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HomeMy WebLinkAboutWI0400198_Monitoring (Report)_20161214DOCUMENT TRACKING FORM REPORT NAME: O l � SITE NUMBER: a ,, Be q 4 TODAY'S DATE: /Q !%- PROJ. NUMBER: p/ &lV r� . Iv/0 SAMPLED DATE: l (�P TASK NUMBER: C{ DATE ANALY REC: PROJ MANAGER: 1sT DRAFT DUE DATE: FINAL DUE DATE: -DRIVE LOCATION• gq 14 5 STRAi H REPOINT U OAD DATE: rs1rY�/ b Report Production: Personnel Assigned Assigned Date Budget l st Draft Comp 2nd Draft Comp Author(s): Tables: Figures: KD Tech Edit: Admin: 6 Modeler: Engineering: PM Review: PE/PG Review: Comments/Delays: Document Production: Date and Time Submitted: DUE DATE "OUT THE DOOR". / 2, N. f {, A- Clip B- Staple C- Three Ring D- Spiral Bound E- CD Other: Copies or BW Deliver To: elivery Carrier by Date Sent Tracking Number Original /Color C J- Copy 1 ; _C`1J� © Llis Ir r 3 I D 3 Copy 2 Copy Copy4 FC� iYr �1 Special lnstr ctions: Final Submittal Review. Name, Work Date: Signature/Date: Must have manager signature prior to any documents being sent out. ARCADIS Design sr Consultancy fornaturaland built assets Mr. Michael Rogers UIC Program Manager NCDEQ — DWR 1636 Mail Service Center Raleigh, North Carolina 27699 Subject: Groundwater Monitoring Report — 2016 Former BP Facility #24163 381 Knollwood Street Winston-Salem, North Carolina 27103 Incident Number: 6400 (Closed) Risk Classification: Low (No Further Action) Dear Mr. Rogers: On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, Arcadis G&M of North Carolina is submitting the attached Groundwater Monitoring Report — 2016 dated December 3, 2016 for the above referenced site. An electronic copy of this report including the associated laboratory analytical report is included with the attached CD. Please contact me at (919) 415-2327 with any questions or concerns related to the Report or this incident number. Sincerely, Arcadis G&M of North Carolina, Inc. r Paul Goodell, E.I. AFS Project Manager 5 Copies: File — BP #24163 Arcadis U.S., Inc. 111-D Sanders Lane Tel 919 854 1282 Fax 919 854 5448 www.arcadis.com A019INel21tIIA011 Date: January 4, 2017 Contact: Paul Goodell Phone: 919.415.2327 Email: Paul.Goodell@Arcadis.com Our ref: GP16BPNA.NC10 Page: 1/1 /aRCADIS design&Consultancy fornaturaland built assets Atlantic Richfield Company c/o BP Products North America, Inc. 2ND SEMI-ANNUAL MONITORING REPORT - 2016 'A Former BP Facility #24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina NCDEQ Incident #6400 (Closed) Injection Permit #W10400198 'A 2nd Semi -Annual Monitoring Report - 2016 2ND SEMI-ANNUAL MONIORING REPORT REPORT - 2016 Prepared for: 1 Atlantic Richfield Company c/o BP Products North America, Inc. Alexandra M. Simpson Mr. Greg Frisch — Project Manager AFS Task Leader 3 4850 E. 4911 Street MBC-3 Room 155C Cuyahoga Heights, Ohio 44125 Tel 216.416.1232 Paul Goodell, E.I. Prepared by: AFS Project Manager 5 Arcadis G&M of North Carolina, Inc. 801 Corporate Center Drive �tIQffiIrr��n Suite 300 Raleigh, North Carolina 27607 ( C. Scott Boitian, P.E. 3 G Tel 919.854.1282 North Carolina P.E. No, 25659 Fax 919.854.5448 Senior EngineelE,`"ao � .a.: �d4j�r:Y � www.arcadis-us com �i • o4 . z %'��y°"nan�wngaan Environmental Our Ref.: GPI6BPNA.NC10 Date: December 3, 2016 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged, confidential and exempt from disclosure under applicable law. Any dissemination, distribution or copying of this document is strictly prohibited. SrC8di5 Gor1i I 2no Semi -Annual Monitoring Report - 2016 2na Semi -Annual Monitoring Report Former BP Facility #24163 381 Knollwood St Winston-Salem, Forsyth County, North Carolina Latitude 361,5' 25.94"N Longitude 800 17' 11.79"W (Reference Figure 1) Groundwater Incident #: Risk Classification: Reason for Risk Classification: Land Use Category. - Source of Release: Date of Release Discovery: Estimated Quantity of Release: Cause of Release: Responsible Party: Property Owner: is 6400 (Closed) Low (No Further Action) Dissolved -phase Sulfate concentrations above groundwater quality standards (2L) Industrial/Commercial Former gasoline UST system(s) 1983 Unknown Former UST System Atlantic Richfield Company c/o BP Products North America, Inc. Attn: Greg Frisch 4850 East 49°h Street MSC-3 Room 155C Cuyahoga Heights, Ohio 44125 (216) 416-1232 Mr. Charles Sherren Thruway Shopping Center, LLC. 7501 Wisconsin Ave., Suite 1500 Bethesda, Maryland, 20814 (301) 986-2925 ext. 215 1, (_ _ /� (�/ I C/'1_�, a Professional Engineer for ARCADIS G&M of North Carolina, Inc., do certify that the information c ntained in this report is correct and accurate to the best of my knowledge. ARCADIS G&M of NorthColina, Inc. is licensed to practice geology and engineering in North Carolina. The certification•nun�ber.T.&the company are C-155 (geology) and C-1869 (engineering). 2nd Semi -Annual Monitoring Report - 2016 CONTENTS 1.0 Site History and Characterization .... 2.0 Groundwater Monitoring ................... 2.1 Groundwater Gauging ................ 2.2 Groundwater Sampling .............. 2.3 Groundwater Analytical Results. 3.0 Site Remediation .............................. 3.1 Remediation Activities to Date... 4.0 Conclusions and Recommendations TABLES Table 1. Well Construction Details Table 2. Groundwater Elevation Data Table 3. Groundwater Quality Field Parameters Table 4. Groundwater Analytical Data FIGUREc' Figure 1. Site Location Map Figure 2. Site Map Figure 3. Potentiometric Surface Map - September 2016 Figure 4. Groundwater Analytical Data Map Figure 5. Sulfate Isoconcentration Map September 19, 2016 APPENDICES A- Historical Groundwater Elevation Data B- Laboratory Analytical Report and Chain -of -Custody Record — September 19, 2016 C- Historical Groundwater Analytical Data 3 4 4 4 5 5 6 7 arcadis.com 2nd Semi -Annual Monitoring Report - 2016 EXECUTIVE SUMMARY On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company Arcadis G&M of North Carolina, Inc. (Arcadis) personnel performed the semi- annual groundwater sampling of monitoring wells associated with Former BP Facility #24163 located at 381 Knollwood Street, in Winston-Salem, Forsyth County, North Carolina (the Site) on September 19, 2016. All groundwater monitoring activities were conducted in response to the final project evaluation requirement specified in Part VII, Item 5 of the Renewal Issuance of Injection Permit W10400198 from the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Quality — Aquifer Protection Section in April 2013. On September 19, 2016, Arcadis completed a semi-annual groundwater monitoring and sampling event at the Site. Five (5) groundwater monitoring wells (MW-3, MW-5R, MW-8R, MW-18, and MW-19) were gauged to determine the depth to water (DTW) and depth to product (DTP), if present. DTW ranged from 13.75 feet below top of casing (btoc) in groundwater monitoring well MW-19 to 14.04 feet btoc in groundwater monitoring well MW-18. Free product was not detected at the Site on September 19, 2016. On September 19, 2016, groundwater samples were collected from groundwater monitoring wells MW-3, MW-5R, MW-8R, MW-18, and MW-19. The maximum concentrations of selected dissolved -phase COCs found during the September 19, 2016 sampling events are summarized in the table below: Maximum Groundwater Concentrations (September 19, 2016) Chemical of Monitoring Well Concentration North Carolina Concern ID (mg/L) Groundwater (COC) Quality (2L) Standards Sulfate MW-5R 2,880 250 Note: Concentration in Bold exceed the applicable North Carolina GCL Standard Dissolved phase sulfate concentrations decreased compared to historical groundwater analytical data. Dissolved phase sulfate was detected above the applicable North Carolina Groundwater Quality (2L) Standard at groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19. Arcadis recommends discontinuing semi-annual sampling of groundwater monitoring well MW-3. Groundwater monitoring well MW-3 has not had a historical dissolved -phase sulfate detection above the applicable North Carolina 2L Standards since groundwater sampling was initiated at the Site. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for March 2017. Groundwater monitoring wells MW- 5R, MW-8R, MW-18, and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-5R, MW-8R, MW 18, and MW-19 for arcadis.com ES-1 2nd Semi -Annual Monitoring Report - 2016 analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2017 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com ES-2 2nd Semi -Annual Monitoring Report - 2016 1.0 SITE HISTORY AND CHARACTERIZATION Former BP Facility #24163 is located at 381 Knollwood Street, Winston-Salem, Forsyth County, North Carolina (the Site). The Site is currently owned by Thruway Shopping Center, LLC. and serves as a parking lot adjacent to surrounding retail stores. The site property is approximately 0.5 acres, covered by asphalt and concrete, and was formerly developed as a retail fueling station which housed gasoline, diesel, waste oil, and kerosene Underground Storage Tanks (USTs). A site location map is presented as Figure 1 and a site map is shown as Figure 2. The North Carolina Department of Environmental Quality (NCDEQ) issued groundwater incident number 6400 due to a subsurface release of gasoline that occurred on or before September 14, 1983 from a ruptured product line associated with the UST system. The quantity of the release remains unknown. One (1) 10,000-gallon steel gasoline UST, three (3) 6,000-gallon steel gasoline USTs, and one (1) 10,000-gallon steel diesel UST were removed from the site in 1990. Three (3) 10,000-gallon gasoline USTs, one (1) 10,000-gallon diesel UST, and one (1) 550-gallon waste oil UST were subsequently installed at the site and the site was purchased by M. M. Fowler, Inc. in January 1994 and continued operation until 2004. The remaining five USTs were removed before 2005 and the site was razed. Site geology and hydrogeology include surficial deposits immediately underlying the site are described generally as sandy silts that grade upward to clayey silts and silty clays. Bedrock beneath the site is mapped as a strongly foliated biotite gneiss and schist. The maximum depth of investigation at the site has been approximately 55 feet below ground surface (bgs); bedrock has not been encountered during site investigation work. Historically, the range for shallow groundwater beneath the site is approximately 11 to 14 feet bgs, and groundwater flow direction is toward the northwest with an apparent horizontal gradient of approximately 0.012 feet per foot (ft/ft). The calculated groundwater seepage velocity for shallow groundwater beneath the site is approximately 2.8 feet per year. Two activated sodium persulfate injections were performed at the Site on June 4 — 9, 2012 and June 3 — 6, 2013 under Underground Injection Control (UIC) Permit #W10400198 which was issued by the NCDEQ Division of Water Quality on August 9, 2011. Approximately 11,237-gallons of sodium persulfate and 6,826-gallons of sodium persulfate were injected at the Site on June 4 — 9, 2012 and June 3 — 6, 2013, respectively. The NCDEQ Risk Classification for this site was reduced to "Low" on January 23, 2015 after issuing a request for Notice of Residual Petroleum (NORP). No Further Action (NFA) status was granted for the subject incident number on April 28, 2015. In accordance with UIC Permit #W10400198 dissolved -phase concentrations of sulfate are being monitored on a semi-annual basis at the Site. Closure of UIC Permit #W10400198 will be requested once dissolved -phase sulfate concentrations are no longer detected above the North Carolina Groundwater Quality (2L) Standards. arcadis.com 2nd Semi -Annual Monitoring Report - 2016 2.0 GROUNDWATER MONITORING 2.1 Groundwater Gauging On September 19, 2016, Arcadis G&M of North Carolina, Inc. (Arcadis) personnel gauged monitoring wells MW-3, MW-5R, MW-8R, MW-18, and MW-19. Gauging was conducted with an oil/water interface probe (IP) prior to purging and sampling to determine DTB, DTW, and DTP, if present. The I and attached tape, marked in 0.01-foot increments, were properly decontaminated before each use with Alconox soap and rinsed with distilled water. The DTW was measured from the marked survey point on the top of well casing (TOC). All measurements were recorded to the nearest 0.01-foot increment. Free product was not detected during the September 19, 2016 groundwater monitoring event. Depth to water ranged from 13.75 btoc in groundwater monitoring well MW-19 to 14.04 feet btoc in groundwater monitoring well MW-18. Monitoring well construction details are included in Table 1. Current groundwater elevations are summarized in Table 2. Historical groundwater gauging data is provided in Appendix A. A potentiometric surface map depicting historical groundwater flow direction is provided as Figure 3. 2.2 Ground water Sampli ng On September 19, 2016, groundwater monitoring wells MW-3, MW-5R, MW-8R, MW-18, and MW-19 were purged of stagnant water to prepare for groundwater sampling. Prior to purging, the amount of water to be removed was calculated using the following formula: 3.1415 x rz x (TD-DTW) x 7.481 = gallons of water (1 well volume) Where: r = radius of well (in feet) TD = total depth of well (in feet) DTW = depth to water (in feet) In order to ensure that the water in the wells after representative of the water in the aquifer, a minimum of three well volumes were removed. Using a YSI-556, field parameters for pH, ORP, Temperature, Dissolved Oxygen, and Specific Conductance were collected for each well after purging. This data can be found in Table 3. Groundwater samples obtained from the groundwater monitoring well were collected from disposable polyethylene bailers using new nylon rope. Groundwater samples were placed in laboratory supplied containers and shipped on wet ice to TestAmerica Inc. in Nashville, Tennessee, for analysis of Sulfate (SO4) by Standard Method 9056A. Groundwater samples submitted for sulfate analysis were collected in 250-milliliter plastic bottles. The laboratory analytical report and chain -of -custody record for the September 19, 2016 groundwater sampling event is included as Appendix B. arcadis.com 4 2nd Semi -Annual Monitoring Report - 2016 2.3 Groundwater Analytical Results Groundwater analytical data from the September 19, 2016 groundwater sampling event indicated the following: • Dissolved -phase concentrations of sulfate were detected in concentrations exceeding the applicable North Carolina 2L Standard of 250 milligrams per liter (mg/L) in groundwater monitoring wells MW-5R (2,880 mg/L), MW-8R (1,330 mg/L), MW-18 (377 mg/L), and MW-19 (1,270 mg/ L). Current groundwater analytical results are presented in Table 4. Historical analytical groundwater data can be found in Appendix C. A dissolved phase concentration map is presented as Figure 4. A sulfate isoconcentration map depicting the dissolved -phase extent of sulfate exceeding the applicable 2L groundwater quality standard is presented in Figure 5. arcadis.com 2nd Semi -Annual Monitoring Report - 2016 3.0 SITE REMEDIATION 3.1 Remediation Activities to Date Summarized in the table below is a chronology of remediation activities performed at the site to date: Date Activity September 14, 1983 Subsurface release of gasoline from a ruptured product line associated with the UST system December 1990 UST systems associated with release removed; 500 tons of contaminated soil removed during UST closure 1992 Vacuum Extraction System Installed 1992 - 1994 Vacuum Extraction System Operation 1994 - 2011 Monitoring of site June 4 — 9, 2012 Activated Sodium Persulfate (ASP) injection event. Approximately 11,237-gallons of sodium persulfate injected. June 3 — 6, 2013 ASP injection event. Approximately 6,826-gallons of sodium persulfate injected. 