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HomeMy WebLinkAboutWI0400198_Monitoring (Report)_20170505DOCUMENT TRACKING FORM REPORT NAME: Jr&zol `] h4 TODAY'S DATE: _ 5 -° S -. /-.7 SAMPLED DATE: 3. 3. /'J DATE ANALY REC: 1�T DRAFT DUE DATE: -DRIVE LOCATION: n62 �2 V1/,3 SITE NUMBER: PROJ. NUMBER:/(� TASK NUMBER: PROJ MANAGER: FINAL DUE DATE: wjA-, 1-,41STRAT SHARED FLOADDATE: Report Production: Personnel Assigned Assigned Date Budget Ist Draft Comp 2nd Draft Comp Author(s): / CS Tables: Figures: Tech Edit: Admin:- Modeler: Engineering: PM Review: PEIPG Review: Document Date and Time Submitted: 5-. s . /09 DUE DATE "OUT THE DOOR": 5 S / % B- Staple C- Three Ring D- Spiral Bound E- CD Other: Copies Color or BW Deliver To: Delivery Carrier by Date Sent Tracking Number Original �� i:2cc1 NG� `1A -W1S1C�3—. Copy 1 r Copy 2 Copy 3 Copy 4 Special Instructions: Final Submittal Review: Name ork Date: Must have manager signature prior to any documents being sent out. ARCADIS Design sr Consultancy fornaturaland built assets Mr. Michael Rogers UIC Program Manager NCDEQ — DWR 1636 Mail Service Center Raleigh, North Carolina 27699 Subject: 1st Semi -Annual Groundwater Monitoring Report — 2017 Former BP Facility #24163 381 Knollwood Street Winston-Salem, North Carolina 27103 Incident Number: 6400 (Closed) Risk Classification: Low (No Further Action) Dear Mr. Rogers: On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina is submitting the attached 1st Semi -Annual Groundwater Monitoring Report — 2017 dated May 3, 2017 for the above referenced site. An electronic copy of this report including the associated laboratory analytical report is included with the attached CD. Please contact me at (919) 415-2327 with any questions or concerns related to the Report or this incident number. Sincerely, Arcadis G&M of North Carolina, Inc. r Paul Goodell, E.I. AFS Project Manager 5 Copies: File — BP #24163 Arcadis U.S., Inc. 111-D Sanders Lane Tel 919 854 1282 Fax 919 854 5448 www.arcadis.com A019Ide7►1tIIA011 Date: May 5, 2017 Contact: Paul Goodell Phone: 919.415.2327 Email: Paul.Goodell@Arcadis.com Our ref: GP16BPNA.NC10 Page: 1/1 /aRCADIS design&Consultancy fornaturaland built assets Atlantic Richfield Company c/o BP Products North America, Inc. 1ST SEMI-ANNUAL MONITORING REPORT - 2017 'A Former BP Facility #24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina NCDEQ Incident #6400 (Closed) Injection Permit #W10400198 May 2017 1st Semi -Annual Monitoring Report - 2017 Alexandra M. Simpson AFS Task Manager 3 r Paul Goodell, E.I. AFS Project Manager 5 C. Scott Bostian, P.E.. 7 s North Carolina P.E. No. 256B9 Senior Engineer, a , JST SEMI-ANNUAL MONITORING REPORT REPORT - 2017 Prepared for: Atlantic Richfield Company c/o BP Products North America, Inc. Mr. Greg Frisch — Project Manager 4850 F. 491" Street MBC-3 Room 155C Cuyahoga Heights, Ohio 44125 Tel 216.416.1232 Prepared by: Arcadis G&M of North Carolina, Inc. 801 Corporate Center Drive Suite 300 Raleigh, North Carolina 27607 Tel 919.854.1282 Fax 919.854.5448 www.arcadis-us.com Environmental Our Ref.: GPI6BPNA.NC10 Date: May 3, 2017 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged, confidential and exempt from disclosure under applicable law. Any dissemination, distribution or copying of this document is strictly prohibited. arcades corn 15t Semi -Annual Monitoring Report - 2017 V` Semi -Annual Monitoring Report - 2017 Former BP Facility #24163 381 Knollwood St Winston-Salem, Forsyth County, North Carolina Latitude 361, 5' 25.94"N Longitude 800 17' 11.79"W (Reference Figure 1) Groundwater Incident #: 6400 (Closed) Risk Classification: Reason for Risk Classification: Land Use Category: Source of Release: Date of Release Discovery: Estimated Quantity of Release: Cause of Release: Responsible Party: Property Owner: Low (No Further Action) Dissolved -phase Sulfate concentrations above groundwater quality standards (2L) Industrial/Commercial Former gasoline UST system(s) 1983 Unknown Former UST System Atlantic Richfield Company c/o BP Products North America, Inc. Attn: Greg Frisch 4850 East 49«' Street MBC-3 Room 155C Cuyahoga Heights, Ohio 44125 (216) 416-1232 Mr. Charles Sherren Thruway Shopping Center, LLC, 7501 Wisconsin Ave., Suite 1500 Bethesda, Maryland, 20814 (301) 986-2925 ext. 215 'v '.. a Professional Engineer for ARCAD[S G&M of North Carolina, Inc., do certift that the information contained in this report is correct and accurate to the best of my knowledgg: ARCAOIS G&M of North Carolina, Inc. is licensed to practice geology and engineering in North rq#xla� TA p6i tifioation numbers of the company are C-155 (geology) and C-1869 (engineering). a�a 1st Semi -Annual Monitoring Report - 2017 CONTENTS 1.0 Site History and Characterization .... 2.0 Groundwater Monitoring ................... 2.1 Groundwater Gauging ................ 2.2 Groundwater Sampling .............. 2.3 Groundwater Analytical Results. 3.0 Site Remediation .............................. 3.1 Remediation Activities to Date... 4.0 Conclusions and Recommendations TABLES Table 1. Well Construction Details Table 2. Current Groundwater Elevation Data Table 3. Current Groundwater Analytical Data FIGURES Figure 1. Site Location Map Figure 2. Site Map Figure 3. Potentiometric Surface Map - March 3, 2017 Figure 4. Groundwater Analytical Data Map Figure 5. Sulfate Isoconcentration Map - March 3, 2017 APPENDICES A- Historical Groundwater Elevation Data B- Laboratory Analytical Report and Chain -of -Custody Record — March 20, 2017 C- Historical Groundwater Analytical Data 2 4 4 4 4 5 6 7 arcadis.com 15t Semi -Annual Monitoring Report - 2017 EXECUTIVE SUMMARY On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina, Inc. (Arcadis) personnel performed the semi- annual groundwater sampling of groundwater monitoring wells associated with Former BP Facility #24163 located at 381 Knollwood Street, in Winston-Salem, Forsyth County, North Carolina (the Site) on March 3, 2017. All groundwater monitoring activities were conducted in response to the final project evaluation requirement specified in Part VII, Item 5 of the Renewal Issuance of Injection Permit W10400198 from the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Quality — Aquifer Protection Section in April 2013. On March 3, 2017, Arcadis completed a semi-annual groundwater monitoring and sampling event at the Site. Four (4) groundwater monitoring wells (MW-5R, MW-8R, MW-18, and MW-19) were gauged to determine