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HomeMy WebLinkAboutWI0400198_Semi-Annual_20160617June 17, 2016 Mr. Charles Sherren Thruway Shopping Center, LLC. 7501 Wisconsin Avenue, Suite 1500 Bethesda, Maryland, 20814 RE: Semi -Annual Report Former Knollwood Gulf Station (BP 24163) 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Injection Permit WI0400198 NCDEQ Incident No. 6400 Dear Mr. Sherren: Please find enclosed a CD containing an electronic copy of the Semi -Annual Report for the above referenced site. A CD has been sent based on your previous request for an electronic copy of reports for the site. Should you want a paper copy as well, or should you have any questions regarding this submittal, please do not hesitate to contact the undersigned at (919) 461-1285 or Jasen.Zinna@aecom.com. Sincerely, URS Corporation — North Carolina Jasen Zinna, PE Project Manager Enclosure URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Tel: 919-461-1100 Fax: 919-461-1415 June 17, 2016 UIC Program Staff DWQ — Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 DWQ — Aquifer Protection Section Winston-Salem Regional Office 585 Waughton Street Winston-Salem, NC 27107 RE: Semi -Annual Report Former Knollwood Gulf Station (BP 24163) 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Injection Permit WI0400198 NCDENR Incident No. 6400 Dear Mr. Rogers: Please find enclosed the Semi -Annual Report for the above referenced site. The report documents injection performance monitoring activities including the most recent groundwater sampling event. The enclosed report is intended to continue the semi-annual reporting schedule proposed in the site Corrective Action Plan (CAP). Should you have any questions regarding this submittal, please do not hesitate to contact the undersigned at (919) 461-1285 or Jasen.Zinna@aecom.com. Sincerely, URS Corporation — North Carolina Jasen Zinna, PE Project Manager Enclosure cc: Charles Sherren, Thruway Shopping Center, LLC (CD); ENFOS, BP (electronic); Project File (electronic) URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Tel: 919-461-1100 Fax: 919-461-1415 SEMI-ANNUAL STATUS REPORT FORMER KNOLLWOOD GULF STATION (BP 24163) 381 KNOLLWOOD STREET WINSTON-SALEM, FORSYTH COUNTY, NORTH CAROLINA INCIDENT NO.: 6400 RISK RANK: LOW LAND USE CLASSIFICATION: INDUSTRIAL/COMMERCIAL AECOM PROJECT NO.: 60486285 Prepared for: Atlantic Richfield Company (ARCO) 1�p A BP Products North America Inc. affiliated company 1114 North Court St. # 125 Medina, Ohio 44256 0 June 17, 2016 Prepared by: URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 UM Tel. 919-461-1100 Fax 919-461-1415 Table of Contents Section1 Introduction..................................................................................................................1-1 1.1 Site Description........................................................................................ 1-1 1.2 Project Background.................................................................................. 1-1 Section 2 Injection Performance Monitoring.........................................................................2-1 2.1 Groundwater Sampling Procedures......................................................... 2-1 Section 3 Results and Discussion............................................................................................... 3-1 3.1 Groundwater Sampling Results............................................................... 3-1 3.2 Performance Monitoring Discussion....................................................... 3-1 Section 4 Statement of Limitations...........................................................................................4-1 Section5 References.....................................................................................................................5-1 TABLES Table 1 Monitoring Well Construction Data Table 2 Summary of Groundwater Results Compared to Groundwater Quality Standards, April 2016 Table 3 Groundwater Field Parameter Data, April 2016 FIGURES Figure 1 Location Map Figure 2 Site Map APPENDICES Appendix A Historical Groundwater Elevation Data Appendix B Historical Groundwater Analytical Summary Appendix C Laboratory Analytical Report Appendix D Historical Groundwater Field Parameter Data Appendix E Performance Monitoring Parameter Time -Trend Graphs Certification Page FORMER I NOLLWOOD GULF STATION (BP 24163) 381 KNOLLWOOD STREET WINSTON-SALEM, FORSYTH COUNTY, NC Report Date: June 17, 2016 Groundwater Incident Number: 6400 Land Use Category: Industrial/Commercial Risk Classification: Low (No Further Action) Responsible Party: Atlantic Richfield Company 1/n BP Products North America, Inc 11114 North Court St. #125 Medina, Ohio 44256 Attn: Greg Frisch Current Property Owner: Thruway Shopping Center, LLC. 7501 Wisconsin Avenue, Suite 1500 Bethesda, Maryland 20814-6522 (301) 986-6077 Attn: Charles Sherren or Zane Zynda Report Prepared By: URS Corporation - North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 (919) 461-1100 Release Information: Release of an unknown quantity of gasoline from an underground storage tank product line 1 ancillary piping prior to September 1983. Release Location: Latitude: 36°05'25.94"N (Topographical Map) Longitude: 80° l T 11.79"W I, Jasen Zinna, a licensed engineer for URS Corporation —North Carolina, do attest that the information contained in this report is c�jreW hildfyo�rcurate to the best of my knowledge. C A f?0' /,fir 0-.E55� Q SEAL r� 044228 Jasen i a, P.E �'•F'N c�� Q.� Date URS rpvratio —North Carolina J'f/9S�cN p Z���1 ►�w URS Corporation — North Carolina is licensed to practice geology/engineering in North Carolina. The certification numbers of the corporation are C-328 and C-2243, respectively. UM i ii SECTIONONE Introduction URS Corporation - North Carolina (URS), on behalf of Atlantic Richfield Company (ARCO), a BP Products North America Inc. affiliated company, is pleased to submit this Groundwater Monitoring Report for Former BP Station No. 24163 located at 381 Knollwood Street, Winston- Salem, Forsyth County, North Carolina (site). This report is intended to satisfy the final project evaluation reporting requirement specified in Part VII, Item 5 of the Renewal Issuance of Injection Permit WI0400198 (NCDENR, 2013). This report presents the procedures and results for the groundwater sampling event performed in April 2016. 1.1 SITE DESCRIPTION The site is located on the eastern side of Knollwood Street, southeast of the intersection with Interstate 40 Business in Winston-Salem, North Carolina. A USGS topographic map depicting the site location and surrounding area is provided as Figure 1. The site property is approximately 0.5 acres, is covered by asphalt and concrete, and was formerly developed as a retail fueling station/convenience store with gasoline, diesel, waste oil, and kerosene Underground Storage Tanks (UST). All UST systems and buildings have been removed from the site and the property is currently utilized as a parking lot for an adjacent shopping center. Site geology, hydrogeology, UST removal history, petroleum release history, environmental investigation and remediation activity history, surrounding property uses, and site ownership history were presented in detail in the site Corrective Action Plan (CAP)(URS 2011). A site map illustrating current and historical site features, including groundwater monitoring well locations, is provided as Figure 2. Currently, ten Type II monitoring wells (MW-3, MW-5R, MW-6, MW-8R, and MW-14 through MW-19) and one Type III monitoring well (MW-6i) are located at the site. Monitoring well construction details are presented in Table 1. 1.2 PROJECT BACKGROUND Two activated sodium persulfate (ASP) injections were performed at the site in accordance with the CAP which was approved by the North Carolina Department of Natural Resources (NCDENR) Division of Waste Management (DWM) UST Section (NCDENR, 2011 a). An Underground Injection Control (UIC) permit application, summarizing the proposed injection activities, was submitted to the NCDENR Division of Water Quality (DWQ) on July 5, 2011. Injection Permit No. WI0400198 was issued by the DWQ on August 9, 2011 (NCDENR, 2011b). Pre -injection investigation and pilot test activities performed in October 2011 were previously documented in a summary report, dated April 23, 2012, submitted to both the DWQ and the DWM UST Section (URS, 2012a). A final ASP injection design, refined based on the results of the pre -design investigation and pilot test results, was also presented in the April 2012 report. The first ASP injection event was performed at the site between June 4, 2012 and June 9, 2012. Injection activities and groundwater sampling performance monitoring were performed in accordance with the approved CAP and Injection Permit No. WI0400198. Baseline data, June 2012 ASP injection activities, and post -injection sampling data through September 2012 were documented in the Activated Sodium Persulfate Injection Completion Report (URS, 2012b). Groundwater sampling events performed in December 2012 and February 2013 were documented in a Semi -Annual Data Report (URS, 2013b). SECTIONONE