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HomeMy WebLinkAboutNC0004979_Regional Office Historical File Pre 2018 (5) r.s DUKE Allen Steam Station ENERGY® 4asarf I ch e. 253 Plant Allen Roaa Belmont,NC 28012 CAROLINAS RECEIVEDINCDENFt/DWR DEC 132018 December 5, 2018 WQROS MOORESVILLE REGIONAL OFFICE N.C. Department of Environmental Quality Division of Water Resources -WQ Permitting Section NPDES Attn: Corey Basinger 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Subject: Permit Application Update - Additional Chemicals Allen Steam Station NPDES Permit Number NC0004979 Gaston County Dear Mr. Basinger: Duke Energy is hereby modifying the active Allen Steam Station NPDES permit application on file and the application submitted in November 2017 to incorporate additional chemicals to be used in the wastewater treatment process. Soda Ash (Sodium Carbonate) will be used in conjunction with the Dry Bottom Ash Submerged Flight Conveyer System (SFC). The remaining chemicals, 25% Sodium Hydroxide, a Flocculating Polymer, and 90-98% Sulfuric acid will be utilized in the facility's wastewater Lined Retention Basin (LRB) treatment system. Soda Ash will be utilized in the closed-loop SFC system for pH adjustment and corrosion control. The 25% Sodium Hydroxide product will be utilized, as needed, in the Holding Basin and LRB system for pH adjustment. A Flocculating Polymer will be utilized, as needed, in the LRB system for solids management. Sulfuric acid 90-98% will be added, as needed, to the LRB system for pH adjustment. Enclosed are the SDS sheets for 25% Sodium Hydroxide (NALCO Caustic 25), Flocculating Polymers (NALCLEAR®7768 and CORE SHELL®71301), Sulfuric acid 90-98%, and Soda Ash (Sodium Carbonate). The final destination of all flows listed above is the secondary pond of the LRB, discharging via permitted wastewater outfall 006. Duke Energy does not anticipate or request any additional permit activities related to this notification as this notification is being sent to administratively update the NPDES applications on file. If you have any questions or comments regarding this information, please contact Ms. Elizabeth Glenn (980) 373-0530 or Elizabeth.cilenn@duke-eneray.com. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerely, Terry W. Tuck General Manager II Allen Steam Station Fossil/Hydro Operations - Carolinas Coal Generation Attachments CC: Julie Grzyb - NCDEQ - Division of Water Resources Page 1 of 6 Material Safety Data Sheet Sulfuric acid 90-98% ACC# 22350 Section 1 - Chemical Product and Company Identification MSDS Name: Sulfuric acid 90-98% Catalog Numbers: AC124640000, AC124640010, AC124640011, AC124640025, AC124640026, AC124645000, AC124645001, AC133610000, AC133610011, AC133610025, AC133610026, AC133610051, AC302070000, AC302070010, AC302070011, AC302070025, AC302070026, AC388270000, AC424520000, AC424520026, AC424525001, 13361-0010, 42452-0025, 42452-5000, A298-212, A298N119, A300-212, A300-225LB, A300-500, A300-500LC, A300-612GAL, A300-700LB, A300C-212, A300C-212002, A300C-212003, A300C-212LC, A300C212004, A300C212005, A300C212006, A300C212007, A300C212008, A300C212009, A300C212010, A3003-500, A300P-500, A300S-212, A300S-212LC, A300S-500, A300SI-212, A468-1, A468-2, A468-250, A468-500, A484-212, A510-212, A510-500, A510SK-212, NC9008405, NC9825433, S71211SC, S71211SCMF, S79200, 5A174-212, SA174-4, SA176- 4, SA196-500 Synonyms: Hydrogen sulfate; Oil of vitriol; Vitriol brown oil; Mattling acid; Battery acid; Sulphuric acid; Electrolyte acid; Dihydrogen sulfate; Spirit of sulfur; Chamber acid. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 For International CHEMTREC assistance, call: 703-527-3887 Section 2 - Composition, Information on Ingredients CAS# - Chemical Name Percent EINECS/ELINCS 7664-93-9 Sulfuric acid 90-98 231-639-5 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear colorless to yellow liquid. Danger! Causes eye and skin burns. Causes digestive and respiratory tract burns. May be fatal if mist inhaled. Strong inorganic acid mists containing sulfuric acid may cause cancer. Concentrated sulfuric acid reacts violently with water and many other substances under certain conditions. May cause lung damage. Hygroscopic (absorbs moisture from the air). Corrosive to metal. Target Organs: Lungs, teeth, eyes, skin. Potential Health Effects Eye: Causes severe eye burns. May cause irreversible eye injury. May cause blindness. May cause permanent corneal opacification. The severity of injury depends on the concentration of the solution and the duration of exposure. Skin: Causes skin burns. The severity of injury depends on the concentration of the solution and the duration of exposure. Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. Inhalation: May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. Causes chemical burns to the respiratory tract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Because its vapor pressure is negligible, it exists in the air only as a mist or spray. Exposure may impair lung http://fscimage.fishersci.com/msds/22350.htm 3/10/2008 Page 2 of 6 /function and cause mucostasis (reduced mucous clearance). Chronic: Prolonged or repeated skin contact may cause dermatitis. Prolonged or repeated inhalation may cause nosebleeds, nasal congestion, erosion of the teeth, perforation of the nasal septum, chest pain and bronchitis. Prolonged or repeated eye contact may cause conjunctivitis. Effects may be delayed. Workers chronically exposed to sulfuric acid mists may show various lesions of the skin, tracheobronchitis, stomatitis, conjunctivitis, or gastritis. Occupational exposure to strong inorganic acid mists containing sulfuric acid is carcinogenic to humans. Section 4 - First Aid Measures Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid immediately. Skin: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid immediately. Wash clothing before reuse. Ingestion: If swallowed, do NOT induce vomiting. Get medical aid immediately. