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HomeMy WebLinkAboutWQ0000430_Regional Office Historical File Pre 2018 (3)The Lincoln, $~ `4 ,� ' •�HandsOnMobileDetailing.com / Couniy S�Club . ' � �� - .� TIE � try ' ?�•. _ 1' 4a#- 6a s,y_ o IV 49 41 UniomElementaryj • W _ tip � ' �, ' ; j a �_,. _.--''� • 'Vale .. 41* �_. ^„ram'" y,�,." �•� ., ,} � • �r HO�lIa ;.s i • „f' �g t ' =�i Unity Chapel LM V. > ` ` Bogle Maps 610 E Center Ave, Mooresville, NC Drive 91.0 miles, 2 h 11 min 28115 to 3900 Park Rd, Charlotte, NC 28209 Larry Wright 704-435-1739 Map data ©2020 2 mi L 610 E Center Ave Mooresville, NC 28115 t 1. Head south on Evergreen St toward E Center Ave 49�7 ft) Take NC-150 W and Reepsville Rd to Cat Square Rd in Vale 3 n jrt-F .6 mi) r 2. Turn right onto E Center Ave 0.9 mi �7 3. Turn left onto Charlotte St 400 ft N 4. Turn right at the 1st cross street onto W McLelland Ave .7 mi 5. Use any lane to.turn left onto NC;150 W/E Plaza Dr eContinue to follow NC-150 W Pass by Zaxby's Chicken Fingers & Buffalo Wings (on the right in 1.3 mi) 23.0 mi f 6. Turn right onto Curve View Rd 9.3 mi fi 7. Turn right onto-Woolie Rd 9.7 mi 41 8. Turn left onto Buffalo Shoals Rd -9.2 mi f• 9. Turn right onto Bethel Church Rd 1.9 mi t 10. Continue onto Clark Creek Rd 1.6 mi 41 11. Turn left onto Startown Rd ^.5 mi 10 12. Turn right onto Reepsville Rd 7.3 mi 41 13. Turn left onto Hoover Elmore Rd 1.9 mi r 14. Turn right onto Cat Square Rd 9.4 mi 1 h 4 min (41.6 mi) Vale North Carolina t 15. Head south on Cat Square Rd toward Bill Ledford Rd t 16. Continue onto Shoal Rd i.7 mi 3 mi r► 17. Turn right onto NC-182 W 236 ft h 18. Turn left onto Johnstown Rd 7 mi 19. Turn left onto Ishmael Beam Rd mi 20. Turn left onto Tot Dellinger Rd .0 mi 13 min (8.9 mi) 736 Tot Dellinger Rd Cherryville, NC 28021 Take Tot Dellinger Rd to E Church St in Cherryville 1 21. Head southeast on Tot Dellinger Rd toward Robert Rd -= +.7mi 22. Turn right onto 1637/Tot Dellinger Rd 102 ft 23. Turn left onto Benaja Black Dr -0.3 mi Take NC-279 E,1-85 N and Billy Graham Pkwy to Park Rd in Charlotte — -- 51.1, h-(-38.4 mi) '1 24. Turn left onto E Church St 0.2 mi r 25.. Turn right onto N Rudisill Ave -0.1 mi 47 26. Turn left onto NC-279 E/E Main St Continue to follow NC-279 E Pass by Waffle House (on the left in 11.5 mi) mi 27. Turn right to merge onto US-321 S Pass by,Taco Bell (on the right in 1.9 mi) 2.3 mi 28. Use the right lane to merge onto 1-85 N via the ramp to Charlotte 16.1 mi 29. Take exit 33 to merge onto Billy Graham Pkwy 5.3 mi t 30. Continue onto W Woodlawn Rd (signs for Interstate 77 S) ePass by Bojangles' Famous Chicken 'n Biscuits (on the . left in 0.5 mi) .3 mi 41 31. Turn left onto Park Rd 0Destination will be on the left ^.4 mi 55 min (40.5 mi) 3900 Park Rd Charlotte, NO 28209 These directions are for planning purposes only. You may find that construction projects, traffic, weather, or other events may cause conditions to differ from•the map results, and you should plan your route accordingly. You must obey all signs or notices regarding your route. Water Resources Environmental Quality tt 6J t February 1, 2018 Mr. Larry Wright, WWTP Superintendent / ORC via Email Town of Cherryville 116 South Main Street Cherryville, North Carolina 28021 Dear Mr. Wright: ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Interim Director Subject: Non -Discharge Permit Inspection Town of Cherryville - Permit No.: WQ0000430 Land Application of Residuals Gaston County Enclosed you will find the report for the compliance inspection conducted on January 30tn 2018 for the referenced permit. You will receive a separate report for the NPDES inspection (permit #NC0044440) conducted by Ori Tuvia, also from the Mooresville Regional Office. I would like to thank you and Chris Heedick (WWTP BLI-ORC) for your time during the inspection. The MRO confirmed notice of the land application event conducted in March 2017 was received as required by the permit. The additional Pathogen and Vector Attraction Reduction information requested was received by email from Erik Bruce (Synagro) on February 1, 2018. The report should be self-explanatory; however, I may be reached by phone (704-235-2184) or email (maria.schutteCaD-ncdenr.gov) with questions. Sincerely, %V�/ " Maria Schutte, Environmental Specialist Mooresville Regional Office Water Quality Regional Operations Section Division of Water Resources, NCDENR Attachment: MQ0000430 Inspection Report CC: Erik Bruce, SYNAGRO (email) State of North Carolina I Environmental Quality I Water Resources I Water Quality Regional Operations Mooresville Regional Office 1 610 East Center Avenue, Suite 3011 Mooresville, North Carolina 28115 704 663 1699 State of North Carolina Department of Environmental Quality Division of Water Resources Roy Cooper, Governor Michael S. Regan, Secretary Linda Culpepper, Interim Director NON -DISCHARGE COMPLIANCE INSPECTION GENERAL INFORMATION Owner: Town of Cherryville County: Gaston Permit #: WQ0000430 Issued: 04/24/2015 Effective: 08/01/2015 Expiration: 07/31/2020 Permittee Contact: Larry Wright (WWTP ORC) — lwright@cityofchgMville.com Phone: 704-435-1700 LA ORC Name: Robert M. (Mike) Cox #13191 Phone: 704-718-2804 LA BU ORC: Erik Bruce #1003528 — ebruce@synajzro.com Phone: 336-703-8681 Reason for Inspection X ROUTINE COMPLAINT FOLLOW-UP OTHER Type of Inspection Collection System Spray Irrigation X Sludge Inspection Date(s): January 30, 2018 Inspection Summary: (additional comments may he included on attached pages) Other This inspection included residuals. storage and a records review. Additional data requested was received by email on February 1, 2018. The MRO recommends this information be maintained at the WWTP either electronically or by paper copy for future inspections. Your permit currently requires 5 years of records be available for review. Please Note: • Synagro staff are contracted for the land application program; however, the permittee, as the responsible party, should review all lab results to ensure compliance prior to land application. • The MRO should be informed of any changes to the contact information noted above. Is a follow-up inspection necessary es X no? Inspector Name/Title: Maria Schutte, Environmental Specialist; Ori Tuvia, Engineer Telephone No.: 704-663-1699 Fax No. 704-663-6040 Date of Inspection: 1/30/2018 Fs Inspection pg. 2 0430 Town of Cherryville — Gaston County e of Residual X Land Application (class B) Distribution and Marketing (class A) Record Keeping Y-yes N-no N/A -not applicable N/E-not evaluated Y Copy of current permit available at residual generating site Y Current metals and nutrient analysis (see permit for frequency) Y TCLP analysis, Y SSFA (Standard Soil Fertility Analysis) Y Nutrient and metals loading calculations (to determine most limiting parameter) YTD Y Hauling records (# gal and/or ton hauled during calendar year to date) Y Field loading records,' Y Field site maps and information NE Records of lime purchased * Y Pathogen & Vector Attraction Reduction Comments: Land application was conducted in March of 2017. * PVAR data was not available on -site, but received by email on February 1 ", 2018. Pathogen & Vector Attraction Reduction (PVAR) records Fecal coliform X SM 9221 E (Class A or B) (Class A, all test must be <1000 MPN / dry gram) (Class B, Geometric mean of 7 samples/monitoring period - <2.0* 106 CFU / dry gram) SM 9222 D (Class B only) (Geometric mean of 7 samples/monitoring period for Class B <2.0* 106 CFU / dry gram) Salmonella (Class A, all tests must be < 3MPN / 4 grams dry Time / Temp records Digester (MCRT) Compost Class A lime stabilization Volatile solids calculations X Bench -top aerobic/anaerobic digestion results pH records for lime stabilization (Class A or B) SOUR calculations Treatment X Aerobic digestion Autothermal Thermophilic Aerobic Digestion Anaerobic digestion Drying beds (may not meet 503's) Alkaline Stabilization Lime Other -describe Comments: This inspection was conducted along with the NPDES inspection (permit #NC0044440). A new bar screen was installed at the pump station. Transport NA — there was no active land application at the time of this inspection. Spill control plan in transport vehicle? NA Does transport vehicle appear to be maintained? NA Condition of land application equipment on site: NA nspection 0 Town of Cherryville — Gaston County pg. 3 days/weeks/months of storage: Per prior inspections, 12+ months. Cherryville typically applies in the all. gage: Storage is a clay -lined lagoon at the WWTP. Per previous inspection report(s), WWTP staff attempt to keep woody vegetation under control, but some work is contracted out for of tciency and saLtX purposes and must be budgeted accordingly. The berm appeared fairly, well maintained at the time of inspection, although, woodLvegetation along the side banks requires constant upkeep. Odors present N Vectors present N Sampling Describe Sampling: Per previous inspections: fecal coliform, metals, nutrients, and a 30 day bench scale test are collected, as grab samples annually by the ORC/land application contractor, from storage prior to land implication in accordance with the permit. Is sampling adequate? NE Is sampling representative? NE *-Sampling should be adequate and representative if the instructions noted in the "Sampling Plan " are followed. Field Sites (end use for class B biosolids) NA. There was no active land application at the time of inspection. Field identification: NA Odors/vectors NA Describe any nuisance conditions and any corrective actions needed. NA Odors present NA Vectors present NA Monitoring wells) Y/N: NA If yes, location of well(s): Comment: This permit currently does not require groundwater monitoring Other noted conditions PAT MCCRORY Governor DONALD R. VAN DER VAART Secretary S. _JAY ZIMMERMAN Director December 9, 2016 Mr. Larry Wright, WWTP Superintendent / ORC via email Town of Cherryville 116 South Main Street Cherryville, North Carolina 28021 Subject: Non -Discharge Permit Inspection Town of Cherryville - Permit No.: WQ0000430 Land Application of Residuals Gaston County Dear Mr. Wright: Enclosed you will find the report for the compliance inspection conducted on December 6th, 2016 for the referenced permit. You will receive a separate report for the NPDES inspection (permit #NC0044440) conducted by Ori Tuvia, also from the Mooresville Regional Office. i Please submit an updated Operator Certification Form as noted in the March 7, 2016 inspection report: According to our database Eric Thompson's operator certification is currently invalid. Please submit an updated operator designation form, which may be located on-line at' the new DEQ web -link below: http://deg. nc.gov/about/divisions/water-resources/wastewater-operator-certification/wastewater- operator-certification/wastewater-operator-certification-down loads I would like to thank you and your staff for your time during the inspection. Per our conversation you are working with Synagro to replace recently lost acreage for application and currently plan to apply in early 2017; however, will utilize unused portions of the plant as necessary to maintain lagoon freeboard and the residuals.program requirements. The report should be self-explanatory; however, I may be reached by phone (704-235-2184) or email (maria.schutteQncdenr.gov) with questions. Sincerely, Maria Schulte, Environmental Specialist Mooresville Regional Office Water Quality Regional Operations Section Division of Water Resources, NCDENR Attachment: WWQ0000430 Inspection Report CC: Marshall Puryear, SYNAGRO (email) State of North Carolina I Environmental Quality I Water Resources I Water Quality Regional Operations Mooresville Regional Office) 610 East Center Avenue, Suite 3011 Mooresville, North Carolina 28115 704 663 1699 date of North Carolina Department of Environmental Quality ivision of Water Resources Pat. McCrory, Governor . Donald R. van der Vaart, Secretary NON -DISCHARGE COMPLIANCE INSPECTION GENERAL INFORMATION Owner: Town of Cherryyille County: Gaston Permit #: WQ0000430 Issued: 04/24/2015 Effective: 08/01/2015 Expiration: 07/31/2020 Permittee Contact:. LarrWright (WWTP ORC) Telephone No.: 704-435-1700 LA ORC Name: Robert M. (Mike) Cox #13191 Telephone No.: 704-718-2804 • LA BU ORC: Eric Thompson #29096 Telephone No.: Reason for Inspection X ROUTINE COMPLAINT FOLLOW-UP OTHER Type of Inspection Collection System Spray Irrigation X Sludge Inspection Date(s): December 6, 2016 Inspection Summary: (additional comments may be included on attached pages) 336-998-7150 Other This inspection included residuals storage and a records review. No new data has been generated since the previous inspection because Cherryville has not land applied. Please note: New land is planned to be added for application in early 2017; however, the sludge storage lagoon 2 foot free -board will be maintained utilizing the un-used portion of the WWTP should unforeseen circumstances prevent land application. • The MRO should be informed of any changes to the contact information noted above. According to our database Eric Thompson's operator certification is -currently invalid. Please submit an undated operator designation form, which may be located on-line at the new DEQ web -link below: http://deq.nc. jzov/about/divisions/water-resources/wastewater-operator-certification/wastewater- operator-certification/wastewater-operator-certification-downloads Is a follow-up inspection necessary _des X no? Inspector Name/Title: Maria Schutte, Environmental Specialist; Ori Tuvia, Engineer Telephone No.: 704-663-1699 Fax No. 704-663-6040 Date of Inspection: 12/06/2016 Inspection 30 Town of Cherryville — Gaston County pg. 2 of Residual X Land Application (class B) Distribution and Marketing (class A) Record Keeping Y-yes N-no N/A -not applicable N/E-not evaluated Y Copy of current permit available at residual generating site Y Current metals and nutrient analysis (see permit for frequency) Y TCLP analysis, Y SSFA (Standard Soil Fertility Analysis) Y Nutrient and metals loading calculations (to determine most limiting parameter) YTD Y Hauling records (# gal and/or ton hauled during calendar year to date) Y Field loading records, Y Field site maps and information NE Records of lime purchased Y Pathogen & Vector Attraction Reduction Comments: The most recent records available were included in the 2015 AR, which was reviewed on -site during the March 2016 inspection. Pathogen & Vector Attraction Reduction (PVAR) records Fecal coliform X SM 9221 E (Class A or B) (Class A, all test must be <1000 MPN / dry gram) (Class B, Geometric mean of 7 samples/monitoring period - <2.0* 106 CFU / dry gram) SM 9222 D (Class B only) (Geometric mean of 7 samples/monitoring period for Class B <2.0* 106 CFU / dry gram) Salmonella (Class A, all tests must be < 3MPN / 4 grams dry Time / Temp records Digester (MCRT) Compost Class A lime stabilization Volatile solids calculations X Bench -top aerobic/anaerobic digestion results pH records for lime stabilization (Class A or B) SOUR calculations Treatment X Aerobic digestion Autothermal Thermophilic Aerobic Digestion Anaerobic digestion Drying beds (may not meet 503's) Alkaline Stabilization Lime Other -describe Comments: This inspection was conducted along with the NPDES inspection (permit #NC0044440). The bar screen at the pump station to the head of the plant is very corroded and proposed to be replaced next year. Transport NA — there was no active land application at the time of this inspection. Spill control plan in transport vehicle? NA Does transport vehicle appear to be maintained? NA Condition of land application equipment on site: NA Inspection 30 Town of Cherryville — Gaston County pg. 3 of days/weeks/months of storage: Per prior inspections, 12+ months. Cherryville typically applies once a year in the fall. Describe storage: Storage is a clay -lined lagoon at the WWTP. Per previous inspection report(s), WWTP staff attempt to keep woody vegetation under control, but some work is contracted out for efficiencyand nd salty purposes and must be budgeted accordingly. Odors present N Vectors present N Sampling Describe Sampling: Per previous inspections: fecal coliform, metals, nutrients, and a 30 day bench scale test are collected, as grab samples annually by the ORC/land application contractor, from storage prior to land application in accordance with the permit. Is sampling adequate? NE I Is sampling representative? NE *-Sampling should be adequate if the instructions noted in the "Sampling Plan" are followed. Field Sites (end use for class B biosolids) NA. There was no active land application at the time of inspection. Field identification: NA Odors/vectors NA Describe any nuisance conditions and any corrective actions needed. NA Odors present NA Vectors present NA Monitoring wells) Y/N: NA If yes, location of well(s): Comment: This permit does not require groundwater monitoring Other noted conditions 'ater Resources RONMENTAL QUALITY March 29, 2016 Mr. Larry Wright, WWTP Superintendent / ORC Town of Cherryville 116 South Main Street Cherryville, North Carolina 28021 Dear Mr., Wright: Emor MCCRORY Gnve r DONALD R. VAN DER VAART Secretary S. JAY ZIMMERMAN Director Subject:, Non -Discharge Permit Inspection and Acknowledgement of Receipt of the 2015 Annual Report Town of Cherryville - Permit No.: WQ0000430 Ladd Application of Residuals Gaston County Enclosed you will find the report for the compliance inspection conducted on March 7th, 2016 for the referenced permit. The 2015 Annual Report was reviewed on -site during the inspection and a copy received at the Mooresville Regional Office on the following day, March 8th, 2016. I would like to thank you for your time during the inspection. The lagoon berm needs routine maintenance for brush removal; otherwise,. the residuals storage. and analyses appeared to meet program requirements at the time of inspection. The report should be self-explanatory; however, I may be reached by phone (704-235- 2184) or email (maria.schuite _ncdenr.gov) with questions. Sincerel , Maria Schutte,, nviron ental Specialist Mooresville Regional Office Water Quality Regional Operations Section Division of Water. Resources, NCDENR Attachment: WWQ0.000430 Inspection Report CC: Marshall Puryear, SYNAGRO (email) Nathaniel Thornburg, CO-LAU (email) State bf North Carolina I Environmental Quality I Water Resources I Water Quality Regional Operations Mooresville Regional Office) 610 East Center Avenue, Suite 3011 Mooresville, North Carolina 28115 704 663 1699 State of North Carolina Department of Environmental Quality Division of Water Resources Pat McCrory, Governor Donald R. van der Vaart, Secretary NON -DISCHARGE COMPLIANCE INSPECTION GENERAL INFORMATION Owner: Town of Cherryville County: Gaston Permit #: W00000430 Issued: 04/24/2015 Effective: 08/01/2015 Expiration: 07/31/2020 Permittee Contact: Larry Wright(WWTP ORC) Telephone No.: 704-435-1700 LA ORC Name: Robert M. (Mike) Cox #13191 Telephone No.: 704-718-2804 • LA BU ORC: Eric Thompson #29096 Telephone No.- 336-998-7150 Reason for Inspection X ROUTINE COMPLAINT FOLLOW-UP - OTHER Tyne of Inspection Collection System Spray Irrigation X Sludge Other Inspection Date(s): March 7, 2016 Inspection. Summary: (additional comments may be included on attached Pages) This inspection included residuals storage and a records review. Data was examined on -site via their 2015 annual report. - Please note; • The sludge storage lagoon was in need of berm maintenance for vegetation. • The'MRO should be informed of any changes to the contact information. noted above. According to our database Eric Thompson's operator certification is currently invalid. Please submit an updated operator designation form, which may be located on-line at the new DEQ web -link below: http://deq.iic. gov/about/divisions/water-resources/wastewater-operator-certification%wastewater- operator-certification/wastewater-operator-certification-downloads Is a follow-up inspection necessary yes X no? Inspector Name/Title: Maria Schutte, Environmental Specialist Telephone No.:-704-663-169.9 Fax No. 704-663-6040 Date of Inspection: 03/07/2016 Inspection 30 Town of Cherryville — Gaston County pg. 2 X Land Application -(class B) Record Keeping Distribution and Marketing (class A) Y-yes - N-no - N/A -not applicable N/E-not evaluated Y Copy of current permit available at residual generating site Y Current metals and nutrient analysis (see permit for frequency) )L TCLP analysis, Y SSFA (Standard Soil Fertility Analysis) Y . Nutrient and metals loading calculations (to determine most limiting parameter) YTD .Y Hauling records (# gal and/or ton hauled during calendar year to date) Y Field loading records, Y Field. site maps and information NE Records of lime purchased Y - Pathogen & Vector Attraction Reduction Comments: The most recent records available were included in the 2015 AR, which was reviewed on -site. Pathogen & Vector Attraction Reduction (PVAR1 records Fecal coliform X. SM 9221 E (Class A or B) (Class A, all test must be <1000 MPN / dry gram) (Class B, Geometric mean of 7 samples/monitoring period - <2.0* 106 CFU / dry gram) SM 9222 D (Class B only) (Geometric mean of 7 samples/monitoring period for Class B <2.0* 106.CFU / dry gram) Salmonella (Class A, all, tests must be < 3MPN / 4 grams dry Time / Temp records Digester (MCRT) Compost Class A lime stabilization Volatile solids calculations X Bench -top aerobic/anaerobic digestion results pH records for lime stabilization (Class A or B) SOUR calculations Treatment X Aerobic digestion Autothermal Thermophilic Aerobic Digestion Anaerobic digestion Drying beds (may not meet 503's). Alkaline Stabilization Lime Other -describe Comments: Typical plant odors were not detected at the time of inspection. Transport NA —there was no active land application at the time of this inspection. . Spill control plan in transport vehicle? NA Does transport vehicle appear to .be maintained? NA .Condition of land application equipment on site: NA Residuals Inspection WQ0000430 Town of Cherryville — Gaston County Storage Number of days/weeks/months of storage: Per prior inspections, 12+ months. Cherryville typical once a year in the tall• Describe storage: Storage is a clay -lined lagoon at the WWTP. The berm was in need of maintenai vegetation growth 'Per previous inspection reports) WWTP sta attem t to o keep woody vegetation under control, but some work is contracted out for efficiency and safeUp�jposes and must be budgeted according Odors present N Vectors present N Samuling Describe Sampling: Per previous inspections: fecal coliform, metals nutrients and a 30 day bench scale test are application in accordance with the ep rmit. . Is sampling adequate? 