Introduction A permit renewal application was submitted to NCDENR DWQ on March 26, 2013, (URS, 2013a) in advance of the July 31, 2013, permit expiration date. Renewal Issuance of Injection Permit WI0400198 was issued by the DWQ on May 24, 2013. The second ASP injection event was performed at the site between June 3, 2013 and June 6, 2013. Injection activities and groundwater sampling performance monitoring were performed in accordance with the approved CAP and Injection Permit No. WI0400198. Baseline groundwater data (May 2013) and June 2013 ASP injection activities were documented in the Quarterly Status Report submitted in August 2013 (URS, 2013c). Quarterly groundwater sampling events were conducted in August 2013, November 2013, February 2014, and June 2014 following the second injection. NCDENR issued a request for Notice of Residual Petroleum (NORP) on January 23, 2015 and reduced the risk classification to low. The NORP was recorded with Forsyth County Register of Deeds and public notice letters were sent to the respective parties. A Notice of No Further Action was issued by NCDENR on April 28, 2015. US 1-2 SECTIONTWO Injection Performance Monitoring 2.1 GROUNDWATER SAMPLING PROCEDURES Groundwater sampling was performed on April 28 and 29, 2016. The sampling was not completed in one day because the peristaltic pump broke on day one and a backup pump was not available. The event included sampling of monitoring wells MW-5R, MW-8R, MW-18, and MW-19 in accordance with the injection well permit and recent correspondence with DWQ. Prior to sampling, groundwater levels were gauged in each monitoring well utilizing a water level meter decontaminated with soap and water prior to each measurement. The current water level measurements are presented along with historical gauging data in Appendix A. Following gauging, each well was sampled utilizing low -flow techniques with new tubing. After stabilization criteria were met, groundwater from each well was transferred to pre -labeled, laboratory -prepared containers and promptly placed on ice in a cooler with a temperature and trip blank. The samples were shipped under chain -of -custody via overnight courier to Accutest Laboratories Southeast and analyzed for sulfate utilizing EPA Method 300. Groundwater pH, dissolved oxygen, temperature, oxidation-reduction potential, and specific conductance were measured in the field at each well utilizing a calibrated Yellow Springs Instrument YSI-5569 water quality meter. Purged groundwater was discharged onto a permeable area of the site in accordance with the UST Section Guidelines for Sampling (NCDENR, 2008). tS 2-1 SECTIONTHREE Results and Discussion 3.1 GROUNDWATER SAMPLING RESULTS Groundwater laboratory analytical results for the April 2016 sampling event are presented in Table 2. Historical analytical data is presented in Appendix B. The laboratory analytical report for the groundwater sampling event is included in Appendix C. Groundwater field parameter data for the sampling event is presented in Table 3. Historical field parameters are presented in Appendix D. Time -trend graphs of various parameters associated with injection performance monitoring are included in Appendix E. 3.2 PERFORMANCE MONITORING DISCUSSION The following list provides a brief summary of notable performance monitoring trends. • The current groundwater field parameter results were consistent with historical monitoring events. The pH levels in the monitoring wells ranged from 5.61 (MW-19) to 8.61 (MW-5R). • The sulfate concentration in MW-18 was below the groundwater quality standard of 250 mg/L while the sulfate concentrations in MW-5R, MW-8R, and MW-19 were above the groundwater quality standard; however, the concentrations continue to decrease. Based on these conclusions, URS recommends the following course of action: • It is recommended to continue collecting groundwater samples from MW-5R, MW- 8R, MW-18, and MW-19 and have them analyzed for sulfate on a semi-annual basis until sulfate concentrations are below the groundwater quality standard for two consecutive sampling events. Additionally, groundwater field parameters will be collected during each sampling event. um 3-1 SECTIONFOUR Statement of Limitations This report has been prepared based on assumptions made by URS related to data and site characterization from previous and proposed site investigations. These assumptions, although thought to be reasonable and appropriate, may not prove to be true in the future. Data and site characterization utilized to develop this summary report and injection plan are restricted by the following limitations. Background information and other data have been furnished to URS by ARCO, NCDENR and/or third parties, which URS has utilized in preparing this report. URS has relied on this information as furnished, and is neither responsible for nor has confirmed the accuracy of this information. In addition, it would be extremely expensive, and perhaps not possible, to perform an investigation which would completely characterize subsurface geological conditions to ensure the detection of all materials at the site which now are, or in the future might be, considered "contaminants" by State or federal regulatory agencies. It is possible that any environmental investigation may fail to reveal the presence of critical subsurface characteristics or contaminants that may be present. The failure of URS to discover hazardous materials or contaminants through reasonable and mutually agreed -upon scopes of work does not guarantee that hazardous materials or contaminants do not exist at the site. Finally, opinions presented herein apply to the existing and reasonably foreseeable site conditions at the time of our assessment. Changes in the condition of this property may occur with time due to natural processes or works of man at the site or on adjacent properties. Changes in applicable standards may also occur as a result of legislation or the broadening of knowledge. Accordingly, the findings of this report may be invalidated, wholly or in part, by changes beyond our control. No expressed or implied representation or warranty is included or intended in our reports except that our services were performed, within the limits prescribed by our clients, with the customary thoroughness and competence of our profession. tS 4-1 SECTIONFIVE References NCDENR, 2008. Guidelines for Sampling. UST Section, North Carolina Department of Environment and Natural Resources Division of Waste Management. July 15, 2008 Version. USEPA, 2008. USEPA Contract Laboratory Program National Functional Guidelines for Superfund Organic Methods Data Review and USEPA CLP NFG Inorganic Superfund Data Review. URS, 2011. Corrective Action Plan, Former Knollwood Gulf Station (BP 24163), Incident No. 6400, 381 Knollwood Street, Winston-Salem, North Carolina. URS Corporation — North Carolina. September 7, 2011. NCDENR, 2011 a. Notice of Regulatory Requirements, 15A NCAC 2L . 0407(c), Risk -based Assessment and Corrective Action for Petroleum Underground Storage Tanks, Knollwood Gulf Station (BP 24163), 381 Knollwood Street, Forsyth County. North Carolina Department of Environment and Natural Resources, Division of Waste Management — UST Section, Winston-Salem Regional Office. October 27, 2011. NCDENR, 201lb. Ref Issuance of Injection Permit WI0400198, Former Knollwood Gulf Station (BP 24163), Winston-Salem, Forsyth County, North Carolina. North Carolina Department of Environment and Natural Resources, Division of Water Quality. August 9, 2011. URS, 2012a. RE: Injection Pilot Test and Additional Investigation Results. Letter Report Submitted to Thomas Moore, North Carolina Department of Environment and Natural Resources, Division of Waste Management — UST Section. URS Corporation -North Carolina. April 23, 2012. URS, 2012b. Activated Sodium Persfulate Injection Completion Report, Former Knollwood Gulf Station (BP 24163), 381 Knollwood Street, Winston-Salem, Forsyth County, North Carolina, Incident No.: 6400. URS Corporation -North Carolina. December 5, 2012. NCDENR, 2013. Ref: Renewal Issuance of Injection Permit WI0400198, Former Knollwood Gulf Station (BP 24163), Winston-Salem, Forsyth County, North Carolina. North Carolina Department of Environment and Natural Resources, Division of Water Quality. May 24, 2013. URS, 2013a. RE: Injection Permit WI0400198 Renewal Application, Former Knollwood Gulf Station (BP 24163), 381 Knollwood Street, Winston-Salem, NC. Submitted to North Carolina Department of Environment and Natural Resources, Division of Water Quality. URS Corporation -North Carolina. March 26, 2013. URS, 2013b. Semi -Annual Data Report, Former Knollwood Gulf Station (BP 24163), 381 Knollwood Street, Winston-Salem, Forsyth County, North Carolina, Incident No.: 6400. URS Corporation -North Carolina. April 30, 2013. URS, 2013c. RE: Quarterly Status Report, Former Knollwood Gulf Station (BP 24163), 381 Knollwood Street, Winston-Salem, NC. Submitted to North Carolina Department of Environment and Natural Resources, Division of Water Quality. URS Corporation -North Carolina. August 8, 2013. um 5-1 SECTIONFIVE References URS, 2013d. RE: Quarterly Status Report, Former Knollwood Gulf Station (BP 24163), 381 Knollwood Street, Winston-Salem, NC. Submitted to North Carolina Department of Environment and Natural Resources, Division of Water Quality. URS Corporation -North Carolina. December 11, 2013. US 5-2 TABLES Table 1 Monitoring Well Construction Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Status Well Type TOC Elevation (2) Total Depth ) Well Diameter (inches) Screen Interval (1) Avg Screen Elevation (2) MW-3 In Use Type II 99.03 20 2 NA NA NA MW-5 Abandoned Type II 99.39 25.5 4 10.5 25.5 81.4 MW-5R In Use Type ll NS 20 2 10 20 NA MW-6 In Use Type II 98.68 25.5 4 10.5 25.5 80.7 MW-6i In Use Type 111 99.26 55 2 50 55 46.8 MW-8 Abandoned Type II 97.84 24 6 NA NA NA MW-8R In Use Type ll NS 20 2 10 20 NA MW-14 In Use Type ll 100.44 22 4 7 22 85.9 MW-15 In Use Type II 99.91 22 4 7 22 85.4 MW-16 In Use Type II 97.42 25 2 10 25 79.9 MW-17 In Use Type II 100.00 22 4 7 22 85.5 MW-18 In Use Type II NS 20 2 10 20 NA MW-19 In Use Type II NS 20 2 10 20 NA Notes: 1. Reported in feet below grade 2. Measured in feet relative to site datum 3. Conestoga Rover and Associates, a former consultant for this Site, previously reported that no reference was found to the following wells MW-1, MW-9, MW-10, MW-11, MW-12 or MW-13. These wells are presumed to be abandoned. 