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Inhalation: POISON material. If inhaled, get medical aid immediately. Remove victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Monitor arterial blood gases, chest x-ray, and pulmonary function tests if respiratory tract irritation or respiratory depression is evident. Treat dermal irritation or burns with standard topical therapy. Effects may be delayed. Do NOT use sodium bicarbonate in an attempt to neutralize the acid. Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Substance is noncombustible. Contact with water can cause violent liberation of heat and splattering of the material. Contact with metals may evolve flammable hydrogen gas. Runoff from fire control or dilution water may cause pollution. Approach fire from upwind to avoid hazardous vapors and toxic decomposition products. Strong dehydrating agent, which may cause ignition of finely divided materials on contact. Oxides of sulfur may be produced in fire. Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire. Do NOT get water inside containers. If water is used, care should be taken, since it can generate heat and cause spattering if applied directly to sulfuric acid. Flash Point: Not applicable. Autoignition Temperature: Not available. Explosion Limits, Lower:Not available. Upper: Not available. NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 2; Special Hazard: -W- Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Carefully scoop up and place into appropriate disposal container. Provide ventilation. Do not get water inside containers. Cover with dry earth, dry sand, or other non- combustible material followed with plastic sheet to minimize spreading and contact with water. Section 7 - Handling and Storage Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Do not allow water to get into the container because of violent reaction. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Discard contaminated shoes. Use only with adequate ventilation. Do not breathe spray or mist. Do not http://fscimage.fishersci.com/msds/22350.htm 3/10/2008 Page 3 of 6 use with metal spatula or other metal items. Inform laundry personnel of contaminant's hazards. Storage: Do not store near combustible materials. Keep container closed when not in use. Store in a cool, dry, well- ventilated area away from incompatible substances. Do not store near alkaline substances. Store protected from moisture. Ideally, sulfuric acid should be stored in isolation from all other chemicals in an approved acid or corrosives safety cabinet. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use a corrosion-resistant ventilation system. Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs Sulfuric acid 0.2 mg/m3 TWA (thoracic 1 mg/m3 TWA 15 mg/m3 IDLH 1 mg/m3 TWA fraction) OSHA Vacated PELs: Sulfuric acid: 1 mg/m3 TWA Personal Protective Equipment Eyes: Wear chemical splash goggles and face shield. Skin: Wear neoprene gloves, apron, and/or clothing. Viton gloves are recommended. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Liquid Appearance: oily - clear colorless to yellow Odor: odorless pH: 0.3 (1N solution) Vapor Pressure: < 0.001 mm Hg @ 20 deg C Vapor Density: 3.38 (air=1) Evaporation Rate:Slower than ether. Viscosity: 21 mPas @ 25 C Boiling Point: 290 - 338 deg C Freezing/Melting Point:10 deg C Decomposition Temperature:340 deg C Solubility: Soluble with much heat Specific Gravity/Density:1.84 Molecular Formula:H2SO4 Molecular Weight:98.07 Section 10 - Stability and Reactivity Chemical Stability: Sulfuric acid reacts vigorously, violently or explosively with many organic and inorganic chemicals and with water. Conditions to Avoid: Excess heat, exposure to moist air or water, Note: Use great caution in mixing with water due to heat evolution that causes explosive spattering. Always add the acid to water, never the reverse.. Incompatibilities with Other Materials: Metals, oxidizing agents, reducing agents, bases, acrylonitrile, chlorates, finely powdered metals, nitrates, perchlorates, permanganates, epichlorohydrin, aniline, carbides, fulminates, picrates, organic materials, flammable liquids. Hazardous Decomposition Products: Oxides of sulfur. http://fscimage.fishersci.com/msds/22350.htm 3/10/2008 Page 4 of 6 Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# 7664-93-9: WS5600000 LD50/LC5O: CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation, mouse: LC50 = 320 mg/m3/2H; Inhalation, mouse: LC50 = 320 mg/m3; Inhalation, rat: LC50 = 510 mg/m3/2H; Inhalation, rat: LC50 = 510 mg/m3; Oral, rat: LD50 = 2140 mg/kg; Carcinogenicity: CAS# 7664-93-9: • ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorganic acid mists) • California: carcinogen, initial date 3/14/03 (listed as Strong inorganic acid mists containing sulfuric acid). • NTP: Known carcinogen (listed as Strong inorganic acid mists containing s). • IARC: Group 1 carcinogen Epidemiology: Workers exposed to industrial sulfuric acid mist showed a statistical increase in laryngeal cancer. This suggests a possible relationship between carcinogenesis and inhalation of sulfuric acid mist. Teratogenicity: Sulfuric acid was not teratogenic in mice and rabbits, but was slightly embryotoxic in rabbits (a minor, rare skeletal variation). The animals were exposed to 5 and 20 mg/m3 for 7 hr/day throughout pregnancy. Slight maternal toxicity was present at the highest dose in both species. Reproductive Effects: No information found Mutagenicity: There are no mutagenicity studies specifically of sulfuric acid. However, there are established effects of reduced pH in mutagenicity testing, as would be caused by sulfuric acid. These effects are an artifact of low pH and are not necessarily due to biological effects of sulfuric acid itself. Neurotoxicity: No information found Other Studies: Section 12 - Ecological Information Ecotoxicity: Fish: Bluegill/Sunfish: 49 mg/L; 48Hr; TLm (tap water @ 20C) Fish: Bluegill/Sunfish: 24.5 ppm; 48Hr; TLm (fresh water) Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information http://fscimage.fishersci.com/msds/22350.htm 3/10/2008 Page 5 of 6 I US DOT Canada TDG Shipping Name: SULFURIC ACID SULFURIC ACID Hazard Class: 8 8 UN Number: UN1830 UN1830 Packing Group: II II Section 15 - Regulatory Information US FEDERAL TSCA CAS# 7664-93-9 is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. CERCLA Hazardous Substances and corresponding RQs CAS# 7664-93-9: 1000 lb final RQ; 454 kg final RQ SARA Section 302 Extremely Hazardous Substances CAS# 7664-93-9: 1000 lb TPQ SARA Codes CAS # 7664-93-9: immediate, delayed, reactive. Section 313 This material contains Sulfuric acid (CAS# 7664-93-9, 90-98%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CAS# 7664-93-9 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts. California Prop 65 The following statement(s) is(are) made in order to comply with the California Safe Drinking Water Act: WARNING: This product contains Sulfuric acid, listed as 'Strong inorganic acid mists contain', a chemical known to the state of California to cause cancer. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: C Risk Phrases: R 35 Causes severe burns. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of http://fscimage.fishersci.com/msds/22350.htm 3/10/2008 Page 6 of 6 water and seek medical advice. S 30 Never add water to this product. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 7664-93-9: 2 Canada - DSL/NDSL CAS# 7664-93-9 is listed on Canada's DSL List. Canada - WHMIS This product has a WHMIS classification of D2A, D1A, E. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. Canadian Ingredient Disclosure List CAS# 7664-93-9 is listed on the Canadian Ingredient Disclosure List. Section 16 - Additional Information MSDS Creation Date: 4/22/1999 Revision #15 Date: 2/13/2008 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages. http://fscimage.fishersci.com/msds/22350.htm 3/10/2008 Page 1 of 10 ' 14)eR Soda Ash / Sodium Carbonate Revision Date:4/21/2017 SAFETY DATA SHEET 1 PRODUCT AND COMPANY IDENTIFICATION 4.1 1.1 PRODUCT IDENTIFIERS Product Name: Soda Ash or Sodium Carbonate Chemical Name: Sodium Carbonate Synonyms / Common Names: Carbonic Acid Sodium Salt Registration Number REACH: 01-2119485498-19-0011 Product Type REACH: Substance/mono-constituent CAS Number: 497- 19-8 EC Index Number: 011-005-00-2 EC Number: 207- 838-8 RTECS Number: V Z4050000 1.2 RELEVANT IDENTIFIED USES II Glass production Paper production Manufacture of substances 'i' I Detergent component Laboratory chemicals Acidity regulator a `1 4141 1.3 MANUFACTURER Ciner Wyoming LLC 254 County Road 4-6 Green River, Wyoming 82935 :14 United States f{ ,. Telephone Number: (307) 875-2600 www.ciner.us.com 1.4 EMERGENCY TELEPHONE NUMBER Emergency Response Information Provider: CHEMTREC Within the United States Emergency Telephone Number: 1-800-424-9300 Outside the United States / International Emergency Telephone Number: +1-703-527-3887 CINER SDS SODA ASH/SODIUM CARBONATE Page 2 of 10 2 HAZARD(S) IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE GHS Classification in accordance with 29 CFR 1910 (OSHA HazCom Standard): Eye Irritation (Category 2A), H319 For the full text of the H-Statements mentioned in this Section, see Section 16. 2.2 GHS LABEL ELEMENTS,INCLUDING PRECAUTIONARY STATEMENTS Pictograms: • Irritant Signal Word: Warning Hazard Statement(s): H319 Causes serious eye irritation. Precautionary Statement(s): P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice / attention. 2.3 HAZARDS NOT OTHERWISE CLASSIFIED OR NOT COVERED BY GHS None 3 COMPOSITION/INFORMATION ON INGREDIENTS 3.1 SUBSTANCES Synonyms: Soda Ash, Sodium Carbonate, Carbonic Acid Sodium Salt Formula: Na2CO3 LINER SDS i SODA ASH/SODIUM CARBONATE Page 3 of 10 Molecular Weight: 105.99 g/mol Component CAS # / EC # Concentration Classifications Remark (REACH Registration) Sodium carbonate CAS #: 497-19-8 ➢ 99% Eye Irrit. 2A, H319 Mono- constituent (01-2119485498-19- EC #: 207-838-8 0011) * For the full text of the H-Statements mentioned in this Section, see Section 16. 4 FIRST-AID MEASURES 4.1 DESCRIPTION OF FIRST-AID MEASURES General - Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. After inhalation - Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. After skin contact - Rinse with water. Soap may be used. Do not apply (chemical) neutralizing agents. Take victim to a doctor if irritation persists. After eye contact - Rinse immediately with plenty of water for at least 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. After ingestion - Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Consult a doctor/medical service if victim is unwell. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS,BOTH ACUTE AND DELAYED 4.2.1 Acute Symptoms If inhaled - Dry/sore throat. Coughing. Slight irritation. Exposure to high concentrations: Irritation of the respiratory tract. Irritation of the nasal mucous membranes. Respiratory difficulties. In case of skin contact - Not irritating In case of eye contact - Inflammation/damage of the eye tissue. Corrosion of the eye tissue. Lacrimation. If swallowed — After absorption of high quantities: Nausea. Vomiting. Abdominal pain. Irritation of the gastric/intestinal mucosa. 4.2.2 Delayed Symptoms No effects known. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED No data available. CINER SDS j SODA ASH/SODIUM CARBONATE Page 4 of 10 5 FIRE-FIGHTING MEASURES 5.1 EXTINGUISHING MEDIA Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE Upon combustion CO and CO2 are formed. Reacts on exposure to water with some metals. CO2 generation occurs when mixed with acidic materials. 5.3 ADVICE FOR FIREFIGHTERS Wear self-contained breathing apparatus for firefighting if necessary. 5.4 SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Gloves. Safety glasses. Protective clothing. Dust cloud protection and heat/fire exposure: Compressed air respirator. 6 ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. 6.2 ENVIRONMENTAL PRECAUTIONS Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Knock down/dilute dust cloud with water spray. Violent exothermic reaction with some acids; release of harmful gases/vapors (carbon dioxide). Carbon dioxide is heavier than air and will collect in ducts, drains and low lying areas. Prevent spreading in sewers. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP Prevent dust cloud formation. Scoop solid spill material into closed containers. Carefully collect the spill. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling. 6.4 REFERENCE TO OTHER SECTIONS For disposal see section 13. CINER SDS SODA ASH/SODIUM CARBONATE Page 5 of 10 7 HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Avoid contact with skin and eyes. Use air conveying/mechanical systems for bulk transfer to storage. Provide appropriate exhaust ventilation at places where dust is formed. In case of insufficient ventilation, wear suitable respiratory equipment if release of airborne dust is expected. 7.2 CONDITIONS FOR SAFE STORAGE,INCLUDING ANY INCOMPATIBILITIES Store in original container. Keep in properly labeled containers. Keep container tightly closed. 7.3 SUITABLE PACKAGING MATERIAL No data available 7.4 INCOMPATIBLE PRODUCTS Aluminum, powdered aluminum, and acids. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 COMPONENTS WITH WORKPLACE CONTROL PARAMETERS Contains no substances with occupational exposure limit values. 8.2 EXPOSURE CONTROLS Appropriate engineering controls - Avoid formation of dust. Keep away from ignition sources. Keep container tightly closed. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 8.3 PERSONAL PROTECTIVE EQUIPMENT Eye/ Face Protection - Safety glasses with side shields or protective goggles. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection - Handle with gloves, butyl rubber or PVC, which have good resistance. Gloves must be inspected prior to use. Use proper glove removal technique to avoid skin contact with product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection - Protective clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection - For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). CINER SDS I SODA ASH/SODIUM CARBONATE Page 6 of 10 8.4 CONTROL OF ENVIRONMENTAL EXPOSURE Prevent leakage or spillage if safe to do so. Do not let product enter drains. See section 6.2, 6.3, and 13. 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES Appearance Form: Crystalline Solid / Crystalline Powder/ Grains/ Lumps Color: Color less Odor: Odorl ess Odor Threshold: No data available Particle Size: 694 pm pH: 11.6; 5.0% Melting Point/ Freezing Point: 851 °C/ 1,564 °F Boiling Point 1,600 °C/ 2,912 °F Flash Point: No data available Explosion Limits: No data available Evaporation Rate: No data available Flammability: No n Combustible Log Kow: -6.19 Estimated value Viscosity: No data available Vapor Pressure: No data available Vapor Density: No data available Solubility water: 212.5 g/I; 20 °C/ 68 °F Relative Density: 2.52 -2.53; 20 °C/ 68 °F Absolute Density: 2,530 kg/m3 Decomposition temperature: >1600 °C/ >2912 °F Auto-ignition temperature: >400 °C/ >752 °F Explosive Properties: No data available Oxidizing Properties: No data available 9.2 PHYSICAL HAZARDS No data available 10 STABILITY AND REACTIVITY 10.1 REACTIVITY None under normal use conditions. 10.2 CHEMICAL STABILITY Stable. Decomposes by reaction with strong acid. 10.3 POSSIBILITY OF HAZARDOUS REACTIONS None under normal processing. CINER SDS SODA ASH/SODIUM CARBONATE Page 7 of 10 10.4 CONDITIONS TO AVOID Exposure to air or moisture over prolonged periods. 10.5 INCOMPATIBLE MATERIALS Aluminum, powdered aluminum, and acids. 10.6 HAZARDOUS POLYMERIZATION Hazardous polymerization does not occur. 11 TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS 11.1.1 Acute toxicity LD50 Oral - rat - 2,800 mg/kg LD50 Dermal - rabbit >2,000 mg/kg LD50 Inhalation - rat - 2.30 mg/I, 2 hour exposure time 11.1.2 Corrosion/irritation Skin - rabbit Result: Mild skin irritation - 24 hours 11.1.3 Serious eye damage/eye irritation Eyes - rabbit Result: Severe eye irritation - 24 hours 11.1.4 Respiratory or skin sensitization Inhalation - no data available Skin Sensitization: no data available 11.1.5 Germ cell mutagenicity No data available 11.1.6 Carcinogenicity No data available 11.1.7 Reproductive toxicity No data available 11.1.8 Specific target organ toxicity-single exposure No data available 11.1.9 Specific target organ toxicity- repeated exposure No data available 11.1.10 Chronic effects from short and long-term exposure On continuous/ repeated exposure / contact: Red skin. Dry skin. Tingling / irritation of the skin. Affection of the nasal septum. CINER SDS 1 SODA ASH/SODIUM CARBONATE Page 8 of 10 12 ECOLOGICAL INFORMATION 12.1 ToxiciTY Parameter Method Value Duration Species Test Fresh/salt Value design water determination Acute toxicity LC50 Other 300 mg/I 96 h Lepomis Static Fresh water Experimental fishes macrohirus system value Acute toxicity EC50 Other 200 - 227 48 h Ceriodaphnia Semi- Fresh water Experimental invertebrates mg/I sp. static value Toxicity algae EC50 242 mg/I 5 days Algae Experimental and other value aquatic plants 12.2 PERSISTENCE AND DEGRADABILITY: Biodegradability: not applicable 12.3 BIOACCUMULATIVE POTENTIAL: Low potential for bioaccumulation (Log Know <4) 12.4 MOBILITY IN SOIL: Low potential for absorption in soil. 12.5 RESULTS OF PBT AND VPVB ASSESSMENT: PBT/vPvB assessment not available as chemical safety assessment is not required/not conducted. 12.6 OTHER ADVERSE EFFECTS: No data available 13 DISPOSAL CONSIDERATIONS 13.1 WASTE DISPOSAL Remove waste in accordance with local and/or national regulations. Contact a licensed professional waste disposal service to dispose of this material. Different types of hazardous waste should not be mixed together if it will entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. Do not discharge into drains. CINER SDS ! SODA ASH/SODIUM CARBONATE Page 9 of 10 14 TRANSPORT INFORMATION 14.1 UNITED STATES DEPARTMENT OF TRANSPORTATION(DOT) Non-regulated 14.2 INTERNATIONAL MARITIME DANGEROUS GOODS(IMDG) Non-regulated 14.3 INTERNATIONAL AIR TRANSPORT ASSOCIATION(IATA) Non-regulated 14.4 TDG/ADN/RID/ADR Non-regulated 15 REGULATORY INFORMATION 15.1 SARA 302 COMPONENTS SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. 15.2 SARA 313 COMPONENTS SARA 313: This material does not contain any chemical with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. 