'NE Is sampling representative? NE * Sampling should be adequate if the instructions noted in the "Sampling Plan" are followed. Field Sites (end use for class S biosolids) NA: There was no active land application at the time of inspection. Field identification: NA Odors/vectors NA Describe any nuisance conditions and any corrective actions needed. NA Odors present NA Vectors present NA Monitoring wells) Y/N: NA If yes, location of well(s): Comment: This permit does not require groundwater monitoring_ Other noted conditions ry A It A r�1 NCDENR North Carolina Department of Environment and Natural November 25, 2014 Mr. Larry Wright, WWTP Superintendent / ORC Town of Cherryville 116 South Main Street Cherryville, North Carolina 28021 Dear Mr. Wright: Resources John. E. Skvarla, III Secretary Subject: Non -Discharge Permit Inspection Town of Cherryville - Permit No.: W00000430 Land Application of Residuals Gaston County Staff of the Mooresville Regional Office (MRO) conducted a compliance inspection on September 25th, 2014 for the Town of Cherryville's land application program. The inspection included a records review and residuals processing and storage at the WWTP facility; and, a land application event. The current permit expiration date is July 31, 2015. A renewal application is due 180 days prior to expiration, which will be January 31st, 2015. Please email an updated copy of the LA-ORC designation form, as the names on the form from 2009 are different from those in our data base. The attached report should be self-explanatory; however, should you have questions please contact me by phone (704-235-2184) or email (maria.schutte(aD_ncdenr.gov). Sincerely, Maria Schulte, Environmental Specialist Mooresville Regional Office Water Quality Regional Operations Section Division of Water Resources, NCDENR Attachment: WWQ0000430 Inspection Report CC: Eric Thompson, SYNAGRO (email) Ed Hardee, Residuals Program Coordinator, CO-LAU (email) Mooresville Regional Office, 610 East Center Avenue, Mooresville, North Carolina 28155 Phone: 704-663-1699\ Internet: www.ncdenr.gov An Equal Opportunity \ Affirmative Action Employer— Made in part by recycled paper State of North ,Carolina Department of Environment and Natural Resources Division of Water Resources Pat McCrory, Governor John E. Skvarla, III, Secretary A' kTT4 � ah; NCDENR NON -DISCHARGE COMPLIANCE INSPECTION GENERAL INFORMATION City/Towr/Owner: Town of Cherryville Permit No.: W00000430 Permittee Contact: Larry Wright (WWTP ORC) LA ORC: Robert M. (Mike) Cox #13191 LA ORC BU: Eric Thompson #29096 County: Gaston Issued: 06/12/2012 Expiration: 07/31/2015 Telephone No.: 704-435-1700 Telephone No.: 704-718-2804 Telephone No.: 336-998-7150 Reason for Inspection X ROUTINE COMPLAINT FOLLOW-UP OTHER Type of inspection Collection System Spray Irrigation X Sludge Other Inspection Date(s): September 25, 2014 Inspection Summary: (additional comments may be included on attached pages) This inspection included a facility and land application site visit. Data records appeared to be in order. Mr. Wright had not yet received the latest results from SYNAGRO, but the MRO received them by email the following day. The sludge storage lagoon was in need of berm maintenance for vegetation. SYNAGRO loading equipment was onsite during the WWTP inspection. A spill from a hose break was reported the day before, and appeared to have been adequately addressed with lime & hay. Land application was taking place at site NC-LT-124-01. The MRO met with Eric Thompson (SYNAGRO) at the WWTP and followed him to the field site. The LA equipment appeared to be in good condition and the field application appeared to meet permit requirements, at the time of inspection. Please note: a Cherryville's current LA permit will expire on July 31st, 2014. A renewal application is due 180 days prior to expiration. • A current LA-ORC designation form was to be submitted, if this has already been done please email a copy to the MRO. Is a follow-up inspection necessary yes X no Inspector(s): Maria Schulte - Environmental Specialist Telephone No.: 704-663-1699 Fax No.: 704-663-6040 Date of Inspection: September 251h, 2014 [Is Inspection 0430 Town of Cherryville — Gaston County pg. 2 e of X Land Application (class B) Y-yes N-no N/A -not applicable Record Keeping Distribution and Marketing (class A) N/E-not evaluated Y Copy of current permit available at residual generating site *Y Current metals and nutrient analysis (see permit for frequency) Y TCLP analysis, Y SSFA (Standard Soil Fertility Analysis) Y Nutrient and metals loading calculations (to determine most limiting parameter) YTD Y Hauling records (9 gal and/or ton hauled during calendar year to date) Y Field loading records, Y Field site maps and information NE Records of lime purchased *Y Pathogen & Vector Attraction Reduction Comments: * The contractor performs sludge compliance testing and submits an annual report on behalf of the permittee. The most recent analytical data had not yet been copied to the permittee, but was received by email request from the contractor the following day. Pathol4en & Vector Attraction Reduction Records Fecal coliform X SM 9221 E (Class A or B) (Class A, all test must be <1000 MPN / dry gram) (Class B, Geometric mean of 7 samples/monitoring period <2.0* 106CFU / dry gram) SM 9222 D (Class B only) (Geometric mean of 7 samples/monitoring period for Class B <2.0* 106 CFU / dry gram) Time / Temp records N/A Digester (MCRT) N/A Volatile solids calculations Y Treatment X Aerobic digestion Autothermal Thermophilic Aerobic Digestion Anaerobic digestion Drying beds (may not meet 503's) Alkaline Stabilization Lime Other -describe (Centrifuge) Comments: Transport Records were reviewed and present in the land application tractor, and the BU ORCs truck. The transport vehicle was not examined. Spill control plan in transport vehicle? NE Does transport vehicle appear to be maintained? NE Condition of land application equipment on site: Equipment appeared to be maintained appropriately. Residuals Inspection WQ0000430 Town of Cherryville — Gaston County Storage Number of days/weeks/months of storage: Per previous reports, 12+ once a year. Describe storage: Storage is a clay -lined lagoon at the WWTP. The berm was in need of maintenance or vegetation growth, and a pipe at one end of the lagoon looked like it needed maintenance. Plant staff attempt to keep wood vegetation under control, but some work is contracted out forefficiency and safety purposes, and must be budgeted accordingly. Odors present N Comments: Sampling Vectors present N Describe Sampling: Per previous inspections, fecal coliform, metals, and nutrient sampling and a 30 day bench scale test are taken as grab samples annually by the ORC/land application contractor, from storage prior to land application in accordance with the permit. Is sampling adequate? Y Is sampling representative? Y Field Sites (end use for class B biosolids) Y Permit on site during application Y Buffers adequate N Documented exceedances of PAN limits N Signs of runoff / ponding Y Spill plan on site Y Cover crop specified in permit Y Site condition adequate Y Rain Gauge on site during application Are there any limiting slopes on fields? NA 10 % for surface application NA 18% for subsurface application Odors/vectors Describe any nuisance conditions and any corrective actions needed. Odors present N Vectors present N Monitoring wells) Y/N: N/A Other noted conditions y®RCN ERRy� cit ® C�te�i�yviI`e y WASTEWATER PLANT-: 116 South Mountain Street North Carolina 28021 r�11 q Phone: (704) 435-1739 U �' 214 0` FAX: (704) 435-1713 u►RRv G. VYRIGHL II www.cityofchenyville.com Plant Supervisor:: q September 26, 2014 CERTIFIED MAIL:b. RETURN RECEIPT REQUESTED NCDENR :..: Division of Water Quality Maria Schutte Environmental Specialist 610 East Center Avenue, Suite 301 Mooresville, North Carolina 28115 Subject: Sludge Spill on 9-23-2014, Land - Application-:: Cherryville WWTP NPDES Permit No. WQ00000430 Gaston County, NC Dear Maria Schutte, This letter is in response.to the spill we had occur on September 23, 2014. Our Contractor Synagro had a hose burst between the tractor/pump and the tanker truck. I was notified of the spill by Mike Cox the same day it happen on September 23, 2014. Mike estimated the spill to be between 40 — 50 gallons. We applied 200 Ibs lime and 4 bales of straw after the event on the. same day. Mike with Synagro-replaced the busted hose with a new one so that this doesn't occur again. We: had no further problems after- that and they were able to finish the land application. project for us. I hope that you find this satisfactory, please contact me. at the number below if you have any questions....:... - Sincerely, . ,ice r .. ... .. ... - -Larry Wright Plant Supervisor/ORC City of Cherryville Wastewater Treatment Plant (704) 435-1739 - office :. LARRY G. WRIGKr 11 Plant Supervisor November 9, 2011 CERTIFIED MAIL RETURN RECEIPT REQUESTED NCDENR Division of Water Quality Ellen Huffman Environmental Specialist 610 East Center Avenue, Suite 301 Mooresville, North Carolina 28115 Dear Ellen Huffman, City of, Cheltyville WASTEWATER PLANT 116 South Mountain Street North Carolina 28021 Phone: (704) 435-1739 FAX: (704) 435-1713 www.cityofcherryville.com RECEIVED DIVISION OF WATER QUALITY NOV 10 2011 SVVP SECTION MOORESVILLE REGIONAL OFFICE Subject: Non -Discharge Inspection Land Application Program Compliance Evaluation Inspection Cherryville WWTP NPDES Permit No. WQ00000430 Gaston County, NC This letter is in response the Compliance Evaluation Inspection conducted by Ellen Huffman on October 6, 2011. I just wanted to acknowledge your inspection report that I received in the mail that was dated October 14, 2011. I'm sorry I missed you that day, if you let me know ahead I will be here for sure. There was no corrective action listed and showed that we were in compliance. I hope that you find this satisfactory, please contact me at the number below if you have any questions. Sil 7, Larry Wright Plant Supervisor/ORC City of Cherryville Wastewater Treatment Plant (704) 435-1739 -office (704) 214-1162 - cell www.cityofcherryville.com ° vr..'r..'7}." r NCDENR North Carolina Department of Environment and Natural "esources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Governor Director October 14, 2011 Mr. Larry Wright, Cherryville WWTP Supervisor City of Cherryville 116 South Main Street Cherryville, North Carolina 28021 Subject: Non -Discharge Inspection Land Application Program Permit No. WQ00000430 Gaston County Dear Mr. Wright: Dee Freeman Secretary Enclosed you will find the report for the compliance inspection that was conducted on October 6, 2011 for the subject non -discharge land application permit. The report should be self-explanatory but should you have any questions regarding this inspection, please call me at 704/235-2186.. Sincerely, ben Huffman Environmental Specialist Attachment cc: Scott Berg, SYNAGRO Ed Hardee, LAU Residuals Program Coordinator MRO files I I I I Division of Water Quality / Aquifer Protection Section I Mooresville Regional Office I 610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 Phone: 704-663-16991 Fax: 704-663-6040 l Customer Service: 1-877-623-6748 IInternet: www.ncwaterquality.org An Eaual O000rtunity 1 Affirmative Action Employer One NorthCarolina Natu'rallay State of North C,ar _,lkl; a Department of Ens iron.rnenm t and Natural Resources Division of Water Quality Beverly Eaves Purdue, Governor Dee Freeman, Secretary Coleen H. Sullins, P.E. Director NON -DISCHARGE COMPLIANCE INSPECTION City/Town/Owner: Che=ille Permit No.: WQ0000430 Last Amended Date: N/A SOC Issuance Date(if applicable): N/A Permittee Contact: Larry Wright ORC Name: Scott Berg ORC Cert.#: LA #22731 Reason ¢or Inspection GENERAL INFOR1M TION County: Gaston Issuance Date: 07/09/2010 Expiration Date: 67/31/2015 Expiration Date: N/A Telephone No.: 704/ 435-1700 Telephone No.: 336-766-0328 B/U 'ORC: Robert Cox #13191 X ROUTINE COMPLAINT FOLLOW-UP OTHER 7vpe of insyection Collection System Spray Irrigation X Sludge Other Inspection .Summary: (additional comments may be included on attached Cafes The current land application contractor for Cherryville is SYNAGRO. The sludge lagoon (sludge storage) was inspected and appears adequately maintained. Sludge analyses reflect compliance. Land application site NC-LT- 120-02 was flagged appropriately. Trucks had spill plans as required. Please note that Cherryville has monitored for TCLP for well over 5 years and can get this monitoring requirement reduced to once every permit cycle, if requested. See information in monitoring section of the permit. Is a folio necessary _yes X no Inspector(s) Name(s)/Title(s) Ellen Huffman / Env. Specialist Telephone No. 704/663-1699 Fax No. 704/663-6040 Date of Inspection October 6, 2011 Residuals Inspection WQ0000430 Cherryville, Gaston County 10/06/2011 Type of Residual _X Land Application (class B) Distribution and Marketing (class A) Y-yes N-no N/E not evaluated N/A not applicable Record Keeping Y/N N/E Copy of current permit available at residual generating site Y Current metals and nutrient analysis Y TCLP analysis, N/E SSFA (Standard Soil Fertility Analysis) Y Nutrient and metals loading calculations Y Hauling records (# gal and/or ton hauled during calendar year to date) Y Field loading records, Y Field site maps and information N/A Records of lime purchased Y Pathogen & Vector Attraction Reduction N/E Field inspection records pg 2 of 3 Comments- The contractor performs sludge compliance testing and submits an annual report on behalf of the permittee. Plant ORC was not available at the time of inspection for record review, however, sludge analyses emailed to the MRO and reflects compliance. Please note that Cherryville has monitored for TCLP for well over over 5 years and can get this monitoring requirement reduced to once every permit cycle if requested. See information in the monitoring section of the permit. Pathogen & Vector Attraction Reduction (VAR) Records (check which methods apply) X SM 9221 E for pathogens (Alternative 1, fecal monitoring) X Option 3 - 30 day bench scale for VAR Time / Temp records N/A Digester (MCRT) N/A Volatile solids calculations X Treatment (check treatment type(s) used) Anaerobic digestion X Aerobic digestion Transport Spill control plan in transport vehicle? A Does transport vehicle appear to be maintained? Y Condition of land application equipment on site: Equipment appeared to be maintained appropriately. t Residuals Inspection WQ0000430 Cherryville, Gaston County 10/06/2011 Storage (Number of days/weeks/months of storage) 12+ months pg 3 of 3 - Describe storage: Storage is a clay -lined lagoon at the wwtp. The lagoon appears to be adequately maintained. One corner of the lagoon is difficult to mow. Plant staffmake an effort to keep woody vegetation (trees) from growing in that area. Sampling Describe Sampling: Fecal Coliform metals and nutrient sampling and a 30 day bench scale test are taken as grab samples annually by the ORC/land application contractor, from storage prior to land application in accordance with the permit. Is sampling adequate? Yes Is sampling representative? Yes Field Sites (end use for class B biosodids) X Permit on site during application X Buffers adequate N Signs of runoff / ponding N/E Rain Gauge on site during application N/E Y Spill plan on site Y Cover crop specified in permit Y Site condition adequate Sludge off loading area was well maintained. There were no spills or excess ponding noted at the field loading area or in the field application area. Buffers were appropriately flagged. Monitoring well(s) Y/N: N/A If yes, location of well(s) Odors/vectors Odors present: N Vectors present: N L ARRY G. WRIGHT II Plant Supervisor NCDENR Division of Water Quality 1636 Mail Service Center Raleigh, North Carolina 27699-1636 May 18, 2010 City of Chenyville WASTEWATER PLANT 116 South Mountain Street North Carolina 28021 Phone:' (704) 435-1739 FAX: (704) 435-1713 www.cityofcherryville.com Subject: Request minor modification for TCLP analyses. Dear Mr. Ed Hardee, I would like to request a minor modification for TCLP analyses and reduce monitoring from annual to every permit cycle. have enclosed copies of our TCLP analyses. We contract our biosoilds to Synagro, they usually come one time per year and land apply our sludge. We have documentation to support all .if needed. If you have any questions please feel free to contact myself or Cynthia Walters the Lab Supervisor/Backup.ORC. Thanks fright _.._ _upervisor/ORC City of Cherryville Wastewater Treatment Plant (704) 435-1739 -office (704) 214-1162 - cell Iwright@cityofcherryville.com www.citvofcherry.viIle.com LARRY G. WRIGHT 0 Plant Supervisor NCDENR City of Chenyville WASTEWATER PLANT 116 South Mountain Street North Carolina 28021 Phone: (704) 435-1739 FAX: (704) 435-1713 www.cityofrherryville.com Division of Water Quality Mooresville Regional Office 610 East Center Avenue, Suite 301 M!AY 1 9 2010 Mooresville, North Carolina 28115 May 18, 2010 Subject: Response to our inspection Dear Mrs. Ellen Huffman Just wanted to let you know that we have removed the small tree samplings from our sludge lagoon. We have also put out weed killer to kill the weeds growing where we cannot mow due to the steep grade of the berm. It looks much better now. I also mailed Ed Hardee a copy of the signature of authority for this permit. If you have 'any questions please feel free to contact myself or Cynthia Walters the Lab Supervisor/Backup ORC. Thanks-, Larry Wright Plant Supervisor/ORC City of Cherryville Wastewater Treatment Plant (704) 435-1739 -office (704) 214-1162 - cell Iwright cityofcherryville.com www.citvofcherrvville.com NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Governor Director April 20, 2010 Mr. Larry Wright, Cherryville WWTP Supervisor City of Cherryville 116 South Main Street Cherryville, North Carolina 28021 Dee Freeman Secretary C�Py Subject: Non -Discharge Inspection Land Application Program Permit No. WQ00000430 Gaston County Dear Mr. Wright: Enclosed you will find the report for the compliance inspection that was conducted on March 31, 2010 for the subject non -discharge land application permit. There was no land application activity at the time of this inspection. The sludge lagoon (sludge storage) was inspected and appears to be well maintained; however, there is an.area of the lagoon berm with small trees (saplings) growing on it. Tree roots can weaken the integrity of the berm and if not maintained, could lead to failure of the berm. These trees will need to be removed. Sludge land application records were reviewed and reflect compliance. Our database shows that Cynthia Walters is listed as having signature authority for this permit. If this is not correct, please notify Ed Hardee (of the permit writing group) in writing at 1636 Mail Service Center, Raleigh, NC 27699-1636. Please state who is to be listed as having this authority for the City. The report. should be self-explanatory but should you have_ any questions regarding this inspection, please call me at 704/235-2186. Sincerely, Lan' {, Environmental Specialist Attachment cc: Scott -Berg, SYNAGRO Ed Hardee, LAU Residuals Program Coordinator MRO files Division of Water Quality / Aquifer Protection Section / Mooresville Regional Office 610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 Phone: 704-663-16991 Fax: 704-663-60401 Customer Service:1-877-623-6748 Internet: www.ncwaterquality,org NorthCarolina An Equal opportunity 1 Affirmative Action Employer LARRY G. WRIGHT 11 Plant Supervisor NCDENR Division of Water Quality 1636 Mail Service Center Raleigh, North Carolina 27699-1636 May 18, 2010 Subject: Signature of Authority Dear Mr. Ed Hardee, City of Chmyville WASTEWATER PLANT 116 South Mountain Street North Carolina 28021 Phone: (704) 435-1739 FAX (704) 435-1713 www.cityofcherryville.com Please find the enclosed copy of the ORC designation form and signature of authority signed by Our City manager Mr. David Hodgkins. faxed this information to Scott Berg with Synagrow on September 30, 2009. If you have any questions please feel free to contact myself or Cynthia Walters the Lab Supervisor/Backup.ORC. runt Supervisor/ORC City of Cherryville Wastewater Treatment Plant (704) 435-1739 -office (704) 214-1162 - cell lwriqht0,cityofcherr\/vi1le.com www. cityofcherrVvi I le. com- cc Ellen Huffman L. yrcn. rvr •• • —� Water Pollution Control System Operator Designation For wPCSOCC NCAC 15A 8G .0201 p Permittee Owner/Officer Name: L. 4 nnY� ae w L [�&,tt 4n 1Vlailing Address: ,!/ 6 5. NAII GN �T• g City: F tt State: /�� Zip: - Phone #: (7 ) Xi 4! 34? Signature: /i Date- l Z" 1 9^y q ............ .................... ............................. ................................................................................. Facility -Name: Permit 1 SUBMIT A SEPARATE FORM FOR EACH TYPE OF SYSTEM 1 Facility Type & Grade: Dye Grade Type Grade Biological WWTP Surface Irrigation N/A Physical/Chemical Land Application N/A Collection System Operator in Responsible Charge (ORC) Print Full Name: 5a 7-1— Z). Certificate Type / de / Number: eA 0?9,�3 L Woirk Phone #: ( ) M " 716-0 Signature: Date: �s2� "I certify that I agree to my designation as the perator in Responsible Charge for the facility noted. I understand and will abide by the rules and regulations pertaining to the responsibilities of the ORC as set forth in 15A NCAC 08G .0204 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission." .............................................................................................................................................. Barb -Up Operator inQResponsible Charge (BU ORC) Print Full Name: oA &t &X Certificate Typft/)GrradAl Number: LiQ IM? Work Phone #: 11 /B'o?�'� Date: 1-2 'I certify that I agree to my designation as a Back-up Operator in Responsible Charge for the facility noted. I understand and will abide by the rules and regulations pertaining to the responsibilities of the 13U ORC as set forth in 15A NCAC 08G .0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission" ................................................................................................................................................ Mail or Fax to: WPCSOCC 1618 Mail Service Center Raleigh, NC 27699-1618 Fax: 919/733-1338 (See next page for designation of additional back-up operators. Designation of mare than one back-up operator is opriwral.) Revised 8-2007 - Water Pollution Control System Operator WPCSOCC NCAC 15A 8G .0201 Permittee Owner/Officer Name: C i y A Designation F vpM frlr�gh'r' !/ Mailiulg Address: I r (A IS M OU IO t ' n _ v City: Signature: Phone #: (76q) q 35 — i'739 . Date: 9 _'30 — D I ................................................................ a . . . . . . . . . . . . . . . Facility Name: (J e_yrVtl,ite WAS�ewA rI Y'�cclmeA+ 9[ 1R� Permit#: NC Q_0 tH-4 t ! SUBMIT A SEPARATE FORM FOR EACH TYPE OF SYSTEM! Facility Type & Grade: iological WWTP P ysic emtcal Collection System Type Grade W W _^ Surface Irrigation Land Application Type County: G. A C`C0 PA Grade N/A N/A ...................................................................................................................... 0....................... Operatorin Responsible Charge (ORC) + , Print Full Name: L0 rry W &?