4. URS Corporation is not responsible for data generated by others. Data included on this table not generated by or on behalf of URS Corporation - North Carolina (URS) has been taken from documents prepared and submitted to the NC DENR by Others and is included only for ease of reference; URS does not assume or accept any responsibility or liability for the quality, accuracy, or completeness of the data included on this table that was not generated by or on behalf of URS. 5. Monitoring wells MW-5 and MW-8 were abandoned on 5/19/2010 and replaced with monitoring wells MW-5R and MW-8R the same day. 6. Monitoring wells MW-18 and MW-19 were installated on October 25, 2011. NA = Not Applicable / Available NS = Not Surveyed TOC = Top of Casing P:TP\Proje \NC\24163, 3Z, W-S, 381 Knollwood S-65.0 D,liv bl,,\5.1 Draft- Interim Delive bl.\4.28 April 2015 GW Rq-\Tables\Tables, Appendiw , and Graphsjuly 13We11. Ca (Table I)6/22/20152:36 PM Table 2 Summary of Groundwater Results Compared to Groundwater Quality Standards, April 2016 Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, NC NC 2L Groundwater Sample ID: MW-5R MW-811 MW-18 MW-19 Standards + Interim (IMACs) Collection Date: 4/28/2016 4/29/2016 4/29/2016 4/28/2016 Parameters NCDENR 04/13 Units Miscellaneous Sulfate 250 mg/L 2,980 1,640 79.4 1,780 Notes: GCL - Gross Contamination Level J - Estimated value mg/L - Milligrams per Liter NE - Not established SVOC - Semivolatile organic compounds UJ - Not detected and the limit is estimated VOC - Volatile organic compounds This table presents the results of all analytes. Sample results have been qualified by URS based on the results of the data review process, which is modeled after the USEPA Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for Superfund Organic Methods Data Review (EPA, June 2008). Gross Contamination Levels, effective April 16, 2012, obtained from the NCDENR, Division of Waste Management, UST Section. A cell with a bold border and green highlight indicates the sample concentration is greater than the GCL. P:\BP\Projects\NC\24163, JZ, W-S, 381 Knollwood Street\5.0 Deliverables\5.1 Draft - Interim Deliverables\4.30 April 2016 GW Report\Tables\Table 2 5/20/2016, 12:48 PM Table 3 Groundwater Field Parameter Data, April 2016 Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Specific DTW pH ORP Temperature DO Well Conductance feet (s.u.) (mV) (GC) (MS/CM) (mg/L) MW-5R 13.61 8.61 40.7 20.58 6.639 0.55 MW-8R 13.53 6.36 67.8 20.24 3.347 1.16 MW-18 13.62 6.54 -15.6 21.75 0.317 2.26 MW-19 13.38 5.61 81.3 20.71 3.571 0.55 Notes: ORP - oxidation-reduction potential DO - dissolved oxygen s.u. - standard units mV - millivolts DC - degrees Celsius mS/cm - milliSiemens per centimeter mg/L - milligrams per liter P:\BP\P jects\NC\24163, JZ, W-S, 381 Knollwood Street\5.0 Delivembles\5.1 Draft -Interim Delivemblee\4.30 April 2016 GW Report\Tables\Tables, Appendices, and Graphs july 13 1 of 1 FIGURES a SITE LOCATION I:\BP\CADD URS\24163\24163—TOPO.DWG SCALE IN FEET QUADRANGLE LOCATION 0 2000 SOURCE: USGS 7.5' TOPOGRAPHIC QUADRANGLES WINSTON-SALEM WEST, NC - DATED 1950, REVISED 1994 FIGURE 1. LOCATION MAP FORMER BP STATION NO. 24163 WINSTON-SALEM, NORTH CAROLINA Prepared tor: BP PRODUCTS PRO DRAWN BY: TSH RW NOR1H CAROl1N427560 DATE: 25AUG03 Fig. O M.H. LEGEND o • U.P. • U.P. �S Cg10 D.P. — PROPERTY LINE • U.P. CONCRETE ABANDONED GROUNDWATER GRASS EL CTRIC MONITORING WELL PARKING METER P FORMER PRODUCT LINE MN�-17 �B 0 CATCH BASIN 101 ® o NH• MAN HOLE ` X�=o AREA LIGHT ASPHALT TRASH • U.P. UTILITY POLE IPARKING ENCLOSURE MW-3 METAL iP SHED F.H.FIRE HYDRANT ❑ T TELEPHONE r 0 � METAL SHED U.P.,` LARGE MANHOLE COVER FORMER GASOLINE UST AREA I GROUNDWATER MONITORING WELL LLB LLJ FORMER BP SERVICE � STATION (n MW-18+ CONCRETE PAD O 2.0 I MW-5R M -14 O Y W 1 MW-8 -' FORMER PUM NOTES: 4F,H, L 11 IMW-8R ISLAND (TYP) FORMER M —6i CANOPY 1. MONITORING WELL LOCATIONS ARE APPROXIMATE. PARKING I 2. THE SITE IS A VACANT PARKING LOT. I ALL SITE FEATURES EXCEPT PARKING --' M LOT RB D WAYS REPRESENT —19 F I SITE CDS FORMER ARACD ER STI M pRM S DIES L R FORMER PUMP ISLAND (TYP) I CON CR E TE7 / FO ER TANK HOLD T 0 0 0 o FORMER T 0 30 • 0 0 0 o CANOPY UP. APPROX. SCALE, ft. � m O .00 O�p0 MW-15 I SCALE DESIGNED BY AS SHOWN DATE Figure 2.Site Map C.B. FORMER VENT RISERS CDPFIDENTIAL-ALL RIGHTS RESERVED -PROPERTY CF DRAWN BY DATE Former BP Station No, 24163 PRL 05NOV12 Winston—Salem, North Carolina CHECKED BY DATE UNO, S D H 05 N OV 12 CONTRACT DRAWING NO. REV. o M.H. APPROVED BY C K DATE 05 N OV 12 38436693 FI FIGURE-2 0 ROD NORTH CAROLINA 275fi0 APPENDIX A HISTORICAL GROUNDWATER ELEVATION DATA Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation (1)(2) * 06/24/93 ND 13.89 0.00 85.14 * 08/23/94 ND 14.36 0.00 84.67 03/21/95 ND 13.58 0.00 85.45 * 08/05/96 ND 13.54 0.00 85.49 11/17/98 ND 14.09 0.00 84.94 * 06/19/01 ND 14.11 0.00 84.92 09/12/01 ND 14.41 0.00 84.62 * 12/27/01 ND 14.51 0.00 84.52 03/05/02 ND 14.29 0.00 84.74 05/13/03 ND 14.35 0.00 84.68 12/09/03 ND 13.63 0.00 85.40 03/23/06 ND 13.64 0.00 85.39 05/08/07 ND 13.40 0.00 85.63 05/14/08 ND 13.42 0.00 85.61 05/28/09 99.03 ND 13.31 0.00 85.72 05/27/10 ND 13.07 0.00 85.96 MW-3 10/31/11 ND 13.87 0.00 85.16 05/22/12 ND 13.55 0.00 85.48 06/14/12 ND 13.53 0.00 85.50 07/09/12 ND 13.98 0.00 85.05 08/14/12 ND 14.24 0.00 84.79 09/19/12 ND 14.08 0.00 84.95 12/05/12 ND 14.42 0.00 84.61 02/26/13 ND 13.55 0.00 85.48 05/31/13 ND 13.58 0.00 85.45 08/28/13 ND 13.57 0.00 85.46 11/07/13 ND 14.30 0.00 84.73 02/27/14 ND 13.28 0.00 85.75 06/02/14 ND 13.34 0.00 85.69 10/16/14 ND 14.18 0.00 84.85 04/23/15 ND 13.54 0.00 85.49 04/28/16 ND 13.51 0.00 85.52 06/24/93 ND 13.51 0.00 85.88 08/23/94 ND 13.82 0.00 85.57 03/21/95 ND 13.71 0.00 85.68 08/05/96 ND 13.54 0.00 85.85 11/17/98 ND 14.08 0.00 85.31 06/19/01 NM NM NM NM 09/12/01 ND 14.46 0.00 84.93 MW-5 12/27/01 99.39 14.51 15.07 0.56 84.73 03/05/02 14.45 14.88 0.43 84.82 05/12/03 NM NM NM NM 12/09/03 13.18 13.60 0.42 86.10 03/23/06 ND 13.67 0.00 85.72 05/08/07 ND 13.45 0.00 85.94 05/14/08 ND 13.51 0.00 85.88 05/28/09 ND 13.39 0.00 86.00 05/27/10 ND 13.70 0.00 NM 10/31/11 ND 13.97 0.00 NM 05/22/12 ND 13.66 0.00 NM 06/14/12 ND 13.73 0.00 NM 07/09/12 ND 14.18 0.00 NM 08/14/12 ND 14.45 0.00 NM 09/19/12 NS ND 14.35 0.00 NM 12/05/12 ND 14.68 0.00 NM 02/26/13 ND 13.89 0.00 NM MW-5R 05/31/13 ND 13.77 0.00 NM 08/28/13 ND 13.83 0.00 NM 11/07/13 ND 14.53 0.00 NM 02/27/14 ND 13.39 0.00 NM 06/02/14 ND 13.47 0.00 NM 10/16/14 ND 14.32 0.00 NM 04/23/15 ND 13.69 0.00 NM 10/13/15 ND 14.19 0.00 NM 04/28/16 ND 13.61 0.00 NM P �aP �,�mwc�a�aa.rz.w-s.,e�I--s...ns.o--­.1o.,R.,�4�m c.��.�.,n�.a�uo.,���o�e cw,�w��*an�a�ren�.a.,�a�ce..em capnsm�r �,c- E1- wPO Ar 5-01612A,- Page 1 of Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation (1)(2) * 06/24/93 ND 12.31 0.00 86.37 * 08/23/94 ND 12.61 0.00 86.07 03/21/95 ND 13.15 0.00 85.53 * 08/05/96 ND 12.39 0.00 86.29 11/17/98 ND 13.16 0.00 85.52 * 06/19/01 NM NM NM NM 09/12/01 ND 13.51 0.00 85.17 * 12/27/01 ND 13.61 0.00 85.07 03/05/02 ND 11.02 0.00 87.66 MW-6 98.68 05/12/03 ND 11.10 0.00 87.58 12/09/03 ND 13.49 0.00 85.19 03/23/06 ND 11.79 0.00 86.89 05/08/07 ND 12.50 0.00 86.18 05/14/08 ND 12.16 0.00 86.52 05/28/09 ND 10.64 0.00 88.04 05/27/10 ND 11.84 0.00 86.84 10/31/11 ND 12.95 0.00 85.73 06/02/14 ND 12.38 0.00 86.30 06/24/93 ND NM 0.00 NM 08/23/94 ND NM 0.00 NM 03/21/95 ND 14.75 0.00 84.51 08/05/96 ND 14.13 0.00 85.13 11/17/98 ND 14.09 0.00 85.17 06/19/01 ND 18.07 0.00 81.19 09/12/01 ND 16.60 0.00 82.66 12/27/01 ND 14.61 0.00 84.65 03/05/02 ND 14.96 0.00 84.30 99.26 MW-6i 05/12/03 ND 15.17 0.00 84.09 12/09/03 ND 13.55 0.00 85.71 03/23/06 ND 13.55 0.00 85.71 05/08/07 ND 12.93 0.00 86.33 05/14/08 ND 13.22 0.00 86.04 05/28/09 ND 13.39 0.00 85.87 05/27/10 ND 13.23 0.00 86.03 10/31/11 ND 13.90 0.00 85.36 06/02/14 ND 13.35 0.00 85.91 04/28/16 ND 13.55 0.00 85.71 08/23/94 ND 12.14 0.00 85.70 03/21/95 ND 12.02 0.00 85.82 08/05/96 ND 11.99 0.00 85.85 * 11/17/98 ND 12.53 0.00 85.31 * 06/19/01 NM NM NM NM * 09/12/01 ND 12.67 0.00 85.17 * 12/27/01 14.47 15.03 0.56 83.26 MW-8 97.84 * 03/05/02 12.42 12.60 0.18 85.38 05/12/03 NM NM NM NM 12/09/03 13.32 13.56 0.24 84.47 03/23/06 ND 12.15 0.00 85.69 05/08/07 ND 11.90 0.00 85.94 05/14/08 ND 11.95 0.00 85.89 05/28/09 ND 11.70 0.00 86.14 P­,u­a­. w.8.381I--8-0--. 