15.3 SARA 311/312 HAZARDS Acute Health Hazard 15.4 PENNSYLVANIA RIGHT To KNOW COMPONENTS Sodium carbonate, CAS-No: 497-19-8 15.5 NEW JERSEY RIGHT To KNOW COMPONENTS Sodium carbonate, CAS-No: 497-19-8 15.6 WHMIS CLASSIFICATION:C, D2 Note: The product listed on this SDS has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations. CINER SDS 1 SODA ASH/SODIUM CARBONATE Page 10 of 10 16 OTHER INFORMATION 16.1 FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTION 2 AND 3. Eye Irrit. Eye Irritation H319 Causes serious eye irritation 16.2 HMIS RATING Health Hazard: 2 Flammability: 0 Physical Hazard: 0 16.3 NFPA RATING Health Hazard: 2 Fire Hazard: 0 Reactivity Hazard: 0 16.4 NOTICE The above information is believed to be correct but is not intended to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Ciner and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. CINER SDS SODA ASH/SODIUM CARBONATE MATERIAL SAFETY DATA SHEET NAACO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : NALCLEAR(R) 7768 APPLICATION : FLOCCULANT COMPANY IDENTIFICATION : Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S) : (800)424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH : 0/ 1 FLAMMABILITY : 1 /1 INSTABILITY : 0/0 OTHER : 0= Insignificant 1 = Slight 2 = Moderate 3= High 4 = Extreme 2. COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200. 3. HAZARDS IDENTIFICATION **EMERGENCY OVERVIEW** CAUTION May cause irritation with prolonged contact. Toxic to aquatic organisms. Do not get in eyes, on skin, on clothing. Do not take internally. Wear suitable protective clothing. Keep container tightly closed. Water in contact with the product will cause slippery floor conditions. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. After contact with skin, wash immediately with plenty of soap and water. Protect product from freezing. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. PRIMARY ROUTES OF EXPOSURE : Eye, Skin HUMAN HEALTH HAZARDS -ACUTE : EYE CONTACT : May cause irritation with prolonged contact. SKIN CONTACT : May cause irritation with prolonged contact. INGESTION : Not a likely route of exposure. If swallowed a jelly mass may form which in digestion may cause blockage. Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 1 / 10 P41 MATERIAL SAFETY DATA SHEET NALGO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC INHALATION : Not a likely route of exposure. No adverse effects expected. SYMPTOMS OF EXPOSURE : Acute : A review of available data does not identify any symptoms from exposure not previously mentioned. Chronic : Frequent or prolonged contact with product may defat and dry the skin, leading to discomfort and dermatitis. AGGRAVATION OF EXISTING CONDITIONS : A review of available data does not identify any worsening of existing conditions. 4. FIRST AID MEASURES EYE CONTACT: Flush affected area with water. If symptoms develop, seek medical advice. SKIN CONTACT : Remove contaminated clothing. Wash off affected area immediately with soap and plenty of water. If symptoms develop, seek medical advice. INGESTION : Do not induce vomiting without medical advice. If conscious, washout mouth and give water to drink. If symptoms develop, seek medical advice. INHALATION : Remove to fresh air, treat symptomatically. If symptoms develop, seek medical advice. Remove to fresh air, treat symptomatically. Get medical attention. NOTE TO PHYSICIAN : Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition. 5. FIRE FIGHTING MEASURES FLASH POINT : > 200 °F/> 93.3 °C ( PMCC ) EXTINGUISHING MEDIA : Foam, Dry powder, Carbon dioxide, Other extinguishing agent suitable for Class B fires UNSUITABLE EXTINGUISHING MEDIA : Do not use water unless flooding amounts are available. FIRE AND EXPLOSION HAZARD : May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 2/ 10 P� MATERIAL SAFETY DATA SHEET NALGO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : Notify appropriate government, occupational health and safety and environmental authorities. Do not touch spilled material. Stop or reduce any leaks if it is safe to do so. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). METHODS FOR CLEANING UP : SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. Water in contact with the product will cause slippery floor conditions. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : This product is toxic to fish. It should not be directly discharged into lakes, ponds, streams, waterways or public water supplies. 7. HANDLING AND STORAGE HANDLING : Do not take internally. Have emergency equipment(for fires, spills, leaks, etc.) readily available. Ensure all containers are labeled. Avoid eye and skin contact. STORAGE CONDITIONS : Store separately from oxidizers. Store the containers tightly closed. Protect product from freezing. SUITABLE CONSTRUCTION MATERIAL : Hastelloy C-276, Stainless Steel 316L, Viton, Stainless Steel 304, Teflon, Plasite 7122, Inconel 625, Plasite 4300, CPVC (rigid), Polypropylene (rigid), Polyethylene (rigid) UNSUITABLE CONSTRUCTION MATERIAL : Brass, Neoprene, Buna-N, Natural rubber, Polyurethane, Hypalon, EPDM, Mild steel, Galvanized metals, Polyethylene tubing 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS : This product does not contain any substance that has an established exposure limit. ENGINEERING MEASURES : General ventilation is recommended. RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: Organic vapor cartridge. with a Particulate pre-filter. If Nalco Company 1601 W. Diehl Road • Naperville. Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 3/ 10 P1MATERIAL SAFETY DATA SHEET N ALCO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection. HAND PROTECTION : Nitrile gloves, PVC gloves SKIN PROTECTION : Wear standard protective clothing. EYE PROTECTION : Wear chemical splash goggles. HYGIENE RECOMMENDATIONS : Keep an eye wash fountain available. Keep a safety shower available. Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke. HUMAN EXPOSURE CHARACTERIZATION : Based on our recommended product application and personal protective equipment, the potential human exposure is: Moderate 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Emulsion APPEARANCE Off-white ODOR Slight, Hydrocarbon SPECIFIC GRAVITY 1.04 @ 77 °F/25 °C DENSITY 8.55-9.05 lb/gal SOLUBILITY IN WATER Emulsifiable pH (1 %) 6.8 VISCOSITY 200 - 1,700 cps @ 77 °F/25 °C FREEZING POINT 26 °F/-3 °C BOILING POINT 215 °F/102 °C VOC CONTENT 26.2 % EPA Method 24 Note: These physical properties are typical values for this product and are subject to change. 