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WQ0000430_Regional Office Historical File Pre 2018 (2)
Schutte, Maria From: Schutte, Maria Sent: Thursday, April 12, 2018 6:03 PM To: 'Larry Wright' Cc: Erik Bruce; Robert Roth; Adam Brigman; Gregory, Sonia; Pitner, Andrew Subject: RE: [External] RE: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request Larry, No. We are good for this report. Just be aware on future reports, so you can review prior to submittal, as the permittee is the responsible party. Thank you for asking! Maria From: Larry Wright[mailto:lwright@cityofcherryville.com] Sent: Thursday, April 12, 2018 3:16 PM To: Schutte, Maria <maria.schutte@ncdenr.gov> Cc: Erik Bruce <ebruce@SYNAGRO.com>; Robert Roth <rroth@SYNAGRO.com>; Adam Brigman <abrigman@SYNAGRO.com>; Gregory, Sonia <Sonia.Gregory@ncdenr.gov>; Pitner, Andrew <andrew.pitner@ncdenr.gov> Subject: Re: [External] RE: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request , � A�r b �S?�u�'�wo f��f�@l�-�I .nrfi�lill�i. D o n n r �u� 14i,h,,,: �:`f"�o);iA�`,F� o'i��ii�.'1�=� d: ir.:�i;i�"., kfi��`��;' . •J,r;`'r' ;''�• ` �. " •:�' �,� � ��1�T ,: `; f:•� f+e,��r� SiJat7i. Maria, Do you need anything else from me on this issue? Sincerely, Larry Wright Cherryville WWTP Sent from my Phone 7 plus On Apr 12, 2018, at 2:14 PM, Schutte, Maria <maria.schutte@ncdenr.gov> wrote: Erik, Thank you for the response. While Adam Brigman did respond on behalf of his permittees, I did still need the follow-up related to this WQ0000430 Cherryville request. Future report changes via clear- presentation or explanation will be welcomed, will aid DWR staff with review and reduce the potential of unnecessary violations for the permittee(s). This email will suffice for the additional information request. I have no further questions related to the referenced 2017 Annual Report. Sincerely, Maria From: Erik Bruce [mailto:ebruce@SYNAGRO.com] Sent: Thursday, April 12, 2018 11:39 AM To: Schutte, Maria<maria.schutte@ncdenr.gov>;'Iwright@citvofcherrvville.com' <Iwright@citvofcherrvville.com> Cc: Robert Roth <rroth@SYNAGRO.com> Subject: [External] RE: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request Hey Maria, It is my understanding that after you talked with Synagro TSS Adam Brigman out of Charlotte, who also received a letter asking for the ESP, that the situation was resolved by using the "%NA" as a representation of the ESP on the soil reports from Waypoint Analytical. Future reports from Waypoint will be structured in a manner that resembles soil reports from NCDA labs, to avoid further confusion. Any questions or issues please contact me and I can provide more information. Thanks, Erik Bruce From: Schutte, Maria [mailto:maria.schutteC ncdenr.gov] Sent: Friday, March 23, 2018 7:15 PM To:'Iwright(cbcityofcherryville.com' Cc: Erik Bruce Subject: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request Mr. Wright, This email will serve as the Acknowledgement of Receipt of the referenced Annual Report. The Mooresville Regional Office received a copy on March 5th, 2018. Upon review, the following additional information is requested.: Please send calculations for, or request an amended Soils Report from your contract lab to include, the Exchangeable Sodium Percentage (ESP) parameter in accordance with permit condition IV.S. of your permit (copied below for your convenience). It is the permittees responsibility to ensure all parameters are sampled, requested on the COC and reported as required, including the appropriate units of measure, in -line with NCDA recommendations. Please email the requested information to me or contact me with any questions. Sincerely, Maria 5, An anatial representative soils analysis (i.e., Standard Soil Fertility Analysis) shall be conducted on each land: api-.4ication, site. listed in Attachment B on which a residuals land application event will occur in, the respective catendar year. "Phis 'analysis shall be in accordance with the "Guidance on Soil Sampling" located in the Sampling Instructions sc*ction of the: NIC Department of Agriculture & Co,nsorner Serviccs' Nvebsite (littp://wv;,xN,.iiezigGgoy/iuonoini/t)ubs,litin), The Permittee. shall imaintain ttiese results and a description of the sampling methodologies usedto detcrinine soil Fertility for a 'period of no less than rive years, and. shall be made available to the Division upon request. At a minimum, the Standard Soil Fertility Analysis shall include the following parameters: Acidity' rc�aible Sodium Perecut, Phosphorus Base Saturation (by cal.cuhation) l Ma- iesiurn Potassium Calcium Manganese Sodium Cation. Exchange Capacity Percent Humic Matter Zinc copper pH [ I 5A NCAC 021' -1 1111 (d)] Maria Schutte Environmental Specialist Water Quality Regional Operations Section Division of Water Resources North Carolina Department of Environmental Quality 704 663 1699 office 704 235 2184 direct Maria. sch utte(o-)-ncdenr. gov 610 East Center Avenue Suite 301 Mooresville, NC 28115 <image002.png> Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Schutte, Maria From: Schutte, Maria Sent: Thursday, April 12, 2018 6:03 PM To: 'Larry Wright' Cc: Erik Bruce; Robert Roth; Adam Brigman; Gregory, Sonia; Pitner, Andrew Subject: RE: [External] RE: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request Larry, No. We are good for this report. Just be aware on future reports, so you can review prior to submittal, as the permittee is the responsible party. Thank you for asking! Maria From: Larry Wright[ma iIto: lwright@cityofcherryviIle.coml Sent: Thursday, April 12, 2018 3:16 PM To: Schutte, Maria <maria.schutte@ncdenr.gov> Cc: Erik Bruce <ebruce@SYNAGRO.com>; Robert Roth <rroth@SYNAGRO.com>; Adam Brigman <abrigman@SYNAGRO.com>; Gregory, Sonia <Sonia.Gregory@ncdenr.gov>; Pitner, Andrew <andrew.pitner@ncdenr.gov> Subject: Re: [External] RE: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request CAUTION: Maria, Do you need anything else from me on this issue? Sincerely, Larry Wright Cherryville WWTP Sent from my Phone 7 plus On Apr 12, 2018, at 2:14 PM, Schutte, Maria <maria.schutte@ncdenr.gov> wrote: Erik, Thank you for the response. While Adam Brigman did respond on behalf of his permittees, I did still need the follow-up related to this WQ0000430 Cherryville request. Future report changes via clear presentation or explanation will be welcomed, will aid DWR staff with review and reduce the potential of unnecessary violations for the permittee(s). . This email will suffice for the additional information request. I have no further questions related to the referenced 2017 Annual Report. Sincerely, Maria From: Erik Bruce [mailto:ebruce@SYNAGRO.com] Sent: Thursday, April 12, 2018 11:39 AM 1 To: Schutte, Maria <maria.schutte@ncdenr.gov>; 'Iwright@cityofcherryville.com' .4 <Iwright@cityofcherryville.com> Cc: Robert Roth <rroth@SYNAGRO.com> Subject: [External] RE: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request Hey Maria, It is my understanding that after you talked with Synagro TSS Adam Brigman out of Charlotte, who also received a letter asking for the ESP, that the situation was resolved by using the "%NA" as a representation of the ESP on the soil reports from Waypoint Analytical. Future reports from Waypoint will be structured in a manner that resembles soil reports from NCDA labs, to avoid further confusion. Any questions or issues please contact me and I can provide more information. Thanks, Erik Bruce From: Schutte, Maria[mailto:maria.schutte@ncdenr.gov] Sent: Friday, March 23, 2018 7:15 PM To: 'Iwright@cityofcherryville.com' Cc: Erik Bruce Subject: WQ0000430 City of Cherryville 2017 Annual Report - Additional Information Request Mr. Wright, This email will serve as the Acknowledgement of Receipt of the referenced Annual Report. The Mooresville Regional Office received a copy on March 5th, 2018. Upon review, the following additional information is requested.: Please send calculations for, or request an amended Soils Report from your contract lab to include, the Exchangeable Sodium Percentage (ESP) parameter in accordance with permit condition IV.S. of your permit (copied below for your convenience). It is the permittees responsibility to ensure all parameters are sampled, requested on the COC and reported as required, including the appropriate units of measure, in -line with NCDA recommendations. Please email the requested information to me or contact me with any questions. Sincerely, Maria 5. An annual representative soils analysis (i.e., Standard Soil Fertility Analysis) shall be conducted on each land application site listed in Attachment 13 on which a residuals land application event will OCCUr in the respcctivo calendar year. This analysis shall be in accordance NvIth the "Guidance on Soil Sampling" located in the Sampling Ilistructimis section of the NC Department of Agriculture & Consumcr Services' Nvebsitc 'File Pen1littee shall maint.ain these results and a description of the sanipling methodologies used to determine soil fertility - for aperiod of no less than rive years, and shall be niiade available to the Division upon request. At a mininitun, the Standard Soil Fertility Analysis shall include the following parameters: Acidity Exchan&T "bl -Sodium Percenta- PhosehorLIS Base Satunation(by calculation) Magnesium Potassium Calcium M an ga 11 e-se Sodium Cation Exchange Capacity Percent Humic Matter Zinc Copper PH [15A NCAC 02T, I J I I(d)] Maria Schutte Environmental Specialist Water Quality Regional Operations Section Division of Water Resources North Carolina Department of Environmental Quality 704 663 1699 office 704 235 2184 direct Maria. sch utte(a ncden r. -gov 610 East Center Avenue Suite 301 Mooresville, NC 28115 <image002.png> Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. -)ROS OFFICE eCl�rj ED IN N R I WVR MOORESVILLE REGIONAL ! ()FrlCa .A. CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2017 ANNUAL REPORT City of Cherryville, NC Residuals Land Application Program 2017 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen ReductionNector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00000430 County Gaston Year 2017 Facility Name (as shown on permit) City of Cherryville WWTP NPDES No. NCO044440 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 7 Total number of fields utilized for land application during the year: 2 Total amount of dry tons applied during the year for all application sites: 87.02 Total number of acres utilized for land application during the year: 38.6 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2017 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. ] am aware that there are significant penalties for submitting false information, incl ding-thi -passibility of fines and imprisonment for knowing, violations." A ,, 1 Larry Wright, Plant ORC & Plant Supervisor Permittee Name and Title (type or print) Signature of Preparer* Date 49fg4a' ure of and Applier (if different from Permittee) (if di rent from Pemuttee and Preparer) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2017 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION CHERRYVILLE, NC CHERRYVILLE, NC LIQUID DRY METRIC MONTH/YEAR AMOUNT UNIT DRY TONS UNIT TONS March 2017 632,400.00 G 87.02 D 78.94 YEARLY TOTAL 632,400.00 G 87.02 D 78.94 2/5/2018 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 01/17/17 Date Composited Percent Solids 3.30 PARAMETERS (mg/kg dry weight) Arsenic 4.84 Cadmium <2 Mercury 1.16 Chromium 68.5 Copper 417 Lead 32.9 Molybdenum 6.07 Nickel 34.6 Selenium <5 Zinc 713 Total Phosphorus 19700 TKN 48600 Ammonia -Nitrogen 12100 Nitrate and Nitrite 625 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel prope ll gatLered and evaluated the information submitted. I am aware that there are significant penalties for_submitting false infQr on, includin the possibility of fines and imprisonment for knowing violations." X (SIGN,TO RIZOF PREPARE I - Date _ IV Is DENR FORM RSSF (5/2003) Printed: Tuesday - February 6 2018 at 15:21:30 for: 2008 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 01/17/17 Date Composited Percent Solids 3.30 PARAMETERS (mg/kg dry weight) Aluminum 30800 Calcium 14200 Magnesium 3430 pH 7.00 Potassium 3300 Sodium 1720 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information -ncluding the possibility of fines and imprisonment for knowing violations." X // N (SIGNATU,R OY PREP NR - Data Ngt Reported or Data Not Required Date 2,_ I L - 19 DENR FORM RSSF-B (7/2002) Printed: Tuesday - February 6 2018 at 15:21:51 for: 2008 01 Page: 1 of 2 Report Number: 17-019-0209 Account Number: 46442 Submitted By: Erik Bruce Send To: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville , NC 27028 Lab Number: 61779 Sample Id : Cherryville WWTP • Waypoint ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project: Cherryville WWTP NC Cert#257 REPORT OF ANALYSIS Date Sampled: 1/17/2017 09:30:00 Date Received: 01/19/2017 00:00 Date Reported: 01/26/2017 Total Solids * 3.30 33000 100.0 JM 01/19/2017 17:00 SM-2540G Moisture * 96.69 100.0 JM 01/19/2017 17:00 SM-2540G Total Kjeldahl Nitrogen 4.86 48600 10.0 JM 01/20/2017 08:55 SM-4500-NH3C-TKN Total Phosphorus 1.97 19700 100 JTR 01/24/2017 02:58 6010C Total Potassium 0.33 3300 1000 JTR 01/24/2017 03:03 6010C Total Sulfur 0.83 8330 100 JTR 01/24/2017 02:58 6010C Total Calcium 1.42 14200 100 JTR 01/24/2017 02:58 6010C Total Magnesium 0.34 3430 100 JTR 01/24/2017 02:58 6010C Total Sodium 0.17 1720 100 JTR 01/24/2017 02:58 6010C Total Iron 29000 100 JTR 01/24/2017 02:58 6010C Total Aluminum 30800 100 JTR 01/24/2017 02:58 6010C Total Manganese 425 5.00 JTR 01/24/2017 02:58 6010C Total Copper 417 5.00 JTR 01/24/2017 02:58 6010C Total Zinc 713 5.00 JTR 01/24/2017 02:58 6010C Ammonia Nitrogen 1.21 12100 10.0 JM 01/20/2017 08:55 SM-4500-NH3C Organic N 3.65 36500 10.0 01/20/2017 08:55 CALCULATION Nitrate+Nitrite-N 625 2.40 SJB 01/23/201713:04 4500NO3F-2011 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. 9 z�u Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole orpart, nor may any reference be made ,ft�A to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Laboratory Supervisor Page: 2 of 2 Report Number: 17-019-0209 Account Number: 46442 Submitted By: Erik Bruce Send To: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville , NC 27028 Lab Number: 61779 Sample Id : Cherryville WWTP D Waypoin(t.w ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project: Cherryville WWTP NC Cert#257 REPORT OF ANALYSIS Date Sampled: 1/1712017 09:30:00 Date Received: 01/19/2017 00:00 Date Reported: 01/26/2017 Total Cadmium <2.00 2.00 JTR 01/24/2017 02:58 6010C Total Chromium 68.5 5.00 JTR 01/24/2017 02:58 6010C Total Nickel 34.6 5.00 JTR 01/24/2017 02:58 6010C Total Lead 32.9 5.00 JTR 01/24/2017 02:58 6010C Total Arsenic 4.84 3.00 JTR 01/24/2017 02:58 6010C Total Mercury 1.16 0.400 JM 01/25/2017 15:50 SW-7471B Total Selenium <5.00 5.00 JTR 01/24/2017 02:58 6010C pH (Standard Units) 7.00 1.00 JM 01/20/2017 08:55 SW-9045D Total Molybdenum 6.07 5.00 JTR 01/24/2017 02:58 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our.reports and letters air- for the exclusive and confidential use of our clients, and may not he reproduced in whole or part nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Laboratory Supervisor Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 1/17/2017 1/1/2017-12/31/2017 0.6088 Na mg/I = (Na mg/kg x % Solids) = 100 = (1720 x 3.3000) _ 100 = 56.76 Ca mg/I = (Ca mg/kg x % Solids) + 100 = (14200 x 3.3000) + 100 = 468.6 Mg mg/I = (mg mg/kg x % Solids) + 100 = (3430 x 3.3000) _ 100 = 113.19 Na meq = Na mg/I + Molec.Wgt.Na = 56.76 _ 23 = 2.46783 Ca meq = Ca mg/I + Molec.Wgt.Ca = 468.6 + 20 = 23.43 Mg meq = Mg mg/I + Molec.Wgt.Mg = 113.19 + 12 = 9.4325 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.46783 + SgrRoot[0.5(23.43+9.4325)] = 0.608806 Printed: 2/6/2018 Page 1 15:20 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: CHERRYVILLE, NC PREDOMINANT SOIL SERIES: CECIL )WNER: WAYNE GILBERT PERMIT #: W00000430 ANNUAL DRY TONS APPLIED: 65.70 >ITE #: NC LT 00120 FIELD# : LT 00120 0002 OPERATOR: WAYNE GILBERT CATION EXCHANGE CAPACITY (NON-503): 3ESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 27.60 ACRES PERMITTED: 27.60 Page: 1 Lune Applied *** Date Lbs/Ac DATE or MONTH allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - all- zation TKN Ammonia Nitrogen Nitrate and PANT (ppm) Crop Total Per Acre 3/9/17 161,200.00 (G) 5840.580 3.30 0.804 CHL DRY 0-<I/2" SUR 0.5 0.30 48,600.p 12,100.00 p 625.00 p 17625 I CORN 3/10/17 105,400.00 (G) 3818.841 3.30 0.526 CHL MOIST 0-<1/2" SUR 0.5 0.30 48,600.p 12,100.00 p 625.00 p 17625 I CORN 3/13/17 68,200.00 (G) 2471.014 3.30 0.340 CHL DRY 0-<1/2" SUR 0.5 0.30 48,600. p 12,100.00 p 625.00 p 17625 I CORN 3/15/17 124,000.00 (G) 4492.754 3.30 0.618 CHL DRY 0-<I/2" SUR 0.5 0.30 48,600. p 12,100.00 p 625.00 p 17625 I CORN 3/16/17 18,600.00 (G) 673.913 3.30 0.093 CHL DRY 0-<1/2" SUR 0.5 0.30 48,600.p 12,100.00 p 625.00 p 17625 CORN Mar-17 477,400.00 (G) 17,297.102 Total Gallons/Ac: 17,297.10 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 84 0.023 0.010 0.326 1.985 0.157 0.006 0.029 0.165 0.024 3.394 93.78 Cumulative lbs/acre 0.120 0.062 2.020 18.973 1.121 0.027 0.499 1.745 0.106 27.883 t �. >r ermit PAN Limit (lbs/acre) 1st Crop/2nd Crop 3, j y r N r r 238 13 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) i F 36.6 34.8 1339.0 267.9 15.0 " 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID X (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = pp- or mg/kg ** Volatilization Rate : Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2018 ANNUAL LAND APPLICATION FIELD SUMMARY FORM 'AGILITY NAME: CHERRYVIILE, NC PREDOMINANT SOIL SERIES: CECIL )WEER: WAYNE GILBERT PERMIT #: WQ0000430 ANNUAL DRY TONS APPLIED: 21.33 ;ITE #: NC LT 00120 FIELD# : LT 00120 0003 OPERATOR: WAYNE GILBERT CATION EXCHANGE CAPACITY (NON-503): tESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 11.00 ACRES PERMITTED: 11.00 Page: 1 Lime Applied *** Date Lbs/Ac DATE or MONTH allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop Total Per Acre 3/13/17 62,000.00 (G) 5636.364 3.30 0.776 CHL DRY 0-<I/2" SUR 0.5 0.30 48,600. p 12,100.00 p 625.00 p 17625 I CORN 3/15/17 68,200.00 (G) 6200.000 3.30 0.853 CHL DRY 0-<1/2" SUR 0.5 0.30 48,600.p 12,100.00 p 625.00 p 17625 I CORN 3/16/17 24,800.00 (G) 2254.545 3.30 0.310 CHL DRY 0-<I/2" SUR 0.5 0.30 48,600.p 12,100.00 p 625.00 p 17625 CORN Mar-17 155,000.00 (G) 14,090.909 Total Uallons/Ac: 14,090.91 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 68 0.019 0.008 0.266 1.617 0.128 0.005 0.024 0.134 0.019 2.765 76.40 Cumulative lbs/acre 0.101 0.052 1.649 16.199 0.883 0.022 0.481 1.579 0.085 22.798 t a. 