the depth to water (DTW). DTW ranged from 13.79 feet below top of casing (btoc) in groundwater monitoring well MW-19 to 14.08 feet btoc in groundwater monitoring well MW-18. The historical groundwater flow direction for the Site is towards the southeast. On March 3, 2017, groundwater samples were collected from groundwater monitoring wells MW- 5R, MW-8R, MW-18, and MW-19. The maximum concentrations of selected dissolved -phase COCs found during the March 3, 2017 sampling events are summarized in the table below: Maximum Groundwater Concentrations (March 3, 2017) Chemical of Monitoring Well Concentration North Carolina Concern ID (mg/L) Groundwater (COC) Quality (2L) Standards Sulfate MW-5R 3,570 250 Note: Concentration in Bold exceeds the applicable North Carolina GCL Standard mg/L: milligrams per liter Dissolved phase sulfate concentrations decreased compared to historical groundwater analytical data. Dissolved phase sulfate was detected above the applicable North Carolina Groundwater Quality (2L) Standard at groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for August 2017. Groundwater monitoring wells MW- 5R, MW-8R, MW-18, and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-5R, MW-8R, MW-18, and MW-19 for analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2017 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com ES-1 15t Semi -Annual Monitoring Report - 2017 1.0 SITE HISTORY AND CHARACTERIZATION Former BP Facility #24163 is located at 381 Knollwood Street, Winston-Salem, Forsyth County, North Carolina (the Site). The Site is currently owned by Thruway Shopping Center, LLC. and serves as a parking lot adjacent to surrounding retail stores. The site property is approximately 0.5 acres, covered by asphalt and concrete, and was formerly developed as a retail fueling station which housed gasoline, diesel, waste oil, and kerosene Underground Storage Tanks (USTs). A site location map is presented as Figure 1 and a site map is shown as Figure 2. The North Carolina Department of Environmental Quality (NCDEQ) issued groundwater incident number 6400 due to a subsurface release of gasoline that occurred on or before September 14, 1983 from a ruptured product line associated with the UST system. The quantity of the release remains unknown. One (1) 10,000-gallon steel gasoline UST, three (3) 6,000-gallon steel gasoline USTs, and one (1) 10,000-gallon steel diesel UST were removed from the site in 1990. Three (3) 10,000-gallon gasoline USTs, one (1) 10,000-gallon diesel UST, and one (1) 550-gallon waste oil UST were subsequently installed at the site and the site was purchased by M. M. Fowler, Inc. in January 1994 and continued operation until 2004. The remaining five USTs were removed before 2005 and the site was razed. Site geology and hydrogeology include surficial deposits immediately underlying the site are described generally as sandy silts that grade upward to clayey silts and silty clays. Bedrock beneath the site is mapped as a strongly foliated biotite gneiss and schist. The maximum depth of investigation at the site has been approximately 55 feet below ground surface (bgs); bedrock has not been encountered during site investigation work. Historically, the range for shallow groundwater beneath the site is approximately 11 to 14 feet bgs, and groundwater flow direction is toward the southeast with an apparent horizontal gradient of approximately 0.012 feet per foot (ft/ft). The calculated groundwater seepage velocity for shallow groundwater beneath the site is approximately 2.8 feet per year. Two activated sodium persulfate injections were performed at the Site on June 4 — 9, 2012 and June 3 — 6, 2013 under Underground Injection Control (UIC) Permit #W10400198 which was issued by the NCDEQ Division of Water Quality on August 9, 2011. Approximately 11,237-gallons of sodium persulfate and 6,826-gallons of sodium persulfate were injected at the Site on June 4 — 9, 2012 and June 3 — 6, 2013, respectively. The NCDEQ Risk Classification for this site was reduced to "Low" on January 23, 2015 after issuing a request for Notice of Residual Petroleum (NORP). The NORP was recorded with the Forsyth County Register of Deeds on March 18, 2015 and imposed the following perpetual restriction on the Site property: • Groundwater: Groundwater from the site is prohibited from use as a water supply. Water supply wells of any kind shall not be installed or operated on the site. No Further Action (NFA) status was granted for the subject incident number by the NCDEQ on April 28, 2015. In accordance with UIC Permit #W10400198, dissolved -phase concentrations of sulfate are being monitored on a semi-annual basis at the Site. Closure of UIC Permit #W10400198 will be requested once arcadis.com 2 15t Semi -Annual Monitoring Report - 2017 dissolved -phase sulfate concentrations are no longer detected above the North Carolina Groundwater Quality (2L) Standards. arcadis.com 15t Semi -Annual Monitoring Report - 2017 2.0 GROUNDWATER MONITORING 2.1 Groundwater Gauging On March 3, 2017 Arcadis G&M of North Carolina, Inc. (Arcadis) personnel gauged groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19. Gauging was conducted with a water interface probe (IP) prior to purging and sampling to determine DTB and DTW. The IP and attached tape, marked in 0.01-foot increments, were properly decontaminated before each use with Alconox soap and rinsed with distilled water. The DTW was measured from the marked survey point on the top of well casing (TOC). All measurements were recorded to the nearest 0.01-foot increment. The DTW ranged from 13.79 btoc in groundwater monitoring well MW-19 to 14.08 feet btoc in groundwater monitoring well MW-18. Groundwater monitoring well construction details are included in Table 1. Current groundwater elevations are summarized in Table 2. Historical groundwater gauging data is provided in Appendix A. A potentiometric surface map depicting historical groundwater flow direction is provided as Figure 3. 