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HomeMy WebLinkAboutWI0400198_Monitoring (Report)_20190507ARCADIS Design sr Consultancy fornaturaland built assets Mr. Michael Rogers UIC Program Manager NCDEQ — DWR 1636 Mail Service Center Raleigh, North Carolina 27699 Subject: 1st Semi -Annual Groundwater Monitoring Report — 2019 Former BP Facility #24163 381 Knollwood Street Winston-Salem, North Carolina 27103 Incident Number: 6400 (Closed) Risk Classification: Low (No Further Action) Dear Mr. Rogers: On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina is submitting the attached 1 st Semi -Annual Groundwater Monitoring Report — 2019 for the above referenced site. An electronic copy of this report including the associated laboratory analytical report is included with the attached CD. Please contact me at (919) 415-2327 with any questions or concerns related to the Report or this incident number. Sincerely, Arcadis G&M of North Carolina, Inc. r Paul Goodell, E.I. AFS Project Manager 5 Copies: File — BP #24163 Arcadis U.S., Inc. 111-D Sanders Lane Bluefield, VA 24605 Tel 276 322 3879 Fax 276 322 3946 www.arcadis.com A019Ide7►1tIIA0II Date: May 7, 2019 Contact: Paul Goodell Phone: 919.415.2327 Email: Paul.Goodell@arcadis.com Our ref: GP16BPNA.NC10 Page: 1/1 ARCADIS ')',sign&Consultancy far naturaand Built assetls Atlantic Richfield Company c/o BP Products North America, Inc. SEMI-ANNUAL MONITORING REPORT - 2019 Former BP Facility #24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina NCDEQ Incident #6400 (Closed) Injection Permit #W10400198 May 2019 1 1 Semi -Annual Monitoring Report - 2019 �'4dv &I, Hardik Patel AFS Task Manager �.�,•f�tvbt's.�'�f Paul Goodell, E.I. Certified Project Manager E, 1 ST SEMI-ANNUAL MONITORING REPORT -2019 Prepared for: Atlantic Richfield Company c/o BP Products North America, Inc. Mr, Greg Frisch — Project Manager 4850 E. 49", Street MEC-3 Room 155C Cuyahoga Heights, Ohio 44125 Tel 216,416.1232 Prepared by: Arcadis G&M of North Carolina, Inc. 5420 Wade Park Blvd. Suite 350 Raleigh, North Carolina 27607 Tel 919.854.1282 Fax 919.854,5448 www.areadi.s-u5.com Environmental Our fie(.: GPI6BPNA.NC10 Date: May 6, 2019 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged, confidential and exempt from disclosure under applicable law. Any dissemination, distribution or copying of this document is strictly prohibited, ES-1 1"1 Semi -Annual Monitoring Report - 2019 1' Semi -Annual Monitoring Report - 2019 Former BP Facility #24163 381 Knollwood St Winston-Salem, Forsyth County, North Carolina Latitude 3611 5' 25.94"N Longitude 8011 17' 11.79"W (Reference Figure 1 ) Groundwater Incident #: Risk Classification: Reason for Risk Classification: Land Use Category: Source of Release: Date of Release Discovery: Estimated Quantity of Release: Cause of Release: Responsible Party: Property Owner 6400 (Closed) Low (No Further Action) Dissolved -phase Sulfate concentrations above groundwater quality standards (2L) Industrial/Commercial Former gasoline UST system(s) 1983 Unknown Former UST System Atlantic Richfield Company clo BP Products North America, Inc. Attn: Greg Frisch 4850 East 4Vh Street MBC-3 Room 155C Cuyahoga Heights, Ohio 44125 (216) 416-1232 Mr. Charles Sherren Thruway Shopping Center, LLC. 7501 Wisconsin Ave., Suite 1500 Bethesda, Maryland, 20814 (301) 986-2925 ext. 215 , a Professional Engineer for Arcadis G&M of North Ih the information contained in this report is correct and accurate to the test of G&M of North Carolina, Inc. is licensed to practice geology and engineering in iljfatlon numbers of the company are C-155 (geology) and C-1869 (engineering). ES-2 1st Semi -Annual Monitoring Report - 2019 CONTENTS 1.0 Site History and Characterization .... 2.0 Groundwater Monitoring ................... 2.1 Groundwater Gauging ............... 2.2 Groundwater Sampling .............. 2.3 Groundwater Analytical Results 3.0 Site Remediation .............................. 3.1 Remediation Activities to Date... 4.0 Conclusions and Recommendations TABLES Table 1. Monitoring Well Construction Data Table 2. Groundwater Elevation Data Table 3. Summary of Groundwater Analytical Data FIGURES Figure 1. Site Location Map Figure 2. Site Map Figure 3. Potentiometric Surface Map - March 15, 2019 Figure 4. Groundwater Analytical Data - September 2017 - March 2019 Figure 5. Sulfate Isoconcentration Map - March 15, 2019 APPENDICES A- Historical Groundwater Elevation Data B- Laboratory Analytical Report and Chain -of -Custody Record — March 28, 2019 C- Historical Groundwater Analytical Data 5 7 7 7 7 8 8 9 arcadis.com ES-3 1s' Semi -Annual Monitoring Report - 2019 EXECUTIVE SUMMARY On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina, Inc. (Arcadis) personnel performed the semi-annual groundwater sampling of groundwater monitoring wells associated with Former BP Facility #24163 located at 381 Knollwood Street, in Winston-Salem, Forsyth County, North Carolina (the Site) on March 15, 2019. All groundwater monitoring activities were conducted in response to the final project evaluation requirement specified in Part VI I, Item 5 of the Renewal Issuance of Injection Permit W10400198 from the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Quality — Aquifer Protection Section in April 2013. On March 15, 2019, Arcadis completed a semi-annual groundwater monitoring and sampling event at the Site. Two (2) groundwater monitoring wells (MW-8R and MW-19) were gauged to determine the depth to water (DTW). DTW ranged from 12.22 feet below top of casing (btoc) in groundwater monitoring well MW- 19 to 13.35 feet btoc in groundwater monitoring well MW-8R. The historical groundwater flow direction for the Site is towards the southeast. On March 15, 2019, groundwater samples were collected from groundwater monitoring wells MW-8R and MW-19. The maximum concentrations of selected dissolved -phase COCs found during the March 15, 2019 sampling events are summarized in the table below: Maximum Groundwater Concentrations (March 15, 2019) Chemical of Monitoring Well Concentration North Carolina Concern ID (mg/L) Groundwater (COC) Quality (2L) Standards Sulfate MW-19 1,150 250 Note: Concentration in Bold exceeds the applicable North Carolina GCL Standard mg/L: milligrams per liter Dissolved phase sulfate concentrations decreased compared to historical groundwater analytical data. Dissolved phase sulfate was detected above the applicable North Carolina Groundwater Quality (2L) Standard at groundwater monitoring well MW-19, only. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for September 2019. Groundwater monitoring wells MW-8R and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-8R, and MW-19 for analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2019 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com ES-4 15t Semi -Annual Monitoring Report - 2019 1.0 SITE HISTORY AND CHARACTERIZATION Former BP Facility #24163 is located at 381 Knollwood Street, Winston-Salem, Forsyth County, North Carolina (the Site). The Site is currently owned by Thruway Shopping Center, LLC. and serves as a parking lot adjacent to surrounding retail stores. The site property is approximately 0.5 acres, covered by asphalt and concrete, and was formerly developed as a retail fueling station which housed gasoline, diesel, waste oil, and kerosene Underground Storage Tanks (USTs). A site location map is presented as Figure 1 and a site map is shown as Figure 2. The North Carolina Department of Environmental Quality (NCDEQ) issued groundwater incident number 6400 due to a subsurface release of gasoline that occurred on or before September 14, 1983 from a ruptured product line associated with the UST system. The quantity of the release remains unknown. One (1) 10,000-gallon steel gasoline UST, three (3) 6,000-gallon steel gasoline USTs, and one (1) 10,000-gallon steel diesel UST were removed from the site in 1990. Three (3) 10,000-gallon gasoline USTs, one (1) 10,000-gallon diesel UST, and one (1) 550-gallon waste oil UST were subsequently installed at the site and the site was purchased by M. M. Fowler, Inc. in January 1994 and continued operation until 2004. The remaining five USTs were removed before 2005 and the site was razed. Site geology and hydrogeology include surficial deposits immediately underlying the site are described generally as sandy silts that grade upward to clayey silts and silty clays. Bedrock beneath the site is mapped as a strongly foliated biotite gneiss and schist. The maximum depth of investigation at the site has been approximately 55 feet below ground surface (bgs); bedrock has not been encountered during site investigation work. Historically, the range for shallow groundwater beneath the site is approximately 11 to 14 feet bgs, and groundwater flow direction is toward the southeast with an apparent horizontal gradient of approximately 0.012 feet per foot (ft/ft). The calculated groundwater seepage velocity for shallow groundwater beneath the site is approximately 2.8 feet per year. Two activated sodium persulfate injections were performed at the Site on June 4 — 9, 2012 and June 3 — 6, 2013 under Underground Injection Control (UIC) Permit #W10400198 which was issued by the NCDEQ Division of Water Quality on August 9, 2011. Approximately 11,237-gallons of sodium persulfate and 6,826-gallons of sodium persulfate were injected at the Site on June 4 — 9, 2012 and June 3 — 6, 2013, respectively. The NCDEQ Risk Classification for this site was reduced to "Low" on January 23, 2015 after issuing a request for Notice of Residual Petroleum (NORP). The NORP was recorded with the Forsyth County Register of Deeds on March 18, 2015 and imposed the following perpetual restriction on the Site property: • Groundwater: Groundwater from the site is prohibited from use as a water supply. Water supply wells of any kind shall not be installed or operated on the site. No Further Action (NFA) status was granted for the subject incident number by the NCDEQ on April 28, 2015. In accordance with UIC Permit #W10400198, dissolved -phase concentrations of sulfate are being monitored on a semi-annual basis at the Site. Closure of UIC Permit #W10400198 will be requested once arcadis.com 15t Semi -Annual Monitoring Report - 2019 dissolved -phase sulfate concentrations are no longer detected above the North Carolina Groundwater Quality (2L) Standards. arcadis.com 15t Semi -Annual Monitoring Report - 2019 2.0 GROUNDWATER MONITORING 2.1 Groundwater Gauging On March 15, 2019, Arcadis G&M of North Carolina, Inc. (Arcadis) personnel gauged groundwater monitoring wells MW-8R and MW-19. Gauging was conducted with a water interface probe (IP) prior to purging and sampling to determine DTB and DTW. The IP and attached tape, marked in 0.01-foot increments, were properly decontaminated before each use with Alconox soap and rinsed with distilled water. The DTW was measured from the marked survey point on the top of well casing (TOC). All measurements were recorded to the nearest 0.01-foot increment. The DTW ranged from 12.22 btoc in groundwater monitoring well MW-19 to 13.35 feet btoc in groundwater monitoring well MW-8R. Groundwater monitoring well construction details are included in Table 1. Current groundwater elevations are summarized in Table 2. Historical groundwater gauging data is provided in Appendix A. A potentiometric surface map depicting historical groundwater flow direction is provided as Figure 3. 2.2 Groundwater Sampling On March 15, 2019, groundwater monitoring wells MW-8R and MW-19 were purged of stagnant water to prepare for groundwater sampling. Prior to purging, the amount of water to be removed was calculated using the following formula: 3.1415 x r2 x (TD-DTW) x 7.481 = gallons of water (1 well volume) Where: r = radius of well (in feet) TD = total depth of well (in feet) DTW = depth to water (in feet) In order to ensure that the water in the wells after purging is representative of the water in the aquifer, a minimum of three well volumes were removed. Groundwater samples obtained from the groundwater monitoring well were collected from disposable polyethylene bailers using new nylon rope. Groundwater samples were placed in laboratory supplied containers and shipped on wet ice to TestAmerica Inc. in Nashville, Tennessee, for analysis of Sulfate (SO4) by Standard Method 9056A. Groundwater samples submitted for sulfate analysis were collected in 250-milliliter plastic bottles. The laboratory analytical report and chain -of -custody record for the March 15, 2019 groundwater sampling event is included as Appendix B. 2.3 Groundwater Analytical Results Groundwater analytical data from the March 15, 2019 groundwater sampling event indicated the following: arcadis.com 15t Semi -Annual Monitoring Report - 2019 • Dissolved -phase concentrations of sulfate were detected in concentrations exceeding the applicable North Carolina 2L Standard of 250 milligrams per liter (mg/L) in groundwater monitoring well MW-19 (1,150 mg/L). Current groundwater analytical results are presented in Table 3. Historical groundwater analytical data can be found in Appendix C. A dissolved phase concentration map is presented as Figure 4. A sulfate isoconcentration map depicting the dissolved -phase extent of sulfate exceeding the applicable 2L groundwater quality standard is presented in Figure 5. 