'ermit PAN Limit (lbs/acre) 1st Crop/2nd Crop 4 1 14 - ! a j K 1 238 { e� +,. �r, d� t,'i .,... ,g • .. z' ., :1, .. FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID X 1 (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2018 Summit Environmental Technologies, Inc. .. y U r= 3310 Win St. EPA' I R 0 N fol E NTA L 3Ss-H?10Lj:�tJ S, eNG Cuyahoga Falls, Ohio 44223 Ik�aP real L ib des TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: httn://wwiv.settek.com January 31, 2018 Erik Bruce Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Cherryville WWTP Dear Erik Bruce: Order No.: 18011035 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/23/2018 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results,_ please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Oklahoma 9940, Oregon OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH009232011-1, Virginia VELAP 9456, Washington C891 Page 1 of 27 Summit Environmental Technologies, Inc. aair- � � • +� 3310 Win St. Case Narrative �. FiWR€ NMENTAL T CHUOLar�S, wq. Cuyahoga Falls, Ohio 44223 W04: 18011035 r:n Flrt r_a! Lahcra�a?l t TEL: (330) 253-8211 FAX: (330) 253-4489 Website: hQ.-11www.settek.com Date: 1/31/2018 CLIENT: Synagro Project: Cherryville WWTP WorkOrder Narrative: 18011035: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation are attached as applicable. Results provided in this report for any parameter not listed on the Scope of Accreditation should be considered "not certified." The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 18011035-OOIA SVOC-SNA_TCLP(8270D): Sample exhibited low recovery for Surrogate: phenol-d6 . due to matrix effect. Analytical Sequence QC Notes: ccv 40ng S8- svoc-mstr_s(8270): CCV exhibited high recovery for Hexachloroethane. Associated samples are ND for these analytes. Original Page 2 of 27 Summit Environmental Technologies, In Qualifiers and Acronyms submmlT 3310 Win 5 FNIVIRONIAENTAL TECHNOLOGIES, INC. Cuyahoga Falls, Ohio 442� WO#: 18011035 Ai-alytt-_al L.sb rah,1 {es TEL: (330) 253-8211 FAX.- (330) 253-446 Website: hay.-Ilwivw.settek.co. Date: 1/31/2018 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. * The result exceeds the Regulatory Limit or Maximum Contamination Limit. m Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on aMass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed. B/M 3+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 27 Summit Environmental Technologies, Inc. :ED 3310 Win St. P�4�If€�YJf�fEN'f�1L=CCi�LG��S,tG, Cuyahoga Falls, Ohio44223 A.rr, fyUcsf LaSoraturFeS TEL: (330) 253-8211 FAY.- (330) 253-4489 Website: htty.-1Avwiv.settekcom Workorder Sample Summary WO#: 18011035 31-Jan-18 CLIENT: Synagro Project: Cherryville WWTP Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 18011035-001 Cherryville W VU (2017 1/22/2018 10:00:00 AM 1/23/2018 7:45:00 AM Sludge Material) Page 4 of 27 Summit Environmental Technologies, Inc. DATES msuMMIT 3310 Win St. 84VI:Tr WilENTAL TFCHUOLtbGIES, IC Cuyahoga Falls, Ohio 44223 WO#: 18011035 Anslyffgal Cslanr9 art TEL: (330) 253-8211 FAX. (330) 253-4489 Website: hito://www.settek.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP Sample,ID Client Sample ID Collection Date Matrix _ Test Name Leachate Date Prep Date Analysis Date 18011035-OOIA Cherryville WWTP (2017 1/22/2018 10:00:00 AM Sludge Ignitability of Solids (SW-846: 1030) 1/25/2018 1:00:00 PM Material) pH (SW9045D) Reactive Cyanide (9014/7.3.3.2)-Solid Reactive Sulfide (9034)/7.3.4.2 1/30/2018 1:08:00 PM 1/25/2018 12:04:00 PM 1/25/2018 12:04:00 PM TCLP Herbicides Analysis (SW1311/81/25/2018 6:00:00 PM 1/26/2018 12:30:00 PM 1/30/2018 2:49:00 PM TCLP Mercury Analysis (SW1311/74-/1/25/2018 6:00:00 PM 1/26/2018 12:45:00 PM 1/26/2018 4:18:00 PM TCLP Metals Analysis (SW1311/6010.1/25/2018 6:00:00 PM 1/26/2018 12:00:00 PM 1/3.1/2018 12:46:16 AM TCLP Pesticides Analysis (SW1311/8(1/25/2018 6:00:00 PM 1/29/2018 9:00:00 AM 1/29/20-18 8:32:00 PM TCLP Semi-Volatiles Analysis 1/25/2018 6:00:00 PM 1/29/2018 7:00:00 AM 1/29/2018 9:20:00 PM (SW1311/8270) TCLP Volatiles Analysis 1/29/2018 6:00:00 PM 1/30/2018 7:29:00 PM Original Page 5 of 27 Summit Environmental Technologies, Inc. 3310 Win St. Analytical Report msummIT FUVIROWMEN'PLg-C3HUCLOG:ES;IKQ. Cuyahoga Falls, Ohio44223 (base report) AraPyUcal LaborahDr£es TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 18011035 Website: httD://ivwiv.settek.com Date Reported: 1/31/2018 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM Lab ED: 18011035-001A Project: Cherryville WWTP Client Sample ID Cherryville WWTP (2017 Material) Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: EAM TCLP MERCURY ANALYSIS (SW7311/7470) TCLP Mercury ND 0.00200 mg/L 1 1/26/2018 4:18:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW3010A Analyst: KMS TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND 0.500 mg/L 1 1/31/2018 12:46:16 AM TCLP Barium(Ba) ND 5.00 mg/L 1 1/31/2018 12:46:16 AM TCLP Cadmium(Cd) ND 0.100 mg/L 1 1/31/2018 12:46:16 AM TCLP Chromium(Cr) ND 0.200 mg/L 1 1/31/2018 12:46:16 AM TCLP Lead(Pb) ND 0.500 mg/L 1 1/31/2018 12:46:16 AM TCLP Selenium(Se) ND 0.0500 mg/L 1 1/31/2018 12:46:16 AM TCLP Silver(Ag) ND 0.500 mg/L 1 1/31/2018 12:46:16 AM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW3510C Analyst: BJH TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)• 1,4-Dichlorobenzene ND 0.0800 mg/L 2 1/29/2018 9:20:00 PM 2,4,5-Trichlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM 2,4,6-Trichlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM 2,4-Dinitrotoluene ND 0.0400 mg/L 2 1/29/2018 9:20:00 PM o-Cresol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM m/p-Cresol(s) ND 0.200 mg/L 2 1/29/2018 9:20:00 PM Cresols, Total ND 4.00 mg/L 2 1/29/2018 9:20:00 PM Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 1/29/2018 9:20:00 PM Hexachlorobenzene ND 0.0400 mg/L 2 1/29/2018 9:20:00 PM Hexachloroethane ND 0.0800 QC+ mg/L 2 1/29/2018 9:20:00 PM Nitrobenzene ND 0.0800 mg/L 2 1/29/2018 9:20:00 PM Pentachlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM Pyridine ND 0.200 mg/L 2 1/29/2018 9:20:00 PM Surr: 2-Fluorophenol 19.9 10 - 109 %Rec 2 1/29/2018 9:20:00 PM Surr: Phenol-d6 9.28 10 - 109 S %Rec 2 1/29/2018 9:20:00 PM Surr: Nitrobenzene-d5 44.9 19 - 120 %Rec 2 1/29/2018 9:20:00 PM Surr: 2,4,6-Tribromophenol 24.0 10 - 120 %Rec 2 1/29/2018 9:20:00 PM Surr: 2-Fluorobiphenyl 59.8 22 - 117 %Rec 2 1/29/2018 9:20:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 6 of 27 TSUMMSummit IT3310 s=iVIROIAIENO.LTECMOLCIMES,„tr. Az-alyfical Laboraiorlra Environmental Technologies, Inc. Win St. Cuyahoga Falls, Ohio44223 TEL: (330) 253-8211 FAX: (330) 253-4489 Analytical Report (base report) WO#: 18011035 Website: hgp://wwiv.settek.com Date Reported: 1/31/2018 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM Lab ED: 18011035-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP (2017 Material) Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW131118270) Surr: p-Terphenyl-d14 63.8 34 - 116 NOTES: Sample exhibited low recovery for Surrogate: phenol-d6 due to matrix effect. TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW131118081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 76.6 Surr: DCB 62.6 SW8270D SW351OC Analyst: BJH %Rec 2 1/29/2018 9:20:00 PM SW8081 SW351OC Analyst: JBN 0.0200 mg/L 2 1/29/2018 8:32:00 PM 0.0400 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 10 - 119 %Rec 2 1/29/2018 8:32:00 PM 10 - 119 %Rec 2 1/29/2018 8:32:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP HERBICIDES ANALYSIS (SW131118151) 2,4-D ND 1.00 2,4,5-TP ND 0.500 d Surr: DCAA 111 20 - 140 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1,2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND SW8151A SW8151A Analyst: JBN mg/L 1 1/30/2018 2:49:00 PM mg/L 1 1/30/2018 2:49:00 PM %Rec 1 1/30/2018 2:49:00 PM SW8260B SW1311M Analyst: MES 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.250 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM Qualifiers: Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds 0 RSD is greater than RSDlimit PL Permit Limit Original RL Reporting Detection Limit Page 7 of 27 Summit Environmental Technologies, Inc. Analytical Report S i �tN'T 3310 Win St. F.WI;RH:0hIMEWAL!PCPU0L'rGJ 5, WC-7, Cuyahoga Falls, Ohio 44223 (base report) r ,�raiy tical t-heraipt'/t:.=. TEL: (330) 253-8211 F - (330) 253-4489 WO#: 18011035 Website: hyp://1vwiv.settek.com Date Reported: 1/31/2018 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM Lab ED: 18011035-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP (2017 Material) Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS Trichloroethene ND Vinyl chloride ND Surr: 4-Bromofluorobenzene 93.4 Surr: Dibromofluoromethane 99.8 Surr: Toluene-d8 97.6 RCI-SOLID-W/ IGNITABILITY1030 REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND RCI-SOLID-WI IGNITABILITY1030 IGNITABILITY OF SOLIDS (SW-846: 1030) Ignitability non-flammable RCI-SOLID-W/ IGNITABILITY1030 PH (SW9045D) pH 7.2 RCI-SOLID-W/ IGNITABILITY1030 REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive 30.0 SW8260B SW1311 M Analyst: MES 0.0500 mg/L 10 0.0200 mg/L 10 70 - 130 %Rec 10 70 - 130 %Rec 10 70 - 130 %Rec 10 SW9014 0.500 mg/Kg 1 SW1030 ' 1 SW9045D Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Lnnit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits s.u.@19.4C 1 SW9034 25.0 mg/Kg 1 1/30/2018 7:29:00 PM 1/30/2018 7:29:00 PM 1/30/2018 7:29:00 PM 1/30/2018 7:29:00 PM 1/30/2018 7:29:00 PM Analyst: MS 1/25/2018 12:04:00 PM Analyst: AJT 1/25/2018 1:00:00 PM Analyst: DHC 1/30/2018 1:08:00 PM Analyst: MS 1/25/2018 12:04:00 PM E Value above quantitatik M Manual Integration used N Tentatively identified con. O RSD is greater than RSDIin PL Permit Limit RL Reporting Detection Limit Summit Environmental Technologies, Inc. Accreditation Program MSUAKMAIF 3310 Win St. a_PrVIROFdWKI I �.L T2CHtZ0L1�Gt=5: WQ Cuyahoga Falls, Ohio 44223 Analytes Deport t1:rai tical Laharaforia= TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 18011035 Website: http://www.settek.con: 31-Jan-18 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC WW SCM Sample ID Matrix Test Name Analyte Status 18011035-OOIA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)n.3.4.2 Sulfide, Reactive U Sludge TCLP Herbicides Analysis (SW1311/8151) 2,4,5-TP A Sludge TCLP Herbicides Analysis (SW1311/8151) 2,4-D A Sludge TCLP Herbicides Analysis (SW1311/8151) DCAA A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) 2,2',3,3',4,4',5,5',6,6'- A Decachlorobiphenyl Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Tetrachloro-m-xylene A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Tribromophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2-Fluorobiphenyl A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2-Fluorophenol A Key Key NC WW SCM A Accredited NC WW SCM U Unavailable Original #1 Page 9 of 27 Summit Environmental Technologies, Inc. Accreditation Program 3310 Win St. rW,FIR0tJh1EN'rALTECWzOL� sje5;WC; Cuyahoga Falls, Ohio44223 Anal teS Report Y P ttrrai;. ti,'ad Latzera�utje5 TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 18011035 Website:'hup://wiviv.settekconi 31-Jan-18 Client: Synagro State: NW Project: Cherryville WWTP Program Dame: NC WW SCM Sample ID Matrix Test Name Analyte Status 18011035-OOIA Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2-Methylphenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 3,4-Methylphenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene-d5 A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Phenol-d6 A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) p-Terphenyl-d14 A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis 4-Bromofluorobenzene A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Dibromofluoromethane A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Toluene-d8 A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC_WW_SCM A Accredited NC WW SCM U Unavailable Original 91 Page 10 of 27 •�ti ~ FF Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT tMVIrcUNNINwlRl. ttr rea•��Lrts3t�s; trtC Cuyahoga Falls, Ohio44223 WO#: 18011035 dil,ti•r f Lx7bo 9tD,rij-J TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://lvww.settelc.coni 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30581 Sample ID MB-30581 SampType: MBLK TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: PBS Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392423 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.00200 Sample ID LCS-30581 SampType: LCS TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/2612018 RunNo: 79934 Client ID: LCSS Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392424 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ TCLP Mercury 0.00467 0.00200 0.00400 0 117 80 120 Sample ID 18011013-001AMS SampType: MS TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: BatchQC Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392426 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] TCLP Mercury 0.00541 0.00200 0.00400 0.0000600 134 75 125 S Sample ID 18011013-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: BatchQC Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392427 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00513 0.00200 0.00400 0.0000600 127 75 125 0.00541 5.31 20 S Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 11 of 27 Summit Environmental Technologies, Inc. QC SUMMARY REPORT sunIMIT - 3310 Win St. er4V1KVTJr41;NlnJ,g4c L'HUULFJGU1-S,11`;C. Cuyahoga Falls, Ohio44223 _ WO#: 18011035 d4.tadyr2l:cal C2�a,r�tn�Fe TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://ivivw.settelc.