2013 - Present Monitored Natural Attenuation arcadis.com 6 2nd Semi -Annual Monitoring Report - 2016 4.0 CONCLUSIONS AND RECOMMENDATIONS Free Product was not observed at the Site during the September 19, 2016 groundwater monitoring and sampling event. Dissolved -phase sulfate was detected above the applicable 2L groundwater quality standard in groundwater monitoring wells MW-5R, MW-8R, MW-18, and MW-19, exceeding the applicable North Carolina 2L standard of 250 mg/L. Arcadis recommends discontinuing semi-annual sampling of groundwater monitoring well MW-3. Groundwater monitoring well MW-3 has not had a historical dissolved -phase sulfate detection above the applicable North Carolina 2L Standards since groundwater sampling was initiated at the Site. Arcadis recommends continuing the semi-annual groundwater monitoring and sampling program at the Site to document the natural attenuation of sulfate. The next semi-annual groundwater monitoring and sampling event is scheduled for March 2017. Groundwater monitoring wells MW- 5R, MW-8R, MW-18, and MW-19 will be gauged to evaluate the potentiometric surface at the Site. Groundwater samples will be collected from MW-5R, MW-8R, MW18, and MW-19 for analysis of sulfate by Standard Method 9056A. A Semi -Annual Groundwater Monitoring Report documenting the proposed activities for 2017 will be submitted to the NCDEQ for review and approval within 45-days of receipt of the laboratory analytical report. arcadis.com 2nd Semi -Annual Monitoring Report - 2016 TABLES arcadis.com Table 1 Monitoring Well Construction Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Status Well Type TOC Elevation (2) Total Depth ��� Well Diameter (inches) Screen Interval (1) Avg Screen Elevation (2) MW-3 In Use Type II 99.03 20 2 NA - NA NA MW-5 Abandoned Type II 99.39 25.5 4 10.5 - 25.5 81.4 MW-5R In Use Type II NS 20 2 10 - 20 NA MW-6 In Use Type II 98.68 25.5 4 10.5 - 25.5 80.7 MW-6i In Use Type III 99.26 55 2 50 - 55 46.8 MW-8 Abandoned Type II 97.84 24 6 NA - NA NA MW-8R In Use Type II NS 20 2 10 - 20 NA MW-14 In Use Type II 100.44 22 4 7 - 22 85.9 MW-15 In Use Type II 99.91 22 4 7 - 22 85.4 MW-16 In Use Type II 97.42 25 2 10 - 25 79.9 MW-17 In Use Type II 100.00 22 4 7 - 22 85.5 MW-18 In Use Type II NS 20 2 10 - 20 NA MW-19 In Use Type II NS 20 2 10 - 20 NA Notes: 1. Reported in feet below grade 2. Measured in feet relative to site datum 3. Conestoga Rover and Associates, a former consultant for this Site, previously reported that no reference was found to the following wells: MW-1, MW-9, MW-10, MW-11, MW-12 or MW-13. These wells are presumed to be abandoned. 4. Monitoring wells MW-5 and MW-8 were abandoned on 5/19/2010 and replaced with monitoring wells MW-5R and MW-8R the same day. 5. Monitoring wells MW-18 and MW-19 were installated on October 25, 2011. NA = Not Applicable / Available NS = Not Surveyed TOC = Top of Casing Page 1 of 1 Table 2 Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina well Date Measured TOC Elevation Depath to LNAPL Depth to Groundwater (btoc) LNAPL Thickness Corrected Groudwater Elevation MW-3 9/19/2016 99.03 ND 13.92 0.00 85.1 MW-5R 9/19/2016 NM ND 13.99 0.00 NM MW-8R 9/19/2016 NM ND 13.91 0.00 NM MW-18 9/19/2016 NM ND 14.04 0.00 NM MW-19 9/19/2016 NM ND 13.75 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Corr. GW Elev. = (ref point elevation) - (depth to groundwater) + (LNAPL thickness)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 LNAPL = Light non -aqueous phase liquid ND = Not detected NM = Not measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing Page 1 of 1 Table 3 Groundwater Field Parameter Data, September 2016 Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Date DTW pH (s.u.) ORP (mV) Temperature (0C) Specific Conductance (MS/CM) DO (mg/L) MW-3 9/19/2016 13.92 6.76 71 24.33 0.884 0.00 MW-5R 9/19/2016 13.99 8.77 -99 23.21 9.04 0.00 MW-8R 9/19/2016 13.91 6.68 12 22.19 4.27 0.00 MW-18 9/19/2016 14.04 7.18 -65 22.91 2.65 12.16 MW-19 9/19/2016 13.75 1 6.13 86 22.60 3.67 0.00 Notes• ORP - oxidation-reduction potential DO - dissolved oxygen s.u. - standard units mV - millivolts °C - degrees Celsius mS/cm - milliSiemens per centimeter mg/L - milligrams per liter Page 1 of 1 Table 4 Summary of Groundwater Results, September 2016 Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, NC Sample ID MW-3 MW-5R MW-8R MW-18 MW-19 Date Sampled 9/19/2016 9/19/2016 9/19/2016 9/19/2016 9/19/2016 Units mg/L mg/L mg/L mg/L mg/L Sulfate 21.3 2880 1330 377 1270 Notes mg/L - milligrams per liter BOLD text indicates NC groundwater standard 2L exceendance of 250 mg/L Page 1 of 1 FIGURES CITY:— DNIGROUP:(ROW) DS:M-Vvos LD:M-VrgS PIC:(Opt) PM:(PAgd) TM:(Opt) LYR:(Opt)ON=•;OFF=•REfi P,+Eovironm to BP Foxglove IVIEAST%North Carollnaf24163iE-Drawingst24163_Figl.dwg LAYOUT:I SAVED: 1W19f20169:43AM AGADVER! 19-1S [LMSTECH] PAGESETUP, -•-• PLOTSTYLETABLE, PLTFULL.CTB PLOTTED, 11115J2016223 PM BYE DEVESH NAMBLE RNHDDD w Vlsta 3 �PADDINGION LN OB Rpra� ; 1� x^ 3 % r, x o SUSSE�Y2 1 PENNINGTON LN NW z AD OAT4 OR£ENgRI£R-RD , 4AIStN�VIRGINIARD �850 r';r iIELDALE AVE FDRESr DR °�" CAROLIHA CIR y REYNOLDS DR fi . 7 L� �, REyNOLDS DR NW WqR� ANGELO ST q0 4EDRGfA AVE - West zo C, Highlands �ro 8 RD Weswi ew �rr►,v RO `. 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AVE ' SITE LOCATION EL12A9E Ardmore ROSEWOOD AVE M � aIr. = QS�O� w WESTOVER DR`"i x 21 r �ZJ } ~ h GASTON ST Hanes , P1 �V FAIRWAY DR w u 4V,�� 5 MAPLEWODD AVE' y IpV µpp WOOD AVE SW ATLANTIC RICHFIELD COMPANY •• ! `cr fit' y'� �' Rs` - rZ ARDSLEY ST C 0 BP PRODUCTS NORTH AM ERICA, INC- �� L� LYNOHURST,AVE t FORMER BP STATION 24163 O,p © - ti 381 KNOLLWOOD ST-, WI NSTON-SALE M, NORTH CAROLINA S HAWTHORN£ RD 2nd SEMI-ANNUAL MONITORING REPORT - SEPTEMBER 2016 r B— e 2 syDyyACKER AVE 15 i r i SITE LOCATION MAP Park � bJ I p J WESTRIDGI, RD JEFFERSDN AVE x o HEALY DR G p k �G,� 3E q�^ PIGDRE West I;l a P+ ARCADI.S I EST AULL RD i�atic !