3.0 SITE REMEDIATION 3.1 Remediation Activities to Date Summarized in the table below is a chronology of remediation activities performed at the site to date: Date Activity September 14, 1983 Subsurface release of gasoline from a ruptured product line associated with the UST system December 1990 UST systems associated with release removed; 500 tons of contaminated soil removed during UST closure 1992 Vacuum Extraction System Installed 1992 - 1994 Vacuum Extraction System Operation 1994 - 2011 Monitoring of site June 4 — 9, 2012 Activated Sodium Persulfate (ASP) injection event. Approximately 11,237-gallons of sodium persulfate injected. June 3 — 6, 2013 ASP injection event. Approximately 6,826-gallons of sodium persulfate injected. 2013 - Present Monitored Natural Attenuation arcadis.com 15t Semi -Annual Monitoring Report - 2019 4.0 CONCLUSIONS & RECOMMENDATIONS Dissolved -phase sulfate was detected above the applicable 2L groundwater quality standard for sulfate of 250 mg/L in groundwater monitoring well MW-19, only on March 15, 2019. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for September 2019. Groundwater monitoring wells MW-8R and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-8R and MW-19 for analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2019 will be submitted to the NCDEQ for review and approval within 45- days of receipt of the laboratory analytical report. arcadis.com 9 15t Semi -Annual Monitoring Report - 2019 TABLES arcadis.com 10 Table 1 Monitoring Well Construction Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Design b iat�c � 04ARCADISIfor ltancy MW-3 In Use Type II 99.03 20 2 NA - NA NA MW-5 Abandoned Type II 99.39 25.5 4 10.5 - 25.5 81.4 MW-5R In Use Type II NS 20 2 10 - 20 NA MW-6 In Use Type II 98.68 25.5 4 10.5 - 25.5 80.7 MW-6i In Use Type III 99.26 55 2 50 - 55 46.8 MW-8 Abandoned Type II 97.84 24 6 NA - NA NA MW-8R In Use Type II NS 20 2 10 - 20 NA MW-14 In Use Type II 100.44 22 4 7 - 22 85.9 MW-15 In Use Type II 99.91 22 4 7 - 22 85.4 MW-16 In Use Type II 97.42 25 2 10 - 25 79.9 MW-17 In Use Type II 100.00 22 4 7 - 22 85.5 MW-18 In Use Type II NS 20 2 10 - 20 NA MW-19 In Use Type II NS 20 2 10 - 20 NA Notes: 1. Reported in feet below grade 2. Measured in feet relative to site datum 3. Conestoga Rover and Associates, a former consultant for this Site, previously reported that no reference was found to the following wells: MW-1, MW-9, MW-10, MW-11, MW-12 or MW-13. These wells are presumed to be abandoned. 4. Monitoring wells MW-5 and MW-8 were abandoned on 5/19/2010 and replaced with monitoring wells MW-5R and MW-8R the same day. 5. Monitoring wells MW-18 and MW-19 were installated on October 25, 2011. NA = Not Applicable / Available NS = Not Surveyed TOC = Top of Casing Page 1 of 1 Table 2 Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina 04 ARC AU S Wft. $ Consaltgncy fornatu and hum assets MW-8R 3/15/2019 NS ND 13.35 0.00 NM MW-19 3/15/2019 NS ND 12.22 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Corr. GW Elev. _ (ref. point elevation) - (depth to groundwater) + (LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 LNAPL = Light non -aqueous phase liquid ND = Not Detected NM = Not Measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing Page 1 of 1 Table 3 Summary of Groundwater Analytical Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, NC Date Sampled Units Sulfate Notes: onsultEncy wid PARCADIS' Muilt.,,M 3/15/2019 3/15/2019 mg/L mg/L 60 1,150 mg/L - milligrams per liter BOLD text indicates exceendance of NC groundwater standard 2L for sulfate (250 mg/L). Page 1 of 1 FIGURES wC�' 9�a v LLo Ow a z 0. nU&A, 2I Buena �Dtiiy W RO@INNOaD RD s�� pDINGTON LN x V1Sta 3 � a x 'I n Q L3 p� SUSSEx O G TON LN N W qpi� o dT RD N N m D g�Ft 9 z GREENBRIER.RD k?x 2 -� 4Q F pIRM� u�i Rp .d 3 VINWNIA RD SSfl r950zf / a FIELDALE 1 r r �v y FOREST DR m CAROLINA CIR 1 DR 57 • L� OLDs DR N W REYN REYNOLDS rn _ ANGELO'ST $tea A iri RO GEORGIA AVE St W, g5� �a Highlands BRO ��'�NC,pp WCS1.L'xeW L y� RD w H� 1 R E RD y J a W �RRD a r x � 41��Qso a jvcx,Ar' i" RD P� ❑ a a s� oy❑ z L 09 w 158 o a rn r yE 42 A CLOVERDAL� �Q M co tA RD RD KiNNAMO _ - SITE LOCATION x ELf2AKTHAVE m Edmore S. a S ❑ ROSEWOOD AVE � n J wEsrOvER DR n 21 r Q ; w GASTON ST Hanes 3 �. �P FAIRWAY -DR rt N MAPLEWOODAVE :F 0. , /[ AV S oar pypPLEWDOD AVE W ? Q�� -"i POD ARDSLEYST LY DHVRSTAVE� Burke w p L[ 5 HAWTHORNE RD o �5 Park 1 HEALY gyp WESTRIDGERD wALKER AVE x � 8 r z t a JEFFERSONAVE x x v r o d DR Wes n ® Oaks i a CHEROKEE 5T © m COEROKEE'LN 3 a _tea a 52 � � REFERENCE: BASE MAP USGS 7.5. MIN. TOPO. QUAD., WINSTON-SALEM WEST, NC, 2016. 0 2000' 4000' w ATLANTIC RICHFIELD COMPANY a Approximate Scale: 1 in. = 2000 ft. C/O BP PRODUCTS NORTH AMERICA, INC. FORMER BP STATION 24163 w a 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 1st SEMI-ANNUAL MONITORING REPORT-2019 a E a AREA LOCATION SITE LOCATION MAP LL FIGURE D &ConsultantY ARC4 DIS Iwi'G'assmnd NORTH CAROLINA O M.H. O m LEGEND: UP 1s4g1Vo — — — PROPERTY LINE • UP • • U.P. ' ABANDONED GROUNDWATER MONITORING WELL ONCRETE` FORMER PRODUCT LINE GRASS EL CTRIC C.B. go M TER O CATCH BASIN PARKING O M.H. MAN HOLE -17 AREA LIGHT �Mi ` ® • U.P. UTILITY POLE ' F.H. FIRE HYDRANT ❑ T TELEPHONE ASPHALT TRASH ,__, LARGE MANHOLE COVER PARKING ENCLOSURE ` GROUNDWATER MONITORING WELL M W-3 METAL SHED v2 O WF — — — — — — I METAL SHED ` LINE FORMER I FORMERUST ''ILL AREA I BP SERVICE V/ I_____ J STATION NOTE: MW-18 CONCRETE YY7 PAD 1. MONITORING WELL LOCATIONS ARE APPROXIMATE. O a, o- O 2. THE SITE IS A VACANT PARKING LOT. ALL SITE FEATURES EXCEPT PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE _ MW-5R MW-14 * CHARACTERISTICS. Fmw_5 J MW-16 O F.H. y� MW-8 FORMERPUMP I l ISLAND(TYP) ` Z I FORMER MW-6i W-8R CANOPY PARKING l I Mi-19 I _ _ J FORMER DIESEL UST I L AREA MW-6 FORMERPUMP ' ISLAND(TYP) II I I CONCRETE FO ER TAN OLD 0 0 0 0 TT 0 30' 60' FORMER 0 0 0 o • CANOPY I I GRAPHIC SCALE I FORMER VENT RISERS ATLANTIC RICHFIELD COMPANY 00 C/O BP PRODUCTS NORTH AMERICA, INC. 0000 FORMER BP STATION 24163 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 1st SEMI-ANNUAL MONITORING REPORT - 2019 MW-1+ ' FORMER VENT RISERS SITE MAP O M.H. FIGURE Design&Consultancy I for natural and r-/aRCJaDIS bd@assets O M.H. O m LEGEND: UP 1s4g1Vo — — — PROPERTY LINE • UP • • U.P. ' ABANDONED GROUNDWATER MONITORING WELL ONCRETE` FORMER PRODUCT LINE GRASS EL CTRIC C.B. go M TER O CATCH BASIN PARKING O M.H. MAN HOLE -17 AREA LIGHT �Mi ` ® • U.P. UTILITY POLE ' F.H. FIRE HYDRANT ❑ T TELEPHONE ASPHALT TRASH ,__, LARGE MANHOLE COVER PARKING ENCLOSURE ` GROUNDWATER MONITORING WELL MW-3 SHEDL y (NSVD) NOT SURVEYED TO VERTICAL DATUM 2a AL DEPICTED GROUNDWATER FLOW (FT HIST W ------� METAL SHED AMSO DI ICRECTION j I • FT AMSL FEET ABOVE MEAN SEA LEVEL uuu� ` LINE FORMER I FORMERUST ''ILL AREA I BP SERVICE V/ J STATION I -- — —— NOTE: MW-18 CONCRETE YY7 PAD 1. MONITORING WELL LOCATIONS ARE APPROXIMATE. O a, o- O 2. THE SITE IS A VACANT PARKING LOT. ALL SITE FEATURES EXCEPT PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE _ MW-5R MW-14 * CHARACTERISTICS. Fmw_5 J MW-16 O F.H.y� MW-8 FORMERPUMP l ISLAND (TYP) ` Z I FORMER MW-6i W 8R CANOPY (NSVD)� l PARKING I MW-19, (NSVD) J FORMER I — DIESEL UST I ` AREA MW-6 FORMER PUMP ' ISLAND(TYP) II I I CONCRETE FO ER TAN OLD 0 0 0 0 TT 0 30' 60' FORMER 0 0 0 o • CANOPY I GRAPHIC SCALE FORMER VENT RISERS ATLANTIC RICHFIELD COMPANY C/O BP PRODUCTS NORTH AMERICA, INC. 0000 FORMER BP STATION 24163 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 1ST SEMI-ANNUAL MONITORING REPORT - 2019 MW-15 ' FORMER VENT RISERS POTENTIOMETRIC SURFACE MAP MARCH 15, 2019 O M.H. FIGURE Design&Consultancy I for natural and r-/aRCJaDIS bd@assets •�� W W 0 0 0 J J 0 Z MW-8R Date 9/20/2017 1 3/1/2018 8/20/2018 3/15/2019 SO4 797 1 677 1 436 1 60 O M.H. MW-19 Date 9/20/2017 3/1/2018 8/20/2018 3/15/2019 SO4 1,020 1 745 806 1 1,150 LEGEND: — — — PROPERTY LINE ABANDONED GROUNDWATER MONITORING WELL FORMER PRODUCT LINE C.B. CATCH BASIN O M.H. MAN HOLE AREA LIGHT • U.P. UTILITY POLE F.H. FIRE HYDRANT TELEPHONE LARGE MANHOLE COVER GROUNDWATER MONITORING WELL mg/L MILLIGRAMS PER LITER LEGEND Abbreviation Constituent 2 L SO4 Sulfate 250 NOTE: 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L 2. VALUES IN BOLD EXCEED NORTH CAROLINA 2L STANDARDS. 0 30' 60' GRAPHIC SCALE O M.H. O O UP • up 1S411V'o U.P. ONCRETE GRASS EL CTRIC PARKING M TER LEGEND: Mi -17 PROPERTY LINE ` ® ABANDONED GROUNDWATER MONITORING WELL FORMER PRODUCT LINE ' C.B. Q CATCH BASIN ASPHALT TRASH O M.H. MAN HOLE PARKING ENCLOSURE ` AREA LIGHT MW-3 METAL • U.P. UTILITY POLE F_ r — — — — — — SHED METAL SHE �Zo F H FIRE HYDRANT LU I TELEPHONE W I LARGE MANHOLE COVER I FORMER GASOLINE FORMER ` GROUNDWATER MONITORING WELL '^ V/ UST AREA I B SERVICE (1,150) SULFATE CONCENTRATION (mg/L) STATION 0 — — — — — MW-18 CONCRETE ` 250 ESTIMATED SULFATE CONCENTRATION CONTOUR 2L STANDARD (mg/L) O 0 PAD 0, e o` (mg/L) MILLIGRAMS PER LITER Fmw_5 MW-5R MW-14 J /S�9LO MW-16 O Z FORMERPUMP F.H. MIN l ISLAND (TYP) MW-6i W-8R (60) I FORMER CANOPY O PARKING NOTE: 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mg/L 2. SHADED VALUES EXCEED NORTH CAROLINA 2L STANDARDS. .� MW-19 lr(1,150)1 J I • FORMER — (�� I-(�I'9} DIESEL UST MW-6 AREA FORMER PUMP ISLAND(TYP) II I I CONCRETE FO ER TAN OLD 0 0 0 0 TT 0 30' 60' FORMER 0 0 0 o CANOPY I GRAPHIC SCALE FORMER VENT RISERS ATLANTIC RICHFIELD COMPANY 00 C/O BP PRODUCTS NORTH AMERICA, INC. p000 FORMER BP STATION 24163 381 KNOLLWOOD ST., WINSTON-SALEM, NORTH CAROLINA 1ST SEMI-ANNUAL MONITORING REPORT - 2019 MW-15 ' FORMER VENT RISERS SULFATE ISOCONCENTRATION MAP MARCH 15, 2019 O M.H. FIGURE Design&Consultancy I r /aRCICOIS Porftmseland 5 bd@assets APPENDIX A Historical Groundwater Elevation Data Appendix A rn Historical Groundwater Elevation Data. /aRCJaDIS tarnatur�tana Former BP Service Station No. 24163 e� tafs 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina 06/24/93 ND 13.89 0.00 85.14 * 08/23/94 ND 14.36 0.00 84.67 * 03/21/95 ND 13.58 0.00 85.45 * 08/05/96 ND 13.54 0.00 85.49 11/17/98 ND 14.09 0.00 84.94 06/19/01 ND 14.11 0.00 84.92 09/12/01 ND 14.41 0.00 84.62 12/27/01 ND 14.51 0.00 84.52 03/05/02 ND 14.29 0.00 84.74 05/13/03 ND 14.35 0.00 84.68 12/09/03 ND 13.63 0.00 85.40 03/23/06 ND 13.64 0.00 85.39 05/08/07 ND 13.40 0.00 85.63 05/14/08 ND 13.42 0.00 85.61 05/28/09 ND 13.31 0.00 85.72 05/27/10 ND 13.07 0.00 85.96 10/31/11 ND 13.87 0.00 85.16 MW-3 99.03 05/22/12 ND 13.55 0.00 85.48 06/14/12 ND 13.53 0.00 85.50 07/09/12 ND 13.98 0.00 85.05 08/14/12 ND 14.24 0.00 84.79 09/19/12 ND 14.08 0.00 84.95 12/05/12 ND 14.42 0.00 84.61 02/26/13 ND 13.55 0.00 85.48 05/31/13 ND 13.58 0.00 85.45 08/28/13 ND 13.57 0.00 85.46 11/07/13 ND 14.30 0.00 84.73 02/27/14 ND 13.28 0.00 85.75 06/02/14 ND 13.34 0.00 85.69 10/16/14 ND 14.18 0.00 84.85 04/23/15 ND 13.54 0.00 85.49 04/28/16 ND 13.51 0.00 85.52 09/19/16 ND 13.92 0.00 85.11 03/03/17 ND NM 0.00 NM 06/24/93 ND 13.51 0.00 85.88 08/23/94 ND 13.82 0.00 85.57 03/21/95 ND 13.71 0.00 85.68 08/05/96 ND 13.54 0.00 85.85 11/17/98 ND 14.08 0.00 85.31 06/19/01 NM _ NM NM NM 09/12/01 ND 14.46 0.00 84.93 MW-5 12/27/01 99.39 14.51 15.07 0.56 84.73 03/05/02 14.45 14.88 0.43 84.82 05/12/03 NM NM NM NM 12/09/03 13.18 13.60 0.42 86.10 03/23/06 ND 13.67 0.00 85.72 05/08/07 ND 13.45 0.00 85.94 05/14/08 ND 13.51 0.00 85.88 05/28/09 ND 13.39 0.00 86.00 Page 1 of 5 Appendix A rn Historical Groundwater Elevation Data. /aRCJaDIS tarnatur�tana Former BP Service Station No. 24163 e� tafs 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina 05/27/10 ND 13.70 0.00 NM 10/31/11 ND 13.97 0.00 NM 05/22/12 ND 13.66 0.00 NM 06/14/12 ND 13.73 0.00 NM 07/09/12 ND 14.18 0.00 NM 08/14/12 ND 14.45 0.00 NM 09/19/12 ND 14.35 0.00 NM 12/05/12 ND 14.68 0.00 NM 02/26/13 ND 13.89 0.00 NM 05/31/13 ND 13.77 0.00 NM 08/28/13 ND 13.83 0.00 NM MW-5R 11/07/13 NS ND 14.53 0.00 NM 02/27/14 ND 13.39 0.00 NM 06/02/14 ND 13.47 0.00 NM 10/16/14 ND 14.32 0.00 NM 04/23/15 ND 13.69 0.00 NM 10/13/15 ND 14.19 0.00 NM 04/28/16 ND 13.61 0.00 NM 09/19/16 ND 13.99 0.00 NM 03/03/17 ND 14.01 0.00 NM 09/20/17 ND 13.67 1.00 NM 03/01/18 ND 13.62 0.00 NM 08/20/18 ND 13.61 0.00 NM 06/24/93 ND 12.31 0.00 86.37 08/23/94 ND 12.61 0.00 86.07 03/21/95 ND 13.15 0.00 85.53 08/05/96 ND 12.39 0.00 86.29 11/17/98 ND 13.16 0.00 85.52 06/19/01 NM NM NM NM 09/12/01 ND 13.51 0.00 85.17 12/27/01 ND 13.61 0.00 85.07 03/05/02 ND 11.02 0.00 87.66 MW-6 98.68 05/12/03 ND 11.10 0.00 87.58 12/09/03 ND 13.49 0.00 85.19 03/23/06 ND 11.79 0.00 86.89 05/08/07 ND 12.50 0.00 86.18 05/14/08 ND 12.16 0.00 86.52 05/28/09 ND 10.64 0.00 88.04 05/27/10 ND 11.84 0.00 86.84 10/31/11 ND 12.95 0.00 85.73 06/02/14 ND 12.38 0.00 86.30 06/24/93 ND NM 0.00 _ _ NM 08/23/94 ND NM 0.00 NM 03/21/95 ND 14.75 0.00 84.51 08/05/96 ND 14.13 0.00 85.13 11/17/98 ND 14.09 0.00 85.17 06/19/01 ND 18.07 0.00 81.19 09/12/01 ND 16.60 0.00 82.66 12/27/01 ND 14.61 0.00 84.65 03/05/02 ND 14.96 0.00 84.30 MW-61 05/12/03 99.26 ND 15.17 0.00 84.09 12/09/03 ND 13.55 0.00 85.71 03/23/06 ND 13.55 0.00 85.71 05/08/07 ND 12.93 0.00 86.33 05/14/08 ND 13.22 0.00 86.04 05/28/09 ND 13.39 0.00 85.87 05/27/10 ND 13.23 0.00 86.03 10/31/11 ND 13.90 0.00 85.36 06/02/14 ND 13.35 0.00 85.91 04/28/16 ND 13.55 0.00 85.71 Page 2 of 5 Appendix A /��V1D� a 5 Historical Groundwater Elevation Data tir��u�ia�a�� Former BP Service Station No. 24163 a�u.. 