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30S81 Sample ID 18011013-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: BatchQC Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/2612018 SegNo: 1392427 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 12 of 27 WJ &Ifva II' Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT LrWIHVINTOkN IAl. 1 is 11?4ULucjl�-S, iltc. Cuyahoga Falls, Ohio 44223 WO#: 18011035 Ana(yRcrrl C rbn,r,9i.ories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: httv://wivw.settelc.coni 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchlD: 30592 Sample ID mb-30592 SampType: mblk TestCode: tclp-svoc-her Units: mg/L Prep Date: 1/26/2018 RunNo: 80052 Client ID: PBS Batch ID: 30592 TestNo: SW8151A SW8151A Analysis Date: 1/30/2018 SegNo: 1397310 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ 2,4-D ND 1.00 0 0 d 2,4,5-TP ND 0.500 0 0 d Surr: DCAA 542 500.0 108 20 140 Sample ID Ics-30592 SampType: Ics TestCode: tclp-svoc-her Units: mg/L Prep Date: 1/2612018 RunNo: 80052 Client ID: LCSS Batch ID: 30592 TestNo: SW8151A SW8151A Analysis Date: 1/30/2018 SegNo: 1397311 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ 2,4-D ND 1.00 0.500 0 94.3 62.6 125 2,4,5-TP ND 0.500 0.500 0 94.3 52.5 128 Surr: DCAA 539 500.0 108 20 140 Qualifiers: Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 13 of 27 rim Summit Environmental Technologies, Inc. QC SUMMARY n E7� O7� T Ton 3310 Win St. O. REPORT l L KQ w,11 N IAL q �aaae�cau�yc3t 5, INC. Cuyahoga Falls, Ohio 44223 WO#: 18011035 _. At. ri1 Pi':cai L: bopq, ioriau TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htto://wwiv.settelc.com 31-Tan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30600 Sample ID 18011034-001AMS SampType: MS TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/29/2018 RunNo: 80053 Client ID: BatchQC Batch ID: 30600 TestNo: SW8270D SW3510C Analysis Date: 1/29/2018 SegNo: 1397326 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.684 0.0800 0.8000 0 85.6 15.2 124 2,4,5-Trichlorophenol 0.837 0.200 0.8000 0 105 30.6 152 2,4,6-Trichlorophenol 0.754 0.200 0.8000 0 94.2 27.6 150 2,4-Dihitrotoluene 0.738 0.0400 0.8000 0 92.2 58 141 o-Cresol 0.513 0.200 0.8000 0 64.1 26.9 132 m/p-Cresol(s) 0.490 0.200 0.8000 0 61.2 27.4 134 Cresols, Total ND 4.00 1.600 0 62.6 27.6 132 Hexachloro-1,3-butadiene 0.762 0.0160 0.8000 0 95.2 -5.3 156 Hexachlorobenzene 0.797 0.0400 0.8000 0 99.6 54.3 142 Hexachloroethane 0.792 0.0800 0.8000 0 99.0 1.92 131 QC+ Nitrobenzene 0.679 0.0800 0.8000 0 84.8 21 135 Pentachlorophenol 0.720 0.200 0.8000 0 90.0 47.4 134 Pyridine ND 0.200 0.8000 0 24.3 -10.3 64.2 Surr:2-Fluorophenol 0.373 1.000 37.3 9.77 146 Surr: Phenol-d6 0.174 1.000 17.4 20.7 130 S Surr: Nitrobenzene-d5 0.746 1.000 74.6 13.9 156 Surr:2,4,6-Tribromophenol 0.665 1.000 66.5 27.3 183 Surr:2-Fluorobiphenyl 1.03 1.000 103 21.4 153 Surr: p-Terphenyl-d14 1.04 1.000 104 54.8 154 NOTES: MS exhibited low recovery for Surrogate: phenol-d6 due to matrix effect. Qualifiers: Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine Original MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 14 of 27 1 SunimitEnvironmental Technologies, Inc. C SUMMARY REPORT Z, f 3310 Win St. r r Ikea rtuir N irl� o a.r rtuaULct€3r�s, irt�. Cuyahoga Falls, Ohio 44223 dl.n rf4tihf CaTlaearwtr�rie TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 18011035 Website: http://wivw.settekcont 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30600 Sample ID 18011034-001AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/2912018 RunNo: 80053 Client ID: BatchQC Batch ID: 30600 TestNo: SW8270D SW3510C Analysis Date: 112912018 SegNo: 1397327 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.627 0.0800 2,4,5-Trichlorophenol 0.730 0.200 2,4,6-Trichlorophenol 0.657 0.200 2,4-Dinitrotoluene 0.655 0.0400 o-Cresol 0.449 0.200 m/p-Cresol(s) 0.448 0.200 Cresols, Total ND 4.00 Hexachloro-1,3-butadiene 0.694 0.0160 Hexachlorobenzene 0.700 0.0400 Hexachloroethane 0.733 0.0800 Nitrobenzene 0.608 0.0800 Pentachlorophenol 0.616 0.200 Pyridine ND 0.200 Surr: 2-Fluorophenol 0.295 Surr: Phenol-d6 0.146 Surr: Nitrobenzene-d5 0.566 Surr: 2,4,6-Tribromophenol 0.490 Surr: 2-Fluorobiphenyl 0.827 Surr: p-Terphenyl-d14 0.804 NOTES: MSD exhibited low recovery for Surrogate: phenol-d6 due to matrix effect. 0.8000 0 78.4 15.2 124 0.6844 8.72 30 0.8000 0 91.2 30.6 152 ' 0.8368 13.7 30 0.8000 0 82.2 27.6 " 150 0.7536 13.7 30 0.8000 0 81.8 58 141 0.7380 11.9 30 0.8000 0 56.1 26.9 132 0.5128 13.3 30 0.8000 0 56.0 27.4 134 0.4896 8.96 30 1.600 0 56.0 27.6 132 0 0 30 0.8000 0 86.8 -5.3 156 0.7616 9.23 30 0.8000 0 87.6 54.3 142 0.7968 12.9 30 0.8000 0 91.7 1.92 131 0.7924 7.76 30 QC+ 0.8000 0 76.0 21 135 0.6788 11.1 30 0.8000 0 77.1 47.4 134 0.7204 15.6 30 0.8000 0 19.6 -10.3 64.2 0 0 30 1.000 29.5 9.77 146 0 1.000 14.6 20.7 130 0 S 1.000 66.6 13.9 156 0 1.000 49.0 27.3 183 0 1.000 82.7 21.4 153 0 1.000 80.4 54.8 154 0 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 15 of 27 -3 Summit Environmental Technologies, Inc. QC SUMMARY REPORT 3310 Win St. t—iV1tcV%Nr4I:N1Ak Ir.+.:rta,lorva1'-a, INC. Cuyahoga Falls, Ohio 44223 WO#: 18011035 w 4,.r,3;lrLdc+31 L'taca,rslp,r��c TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: httD://www.settelc.conz 31-Jan-18 Client: Synagro Project: Chenyville WWTP BatchID: 30617 Sample ID mb-30617 SampType: MBLK TestCode: telp-voc-mstr Units: mg/L Prep Date: 112912018 RunNo: 80054 client ID: PBS Batch ID: 30617 TestNo: SW82608 SW1311M Analysis Date: 1/30/2018 SegNo: 1397367 analyte • Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qua] 1,1-Dichloroethene ND 0.0500 1,2-Dichloroethane ND 0.0500 MEK ND 0.250 Benzene ND 0.0500 Carbon tetrachloride ND 0.0500 Chlorobenzene ND 0.0500 Chloroform ND 0.0500 Tetrachloroethene ND 0.0500 Trichloroethene ND 0.0500 Vinyl chloride ND 0.02.00 Surr: 4-Bromofluorobenzene 496 Surr: Dibromofluoromethane 482 Surr: Toluene-d8 499 Qualifiers: Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds 500.0 99.1 70 500.0 96.4 70 500.0 99.9 70 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 130 130 130 B Value above quantitation range M Manual Integration used to determine 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 16 of 27 Summit Environmental Technologies, Inc. QC SUMMARY REPORT PSUMMIT 3310 Win St. �r IH� Nn1l h IA w ev �„�uatat a; artw. Cuyahoga Falls, Ohio 44223 WO#: 18011035 �6re�t!•r.[i':Gi�1 Cs7.i?ta,Y,�tr��1� TEL: (330) 253-8211 FAX• (330) 253-4489 Website: http://ivww.settelf.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30617 Sample ID 18010967-001ams SampType: MS TestCode: telp-voc-MST Units: mg/L Prep Date: RunNo: 80027 Client ID: BatchQC Batch ID: 30617 TestNo: SW8260B SW1311M Analysis Date: 1/30/2018 SegNo: 1397296 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ 1,1-Dichloroethene 0.221 0.0500 0.200 0 110 39.9 160 1,2-Dichloroethane 0.191 0.0500 0.200 0 95.3 42.5 157 MEK 1.02 0.250 1.00 0.0476 96.8 16.6 227 Benzene 0.195 0.0500 0.200 0 97.6 38.1 155 Carbon tetrachloride 0.196 0.0500 0.200 0 98.1 40.8 162 Chlorobenzene 0.191 0.0500 0.200 0 95.6 35.7 168 Chloroform 0.199 0.0500 0.200 0 99.3 18.3 199 Tetrachloroethene 0.205 0.0500 0.200 0 102 10 261 Trichooroethene 0.194 0.0500 0.200 0 97.0 23.8 175 Vinyl chloride 0.171 0.0200 0.200 0 85.6 10 165 Surr:4-Bromofluorobenzene 526 500.0 105 84.6 130 Surr: Dibromofluoromethane 505 500.0 101 71.4 127 Surr: Toluene-d8 515 500.0 103 74.6 127 Sample ID 18010967-001amsd SampType: MSD TestCode: telp-voc-MST Units: mg/L Prep Date: RunNo: 80027 Client ID: BatchQC Batch ID: 30617 TestNo: SW8260B SW1311M Analysis Date: 1/30/2018 SegNo: 1397297 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.227 0.0500 0.200 0 113 39.9 160 0.221 2.54 25 1,2-Dichloroethane 0.194 0.0500 0.200 0 96.8 42.5 157 0.191 1.56 25 MEK 1.02 0.250 1.00 0.0476 97.1 16.6 227 1.02 0.230 25 Benzene 0.197 0.0500 0.200 0 98.5 38.1 155 0.195 0.897 25 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine Original MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 17 of 27 r ' ? - l Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ,—-Is eravlres�;rv�fnervinl.rrtia�e�oLtr�1�4,1h.�. Cuyahoga Falls, Ohio44223 WO#: 18011035 ?1.nz44,`ii.cal L7ba.rWortE , TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htta:Uwww.settekcom 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30617 Sample ID 18010967-001amsd SampType: MSD TestCode: tclp-voc-MST Units: mg/L Prep Date: RunNo: 80027 Client ID: BatchQC Batch ID: 30617 TestNo: SW8260B SW1311M Analysis Date: 113012018 SegNo: 1397297 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.198 0.0500 0.200 0 99.1 40.8 162 0.196 1.03 25 Chlorobenzene 0.192 0.0500 0.200 0 96.1 35.7 168 0.191 0.600 25 Chloroform 0.201 0.0500 0.200 0 100 18.3 199 0.199 1.04 25 Tetrachloroethene 0.209 0.0500 0.200 0 105 10 261 0.205 2.18 25 Trichloroethene 0.197 0.0500 0.200 0 98.7 23.8 175 0.194 1.79 25 Vinyl chloride 0.198 0.0200 0.200 0 98.9 10 165 0.171 14.4 25 Surr: 4-Bromofluo ro benzene 522 500.0 104 84.6 130 0 25 Surr: Dibromofluoromethane 505 500.0 101 71.4 127 0 25 Surr: Toluene-d8 514 500.0 103 74.6 127 0 25 Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 18 of 27 e E mu Summit Environmental Technologies, Inc. 3310 Win St. _ QC SUMMARY REPORT tr4.%-1K 'Nfo1WN IAk p 1.4.;H FJLUUR—!a`, INC. Cuyahoga Falls, Ohio 44223 WO#: 18011035 flr,ntyR-q r1 Lab)vAstorips TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htto:/gwww.settelc.coni 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: R79880 Sample ID MB-R79880 SampType: MBLK TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 Client ID: PBW Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390960 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Cyanide, Reactive ND 0.500 Sample ID LCS-R79880 SampType: LCS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 Client ID: LCSW Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390962 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Cyanide, Reactive 0.987 0.500 1.000 0 98.7 85 115 Sample ID 18010875-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 Client ID: BatchQC Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390965 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] Cyanide, Reactive 1.08 0.500 1.000 0 108 81.3 118 W NOTES: Sample was received not meeting proper temperature requirements. Sample ID 18010875-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 Client ID: BatchQC Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390966 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Qualifiers: x Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank B Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to detennine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 19 of 27 y Summit Environmental Technologies, Inc. QC SUMMARY REPORT 3310 Win St. �,[ 1. �7 U lalvd 1 1 t711M}rVNPr11,N JAI. e ti. "uULu 3i 5: arviC Cuyahoga Falls, Ohio 44223 WO#: 15011035 Anzr,.+Uff1 L2xbcrafurieu TEL: (330) 253-8211 FAX- (330) 253-4489 Website: httD•//wwiv.settelc.com 31-Tan-18 Client: Synagro Project: Cherryville WWTP BatchID: R79880 Sample ID 18010875-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 Client ID: Batch= Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390966 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qua[ Cyanide, Reactive 1.07 0.500 1.000 .0 107 81.3 118 1.075 0.186 10 W NOTES: Sample was received not meeting proper temperature requirements. Qualifiers: :k Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank 7 Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 20 of 27 Summit Environmental Technologies, Inc. QC SUMMARY REPORT summlor 3310 Win St. e V 1H NratiM IAL 7 t t a NULttMS, rrtw. Cuyahoga Falls, Ohio 44223 WO#: 18011035 Arv?yle-cal' L.xiao.ra ur±es TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htty✓/www.settelf.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: R79884 Sample ID LCS-R79884 SampType: LCS TestCode: Ignitability_S Units: Prep Date: RunNo: 79884 ;lient ID: LCSS Batch ID: R79884 TestNo: SW1030 Analysis Date: 1/25/2018 SegNo: 1391034 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability 6.22 Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds 7.240 0 85.9 70 130 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 21 of 27 Summit Environmental Technologies, � �� `} 1, : - 331Inc. Win St. QC SUMMARY REPORT t'e Irrca carol M I RL r Ltuaa�uutt�ts. INC Cuyahoga Falls, Ohio 44223 WO#: 18011035 71.rrtrlyllaal Laborai.o,rier TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settelc.coni 31-Jan-I8 Client: Synagro Project: Cherryville WWTP BatchID: R79888 Sample ID MB-R79888 SampType: MBLK TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: PBW Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391078 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive ND 25.0 Sample ID LCS-R79888 SampType: LCS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: LCSW Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/26/2018 SegNo: 1391079 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Sulfide, Reactive 4710 25.0 4800 0 " 98.1 85 115 Sample ID 18010875-001AMS SampType: MS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: BatchQC Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391081 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4860 25.0 4800 0 101 75 125 W NOTES: Sample was received not meeting proper temperature requirements. Sample ID 18010876-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: BatchQC Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391082 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 22 of 27 T 7 a Summit Environmental Technologies, Inc. QC SUMMARY U M ,� R REPORT b IiJ 3310 Win St. li U let i �1� i REPORT 1 Lr oIKu,r-aroi.NIAI, i4-t;"F4uLuiaits,irtc. Cuyahoga Falls, Ohio44223 WO#: 18011035 a} �ayrPl,c+�i LRTgr�ta" TEL: (330) 253-8211 FAX.- (330) 253-4489 6lrebsite: hgp://www.settelr.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP Batch)D: R79888 Sample ID 18010876-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: BatchQC Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391082 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Sulfide, Reactive 4700 25.0 NOTES: Sample was received not meeting proper temperature requirements. Qualifiers: ;k Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds 4800 0 97.9 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 75 125 4860 3.35 E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits 30 W Original Page 23 of 27 gi-Summit Environmental Technologies, Inc. QC SUMMARY REPORT �l 1 3310 Win St. n IM4rrarru Pd I ?h a'rr.4adsaLr�lta, �rsti, Cuyahoga Falls, Ohio 44223 WO#: 18011035 4 zffieUY CxT+btr,r fra,rre TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htto:/hvivw.settelc.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: R80006 Sample ID 18011425-001ADUP SampType: DUP TestCode: pH_Oil(9045 Units: s.u.@18.6C Prep Date: RunNo: 80006 client ID: BatchQC Batch ID: R80006 TestNo: SW9045D Analysis Date: 1/30/2018 SegNo: 1395686 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 5.5 0 0 5.5 0.5 10 Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Penn it Limit E Value above quantitation range M Manual Integration used to determine 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 24 of 27 T �$Summit Environmental Technologies, Inc. QC SUMMARY REPORT G k3310 Win St. Lr tiIrir.��NTAI N I Al. u n aa�a�uuat3t�sINN: Cuyahoga Falls, Ohio 44223k.nzfdlrPicAi t ;T'uar9itarrE s WO#: 18011035 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:/hviviv.settelc.coni 31-.Tan-18 Client: Synagro Project: Cherryville WWTP BatchID: R80006 Sample ID LCS-R80006 SampType: LCS TestCode: pH_DW(4500- Units: s.u.@21.7C Prep Date: RunNo: 80006 Client ID: LCSW Batch ID: R80006 TestNo: SW9045D Analysis Date: 113012018 SegNo: 1396673 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 98.6 101.4 Sample ID 18011149-001BDUP SampType: DUP TestCode: pH_DW(4500- Units: s.u.@19.8C Prep Date: RunNo: 80006 Client ID: BatchQC Batch ID: R80006 TestNo: SW9045D Analysis Date: 1/30/2018 SegNo: 1395675 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.2 7.2 0 5 Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. P Second column confirmation exceeds B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine O RSD is greater than RSDlimit R RPD outside accepted recovery limits Original Page 25 of 27 Emll� Summit Environmental Technologies, Inc. Anal Request/Chain of Custody 3310 Wm Street Analysis Cuyahoga RIK Ohio 44223 TW: 330,253.8211 Fax: 330.253.4489 For Summit Environmental Technologies, Inc. use only Page -of- I SET Na Company Name, (Please Print) Project 196ID& . ..... 7 __7 rame rs OW'Pa te and Methods Company *(Iressf Project Address Z 07 k� L2 Client Phone Na 33,� 7 t>6 W Report to Client Fax No. Please F" HMWdts PON a ii -fleagg Haman EMAUr ClfpntFmafi Quote No. v r St'J vko'k MI, V1 contact Persol, .2 0.4 6 .0 % — �-4 Sinpla by k Check WOWD YAP samples &f✓.2, El: Collected 611Wd z Q,e_rr4M"1k,z 1,\)kmp 1.0 WA ovI IV '101:7 %Av 1 %001 -IT%, op Deceived by: Date 9ime a er x2 J state of Sample Orlgln-.__.0 Must be aPp—od 77 Rush Requested By. LD6--\J Check if FOR COMPLIANCE Dato I by lab manager White Sad yellow pages shMd accompany.umples to Ux labordory. no client 126458_f,� I of 1 Page 26 of 27 t Summit Environmental Technologies, Inc. 3310 Win St. r k'41R4hIPdEt'rI.L?