1o.,R.,�4�mo.�,.�.,e�.,�..30.,���o�bow�.,��r,e�a�re�...,�a,ce..,w�n,m�r�31,,,ow11-wPoAr5-01612A,- Page 2of5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation (1)(2) 05/27/10 ND 12.97 0.00 NM 10/31/11 ND 13.34 0.00 NM 05/22/12 ND 13.69 0.00 NM 06/14/12 ND 14.94 0.00 NM 07/09/12 ND 14.08 0.00 NM 08/14/12 ND 14.29 0.00 NM 09/19/12 NS ND 14.08 0.00 NM 12/05/12 ND 14.53 0.00 NM 02/26/13 ND 13.80 0.00 NM MW-8R 05/31/13 ND 13.61 0.00 NM 08/28/13 ND 13.74 0.00 NM 11/07/13 ND 14.42 0.00 NM 02/27/14 ND 13.33 0.00 NM 06/02/14 ND 13.34 0.00 NM 10/16/14 ND 14.18 0.00 NM 04/23/15 ND 13.57 0.00 NM 10/13/15 ND 14.08 0.00 NM 04/28/16 ND 13.53 0.00 NM 06/24/93 NM NM NM NM O8/23/94 NM NM NM NM 03/21/95 ND 13.55 0.00 86.89 08/05/96 ND 13.64 0.00 86.80 11/17/98 ND 14.26 0.00 86.18 06/19/O1 ND 14.55 0.00 85.89 09/12/O1 ND 14.81 0.00 85.63 12/27/O1 ND 14.85 0.00 85.59 03/05/02 100.44 ND 14.64 0.00 85.80 MW-14 05/12/03 ND 13.41 0.00 87.03 12/09/03 ND 13.51 0.00 86.93 03/23/06 ND 13.82 0.00 86.62 05/08/07 ND 13.54 0.00 86.90 05/14/08 ND 13.64 0.00 86.80 05/28/09 ND 13.47 0.00 86.97 05/27/10 ND 13.00 0.00 87.44 10/13/11 ND 14.14 0.00 86.30 06/02/14 ND 13.42 0.00 87.02 04/28/16 ND 13.65 0.00 86.79 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.83 0.00 87.08 08/05/96 ND 12.77 0.00 87.14 11/17/98 ND 13.58 0.00 86.33 06/19/O1 ND 13.80 0.00 86.11 09/12/01 ND 14.18 0.00 85.73 12/27/01 ND 14.29 0.00 85.62 03/05/02 ND 13.98 0.00 85.93 99.91 05/12/03 NM 12.75 NM 87.16 MW-15 12/09/03 ND 12.89 0.00 87.02 03/23/06 ND 13.14 0.00 86.77 05/08/07 ND 12.90 0.00 87.01 05/14/08 ND 13.12 0.00 86.79 05/28/09 ND 12.90 0.00 87.01 05/27/10 ND 12.25 0.00 87.66 10/31/11 ND 13.61 0.00 86.30 06/02/14 ND 12.82 0.00 87.09 10/16/14 ND 13.91 0.00 86.00 04/28/16 ND 13.15 0.00 86.76 P �aP �,umwcva�aa, rz, w-s.,e� I-- s... 0 en-. 1 o.,R-,�4�m en�.�.,m.a�..,o A,�� �me cw w„�,ran�a rem.. A�a�ceo, em capnsm�r �,c- 11-(A,, A) 5-01612A, - Page 3 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater (1) (feet btoc) (feet btoc) (feet) Elevation (1)(2) 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.06 0.00 85.36 08/05/96 ND 12.09 0.00 85.33 11/17/98 ND 12.60 0.00 84.82 06/19/01 ND 12.74 0.00 84.68 09/12/01 ND 12.98 0.00 84.44 12/27/01 NM NM NM NM 03/05/02 ND 12.83 0.00 84.59 MW-16 05/12/03 97.42 NM NM NM NM 12/09/03 ND 12.13 0.00 85.29 03/23/06 ND 12.18 0.00 85.24 05/08/07 NM NM NM NM 05/14/08 ND 12.03 0.00 85.39 05/28/09 ND 11.96 0.00 85.46 05/27/10 ND 11.69 0.00 85.73 10/31/11 ND 12.45 0.00 84.97 11/07/13 ND 12.88 0.00 84.54 06/02/14 ND 11.97 0.00 85.45 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 14.42 0.00 85.58 08/05/96 ND 14.46 0.00 85.54 11/17/98 ND 14.91 0.00 85.09 06/19/01 ND 15.03 0.00 84.97 09/12/01 ND 15.28 0.00 84.72 12/27/01 ND 15.37 0.00 84.63 03/05/02 ND 15.15 0.00 84.85 05/12/03 100.00 NM 14.15 NM 85.85 MW-17 12/09/03 ND 14.50 0.00 85.50 03/23/06 ND 14.45 0.00 85.55 05/08/07 ND 14.22 0.00 85.78 05/14/08 ND 14.22 0.00 85.78 05/28/09 ND 14.12 0.00 85.88 05/27/10 ND 13.90 0.00 86.10 10/31/11 ND 14.72 0.00 85.28 06/02/14 ND 14.14 0.00 85.86 04/28/16 ND 14.36 0.00 85.64 10/31/11 ND 13.95 0.00 NM 05/22/12 ND 14.10 0.00 NM 06/14/12 ND 13.61 0.00 NM 07/09/12 ND 14.05 0.00 NM 08/14/12 ND 14.43 0.00 NM 09/19/12 ND 14.34 0.00 NM 12/05/12 NS ND 14.62 0.00 NM 02/26/13 ND 14.67 0.00 NM 05/31/13 ND 14.57 0.00 NM MW 18 08/28/13 ND 14.33 0.00 NM 11/07/13 ND 14.51 0.00 NM 02/27/14 ND 13.76 0.00 NM 06/02/14 ND 13.55 0.00 NM 10/16/14 ND 14.37 0.00 NM 04/23/15 ND 13.84 0.00 NM 10/13/15 ND 14.81 0.00 NM 04/28/16 ND 13.62 0.00 NM 1 �aP �,umwcva�a3. 3. w.6. 3811--66.. 0on­. I-- 1- on­­.301, 12016c aw­a�ra A. d­ a 31- E1- (A,, A) 5a 01612A,- Page 4 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Date TOC Elevation (1) Depth to LNAPL (feet btoc) Depth to Groundwater (feet btoc) LNAPL Thickness (feet) Corrected Groundwater Elevation (1)(2) 10/31/11 ND 13.75 0.00 NM 05/22/12 ND 13.37 0.00 NM 06/14/12 ND 13.39 0.00 NM 07/09/12 ND 13.89 0.00 NM 08/14/12 ND 14.13 0.00 NM 09/19/12 ND 14.02 0.00 NM 12/05/12 NS ND 14.39 0.00 NM 02/26/13 ND 13.62 0.00 NM 05/31/13 ND 13.47 0.00 NM MW-19 08/28/13 ND 13.56 0.00 NM 11/07/13 ND 14.25 0.00 NM 02/27/14 ND 13.17 0.00 NM 06/02/14 ND 13.14 0.00 NM 10/16/14 ND 14.03 0.00 NM 04/23/15 ND 13.46 0.00 NM 10/13/15 ND 14.01 0.00 NM 04/28/16 ND 13.38 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Corr. GW Elev. _ (ref. point elevation) - (depth to groundwater) + (LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 * - Prior to URS' work at this Site, monitoring well MW-3 has previously been reported as MW-2, monitoring well MW-6 has previously been reported as MW- 8, and monitoring well MW-8 has previously been reported as MW-6. - URS Corporation is not responsible for data generated by others. Data included on this table not generated by or on behalf of URS Corporation - North Carolina (URS) has been taken from documents prepared and submitted to the NCDENR by others and is included only for ease of referece; URS does not assume or accept any responsibility or liability for the quality, accuracy, or completeness of the data included on this table that was not generated by or on behalf of URS. LNAPL = Light non -aqueous phase liquid ND = Not detected NM - Not measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing - During the May 2003 sampling event LNAPL was observed in MW-5. Depth to groundwater and thickness of LNAPL were not measured. P�aP�,umw�a��.rz,w.:.,aI­­:-ooe1--I 201ow�­ar,M...�a,ce. c IP Iy31,,,ow11-(A,,A)5-0161=:a,PM Page 5of5 APPENDIX B HISTORICAL GROUNDWATER ANALYTICAL SUMMARY Appendix B Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE Units: 1 1 /1 1 1 Mg/1 mg/1 MW-03 5/13/2003 8.5 0.98 J 0.61 J 1.7 J 8 -- -- 12/9/2003 47.4 14.3 1.9 1 8.1 37.3 1-- -- 3/23/2006 4.5 J < 0.5 < 0.5 UJ < 1 UJ 5.5 -- -- 5/8/2007 40.4 3.7 1.4 2 J 13.1 -- -- 5/14/2008 4.3 J < 0.8 < 0.7 < 0.8 14 -- -- 5/28/2009 5.4 0.44 J 0.14 J 0.49 J 5.6 -- -- 5/27/2010 0.44 J < 0.11 0.3 J < 0.32 4.8 -- -- 10/31/2011 5.5 0.76 < 0.17 U1 0.38 J 19.1 1 8.4 405 5/22/2012 < 0.43 U < 0.2 < 0.2 < 0.52 4.6 15.3 378 6/14/2012 12.1 6.7 0.72 4.7 15.4 6.6 J 344 7/9/2012 2.2 1.6 2.6 3 14.7 9.9 393 8/14/2012 2 2.1 < 0.13 0.4 J 17.9 3.6 303 9/19/2012 2.7 0.66 < 0.13 0.33 J 19.8 2.8 459 12/5/2012 11.3 1.2 0.43 J 1.1 J 19.3 0.78 J 377 2/26/2013 0.23 J < 0.1 < 0.1 < 0.22 5.4 32.6 338 5/31/2013 0.32 J < 0.1 < 0.1 < 0.22 10.5 17.9 334 8/28/2013 3.6 0.53 0.12 J 0.31 J 10.3 21.9 457 11/7/2013 4.3 0.27 J 0.13 J < 0.22 10 21.7 536 2/27/2014 < 0.1 < 0.1 < 0.1 < 0.2 1.3 42.2 198 6/3/2014 0.48 J 0.15 J < 0.1 < 0.2 3.1 -- -- 10/16/2014 - -- -- -- -- 18.0 372 4/23/2015 - -- -- -- -- 22.8 296 MW-05 3/23/2006 11700 2,440 32,000 13,500 16,100 -- -- 3/23/2006 11,000 2,370 30,700 13,200 15,400 -- -- 5/8/2007 7,410 1,590 21,100 8,920 8,830 -- - 5/8/2007 (" 7,400 1,680 20,100 9,290 9,360 -- -- 5/14/2008 10,000 2,100 29,000 12,000 18,000 -- - 5/14/2008 (') 10,000 2,100 30,000 12,000 18,000 -- -- 5/28/2009 7,390 2,330 25,700 13,400 6,920 -- -- 5/28/2009 (') 61510 2,240 22,100 12,900 6,510 1-- -- MW-05R 5/27/2010 6,610 2,810 24,300 J 15,700 4,330 -- -- 5/27/2010 (') 6,090 2,380 30,100 J 13,300 4,250 -- - 10/31/2011 7,960 2,660 28,000 13,800 3,830 < 1 < 5 10/31/2011 8,360 2,870 24,600 14,800 4,070 -- -- 5/22/2012 7,980 3,470 32,200 19,200 3,820 < 5 179 6/15/2012 (2) 244 227 1,190 1,120 36.9 6,070 1,820 7/9/2012 336 J 481 J 2,010 J 2,400 J 48.4 J 6,470 2,620 8/14/2012 201 283 1,050 1,300 48.5 14,700 4,190 9/19/2012 158 181 650 883 114 19,000 3,280 12/5/2012 754 505 2,220 2,380 1,160 13,600 1,840 2/26/2013 1,360 878 3,520 3,940 1,660 8,520 1,530 5/31/2013 1,410 1,380 5,930 1 6,220 1,150 J 4,680 1,560 8/28/2013 165 1 178 489 1,380 417 13,900 1,590 11/7/2013 214 131 331 969 651 14,400 1,570 2/27/2014 142 177 328 1,060 240 2,990 1 807 P:\BP\Projects\NC\24163, JZ, W-S, 381 Knollwood Street\5.0 Deliverables\5.1 Draft - Interim Deliverables\4.30 April 2016 GW Report\Appendices\Appendix B 6/16/2016, 12:40 PM Appendix B Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE Units: 1 1 /1 1 1 Mg/1 mg/1 MW-05R 6/2/2014 256 436 1040 2520 519 J -- -- 10/16/2014 -- - -- -- -- 9,950 1,390 4/23/2015 -- -- -- -- -- 5,980 1,510 10/13/2015 -- -- -- -- -- 5,790 - 4/28/2016 -- -- -- -- -- 2,980 -- MW-06 5/12/2003 < 0.5 0.52 J < 0.5 < 1 3 -- -- 12/9/2003 2.3 0.64 J 1.1 1 3.6 17.6 1-- -- 12/9/2003 2.4 0.68 J 1.1 3.8 18 -- -- 3/23/2006 0.76 J 0.59 J 3.6 2.8 J 1.1 -- -- 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 -- -- 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 -- -- 5/28/2009 < 0.06 < 0.05 < 0.06 < 0.14 0.17 J -- -- 5/27/2010 < 0.11 0.13 J 0.38 J 0.46 J < 0.12 -- -- 10/31/2011 8.7 J 11.7 J 27.5 J 132 J < 0.26 UJ 131 2,130 6/2/2014 17.6 J 59.4 J 31.6 J 99.4 J 783 J -- -- MW-06I 