� ! v CHEROKEE ST I 1 y ey �" M W-1 a Lu Lu ch N 0 0 rl 0 z !e ORA49 PARKING MW-17 d11 ASPRALT TRASH PARKING ENCl08URE M MSHMPORmERGkmLIkE ustAREA , 1 P FORMER I STAT _ 1 STATION �MW-5B woo d O MW 5R M -6 f Jf I ru�wo } J Mw-woo C TAM FORMER CANOPY • FORMER r—� VENT RISERS 0 MW-15 r F ORAtPR Qe _+ VENT RI$ZRC LEGEND: PROPERTY LINE r� ADM DON ED GROUNDWATER MONITORING WELL FORMER PRODUCT LINE a.9 CATCH BASIN Q sex MAN HOLE AREA LIGHT • u.". UTILITY POLE Yn. FIRE HYDRANT _ 'rFi cPHONE LARGE MANHOLE COVER GROUNDWATER MONITORING WELL NOTES: 1. MONITORING WELL LOCATIONS ARE APPROXIMATE 2. THE SITE IS A VACANT PARKING LOT. ALL SITE FEATURES EXCEPT PARKING LOT CURBS AND ROADWAYS REPRESENT FORMER SITE CHARACTERISTICS. D 30' IiC GRAPHIC SCALE I CEO SP PRODUCT$ NORTH AMERICA, INC, FORMER BP STATION 24163 381 KNOLLWOOO ST., WINSTON-SALEM, NORTH CRROLINA SITE MAP FIGUgE fh ARCADIS 2 0 a • _"tA'p 1 GriAS$ At H I FIAiHCING ,y M i •17 Ij� I PRR1[lµ RiKW)7 CRASH � ENCLCt611RE _ Li SHED I+ss.111 1 � ' Meru sNeo FORMER AR { FflAMER STATION n• 1 raW s PAW-14 r MW�5R M NM F.1{ r Fow�ww fNM) i�unrr.=I rvau�n MWBi ' fNM) _ J TW-g MW-19q� ffJM1y� ��1rwi FG ER I ronox-i[� T fTl � ° I CANOPY .001-0 VENT FIBERS VENT RLYERS 4 MW-15 ❑9 _ . FORMER YENT tetgpRS LEGEND: — — — PROPERTY LINE ABANDONED GROU NOWATER MON ITORI NG WELL FORMER PRODUCT LINE OCR CATCH BASIN O MR. MAN HOLE w{ AREA LIGHT 0 �P. LmLTTY POLE Fkl FIRE HYDRANT -TELEPHONE C LARGE MANHOLE COVER GROUNDWATER MONITORING WELL {B,R.11 j GROUNDWATER ELEVATION [FT AMSLj - HISTORICAL DEPICTED GROUNDWATER FLAW (FT AMSL) DIRECTION FT AMSL FEET ABOVE MEAN SEA LEVEL (NM) NOT MEASURED O 3W BP GRAPHIC SCALE n= mw-l6 N w W H 0 J J 0 2 Y 0 I d r, a • ��N7 GRA,45 PARKING M TER ,y M i •17 AMLT PARKING TRASH ENCLOSURE sr� M2rRL sFleo +F ' F • ARC ' FOWEA Data 11011312 1 J STATION MW18 M j MW 5R l,+w-easy ¢� 1 F.FL�I Kjl- — Pmv"pLw I4A»OPiYgI fOR1EP 1 GVCaY I FQF IER oow•7e� 3120TS a T AW v ❑ LFORIAER ° I _ CANOPY FORMER l - 0 VFM RMERS MW-15 ► M W-18 O� FORMER 1 1 VENT RelBERS LEGEND: - -- PROPERTYLINE 1 ABANDONED GROUNDWATER MONRORING WELL FORMER PRODUCT LINE CATCH BASIN ❑ µN MAN HOLE F► AREA LIGHT UTILITY POLE F" FIRE HYDRANT TELEPHONE LARGE MANHOLE COVER GROUNDWATER MONITORING WELL mwkL MILIGRAMS PER LITER LEGEND Abbreviation I Constituent 2L 504 I Sulfate 250 HATE: 1. THE NORTH CAROLINA 2L STANDARD FOR SULFATE IS 250 mot 2. BOLDED VALUES EXCEED NORTH CAROUNA 2L STANDARDS. 6 3W BP GRAPHIC SCALE low-+6 FGRASS w M pIAF ", .-F.. ,y i •t7 1� � ASP ALT TRH AARPOW EHCLr3WRE 8 HED ' SHED f ' Meru SHED ' FORMER (A -SOIL W AREA { ± FORMER 1 1 9P SERVICE ' � STAIILIN MW � T caxcra-rE mW-$ 2.080) x,esuy^ _ .BR FCNA1pRPWV �iaso> I��F*YP, Hyg4P L - awcPr -g MLV-14 r �a rowers wm ' FO ER4OL rowa:7e� a T ❑ L FF11-IR CANDPY I FORMER ETRI VENC RISERS - IN W-" .. FORMER VENTRISERS LEGEND: — - — PROPERTYLINE ABANDON ED GROUNDWATER MONITORING WELL FORMER PRODUCT LINE OCB. CATCH BASIN Q MN MAN HOLE W* AREA LIGHT ■ LP UTILITY POLE 4b "' FIRE HYDRANT TELEPHONE LARGE MANHOLE COVER GROUNDWATER MONITORING WELL [2,880y SULFATE CONCENTRATION ¢ngny ESTIMATED BENZENE CONCENTRATION CONTOUR 2L STANDARD (MWL) R1g1I MILLIGRAMS PER LITER NOTES: 1. THE NORTH CAROL INA X STANDARD POR SULFATE IS 754 nVL 0 3Y nC GRAPHIC SCALE M � � A,��I/A-A, Historical Groundwater Elevation Data Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Wen Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet bloc) (feet bloc) (feet) Elevation (1)(2) * 06/24/93 ND 13.89 0.00 85.14 08/23/94 ND 14.36 0.00 84.67 03/21/95 ND 13.58 0.00 85.45 08/05/96 ND 13.54 0.00 85.49 11/17/98 ND 14.09 0.00 84.94 06/19/01 ND 14.11 0.00 84.92 09/12/01 ND 14.41 0.00 84.62 12/27/01 ND 14.51 0.00 84.52 03/05/02 ND 14.29 0.00 84.74 05/13/03 ND 14.35 0.00 84.68 12/09/03 ND 13.63 0.00 85.40 03/23/06 ND 13.64 0.00 85.39 05/08/07 ND 13.40 0.00 85.63 05/14/08 ND 13.42 0.00 85.61 05/28/09 ND 13.31 0.00 85.72 05/27/10 ND 13.07 0.00 85.96 MW-3 10/31/11 99.03 ND 13.87 0.00 85.16 05/22/12 ND 13.55 0.00 85.48 06/14/12 ND 13.53 0.00 85.50 07/09/12 ND 13.98 0.00 85.05 08/14/12 ND 14.24 0.00 84.79 09/19/12 ND 14.08 0.00 84.95 12/05/12 ND 14.42 0.00 84.61 02/26/13 ND 13.55 0.00 85.48 05/31/13 ND 13.58 0.00 85.45 08/28/13 ND 13.57 0.00 85.46 11/07/13 ND 14.30 0.00 84.73 02/27/14 ND 13.28 0.00 85.75 06/02/14 ND 13.34 0.00 85.69 10/16/14 ND 14.18 0.00 84.85 04/23/15 ND 13.54 0.00 85.49 04/28/16 ND 13.51 0.00 85.52 09/19/16 ND 13.92 0.00 85.11 06/24/93 ND 13.51 0.00 85.88 08/23/94 ND 13.82 0.00 85.57 03/21/95 ND 13.71 0.00 85.68 08/05/96 ND 13.54 0.00 85.85 11/17/98 ND 14.08 0.00 85.31 06/19/01 NM NM NM NM 09/12/01 ND 14.46 0.00 84.93 MW-5 12/27/01 99.39 14.51 15.07 0.56 84.73 03/05/02 14.45 14.88 0.43 84.82 05/12/03 NM NM NM NM 12/09/03 13.18 13.60 0.42 86.10 03/23/06 ND 13.67 0.00 85.72 05/08/07 ND 13.45 0.00 85.94 05/14/08 ND 13.51 0.00 85.88 05/28/09 ND 13.39 0.00 86.00 05/27/10 ND 13.70 0.00 NM 10/31/11 ND 13.97 0.00 NM 05/22/12 ND 13.66 0.00 NM 06/14/12 ND 13.73 0.00 NM 07/09/12 ND 14.18 0.00 NM 08/14/12 ND 14.45 0.00 NM 09/19/12 ND 14.35 0.00 NM 12/05/12 ND 14.68 0.00 NM 02/26/13 ND 13.89 0.00 NM NM-5R 05/31/13 NS ND 13.77 0.00 NM 08/28/13 ND 13.83 0.00 NM 11/07/13 ND 14.53 0.00 NM 02/27/14 ND 13.39 0.00 NM 06/02/14 ND 13.47 0.00 NM 10/16/14 ND 14.32 0.00 NM 04/23/15 ND 13.69 0.00 NM 10/13/15 ND 14.19 0.00 NM 04/28/16 ND 13.61 0.00 NM 09/19/16 ND 13.99 0.00 NM Page 1 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet btoc) (feet bloc) (feet) Elevation (1)(2) * 06/24/93 ND 12.31 0.00 86.37 08/23/94 ND 12.61 0.00 86.07 03/21/95 ND 13.15 0.00 85.53 08/05/96 ND 12.39 0.00 86.29 11/17/98 ND 13.16 0.00 85.52 06/19/01 NM NM NM NM 09/12/01 ND 13.51 0.00 85.17 12/27/01 ND 13.61 0.00 85.07 MW 6 03/05/02 98.68 ND 11.02 0.00 87.66 05/12/03 ND 11.10 0.00 87.58 12/09/03 ND 13.49 0.00 85.19 03/23/06 ND 11.79 0.00 86.89 05/08/07 ND 12.50 0.00 86.18 05/14/08 ND 12.16 0.00 86.52 05/28/09 ND 10.64 0.00 88.04 05/27/10 ND 11.84 0.00 86.84 10/31/11 ND 12.95 0.00 85.73 06/02/14 ND 12.38 0.00 86.30 06/24/93 ND NM 0.00 NM 08/23/94 ND NM 0.00 NM 03/21/95 ND 14.75 0.00 84.51 08/05/96 ND 14.13 0.00 85.13 11/17/98 ND 14.09 0.00 85.17 06/19/O1 ND 18.07 0.00 81.19 09/12/O1 ND 16.60 0.00 82.66 12/27/01 ND 14.61 0.00 84.65 03/05/02 ND 14.96 0.00 84.30 MW-6i 05/12/03 99.26 ND 15.17 0.00 84.09 12/09/03 ND 13.55 0.00 85.71 03/23/06 ND 13.55 0.00 85.71 05/08/07 ND 12.93 0.00 86.33 05/14/08 ND 13.22 0.00 86.04 05/28/09 ND 13.39 0.00 85.87 05/27/10 ND 13.23 0.00 86.03 10/31/11 ND 13.90 0.00 85.36 06/02/14 ND 13.35 0.00 85.91 04/28/16 ND 13.55 0.00 85.71 * 08/23/94 ND 12.14 0.00 85.70 * 03/21/95 ND 12.02 0.00 85.82 * 08/05/96 ND 11.99 0.00 85.85 * 11/17/98 ND 12.53 0.00 85.31 * 06/19/01 NM NM NM NM * 09/12/01 ND 12.67 0.00 85.17 MW 8 * 12/27/O1 97.84 14.47 15.03 0.56 83.26 * 03/05/02 12.42 12.60 0.18 85.38 05/12/03 NM NM NM NM 12/09/03 13.32 13.56 0.24 84.47 03/23/06 ND 12.15 0.00 85.69 05/08/07 ND 11.90 0.00 85.94 05/14/08 ND 11.95 0.00 85.89 05/28/09 ND 11.70 0.00 86.14 Page 2 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet btoc) (feet bloc) (feet) Elevation (1)(2) 05/27/10 ND 12.97 0.00 NM 10/31/11 ND 13.34 0.00 NM 05/22/12 ND 13.69 0.00 NM 06/14/12 ND 14.94 0.00 NM 07/09/12 ND 14.08 0.00 NM 08/14/12 ND 14.29 0.00 NM 09/19/12 ND 14.08 0.00 NM 12/05/12 ND 14.53 0.00 NM 02/26/13 ND 13.80 0.00 NM MW-8R 05/31/13 NS ND 13.61 0.00 NM 08/28/13 ND 13.74 0.00 NM 11/07/13 ND 14.42 0.00 NM 02/27/14 ND 13.33 0.00 NM 06/02/14 ND 13.34 0.00 NM 10/16/14 ND 14.18 0.00 NM 04/23/15 ND 13.57 0.00 NM 10/13/15 ND 14.08 0.00 NM 04/28/16 ND 13.53 0.00 NM 09/19/16 ND 13.91 0.00 NM 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 13.55 0.00 86.89 08/05/96 ND 13.64 0.00 86.80 11/17/98 ND 14.26 0.00 86.18 06/19/O1 ND 14.55 0.00 85.89 09/12/01 ND 14.81 0.00 85.63 12/27/01 ND 14.85 0.00 85.59 03/05/02 ND 