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina 08/23/94 ND 12.14 0.00 85.70 03/21/95 ND 12.02 0.00 85.82 08/05/96 ND 11.99 0.00 85.85 11/17/98 ND 12.53 0.00 85.31 06/19/01 NM NM NM NM 09/12/01 ND 12.67 0.00 85.17 12/27/01 14.47 15.03 0.56 83.26 MW 8 97.84 03/05/02 12.42 12.60 0.18 85.38 05/12/03 NM NM NM NM 12/09/03 13.32 13.56 0.24 84.47 03/23/06 ND 12.15 0.00 85.69 05/08/07 ND 11.90 0.00 85.94 05/14/08 ND 11.95 0.00 85.89 05/28/09 ND 11.70 0.00 86.14 05/27/10 ND 12.97 0.00 NM 10/31/11 ND 13.34 0.00 NM 05/22/12 ND 13.69 0.00 NM 06/14/12 ND 14.94 0.00 NM 07/09/12 ND 14.08 0.00 NM 08/14/12 ND 14.29 0.00 NM 09/19/12 ND 14.08 0.00 NM 12/05/12 ND 14.53 0.00 NM 02/26/13 ND 13.80 0.00 NM 05/31/13 ND 13.61 0.00 NM 08/28/13 ND 13.74 0.00 NM 11/07/13 ND 14.42 0.00 NM MW-8R NS 02/27/14 ND 13.33 0.00 NM 06/02/14 ND 13.34 0.00 NM 10/16/14 ND 14.18 0.00 NM 04/23/15 ND 13.57 0.00 NM 10/13/15 ND 14.08 0.00 NM 04/28/16 ND 13.53 0.00 NM 09/19/16 ND 13.91 0.00 NM 03/03/17 ND 13.92 0.00 NM 09/20/17 ND 13.61 0.00 NM 03/01/18 ND 13.63 0.00 NM 08/20/18 ND 13.52 0.00 NM 03/15/19 ND 13.35 0.00 NM 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 13.55 0.00 86.89 08/05/96 ND 13.64 0.00 86.80 11/17/98 ND 14.26 0.00 86.18 06/19/01 ND 14.55 0.00 85.89 09/12/01 ND 14.81 0.00 85.63 12/27/01 ND 14.85 0.00 85.59 03/05/02 ND 14.64 0.00 85.80 MW-14 05/12/03 100.44 ND 13.41 0.00 87.03 12/09/03 ND 13.51 0.00 86.93 03/23/06 ND 13.82 0.00 86.62 05/08/07 ND 13.54 0.00 86.90 05/14/08 ND 13.64 0.00 86.80 05/28/09 ND 13.47 0.00 86.97 05/27/10 ND 13.00 0.00 87.44 10/13/11 ND 14.14 0.00 86.30 06/02/14 ND 13.42 0.00 87.02 04/28/16 ND 13.65 0.00 86.79 Page 3 of 5 Appendix A rn Historical Groundwater Elevation Data. /aRCJaDIS tarnatur�tana Former BP Service Station No. 24163 e� tafs 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.83 0.00 87.08 08/05/96 ND 12.77 0.00 87.14 11/17/98 ND 13.58 0.00 86.33 06/19/01 ND 13.80 0.00 86.11 09/12/01 ND 14.18 0.00 85.73 12/27/01 ND 14.29 0.00 85.62 03/05/02 ND 13.98 0.00 85.93 05/12/03 NM 12.75 NM 87.16 MW-15 9991 12/09/03 ND 12.89 0.00 87.02 03/23/06 ND 13.14 0.00 86.77 05/08/07 ND 12.90 0.00 87.01 05/14/08 ND 13.12 0.00 86.79 05/28/09 ND 12.90 0.00 87.01 05/27/10 ND 12.25 0.00 87.66 10/31/11 ND 13.61 0.00 86.30 06/02/14 ND 12.82 0.00 87.09 10/16/14 ND 13.91 0.00 86.00 04/28/16 ND 13.15 0.00 86.76 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.06 0.00 85.36 08/05/96 ND 12.09 0.00 85.33 11/17/98 ND 12.60 0.00 84.82 06/19/01 ND 12.74 0.00 84.68 09/12/01 ND 12.98 0.00 84.44 12/27/01 NM NM NM NM 03/05/02 ND 12.83 0.00 84.59 MW-16 05/12/03 97.42 NM NM NM NM 12/09/03 ND 12.13 0.00 85.29 03/23/06 ND 12.18 0.00 85.24 05/08/07 NM NM NM NM 05/14/08 ND 12.03 0.00 85.39 05/28/09 ND 11.96 0.00 85.46 05/27/10 ND 11.69 0.00 85.73 10/31/11 ND 12.45 0.00 84.97 11/07/13 ND 12.88 0.00 84.54 06/02/14 ND 11.97 0.00 85.45 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 14.42 0.00 85.58 08/05/96 ND 14.46 0.00 85.54 11/17/98 ND 14.91 0.00 85.09 06/19/01 ND 15.03 0.00 84.97 09/12/01 ND 15.28 0.00 84.72 12/27/01 ND 15.37 0.00 84.63 03/05/02 ND 15.15 0.00 84.85 05/12/03 NM 14.15 NM 85.85 MW-17 100.00 12/09/03 ND 14.50 0.00 85.50 03/23/06 ND 14.45 0.00 85.55 05/08/07 ND 14.22 0.00 85.78 05/14/08 ND 14.22 0.00 85.78 05/28/09 ND 14.12 0.00 85.88 05/27/10 ND 13.90 0.00 86.10 10/31/11 ND 14.72 0.00 85.28 06/02/14 ND 14.14 0.00 85.86 04/28/16 ND 14.36 0.00 85.64 Page 4 of 5 Appendix A rn Historical Groundwater Elevation Data. /aRCJaD I S tarnatu 31ana Former BP Service Station No. 24163 e� tafs 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina -.-. , • •, 10/31/11 ND 13.95 0.00 NM 05/22/12 ND 14.10 0.00 NM 06/14/12 ND 13.61 0.00 NM 07/09/12 ND 14.05 0.00 NM 08/14/12 ND 14.43 0.00 NM 09/19/12 ND 14.34 0.00 NM 12/05/12 ND 14.62 0.00 NM 02/26/13 ND 14.67 0.00 NM 05/31/13 ND 14.57 0.00 NM 08/28/13 ND 14.33 0.00 NM 11/07/13 ND 14.51 0.00 NM MW-18 NS 02/27/14 ND 13.76 0.00 NM 06/02/14 ND 13.55 0.00 NM 10/16/14 ND 14.37 0.00 NM 04/23/15 ND 13.84 0.00 NM 10/13/15 ND 14.81 0.00 NM 04/28/16 ND 13.62 0.00 NM 09/19/16 ND 14.04 0.00 NM 03/03/17 ND 14.08 0.00 NM 09/20/17 ND 13.21 0.00 NM 03/01/18 ND 13.60 0.00 NM 08/20/18 ND 13.42 0.00 NM 10/31/11 ND 13.75 0.00 NM 05/22/12 ND 13.37 0.00 NM 06/14/12 ND 13.39 0.00 NM 07/09/12 ND 13.89 0.00 NM 08/14/12 ND 14.13 0.00 NM 09/19/12 ND 14.02 0.00 NM 12/05/12 ND 14.39 0.00 NM 02/26/13 ND 13.62 0.00 NM 05/31/13 ND 13.47 0.00 NM 08/28/13 ND 13.56 0.00 NM 11/07/13 ND 14.25 0.00 NM MW-19 02/27/14 NS ND 13.17 0.00 NM 06/02/14 ND 13.14 0.00 NM 10/16/14 ND 14.03 0.00 NM 04/23/15 ND 13.46 0.00 NM 10/13/15 ND 14.01 0.00 NM 04/28/16 ND 13.38 0.00 NM 09/19/16 ND 13.75 0.00 NM 03/03/17 ND 13.79 0.00 NM 09/20/17 ND 13.48 0.00 NM 03/01/18 ND 13.42 0.00 NM 08/20/18 ND 13.38 0.00 NM 03/15/19 ND 12.22 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Corr. GW Elev. _ (ref. point elevation) - (depth to groundwater) + (LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 * - Prior to URS' work at this Site, monitoring well MW-3 has previously been reported as MW-2, monitoring well MW-6 has previously been reported as MW-8, and monitoring well MW-8 has previously been reported as MW-6. LNAPL = Light non -aqueous phase liquid ND = Not detected NM = Not measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing - During the May 2003 sampling event LNAPL was observed in MW-5. Depth to groundwater and thickness of LNAPL were not measured. Page 5 of 5 APPENDIX B Laboratory Analytical Report and Chain -of -Custody Record — March 28, 2019 TestAmerica THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel: (615)726-0177 TestAmerica Job ID: 490-170333-1 TestAmerica SDG: 381 Knollwood St. Winston-Salem, North Carolina Client Project/Site: Former BP Facility #24163 For: ARCADIS U.S., Inc. 5420 Wade Park Boulevard Suite 350 Raleigh, North Carolina 27607 Attn: Paul Goodell ie"ma..�, Authorized for release by. 3/28/2019 11:22:45 PM Jennifer Huckaba, Project Manager II (615)301-5042 jennifer.huckaba@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-170333-1 F Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St. Winston-Salem, North Carolina Table of Contents CoverPage .............................................. 1 Table of Contents ......................................... 2 Sample Summary ......................................... 3 Case Narrative ........................................... 4 Definitions............................................... 5 Client Sample Results ...................................... 6 QC Sample Results ........................................ 8 QC Association ........................................... 9 Chronicle ................................................ 10 Method Summary ......................................... 11 Certification Summary ...................................... 12 Chain of Custody .......................................... 