_ 3tPdt�L4Gs , tG_ Cuyahoga Falls, Ohio44223 Sample Login Check List Arr,31"vU+ 31 Labaraioriaw TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://wwiv.settek.com Client Name: SYN-NC-27028 Work Order Number: 18011035 RcptNo: 1 Logged by: Christopher Livengood 1/23/2018 7:45:00 AM ' Completed By: Christopher Livengood 1/23/2018 1:35:15 PM Reviewed By: Jennifer Woolf 1/26/2018 6:22:22 PM Chain of Custody 1. Is Chain of Custody complete? Yes ❑d No ❑ Not Present ❑ 2. How was the sample delivered? FedEx Log In 3. Coolers are present? Yes ❑d No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes 0 No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes d❑ No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes d❑ No ❑ 8, Sufficient sample volume for indicated test(s)? Yes d❑ No ❑ g. Are samples (except VOA and ONG) properly preserved? Yes 91 No ❑ 10. Was preservative added to bottles? Yes ❑ No ❑ NA ❑J NA 11. Is the headspace in the VOA vials less than 114 inch or 6 mm? Yes ❑ No ❑ No VOA Vials 0 12. Were any sample containers received broken? Yes ❑ No 13. Does paperwork match bottle labels? Yes 0 No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes W1 No ❑ 15. Is it clear what analyses were requested? Yes W No ❑ 16. Were all holding times able to be met? Yes Se No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA 0 Person Notified: Date Ir By Whom: I ` v Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact I Seal No Seal Date Signed By 1 13.8 Goodl Not Present Page 27 of 27 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Cherryville WQ Permit Number: WWTP Name: City of Cherryville WWTP NPDES Number: — V00000430 NCO044440 Monitoring Period: From Jan 1, 2017 To Dec 31, 2017 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. l/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative perlormeril Class A or Culass 13 com fete the ionowing monitoring aata: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10to the 6th MPN MPN/g Coliform power per gram of total solids 19,697 27,646 37,695 CFU/g 0 Annual grab SM9221E CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 (VTreduction) Option/Alt. 5 (14-Day Aerobic) Option/Alt. 9 (Injection) Option/Alt. 2 (40-day bench) Option/Alt. 6 (Alk Stabilization) Option/Alt. 10 (Incorporation) CERTIFICATION STATEMENT (please check the appropriate statement) Option/Alt. 3 (30-day bench) X Option/Alt. 7 (Drying — Stable) Option/Alt. 4 (Spec. 02 uptake) Option/Alt. 8 (Drying — Unstable) No vector attraction reduction alternatives were performed "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including me and imprisonment." Larry WriLrht, Plant ORC.& PlantSuperintendent —7cs�1 d^- � � e. ""5 Preparer ame and Title (type r print Land Applier Name and Title. (if applicable) (type or print) rignayre o rep er* Date Signature L ier (f pplicable) hate atrep is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) plAmIll PROM PT- A CCU RATE -RE LIABLE LABORATORIF.S, INC WWWPARLABS.CUN1 REPORT OF ANALYSES Attn: ERIX BRUCE SYNAGRO 284 BOGER ROAD MOCRSVILLE, NC 27028- PROJECT NAME: JAN 17 DATE: 02/22/17 SAMPLE NUMBER- 126318 SAMPLE IDL CHERRYVILLE, NC SAMPLE MATRIX- SO DATE SAMPLED- 01/17/17 TIME SAMPLED- 0930 DATE RECEIVED- 01/17/17 SAMPLER- EB RECEIVED BY- DJ TIME RECEIVED- 1130 DELIVERED BY- EB TYPE SAMPLE- Grab Page 1 of 1 ANALYSIS ANALYSIS METHOD DATE TIME BY RESULT UNITS 30 DAY- BENCH --SCALE TEST - --- - - -VAR- ---- - 01/17/17 --RE ATTACHED-- ..-__.._ . FECAL COLIFORM (GEOM. MEAN) SM 9221 E 01/17/17 1345 RE 27,646 MPN/g LABORATORY DIRECTOR P.O. Box 411483 • Charlotte, NC 28241-1483 Phone: (704) 588-8333 • Fax: (704) 588-8335 PAAF;Z PROMPT -ACCURATE- RELIABLE I.ABORAT®RIES, IWC WWW.PARLABS.COM 30 ®ay Bench Scale Extended Aeration Test Percent Volatile Solids Deduction C, Ei�'li TUAME. SAMPLE ID,:CHERRYVILLE, .:SAMPLE°j# � � • , � . ,� START DATE:, • NC E-ND Start: End: TS () 0.1591 0.1433 TS% 1.06% 1.02% VS ( 0.0997 0.0845 VS% 62.66% 58.97% N 0.002732 pUT 0.00237861 FSVR (Mass Balance) 12.95% FSVR (Van Kleeck) 14.38% FSVR Mass Balance) <15% _YES --- FSVR (Van Kleeck) <15% YES P.O. Box 411483 • Charlotte, NC 28241-1483 Phone: (704) 588-8333 a Fax: (704) 588-8335 I ra RA PROM PT-ACCURATE • RELIABLE LABOI2ATORIES� INC 2217 Graham Park Drive PO Box 411483 Charlotte, NC 28241-1483 NC Cert # 20; SC Cert # 99003001 SYNAGRO CHERRYVILLE, NC 01/17/17 FECAL COLIFORM, GEOMETRIC MEAN RI A R 11 SM 9221 E WM LAE W 8 1 326 1.06% 30,857.26 -- ---- - 2 369 0.98% 37,695.69 3 243 1.00% 24,285.90 4 248 0.94% 26,209.63 - 5 - 284--- --0 96%- - -29;605:42- 6 195 0.99% 19,697.76 7 294 1.03% 28,588.75 Fecal Coliform Geometric_ Mean=_ •' • LPAR ATORIES. INC. www.parlabs.com Shipping: 2217 Graham Park Drive Charlotte, NC 28273 CHAIN OF CUSTODY PAR Laboratories, Inc Phone (704) 588-8333 Fax (704) 588-8335 Mailing: PO Box 411483 Charlotte, NC 28241-1483 It is essential that all information be recorded on this Chain of Custody document for acceptance by PAR Laboratories, Inc. and the North carouna ueparcmenc or rnwronmemal dnu Ndwidi ncaum ca. Company Name (billing) SYNAGRO CENTRAL Address 284 BOGER ROAD City, State Et zip code MOCKSVILLE, NC 27028 Point of Contact Et Telephone Number ERIK BRUCE 336-703-8681 Comments/ Special Instructions F-6Luce e -S� V�"05rc I Corv'- Sample Taken By: SIGNATURE PRINTED NAME�- 4-- ARE SAMPLES FOR STATE or EPA REPORTING? YES NO *Sample Type: DW ww GWMW _ HW _ Soil other 1J Sample Temp at time of sampling: ° C Sample Temp upon receipt: ° C **Field Preserved: Yes No Teflon Liner/Zero Headspace: Yes No n/a Residual Chlorine checked at time of sampling (YIN): Dechlorination Necessary (Y/N): lient Sample I.D. (Sample Location ! Number) Comp Grab Presenr. Set Up Date/Time Collection Date rime Analyses Requested I-7:3 hM 30 DAY BENCH �l s- t/I�yS A FC/GM Relinquished by: uatet I ime Kecewe Uv: —.1 . unc Relinq d by: Dale/Time Received by: Date/Time C=Composite G=Grab DW=Drinking Water WW=Wastewater GWMW=Groundwater Monitoring Well HW=Hazardous Waste — See Other Side Agricultural Lime Application Log Year: 2017 Project: Cherryville Field (state -county -site -field) Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied LT-120-2 5.4 0.8T/Ac. 'Variable Rate 02/28/17 LT-120-3 4.9 2.1 T/Ac. *Variable Rate 02/28/17 0.OT/Ac. O.OT/Ac. O.OT/Ac. "I he Farmer used grid soil sampling to hit targeted FH levels, varying the amount or lime applied to eacr Attached is a copy of this grid and amount of lime applied. Page 1 of 1 Report Number: 17-051-0872 ' • Account Number: 46488 WayOl ��TM 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 o Fax 804-271-6446 � Send To: SYNAGRO CENTRAL LLC/SALISBURY ANALYTICAL www.waypointanalytical.com Mary Brewer Every acre... Every year. Grower: Wayne Gulbert 284 BOGER RD MOCKSVILLE NC 27028 SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH 1 _. U t Date Received: 02/20/2017 Date Of Analysis: 02/21/2017 Date Of Report: 02/22/2017 �� ✓ ty t 2gib ✓ (� , k `' t ( �'r ` r' OM W1V ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity _.C'E.0 Sample ID Lab Field ID Number % Soil Ibs/A M3 K Mg Ca Na Soil Buffer H Rate Class ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g LT-120-2 12926 5.6 150 176 VH 87 L 86 L 640 L 10 VL 4.9 6.60 3.3 7.5 IMIN H NC = 147 NC = 45 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron soluble Salts Sample ID Field ID K Mg Ca Na H NO, N S Zn Mn Fe Cu B SS % % % IN, % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate LT-120-2 3.0 9.6 42.7 0.6 44.0 120 VH 8.5 VH 15 M 162 VH 5.3 VH 0.4 L 0.51 L NC=250 NC=212.5 NC=94 NC=265.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), H VH (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. by: gw`. (High), (Very High). ENR - Estimated Nitrogen Release. C.E.C. -Cation Exchange Capacity. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble Salts ms/cm x 640 = ppm; Analysis prepared by: Waypoint Analytical Virginia, Inc. S � �._ 1 F �. i J,,- j �J r; r. ,V ,N� Pauric McGroary Date Received: 02/20/2017 Date Of Report: 02/22/2017 SOIL FERTILITY RECOMMENDATIONS Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Sample ID Intended Crop Yield Goal Lime N P206 K20 Mg S Zn Mn Fe Cu B Field ID Tons/A Ib/A ib/A Ib/A Ib/A Ib1A Ib/A Ib/A Ib/A Ib/A Ib/A LT-120-2 Adjust pH to 6.0 0 2.1 0 2 0 Comments "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977. Page 1 of 1 Report Number: 17-355-0740 • Account Number: 46488 Waypoint Send To: SYNAGRO CENTRAL LLC/SALISBURY ANALYTICAL Mary Brewer Every acre... Every year.'4M 284 BOGER RD MOCKSVILLE NC 27028 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Grower: Wayne Gilbert Farm-ID/Name: LT-120 SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH Date Received: 12/21/2017 - Date Of Analysis: 12/22/2017 Date Of Report: 12/22/2017 Sample ID Lab OM WN ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Field ID Number % Soil Ibs/A M3 K Mg Ca Na Soil Buffer H Rate Class ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate PH Index meq/100g meq/100g 03 04730 4.5 133 161 VH 93 H 88 H - 443 L 15 VL 5.4 6.80 1.3 4.6 MIN M NC = 134 NC = 48 Sample Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts ID Field ID K Mg Ca Na H NO,N S Zn Mn Fe Cu B SS % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate 03 5.2 15.9 48.2 1.4 28.3 21 M 6.4 H 16 M 155 VH 4.2 VH' 0.4 L 0.14 VL NC=44 NC=160.0 NC=100 NC=210.0 L,� ,cNuL IcNnuro Ieset pianL avauame nuirients in me soil. Rating after each value: VL (Very Low), L (Low), M (Medium), H (High), VH (Very High). ENR - Estimated Nitrogen Release. C.E.C. - Cation Exchange Capacity. Date Received: 12/21/2017 Date Of Report: 12/22/2017 explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble Salts ms/cm x 640 = ppm. Analysis prepared by: Waypointnnalytical Virginia, Inc. SOIL FERTILITY RECOMMENDATIONS by: Pw,. P 6ewr Pauric McGroary Sample ID Yield Goal Lime Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Field ID Intended Crop Tons/A N P205 K20 Mg S Zn Mn Fe Cu B Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A 03 Adjust pH to 6.0 0 0.8 1 1 1 1 0 2 0 comments: "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977. RECEIVED/NCDENR/DWR 3 MAR - 6 20P WQROS MOORESVILLE REGIONAL OFFICE CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. VW00000430 2016 ANNUAL REPORT ECE'IJLD Itfvii'ia%1;L'T? FC�� fi > flii ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00000430 County Gaston Year 2016 Facility Name (as shown on permit) City of Cherryville W WTP NPDES No. NCO044440 Land Application Operator S�nagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: Total number of fields utilized for land application during the year: Total amount of dry tons applied during the year for all application sites: Total number of acres utilized for land application during the year: Part B — Annual Compliance Statement: Facility co m lian daA i i e nclu ' ut limited to items bel iss i I iof p ����t� �� V4 ,ple r nipt ac was no complian , e orr ak� 6 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including t e s111' ' of fines and imprisonment for knowing violations." y Larry Wright, Plant ORC & Plant Supervisor a Permittee Name and Title (type or print) SignatIre of Perml4ee Date Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) RECEIVEDINCDENRIDWR MAR 8 2016 WQROS MOORESVILLE REGIONAL OFFICE CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2015 ANNUAL REPORT City of Cherryville, NC Residuals Land Application Program 2015 Annual Report TABLE OF CONTENTS 1. Certification Form, Annual Operations Summary, Facility and Land Applier Contact Information 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen ReductionNector Attraction Reduction 6. Soil. pH & Lime Application Records 7. Soil Analyses .41 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00000430 County Gaston Year 2015 Facility Name (as shown on permit) City of Cherryville WWTP NPDES No. NCO044440 Land Application Operator S} nagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 9 Total number of fields utilized for land application during the year: 2 Total amount of dry tons applied during the year for all application sites: 90.52 Total number of acres utilized for land application during the year: 40.1 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2015 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including ticossibility of fines and imprisonment for knowing violations." Larry Wright. Plant ORC & Plant Supervisor Pennittee Name and Title (type or print) ;Ae 6 2016 Signature of Preparer* Date . Sigature of Land Arplier Date (if different from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2015 ANNUAL OPERATIONS SUMMARY -LAND APPLICATION CHERRYVILLE, NC CHERRYVILLE, NC LIQUID MONTHNEAR November 2015 YEARLY TOTAL AMOUNT UNIT DRY TONS 756,400.00 G 90.52 756,400.00 G 90.52 DRY METRIC UNIT TONS D 82.11 D 82.11 1 /29/2016 2015 ANNUAL REPORT PROJECT: City of Cherryville, NC FACILITY: City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 NPDES PERMIT NUMBER: NCO044440 RESPONSIBLE OFFICIAL: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 FACILITY OPERATOR: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 LAND APPLIER AND PREPARER OF LAND APPLICATION ANNUAL REPORT: Synagro Central, LLC Contact: Marshall Puryear (336) 998-7150 ext. 17 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 09/21/15 Date Composited Percent Solids 2.87 PARAMETERS (mg/kg dry weight) Arsenic 5 Cadmium 3 Mercury 1.5 Chromium 142 Copper 829 Lead 36 Molybdenum 17 Nickel 85 Selenium <5 Zinc 1040 Total Phosphorus 17800 TKN 38300 Ammonia -Nitrogen 14300 Nitrate and Nitrite <2 Laboratory WAYPOINT ANALYTICAL "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false ' mation, including the possibility of fines and imprisonment for knowing violations." 1l E OF PFEPARER) Date � - 9 — Ro DENR FORM RSSF (5/2003) Printed: Friday - January 29, 2016 at 10:03:54 for: 2008 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 09/21/15 Date Composited Percent Solids 2.87 PARAMETERS (mg/kg dry weight) Aluminum 26400 Calcium 12000 Magnesium 3620 pH 7.91 Potassium 2 68 0 Sodium 1750 Laboratory WAYPOINT ANALYTICAL "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." X (SI NR - Date 1�6t Reported or Data Not Required Date 2-9-I1� nENR FORM RSSF-B (7/2002) Printed: Friday - JanuarV 29, 2016 at 10:04:20 for: 2008 01 Page: 1 of 2 Report Number: 15-266-0201 Account Number: 46442 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 64374 Sample Id: CHERRYVILLE . '0� Waypoint �. rANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project: CHERRYVILLE NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/21/2015 11:30:00 Date Received: 09/23/2015 00:00 Date Reported: 09/28/2015 Total Solids * 2.87 28700 100.0 JM 09/23/2015 15:20 SM-2540G Moisture * 97.13 100.0 JM 09/23/2015 15:20 SM-254OG Total Kjeldahl Nitrogen 3.83 38300 10.0 JM 09/24/2015 09:24 SM-4500-NH3C-TKN Total Phosphorus 1.78 17800 100 KM 09/24/2015 10:03 SW 6010C Total Potassium 0.27 2680 100 KM 09/24/2015 10:03 SW 6010C Total Sulfur 0.86 8630 100 KM 09/24/2015 10:03 SW 6010C Total Calcium 1.20 12000 100 KM 09/24/2015 10:03 SW 6010C Total Magnesium 0.36 3620 100 KM 09/24/2015 10:03 SW 6010C Total Sodium 0.18 1750 100 KM 09/24/2015 10:03 SW 6010C Total Iron 29000 100 KM 09/24/2015 10:03 SW 6010C Total Aluminum 26400 100 KM 09/24/2015 10:03 SW 6010C Total Manganese 455 5 KM 09/24/2015 10:03 SW 6010C Total Copper 829 5 KM 09/24/2015 10:03 SW 6010C Total Zinc 1040 5 KM 09/24/2015 10:03 SW 6010C Ammonia Nitrogen 1.43 14300 10.0 JM 09/24/2015 09:24 SM-4500-NI3C Organic N 2.40 24000 10.0 09/24/2015 09:24 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 09/24/2015 09:25 SM-4500NO3E Total Cadmium 3.0 2.0 KM 09/24/2015 10:03 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters am lorlhe exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made , to the wcltr, the results, or the company in any advertising, news release, or otherpublic announcements without obtaining ourpdor written authorization. Debbie Holt Page: 2 of 2 Report Number: 15-266-0201 Account Number: 46442 Submitted By: MARSHALL PURYEAR Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 a ip Waypoint ANALYTICAL 7621 Whiteping Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804,271-6446 www.waypointanalytical.com Project: CHERRYVILLE NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/21/2015 11:30:00 Lab Number: 64374 Date Received: 09/23/2015 00:00 Sample Id: CHERRYVILLE Date Reported: 09/28/2015 Total Chromium 142 5 KM 09/24/2015 10:03 SW 6010C Total Nickel 85 5 KM 09/24/2015 10:03 SW 6010C Total Lead 36 5 KM 09/24/2015 10:03 SW 6010C Total Arsenic 5.0 3.0 KM 09/24/2015 10:03 SW 6010C Total Mercury 1.5 0.4 KM 09/23/2015 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 09/24/2015 10:03 SW 6010C pH (Standard Units) * 7.91 2.00 JM 09/24/2015 09:24 SW-9045D Total Molybdenum 17 5 KM 09/24/2015 10:03 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announrements without obtaining our prior written authorization. Debbie Holt n1d �IS 4sp -0. PLI17 n . 