: 9252397004 Collected: 09/02/09 09:06 Received: 09/03/09 13:38 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. ❑ual 6011602 Volatlles by SM 6200 Analytical Method: 5M 6200B Benzene NO ug1L 1.0 1.0 1 09/10/09 11:35 71.43.2 Bromodichloromethane NO uglL 1.0 1.0 1 09/10109 11:35 75-27-4 Bromoform ND uglL 1.0 1.0 1 09110/0911:35 75-25-2 Bromomethane NO uglL 1.0 1.0 1 09/10/09 11:35 74-83-9 Carbon tetrachloride ND uglL 1.0 1.0 1 09/10/09 11.35 56-23-5 Chlorobenzene NO uglL 1.0 1.0 1 0911010911:35 108-90-7 Chlomethane NO uglL 1.0 1.0 1 09/10/0911,35 75-00-3 Chloroform ND ug1L 1.0 1.0 1 09/10/09 11:35 67-66-3 Chloromethane NO ug1L 1.0 1.0 1 09/10109 11:35 74-87-3 Dlbromochloromethane ND ug1L 1.0 1,0 1 0911010911:35 124-48-1 1,2-Dibromoethane (EDS) ND ug1L 1.0 1.0 1 09/10109 11:35 106-93-4 1,2-Dichlorobenzene NO ug1L 1.0 1 A 1 0911 D109 11.35 95.50-1 1,3-Dichlorobenzene NO uglL 1.0 1,0 1 09110/0911:35 541-73-1 1,4-Dichlorobenzene NO uglL 1.0 1.0 1 09/10/09 11:35 10646-7 Dichierodifluoromethane NO uglL 1.0 1.0 1 09/10/09 11:35 75.71-8 1,1-Dichloroethane N❑ uglL 1.0 1.0 1 09/10/09 11:35 75-34-3 1,2-Dichloroethane N❑ uglL 1.0 1.0 1 09110/0911:36 107-06-2 1,1-Dichloroethene ND uglL 1.0 1.0 1 09110/0911.35 75-35-4 cis-1,2-Dichloroethene 16.7 uglL 1.0 1.0 1 09/10/0911:36 156-59-2 trans-1,2-Dichloroethene NO uglL 1.0 1.0 1 09/10109 11.35 156-60-5 1,2-Dichlompropane NO uglL 1.0 1.0 1 D911010911:35 78-87-5 cis-1,3-Dichloropropene NO uglL 1.0 1.0 1 09/10/09 11:35 10061-01-5 trans-1,3-Dichloropropene NO uglL 1.0 1A 1 0911010911:35 10061-02-6 Diisopropyl ether NO ug1L 1.0 1.0 1 09/10/09 11:35 108-20-3 Ethylbenzene ND uglL 1.0 1.0 1 09/10/09 11:35 100-41-4 Methylene Chloride NO uglL 2.0 2.0 1 09/10/09 11:35 75-09-2 Methyl-tert-butyl ether 23.1 uglL 1.0 1.0 1 09/10/09 11:35 1634-04-4 Naphthalene NO uglL 2.0 2.0 1 0911010911:35 91-20-3 1,1,2,2-Tetrachloroethane NO ug1L 1.0 1.D 1 09/10/0911:36 79.34-5 Tetrachloroethene NO uglL 1.0 1.0 1 09/1010911,35 127-18-4 Toluene NO uglL 1.0 1.0 1 0911 D109 11:35 108-8B-3 1,1,1-Trichloroethane ND uglL 1.0 1.0 1 09110/0911:35 71-55-6 1,1,2-Trlchloroethane ND uglL 1.0 1.0 1 09110/0911:35 79-00-5 Trichloroethene NO uglL 1.0 1.0 1 09/10/09 11:35 79-01-6 Trich{orofluoromethane NO uglL 1.0 1.0 1 09110/0911:35 75-69-4 Vinyl chloride 5.3 uglL 1.0 1.0 1 09/10/09 11:35 75-01-4 Xylene (Total) NO uglL 2.D 2.0 1 09/10/09 11:35 1330-20-7 m&p-Xylene NO ug1L 2.0 2.0 1 09/10/09 11:35 1330-20-7 o-Xylene ND uglL 1.0 1.0 1 09/10/09 11:35 95-47-6 4-Bromofluorobenzene (S) 95 % 70-130 1 09/10/09 11:35 460-004 Dibromofluoromethane (S) 102 % 70-130 1 09110/09 11:35 1868-53.7 1,24)ichloroethane-d4 (S) 101 % 70-130 1 09110/09 11:35 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 09/10/09 11:35 2037-26-5 Date: 09/14/2009 09:56 AM REPORT OF LABORATORY ANALYSIS Page 8 of 21 This report shall not be reproduced, except in full, without the written wnsent of Pace +Aria lytical Services, Inc., ��l .ItGIR1L� aceAnalytical w wPecatebamm Project: GILBARCQ 97746 Pace Project No.: 9252397 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 28804 (&28)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kinney Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-14 Lab ID: 9252397005 Collected: 09/02/09 13:20 Received: 09/03/09 13:38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6011602 Vvlatiles by SM 6200 Benzene Bromod ich torometh a n e Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane ❑ibmmochloromethane 1,2-Dibromoethane (EDB) 1,2-Dichlarobenzene 1,3-Dichimbenzene 1,4-Dichlorobenzene DI ch 10 rod ifl u0rometh a n e 1,1-Dichloroethane 1,2-Dichloroethane 1.1-Dichloroethane cis-1 ,2-Dichloroethane trans- l ,2-Dichloroethene 1,2-Dichlompropane cis-1,3-Dichloropropene trans-1,3-DicMoropropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl4ert-butyl ether Naphthalene 1,1,22-Tetrachloroethane Tetrachtorcethene Toluene 1,1.1-Trichloroethane 1,1,2-TOchloroethane Trichloroethene Tdchlarofluoromethane Vinyl chloride Xyiene (Total) m&p-Xylene o-xyiene 4-Bromofluorobenzene (S) Dibnomofiuoromethane (S) 1,2-Dichloroethane-dill (S) Toluene-d8 (S) Date: 09/14/2009 09:56 AM Analytical Method: 5M 6200B ND uglL 1.0 1.0 1 09110/09 11.58 71-43-2 NO uglL 1.0 1.0 1 09110/09 11:58 75-27-4 NO ug1L 1.0 1 A 1 D9110/09 11:58 75-25-2 NO ug1L 1.0 1.0 1 09/10/09 11:58 74-83-9 ND ug/L 1.0 1.0 1 09/10/09 11:58 56-23-5 NO ug1L 1.0 1.0 1 09/10109 11:58 108-90-7 ND ug/L 1.0 1.0 1 09/10109 11:58 75-OD-3 ND ug1L 1.0 1.D 1 09/10109 11:58 67-66-3 NO uglL 1.0 1.0 1 09/10/09 11:58 74-87-3 ND ug)L 1.0 1.0 1 09/10/09 11:58 124-48-1 NO uglL 1.0 1.0 1 09/10/09 1158 106.93-4 NO ugJL 1.0 1.0 1 09/10/09 11.58 95-50-1 NO uglL 1.0 1.0 1 09/1D/0911:58 541-73-1 NO ug/L 1.0 1.0 1 09110/09 11:58 106-46-7 NO uglL 1.0 1.0 1 09/1D10911:58 75-71-8 ND ug1L 1.0 1.0 1 09/10/09 11:58 75-34-3 NO uglL 1.0 1.0 1 09/10/09 11:58 107-06-2 ND ug1L 1.0 1.0 1 09/10/09 11:58 75-35-4 ND uglL 1.0 1.0 1 09/10/09 11:59 156-59-2 ND uglL 1.0 1.0 1 D9110109 11:58 156-60-5 ND uglL 1.0 1.0 1 09/10/09 11:58 78-87-5 NO uglL 1.0 1.0 1 09/10/09 11:58 10061-01-5 NO ug1L 1.0 1.0 1 09/10/09 11:58 10061-02-6 NO ugIL 1.0 1.0 1 09/10/09 11:58 108-20.3 NO ug1L 1.0 1.0 1 09/10/09 11:58 