2.2 Ground water Sampli ng On March 3, 2017, groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19 were purged of stagnant water to prepare for groundwater sampling. Prior to purging, the amount of water to be removed was calculated using the following formula: 3.1415 x rz x (TD-DTW) x 7.481 = gallons of water (1 well volume) Where: r = radius of well (in feet) TD = total depth of well (in feet) DTW = depth to water (in feet) In order to ensure that the water in the wells after purging is representative of the water in the aquifer, a minimum of three well volumes were removed. Groundwater samples obtained from the groundwater monitoring well were collected from disposable polyethylene bailers using new nylon rope. Groundwater samples were placed in laboratory supplied containers and shipped on wet ice to TestAmerica Inc. in Nashville, Tennessee, for analysis of Sulfate (SO4) by Standard Method 9056A. Groundwater samples submitted for sulfate analysis were collected in 250-milliliter plastic bottles. The laboratory analytical report and chain -of -custody record for the March 3, 2017 groundwater sampling event is included as Appendix B. 2.3 Groundwater Analytical Results Groundwater analytical data from the March 3, 2017 groundwater sampling event indicated the following: arcadis.com 4 15t Semi -Annual Monitoring Report - 2017 • Dissolved -phase concentrations of sulfate were detected in concentrations exceeding the applicable North Carolina 2L Standard of 250 milligrams per liter (mg/L) in groundwater monitoring wells MW-5R (3,570 mg/L), MW-8R (1,720 mg/L), MW-18 (295 mg/L), and MW-19 (941 mg/L). Current groundwater analytical results are presented in Table 3. Historical analytical groundwater data can be found in Appendix C. A dissolved phase concentration map is presented as Figure 4. A sulfate isoconcentration map depicting the dissolved -phase extent of sulfate exceeding the applicable 2L groundwater quality standard is presented in Figure 5. arcadis.com 1st Semi -Annual Monitoring Report - 2017 3.0 SITE REMEDIATION 3.1 Remediation Activities to Date Summarized in the table below is a chronology of remediation activities performed at the site to date: Date Activity September 14, 1983 Subsurface release of gasoline from a ruptured product line associated with the UST system December 1990 UST systems associated with release removed; 500 tons of contaminated soil removed during UST closure 1992 Vacuum Extraction System Installed 1992 - 1994 Vacuum Extraction System Operation 1994 - 2011 Monitoring of site June 4 — 9, 2012 Activated Sodium Persulfate (ASP) injection event. Approximately 11,237-gallons of sodium persulfate injected. June 3 — 6, 2013 ASP injection event. Approximately 6,826-gallons of sodium persulfate injected. 2013 - Present Monitored Natural Attenuation arcadis.com 6 15t Semi -Annual Monitoring Report - 2017 4.0 CONCLUSIONS AND RECOMMENDATIONS Dissolved -phase sulfate was detected above the applicable 2L groundwater quality standard for sulfate of 250 mg/L in groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19 on March 3, 2017. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for August 2017. Groundwater monitoring wells MW- 5R, MW-8R, MW-18, and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-5R, MW-8R, MW 18, and MW-19 for analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2017 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com 15t Semi -Annual Monitoring Report - 2017 TABLES arcadis.com Table 1 Monitoring Well Construction Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Status Well Type TOC Elevation (2) Total Depth ��� Well Diameter (inches) Screen Interval (1) Avg Screen Elevation (2) MW-3 In Use Type II 99.03 20 2 NA - NA NA MW-5 Abandoned Type II 99.39 25.5 4 10.5 - 25.5 81.4 MW-5R In Use Type II NS 20 2 10 - 20 NA MW-6 In Use Type II 98.68 25.5 4 10.5 - 25.5 80.7 MW-6i In Use Type III 99.26 55 2 50 - 55 46.8 MW-8 Abandoned Type II 97.84 24 6 NA - NA NA MW-8R In Use Type II NS 20 2 10 - 20 NA MW-14 In Use Type II 100.44 22 4 7 - 22 85.9 MW-15 In Use Type II 99.91 22 4 7 - 22 85.4 MW-16 In Use Type II 97.42 25 2 10 - 25 79.9 MW-17 In Use Type II 100.00 22 4 7 - 22 85.5 MW-18 In Use Type II NS 20 2 10 - 20 NA MW-19 In Use Type II NS 20 2 10 - 20 NA Notes: 1. Reported in feet below grade 2. Measured in feet relative to site datum 3. Conestoga Rover and Associates, a former consultant for this Site, previously reported that no reference was found to the following wells: MW-1, MW-9, MW-10, MW-11, MW-12 or MW-13. These wells are presumed to be abandoned. 4. Monitoring wells MW-5 and MW-8 were abandoned on 5/19/2010 and replaced with monitoring wells MW-5R and MW-8R the same day. 5. Monitoring wells MW-18 and MW-19 were installated on October 25, 2011. NA = Not Applicable / Available NS = Not Surveyed TOC = Top of Casing Page 1 of 1 Table 2 Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina well Date Measured TOC Elevation Depath to LNAPL Depth to Groundwater (btoc) LNAPL Thickness Corrected Groudwater Elevation MW-5R 3/3/2017 NM ND 14.01 0.00 NM MW-8R 3/3/2017 NM ND 13.92 0.00 NM MW-18 3/3/2017 NM ND 14.08 0.00 NM MW-19 3/3/2017 NM ND 13.79 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Corr. GW Elev. = (ref point elevation) - (depth to groundwater) + (LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 LNAPL = Light non -aqueous phase liquid ND = Not detected NM = Not measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing Page 1 of 1 Table 3 Summary of Groundwater Results, March 2017 Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, NC Sample ID MW-5R MW-8R MW-18 MW-19 Date Sampled 3/3/2017 3/3/2017 3/3/2017 3/3/2017 Units mg/L mg/L mg/L mg/L Sulfate 3,570 1,720 295 941 Notes• mg/L - milligrams per liter BOLD text indicates exceendance of NC groundwater standard 2L for sulfate (250 mg/L). Page 1 of 1 FIGURES CITY:— DIVIGROUP:(Regd) DB:M. Vives LD:M. 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CATCH BASIN O M.H. MAN HOLE M AREA LIGHT • U.P. UTILITY POLE F.H. FIRE HYDRANT ❑ T TELEPHONE ❑ LARGE MANHOLE COVER GROUNDWATER MONITORING WELL NOTE: 1. MONITORING WELL LOCATIONS ARE APPROXIMATE 2. THE SITE IS A VACANT PARKING LOT. ALL SITE FEATURES EXCEPT PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE CHARACTERISTICS. 0 30' 60' GRAPHIC SCALE W W 0 0 0 J J 0 Z Y LEGEND: PROPERTY LINE ABANDONED GROUNDWATER MONITORING WELL P- FORMER PRODUCT LINE 0" CATCH BASIN O M.H. MAN HOLE me AREA LIGHT • uF. UTILITY POLE F.H. FIRE HYDRANT ❑ T TELEPHONE [_] LARGE MANHOLE COVER GROUNDWATER MONITORING WELL (NSVD) NOT SURVEYED TO VERTICAL DATUM HISTORICAL DEPICTED GROUNDWATER FLOW (FT AMSL) DIRECTION FT AMSL FEET ABOVE MEAN SEA LEVEL NOTE: 1. MONITORING WELL LOCATIONS ARE APPROXIMATE 2. THE SITE IS A VACANT PARKING LOT. ALL SITE FEATURES EXCEPT PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE CHARACTERISTICS. 