13 TestAmerica Nashville Page 2 of 14 3/28/2019 Sample Summary Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-170333-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St. Winston-Salem, North Carolina Lab Sample ID Client Sample ID Matrix Collected Received 490-170333-1 MW-8R Water 03/15/19 10:30 03/16/19 09:40 490-170333-2 MW-19 Water 03/15/19 10:00 03/16/19 09:40 TestAmerica Nashville Page 3 of 14 3/28/2019 Case Narrative C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-170333-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St. Winston-Salem, North Carolina Job ID: 490-170333-1 Laboratory: TestAmerica Nashville Narrative Job Narrative 490-170333-1 Comments No additional comments. Receipt The samples were received on 3/16/2019 9:40 AM; the samples arrived in good condition, properly preserved and, where required, on ice The temperature of the cooler at receipt was 2.00 C. HPLC/IC Method(s) 9056A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for 490-583274 were within the acceptance limits for sulfate. However, the sample results exceeded the calibration curve limits: (490-170333-A-1 MS) and (490-170333-A-1 MSD). No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. TestAmerica Nashville Page 4 of 14 3/28/2019 Definitions/Glossary Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-170333-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St. Winston-Salem, North Carolina Qualifiers HPLCAC Qualifier Qualifier Description 4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. E Result exceeded calibration range. Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. tt Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TestAmerica Nashville Page 5 of 14 3/28/2019 Client Sample Results Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-8R Date Collected: 03/15/19 10:30 Date Received: 03/16/19 09:40 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier RL Sulfate 60.0 10.0 TestAmerica Job ID: 490-170333-1 SDG: 381 Knollwood St. Winston-Salem, North Carolina Lab Sample ID: 490-170333-1 Matrix: Water MDL Unit D Prepared mg/L Analyzed Dil Fac 03/26/19 07:06 10 TestAmerica Nashville Page 6 of 14 3/28/2019 Client Sample Results Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-19 Date Collected: 03/15/19 10:00 Date Received: 03/16/19 09:40 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier RL Sulfate 1150 50.0 TestAmerica Job ID: 490-170333-1 SDG: 381 Knollwood St. Winston-Salem, North Carolina Lab Sample ID: 490-170333-2 Matrix: Water MDL Unit D Prepared mg/L Analyzed Dil Fac 03/26/19 07:41 50 TestAmerica Nashville Page 7 of 14 3/28/2019 QC Sample Results C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-170333-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St. Winston-Salem, North Carolina Method: 9056A - Anions, Ion Chromatography Lab Sample ID: MB 490-583274/3 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 583274 L MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Sulfate ND 1.00 mg/L 03/26/19 05:29 1 Lab Sample ID: LCS 490-583274/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 583274 Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Sulfate 5.01 4.533 mg/L 91 80 -120 Lab Sample ID: LCSD 490-583274/5 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 583274 Spike LCSD LCSD %Rec. RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 5.01 4.533 mg/L 91 80 -120 0 20 Lab Sample ID: 490-170333-1 MS Client Sample ID: MW-8R Matrix: Water Prep Type: Total/NA Analysis Batch: 583274 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 75.8 E 5.01 81.70 E 4 mg/L 118 80 -120 Lab Sample ID: 490-170333-1 MSD Client Sample ID: MW-8R Matrix: Water Prep Type: Total/NA Analysis Batch: 583274 Sample Sample Spike MSD MSD %Rec. RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 75.8 E 5.01 81.55 E 4 mg/L 115 80 -120 0 20 TestAmerica Nashville Page 8 of 14 3/28/2019 QC Association Summary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 HPLC/IC Analysis Batch: 583274 Lab Sample ID 490-170333-1 490-170333-2 MB 490-583274/3 LCS 490-583274/4 LCSD 490-583274/5 490-170333-1 MS 490-170333-1 MSD TestAmerica Job ID: 490-170333-1 SDG: 381 Knollwood St. Winston-Salem, North Carolina Client Sample ID Prep Type Matrix Method MW-8R Total/NA Water 9056A MW-19 Total/NA Water 9056A Method Blank Total/NA Water 9056A Lab Control Sample Total/NA Water 9056A Lab Control Sample Dup Total/NA Water 9056A MW-8R Total/NA Water 9056A MW-8R Total/NA Water 9056A Prep Batch 0 TestAmerica Nashville Page 9 of 14 3/28/2019 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-8R Date Collected: 03/15/19 10:30 Date Received: 03/16/19 09:40 Lab Chronicle C TestAmerica Job ID: 490-170333-1 SDG: 381 Knollwood St. Winston-Salem, North Carolina Lab Sample ID: 490-170333-1 Matrix: Water Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analvsis 9056A 10 583274 03/26/19 07:08 SW1 TAL NSH Client Sample ID: MW-19 Lab Sample ID: 490-170333-2 Date Collected: 03/15/19 10:00 Matrix: Water Date Received: 03/16/19 09:40 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056A 50 583274 03/26/19 07:41 SW1 TAL NSH Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 0 L Page 10 of 14 TestAmerica Nashville 3/28/2019 Method Summary C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-170333-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St. Winston-Salem, North Carolina Method Method Description Protocol Laboratory 9056A Anions, Ion Chromatography SW846 TAL NSH Protocol References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 TestAmerica Nashville Page 11 of 14 3/28/2019 Accreditation/Certification Summary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 TestAmerica Job ID: 490-170333-1 SDG: 381 Knollwood St. Winston-Salem, North Carolina Laboratory: TestAmerica Nashville All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program EPA Region Identification Number Expiration Date A2LA ISO/IEC 17025 0453.07 12-31-19 Alaska (UST) State Program 10 UST-087 06-30-19 Arizona State Program 9 AZ0473 05-05-19 Arkansas DEQ State Program 6 88-0737 04-25-19 California State Program 9 2938 06-30-19 Connecticut State Program 1 PH-0220 12-31-19 Florida NELAP 4 E87358 06-30-19 Georgia State Program 4 NA: NELAP & A2LA 12-31-19 Illinois NELAP 5 200010 12-09-18' Iowa State Program 7 131 04-01-20 Kansas NELAP 7 E-10229 10-31-19 Kentucky (UST) State Program 4 19 06-30-19 Kentucky (WW) State Program 4 90038 12-31-19 Louisiana NELAP 6 30613 06-30-19 Maine State Program 1 TN00032 11-03-19 Maryland State Program 3 316 03-31-20 Massachusetts State Program 1 M-TN032 06-30-19 Minnesota NELAP 5 047-999-345 12-31-19 Mississippi State Program 4 N/A 06-30-19 Nevada State Program 9 TN00032 07-31-19 New Hampshire NELAP 1 2963 10-09-19 New Jersey NELAP 2 TN965 06-30-19 New York NELAP 2 11342 03-31-19 North Carolina (WW/SW) State Program 4 387 12-31-19 North Dakota State Program 8 R-146 06-30-19 Ohio VAP State Program 5 CL0033 07-06-19 Oklahoma State Program 6 9412 08-31-19 Oregon NELAP 10 TN200001 04-26-19 Pennsylvania NELAP 3 68-00585 07-31-19 Rhode Island State Program 1 LAO00268 12-30-19 South Carolina State Program 4 84009 (001) 02-28-19 " Tennessee