5/12/2003 < 0.5 < 0.5 < 0.5 1.11 < 0.5 -- -- 12/9/2003 < 2.5 < 2.5 < 2.5 < 5 < 2.5 -- -- 3/23/2006 49.7 18.9 48.7 443 3,560 -- -- 5/8/2007 < 25 < 25 < 25 < 50 6,910 -- -- 5/14/2008 5.2 J < 2 < 1.8 < 2 3,400 -- -- 5/28/2009 2.5 < 0.05 < 0.06 < 0.14 1,150 -- -- 5/27/2010 1.6 J < 1.1 < 1.1 < 3.2 492 -- -- 10/31/2011 0.41 J < 0.36 < 0.32 < 0.75 122 < 1 76.1 6/2/2014 < 0.1 < 0.1 < 0.1 < 0.2 3.3 -- -- MW-08 3/23/2006 671 1,340 1,230 8,100 124 1-- -- 5/8/2007 1,160 799 196 2,990 1,440 -- -- 5/14/2008 600 1,800 700 3,000 190 - -- 5/28/2009 1,390 2,050 357 3,310 1560 -- -- MW-08R 5/27/2010 8,570 2,870 31,700 15,700 6,260 -- - 10/31/2011 8,000 3,180 32,100 17,200 3,170 < 1 < 5 5/22/2012 8,270 3,360 36,400 J 17,800 3,920 < 5 119 6/15/2012 (2) 726 47 J 760 242 J 96.3 J 4,760 22,200 7/9/2012 45540 J 15870 J 17,100 J 105800 J 15530 J 65570 4,500 8/14/2012 4,370 1,610 19,300 8,780 2,000 7,010 1,560 9/19/2012 4,780 1,800 20,900 10,400 2,600 6,700 1,100 12/5/2012 7,760 2,440 31,900 13,800 4,560 2,410 635 2/26/2013 7,310 2,480 30,500 13,400 4,530 959 590 5/31/2013 6,540 3,040 30,500 125500 45200 439 437 8/28/2013 1,600 628 5,390 3,990 1,380 4,770 703 11/7/2013 1,130 329 2,440 1,830 1,770 7,460 766 2/27/2014 15020 603 3,200 3,430 1,190 7,670 940 6/2/2014 1,360 J 680 J 3,510 J 3,330 J 2,110 J -- -- 6/2/2014 (1) 1,540 556 J 3,650 2,630 J 2,640 J -- -- 10/16/2014 35310 883 9,070 45990 35910 35560 842 4/23/2015 -- -- -- -- -- 2,050 812 10/13/2015 -- -- -- - -- 1,600 -- 4/29/2016 -- -- -- -- -- 1,640 - P:\BP\Projects\NC\24163, JZ, W-S, 381 Knollwood Street\5.0 Deliverables\5.1 Draft - Interim Deliverables\4.30 April 2016 GW Report\Appendices\Appendix B 6/16/2016, 12:40 PM Appendix B Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE Units: 1 1 /1 1 1 Mg/1 mg/1 MW-14 5/12/2003 < 0.5 < 0.5 < 0.5 < 1 0.52 J -- -- 12/9/2003 < 0.5 < 0.5 < 0.5 1 < 1 5.9 -- -- 3/23/2006 < 0.5 < 0.5 < 0.5 < 1 < 0.5 -- -- 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 -- -- 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 -- -- 5/28/2009 < 0.06 < 0.05 0.077 J < 0.14 < 0.06 -- - 5/27/2010 < 0.11 < 0.11 < 0.11 < 0.32 < 0.12 -- -- 10/31/2011 <0.13 <0.15 <0.42U <0.3 <0.13 43.2 <5 6/3/2014 < 0.1 < 0.1 < 0.1 1 < 0.2 < 0.1 -- -- MW-15 3/23/2006 0.63 J 2.1 < 0.5 18.6 1.6 -- -- 5/8/2007 < 0.5 < 0.5 < 0.5 2.2 J < 0.5 -- -- 5/14/2008 < 0.5 < 0.8 < 0.7 3.7 J < 0.5 -- -- 5/27/2010 < 0.11 < 0.11 < 0.11 < 0.32 < 0.12 -- -- 10/31/2011 <0.13 <0.15 <0.13 <0.3 <0.13 <1 <5 6/3/2014 < 0.1 < 0.1 < 0.1 1 < 0.2 < 0.1 -- -- 10/16/2014 <0.1 <0.1 <0.1 <0.2 <0.1 -- -- MW-16 3/23/2006 < 2.5 90.8 15.8 836 2.8 J -- -- 5/14/2008 < 0.5 160 15 1,600 4.1 J -- -- 5/27/2010 3.6 54.7 J 5.1 525 J 1.3 -- -- 10/31/2011 < 0.65 17.2 < 1.4 U 321 < 0.65 194 < 5 11/7/2013 -- -- -- 1-- -- 55.4 < 5 6/3/2014 < 0.1 25 0.92 417 J < 0.1 -- -- MW-17 5/13/2003 57.7 < 0.5 < 0.5 < 1 69 -- -- 5/13/2003 40.8 < 0.5 < 0.5 < 1 63.3 -- -- 12/9/2003 6.6 0.65 J < 0.5 < 1 80.6 -- -- 3/23/2006 1 < 0.5 < 0.5 < 1 58.9 -- -- 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 17.4 -- -- 5/14/2008 3.7 J < 0.8 < 0.7 < 0.8 19 -- -- 5/28/2009 7 < 0.05 0.076 J < 0.14 14.5 -- -- 5/27/2010 5.7 < 0.11 < 0.11 < 0.32 12.4 -- -- 10/31/2011 0.51 0.16 J < 0.81 U 0.57 J 8.9 < 1 422 6/3/2014 < 0.1 < 0.1 < 0.1 < 0.2 4.1 -- -- MW-18 10/31/2011 3,140 998 11,100 8,950 1,140 1 8.2 446 5/22/2012 2,280 2,790 18,200 12,000 789 < 5 307 6/15/2012 (21 373 910 4,800 3,910 114 10,600 3,410 7/9/2012 1,730 J 2,170 J 15,000 J 9,750 J 676 J 2,300 835 8/14/2012 3,020 2,990 24,400 12,800 1,090 758 580 9/19/2012 3,190 3,090 22,600 14,000 1,240 322 542 12/5/2012 3,370 2,970 20,100 12,800 1,380 32.2 436 2/26/2013 2,510 2,970 10,100 8,690 1,140 13.8 500 5/31/2013 2,780 3,070 8,210 5,740 1,000 83.3 475 8/28/2013 182 368 730 1,660 139 7,850 2,230 11/7/2013 1,140 727 4,910 3,250 694 2,640 1,370 2/27/2014 16.6 109 20.2 45.8 18.5 4,310 1,270 6/2/2014 26.2 J 125 J 37.5 J 31.6 J 37.4 J -- -- 10/16/2014 359 388 244 138 364 1,540 513 4/23/2015 -- - -- -- -- 780 1,100 10/13/2015 -- -- -- -- -- 516 - 4/29/2016 -- -- -- -- -- 79.4 -- P:\BP\Projects\NC\24163, JZ, W-S, 381 Knollwood Street\5.0 Deliverables\5.1 Draft - Interim Deliverables\4.30 April 2016 GW Report\Appendices\Appendix B 6/16/2016, 12:40 PM Appendix B Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene y enes (Total) MTBE Sulfate Carbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE Units: 1 1 /1 1 1 mg/1 mg/1 MW-19 10/31/2011 2,390 1,380 8,790 7,040 5,160 3.7 425 5/22/2012 2,700 1,560 14,200 7,940 4,880 1 < 5 310 6/15/2012 (" 4,020 1,440 18,200 7,940 3,290 1,090 6,520 7/9/2012 5,130 2,910 30,400 J 16,300 5,330 232 991 8/14/2012 2,420 1,650 14,200 8,370 4,090 469 1,080 9/19/2012 2,090 1,630 12,900 8,640 3,960 260 690 12/5/2012 2,320 1,810 15,200 10,400 4,010 58.8 588 2/26/2013 2,210 1,110 10,600 6,990 3,890 169 503 5/31/2013 1,830 894 8,820 5,250 3,120 1,530 606 8/28/2013 2,710 J 1,190 J 13,100 7,420 J 3,240 J 2,660 525 11/7/2013 2,020 984 9,850 5,620 2,260 2,890 255 2/27/2014 1 2,550 1,400 10,900 7,880 3,320 2,790 322 6/2/2014 2,370 1,260 11,900 7,260 21830 -- I- 10/16/2014 -- -- -- -- -- 2,340 632 4/23/2015 -- -- -- -- -- 21540 514 10/13/2015 -- -- -- -- -- 1,960 - 4/28/2016 -- -- -- -- -- 1,780 -- Notes: (1) Field duplicate (2) Alkalinity, sulfate, and carbon dioxide samples were collected 6/14/2012 and volatile organic analysis samples were collected 6/15/12. -" - Not sampled or analyzed < - Not detected at the specified detection limit µg/1- Micrograms per Liter GCL - Gross Contamination Level J - Estimated value mg/l - Milligrams per Liter MTBE - Methyl tert-Butyl Ether NE - Not established U - Not present above the associated level; blank contamination exists UJ - Not detected and the detection limit is estimated Bold cell with a green highlight indicates GCL exceedance. Activated sodium persulfate injections were performed at the site from June 4, 2012, to June 9, 2012, and from June 3, 2013, to June 6, 2013. This table presents the results of all analytes. Sample results have been qualified by URS based on the results of the data review process, which is modeled after the USEPA Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for Superfund Organic Methods Data Review (EPA, June 2008) and USEPA CLP NFG for Inorganic Superfund Data Review (USEPA, January 2010). Gross Contamination Levels, effective April 16, 2012, obtained from the NCDENR, Division of Waste Management, UST Section. P:\BP\Projects\NC\24163, JZ, W-S, 381 Knollwood Street\5.0 Deliverables\5.1 Draft - Interim Deliverables\4.30 April 2016 GW Report\Appendices\Appendix B 6/16/2016, 12:40 PM APPENDIX C LABORATORY ANALYTICAL REPORT 5MI ACCUTEST Southeast SGS ACCUTEST I5 PART Of SGS, THE WORLD'S LEADING INSPECTION, VERIFICATION, TESTING AND CERTIFICATION COMPANY. Technical Report for e-Hardcopy 2.0 Automated Report Atlantic Richfield Company URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC 60486285.106081 SGS Accutest Job Number: FA33584 Sampling Dates: 04/28/ 16 - 04/29/ 16 Report to: AECOM, INC. 1600 Perimeter Park Drive Suite 400 Morrisville, NC 27560 ncchemistsnurs. corn ATTN: Martha Meyers -Lee / Jasen Zinna Total number of pages in report: 20 Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable. Norm Farmer Technical Director Client Service contact: Heather Wandrey 407-425-6700 Certifications: FL (E83510), LA (03051), KS (E-10327), IA (366), IL (200063), NC (573), NJ (FLO02), SC (96038001) DoD ELAP (L-A-B L2229), CA (2937), TX (T104704404), PA (68-03573), VA (460177), AK, AR, GA, KY, MA, NV, OK, UT, WA This report shall not be reproduced, except in its entirety, without the written approval of SGS Accutest. Test results relate only to samples analyzed. Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707 • http://www.accutest.com SGS , 40 SGS Accutest is the sole authority for authorizing edits or modifications to this document. ACCUTEST Unauthorized modification of this report is strictly prohibited. FA33584 Table of Contents 1 Section1: Sample Summary................................................................................................... Section 2: Case Narrative/Conformance Summary.............................................................. Section3: Summary of Hits.................................................................................................... Section4: Sample Results........................................................................................................ 4.1: FA33584-1: MW-5R..................................................................................................... 4.2: FA33584-2: MW-8R..................................................................................................... 4.3: FA33584-3: MW-18...................................................................................................... 4.4: FA33584-4: MW-19...................................................................................................... Section5: Misc. Forms............................................................................................................ 