0. .1 _L alse 'ujS pu.13 joddoo'OsQuOuPINA.u. uj(unjV'CJQlj..LUnjPOS'Wn!s APIN 'wnioNo 'm InS s UlnjsSL,Jod pUe '$nJQLjd§cq4 lu@OojliN ILILIP191A ltqOL "(OJn.IS.IOV4) 1MICS IPTOL I MS -001 '001 osl ool 04, po N SpIJQs,7-ATdb5 Hd OS 614 -SV qd. IN JO N ON !3. ids 3. OW aldWVS is2n.ww siskivnv ....... Ul Nis) ,q POA�R� OLUJJ up(l :Aq, paqsjnbujjaH A ... .......... . :A-q pp "R b JL T-lp We S�q 14 a3ddiHS MIA.HaS211:1d, aWIl 31VCI StONIVU00 aoHiaw ONI-Idwvs :30 WV Isafaweg Qmqyl 10 ljojj;qellojauj AM. I s- Ino Ao- wl NOUVO4-1 ev-1 21'I-dWVS UNIldWVS waimoisno Tv -l9VNVW.LO�TOlJd M, :uEnmoisno. 001 ON.pcjlNvq Sodium Absorption Ratio Calculati®n (SAR) Product Code Product Name Sample Date ReportRange Ratio 2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 9/21/2016 111/2015-12/31/2015 0.6071 Na mg/I = (Na mg/kg x % Solids) = 100 = (1750 x 2.8700) = 100 = 50.225 Ca mg/1 = (Ca mg/kg x % Solids) _ 100 = (12000 x 2.8700) _ 100 = 344.4 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (3620 x 2.8700) = 100 = 103.894 Na meq = Na mg/I _ Molec.Wgt.Na = 50.225 _ 23 = 2.1837 Ca meq = Ca mg/I = Molec.Wgt.Ca = 344.4 _ 20 = 17.22 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 103.894 = 12 = 8.65783 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.1837 _ SgrRoot[0.5(17.22+8.65783)] = 0.607076 Printed: 1/29/2016 Page 1 10:07 FACILITY NAME: CHERRYVILLE, NC OWNER: KEITH BEAM SITE #: NC LT 00124 FIELD# : LT 00124 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: W00000430 ANNUAL DRY TONS APPLIED: 72.72 OPERATOR: KEITII BEAM CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 30.00 ACRES PERMITTED: 30.00 Page: 1 Lime Applied *** Date Lbs/Ac DATE or MONTH allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop Total Per Acre 11/14/15 186,000.00 (G) 6200.000 2.87 0,742 CHL MOIST 0-<1/2" SUR 0.5 0.30 38,300.p 14,300.00 p 2.00 p F 14352 FESCUE PASTURE 11/15/15 167,400.00 (G) 5580.000 2.87 0.668 CHL MOIST 0-<1/2" SUR 0.5 0.30 38,300. p 14,300.00 p 2.00 p 14352 FESCUE PASTURE 11/16/15 217,000.00 (G) 7233.333 2.87 0.866 CHL DRY 0-<1/2" SUR 0.5 0.30 38,300.p 14,300.00 p 2.00 p 14352 FESCUE PASTURE 1.1/17/15 37,200.00 (G) 1240.000 2.87 0.148 CHL DRY 0-<1/2" SUR 0.5 0.30 38,300. p 14,300.00 p 2.00 p 14352 FESCUE PASTURE Nov-15 607,600.00 (G) 20,253.333 Fatal Gallons/Ac: 20,253.33 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annual lbs/acre 70 0.024 0.015 0.688 4.019 0.175 0.007 0.082 0.412 0.024 5.042 86.29 Cumulative lbs/acre 0.163 0.114 4.744 27.510 1.475 0.037 0.645 3.276 0.164 44.896 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop ;' w ;' 156 F.D Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 , , 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID x .2-o 9// 6 (SIG A'P RE d LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/lcg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2016 FACILITY NAME: CHERRYVILLE, NC OWNER: KEITH BEAM SITE #: NC LT 00124 FIELD# : LT 00124 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: WQ0000430 ANNUAL DRY TONS APPLIED: 17.81 OPERATOR: KEITH BEAM CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 10.10 ACRES PERMITTED: 10.10 Page: 1 Lime Applied *** Date Lbs/Ac DATE or MONTH allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop Total Per Acre 11/17/15 130,200.00 (G) 12891.089 2.87 1.543 CHL DRY 0-<1/2" SUR 0.5 0.30 38,300. p 14,300.00 p 2.00 p 14352 FESCUE PASTURE 11/18/15 18,600.00 (G) 1841.584 2.87 0.220 CHL DRY 0-<I/2" SUR 0.5 0.30 38,300. p 14,300.00 p 2.00 p 14352 FESCUE PASTURE Nov-15 148,800.00 (G) 14,732.673 1 otal t_iallons/Ac: 14,732.67 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annual lbs/acre 51 0.018 0.011 0.501 2.923 0.127 0.005 0.060 0.300 0.018 3.667 62.77 Cumulative lbs/acre 0.027 0.017 0.764 5.275 0.214 0.008 0.094 0.459 0.035 7.279 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop77 129 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID eC Q (STGNAT RE OF LAND APPLIER) DATE "I certify, tinder penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2016 Cherrm le WWTP, NC TCLP TCLP is only required once perpermit cycle. Sampling was done on 7/25/2011 and the results were submitted in the 2011 Annual Report. ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Cherryville WQ Permit Number: WQ0000430 WWTP Name: City of Cherryyille WW NPDES Number: NCO044440 Monitoring Period: From Jan 1, 2015 To Dec 31, 2015 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2xl0 to the Oh MPN 11,948 17,326 21,409 MPN/g 0 Annual grab SM 9221E Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) X (Spec. 02 uptake) Option/Alt. 5 Option/Mt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X_ reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met_ I am aware that there are significant penalties for false certification including fine and imprisonment." Larry Wright, Plant ORC & Plant Superintendent Prep er Name and Tpct,51Nor print) Land Applier Name and Title (if applicable) (type or print) 2__q 16 S afore of reparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) PA LABOR—A:rORIES, INC 2 No, 7 r-� 02 lVE17D a 7. 7S 7S, EM" 7 7 RO. fiux 411483 - Charloite. NC .-'i24 1-14,S3 Fax: i-,04) 58,�-83- ) RA i'RpMPT ACC.7URATE• RELIABLE T--kBQOR—A=OR.ZES, IWC 2217 Graham Park Drive PO Box 411.483 Charlotte, NC 28241-1483 NC Cert#20, SC Cert#99003001 le.t!-a n ^ „try �' 'a 4kALYSIS;II EjkCQi • P�E��.iFo fi Fcl� 1. FCgra �'eanee�rc itft�an-�`tY� • PA: PROMT-ACCURAT•R�LIAB LE P LABC)i2ATC)RIBSj IZV'C WWW.PARLAeS.COM 30 Day Bench Scale Extended Aeration Test Percent Volatile Solids Red'uctian Start: End: TS ) 0.2215 0.2219 TS% 1.59°/a 1..59% VS (g) 0.1007 0.0976 VS% 45.46% 43.98% IN 0.002809 OUT 10.00272062 FSVR (Mass Balance) 3.16% FSVR (Van Kleeck) 5.81 % FSVR (Mass Balance) <15% YES FSVR (Van Kleeck) <15% YES P.O. B=41 t483 s Charlotte, NC W2#1-f483 Phone- (7G4) 388-8333 o Fax_ (794) +88-8335 ea ter, P PROMRTtACCURATE• RELIABLE L-A130P-A-rORiES; INC Shipping: 2217 Graham Park Drive Charlotte, NC 28273 CHAIN OF CUSTODY Phone, (704)588-8333 >=ax (704) 588-8335 Mailing: PO Box 411483 Charlotte, NC 28241-1483 It is essential, that all information be mconded cl this Chain cf Custody dccurr.enL for acceptance by PAR Laboratories, frc. and the Narih Carolina Department of Environmental and Natural Resources. Company Name (bitting) Comments/ Special Instructions t t3acress City, State & lip code fit uj�-K� , f/ Paint{of Contact i s Te?epho, N nbE Sample Taken By: -SIGNATURE -4-( 1-1--7,38- , PRINTED NAME -`, %� /leA ARE SAMPLES FOR STATE or EPA REPORTING? YES C�O *Sample Type: tint ww ` �� GtFAW 11W Solt Other Sample Temp at time of sampling: ° O Sample Temp upon receipt: ° G "Field Preserved: Yes No Teflon Liner/Zero Headspace: Yes No _ nia Residual Chlorine checked at time of sampling (YIN): Dechiorination Necessary (.YIN)`: Client Sample LD, Sample Location 1 Number) 1 + Comp I Grab Set Up Coiledicn Analyses , Pteserr, Date/Time Datefrime Requested i ; t i f f (E f Re.!P ulsned bT A U21t kme. mec 1wep Qy f' Y/ t ,� i 2j�.- llCiCf 11111C Retinquisheidl by: batejmrne Received by: DateMme C=Composite G=Grab DVS DrinkingVlater W P1=+Alastewater GIMA asoundrlater Monitoring Well HN=Hazardous+tJaste Agricultural Lime Application Log Year: 2015 Project: City of Cherryville Field pH(from Requirement Tons/Acre Date Applied LLime (state -county -site -field code) ILSoil soil analysis) Applied NC-LT-124-1 6.5 O.OT/ac N/A N/A NC-LT-I24-2 5.9 0.OT/ac N/A N/A NCDABC.S u—riomic Division .., Phone, (919.) 733-2655 Webslte: vp",4mvaur.gov/agronomi/ ReportNo. FY.,,, ,020906 Client: Keith Beam Advisor: Synagro !I v�7trr +~.4 Predictive 3079 Ishmael Beam Rd 284 Boger Rd Soil Report Mehlich-3 Extraction Cher ville, NC 28021 ry Mocksville, NC 27028 k..s5;1 Sampled County: Lincoln Sampled: Received: 12/01/2015 Completed: 01/15/2016 Farm: NC-LT-124 Links to Helpful Information Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) _ More Crop (tons/acre) N P2O6 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, 1 0.0 120-200 0 50 0 0 pH$ 0 0 0 Note: 12 Note: 2 -Fescue/OGrass/Tim, 0.0 120-200 0 50 0 0 pH$ 0 0 0 Note: 12 Note: . Test Results [units - W/V in g/c0; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.60 1.07 9.7 92 0.8 6.5 75 45 60 30 47 147 97 97 189 189 177 0.0 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O6 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, 1 0.0 120-200 0 10 0 0 0 0 0 0 Note: 12 2-Fescue/OGrass/Tim, 0.0 120-200 0 1'0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cni3; CEC and Na in meq/100 cm3; NO3-N in mg/do]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.56 1.07 8.5 81 1.6 5.9 88 71 52 25 30 160 113 113 148 148 125 0.0 North -Caroll: Ila a I Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve 7`rox NCDA&CS .=.,,-nomic Division Phone: (819) 733-2655 Websitec www..-�Pur,gov/agronomi/ Report No. FY°iu-QL Q2R906 Keith Beam Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Lime If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at o time, even if the report recommends more. You can apply the rest in similar increments every six months until the full ra is applied. If MG is recommended and lime is needed, use dolomitric lime. Fertilizer Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of Nacre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies for the crop being grown, not on soil test results. K-I and P-1 values are based on test results and should be > 50. If they are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear only on reports for greenhouse soil or problem samples. Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit ncagr.gov/agroiiomi/pubs.htm. Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find the exact fertilizer grade recommended on the report, visit www.ncacrr.pov/agronomi/obyart4.html sFind information that may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizes Test Results The first seven values (soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The remaining 16 (P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cud, S-1, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncaur.gov/agronomi/iivrst.htm Report Abbreviations Ac exchangeable acidity B boron BS% % CEC occupied by basic cations Ca% % CEC occupied by calcium CEC cation exchange capacity Cu-I copper index ESP exchangeable sodium percent HM% percent humic matter K-1 potassium index K20 potash Mg% % CEC occupied by magnesium MIN mineral soil class Mn manganese Mn-All Mn-availability index for crop 1 Mn-AI2 Mn-availability index for crop 2 Mn-I manganese index M-0 mineral -organic soil class N nitrogen Na sodium NO3-N nitrate nitrogen ORG organic soil class pH current soil pl-1 P-1 phosphorus index P206 phosphate S-1 sulfur index SS-1 soluble salt index W/V weight per volume Zn-AI zinc availability index Zn-I zinc index A*A NCDENR North Carolina Department of Environment and Natural Resources Pat McCrory Governor Mr. Larry Wright, WWTP Superintendent / ORC Town of Cherryville 116 South Main Street Cherryville, North Carolina -28021 Dear Mr. Wright: John E. Skvarla, III Secretary Subject: Acknowledgement of Receipt of the 2013 Annual Report Town of Cherryville - Permit No.: WQ0000430 Land Application of Residuals Gaston County The Mooresville Regional Office (MRO) received and reviewed the 2013 Annual Report for the above permit. The data submitted appears to be in accordance with permit requirements. The MRO plans to conduct an on -site facility inspection within the calendar year; however, if you have any immediate concerns or questions, please contact me by phone at (704) 663-1699 or email (maria.schutte a@ncdenr.gov). Sincerely; t . vVV aria Schulte, Environmental Specialist Mooresville Regional Office Water Quality Regional Operations Section Division of Water Resources, NCDENR CC: Marshall Puryear, Synagro (email) Ed Hardee, LAU Compliance, CO -Raleigh (email) Mooresville Regional Office, 610 East Center Avenue,. Mooresville, North Carolina 28155 Phone: 704-663-16991 Internet: www.ncdenr.gov An Equal Opportunity 1 Affirmative Action Employer — Made in part by recycled paper CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2013 ANNUAL REPORT P, E GLIZ�;VEI_ D c)F'MATEER QUALi-Pil F _E B 25 2014 RECEIVEDIDENRON FEB 2 0 2-014 Water Quality Permitting Section City of Cherryville, NC Residuals Land Application Program 2013 Annual -Report TABLE OF CONTENTS 1. Certification Form, Annual Operations Summary, Facility and Land Applier Contact Information 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. - Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses t,. mr—A.WP A YL LAVID, A,IPPLY—Z TION CERTIFICATION FORM WQ Permit #: W00000430 County Gaston Year 2013 Facility Name (as shown on permit) City of Cherryyille WWTP NPDES No. NCO044440 Land Application Operator Synaero Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 9 Total number of fields utilized for land application during the year: 2 Total amount of dry tons applied during the year for all application sites: 66.30 Total number of acres utilized for land application during the year: 45.3 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2013 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water QualityX YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. it. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Larry Wright. Plant ORC & Plant Supervisor Permittee Name and Title (type or print) Signature of Preparer* Date (if different from Permittee) r f e itt s Date Signature Signature of Land Applier Date (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) D1ENR FORM 91-C Ell V f'J-M ENR/DW R FEB 2 0 2014 Water Quality Permitting Section 2013 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION CHERRYVILLE, NC ,HERRYVILLE, NC LIQUID MONTHNEAR AMOUNT UNIT DRY TONS UNIT October 2013 551,800.00 G 53.16 D. November 2013 136,400.00 G 13.14 D YEARLY TOTAL 688,200.00 G 66.30 D DRY METRIC TONS 48.22 11.92 60.14 1 /22/2014 2013 ANNUAL REPORT PROJECT: City of Cherryville, NC FACILITY: City of.Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 NPDES PERMIT NUMBER: NCO044440 RESPONSIBLE OFFICIAL: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WVVTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 FACILITY OPERATOR: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 LAND APPLIER AND PREPARER OF LAND APPLICATION ANNUAL REPORT: Synagro Central, LLC Contact: Marshall Puryear (336) 998-7150 ext. 17 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: W00000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 09/04/13 Date Composited Percent Solids 2.31 PARAMETERS (mg/kg dry weight) Arsenic 4 Cadmium 4 Mercury 1.6 Chromium 76 Copper 926 Lead 39 Molybdenum 15 Nickel 78 Selenium <5 Zinc 1380 Total Phosphorus 17400 TKN 27300 Ammonia -Nitrogen 15200 Nitrate and Nitrite <2 Laboratory A&L EASTERN LABORATORIES, INC. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." X J, Date (SIG TU E OF.PREPARER DENR FORM RSSF (512003) Printed: Wednesday - January 22, 2014 at 12:58:20 for: 2008 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 09/04/13 Date Composited Percent Solids 2.31 PARAMETERS (mg/kg dry weight) Aluminum 25400 Calcium 10400 Magnesium 3060 pH 7.61 Potassium 2590 Sodium 1620 Laboratory A&L EASTERN LABORATORIES, INC. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penaltieps for submitting false information, including the possibility of fines and imprisonment for knowing violations." Date -11- i l (SIGVAT,JRE OF PREPARER) NR - D la Not Reported or Data Not Requi DENR FORM RSSF-B (7/2002) Printed: Wednesday - January 22. 