14.64 0.00 85.80 MW-14 05/12/03 100.44 ND 13.41 0.00 87.03 12/09/03 ND 13.51 0.00 86.93 03/23/06 ND 13.82 0.00 86.62 05/08/07 ND 13.54 0.00 86.90 05/14/08 ND 13.64 0.00 86.80 05/28/09 ND 13.47 0.00 86.97 05/27/10 ND 13.00 0.00 87.44 10/13/11 ND 14.14 0.00 86.30 06/02/14 ND 13.42 0.00 87.02 04/28/16 ND 13.65 0.00 86.79 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.83 0.00 87.08 08/05/96 ND 12.77 0.00 87.14 11/17/98 ND 13.58 0.00 86.33 06/19/O1 ND 13.80 0.00 86.11 09/12/01 ND 14.18 0.00 85.73 12/27/01 ND 14.29 0.00 85.62 03/05/02 ND 13.98 0.00 85.93 MW-15 05/12/03 99.91 NM 12.75 NM 87.16 12/09/03 ND 12.89 0.00 87.02 03/23/06 ND 13.14 0.00 86.77 05/08/07 ND 12.90 0.00 87.01 05/14/08 ND 13.12 0.00 86.79 05/28/09 ND 12.90 0.00 87.01 05/27/10 ND 12.25 0.00 87.66 10/31/11 ND 13.61 0.00 86.30 06/02/14 ND 12.82 0.00 87.09 10/16/14 ND 13.91 0.00 86.00 04/28/16 ND 13.15 0.00 86.76 Page 3 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina TOC Depth to Depth to LNAPL Corrected Well Date Elevation LNAPL Groundwater Thickness Groundwater -1 (feet btoc) (feet bloc) (feet) Elevation (1)(2) 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 12.06 0.00 85.36 08/05/96 ND 12.09 0.00 85.33 11/17/98 ND 12.60 0.00 84.82 06/19/01 ND 12.74 0.00 84.68 09/12/01 ND 12.98 0.00 84.44 12/27/01 NM NM NM NM 03/05/02 ND 12.83 0.00 84.59 MW-16 05/12/03 97.42 NM NM NM NM 12/09/03 ND 12.13 0.00 85.29 03/23/06 ND 12.18 0.00 85.24 05/08/07 NM NM NM NM 05/14/08 ND 12.03 0.00 85.39 05/28/09 ND 11.96 0.00 85.46 05/27/10 ND 11.69 0.00 85.73 10/31/11 ND 12.45 0.00 84.97 11/07/13 ND 12.88 0.00 84.54 06/02/14 ND 11.97 0.00 85.45 06/24/93 NM NM NM NM 08/23/94 NM NM NM NM 03/21/95 ND 14.42 0.00 85.58 08/05/96 ND 14.46 0.00 85.54 11/17/98 ND 14.91 0.00 85.09 06/19/01 ND 15.03 0.00 84.97 09/12/01 ND 15.28 0.00 84.72 12/27/O1 ND 15.37 0.00 84.63 03/05/02 ND 15.15 0.00 84.85 MW-17 05/12/03 100.00 NM 14.15 NM 85.85 12/09/03 ND 14.50 0.00 85.50 03/23/06 ND 14.45 0.00 85.55 05/08/07 ND 14.22 0.00 85.78 05/14/08 ND 14.22 0.00 85.78 05/28/09 ND 14.12 0.00 85.88 05/27/10 ND 13.90 0.00 86.10 10/31/11 ND 14.72 0.00 85.28 06/02/14 ND 14.14 0.00 85.86 04/28/16 ND 14.36 0.00 85.64 10/31/11 ND 13.95 0.00 NM 05/22/12 ND 14.10 0.00 NM 06/14/12 ND 13.61 0.00 NM 07/09/12 ND 14.05 0.00 NM 08/14/12 ND 14.43 0.00 NM 09/19/12 ND 14.34 0.00 NM 12/05/12 ND 14.62 0.00 NM 02/26/13 ND 14.67 0.00 NM MW-18 05/31/13 NS ND 14.57 0.00 NM 08/28/13 ND 14.33 0.00 NM 11/07/13 ND 14.51 0.00 NM 02/27/14 ND 13.76 0.00 NM 06/02/14 ND 13.55 0.00 NM 10/16/14 ND 14.37 0.00 NM 04/23/15 ND 13.84 0.00 NM 10/13/15 ND 14.81 0.00 NM 04/28/16 ND 13.62 0.00 NM 09/19/16 ND 14.04 0.00 NM Page 4 of 5 Appendix A Historical Groundwater Elevation Data Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Date TOC Elevation -1 Depth to LNAPL (feet btoc) Depth to Groundwater ( LNAPL Thickness (feet) Corrected Groundwater Elevation (1)(2) 10/31/11 ND 13.75 0.00 NM 05/22/12 ND 13.37 0.00 NM 06/14/12 ND 13.39 0.00 NM 07/09/12 ND 13.89 0.00 NM 08/14/12 ND 14.13 0.00 NM 09/19/12 ND 14.02 0.00 NM 12/05/12 ND 14.39 0.00 NM 02/26/13 ND 13.62 0.00 NM 05/31/13 ND 13.47 0.00 NM MW-19 NS 08/28/13 ND 13.56 0.00 NM 11/07/13 ND 14.25 0.00 NM 02/27/14 ND 13.17 0.00 NM 06/02/14 ND 13.14 0.00 NM 10/16/14 ND 14.03 0.00 NM 04/23/15 ND 13.46 0.00 NM 10/13/15 ND 14.01 0.00 NM 04/28/16 ND 13.38 0.00 NM 09/19/16 ND 13.75 0.00 NM Notes: 1. Measured in feet relative to site datum 2. Con. GW Elev. = (ref point elevation) - (depth to groundwater) + (LNAPL thiclmess)(LNAPL specific gravity) 3. LNAPL specific gravity assumed to be 0.73 » Monitoring well MW-3 was previously reported as MW-2, monitoring well MW-6 was previously reported as MW-8, and monitoring well MW-8 was previously been reported as MW-6. LNAPL = Light non -aqueous phase liquid ND = Not detected NM = Not measured NS = Not Surveyed TOC = Top of casing btoc = below top of casing - During the May 2003 sampling event LNAPL was observed in MW-5. Depth to groundwater and thickness of LNAPL were not measured. Page 5 of 5 Laboratory Analytical Report and Chain -of -Custody Record — September 19, 2016 TestAmerica ° THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel: (615)726-0177 TestAmerica Job ID: 490-112156-1 TestAmerica SDG: 381 Knollwood St, Winston-Salem, NC Client Project/Site: Former BP Facility #24163 ror: ARCADIS U.S., Inc. 801 Corporate Center Drive Suite 300 Raleigh, North Carolina 27607-5073 Attn: Paul Goodell ie*'_� Authorized for release by. 101512016 10:01:56 PM Jennifer Huckaba, Project Manager II (615)301-5042 jennifer.huckaba@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Table of Contents CoverPage .............................................. 1 Table of Contents ......................................... 2 Sample Summary ......................................... 3 Case Narrative ........................................... 4 Definitions............................................... 5 Client Sample Results ...................................... 6 QC Sample Results ........................................ 11 QC Association ........................................... 13 Chronicle................................................ 14 Method Summary ......................................... 15 Certification Summary ...................................... 16 Chain of Custody .......................................... 17 Receipt Checklists ......................................... 19 TestAmerica Nashville Page 2 of 19 10/5/2016 Sample Summary Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-112156-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St, Winston-Salem, NC Lab Sample ID Client Sample ID Matrix Collected Received 490-112156-1 MW-5R Ground Water 09/19/16 14:05 09/21/16 09:45 490-112156-2 MW-8R Ground Water 09/19/16 14:30 09/21/16 09:45 490-112156-3 MW-18 Ground Water 09/19/16 13:15 09/21/16 09:45 490-112156-4 MW-19 Ground Water 09/19/16 15:10 09/21/16 09:45 490-112156-5 MW-3 Ground Water 09/19/16 15:40 09/21/16 09:45 TestAmerica Nashville Page 3 of 19 10/5/2016 Case Narrative C Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-112156-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St, Winston-Salem, NC Job ID: 490-112156-1 Laboratory: TestAmerica Nashville Narrative Job Narrative 490-112156-1 Comments Sulfate method was switched to 9056A to match the matrix. The Carbon Dioxide and Alkalinity were cancelled per client request. Receipt The samples were received on 9/21/2016 9:45 AM; the samples arrived in good condition, properly preserved and, where required, on ice The temperature of the cooler at receipt was 3.91 C. HPLC/IC Method(s) 9056, 9056A: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for analytical batch 490-373905 were outside control limits. Sample matrix interference and/or non -homogeneity are suspected because the associated laboratory control sample / laboratory control sample duplicate (LCS/LCSD) recoveries were within the acceptance limits. Method(s) 9056A: The following samples were diluted due to the nature of the sample matrix: MW-5R (490-112156-1), MW-8R (490-112156-2), MW-18 (490-112156-3) and MW-19 (490-112156-4). Elevated reporting limits (RLs) are provided. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. C TestAmerica Nashville Page 4 of 19 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Qualifiers :I;JIlMC« Definitions/Glossary C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Qualifier Qualifier Description 4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not applicable. E Result exceeded calibration range. Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. n Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CNF Contains no Free Liquid DER Duplicate error ratio (normalized absolute difference) Dil Fac Dilution Factor DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision level concentration MDA Minimum detectable activity EDL Estimated Detection Limit MDC Minimum detectable concentration MDL Method Detection Limit MIL Minimum Level (Dioxin) NC Not Calculated ND Not detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative error ratio RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) TestAmerica Nashville Page 5 of 19 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-5R Date Collected: 09/19/16 14:05 Date Received: 09/21/16 09:45 Client Sample Results C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 2880 Lab Sample ID: 490-112156-1 Matrix: Ground Water RL MDL Unit D Prepared Analyzed Dil Fac 100 mg/L 09/29/16 21:38 100 TestAmerica Nashville Page 6 of 19 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample Results C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Client Sample ID: MW-8R Lab Sample ID: 490-112156-2 Date Collected: 09/19/16 14:30 Matrix: Ground Water Date Received: 09/21/16 09:45 Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 1330 RL MDL Unit D Prepared Analyzed Dil Fac 100 mg/L 09/29/16 21:49 100 TestAmerica Nashville Page 7 of 19 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-18 Date Collected: 09/19/16 13:15 Date Received: 09/21/16 09:45 Client Sample Results C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 377 Lab Sample ID: 490-112156-3 Matrix: Ground Water RL MDL Unit D Prepared Analyzed Dil Fac 100 mg/L 09/29/16 22:00 100 TestAmerica Nashville Page 8 of 19 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-19 Date Collected: 09/19/16 15:10 Date Received: 09/21/16 09:45 Client Sample Results C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 1270 Lab Sample ID: 490-112156-4 Matrix: Ground Water RL MDL Unit D Prepared Analyzed Dil Fac 100 mg/L 09/29/16 22:12 100 TestAmerica Nashville Page 9 of 19 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-3 Date Collected: 09/19/16 15:40 Date Received: 09/21/16 09:45 Client Sample Results C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Analyte Result Qualifier Sulfate 21.3 Lab Sample ID: 490-112156-5 Matrix: Ground Water RL MDL Unit D Prepared Analyzed Dil Fac 1.00 mg/L 09/28/1618:12 1 TestAmerica Nashville Page 10 of 19 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 QC Sample Results C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography Lab Sample ID: MB 490-373905/3 Matrix: Water Analysis Batch: 373905 MB MB Analyte Result Qualifier Sulfate ND Lab Sample ID: LCS 490-373905/4 Matrix: Water Analysis Batch: 373905 Analyte Sulfate Lab Sample ID: LCSD 490-373905/5 Matrix: Water Analysis Batch: 373905 Analyte Sulfate Lab Sample ID: 490-112156-1 MS Matrix: Ground Water Analysis Batch: 373905 Sample Sample Analyte Result Qualifier Sulfate 1740 E Lab Sample ID: 490-112156-1 MSD Matrix: Ground Water Analysis Batch: 373905 Sample Sample Analyte Result Qualifier Sulfate 1740 E Lab Sample ID: MB 490-374278/3 Matrix: Water Analysis Batch: 374278 MB MB Analyte Result Qualifier Sulfate ND Lab Sample ID: LCS 490-374278/4 Matrix: Water Analysis Batch: 374278 Analyte Sulfate Client Sample ID: Method Blank Prep Type: Total/NA L RL MDL Unit D Prepared Analyzed Dil Fac 1.06 mg/L 09/28/1616:32 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec. Added Result Qualifier Unit D %Rec Limits 10.0 9.425 mg/L 94 80 - 120 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec. RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 10.0 9.413 mg/L 94 80 - 120 0 20 Client Sample ID: MW-5R Prep Type: Total/NA Spike MS MS %Rec. Added Result Qualifier Unit D %Rec Limits 2.00 1453 E 4 mg/L -1453 80 - 120 7 Client Sample ID: MW-5R Prep Type: Total/NA Spike MSD MSD %Rec. RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 2.00 1452 E 4 mg/L -1457 80 - 120 0 20 4 Client Sample ID: Method Blank Prep Type: Total/NA RL MDL Unit D Prepared Analyzed Dil Fac 1.00 mg/L 09/29/1619:36 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Rec. Added Result Qualifier Unit D %Rec Limits 10.0 9.861 mg/L 99 80 - 120 Page 11 of 19 TestAmerica Nashville 10/5/2016 QC Sample Results Client: ARCADIS U.S., Inc. TestAmerica Job ID: 490-112156-1 Project/Site: Former BP Facility #24163 SDG: 381 Knollwood St, Winston-Salem, NC Method: 9056A - Anions, Ion Chromatography (Continued) Lab Sample ID: LCSD 490-37427815 Client Sample ID: Lab Control Sample Dup Matrix: Water Prep Type: Total/NA Analysis Batch: 374278 Spike LCSD LCSD %Rec. RPD Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 10.0 9.892 mg/L 99 80.120 0 20 Lab Sample ID: 490-112667-G-2 MS Client Sample ID: Matrix Spike Matrix: Water Prep Type: Total/NA Analysis Batch: 374278 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Sulfate 1890 E 2.00 1574 E 4 — mg/L - 5585 80 - 120 1 Lab Sample ID: 490-112667-G-2 MSD Client Sample ID: Matrix Spike Duplicate Matrix: Water Prep Type: Total/NA Analysis Batch: 374278 Sample Sample Spike MSD MSD %Rec. RPD Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit Sulfate 1890 E 2.00 1561 E 4 mg/L -1648 80.120 1 20 9 TestAmerica Nashville Page 12 of 19 10/5/2016 QC Association Summary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC HPLUC Analysis Batch: 373905 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 490-112156-5 MW-3 Total/NA Ground Water 9056A MB 490-373905/3 Method Blank Total/NA Water 9056A LCS 490-373905/4 Lab Control Sample Total/NA Water 9056A LCSD 490-373905/5 Lab Control Sample Dup Total/NA Water 9056A 490-112156-1 MS MW-5R Total/NA Ground Water 9056A 490-112156-1 MSD MW-5R Total/NA Ground Water 9056A Analysis Batch: 374278 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 490-112156-1 MW-5R Total/NA Ground Water 9056A 490-112156-2 MW-8R Total/NA Ground Water 9056A 490-112156-3 MW-18 Total/NA Ground Water 9056A 490-112156-4 MW-19 Total/NA Ground Water 9056A MB 490-374278/3 Method Blank Total/NA Water 9056A LCS 490-374278/4 Lab Control Sample Total/NA Water 9056A LCSD 490-374278/5 Lab Control Sample Dup Total/NA Water 9056A 490-112667-G-2 MS Matrix Spike Total/NA Water 9056A 490-112667-G-2 MSD Matrix Spike Duplicate Total/NA Water 9056A Page 13 of 19 TestAmerica Nashville 10/5/2016 Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Client Sample ID: MW-5R Date Collected: 09/19/16 14:05 Date Received: 09/21/16 09:45 Batch Batch Prep Type Type Method Total/NA Analysis 9056A Client Sample ID: MW-8R Date Collected: 09/19/16 14:30 Date Received: 09/21/16 09:45 Batch Batch Prep Type Type Method Total/NA Analysis 9056A Client Sample ID: MW-18 Date Collected: 09/19/16 13:15 Date Received: 09/21/16 09:45 Lab Chronicle C TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Lab Sample ID: 490-112156-1 Matrix: Ground Water Dil Initial Final Batch Prepared Run Factor Amount Amount Number or Analyzed Analyst Lab 100 374278 09/29/16 21:38 NC TAL NSH Lab Sample ID: 490-112156-2 Matrix: Ground Water Dil Initial Final Batch Prepared Run Factor Amount Amount Number or Analyzed Analyst Lab 100 374278 