5.1: Chain of Custody........................................................................................................... Section 6: General Chemistry - QC Data Summaries.......................................................... 6.1: Method Blank and Spike Results Summary.................................................................. 6.2: Matrix Spike Results Summary..................................................................................... 6.3: Matrix Spike Duplicate Results Summary.................................................................... Sections: 3 7 9 10 11 12 13 14 17 18 19 20 0 0 0 SGSACCUTEST FA33584 SGS Accutest Sample Summary Atlantic Richfield Company Job No: FA33584 URSNCM: S/S 24163: 381 Knollwood St, Winston-Salem, NC Project No: 60486285.106081 Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID FA33584-1 04/28/16 13:41 AC 04/30/16 AQ Ground Water MW-5R FA33584-2 04/29/16 10:47 AC 04/30/16 AQ Ground Water MW-8R FA33584-3 04/29/16 12:11 AC 04/30/16 AQ Ground Water MW-18 FA33584-4 04/28/16 12:33 AC 04/30/16 AQ Ground Water MW-19 SGSACCUTEST FA33584 SAMPLE DELIVERY GROUP CASE NARRATIVE Client: Atlantic Richfield Company Job No: FA33584 Site: URSNCM: S/S 24163: 381 Knollwood St, Winston-Salem, NC Report Date 5/4/2016 4:04:20 PM 4 Samples were collected on/between 04/28/2016 and 04/29/2016 and were received at SGS Accutest Southeast (SASE) on 04/30/2016 properly preserved, at 3.4 Deg. C and intact. These Samples received an SASE job number of FA33584. A listing of the Laboratory Sample ID, Client Sample ID and dates of collection are presented in the Results Summary Section. Except as noted below, all method specified calibrations and quality control performance criteria were met for this job. For more information, please refer to QC summary pages. Wet Chemistry By Method EPA 300/SW846 9056A Matrix: AQ Batch ID: GP27884 All samples were prepped within the recommended method holding time. All samples were analyzed within the recommended method holding time. All method blanks for this batch meet method specific criteria. Sample(s) FA33584-3MS, FA33584-3MSD were used as the QC samples for Sulfate. SGS Accutest (SASE) certifies that this report meets the project requirements for analytical data produced for the samples as received at SASE and as stated on the COC. SASE certifies that the data meets the Data Quality Objectives for precision, accuracy and completeness as specified in the SASE Quality Manual except as noted above. This report is to be used in its entirety. SASE is not responsible for any assumptions of data quality if partial data packages are used Narrative prepared by: Date: May 4, 2016 Lovelie Metzgar, QA Officer (signature on file) Wednesday, May 04, 2016 Page 1 of 1 SGSACCUTEST FA33584 Laboratory Report Glossary Client Sample ID: Normally refers to a point of collection — a monitoring well, discharge outfall, treatment facility intake, soil core grid location and depth, or any other identification client assigns to a sample. Lab Sample ID: Letter prefix identifies one of Accutest laboratories and the rest is a consecutive number of the job (or SDG) received. Number after dash is a sample number and it is unequivocally linked in the LIMS to the Client Sample ID (see above). Matrix (Matrix Code): • AQ- Water Samples • SO- Soil/Solid Samples • LIQ- Non -Water Liquid Samples • OIL- Oil Samples Matrix Type: • SW for Surface Water • SO for Soil/Sediment • GW for Ground Water • DW for Drinking Water All available definitions are found on Chain of Custody form. Deg. C: Degrees Celsius, measurement of temperature. Method: Analytical and preparation methods used for the analysis, with the version or revision identified. Date Sampled: This information is entered from Chain of Custody at the time of login for every sample. Date Received: When the job was received by Accutest Laboratories. Percent Solids: Applicable only to SO matrix. For other matrices this field defaults to "n/a". Run #: Provides information how many attempts were made in the analysis of the sample. LIMS can merge information from several attempts and lists all of them, including dilution, confirmation, etc. #1 designation is assigned to the analytical run with majority of analytes reported from it, not necessarily in chronological order. File ID: Actual instrument data acquisition file that produced the final result. Letter prefix identifies the instrument; the rest is a consecutive injection number for that instrument. DF (Dilution Factor): Most common reasons are either to fit into the range of the calibration, or alleviate matrix interference. DF other than 1 are accompanied with a comment at the end of the sample report. Analyzed: Date of analysis. By: Field Technician or Analyst uniquely identified by initials. Prep Date: Date of sample preparation. If hold time is 72 hours or less, time of preparation is also indicated. Prep Batch: Letter prefix OP followed by a consecutive number. For VOC analysis preparation happens at the time of analysis, therefore analytical batch and preparation batch are the same. Size of prep batch is limited to 20 field samples of similar matrix and the entire batch should be completed within 12 hour time. Analytical Batch: Letter prefix identifies the instrument and is followed by a consecutive number. Not limited by a number of samples. Initial Weight or Initial Volume: Raw sample size used for preparation. Final Volume: Final volume of extract. If different from method -prescribed volume, reasons are reflected in the comments at the end of the report form. CAS Number: Chemical Abstracts Service (CAS), a division of the American Chemical Society. Compound: Most commonly used names of chemical compounds. Result: Depending on project requirements, this field could be set up as text, such as ND (for Non Detected) or a number. The number may be reported with a qualifier. MDL (Method Detection Limit): This value is defined as 99% probability that analyte above this concentration is positively (qualitatively) identified. RL (Reporting Limit): This value is supported by the low calibration standard and defines lowest point of quantitative identification of analyte. DL (Detection Limit): The smallest analyte concentration that can be demonstrated to be different from zero or a blank concentration with 99% confidence. At the DL, the false positive rate (Type I error) is 1 %. LOD (Limit of Detection): The smallest concentration of a substance that must be present in a sample in order to be detected at the DL with 99% confidence. At the LOD, the false negative rate (Type II error) is 1%. LOQ (Limit of Quantitation): The smallest concentration that produces a quantitative result with known and recorded precision and bias. SGSACCUTEST FA33584 Units: ug/1 (micrograms per liter) for aqueous samples and ug/kg (micrograms per kilogram) for solids (or ppb — parts per billion). The units could be set according to project or state -specific requirements, such as mg/1(milligrams per liter), or mg/kg (milligrams per kilogram). Qualifiers (Q): Defmitions of most often used qualifiers are found at the bottom of each result page. Applied depending on the program — state -specific (Florida A.C. 62-160), CLP-like, AFCEE, DOD QSM, etc. Tentatively Identified Compound (TIC): Used when client requests a search for analytes that are not part of instrument calibration. Unknown peaks are compared with published spectral libraries and best match is reported as TIC. Surrogate (Sl, S2, S3 etc.): are positive controls that are used in most organics methods to ascertain preparation efficiency and matrix effect in individual samples. These chemicals mimic common method constituents but are unlikely to be found in real samples. Recoveries can be reported for every analytical run used in the analysis. IS (Internal Standard ISl, IS2, IS3, etc): quantitative reference used to adjust for instrument performance fluctuations. Area (of chromatographic peak): signal intensity directly related to compound concentration. RT (Retention Time): time required for analyte to traverse the length of analytical column. Used for compound identification. ICAL (Initial Calibration): Must pass calibration criteria established by method. ICV (Independent Calibration Verification): Used to verify ICAL preparation and concentration of calibration points. CCV (Continuing Calibration Verification): Used to assess calibration status of the instrument and must recover within established acceptance criteria. MB (Method Blank): is a negative batch control. MB is an aliquot of matrix free of analyte of interest (either ASTM Type II water or appropriate solid substance) that is put through all the preparation and possible clean-up steps alongside investigative (field) samples. MB should be free of interferences above a set level. BS (Blank Spike, Laboratory Fortified Blank - LFB, Laboratory Control Sample - LCS): is a positive control used to determine method accuracy - in clean matrix, i.e. matrix free of analytes of interest. BSD (Blank Spike Duplicate): Used to assess recovery reproducibility - method precision — per analytical method requirement. %Recovery and Relative Percent Difference (%RPD) are compared with the established acceptance criteria. MS and/or MSD (Matrix Spike