100-41-4 NO ug/L 2.0 2.0 1 09/10/09 11:58 75-09-2 NO uglL 1.0 1.0 1 09/10/09 11:58 1634-04-4 NO ug/L 2.0 2.0 1 09/10109 11:58 91-20-3 NO uglL 1.0 1.0 1 09/10/09 11:58 79-34-5 23.8 uglL 1.0 1.0 1 09110109 11:58 127-18-4 NO uglL 1.0 1.0 1 09/10/09 11:58 108-88-3 NO uglL 1 A I Z 1 0911 D/D9 11:58 71-55-6 ND ug1L 1.0 1.0 1 09110/09 11:58 79-00-5 ND uglL 1.0 1.0 1 09110/09 11:58 79-01-6 ND uglL 1.0 1.0 1 09/10/09 11.58 75-69-4 NO uglL 1.0 1A 1 09110/09 11:58 75-01-4 NO uglL 2.0 2.0 1 0911 D109 11:58 1330-20-7 NO uglL 2.0 2.0 1 09/10/09 11:58 1330-20-7 NO ug1L 1.0 1.0 1 09/10/09 11:58 95-47-6 94 % 70-130 1 09/10/09 11:58 460.00-4 105 % 70-130 1 09110/09 11.58 1868-53-7 105 % 70-130 1 09/10/09 11:58 17060-07-0 99 % 70-130 1 09/10/09 11:58 2037.26-5 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full. without the written consent of P300 A�naiyticaI Services, Inc,. Page 9 of 21 aceAnalyticai� wwwpOuela6s.com Project: GILBARCO 97746 Pace Project No.: 9252397 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services. Inc. 98DO KinoeyAve. Suite 100 Huntersville, NC 28078 (744)875-9092 Sample: MIN-23D Lab ID: 9252397006 Collected: 09/02/09 09:03 Received: 09/03/09 13:38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Quaff 6011602 Volatiles by SM 6200 Analytical Method: SM 6200B Benzene 2.7 ug1L 2.0 2.O 2 09/10/09 12:22 71-43-2 Bromodichioromethane NO uglL 2.0 2.0 2 09/10/09 12:22 75-27-4 Bromoform NO uglL 2.0 2.0 2 09/10109 12:22 75-25-2 Bromemethane NO uglL 2.0 2.0 2 09/1010912:22 74-63-9 Carbon tetrachloride ND uglL 2.0 2.0 2 09/10/09 12:22 56-23-5 Chlorobenzene NO uglL 2.0 2.0 2 09/10/09 12:22 108-90-7 Chloroethane ND uglL 2.0 2.0 2 09/10/09 12:22 75-00-3 Chloroform NO uglL 2.0 2.0 2 09/10/09 12:22 67-66-3 Chloromethane NO uglL 2.0 2.0 2 09110/09 12:22 74-87-3 Dibromochioromethane NO ug& 2.0 2.0 2 09/10/09 12.22 124-48-1 1,2-Dibromoethane (EDB) ND uglL 2.0 2.0 2 09/10/09 12:22 106-93-4 1,2-Dichlorobenzene ND uglL 2.0 2.0 2 09/10/09 12:22 95-50.1 1,3-Dichiorobenzene ND uglL 2.D 2.0 2 09/10/09 12:22 541-73-1 1,4-Dichiorobenzene ND ug1L 2.o 2.0 2 D911010912:22 106-46-7 Dichlorodifluoromethane NO uglL 2.0 2.0 2 09/1010912:22 75-71-8 1.1-Dichloroethane NO uglL 2.0 2.O 2 09/1010912:22 75-34-3 1.2-Dichloroethane NO uglL 2.0 2.0 2 09/10/09 12:22 107-06-2 1,1-Dichloroethene NO uglL 2.0 2.0 2 09110/0912:22 75-35-4 cis- 1,2-Dichloroethene 140 uglL 2.0 2.0 2 0911010912:22 156-59-2 trans-1,2-Dichloroethene ND uglL 2.0 2.0 2 09/10/09 12:22 156-60-5 1,2-Dichloropropane ND uglL 2.0 2.0 2 09110/091222 78-87-5 cis-1.3-Dichioropropene ND uglL 2.0 2.0 2 09/10/09 12:22 10061-01-5 trans-1,3-Dichloropropene ND uglL 2.0 2.0 2 09110/0912:22 10061-02-6 Diisopropyl ether 6.4 uglL 2.0 2.0 2 09/10/09 12:22 106-20-3 Ethylbenzene NO ug1L 2.0 2.0 2 09/10/09 12:22 100-41-4 Methylene Chlonde NO uglL 4.0 4.0 2 D9110109 12:22 75-09-2 Methyl -tent -butyl ether 317 uglL 2.0 2.0 2 09/10109 12:22 1634-04-4 Naphthalene NO uglL 4.0 4.0 2 09/10/09 12:22 91-20-3 1.1,2,2-TetrachIoroethane NO ug1L 2.0 2.0 2 09/10/09 12:22 79-34-5 Tetrachloroethene ND uglL 2.0 2.0 2 09/10/09 12:22 127.18-4 Toluene ND uglL 2.0 2.0 2 09/1010912:22 109-88-3 1.1,1-Tichloroethane NO ug1L 2.0 2.0 2 09/1010912:22 71-55-6 1,1.2-ThchIoroethane ND uglL 2.0 2.0 2 09/10/09 12:22 79-00-5 Trichloroethene ND uglL 2.0 2.0 2 09/10/09 12:22 79-01-6 TnchOrofluoromethane N❑ uglL 2.0 2.0 2 09/10/09 12:22 75-69-4 Vinyl chloride 23.5 uglL 2.0 2.O 2 09/10109 12:22 75-01-4 Xylene (Total) ND uglL 4.0 4.0 2 09/10/09 12:22 1330-20-7 m&p-Xylene ND uglL 4.0 4.0 2 09110/09 12:22 1330-20-7 o-Xylene NO uglL 2.0 2.0 2 091101D912:22 9547-6 4-Bromefluorobenzene (S) 94 % 70-130 2 09/10/09 12:22 46MO-4 Dibromofluoromethane (S) 100 % 70-130 2 09110/09 12:22 1868-53-7 1,2-Dichloroethane-d4 {Sj 101 % 70-130 2 09/10/09 12:22 17060-07-0 Toluene -dB (S) 100 % 70-130 2 09/10/09 12:22 2037-26-5 Date: 09/14/2009 09:56 AM REPORT OF LABORATORY ANALYSIS Page 10 of 21 This report shall not be reproduced, except in full, without the written can sent of Pace Ana Services, Inc., j� . ditns r t 6Analytical" wwwp::csfabs.mm Project: GILBARCO 97746 Pace Project No.: 9252397 Pace Analytical Services. Inc. 2225 Riverside Dr - Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Paco Analytical Services, Inc. 9800 Kin cey Ave. Suits 100 Huntersville, NC 28078 (7041075-9092 Sample: MW-24 Lab ID: 9252397007 Coiiected: 09/02/09 12:56 Received: D9103109 13:38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No, Qual 6011602 Volatlles by SM 6200 Benzene Bromod ich lorometha n e Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichl prod ifl uo rometha n e 11-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropro pane cis-1,3-Dichloropropene trans- 1, 3-Dich lompropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1,1.2,2-Tetrachloroethane Tetrachloroethene Toluene 1,11-Trichloroethane 1,1,2-Trichloroethene Tdchloroethene Trich loroflu orometh a ne Vnyl chloride xylene (Total) m&p-Xylene o-xylene 4-Bromofluorobenzene (S) Dibromofluoromethane [S] 1,2-0ichloroethane-d4 (S) Toluene-d8 {S) Date: 09/14/2009 09:56 AM Analytical Method: SM 6200B 537 ug/L 5.0 5.0 5 09/10/09 12:46 71-43-2 ND ug1L 5.0 5.0 5 09/10109 12:46 75-27-4 