09/29/16 21:49 NC TAL NSH Lab Sample ID: 490-112156-3 Matrix: Ground Water Prep Type Batch Type Batch Method Dil Initial Run Factor Amount Total/NA Analysis 9056A 100 Client Sample ID: MW-19 Date Collected: 09/19/16 15:10 Date Received: 09/21/16 09:45 Batch Prep Type Type Batch Method Total/NA Analysis 9056A Final Batch Prepared Amount Number or Analyzed Analyst Lab 374278 09/29/16 22:00 NC TAL NSH Lab Sample ID: 490-112156-4 Matrix: Ground Water Dil Initial Final Batch Prepared Run Factor Amount Amount Number or Analyzed Analyst Lab 100 374278 09/29/16 22:12 NC TAL NSH Client Sample ID: MW-3 Lab Sample ID: 490-112156-5 Date Collected: 09/19/16 15:40 Matrix: Ground Water Date Received: 09/21/16 09:45 F Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis 9056A 1 373905 09/28/16 18:12 LDC TAL NSH Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 Page 14 of 19 TestAmerica Nashville 10/5/2016 Method Summary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC Method Method Description Protocol Laboratory 9056A Anions, Ion Chromatography SW846 TAL NSH Protocol References: SW846 ='Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 TestAmerica Nashville Page 15 of 19 10/5/2016 Certification Summary Client: ARCADIS U.S., Inc. Project/Site: Former BP Facility #24163 Laboratory: TestAmerica Nashville The certifications listed below are applicable to this report. TestAmerica Job ID: 490-112156-1 SDG: 381 Knollwood St, Winston-Salem, NC F_ Authority Program EPA Region Certification ID Expiration Date North Carolina (WW/SW) State Program 4 387 12-31-16 TestAmerica Nashville Page 16 of 19 10/5/2016 TestAmeriaa 490_112156 Chain otCustody ium,,ur THE Lf_IDER 114 ENVIROWAENTAL TESTING ---"-'�-- -- --.- _ Nashville, TN COOLER RECEIPT FORIM Cooler Received/Opened On 912112015 a 0945 Time Samples Removed Fi, ooler 10 Time Samples Placed In Storage 145 (2 Hour Window) Y 1. Tracking # LJ (last 4 digits, FedEx) Courier: _Fed Ex_ ]R Gun I❑ 17960357 pH Strip Lot HC551117 Chlorine Strip Lot 040715C 2. Temperature of rep. sample or temp blank when opened:�Degrees Celsius 3. If Item #2 temperature is 0°C or less, was the representative sample or temp blank frozen? YES NO.t4 4. Were custody seals on outside of cooler? NO. If yes, how man and where: I — 5. Were the seals intact, signed, and dated correctly? NO...NA 6. Were custody papers inside cooler? ...NO...NA I certify that I opened the cooler and answered questions 1-6 {intial] 7. Were custody seals on containers: YES and Intact YES.,.NO.,& Were these signed and dated correctly? YES...No-.-o 8. Packing mat'] used? Bubdlewrap Plastic bag Peanuts Vermiculite Foam Insert Paper Other one 9. Goofing process: Ice Ice -pack ra {direct canto } Dry ice Other None 10. Did all containers arrive in good condition {unbroken}? tS..NO_.NA 11. Were all container labels complete (#, date, signed, pres., etc)7 (D..N0_.NA 12" Did all container labels and tags agree with custody papers? <a".NO... NA 13a. Were VOA vials received? YES,,(S).NA b. Was there any observable head space present in any VOA vial? YES_NO. [ 14. Was there a Trip Blank in this tooter? YE5...NO_9M If multiple coolers, sequence # I certifV that I unloaded the cooler and answered questions 7.14 (intial) Jo hy" _ 15a. On pres'd bottles, did pH test strips suggest preservation reached the correct pH level? YES..NO� b. Aid the bottle labels Indicate that the correct preservatives were used YES ... NO..9!%: 16. Was residual chlorine present? YES.."NO""C'D I certify that I cliecked for chlorine and pH as per SOP and answered questions 15-16 (intial) d ►UOM 17. Were custody papers properlyfilled out (ink, signed, etc)? .NO...NA 18. Did you sign the custody papers in the appropriate place? 1 Ec .. O_NA 19. Were correct containers used for the analysis requested? (55.N0...NA 20. Was sufficient amount of sample sent in each container? 0E 1..No...NA I certify that 1 entered this project into LIMS and answered questions 17-20 (intial) ,.,e, 'I -- I certify that I attached a label with the unique LIMS number to each container lintial) oaj} � 21. Were there Non -Conformance issues at Iog1n7 YES-195was a NCM generated? YES.. +E , # BIS = $10kL11 in shipment Cooler llmvipt Furrn,doc i_f'-1 RvvisM 12115115 End of Form Page 17 of 19 10/5/2016 Loc: 490 112156 N ll) O TestAmeri 515-7264177 C ea Y850 FI11aster Clre ghton TPhone: all Free: 300.76541M SHE LEAOCR IN CNV,RONMENTAL, TESTING-. NashNlle, TN 37204 Fax: 615-72&34114 Consultant Name: ARCADIS TA Account Ilk PO#: � A"rerm 111-DSoneem Lane! Invoice Te: ACCOUNTSPAYABLE.AUMINISTRATION ARGAUIS-US.Ct7 CitylftateMp: BLUEKIELD, VA 2460 Report To: Paul Goodell Consultant Project Mgr. Paul Goodell Project Name: Former BP Faclll *24163 C onsultam. Telephone Number. 919415-2327 Fax No,: 276322.3946 Retail (MRN ik 24163 Sampler Natne2 (Prin)�x �� Mgjor Project (AFEJ{k Sampler Signature: ✓L site Address 381 Kno,b000d St City, State, by Winston-Salem. North CamnIna Regulatory District (CA) c n 0 O 61 e p m a sanylo ID or Field 14 p x v x x S r3 o S� i ❑ rj F MW-6R f .i�•a+� J / f9 1 x % 1 MW-8R 1 x / 1 x / !7 MW-18 7315 1 x 1 % MW-19 /S70 1 x 1 x Q I�.0 0 Commontsfspeew InSVVtgow Laboratory ccrm anted-- Tomoarelure upon Receipt �= ` Sample Contalners Intact? V N VOCs Frft of NBaogpaco? Y N �e . ta- e1.1. �a,2 �.I3 L&M4 OM Rear�YlEh l+� d! Pete Tlme Re O-W inre fig.aO-I� km �r dal���- cap.ad.iG ]6� RdnquWiad W-- Del. Time R. Ned yy- D f . rmn Q-v'R+ � ,.w ",f - It well he the mporsibi IIV of SP or Its eansuKard W notify the TestAmerka ProAct Msmger Reflngrruhed by Ll 9 Timo Recefvrd by TcMAMMM Darr Tlme by phone or Fax thata Risk sam*ulll be submitted. TA Pro eu Manager. Dale: O 00 N CM ca d Login Sample Receipt Checklist Client: ARCADIS U.S., Inc. Login Number: 112156 List Number: 1 Creator: McBride, Mike Question Job Number: 490-112156-1 SDG Number: 381 Knollwood St, Winston-Salem, NC List Source: TestAmerica Nashville Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. N/A The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A TestAmerica Nashville Page 19 of 19 10/5/2016 APPENDIX C Historical Groundwater Analytical Data Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene Xylenes (Total) MTBE Sulfate arbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 1 1 1 1 m l Mg/1 MW-3 5/13/2003 8.5 0.98 J 0.61 J 1.7 J 8 12/9/2003 47.4 14.3 1.9 8.1 37.3 3/23/2006 4.5 J < 0.5 < 0.5 UJ < 1 UJ 5.5 5/8/2007 40.4 3.7 1.4 2 J 13.1 5/14/2008 4.3 J < 0.8 < 0.7 < 0.8 14 5/28/2009 5.4 0.44 J 0.14 J 0.49 J 5.6 5/27/2010 0.44 J < 0.11 0.3 J < 0.32 4.8 10/31/2011 5.5 0.76 < 0.17 U 0.38 J 19.1 8.4 405 5/22/2012 < 0.43 U < 0.2 < 0.2 < 0.52 4.6 15.3 378 6/14/2012 12.1 6.7 0.72 4.7 15.4 6.6 J 344 7/9/2012 2.2 1.6 2.6 3 14.7 9.9 393 8/14/2012 2 2.1 <0.13 0.4J 17.9 3.6 303 9/19/2012 2.7 0.66 < 0.13 0.33 J 19.8 2.8 459 12/5/2012 11.3 1.2 0.43 J 1.11 19.3 0.78 J 377 2/26/2013 0.23 J < 0.1 < 0.1 < 0.22 5.4 32.6 338 5/31/2013 0.32 J < 0.1 < 0.1 < 0.22 10.5 17.9 334 8/28/2013 3.6 0.53 0.12 J 0.31 J 10.3 21.9 457 11/7/2013 4.3 0.27 J 0.13 J < 0.22 10 21.7 536 2/27/2014 < 0.1 < 0.1 < 0.1 < 0.2 1.3 42.2 198 6/3/2014 0.48 J 0.15 J < 0.1 < 0.2 3.1 10/16/2014 -- -- -- 18.0 372 4/23/2015 -- -- -- 22.8 296 9/19/2016 -- -- 21.3 MW-5 3/23/2006 11,700 2,440 32,000 13,500 16,100 3/23/2006 "' 11,000 2,370 30,700 13,200 15,400 5/8/2007 7,410 1,590 21,100 8,920 8,830 5/8/2007 (" 7,400 1,680 20,100 9,290 