and Matrix Spike Duplicate): positive batch controls which indicate matrix effect on the precision and accuracy of the method in given sample matrix. Results are expressed in %Recovery and Relative Percent Difference (%RPD), and compared with the established acceptance criteria. DUP (Matrix Duplicate): Positive batch control, a way of assessing laboratory's precision; however, the composition of the samples is unknown and may not yield meaningful results. REC (Recovery in Percent): expresses method accuracy. RPD (Relative Percent Difference): expresses method precision. Limits: Recovery limits for surrogates and spikes SGSACCUIEST FA33584 Summary of Hits Page 1 of 1 Job Number: FA33584 Account: Atlantic Richfield Company Project: URSNCM: S/S 24163: 381 Knollwood St, Winston-Salem, NC Collected: 04/28/16 thru 04/29/16 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method FA33584-1 MW-5R Sulfate FA33584-2 MW-8R Sulfate FA33584-3 MW-18 Sulfate FA33584-4 MW-19 Sulfate 2980 100 30 mg/l EPA 300/SW846 9056A 1640 50 15 mg/l EPA 300/SW846 9056A 79.4 2.0 0.60 mg/l EPA 300/SW846 9056A 1780 20 6.0 mg/1 EPA 300/SW846 9056A SGS ACCUIEST FA33584 ACCUTEST Southeast Sample Results Report of Analysis Section 4 SGS ACCUTEST FA33584 SGS Accutest Report of Analysis Client Sample ID: MW-5R Lab Sample ID: FA33584-1 Date Sampled: 04/28/16 Matrix: AQ - Ground Water Date Received: 04/30/ 16 Percent Solids: n/a Project: URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC General Chemistry Analyte Result RL MDL Units DF Sulfate 2980 100 30 mg/1 50 RL = Reporting Limit MDL = Method Detection Limit Page 1 of 1 Analyzed By Method 05/03/16 21:48 LJ EPA 300/SW846 9056A U = Indicates a result < MDL B = Indicates a result > = MDL but < RL SGS ACCUTEST FA33584 SGS Accutest Report of Analysis Client Sample ID: MW-8R Lab Sample ID: FA33584-2 Date Sampled: 04/29/16 Matrix: AQ - Ground Water Date Received: 04/30/ 16 Percent Solids: n/a Project: URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC General Chemistry Analyte Result RL MDL Units DF Sulfate 1640 50 15 mg/1 25 RL = Reporting Limit MDL = Method Detection Limit Page 1 of 1 Analyzed By Method 05/03/16 22:06 LJ EPA 300/SW846 9056A U = Indicates a result < MDL B = Indicates a result > = MDL but < RL SGS ACCUTEST FA33584 SGS Accutest Report of Analysis Client Sample ID: MW-18 Lab Sample ID: FA33584-3 Date Sampled: 04/29/16 Matrix: AQ - Ground Water Date Received: 04/30/ 16 Percent Solids: n/a Project: URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC General Chemistry Analyte Result RL MDL Units DF Sulfate 79.4 2.0 0.60 mg/1 1 RL = Reporting Limit MDL = Method Detection Limit Page 1 of 1 Analyzed By Method 05/03/16 22:24 LJ EPA 300/SW846 9056A U = Indicates a result < MDL B = Indicates a result > = MDL but < RL SGS ACCUTEST FA33584 SGS Accutest Report of Analysis Client Sample ID: MW-19 Lab Sample ID: FA33584-4 Date Sampled: 04/28/16 Matrix: AQ - Ground Water Date Received: 04/30/ 16 Percent Solids: n/a Project: URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC General Chemistry Analyte Result RL MDL Units DF Sulfate 1780 20 6.0 mg/1 10 RL = Reporting Limit MDL = Method Detection Limit Page 1 of 1 A 46 0 Analyzed By Method 05/03/16 23:18 LJ EPA 300/SW846 9056A U = Indicates a result < MDL B = Indicates a result > = MDL but < RL SGS ACCUTEST FA33584 ACCUTEST Southeast Misc. Forms Custody Documents and Other Forms Includes the following where applicable: • Chain of Custody Section 5 SGS ACCUTEST FA33584 Accutest Laboratories Southeast TC �Q! MMR Chain of Custody gccutest JOB # ` A 3 3 PA__,�--_„ -_OF r ACCIJTEST 4405 Vineland Road, Suite G Orlando, 32811 LABORATORIES TEL. 407-425-6700 • FAX: 407-425-0707 Www.accutest.com ccutest Quote Client f Reporting Intonation 777777777 Project Information AnalOwl Information .. ,n Matrix Codes CompanyName u� Project Name: Z� o VO In Dw- Drinking Water GW- Ground Water WW - Water SW - Surlaca Water SW so - soll GL- Sludge a -al O.Other Liqu d AIR-ar S0Other Solid WP Y�Ix Address % c Ld T�<• qat01YB81 3<{{ city state NL zip 229'J. I city state Project Contact E-mail Sasec Ziw a T' GG lA project# / W Z E Pnona# cm 6 -!l Fax # Sampler(.) Names) (Primed) AM ety Client Puase Orer a'ccu'c" e # Field ID! Point of Collection SAMPLED MATPI% o1L# ? 8 3 - W -S 2a l6 rwl xX S — t{�t9%rb I oWy �I.7c63 TURNAROUND TIME Business D a s Dala Deliverabl Informstion Comments l R emarks Approved By:! Rush Code ET'10 Days Standard ❑ 7 Day RUSH _ ❑ 5 Day 9USH ❑ 3 Day EMERGENCY ❑ 2Day EMERGENCY ❑ 1 Day EMERGENCY __ __ _ ❑ OTHER Emsrgsncy or Rush T!a Data Available VIA Email or Labllnk COMMERCIAL "A" (RESULTS ONLY) � COMMERCIAL "B" (RESULTS PLUS QC) REDT1 (EPA LEVEL 3) �FULT1 (EPA LEVEL 4)�-v__. EDD'S _ CMUDII l rt+,e„-:mn,1:a m V t be a t dach time samples chance wv Relinq h tl by S mpler: 1 iuf(Ib Date Time: j 3 s9 z Re eiv :. R In u Date'11me: / :Oo Rec ' a Relinquished by: ,�/n,,'�" 5 1. \. Date Time: AL'-d20-- t 6 Re wed By: Relinquished 6. . �O 7 by: Date Time: Received By: 1 8 Lab Use Only: Custody Seal in Place: Y N Temp Blank Provider: Y N Preserved where Applicable: Y N Total # of Coolers:: Gooier Temperature s Celsius: FA33584: Chain of Custody Page 1 of 3 Ln 3 SGSACCUTEST FA33584 ACCUTEST LABORATORIES SAMPLE RECEIPT CONFIRMATION ACCUTEST'S JOB NUMBER: EA 33 S �4 _ CLIENT: A EdoM PROJECT:_[ ,Q_416 S DATE/TIMERECEIVED: )� 'C O^ ( 6 {MM/DD/YY 24:00) NUMBER OF COOLERS RECEIVED:_ METHOD OF DELIVERY: FEDEX UPS ACCUTEST COURIER DELIVERY OTHER: AHMILL NUMBERS: 1762 2 S.S V to o 9 COOLER INFORMATION CUSTODY SEAL NOT PRESENT OR NOT INTACT CHAIN OF CUSTODY NOT RECEIVED (COC) ANALYSIS REQUESTED IS UNCLEAR OR MISSING SAMPLE DATES OR TIMES UNCLEAR OR MISSING TEMPERATURE CRITERIA NOT MET TRIP BLANK INFORMATION TRIP BLANK PROVIDED TRIP BLANK NOT PROVIDED TRliP BLANK NOT ON COC TRIP BLANK INTACT TRW BLANK NOT INTACT RECEIVED WATER TRIP BLANK RECEIVED SOIL TRIP BLANK MISC. INFORMATION NUMBER OF ENCORES ? 25-GRAM 5-GRAM NUMBER OF 5035 FIELD KITS ? NUMBER OF LAB FILTERED METALS ? TEST STRIP LOTps pH 0-3_230315 SUMMARY OF TECHNICIAN SIGNA NF 11/15 TEMPERATURE INFORMATION IR THERM ID� I CORR. FACTOR •'O, 2 OBSERVED TEMPS: 3. L CORRECTED TEMPS: 3 ­4 (USED FOR LIMS) SAMPLE INFORMATION INCORRECT NUMBER OF CONTAINERS USED SAMPLE RECEIVED IMPROPERLY PRESERVED INSUFFICIENT VOLUME FOR ANALYSIS DATESITIMES ON COC DO NOT MATCH SAMPLE LABEL ID'S ON COC DO NOT MATCH LABEL VOC VIALS HAVE HEADSPACE (MACRO BUBBLES) BOTTLES RECEIVED BUT ANALYSIS NOT REQUESTED NO BOTTLES RECEIVED FOR ANALYSIS REQUESTED UNCLEAR FILTERING OR COMPOSITING INSTRUCTIONS SAMPLE CONTAINER(S)RECEIVED BROKEN 5035 FIELD KITS NOT RECEIVED WITHIN 48 HOURS BULK VOA SOIL JARS NOT RECEIVED WITHIN 48 HOURS SOLIDS JAR NOT RECEIVED RESIDUAL CHLORINE PRESENT LOTS (APPLICABLE TO EPA 600 SERIES OR NORTH CAROLINA ORGANICS) PH 10-12 _219813A OTHER (specify) -- ,;� —/ u REVIEWER SIGNATURE/DA RECEI PTLOG040416.xls FA33584: Chain of Custody Page 2 of 3 SGSACCUTEST FA33584 48g££tld OZ bo 96 L0 £ 30 £ a2lud Spoisna jo uivuji, :b8S££V3 X 1� O N V � V p N M n.rrnrr_ � CO m � v z A p � C F7 Z1 N < a a f7 O° Q o Oy 1 v I Cn +^rmcnl'1� 2a (AZMM art r.. -4 m 1-1M CO nz m MO Im M q v C)I rn o $grn �mm 540JM042f/27F https://www.fedex.coiTVshipping(htmi/eWPrir,tiFranie.hMnl After printing this label: 1. 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Written claims must be filed within strict time limits, see current FedEx Service Guide. ` I of 7 4/29/2016 9:57 AM FMI ACCUTEST Southeast General Chemistry QC Data Summaries Includes the following where applicable: • Method Blank and Blank Spike Summaries • Duplicate Summaries • Matrix Spike Summaries ��A Section 6 0 SGSACCUTEST FA33584 METHOD BLANK AND SPIKE RESULTS SUMMARY GENERAL CHEMISTRY Login Number: FA33584 Account: BPAMSS - Atlantic Richfield Company Project: URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC ME Spike BSP BSP QC Analyte Batch ID RL Result Units Amount Result %Recov Limits Chloride GP27884/GN70789 2.0 0.0 mg/l 50 51.7 103.4 Fluoride GP27884/GN70789 0.20 0.0 mg/l 2.5 2.60 104.0 Nitrogen, Nitrate GP27884/GN70789 0.10 0.0 mg/l 2.5 2.32 92.8 Sulfate GP27884/GN70789 2.0 0.0 mg/l 50 53.1 106.2 Associated Samples: Batch GP27884: FA33584-1, FA33584-2, FA33584-3, FA33584-4 (*) Outside of QC limits Page 1 90-110% 90-110% 90-110% 90-110% Q1 i SGS ACCUTEST FA33584 MATRIX SPIKE RESULTS SUMMARY GENERAL CHEMISTRY Login Number: FA33584 Account: BPAMSS - Atlantic Richfield Company Project: URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC QC Original Spike MS QC Analyte Batch ID Sample Units Result Amount Result %Rec Limits Chloride GP27884/GN70789 FA33584-3 mg/l Fluoride GP27884/GN70789 FA33584-3 mg/l Nitrogen, Nitrate GP27884/GN70789 FA33584-3 mg/1 Sulfate GP27884/GN70789 FA33584-3 mg/l Associated Samples: Batch GP27884: FA33584-1, FA33584-2, FA33584-3, FA33584-4 (*) Outside of QC limits (N) Matrix Spike Rec. outside of QC limits Page 1 5.8 50 57.7 103.8 90-110% 0.13 B 2.5 2.7 102.8 90-110% 0.050 U 2.5 2.4 96.0 90-110% 79.4 50 130 101.2 90-110% O� N 1 SGSACCUTEST FA33584 MATRIX SPIKE DUPLICATE RESULTS SUMMARY GENERAL CHEMISTRY Login Number: FA33584 Account: BPAMSS - Atlantic Richfield Company