ND ug)L 5,0 5.0 5 09110109 12:46 75.25-2 NO ug1 5.0 5,0 5 09/10/09 12:46 74-83-9 ND ug/L 5.0 5.0 5 09110/09 12,46 56-23-5 NO ug/L 5.0 5.0 5 09/10/09 12:46 108-90-7 NO ug/L 5.0 5.0 5 09/10/09 12:46 75-00-3 N❑ ug/L 5.0 5.0 5 09/10/09 12.46 67-66-3 ND uglL 5.0 5.0 5 09110/0912:46 74-B7-3 ND uglL 5.0 5.0 5 09/10/091Z46 124-48-1 ND ug/L 5.0 5.0 5 09/10/09 12:46 106-93-4 NO ug/L 5.0 5,0 5 09/10109 12:46 95-50-1 NO ug/L 5.0 5.0 5 D9110109 12:46 541-73-1 NO ug1L 5.0 5.0 5 09/10/09 12,46 106-46-7 ND uglL 5.0 5,0 5 09/10/09 12:46 75-71-8 6.2 ug/L 5.0 5.0 5 09/10/09 12:46 75-34-3 ND ug/L 5.0 5.0 5 09/10/09 12:46 107-06-2 9.7 uglL 5.0 5,0 5 09110/09 12:46 75-35-4 760 uglL 5.0 5.0 5 09/10/09 12:46 156-59-2 NO ug/L 5.0 5.0 5 09/10/09 12:46 156-60-5 NO ug/L 5.0 5.0 5 09/10/09 12:46 78-87-5 ND uglL 5.0 5.0 5 09/10/09 12:46 10061-01-5 ND uglL 5.0 5.0 5 09/10/09 12:46 10061-02-6 165 ugIL 5.0 5.0 5 09/10/09 12.46 108.20-3 NO ugfL 5.0 5.0 5 09/10/09 12,46 100-414 ND uglL 10.0 10.0 5 09/10/09 12.46 15-09-2 77.5 uglL 5.0 5.0 5 09/10/09 12:45 1634-04-4 15.5 uglL 10.0 10.0 5 09/10/09 12:46 91-20-3 NO ug/L 5.0 5.0 5 09/10/09 12:46 79-34-5 946 ug/L 50.D 50.0 50 09/11109 13:50 127-18-4 ND ug/L 5.0 5.0 5 09/10/09 12:46 108-88-3 ND ug/L 5.0 5.0 5 09/10/09 12:46 71-55-6 ND uglL 5.0 5.0 5 09/10/09 12:46 79-00-5 127 uglL 5.0 5.0 5 09/10109 12:46 79-01-6 32.0 uglL 5.0 5.0 5 09/10/09 12:46 75-69-4 121 uglL 5.0 6.0 5 09/10/09 12:46 75-01-4 13.7 uglL 10.0 10.0 5 09/10/09 12:46 1330-20-7 NO uglL 10.0 10.0 5 09/10/09 12:46 1330-2D-7 11.1 uglL 5.0 5.0 5 09/1010912:46 95-47-6 100 % 70-130 5 09/1010912:46 460-00-4 94 % 70-130 5 09/10/09 12:46 1868-53-7 94 % 70-130 5 0911010912:46 17060-07-0 97 % 70-130 5 09/10/09 12:46 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written can sent �of PPa�ajjce�eAnalytical Services, Inc. ;`:. Page 11 of 21 ace Analytical e ww pacelabs.eam Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28004 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services. Inc. 9M Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)875-9092 Project: GILBARCD 97746 Pace Project No.: 9252397 Sample: MW-25 Lab ID: 9252397008 Collected: 09/02/09 13:00 Received: 09/03/09 13.38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 601/602 Volatiles by SM 6200 Benzene Bromodi ch lof o metha n e Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Di bromochl orometh an e 1,2-Dibromoethane (EDB) 1,2-Dichforobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene ❑ ichl orodifl u oromethane 1,1-Dichloreethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans-1, 3-Dichloropropene Diisopropyf ether Ethylbenzene Methylene Chloride Methyl-tert-bury! ether Naphthalene 1,1,2,2-Tetrachtoroethane Tetrachloroethene Toluene 1,1,1-T6chloroethane 1,1,2-Trichtoroethane Trichloroethene Tri ch loroflu oromet h ane Vinyl chloride Xylene (Totaf) m&p-Xylene o-Xylene 4-Bromofluorobenzene (5) Dibromofluoromethane (S) 1,2-Dichloroethene-d4 (S) Toluene-d8 (S) Date: 09/14/2009 09:56 AM Analytical Method: SM 6200B ND ug/L 1.0 ND ug/L 1.0 N❑ ug/L 1.0 ND ugIL 1.0 N❑ ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 N ❑ ug/L 1.0 Nil ug/L 1.0 ND ugIL 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 N❑ ug/L 1.0 1.1 ug/L 1.0 N❑ ug/L 1.0 1.6 ugIL 1.0 60.1 ugIL 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1,0 N❑ ug/L 1.0 9.1 ug/L 1.0 ND ug/L 1.0 N❑ ug/L 2,0 8.9 ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 24.8 ugIL 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 7.9 ug/L 1.0 ND ug/L 1.0 N❑ ug/L 1.0 N❑ ugIL 2.0 ND ug/L 2.0 ND ug/L 1.0 94 % 70-130 103 % 70-13D 102 % 70-130 99 % 70-130 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.D 1.0 1.0 1.0 1.0 1.0 2.0 1.0 2.0 1.0 1.0 I'D 1.0 1.0 1.0 1.0 1.0 2.0 2.0 1.0 i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc., 09/101091109 7143-2 09/10/0913*09 75-27-4 09110/0913:09 75-25-2 09/1010913.09 74-83-9 09/10/09 13:09 56-23-5 09/10/09 13:09 108-9 0-7 09/10/09 13:09 75-00-3 09/10/09 13:09 67-66-3 09110/0913:09 74-87-3 0 9110109 13:09 124-48 -1 09/10/09 13:09 106-93-4 09/1010913:09 95-50-1 09/10/09 13:09 541-73-1 09110109 13:09 106-46-7 091101D913.09 75-71-8 09/1010913:09 75-34-3 D9110109 13:09 107-06-2 09/10/09 13:09 75-35-4 D9110109 13:09 156-59-2 09/10/09 13:09 156-60-5 09110/0913:09 78-87-5 09110/0913:09 10061-01-5 09/10/09 13:09 10061-D2-6 09/10/09 13:09 108-20-3 09110109 13:09 1 DO-41-4 09/10/0913:09 75-09-2 09/10/09 13:09 1634-04-4 09/10/09 13:09 91-20-3 0911010913:09 79-34-5 09/10/09 13:09 127-1 B-4 09/10/09 13: 09 108-88 -3 09/10/091109 71-55-6 09110/0913:09 79-00-5 09/10109 13: D9 79-01-6 09/1010913:09 75-69-4 091101091109 75-01-4 D9110109 13:09 1330-20-7 09110/0 9 13:09 13 30-2 0-7 09/1010913:09 95-47-6 09/10/0913,09 460-00-4 09110109 13:09 186 8.5 3-7 09/10/09 13:09 17060-07-0 09/10/09 13:09 2037-26-5 Page 12 of 21 aceAnaly4lcal" wwPwvh ba.00m Project: GILBARCD 97746 Pace Project No.: 9252397 Pace Analytical Services. Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Knoey Ave. Suite 100 Huntersville, NC 28078 t704j875-9D92 Sample: MW-42 Lab ID: 9252397009 Collected, 09/02/09 14.52 Received: 09/03/09 1138 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6011602 Volatiles by SM 6200 Benzene Bromod i ch is ro metha n e Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloraethane Chloroform Chloromethane Di b rom o chl orometh an e 1,2-Dibromoethane (EDB) 12-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene ❑i chi orodifl u oromethane 1.I-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichforoethene 1.2-DichIoropropane cis-1,3-Dichioropropene trans- 1, 3-Di ch lorop ropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1.1,1-TrichIoroethane 1,1,2-Trichloreethane Trichloroethene Trich lorofl uo ro methan e Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene 4-Bromoflucrobenzene (S) Dibromofluaromethane (S) 1.2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/14/2009 09:56 AM Analytical Method, SM 6200B NO ug/L 1.0 1.0 1 09/10/09 13.33 7143-2 NO ug[L 1.0 1.0 1 09/10/09 13:33 75-27-4 Na uglL 1.D 1.0 1 09/10/09 13:33 75-25-2 NO ug/L 1.0 1.0 1 09110/09 13:33 74-83-9 NO ug1L 1.0 1.0 1 09/10/09 13:33 56-23-5 NO ug/L 1.0 1.0 1 09110/09 13:33 108-90.7 NO ug/L 1.0 1.0 1 09/10/09 13:33 75-00-3 NO uglL 1.0 1.0 1 09/10/09 13:33 67-66-3 ND uglL 1.0 1.0 1 09/10/09 13:33 74-87-3 NO uglL 1.0 1.0 1 09/10/09 13:33 124.48-1 NO uglL 1,0 1.0 1 09/10/09 13:33 106-93-4 ND uglL 1.0 1.D 1 09/10/09 13:33 95.50-1 ND ug/L 1,0 1.0 1 09/10/09 13:33 541-73-1 NO ug/L 1.0 1.0 1 D9110109 13:33 106-46-7 ND uglL 1.0 1.0 1 09/10/09 13:33 75-71-8 NO uglL 1.0 1.0 1 09/10/09 13:33 75-34-3 ND uglL 1.0 1.0 1 09/10/09 13:33 107-06-2 ND uglL 1.0 1.0 1 09110/09 13:33 75,35-4 ND ug1L 1.0 1.0 1 09/10/09 13:33 156-59-2 NO ug1L 1.0 1.0 1 09110/09 13:33 156-60-5 NO ug/L 1.0 1.0 1 09/10/09 13:33 78-87-5 NO ug/L 1.0 1.0 1 09/10/09 13:33 10061-01-5 NO uglL 1.0 1.0 1 09/10/09 13:33 10061-02-6 NO uglL 1.0 1.0 1 09/10/09 13:33 108-20-3 ND uglL 1.0 1.0 1 09/10/09 13:33 100414 ND uglL 2.0 2.0 1 09/10/09 13.33 75-09-2 ND uglL 1.0 1.0 1 09/10/09 13:33 1634-04-4 NO uglL 2.0 2.0 1 09/10/09 13:33 91-20-3 ND ug1L 1.0 1.0 1 09/10/09 13:33 79-34-5 3.4 ug1L 1.0 1.0 1 09/10/09 13:33 127-18-4 NO ug/L 1.0 1.0 1 09/10109 13:33 108-88-3 NO uglL 1.0 1.0 1 09/10/09 13:33 71-55-6 NO uglL 1.D 1.0 1 D9/10/09 13:33 79-00-5 ND uglL 1.0 1.0 1 09/10/09 13:33 79-01-6 ND uglL 1.0 1.0 1 D9/10/09 13:33 75-69-4 ND ug1L 1.0 1.0 1 09/10/09 13:33 75-01-4 ND ug1L 2.0 2.0 1 09110/09 13:33 1330-20-7 NO ug1L 2.0 2.0 1 09/10/09 13:33 1330-20-7 NO ug/L 1.0 1.0 1 09/10/09 13:33 95-47-6 94 % 70-130 1 09110/091&33 460-00-4 105 % 70-130 1 09/10/09 13:33 1B66-53-7 104 °% 70-130 1 09/10/09 13:33 17060-07-0 100 % 70-130 1 0911D109 13:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written ccnsont of Parse Analytical Services, Inc.. Page 13 of 21 e ace Analjftal www.pacalebs.00m Project: GILBARCQ 97746 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 i828y254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (764)875-9092 Pace Project No.. 9252397 Sample: MW-43D Lab ID: 9252397010 Collected: 09/02/09 14:48 Received: 09/03/09 13:36 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 60111602 Volatlles by SM 6200 Analytical Method: SM 6200B Benzene 3.0 uglL 2.0 2.0 2 09110109 13:57 71-43-2 Bromodichlaromethane NO uglL 2.0 2.0 2 09110/09 13:57 76.27-4 Bromoform ND uglL 2.0 2.0 2 09110/09 13:57 75-25-2 Bromomethane NO uglL 2.0 2.0 2 09/1010913:57 74-83-9 Carbon tetrachloride NO uglL 2.0 2.0 2 09110/09 13:57 56-23-5 Chlorobenzene NO uglL 2.0 2.0 2 09110109 13:57 108-90-7 Chloroethane NO ug1L 2.0 2.0 2 09/10/09 13:57 75-00-3 Chloroform ND ug1L 2.0 2.0 2 09/10/09 13:57 67-66-3 Chloromethane 3.8 uglL 2.0 2.0 2 09/10/09 13:57 74-87-3 Dibromochlaromethane ND ug1L 2.0 2.0 2 09/10/09 13:57 124-48-1 1,2-Dibromoethane (EDB) ND uglL 2.0 2.0 2 09/10/09 13:57 106-93-4 1,2-Dichiorobenzene NO uglL 2.0 2.0 2 09/1010913:57 95-50-1 1,3-Dichiorobenzene NO uglL 2.0 2.0 2 09/1D10913:57 541-73-1 1,4-Dichlorobenzene NO uglL 2.0 2.0 2 0911010913:57 106-46-7 Dichlarodifluoromethane ND ug1L 2.0 2.0 2 09/10/09 13:57 75-71-8 1,1-Dichloroethane 3.9 ug1L 2,0 2.0 2 09/10/09 13:57 75-34-3 1,2-Dichloroethane ND uglL 2.0 2.0 2 09/10/09 13.57 107-06-2 1,1-Dichloroethene 13.9 ug1L 2.0 2.0 2 09/10/09 13:57 75-354 cis-1,2-Dichloroethene 99.4 uglL 2.0 2.0 2 0911010913.57 15&59-2 trans-1,2-Dichloroethene NO uglL 2A 2.0 2 09/10/09 13:57 156-60-5 1.2-Dichlorapropane NO uglL 2.0 2.0 2 09/10109 13:57 78-87-5 cis- 1,3-Dichloropropene NO uglL 2.0 2.0 2 09110/0913:67 10061-01-5 trans-1,3-❑ichforopropene ND uglL 2.0 2,0 2 0911010913:57 10061-02-6 Diisopropyl ether 29.9 uglL 2.0 2.0 2 09/10/09 13:57 108-20-3 Ethylbenzene NO uglL 2.0 2.0 2 09/10/09 13:57 100-41-4 Methylene Chloride ND ug1L 4.0 4.0 2 0911 D109 13:57 75-09-2 Methyl -tent -butyl ether 16.7 uglL 2.0 2.0 2 09/10/09 1157 1634-04-4 Naphthalene NO uglL 4.0 4,0 2 09/10/09 13:57 91.20-3 1.1.2.2-Tetrachloroethane NO uglL 2.0 2.0 2 09/10/09 13:57 79-34-5 Tetrachloroethene 337 uglL 2.0 2.0 2 09/10/09 13:57 127-18-4 Toluene N❑ uglL 2.0 2.0 2 09/10/09 13:57 108-88-3 1, 1,1 -Trichloroethane ND uglL 2.0 2.0 2 09110/09 13:57 71-55-6 1,1,2-Trichi Oroethane ND uglL 2.0 2.0 2 09110/09 13:57 79-00-5 Trichloroethene 11.4 uglL 2.0 2.0 2 09110/09 13:57 79-01-6 Trichlorofluoromethane 3.7 uglL 2.0 20 2 09110/09 13:57 75-69-4 Vinyl chloride ND