2014 at 12:58:47 for: 2008 01 Page: 1 of 2 Report Number: 13-249-0205 Account Number: 46442 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 95355 Sample Id : CHERRYVILLE A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.6446 www.aleastem.com Project: CHERRYVILLE NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/4/2013 12:15:00 Date Received: 09/06/2013 00:00 Date Reported: 09/30/2013 Total Solids * 2.31 23100 100.0 JM 09/06/2013 14:30 SM-2540G Moisture * 97.69 100.0 JM 09/06/2013 14:30 SM-2540G Total Kjeldahl Nitrogen 2.73 27300 10.0 JM 09/16/2013 09:15 SM-4500-NH3C-TKN Total Phosphorus 1.74 17400 100 KM 09/09/2013 12:33 SW 6010C Total Potassium 0.26 2590 100 KM 09/09/2013 12:33 SW 6010C Total Sulfur 0.83 8300 100 KM 09/09/2013 12:33 SW 6010C Total Calcium 1.04 10400 100 KM 09/09/2013 12:33 SW 6010C Total Magnesium 0.31 3060 100 KM 09/09/2013 12:33 SW 6010C Total Sodium 0.16 1620 100 KM 09/09/2013 12:33 SW 6010C Total Iron 33300 100 KM 09/09/2013 12:33 SW 6010C Total Aluminum 25400 100 KM 09/09/2013 12:33 SW 6010C Total Manganese 689 5 KM 09/09/2013 12:33 SW 6010C Total Copper 926 5 KM 09/09/2013 12:33 SW 6010C Total Zinc 1380 5 KM 09/09/2013 12:33 SW 6010C Ammonia Nitrogen 1.52 15200 10.0 JM 09/16/2013 09:15 SM-4500-NI3C Organic N 1.21 12100 10.0 09/16/2013 09:15 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 09/09/2013 09:15 SM-450ONO3F Total Cadmium 4.0 2.0 KM 09/09/2013 12:33 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. JL&d Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made a�l to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 13-249-0205 Account Number: 46442 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 95355 Sample ld : CHERRYVILLE @D. A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (604) 743-9401 Fax (804) 271-6446 www.aleastern.com Project: CHERRYVILLE NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/4/2013 12:15:00 Date Received: 09/06/2013 00:00 Date Reported: 09/30/2013 Total Chromium 76 5 KM 09/09/2013 12:33 SW 6010C Total Nickel 78 5 KM 09/09/2013 12:33 SW 6010C Total Lead 39 5 KM 09/09/2013 12:33 SW 6010C Total Arsenic 4.0 3.0 KM 09/09/2013 12:33 SW 6010C Total Mercury 1.6 0.4 KM 09/09/2013 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 09/09/2013 12:33 SW 6010C pH (Standard Units) * 7.61 2.00 JM 09/09/2013 09:15 SW-9045D Total Molybdenum 15 5 KM 09/09/2013 12:33 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE %RPD WAS OUT OF LIMITS FOR "TKN". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Fe", "P", AND "S". ALL OTHER QC DATA IS ACCEPTABLE. TKN AND NH4-N RERAN PER CLIENT REQUEST. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt 5AMITI-L,143! LOG,* Y 08WMEJ S NAGIA1.0 -SOUTHE T _ - 8 it lllllllC�flll�llll�lf ��I011I�IIIIIIICIlll�1111��1(I2 -Sk"GROZENTRAIMIKERRY-ViLL5 ,. ,. -J mPROJ.5QT MAN ER,,CHERRYVLLF Phond- . � At& L C-USTOWR UUOU Ne DVAM # OF SAMPL151J), (LOCATION tYPE CONTAINERS GATE 'T199 PRkgER 4*4 o3 -.a SPECIAL [N$TRUGTIONS,, For. Af C monitoring porpo.set,. PO& METOOD 8.0006) SAMPLE ANAL YtigmeEm gsTr $L, 912, NA4.N N$�(f ic 7 ic N. ,0 d OR '0 mo C xoeu Kjejddh1:Nft.rogen,, Ph.trsohottis';;i ndiPotas-didm �f - _ 7 `SL2-'13asIcTAluminum .K4�f6 -d incZ- est SLI pf us-;��uffur- Qa[61 - m 'I- 9. Magnaslurn� Sodiu m; ran__nP.s zbpperan A. L an!iy--4 8�. a 4MANAGER GO py * i e t J iRn Product Code Product Name Sample Date Report Range Ratio 2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 9/4/2013 1011/2013-1113012013 0.5438 Na mg/I = (Na mg/kg x % Solids) _ 100 = (1620 x 2.3100) + 100 = 37.422 Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (10400 x 2.3100) + 100 = 240.24 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (3060 x 2.3100) + 100 = 70.686 Na meq = Na mg/I _ Molec.Wgt.Na = 37.422 23 = 1.62704 Ca meq = Ca mg/I + Molec.Wgt.Ca = 240.24 _ 20 = 12.012 Mg meq = Mg mg/I = Molec.Wgt.Mg = 70.686 _ 12 = 5.8905 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.62704 _ SgrRoot[0.5(12.012+5.8905)] = 0.543823 Printed: 1/22/2014 Page 1 13:04 r� FACILITY NAME: CHERRYVILLE, NC OWNER: CURTIS PRUITT SITE #: NC GA 00100 FIELD# : GA 00100 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: MADISON PERMIT #: W00000430 ANNUAL DRY TONS APPLIED: 13.14 OPERATOR: CURTIS PRUITT CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 13.50 ACRES PERMITTED: 13.50. Page: 1 Lune Applied **" Date Hs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WTI (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (pptn) Crop MONTH Total Per Acre Solids 11/4/13 93,000.00 (G) 6888.889 2.31 0.664 CHL DRY 0-<1/2" SUR 0.5 0.30 27,300. p 15,200.00 p 2.00 p 11232 I FESCUE 11/5/13 43,400.00 (G) 3214.815 1 2.31 0.310 CHL DRY 0-<1/2" SUR 0.5 0.30 27,300. p 15,200.00 p 2.00 p 11232 FESCUE Nov-13 1 136,400.00 (G) 10,103.704 Total Gallons/Ac: 10,103.70 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: 22 Annual lbs/acre 0.008 0.008 0.148 1.802 0.076 0.003 0.029 0.152 0.010 2.686 33.87 Cumulative lbs/acre 0.029 0.028 0.664 8.764 0.689 0.009 0.408 0.446 0.034 8.858 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop ,. 167 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 L _ 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID R (SIGN URE O LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the. possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required %= percent p = ppm or mg/lcg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2014 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: CHERRYVILLE, NC PREDOMINANT SOIL SERIES: CECIL OWNER: KEITH BEAM PERMIT #: W00000430 ANNUAL DRY TONS APPLIED: 53.15 SITE #: NC LT 00124 FIELD# : LT 00124 0001 OPERATOR: KEITH BEAM CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 31.80 ACRES PERMITTED: 31.80 Page: 1 Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm ) Crop p MONTH Total Per Acre Solids 10/28/13 136,400.00 (G) 4289.308 2.31 0.413 CHL DRY 0-<1/2" SUR 0.5 0.30 27,300. p 15,200.00 p 2.00 p 11232 I FESCUE 10/29/13 136,400.00 (G) 4289.308 2.31 0.413 CHL DRY 0-<1/2" SUR 0.5 0.30 27,300. p 15,200.00, p 2.00 p 11232 I FESCUE 10/30/13 142,600.00 (G) 4484.277 2.31 0.432 CHL DRY 0-<1/2" SUR 0.5 0.30 27,300. p 15,200.00 p 2.00 p 11232 I FESCUE 10/31/13 136,400.00 (G) 4289.308 2.31 0.413 CHL DRY 0-<I/2" SUR 0.5 0.30 27,300.p 15,200.00 p 2.00 p 11232 FESCUE Oct-13 551,800.00 (G) 17,352.201 Total Gallons/Ac: 17,352.20 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 38 0.013 0.013 0.254 3.096 0.130 0.005 0.050 0.261 0.017 4.613 58.17 Cumulative Ibs/acre 0.080 0.053 1.507 15.290 0.793 0.021 0.339 1.353 0.080 22.154 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 209 ' FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 i 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID x 3 e/ `f (SIGNATYRE OF A APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR= Not Reported or Not Required %= percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2014 Cherryville WWTP, NC TCLP TCLP is only required once per permit cycle. Sampling was done on 7/25/2011 and the results were submitted in the 2011 Annual Report. a. -- :AMgT-_IAL.P THQGXE".N X C19—R ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Chenyville WQ Permit Number: WQ0000430 WWTP Name: City of Cherryville WWTP NPDES Number: NCO044440 Monitoring Period: From Jan. 1, 2013 To Dec. 31, 2013 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion .,1+or.,.,+-- „orf r nfl 1PIn cc A nr P1acc Rl rmmnlafa fhn fnllnwina mnnitnrina dntn- Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10to the 6 th MPN 14,013 15,144 17,613 MPN/g 0 Annual grab SM 9221E Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0ption/Alt. 1 Option/Mt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) X (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement In 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Larry Wright, Plant ORC & Plal Preparer Nape and Title (type or print) of Preparer* dent 2-11-0 Date Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) PROMPT -ACCURATE. RELIABLE L,A,BORkrOR-1ESy JWC: WWW PARLABS.COM Attn: ERIC TFIOMPSON SYNAGRO 284 BOGER ROAD MOCKSVILLE, NC 27028- REPORT OF ANALYSES PROJECT NAME: SEP 13 DATE: 10/07/13 SAMPLE NUMBER- 110884 SAMPLE ID- CHERRYVILLE DATE SAMPLED- 09/04/13 DATE RECEIVED- 09/04/13 SAMPLER- ET TIME RECEIVED- 1343 DELIVERED BY- ET Page 1 of 1 SAMPLE MATRIX- WW TIME SAMPLED- 1215 RECEIVED BY- DJ TYPE SAMPLE- Grab ANALYSIS ANALYSISMETHOD DATE TIME BY RESULT UNITS 30 DAY BENCH SCALE TEST VAR 09/04/13 1550 RE ATTACHED FECAL COLIFORM (GEOM. MEAN) SM 9221 E 09/06/13 1145 RE 15,144 MPN/g LABORATORY DIRECTOR � P.O. Box 411483 o Charlotte, NC 28241-1483 Phone: (704) 588-8333 • Fax: (704) 588-8335 PROMPT•ACOURATE• RELIABLE g.-A�IB0P.A.'rOP..Y.ES,, YINTc 2217 Graham Park Drive PO Box 411483 Charlotte, NC 28241-1483 NC Cert # 20; SC Cert # 99003001 CLIENTVAME: SAMPLE ID: SAMPLE `DATE_: ANALYSIS: ANALYSIS :METH:OD, FTIX- • • • EL • • MMKVMUM—� 110884 u 1 7o 0 303 o a 2.07% • 14,623.64 2 287 1.98% 14,471.36 3 274 1.92% 14,256.39 4 356 2.02% 17,612.94 5 320 1.95% 16,419.01 6 281 1.88% 14,944.23 7 276 1.97% 14'012.81 fecal .Coliform; :Geometric Mean=_ _ :M:7 • PROMPT•AC CLIRATE•RELIAB LE LABOREITORIES� INC WWW. PARLA65. COM 30 ®ay Bench Scale Extended Aeration Test Percent Volatile Solids Reduction �$A�MPLE •ID 1 I O CHERRYVILLE rS'AkOLE # Sl'ART' DATES TS 0.4378 V I lY. 0.2980 TS% 1.98% 1.98% VS 0.2759 0.1820 VS% 63.02% 61.07% ylN 0-006707 _ OUT 0.00588233 FSVR (Mass Balance) 12.30% FSVR (Van Kleeck) 7 93% FSVR (Mass Balance) <159/o YES FSVR (Van Kleeck) <15% YES P.O. Box 411483 o Charlotte, NC 28241-1483 Phone: (704) 588-8333 9 Fax: (704) 588-5335 ��� .� CHAIN OF CUSTODY LABORATORIES, INC. eriLa U VI Phone (704) 588-8333 Fax (704) 588-8335 www.parlabs.com Shipping: Mailing: 2217 Graham Park Drive PO Box 411483 Charlotte, NC 28273 Charlotte, NC 28241-1483 It is essential that all information recorded on this Chain of Custody document for acceptance by PAR Laboratories, Inc. and the North Carolina Department of Environmental and Natural Resources. Company Name (billing) / SYNAGRO G Address 284 BOGER ROAD City, State & zip code MOCKSVILLE NC 27028 Point of Contact & Telephone Number ViLI COMMENTSISPECIAL INSTRUCTIONS Sample taken by: �9' [ (Y4,, , S4 IS THIS FOR STATE or EPA REPORTING? YES i-,-- NO *Sample type: DW WW ✓ GWMW HW Soil Other Sample Temp upon receipt: 3 °C ** Preserved: Yes No ✓ Teflon Liner/ Zero Headspace: Yes No NIA ✓ went Sample I.D. (Sample Location I Number) Comp Grab . Prese.rv. Set Up DaWrime CollectionTRe Date/Timeted s E� L/ S .. Relinauished by v ( r F (+orr;-- 'L 3� Dti - ;1 ' (d 7 • ua[e! I Ime Relinquished by: Pj/�DMelfime Received by: Date/Time C=Composite G=Grab DW=Drinking Water WW=Wastewater GWMW=Groundwater Monitoring Well HW=Hazardous Waste "See Other Side I Agricultural Lime Application Log Year: 2013 Project: City of Cherryville IFField (state -county -site -field code) Soil pH Lime Requirement Tons/Acre (from soil analysis) Applied Date Applied NC- GA-100-2 5.4 1.0 T/ac. ** ** NC-LT-124-1 6.9 N/A . N/A ...... - ...: N/A ,.. . ** = Lime will be applied as weather permits. Page 1 of 1 Report Number: 14-017-0541 Account Number:46442 Send To: SYNAGRO CENTRAL/CHERRYVILLEaleastern.cam Mary Brewer 284 BOGER RD MOCKSVILLE NC 27028 Date Received: 01/17/2014 Date Of Analysis: 01/20/2014 A&L Lastern Laboratories 7621 Whitepine.Road Richmond, Virginia 23237 (804) 743-9401 Fax (894) 271-6446 Grower: CURTIS PRUITT CHERRYVILLE ANNUAL SOIL ANALYSIS REPORT Date Of Report: 01/20/2014 Submitted By: ERIC THOMPSON Farm ID: GA-100 Analytical Method(s): Mehlich 3 Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab ENR Mehlich 3 Reserve K Mg Ca Na Soil Buffer - H Field ID Number o /o Rate Ibs/A ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate P H Index meg1100g meq/100g GA-100-2 18605 5.2 H 145 96 H 97 M 137 H 645 L 16 VL 5.4 6.74 1.9 6.5 NC=80 NC=50 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Chloride I Aluminum Sample ID K Mg Ca Na H NON S Zn Mn Fe Cu B SS Cl Al Field ID % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate ppm Rate ppm GA-100-2 v5+ 12 L 10.1 VH 19 M 324 VH 3.9 VH 0.6 M 0.09 VL 3.8 17.6 49.6 1.1 28.5 NC=25 NC=252.5 NC=119 NC=195.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. by: ?X'" me G� H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble Analysis prepared by: A&L Eastern Laboratories, Inc. C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Pauric McGroary Page 1 of 1 - Report Number: 14-017-0540 Account Number: 46442 Send To: SYNAGRO CENTRAL/CHERRYVILLEaleastern.com Mary Brewer 284 BOGER RD MOCKSVILLE NC 27028 Date Received: 01/17/2014 Date Of Analysis: 01/20/2014 A&L Eastern Laboratories 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.WS Grower: KEITH BEAM CHERRYVILLE ANNUAL SOIL ANALYSIS REPORT Date Of Report: 01/20/2014 Submitted By: ERIC THOMPSON Farm ID: LT-124 Analytical Method(s): Mehlich 3 Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab Field ID Number ENR % Rate Mehlich 3 Reserve K Mg Ca Na Soil Buffer H Ibs/A ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g LT-124-1 299 VH 232 VH 467 VH 1454 M 22 VL 18604 7.1 VH 150 6.9 0.2 12.0 NC=249 NC=119 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble salts Chloride Aluminum` Sample ID l Fed ID K Mg , Ca Na H NON S Zn Mn Fe Cu B SS CI Al j % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate ppm Rate ppm {� LT-124-1 r 13 L 19.4 VH 31 H 214 VH 7.3 VH 1.1 M 0.16 VL; 5.0 32.4 60.6 0.8 1.4 NC = 27 NC = 485.0 NC = 194 NC = 365.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble Analysis prepared by: A&L Eastern Laboratories, Inc. C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. r� by: I Glt�ic me G� ; Pauric McGroary I A.-THAA�=�LE NCDENR North Carolina Department of Environment and Natural Resources Pat McCrory Donald van der Vaart Governor Secretary March 19, 2015 Mr. Larry Wright, WWTP Superintendent / ORC Town of Cherryville 116 South Main Street. Cherryville, North Carolina 28021 Subject: Acknowledgement of Receipt of the 2014 Annual Report Town of Cherryville - Permit No.: WQ0000430 Land Application of Residuals Gaston County Dear Mr. Wright: The Mooresville Regional Office received and reviewed the 2014 Annual Report for the above permit. The data submitted appears to be in accordance with permit requirements. This permit is currently in the renewal process. I may be reached by phone at (704) 663-1699 or email (maria. schutte(Qncdenr.gov) should you have questions about this permit or the renewal. Sincerely, Maria Schutte, Environmental Specialist Mooresville Regional Office Water Quality Regional Operations Section Division of Water Resources, NCDENR CC: Marshall Puryear, SYNAGRO (Email) Ed Hardee, LAU Compliance, CO -Raleigh (Email) Mooresville Regional Office 610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 Phone: 704-663-16991 Fax: 704-663-60401Customer Service 1-877-623-6748 Internet: www.ncdenr.gov An Equal Opportunity 1 Affirmative Action Employer — Made in part by recycled paper 00� CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2014 ANNUAL REPORT DiviSiON ' QUALITY FEB 16 H115 `W,,t . _ . ,...'J u1,J , G �i 1 City of Cherryville, NC Residuals Land Application Program 2014 Annual Report TABLE OF CONTENTS 1. Certification Form, Annual Operations Summary, Facility and Land Applier Contact Information 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. Annual Land Application Field Summary Form 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analysis ANNUAL LAND APPLICATION .CERTIFICATION FORM WQ Permit #: W00000430 County Gaston Year 2014 - Facility Name (as shown on permit) City of Cherrvville W WTP NPDES No. NCO044440 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO, If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 9 Total number of fields utilized for land application during the year: 1 Total amount of dry tons applied during the year for all application sites: 187.62 Total number of acres utilized for land application during the year: 31.8 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2014 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4: Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities).. 