10. STABILITY AND REACTIVITY STABILITY : Stable under normal conditions. HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. Nalco Company 1601 W. Diehl Road • Naperville. Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 4/ 10 P41MATERIAL SAFETY DATA SHEET NALGO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC CONDITIONS TO AVOID : Freezing temperatures. MATERIALS TO AVOID : Addition of water results in gelling. Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of carbon, Oxides of nitrogen 11. TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product. SENSITIZATION : This product is not expected to be a sensitizer. CARCINOGENICITY : None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer(IARC),the National'Toxicology Program (NTP)or the American Conference of Governmental Industrial Hygienists (ACGIH). HUMAN HAZARD CHARACTERIZATION : Based on our hazard characterization, the potential human hazard is: Low 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS : The following results are for the product, unless otherwise indicated. ACUTE FISH RESULTS : Species Exposure LC50 Test Descriptor Fathead Minnow 96 hrs 240 mg/I Similar Product Rainbow Trout 96 hrs 8,500 mg/I 1%Aqueous Solution of Product Sheepshead Minnow 96 hrs > 1,000 mg/I 1%Aqueous Solution of a Similar Product Inland Silverside 96 hrs 90.7 mg/I Product Rainbow Trout 96 hrs 157.5 mg/I Product ACUTE INVERTEBRATE RESULTS : Species Exposure LC50 EC50 Test Descriptor Mysid Shrimp (M. litoralis) 96 hrs 188.9 mg/I Product Daphnia magna 48 hrs 200 mg/I 1%Aqueous Solution of Product Mysid Shrimp (Mysidopsis 96 hrs 67.4 mg/I Product bahia) Daphnia magna 96 hrs 400 mg/I 1%Aqueous Solution of a Similar Product Nalco Company 1601 W. Diehl Road • Naperville. Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 5/ 10 PdMATERIAL SAFETY DATA SHEET NALGO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC Daphnia magna 48 hrs 0.12 mg/I Similar Product Daphnia magna 48 hrs 0.694 mg/I Product AQUATIC PLANT RESULTS : Species Exposure EC50/LC50 Test Descriptor Marine Algae(Skeletonema 72 hrs 23 mg/I (EC50) Product costatum) PERSISTENCY AND DEGRADATION : Chemical Oxygen Demand (COD) : 429,000 mg/I Biological Oxygen Demand (BOD) : Incubation Period Value Test Descriptor 5 d 200,000 mg/I Product The organic portion of this preparation is expected to be inherently biodegradable. MOBILITY : The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM , provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment <5% 10-30% 70-90% The portion in water is expected to be soluble or dispersible. BIOACCUMULATION POTENTIAL Component substances have a potential to bioaccumulate. ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low Based on our recommended product application and the product's characteristics, the potential environmental exposure is: Moderate If released into the environment, see CERCLA/SUPERFUND in Section 15. 13. DISPOSAL CONSIDERATIONS If this product becomes a waste, it is not a hazardous waste as defined by the Resource Conservation and Recovery Act(RCRA)40 CFR 261, since it does not have the characteristics of Subpart C, nor is it listed under Subpart D. Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 6/ 10 "NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC As a non-hazardous waste, it is not subject to federal regulation. Consult state or local regulation for any additional handling, treatment or disposal requirements. For disposal, contact a properly licensed waste treatment, storage, disposal or recycling facility. 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper(bill of lading) specific to an order. Please note that the proper Shipping Name/Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. LAND TRANSPORT : Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION AIR TRANSPORT(ICAO/IATA) : Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION MARINE TRANSPORT(IMDG/IMO) : Proper Shipping Name : PRODUCT IS NOT REGULATED DURING TRANSPORTATION 15. REGULATORY INFORMATION NATIONAL REGULATIONS, USA : OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 : Based on our hazard evaluation, none of the substances in this product are hazardous. CERCLA/SUPERFUND, 40 CFR 117, 302 : Notification of spills of this product is not required. SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) -SECTIONS 302, 311, 312,AND 313 : SECTION 302 -EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 AND 312 -MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) : Our hazard evaluation has found that this product is not hazardous under 29 CFR 1910.1200. Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are: 500 pounds or the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. Nalco Company 1601 W. Diehl Road • Naperville. Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 7/ 10 P41MATERIAL SAFETY DATA SHEET N ALCO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC SECTION 313 -LIST OF TOXIC CHEMICALS (40 CFR 372) : This product does not contain substances on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT(TSCA) : The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) NSF INTERNATIONAL : This product has received NSF/International certification under NSF/ANSI Standard 60 in the coagulation and flocculation category. The official name is"Polyacrylamide." Maximum product application dosage is : 1 mg/I. FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/formerly Sec. 307, 40 CFR 116.4/formerly Sec. 311 : This product may contain trace levels(<0.1%for carcinogens, <1% all other substances) of the following substance(s) listed under the regulation: Substance(s) Citations • Cupric Sulphate Sec. 307, Sec. 311 CLEAN AIR ACT, Sec. 112 (40 CFR 61, Hazardous Air Pollutants), Sec. 602 (40 CFR 82, Class I and II Ozone Depleting Substances) : None of the substances are specifically listed in the regulation. CALIFORNIA PROPOSITION 65 : This product does not contain substances which require warning under California Proposition 65. MICHIGAN CRITICAL MATERIALS : None of the substances are specifically listed in the regulation. STATE RIGHT TO KNOW LAWS : None of the substances are specifically listed in the regulation. NATIONAL REGULATIONS, CANADA : WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS CLASSIFICATION : Not considered a WHMIS controlled product. CANADIAN ENVIRONMENTAL PROTECTION ACT(CEPA) : The substance(s) in this preparation are included in or exempted from the Domestic Substance List(DSL). INTERNATIONAL CHEMICAL CONTROL LAWS Nalco Company 1601 W. Diehl Road • Naperville. Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 8/ 10 PdMATERIAL SAFETY DATA SHEET NALGO PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC AUSTRALIA All substances in this product comply with the National Industrial Chemicals Notification &Assessment Scheme (NICNAS). CHINA All substances in this product comply with the Chemical Control Law and are listed on the Inventory of Existing Chemical Substances China (IECSC). EUROPE The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories. JAPAN All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI). KOREA All substances in this product comply with the Toxic Chemical Control Law(TCCL) and are listed on the Existing Chemicals List (ECL) PHILIPPINES All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippine Inventory of Chemicals &Chemical Substances(PICCS). 16. OTHER INFORMATION Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and exposures of this product. Based on our recommended use of this product, we have characterized the product's general risk. This information should provide assistance for your own risk management practices. We have evaluated our product's risk as follows: *The human risk is: Low *The environmental risk is: Low Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative will assist you to determine if your product application is consistent with our recommendations. Together we can implement an appropriate risk management process. This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices,American Conference of Governmental Industrial Hygienists, OH., (Ariel Insight#CD-ROM Version), Ariel Research Corp., Bethesda, MD. Nalco Company 1601 W. Diehl Road • Naperville. Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 9/ 10 PINALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCLEAR(R) 7768 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS#CD-ROM Version), Micromedex, Inc., Englewood, CO. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer. Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS#CD- ROM Version), Micromedex, Inc., Englewood, CO. Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service. Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA), (Ariel Insight#CD-ROM Version),Ariel Research Corp., Bethesda, MD. Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS#CD-ROM Version), Micromedex, Inc., Englewood, CO. Ariel Insight#(An integrated guide to industrial chemicals covered under major regulatory and advisory programs), North American Module, Western European Module, Chemical Inventories Module and the Generics Module (Ariel Insight#CD-ROM Version),Ariel Research Corp., Bethesda, MD. The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS#CD-ROM Version), Micromedex, Inc., Englewood, CO. Prepared By : Product Safety Department Date issued : 01/14/2008 Version Number: 1.16 Nalco Company 1601 W. Diehl Road • Naperville. Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access 10/ 10 PRODUCT NAME CORE SHELL® 71301 Cationic Flocculant PRODUCT DESCRIPTION AND APPLICATION CORE SHELL 71301 is an innovative, proprietary, high performance polymer designed for sludge dewatering and wastewater treatment. CORE SHELL 71301 is architecturally modified on the molecular level, providing unique solution properties and performance characteristics. CORE SHELL 71301 provides excellent sludge dewatering performance in applications such as filter presses and centrifuges. REGULATORY APPROVALS Refer to the Material Safety Data Sheet(MSDS), SECTION 15 for the most recent information on approvals. MATERIALS OF COMPATIBILITY Compatible Not Compatible Hasteloy C-276 316 Stainless Steel Inconel 625 Polyethylene tubing Viton Brass Teflon 304 Stainless Steel Polyethylene (rigid) Neoprene Polypropylene (rigid) Buna-N Rubber CPVC (rigid) Natural Rubber Plasite 4300 (vinyl ester resin) Polyurethane Plasite 7122 (epoxy phenolic) Hypalon EPDM Mild Steel Galvanized Steel Note: Feed System Acceptable Materials Utilize plastic piping and fittings where possible on neat polymer feed lines.Where strength is needed, 316 SS pumps, valves, etc. can be used. However, these components, especially pump internals, will have a reduced life span. Be sure to routinely inspect all 316 SS components for signs of corrosion and to utilize check valves with Teflon or epoxy-coated springs. DOSAGE AND FEEDING CORE SHELL 71301 should be fed via a closed feed system. A closed feed system is defined as a system in which fluid is moved from a closed storage vessel into a treated media without exposure to the atmosphere (except through normal venting or pressure devices). Emulsion flocculants must be fed following proper makeup procedures. Suitable inversion systems should be utilized to allow for adequate inversion and feeding control. The quality of water used to invert the polymer is important. Avoid using plant recycle water or other water sources high in suspended solids, mineral salts and iron, and with a pH either below 6.5 or above 7.8.A dilution aging tank is highly recommended,with a minimum of 30 minutes aging in order to gain full product activity. Inverting the emulsion flocculant below a concentration of 0.2%, or above a concentration of 0.5%, is not recommended. A positive displacement pump is recommended for feeding the inverted material to the treatment system. In some cases, continuous dilution of pre-inverted flocculant will enhance activity and generate more cost-effective results. Improved performance using dilution water is site specific. To determine if post- dilution is advantageous,feed inverted product through a standard mixing tee to an active dilution water line. The water temperature should be close to ambient and low on suspended solids, mineral