ug1L 2.0 2A 2 09/10/09 13:57 75-01-4 Xylene (Total) ND ug1L 4.0 4.0 2 09110/09 13:57 1330-20-7 m&p-Xylene NO uglL 4.0 4.0 2 09/1010913:57 1330-20-7 0-Xylene N❑ uglL 2.0 2.0 2 09/10/09 13.57 95-47-6 4-Bromofluorobenzene (S) 95 % 70-130 2 09/10/09 13:57 460.00-4 ❑ibromofluoromethane (S) 103 % 70-130 2 09/10/09 13:57 1868-53-7 1,2-Dichloroethene-d4 (S) 102 % 70-130 2 09/10/09 13:57 17060-07-0 Toluene-d8 (S) 101 % 70-130 2 0911 D109 13:57 2037-26-5 ❑ate: 09114/2009 09,56 AM REPORT OF LABORATORY ANALYSIS Page 14 of 21 This report shall not be reproduced, except in full, w the Lit the written consent of PPaaceerAnalyliraI Services. Inc.. aceAnalytical V, paceiaba.aom Project: GILBARCO 97746 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc, 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 Pace Project No.: 9252397 Sample: MW-45 Lab ID: 9252397011 Collected: 09/02/09 15:05 Received: 09/03/09 13:38 Matrix: Water (704)975-9092 Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6011602 Volatiles by SM 6200 Anatytical Method' SM 62008 Benzene ND ug1L 1.0 1.0 1 09/10109 14:20 71-43-2 Bromodichloromethane ND uglL 1.0 1.0 1 09/10/09 14:20 75-27-4 Bromoform ND ug1L 1.0 1.0 1 09/10109 14:20 75-25-2 Bromomethane NO uglL 1.0 1.0 1 09/10/09 14:2D 74-83-9 Carbon tetrachloride NO ug1L 1.0 1.0 1 09/10/09 14 20 56-23-5 Chlorobenzene ND ug1L 1.0 1.0 1 09/10/09 14:20 108-90-7 Chloroethane ND uglL 1.0 1.0 1 09110/09 14:20 75-00-3 Chloroform ND uglL 1.0 1.0 1 09110/09 14:20 67-66-3 Chloromethane ND uglL 1.0 1.0 1 09/10/09 14:20 74.87.3 Dibromochloromethane ND uglL 1.0 1.0 1 09/10/09 14:20 124-48-1 1,2-Dibromoethane (EDB) NO uglL 1.0 1.0 1 09/10/09 14:20 106-93-4 1,2-Diohlorobenzene NO uglL 1.0 1.0 1 09110/0914:20 95-50-1 1,3-Dichlorobenzene NO uglL 1.D 1.0 1 09/10/09 14:20 541-73-1 1,4-Dichlorobenzene NO uglL 1.0 1.0 1 09/10/09 14:20 106-46-7 Dichlorodifluoromethane NO uglL 1.0 1.0 1 09110M9 14:20 75-71-8 1,1-Dichloroethane NO uglL 1.0 1.0 1 09/10/09 14:20 75-34-3 1,2-Oichloroethane ND uglL 1.0 1.0 1 09/10/09 14:20 107-06-2 1,1-Dichloroethene ND uglL 1.0 1.0 1 09/10/09 14:20 75-35-4 cis-1,2-Dichtoroethene ND uglL 1.0 1.0 1 09/10/09 14:20 156-59-2 trans-1,2-Dichloroethene NO ug1L 1.0 1.0 1 D911010914:20 156-60-5 1,2-Dichloropropane ND ug1L 1.0 1.0 1 09/10/0914.20 78-87-5 cis-1,3-Dichloropropene NO uglL 1.0 1.0 1 09110/09 14:20 10061-01-5 trans-1,3-Dichloropropene ND uglL 1.D 1.0 1 09/10/0914,20 10061-02.6 Diisopropyl ether ND ug1L 1.0 1.0 1 09/10/09 14:20 108-20-3 Ethylbenzene NO ug1L 1.0 1.0 1 09/10/09 14:20 100-41-4 Methylene Chloride NO uglL 2.0 2.0 1 09/10/09 14:20 75-09-2 Methyl-tert-butyl ether NO uglL I.0 1.0 1 09/10/09 14;20 1634-04-4 Naphthalene NO uglL 2.0 2.0 1 09/10/D9 14:20 91-20-3 1,1,2,2-Tetrachloroethane NO ug/L 1.0 1.0 1 09/10/09 14:20 79-34-5 Tetra ch loroethe n e 2.4 uglL 1.0 1.0 1 09/10109 14:20 127-18-4 Toluene NO ug1L 1.0 1.0 1 09/10/09 14:20 10"8-3 1,1,1-Trichloroethane ND uglL 1.0 1,0 1 0911010914:20 71-55-6 1.1.2-Trichloroethane NO ug1L 1.0 1.0 1 D911010914:20 79-00-5 Trichloroethene 1.1 uglL 1.0 1.0 1 0911010914:20 79-01-6 Trichlorofluoromethane NO uglL 1.0 1.0 1 09/10/09 14:20 75-69-4 Vinyl chloride NO uglL 1.0 1.0 1 09/10/09 14:20 75-01-4 Xylene (Total) ND uglL 2.0 2.0 1 09/10/09 14:20 1330-20-7 m&p-Xylene NO uglL 2.0 2.0 1 09110/09 14:20 1330-20-7 o-Xylene ND uglL 1.0 1.0 1 09/10/09 14.20 95-47.6 4-Bromofluorobenzene (S) 90 p% 70-130 1 09/10/09 14:20 460-00-4 Dibromofluoromethane (S) 107 °% 70-130 1 09110/09 14:20 1868-53-7 1,2-Dichloroethane-d4 (S) 106 °fin 70-130 1 09/10/09 14:2D 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 09/10109 14:20 2037-26-5 Date: 09/14/2009 09:56 AM REPORT OF LABORATORY ANALYSIS page 15 of 21 This report shall not be reproduced, except in full, without the written consent of Pace�e+�Analytical Services, Inc.. laceAnalXical" www.pWalfiftom i Project: GILBARCO 97746 Pace Project No.: 9252397 Pace Analytical Services, Inc. 2225 Riverside Or - Asheville. NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9600 KinceyAve. Suite 100 Huntersville, NC 2807B (T04)875.9097 Sample: MW-14D Lab ID: 9252397012 Collected: 09/02/09 13:12 Received: 09/03/09 13:38 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No, Qua# 6011602 Volatfles by SM 6200 Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane D i brorn ochl orom eth an e 1,2-Dibromoethane (EDB) 1 ,2 -Di ch lofobe n zen e 1,3-Dichlorobenzene 1,4•Dichlorobenzene Di ch I o rodifl uorometh ane 1,1-Dichloroethane 1,2-Dichloroethane 1, 1 -Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis- 1,3-0ichlorop rope ne trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1.1,2,2-Tetrachloroethane Tetrachioroethene Toluene 1,1,1-TrichIoroethane 1.1,2-TrichIoroethane Trichloroethene Tdch lorofl uoromethane Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene 4-Bromofluorobenzene (S) Dibromofluoromethane (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 09/14/2009 09:56 AM Analytical Method: SM 6200B 1.8 ug/L 1.0 1.0 1 09/10/09 14:44 71.43-2 ND ugIL 1.0 1.0 1 09/10/09 14:44 75-27-4 ND ug/L 1.0 1.0 1 09/10/09 14:44 75-25-2 ND ug/L 1.0 1.0 1 09/10/09 14:44 74-83-9 ND ug/L 1.0 1.0 1 09/10/09 14:44 56-23-5 NO