9,360 5/14/2008 10,000 2,100 29,000 12,000 18,000 5/14/2008(" 10,000 2,100 30,000 12,000 18,000 5/28/2009 7,390 2,330 25,700 13,400 6,920 5/28/2009 (1) 1 6,510 2,240 22,100 12,900 6,510 MW-5R 5/27/2010 6,610 2,810 24,300 J 15,700 4,330 5/27/2010 (" 6,090 2,380 30,100 J 13,300 4,250 10/31/2011 7,960 2,660 28,000 13,800 3,830 < 1 < 5 10/31/2011 (" 8,360 2,870 24,600 14,800 4,070 5/22/2012 7,980 3,470 32,200 19,200 3,820 < 5 179 6/15/2012 (2) 244 227 1,190 1,120 36.9 6,070 1,820 7/9/2012 336 J 481 J 2,010 J 2,400 J 48.4 J 6,470 2,620 8/14/2012 201 283 1,050 1,300 48.5 14,700 4,190 9/19/2012 158 181 650 883 114 19,000 3,280 12/5/2012 754 505 2,220 2,380 1,160 13,600 1,840 2/26/2013 1,360 878 3,520 3,940 1,660 8,520 1,530 5/31/2013 1,410 1,380 5,930 6,220 1,150 J 4,680 1,560 8/28/2013 165 178 489 1,380 417 13,900 1,590 11/7/2013 214 131 331 969 651 14,400 1,570 2/27/2014 1 142 177 328 1,060 240 2,990 807 Page 1 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene Xylenes (Total) MTBE Sulfate arbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 1 1 1 1 m l m l MW-SR 6/2/2014 256 436 1040 2520 519 J 10/16/2014 -- -- -- 9,950 1,390 4/23/2015 - 5,980 1,510 10/13/2015 5,790 4/28/2016 2,980 9/19/2016 -- -- 2,880 MW-6 5/12/2003 < 0.5 0.52 J < 0.5 < 1 3 12/9/2003 2.3 0.64 J 1.1 1 3.6 17.6 12/9/2003 2.4 0.68 J 1.1 3.8 18 3/23/2006 0.76 J 0.59 J 3.6 2.8 J 1.1 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 5/28/2009 < 0.06 < 0.05 < 0.06 < 0.14 0.17 J 5/27/2010 < 0.11 0.13 J 0.38 J 0.46 J < 0.12 10/31/2011 8.7 J 11.7 J 27.5 J 132 J <0.26 UJ 131 2,130 6/2/2014 17.6 J 59.4 J 31.6 J 99.4 J 783 J MW-6I 5/12/2003 < 0.5 < 0.5 < 0.5 1.11 < 0.5 12/9/2003 < 2.5 < 2.5 < 2.5 < 5 < 2.5 3/23/2006 49.7 18.9 48.7 443 3,560 5/8/2007 < 25 < 25 < 25 < 50 6,910 5/14/2008 5.2 J < 2 < 1.8 < 2 3,400 5/28/2009 2.5 < 0.05 < 0.06 < 0.14 1,150 5/27/2010 1.6 J < 1.1 < 1.1 < 3.2 492 10/31/2011 0.41 J < 0.36 < 0.32 < 0.75 122 < 1 76.1 6/2/2014 < 0.1 < 0.1 < 0.1 < 0.2 3.3 MW 8 3/23/2006 671 1,340 1,230 8,100 124 5/8/2007 1,160 799 196 2,990 1,440 5/14/2008 600 1,800 700 3,000 190 5/28/2009 1,390 2,050 357 3,310 1,560 MW-8R 5/27/2010 8,570 2,870 31,700 15,700 6,260 10/31/2011 8,000 3,180 32,100 17,200 3,170 1 < 1 < 5 5/22/2012 8,270 3,360 36,400 J 17,800 3,920 < 5 119 6/15/2012 (2) 726 47 J 760 242 J 96.3 J 4,760 22,200 7/9/2012 4,540 J 1,870 J 17,100 J 10,800 J 1,530 J 6,570 4,500 8/14/2012 4,370 1,610 19,300 8,780 2,000 7,010 1,560 9/19/2012 4,780 1,800 20,900 10,400 2,600 6,700 1,100 12/5/2012 7,760 2,440 31,900 13,800 4,560 2,410 635 2/26/2013 7,310 2,480 30,500 13,400 4,530 959 590 5/31/2013 6,540 3,040 30,500 1 12,500 4,200 439 437 8/28/2013 1,600 628 5,390 3,990 1,380 4,770 703 11/7/2013 1,130 329 2,440 1,830 1,770 7,460 766 2/27/2014 1,020 603 3,200 3,430 1,190 7,670 940 6/2/2014 1,360 J 680 J 3,510 J 3,330 J 2,110 J 6/2/2014 (1) 1,540 556 J 3,650 2,630 J 2,640 J 10/16/2014 3,310 883 9,070 1 4,990 3,910 3,560 842 4/23/2015 -- -- -- 2,050 812 10/13/2015 -- -- -- 1,600 4/29/2016 -- -- -- 1,640 9/19/2016 -- - -- 1,330 Page 2 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene Xylenes (Total) MTBE Sulfate arbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 1 1 1 1 m l m l MW-14 5/12/2003 < 0.5 < 0.5 < 0.5 < 1 0.52 J 12/9/2003 < 0.5 < 0.5 < 0.5 1 < 1 5.9 3/23/2006 < 0.5 < 0.5 < 0.5 < 1 < 0.5 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 < 0.5 5/14/2008 < 0.5 < 0.8 < 0.7 < 0.8 < 0.5 5/28/2009 < 0.06 < 0.05 0.077 J < 0.14 < 0.06 5/27/2010 < 0.11 < 0.11 < 0.11 < 0.32 < 0.12 10/31/2011 <0.13 <0.15 < 0.42 U1 <0.3 <0.13 1 43.2 <5 6/3/2014 < 0.1 < 0.1 < 0.1 1 < 0.2 < 0.1 MW-15 3/23/2006 0.63 J 2.1 < 0.5 18.6 1.6 5/8/2007 < 0.5 < 0.5 < 0.5 2.2 J < 0.5 5/14/2008 < 0.5 < 0.8 < 0.7 3.7 J < 0.5 5/27/2010 < 0.11 < 0.11 < 0.11 < 0.32 < 0.12 10/31/2011 <0.13 <0.15 <0.13 <0.3 <0.13 <1 <5 6/3/2014 < 0.1 < 0.1 < 0.1 1 < 0.2 < 0.1 10/16/2014 <0.1 <0.1 <0.1 <0.2 <0.1 MW-16 3/23/2006 < 2.5 90.8 15.8 836 2.8 J 5/14/2008 <0.5 160 15 1,600 4.1 J 5/27/2010 3.6 54.7 J 5.1 525 J 1.3 10/31/2011 < 0.65 17.2 < 1.4 U 321 < 0.65 194 < 5 11/7/2013 -- -- -- 55.4 < 5 6/3/2014 < 0.1 25 0.92 417 J < 0.1 MW 17 5/13/2003 57.7 < 0.5 < 0.5 < 1 69 5/13/2003 40.8 < 0.5 < 0.5 < 1 63.3 12/9/2003 6.6 0.65 J < 0.5 < 1 80.6 3/23/2006 1 < 0.5 < 0.5 < 1 58.9 5/8/2007 < 0.5 < 0.5 < 0.5 < 1 17.4 5/14/2008 3.7 J < 0.8 < 0.7 < 0.8 19 5/28/2009 7 < 0.05 0.076 J < 0.14 14.5 5/27/2010 5.7 < 0.11 < 0.11 < 0.32 12.4 10/31/2011 0.51 0.16 J < 0.81 U 0.57 J 8.9 < 1 422 6/3/2014 < 0.1 < 0.1 < 0.1 < 0.2 4.1 MW-18 10/31/2011 3,140 998 11,100 8,950 1,140 8.2 446 5/22/2012 2,280 2,790 18,200 12,000 789 < 5 307 6/15/2012 (2) 373 910 4,800 3,910 114 10,600 3,410 7/9/2012 1,730 J 2,170 J 15,000 J 9,750 J 676 J 2,300 835 8/14/2012 3,020 2,990 24,400 12,800 1,090 758 580 9/19/2012 3,190 3,090 22,600 14,000 1,240 322 542 12/5/2012 3,370 2,970 20,100 12,800 1,380 32 436 2/26/2013 21510 2,970 10,100 8,690 1,140 13.8 500 5/31/2013 2,780 3,070 8,210 5,740 1,000 1 83.3 475 8/28/2013 182 368 730 1,660 139 7,850 2,230 11/7/2013 1,140 727 4,910 3,250 694 2,640 1,370 2/27/2014 16.6 109 20.2 45.8 18.5 4,310 1,270 6/2/2014 26.2 J 125 J 37.5 J 31.6 J 37.4 J 10/16/2014 359 388 244 138 364 1,540 513 4/23/2015 -- -- -- 780 1,100 10/13/2015 -- -- 516 4/29/2016 -- 79.4 9/19/2016 -- 377 Page 3 of 4 Appendix C Historical Groundwater Analytical Summary Former BP Service Station No. 24163 381 Knollwood Street Winston-Salem, Forsyth County, North Carolina Well Sample Date Benzene Ethyl benzene Toluene Xylenes (Total) MTBE Sulfate arbon dioxide NC GCL: 5,000 84,500 260,000 85,500 20,000 NE NE INC 2L 1 600 600 500 20 250 NE Units: 1 1 1 1 1 m l m l MW-19 10/31/2011 2,390 1,380 8,790 7,040 5,160 1 3.7 425 5/22/2012 2,700 1,560 14,200 7,940 4,880 < 5 310 6/15/2012121 4,020 1,440 18,200 7,940 3,290 1,090 6,520 7/9/2012 5,130 2,910 30,400 J 16,300 5,330 232 991 8/14/2012 2,420 1,650 14,200 8,370 4,090 469 1,080 9/19/2012 2,090 1,630 12,900 8,640 3,960 260 690 12/5/2012 2,320 1,810 15,200 10,400 4,010 58.8 588 2/26/2013 2,210 1,110 10,600 6,990 3,890 169 503 5/31/2013 1,830 894 8,820 5,250 3,120 1,530 606 8/28/2013 2,710 J 1,190 J 13,100 7,420 J 3,240 J 2,660 525 11/7/2013 2,020 984 9,850 5,620 2,260 2,890 255 2/27/2014 2,550 1,400 10,900 7,880 3,320 2,790 322 6/2/2014 2,370 1,260 11,900 7,260 2,830 -- -- 10/16/2014 -- -- -- 2,340 632 4/23/2015 -- 2,540 514 10/13/2015 1,960 4/28/2016 1,780 9/19/2016 1,270 Notes: (l) Field duplicate (2) Alkalinity, sulfate, and carbon dioxide samples were collected 6/14/2012 and volatile organic analysis samples were collected 6/15/12. -" - Not sampled or analyzed < - Not detected at the specified detection limit µg/l - Micrograms per Liter GCL - Gross Contamination Level 2L - North Carolina Groundwater Quality (2L) Standard J - Estimated value mg/l - Milligrams per Liter MTBE - Methyl tert-Butyl Ether NE - Not established U - Not present above the associated level; blank contamination exists UJ - Not detected and the detection limit is estimated BOLD text indicates 2L exceedance Bold cell with green highlight indicates GCL exceedence Activated sodium persulfate injections were performed at the site from June 4, 2012, to June 9, 2012, and from June 3, 2013, to June 6, 2013. Page 4 of 4 04ARCADIS5deign&Consultancy for naturaland built assets Arcadis U.S., Inc. 111-D Sanders Lane Bluefield, Virginia 24605 Tel 276 322 3879 Fax 276 322 3946 www.arcadis.com