_11 e_ r 1 qNn Certificate Type /,qrade / Number: w W : S Work Phone #: (170q ) Date: q ,�> © — "I ce� I agree to my designation as the Operator in lt-e pulnAle Charge for the facility noted, l understand and will abide by the rule regulations pertaining to the responsibilities of the ORC as set forth in 15A NCAC 08G .0204 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission." ................................................................................................................................................ Back -Up Operator in Responsible W Charge 1(BU+ORC) Print Full Name: Qn-OKIA A -- e lrS Certificate Type Grade /Number: iNW 2 ��o Work Phone #: (70 1 43S - 1''l -3 q Signature: �7� Date: 30440,7 "I certify that I agree to my designation as a Back-up Operator in Responsible Charge for the facility noted. I understand and will abide by the rules and regulations pertaining to the responsibilities of the BU ORC as set forth in 15A NCAC 08G .0205 and failing to do so, can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission," •..............u:u...... .......................ou...................................uuu...............u.........ou................ Mail or Fax to: WPCSOCC 1618 Mail Service Center Raleigh, NC 27699-1618 Fax:919/733-1338 (See next page for designation of additional back-up operators. Designation of more than one back-up operator is optional.) Revised 8-2007 City o Chenyville 116 South Mountain Street NORTH CAROLINA 28021 Phone: (704) 435-1710 FAX (704) 435-1707 OFFICE OF CITY MANAGER September 30 2009 To Whom It May Concern: I, David P. Hodgkins, City Manager for the City of Cherryville authorize Larry Gene Wright II as Permittee and ORC of the Cherryville Wastewater Treatment Plant as of October 1, 2009. If you have any questions or I may be of any further assistance to you please feel free.to contact me at 704-435-1711. Regards, i David P. Hodgkins City Manager r !I A4jp A WDENR F I L E North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Governor Director Dee Freeman Secretary April 20, 2010 Mr. Larry Wright, Cherryville WWTP Supervisor City of Cherryville 116 South Main Street Cherryville, North Carolina 28021 Subject: Non -Discharge Inspection Land Application Program Permit No. WQ00000430 Gaston County Dear Mr. Wright: Enclosed you will find the report for the compliance inspection that was conducted on March 31; 2010 for the subject non -discharge land application permit. ._, There was no land application activity at the time of this inspection. The sludge lagoon (sludge storage) was inspected and appears to be well maintained; however, there is an.area of the lagoon berm with small trees (saplings) growing on it. Tree roots can weaken the integrity of the berm and if not maintained, could lead to failure of the berm. These trees will need to be removed. Sludge land application records were reviewed and reflect compliance. Our database shows that Cynthia Walters is listed as having signature authority for this permit. If this is not correct, please notify Ed Hardee (of the permit writing group) in writing at 1636 Mail Service Center, Raleigh, NC 27699-1636. Please state who is to be listed as having this authority for the City. The report should be self-explanatory but should you have any questions regarding this inspection, please call me at 704/235-2186. Attachment cc: Scott Berg, SYNAGRO Ed Hardee, LAU Residuals Program Coordinator MRO files Division of Water Quality / Aquifer Protection Section / Mooresville Regional Office 610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 Phone: 704-663-16991 Fax: 704-663-60401 Customer Service: 1-877-623-6748 Internet: www.ncwaterquality.org Sincerely, Ellen Huffman J Environmental Specialist NorthCarolina An Equal Opportunity 1 Affirmative Action Employer a State of North Carolina Department of Environment and Natural Resou "ces Division of Water Quality Beverly Eaves Purdue, Governor Dee Freeman, Secretary Coleen H. Sullins, P.E. Director A ffl:*!W'A NCDENR NON -DISCHARGE COMPLIANCE INSPECTION City/Town/Owner: Cherryville Permit No.: WQ0000430 Last Amended Date: N/A SOC Issuance Date(if applicable): N/A Permittee Contact: Larry Wright ORC Name: Scott Bera ORC Cert.#: LA 922731 Reason for Inspection GENERAL INFORMATION County: Gaston Issuance Date: 08/30/2006 Expiration Date: 07/31/2014 Expiration Date: N/A Telephone No.: 704/ 435-1700 Telephone No.: 336-766-0328 B/U ORC: Robert Cox 913191 X ROUTINE COMPLAINT FOLLOW-UP OTHER Type of inspection Collection System Spray Irrigation X Sludge Other Inspection Summary: (additional comments may be included on attached pages) The current land application contractor for Cherryville is SYNAGRO. There was no land application occurring at the time of this inspection. The sludge lagoon (sludge storage) was inspected and appears well maintained. There was only one area of the lagoon berm that has small tree saplings growing on it. Tree roots can cause weakness and possible failure of the berm and will need to be removed. Sludge land application records were reviewed and reflect compliance. It was noted that plant personnel are very conscious of keeping the supernatant pumped off of the sludge storage lagoon keeping plenty of freeboard space available in case of heavy rains. Is a necessary des X no Inspector(s) Name(s)/Title(s) Ellen Huffman / Env. Specialist Telephone No. 704/663-1699 . Fax No. 704/663-6040 Date of Inspection March 31, 2010 le Residuals Inspection WQ0000430 Cherryville, Gaston County 03/31/2010 Type of Residual X Land Application (class B) Distribution and Marketing (class A) Y-yes N-no N/E not evaluated N/A not applicable Record Keepin-- Y/N Y Copy of current permit available at residual generating site Y Current metals and nutrient analysis (see permit for frequency) Y TCLP analysis, Y SSFA (Standard Soil Fertility Analysis) Y Nutrient and metals loading calculations YTD Y Hauling records (# gal and/or ton hauled during calendar year to date) Y Field loading records, Y Field site maps and information N/A Records of lime purchased Y Pathogen & Vector Attraction Reduction N/E Field inspection records pg 2 Comments- The contractor performs compliance testing and submits an annual report on behalf of the permittee. Those records were reviewed at the wastewater treatment plant office. The permit (Section III, item 4) requires that compliance monitoring data be maintained on file by the permittee for a minimum of five (5) years. Pathogen & Vector Attraction Reduction (VAR) Records (check which methods apply) X SM 9221 E for pathogens (Alternative 1, fecal monitoring) X Option 3 - 30 day bench scale for VAR Time / Temp records N/A Digester (MCRT) N/A Volatile solids calculations X Treatment (check treatment type(s) used) Anaerobic digestion X Aerobic digestion Transport N/A Spill control plan in transport vehicle? N/E Does transport vehicle appear to be maintained? N/E Condition of land application equipment on site: N/E 0 Residuals Inspection pg 3 WQ0000430 Cherryville, Gaston County 03/31/2010 Storage (Number of days/weeks/months of storage) 12+ months Describe storage: Storage is a clay -lined lagoon at the wwtp. The lagoon appears to be well maintained, however, there are a few small trees growing on one corner that will need to be removed. Sampling Describe Sampling: Fecal Coliform, metals, and nutrient sampling, and a 30 day bench scale test are taken as grab samples annually by the ORC/land application contractor, from storage prior to land application in accordance with the permit. Is sampling adequate? Yes Is sampling representative? Yes Field Sites (end use for class B biosolids) N/E Permit do site during application Buffers adequate Documented exceedances of PAN limits Signs of runoff / ponding Rain Gauge on site during application Monitoring well(s) Y/N: N/A If yes, location of well(s) Odors/vectors N/E Odors present: Vectors present: Spill plan on site Cover crop specified in permit Site condition adequate Google Maps fyY % L Notes Cherryville wwtp A. City of Cherryville Wastewater Plant 736 Tot Dellinger Road, Cherryville, NC, NC (704) 435-1739 Page 1 of 1 http://maps.go6gle.comlmaps?hl=en&ie=tJTF 8&q=Cherryville+kwastewater+treatment+pl 10/6/2011 Google Maps Page 1 of 1 m Notes Cherryville wwtp - 182} y Dace F(e fib. v 182 } . Qa ' arnef 2T4 &.or } Crouse Ra b e 159 yC s � Croyyuse''` ' ♦ ,ram �0 T t S 15oIr Dellview 2T9 *� I54 t '+ro- �s, Cherryviile , � 279A. s kko Ap 274 2T9 a ©2011 Goo le - Map data ©2011 Goo A. City of Cherryville Wastewater Plant 736 Tot Dellinger Road, Cherryville, NC, NC (704) .435-1739 http://maps.google.comlmaps?hl=en&ie=UTF8&q=Cherryville+wastewater+treatment+pl... 10/6/2011 SYNAGOO, A Residuals Management Company August 22, 2008 Ellen Huffman NCDENR-LAU Mooresville Regional Office 610 East Center Ave. Mooresville, NC 28115 Dear Mrs. Huffman: D Er�C AUG 2 5 2008 On August 18"', I called to inform you of an application event on site NC-LT-120-2 that had been flagged incorrectly with respect to an on -site well buffer on the southern most portion of the field that had been discovered by Synagro staff while conducting an internal compliance inspection. This letter is to serve as the required written notification and report for that event. On Friday, August 151h, the Synagro Technical Services Manager (TSM), while conducting an internal compliance inspection on the field and operations crew, discovered that a buffer area on the southern portion of the field had been flagged incorrectly. The TSM immediately placed the flags in their correct position (using a laser rangefinder). Upon doing so, it was discovered that a small portion (approximately 50' x 40') had been applied by the Synagro Field Manager (FM), who was on -site. The Synagro Operations Manager (OM) had flagged the field prior to the event and misinterpreted the map with respect to the buffer at the southern.portion of the field. The TSM observed that all other buffers were marked and measured correctly. According to the landowner, the on -site house has county water and the well in question has not been used for human consumption for many years. Based on my evaluation of the situation, the OM mistakenly overlooked the well buffer shown on the map, and did not make a conscious decision in the field to ignore the buffer. The fact that the well is not in use currently provides some relief in the fact that, in the event material is transported the 200' to the well head, that no adverse public impacts are expected. Due to this event, the importance of the buffer maps has been emphasized to the OM by the Synagro Technical Services Director (TSD). He has been instructed that all buffers listed on the map are to be verbally discussed with the TSM prior to spreading the field. In the meantime, the TSM has taken a rfivr­_ aGiZVE: rvic i0:1 field selection and flac7 ing while the OM beconila es railiar with these new requirements. The level of involvement from the TSM in this project will continue to be high in order to alleviate any compliance issues in the future. If you have any questions or require any additional information for your evaluation of this situation, please let me know. Sincerely, Todd E. Shearin Technical Services Director Cc: Cynthia Walters, City of Cherryville Attachments: Application Map (NC-LT-120) 284 Boger Road • Mocksville, NC 27028-7619 • Ph: (336) 998-7150 . Fax: (336) 998-8450 • Toll Free: (877) 267-2687 -0,101 SMGI\O APPLICATION AREA MAP d n__.,_ ,. Owner W,4 Y.y,--- iUC zT-. /ZD} Scale: Field # +A f Total Acres a Net Acres ee sK�r.tra 6 A� . . > STREAM APPLICATION AREA — — — — — - PRIVATE ROAD • > CD DRAIN SURFACE WATER ■ HOUSE. FORESTED AREA 0 OUTBUIL_ DING UNSUITABLE i�---C—^E-- FENCE 0 WELL STORAGE AREA Q SOIL 'DESCRIPTION SUITABLE FOR PROPERTII LINE ® INCORPORATION, 8-12% SLOPE 523 958 401 US Postal Service Receipt for Ceftified hfiai: No Insurance Coverage Provided. nn not use for International Mail (See reverse) Sent to gob Shull Cit of Cherryville Street & Numberl5 6. Mountain ST . Post Office, State, & ZIP Code Cheryville NC 280 Postage s CERTIFIED MAIL RETURN RECEIPT Mr. Bob Shull City of Cherryville 116 South Mountain Street Cherryville, NC Dear Mr. Shull: LTC! 'T4 1 0 in ent Dr Ann ,CDEN NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES UEST.ED mEy 17, 1999 Subject: NVotrceof_Deficienc',y . tiCir<`ofCherrvville Permit Number: WQ0000430 Land Application of Biosolids Gaston County The Non Discharge Compliance / Enforcement Unit has conducted a preliminary review of the submitted 1998 Annual Report of land application activities. You are hereby notified that you are in non-compliance with permit requirement I. 11. which requires that land applied biosolids meet 40 CFR 503.33. The reported S'QUR was not performed as per the Standard Method (Am. Pub. Health Assoc. 1992). This Method requires that the sample percent solids be lessrthan_o er qual-to ? 0� Your submitted reporting shows that the percent solids of the sample taken was 2.37. If you have any questions regarding this Notice of Deficiency, please do not hesitate to call Kevin Barnett of our central office staff at 919-733-5083 ext. 529. Nothing in this letter should be taken as removing from you the responsibility or liability for failure to comply with all applicable state laws and regulations. Sincerely, D. Rex Gleason, P.E. Mooresville Water Quality Supervisor cc: Non -Discharge Compliance / Enforcement Unit Non -Discharge Permitting Unit Mooresville Regional Office Technical Assistance and Certification Unit Central Files P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 Fax 919-715-6048 An Equal Opportunity Affirmative Action Employer 50% recycled/10% post -consumer paper State of North Carolina Department of Environment and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Wayne McDevitt, Secretary Kerr T. Stevens, Director CERTIFIED MAIL RETURN RECEIPT REQUESTED Mr. Bob Shull City of Cherryville 116 South Mountain Street Cherryville, NC Dear Mr. Shull: ILI�A T W Owl-% 00000M.% 000ft NCDENFt NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES Nay 17, 1999 Subject: Notice of Deficiency City of Chenyville Permit Number: WQ0000430 Land Application of Biosolids Gaston County The Non Discharge Compliance / Enforcement Unit has conducted a preliminary review of the submitted 1998 Annual Report of land application activities. You are hereby notified that you are in non-compliance with permit requirement I. 11. which requires that land applied biosolids meet 40 CFR 503.33. The reported SOUR was not performed as per the Standard Method (Am. Pub. Health Assoc. 1992). This Method requires that the sample percent solids be less than or equal to 2.0. Your submitted reporting shows that the percent solids of the sample taken was 2.37. If you have any questions regarding this Notice of Deficiency, please do not hesitate to call Kevin Barnett of our central office staff at 919-733-5083 ext. 529. Nothing in this letter should be taken as removing from you the responsibility or liability for failure to comply with all applicable state laws and regulations. Sincerely, D. Rex Gleason, P.E. Mooresville Water Quality Supervisor cc: Non -Discharge Compliance / Enforcement Unit Non -Discharge Permitting Unit _-- - __ __ _ _ __ -- ____ Mooresville Regional Office + Technical Assistance and Certification Unit �Z 523 958 401 Central Files US Postal Service Receipt for Certified Mail No Insurance Coverage Provided. no not nsa for Intamatinnal Mail /See reverse) Sent to Bob City Shull of Cherr ville Street&Numbfrl5 S. Mountain ST. Post Office, State, &.ZIP Code Cher ville NC 280 Postage s P.O. Box 29535, Raleigh, North Carolina 27626-0535 An Equal Opportunity Affirmative Action Employer I I Telephone 919-733-5083 Fax 919-71.5-6048 50% recycled/10% post -consumer paper 435 Williams Court, Suite 100 Baltimore, NM 21220 wwwsynagro.com FEBRUARY 21, 2020 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2019 Annual Report for Permit No. WQ0000430 cc Dear NCDEQ: �S0r\0ge� Synagro is submitting one copy and one electronic copy of the above referenced report on behalf of the City of Cherryville, NC. RECEIVEI?IN CbEN R!®WIR NiAR -- 2 2020 WQROS MOORESVILLE REGIONAL OFFICE If you have any questions or need additional information, please do not hesitate to contact Larry Wright at (704) 435-1739 or Alex Fox at (336) 703-8681. Sincerely, h Derrick Shivar Environmental Compliance Manager Enclosures cc: Larry Wright, City of Cherryville Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2019 ANNUAL REPORT City of Cherryville, NC Residuals Land Application Program 2019 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen ReductionNector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: WO0000430 County Gaston Year 2019 Facility Name (as shown on permit) City of Cherryville WWTP NPDES No. NC0044440 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 7 Total number of fields utilized for land application during the year: 1 Total amount of dry tons applied during the year for all application sites: 68.8 Total number of acres utilized for land application during the year: 17 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2019 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T . 1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .I I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." A_ Larry Wright. Plant ORC & Plant Supervisor Permittee Name and Tit t3 • rint) S a re of reparer* Date different orn Permi ee) (if different frorrVermittee and �.'7• 2®2O Date Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2019 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC CHERRYVILLE, NC CHERRYVILLE, NC LIQUID DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS August 2019 365,800.00 G 68.80 D 62.40 YEARLY TOTAL 365,800.00 G 68.80 D 62.40 1 /30/2020 SECTION 2 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: W00000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 05/14/19 Date Composited Percent Solids 4.51 PARAMETERS (mg/kg dry weight) Arsenic <5 Cadmium 2.57 Mercury 2.15 Chromium 147 Copper 996 Lead 34.7 Molybdenum 8.44 Nickel 70.8 Selenium <5 Zinc 897 Total Phosphorus 12900 TKN 31800 Ammonia -Nitrogen 4220 Nitrate and Nitrite ; , 195 Laboratory Waypoint Analytical Virginia Inc. law, that this document was prepared under my direction or supervision in accordance with a system ialified personnel properly gathered and evaluated the information submitted. I am aware that there are F^1sei€v a ion, i ing the possibility of fines and imprisonment for knowing violations." Date 2 - / 2. o 2 O Printed: Wednesday - February 5, 2020 at 12:55:08 for: 2008 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 05/14/19 Date Composited Percent Solids 4.51 PARAMETERS (mg/kg dry weight) Aluminum 16500 Calcium 7590 Magnesium 2230 pH 6.70 Potassium 1700 Sodium 833 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel r athered and evaluated the information submitted. I am aware that there are significant penalties for submitting falsg4lof rraotion, indtt<ing the possibility of fines and imprisonment for knowing violations." 1 / \PREPA EF Not Requ Date z - r - 2 o zo _Printed: Wednesday - February 5, 2020 at 12:55:29 for: 2008 01 ;G Waypol�t. ANALYTICAL 5/24/2019 Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 19-136-0211 Project Description: Cherryville WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointantlytica l.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 5/16/2019 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, &a. P 0-7- Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Virginia 460014 Page 1 of 6 a • WP ��� ' 7621 Whitepine Road, Richmond, VA 23237 y Main $04-743-9401 ° Fax 804-171-6446 ANALYTICAL www.waypoint8nalytical.com Sample Summary Table Report Number: 19-136-0211 Client Project Description: Cherryville WWTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 66425 Cherryville WWTP Solids 05/14/2019 11:00 05/16/2019 WTN: Waypoint Analytical - TN, Memphis, TN, Certification: #1354 SM-4500-NH3C WTN 9045D WTN 4500NO3F-2011 WTN 6010D WTN SW-7471B WTN SM-4500-NH3C-TKN WTN SM-2540G WTN Page 2 of 6 Ref lumber: 19-136-0211 Account (dumber: 46442 Send To: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville , NC 27028 Waypoi t(D ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project: Cherryville WWTP REPORT OF ANALYSIS Date Sampled: 5/14/2019 11:00:00 Lab Number: 66425 Date Received: 05/16/2019 00:00 Sample Id : Cherryville WWTP Date Reported: 05/24/2019 Total Solids " Moisture * Total Kjeldahl Nitrogen Phosphorus Potassium Sulfur Calcium Magnesium Sodium Iron Aluminum Manganese Copper Zinc Ammonia Nitrogen Organic N Nitrate+Nitrite-N 4.51 95.50 3.18 1.29 0.17 0.79 0.76 0.22 0.08 0.42 2.76 31800 12900 1700 7880 7590 2230 833 28300 16500 443 996 897 4220 27580 195 250 50.0 50.0 50.0 250 50.0 250 50.0 50.0 5.00 2.50 12.5 100 250 4.71 ADM ADM CLP KKM KKM KKM KKM KKM KKM KKM KKM KKM KKM KKM ZBD ZBD 05/21/2019 16:54 05/21/2019 16:54 05/23/2019 13:30 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/21/2019 23:43 05/23/2019 16:00 05/23/2019 13:30 05/22/2019 13:46 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B-Analyte detected in blank H - Beyond Holding Time Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other_public announcements without obtaining our prior written authorization. SM-2540G SM-2540G SM-4500-NH3C-TKN 6010D 6010D 601OD 6010D 6010D 6010D 6010D 6010D 6010D 6010D 6010D SM-4500-NH3C CALCULATION 4500NO3F-2011 Pauric McGroary Agronomist Page 3 of 6 Rel lumber: 19-136-0211 Account Number: 46442 Send To: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville , NC 27028 Waypoi t(D ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project: Cherryville WWTP REPORT OF ANALYSIS Date Sampled: 5/14/2019 11:00:00 Lab Number: 66425 Date Received: 05/16/2019 00:00 Sample Id : Cherryville WWTP Date Reported: 05/24/2019 cadmium 2.57 1.00 KKM 05/21/2019 23:43 6010D Chromium 147 2.50 KKM 05/21/2019 23:43 6010D Nickel 70.8 2.50 KKM 05/21/2019 23:43 6010D Lead 34.7 3.00 KKM 05/21/2019 23:43 6010D Arsenic <5.00 5.00 KKM 05/21/2019 23:43 601 OD Mercury 2.15 0.0143 TJS 05/22/2019 12:37 SW-7471 B Selenium <5.00 5.00 KKM 05/21/2019 23:43 601OD pH * 6.7 JSL 05/21/2019 08:40 9045D Molybdenum 8.44 2.50 KKM 05/21/2019 23:43 6010D Comments: All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B - Analyte detected in blank H - Beyond Holding Time �f�G � Gew� Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made Pauric McGroary to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Agronomist Page 4 of 6 s Way nt . PA Customer Number: 46442 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Cooler Receipt Form Customer Name: Synagro Central LLC/ Cherryville Report Number: 19-136-0211 Shipping Method 0 Fed Ex 0 US Postal 0 Lab UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 40 Yes 0 No Number of coolers received 1 Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Required Custody seals intact on sample bottles? 0 Yes 0 No Not Required Chain of Custody (COC) present? 4D Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed ID Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? is Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 10 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No N/A F_ High concentration container (48 hr) F_ Low concentration Encore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes 0 No Comments: Signature: lBrandi Watson Date & Time: 05/16/2019 13:46:49 Page 5 of 6 SAMPLING LOG # ��, IIIIIIIIIIIIIIIIIIIIINIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII Synagro 91 ABS, INC. �( ®��® CUSTODY �W ��p Central LLC! Chermille 6� 0 CUSTOMER: SY11iQAGRO ChUrWille WVVTP 13:44:33 RECORD PROJECT MANAGER: ast that the proper field sampling procedures were used during the collection of these samples. (' } '(fib tlolU- Phone: SAMP A & L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAB #f SAMPLE I.D. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED Clrrti��lle �1v� ,�-r2 l a & e��.-� S/I `� L� e� ► C 6-- Coo i fit" Relinquished by Sampler: w Relinquished by: a, o Relinquished by: r„ SPECIAL INSTRUCTIONS: tte Time S Z�GG _jDate, Time Wk- 5 For �"' monitoring purposes. Time Recleved by: ved by: Recleved by: PO#: REMARKS: SAMPLE ANALYSIS REQUEST SLI SL2 NH4-N NO3 N Organic N Cd Ce Ni Pb As H Se pH CaCO3 equty. Volatile Solids Mo Cl NO N JAW 1,0 no n:0R4110 koo,,0 no PO ,,�0 r zi!-u. imal zDonas W101sture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date ReportRange Ratio 2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 5/14/2019 111/2019-12/31/2019 0.4575 Na mg/I = (Na mg/kg x % Solids) _ 100 = (833 x 4.5100) + 100 = 37.5683 Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (7590 x 4.5100) _ 100 = 342.809 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (2230 x 4.5100) _ 100 = 100.573 Na meq = Na mg/I _ Molec.Wgt.Na = 37.5683 + 23 = 1.6334 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 342.309 _ 20 = 17.1155 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 100.573 _ 12 = 8.38108 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 1.6334 _ SgrRoot[0.5(17.1155+8.38108)] = 0.457476 Printed: 2/5/2020 Page 1 12:59 SECTION 3 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: CHERRYVILLE, NC PREDOMINANT SOIL SERIES: CECIL OWNER: CALVIN WEHUNT PERMIT #: W00000430 ANNUAL DRY TONS APPLIED: 68.80 SITE #: NC LT 00107 FIELD# : LT 00107 0003 OPERATOR: CALVIN WEHUNT CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S): See list at bottom of report ACRES UTILIZED: 17.00 ACRES PERMITTED: 17.00 Page Lime Applied *** Date Lbs//Ac DATE or MONTH Gallons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry, Tons per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop Total I Per Acre Acre Source Moist Hours * Rate** Rate Nitrite 8/19/19 99,200.00 (G) 5835.294 4.51 1.097 CHL DRY 0-<1/2" SUR 0.5 0.30 31,800. p 4,220.00 p 195.00 p 10579 SORGHUM/SUDAN HAY 8/21/19 204,600.00 (G) 12035.294 4.51 2.263 CHL MOIST 0-<1/2" SUR 0.5 0.30 31,800. p 4,220.00 p 195.00 p 10579 SORGHUM/SUDAN HAY 8/22/19 62,000.00 (G) 3647.059 4.51 0.686 CHL DRY 0-<1/2" SUR 0.5 0.30 31,800. p 4,220.00 p 195.00 p 10579 SORGHUM/SUDAN HAY Aug-19 365,800.00 (G) 21,517.647 Total Gallons/Ac: Total Wet Tons/Ac: 21,517.65 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annual lbs/acre 86 0.040 0.021 1.190 8.061 0.281 0.017 0.068 0.573 0.040 7.260 104.41 Cumulative lbs/acre 0.040 0.021 1.190 8.061 0.281 0.017 0.068 0.573 0.040 7.260 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop --------- --___ 221 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 1 375.0 89.0 2500.0 �A CHL = CHERRYVILLE, NC LIQUID 0 �)k x b4 !�e, � - 7- JO 2o (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = pp- or mg/kg ** Volatilization Rate : Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 SECTION 4 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. € :Sfli?OfJPa3=?1TAL ct tiA±QLt3G1�$. IP40 Cuyahoga Falls, Ohio 44223 An3rM; cvl L2ba'alorlag TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://wlvw.settek.com June 05, 2019 Erik Bruce Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Cherryville WWTP Dear Erik Bruce: Order No.: 19051264 Summit Environmental Technologies, Inc. received 1 sample(s) on 5/16/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, Califomia 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH00923201 I - 1, Virginia VELAP 9456, Washington C891 Page 1 of 35 Summit Environmental Technologies, Inc. Case Narrative IMSUMMIT 3310 Win St. Eiik(VIRi7AlFa1EMUL _S`d-CHN0LQ iF_%, WC. Cuyahoga Falls, Ohio 44223 WO#: 19051264 A rr i tprlc€l ? aboralarlQi1g TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: hito:llivww.settek.com Date: 6/5/2019 _LIENT: Synagro Project: Cherryville WWTP WorkOrder Narrative: 19051264: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible Dr use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 19051264-OOIA TCLP-SVOC_8270E: The CCV (Batch R98606) exhibited high recovery of 2,4- Dinitrotoluene. The associated samples are ND for 2,4-Dinitrotoluene. 19051264-OOIA TCLP-SVOC-CPest(8081B): CCV exhibited high recoveries for Endrin. Associated samples were ND Revision vl Page 2 of 35 Summit Environmental Technologies, In Qualifiers and Acronyms summlor 3310 Win b 1-141(Ir±0WaEt4T,n.L. Ti=c* mDLr)r,;i<S, iF4r, Cuyahoga Falls, Ohio 442� WO#: 19051264 Ana' ytleat Labarworle TEL: (330) 253-8211 FAX.- (330) 253-446 Website: httn:11www.settek.co Date: 6/5/2019 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. x The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1.`1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Revision vl Page 3 of 35 TdWK M Summit Environmental Technologies, Inc. Workorder 3310 Win St. Pic. Cuyahoga Falls, Ohio 44223 Sample Summary At%fr,�ICt O l:ahttraforflas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http:lAvww.settek,.com 05-Jun-19 CLIENT: Synagro Project: Cherryville WWTP Lab SampleID Client Sample ID 19051264-001 Cherryville WWTP Tag No Date Collected 5/14/2019 11:00:00 AM Date Received Matrix 5/16/2019 10:20:00 AM Sludge Page 4 of 35 Summit Environmental Technologies, Inc. DATES IR 'ORT M-IUMMIT 3310Win St. 1=6V inom?.1r:NT.AL ��CHWQLOGiZ5,1ffJC. Cuyahoga Falls, Ohio 44223 Anifytical Labora8raxl'cas TEL (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http://Www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 19051264-OOIA Cherryville WWTP 5/14/2019 11:00:00 AM Sludge Ignitability of Solids (SW-846: 1030) 6/3/2019 5:55:23 PM pH (SW9045D) Reactive Cyanide (9014/7.3.3.2)-Solid 5/31/2019 3:40:31 PM 5/17/2019 8:10:00 PM Reactive Sulfide (9034)/7.3.4.2 5/17/2019 8:10:00 PM SVOC SW-846: 8151 Herbicides-TCL5/18/2019 6:00:00 PM 5/24/2019 2:15:00 PM 6/1/2019 8:31:00 AM TCLP Mercury Analysis (SW131 in475/18/2019 6:00:00 PM 5/20/2019 2:35:00 PM 5/20/2019 6:58:00 PM TCLP Metals Analysis (SW1311/6010'5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 8:27:03 PM TCLP Metals Analysis (SW1311/6010.5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 4:04:46 PM TCLP Pesticides Analysis (SW1311/8(5/18/2019 6:00:00 PM 5/24/2019 1:00:06 PM 5/31/2019 11:17:00 PM TCLP Semi-Volatiles Analysis 5/18/2019 6:00:00 PM 5/20/2019 1:00:00 PM 5/21/2019 3:47:00 PM (SW 1311/8270) TCLP Volatiles Analysis 5/18/2019 6:00:00 PM 5/20/2019 5:32:00 PM Revision vl Page 5 of 35 Summit Environmental Technologies, Inc. 3310 Win St. Analytical Report Ensummilu s=r:�lii?�t�P1=t•3TP�.L$iC�i�34'Jl.ft{;355. INC Cu aho a Falls, Ohio 44223 gY Amarriytical Laborarerw TEL: (330) 253-8211 FAX.- (330) 253-4489 (base report) WO#: 19051264 Website: http://www.settek.com Date Reported: 6/5/2019 'LIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM Lab ID: 19051264-001A Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW7470A SW7470A Analyst: DNS TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.00500 mg/L 1 5/20/2019 6:58:00 PM TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW6010D SW3010A Analyst: KMO TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND 1.25 mg/L 1 5/22/2019 4:04:46 PM TCLP Barium(Ba) ND 12.5 mg/L 1 5/22/2019 4:04:46 PM TCLP Cadmium(Cd) ND 0.250 mg/L 1 5/22/2019 4:04:46 PM TCLP Chromium(Cr) ND 0.500 mg/L 1 5/22/2019 4:04:46 PM TCLP Lead(Pb) ND 1.25 mg/L 1 5/22/2019 8:27:03 PM TCLP Selenium(Se) ND 0.125 mg/L 1 5/22/2019 4:04:46 PM TCLP Silver(Ag) ND 1.25 mg/L 1 5/22/2019 4:04:46 PM CLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8270 SW3510C Analyst: BJH TCLP SEMI-VOLATILES ANALYSIS (SW131118270) 1,4-Dichlorobenzene ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM 2,4,5-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM 2,4,6-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM 2,4-Dinitrotoluene ND 0.0400 QC+ mg/L 2 5/21/2019 3:47:00 PM Cresols, Total ND 4.00 mg/L 2 5/21/2019 3:47:00 PM Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 5/21/2019 3:47:00 PM Hexachlorobenzene ND 0.0400 mg/L 2 5/21/2019 3:47:00 PM Hexachloroethane ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM Nitrobenzene ND 0.0800 mg/L 2 5/21/2019 3:47:00 PM Pentachlorophenol ND 0.200 mg/L 2 5/21/2019 3:47:00 PM Pyridine ND 0.200 mg/L 2 5/21/2019 3:47:00 PM Surr: 2-Fluorophenol 53.3 10 - 109 %Rec 2 5/21/2019 3:47:00 PM Surr: Phenol-d6 64.7 10 - 109 %Rec 2 5/21/2019 3:47:00 PM Surr: Nitrobenzene-d5 49.6 19 - 120 %Rec 2 5/21/2019 3:47:00 PM Surr: 2,4,6-Tribromophenol 96.5 10 - 120 %Rec 2 5/21/2019 3:47:00 PM Surr: 2-Fluorobiphenyl 49.4 22 - 117 %Rec 2 5/21/2019 3:47:00 PM Surr: p-TerphenylA14 85.9 34 - 116 %Rec 2 5/21/2019 3:47:00 PM Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Revision v1 RL Reporting Detection Limit U Samples with CaleVa1 < MDL Page 6 of 35 summeir Sunsnsit Environnsental Technologies, Inc. 3310 Win St. Analytical Report 1 ra4lli?CStJPs7cA1T�° L0��t 0 3P, gPd4 Cuyahoga Falls, Ohio 44223 (base report) - - -- Alm tlnlcal Laborarones TEL: (330) 253-8211 FAX- (330) 253-4489 WO#: 19051264 Website: hitp:llwww.settek.coni Date Reported: 6/5/2019 'LIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM Lab ID: 19051264-001A Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8081 SW3510C Analyst: SFG TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.0250 mg/L 10 5/31/2019 11:17:00 PM Toxaphene ND 0.0500 mg/L 10 5/31/2019 11:17:00 PM Endrin ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM gamma-BHC ND 0.00500 d mg/L 10 5/31/2019 11:17:00 PM Heptachlor ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM Heptachlor epoxide ND 0.00500 mg/L 10 5/31/2019 11:17:00 PM Methoxychlor ND 0.00500 d mg/L 10 5/31/2019 11:17:00 PM Surr: TCMX 61.7 10 - 119 %Rec 10 5/31/2019 11:17:00 PM Surr: DCB 76.7 10 - 119 %Rec 10 5/31/2019 11:17:00 PM TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8151A SW8151A Analyst: MES c-'VOC SW-846: 8151 HERBICIDES-TCLP 2,4-D ND 0.0100 mg/L 1 6/1/2019 8:31:00 AM 2,4,5-TP ND '0.00500 mg/L 1 6/1/2019 8:31:00 AM Surr: 2,4-Dichlorophenylacetic aci 70.8 20 - 140 %Rec 1 6/1/2019 8:31:00 AM TCLP METALS, VOC, BNA, PEST, HERB -LIQUID SW8260 Analyst: CTB TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM 1,2-Dichloroethane ND 0.500 mg/L 100 5/20/2019 5:32:00 PM MEK ND 10.0 mg/L 100 5/20/2019 5:32:00 PM Benzene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Carbon tetrachloride ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Chlorobenzene ND 5.00 mg/L 100 5/20/2019 5:32:00 PM Chloroform ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Tetrachloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Trichloroethene ND 0.500 mg/L 100 5/20/2019 5:32:00 PM Vinyl chloride ND 0.200 mg/L 100 5/20/2019 5:32:00 PM Surr: 4-Bromofluorobenzene 102 70 - 130 %Rec 100 5/20/2019 5:32:00 PM Surr: Dibromofluorom ethane 96.7 70 - 130 %Rec 100 5/20/2019 5:32:00 PM Surr: Toluene-d8 107 70 - 130 %Rec 100 5/20/2019 5:32:00 PM Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Revision v1 RL Reporting Detection Limit U Samples with CalcVal < MDL Page 7 of 35 summifft Summit Environmental Technologies, Inc. 3310 Win St. Analytical Report 1S;l+lf?t�Alt+t�A3T�L a ttCi[?l C�c�� , INC., Cuyahoga Falls, Ohio 44223 (base report) -- - 4..rta,ly+tical Laboraloitli�s TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http://www.settek.com Date Reported: 6/5/2019 'LIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 5/14/2019 11:00:00 AM Lab ID: 19051264-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP Analyses Result RL Qual Units DE Date Analyzed RCI-SOLID-W/ IGNITABILITY1030 SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.476 mg/Kg 1 5/17/2019 8:10:00 PM RCI-SOLID-W/ IGNITABILITY1030 SW1030 Analyst: CXS IGNITABILITY OF SOLIDS (SW-846: 1030) Ignitability nonflammable 1 6/3/2019 5:55:23 PM RCI-SOLID-W/ IGNITABILITY1030 SW9045D Analyst: VVK PH (SW9045D) pH 7.1 s.u.@20.9C 1 5/31/2019 3:40:31 PM RCI-SOLID-W/ IGNITABILITY1030 SW9034 Analyst: MS -.EACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 5/17/2019 8:10:00 PM Qualifiers: E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds 0 RSD is greater than RSDlimit PL Permit Limit RL Reporting Detection Limit H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits Revision v1 U Samples with CalcVal < MDL Page 8 of 35 Summit Environmental Technologies, Inc. Accreditation Program MSUMMIT 3310 Win St. Anal teS Report �t ��li?�1Jeat tdl'AL S C4ihlOt.c i ,, INC Cuyahoga Falls, Ohio 44223 Y p '4137aly0ca-1 Laboratcrles TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http://www.settek.com 05-Jun-19 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 19051264-00 lA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,4,5-TP A Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Key Key NC_WW SCM A Accredited NC WW SCM U Unavailable Version #3 Page 9 of 35 Summit Environmental Technologies, Inc. g Accreditation Program - 3310 Win St. Anal te5 Report y p l�ltit}tdt�t_?TAL $3it7[ cat=St t Cuyahoga Falls, Ohio 44223 r4�8#Ytlial L'ftB6raIOrI6G TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: htW:Ilwww.settek.com 05-Jun-19 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 19051264-001A Sludge TCLP Volatiles Analysis 1, 1 -Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A Key Key NC_WW SCM A Accredited NC WW SCM U Unavailable Version #3 Page 10 of 35 T Summit Environmental Technologies, Inc. Q C SUMMARY m Rl� R A n �T i7 L.IORT 3310 Win St. \[ �7 V 1r11V11 lit i i� ihn4rl'it� itJ Po9:i aT� Lx'. oca t ut; i 5, 1� Cuyahoga Falls, Ohio 44223 WO#: 19051264 AnMyrtoni L,gbcrrataracs; TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro. Project: Cherryville WWTP BatchID: 37518 Sample ID 19051239-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 Client ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 6/22/2019 SegNo: 2124011 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] TCLP Arsenic(As) 2.27 0.500 2.000 0 113 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2309 105 70 130 TCLP Cadmium(Cd) 2.04 0.100 2.000 0 102 70 130 TCLP Chromium(Cr) 2.16 0.200 2.000 0 108 70 130 TCLP Selenium(Se) 2.32 0.0500 2.000 0 116 70 130 TCLP Silver(Ag) 2.43 0.500 2.000 0.0007661 122 70 130 Sample ID 19051239-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 Client ID: Batch= Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124012 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] TCLP Arsenic(As) 2.19 0.500 2.000 0 109 70 130 2.267 3.48 20 TCLP Barium(Ba) ND 5.00 2.000 0.2309 101 70 130 0 0 20 TCLP Cadmium(Cd) 1.96 0.100 2.000 0 97.8 70 130 2.036 4.02 20 TCLP Chromium(Cr) 2.08 0.200 2.000 0 104 70 130 2.159 3.78 20 TCLP Selenium(Se) 2.24 0.0500 2.000 0 112 70 130 2.323 3.45 20 TCLP Silver(Ag) 2.34 0.500 2.000 0.0007661 117 70 130 2.432 3.95 20 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision V 1 RL Reporting Detection Limit Page 11 of 35 � M�fl Summit Environmental Technologies, Inc. QC SUMMARY R..,'ORT 3310 Win St. E{94r1�8D�IPjt6 3%d1L' �3�tWca[ i3�al INC Cuyahoga Falls, Ohio 44223 4�ia,t}rPlaP i1�errttlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: htto:11Www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchIM. 37518 Sample ID 19051239-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 ;lient ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124063 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual -CLP Lead(Pb) 2.16 0.500 2.000 0.01223 107 70 130 Sample ID 19051239-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666 ,lient ID: Batch= Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124064 analyte Result PQL SPK value SPK Ref Val %REC LowLimit, HighLimit RPD Ref Val %RPD RPDLimit Qua[ FCLP Lead(Pb) 2.16 0.500 2.000 0.01223 108 70 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits 130 2.157 0.351 20 H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision vl RL Reporting Detection Limit Page 12 of 35 Summit Environmental Technologies, Inc."MMIT 3310 Win St. QC SUMMARY R ■',1'®RT ElKfl'nOfJPJr:N7AL "r-r—CH 01,0014-5,. JKG Cuyahoga Falls, Ohio 44223 Anal rIcal TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37518 Sample ID MB-37518 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499 Client ID: PBS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118254 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID LCS-37518 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499 Client ID: LCSS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118255 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual I ULF Arsenic(As) 2.11 0.500 2.000 0 105 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 106 80 120 TCLP Cadmium(Cd) 1.95 0.100 2.000 0 97.3 80 120 TCLP Chromium(Cr) 2.19 0.200 2.000 0 110 80 120 TCLP Lead(Pb) 2.23 0.500 2.000 0 111 80 120 TCLP Selenium(Se) 2.17 0.0500 2.000 0 108 80 120 TCLP Silver(Ag) 2.32 0.500 2.000 0 116 80 120 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anali MC Value is below Minimum Compound P Second column confirmation exceeds Revision vl RL Reporting Detection Limit Page 13 of 35 !&'umm I T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY Rom-1 'ORT ENVI OIJMEMTAL TECHNCLt OVVJ!:S,: l c Cuyahoga Falls, Ohio 44223 A.J*�dDa'1 L tatrraJr td s TEL: (330) 253-8211 FAX (330) 253-4489 WO#: 19051264 Website: htW:Ilwww.settek.com 09-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37523 Sample ID MB-37523 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 5/20/2019 RunNo: 98535 Client ID: PBS Batch ID: 37523 TestNo: SW7470A SW7470A Analysis Date: 5/20/2019 SegNo: 2117843 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] TCLP Mercury ND 0.00200 imple ID LCS-37523 SampType: LCS TestCode: HG_TCLP(74 Units: PPM Prep Date: 5/20/2019 RunNo: 98535 ient ID: LCSS Batch ID: 37523 TestNo: SW7470A SW7470A Analysis Date: 5/20/2019 SegNo: 2117844 ialyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00397 0.00200 0.00400 0 99.2 80 120 ample ID 19051026-001AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM Prep Date: 5/2012019 RunNo: 98535 ient ID: BatchQC Batch ID: 37523 TestNo: SW7470A SW7470A Analysis Date: 5/20/2019 SegNo: 2117848 ialyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00435 0.00200 0.00400 0.0000500 108 75 125 Sample ID 19051026-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 512012019 RunNo: 98535 Client ID: BatchQC Batch ID: 37523 TestNo: SW7470A SW7470A Analysis Date: 5/20/2019 SegNo: 2117849 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ TCLP Mercury 0.00439 0.00200 0.00400 0.0000500 108 75 125 0.00435 0.915 20 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision V 1 RL Reporting Detection Limit Page 14 of 35 Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY RL.'ORT � EWlr� i,NPilEMTAL'nChNrJLOG M:_q, WC Cuyahoga Falls, Ohio 44223 AnaiyOoa/ LabarttPpt' os TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: htW:11www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37523 Sample ID 19051026-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 5/20/2019 RunNo: 98535 client ID: BatchQC Batch ID: 37523 TestNo: SW7470A SW7470A Analysis Date: 5/20/2019 SegNo: 2117849 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds ReV1S10n V 1 RL Reporting Detection Limit Page 15 of 35 ' Summit Environmental Technologies, Inc. 3310 Win St. (>C SUMMARY�x'ORT �C iV 1ptiP1 uN1+9.A37diL 1e�:t i3i,:1N Cuyahoga Falls, Ohio 44223 Antttydoof L�aaberralorfes; TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: hQ:11Www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37528 Sample ID 19051350-001AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606 Client ID: Batch= Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120533 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.282 0.0800 0.8000 0 35.3 33.8 126 QMR 2,4,5-Trichlorophenol 0.432 0.200 0.8000 0 54.0 28.7 144 QMR 2,4,6-Trichlorophenol 0.451 0.200 0.8000 0 56.4 12.8 153 QMR 2,4-Dinitrotoluene 0.455 0.0400 0.8000 0 56.9 20.4 155 QC+QMR Cresols, Total ND 4.00 1.600 0 50.3 10 148 QMR Hexachloro-1,3-butadiene 0.281 0.0160 0.8000 0 35.1 29 126 QMR Hexachlorobenzene 0.352 0.0400 0.8000 0 44.0 33.7 134 QMR Hexachloroethane 0.267 0.0800 0.8000 0 33.4 32.8 132 QMR Nitrobenzene 0.358 0.0800 0.8000 0 44.8 20 158 QMR Pentachlorophenol 0.473 0.200 0.8000 0 59.1 10 176 Pyridine 0.254 0.200 0.8000 0 31.7 10 130 Surr:2-Fluorophenol 0.404 1.000 40.4 3.39 130 ' Surr: Phenol-d6 0.457 1.000 45.7 5 130 Surr: Nitrobenzene-d5 0.344 1.000 34.4 14.5 154 Surr: 2,4,6-Tribromophenol 0.524 1.000 52.4 19.5 130 Surr:2-Fluorobiphenyl 0.350 1.000 35.0 34.4 130 Surr: p-Terphenyl-d14 0.539 1.000 53.9 8.86 156 Sample ID 19051350-001AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606 Client ID: BatchQC Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120534 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E . Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds Revision vl PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 16 of 35 I r Su3310 Win St. QC Environmental Technologies, Inc. QC SUMMARY Rj ,'ORT EWIR.}tdVENTAL TE!Gr1NO[.OG1BS, Jfzr, Cuyahoga Falls, Ohio 44223 WO#: 19051264 ffJ Anr/1„Pf/r<af t.ahtararona!; TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37528 Sample ID 19051350-001AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606 Client ID: BatchQC Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120534 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.402 0.0800 1.600 0 25.2 33.8 126 0.2824 35.0 30 RS 2,4,5-Trichlorophenol 0.625 0.200 1.600 0 39.1 28.7 144 0.4320 36.5 30 R 2,4,6-Trichlorophenol 0.634 0.200 1.600 0 39.6 12.8 153 0.4508 33.8 30 R 2,4-Dinitrotoluene 0.654 0.0400 1.600 0 40.9 20.4 155 0.4548 35.9 30 RQC+ Cresols, Total ND 4.00 3.200 0 34.9 10 148 0 0 30 R Hexachloro-1,3-butadiene 0.423 0.0160 1.600 0 26.4 29 126 0.2808 40.5 30 RS Hexachlorobenzene 0.498 0.0400 1.600 0 31.2 33.7 134 0.3520 34.4 30 RS Hexachloroethane 0.374 0.0800 1.600 0 23.4 32.8 132 0.2668 33.6 30 RS Nitrobenzene 0.513 0.0800 1.600 0 32.1 20 158 0.3580 35.6 30 R Pentachlorophenol 0.607 0.200 1.600 0 37.9 10 176 0.4728 24.8 30 Pyridine 0.312 0.200 1.600 0 19.5 10 130 0.2536 20.5 30 Surr:2-Fluorophenol 0.590 2.000 29.5 3.39 130 0 Surr: Phenol-d6 0.646 2.000 32.3 10 130 0 Surr: Nitrobenzene-d5 0.500 2.000 25.0 14.5 154 0 Surr: 2,4,6-Tribromophenol 0.776 2.000 38.8 19.5 130 0 Surr:2-Fluorobiphenyl 0.507 2.000 25.4 34.4 130 0 S Surr: p-Terphenyl-d14 0.754 2.000 37.7 8.86 156 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Revision vl Page 17 of 35 Summit Environmental Technologies, Inc. QC SUMMARY RL' LIOR 1 OJ Vmmly 3310 Win St. f 74rI3YdF:1Y7Ti1L re,?SNGLCr1 iPc Cuyahoga Falls, Ohio 44223 4r��rPG�[/c 11 tlaartatc:rl TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19051264 Website: httn:llwww.settek-.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37528 Sample ID MB-37528 Client ID: PBS Analyte 1,4-Dichlorobenzene 2,4,5-Trichlorophenol 2,4, 6-Trichlorophenol 2,4-Dinitrotoluene Cresols, Total Hexachloro-1, 3-butadiene Hexachlorobenzene Hexachloroethane Nitrobenzene Pentachlorophenol Pyridine Surr: 2-Fluorophenol Surr: Phenol-d6 Surr: Nitrobenzene-d5 Sum 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: p-Terphenyl-d14 SampType: MBLK Batch ID: 37528 Result ND ND ND ND ND ND ND ND ND ND ND 0.486 0.605 0.501 0.585 0.566 0.676 TestCode: SVOC-BNA_T Units: mg/L TestNo: SW8270 SW3510C PQL SPK value SPK Ref Val 0.0400 0.100 0.100 0.0200 2.00 0.00800 0.0200 0.0400 0.0400 0.100 0.100 Prep Date: 5/20/2019 Analysis Date: 5/21/2019 %REC Lowl-imit HighLimit RPD Ref Val 1.000 48.6 10 109 1.000 60.5 10 109 1.000 50.1 19 120 1.000 58.5 10 120 1.000 56.6 22 117 1.000 67.6 34 116 RunNo: 98559 SegNo: 2119054 %RPD RPDLimit Qual Sample ID LCS-37528 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98559 Client ID: LCSS Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2119055 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds Revision V 1 PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 18 of 35 Summit Environmental Technologies, Inc. mm's T 3310 Win St. QC SUMMARY RL' 1I0R iT EWlft{}PdiL rENTAL TSCHu'JOLL'� G;-!,�S„itd;ts Cuyahoga Falls, Ohio 44223 'at}rCIc1:LPiatrarac TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: htW:Ilwww.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37528 Sample ID LCS-37528 Client ID: LCSS Analyte 1,4-Dichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 2,4-Dinitrotoluene Cresols, Total Hexachloro-1,3-butadiene Hexachlorobenzene Hexachloroethane Nitrobenzene Pentachloro phenol Pyridine Surr: 2-Fluorophenol Surr: Phenol-d6 Surr: Nitrobenzene-d5 Surr: 2,4,6-Tribromophenol Surr: 2-Fluorobiphenyl Surr: p-Terphenyl-d14 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val 0.409 0.0400 0.8000 0 51.2 36.4 130 0.571 0.100 0.8000 0 71.4 31.7 132 0.570 0.100 0.8000 0 71.2 31.1 133 0.568 0.0200 0.8000 0 71.0 43.3 130 ND 2.00 1.600 0 65.2 31.7 130 0.403 0.00800 0.8000 0 50.4 31.4 130 0.528 0.0200 0.8000 0 66.0 43.1 130 0.396 0.0400 0.8000 0 49.5 36.5 130 0.499 0.0400 0.8000 0 62.4 39.5 130 0.518 0.100 0.8000 0 64.8 34 130 0.138 0.100 0.8000 0 17.3 10 130 0.604 1.000 60.4 17.1 130 0.648 1.000 64.8 10 130 0.615 1.000 61.5 32.6 130 0.714 1.000 71.4 4.43 130 0.621 1.000 62.1 41.8 130 0.814 1.000 81.4 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits RunNo: 98559 SegNo: 2119055 %RPD RPDLimit Qual m H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision V 1 RL Reporting Detection Limit Page 19 of 35 Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY m /�1W11V1 ARY RLx"ORT EN.VlPOAfilr: NTAL Ti!CH OLLoGiz:.S, i�4C Cuyahoga Falls, Ohio 44223 atyrYv :l L.a/.:o,roxorjos TEL: (330) 253-8211 FAX- (330) 253-4489 WO#: 19051264 ?;rr Website: hto:llwww.settelc.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37600 Sample ID MB-37600 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799 client ID: PBS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142057 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 gamma-BHC ND 0.000500 d Heptachlor ND 0.000500 d Heptachlor epoxide ND 0.000500 d Methoxychlor ND 0.000500 d Surr: TCMX 9.56 20.00 47.8 10 119 Surr: DCB 16.6 20.00 82.9 10 119 Sample ID LCS-37600 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799 client ID: LCSS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142058 analyte Result PQL SPK value SPK Ref Val %REC Lowt-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.0101 0.000500 0.0100 0 101 20 216 gamma-BHC 0.00768 0.000500 0.0100 0 76.8 20 197 Heptachlor 0.00679 0.000500 0.0100 0 67.9 20 200 Heptachlor epoxide 0.00803 0.000500 0.0100 0 80.3 20 200 Methoxychlor 0.00978 0.000500 0.0100 0 97.8 20 227 Surr: TCMX 11.5 20.00 57.5 20 143 Surr: DCB 18.7 20.00 93.5 20 151 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision V 1 RL Reporting Detection Limit Page 20 of 35 Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY R.,'ORT EN%FITION MENTAL `3 u-CtONcr ;: dg:5, JNC Cuyahoga Falls, Ohio 44223 k��flo9 tcarrc�ade, TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http:1Avww.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: 37650 Sample ID MB-37650 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 99034 Client ID: PBS Batch ID: 37650 TestNo: SW8151A SW8151A Analysis Date: 5/31/2019 SegNo: 2141487 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] 2,4-D ND 0.0100 0 0 d 2,4,5-TP ND 0.00500 0 0 d Surr: DCAA 253 500.0 50.6 20 140 ample ID LCS-37650 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 99034 ient ID: LCSS Batch ID: 37650 TestNo: SW8151A SW8151A Analysis Date: 5/31/2019 SegNo: 2141488 ialyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.406 0.0100 0.500 0 81.2 43.8 130 2,4,5-TP 0.413 0.00500 0.500 0 82.6 51.5 111 Surr: DCAA 597 500.0 119 34.2 150 ample ID LCSD-37650 SampType: LCSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 99034 ient ID: LCSS02 Batch ID: 37650 TestNo: SW8151A SW8151A Analysis Date: 5/31/2019 SegNo: 2141489 ialyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.408 0.0100 0.500 0 81.6 43.8 130 0.406 0.589 30 2,4,5-TP 0.428 0.00500 0.500 0 85.5 51.5 130 0.413 3.54 30 Surr: DCAA 292 500.0 58.3 34.2 150 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds Revision vl PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 21 of 35 i Summit Environmental Technologies, Inc.1W."Nkmir _ QC SiTMMAR i itl`i'ORT 3310 Win St. ENV1nOflM1: TrAL „'INC. Cuyahoga Falls, Ohio 44223 WO#: 19051264 nitici°:L@torattara`cs TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP _ BatchID: R98525 Sample ID LCS-98525 SampType: LCS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 ;lient ID: LCSW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117453 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0167 0.00500 0.0200 0 83.7 70 138 1,2-Dichloroethane 0.0178 0.00500 0.0200 0 89.2 70 130 MEK 0.0961 0.0250 0.100 0 96.1 70 130 Benzene 0.0192 0.00500 0.0200 0 96.0 10 199 Carbon tetrachloride 0.0195 0.00500 0.0200 0 97.4 21.3 240 Chlorobenzene 0.0190 0.00500 0.0200 0 94.8 70 132 Chloroform 0.0193 0.00500 0.0200 0 96.5 70 130 Tetrachloroethene 0.0184 0.00500 0.0200 0 92.2 10 130 Trichloroethene 0.0193 0.00500 0.0200 0 96.6 70 130 Vinyl chloride 0.0189 0.00200 0.0200 0 94.3 70 130 Surr:4-Bromofluorobenzene 50.8 50.00 102 70 130 Surr: Dibromofluoromethane 47.6 50.00 95.2 70 130 Surr: Toluene-d8 54.2 50.00 108 70 130 Sample ID MB-98525 SampType: MBLK TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 Client ID: PBW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117457 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit . Qua] 1,1-Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0.00500 MEK ND 0.0250 Benzene ND 0.00500 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds Revision vl PL Permit Limit R . RPD outside accepted recovery limits RL Reporting Detection Limit Page 22 of 35 Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY R-ILix'ORT E�',KflrtOfJ N1 i 17�tL 7 ,d36�� 1 ib i�.5, a1 0 A-iafy[tcafta.barafon,''os: TEL: Cuyahoga Falls, Ohio 44223 (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: htW://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID• R98525 Sample ID MB-98525 SampType: MBLK TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 client ID: PBW Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2117457 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 Surr: 4-Brom ofl uorobenzene 50.3 50.00 101 70 130 Surr: Dibromofluoromethane 47.4 50.00 94.9 70 130 Surr: Toluene-d8 54.0 50.00 108 70 130 Sample ID 19051144-00laMS SampType: MS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119583 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] 1,1-Uichloroethene 0.131 0.0500 0.200 0 65.3 63.8 148 1,2-Dichloroethane 0.170 0.0500 0.200 0 85.0 70 130 MEK 0.943 0.250 1.00 0 94.3 10 130 Benzene 0.727 0.0500 0.200 0.547 89.9 70 130 Carbon tetrachloride 0.142 0.0500 0.200 0 71.0 70 130 Chlorobenzene 0.173 0.0500 0.200 0 86.2 70 130 Chloroform 0.180 0.0500 0.200 0 90.2 70 130 Tetrachloroethene 0.142 0.0500 0.200 0 70.8 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds Revision v1 PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 23 of 35 Summit Environmental Technologies, Inc. QC SUMMARY MMARY i\.-,,IO t 1 3310 Win St. FENN]PEO 61EMTAL t-r-t<tbtkit~tLacj�:Z, iNC Cuyahoga Falls, Ohio 44223 WO#: 19051264 Anatytical .t a•-orrarorpos TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98525 Sample ID 19051144-001aMS SampType: MS TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 Client ID: Batch= Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119583 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Trichloroethene 0.167 0.0500 0.200 0 83.7 70 130 Vinyl chloride 0.138 0.0200 0.200 0 69.2 53.9 141 Surr: 4-Bromofluorobenzene 507 500.0 101 70 130 Surr: Dibrom ofl uorom ethane 471 500.0 94.2 70 130 Surr: Toluene-d8 544 500.0 109 70 130 Sample ID 19051144-001aMSD SampType: MSD TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 Client ID: Batch= Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119584 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] 1,1-Dichloroethene 0.144 0.0500 0.200 0 72.0 63.8 148 0.131 9.83 30 1,2-Dichloroethane 0.174 0.0500 0.200 0 87.2 70 130 0.170 2.61 25 MEK 0.927 0.250 1.00 0 92.7 10 130 0.943 1.69 25 Benzene 0.716 0.0500 0.200 0.547 84.6 70 130 0.727 1.48 30 Carbon tetrachloride 0.157 0.0500 0.200 0 78.4 70 130 0.142 9.91 25 Chlorobenzene 0.176 0.0500 0.200 0 88.2 70 130 0.173 2.29 30 Chloroform 0.182 0.0500 0.200 0 91.1 70 130 0.180 0.883 25 Tetrachloroethene 0.154 0.0500 0.200 0 77.0 70 130 0.142 8.25 25 Trichloroethene 0.174 0.0500 0.200 0 87.2 70 130 0.167 4.10 30 Vinyl chloride 0.134 0.0200 0.200 0 66.8 53.9 141 0.138 3.60 25 Surr:4-Bromofluorobenzene 510 500.0 102 70 130 0 25 Surr: Di bromofluorom ethane 468 500.0 93.7 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds Revision V 1 PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 24 of 35 Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY R�.,'ORT �q'Jl�rS:PJMt taTdtLcctffitt�I,ik";i5,.lt�".. Cuyahoga Falls, Ohio 44223 AraNY0011 Laba,ralor�OG TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http://www.settelc.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98525 Sample ID 19051144-001aMSD SampType: MSD TestCode: voc-mstr_np Units: mg/L Prep Date: RunNo: 98525 Client ID: BatchQC Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/21/2019 SegNo: 2119584 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Surr: Toluene-d8 547 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 500.0 109 70 130 E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits 0 25 H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision vl RL Reporting Detection Limit Page 25 of 35 Summit Environmental Technologies, Inc.!&-utamut _ QC SUMMARY ST Tl� ti�/� � � tT 77 LiP®RT 3310 Win St. C S V 1VllaAR i Li �1k4tlfiirJl�1n7TALc.tiaea�c5t1, au Cuyahoga Falls, Ohio 44223 t-l+1'oMyLvaf Laborjtotrev TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http:lAvww.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98525 Sample ID LCS-98525 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 98525 Client ID: LCSS Batch ID: R98525 TestNo: SW8260 Analysis Date: 5/20/2019 SegNo: 2119592 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] 1,1-Dichloroethene 0.0167 0.00500 0.0200 0 83.7 79.4 131 1,2-Dichloroethane 0.0178 0.00500 0.0200 0 89.2 73.6 137 MEK ND 0.100 0.100 0 96.1 55.1 163 Benzene 0.0192 0.00500 0.0200 0 96.0 73.1 132 Carbon tetrachloride 0.0195 0.00500 0.0200 0 97.4 63.7 139 Chlorobenzene ND 0.0500 0.0200 , 0 94.8 72.3 139 Chloroform 0.0193 0.00500 0.0200 0 96.5 79.3 129 Tetrachloroethene 0.0184 0.00500 0.0200 0 92.2 56.2 187 Trichloroethene 0.0193 0.00500 0.0200 0 96.6 64.1 138 Vinyl chloride 0.0189 0.00200 0.0200 0 94.3 22.1 147 Surr:4-Bromofluorobenzene 50.8 50.00 102 80.4 126 Surr: Dibrom ofl uorom ethane 47.6 50.00 95.2 70.3 125 Surr: Toluene-d8 54.2 50.00 108 82 117 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Revision v1 Page 26 of 35 !Wumm I lot Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY RLxi 'ORT EN��PIII ts�l Pai�r�r,�L �Ca�Ne, [�c��tta S. IN tP�Jr> lca/ z e�arr�a 1 TEL: Cuyahoga Falls, Ohio 44223 (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http:lAvww.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98750 iample ID Blank SampType: MBLK TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 ,lient ID: PBW Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019. SegNo: 2129296 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ ;yanide, Reactive ND 0.485 Sample ID LCS SampType: LCS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 Client ID: LCSW Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129297 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.43 0.490 10.00 0 94.3 85 115 Sample ID RI -Check SampType: RLC TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 Client ID: BatchQC Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129299 Analyte, Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Cyanide, Reactive 0.524 0.490 0.5000 0 105 50 150 Sample ID 19051158-011AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 Client ID: BatchQC Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129319 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Cyanide, Reactive 10.0 0.500 10.00 0.3081 97.3 81.3 118 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision vl RL Reporting Detection Limit Page 27 of 35 Summit Environmental Technologies, Inc. _ WkMIAt 3310 Win St. QC SUMMARY R�x'ORT FA 4 IrtOpdpUT- tL retW t i 0iw 1 Cuyahoga Falls, Ohio 44223 Aiaalydoa/ Laboiwdrlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID• R98750 Sample ID 19051158-011AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 Client ID: BatchQC Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129319 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] Sample ID 19051158-011AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 98750 client ID: BatchQC Batch ID: R98750 TestNo: SW9014 Analysis Date: 5/17/2019 SegNo: 2129320 %nalyte Result PQL . SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual ;yaniUe, Reactive 10.2 0.500 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 10.00 0.3081 98.7 81.3 E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits 118 10.04 1.39 5 H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision vl RL Reporting Detection Limit Page 28 of 35 Summit Environmental Technologies, Inc. QC SUMMAR i itLi�ORT 3310 Win St. �C 4�ICtdP.o1TaL 9 r9@EdtSLG+a9,; INC Cuyahoga Falls, Ohio 44223 ra.tyrdc t actraard TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: htt,2://www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98776 Sample ID MB-R98776 SampType: MBLK TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 98776 Client ID: PBW Batch ID: R98776 TestNo: SW9034 Analysis Date: 5/17/2019 SegNo: 2130197 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive ND 25.0 Sample ID LCS-R98776 SampType: LCS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 98776 Client ID: LCSW Batch ID: R98776 TestNo: SW9034 Analysis Date: 5/17/2019 SegNo: 2130198 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4560 25.0 4800 0 95.0 85 115 Sample ID 19051158-011AMS SampType: MS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 98776 Client ID: Batch= Batch ID:_ R98776 TestNo: SW9034 Analysis Date: 5/17/2019 SegNo: 2130209 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ Sulfide, Reactive 4720 25.0 4800 0 98.3 75 125 Sample ID 19051158-011AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 98776 Client ID: BatchQC Batch ID: R98776 TestNo: SW9034 Analysis Date: 5/17/2019 SegNo: 2130210 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4680 25.0 4800 0 97.5 75 125 4720 0.851 30 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anali MC Value is below Minimum Compound P Second column confirmation exceeds Revision v1 RL Reporting Detection Limit Page 29 of 35 1 Summit Environmental Technologies, Inc. QC SUMMARY R �'�iOOi\ 1 3310 Win St. ENWInOUMdENITAL e ��Y it L[SGI �,. artr; Cuyahoga Falls, Ohio 44223 fflr1ntllyfluall Labornt'ort O� TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http:lAvww.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98776 Sample ID 19051158-011AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 98776 client ID: BatchQC Batch ID: R98776 TestNo: SW9034 Analysis Date: 5/17/2019 SegNo: 2130210 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision V 1 RL Reporting Detection Limit Page 30 of 35 Summit Environmental Technologies, Inc. R �'���ORT 1pummilu 3310 Win St. `t (>C SUMMARY EP41 ItiOAMENTAL Cuyahoga Falls, Ohio 44223 WO#: 19051264 Aaa,Api'yrIva TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: ham://Www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98995 Sample ID LCS-R98995 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@22.00 Prep Date: RunNo: 98995 ;lient ID: LCSS Batch ID: R98995 TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2139142 analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ pH 7.0 7.0 0 100 90 110 Sample ID CHECK 7 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@22.3C Prep Date: RunNo: 98995 client ID: LCSS Batch ID: R98995 TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2140377 %nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 7.0 0 101 90 110 E Value above quantitation range M Manual Integration used to determine area response 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision vl RL Reporting Detection Limit Page 31 of 35 Summit Environmental Technologies, Inc. QC SUMMARY 1V11W ARY i�LiIORT 3310 Win St. sLNkVl'fi�C}tJNa1 17,�.L E :u 3 1 w'a ai ,. a Cuyahoga Falls, Ohio 44223 �aautyC���'.i#rlt�ac TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19051264 Website: http://Www.settek.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R98995 Sample ID 19052000-001BDUP SampType: DUP Client ID: BatchQC Batch ID: R98995 Analyte Result pH 6.9 TestCode: pH_NPW(450 Units: s.u.@20.3C Prep Date: RunNo: 98995 TestNo: SW9045D Analysis Date: 5/31/2019 SegNo: 2140375 PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 6.9 0.6 5 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response O RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds Revision vl RL Reporting Detection Limit Page 32 of 35 at Summit Environmental Technologies, Inc. QC SUMMARY � �T n 1'On T 3310 Win St. S lJ M AR i RiL it ENWliiNlNttAt7AL G'c12Stltit [*a,Iw, ire. Cuyahoga Falls, Ohio 442231 NJ WO#: 19051264 n tP "tl� J .l rt tlt��tt�dlu TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settelc.com 05-Jun-19 Client: Synagro Project: Cherryville WWTP BatchID: R99073 Sample ID LCS-R99073 SampType: LCS TestCode: Ignitability_S Units: Prep Date: RunNo: 99073 Client ID: LCSS Batch ID: R99073 TestNo: SW1030 Analysis Date: 6/3/2019 SegNo: 2142958 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] Ignitability 7.94 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 7.240 0 110 70 130 E Value above quantitation range M Manual Integration used to determine area response 0 RSD is greater than RSDlimit R RPD outside accepted recovery limits H Holding times for preparation or anal, MC Value is below Minimum Compound Revision vl P Second column confirmation exceeds RL Reporting Detection Limit Page 33 of 35 Suninift Environmental 1bchnologie,.;�, 111c. KJ -13 [O.Win Street Cuyahoga Falls. Ohio 4422-1 Analysis Reques _t/0ah) of Custody For' Summit Envimmitema[ Tecf)llcijagie. , s , 111c. use ortkgol, Company MmL! (Ilteat;c Prip,j) Toll Ip Ifly Pniject Name 0'roject 1 I r AT, a" a d , Client 1111one No. c�tient5:76� -7 ?6' IG) M —,N,—,. —l""' v El Report to P09' client Email 11 Se Em. QuoteNo. ip, Slampled by AEl Check i r dMia I Sample Identirle.1tictf) 17— 'J'Q L —UH—Ic— ffi,a�e kd by:, to 11,41TIC NousI.Comm RecchWed, )i labl)y: Date '11me Rmsh Wilutsted Ity: aFc Page- -Of—, — I Mike and Yellow pugcs "911OU111 a000mpaqsarflpl Cs IL, the Ill lorawry, T 20 clictit rrillimi rlic pilik -WIC!}1"SU111111V :I.;R 11HCATION RF.,Q(jjjiLI, 4�� No 1111,014TTOS11 _A . 1, 1 D %N1 1),NI It pleiLsc I'T"Vidle F.'tVS ISR)4pil 1.1r­�,'Ijflj�j"., ", a J, h. , , L "Or 4"1 Page 34 of 35 Summit Environmental Technologies, Inc. ms"Mmily 3310 Win St. t�E�tr"r�ir.9ctiT�L3E�s� €�t c'i? INC. Cuyahoga Falls, Ohio44223 A.,7aytltr.,# Labararo.46s TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htip.•Ilwww.settek.com Sample Log -In Check List Client Name: SYN-NC-27028 Work Order Number: 19061264 RcptNo: 1 Logged by: Kayla L. Oulton 5/16/2019 10:20:00 AM Completed By: Jesseca E. Westfall 5/16/2019 5:34:18 PM 1 Reviewed By: Jennifer Woolf 5/17/2019 3:21:16 PM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present d❑ No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes ❑d No ❑ NA ❑ 6, Were all samples received at a temperature of >0° C to 6.0°C Yes �/❑ No ❑ NA ❑ 7, Sample(s) in proper container(s)? Yes ❑d No ❑ 8. Sufficient sample volume for indicated test(s)? Yes No ❑ 9, Are samples (except VOA and ONG) properly preserved? Yes No ❑ 10. Was preservative added to bottles? Yes ❑ No d❑ NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials❑ 12. Were any sample containers received broken? Yes ❑ No d❑ 13. Does paperwork match bottle labels? Yes No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes No ❑ 15. Is it clear what analyses were requested? Yes ❑d No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: _ 18. Additional remarks: Cooler Information Cooler No I Temp °C I Condition Seal Intact I Seal No Seal Date Signed B 1 14.6 1 Goodl Not Present Page 35 of 35 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City Of Cherryville WQ Permit Number: WQ0000430 WWTP Name: City of Cherryville WWTP NPDES Number: NCO044440 Monitoring Period: From Jan 1, 2019 To Dec 31, 2019 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) ' Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Anaerobic Digestion Composting Aerobic Digestion If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10to the 01 MPN <1156 <1775 <2381 MPN/g 0 Annual Grab SM9221C Coliform power per gram E-2006 of total solids CFU CFU/g 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Mt. 1 (VS reduction) Option/Alt. 5 (14-Day Aerobic) Option/Alt. 9 (Injection) Option/Alt. 2 (40-day bench) Option/Alt. 6 (Alk Stabilization) Option/Alt. 10 (Incorporation) CERTIFICATION STATEMENT (please check the appropriate statement) Option/Alt. 3 (30-day bench) X Option/Alt. 7 (Drying — Stable) Option/Alt. 4 (Spec. 02 uptake) Option/Alt. 8 (Drying — Unstable) No vector attraction reduction alternatives were performed "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the athogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification inc ding fine and imprisonment.';�� Larry Wright, Plant ORC & Plant Superintendent � , FY 1rr Prep er Name and Titl e or print) Land A 1' r Name and Title (if applicable) (type or print) Prep, 7- Zo 20 �� 7 7Fgnature of eparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Analytical Results S7A1°EsY9LLE ANALYTICAL Synagro 284 Boger Rd. Mocksville, NC 27028 Receive Date: 05/14/2019 Reported: 05/15/2019 For: Cherryville WWTP Comments: Geometric Mean_ <1775 MPN/g Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 190514-37-01 Fecal Coliforms 1 <2381 MPN/g SMMlCE2006 05/14/2019 CL 190514-37-01 Percent Solids 1 0.84 % SM25408-2011 05/14/2019 CL 190514-37-02 Fecal Coliforms 2 <1515 MPN/g 8M9221cE 2006 05/14/2019 CL 190514-37-02 Percent Solids 2 1:32 ova SM254OB-2011 05/14/2019 CL 190514-37-03 Fecal Coliforms 3 <1961 MPN/g sM9227cE-2006 05/14/2019 CL 190514-37-03 Percent Solids 3 1.02 %u SM2540B-2011 05/14/2019 CL 190514-37-04 Fecal Coliforms 4 <1156 MPN/g SM92210E-2006 05/14/2019 CL " 190514-37-04 Percent Solids 4 1.73 % SM25408-2011 05/14/2019 CL 190514-37-05 Fecal Coliforms 5 <1905 MPN/g SM9 ME-20os 05/14/2019 CL 190514-37-05 Percent Solids 5 1.05 % SM254OB-2011 05/1412019 CL 190514-37-06 Fecal Coliforms 6 <2105 MPN/g sM9221cE-2006 05/14/2019 CL 190514-37-06 Percent Solids 6 0.95 % SM254OB-2011 05/14/2019 CL 190514-37-07 Fecal Coliforms 7 <1695 MPN/g SM92210E-20o6 05/14/2019 CL 190514-37-07 Percent Solids 7 1.18 % SM2540B-2011 05/14/2019 CL Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA 9NC00909 PO Box 228 • Statesville, NC 28687. 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 190514-37-01 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-02 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-03 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-04 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190614-37-05 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-06 Temp on Arrival: 2.3 PO Box 228 - Statesville, NC 28687 - 704/872/4697 Page 2 of 4 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Sample Number 190514-37-07 Temp on Arrival: 2.3 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 O w 0 x N N 00 � O m 00 V o N � A Lo V Ctient: j �44Q29 M STATFSVILLEANALYTICAL Address: 122 Court Strad • P.O. Box 228 Statmiar NC 28687 (704)872-4697 C1181fl of CusWY Record one # t FAX# Contact Person: PhG �Fo U PO # Requisitioned by: (Time pale) Customer Sdm le 1D8 ! abdp # Time Sampled (Grab Only) pals Sampled {GraO OnH) n Matrtx w wvr PAM=. eery rNuestedforarLdysis t.,s r utt�e Q:uU s t l.. v( -e O=Gk r 6 G" 6z 1. .o %w . r.26 ac>s i - 47 10:t� Relinquished by; Time am,��DatelT Sampled by: --�� Received : b Y � u Time am, pm Date ! Transported by: r Relinquished by: Time am, pm Date _/_/ Holding times met Received by: Time am, pm Date _I J Compliance work: omposile sampling #1 Time begin am, pm Date _I I Non-compliance work: Time end am, pm Date —J___/ Composite Sampling #2• Lab Comments: Samples Transported On Ice: Time begin am, pm Date / ! Time end am, pm Date /_/ Initials: Analytical Results STATESVILLE ANALYTICAL Synagro 284 Boger Rd. Mocksville, NC 27028 Receive Date: 05/14/2019 Reported: 06/12/2019 For: Cherryville WWTP Comments: Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 190514-38-01 30 Day Benchscale Cherryville 9.7 % EPA625-R-92(0 05/14/2019 WC Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 •Statesville, NC 28687 • 704/872/4697 Page 1 of 2 -o O m 0 x N N 00 Cliertf: 3e.) l, SFATESYILLEANALY77CAL 122 Coun Smeet • P.O.9ox 228 Sratesville, NC 29687 (704) 972-4697 Chain of Address: Contact Parson: C rJ Phone # �O I I7AX# b PO # Requisitioned by: (rime Dare) III Custody Record Customer Sa npEs IDt WHO it 11me sampled (Grab Only) Date Sampled (Grab Only) a d Matrlx S aP W ww Paramaecs regained formulysis Relinquished by: Received by: Relinquished by: Received by: Composite Sampling #1: Time begin am, pm Date __J I Time end am, pm Date /_I_ COMOSIte Samplirka #2: Time begin am, pm Date Time end am, pm Date �/ / Time Time %2�-D Time Time Lab comments: aM;:: i Data !�_Jl_/_12 Sampled by: am, pm Date l� 'ftansported by: am, pm Date Holding times met: am, pm Date _/ ! 4f Compliance work Non-compliance work: Samples Transported On Ice: Initials. Analytical Results Synagro Entered: 05-14-2019 Reported: 06-14-2019 Sample ID: 190514-38-01 For: Cherryville PARAMETER: Vector Attraction Reduction/Aerobically Digested Sludge (30day) Total Solids Volatile Solids % Volatile Solids Week 1 2.95 1.57 0.5172 Week 2 2.79 1.37 0.4894 Week 3 2.96 .1.47 0.4924 Week 4 2.80 1.35 0.4814 Week 5 1.83 0.90 0.4916 Volatile Solids Reduction: 0.5172 - 0.4916X100 = 9.7% 0.5172 - (0.5172X 0.4916) Respectfully submitted, Dena Myers Statesville Analytical, Inc. NC WW Cert.# 440NC DW Cert. #37755 SECTION 6 Agricultural Lime Application Log Year: 2019 Project: Cherryville Field (state -county -site -field) ::]_PH Soil Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied LT-107-3 4.8 1.3 T/Ac. 1.3T/Ac 11/15/19 SECTION 7 NCDA&CS Agr ,, " iic Division Phone: (919) 733-2655 Website: www. Ter` a ,fk Predictive Soil Report Mehlich-3 Extraction ��SpN.hIY.51 nN� � Links to Helpful Information Sampled: Received: 09/12/2019 completed: 09/21/2019 Farm: NC-Lt-107 Sample ID: 03 Recommendations: Lime Crop (tons/acre) N P2O5 Lime History: 1 -Sudan/Sorghum past. 1.3 140-180 70 2 - 0.0 .Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% 0.22 1.07 3.7 46 2.0 4.8 28 63 27 11 ir.gov/agronomi/ Report No. 0-SL0041614 Client: Calvin (John) Wehunt Advisor: Alex Fox 2385 Norman Parker Synagro Cherryville, NC 28021 284 Boger Rd Mocksville, NC 27028 Sampled County: Lincoln Client ID: 324632 Advisor ID: 501947 I YULI1MILO k1U/cII:IC) More K2O Mg S Mn Zn Cu B Information 70 0 0 0 0 0 0 Note:12 Soil Class: Mineral S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 215 45 44 35 3n R7 n n Reprogramming of the laboratory -information -management system that makes this report possible is"being funded through a grant from the North Carolina Tobacco Trust Fund Commission.: Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler. Commissioner ofAwiculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Calvin (John) Wehunt Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Lime If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at time, even if the report recommends more. You can apply the rest in similar increments every six months until the full is applied. If MG is recommended and lime is needed, use dolomitric lime. Fertilizer Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear only on reports for greenhouse soil or problem samples. Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients In general, homeowners do not need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit ncagr.gov/agronomi/pubs.htm. Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find the exact fertilizer grade recommended on the report, visit www.ncacrr.pov/acrronomi/obpart4.htmind information that may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizes Test Results The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-Al, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routine[ available)] indicate levels of plant nutrients or other fertility measurement. Visit www•ncaar.gov/a gronomi/uvrst.htm Report No. FY20-SL004614 Page 2 of 2 Report Abbreviations Ac exchangeable acidity B boron BS% % CEC occupied by basic cations Ca% % CEC occupied by calcium CEC cation exchange capacity Cu-I copper index ESP exchangeable sodium percent HM% percent humic matter K-1 potassium index K20 potash Mg% % CEC occupied by magnesium MIN mineral soil class Mn manganese Mn-All Mn-availability index for crop 1 Mn-AI2 Mn-availability index for crop 2 Mn-I manganese index M-0 , mineral -organic soil class N nitrogen Na sodium NO3-N nitrate nitrogen ORG organic soil class pH current soil pH P-1 phosphorus index P205 phosphate S-1 sulfur index SS-1 soluble salt index WN weight per volume Zn-AI zinc availability index Zn-I zinc index Schutte, Maria From: Sent: To: Cc: Subject: Attachments: Maria, Nate Roth <rroth@SYNAGRO.com> Monday, September 30, 2019 2:01 PM Larry Wright; Schutte, Maria Alex Fox [External] RE: Cherryville WWTP WQ0000430 Cherryville WWTP 2018 Annual Report; 30 Day Bench Calc 2018 Cherryville.pdf, 2018 30 Day Lab Data.pdf Please see the response below for attached email concerning Cherryville's 2018 annual report review: • Upon inspection of the "handwritten" lab calculations I have determined that formatting issues cut off a portion of the document. The attached 30 Day Bench Calc. pdf provides the entire document which now includes a result of 12.77% VSR through the mass balance calculation. This calculation can be found on page 132 of the EPA's Control of Pathogens and Vector Attraction in Sewage Sludge Handbook. The lab data for each week of additional digestion is also attached. Statesville Analytical provided this data. • Future annual reports will include all the requested data and explanation of formulas used in calculating VSR if they differ from lab calculations. Please let me know if you require and additional information or clarification, Nate From: Larry Wright <Iwright@cityofcherryville.com> Sent: Monday, September 30, 2019 12:23 PM To: Nate Roth <rroth@SYNAGRO.com>; Larry Wright <Iwright@cityofcherryville.com>; Maria Schutte <Maria.schutte@ncdenr.gov> Subject: Cherryville WWTP Nate, See the attached email below from Maria Schutte with NCDENR. We need to respond to this ASAP. Can you check with your lab and copy me on their response. Thanks, Larry Wright Cherryville WWTP From: "Schutte, Maria" <maria.schutte@ncdenr.gov> Date: September 27, 2019 at 9:51:02 AM EDT To: Larry Wright <larrygwrightii@icloud.com> . Subject: RE: [External] Cherryville WWTP 1 Thank you-; Larryl Looks goodi L-et-m,e know when your application event gets closer and we will coordinate with your inspection. Also, I did not receive a response to the attached email related to your annual report. Please review and respond. Maria From: Larry Wright[mailto:larrygwrightii@icloud.com] Sent: Friday, September 27, 2019 9:08 AM To: Schutte, Maria <maria.schutte@ncdenr.gov>; Larry Wright <Iwright@citvofcherrvville.com> Subject: [External] Cherryville WWTP CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to report. spam@nc.gov<maiIto: report. spam a,nc.gov> Hi Maria, Took some pictures and video that I wanted to share with you. I have a contractor come in and mow around our sludge lagoon. He also gets any small trees or brush. Also Synagro hauled in August and said they were coming back in October to finish after the farmer cuts his soybeans. I've attached a few photos and video clips below. Thanks, Larry Wright City of Cherryville Wastewater Treatment Plantt 704-308-3552 - office 704-214-1162 - cell Lwrightgwo fcherryvi11e. com Sent from my iPhone Nate Roth _ Technical Services Manager 284 Boger Road, Mocksville, NC, 27028 0: 1-336-355-1965 1 M: 1-336-403-4324 rroth@SYNAGRO.com I synagro.com Facebook I Twitter I Linkedin %VS R (older, more conservative method) %VS in 0.5551 Enter in %VS out 0.4842 L decimal form %VSR_ (%VS in - %VS out) ((%VS in - (%VS in x %VS out)) %VSR= 24.76 (method from p.132 of WH manual) %VSR—_ (%VS in - %VS out) %VS in 30 Day Bench Worksheet � ��11 "I Sampl 1D # ��Y'ZQ • 2'� Week Total Sollds Volatile Bolick a/ Average Week Total 1. Average I J Week Total I Average II Week Total Average L—L Week 5 Total Sc Volatile Solids Volatile Solids % Volatile Fraction % Volatile Fraction Fraction Average / O Van Kleeck Reductio : Initial % Vol Fraction - Flnai % Vol Fraction X 100 Initial % Vol, Fraction -(Initial % Vol. Fraction X Final % Vol. Fraction) Q• 5�51 �0•�iBW"2 Y, i00 00' 6140,5561,XOMNI) .0�1� Schutte; Maria From: Schutte, Maria <maria.schutte@ncdenr.gov> Sent: Thursday, May 2, 2019 4:10 PM To: 'Iwright@cityofcherryville.com' Cc: Erik Bruce; Graves, Sonia; Pitner, Andrew Subject: WQ0000430 Cherryville WWTP 2018 Annual Report Mr. Wright, A copy of the referenced annual report was received in the Mooresville Regional Office on March 15", 2019. Upon review, MRO staff communicated with Statesville Analytical staff and received a copy of the 30-day bench work -sheet documentation. By the typical Van Kleeck formula the results fail, but appear to pass by the alternate Mass Balance. equation at 12.77%. The following additional information is requested: Clarification for the hand-written formula across the lab results page, which does not appear to be either the Van Kleeck or Mass Balance equation and does not equal 12.77%. Correction to future reports: Include lab documentation page for the 30 day procedure (dates, temp., % solids, etc.) and justification for any formula/calculation that differs from the'lab result as a separate write-up signed . and dated. Submission of a final laboratory report with unexplained, hand-written comments is unacceptable. Please contact me with any questions. Maria Schutte Environmental Specialist Water Quality Regional Operations Section Division of Water Resources North Carolina Department of Environmental Quality 704 663 1699 office 704 235 2184 direct Maria. schutte(cr�.ncdenr.gov 610 East Center Avenue Suite 301 Mooresville, NC 28115 Nothing Compares.. Email correspondence to and from this address is subject to the - North Carolina Public Records Law and may be disclosed to third parties. • 435 Williams Court, Suite 100 Baltimore, IAD 21220 www synagro.com FEBRUARY 22, 2019 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2018 Annual Report for Permit No. WQ0000430 Dear NCDEQ: �CC�1�'GDPhlCR�1=f\IR1D1{�JI� w" r,0S AOORFSVILLR t,DGI ONAL OFFICE Synagro is submitting one copy and one electronic copy of the above referenced report on behalf of the City of Cherryville, NC. If you have any questions or need additional information, please do not hesitate to contact Larry Wright at (704) 435-1739 or Erik Bruce at (336) 703-8681. Sincerely, Kl-- a____ Derrick Shivar Environmental Compliance Manager Enclosures cc: Larry Wright, City of Chetryville Erik Bruce, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF CHERRYVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0000430 2018 ANNUAL REPORT City of Cherryville, NC Residuals Land Application Program 2018 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms, Residuals Analysis, & SAR Calculation Page 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: WO0000430 County Gaston Year 2018 Facility Name (as shown on permit) City of Cherryville WWTP NPDES No. NC0044440 Land Application Operator Synaaro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, "and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 7 Total number of fields utilized for land application during the year: 2 Total amount of dry tons applied during the year for all application sites: 79.37 Total number of acres utilized for land application during the year: 38.6 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2018 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T A 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .I I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the poss'bility-offines d imprisonment for knowing violations." o Larry Wright, Plant ORC & Plant Supervisor l I Permittee Name and Title (type or print) hignature of crnj4leM h Date _ Signature of Preparer* Date Signatur o and Applie Date (if different from Permittee) (if different from ermittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) 2018 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION IN NC CHERRYVILLE, NC HERRYVILLE, NC LIQUID DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS June 2018 620,000.00 G 79.37 D 72.00 YEARLY TOTAL 620,000.00 G 79.37 D 72.00 1/28/2019 SECTION 2 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Laboratory Facility Name: CHERRYVILLE, NC Waypoint Analytical Virginia Inc. NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 01/22/18 Date Composited Percent Solids 3.07 PARAMETERS (mg/kg dry weight) Arsenic 4.7 Cadmium <2 Mercury 0.941 Chromium 52.3 Copper 471 Lead 32.8 Molybdenum 8.08 Nickel 25.6 Selenium <5 Zinc 786 Total Phosphorus 16000 TKN 9420 Ammonia -Nitrogen 7790 Nitrate and Nitrite 216 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel pro pe and evaluated the information submitted. I am aware that there are significant penalties for submitting false in F ation, including the possibility of fines and imprisonment for knowing violations." X Date 2-1) - ZO 1 9 DENR FORM RSSF (512003) Printed: Monday - January 28, 2019 at 18:57:31 for: 2008 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0000430 Facility Name: CHERRYVILLE, NC NPDES# : NCO044440 or WQ# (residual only) WWTP Name: CHERRYVILLE Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 01/22/18 Date Composited Percent Solids 3.07 PARAMETERS (mg/kg dry weight) Aluminum 8030 Calcium 11000 Magnesium 2420 pH 7.10 Potassium 1680 Sodium 1700 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false informaton inelrr�dtng`lbe possibility of fines and imprisonment for knowing violations." M (SIGNAT441RE OF/PR N R - Data Not R ARER) or Data N`ot Required Date 2-0—Z019 DENR FORM RSSF-B (7/2002) Printed: Monday - January 28, 2019 at 19:04:53 for: 2008 01 Page: 1 of 2 Report Number: 18-023-0208 Account Number: 46442 Submitted By- Erik Bruce Send To: Synagro Central LLC/ Cherryville Mary Brewer 284 Boger Road Mocksville , NC 27028 • Waypoint� ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 a Fax 804-271-6446 www.waypointanalytical.com Project: Cherryville WWTP REPORT OFANALYSIS Date Sampled: 1/22/2018 09:00:00 Lab Number: 58182 Date Received: 01/23/2018 00:00 Sample Id : Cherryville WWTP RESULT RESULT QUANTITATION Date Reported: 01/30/2018 PARAMETER Total Solids 3.07 30700 100.0 R D 01/23/2018 14:30 METHOD SM-2540G Moisture" 96.92 100.0 RD 01/231201814:30 SM-2540G Total Kjeldahl Nitrogen 0.94 9420 50.0 R D 01/24/2018 09:00 SM-4500-NH3C-TKN Total Phosphorus 1.60 16000 100 MOS 01/25/2018 17:18 6010C Total Potassium 0.17 1680 100 MOS 01/25/2018 17:18 6010C Total Sulfur 1.02 10200 100 MOS 01/26/2018 13:59 6010C Total Calcium 1.10 11000 100 MOS 01/25/2018 17:18 6010C Total Magnesium 0.24 2420 100 MOS 01/25/2018 17:18 6010C Total Sodium 0.17 1700 100 MOS 01/25/2018 17:18 6010C Total Iron 27800 100 MOS 01/25/2018 17:18 6010C Total Aluminum 8030 100 MOS 01/25/2018 17:18 6010C Total Manganese 464 5.00 MOS 01/25/2018 17:18 6010C Total Copper 471 5.00 MOS 01/25/2018 17:18 6010C Total Zinc 786 5.00 MOS 01/25/2018 17:18 6010C Ammonia Nitrogen 0.78 7790. 50.0 R D 01/26/2018 08:45 SM-4500-NI3C Organic N 0.16 1630 0.005 R D 01/30/2018 11:03 CALCULATION Nitrate+Nitrite-N 216 2.45 MMT 01/25/2018 08:57 4500NO3F-2011 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or pail, nor may any reference be made to the work. the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Pauric McGroary Agronomist Page: 2 of 2 Report Number: 18-023-0208 Account Number: 46442 Submitted By: Erik Bruce Send To: Synagro Central LLC/ Chenyville Mary Brewer 284 Boger Road Mocksville , NC 27028 Waypo0 0 int.. ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project: Cherryville WWTP REPORT OFANALYSIS Date Sampled: 1/22/2018 09:00:00 Lab Number: 58182 Date Received: 01/23/2018 00:00 Sample Id : Cherryville WWTP RESULT QUANTITATION LIMIT Date Reported: 01/30/2018 ANALYSIS Total Cadmium <2.00 2.00 MOS METHODRESULT 01/26/2018 13:59 6010C Total Chromium 52.3 5.00 MOS 01/25/2018 17:18 6010C Total Nickel 25.6 5.00 MOS 01/25/2018 17:18 6010C Total Lead 32.8 5.00 MOS 01/25/2018 17:18 6010C Total Arsenic 4.70 3.00 MOS 01/25/2018 17:18 6010C Total Mercury 0.941 0.400 MOS 01/29/2018 14:23 SW-7471B Total Selenium <5.00 5.00 MOS 01/25/2018 17:18 6010C pH ' 7.1 1.0 JM 01/24/2018 09:00 9045D Total Molybdenum 8.08 5.00 MOS 01/25/2018 17:18 6010C Comments: NC CERT#257, SC CERT#9300 7001 SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. P Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising. news release, or other public announcements without obtaining our prior written authorization. Pauric McGroary Agronomist SAMPLING LOG # t� lllllllllililllllllll llilllllllllllll!11111111111111111111111111123 02°8 „ A 12 L fcEl,6401-23 ®Irk (�[�ls`LYS9 7621 �/�/r Svnagro Central LLC/ Cherrwill© °1-23-2018 9 � A���Q3 Cherrwille WWTP Richmor A�1 13:42:58 ECORD CUSTOMER: SYINAG O ® 804/743 I attest that the proper neru act, npling procedures PROJECT MANAGER: < < — c-'j c were used during the collection of these samples. Phone: (3.3 ) (2 J-e. SAMPLER' --- A & L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAB # SAMPLE I.D. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED GIN yyMQ ri.l 7CIi� �7��-� 5�� t��-e 1 i1z� 9 Av— 1 c C�;� l' Relinquished by Sampler: Date Time Recieved by: REMARKS: Zln,� `,/z. L 3 - oa Relinquished by: bat Time Recieved by: � 23 Relinquished by: Dat Time Recieved by: SPECIAL INSTRUCTIONS: <%A For V'`' � monitoring purposes. PO#: SAMPLE ANALYSIS REQUEST I.D. SL1 SL2 NHQ N NO3 N Organic Cd Cr Ni Pb As Hg Se pH CaCequO3 SolidsVolatile Mo Cl NO N Gk_�T 1 (�A l WLa'C� -e yvo e0 P� AO 140 P 900 10 SLI: Total Solids (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SLi plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date ReportRange Ratio 2008-01-LIQ-NC CHERRYVILLE, NC LIQUID 1/22/2018 1/1/2018-12/31/2018 0.6680 Na mg/I = (Na mg/kg x % Solids) = 100 = (1700 x 3.0700) _ 100 = 52.19 Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (11000 x 3.0700) _ 100 = 337.7 Mg mg/I = (mg mg/kg x % Solids) + 100 = (2420 x 3.0700) _ 100 = 74.294 Na meq = Na mg/I _ Molec.Wgt.Na = 52.19 = 23 = 2.26913 Ca meq = Ca mg/I = Molec.Wgt.Ca = 337.7 _ 20 = 16.885 Mg meq = Mg mg/1 = Molec.Wgt.Mg = 74.294 = 12 = 6.19117 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.26913 _ SgrRoot[0.5(16.885+6.19117)] = 0.668025 Printed: 1 /3012019 Page 1 14:45 SECTION 3 FACILITY NAME: CHERRYVILLE, NC OWNER: WAYNE GILBERT SITE #: NC LT 00120 FIELD# : LT 00120 0002 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: W00000430 ANNUAL DRY TONS APPLIED: 57.15 OPERATOR: WAYNE GILBERT CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 27.60 ACRES PERMITTED: 27.60 Page : 1 Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or or Wet Tons (WT) (specify) Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 6/19/18 111,600.00 (G) 4043.478 3.07 0.518 CHL DRY 0-<1/2" SUR 0.5 0.30 9,420.0 p 7,790.00 p 216.00 p 4 000 SOYBEANS 6/20/18 161,200.00 (G) 5840.580 3.07 0.748 CHL DRY 0-<1/2" SUR 0.5 0.30 9,420.0 p 7,790.00 p 216.00 p 4600 I SOYBEANS 6/21/18 74,400.00 (G) 2695.652 3.07 0.345 CHL DRY 0-<I/2" SUR 0.5 0.30 9,420.0 p 7,790.00 p 216.00 p 4600 I SOYBEANS 6/22/18 99,200.00 (G) 3594.203 3.07 0.460 CHL DRY 0-<1/2" SUR 0.5 0.30 9,420.0 p 7,790.00 p 216.00 p 4600 SOYBEANS Jun-18 446,400.00 (G) 16,173.913 Total Gallons/Ac: 16,173.91 Total Wet Tons/Ac: Total Cubic Yds/Ac: 0.00 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annual lbs/acre 19 0.019 0.008 0.217 1.950 0.136 0.004 0.033 0.106 0.021 3.255 66.26 Cumulative lbs/acre 0.139 0.071 2.237 20.924 1.257 0.031 0.532 1.851 0.127 31.138 , PAN Limit (lbs/acre) 1st Crop/2nd Crop �. 734�1 .Permit 167 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 1339.0 267.9 15.0 375.0 89.0 2500.0 " CHL = CHERRYVILLE, NC LIQUID (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required %= percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2019 FACILITY NAME: CHERRYVILLE, NC OWNER: WAYNE GILBERT SITE #: NC LT 00120 FIELD# : LT 00120 0003 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: WQ0000430 ANNUAL DRY TONS APPLIED: 22.22 OPERATOR: WAYNE GILBERT CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 11.00 ACRES PERMITTED: 11.00 Page: 1 Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 6/19/18 62,000.00 (G) 5636.364 3.07 0.722 CHL DRY 0-<1/2" SUR 0.5 0.30 9,420.0 p 7,790.00 p 216.00 p F 46 00 I SOYBEANS 6/20/18 37,200.00 (G) 3381.818 3.07 0.433 CHL DRY 0-<1/2" SUR 0.5 0.30 9,420.0 p 7,790.00 p 216.00 p 4600 Ij SOYBEANS 6/21/18 74,400.00 (G) 6763.636 3.07 0.866 CHL SUR 0.5 0.30 9,420.0 p 7,790.00 p 216.00 p 4600 SOYBEANS Jun-18 173,600.00 (G) 15,781.818 Total Gallons/Ac: 15,781.82 Total Wet Tons/Ac: Total Cubic Yds/Ac: 0.00 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annual lbs/acre 19 0.019 0.008 0.211 1.903 0.133 0.004 0.033 0.103 0.020 3.176 64.65 Cumulative lbs/acre 0.120 0.060 1.860 18.102 1.015 0.026 0.514 1.682 0.105 25.974 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 170 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 CHL = CHERRYVILLE, NC LIQUID x fir( l (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = pp- or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2019 SECTION 4 din 1U Summit Environmental Technologies, Inc. 3310 Win St. r,��14r�rdhtE;dTAL�ffY. ddLt?cl_s, W , Cuyahoga Falls, Ohio 44223 Analytim-1 r-,74:twafories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htty.-Mvwiv.settek.com January 31, 2018 Erik Bruce Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Cherryville WWTP Dear Erik Bruce: Order No.: 18011035 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/23/2018 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Oklahoma 9940, Oregon OH2O0001, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH009232011-I, Virginia VELAP 9456, Washington C891 Page 1 of 27 Summit Environmental Technologies, Inc. Case Narrative frSUMMIT 3310 Win St. FHVIRONMEN'rAL'lECHNOLMES, MQ_ Cuyahoga Falls, Ohio 44223 WO#: 18011035 ArvalytTrs1 L-Rbaratorles TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htW.-Iliviviv.settek.coni Date: 1/31/2018 CLIENT: Synagro Project: Cherryville WWTP WorkOrder Narrative: 18011035: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. State Certificates and Scopes of Accreditation are attached as applicable. Results provided in this report for any parameter not listed on the Scope of Accreditation should be considered "not certified." The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 18011035-OOIA SVOC-BNA TCLP(8270D): Sample exhibited low recovery for Surrogate: phenol-d6 due to matrix effect. Analytical Sequence QC Notes: ccv 40ng S8- svoc-mstr_s(8270): CCV exhibited high recovery for Hexachloroethane. Associated samples are ND for these analytes. Original Page 2 of 27 two UM Summit Environmental Technologies, In Qualifiers and Acronyms 3310 Win 5 E`SVIRC1tJPdEhITt.L3'�G9ir.[7L�Gi=S,INC. CtryahogaFalls, Ohio 4421 WO#: 18011035 A1P„ I,vUcal LhhoraiorfPf, TEL: (330) 253-8211 FAX.- (330) 253-446 Website: htto.- Avivw.settek.co Date: 1/31/2018 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. * The result exceeds the Regulatory Limit or Maximum Contamination Limit. m Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GUMS Analysis was performed. B/M]3+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+), S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MiuCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 27 Summit Environmental Technologies, Inc. 12SUMM111 3310 Win St. FNIVIRONIa1ENTALTECHNOL(�GlcS,B`dC. Cuyahoga Falls, Ohio44223 Analytirisl'iRboratoriet, TEL: (330) 253-8211 FAX: (330) 253-4489 Website: httP.-Avwiv.settek.com CLIENT: Synagro Project: Cherryville WWTP Lab SampleID Client Sample LD 18011035-001 Cherryville WWTP (2017 Material) Tag No Date Collected 1/22/2018 10:00:00 AM Workorder Sample Summary WO#: 18011035 Date Received 1/23/2018 7:45:00 AM 31-Jan-18 Matrix Sludge Page 4 of 27 ®� Summit Farvironmenial Technologies, Inc.SumDATES REPORT 3310 Win St. ENVIROIJI,IENTALTECH'JOLOni=—S, INC. Cuyahoga Falls, Ohio 44223 Analyllcal Laboratanes Ta: (330) 253-8211 FAX- (330) 253-4489 WO#: 18011035 Wehsite: htin:/hve,iv.settek.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 18011035-OOIA Chenyville WWTP (2017 1/22/2018 10:00:00 AM Sludge Ignitability of Solids (SW-846: 1030) 1/25/2018 1:00:00 PM Material) pH (SW9045D) 1/30/2018 1:08:00 PM Reactive Cyanide (9014/7.3.3.2)-Solid 1/25/2018 12:04:00 PM Reactive Sulfide (9034)/7.3.4.2 1/25/2018 12:04:00 PM TCLP Herbicides Analysis (SW1311/81/25/2018 6:00:00 PM 1/26/2018 12:30:00 PM 1/30/2018 2:49:00 PM TCLP Mercury Analysis (SW1311/7471/25/2018 6:00:00 PM 1/26/2018 12:45:00 PM 1/26/2019 4:18:00 PM TCLP Metals Analysis (SW 1311160101125/2018 6:00:00 PM 1/26/2018 12:00:00 PM 1/31/2018 12:46:16 AM TCLP Pesticides Analysis (SW 1311/8(1/25/2018 6:00:00 PM 1/29/2018 9:00:00 AM 1/29/2018 8:32:00 PM TCLP Semi-Volatiles Analysis 1/25/2018 6:00:00 PM 1/29/2018 7:00:00 AM 1/29/2018 9:20:00 PM (S W 1311/8270) TCLP Volatiles Analysis 1/29/2018 6:00:00 PM 1/30/2018 7:29:00 PM Original Page 5 of 27 asurArolot3310 Summit Environmental Technologies, Inc. Win St. Analytical Report FW[RONIelENTALTECiltdc71,CG1ES, INC, , In Cuyahoga Falls, Ohio44223 (base report) Armlyffral U?baratories: TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 18011035 Website: htip://wiviv.settek.com Date Reported: 1/31/2018 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM Lab ID: 18011035-001A Project: Cherryville WWTP Client Sample ID Cherryville WWTP (2017 Material) Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: EAM TCLP MERCURY ANALYSIS (SW131117470) TCLP Mercury ND 0.00200 mg/L 1 1/26/2018 4:18:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW3010A Analyst: KMS TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND 0.500 mg/L 1 1/31/2018 12:46:16 AM TCLP Barium(Ba) ND 5.00 mg/L 1 1/31/2018 12:46:16 AM TCLP Cadmium(Cd) ND 0.100 mg/L 1 1/31/2018 12:46:16 AM TCLP Chromium(Cr) ND 0.200 mg/L 1 1/31/2018 12:46:16 AM TCLP Lead(Pb) ND 0.500 mg/L 1 1/31/2018 12:46:16 AM TCLP Selenium(Se) ND 0.0500 mg/L 1 1/31/2018 12:46:16 AM TCLP Silver(Ag) ND 0.500 mg/L 1 1/31/2018 12:46:16 AM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270D SW3510C Analyst: BJH TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.0800 mg/L 2 1/29/2018 9:20:00 PM 2,4,5-Trichlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM 2,4,6-Trichlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM 2,4-Dinitrotoluene ND 0.0400 mg/L 2 1/29/2018 9:20:00 PM o-Cresol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM m/p-Cresol(s) ND 0.200 mg/L 2 1/29/2018 9:20:00 PM Cresols, Total ND 4.00 mg/L 2 1/29/2018 9:20:00 PM Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 1/29/2018 9:20:00 PM Hexachlorobenzene ND 0.0400 mg/L 2 1/29/2018 9:20:00 PM Hexachloroethane ND 0.0800 QC+ mg/L 2 1/29/2018 9:20:00 PM Nitrobenzene ND 0.0800 mg/L 2 1/29/2018 9:20:00 PM Pentachlorophenol ND 0.200 mg/L 2 1/29/2018 9:20:00 PM Pyridine ND 0.200 mg/L 2 1/29/2018 9:20:00 PM Surr: 2-Fluorophenol 19.9 10 - 109 %Rec 2 1/29/2018 9:20:00 PM Surr: Phenol-d6 9.28 10 - 109 S %Rec 2 1/29/2018 9:20:00 PM Surr: Nitrobenzene-d5 44.9 19 - 120 %Rec 2 1/29/2018 9:20:00 PM Surr: 2,4,6-Tribromophenol 24.0 10 - 120 %Rec 2 1/29/2018 9:20:00 PM Surr: 2-Fluorobiphenyl 59.8 22 - 117 %Rec 2 1/29/2018 9:20:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds O RSD is greater than RSDlimit PL Permit Limit Original RL Reporting Detection Limit Page 6 of 27 Summit Environmental Technologies, Inc. Analytical Report m5s"Mmlor 3310 Win St. FUVIROWAENITALTECWJ0L0GIE5,.WC;. Cuyahoga Falls, Ohio44223 (base report) Artaryticsl LRbioratvrie� TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 18011035 Website: http://wiviv.sette%com Date Reported: 1/31/2018 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM Lab ID: 18011035-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP (2017 Material) Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) Surr: p-Terphenyl-d14 63.8 34- 116 NOTES: Sample exhibited low recovery for Surrogate: phenol-d6 due to matrix effect. TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 76.6 Surr: DCB 62.6 SW8270D SW351OC Analyst: BJH %Rec 2 1/29/2018 9:20:00 PM SW8081 SW351OC Analyst: JBN 0.0200 mg/L 2 1/29/2018 8:32:00 PM 0.0400 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 0.00200 mg/L 2 1/29/2018 8:32:00 PM 10 - 119 %Rec 2 1/29/2018 8:32:00 PM 10 - 119 %Rec 2 1/29/2018 8:32:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP HERBICIDES ANALYSIS (SW1311/8151) 2,4-D ND 1.00 2,4,5-TP ND 0.500 d Surr: DCAA ill 20 - 140 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1,2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND SW8151A SW8151A Analyst: JBN mg/L 1 1/30/2018 2:49:00 PM mg/L 1 1/30/2018 2:49:00 PM %Rec 1 1/30/2018 2:49:00 PM SW8260B SW1311M Analyst: MES 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.250 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM 0.0500 mg/L 10 1/30/2018 7:29:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds O RSD is greater than RSDlimit PL Permit Limit Original RL Reporting Detection Limit Page 7 of 27 Summit Environmental Technologies, Inc. 3310 Win St. Analytical Report lEsummiffir FKVIROMAENTALTECWJOLRG:ES,VIC,. Cuyahoga Falls, Ohio44223 (base report) Armlytical Labarerorie5 TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 18011035 Website: htip:/hviviv.settek.com Date Reported: 1/31/2018 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/22/2018 10:00:00 AM Lab ID: 18011035-OOIA Project: Cherryville WWTP Client Sample ID Cherryville WWTP (2017 Material) Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260B SW1311M Analyst: MES TCLP VOLATILES ANALYSIS Trichloroethene ND 0.0500 mg/L 10 1/30/2018 7:29:00 PM Vinyl chloride ND 0.0200 mg/L 10 1/30/2018 7:29:00 PM Surr: 4-Bromofluorobenzene 93.4 70 - 130 %Rec 10 1/30/2018 7:29:00 PM Surr: Dibromofluoromethane 99.8 70 - 130 %Rec 10 1/30/2018 7:29:00 PM Surr: Toluene-d8 97.6 70 - 130 %Rec 10 1/30/2018 7:29:00 PM RCI-SOLID-W/ IGNITABILITY1030 SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.500 mg/Kg 1 1/25/2018 12:04:00 PM RCI-SOLID-W/ IGNITABILITY1030 SW1030 Analyst: AJT IGNITABILITY OF SOLIDS (SW-846: 1030) Ignitability non-flammable 1 1/25/2018 1:00:00 PM RCI-SOLID-W/ IGNITABILITY1030 SW9045D Analyst: DHC PH (SW9045D) pH 7.2 s.u.@19.4C 1 1/30/2018 1:08:00 PM RCI-SOLID-W/ IGNITABILITY1030 SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive 30.0 25.0 mg/Kg 1 1/25/2018 12:04:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds O RSD is greater than RSDlimit PL Permit Limit Original RL Reporting Detection Limit Page 8 of 27 Summit Environmental Technologies, Inc. Accreditation Program m9summiwr 3310 Win St. Anal teS Report y P FNIVIR©WtIENTAL`i`ECW4QLdG:ES,NQ. Cuyahoga Falls, Ohio44223 Ana;ytlaal Lpbararorie,, TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 18011035 Website: http://www.settek.com 31-Jan-18 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC WW_SCM Sample ID Matrix Test Name Analyte Status 18011035-OOIA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Sludge TCLP Herbicides Analysis (SW1311/8151) 2,4,5-TP A Sludge TCLP Herbicides Analysis (SW1311/8151) 2,4-D A Sludge TCLP Herbicides Analysis (SW1311/8151) DCAA A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW131116010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) 2,2',3,3',4,4',5,5',6,6'- A Decachlorobiphenyl Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Tetrachloro-m-xylene A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Tribromophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2-Fluorobiphenyl A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2-Fluorophenol A Key Key NC WW SCM A Accredited NC WW SCM U Unavailable Original #1 Page 9 of 27 Summit Environmental Technologies, Inc. Accreditation Program In SUMMINIL 3310 Win St. Anal teS Report Y P FE9rIRDhlI+1EN`t,�.L :El litVO�RG:c�, 3P2C Cuyahoga Falls, Ohio 44223 Anaiytf—,F1 Lsboratorfes TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 18011035 Wehsite: hap.-Ilivivrv.settek.con: 31-Jan-18 Client: Synagro State: NW Project: Cherryville WWTP Program Name: NC WW SCM Sample ID Matrix Test Name Analyte Status 18011035-OOIA Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2-Methylphenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 3,4-Methylphenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene-d5 A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Phenol-d6 A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) p-Terphenyl-d14 A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis 4-Bromofluorobenzene A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Dibromofluoromethane A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Toluene-d8 A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM U Unavailable Original #1 Page 10 of 27 'ETSuninutGivironmentalTechnologies, Inc. S,310 Win St. QC SUMMARY REPORT ENVIRON AL TEC93JOLOOIE, INCi Cuyahoga Falls, Ohio 44223 <l.halytica/ taboraforfes TEL: (330) 253-8211 FAX." (330) 253-4489 WO#: 18011035 Website: ho.,Mvun .settekcom 31-Jair-18 Client: Synagro Project: Cherryville WWTP BatchID: 30581 Sample ID MB-30581 SampType: MBLK TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: PBS Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392423 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ TCLP Mercury ND 0.00200 Sample ID LCS30581 SampType: LCS TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: LCSS Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392424 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00467 0.00200 0.00400 0 117 80 120 Sample ID 18011013-001AMS SampType: MS TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: BatchQC Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392426 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ TCLP Mercury 0.00541 0.00200 0.00400 0.0000600 134 75 126 S Sample ID 18011013-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: BatchQC Batch ID: 30581 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392427 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00513 0.00200 0.00400 0.0000600 127 75 125 0.00541 5.31 20 S Qualifiers: + Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. J ND Analyte detected below quantitation limits Not Detected M 0 Manual Integration used to determine RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 11 of 27 Insummogr Summit Environmental Technologies,. QC SUMMARYREPORT33! 100 Win St. Sr. ENVIRQN6IE4TAL TECHRdOLOG1Z8,:NC Cuyahoga Falls, Ohio 44223 Anaiytfcaf L'aborsiories TEL: (330) 253-8211 FAX- (330) 2534489 WO#: 18011035 Wehsite: http:Uwrnw.seltek.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchED: 30581 Sample ID 18011013-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: mg/L Prep Date: 1/26/2018 RunNo: 79934 Client ID: BatchQC Batch ID: 30681 TestNo: SW7470A SW7470A Analysis Date: 1/26/2018 SegNo: 1392427 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PI, Permit Limit R RPD outside accepted recovery limits Page 12 of 27 - ®� Snnn:if Envirarmental Technologies, Inc.Mfl 3310 Win St. QC SUMMARY REPORT Er.VIRONIAE14TALTEC141JOLOG1E-9, INC Cuyahoga Falls, Ohio 44223 AnalylFcal tnborstorFes TEL: (330) 253-8211 FAX.' (330) 253-4489 WO#: 18011035 Website: hfto:/hvwiv.settekcom 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchlD: 30592 Sample ID mb-30592 SampType: mblk TestCode: tclp-svoc-her Units: mg/L Prep Date: 1/26/2018 RunNo: 80052 Client ID: PBS Batch ID: 30592 TestNo: SW8151A SW8151A Analysis Date: 1/30/2018 SegNo: 1397310 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua[ 2,4-D ND 1.00 0 0 d 2,4,5-TP ND 0.500 0 0 d Surr. DCAA 542 500.0 108 20 140 Sample ID Ics-30592 SampType: Ics TestCode: tclp-svoc-her Units: mg/L Prep Date: 1/26/2018 RunNo: 80052 Client ID: LCSS Batch ID: 30592 TestNo: SW8151A SW8151A Analysis Date: 1/30/2018 SegNo: 1397311 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] 2,4-D 2,4,5-TP Surr. DCAA ND 1.00 0.500 0 94.3 62.6 125 ND 0.500 0.500 0 94.3 52.5 128 539 500.0 108 20 140 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitati on range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 13 of 27 'In summlir Sunnnit Environmental Technologies, Inc. 3310 Win St. VWIROMdENTAL TECIMOLOOIES, INC Cuyahoga Falls, Ohio 44223 Analgtical Laborslaries TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: h1tm1A-,w.settek.com QC SUMMARY REPORT WO#: 18011035 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30600 iample ID 18011034-001AMS SampType: MS TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/29/2018 RunNo: 80053 ,lient ID: BatchQC Batch ID: 30600 TestNo: SW8270D SW3510C Analysis Date: 1/29/2018 SegNo: 1397326 lnalyte Result PQL SPK value SPK Ref Val % REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.684 0.0800 2,4,5-Trichlorophenol 0.837 0.200 2,4,6-Trichlorophenol 0.754 0.200 2,4-Dinitrotoluene 0.738 0.0400 o-Cresol 0.513 0.200 mlp-Cresol(s) 0.490 0.200 Cresols, Total ND 4.00 Hexachloro-1,3-butadiene 0.762 0.0160 Hexachlorobenzene 0.797 0.0400 Hexachloroethane 0.792 0.0800 Nitrobenzene 0.679 0.0800 Pentachlorophenol 0.720 0.200 Pyridine ND 0.200 Surr. 2-Fluorophenol 0.373 Surr. Phenol-d6 0.174 Surr: Nitrobenzene-d5 0.746 Surr. 2,4,6-Tribrom ophenol 0.665 Surr. 2-Fluorobiphenyl 1.03 Surr. p-Terphenyl-d14 1.04 NOTES: MS exhibited low recovery for Surrogate: phenol-d6 due to matrix effect. 0.8000 0 85.6 15.2 124 0.8000 0 105 30.6 152 0.8000 0 94.2 27.6 150 0.8000 0 92.2 58 141 0.8000 0 64.1 26.9 132 0.8000 0 61.2 27.4 134 1.600 0 62.6 27.6 132 0.8000 0 95.2 -5.3 156 0.8000 0 99.6 54.3 142 0.8000 0 99.0 1.92 131 0.8000 0 84.8 21 135 0.8000 0 90.0 47.4 134 0.8000 0 24.3 -10.3 64.2 1.000 37.3 9.77 146 1.000 17.4 20.7 130 1.000 74.6 13.9 156 1.000 66.5 27.3 183 1.000 103 21.4 153 1.000 104 54.8 154 QC+ S Qualifiers: • Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitati on range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 14 of 27 ®� Summit Environmental Technologies, Inc. suma3310 Win St. ErWIRONIAENTAL TECHNOLDGIES,_INC Cuyahoga Falls, Ohio 44223 Analytical La66rz1ories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: hun:/hviviv.setlek.com QC SUMMARY REPORT WO#: 18011035 31-Jan-18 Client: Synagro Project: Cheryville WWTP BatchED: 30600 Sample ID 18011034-o01AMSD SampType: MSD TestCode: SVOC-BNA T Units: mg/L Prep Date: 1/29/2018 RunNo: 80053 Client ID: BatchQC Batch ID: 30600 TestNo: SW8270D SW3510C Analysis Date: 1/29/2018 SegNo: 1397327 4nalyte Result PQL SPK value SPK Ref Val % REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.627 0.0300 2,4,5-Trichlorophenol 0.730 0.200 2,4,6-Trichlorophenol 0.657 0.200 2,4-Dinitrotoluene 0.655 0.0400 o-Cresol 0.449 0.200 m/p-Cresol(s) 0.448 0.200 Cresols, Total ND 4.00 Hexachloro-1,3-butadiene 0.694 0.0160 Hexachlorobenzene 0.700 0.0400 Hexachloroethane 0.733 0.0800 Nitrobenzene 0.608 0.0800 Pentachlorophenol 0.616 0.200 Pyridine ND 0.200 Surr. 2-Fluorophenol 0.295 Surr. Phenol-d6 0.146 Surr. Nitrobenzene-d5 0.566 Surr. 2, 4,6-Tdbrom ophenol 0.490 Surr: 2-Fluorobiphenyl 0.827 Surr. p-Terphenyl<14 0.804 NOTES: MSD exhibited low recovery for Surrogate: phenoA6 due to matrix effect. 0.8000 0 78.4 15.2 124 0.6844 8.72 30 0.8000 0 91.2 30.6 152 0.8368 13.7 30 0.8000 0 82.2 27.6 150 0.7536 13.7 30 0.8000 0 81.8 58 141 0.7380 11.9 30 0.8000 0 56.1 26.9 132 0.5128 13.3 30 0.8000 0 56.0 27.4 134 0.4896 8.96 30 1.600 0 56.0 27.6 132 0 0 30 0.8000 0 86.8 -5.3 156 0.7616 9.23 30 0.8000 0 87.6 54.3 142 0.7968 12.9 30 0.8000 0 91.7 1.92 131 0.7924 7.76 30 QC+ 0.8000 0 76.0 21 135 0.6788 11.1 30 0.8000 0 77.1 47.4 134 0.7204 15.6 30 0.8000 0 19.6 -10.3 64.2 0 0 30 1.000 29.5 9.77 146 0 1.000 14.6 20.7 130 0 S 1.000 56.6 13.9 156 0 1.000 49.0 27.3 183 0 1.000 82.7 21.4 153 0 1.000 80.4 54.8 154 0 Qualifiers: ' Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 15 of 27 Stanntit Environmental Technologies, Inc. Insummly- 3310 Witt St. ENVIRONMENTAL TEC"HOI.GGIES,:NC Cuyahoga Falls, Ohio 44223 Anafyllcal laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: hup:11Www.set1ek.cotn QC SUMMARY REPORT WO#: 18011035 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: 30617 iample ID mb-30617 SampType: MBLK TestCode: tclp-voc-mstr Units: mg/L Prep Date: 1/2912018 RunNo: 80054 ;lient ID: PBS Batch ID: 30617 TestNo: SW8260B SW1311M Analysis Date: 1/30/2018 SegNo: 1397357 lnalyte Result PQL SPK value SPK Ref VaI % REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ 1,1-Dichloroethene ND 0.0500 1,2-Dichloroethane ND 0.0500 MEK ND 0.250 Benzene ND 0.0500 Carbon tetrachloride ND 0.0500 Chlorobenzene ND 0.0500 Chloroform ND 0.0500 Tetrachloroethene ND 0.0500 Trichloroethene ND 0.0500 Vinyl chloride No 0.0200 Surr.4-Bromofluorobenzene 496 Surr. Dibromofluoromethane 482 Surr: Toluene-d8 499 500.0 99.1 70 130 500.0 96.4 70 130 500.0 99.9 70 130 Qualifiers: ' Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded 7 Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 16 of 27 Summit Environmental Technologies, Inc. In Summit 3310WinSt. Q!SUMMARY REPORT ENVIRONIdENTALTECBNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Armlytical traboralorles TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 18011035 Website: hap:IA-w..settek.com 31-Jan-18 Client: Synagr0 Project: Cherryville WWTP BatchID: 30617 Sample ID 18010967-001ams SampType: MS TestCode: tclp-voc-MST Units: mg/L Prep Date: RunNo: 80027 Client ID: BatchQC Batch ID: 30617 TestNo: SW8260B SW1311M Analysis Date: 1/30/2018 SegNo: 1397295 Analyte Result PQL SPK value SPK Ref Val %REC Lowt-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.221 0.0500 0.200 0 110 39.9 160 1,2-Dichloroethane 0.191 0.0500 0.200 0 95.3 42.5 157 MEK 1.02 0.250 1.00 0.0476 96.8 16.6 227 Benzene 0.195 0.0500 0.200 0 97.6 38.1 155 Carbon tetrachloride 0.196 0.0500 0.200 0 98.1 40.8 162 Chlorobenzene 0.191 0.0500 0.200 0 95.6 35.7 168 Chloroform 0.199 0.0500 0.200 0 99.3 18.3 199 Tetrachloroethene 0.205 0.0500 0.200 0 102 10 261 Trichloroethene 0.194 0.0500 0.200 0 97.0 23.8 175 Vinyl chloride 0.171 0.0200 0.200 0 85.6 10 165 Surr.4-Bromofluorobenzene 526 500.0 105 84.6 130 Surr. Dibromofluoromethane 505 500.0 101 71.4 127 Surr. Toluene -dB 515 500.0 103 74.6 127 Sample ID 18010967.001amsd SampType: MSD TestCode: tclp-voc-MST Units: mg/L Prep Date: RunNo: 80027 Client ID: BatchQC Batch ID: 30617 TestNo: SW8260B SW1311M Analysis Date: 1/30/2018 SegNo: 1397297 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.227 0.0500 0.200 0 113 39.9 160 0.221 2.54 25 1,2-Dichloroethane 0.194 0.0500 0.200 0 96.8 42.5 157 0.191 1.56 25 MEK 1.02 0.250 1.00 0.0476 97.1 16.6 227 1.02 0.230 25 Benzene 0.197 0.0500 0.200 0 98.5 38.1 155 0.195 0.897 25 Qualifiers: " Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H MC Holding times for preparation or analysis exceeded Value is below Minimum Compound Limit. J ND Analyte detected below quantitation limits Not Detected M 0 Manual Integration used to determine RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 17 of 27 Summit F.trvironmenla/Technologies, Lva!fsum 3310 Win St QC SUMMARY REPORT ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 WO#: 18011035 Analytical LAbormarlee TEL: (330) 253-8211 FAX..- (330) 253-4489 Wehsite: hun.-A }n,vettek.com 31-Jan-18 Client: Synagro Project: Chenyville WWTP BatchID: 30617 ;ample ID 18010967-001amsd SampType: MSD TestCode: tclp-voc-MST Units: mg/L Prep Date: RunNo: 80027 ;lient ID: BatchQC Batch ID: 30617 TestNo: SW82608 SW1311M Analysis Date: 1/30/2018 SegNo: 1397297 lnalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.198 0.0500 0.200 0 99.1 40.8 162 0.196 1.03 25 Chlorobenzene 0.192 0.0500 0.200 0 96.1 35.7 168 0.191 0.600 25 Chloroform 0.201 0.0500 0.200 0 100 18.3 199 0.199 1.04 25 Tetrachloroethene 0.209 0.0500 0.200 0 105 10 261 0.205 2.18 25 Trichloroethene 0.197 0.0500 0.200 0 98.7 23.8 175 0.194 1.79 25 Vinyl chloride 0.198 0.0200 0.200 0 98.9 10 165 0.171 14.4 25 Surr.4-Bromofluorobenzene 522 500.0 104 84.6 130 0 25 Surr. Dibromofluoromethane 505 500.0 101 71.4 127 0 25 Surr: Toluene-d8 514 500.0 103 74.6 127 0 25 Qualifiers: . Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PI, Permit Limit R RPD outside accepted recovery limits Page 18 of 27 SunmritEuvironmentalTechnologies, Inc. QC SUMMARY 77tT nLs7Z•O77T 3310 Win St. S lJ 1V11WiL- R 1 REPORT 1 EP.VIRON1,IENTALTIICliNOLDOI_�, INC Cuyahoga Falls, Ohio 44223 Arraly ilcal L'7borareries TEL: (330) 253-8211 FAX, (330) 253-4489 WO#: 18011035 Websile: him.-lAt,",.settek.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: R79880 Sample ID MB-R79880 SampType: MBLK TestCode: Cyanide,Rea Units: mg/L Prep Dale: RunNo: 79880 Client ID: PBW Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390960 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive ND 0.500 Sample ID LCS-R79880 SampType: LCS TestCode: Cyanide,Rea Units: mg1L Prep Date: RunNo: 79880 Client ID: LCSW Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390962 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 0.987 0.500 1.000 0 98.7 85 115 Sample ID 18010875-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 Client ID: BatchQC Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390965 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] Cyanide, Reactive 1.08 0.500 1.000 0 108 81.3 118 W NOTES: Sample was received not meeting proper temperature requirements. Sample ID 18010875-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 Client ID: BatchQC Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390966 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit oust Qualifiers: " Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded 7 Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 19 of 27 ®��' /� �� Summit Etrvironmenlal Technologies, Inc.ffl QC SUMMARY REPORT 3310 Wur St. rNVIe7ONh1ENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Arralyfical Iaboraiaries TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 18011035 Website: httn:/At,imv..vettek.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: R79880 iample ID 18010875-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 79880 ;lient ID: BatchQC Batch ID: R79880 TestNo: SW9014 Analysis Date: 1/25/2018 SegNo: 1390966 knalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 1.07 0.500 1.000 0 107 81.3 118 1.075 0.186 10 W NOTES: Sample was received not meeting proper temperature requirements. Qualifiers: . Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSDisgreater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 20 of 27 _ SumnritEnvironmental Technologies, Inc.In SUMM1.7/'��y SUMMARY 77�7 7�L�pOq�r�, 3310 Win St. QC S lJ lr AR REPORT 1 EIVVIROt4h1EIJTALTECNtJOL4)OI'cS, INC Cuyahoga Falls, Ohio 44223 Analytical kavzoraforle5 TEL: (330) 253-8211 FAX., (330) 2534489 WO#: 18011035 Websile: htln:/Rvnnv.senekcom 31-Jart-18 Client: Synagro Project: Cherryville WWTP BatchID: R79884 'ample ID LCS-R79884 SampType: LCS TestCode: Ignitability_S Units: Prep Date: RunNo: 79894 ;lient ID: LCSS Batch ID: R79884 TestNo: SW1030 Analysis Date: 1/2512018 SegNo: 1391034 knalyte Result PQL SPK value SPK Ref Val % REC Lowl-imit Highl-imit RPD Ref Val % RPD RPDLimit Qua] Ignitability 6.22 7.240 0 85.9 70 130 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 21 of 27 'IE _ Stmmtit Environmental Technologies, Inc. (��-t SUMMARY t T Tl� �iA R 77 �T REPORT 1 3310 Win St. QC tJ lJ 1Wll�lAR 1 ENVIRONIdDITAL TECHt7OI-JOWE_S,WC Cuyahoga Falls, Ohio 44123 t1.RalpiiFal L-ebarsiorie. TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 18011035 Websile: http:Asni v.seltek.com 31-Jan-18 Client: Synagro Project: CheryvilleWWTP BatchED: R79888 Sample ID MB-R79888 SampType: MBLK TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: PBW Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391078 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive ND 25.0 Sample ID LCS-R79888 SampType: LCS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: LCSW Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391079 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4710 25.0 4800 0 98.1 85 115 Sample ID 18010875-001AMS SampType: MS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: BatchQC Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391081 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4860 25.0 4800 0 101 75 125 W NOTES: Sample was received not meeting proper temperature requirements. Sample ID 18010875-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 Client ID: BatchQC Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/2512018 SegNo: 1391082 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qua] Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantization range H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. J ND Analyte detected below quantitation limits Not Detected M 0 Manual Integration used to determine RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 22 of 27 UMM11Sannnil Errviramrenlal 3310Win SSfrTechno.. QC SUMMARY REPORT EEa\1IR0N&1ENTAL TECUNCLOGIES, INC Cuyahoga Falls, Ohio 44223 Arralyllcal l rrbaraiories TFL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 18011035 Websire: hup.-Minwv.settek.com 31-Jmt-18 Client: Synagro Project: Cherryville WWTP BatchED: R79888 Sample ID 18010875-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 79888 :lient ID: BatchQC Batch ID: R79888 TestNo: SW9034 Analysis Date: 1/25/2018 SegNo: 1391082 %nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qua[ Sulfide, Reactive 4700 25.0 4800 0 97.9 75 125 4860 3.35 30 W NOTES: Sample was received not meeting proper temperature requirements. Qualifiers: ' Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 23 of 27 Insummlir Summit Ermironmental Technologies, Inc. QC SUMMARY RY REPORT 3310 Win St. �L 1. t.7 V 1�'1 L-�l� i iW i 1� 1 Er.VIROtJId ENThLTECtiNO1DOIES, INC Cuyahoga Falls, Ohio 44223 elnalytlral kaoorsiories WO#: 18011035 TEL: (330) 253-821I FAX., (330) 253-4489 Websile: ht1o.,1A-w.se11ek.com 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: R80006 Sample ID 18011425-001ADUP SampType: DUP TestCode: pH_Oil(9045 Units: s.u.@18.6C Prep Date: RunNo: 80006 :lient ID: BatchQC Batch ID: R80006 TestNo: SW9045D Analysis Date: 1/30/2018 SegNo: 1395686 knalyte Result PQL SPK value SPK Ref Val %REC LowLimit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 5.5 0 0 5.5 0.5 10 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PI, Permit Limit R RPD outside accepted recovery limits Page 24 of 27 SumnritEirvironmeata/Techtrologies, Inc.msum 3310 Win St. QC SUMMARY REPORT EtiVIRONId ENTALTEC!i)d01Dfl1=__S, INC Cuyahoga Falls, Ohio 44223 WO#: 18011035 Anatytica/ Laborstories TEL: (330) 253-8111 FAX., (330) 253-4489 Website: hop.-1 m my.sellekCom 31-Jan-18 Client: Synagro Project: Cherryville WWTP BatchID: R80006 Sample ID LCS-R80006 SampType: LCS TestCode: pH_DW(4500- Units: s.u.@21.7C Prep Date: RunNo: 80006 Client ID: LCSW Batch ID: R80006 TestNo: SW9045D Analysis Date: 1/30/2018 SegNo: 1395673 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 98.6 101.4 Sample ID 18011149-001BDUP SampType: DUP TestCode: pH_DW(4500- Units: s.u.@19.8C Prep Date: RunNo: 80006 Client ID: BatchQC Batch ID: R80006 TestNo: SW9045D Analysis Date: 1/30/2018 SegNo: 1395675 Analyte Result PQL SPK value SPK Ref Val % REC Lowl-imit HighLimit RPD Ref Val % RPD RPDLimit Qua] pH 7.2 7.2 0 5 Qualifiers: " Value exceeds Maximum Contaminant Level, B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine Original MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 25 of 27 ®Summit Environmental Technologies, Inc Analysis Request/Chain of Custody 3310 Win Street For Summit Environmental Technologies, Inc. use only Cuyahoga Falls, Ohio 44223 Tel: 330.253.8211 Fax: 330.253.4489 Page of SEI' Na Company Name (Please Print) Project Name -°°4 Fr Y"✓' 6l Piimmeters and Methods S l G G.etr Vl r Company MdreV - Project Address r _ks V 67 IT U"-rr v M � 3 Q a d , 'a A ,a A S. (]- d s L Client Phone No. 3310 & -7o3 ,, Report to Cbent Farr No. Please Fax Results J PO# Client Emal Please Funad Results J Quote No. tv e 5 rv•-O.n ..7 a 5 9 Contact Person F-rA k 13I'LL5r Sampled by 'I Check if Ohio VAP samples ✓ '� m a A• z ICY J n - # t,y-�h.r.-.",-a.:.'a S"avit'eIdencatioa Date Collected Call t7 Cg itn ■ 1. c.FIM■H®®eeo■■■■■■ ■ ■■M■■■■■■■■■■■■■■■ ■ MM■■■■■■■■■■■■■■■ ■ M■■■■■M■■■■■■■■■■■ ■ MM■■■■■■■■■■■■■■■ I nine I Received - Date I lime ry 2L 3'•�C Notes/Comments: } 1 State of Sample Origin: _.: ReceicedinlatsfiyE4-_ °'`-agnfe'r�.. 15me Rush Requested np: M"st lu approved S ���/Check'rf FOR COMPLIANCE S Bate by lab manager White and yellow pages should accompany samples to the laboratory. The client retains the pink psga. I 126458 _ I 1 of 1 Page 26 of 27 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. MVIRONFilENYALTE7;3i�"dQL(SGi'c�,-��dC_ Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arraivff6z1 LRborator,en TEL: (330) 253-8211 FAX. (330) 253-4489 Wehsite: htto://lviviv.settek.com Client Name: SYN-NC-27028 Work Order Number: 18011035 RcptNo: 1 Logged by: Christopher Livengood 1/23/2018 7:45:00 AM ' Completed By: Christopher Livengood 1/23/2018 1:35:15 PM Reviewed By: Jennifer Woolf 1/26/2018 6:22:22 PM Chain of Custody 1. Is Chain of Custody complete? 2. How was the sample delivered? Log In 3, Coolers are present? 4. Shipping container/cooler in good condition? Custody seals intact on shipping container/cooler? No. Seal Date: 5. Was an attempt made to cool the samples? 6. Were all samples received at a temperature of >0° C to 6.0°C 7. Sample(s) in proper container(s)? 8. Sufficient sample volume for indicated test(s)? g. Are samples (except VOA and ONG) properly preserved? 10. Was preservative added to bottles? 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? 12. Were any sample containers received broken? 13. Does paperwork match bottle labels? (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? 15. Is it clear what analyses were requested? 16. Were all holding times able to be met? (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑d No ❑ Not Present ❑ FedEx Yes❑ No ❑ NA ❑ Yes 0 No ❑ Yes ❑ No ❑ Not Present R] Signed By: Yes RI No ❑ NA ❑ Yes V No ❑ NA ❑ Yes 0 No ❑ Yes 0 No ❑ Yes W No ❑ Yes ❑ No ❑ NA ❑� NA Yes ❑ No ❑ No VOA Vials ❑d Yes ❑ No d❑ Yes d❑ No ❑ Yes d❑ No ❑ Yes ❑d No ❑ Yes No ❑ Yes ❑ No ❑ NA ❑d Person Notified: Date By Whom: i rl Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No I Temp °C I Condition I Seal Intact I Seal No I Seal Date ISigned By 1 13.8 1 Goodl Not Present Page 27 of 27 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Cherryville WQ Permit Number: WWTP Name: City of Cherryville WWTP NPDES Number: Monitoring Period: From Jan 1, 2018 To Dec 31, 2018 WQ0000430 NCO044440 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion if annheable to alternative performed (Class A or Class R) comnlete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10 to the 61h MPN 2676 4607 7473 MPN/g 0 Annual Grab SM9221C Coliform power per gram E-2006 of total solids CFU CFU/g 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) X (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X_ reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Fright, Plant ORC & Plant Name and Title ( or Urm erintendent Land Applier Name and Title (if applicable) (type or print) 2011 Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Analytical Results Synagro 284 Boger Rd. Mocksville, NC 27028 Receive Date: 06/13/2018 Reported: 06/14/2018 For: Cherryville WWTP Comments: Geometric Mean= 4607 MPN/g Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 180613-15-01 Fecal Coliforms C-1 3963 MPN/g sm9221cE-2006 06/13/2018 CL 180613-15-01 Percent Solids C-1 - 3.26 % SM25408-1997 06/13/2018 CL 180613-15-02 Fecal Coliforms C-2 6962 MPN/g SM92210E-2006 06/13/2018 CL 180613-15-02 Percent Solids C-2 8.16 % SM254OB-1997 06/13/2018 CL 180613-15-03 Fecal Coliforms C-3 5140 MPN/g smm'cE-zoos 06/13/2018 CL 180613-15-03 Percent Solids C-3 2.14 % SM254OB-1997 06/13/2018 CL 180613-15-04 Fecal Coliforms C-4 7473 MPNIg SM92210E-2006 06/13/2018 CL 180613-15-04 . Percent Solids C-4 2.81 % SM254OB-1997 06113/2018 CL 180613-15-05 Fecal Coliforms C-5 4348 MPNIg SM92210E-2006 06/13/2018 CL 180613-15-05 Percent Solids C-5 2.90 % SM25408-1997 06/13/2018 CL. 180613-15-06 • Fecal Coliforms C-6 3571 MPNIg SM92210E-2006 06/13/2018 CL 18061.3-15-06 Percent Solids C-6 3.64 % SM254OB-1997 06/13/2018 CL 180613-15-07 Fecal Coliforms C-7 2676 MPN/g SM92210E-2006 06/13/2018 CL 180613-15-07 Percent Solids C-7 2.99 % SM2540B-1997 06/13/2018 CL Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 180613-15-01 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180613-15-02 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180613-15-03 Temp on'Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180613-15-04 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180613-15-05. Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180613-15-06 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 180613-15-07 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 WWI? � STATESVILLE,iNALY'fJCAL 122CwnStreet - P.O.Dox228 Address: Sletesviile, NC 29697 - (704) 87�.4697 Contact Person: .., t U <� y phone# 36G 7� FAXH Chain of Custody Record PO #! Q Requisitioned by: ( me Date) Customer Sample IN lah-ID k The (Grab Sampled On) Dale Sampled (Grab only) ,� Matrix swan yi ywy Pa=e= mquested formalrsis tQ I U 0&(3-JlLof :OS (0- 13 " Z il 15-012 f6-C,3 Relinquished by: Time 5 <92iI pm Date+ J GI Is!pp Sampled by: Received by: Time'ZQ55 am,pm Date-- as — Transported by; Relinquished by: Time am, pm Date _/ !_ Holding times met: Received by: Time am, pm Date mpliance work Composite Sampling #1; Time begin _ am, pm Date / _/_ Non-compliance work: Time end__.__,.__ am, pm Date ,_/ / Lab Comments: Samples Transported On Ice; Composite Sampling #2; Time begin am, pm Date Time end am, pm Date _l--./_ 0 Initlafs: — r� W Lo 00 N U z y al Ln Ln r" N N X O to O rl Yll 30, IYOk ench Week 4 To6r, G.#& Volatile Q-iriffiAill "'Ok MOM Week I Total A i ftl_ ­v6i 1p- ow/mIr Nam Volatile' % Volgtile F_racAi6m kwmol I 'W*6k 4! Average Week 5, Total Solids olatilim Qo%l'.A S; 9% vcihi MIKES mmmok- M�MKORKMMMOM M I I I ll� YR CldOdk_R6'dddjon+:�lei Initial Q:Vol hfraction-(Injtj -Fin 2j, I t I 30, Day Bench 'Test- Aerobic 77 Date be gan: 11, 12 Yst: Anal Sam le Itig: Time Started: WEEK 1; DO: �,' �40-` �>2) emp: 'Z 12' % Total Solids Dish Dry Wt., + Dish Wt.: Dish Wt.; Sample. Wt. % Total Solids: Volatile Solids Dry Wt.& Dish Wt_ Ash Wt.:_':' Sample Wt. 6/0 Vol. Soli % Volatile Solids Dry Wt.& Dish Wt.:` C1 Ash Wt.:.. Sample Wt.: %Vol:. Solids!.7-71LjM_ % Total Solids, Dish #: Dry Wt. + Dish Wt.: Dish Wt.. Sample Wt.: % Total Solids: %, Volatile Solids" Dry Wt.&l)ishWt.: Ash Wt.: r. SampleWt.:..41_'__' % Vol. Solids: LAM WEEK 2 DO. _2), Temp: C, % j Total Solids Dish #-_ Dry Wt.,+ Dish Wt Dish wt.:__ Sample Wt.. % Total Solid �1� ...... . . . .... . % Volatile Solids! Dry Wt.& Dish Wt.: Ash,Wt..: Sample Wt.—_.- % Vol. Solids: O/o Total Solids Dish #: Dry Wt. + Dish; Wt.: Dish Wt- Sample Wt.: % Total Solids: % Volatile Solids- 46 - I Dry. Wt.& Dish Wf.�,� Ash Wt. : Sample Wt % Vol. Solids % Total Solidsi Dish #: Dry, Wt. + Dish Wt.: Dish Wt.: Sample Wt.: Total Solids: %, Volatile Solids Dry Wt.& Dish Wt.: Ash Wt.: Sample Wt.:�,��11'1 % Vol. Solids" L. "0111 0 WEEK DO:. (>2) Temp:_]Zj�� 6/6. Total So -lids Dish Dry-Wt. + Dish-W Dish-W Sample W % Total Solic % Volatile Solids - 10 Dry Wt.& Dish Wt. Ash.,W K Sample Wt.: % Vol. Solids: % Total Solids Dish # Dry Wt. + Dish Wt. Dish Wt. Sample Wt. Total Solids % Volatile Solids Dry Wt.& Dish Ash WtY Fra Sample Wt.:, % Vol. Soli % Volatile Solids r J_ DryWt.&Dish NAt Ash Wt.. q! Sample Wt.:,_­..... Vol. Solids: WEEK DOi-lAil 211 c! (>2) TemP- % Total Solids Dish #: Dry Wt., + Dish Wt'�-! Dish Wt.:: t Sample Wt, % Total Solids; % Volatile Solids Dry Wt. &, Dish Wt.: Ash Wt Sarnple,WU;*_ % Vol., Solid"s ,__ % Total Solids Dish Dry Wt. + Dish Wt. Dish Wt. Sample Wt. % Total Solids %Volatile Solids, Dry Wt.& Dish Wi.`�11t"hf. Ash Wt..-. Sample Wt.: % Vol. Solids: Total Solids Dish #: Dry Wt. + Dish Wt.: Dish Wt.: Sample Wt.: I/o Total Sol -ids: % Volatile Solids,, Dry. Wt.& Dish Wt.: Ash ,Wt .: Sample Wt.: % VoL Solids III WEEK- 5, 60; (>2) Temp _ % Total Solids Dish Dry Wt. +Dish Wt. Dish Wt ' J, M,51 Sample Wt.: O/o Total Solids.: % Volatile Solids :1 iu Dry Wt.& Dish V� Ash Wt Sample Wt.-:-,,' 1:2 1" % Vol. Solids�L_... % Total Solids Dish#': Dry Wt. + Dish Wt. Dish Wt.: Sample Wt. % Total Solids % Volatile Solids, Dry Wt.& Dish Wt.,,,. Ash Wt.: Sample Wt..., % Vol. DL ------- % Total Solids Dish Dry Wt. + Dish Wt.: Dish Wt.: Sample Wt.: % Total Solids: % Volatile Solids Dry Wt.& Dish Wt.:" Ash Wt.:!:241 Sample Wt.: % Vol. Solids``_-_}__ %VSR l' (older, more conservative method) %VS in 0.5551 Enter in %VS out 1 0.4842 _ ' decimal form %VSR= (%VS in - %VS out) ((%VS in - (%VS in x %VS out)) %VSR= 24.76 (method from p.132 of WH manual) %VSR= (%VS in - %VS out) min 1 V l (i . SS51 ( .555 1 x Analytical Results Synagro 284 Boger Rd. Mocksville, NC 27028 Receive Date: 04/20/2018 Reported: 05/30/2018 For: Cherryville WWTP Comments: Sample Number parameter Sample ID Result 180420-12-01 30 Day Benchscale Cherryville WWTP Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 25 Unit Method Analyzed Analyst EPA525-R-8210 04/19/2018 WC PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 3 Condition of Receipt Sample Number 180420-12-01 Temp on Arrival: 3.2 Parameter Schedule: Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 s 704/872/4697 Page 2 of 3 to ar 0 rD z n N 00 rn 00 V Client: I ll I ^� 5\ STATESVILLEANALYTICAL 122 Corot Street • P.O. Box 228 Statcsvillc. NC: 28687 (704)872.4697 Address: 02 Contact Person: S Cv c 9— hone SAo -7 �� � FAX# Chain of Custody Record PO # Requisitioned by: Crime Date) — Customer Sample IDM Lab-ID a Timo Sampled (Grab Only) Cate Sampled (Grab Onty) Malrix swa w ww ftrammersrequested for Analysis CA"Lr Relinquished by: I Received by: Relinquished by: Received by: Coro osl a Sam lin #1 6� •t P 9 Time begin am, pm Date _!_-_/ Time end am, pm Date _I_I­ Composite Sampllnn #2: Time begin am, pm Date Time end am, pm Date J / Time : (} j / am, ate �/� r4 Sampled by: n Time l am, Cm)Date4- /2Q` 6 Transported by: Time am, pm Date _I_I Holding times met: Time am, pm Date —/ Compliance work: Non-compliance work: Lab Comments: Samples Transported On Ica: _V Initials: SECTION 6 Agricultural Lime Application Log Year: 2017 Project: Cherryville Field Soil Lime Requirement Tons/Acre Date Applied (state -county -site -field) pH (from soil analysis) Applied(CCE Eq.) *lime will be applied when field dries up SECTION 7 NCDABCS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomit Report No. FY18-SL037943 Predictive Client: Wayne Gilbert Advisor: E Bruce ° �Nr 884 Cat Square Rd Synagro & Soil Report Mehlich-3Extraction Vale, NC28168 284Boger Rd m o A Mocksville, NC 27028 Sampled County: Lincoln Links to Helpful Information Sampled: 06/16/2018 Received: 06/28/2018 Farm: LT-120 Completed: 07/09/2018 Client ID: 289124 Advisor ID: 475821 Sample ID: 12002 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 1.3 0 0 50 0 0 0 0 0 0 Note: 3 2- Test Results [units - WN in glcm3; CEC and Na in meg1100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-I Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.71 1.10 6.2 66 2.1 5.1 224 46 47 15 62 136 92 246 246 372 0.2 3 Sample ID: 12003 Recommendations: Lime Nutrients (Ib/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.0 0 0 20 0 0 0 0 0 0 Note: 3 2- A Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral IM% WN CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.66 1.06 9.8 86 1.4 6.0 179 64 63 19 47 96 68 324 324 413 0.1 1 North Carolina R;µ Tobacco Trust Fund Commission Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, CommissionerofAgriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY18SL037943 Wayne Gilbert Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS % % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca % % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-Ali Mn-availability index for crop 1 Mn-AI2 Mn-availability index for crop 2 Mn-I manganese index rmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z M-O mineral -organic soil class .._cations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrfents_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations forsmall areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr4ov/agronomi/obpart4.htmilt nd information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index WN weight per volume The first seven values [soil class, HM%, WIV, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index remaining 16 [P-1, K-1, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-1, SS-1, Na, ESP, SS -I, NO3-N (not routine) Zn-I zinc index available)] indicate levels of plant nutrients or other fertility measurement. Visit wn n ncaorgov/agronomi/uvrsthtm