ug/L 1.0 1.0 1 09/10/09 14:44 1OB-90-7 ND ug/L 1.0 1.0 1 09/10/09 14:44 75-00-3 ND ug/L 1.0 1.0 1 09/10/09 14:44 67-66-3 ND ugIL 1.0 1.0 1 09/10/09 14:44 74-87-3 ND ugIL 1.0 1.0 1 09/10/09 14:44 124-48-1 N❑ ugIL 1.0 1.0 1 09/10/09 14:44 106-93-4 ND ug/L 1.0 1.D 1 09/10/09 14:44 95-50-1 ND uglL 1.0 1.0 1 09/10/09 14:44 541-73-1 ND ug/L 1.0 1.0 1 09/10/09 14:44 106-46-7 ND ug/L 1.0 1.0 1 09/10/09 14:44 75.71-8 ND ug/L 1.D 1.0 1 09/10/0914:44 75-34-3 ND uglL 1.0 1.0 1 09/10109 14,44 107-06-2 NO ug/L 1.0 1.0 1 09/10/09 14:44 75-35-4 8.8 ug/L 1.0 1.0 1 D9110109 14:44 156-59-2 NO ug1L 1.0 1.0 1 09/10/09 14:44 156-60-5 ND ug/L 1.0 1.0 1 09/10/09 14:44 78-87-5 ND ug/L 1.0 1.0 1 09/10/09 14A4 10061-01-5 ND ug/L 1.0 1.0 1 09/10/09 14:44 10061-02-6 2.9 ug/L 1.0 1.0 1 09/10/09 14:44 108-20-3 ND ug/L 1.0 1.0 1 09/10/09 14:44 100-41-4 NO ug/L 2.0 2.0 1 09110/0914:44 75-09-2 1.3 ug/L 1.0 1.0 1 09/10/09 14:44 1634-04-4 NO ug/L 2.0 2.0 1 09/10/09 14:44 91-20-3 NO ug/L 1.0 1.0 1 09/10/0914:44 79-34-5 27.1 ug/L ID 1.0 1 09/10109 14:44 127-18-4 ND uglL 1.0 1.0 1 09/10/09 14,44 108-88.3 ND ug/L 1.0 1.0 1 D9I1010914:44 71-55-6 ND ug/L 1.0 1.0 1 09/10/09 14:44 79-00-5 1.4 ug/L 1.0 1.0 1 09/10/09 14,44 79-01-6 NO ug/L 1.0 1.0 1 09/10/09 14:44 75-69-4 NO ug/L 1.0 1.0 1 09110/0914:44 75-01-4 NO ug/L 2.0 2.0 1 09/10/09 14:4.4 1330-20-7 ND ug/L 2.0 2.0 1 09/10/09 14A4 1330-20-7 ND ug/L 1.0 1.0 1 09/10109 14:44 95-47-6 93 °% 70-130 1 09/10109 14.44 460-00-4 105 % 70-130 1 09110/09 14:44 1868-53-7 104 % 70-130 1 09/10/09 14:44 17060-07-0 100 °% 70-130 1 09/10/09 14:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shaft not be reproduced, except in lull, without the written con sent of PPaace ,AnalyticaI Services, Inc.. Ll�lf]11.._ Page 16 of 21 accAnaVical wr -Vpa[r+faas.cro,r Project: GILBARCO 97745 Face Project No.: 9252397 Pace Analytical Services, Inc, 2225 Riverside Dr. Asheville, NC 28804 QUALITY CONTROL DATA (828)254-7176 Pace Analytical Services, Inc. 9900 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 C1C Batch: MSV18220 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6011602 Volattles by SM 6200 Associated Lab Samples: 9252397001, 9252397002, 9252397003, 9252397004, 9252397005, 9252397006. 9252397007, 9252397008. 9252397009,9252397010,9252397011,9252397012 METHOD BLANK: 332963 Matrix: Water Associated Lab Samples: 92523 97 001. 9252397002, 9252397003. 92 523 97004. 9252 39 7005. 92 5239 7006, 9252397007, 9252397008, 9252397009,9252397010,9252397011,9252397012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1-Tdchloroethane uglL ND 1.0 09/10/09 10:00 1,1,2,2-Tetrachloroethane uglL ND 1.0 09/10/0910:00 1,12-Tdchloroethane uglL ND 1.0 0911010910:00 1,1-Dichloroethane uglL ND 1.0 09110/0910:00 1,1-Dichloroethene ug/L NO 1.0 0911010910:00 1,2-Dibromoethane (EDB) uglL ND 1.0 09/10/09 10:00 1,2-Dichlorobenzene uglL N❑ 1.0 09/10/0910:00 1,2-Dichloroethane uglL Nd 1.0 09/10/0910:00 1.2-Dichloropropane uglL NO 1.0 09110/09 10 :00 1,3-Dichlorobenzene uglL ND 1.0 09110/09 10., 00 1,4-Dichlorobenzene ug1L ND 1.0 0911010910:01) Benzene ug1L NO 1.0 09110/0910:00 Bromodichloromethane uglL N❑ 1.0 09/10/0910:00 Bromoform ug1L NO 1.0 09110/0910:00 Bromomethane uglL ND 1.0 09/1010910:00 Carbon tetrachloride uglL ND 1.0 09/10/0910:00 Chlorobenzene uglL ND 1.0 09/10/0910:00 Chloroethane uglL ND 1.0 09/10/0910:00 Chloroform ug1L ND 1.0 09/1010910:00 Chloromethane ug/L ND 1.0 09/10/0910:00 cis-1,2-Dichloroethene uglL ND 1.0 09/1010910.00 cis- 1,3-Dichioropropene ug/L NO 1.0 09/1010910:00 Dibromochloromethane uglL ND 1.0 09/1010910:00 Dichlorodifluoromethane uglL NO 1.0 09/1 DI09 10.00 Diisopropyl ether uglL NO 1.0 D9110109 10.00 Ethylbenzene uglL NO 1.0 0911010910:00 m&p-Xyiene uglL ND 2.0 0911010910:00 Methyl-tert-butyl ether uglL N❑ 1.0 09/10/09 10:00 Methylene Chloride ugIL N❑ 2.0 09/10/09 10:00 Naphthalene ug1L ND 2.0 09110/0910:00 o-Xylene uglL NO 1.0 09/10/0910:00 Tetrachtoroethene ug/L NO 1.0 09/10/0910:00 Toluene ug/l_ ND 1.0 09/10/0910:00 trans-1,2-Dichloroetene uglL ND 1.0 09/1010910:00 trans-1,3-Dichloropropene uglL ND 1.0 09/10/0910:00 Trichloroethene uglL ND 1.0 09/1010910:00 Trichlorofluoromethane uglL NO 1.0 09/10109 10: 0 D Vinyl chloride uglL NO 1.0 09110109 10:00 Xylene Jotaly ug1L NO 2.0 D9110109 10:00 1,2-Dichloroethane-d4 jSj % 102 70-130 0911010910:00 4-Bromofluorobenzene (S) % 97 70-130 09110/0910:00 Date: 09/14/2009 09:56 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except +n full. without the written conseni of Pace +Analytical Services, Inc.. Page 17 of 21 aceAnalyfr'cal WKWpacelaucam Project: GILBARCO 97746 Pace Project No.: 9252397 Pace Analytical Services, Inc. 2225 Riverside Dr - Asheville. NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)875.9092 METHOD BLANK. 332963 Matrix: Water Associated Lab Samples: 9252397001. 9252397002, 9252397003. 9252397004. 