State Program 4 2008 02-23-20 Texas NELAP 6 T104704077 08-31-19 USDA Federal P330-13-00306 12-01-19 Utah NELAP 8 TN00032 07-31-19 Virginia NELAP 3 460152 06-14-19 Washington State Program 10 C789 07-19-19 West Virginia DEP State Program 3 219 02-28-19' Wisconsin State Program 5 998020430 08-31-19 Wyoming (UST) A2LA 8 453.07 12-31-19 " Accreditation/Certification renewal pending - accreditation/certification considered valid. TestAmerica Nashville Page 12 of 14 3/28/2019 Test medca THE LEADER IN ENVIRONIv1ENTAL TESTING Nashville, TN COOLER RECEIPT FORM 490-170333 Chain of Custody Cooler Received/Opened On 03-16-2019_@_09:40 1 11r/ Time Samples Removed From Cooler is Time Samples Placed In Storage ` Iv (2 Hour Window) 1. Tracking # ( (last 4 digits, FedEx) Courier: _FedEx_ IR Gun ID_31470368 pH Strip Lot1Y1114 Chlorine Strip Lot 2. Temperature of rep. sample or temp blank when opened:""% - D Degrees Celsius 3. If Item #2 temperature is 0°C or less, was the representative sample or temp blank rozen? YY/E''S�� NO...O 4. Were custody seals on outside of cooler? KES..NO... NA If yes, how many and where: %d" 5. Were the seals intact, signed, and dated correctly? 6E.. N0...NA 6. Were custody papers inside cooler? NO NA I certify that I opened the cooler and answered questions 1-6 (intial) 7. Were custody seals on containers: YES 490 and Intact YES ... NO..(!!� Were these signed and dated correctly? YES ... NO.. 1& 8. Packing mat'I used? bble p PlasticbagPeanuts Vermiculite Foam Insert Paper Other None 9. Cooling process: -lee Ice -pack Ice (direct contact) Dry ice Other None 10. Did all containers arrive in good condition (unbroken)? ..NO ... NA 11. Were all container labels complete (#, date, signed, pres., etc)? &...NO ... NA 12, Did all container labels and tags agree with custody papers? FS.?.NO... NA 13a. Were VOA vials received? YES..(...NA b. Was there any observable headspace present in any VOA vial? YES ... NO. & AMIL UP 40 Larger than this. 14. Was there a Trip Blank in this cooler? YES... 61NA If multiple coolers, sequence # I certify that I unloaded the cooler and answered questions 7-14 (intial) 15a. On pres'd bottles, did pH test strips suggest preservation reached the correG pH level? YES ... NO.,ddZA b. Did the bottle labels indicate that the correct preservatives were used )?S... NO ... NA 16. Was residual chlorine present? YES ... NO ... to I certify that I checked for chlorine and pH as per SOP and answered questions 15-16 (intial) �! 17. Were custody papers properly filled out (ink, signed, etc)? /rrSNO ..NA 18. Did you sign the custody papers in the appropriate place? � ... . NO ... NA 19. Were correct containers used for the analysis requested? �...NO...NA 20. Was sufficient amount of sample sent in each container? ... NO ... NA I certify that 1 entered this project into LIMS and answered questions 17-20 (intial) / l 1 certifv that I attached a label with the unique LIMS number to each container (intial) 21. Were there Non -Conformance issues at login? YES...t t) Was a NCM §enerated? YES. ... # B1S = Broken in shipment Cooler Receipt Fonn.doc LF-1 End of Fonn Revised 8/23/17 I i 3/28/2019 Page 13 of 14 CD O W N of N O Loc: 490 170333 %stAmer ica Nash "A�' Creighton Creighton 177 Phoee:800-765-0980 Faster 2960 Foster Toll Free: 800-768.0980 THE LEADER IN ENVIRONMENTAL TESTING Nashville, TN 37204 Fax: 615-726-3404 Consultant Name: ARCADIS TA Account#: PO#: Address: 111-D Sanders Lane Invoice To: ACCOUNTSPAYABLE ADMINISTRATION(a�ARCADIS-US.COM City/Statelzp: BLUEFIELD, VA 24605 Report To: Paul Goodell Consultant Project Mgr. Paul Goodell Project Name: Former RP Facility 424163 Consultant Telephone Number. 919-4152327 Fax No.: 276-322-3946 Retail # (MRN #): 24163 Sampler Name: (Print) - "Wl'L;.'1t '. s.. Major Project (AFE#): Sampler Signature: Site Address 381 Knolhwocd St 2J City, State, rip Winston-Salem, North Carolina Regulatory District (CA) - N ❑ a. y @ N a w E 6 o $- o y z o = z N F = F- x OA m Sample ID or Field ID ❑ F- Q U - U� i — O y ¢ LL ❑' ji 01V MW-8R 1 x 1 x MW-19� / 1 x 1 x Comments/Special Instructions: Laboratory Comments: �j( Temperature Upon Receipt of /� 9 Sample Containers Intact? N VOCs Free of Headspace? Y N QC Deliverables (please cimla one) Level Levc13 Level4 Other Rey ish ® Date Time C Received by: Date Tme y _i j P7 f/ Relirga ed by Date Time Received by: Date Time tf ' It Ail be the responsibility of BP or its ca consultantto notifythe TestAmeriProject Manager by ph --fax that a rush sample willbe submitted. Relinquished by: Date Time Received by TestA dca: Date 34w �) .� Tme lC;,,//"J 1�l f (J TA Project Manager. Date: 7� APPENDIX C Historical Groundwater Analytical Data Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina P ARCADIS (ornaturalanA hullr assets NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE NC 2L 1 600 600 500 20 250 NE Units: Ng/I Ng/I Ng/I Ng/I Ng/I mg/I mg/I 5/13/2003 8.5 0.98 J 0.61 J 1.7 J 8 12/9/2003 47.4 14.3 1.9 8.1 37.3 3/23/2006 4.5 J < 0.5 < 0.5 UJ < 1 UJ 5.5 5/8/2007 40.4 3.7 1.4 2 J 13.1 5/14/2008 4.3 J < 0.8 < 0.7 < 0.8 14 5/28/2009 5.4 0.44 J 0.14 J 0.49 J 5.6 5/27/2010 0.44 J < 0.11 0.3 J < 0.32 4.8 10/31/2011 5.5 0.76 < 0.17 U_ 0.38 J 19.1 8.4 405 5/22/2012 < 0.43 U < 0.2 < 0.2 < 0.52 4.6 15.3 378 6/14/2012 12.1 6.7 0.72 4.7 15.4 6.6 J 344 7/9/2012 2.2 1.6 2.6 3 14.7 9.9 393 MW-3 8/14/2012 2 2.1 < 0.13 0.4 J 17.9 3.6 303 9/19/2012 2.7 0.66 < 0.13 0.33 J 19.8 2.8 459 12/5/2012 11.3 1.2 0.43 J 1.1 J 19.3 0.78 J 377 2/26/2013 0.23 J < 0.1 < 0.1 < 0.22 5.4 32.6 338 5/31 /2013 0.32 J < 0.1 < 0.1 < 0.22 10.5 17.9 334 8/28/2013 3.6 0.53 0.12 J 0.31 J 10.3 21.9 457 11 /7/2013 4.3 0.27 J 0.13 J < 0.22 10 21.7 536 2/27/2014 < 0.1 < 0.1 < 0.1 < 0.2 1.3 42.2 198 6/3/2014 0.48 J 0.15 J < 0.1 < 0.2 3.1 10/16/2014 18.0 372 4/23/2015 22.8 296 9/19/2016 -- 21.3 3/23/2006 11,700 2,440 32,000 _ 13,500 16,100 3/23/2006 i1i 11,000 2,370 30,700 13,200 15,400 5/8/2007 7,410 1,590 21,100 8,920 8,830 5/8/2007 (1) 7,400 1,680 20,100 9,290 9,360 MW-5 5/14/2008 10,000 2,100 29,000 12,000 18,000 5/14/2008 (1) 10,000 2,100 30,000 12,000 18,000 5/28/2009 7,390 2,330 25,700 13,400 6,920 5/28/2009 (1) 6,510 2,240 22,100 12,900 6,510 5/27/2010 6,610 2,810 24,300 J 15,700 4,330 5/27/2010 (1) 6,090 2,380 30,100 J 13,300 4,250 10/31/2011 7,960 2,660 28,000 13,800 3,830 < 1 < 5 10/31/2011 (1)M 8,360 2,870 1 24,600 14,800 4,070 5/22/2012 IL 7,980 3,470 32,200 19,200 3,820 < 5 179 6/15/2012 (2) 244 227 1,190 1,120 36.9 6,070 1,820 7/9/2012 336 J 481 J 2,010 J 2,400 J 48.4 J 6,470 2,620 MW-5R 8/14/2012 201 283 1,050 1,300 48.5 14,700 4,190 9/19/2012 158 181 650 883 114 19,000 3,280 12/5/2012 754 505 2,220 2,380 1,160 13,600 1,840 2/26/2013 1,360 878 3,520 3,940 1,660 8,520 1,530 5/31/2013 1,410 1,380 5,930 6,220 1,1501 4,680 1,560 8/28/2013 165 178 489 1,380 