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Larry Wright. Plant ORC & PIant Supervisor Permittee Name and Title (type or print) Signature ofPreparer* Date (if different from Permittee) lei 201D r f. Date Signature of Snd Applier Date (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2014 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION CHERRYVILLE, NC CHERRYVILLE, NC LIQUID DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS September 2014 762,600.00 G 187.62 D 170.17 YEARLY TOTAL 762,600.00 G 187.62 D 170.17 1 /26/2015 2014 ANNUAL REPORT PROJECT: City of Cherryville, NC FACILITY: City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 NPDES PERMIT NUMBER: NCO044440 RESPONSIBLE OFFICIAL: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 FACILITY OPERATOR: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WWTP. 116 South Main Street Cherryville, NC 28021 (704) 435-1739 LAND APPLIER AND PREPARER OF LAND APPLICATION ANNUAL REPORT: Synagro Central, LLC Contact: Marshall Puryear (336) 998-7150 ext. 17 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or VVQ# (residual only) WVVTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 08/11/14 Date Composited Percent Solids 5.90 PARAMETERS (mg/kg dry weight) Laboratory A&L Eastern Laboratories Inc. Arsenic 5 Cadmium 4 Mercury 0.8 Chromium 216 Copper 695 Lead 43 Molybdenum 19 Nickel 128 Selenium <5 Zinc 1500 Total Phosphorus 31500 TKN 31400 Ammonia -Nitrogen 8 640 Nitrate and Nitrite 40.7 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." x Z Date --2 - 2( DENR FORM RSSF (5/2003) Printed: Monday - January 26, 2015 at 13:42:16 for: 2008 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 08/11/14 Date Composited Percent Solids 5. 90 PARAMETERS (mg/kg dry weight) Aluminum 15400 Calcium 11200 Magnesium 3370 pH 7.58 Potassium 2230 Sodium 1080 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Date z ^ 2 - 201 (SIGNKU,RE OF -PREP NR - Datid Not Reported or Data Not Required DENR FORM RSSF-B (7/2002) Printed: Monday - January 26, 2015 at 13:42:39 for: 2008 01 Page: 1 of z Report Number: 14-225-0201 Account Number: 46442 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAUCHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57004 Sample Id: CHERRYVILLE AFL Eastern Laboratories, Inc. TJIL� 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-0401 Fax (804) 271-.6446 wwwaleastern.com Project: CHERRYVILLE NC CERT#257 REPORT OF ANALYSIS Date Sampled: 8/11/2014 11:30:00 Date Received: 08/13/2014 00:00 Date Reported: 08/19/2014 Total Solids ` 5.90 59000 100.0 JM 08/13/2014 13:50 SM-2540G Moisture * 94.10 100.0 JM 08/13/2014 13:50 SM-2540G . Total Kjeldahl Nitrogen 3.14 31400 10.0 JM 08/14/2014 07:50 SM-4500-NH3C-TKN Total Phosphorus 3.15 31500 100 KM 08/14/2014 14:37 SW 6010C Total Potassium 0.22 2230 100 KM 08/14/2014 14:37 SW 6010C Total Sulfur 0.91 9110 100 KM 08/14/2014 14:37 SW 6010C Total Calcium 1.12 11200 100 KM 08/14/2014 14:37 SW 6010C Total Magnesium 0.34 3370 100 KM 08/14/2014 14:37 SW 6010C Total Sodium 0.11 1080 100 KM 08/14/2014 14:37 SW 6010C Total Iron 57300 100 KM 08/14/2014 14:37 SW 6010C Total Aluminum 15400 100 KM 08/14/2014 14:37 SW 6010C Total Manganese 970 5 KM 08/14/2014 14:37 SW 6010C Total Copper 695 5 KM 08/14/2014 14:37 SW 6010C Total Zinc 1500 10 KM 08/14/2014 14:37 SW 6010C Ammonia Nitrogen 0.86 8640 10.0 JM 08/15/2014 08:55 SM-4500-NH3C Organic N 2.28 22760 10.0 08/14/2014 07:50 CALCULATION Nitrate+Nitrite-N 40.7 2.00 JM 08/14/2014 07:50 SM-450ONO3F Total Cadmium 4.0 2.0 KM 08/14/2014 14:37 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-225-0201 Account Number: 46442 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57004 Sample Id : CHERRYVILLE A&L Eastern Laboratories, Inc. UL 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.6446 www aleastern,coin Project: CHERRYVILLE NC CERT#257 REPORT OF ANALYSIS Date Sampled: 8/11/2014 11:30:00 Date Received: 08/13/2014 00:00 Date Reported: 08/19/2014 Total Chromium 216 5 KM 08/14/2014 14:37 SW 6010C Total Nickel 128 5 KM 08/14/2014 14:37 SW 6010C Total Lead 43 5 KM 08/14/2014 14:37 SW 6010C Total Arsenic 5.0 3.0 KM 08/14/2014 14:37 SW 6010C Total Mercury 0.8 0.4 KM 08/15/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 08/14/2014 14:37 SW 6010C pH (Standard Units) * 7.58 2.00 JM 08/14/2014 08:05 SW-9045D Total Molybdenum 19 5 KM 08/14/2014 14:37 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. " QUALIFIER: THE LCS WAS OUT OF LIMITS FOR "Al", "K", "Na", AND "S". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al", "P", AND "S". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt SANIPI-ING LOG # 7 76121 " Pichm CUST0MF-9,-- SYNAORO SOUTHEAST 8041.0 PROJECT MANAGER.' - Phone: 14-225-0201 46442 084041114i RRYVILLE 1218:25 -:HEPRYV1LLE/NC C81RT4.257" 4 OF--Oustoviv- RE);' & ANALYSIS ,RECORD - 3'mpflng' procedures .)n of thesff.samplas. A-& L CUSTOMER, SAMPLING SAMPLE 'OF SAMPLENG METHOD, METROP LAB # SAMPLE1.D-. LOCATION TYPE; - -CONTAINERS DATE TIME 'PRESERVED SHIPPED, 1pIin'q"wished 1bySjan3pI' -` Anclu fshed'.by: Relinquished byj, 'SPECIAL INSTRUCTIONS, For monitoring purposes. Time, Recieved by; D&le, - Ti m e Date, Time Recieved by: 'Recleved by. Pok REMARKS; ANALY818�'REQUEST* .SAMPLE 1-0- 131-1- bL2. -1 )rganic iN Ni: Pig As 14g -Se Ca,cequo VdIatil 01 Mu CI fqq2-N -Pol,- 7 blow- -POE-- TO'- too too -polp- -P -or- 7 Pow— SL11: Tbtal.'SoIlds:(Moisture)-, T-6W 11bldahl Nitrogen, Phosphorus, •and! Potassium SL2:"Basic Test,SL11 plus, Sulfur,", Cgl'cium, XagnesiLfnT, Sodium -'Ircin, Alurfiinurn,- Manqan.qse, Copper;and Zinc: White -A'& L Canary— MANAGER' COPY Sodium Absorption Ratio Calculation (SAID) Product Code Product Name Sample Date Report Range Ratio 2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 8111/2014 9/1/2014-10/31/2014 0.5563 Na mg/I = (Na mg/kg x % Solids) + 100 = (1080 x 5.9000) + 100 = 63.72 Ca mg/I =.(Ca mg/kg x % Solids) _ 100 = (11200 x 5.9000) _ 100 = 660.8 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (3370 x 5.9000) _ 100 = 198.83 Na meq = Na mg/I + Molec.Wgt.Na = 63.72 - 23 = 2.77043 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 660.8 _ 20 = 33.04 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 198.83 _ 12 = 16.5692 SAR = Na meq _ SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.77043 _ SgrRoot[0.5(33.04+16.5692)] = 0.556265 Printed: 1/26/2015 Page 1 13:54 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: CHERRYVILLE, NC PREDOMINANT SOIL SERIES: CECIL OWNER: KEITH BEAM PERMIT #: W00000430 ANNUAL DRY TONS APPLIED: 187.62 SITE #: NC LT 00124 FIELD# : LT 00124 0001 OPERATOR: KEITH BEAM CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 31.80 ACRES PERMITTED: 31.80 Page Lune Applied °** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TI4V Anunonia Nitrogen Nitrate and PAN (ppnr) Crop MONTH Total Per Acre Solids 9/22/14 148,800.00 (G) 4679.245 5.90 1.151 CHL DRY 0-<I/2" SUR 0.5 0.30 31,400. p 8,640.00 p 40.70 p F 11 99 I FESCUE 9/23/14 173,600.00 (G) 5459.119 5.90 1.343 CHL DRY 0-<I/2" SUR 0.5 0.30 31,400. p 8,640.00 p 40.70 p 11189 I FESCUE 9/24/14 130,200.00 (G) 4094.340 5.90 1.007 CHL DRY 0-<1/2" SUR 0.5 0.30 31,400. p 8,640.00 p 40.70 p 11189 I FESCUE 9/25/14 223,200.00 . (G) 7018.868 5.90 1.727 CHL MOIST 0-<1/2" SUR 0.5 0.30 31,400. p 8,640.00 p 40.70 p 11189 I FESCUE 9/26/14 86,800.00 (G) 2729.560 5.90 0.672 CHL DRY 0-<1/2" SUR 0.5 0.30 31,400. p 8,640.00 p 40.70 p 11189 FESCUE Sep-14 1 762,600.00 (G) 1 23,981.132 Total Gallons/Ac: 23,981.13 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 132 0.059 0.047 2.549 8.201 0.507 0.009 0.224 1.510 0.059 17.700 371.70 Cumulative lbs/acre 0.139 0.100 4.056 23.491 1.300 0.030 0.563 2.863 0.139 39.854 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop ` k i - a ,•, �' ;� I p 209 ' FD Cumulative Pollutant LoadingRate Limit lbs/acre ( ) 36.G 34.8 � � 1339.0 267.9 15.0 k^ 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID X r I - 1-1)/7 6/ ll! r r (SIGNATgeOF L APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/lcg * * Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 CherMille WWTP, NC TCLP TCLP is only required once per permit cycle. Sampling was done on 7/25/2011 and the results were submitted in the 2011 Annual Report. ANNUAL PATHOVEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Chenyville WQ Permit Number: WQ0000430 WWTP Name: City of Chenyville WWTP NPDES Number: NCO044440 Monitoring Period: From Jan 1, 2014 To Dec 31, 2014 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion Tf annNeahle fn alfe nfivP nPrfnrmPdl WIncc A nr f incc R) rmmnlefe the fnllnwina mnnitnrina dntn- Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10to the 6 1h MPN 10,736 12,053 12,941 MPN/g 0 Annual grab SM 9221E Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt.2 Option/Alt. 3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) X (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Larry Wright, PlanttOR, C & Plant Superintendent Prep rer Name and tle (ty ple or print) 6Ignature o reparer* Date Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) R AIft PROMPT' ACCURATE- RELIAOLE LAR BOATORIES, INC \V1Y1Y.1'ARI.ABS.00\1 REPORT OF ANALYSES Attn: ERIC THOMPSON SYNAGRO 284 EOGER ROAD NOCKSVILLE, NC 27028- PROJECT NAME: AUG 14 DATE: 09/15/14 SAMPLE, NUMBER- 115303 SAMPLE ID- CHERRYVILLE SAMPLE MATRIX- Wtd DATE SAMPLED- 08/11/14- TIME SAMPLED- 1130 DATE RECEIVED-'OS/11/'14 SAMPLER- ET RECEIVED BY- DJ TIME RECEIVED- 1308 DELIVERED BY- ET TYPE SAMPLE- Grab Page 1 of 2 ANALYSIS ANALYSIS METHOD DATE TIME BY RESULT UNITS FECAL COLI'FORM (GEOM. MEAN) SM 9221 E 08/11/14 1425 RE 12,053 MPN/g 9• LABORATORY DIRECTOR P.O. Box 411483 • Charlotte, NC 28241-1483 Phone: (704) 588-5333 • Fax: (704) 585-8335 AM PRO MPT•ACCURATE• RELYAE]LE :LA.SORIL-rG LalES., INC 2217 Graham Park Drive PO Box 411483 Charlotte, NC 28241-1483 NC Cert # 20; SC Cert # 99003001 ®R 4` ® ,`+ �.0 ? SYNAGRO CHERRYVILLE 08/11/14 FECAL COLIFORM, GEOMETRIC MEAN SM 9221 E 115303 1 830 6.41 % 12,941.21 2 797 6.48% 12,302.62 3 783 6.39% 12,257.26 4 772 6.42% 12,019.93 5 687 6.40% 10,736.37 6 819 6.42% 12,749.71 7 738 6.41 % 11,507.01 c 12,053 1101% tmwZ A R PRO MPT- A CCU RATE -RE LIAB LEE LABORATORIES, INC WNVNV. PAW-% BSXOAl REPORT OF ANALYSES Attn: ERIC THOMPSON SYNAGRO 284 BOGER ROAD MOCXSVILLE, NC 27028- PROJECT NAME: AUG 14 DATE: 09/15/14 SAMPLE NUMBER- 115304 SAMPLE ID- CHERRYVILLE SAMPLE MATRIX- WW DATE SAMPLED- 08/11/14 TIME SAMPLED- 1145 DATE RECEIVED- 08/11/14 SAMPLER- ET RECEIVED BY- DJ TIME RECEIVED- 1308 DELIVERED BY- ET TYPE SAMPLE- Grab Page 2 of 2 ANALYSIS ANALYSES METHOD DATE TIME BY -RESULT UNITS 30 DAY BENCH SCALE TEST VAR 08/15/14 1018 RE ATTACHED LABORATORY DIRECTOR P.O. Box 411483 - Charlotte, NC 28241-1483 Phone: (704) 588-8333 - F,,,x: (704) 588-3335 PROM PT•ACCIJRATE• RELIl16 LE x.�iB�0I2ATOF�IES� INC WWW.PARLABS.COM 30 ®ay Bench Scale Extended Aeration Test Percent !Volatile Solids Reduction ,� i Iit h, 1.1�' .. � � 4 SYNAGRO CHERRYVILLE 115304 03/15/14 09/12/14 Start: End: TS 0.3778 0.3732 TS% 1.84% 1.85% VS 0.1524 0.1435 VS% 40.34% 38.45% 71 N 0.003444 yOUT 0.00332688 FSVR (Mass Balance) 3.41% FSVR (Van Kleeck) 7.60% FSVR (Mass Balance) <15% YES FSVR (Van Kleeck) <15% YES Sample received 08111/14. Starting solids was 6.41%. RO.11ox 4l 1483 a Charlotte, h:C 28241.1•C83 Phone: (704) 588.8333 0 Fax: (704) 585-8335 .R 'A PROM PT•ACOU RATE• RELIABLE 3LABOPLATOnI]ESy INC CHAIN OF CUSTODY Phone (704) 588-8333 Fax (704) 588-8335 Shipping: Mailing: 2217 Graham Park Drive PO Box 411483 Charlotte, NC 28273 Charlotte, NC 28241-1483 t is essential that all informatiori be recorded on this Chain of Custody document for acceptance by PAR Laboratories, Inc. and the North Carolina Department of Environmental and Natural Resources. Company Name (billing) Comments/ Special Instructions Address 2-%y �v City, state t zip code PointofContact ti Telephone Number Sample Taken By: SIGNATURE PRINTED NAME ARE SAMPLES FOR STATE or EPA REPORTING? YES ✓ NO -Sample I ype: pW WW t� GWMW HW Soil Other Sample Temp at time of sampling: _0 C Sample Temp upon receipt: U o C *Field Preserved: Yes No LTeflon Liner/Zero Headspace: Yes No n/a Residual Chlorine checked at time of samnlinn IVINI- r1/ nPrhtnrinn+inn Aloroc nm# IV/An- Client Sample I.D_ (Sample Location / Number) Comp Grab Preserv. Set Up Date/Time Collection Date/Time nalyses Requested Vrl.(40 I ✓ V vI I L ( I G _e tV, LK-1— Relinouished by -�� ----_ jy t�Q�rllf'i i J D •• 7• i �" ,/r1 rs�!{-7 /YL/�t4rii/ LJd ICI IHU telinquis)redby: / Date/Time Received by: % /J/i Date/Time C=Composite G=Grab DW=Drinking Water WW=Wastewater GWMW=Groundwater Monitoring Well HW=Hazardous Waste **See er e Agricultural Lime Application Log Year: 2014 Project: City of Cherryville Field Soil pH Lime Requirement Tons/Acre Date Applied (state -county -site -field code) (from soil analysis) Applied NC-LT-124-1 6.6 i r _ _.,_ rN/A; - - --- N/N �,_ .: ----`;N/A ,.:4; Page 1 of 1 - '.. Report Number: 15-020-0569 y I( @�� Account Number: 46442 www.aleastern.cottt Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE NC 27028 Date Received: 01120/2015 Date OfAnalvsis: 01/21/2015 A&L Eastern Laboratories 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-,9401 Fax (004) 271.6446 Grower: K BEAM CHERRYVILLE ANNUAL SOIL ANALYSIS REPORT Date Of Report: 01/23/2015 Submitted By: ERIC THOMPSON Farm ID: LT-124 Analytical Method(s): Mehlich 3 Organic Matter Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab ENR Mehlich 3 Reserve K Mg Ca Na Soil Buffer H Field ID Number % Rate lbs/A ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate P H _, Index meq/100g meq/100g 1 07472 5.8 H 150 226 VH 119 M 400 VH 1307 M 15 VL �6 0.6 �1 %10.9 NC = 188 NC = 61 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Chloride Aluminum Sample ID K Mg Ca Na H NON S Zn Mn Fe Cu B SS Cl Al Field ID % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate ppm Rate ppm 1 14 L 13.2 VH 27 H 195 VH 6.2 VH 0.8 M 0.07 VL 2.8 30.6 60.0 0.6 5.9 NC=29 NC=330.0 NC=169 NC=310.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. by: �Aylic me G� H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble Analysis prepared by: A&L Eastern Laboratories, Inc. C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Pauric McGroary rt�c NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Pat McCrory Thomas A. Reeder John Skvarla Governor Acting Director Secretary July 2, 2013 Mr. Larry Wright, WWTP Superintendent / ORC Town of Cherryville 116 South. Main Street Cherryville, North Carolina 28021 Subject: Acknowledgement of Receipt of the 2012 Annual Report Town of Cherryville - Permit No.: WQ0000430 Land Application of Residuals Gaston County Dear Mr. Wright: The Mooresville Regional Office (MRO) received and reviewed the 2012 Annual Report (AR) for the above permit. The data submitted appears to be in accordance with the requirements of your permit. The MRO plans to conduct an on -site facility inspection within the calendar year; however, if you have any immediate concerns or questions, please contact me at (704) 663-1699. Sincerely, 11 74""'o �LA Maria Schulte Environmental Specialist cc: Chonticha McDaniel, Residuals Management, CO-LAU (email) Marshall Puryear, Synagro (email) Division of Water Quality / Aquifer Protection Section / Mooresville Regional Office One 610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 NorthCarollna Phone: 704-663-16991 Fax: 704-663.60401 Customer Service:1-877.623-6748 Internet: www.ncwaterquality.org Naturally urally An Fmial nnnnrf inity 1 Affirmafiva Antinn Fmnlnver CITY OF CHERRYVILLE, MC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2012 ANNUAL REPORT fla- (34 FED 2.5 2013 City of Cherrywille, NC Residuals Land Application Program 2012 Annual Report TABLE OF CONTENTS �. Certification Form, Annual Operations Summary, Facility and Land Applier Contact Information 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. Annual Land Application Field Summary Forges 4. TCLP Analysis 6. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00000430 County Gaston Year 2012 Facility Name (as shown on permit) City of Cherryville WWTP NPDES No. NCO044440 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part Band proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summar Total number of application fields in the permit: 9 Total number of fields utilized for land application during the year: 2 Total amount of dry tons applied during the year for all application sites: 58.36 Total number of acres utilized for land application during the year: 44.4 Part B — Annual Compliance Statement: Facility was compliant during calendar. year 2012 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water QualityX YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis -(if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T . 1105(a) or the Pollutant Loading Rates in 15A NCAC 02T . 