0 30' 60' GRAPHIC SCALE MW-1 W W V! O O J Z Y ASPHALT PARKING FORMER PAD Date 4/29 SO4 1 7! (RASH ;LOSUR METAL ` m SHED ` �2 o METAL SHED FORMER , Date 4/28/21 BP SERVICE ` STATION 504 2.98, oe MW-5 MW 1� r MW-SR MW-8WIM F.H.W-8R ISLAND(TYP)P carvovv I-61 PARKING I MW-6 MW-19 FDasER DIESEL I u T IREn I I ` ' =ERPUMP ISLAND (TYP) CONCRETE FO ER TAN iOUD /2017 FORMER 720 • CANOPY I I FORMER VENT RISERS oo O O MW-19 Date 14/28/201619/1 MW-15 FORMER SO4 1 1730 1 1 e _ m VENT RISERS LEGEND: — — — PROPERTY LINE V ABANDONED GROUNDWATER MONITORING WELL N— FORMER PRODUCT LINE 0" CATCH BASIN 0 M.H. MAN HOLE IM AREA LIGHT • UP. UTILITY POLE F.H. FIRE HYDRANT ❑ T TELEPHONE ❑ LARGE MANHOLE COVER GROUNDWATER MONITORING WELL mg/L MILLIGRAMS PER LITER LEGEND Abbreviation Constituent 2 L SO4 Sulfate 250 NOTE: 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L 2. VALUES IN BOLD EXCEED NORTH CAROLINA 2L STANDARDS. 0 30' 60, GRAPHIC SCALE W W O J Z Y Om 11 .°- . ass w ' M i-17 \ 1 ASPHALT TRASH PARKING ENCLOSURE SHEDL N� METAL SHED ZQ I I FORMERUST AREAGASOLINE I FORME SP SERVICE STATION *MW 16 �a CONCRETE (295) o \ O MW-1MW-5R-I1L:mw:,k (3,570)_ MW-6R M Isurvo mPl F R"IR ` MW-61 PARKING I MW-6 MW-1'FO 9 R DIESEL (941) R T l^ FORMER PUMP FO IER I corvcRETe� TAN OoD FORMER � o 0 o CANOPY I I FORMER ' O VENT RISERS / \ FORMER VENT RISERS LEGEND: PROPERTY LINE Y ABANDONED GROUNDWATER MONITORING WELL P— FORMER PRODUCT LINE 0C.B. CATCH BASIN O M.H. MAN HOLE M AREA LIGHT • D'P' UTILITY POLE F.H. FIRE HYDRANT ❑ T TELEPHONE ❑ LARGE MANHOLE COVER GROUNDWATER MONITORING WELL (3,570) SULFATE CONCENTRATION (mg/L) 250 MATED Ih TE CONCENTRATION CONTOUR 2L SEST TANDARD (mg%L) (mg/L) MILLIGRAMS PER LITER NOTE: 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L 2. SHADED VALUES EXCEED NORTH CAROLINA 2L STANDARDS. 0 30' 60' GRAPHIC SCALE Historical Groundwater Elevation Data Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Wen Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet bloc) (feet bloc) (feet) Elevation (1)(2) * 06/24/93 ND 13.89 0.00 85.14 08/23/94 ND 14.36 0.00 84.67 03/21/95 ND 13.58 0.00 85.45 08/05/96 ND 13.54 0.00 85.49 11/17/98 ND 14.09 0.00 84.94 06/19/01 ND 14.11 0.00 84.92 09/12/01 ND 14.41 0.00 84.62 12/27/01 ND 14.51 0.00 84.52 03/05/02 ND 14.29 0.00 84.74 05/13/03 ND 14.35 0.00 84.68 12/09/03 ND 13.63 0.00 85.40 03/23/06 ND 13.64 0.00 85.39 05/08/07 ND 13.40 0.00 85.63 05/14/08 ND 13.42 0.00 85.61 05/28/09 ND 13.31 0.00 85.72 05/27/10 ND 13.07 0.00 85.96 MW-3 10/31/11 99.03 ND 13.87 0.00 85.16 05/22/12 ND 13.55 0.00 85.48 06/14/12 ND 13.53 0.00 85.50 07/09/12 ND 13.98 0.00 85.05 08/14/12 ND 14.24 0.00 84.79 09/19/12 ND 14.08 0.00 84.95 12/05/12 ND 14.42 0.00 84.61 02/26/13 ND 13.55 0.00 85.48 05/31/13 ND 13.58 0.00 85.45 08/28/13 ND 13.57 0.00 85.46 11/07/13 ND 14.30 0.00 84.73 02/27/14 ND 13.28 0.00 85.75 06/02/14 ND 13.34 0.00 85.69 10/16/14 ND 14.18 0.00 84.85 04/23/15 ND 13.54 0.00 85.49 04/28/16 ND 13.51 0.00 85.52 09/19/16 ND 13.92 0.00 85.11 03/03/17 ND NM 0.00 NM 06/24/93 ND 13.51 0.00 85.88 08/23/94 ND 13.82 0.00 85.57 03/21/95 ND 13.71 0.00 85.68 08/05/96 ND 13.54 0.00 85.85 11/17/98 ND 14.08 0.00 85.31 06/19/01 NM NM NM NM 09/12/01 ND 14.46 0.00 84.93 MW-5 12/27/01 99.39 14.51 15.07 0.56 84.73 03/05/02 14.45 14.88 0.43 84.82 05/12/03 NM NM NM NM 12/09/03 13.18 13.60 0.42 86.10 03/23/06 ND 13.67 0.00 85.72 05/08/07 ND 13.45 0.00 85.94 05/14/08 ND 13.51 0.00 85.88 05/28/09 ND 13.39 0.00 86.00 05/27/10 ND 13.70 0.00 NM 10/31/11 ND 13.97 0.00 NM 05/22/12 ND 13.66 0.00 NM 06/14/12 ND 13.73 0.00 NM 07/09/12 ND 14.18 0.00 NM 08/14/12 ND 14.45 0.00 NM 09/19/12 ND 14.35 0.00 NM 12/05/12 ND 14.68 0.00 NM 02/26/13 ND 13.89 0.00 NM NM-5R 05/31/13 NS ND 13.77 0.00 NM 08/28/13 ND 13.83 0.00 NM 11/07/13 ND 14.53 0.00 NM 02/27/14 ND 13.39 0.00 NM 06/02/14 ND 13.47 0.00 NM 10/16/14 ND 14.32 0.00 NM 04/23/15 ND 13.69 0.00 NM 10/13/15 ND 14.19 0.00 NM 04/28/16 ND 13.61 0.00 NM 09/19/16 ND 13.99 0.00 NM 03/03/17 ND 14.01 0.00 NM Page 1 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet btoc) (feet bloc) (feet) Elevation (1)(2) * 06/24/93 ND 12.31 0.00 86.37 08/23/94 ND 12.61 0.00 86.07 03/21/95 ND 13.15 0.00 85.53 08/05/96 ND 12.39 0.00 86.29 11/17/98 ND 13.16 0.00 85.52 06/19/01 NM NM NM NM 09/12/01 ND 13.51 0.00 85.17 12/27/01 ND 13.61 0.00 85.07 MW 6 03/05/02 98.68 ND 11.02 0.00 87.66 05/12/03 ND 11.10 0.00 87.58 12/09/03 ND 13.49 0.00 85.19 03/23/06 ND 11.79 0.00 86.89 05/08/07 ND 12.50 0.00 86.18 05/14/08 ND 12.16 0.00 86.52 05/28/09 ND 10.64 0.00 88.04 05/27/10 ND 11.84 0.00 86.84 10/31/11 ND 12.95 0.00 85.73 06/02/14 ND 12.38 0.00 86.30 06/24/93 ND NM 0.00 NM 08/23/94 ND NM 0.00 NM 03/21/95 ND 14.75 0.00 84.51 08/05/96 ND 14.13 0.00 85.13 11/17/98 ND 14.09 0.00 85.17 06/19/O1 ND 18.07 0.00 81.19 09/12/O1 ND 16.60 0.00 82.66 12/27/01 ND 14.61 0.00 84.65 03/05/02 ND 14.96 0.00 84.30 MW-6i 05/12/03 99.26 ND 15.17 0.00 84.09 12/09/03 ND 13.55 0.00 85.71 03/23/06 ND 13.55 0.00 85.71 05/08/07 ND 12.93 0.00 86.33 05/14/08 ND 13.22 0.00 86.04 05/28/09 ND 13.39 0.00 85.87 05/27/10 ND 13.23 0.00 86.03 10/31/11 ND 13.90 0.00 85.36 06/02/14 ND 13.35 0.00 85.91 04/28/16 ND 13.55 0.00 85.71 * 08/23/94 ND 12.14 0.00 85.70 * 03/21/95 ND 12.02 0.00 85.82 * 08/05/96 ND 11.99 0.00 85.85 * 11/17/98 ND 12.53 0.00 85.31 * 06/19/01 NM NM NM NM * 09/12/01 ND 12.67 0.00 85.17 MW 8 * 12/27/O1 97.84 14.47 15.03 0.56 83.26 * 03/05/02 12.42 12.60 0.18 85.38 05/12/03 NM NM NM NM 12/09/03 13.32 13.56 0.24 84.47 03/23/06 ND 12.15 0.00 85.69 05/08/07 ND 11.90 0.00 85.94 05/14/08 ND 11.95 0.00 85.89 05/28/09 ND 11.70 0.00 86.14 Page 2 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Wen Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet btoc) (feet bloc) (feet) Elevation (1)(2) 05/27/10 ND 12.97 0.00 NM 10/31/11 ND 13.34 0.00 NM 05/22/12 ND 13.69 0.00 NM 06/14/12 ND 14.94 0.00 NM 07/09/12 ND 14.08 0.00 NM 08/14/12 ND 14.29 0.00 NM 09/19/12 ND 14.08 0.00 NM 12/05/12 ND 14.53 0.00 NM 02/26/13 ND 13.80 0.00 NM MW-8R 05/31/13 NS ND 13.61 0.00 NM 08/28/13 ND 13.74 0.00 NM 11/07/13 ND 14.42 0.00 NM 02/27/14 ND 13.33 0.00 NM 06/02/14 ND 13.34 0.00 NM 10/16/14 ND 14.18 0.00 NM 04/23/15 ND 13.57 0.00 NM 10/13/15 ND 14.08 0.00 NM 04/28/16 ND 13.53 0.00 NM 09/19/16 ND 13.91 0.00 NM 03/03/17 ND 13.92 0.00 NM 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 13.55 0.00 86.89 08/05/96 ND 13.64 0.00 86.80 11/17/98 ND 14.26 0.00 86.18 06/19/O1 ND 14.55 0.00 85.89 09/12/01 ND 14.81 0.00 85.63 12/27/01 ND 14.85 0.00 85.59 03/05/02 ND 14.64 0.00 85.80 MW-14 05/12/03 