417 13,900 1,590 11/7/2013 214 131 331 969 651 14,400 1,570 2/27/2014 142 177 328 1,060 240 2,990 807 6/2/2014 256 436 1040 2520 519 J 10/16/2014 9,950 1,390 4/23/2015 5,980 1,510 10/13/2015 5,790 4/28/2016 2,980 MW-5R 9/19/2016 - 2,880 3/3/2017 3,570 9/20/2017 1,060 3/1 /2018 163 8/20/2018 147 Page 1 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina P ARCADIS (ornaturalanA hullr assets NC GCL: NC 2L Units: 5,000 1 Ng/I 84,500 600 Ng/I 260,000 600 Ng/I 85,500 500 Ng/I 20,000 20 Ng/I NE 250 mg/I NE NE mg/I 5/12/2003 < 0.5 0.52 J < 0.5 < 1 3 12/9/2003 2.3 0.64 J 1.1 3.6 17.6 12/9/2003 2.4 0.68 J 1.1 3.8 18 3/23/2006 0.76 J 0.59 J 3.6 2.8 J 1.1 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 MW-6 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 5/28/2009 < 0.06 < 0.05 < 0.06 < 0.14 0.17 J 5/27/2010 < 0.11 0.13 J 0.38 J 0.46 J < 0.12 10/31/2011 8.7 J 11.7 J 27.5 J 132 J < 0.26 UJ 131 2,130 6/2/2014 17.6 J 59.4 J 31.6 J 99.4 J 783 J 5/12/2003 < 0.5 < 0.5 < 0.5 1.1 J < 0.5 12/9/2003 < 2.5 < 2.5 < 2.5 < 5 < 2.5 3/23/2006 49.7 18.9 48.7 443 3,560 5/8/2007 < 25 < 25 < 25 < 50 6,910 MW-61 5/14/2008 5.2 J < 2 < 1.8 < 2 3,400 5/28/2009 2.5 < 0.05 < 0.06 < 0.14 1,150 5/27/2010 1.6 J < 1.1 < 1.1 < 3.2 492 10/31/2011 0.41 J < 0.36 < 0.32 < 0.75 122 < 1 76.1 6/2/2014 < 0.1 < 0.1 < 0.1 < 0.2 3.3 3/23/2006 671 1,340 1,230 8,100 124 5/8/2007 1,160 799 196 2,990 1,440 MW 8 5/14/2008 600 1,800 700 3,,000 190 5/28/2009 1,390 2,050 357 _3,310 1,560 5/27/2010 8,570 2,870 31,700 15,700 6,260 10/31/2011 8,000 3,180 32,100 17,200 3,170 <1 <5 5/22/2012 8,270 + 3,360 36,400 J 17,800 3,920 < 5 119 6/15/2012 (2) 726 47 J 760 242 J 96.3 J 4,760 22,200 7/9/2012 4,540 J 1,870 J 17,100 J 10,800 J 1,530 J 6,570 4,500 8/14/2012 4,370 1,610 19,300 8,780 2,000 7,010 1,560 9/19/2012 4,780 1,800 20,900 10,400 2,600 6,700 1,100 12/5/2012 7,760 2,440 31,900 13,800 4,560 2,410 635 2/26/2013 7,310 2,480 30,500 13,400 4,530 959 590 5/31/2013 6,540 , 3,040 30,500 12,500 4,200 439 437 8/28/2013 1,600 628 5,390 3,990 1,380 4,770 703 11/7/2013 1,130 329 2,440 1,830 1,770 7,460 766 MW-8R 2/27/2014 1,020 603 3,200 3,430 1,190 7,670 940 6/2/2014 1,360 J 680 J 3,510 J 3,330 J 2,110 J 6/2/20141'i 1,540 556 J 3,650 2,630 J 2,640 J 10/16/2014 3,310 883 9,070 4,990 3,910 3,560 842 4/23/2015 2,050 812 10/13/2015 1,600 4/29/2016 1,640 9/19/2016 1,330 3/3/2017 -- -- -- -- -- 1,720 -- 9/20/2017 -- 797 3/1/2018 -- 677 8/20/2018 -- 436 3/15/2019 60 5/12/2003 < 0.5 _-- < 0.5 < _-- 0.5 < 1 _ 0.5271 12/9/2003 < 0.5 < 0.5 < 0.5 < 1 5.9 3/23/2006 < 0.5 < 0.5 < 0.5 < 1 < 0.5 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 MW-14 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 5/28/2009 < 0.06 < 0.05 0.077 J < 0.14 < 0.06 5/27/2010 < 0.11 < 0.11 < 0.11 < 0.32 < 0.12 10/31/2011 <0.13 <0.15 <0.42U <0.3 <0.13 43.2 <5 6/3/2014 <0.1 <0.1 <0.1 <0.2 <0.1 Page 2 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina P ARCADIS (ornaturalanA hullr assets NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE NC 2L 1 600 600 500 20 250 NE Units: Ng/I Ng/I Ng/I Ng/I Ng/I mg/I mg/I 3/23/2006 0.63 J 2.1 < 0.5 18.6 1.6 5/8/2007 < 0.5 < 0.5 < 0.5 2.2 J < 0.5 5/14/2008 < 0.5 < 0.8 < 0.7 3.7 J < 0.5 MW-15 5/27/2010 < 0.11 < 0.11 < 0.11 < 0.32 < 0.12 10/31/2011 <0.13 <0.15 <0.13 <0.3 <0.13 <1 <5 6/3/2014 < 0.1 < 0.1 < 0.1 < 0.2 < 0.1 10/16/2014 <0.1 <0.1 <0.1 <0.2 <01 3/23/2006 < 2.5 90.8 15.8 836 2.8 J 5/14/2008 <0.5 160 15 1,600 4.1 J 5/27/2010 3.6 54.7 J 5.1 525 J 1.3 MW-16 10/31/2011 < 0.65 17.2 < 1.4 U 321 < 0.65 194 < 5 11 /7/2013 -- 55.4 < 5 6/3/2014 < 0.1 0.92 417 J < 0.1 5/13/2003 57 _25 <.7 0.5 < 0.5 < 1 69 5/13/2003 40.8 < 0.5 < 0.5 < 1 63.3 12/9/2003 6.6 0.65 J < 0.5 < 1 80.6 3/23/2006 1 < 0.5 < 0.5 < 1 58.9 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 17.4 MW-17 5/14/2008 3.7 J < 0.8 < 0.7 < 0.8 19 5/28/2009 7 < 0.05 0.076 J < 0.14 14.5 5/27/2010 5.7 < 0.11 < 0.11 < 0.32 12.4 10/31/2011 0.51 0.16 J < 0.81 U 0.57 J 8.9 < 1 422 6/3/2014 < 0.1 < 0.1 < 0.1 < 0.2 4.1 10/31/2011 3,140 998 11,100 8,950 1,140 8.2 446 5/22/2012 2,280 2,790 18,200 12,000 789 '5 307 6/15/2012 (2) 373 910 4,800 3,910 114 10,600 3,410 7/9/2012 1,730 J 2,170 J 15,000 J 9,750 J 676 J 2,300 835 8/14/2012 3,020 2,990 24,400 12,800 1,090 758 580 9/19/2012 3,190 3,090 22,600 14,000 1,240 322 542 12/5/2012 3,370 2,970 20,100 12,800 1,380 32 436 2/26/2013 2,510 2,970 10,100 8,690 1,140 13.8 500 5/31/2013 2,780 3,070 8,210 5,740 1,000 83.3 475 8/28/2013 182 368 730 1,660 139 7,850 2,230 MW-18 11/7/2013 1,140 727 4,910 3,250 694 2,640 1,370 2/27/2014 16.6 109 20.2 45.8 18.5 4,310 1,270 6/2/2014 26.2 J 125 J 37.5 J 31.6 J 37.4 J 10/16/2014 359 388 244 138 364 1,540 513 4/23/2015 780 1,100 10/13/2015 516 4/29/2016 79.4 9/19/2016 377 3/3/2017 -- -- -- -- -- 295 -- 9/20/2017 257 3/1 /2018 253 8/20/2018 173 Page 3 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina P ARCADIS (ornaturalanA hullr assets INC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: pg/I pg/I pg/I pg/I pg/I mg/I mg/I 10/31/2011 2,390 1,380 8,790 7,040 5,160 3.7 425 5/22/2012 2,700 1,560 14,200 7,940 4,880 <5 310 6/15/201212i 4,020 1,440 18,200 7,940 3,290 1,090 6,520 7/9/2012 5,130 2,910 30,400 J 16,300 5,330 232 991 8/14/2012 2,420 1,650 14,200 8,370 4,090 469 1,080 9/19/2012 2,090 1,630 12,900 8,640 3,960 260 690 12/5/2012 2,320 1,810 15,200 10,400 4,010 58.8 588 2/26/2013 2,210 1,110 10,600 6,990 3,890 169 503 5/31/2013 1,830 894 8,820 5,250 3,120 1,530 606 8/28/2013 2,710 J 1,190 J 13,100 7,420 J 3,240 J 2,660 525 11/7/2013 2,020 984 9,850 5,620 2,260 2,890 255 MW-19 2/27/2014 2,550 1,400 10,900 7,880 3,320 2,790 322 6/2/2014 2,370 1,260 11,900 7,260 2,830 10/16/2014 2,340 632 4/23/2015 2,540 514 10/13/2015 1,960 4/28/2016 1,780 9/19/2016 1,270 3/3/2017 941 9/20/2017 1,020 3/1 /2018 745 8/20/2018 806 3/15/2019 1,150 Notes: I'i Field duplicate i21Alkalinity, sulfate, and carbon dioxide samples were collected 6/14/2012 and volatile organic analysis samples were collected 6/15/12. -" - Not sampled or analyzed < - Not detected at the specified detection limit pg/I - Micrograms per Liter GCL - Gross Contamination Level 2L - North Carolina Groundwater Quality (2L) Standard J - Estimated value mg/I - Milligrams per Liter MTBE - Methyl tert-Butyl Ether NE - Not established U - Not present above the associated level; blank contamination exists UJ - Not detected and the detection limit is estimated BOLD text indicates 2L exceedance -Bold cell with green highlight indicates GCL exceedence Activated sodium persulfate injections were performed at the site from June 4, 2012, to June 9, 2012, and from June 3, 2013, to June 6, 2013. Page 4 of 4 04ARCADIS5deign&Consultancy for naturaland built assets Arcadis U.S., Inc. 111-D Sanders Lane Bluefield, Virginia 24605 Tel 276 322 3879 Fax 276 322 3946 www.arcadis.com