1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under,penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am. aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations:" Larry Wrieht. Plant OR9'&Tlant Supervisor Perm' ee Name and Tale (ty a or print) of��--Frff e 2-i3-13 - ignature er* Date Signature of Land Applier Date (if different"froffPerm' 2CFR (if different from Permittee and Preparer) *Preparer is defined i art503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2012 ANNUAL OPERATaOHS SUMMARY ® LAND APPLICATION rHERRYVILLE, NC —HERRYVILLE, NC LIQUID MONTHNEAR November 2012 YEARLY TOTAL AMOUNT UNIT 657,200.00 G 657,200.00 G DRY TONS UNIT 58.36 D 58.36 D DRY METRIC 52.94 52.94 1 /22/2013 PROJECT: FACILITY: NPDES PERMIT NUMBER: 2012 ANNUAL REPORT City of Cherryville, NC City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 NCO044440 RESPONSIBLE OFFICIAL: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739 FACILITY OPERATOR: Larry Wright, Plant ORC & Plant Supervisor City of Cherryville WWTP 116 South Main Street Cherryville, NC 28021 (704) 435-1739, LAND APPLIER AND PREPARER OF LAND APPLICATION ANNUAL REPORT: Synagro Central, LLC Contact: Marshall Puryear (336) 998-7150 ext. 17 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 10/02/12 Date Composited Percent Solids 2.13 PARAMETERS (mg/kg dry weight) Arsenic 4 Cadmium 1 Mercury 0.8 Chromium 64 Copper 381 Lead 30 Molybdenum 7 Nickel 78 Selenium 2 Zinc 827 Total Phosphorus 23500 TKN 65300 Ammonia -Nitrogen 18300 Nitrate and Nitrite <2 Laboratory A&L EASTERN LABORATORIES, INC. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties foAubmitting false information, in he possibility of fines and imprisonment for knowing violations." X T,URE OF PREPARER) Date 2-J 1 3^ ) 3 DENR FORM RSSF (512003) Printed: Tuesday - January 22, 2013 at 08:42:34 for: 2008 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit dumber: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 10/02/12 Date Composited Percent Solids 2.13 PARAMETERS (mg/kg dry weight) Aluminum 18300 Calcium 14 600 Magnesium 5010 pH 7.42 Potassium 4610 Sodium 2730 Laboratory A&L EASTERN LABORATORIES, INC. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties fo,�Obmitting false information, jae nng t e ossibility of fines and imprisonment for knowing violations." X RE OF PREPARER) NR - Data Not Reported or Data Not Requ Date 2 _ ) 3 ` l 3 DENR FORM RSSF-B (7/2002) Printed: Tuesday - January 22, 2013 at 08:42:59 for: 2008 01 Page: 1 of 2 Report Number: 12-277-0203 Account Number: 46442 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 89681 Sample Id : CHERRYVILLE ¢y A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 wwwaleastern.com Project: CHERRYVILLE NC CERT # 257 REPORT OF ANALYSIS Date Sampled: 10/2/2012 11:00:00 Date Received: 10/03/2012 00:00 Date Reported: 10/05/2012 Total Solids " 2.13 21300 100.0 JM 10/03/2012 14:30 SM-2540G Moisture * 97.87 100.0 JM 10/03/2012 14:30 SM-2540G Total Kjeldahl Nitrogen 6.53 65300 10.0 JM 10/04/2012 08:19 SM-4500-NH3C-TKN Total Phosphorus 2.35 23500 100 BW 10/04/2012 09:00 SW 6010C Total Potassium 0.46 4610 100 BW 10/04/2012 09:00 SW 6010C Total Sulfur. 0.94 9380 100 BW 10/04/2012 09:00 SW 6010C Total Calcium 1.46 14600 100 BW 10/04/2012 09:00 SW 6010C Total Magnesium 0.50 5010 100 BW 10/04/2012 09:00 SW 6010C Total Sodium 0.27 2730 100 BW 10/04/2012 09:00 SW 6010C Total Iron 23400 1 BW 10/04/2012 09:00 SW 6010C Total Aluminum 18300 10 BW 10/04/2012 09:00 SW 6010C Total Manganese 350 1 BW 10/04/2012 09:00 SW 6010C Total Copper 381 1 BW 10/04/2012 09:00 SW 6010C Total Zinc 827 1 BW 10/04/2012 09:00 SW 6010C Ammonia Nitrogen 1.83 18300 10.0 JM 10/04/2012 08:19 SM-4500-NH3C Organic N 4.70 47000 10.0 10/04/2012 08:19 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 10/04/2012 08:20 SM-450ONO3F Total Cadmium 1.0 1.0 BW 10/04/2012 09:00 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made ((�� to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 12-277-0203 Account Number: 46442 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL/CHERRYVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 89681 Sample Id : CHERRYVILLE ' A&L Eastern Laboratories, Inc. Ykd ip, k 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 www.aleastern.com Project: CHERRYVILLE NC CERT # 257 REPORT OF ANALYSIS Date Sampled: 10/2/2012 11:00:00 Date Received: 10/03/2012 00:00 Date Reported: 10/05/2012 . Total Chromium 64 5 BW 10/04/2012 09:00 SW 6010C Total Nickel 78 5 BW 10/04/2012 09:00 SW 6010C Total Lead 30 5 BW 10/04/2012 09:00 SW 6010C Total Arsenic 4.0 1.0 BW 10/04/2012 09:00 SW 6010C Total Mercury 0.8 0.4 JM 10/04/2012 10:00 SW-7471 B Total Selenium 2.0 1.0 BW 10/04/2012 09:00 SW 6010C pH (Standard Units) 7.42 2.00 JM 10/04/2012 09:20 SW-9045D Total Molybdenum 7 5 BW 10/04/2012 09:00 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "K", "Mg", "Na", AND "P". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made (c�� to the work, the results, or the company in any advertising, news release, or otherpublic announcements without obtaining our prior written authorization. Debbie Holt SAMPLING LOG.# M-277-0203 46442 'S.YNA(3;FZO'i,ENTRALJCHERfRYVILLE 2012-10-03 'CUSTOMER: SYNAGRO SOUTHE CHERRYVILLE 11 '53:46 PR 0JE.CT:mANAGlER: Phone;. 71 - -469-� JURAL LABS, INC.. CHAUN OF CUS-TODY, RECORD& ANALYSIS 171-6446 . RECORD I attest that the.prgper field ' sampling procedures' Wer# used during the: collection of these- samples : / llt� A-& L LAB # CUSTOMER SAMPLE I.D. SAMPLIN LOCATION SAMPLE TYPE W bF CONTAINERS ;LICG DATE TIME METHOD PRESERVED METHOD IPPED SKIPPED ffiAk? - 111191 /' S-) - r-ozx Reflnquishbd,by Sampler- Date Time, ReGieved by:. REMARKS: J UZ 6- Relinquished- I by: Date Time RecieVed by; x q9�1.ms /P'z�o Relinquished by: DAie Time Recleved by, SPECIAL INSTRUCTIONS: .For monitoring ,purposes. P09:- SAMPLE j ANALYSIS, REQUEST jd•Volatile SLI. SL2 N I argan'cl Cd I Cr I NI PbAs Hg pH CAC03 N 'N NO, _equiv. SolidsMa Cl, 1111 O'N PP_ P ev;40Z,�Jl. SLI-Total Solids, (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium . ' SL2: Basic Test SLI:plus,Sulfur, Oalcium,Wagnesium, Sodium, Iron, Aluminum, Manganese; Qopperand Zinc White .A.& L. Canary -MANAGER COPY 11� 111l a' ! a r pp1� 1 c• + . F iiJ y .¢ 1 { r q. , c tt i. ��_ •� t - t • 11 1�.' r`+..+ .�1 ! .fir �' } 6 i' Product Code Product Name Sample Date Report Range Ratio 2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 10/2/2012 1011/2012-12131/2012 0.7232 Na mg/I = (Na mg/kg x % Solids) = 100 = (2730 x 2.1300) + 100 = 58.149 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (14600 x 2.1300) + 100 = 310.98 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (5010 x 2.1300) + 100 = 106.713 Na meq = Na mg/I = Molec.Wgt.Na = 58.149 _ 23 = 2.52822 Ca meq = Ca mg/I = Molec.Wgt.Ca = 310.98 + 20 = 15.549 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 106.713 = 12 = 8.89275 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.52822 = SgrRoot[0.5(15.549+8.89275)] = 0.723208 Printed: 1 /22/2013 Page 1 08:43 FACILITY NAME: CHERRYVILLE, NC OWNER: WAYNE GILBERT SITE #: NC LT 00120 FIELD# : LT 00120 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: WQ0000430 ANNUAL DRY TONS APPLIED: 35.80 OPERATOR: WAYNE GILBERT CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 31.70 ACRES PERMITTED: 31.70 Page Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppin) Crop Total Per Acre MONTH 11/12/12 18,600.00 (G) 586.751 2.13 0.052 CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 I FESCUE 11/13/12 105,400.00 (G) 3324.921 2.13 0.295 CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 I FESCUE 11/14/12 117,800.00 (G) 3716.088 2.13 0.330 CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 I FESCUE 11/15/12 105,400.00 (G) 3324.921 2.13 0.295 CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 I FESCUE 11/16/12 31,000.00 (G) 977.918 2.13 0.087 CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 I FESCUE 11/19/12 24,800.00 (G) 782.334 2.13 0.069 CHL DRY 0-<I/2" SUR 0.5 0.30 65,300.p 18,300.00 p 2.00 p 23252 FESCUE Nov-12 1 403,000.00 (G) 12,712.933 Total Gallons/Ac: 12,712.93 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annuallbs/acre 53 0.009 0.002 0.145 0.860 0.068 0.002 0.016 0.176 0.005 1.868 53.07 Cumulative lbs/acre 0.097 0.053 1.694 16.988 0.965 0.021 0.470 1.580 0.082 24.489 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop " 2 09 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID X 42 6 2 , (SIGN RE OF D APPLIER) DATE "Ice Ify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a. system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/lcg * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation ** Volatilization Rate: Surface 0.5, Injection/incorporation 1.0 *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2013 FACILITY NAME: CHERRYVILLE, NC OWNER: WAYNE GILBERT SITE #: NC LT 00120 FIELD# : LT 00120 0003 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: WQ0000430 ANNUAL DRY TONS APPLIED: 22.58 OPERATOR: WAYNE GILBERT CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 12.70 ACRES PERMITTED: 12.70 Page Lime Applied *** Date:T Lbs/Ac DATE or MONTH allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop Total Per Acre 11/12/12 86,800.00 (G) 6834.646 2.13 0.607 CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 I FESCUE 11/16/12 80,600.00 (G) 6346.457 2.13 0.56� CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 I FESCUE 11/19/12 86,800.00 (G) 6834.646 2.13 0.60h CHL DRY 0-<1/2" SUR 0.5 0.30 65,300. p 18,300.00 p 2.00 p 23252 FESCUE Nov-12 1 254,200.00 (G) 20,015.749 Total Gallons/Ac: 20,015.75 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annuallbs/acre 83 0.014 0.004 0.228 1.355 0.107 0.003 0.025 0.277 0.007 2.941 83.56 Cumulative Ibs/acre 0.082 0.044 1.383 14.582 0.755 0.017 0.458 1.444 0.066 20.033 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 209 FD Cumulative Pollutant Loading Rate Limit (Ibs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID X (SIGN RE 0.5 AND APPLIER) DATE "Ice ify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required %= percent p = ppm or mg/k.- ** Volatilization Rate: Surface 0.5, htjection/hncorporation 1.0 Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2013 Cherryville WWTP, NC TCLP TCLP is only required once per permit cycle. Sampling was done on 7/25/2011 and the results were submitted in the 2011 Annual Report. ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Chet'tyville WQ Permit Number WWTP Name: City of Chertyville WWTP NPDES Number: Monitoring Period: From Jan. 1, 2012 To Dec. 31, 2012 WQ0000430 NCO044440 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable'to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If annlirahip fn aIfPrnativP nPrfnrmPd it -lace A nr Clace R) emmnlPtP the fnIInwina mnnitnrina data' Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical I Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10 to the 6 th MPN 11,225.20 14,695 18,673.43 MPN/g 0 Annual grab SM 9221E Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) X (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have, been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Preparer ame and it 511ure of Preparer *Preparer is defined in 40 or print) Land Applier Name and Title (if applicable) (type or print) 2 Date Signature of Land Applier (if applicable) .9(r) and 15A NCAC 2T.1102 (26) Date PROM PT-ACCU RATE- RELIABLE I..A�®RAT®]E2.Y�Sy iNC WWW.PARLAB-9.COM REPORT OF ANALYSES Attn: ERIC THOMPSON SYNAGRO 284 BOGER ROAD MOCKSVILLE, NC 27028- PROJECT NAME: OCT 12 DATE: 11/07/12 SAMPLE NUMBER- 106786 SAMPLE ID- CHERRYVILLE SAMPLE MATRIX- WW DATE SAMPLED- 10/02/12 TIME SAMPLED- 1100 DATE.RECEIVED- 10/02/12 SAMPLER- ET RECEIVED BY- DJ TIME RECEIVED- 1227 DELIVERED BY- ET TYPE SAMPLE- Grab Page 1 of 1 ANALYSIS ANALYSIS METHOD DATE TIME BY RESULT UNITS 30 DAY BENCH SCALE TEST VAR 10/03/12 RE ATTACHED FECAL COLIFORM (GEOM. MEAN) SM 9221 E 10/02/12 1445 RE 14,695 MPN/g LABORATORY DIRECTOR P.O. Box411483 o Charlotte, NC 28241-1483 Phone: (704) 588.833.3 ® Fax: (704) 588-8335 e ••ee A. PROM PT•AGOUKATE•REL.I. W-E; 2217 Graham Park Drive PO Box 411483 Charlotte, NC 28241-1483 NC Cert # 20; SC Cert # 99003001 SYNAGRO CHERRYVILLE 10/02/12 FECAL'COLIFORM, GEOMETRIC MEAN • o SM 9221 E UA :IID ,. . 7 106786 1 237 2.11 % 11, 225.20 2 287 2.04% 14,100.24 3 359 1.92% 18,673.43 4 250 1.95% 12,833.63 5 316 1.70% 18,663.13 6 278 1.81 % 15,409.43 7 274 2.02% 13,562.57 Fecal Coliform Geometric, Mean- . ,. . • CHAINh f PAR'�3 dot , t.� CUSTODY �Sa t.� { �'S� a LABORATORfES.INC. PAR Laboratories, Inc ifigi as Phone /4588-8333 1 4588-8335 .u,.zr.•.s,:u�u:u-�.�-:.s,xw,c::vri'�:.rx : h; www.pariabs.com Shipping: Mailing: 2217 Graham Park Drive PO Box 411483 Charlotte, NC 28273 Charlotte, NC 28241-1483 It is essential that all information recorded on this Chain of Custody document for acceptance by PAR Laboratories, Inc. and the North Carolina Department of Environmental and Natural Resources. Company Name (billing) COMMENTS/SPECIAL SYNAGRO INSTRUCTIONS Address 284 BOGER ROAD City, State & zip code MOCKSVILLE NC 27028 Point of Contact & Telephone Number ERIC THOMPSON 336-998-7150 Sample taken by: l IS THIS FOR STATE or EPA REPOffING? YES f NO *Sample type: DW WW V GWMW Riw Soil Other Sample Temp upon receipt: �_ °C "Preserved. Yes No__ , Teflon Liner/ Zero Heaclspace: Yes _ No L, NIA _ Client Sample I.D. (Sample. Location /;Number) ... Comp Gra6 Preserv. SetupCollecio .:.Date/Time'r :: DatelTime; ` ! nalyseE Reggested;,, v U "{ ✓ t a_� Ir Z � � (Dvll',� and � 3� 1! �.'ii Cli l` 05 rsnea p Dater I ime Ke a ved by: Date/Time I 2. ` f Z 7 Khedja,r Date/Time Received by: Date/Time C=Composite G=Grab DW=Drinking Water WW=Wastewater GWMW=Groundwater Monitoring Well HW=Hazardous Waste **See Other Side r72 All r�AaFZ PROMPT•-,0MURATE• RELIABLE I..ABORA']CORIES� INC WWW.P°ARLABS.COM 30 Day Bench Scale Extended aeration Test Percent Volatile Solids Reduction SYNAGRO CHERRYVILLE 106786 10/03112 ' 10/31 12 Start: End: TS 0.4782 0.4384 TS% 1.94% 1.94% VS 0.3011 0.2681 VS% 62.97% 61.15% yl N 0.007136 yOUT 0.006289 FSVR (Mass Balance) 11.86% FSVR (Van Kleeck) 7.40% FSVR (Mass Balance) <15% YES FSVR (Van Kleeck) <15% YES FVSR (Mass Balance) Using Fixed Solids Xin 0.004197 Xout 0.003995 FVSR 20.33% FFSR 4.92% FSVR (Mass Balance) <15% 1NO P.O. Box 411483 a Charlotte, NC 28241-1483 Phone: (704) 538-8333 9 Fax: (704•) 588-8335 L R I` g PROMPT. -CCU M^7MT- R. F_�rLInB LE WWW.PAF;ZLASS.COM 30 Day Beach Scale Extended Aeration Fast PPrCFAnt Volatile Solids Reduction LL(tr �C�1111 - As Received Tare Wt (g) 17.8434 Sample(g) 45.1076 Dried Wt(g) 18.4185 TS% 2.11 % Day 0 10/03/12 y 0.007136 Tare Wt (g) 17.5454 x 0.004197 Sample + Tare(! 42.1970 TS 0.4782 Dried Wt(g) 18.0236 VS 0.3011 Burned Wt(g) 17.7225 TS% 1.94% VS% 62.97% Volatile Fraction In: 0.32459 Day 7 10/10/12 Tare Wt (g) 18.0079 Sample + Tare(! 41.2179 Dried Wt(g) 18.4535 Burned Wt(g) 18.1742 TS% 1.92% VS% 62.68% Day 14 10/17/12 Tare Wt (g) 16.6222 Sample + Tare(, 35.3000 Dried Wt(g) 16.9855 Burned Wt(g) 16.7594 TS% 1.95% VS% 62.24% Day 21 10/24/12 Tare Wt (g) 17,1156 Sample + Tare(, 36.6070 Dried Wt(g) 17.4859 Burned Wt(g) 17.2591 TS% 1.90% VS% 61.25% Day 28 10/31/12 y 0.006289 Tare Wt (g) 20.0329 x 0.003995 Sample + Tare(i 42.6299 TS 0.4384 Dried Wt(g) 20.4713 VS 0.2681 Burned Wt(g) 20.2032 TS% 1.94% VS% 61.15% Volatile Fraction Out: 0.31521 P0.IIox411483 © Charlotte, NC 28241-1483n Phoe: (704) 538-8333 or.: (704) 588-8335 Agricultural Lime Application Log Year: 2012 Project: City of Cherryville Field (state -county -site -field code) Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied Date Applied NC-LT-120-2 6.1 N/A N/A N/A NC-LT-120-3 6.0 N/A N/A N/A NCDA&CS , Dmic Division Phone: (919) 733-2655 Website: wwwa gov/agronomi/ Report No. FY D18194 Client: Wayne Gilbert Advisor- Synagro }.' Predictive 884 Cat Square Rd 284 Boger Rd Vale, NC 28168 Mocksville, NC 27028 Mehlich-3 SoH Report Extraction County: Lincoln Sampled: 11/26/2012 Received: 12/13/2012 Completed: 12/21/2012 Farm: Lt-120 Links to Helpful Information Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fes/OG/Tim,E 0.8 50-70 0 0 0 0 0 0 0 0 Note: 12 2-Fes/OG/Tim,M 0.0 120-200 0 20 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cd; CEC and Na in meq/100 cnr3; NO3-N in mg/drrr3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.51 1.02 9.3 90 1.0 6.1 175 63 57 30 47 127 86 92 414 414 463 0.1 1 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fes/OG/Tim,E 1.0 50-70 0 10 0 0 0 0 0 0 Note: 12 2 - Fes/OG/Tim,M 0.0 120-200 0 50 0 0 0 0 0 0 Note: 12 Test Results [units - WN in g/crrr3; CEC and Na in meq/100 crrp; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-Al Cu-I Na ESP SS-1 NO3-N 0.51 1.03 9.6 88 1.2 6.0 153 46 58 27 39 116 79 86 390 390 436 0.1 1 North Carolina 77. .. ' as1�Y;ICI,e '� 1 LJS' F L!ILI � L:a111w1iS'.li?IY Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture