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HomeMy WebLinkAboutWI0400198_Monitoring (Report)_20171031ARCADIS Design sr Consultancy fornaturaland built assets Mr. Michael Rogers UIC Program Manager NCDEQ — DWR 1636 Mail Service Center Raleigh, North Carolina 27699 Subject: 2nd Semi -Annual Groundwater Monitoring Report — 2017 Former BP Facility #24163 381 Knollwood Street Winston-Salem, North Carolina 27103 Incident Number: 6400 (Closed) Risk Classification: Low (No Further Action) Dear Mr. Rogers: On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina is submitting the attached 2nd Semi -Annual Groundwater Monitoring Report — 2017 dated October 31, 2017 for the above referenced site. An electronic copy of this report including the associated laboratory analytical report is included with the attached CD. Please contact me at (919) 415-2327 with any questions or concerns related to the Report or this incident number. Sincerely, Arcadis G&M of North Carolina, Inc. r Paul Goodell, E.I. AFS Project Manager 5 Copies: File — BP #24163 Arcadis U.S., Inc. 111-D Sanders Lane Tel 919 854 1282 Fax 919 854 5448 www.arcadis.com A019Ide7►1tIIA011 Date: October 31, 2017 Contact: Paul Goodell Phone: 919.415.2327 Email: Paul.Goodell@Arcadis.com Our ref: GP16BPNA.NC10 Page: 1/1 ARCADIS ')',sign&Consultancy far naturaand Built assetls Atlantic Richfield Company c/o BP Products North America, Inc. 2ND SEMI-ANNUAL MONITORING REPORT - 2017 Former BP Facility #24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina NCDEQ Incident #6400 (Closed) Injection Permit #W10400198 October 2017 2"d Semi -Annual Monitoring Report - 2017 lr Alexandra M. Simpson AFS Task Manager 3 Paul Goodell, E.I. AFS Project Manager 5 C. Scott Bostian, P.E. 154.' Z � North Carolina P-zk. Nt., 5669 Senior Engineer �VJge f � � N ''fir o as i% 2ND SEMI-ANNUAL MONITORING REPORT REPORT - 2017 Prepared for: Atlantic Richfield Company c/o BP Products North America, Inc. Mr. Greg Frisch — Project Manager 4850 E. 4911 Street MBC-3 Room 155C Cuyahoga Heights, Ohio 44125 Tel 216.416.1232 Prepared by: Arcadis G&M of North Carolina, Inc. 801 Corporate Center Drive Suite 300 Raleigh, North Carolina 27607 Tel 919.854.1282 Fax 919.854.5448 www.arcadis-us com Environmental Our Ref: GPI6BPNA.NC10 Date: October 24, 2017 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged, confidential and exempt from disclosure under applicable law. Any dissemination, distribution or copying of this document is strictly prohibited. arcades com 2nd Semi -Annual Monitoring Report - 2017 2nd Semi -Annual Monitoring Report - 2017 Former BP Facility #24163 381 Knollwood St Winston-Salem, Forsyth County, North Carolina Latitude 361, 5' 25.94"N Longitude 801) 17' 11.79"W (Reference Figure 1) Groundwater Incident #: 6400 (Closed) Risk Classification: Reason for Risk Classification: Land Use Category; Source of Release: Date of Release Discovery: Estimated Quantity of Release. - Cause of Release: Responsible Party: Property Owner: Low (No Further Action) Dissolved -phase Sulfate concentrations above groundwater quality standards (2L) Industrial/Commercial Former gasoline UST system(s) 1983 Unknown Former UST System Atlantic Richfield Company c/o BP Products North America, Inc. Attn: Greg Frisch 4850 East 49h Street MBC-3 Room 155C Cuyahoga Heights, Ohio 44125 (216) 416-1232 Mr, Charles Sherren Thruway Shopping Center, LLC. 7501 Wisconsin Ave., Suite 1500 Bethesda, Maryland, 20814 (301) 986-2925 ext. 215 ,p a Professional Engineer for Arcadis G&M of North ter, Carolina, trio., do-certi�rti�t the information contained in this report is correct and accurate to the best of my knowledge, At'eadis G&M of North Carolina, Inc. is licensed to practice geology and engineering in North C, rQlin J-TWcerWication numbers of the company are C-155 (geology) and C-1869 (engineering). >r ANr waaoc � ­10F. LO�II 2nd Semi -Annual Monitoring Report - 2017 CONTENTS 1.0 Site History and Characterization .... 2.0 Groundwater Monitoring ................... 2.1 Groundwater Gauging ................ 2.2 Groundwater Sampling .............. 2.3 Groundwater Analytical Results. 3.0 Site Remediation .............................. 3.1 Remediation Activities to Date... 4.0 Conclusions and Recommendations TABLES Table 1. Monitoring Well Construction Data Table 2. Groundwater Elevation Data Table 3. Summary of Groundwater Analytical Data FIGURES Figure 1. Site Location Map Figure 2. Site Map Figure 3. Potentiometric Surface Map - September 20, 2017 Figure 4. Groundwater Analytical Data - September 2016 - September 2017 Figure 5. Sulfate Isoconcentration Map - September 20, 2017 APPENDICES A- Historical Groundwater Elevation Data B- Laboratory Analytical Report and Chain -of -Custody Record — September 20, 2017 C- Historical Groundwater Analytical Data 2 4 4 4 4 5 6 7 arcadis.com 2"d Semi -Annual Monitoring Report - 2017 EXECUTIVE SUMMARY On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina, Inc. (Arcadis) personnel performed the semi- annual groundwater sampling of groundwater monitoring wells associated with Former BP Facility #24163 located at 381 Knollwood Street, in Winston-Salem, Forsyth County, North Carolina (the Site) on September 20, 2017. All groundwater monitoring activities were conducted in response to the final project evaluation requirement specified in Part VII, Item 5 of the Renewal Issuance of Injection Permit W10400198 from the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Quality — Aquifer Protection Section in April 2013. On September 20, 2017, Arcadis completed a semi-annual groundwater monitoring and sampling event at the Site. Four (4) groundwater monitoring wells (MW-5R, MW-8R, MW-18, and MW-19) were gauged to determine the depth to water (DTW). DTW ranged from 13.21 feet below top of casing (btoc) in groundwater monitoring well MW-18 to 13.67 feet btoc in groundwater monitoring well MW-5R. The historical groundwater flow direction for the Site is towards the southeast. On September 20, 2017, groundwater samples were collected from groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19. The maximum concentrations of selected dissolved -phase COCs found during the September 20, 2017 sampling events are summarized in the table below: Maximum Groundwater Concentrations (September 20, 2017) Chemical of Monitoring Well Concentration North Carolina Concern ID (mg/L) Groundwater (COC) Quality (2L) Standards Sulfate MW-5R 1,060 250 Note: Concentration in Bold exceeds the applicable North Carolina GCL Standard mg/L: milligrams per liter Dissolved phase sulfate concentrations decreased compared to historical groundwater analytical data. Dissolved phase sulfate was detected above the applicable North Carolina Groundwater Quality (2L) Standard at groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for March 2018. Groundwater monitoring wells MW- 5R, MW-8R, MW-18, and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-5R, MW-8R, MW-18, and MW-19 for analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2018 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com ES-1 2"d Semi -Annual Monitoring Report - 2017 1.0 SITE HISTORY AND CHARACTERIZATION Former BP Facility #24163 is located at 381 Knollwood Street, Winston-Salem, Forsyth County, North Carolina (the Site). The Site is currently owned by Thruway Shopping Center, LLC. and serves as a parking lot adjacent to surrounding retail stores. The site property is approximately 0.5 acres, covered by asphalt and concrete, and was formerly developed as a retail fueling station which housed gasoline, diesel, waste oil, and kerosene Underground Storage Tanks (USTs). A site location map is presented as Figure 1 and a site map is shown as Figure 2. The North Carolina Department of Environmental Quality (NCDEQ) issued groundwater incident number 6400 due to a subsurface release of gasoline that occurred on or before September 14, 1983 from a ruptured product line associated with the UST system. The quantity of the release remains unknown. One (1) 10,000-gallon steel gasoline UST, three (3) 6,000-gallon steel gasoline USTs, and one (1) 10,000-gallon steel diesel UST were removed from the site in 1990. Three (3) 10,000-gallon gasoline USTs, one (1) 10,000-gallon diesel UST, and one (1) 550-gallon waste oil UST were subsequently installed at the site and the site was purchased by M. M. Fowler, Inc. in January 1994 and continued operation until 2004. The remaining five USTs were removed before 2005 and the site was razed. Site geology and hydrogeology include surficial deposits immediately underlying the site are described generally as sandy silts that grade upward to clayey silts and silty clays. Bedrock beneath the site is mapped as a strongly foliated biotite gneiss and schist. The maximum depth of investigation at the site has been approximately 55 feet below ground surface (bgs); bedrock has not been encountered during site investigation work. Historically, the range for shallow groundwater beneath the site is approximately 11 to 14 feet bgs, and groundwater flow direction is toward the southeast with an apparent horizontal gradient of approximately 0.012 feet per foot (ft/ft). The calculated groundwater seepage velocity for shallow groundwater beneath the site is approximately 2.8 feet per year. Two activated sodium persulfate injections were performed at the Site on June 4 — 9, 2012 and June 3 — 6, 2013 under Underground Injection Control (UIC) Permit #W10400198 which was issued by the NCDEQ Division of Water Quality on August 9, 2011. Approximately 11,237-gallons of sodium persulfate and 6,826-gallons of sodium persulfate were injected at the Site on June 4 — 9, 2012 and June 3 — 6, 2013, respectively. The NCDEQ Risk Classification for this site was reduced to "Low" on January 23, 2015 after issuing a request for Notice of Residual Petroleum (NORP). The NORP was recorded with the Forsyth County Register of Deeds on March 18, 2015 and imposed the following perpetual restriction on the Site property: • Groundwater: Groundwater from the site is prohibited from use as a water supply. Water supply wells of any kind shall not be installed or operated on the site. No Further Action (NFA) status was granted for the subject incident number by the NCDEQ on April 28, 2015. In accordance with UIC Permit #W10400198, dissolved -phase concentrations of sulfate are being monitored on a semi-annual basis at the Site. Closure of UIC Permit #W10400198 will be requested once arcadis.com 2 2"d Semi -Annual Monitoring Report - 2017 dissolved -phase sulfate concentrations are no longer detected above the North Carolina Groundwater Quality (2L) Standards. arcadis.com 2"d Semi -Annual Monitoring Report - 2017 2.0 GROUNDWATER MONITORING 2.1 Groundwater Gauging On September 20, 2017 Arcadis G&M of North Carolina, Inc. (Arcadis) personnel gauged groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19. Gauging was conducted with a water interface probe (IP) prior to purging and sampling to determine DTB and DTW. The IP and attached tape, marked in 0.01-foot increments, were properly decontaminated before each use with Alconox soap and rinsed with distilled water. The DTW was measured from the marked survey point on the top of well casing (TOC). All measurements were recorded to the nearest 0.01-foot increment. The DTW ranged from 13.21 btoc in groundwater monitoring well MW-18 to 13.67 feet btoc in groundwater monitoring well MW-5R. Groundwater monitoring well construction details are included in Table 1. Current groundwater elevations are summarized in Table 2. Historical groundwater gauging data is provided in Appendix A. A potentiometric surface map depicting historical groundwater flow direction is provided as Figure 3. 2.2 Ground water Sampli ng On September 20, 2017, groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19 were purged of stagnant water to prepare for groundwater sampling. Prior to purging, the amount of water to be removed was calculated using the following formula: 3.1415 x r2 x (TD-DTW) x 7.481 = gallons of water (1 well volume) Where: r = radius of well (in feet) TD = total depth of well (in feet) DTW = depth to water (in feet) In order to ensure that the water in the wells after purging is representative of the water in the aquifer, a minimum of three well volumes were removed. Groundwater samples obtained from the groundwater monitoring well were collected from disposable polyethylene bailers using new nylon rope. Groundwater samples were placed in laboratory supplied containers and shipped on wet ice to TestAmerica Inc. in Nashville, Tennessee, for analysis of Sulfate (SO4) by Standard Method 9056A. Groundwater samples submitted for sulfate analysis were collected in 250-milliliter plastic bottles. The laboratory analytical report and chain -of -custody record for the September 20, 2017 groundwater sampling event is included as Appendix B. 2.3 Groundwater Analytical Results Groundwater analytical data from the September 20, 2017 groundwater sampling event indicated the following: arcadis.com 4 2"d Semi -Annual Monitoring Report - 2017 Dissolved -phase concentrations of sulfate were detected in concentrations exceeding the applicable North Carolina 2L Standard of 250 milligrams per liter (mg/L) in groundwater monitoring wells MW-5R (1,060 mg/L), MW-8R (797 mg/L), MW-18 (257 mg/L), and MW- 19 (1,020 mg/L). Current groundwater analytical results are presented in Table 3. Historical groundwater analytical data can be found in Appendix C. A dissolved phase concentration map is presented as Figure 4. A sulfate isoconcentration map depicting the dissolved -phase extent of sulfate exceeding the applicable 2L groundwater quality standard is presented in Figure 5. arcadis.com 2nd Semi -Annual Monitoring Report - 2017 3.0 SITE REMEDIATION 3.1 Remediation Activities to Date Summarized in the table below is a chronology of remediation activities performed at the site to date: Date Activity September 14, 1983 Subsurface release of gasoline from a ruptured product line associated with the UST system December 1990 UST systems associated with release removed; 500 tons of contaminated soil removed during UST closure 1992 Vacuum Extraction System Installed 1992 - 1994 Vacuum Extraction System Operation 1994 - 2011 Monitoring of site June 4 — 9, 2012 Activated Sodium Persulfate (ASP) injection event. Approximately 11,237-gallons of sodium persulfate injected. June 3 — 6, 2013 ASP injection event. Approximately 6,826-gallons of sodium persulfate injected. 2013 - Present Monitored Natural Attenuation arcadis.com 2"d Semi -Annual Monitoring Report - 2017 4.0 CONCLUSIONS AND RECOMMENDATIONS Dissolved -phase sulfate was detected above the applicable 2L groundwater quality standard for sulfate of 250 mg/L in groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19 on September 20, 2017. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for March 2018. Groundwater monitoring wells MW- 5R, MW-8R, MW-18, and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-5R, MW-8R, MW 18, and MW-19 for analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2018 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com 2"d Semi -Annual Monitoring Report - 2017 TABLES arcadis.com Table 1 Monitoring Well Construction Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina ARCADI Design & CnnsuLYancy 00 � for naturaland built assets 7MW-3 . - . In Use Type II 99.03 20 2 NA - NA NA MW-5 Abandoned Type II 99.39 25.5 4 10.5 - 25.5 81.4 MW-5R In Use Type II NS 20 2 10 - 20 NA MW-6 In Use Type II 98.68 25.5 4 10.5 - 25.5 80.7 MW-6i In Use Type III 99.26 55 2 50 - 55 46.8 MW-8 Abandoned Type II 97.84 24 6 NA - NA NA MW-8R In Use Type II NS 20 2 10 - 20 NA MW-14 In Use Type II 100.44 22 4 7 - 22 85.9 MW-15 In Use Type II 99.91 22 4 7 - 22 85.4 MW-16 In Use Type II 97.42 25 2 10 - 25 79.9 MW-17 In Use Type II 100.00 22 4 7 - 22 85.5 MW-18 In Use Type II NS 20 2 10 - 20 NA MW-19 In Use Type II NS 20 2 10 - 20 NA Notes: 1. Reported in feet below grade 2. Measured in feet relative to site datum 3. Conestoga Rover and Associates, a former consultant for this Site, previously reported that no reference was found to the following wells: MW-1, MW-9, MW-10, MW-11, MW-12 or MW-13. These wells are presumed to be abandoned. 4. Monitoring wells MW-5 and MW-8 were abandoned on 5/19/2010 and replaced with monitoring wells MW-5R and MW-8R the same day. 5. Monitoring wells MW-18 and MW-19 were installated on October 25, 2011. NA = Not Applicable / Available NS = Not Surveyed TOC = Top of Casing Page 1 of 1 Table 2 Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AAR'' DI 6ul]esign&Consultancy V fornatwaland itassets MW-5R 9/20/2017 NM ND 13.67 0.00 NM MW-8R 9/20/2017 NM ND 13.61 0.00 NM MW-18 9/20/2017 NM ND 13.21 0.00 NM MW-19 9/20/2017 NM ND 13.48 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Corr. GW Elev. _ (ref. point elevation) - (depth to groundwater) + (LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 LNAPL = Light non -aqueous phase liquid ND = Not detected NM = Not measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing Page 1 of 1 Table 3 Summary of Groundwater Analytical Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, NC ARCADISA15 esignBCnsultsnty ornaturaland uilt assets Sample. �. Date Sampled 9/20/2017 9/20/2017 9/20/2017 9/20/2017 Units mg/L mg/L mg/L mg/L Sulfate 1,060 797 257 1,020 Notes: mg/L - milligrams per liter BOLD text indicates exceendance of NC groundwater standard 2L for sulfate (250 mg/L). Page 1 of 1 FIGURES e4 o 3 fc* !p 4+ Buena pOINGTON LN �NHODD RD y� VILa W z a � x x x x z a 3 a z '^ a S"'S a 3 Y GTON LN N W .�GREEN6RIER o N RD q a o O fog VfRG1+V0 1A RD 85 s r9,O a �04 _zf FIELDALEAVECL FOREST DR 1i t CARDLI QQ� DR DR NW REYNOLDS m ANGELO:ST 87 t�� REY OLDS _ Wq Irk t 1 �D GEORGlA AYE es D HlghIan ds / g,�UNrRrCz&8 West!view rr�Nvq° �v yy��� � RD N-t.� f, NOD& . of a a SOR Q � N9 �+ 2 ti 8uCKINGHAM �. RD RD D c� � x x w x EEC a a a o 0 0 PR x rn ro R o. �tlE 158 ao F q y� CLOVER9ALE h xr co 1 OR.¢DIRV . rn = SITE LOCATION q f w. z EIJ%ABETHAVE ROSEWOOD AVE a a �] a WESTOVER DR n a 21 r s�yp o�e(i-p Q w y. GASTONST a Hanes FAlRWAY•DR u rn� w SOP Qv 6P �P? MApLEyyOOAAVI SW Q� MAPLEWOODAVE AROSLEY ST LYNDHLRST,AVE _ Burke O .- 5 FfliWTHORME RD 4 WALKER AVE r z Park co = W AVE 9 a Po WESTRIDGERD r- JEFFERSON x r HEALY OR n ® y West RD +- i a a CHEROKEE ST 3 N Oaks �". J REFERENCE: BASE MAP USGS 7.5. MIN. TOPO. QUAD., WINSTON-SALEM WEST, NC, 2016. 0 2000' 4000' w ATLANTIC RICHFIELD COMPANY Approximate Scale: 1 in. = 2000 ft. C/O BP PRODUCTS NORTH AMERICA, INC. FORMER BP STATION 24163 w 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA &3: 2nd SEMI-ANNUAL MONITORING REPORT-2017 aE a AREA LOCATION SITE LOCATION MAP �3 FIGURE A ARCAD I S bulltasseU nd NORTH CAROLINA m O M.H. LEGEND: UP is�q�o - - PROPERTY LINE • U.P.• • UP. 00- f ABANDONED GROUNDWATER MONITORING WELL ONCRETE FORMER PRODUCT LINE GRASS EL METER IC QC.B. g CATCH BASIN PARKING M-17 Q M.H. MAN HOLE AREA LIGHT ` • U.P. UTILITY POLE ' b- F.H. FIRE HYDRANT TELEPHONE ASPHALT TRASH LARGE MANHOLE COVER PARKING ENCLOSURE ` GROUNDWATER MONITORING WELL MW-3 METAL SHED N �2 O W' r — — — — — — I METAL SHE I • ����Lu/ FORMRMER EGASOLINE SERVICE ` AREAI gP STATION Q MW-18 — — ` NOTE: CONCRETE PAD 1. MONITORING WELL LOCATIONS ARE APPROXIMATE. 0 0 40. 0 0 2. THE SITE PARKING IS A VACANT PARKING LOT. ALL SITE FEATURES EXCEPT LOT CURBS AND ROADWAYS REPRESENT FORMER SITE MW-5MW-5R MW-14 CHARACTERISTICS. J MW-16 0 MW-8 F.H. ��, FORMER PUMP MW_8R ISLAND(TYP) FORMER ` �Q Z MW-6i I CANOPY PARKING I JMW-1I —_ FORMER DIESEL UST AREA I I MW-6 _ FORMER PUMP ' ISLAND(TYP) I CONCRETE FO ER TAN OLD 0 0 0 o FORMER T 0 30' 60' 0 0 0 o • CANOPY I GRAPHIC SCALE ❑ - I FORMER VENT RISERS ATLANTIC RICHFIELD COMPANY C/O BP PRODUCTS NORTH AMERICA, INC. pp0 FORMER BP STATION 24163 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 2nd SEMI-ANNUAL MONITORING REPORT - 2017 MW-15 00 FORMER OG0 VENT RISERS SITE MAP O M.H. FIGURE PARCADIS WI&lnd I m O M.H. LEGEND: UP is�q�o - - PROPERTY LINE • U.P.• • UP. 00- f ABANDONED GROUNDWATER MONITORING WELL ONCRETE FORMER PRODUCT LINE GRASS EL METER IC QC.B. g CATCH BASIN PARKING M-17 Q M.H. MAN HOLE AREA LIGHT ` • U.P. UTILITY POLE ' b- F.H. FIRE HYDRANT TELEPHONE ASPHALT TRASH LARGE MANHOLE COVER PARKING ENCLOSURE ` GROUNDWATER MONITORING WELL MW-3 METAL y (NSVD) NOT SURVEYED TO VERTICAL DATUM Zo HISTMETAL L DEPICTED GROUNDWATER FLOW (FT W F------� SHE AMSO DI IC Lu I • FT AMSL FEET ABOVE MEAN SEA LEVEL ����Lu/ FORMRMER EGASOLINE SERVICE ` AREAI gP STATION 0 MW-18 — — ` NOTE: (NSVD) CONCRETE PAD 1. MONITORING WELL LOCATIONS ARE APPROXIMATE. O 40. 0 O 0 2. THE SITE IS A VACANT PARKING LOT. ALL SITE FEATURES EXCEPT PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE MW-S--- MW-5R MW-14 CHARACTERISTICS. J I (NSVD) MW-16 O7 M W-8 - - F.H. ���, FORMER PUMP MW-8R ISLAND(TYP) ` IQ Z MW-61 YI NSVD (NSVD))11 FORMEY CANOPY PARKING I JM W 1 r�am�,� (NSVD) FORMER DIESEL ray I UST AREA _ I ` MW-6 —FORMERPUMP ' ISLAND (TYP) I CONCRETE FO ER TAN OLD 0 0 T 0 30 60 FORMER 0 0 • UO uI'Fbi CANOPY aaaaaaaal I GRAPHIC SCALE ❑ - I FORMER VENT RISERS 00 ATLANTIC RICHFIELD COMPANY C/O BP PRODUCTS NORTH AMERICA, INC. pp0 FORMER BP STATION 24163 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 2nd SEMI-ANNUAL MONITORING REPORT - 2017 MW-15 00 FORMER OG0 VENT RISERS POTENTIOMETRIC SURFACE MAP SEPTEMBER 20, 2017 O M.H. FIGURE for natural. and PARCADIS Wil I lmlsset. O M.H. O • U.P. • U.P. • UP ONCRETE LEGEND: — — — PROPERTY LINE GRASS E CTRIC ABANDONED GROUNDWATER MONITORING WELL PARKING M TER MW 17 FORMER PRODUCT LINE Oc.6. ` CATCH BASIN Q M.H. MAN HOLE ' AREA LIGHT • U.P. UTILITY POLE ASPHALT TRASH F.H. FIRE HYDRANT PARKING ENCLOSU ` TELEPHONE MW-3 METAL in LARGE MANHOLE COVER SHED � Zo GROUNDWATER MONITORING WELL W F — — — — — METAL SHED mg/L MILLIGRAMS PER LITER ���Lu I • FORME ASCLINE I FORMER ` '^ AREA I BP SERVICE V / STAT E] Q I MW-18 — — � CONCRETE 0 PA NOTE: 0 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L MW-S--- MW-5R MW-14 J I 2. VALUES IN BOLD EXCEED NORTH CAROLINA 2L STANDARDS. M W-8 MW-16 F.H. ��, FORMER PUMP �Q 0 ' �T M W - 8 R ISLAND(( Y') ` FORMER Z MW-6i I CANOPY PARKING I JMW-1I —_ ��_� 11: FORMER DIESEL11 I#-s.USTiREAMW-6 ' FORMER PUMP ISLAND(TYP) I CONCRETE FO ER TAN OLD 0 0 0 o FORMER T 0 30 60 0 0 0 0 CANOPY • ❑ I — I GRAPHIC SCALE FORMER VENT RISERS ATLANTIC RICHFIELD COMPANY C/O BP PRODUCTS NORTH AMERICA, INC. 00o FORMER BP STATION 24163 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 2nd SEMI-ANNUAL MONITORING REPORT - 2017 OG0 MW-15 FORMER VENT RISERS GROUNDWATER ANALYTICAL DATA SEPTEMBER 2016 - SEPTEMBER 2017 O M.H. /� /� A`VADIS for natural. Willmassets�d._ I FIGURE MW-8R Date 9/19/2016 3/3/2017 9/20/2017 SO4 1,330 1,720 797 MW-18 Date 9/19/2016 3/3/2017 9/20/2017 SO4 377 295 257 MW-5R Date 9/19/2016 3/3/2017 9/20/2017 SO4 2,880 3,570 1,060 MW-19 Date 9/19/2016 3/3/2017 9/20/2017 SO4 1,270 941 1,020 LEGEND Abbreviation Constituent 2 L SO4 Sulfate 250 O M.H. O U.P. • U.P. U.P. ONCRETE GRASS ELECTRIC PARKING M TER I LEGEND: MW-17 — — — PROPERTY LINE ` f ABANDONED GROUNDWATER MONITORING WELL FORMER PRODUCT LINE ' QC.B. CATCH BASIN ASPHALT TRASH O M.H. MAN HOLE PARKING ENCLOSURE ` AREA LIGHT MW-3 METAL N� • U.P. UTILITY POLE SHED vo � F.H. FIRE HYDRANT r — — — — — — METAL SHED W I TELEPHONE W I LARGE MANHOLE COVER w I I GROUNDWATER MONITORING WELL FORMER GASOLINE FORMER ` co UST AREA I BP SERVICE (1,060) SULFATE CONCENTRATION (mg/L) `�� STATION ` 250 ESTIMATED SULFATE CONCENTRATION CONTOUR 2L coNCRETE STANDARD (mg/L) PAD O ` 0 °m (mg/L) MILLIGRAMS PER LITER N/ M257)8 O o° MW-5 MW-5R MW-14 J I (1,os0) MW- — — — O sly NOTE: �Q MW-16 O F.H. FORMER PUMP I MW-8R ISLAND (TYP) ` FORMER 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L Z 1 MW-6i 797 CANOPY 2. SHADED VALUES EXCEED NORTH CAROLINA 2L STANDARDS. PARKING I �I _ MW-19 _ (1,02U) FOR DIESEL — `i I IREA I I ` _ MW-6 FORMER PUMP ' ISLAND(TYP) CONCRETE FO ER TAN OLD 0 00 30' 60' FORMER 0 o CANOPY aaaaaaaal UO I GRAPHIC SCALE ❑ — I FORMER VENT RISERS ATLANTIC RICHFIELD COMPANY 00 C/O BP PRODUCTS NORTH AMERICA, INC. �p0 FORMER BP STATION 24163 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 2nd SEMI-ANNUAL MONITORING REPORT - 2017 Mw-15 00 FORMER 0°0 VENT RISERS SULFATE ISOCONCENTRATION MAP SEPTEMBER 20, 2017 O M.H. FIGURE PARCADIS for natural. builtaassetsnd I APPENDIX A Historical Groundwater Elevation Data Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina P ARCAD I S Oesign 8 rmisul[a uy firmtwaland nulttamts * 06/24/93 ND 13.89 0.00 85.14 08/23/94 ND 14.36 0.00 84.67 03/21/95 ND 13.58 0.00 85.45 08/05/96 ND 13.54 0.00 85.49 11/17/98 ND 14.09 0.00 84.94 06/19/01 ND 14.11 0.00 84.92 09/12/01 ND 14.41 0.00 84.62 12/27/01 ND 14.51 0.00 84.52 03/05/02 ND 14.29 0.00 84.74 05/13/03 ND 14.35 0.00 84.68 12/09/03 ND 13.63 0.00 85.40 03/23/06 ND 13.64 0.00 85.39 05/08/07 ND 13.40 0.00 85.63 05/14/08 ND 13.42 0.00 85.61 05/28/09 ND 13.31 0.00 85.72 05/27/10 ND 13.07 0.00 85.96 10/31/11 ND 13.87 0.00 85.16 MW-3 99.03 05/22/12 ND 13.55 0.00 85.48 06/14/12 ND 13.53 0.00 85.50 07/09/12 ND 13.98 0.00 85.05 08/14/12 ND 14.24 0.00 84.79 09/19/12 ND 14.08 0.00 84.95 12/05/12 ND 14.42 0.00 84.61 02/26/13 ND 13.55 0.00 85.48 05/31/13 ND 13.58 0.00 85.45 08/28/13 ND 13.57 0.00 85.46 11/07/13 ND 14.30 0.00 84.73 02/27/14 ND 13.28 0.00 85.75 06/02/14 ND 13.34 0.00 85.69 10/16/14 ND 14.18 0.00 84.85 04/23/15 ND 13.54 0.00 85.49 04/28/16 ND 13.51 0.00 85.52 09/19/16 ND 13.92 0.00 85.11 03/03/17 ND NM 0.00 NM 06/24/93 ND 13.51 0.00 85.88 08/23/94 ND 13.82 0.00 85.57 03/21/95 ND 13.71 0.00 85.68 08/05/96 ND 13.54 0.00 85.85 11/17/98 ND 14.08 0.00 85.31 06/19/01 NM NM NM NM 09/12/01 ND 14.46 0.00 84.93 MW-5 12/27/01 99.39 14.51 15.07 0.56 84.73 03/05/02 14.45 14.88 0.43 84.82 05/12/03 NM NM NM NM 12/09/03 13.18 13.60 0.42 86.10 03/23/06 ND 13.67 0.00 85.72 05/08/07 ND 13.45 0.00 85.94 05/14/08 ND 13.51 0.00 85.88 05/28/09 ND 13.39 0.00 86.00 Page 1 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AAFRCJaDIS OfinwdnalandeIIgtE ''1ta ry FE05/27/101 ND 13.70 0.00 NM 10/31/11 ND 13.97 0.00 NM 05/22/12 ND 13.66 0.00 NM 06/14/12 ND 13.73 0.00 NM 07/09/12 ND 14.18 0.00 NM 08/14/12 ND 14.45 0.00 NM 09/19/12 ND 14.35 0.00 NM 12/05/12 ND 14.68 0.00 NM 02/26/13 ND 13.89 0.00 NM 05/31/13 ND 13.77 0.00 NM MW-5R 08/28/13 NS ND 13.83 0.00 NM 11/07/13 ND 14.53 0.00 NM 02/27/14 ND 13.39 0.00 NM 06/02/14 ND 13.47 0.00 NM 10/16/14 ND 14.32 0.00 NM 04/23/15 ND 13.69 0.00 NM 10/13/15 ND 14.19 0.00 NM 04/28/16 ND 13.61 0.00 NM 09/19/16 ND 13.99 0.00 NM 03/03/17 ND 14.01 0.00 NM 09/20/17 ND 13.67 0.00 NM 06/24/93 ND 12.31 0.00 86.37 08/23/94 ND 12.61 0.00 86.07 03/21/95 ND 13.15 0.00 85.53 08/05/96 ND 12.39 0.00 86.29 11/17/98 ND 13.16 0.00 85.52 06/19/01 NM NM NM NM 09/12/01 ND 13.51 0.00 85.17 12/27/01 ND 13.61 0.00 85.07 03/05/02 ND 11.02 0.00 87.66 MW-6 98.68 05/12/03 ND 11.10 0.00 87.58 12/09/03 ND 13.49 0.00 85.19 03/23/06 ND 11.79 0.00 86.89 05/08/07 ND 12.50 0.00 86.18 05/14/08 ND 12.16 0.00 86.52 05/28/09 ND 10.64 0.00 88.04 05/27/10 ND 11.84 0.00 86.84 10/31/11 ND 12.95 0.00 85.73 06/02/14 ND 12.38 0.00 86.30 06/24/93 ND NM 0.00 NM 08/23/94 ND NM 0.00 NM 03/21/95 ND 14.75 0.00 84.51 08/05/96 ND 14.13 0.00 85.13 11/17/98 ND 14.09 0.00 85.17 06/19/01 ND 18.07 0.00 81.19 09/12/01 ND 16.60 0.00 82.66 12/27/01 ND 14.61 0.00 84.65 03/05/02 ND 14.96 0.00 84.30 MW-6i 05/12/03 99.26 ND 15.17 0.00 84.09 12/09/03 ND 13.55 0.00 85.71 03/23/06 ND 13.55 0.00 85.71 05/08/07 ND 12.93 0.00 86.33 05/14/08 ND 13.22 0.00 86.04 05/28/09 ND 13.39 0.00 85.87 05/27/10 ND 13.23 0.00 86.03 10/31/11 ND 13.90 0.00 85.36 06/02/14 ND 13.35 0.00 85.91 04/28/16 ND 13.55 0.00 85.71 Page 2 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AAFRCJaDIS OfinwdnalandeIIgtE ''1ta ry =08/23/94 ND 12.14 0.00 85.70 03/21/95 ND 12.02 0.00 85.82 08/05/96 ND 11.99 0.00 85.85 11/17/98 ND 12.53 0.00 85.31 06/19/01 NM NM NM NM 09/12/01 ND 12.67 0.00 85.17 12/27/01 14.47 15.03 0.56 83.26 MW 8 97.84 03/05/02 12.42 12.60 0.18 85.38 05/12/03 NM NM NM NM 12/09/03 13.32 13.56 0.24 84.47 03/23/06 ND 12.15 0.00 85.69 05/08/07 ND 11.90 0.00 85.94 05/14/08 ND 11.95 0.00 85.89 05/28/09 ND 11.70 0.00 86.14 05/27/10 ND 12.97 0.00 NM 10/31/11 ND 13.34 0.00 NM 05/22/12 ND 13.69 0.00 NM 06/14/12 ND 14.94 0.00 NM 07/09/12 ND 14.08 0.00 NM 08/14/12 ND 14.29 0.00 NM 09/19/12 ND 14.08 0.00 NM 12/05/12 ND 14.53 0.00 NM 02/26/13 ND 13.80 0.00 NM 05/31/13 ND 13.61 0.00 NM MW-8R 08/28/13 NS ND 13.74 0.00 NM 11/07/13 ND 14.42 0.00 NM 02/27/14 ND 13.33 0.00 NM 06/02/14 ND 13.34 0.00 NM 10/16/14 ND 14.18 0.00 NM 04/23/15 ND 13.57 0.00 NM 10/13/15 ND 14.08 0.00 NM 04/28/16 ND 13.53 0.00 NM 09/19/16 ND 13.91 0.00 NM 03/03/17 ND 13.92 0.00 NM 09/20/17 ND 13.61 0.00 NM 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 13.55 0.00 86.89 08/05/96 ND 13.64 0.00 86.80 11/17/98 ND 14.26 0.00 86.18 06/19/01 ND 14.55 0.00 85.89 09/12/01 ND 14.81 0.00 85.63 12/27/01 ND 14.85 0.00 85.59 03/05/02 ND 14.64 0.00 85.80 MW-14 05/12/03 100.44 ND 13.41 0.00 87.03 12/09/03 ND 13.51 0.00 86.93 03/23/06 ND 13.82 0.00 86.62 05/08/07 ND 13.54 0.00 86.90 05/14/08 ND 13.64 0.00 86.80 05/28/09 ND 13.47 0.00 86.97 05/27/10 ND 13.00 0.00 87.44 10/13/11 ND 14.14 0.00 86.30 06/02/14 ND 13.42 0.00 87.02 04/28/16 ND 13.65 0.00 86.79 Page 3 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AAFRCJaDIS OfinwdnalandeIIgtE ''1ta ry FM06/24/931 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.83 0.00 87.08 08/05/96 ND 12.77 0.00 87.14 11/17/98 ND 13.58 0.00 86.33 06/19/01 ND 13.80 0.00 86.11 09/12/01 ND 14.18 0.00 85.73 12/27/01 ND 14.29 0.00 85.62 03/05/02 ND 13.98 0.00 85.93 05/12/03 NM 12.75 NM 87.16 MW-15 99.91 12/09/03 ND 12.89 0.00 87.02 03/23/06 ND 13.14 0.00 86.77 05/08/07 ND 12.90 0.00 87.01 05/14/08 ND 13.12 0.00 86.79 05/28/09 ND 12.90 0.00 87.01 05/27/10 ND 12.25 0.00 87.66 10/31/11 ND 13.61 0.00 86.30 06/02/14 ND 12.82 0.00 87.09 10/16/14 ND 13.91 0.00 86.00 04/28/16 ND 13.15 0.00 86.76 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.06 0.00 85.36 08/05/96 ND 12.09 0.00 85.33 11/17/98 ND 12.60 0.00 84.82 06/19/01 ND 12.74 0.00 84.68 09/12/01 ND 12.98 0.00 84.44 12/27/01 NM NM NM NM 03/05/02 ND 12.83 0.00 84.59 MW-16 05/12/03 97.42 NM NM NM NM 12/09/03 ND 12.13 0.00 85.29 03/23/06 ND 12.18 0.00 85.24 05/08/07 NM NM NM NM 05/14/08 ND 12.03 0.00 85.39 05/28/09 ND 11.96 0.00 85.46 05/27/10 ND 11.69 0.00 85.73 10/31/11 ND 12.45 0.00 84.97 11 /07/ 13 ND 12.88 0.00 84.54 06/02/14 ND 11.97 0.00 85.45 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 14.42 0.00 85.58 08/05/96 ND 14.46 0.00 85.54 11/17/98 ND 14.91 0.00 85.09 06/19/01 ND 15.03 0.00 84.97 09/12/01 ND 15.28 0.00 84.72 12/27/01 ND 15.37 0.00 84.63 03/05/02 ND 15.15 0.00 84.85 MW-17 05/12/03 100.00 NM 14.15 NM 85.85 12/09/03 ND 14.50 0.00 85.50 03/23/06 ND 14.45 0.00 85.55 05/08/07 ND 14.22 0.00 85.78 05/14/08 ND 14.22 0.00 85.78 05/28/09 ND 14.12 0.00 85.88 05/27/10 ND 13.90 0.00 86.10 10/31/11 ND 14.72 0.00 85.28 06/02/14 ND 14.14 0.00 85.86 04/28/16 ND 14.36 0.00 85.64 Page 4 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AAFRCJaDIS OfinwdnalandeIIgtE ''1ta ry 101 1/11 ND 13.95 0.00 NM 05 212112 ND 14.10 0.00 NM 06/14/12 ND 13.61 0.00 NM 07/09/12 ND 14.05 0.00 NM 08/14/12 ND 14.43 0.00 NM 09/19/12 ND 14.34 0.00 NM 12/05/12 ND 14.62 0.00 NM 02/26/13 ND 14.67 0.00 NM 05/31/13 ND 14.57 0.00 NM 08/28/13 ND 14.33 0.00 NM MW-18 NS 11/07/13 ND 14.51 0.00 NM 02/27/14 ND 13.76 0.00 NM 06/02/14 ND 13.55 0.00 NM 10/16/14 ND 14.37 0.00 NM 04/23/15 ND 13.84 0.00 NM 10/13/15 ND 14.81 0.00 NM 04/28/16 ND 13.62 0.00 NM 09/19/16 ND 14.04 0.00 NM 03/03/17 ND 14.08 0.00 NM 09/20/17 ND 13.21 0.00 NM 10/31/11 ND 13.75 0.00 NM 05/22/12 ND 13.37 0.00 NM 06/14/12 ND 13.39 0.00 NM 07/09/12 ND 13.89 0.00 NM 08/14/12 ND 14.13 0.00 NM 09/19/12 ND 14.02 0.00 NM 12/05/12 ND 14.39 0.00 NM 02/26/13 ND 13.62 0.00 NM 05/31/13 ND 13.47 0.00 NM 08/28/13 ND 13.56 0.00 NM MW-19 NS 11/07/13 ND 14.25 0.00 NM 02/27/14 ND 13.17 0.00 NM 06/02/14 ND 13.14 0.00 NM 10/16/14 ND 14.03 0.00 NM 04/23/15 ND 13.46 0.00 NM 10/13/15 ND 14.01 0.00 NM 04/28/16 ND 13.38 0.00 NM 09/19/16 ND 13.75 0.00 NM 03/03/17 ND 13.79 0.00 NM 09/20/17 ND 13.48 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Corr. GW Elev. _ (ref. point elevation) - (depth to groundwater) + (LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 * - Prior to URS' work at this Site, monitoring well MW-3 has previously been reported as MW-2, monitoring well MW-6 has previously been reported as MW-8, and monitoring well MW-8 has previously been reported as MW-6. LNAPL = Light non -aqueous phase liquid ND = Not detected NM = Not measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing - During the May 2003 sampling event LNAPL was observed in MW-5. Depth to groundwater and thickness of LNAPL were not measured. Page 5 of 5 APPENDIX B Laboratory Analytical Report and Chain -of -Custody Record — September 20, 2017 TestAmerica ° THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel: (615)726-0177 TestAmerica Job ID: 490-137200-1 TestAmerica SDG: 381 Knollwood St, Winston-Salem, NC Client Project/Site: BP #24163 - Winston-Salem, NC ror: ARCADIS U.S., Inc. 801 Corporate Center Drive Suite 300 Raleigh, North Carolina 27607-5073 Attn: Paul Goodell q4*jujces�� Authorized for release by. 9/29/2017 10:33:43 PM Heather Wagner, Project Manager 1 (615)301-5763 heather.wagner@testamericainc.com Designee for Jennifer Huckaba, Project Manager 11 (615)301-5042 jennifer.huckaba@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC Table of Contents CoverPage .............................................. 1 Table of Contents ......................................... 2 Sample Summary ......................................... 3 Case Narrative ........................................... 4 Definitions............................................... 5 Client Sample Results ...................................... 6 QC Sample Results ........................................ 10 QC Association ........................................... 11 Chronicle................................................ 12 Method Summary ......................................... 13 Certification Summary ...................................... 14 Chain of Custody .......................................... 15 Receipt Checklists ......................................... 17 TestAmerica Nashville Page 2 of 17 9/29/2017 Sample Summary Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-137200-1 Project/Site: BP #24163 - Winston-Salem, NC SDG: 381 Knollwood St, Winston-Salem, NC Lab Sample ID Client Sample ID Matrix Collected Received 490-137200-1 MW-5R Water 09/20/17 15:15 09/22/17 09:40 490-137200-2 MW-8R Water 09/20/17 15:00 09/22/17 09:40 490-137200-3 MW-18 Water 09/20/17 15:30 09/22/17 09:40 490-137200-4 MW-19 Water 09/20/17 14:45 09/22/17 09:40 TestAmerica Nashville Page 3 of 17 9/29/2017 Case Narrative Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC Job ID: 490-137200-1 Laboratory: TestAmerica Nashville Narrative TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC 0 Job Narrative 490-137200-1 Comments No additional comments. Receipt The samples were received on 9/22/2017 9:40 AM; the samples arrived in good condition, properly preserved and, where required, on ice The temperature of the cooler at receipt was 0.21 C. HPLC/IC No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. TestAmerica Nashville Page 4 of 17 9/29/2017 Definitions/Glossary Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC Glossary Abbreviation a % R CFL CNF DER Dil Fac DL DL, RA, RE, IN DLC EDL LOD LOQ MDA MDC MDL ML NC ND PQL QC RER RL RPD TEF TEQ TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis Percent Recovery Contains Free Liquid Contains No Free Liquid Duplicate Error Ratio (normalized absolute difference) Dilution Factor Detection Limit (DoD/DOE) Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample Decision Level Concentration (Radiochemistry) Estimated Detection Limit (Dioxin) Limit of Detection (DoD/DOE) Limit of Quantitation (DoD/DOE) Minimum Detectable Activity (Radiochemistry) Minimum Detectable Concentration (Radiochemistry) Method Detection Limit Minimum Level (Dioxin) Not Calculated Not Detected at the reporting limit (or MDL or EDL if shown) Practical Quantitation Limit Quality Control Relative Error Ratio (Radiochemistry) Reporting Limit or Requested Limit (Radiochemistry) Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin) Toxicity Equivalent Quotient (Dioxin) TestAmerica Nashville Page 5 of 17 9/29/2017 Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC Client Sample ID: MW-5R Date Collected: 09/20/17 15:15 Date Received: 09/22/17 09:40 Client Sample Results C TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier RL Sulfate 1060 100 Lab Sample ID: 490-137200-1 Matrix: Water MDL Unit D Prepared mg/L Analyzed Dil Fac 09/29/17 03:18 100 TestAmerica Nashville Page 6 of 17 9/29/2017 Client Sample Results C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-137200-1 Project/Site: BP #24163 - Winston-Salem, NC SDG: 381 Knollwood St, Winston-Salem, NC Client Sample ID: MW-8R Lab Sample ID: 490-137200-2 Date Collected: 09/20/17 15:00 Matrix: Water Date Received: 09/22/17 09:40 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier RL Sulfate 797 50.0 MDL Unit D Prepared Analyzed Dil Fac mg/L 09/29/17 03:36 50 TestAmerica Nashville Page 7 of 17 9/29/2017 Client Sample Results C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-137200-1 Project/Site: BP #24163 - Winston-Salem, NC SDG: 381 Knollwood St, Winston-Salem, NC Client Sample ID: MW-18 Lab Sample ID: 490-137200-3 Date Collected: 09/20/17 15:30 Matrix: Water Date Received: 09/22/17 09:40 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 257 RL MDL Unit D Prepared Analyzed Dil Fac 25.0 mg/L 09/29/17 04:13 25 TestAmerica Nashville Page 8 of 17 9/29/2017 Client Sample Results C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-137200-1 Project/Site: BP #24163 - Winston-Salem, NC SDG: 381 Knollwood St, Winston-Salem, NC Client Sample ID: MW-19 Lab Sample ID: 490-137200-4 Date Collected: 09/20/17 14:45 Matrix: Water Date Received: 09/22/17 09:40 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 1020 RL MDL Unit D Prepared Analyzed Dil Fac 100 mg/L 09/29/17 04:31 100 TestAmerica Nashville Page 9 of 17 9/29/2017 QC Sample Results Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Lab Sample ID: MB 490-464215/3 Matrix: Water Analysis Batch: 464215 MB MB Analyte Result Qualifier RL Sulfate ND 1.00 Lab Sample ID: LCS 490-464215/4 Matrix: Water Analysis Batch: 464215 TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac mg/L 09/29/17 02:24 1 Client Sample ID: Lab Control Sample 0 Prep Type: Total/NA F Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 10.0 10.41 mg/L 104 — 80 -120 Lab Sample ID: LCSD 490-464215/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 464215 Spike LCSD LCSD %Rec. RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 10.50 mg/L 105 80-120 1 20 TestAmerica Nashville Page 10 of 17 9/29/2017 QC Association Summary Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC HPLC/IC Analysis Batch: 464215 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 490-137200-1 MW-5R Total/NA Water 9056A 490-137200-2 MW-8R Total/NA Water 9056A 490-137200-3 MW-18 Total/NA Water 9056A 490-137200-4 MW-19 Total/NA Water 9056A MB 490-464215/3 Method Blank Total/NA Water 9056A LCS 490-464215/4 Lab Control Sample Total/NA Water 9056A LCSD 490-464215/5 Lab Control Sample Dup Total/NA Water 9056A TestAmerica Nashville Page 11 of 17 9/29/2017 Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC Client Sample ID: MW-5R Date Collected: 09/20/17 15:15 Date Received: 09/22/17 09:40 Batch Batch Prep Type Type Method Run Total/NA Analysis 9056A Client Sample ID: MW-8R Date Collected: 09/20/17 15:00 Date Received: 09/22/17 09:40 Batch Batch Prep Type Type Method Run Total/NA Analysis 9056A Client Sample ID: MW-18 Date Collected: 09/20/17 15:30 Date Received: 09/22/17 09:40 Lab Chronicle C TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC Lab Sample ID: 490-137200-1 Matrix: Water Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 100 464215 09/29/17 03:18 JHS TAL NSH Lab Sample ID: 490-137200-2 Matrix: Water Dil Initial Final L Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 50 464215 09/29/17 03:36 JHS TAL NSH Lab Sample ID: 490-137200-3 Matrix: Water Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056A 25 464215 09/29/17 04:13 JHS TAL NSH Client Sample ID: MW-19 Date Collected: 09/20/17 14:45 Date Received: 09/22/17 09:40 Lab Sample ID: 490-137200-4 Matrix: Water Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056A 100 464215 09/29/17 04:31 JHS TAL NSH Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 Page 12 of 17 TestAmerica Nashville 9/29/2017 Method Summary Client: ARCADIS U.S., Inc. Project/Site: BP #24163 - Winston-Salem, NC TestAmerica Job ID: 490-137200-1 SDG: 381 Knollwood St, Winston-Salem, NC Method Method Description Protocol Laboratory 9056A Anions, Ion Chromatography SW846 TAL NSH Protocol References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 TestAmerica Nashville Page 13 of 17 9/29/2017 Accreditation/Certification Summary C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-137200-1 Project/Site: BP #24163 - Winston-Salem, NC SDG: 381 Knollwood St, Winston-Salem, NC Laboratory: TestAmerica Nashville Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below. Authority Program EPA Region Identification Number Expiration Date North Carolina (WW/SW) State Program 4 387 12-31-17 The following analytes are included in this report, but are not accredited/certified under this accreditation/certification: Analysis Method Prep Method Matrix Analyte 9056A Water Sulfate TestAmerica Nashville Page 14 of 17 9/29/2017 Test medca THE LEADER IN ENVIRONMENTAL TESTING �������1�(�ii iif111lull IIIII Nashville, TN COOLER RECEIPT FORM 490-137200 Chain of Custody Cooler Received/Opened On_9/22/17 0940 Time Samples Removed From Cooler Time Samples Placed In Storage I (2 Hour Window) Z3 1. Tracking # I(last 4 digits, FedEx) Courier: _FedEx_ IR Gun ID_17960353 pH Strip Lot Chlorine Strip Lot 2. Temperature of rep, sample or temp blank when opened: Degrees Celsius i 3. If Item #2 temperature is 0°C or less, was the representative sample or temp blank frozen? YES NO... 1� JJJIi 4. Were custody seals on outside of cooler? E ...NO...NA If yes, how many and where: 5. Were the seals intact, signed, and dated correctly? ES..NO... NA i 6. Were custody papers inside cooler?...NO...NA I certifV that I opened the cooler and answered questions 1-6/6''(intial) 7. Were custody seals on containers: YES QO/ and Intact YES ... NO.0 Were these signed and dated correctly? YES ... NO.S�l i 8. Packing mat'I used? Bubblewrap Plastic b Peanuts Vermiculite Foam Insert Paper Other None 1 9. Cooling process: Ic Ice -pack Ice (direct contact) Dry ice Other None 10, Did all containers arrive in good condition (unbroken)? 3E ..NO ... NA 11. Were all container labels complete (#, date, signed, pres., etc)? YE ... NO ... NA 12. Did all container labels and tags dgree with custody papers? ... NO ... NA 13a. Were VOA vials received? YES.<N ..NA b. Was there any observable headspace present in any VOA vial? YES ...NO., ® On Larger than this. 14. Was there a Trip Blank in this cooler? YES. .9..NA If muitipil co r� sequence #_ IA 1 certify that I unloaded the cooler and answered questions 7-14 (intial) //� 15a. On pres'd bottles, did pH test strips suggest preservation reached th c rre level? ... NO ... NA b. Did the bottle labels indicate that the correct preservatives were used V...NO... NA 16. Was residual chlorine present? YES..A... NA I certify that i checked for chlorine and pH as per SOP and answered questions 15.16 (intial} 17. Were custody papers properly filled out (ink, signed, etc)? dft... NO...NA 18. Did you sign the custody papers in the appropriate place? ...NO ... NA 19. Were correct containers used for the analysis requested? NO ... NA 20. Was sufficient amount of sample sent in each container?/ ft-NO...NA I certify that I entered this project into LIMS and answered questions 17-20 (intial) AN 21. Were there Non -Conformance issues at login? YES.. NO Was a NCM generated? YES..4... # BIS = Broken in shipment Cooler Receipt Fonn.doc LF-1 Revised 8/23/17 End of Fonn Page 15 of 17 9/29/2017 N N O TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Phone (615) 726-0177 Fax (615) 726-3404 Chain of Custody Record TestAmedca THE LEADER IN ENVIRONMENTAL TESTENG Client Information Sampler, �vJ • rr;( Lab PM: Huckaba, Jennifer [ennifer.huckaba@testamericainc.com Carrier Tracking No(s): COC No: 490-71997-22130.1 Client Contact: l: Paul Goodell Phone `7 + . -aa . Q3 d j E-mail: Page Page)of Company: ARCADIS U.S., Inc. Analysis Requested Job* Address: 801 Corporate Center Drive Suite 300 Due Date Requested: -.. 1 o ? $ m }• m E I = 'yya — lZ .. a , — rn J Hi o e Loc: 490 13720a m 5 0 E 0 z. R F° . Preservation Codes: A - HCL M -Hexane 6 - NaOH N - None C - Zn Acetate O - AsNa02 D - Nitric Acid P - Na2O4S E - NaHSO4 0 - Na2SO3 F - McOH R - Na2S203 G-Amcrnor S -Hzsoa H -Ascorbic Acid T -TSP Dodecahydrate I - Ice U - Acetone K- EDTAter W pH 4 5 L -EDA Z- other(specify) Other: City: Raleigh TAT Requested (days): /pr d(1/ / V f� a J State, Zip: NC, 27607-5073 Phone: 919-415-2299(Tel) PO #: Purchase Order not required Email: paul.goodell@arcadis-us.com WO #: Project Name: BP #24163 - Winston-Salem, NC Project#: 49011104 Site: 381 Knollwood St, Winston-Salem, NC SSOW#. Sample Identification Sample Date Sample Time Sample Type Yp (C=comp, G=grab) Matrix (#=Meter. s=.atd, o=wesrercn, aT=resee,A=A,r S ecial Instructions/Note: Presefvatinn Codei"' •^ ;. F 167 It Possible Hazard Identification I� ��'' Non -Hazard =Flammable kin Irritant `Poison B �nknown radiological Sample Disposal (A fee maybe sensed if samples are retained longer than 1 month) Return To Client maybe By Lab =rchive For Months Deliverable Requested: I, II, 111, IV, Other (specify) Special Instructions/QC Requirements: Empty Kit Relinquished by: Date: Time: Method of Shipment: Relinquishedb L rD+aate/Time: J V4, l �- /�DS Comp 'S Repeiivo Q � t ` � 1 Z y 3 I Date Time: /� O9,a) (� ��VS� Co�m-p-an _ ! f J L� Relinquished by, Daterrime: Company Received by: Datenime. Company Relinquished by, DateRme: Company Rec etl ny: Datemme: Com� j Custody Seals Intact: A Yes A No Custody Seal No.: Cooler Temperature(411pjAd Other marks: F-1 Login Sample Receipt Checklist Client: ARCADIS U.S., Inc. Login Number: 137200 List Number: 1 Creator: Abernathy, Eric Question Job Number: 490-137200-1 SDG Number: 381 Knollwood St, Winston-Salem, NC List Source: TestAmerica Nashville Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A TestAmerica Nashville Page 17 of 17 9/29/2017 APPENDIX C Historical Groundwater Analytical Data Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AARCADI {ar atu a{andd any krn tumi NC GCL: NC 2L Units: 5,000 1 Ng/I 84,500 600 Ng/I 260,000 600 Ng/I 85,500 500 Ng/I 20,000 20 Ng/I NE 250 mg/I NE NE mg/I 5/13/2003 8.5 0.98 J 0.61 J 1.7 J 8 12/9/2003 47.4 14.3 1.9 8.1 37.3 3/23/2006 4.5 J < 0.5 < 0.5 UJ < 1 UJ 5.5 5/8/2007 40.4 3.7 2 J 13.1 5/14/2008 4.3 J < 0.8 _1.4 < 0.7 < 0.8 14 5/28/2009 5.4 0.44 J 0_ 14 J 0.49 J 5.6 5/27/2010 0.44 J < 0.11 0.3 J < 0.32 4.8 10/31/2011 5.5 0.76 < 0.17 U 0.38 J 19.1 8.4 405 5/22/2012 < 0.43 U < 0.2 < 0.2 < 0.52 4.6 15.3 378 6/14/2012 12.1 6.7 0.72 4.7 15.4 6.6 J 344 7/9/2012 2.2 1.6 2.6 3 14.7 9.9 393 MW-3 8/14/2012 2 2.1 < 0.13 0.4 J 17.9 3.6 303 9/19/2012 2.7 0.66 < 0.13 0.33 J 19.8 2.8 459 12/5/2012 11.3 1.2 0.43 J 1.11 19.3 0.78 J 377 2/26/2013 0.23 J < 0.1 < 0.1 < 0.22 5.4 32.6 338 5/31 /2013 0.32 J < 0.1 < 0.1 < 0.22 10.5 17.9 334 8/28/2013 3.6 0.53 0.12 J 0.31 J 10.3 21.9 457 11/7/2013 4.3 0.27 J 0.13 J < 0.22 10 21.7 536 2/27/2014 < 0.1 < 0.1 < 0.1 < 0.2 1.3 42.2 198 6/3/2014 0.48 J 0.15 J < 0.1 < 0.2 3.1 10/16/2014 18.0 372 4/23/2015 22.8 296 9/19/2016 21.3 3/23/2006 11,700 2,440 32,000 13,500 16,100 3/23/2006 (1) 11,000 2,370 30,700 13,200 15,400 5/8/2007 7,410 1,590 21,100 8,920 8,830 5/8/2007 (1) 7,400 1,680 20,100 9,290 9,360 MW-5 5/14/2008 10,000 2,100 29,000 12,000 18,000 5/14/2008 (1) 10,000 2,100 30,000 12,000 18,000 5/28/2009 7,390 2,330 25,700 13,400 6,920 5/28/2009 (1) 6,510 2,240 22,100 12,900 6,510 5/27/2010 6,610 2,810 24,300 J 15,700 4,330 5/27/2010 (1) 6,090 2,380 30,100 J 13,300 4,250 10/31/2011 7,960 2,660 28,000 13,800 3,830 < 1 < 5 10/31/2011 (1) 8,360 2,870 24,600 14,800 4,070 5/22/2012 7,980 3,470 32,200 19,200 3,820 < 5 179 6/15/2012 (2) 244 227 1,190 1,120 36.9 6,070 1,820 7/9/2012 336 J 481 J 2,010 J 2,400 J 48.4 J 6,470 2,620 MW-5R 8/14/2012 201 283 1,050 1,300 48.5 14,700 4,190 9/19/2012 _ 158 181 650 883 114 19,000 3,280 12/5/2012 754 505 2,220 2,380 1,160 13,600 1,840 2/26/2013 1,360 878 3,520 3,940 1,660 8,520 1,530 5/31/2013 1,410 1,380 5,930 6,220 1,150 J 4,680 1,560 8/28/2013 165 178 489 1,380 417 13,900 1,590 11/7/2013 214 131 331 969 651 14,400 1,570 Page 1 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AARCADI {ar atu a{andd any krn tumi NC GCL: NC 2L Units: 5,000 1 Ng/I 84,500 600 Ng/I 260,000 600 Ng/I 85,500 500 Ng/I 20,000 20 Ng/I NE 250 mg/I NE NE mg/I 6/2/2014 256 436 1040 2520 519 J 10/16/2014 9,950 1,390 4/23/2015 5,980 1,510 10/13/2015 5,790 MW-5R 4/28/2016 2,980 9/19/2016 2,880 3/3/2017 3,570 9/20/2017 1,060 5/12/2003 < 0.5 0.52 J < 0.5 < 1 3 12/9/2003 2.3 0.64 J 1.1 3.6 17.6 12/9/2003 2.4 0.68 J 1.1 3.8 18 3/23/2006 0.76 J 0.59 J 3.6 2.8 J 1.1 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 MW-6 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 5/28/2009 < 0.06 < 0.05 < 0.06 < 0.14 0.17 J 5/27/2010 < 0.11 0.13 J 0.38 J 0.46 J < 0.12 10/31/2011 8.7 J 11.7 J 27.5 J 132 J < 0.26 UJ 131 2,130 6/2/2014 17.6 J 59.4 J 31.6 J 99.4 J 783 J 5/12/2003 < 0.5 < 0.5 < 0.5 1.11 < 75 12/9/2003 < 2.5 < 2.5 < 2.5 < 5 < 2.5 3/23/2006 49.7 18.9 48.7 443 3,560 5/8/2007 < 25 < 25 < 25 < 50 6,910 MW-61 5/14/2008 5.2 J < 2 < 1.8 < 2 3,400 5/28/2009 2.5 < 0.05 < 0.06 < 0.14 1,150 5/27/2010 1.6 J < 1.1 < 1.1 < 3.2 492 10/31/2011 0.41 J < 0.36 < 0.32 < 0.75 122 < 1 76.1 6/2/2014 < 0.1 < 0.1 < 0.1 < 0.2 3.3 3/23/2006 671 1,340 1,230 8,100 124 5/8/2007 1,160 799 196 2,990 1,440 MW 8 5/14/2008 600 1,800 700 3,000 190 5/28/2009 1,390 2,050 1 3,310 1,560 5/27/2010 8,570 2,870 _357 31,700 15,700 6,260 10/31/2011 8,000 3,180 32,100 17,200 3,170 < 1 < 5 5/22/2012 8,270 3,360 36,400 J 17,800 3,920 < 5 119 6/15/2012 (2) 726 47 J 760 242 J 96.3 J 4,760 22,200 7/9/2012 4,540 J 1,870 J�17,100 J 10,800 J 1,530 J 6,570 4,500 8/14/2012 4,370 1,610 19,300 8,780 2,600 7,010 1,560 9/19/2012 4,780 1,800 20,900 10,400 2,&0 6,700 1,100 12/5/2012 7,760 2,440 31,900 13,800 4,560 2,410 635 2/26/2013 7,310 2,480 30,500 13,400 4,530 959 590 5/31/2013 6,540 3,040 30,500 12,500 4,200 439 437 8/28/2013 1,600 628 5,390 1,380 4,770 703 MW-8R 11/7/2013 1,130 329 2,440 _3,990 1,830 1,770 7,460 766 2/27/2014 1,020 603 3,200 3,430 1,190 7,670 940 6/2/2014 1,360 J 680 J 3,510 J 3,330 J 2,110 J 6/2/2014 (1) 1,540 556 J 3,650 2,630 J 2,640 J 10/16/2014 3,310 883 9,070 4,990 3,910 3,560 842 4/23/2015 2,050 812 10/13/2015 _ _-- _-- 1,600 4/29/2016 1,640 9/19/2016 1,330 3/3/2017 1,720 9/20/2017 797 5/12/2003 < 0.5 < 0.5 < 0.5 < 1 0.52 J 12/9/2003 < 0.5 < 0.5 < 0.5 < 1 5.9 3/23/2006 < 0.5 < 0.5 < 0.5 < 1 < 0.5 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 MW-14 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 5/28/2009 < 0.06 < 6.05 0.077 J < 0.14 < 0.06 5/27/2010 < 0.11 < 0.11 < 0.11 < 0.32 < 0.12 10/31/2011 <0.13 <0.15 <0.42U <0.3 <0.13 43.2 <5 6/3/2014 <0.1 <0.1 <0.1 <0.2 <0.1 Page 2 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina MW-15 MW-16 MW-17 MW-18 NC GCL: 5,000 NC 2L 1 Units: ua/I 5/8/2007 5/14/2008 5/27/2010 10/31/2011 6/3/2014 10/16/2014 3/23/2006 5/14/2008 5/27/2010 10/31/2011 11/7/2013 6/3/2014 5/13/2003 5/13/2003 12/9/2003 3/23/2006 5/8/2007 5/14/2008 5/28/2009 5/27/2010 10/31/2011 6/3/2014 10/31/2011 5/22/2012 6/15/2012 (2) 7/9/2012 8/14/2012 9/19/2012 12/5/2012 2/26/2013 5/31 /2013 8/28/2013 11/7/2013 2/27/2014 6/2/2014 10116I2014 4/23/2015 10/13/2015 4/29/_2016 19/ 9/2016 3/3/2017 < 0.5 < 0.5 < 0.11 < 0.13 < 0.1 <0.1 < 2.5 < 0.5 3.6 < 0.65 < 0.1 57.7 40.8 6.6 1 < 0.5 3.7 J 7 5.7 0.51 < 0.1 3,140 2,280 373 1,730 J 3,020 3,190 3,370 2,510 2,780 182 1,140 16.6 26.2 J 359 AARCADI {ar atu a{anddlanav krn tumi 84,500 260,000 85,500 20,000 NE NE 600 600 500 20 250 NE 2.1 < 0.5 18.6 < 0.5 < 0.5 2.2 J < 0.8 < 0.7 3.7 J <0.11 <0.11 <0.32 < 0.15 < 0.13 < 0.3 < 0.1 < 0.1 < 0.2 <0.1 <0.1 <0.2 90.8 15.8 836 160 15 1,600 54.7 J 5.1 525 J 17.2 < 1.4 U 321 25 0.92 417 J < 0.5 < 0.5 < 1 < 0.5 < 0.5 < 1 0.65 J < 0.5 < 1 < 0.5 < 0.5 < 1 < 0.5 < 0.5 < 1 < 0.8 < 0.7 < 0.8 < 0.05 0.076 J < 0.14 <0.11 <0.11 <0.32 0.16J <0.81 U 0.57J < 0.1 < 0.1 < 0.2 998 11,100 8,950 2,790 18,200 12,000 910 4,800 3,910 2,170 J 15,000 J 9,750 J 2,990 24,400 12,860 3,090 22,600 14,000 2,970 20,100 12,800 2,970 10,100 8,690 3,070 8,210 5,740 368 730 1,660 727 4,910 3,250 109 20.2 45.8 125J 37.5J 31.6J 388 244 138 < 0.5 < 0.5 < 0.12 <0.13 <1 <5 <0.1 2.8 J 4.1 J 1.3 < 0.65 194 < 5 55.4 < 5 < 0.1 69 63.3 80.6 58.9 17.4 19 14.5 12.4 8.9 < 1 422 4.1 1,140 8.2 446 789 < 5 307 114 10,600 3,410 676 J 2,300 835 1,090 758 580 1,240 322 542 1,380 32 436 1,140 13.8 500 1,000 83.3 475 139 7,850 2,230 694 2,640 1,370 18.5 37.4 J 4,310 1,270 364 1,540 513 780 1,100 516 79.4 377 295 257 Page 3 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina AARCADI {ar atu a{andd any krn tumi NC GCL: NC 2L Units: 5,000 1 Ng/I 84,500 600 pg/I 260,000 600 ug/I 85,500 500 pg/I 20,000 20 Ng/I NE 250 mg/I NE NE mg/I 10/31/2011 2,390 1,380 8,790 7,040 5,160 3.7 425 5/22/2012 2,700 1,560 14,200 7,940 4,880 < 5 310 6/15/2012 (2) 4,020 1,440 18,200 7,940 3,290 1,090 6,520 7/9/2012 5,130 2,910 30,400 J 16,300 5,330 232 991 8/14/2012 2,420 1,650 14,200 8,370 4,090 469 1,080 9/19/2012 2,090 1,630 12,900 8,640 3,960 260 690 12/5/2012 2,320 1,810 15,200 10,400 4,010 58.8 588 2/26/2013 2,210 1,110 10,600 6,990 3,890 169 503 5/31/2013 1,830 894 8,820 5,250 3,120 1,530 606 MW 19 8/28/2013 2,710 J 1,190 J 13,100 7,420 J 3,240 J 2,660 525 11/7/2013 2,020 984 9,850 5,620 2,260 2,890 255 2/27/2014 2,550 1,400 10,900 7,880 3,320 2,790 322 6/2/2014 2,370 1,260 11,900 7,260 2,830 10/16/2014 - 2,340 632 4/23/2015 - 2,540 514 10/13/2015 - 1,960 4/28/2016 1,780 9/19/2016 _- 1,270 3/3/2017 941 9/20/2017 1.020 Notes: (1) Field duplicate (2)Alkalinity, sulfate, and carbon dioxide samples were collected 6/14/2012 and volatile organic analysis samples were collected 6/15/12. -" - Not sampled or analyzed < - Not detected at the specified detection limit pg/I - Micrograms per Liter GCL - Gross Contamination Level 2L - North Carolina Groundwater Quality (2L) Standard J - Estimated value mg/I - Milligrams per Liter MTBE - Methyl tert-Butyl Ether NE - Not established U - Not present above the associated level; blank contamination exists UJ - Not detected and the detection limit is estimated BOLD text indicates 2L exceedance Bold cell with green highlight indicates GCL exceedence Activated sodium persulfate injections were performed at the site from June 4, 2012, to June 9, 2012, and from June 3, 2013, to June 6, 2013. Page 4 of 4 04ARCADIS5deign&Consultancy for naturaland built assets Arcadis U.S., Inc. 111-D Sanders Lane Bluefield, Virginia 24605 Tel 276 322 3879 Fax 276 322 3946 www.arcadis.com