100.44 ND 13.41 0.00 87.03 12/09/03 ND 13.51 0.00 86.93 03/23/06 ND 13.82 0.00 86.62 05/08/07 ND 13.54 0.00 86.90 05/14/08 ND 13.64 0.00 86.80 05/28/09 ND 13.47 0.00 86.97 05/27/10 ND 13.00 0.00 87.44 10/13/11 ND 14.14 0.00 86.30 06/02/14 ND 13.42 0.00 87.02 04/28/16 ND 13.65 0.00 86.79 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.83 0.00 87.08 08/05/96 ND 12.77 0.00 87.14 11/17/98 ND 13.58 0.00 86.33 06/19/01 ND 13.80 0.00 86.11 09/12/01 ND 14.18 0.00 85.73 12/27/01 ND 14.29 0.00 85.62 03/05/02 ND 13.98 0.00 85.93 MW-15 05/12/03 99.91 NM 12.75 NM 87.16 12/09/03 ND 12.89 0.00 87.02 03/23/06 ND 13.14 0.00 86.77 05/08/07 ND 12.90 0.00 87.01 05/14/08 ND 13.12 0.00 86.79 05/28/09 ND 12.90 0.00 87.01 05/27/10 ND 12.25 0.00 87.66 10/31/11 ND 13.61 0.00 86.30 06/02/14 ND 12.82 0.00 87.09 10/16/14 ND 13.91 0.00 86.00 04/28/16 ND 13.15 0.00 86.76 Page 3 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet btoc) (feet bloc) (feet) Elevation (1)(2) 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.06 0.00 85.36 08/05/96 ND 12.09 0.00 85.33 11/17/98 ND 12.60 0.00 84.82 06/19/01 ND 12.74 0.00 84.68 09/12/01 ND 12.98 0.00 84.44 12/27/01 NM NM NM NM 03/05/02 ND 12.83 0.00 84.59 MW-16 05/12/03 97.42 NM NM NM NM 12/09/03 ND 12.13 0.00 85.29 03/23/06 ND 12.18 0.00 85.24 05/08/07 NM NM NM NM 05/14/08 ND 12.03 0.00 85.39 05/28/09 ND 11.96 0.00 85.46 05/27/10 ND 11.69 0.00 85.73 10/31/11 ND 12.45 0.00 84.97 11/07/13 ND 12.88 0.00 84.54 06/02/14 ND 11.97 0.00 85.45 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 14.42 0.00 85.58 08/05/96 ND 14.46 0.00 85.54 11/17/98 ND 14.91 0.00 85.09 06/19/01 ND 15.03 0.00 84.97 09/12/01 ND 15.28 0.00 84.72 12/27/O1 ND 15.37 0.00 84.63 03/05/02 ND 15.15 0.00 84.85 MW-17 05/12/03 100.00 NM 14.15 NM 85.85 12/09/03 ND 14.50 0.00 85.50 03/23/06 ND 14.45 0.00 85.55 05/08/07 ND 14.22 0.00 85.78 05/14/08 ND 14.22 0.00 85.78 05/28/09 ND 14.12 0.00 85.88 05/27/10 ND 13.90 0.00 86.10 10/31/11 ND 14.72 0.00 85.28 06/02/14 ND 14.14 0.00 85.86 04/28/16 ND 14.36 0.00 85.64 10/31/11 ND 13.95 0.00 NM 05/22/12 ND 14.10 0.00 NM 06/14/12 ND 13.61 0.00 NM 07/09/12 ND 14.05 0.00 NM 08/14/12 ND 14.43 0.00 NM 09/19/12 ND 14.34 0.00 NM 12/05/12 ND 14.62 0.00 NM 02/26/13 ND 14.67 0.00 NM 05/31/13 ND 14.57 0.00 NM MW-18 08/28/13 NS ND 14.33 0.00 NM 11/07/13 ND 14.51 0.00 NM 02/27/14 ND 13.76 0.00 NM 06/02/14 ND 13.55 0.00 NM 10/16/14 ND 14.37 0.00 NM 04/23/15 ND 13.84 0.00 NM 10/13/15 ND 14.81 0.00 NM 04/28/16 ND 13.62 0.00 NM 09/19/16 ND 14.04 0.00 NM 03/03/17 ND 14.08 0.00 NM Page 4 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Date TOC Elevation -1 Depth to LNAPL (feet btoc) Depth to Groundwater ( LNAPL Thickness (feet) Corrected Groundwater Elevation (1)(2) 10/31/11 ND 13.75 0.00 NM 05/22/12 ND 13.37 0.00 NM 06/14/12 ND 13.39 0.00 NM 07/09/12 ND 13.89 0.00 NM 08/14/12 ND 14.13 0.00 NM 09/19/12 ND 14.02 0.00 NM 12/05/12 ND 14.39 0.00 NM 02/26/13 ND 13.62 0.00 NM 05/31/13 ND 13.47 0.00 NM MW-19 08/28/13 NS ND 13.56 0.00 NM 11/07/13 ND 14.25 0.00 NM 02/27/14 ND 13.17 0.00 NM 06/02/14 ND 13.14 0.00 NM 10/16/14 ND 14.03 0.00 NM 04/23/15 ND 13.46 0.00 NM 10/13/15 ND 14.01 0.00 NM 04/28/16 ND 13.38 0.00 NM 09/19/16 ND 13.75 0.00 NM 03/03/17 ND 13.79 0.00 NM Notes: L Measured in feet relative to site datum 2. Corr. GW Elev. _ (ref. point elevation) - (depth to groundwater) + (LNAPL thiclmess)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 • Monitoring well MW-3 was previously reported as MW-2, monitoring well MW-6 was previously reported m MW-8, and monitoring well MW-8 was previously been reported as MW-6. LNAPL = Light non -aqueous phase liquid ND = Not detected NM = Not measured NS = Not Surveyed TOC = Top of casing bloc = below top of casing - During the May 2003 sampling event LNAPL was observed in MW-5. Depth to groundwater and thickness of LNAPL were not measured. Page 5 of 5 FAIMIlk W w A , Laboratory Analytical Report and Chain -of -Custody Record — March 3, 2017 TestAmerica ° THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel: (615)726-0177 TestAmerica Job ID: 490-123161-1 TestAmerica SDG: 381 Knollwood St, Winston-Salem, NC Client Project/Site: Former BP Facility #24163 For: ARCADIS U.S., Inc. 801 Corporate Center Drive Suite 300 Raleigh, North Carolina 27607-5073 Attn: Paul Goodell q44J.- W Authorized for release by. 312012017 11:23:22 AM Heather Wagner, Project Manager 1 (615)301-5763 heather.wagner@testamericainc.com Designee for Jennifer Huckaba, Project Manager 11 (615)301-5042 jennifer.huckaba@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Table of Contents CoverPage .............................................. 1 Table of Contents ......................................... 2 Sample Summary ......................................... 3 Case Narrative ........................................... 4 Definitions............................................... 5 Client Sample Results ...................................... 6 QC Sample Results ........................................ 10 QC Association ........................................... 11 Chronicle................................................ 12 Method Summary ......................................... 13 Certification Summary ...................................... 14 Chain of Custody .......................................... 15 Receipt Checklists ......................................... 17 TestAmerica Nashville Page 2 of 17 3/20/2017 Sample Summary Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-123161-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St, Winston-Salem, NC Lab Sample ID Client Sample ID Matrix Collected Received 490-123161-1 MW-5R Ground Water 03/03/17 11:35 03/04/17 09:30 490-123161-2 MW-8R Ground Water 03/03/17 11:45 03/04/17 09:30 490-123161-3 MW-18 Ground Water 03/03/17 11:55 03/04/17 09:30 490-123161-4 MW-19 Ground Water 03/03/17 12:05 03/04/17 09:30 TestAmerica Nashville Page 3 of 17 3/20/2017 Case Narrative Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Job ID: 490-123161-1 Laboratory: TestAmerica Nashville Narrative TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC 0 Job Narrative 490-123161-1 Comments No additional comments. Receipt The samples were received on 3/4/2017 9:30 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperature of the cooler at receipt was 0.41 C. HPLC/IC Method(s) 9056A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 490-415484 were outside control limits. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample (LCS) recovery was within acceptance limits. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. TestAmerica Nashville Page 4 of 17 3/20/2017 Definitions/Glossary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Qualifiers TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC HPLCAC Qualifier Qualifier Description 4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. G Abbreviation a %R CFL CNF DER Dil Fac DL, RA, RE, IN DLC M DA EDL MDC MDL ML NC ND PQL QC RER RL RPD TEF TEQ These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis Percent Recovery Contains Free Liquid Contains no Free Liquid Duplicate error ratio (normalized absolute difference) Dilution Factor Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample Decision level concentration Minimum detectable activity Estimated Detection Limit Minimum detectable concentration Method Detection Limit Minimum Level (Dioxin) Not Calculated Not detected at the reporting limit (or MDL or EDL if shown) Practical Quantitation Limit Quality Control Relative error ratio Reporting Limit or Requested Limit (Radiochemistry) Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin) Toxicity Equivalent Quotient (Dioxin) TestAmerica Nashville Page 5 of 17 3/20/2017 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-5R Date Collected: 03/03/17 11:35 Date Received: 03/04/17 09:30 Client Sample Results C TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier RL Sulfate 3570 100 Lab Sample ID: 490-123161-1 Matrix: Ground Water MDL Unit D Prepared mg/L Analyzed Dil Fac 03/17/1719:27 100 TestAmerica Nashville Page 6 of 17 3/20/2017 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample Results C TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Client Sample ID: MW-8R Lab Sample ID: 490-123161-2 Date Collected: 03/03/17 11:45 Matrix: Ground Water Date Received: 03/04/17 09:30 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 1720 RL MDL Unit D Prepared Analyzed Dil Fac 100 mg/L 03/17/1719:38 100 TestAmerica Nashville Page 7 of 17 3/20/2017 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample Results C TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Client Sample ID: MW-18 Lab Sample ID: 490-123161-3 Date Collected: 03/03/17 11:55 Matrix: Ground Water Date Received: 03/04/17 09:30 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 295 RL MDL Unit D Prepared Analyzed Dil Fac 10.0 mg/L 03/17/1719:49 10 TestAmerica Nashville Page 8 of 17 3/20/2017 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-19 Date Collected: 03/03/17 12:05 Date Received: 03/04/17 09:30 Client Sample Results C TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier RL Sulfate 941 100 Lab Sample ID: 490-123161-4 Matrix: Ground Water MDL Unit D Prepared mg/L Analyzed Dil Fac 03/17/17 20:45 100 TestAmerica Nashville Page 9 of 17 3/20/2017 QC Sample Results C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-123161-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Lab Sample ID: MB 490-415484/3 Matrix: Water Analysis Batch: 415484 MB MB Analyte Result Qualifier RL Sulfate ND 1.00 Lab Sample ID: LCS 490-415484/4 Matrix: Water Analysis Batch: 415484 Client Sample ID: Method Blank Prep Type: Total/NA MDL Unit D Prepared Analyzed Dil Fac mg/L 03/17/17 18:54 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 10.0 9.811 mg/L 98 80 -120 Lab Sample ID: LCSD 490-415484/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 415484 Spike LCSD LCSD %Rec. RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 9.804 mg/L 98 80 -120 0 20 Lab Sample ID: 490-123161-3 MS Client Sample ID: MW-18 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 415484 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 295 20.0 256.1 4 mg/L -197 80 - 120 Lab Sample ID: 490-123161-3 MSD Client Sample ID: MW-18 Matrix: Ground Water Prep Type: Total/NA Analysis Batch: 415484 Sample Sample Spike MSD MSD %Rec. RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 295 20.0 257.1 4 mg/L -192 80-120 0 20 TestAmerica Nashville Page 10 of 17 3/20/2017 QC Association Summary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 HPLC/IC Analysis Batch: 415484 Lab Sample ID 490-123161-1 490-123161-2 490-123161-3 490-123161-4 MB 490-415484/3 LCS 490-415484/4 LCSD 490-415484/5 490-123161-3 MS 490-123161-3 MSD Client Sample ID MW-8R MW-18 MW-19 Method Blank Lab Control Sample Lab Control Sample Dup MW-18 MW-18 TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Prep Type Matrix Method Total/NA Ground Water 9056A Total/NA Ground Water 9056A Total/NA Ground Water 9056A Total/NA Ground Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Water 9056A Total/NA Ground Water 9056A Total/NA Ground Water 9056A Prep Batch 0 Page 11 of 17 TestAmerica Nashville 3/20/2017 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-5R Date Collected: 03/03/17 11:35 Date Received: 03/04/17 09:30 Batch Batch Prep Type Type Method Run Total/NA Analysis 9056A Client Sample ID: MW-8R Date Collected: 03/03/17 11:45 Date Received: 03/04/17 09:30 Batch Batch Prep Type Type Method Run Total/NA Analysis 9056A Client Sample ID: MW-18 Date Collected: 03/03/17 11:55 Date Received: 03/04/17 09:30 Lab Chronicle C TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Lab Sample ID: 490-123161-1 Matrix: Ground Water Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 100 415484 03/17/17 19:27 T1C TAL NSH Dil Initial Final Factor Amount Amount 100 Lab Sample ID: 490-123161-2 Matrix: Ground Water Batch Prepared Number or Analyzed Analyst Lab 415484 03/17/17 19:38 T1C TAL NSH Lab Sample ID: 490-123161-3 Matrix: Ground Water Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056A 10 415484 03/17/17 19:49 T1C TAL NSH Client Sample ID: MW-19 Date Collected: 03/03/17 12:05 Date Received: 03/04/17 09:30 Lab Sample ID: 490-123161-4 Matrix: Ground Water Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056A 100 415484 03/17/17 20:45 T1 C TAL NSH Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 Page 12 of 17 TestAmerica Nashville 3/20/2017 Method Summary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 TestAmerica Job ID: 490-123161-1 SDG: 381 Knollwood St, Winston-Salem, NC Method Method Description Protocol Laboratory 9056A Anions, Ion Chromatography SW846 TAL NSH Protocol References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 TestAmerica Nashville Page 13 of 17 3/20/2017 Certification Summary Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-123161-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St, Winston-Salem, NC