9252397005, 9252397DQ6, 9252397007, 9252397008, 9252397009,9252397010,9252397011,9252397012 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Dibromofluoromethane (S) % Toluene -dB (S) % 102 70-130 09/10/0910:00 102 70-130 09/10/0910:00 LABORATORY CONTROL SAMPLE: Parameter 332964 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,11-Trichlaroethane ug/L 50 49.6 99 60-140 1,12,2- Tetra chloroethane ug/L 50 46.4 93 60-140 1,1,2-Trichtoroethane ug/L 50 51.0 102 60-140 1,1-Dichloroethane ug/L 50 48.8 98 60-140 1,1-1)ichloroethene ug/L 50 50.3 101 60-140 1,2-Dibromoethane (EDB) ug/L 50 55.2 110 60-140 1,2-Dichlorobenzene ug/L 50 50.2 1 D0 60-140 1,2-Dichloroethane ugIL 50 46.7 93 60-140 1,2-Dichlorapropans ug/L 50 53.6 107 60-140 1,3-Dichlorobenzene ug/L 50 49.7 99 60-140 1,4-Dichlorobenzene ug/L 50 47.8 96 60-140 Benzene uglL 50 49.9 100 60-140 Bromcdichloromethane ug/L 50 49.6 99 60-140 Bromoform ugIL 50 45.4 91 60-140 Bromomethane ug/L 50 61.8 124 60-140 Carbon tetrachloride ug/L 50 56.4 113 60-140 Chlorobenzene uglL 50 51.7 103 60-140 Chloroethane ug/L 50 47.5 95 60-140 Chloroform ug/L 50 47.8 96 60-140 Chloromethane ug/L 50 45A 92 60-140 cis-1,2-Dichloroethene ug/L 50 52A 105 60-140 cis- 1,3-Dichloropropene ug/L 50 55.4 111 60-140 Dibromochloromethane ug/L 50 52.9 106 60-140 Dichlorodifluoromethane ug/L 50 46.3 93 60-140 Diisopropyl ether ug/L 50 48.8 98 60-140 Ethylbenzene ugIL 50 51.3 103 60-140 m&p-Xylene ug/L 100 104 104 60-140 Methyl-tert-butyl ether ug1L 50 46.6 93 60-140 Methylene Chloride ug/L 50 46.7 93 60-140 Naphthalene ug/L 50 55.7 111 60-140 o-Xylene ug/L 50 53A 107 60-140 Tetrachloroethene ug/L 50 53.6 107 60-140 Toluene ugIL 50 413.4 97 60-140 trans-1,2-01chloreethene ug/L 50 47.2 94 60-140 trans-1,3-Dichloropropene ug/L 50 53.7 107 60-140 Trichloroethene ug/L 50 56.4 113 60-140 Tdchlorofluoromethane ug/L 50 38.2 76 60-140 Vinyl chloride ug/L 50 48.2 96 60-140 Date: 09114120D9 09:56 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 18 of 21 t aceAnalylical wwwpecelabs.cam Project. GILBARCO 97746 Pace Project No.: 9252397 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kin coy Ave, Suite too Huntersvilie, NC 28078 LABORATORY CONTROL SAMPLE' 332964 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Xylene (Total) ugIL 150 157 105 60-140 12-❑ichtoroethane-d4 (S) % 87 70-130 4-Bromofluorobenzene (S) % 108 70-130 Dibromofluoromethane (5) % 96 70-130 Toluene -dB (S) % 99 70-130 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 332965 9252397011 Parameter Units Result MS Spike Conc. MSD Spike Conc. 332966 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RP❑ RPD Qual 1,1,1-Trichioroethane ug/L NO 20 20 23.3 23.0 116 115 60-140 1 30 1,1,22-Tetrachloroethane ugIL ND 20 20 23.6 22.3 118 112 60-140 5 30 1,1,2-Trichloroethane ug/L ND 20 20 23.4 22.8 117 114 60-140 2 30 1,1-Dichloroethane ugIL ND 20 20 23.4 22.5 117 112 60-140 4 30 1,1-Dichloroethene ugIL N❑ 20 20 24.0 21.1 120 105 60-140 13 30 1,2-Dibromoethane (EDB) ug/L ND 20 20 24.8 24.1 124 121 60-140 3 30 1,2-Dichlorobenzene ug/L ND 20 20 21.9 22.5 110 112 60-140 3 30 12-Dichloroethane ug/L ND 20 20 22A 21.9 112 110 60-140 2 30 1,2-Dichloropropane ug/L NO 20 20 24.0 23.6 120 118 60-140 1 30 1,3-Dichlorobenzene ugIL ND 20 20 21.8 21.9 109 110 60-140 D 30 1,4-Dichlorobenzene ugIL NO 20 20 20.9 20.9 104 105 60-140 0 30 Benzene ug/L N❑ 20 20 23.0 22.7 115 113 60-140 1 30 Bromodichloromethane ug/L NO 20 20 21.9 21.5 110 108 60-140 2 30 Bromeform ug/L NO 20 20 20.6 20.1 103 100 60-140 3 3D Bromomethane ug/L NO 20 20 23.4 25.8 117 129 60-140 10 3D Carbon tetrachloride ug/L ND 20 20 25.0 24.8 125 124 60-140 1 30 Chlorobenzene ug/L NO 20 20 23.0 22.7 115 113 6D-140 1 30 Chloroethane ug/L ND 20 20 22.9 23.6 114 118 60-140 3 30 Chloroform ug/L NO 20 20 22.5 21.8 113 109 60-140 3 30 Chloromethane ugIL ND 20 20 21.5 21.5 107 108 60-140 0 34 cis-1,2-Dichloroethene ug/L ND 20 20 25.1 24.9 123 121 60-140 1 30 cis-1,3-Dichloropropene ug/L N❑ 20 20 21.2 20.8 106 104 60-140 2 30 Dibromochloromethane ug/L ND 20 20 23.3 22A 117 112 60-140 4 30 Dichlorodifluoromethane ugIL ND 20 20 23.8 23.1 119 116 60-140 3 30 Diisopropyl ether ug/L NO 20 20 22.2 21.8 111 109 60-140 2 30 Ethylbenzene ug/L ND 20 20 22.5 22.6 113 113 60-140 0 30 m&p-Xylene ug/L ND 40 40 42.3 41.8 106 105 60-140 1 30 Methyl-tert-butyl ether ug/L ND 20 20 21.6 20.7 108 104 60-140 4 30 Methylene Chloride ug/L NO 20 20 20.7 20.0 104 100 60-140 3 30 Naphthalene ug/L NO 20 20 21,0 23.7 105 119 60-140 12 30 o-Xylene ug/L ND 20 20 22.1 22.3 111 111 60-140 1 30 Tetrachlaroethene ug/L 2.4 20 20 25.1 25.0 113 113 60-140 0 30 Toluene ugIL NO 20 20 22.0 21.7 110 108 60-140 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.7 21.5 108 108 6D-140 1 30 trans-1,3-Dichloropropene uglL ND 20 20 20.2 20.3 101 101 60-140 0 30 Trichloroethene ug/L 1.1 20 20 26.3 25.8 126 124 60-140 2 30 Trichlorofiuoromethane ug/L N❑ 20 20 21.1 18.6 105 93 60.140 13 30 Date: 09/14/2009 09:56 AM REPORT OF LABORATORY ANALYSIS Page 19 of 21 This report shall not be reproduced, except in full, without the written consent of�Pace rAnalytical Services, Inc aceAnalXical www.pac+afahs.00m i Project: GILBARCC 97746 Pace Project No.: 9252397 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 332965 MS 9252397011 Spike Parameter Un€ts Result Conc. Vinyl chforide ug/L N❑ 20 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Dibromofluoromethane (S) % Toluene-d8 (S) % Date. 09/14/2009 09:56 AM Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 332966 MSD