Project: URSNCM:S/S 24163: 381 Knollwood St, Winston-Salem, NC QC Original Spike MSD QC Analyte Batch ID Sample Units Result Amount Result RPD Limit Chloride GP27884/GN70789 FA33584-3 mg/l Fluoride GP27884/GN70789 FA33584-3 mg/l Nitrogen, Nitrate GP27884/GN70789 FA33584-3 mg/l Sulfate GP27884/GN70789 FA33584-3 mg/l Associated Samples: Batch GP27884: FA33584-1, FA33584-2, FA33584-3, FA33584-4 (*) Outside of QC limits (N) Matrix Spike Rec. outside of QC limits Page 1 5.8 50 57.9 0.3 200 0.13 B 2.5 2.8 3.6 200 0.050 U 2.5 2.4 0.0 20% 79.4 50 130 0.0 20e SGSACCUTEST FA33584 APPENDIX D HISTORICAL GROUNDWATER FIELD PARAMETER DATA Appendix D Historical Groundwater Field Parameter Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Date Sodium Persulfate pH ORP Temp. Specific Cond. DO g/L S.U. mV °C MS/CM mg/L 3/23/06 6.97 -44 19.1 0.696 0.48 5/8/07 7.00 -190.8 20.30 0.388 1.00 5/14/08 6.18 19.0 0.668 5/28/09 7.20 19.7 0.452 5/27/10 6.84 36.3 19.09 0.390 2.1 10/31/11 6.84 -72 22.04 1.171 3.2 5/22/12 0.07' 7.13 -5.4 20.32 0.708 4.6 6/14/12 ND 6.84 21.7 20.53 0.854 0.5 7/9/12 ND 7.08 -7 21.42 0.753 3.6 8/14/12 ND 7.02 -51.9 22.43 0.552 2.7 MW-3 9/19/12 0.07' 7.00 -125.9 22.06 0.854 0.9 12/5/12 6.89 -66.6 20.65 0.774 1.3 2/26/12 6.61 -72.5 16.30 0.573 1.3 5/31/13 6.82 -10.6 19.81 0.823 3.8 8/28/13 6.65 -21.3 22.43 0.855 1.93 11/7/13 ND 1 6.44 -17.5 21.15 0.752 2.08 2/27/14 7.36 -58.2 14.23 0.522 6.92 6/3/14 6.71 67.3 19.28 0.615 0.42 10/16/14 6.60 -39.9 21.35 0.750 2.83 4/23/15 6.64 -71.9 18.64 0.679 3.31 3/23/06 5.67 5.0 18.44 0.144 0.77 5/8/07 5.15 143.2 20.60 0.076 0.65 MW-5 5/14/08 3.45 19.5 0.104 5/28/09 6.11 19.7 0.328 5/27/10 2.624 129.1 18.95 0.193 4.1 10/31/11 4.89 185.6 22.00 0.123 1 1.7 5/22/12 ND 4.19 153.9 20.04 0.078 1.1 6/14/12 ND 13.08 8.9 23.57 37.82 0.5 7/9/12 ND 13.10 39.9 22.42 35.02 7.2 8/14/12 0.07' 1 13.38 144.1 23.36 34.91 0.3 9/19/12 ND 13.36 39.9 23.12 46.21 0.2 12/5/12 12.39 1.2 1 22.79 27.87 0.6 2/26/12 11.66 -44.7 15.14 16.44 1 1.2 MW-5R 5/31/13 10.76 -60.4 20.03 11.25 0.7 8/28/13 11.42 165.1 22.12 29.66 3.01 11/7/13 3.94 10.61 110.1 21.59 24.82 2.00 2/27/14 ND 9.42 128 16.26 5.735 4.53 6/2/14 1 8.61 143.2 21.87 11.109 0.61 10/16/14 8.99 46.7 1 22.00 19.220 0.39 4/23/15 8.64 -232.9 18.72 10.400 0.77 10/13/15 7.86 -122.0 23.52 12.430 0.41 4/28/16 8.61 40.7 20.58 6.639 0.55 3/23/06 6.18 217 18.19 0.656 0.3 5/8/07 1 6.59 67.7 19.22 0.683 2.01 5/14/08 5.40 18.2 0.382 MW-6 5/28/09 4.51 19.3 0.325 -- 5/27/10 5.97 88.4 17.91 0.311 3.07 10/31/11 13.772 -184.7 20.71 49.87 1.25 6/2/14 7.54 9.4 20.86 4.19 1.30 a.w:.- oo.­., --,.gym - w_.a.­ . I of 3 Appendix D Historical Groundwater Field Parameter Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Date Sodium Persulfate pH ORP Temp. Specific Cond. DO g/L S.U. mV °C MS/CM mg/L 3/23/06 6.08 -32 18.3 0.277 0.25 5/8/07 6.67 -123.5 19.66 0.169 0.40 5/14/08 6.32 18.3 0.159 MW-6I 5/28/09 6.43 19.4 0.132 5/27/10 5.35 10.3 18.57 0.060 0.67 10/31/11 6.89 -32.5 18.85 0.184 1.40 6/2/14 5.62 90.3 21.11 0.181 2.23 3/23/06 6.95 -150 17.93 0.601 0.14 5/8/07 7.05 -118.0 19.88 0.556 0.36 MW 8 5/14/08 5.91 19.3 0.445 5/28/09 6.49 19.5 0.469 5/27/10 4.03 105.1 18.38 0.090 2.55 10/31/11 4.80 198.1 21.88 0.250 1.9 5/22/12 ND 4.59 250.4 19.80 0.158 0.8 6/14/12 32.18 13.32 17.2 22.80 194.5 17.163 7/9/12 8.4 13.38 116.7 21.56 68.5 32.85' 8/14/12 3.64 1 13.09 171 21.75 20.15 42.28' 9/19/12 0.665 12.74 123.9 21.92 19.1 13.97' 12/5/12 ND 11.34 25.4 22.10 6.993 2.1 2/26/12 10.02 -59.2 15.35 2.298 0.7 MW-8R 5/31/13 10.18 -25.1 19.66 2.322 0.6 8/28/13 9.10 173.2 21.96 14.13 3.15 11/7/13 0.96 7.03 262.9 21.01 14.96 1.43 2/27/14 1.86 1 7.64 149.7 16.53 11.65 3.81 6/2/14 6.40 149.7 19.88 10.153 0.17 10/16/14 6.42 141.9 21.35 7.601 0.97 4/23/15 6.19 -79.4 18.12 3.939 1.33 10/13/15 5.10 -24.9 23.25 4.131 0.26 4/29/16 6.36 67.8 20.24 3.347 1.16 3/23/06 1 4.62 257 18.99 0.081 0.39 5/8/07 4.46 196.8 19.09 0.060 0.95 5/14/08 4.49 18.8 0.079 MW-14 5/28/09 4.75 19.9 0.077 5/27/10 1.564 253.3 18.82 0.169 2.97 10/31/11 4.59 260.9 21.31 0.157 2.84 6/3/14 4.24 161.1 19.31 0.093 0.24 3/23/06 1 4.48 294 1 17.85 0.048 1 0.06 5/8/07 4.31 -134.4 19.34 0.042 0.32 5/14/08 3.40 18.3 0.042 5/28/09 MW-15 5/27/10 3.46 119.5 17.03 0.130 2.99 10/31/11 4.44 254.1 19.32 0.061 2.80 6/3/14 4.23 198.4 17.31 0.076 1.76 10/16/14 4.99 175.8 18.27 1 0.080 1.92 3/23/06 4.33 529 18.07 6.81 5/8/07 5/14/08 3.83 17.7 0.736 5/28/09 MW-16 5/27/10 3.97 99.9 17.32 0.687 1.60 10/31/11 4.44 244.9 19.62 0.706 3.20 11/7/13 ND 4.27 210.1 18.91 0.533 1.30 6/3/14 4.13 191.3 17.26 0.725 1.84 a.w:.- oo.­w --,.gym ­- . ,1 - w_.a.­ . 2 of 3 Appendix D Historical Groundwater Field Parameter Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Date Sodium Persulfate pH ORP Temp. Specific Cond. DO g/L S.U. mV °C mS/cm mg/L 3/23/06 4.21 488 18.86 4.63 5/8/07 6.46 -14.4 20.06 0.392 1.15 5/14/08 4.98 20.1 0.391 MW-17 5/28/09 6.11 19.6 0.310 5/27/10 5.25 57.9 18.43 0.287 0.57 10/31/11 6.31 -90.5 20.80 0.556 0.66 6/3/14 6.00 -35.4 18.64 0.407 0.14 10/31/11 6.86 12.9 22.47 0.117 2.4 5/22/12 ND 6.20 30.7 21.43 0.001 3.0 6/14/12 ND 13.12 5 1 21.06 54.11 1 0.3 7/9/12 ND 11.92 40.4 21.29 10.05 1.2 8/14/12 ND 10.88 -35 22.59 2.533 0.2 9/19/12 ND 11.09 -35 22.59 3.301 0.2 12/5/12 6.91 -68.1 22.85 0.859 0.7 2/26/12 6.11 -84.2 14.86 0.589 1.0 5/31/13 6.42 -117.2 19.62 1.036 1.0 MW-18 8/28/13 9.06 219.9 21.71 16.08 1.79 11/7/13 ND 9.84 158.7 20.02 6.111 1.82 2/27/14 7.24 -101 13.93 6.157 4.26 6/2/14 7.01 -98.3 20.39 8.162 0.13 10/16/14 6.96 -212.9 22.56 4.798 0.49 4/23/15 7.02 -187.4 19.15 3.242 1.82 10/13/15 6.21 -107.4 26.42 3.289 0.23 4/29/16 6.54 -15.6 21.75 0.317 1 2.26 10/31/11 5.37 190 21.81 0.193 3.9 5/22/12 ND 4.62 131.7 19.89 0.103 0.9 6/14/12 6.615 13.30 -15.8 21.57 117.8 22.383 7/9/12 ND 12.75 46.9 21.91 13.4 25.793 8/14/12 0.07 1 12.50 162 22.57 10.21 25.463 9/19/12 0.07' 11.71 157 22.47 3.424 1 12.93 12/5/12 9.99 20.1 23.03 1.537 5.2 2/26/12 8.14 -41.9 16.85 1.511 0.8 5/31/13 7.50 192.5 19.86 5.885 2.7 MW-19 8/28/13 6.20 213.1 21.16 5.29 3.30 11/7/13 ND 5.84 229.2 21.01 5.124 3.48 2/27/14 1 6.21 95.7 16.11 4.303 3.65 6/2/14 5.82 160.8 1 20.70 5.681 1 2.19 10/16/14 5.76 64.9 22.42 4.739 0.20 4/23/15 5.49 -77.4 18.81 4.276 1.21 10/13/15 4.57 -61.8 24.60 4.446 0.25 4/28/16 5.61 81.3 20.71 3.571 0.55 Notes: 1.) Sodium persulfate test kits results of 0.07 g/L are treated as "non -detections", as they are within the margin -of -error for detection. 2.) Values are not consistant with historic values and may be the result of instrument malfunction. 3.) Dissolved oxygen results above saturation (approximately 9.1 mg/L at 2(°C) are considered to represent measurement error and are not considered representative of actual dissolved oxygen concentration in groundwater. Error in measurements for the sensor used, a steady-state polarographic sensor, can be caused by membrane fouling and interference gases, among other causes (YSI, 2009). The likelihood of measurement error from these sources may have been heightened by the injection. 4.) Elevated pH is the result of the October 2011 sodium hydroxide pilot test injection adjacent to MW-6. Subsequent elevated pH measurements in MW-5R, MW-8R, MW-18, and NM-19 are associated with June 2012 and June 2013 sodium persulfate and sodium hydroxide injections. - activated sodium persulfate injections were performed at the site from June 4, 2012, to June 9, 2012, and from June 3, 2013, to June 6, 2013. ORP - oxidation reduction potential DO - dissolved oxygen g/L - grams per liter s.u. - standard units mV - millivolts °C - degrees Celsius = Not Measured ND - Not Detected Temp. - temperature Specific Cond. - specific conductance mS/cm - milliSiemens per centimeter mg/L - milligrams per liter a.w:.- oo.­­-.,.gym - w_.a.­ . 3 of 3 APPENDIX E ASP INJECTION PERFORMANCE MONITORING PARAMETER TIME -TREND GRAPHS 14.0 12.0 10.0 M1 V1 2 Q 6.0 EXI] pH over Time -1 —1 N N N N N N M M M M M cn cn cn 1n cn cn 1n �D �D O O O O O O O O O O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N N N N N N N N -1 a) O O "1 r-I r-I 00 O O r-I r-I r-I 00 O O r-I r-I r-I 00 O O r-I r-I r-I M O M M N M M M M M N M M M M M N M M M M M N M M M M M N M \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ O N N lD 00 O N N Rt lD 00 O N N lD 00 O N N lD 00 O N N ci ci ci ci ci ci ci ci ci c-I Date MW-3 (control) MW-5R MW-8R MW-18 M W-19 P:\BP\Prjer,ts\NC\24163, JZ, W-S, 381 Knollwood Street\5.0 Deli-rables\5.1 Draft - Interim Deli-rables\4.30 April 2016 GW Report\Tables\Tables, Appendices, and Graphsjuly 13 Sulfate over Time 20000 Iniection Event MW-3 (control) E R-IZIZI] 16000 14000 12000 J dA E a) 10000 f0 3 N 8000 - 4000 0 200 160 140 E v N 120 3 100 c 0 U 80 'v GJ CL 40 20 0 Specific Conductivity over Time i -1 N N N N N N M M M M M cn M in Ln Ln in Ln �O �o O O O O O O O O O O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N N N N N N N N rl -1 a) O O -1 -1 -1 00 O O r-I r-I r-I 00 O O r-I r-I r-I 00 O O r-I r-I r-I a> O M M N M M M M M N M M M M M N M M M M M N M M M M M N M \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ O N N �t lD 00 O N N Rt lD 00 O N N -Zt lD 00 O N N -tt lD 00 O N N R* r-I ci ci rl ci rl ci ci ci ci Date MW-3 (control) MW-5R M W-8R MW-18 MW-19