Laboratory: TestAmerica Nashville Unless otherwise noted, all analytes for this laboratory were covered under each certification below. Authority Program EPA Region Certification ID Expiration Date North Carolina (WW/SW) State Program 4 387 12-31-17 The following analytes are included in this report, but are not certified under this certification: Analysis Method Prep Method Matrix Analyte 9056A Ground Water Sulfate TestAmerica Nashville Page 14 of 17 3/20/2017 TestAmedca THE LEADER IN ENVIRONMENTAL TESTING Nashville, TN COOLER RECEIPT FORA? dgD-123181 Chain of Custor; Cooler Received/Opened On 3l412017 093i1 -- Time Samples Removed From Cooler Time Samples Placed In Storage 12 Hour Window) 1. Tracking # I (last 4 digits, FedEx) Courier: _FedEx_ IR Gun Wi7960353_ pH Strip Lot Chlorine Strip Lot 2. Temperature of rep. sample or temp blank when opened: a ► begrees Celsius 3. If Item 92 temperatures Is QCC or less, was the representative sample or temp blank frozen? YES N0... IA 4. Were custody seals on outside of cooler? &4/VTAM>Lp YE ..NO.,6 If yes, how many and where: +� r / 5. Were the seals intact, signed, and dated correctly? 3YE NO...NA 6. Were custody papers inside cooler? .NO...NA certify that I opened the copier and answered questions 1.6 (initial! rJ 7. Were custody seals on containers: YES I and Intact YES...NO..� Were these signed and dated correctly? YES...NO.14 6. Packing mat'I used? Bubbiewrap Plastic bag Peanuts Vermiculite Foam Insert Paper OtheAZnb 9. Cooling process: Ice Ice -pack .. a rect contact Dry Ice Other None 10. Did all containers arrive in good condition (unbroken)? € ...NO...NA 11. Were ail contalner labels complete (0, data, signed, pres., etc)? NO...NA 12. Did all container labels and tags agree with custody papers? E ...NO...NA 13a. Were VOA vials received? YES...,NA b. Was there any observable headspace present in any VOA vial? YES...NO.C�1. 14. Was there a Trip Blank in this cooler? YES..0P..NA if multiple Gaolers, sequence # ✓A I certify that I unloaded the coofer and answered questions 7-14 initial �� 15a. On pres'd battles, d I d pH test strips suggest preservation reached the correct pH level? YES..N0 3 b. Did the bottle labels indicate that the correct preservatives were used YF ..NO...NA 16. was residual chlorine present? YES...NO. No certify that I checked for chlorine and pH as per SOP and answered questions 15-16 (initial 17. Were custody papers properly filled out (ink, signed, etc)? No ... NA 18, Did you sign the custody papers in the appropriate place? E ...NO...NA 19. Were correct containers used for the analysis requested? 14�...NO... NA 20. Was sufficient amount of sample sent in each container? &E ...NO...NA I certify that I entered this droIact into LIMS and answered questions 17-20 [Initial] 21. Were there Non -Conformance issues at login? YES.. a NCM generated? YES. .,lN01..# i115 = Bioken in Et1Tipmenl CoolerRLanpt I-enn.duc U-I Revised I21MI5 End of roan Page 15 of 17 3/20/2017 CD N CD N (h T� ` _ — �� H tshuillvfliv]Elon g�1"i!� ,Y'7, 29B0 Faster Creiflhoof. phase: 726-OS77 TOFn�: $00- 800.756.0980 THE LEADEA In4 ENVIRONMENTAL TI:BT INC Ngsjtyille, TN 37204 Fix: SIS-72e34lt,1 Consukant Name: ARG40IS Addre Ill -0 Sanders Lane GdylStetvl4FP: BLUE FIELD, VA 2480.9 C on!+Atvnt Project Mgr. PaW 43ppdad Consultant To rephpne Number: 9194 1&2327 F!" Na.: 278-322-" 9w Sampl.r Hemp; trd.tS CL e' 1 samp4er Signature_ _ Y ;`. P�!aff TA Account p; Pot, Invoice To: N75PAYA8LE.AflFAINI T t1aN ARCADIS )S.COM Report To; P;.O GvDdefl - Project flame: Fommer pP fadIIH R.taa R (MRN 4); 241IZ — Major Project(Al2M. Site Address 381 ttnmlhypad 8t City. Slam, Zip WiRatorr.Salmn, Nam Carolina Regulatory diwtct iC-A) Pra4wl &,e I Mamm I Anr" Far, c n c 6 4 33i 0 = m s w Loa: 490 p 123161 g yy ag E n R 191 ~ n Sa to ID or Fkd ID O Z li cc Cr fi i rJ 4 �S S ¢ Q MW-8R �i4j i z / i x mw-TS 1rSj T z 7 x MW-79 i b� 1 x i x CamrnonwsPecial lnsuuctlons L�tiorelpry Gontsrants: ��7 Temparma]m Upor. Rexlp: V' Sampe Conumonis Irasci7 Y N VOCS F[ec of Yl�dspaca� Y H �¢LVr�dyles {ylesee�Srele m�e7 Lenel2 Lerel3 Le.nl4 CM.r Rot9ingvl nee L /�Dre 7 1 Tm. R DM. � j Time rory� • - L.. IL�� +V [ / f" I Q4. �. i 1 R.enq,i.hw by-- Dot. T]m. Re:eiysd 4y' Deis 71mo - rt >,dh he the rarpomlhehy yr 8p or � con dt m Wq a,e TesrAmetln Fr jen Manager Repnqulshed e'!• Call Tlm. R by tier. Tm. [/��-.� by pC or I- tirat a nqh -.pm va"sutmide6. �' I j �7� 7A psi ect Wwr-ON'. Da1rc Login Sample Receipt Checklist Client: ARCADIS U.S., Inc. Login Number: 123161 List Number: 1 Creator: Abernathy, Eric Question Job Number: 490-123161-1 SDG Number: 381 Knollwood St, Winston-Salem, NC List Source: TestAmerica Nashville Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey N/A meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A TestAmerica Nashville Page 17 of 17 3/20/2017 APPENDIX C Historical Groundwater Analytical Data Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 1 m l Mg/1 MW-3 5/13/2003 8.5 0.98 J 0.61 J 1.7 J 8 12/9/2003 47.4 1 14.3 1.9 1 8.1 1 37.3 3/23/2006 4.5 J < 0.5 < 0.5 UJ < 1 UJ 5.5 5/8/2007 40.4 3.7 1.4 2 J 13.1 5/14/2008 4.3J <0.8 <0.7 <0.8 14 5/28/2009 5.4 0.44 J 0.14 J 0.49 J 5.6 5/27/2010 0.44 J < 0.11 0.3 J < 0.32 4.8 10/31/2011 5.5 0.76 < 0.17 U 0.38 J 19.1 8.4 405 5/22/2012 < 0.43 U < 0.2 < 0.2 < 0.52 4.6 15.3 378 6/14/2012 12.1 6.7 0.72 4.7 15.4 6.6 J 344 7/9/2012 2.2 1.6 2.6 3 14.7 9.9 393 8/14/2012 2 2.1 < 0.13 0.4 J 17.9 3.6 303 9/19/2012 2.7 0.66 <0.13 0.33J 19.8 2.8 459 12/5/2012 11.3 1.2 0.43 J 1.1 J 19.3 0.78 J 377 2/26/2013 0.23 J < 0.1 < 0.1 < 0.22 5.4 32.6 338 5/31/2013 0.32J <0.1 <0.1 <0.22 10.5 17.9 334 8/28/2013 3.6 0.53 0.12 J 0.31 J 10.3 21.9 457 11/7/2013 4.3 0.27 J 0.13 J <0.22 10 21.7 536 2/27/2014 < 0.1 < 0.1 < 0.1 < 0.2 1.3 42.2 198 6/3/2014 0.48 J 0.15 J < 0.1 < 0.2 3.1 10/16/2014 18.0 372 4/23/2015 22.8 296 9/19/2016 21.3 MW-5 3/23/2006 11,700 2,440 32,000 13,500 16,100 3/23/2006 11,000 2,370 30,700 13,200 15,400 5/8/2007 7,410 1,590 21,100 8,920 8,830 5/8/2007 0) 7,400 1,680 20,100 9,290 9,360 5/14/2008 10,000 2,100 29,000 12,000 18,000 5/14/2008 01 10,000 2,100 30,000 12,000 18,000 5/28/2009 7,390 2,330 25,700 13,400 6,920 5/28/2009 (1) 6,510 2,240 22,100 12,900 6,510 MW-5R 5/27/2010 6,610 2,810 24,300 J 15,700 4,330 5/27/2010 00 6,090 2,380 30,100 J 13,300 4,250 10/31/2011 7,960 2,660 28,000 13,800 3,830 < 1 < 5 10/31/2011 (i> 8,360 2,870 24,600 14,800 4,070 5/22/2012 7,980 3,470 32,200 19,200 3,820 < 5 179 6/15/2012 «> 244 227 1,190 1,120 36.9 6,070 1,820 7/9/2012 336 J 481 J 2,010 J 2,400 J 48.4 J 6,470 2,620 8/14/2012 201 283 1,050 1,300 48.5 14,700. 4,190 9/19/2012 158 181 650 883 114 19,000 3,280 12/5/2012 754 505 2,220 2,380 1,160 13,600 1,840 2/26/2013 1,360 878 3,520 3,940 1,660 8,520 1,530 5/31/2013 1,410 1,380 5,930 6,220 1,150 J 4 680 1,560 8/28/2013 165 178 489 1,380 417 13,900 1,590 11/7/2013 214 131 331 969 651 14 400 1,570 2/27/2014 142 177 328 1,060 240 2,990 807 Page 1 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 MW-5R 6/2/2014 256 436 _IL1 1040 2520 519 J 10/16/2014 9,950 1,390 4/23/2015 5,980 1,510 10/13/2015 5,790 4/28/2016 2,980 9/19/2016 2,880 3/3/2017 3 570 MW-6 5/12/2003 < 0.5 0.52 J < 0.5 < 1 3 12/9/2003 2.3 0.64 J 1.1 3.6 17.6 12/9/2003 2.4 0.68 J 1.1 3.8 18 3/23/2006 0.76 J 0.59 J 3.6 2.8 J 1.1 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 5/14/2008 <0.5 <0.8 <0.7 <0.8 <0.5 5/28/2009 < 0.06 < 0.05 < 0.06 < 0.14 0.17 J 5/27/2010 <0.11 0.13 J 0.38 J 0.46 J <0.12 10/31/2011 8.7 J 11.7 J 27.5 J 132 J <0.26 UJ 131 2,130 6/2/2014 17.6 J 59.4 J 31.6 J 99.4 J 783 J MW-6I 5/12/2003 <0.5 <0.5 <0.5 1.11 <0.5 12/9/2003 < 2.5 < 2.5 < 2.5 < 5 < 2.5 3/23/2006 49.7 18.9 48.7 443 3,560 5/8/2007 < 25 < 25 < 25 < 50 6,910 5/14/2008 5.2J <2 <1.8 <2 3,400 5/28/2009 2.5 <0.05 <0.06 <0.14 1,150 5/27/2010 1.6 J < 1.1 < 1.1 < 3.2 492 10/31/2011 0.41 J < 0.36 < 0.32 < 0.75 122 < 1 76.1 6/2/2014 < 0.1 < 0.1 < 0.1 < 0.2 3.3 MW 8 3/23/2006 671 1,340 1,230 8,100 124 5/8/2007 1,160 799 196 2,990 1,440 5/14/2008 600 1,800 700 3,000 190 5/28/2009 1,390 2,050 357 3,310 1,560 5/27/2010 8,570 2,870 31,700 15,700 6,260 10/31/2011 8,000 3,180 32,100 17,200 3,170 <1 <5 5/22/2012 8,270 3,360 36,400 J 17,800 3,920 < 5 119 6/15/2012 «1 726 47 J 760 242 J 96.3 J 4,760 22,200 7/9/2012 4,540 J 1,870 J 17,100 J 10,800 J 1,530 J 6 570 4,500 8/14/2012 4,370 1,610 19,300 8,780 2,000 7,010 1,560 MW-8R 9/19/2012 4,780 1,800 20,900 10,400 2,600 6,700 1,100 12/5/2012 7,760 2,440 31,900 13,800 4,560 2,410 635 2/26/2013 7,310 2,480 30,500 13,400 4,530 959 590 5/31/2013 6,540 3,040 30,500 12,500 4,200 439 437 8/28/2013 1,600 628 5,390 3,990 1,380 4 770 703 11/7/2013 1,130 329 2,440 1,830 1,770 7,460 766 2/27/2014 1,020 1 603 3,200 3,430 1,190 7 670 940 6/2/2014 1,360 J 680 J 3,510 J 3,330 J 2,110 J 6/2/2014 (1) 1,540 556 J 3,650 2,630 J 2,640 J -- 10/16/2014 3,310 883 9,070 4,990 3,910 3,560 842 4/23/2015 2,050 812 10/13/2015 1,600 4/29/2016 1,640 9/19/2016 1,330 3/3/2017 1,720 5/ 12/2003 < 0.5 < 0.5 < 0.5 < 1 0.52 J 12/9/2003 < 0.5 < 0.5 < 0.5 < 1 5.9 3/23/2006 < 0.5 < 0.5 < 0.5 < 1 < 0.5 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 MW-14 5/14/2008 <0.5 <0.8 <0.7 <0.8 <0.5 5/28/2009 < 0.06 < 0.05 0.077 J < 0.14 < 0.06 5/27/2010 <0.11 <0.11 <0.11 <0.32 <0.12 10/31/2011 < 0.13 < 0.15 < 0.42 U < 0.3 < 0.13 43.2 < 5 6/3/2014 <0.1 <0.1 <0.1 <0.2 <0.1 Page 2 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 m 1 m MW-15 3/23/2006 0.63 J 2.1 _IL1 <0.5 18.6 1.6 5/8/2007 < 0.5 < 0.5 < 0.5 2.2 J < 0.5 5/14/2008 <0.5 <0.8 <0.7 3.7J <0.5 5/27/2010 <0.11 <0.11 <0.11 <0.32 <0.12 10/31/2011 <0.13 <0.15 <0.13 <0.3 <0.13 <1 <5 6/3/2014 <0.1 <0.1 <0.1 <0.2 <0.1 10/16/2014 <0.1 <0.1 <0.1 <0.2 <0.1 MW-16 3/23/2006 <2.5 90.8 15.8 836 2.8J 5/14/2008 <0.5 160 15 1,600 4.1 J 5/27/2010 3.6 54.7 J 5.1 525 J 1.3 10/31/2011 < 0.65 17.2 < 1.4 U 321 < 0.65 194 < 5 11/7/2013 55.4 <5 6/3/2014 < 0.1 25 0.92 417 J < 0.1 MW-17 5/13/2003 57.7 <0.5 <0.5 <1 69 5/13/2003 40.8 <0.5 <0.5 <1 63.3 12/9/2003 6.6 0.65 J < 0.5 1 < 1 80.6 3/23/2006 1 <0.5 <0.5 <1 58.9 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 17.4 5/14/2008 3.7J <0.8 <0.7 <0.8 19 5/28/2009 7 < 0.05 0.076 J < 0.14 14.5 5/27/2010 5.7 < 0.11 < 0.11 < 0.32 12.4 10/31/2011 0.51 0.16 J < 0.81 U 0.57 J 8.9 < 1 422 6/3/2014 < 0.1 < 0.1 < 0.1 < 0.2 4.1 10/31/2011 3,140 998 11,100 8,950 1,140 8.2 446 5/22/2012 2,280 2,790 18,200 12,000 789 < 5 307 6/15/2012 «1 373 910 4,800 3,910 114 10,600 3,410 7/9/2012 1,730 J 2,170 J 15,000 J 9,750 J 676 J 2 300 835 8/14/2012 3,020 2,990 24,400 12,800 1,090 758 580 9/19/2012 3,190 3,090 22,600 14,000 1,240 322 542 12/5/2012 3,370 2,970 20,100 12,800 1,380 32 1 436 2/26/2013 2,510 2,970 10,100 8,690 1,140 13.8 500 5/31/2013 2,780 3,070 8,210 5,740 1,000 83.3 475 MW-18 8/28/2013 182 368 730 1,660 139 7 850 21230 11/7/2013 1,140 727 4,910 3,250 694 2,640 1,370 2/27/2014 16.6 109 20.2 45.8 18.5 4 310 1,270 6/2/2014 26.2 J 125 J 37.5 J 31.6 J 37.4 J 10/16/2014 359 388 244 138 364 1,540 513 4/23/2015 780 1,100 10/13/2015 516 4/29/2016 79.4 9/19/2016 377 3/3/2017 295 Page 3 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 m 1 m MW-19 10/31/2011 2,390 1,380 _IL1 8,790 7,040 5,160 3.7 425 5/22/2012 2,700 1 1,560 14,200 1 7,940 1 4,880 < 5 310 6/15/2012 (2) 4,020 1,440 18,200 7,940 3,290 1,090 6,520 7/9/2012 5 130 2,910 30,400 J 16,300 5,330 232 991 8/14/2012 2,420 1,650 14,200 8,370 4,090 469 1,080 9/19/2012 2,090 1,630 12,900 8,640 3,960 260 690 12/5/2012 2,320 1,810 15,200 10,400 4,010 58.8 588 2/26/2013 2,210 1,110 10,600 6,990 3,890 169 503 5/31/2013 1,830 1 894 8,820 1 5,250 1 3,120 1530 606 8/28/2013 2,710 J 1,190 J 13,100 7,420 J 3,240 J 2,660 525 11/7/2013 2,020 984 9,850 5,620 2,260 2 890 255 2/27/2014 2,550 1,400 10,900 7,880 3,320 2 790 322 6/2/2014 2,370 1,260 11,900 7,260 2,830 10/16/2014 2,340 632 4/23/2015 2 540 514 10/13/2015 1 960 4/28/2016 1,780 9/19/2016 1,270 3/3/2017 941 Notes: t11 Field duplicate (2) Alkalinity, sulfate, and carbon dioxide samples were collected 6/14/2012 and volatile organic analysis samples were collected 6/15/12. -" - Not sampled or analyzed < - Not detected at the specified detection limit µg/l - Micrograms per Liter GCL - Gross Contamination Level 2L - North Carolina Groundwater Quality (2L) Standard J - Estimated value mg/l - Milligrams per Liter MTBE - Methyl tert-Butyl Ether NE - Not established U - Not present above the associated level; blank contamination exists UJ - Not detected and the detection limit is estimated BOLD text indicates 2L exceedance -Bold cell with green highlight indicates GCL exceedence Activated sodium persulfate injections were performed at the site from June 4, 2012, to June 9, 2012, and from June 3, 2013, to June 6, 2013. Page 4 of 4 04ARCADIS5deign&Consultancy for naturaland built assets Arcadis U.S., Inc. 111-D Sanders Lane Bluefield, Virginia 24605 Tel 276 322 3879 Fax 276 322 3946 www.arcadis.com