Spike MS MSD MS MSD % Rea Max Conc. Result Result % Rec % Rec Limits RPD RPD Gual 20 23.2 23.7 116 119 60-140 2 30 94 91 70-130 103 105 70-130 101 99 70-130 98 98 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. �fi^aeh Page 20 of 21 r, Pace Analytical Services, Inc, Pace Analytical Services, Inc. /1� laceAnayical 2225 Riverside 0r.9800 ICinceyAve. Suite 1D0 www.pacalabs cam Asheville, NC 288D4 Huntersvilie, NC 28078 QUALIFIERS Project: GtLBARCO 97746 Pace Project No,: 9252397 DEFINITIONS (828)254-7176 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. S - Surrogate 1.2-❑ipheny1hydrazine (8270 listed analyte) decomposes toAzobenzene. Consistent with FPA guidelines, unrounded data are displayed and have been used to calculate Io recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. U - Indicates the compound was analyzed for, but not detected. (704)875-9092 Date: 09/14/2009 09 56 AM REPORT OF LABORATORY ANALYSIS Page 21 of 21 This report shall not be reproduced. except In full, Without the written consent of Pace Analytical Services, Inc.. cv*�� �'aC2Ark?lyfrra! Section A Required Client Information: Section B Required Project information CHAIN -OF -CUSTODY ! Analytical Request Document The Chain-of-Cuslody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Pane : 1 Of Company Klelnfelder Report To. Gail Lica an Altenliun Gail Lica an Address 313 Gallimore Dairy Rd Copy To Company Name Kleinfelder Greensboro, NC 27409 Address. 313 Gallimare Dairy Rd, Greensboro, N Regulatory A errs Email To glicayan@kleinfelder.com Purchase Order No Pace Quote Reference: Phone (336) 668.0093 FaX Client Project I❑ GILBARCO 97746 Pace Project Manager McKee, Bonnie 8feH1 L"N"a Requesled Due Date1TAT 10 Da Default Container Order Number Pace Profile 4 North Carolina R Analyela Filtered YIN) _o n f MATRIX CODE 8 O COLLECTED z Preservatives O-king WW. D1N U O Wa. VVT u Y w W ape WMer WW PrvO�cl P c Z SAMPLE ID S., Sar'a SL u r7 START ENO x Oil oL .. F ui One Ctsarectn per box. Mpa wv w w a z v H a IA -I, 0-91, •} oap AR th. a O w a U ✓✓✓ # Sample Ids must be unique T,rrow Ts x w w p n a N mo W d a a n ON L F Q Q N DATE TIME DATE TIME �+ ❑ at C [V _ 2 = CJ z 16 z W z m W a 1 MW-7 WT G 912109 AA x x i MW-11 VIT G 9009 R3,1 1 3 x I I I I X 3 MW-13 WT G 912109 91b 1 3 X X 4 MW-13D WT G 9l2M9 -166 1 3 x X 6 MW-14 WT G 912*9 f 3 x x 6 MVV•14O WT G WM9 3 x k 7 MW73D WT G 912109 3 1 1 1 X I I X 8 MW-24 WT G 912109 11V5CP 3 x x 9 MW-25 WT G 91209 3 x x 10 MWA2 WTI G 912109 3 I I % I I I X 11 JMWA3D WT G 912109 3 I I x % 12 MWA5 WTI G 1 912109 1`1,561 1 x1+�fl ]( ADDITIONAL COMMENTS RELINQUISHED BY) AFFtUATION DATE TOE ACCEPTER BY IARFZ♦.IAMON DATE TIME SAMPLE CRNDRIQNS SAMPLERNAME AND SIGNATURE `m x a PRINT Name of SAMPLER: Gail Lica an 11m w m d Fa m m ? SIGNATURE of SAMPLER: DATE Signed (I tr u 5 w r rn ? APPENDIX B CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-7 t Total VOCs 0 Chlorinated VOCs n 15,000 0 n 10,000 t m 1-1 1�0 h ao '0 '0 � �0 *Q %0 7b �y Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-11 imc :ir 600 0 n ro m 400 m - T 7 rl- 0 Llo 7 �s 79 ri'9 �0 %> 7 0 �l0 rl'0 h'0 ri3O r1'0 *� 7o 7 �i� 0 '00 r0 '90 r r' u' s '�s j 8 �9 0 r 2 U' � S g5' � � .9 Data CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-13 m w N r- 400 'Fl Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-13D --- 1,000 —+ Total VOCs + Chlorinated VOCs Date m 600 0 n co 4 w 400 � CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-14 15,000 o n m 3 io io 111 t!0 ` [lq} t/� vlo Jl G/� �!� , v� , t/� t/� ' �� , �� c% v� ` ✓1 , v� s /� cf� t�� Vlo '0 �i9 'y9 �9 h �� �9 �9 �0 p '�0 �7 h p r1, `i'0 �o �0 r r 2 � 'fir S `�S � S 9 �D r � � �u S � � S 9 0 Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-14D WE m 600 q n In CD m 400 Date D N CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-23D m 600 Q n m s 7 co 400 T a] a v� v� , `'iQ' v�, vl `l` `�Q' `� `��' `lql `iQ' v� ✓1 c% `rQ' `lq `ro'' c% vq s/o v� �i �g o �9 ri, �0 f!, �9 � '0 h0 �0 70 �i p �0 f!, �D �0 r `� �' 2 cr `Qsr S `�5' � 8 � � T c� cs� � S �6' � � �i9 D Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-24 1 'TyT, 15,000 0 m n m m 11, 411 191 ri,9 ri,�,� �9 h9 7o '� ADD �0 �i0 'D �o �0Q '� `9D i tp 19 S E '�9 O ! u� F S Db' Dig D Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-25 — Total VCCs 0 Chlorinated VOCs +2 Elio] 600 0 n ca 3 m 0 IA 400 200 F, L10 �� �9 �,� �s %� �o �a �� 7� po o r '$� r 2 '�Sz s '�S S °o r 0sr S S 09 a Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-42 m :m 600 0 3 n tp w O N 400 C vQI ✓� J� ✓� v4, v� vpv� v�, v� v� vo 1 1 ✓1 ,P c% v4, vl 110 c%, v1 �0 �o �.0 �0 79 fi, 7.0 fi, �� fi, '}0 ri0 0 o 7o ri' n0 ri' , r 90 r 2 1? Q S � > `Sip �9 0o r 2 0 u S 06 > 0cP 09 0 Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-43D t Total VOCs +Chlorinated VOCs Teti E 1+I0] 600 0 n m N b 7 N 400 A 10f V91 1/1� '� �19 �91 90 '9v �'9s `'�, �9j �-9& �`99 °o 'v, '°a �O1p �Cisr °s �°�, �Y7� �1?p �019 '/0 Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-45 ME rlflf 600 0 n 3 N 0 (n 400 If I., v� ✓� v4, v� W� v� ' c% , v� v� , v� �� e%y c�� sly v� ✓� , �� �� �9�o '0 �o �� �'o �o 'r 'SD r r' u' r s S' ` o r 2 o S 00 � qc9 9 0 Date