salts and iron. In most cases, inverted flocculant should be fed on the discharge side of the feed pump. There may be isolated cases where the additional mixing rendered by distributing the polymer on the suction side of the pump will yield better program results. Bulk viscosity of neat CORE SHELL 71301 Temperature[°C] Bulk viscosity [cp] 4 • 7300 8 2840 13 2160 17 1520 20.5 920 Solution Viscosity of CORE SHELL 71301 % Solution Solution viscosity [cp] 0.5 480 1.0 920 1.5 1600 ROI CRITICAL SUCCESS FACTORS Value Proposition Replacement ratio to traditional latex products: 0.8 Replacement ratio to dry polymers: 1.3 ENVIRONMENTAL AND TOXICITY DATA Refer to the Material Safety Data Sheet(MSDS), SECTIONS 11 and 12,for the most current data. SAFETY AND HANDLING As with any chemical, CORE SHELL 71301 should be handled with responsible care. Refer to the Material Safety Data Sheet(MSDS), SECTIONS 3 and 8, for the most current data. In case of small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Smaller spills can be effectively cleaned up with NALCO POLYCLEAN 7. STORAGE Keep containers closed and protect from frost and moisture. Low temperatures should be avoided since viscosity increases and pumping problems can occur. When frozen, warm the product slowly to ambient temperature and agitate with a low(<200) RPM mixer. After warming up to 8-10°C and re- homogenization by gentle agitation for about 2 hrs, the product can be re-used without loss in efficiency. Nevertheless freezing should be avoided. When the product has been exposed to heat, the product should be gently agitated while its temperature is allowed to lower to room temperature.After the product is back to room temperature, about 2 hrs of gentle agitation should be sufficient to make the product ready for use. While product performance should not be affected if the product freezes or warms up, some loss in physical stability should be expected. If the product is to be stored for longer than two weeks, i.e., bulk tank storage, periodic agitation of the product will help keep the product fully homogenized and ensure consistent performance. Refer to the Material Safety Data Sheet (MSDS), SECTION 7,for the most current data. REMARKS If you need assistance or more information on this product, please call your nearest Nalco Representative. For more news about Nalco Company, visit our website at www.nalco.com. For Medical and Transportation Emergencies involving Nalco products, please see the Material Safety Data Sheet for the phone number. ADDITIONAL INFORMATION CORE SHELL, NALCO,the Logo and Tagline are trademarks of Nalco Company (3-9-2007) Each application is unique. Testing products of different charge and molecular weight is highly recommended for proper program selection. Emulsion flocculants should be inverted to a 0.5% concentration. After makeup and proper aging, a further dilution of the sample may be necessary for jar testing in order to gain adequate dispersion, and minimize adherence to testing equipment. SAFETY DATA SHEET NALGO PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME : Caustic 25 COMPANY IDENTIFICATION : Nalco Company 1601 W. Diehl Road Naperville, Illinois 60563-1198 EMERGENCY TELEPHONE NUMBER(S) : (800)424-9300 (24 Hours) CHEMTREC NFPA 704M/HMIS RATING HEALTH : 3/3 FLAMMABILITY: 0/0 INSTABILITY: 2/2 OTHER : 0= Insignificant 1 =Slight 2 =Moderate 3 = High 4= Extreme *=Chronic Health Hazard 2. COMPOSITION/INFORMATION ON INGREDIENTS Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for the nature of the hazard(s). Hazardous Substance(s) CAS NO % (w/w) Sodium Hydroxide 1310-73-2 10.0- 30.0 3. HAZARDS IDENTIFICATION **EMERGENCY OVERVIEW** DANGER Corrosive. May cause tissue damage. Do not get in eyes, on skin,on clothing. Do not take internally. Use with adequate ventilation. Keep container tightly closed and in a well-ventilated place. In case of contact with eyes,rinse immediately with plenty of water and seek medical advice. After contact with skin,wash immediately with plenty of water. Wear a face shield. Wear chemical resistant apron,chemical splash goggles, impervious gloves and boots. Not flammable or combustible. May evolve oxides of sodium under fire conditons. PRIMARY ROUTES OF EXPOSURE : Eye, Skin HUMAN HEALTH HAZARDS-ACUTE : EYE CONTACT: Corrosive. Will cause eye burns and permanent tissue damage. SKIN CONTACT: Corrosive;causes permanent skin damage. Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 1 /10 P4d SAFETY DATA SHEET NALGO PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC INGESTION : Not a likely route of exposure. Corrosive; causes chemical burns to the mouth,throat and stomach. INHALATION : Not a likely route of exposure. Elevated temperatures or mechanical action may form vapors, mists or fumes which may be irritating to the eyes, nose,throat and lungs. AGGRAVATION OF EXISTING CONDITIONS : A review of available data does not identify any worsening of existing conditions. HUMAN HEALTH HAZARDS-CHRONIC: No adverse,effects expected other than those mentioned above. 4. FIRST AID MEASURES EYE CONTACT: Immediately flush eye with water for at least 15 minutes while holding eyelids open. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Get immediate medical attention. • SKIN CONTACT: Immediately flush with plenty of water for at least 15 minutes. For a large splash,flood body under a shower. Remove contaminated clothing.Wash off affected area immediately with plenty of water. Get immediate medical attention. Contaminated clothing,shoes, and leather goods must be discarded or cleaned before re-use. INGESTION : Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious,washout mouth and give water to drink. INHALATION : Remove to fresh air, treat symptomatically. Get medical attention. NOTE TO PHYSICIAN : Probable mucosa!damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient,the physician's judgement should be used to control symptoms and clinical condition. 5. FIRE FIGHTING MEASURES FLASH POINT: None EXTINGUISHING MEDIA: Not expected to burn. Use extinguishing media appropriate for surrounding fire. FIRE AND EXPLOSION HAZARD : Not flammable or combustible. May evolve oxides of sodium under fire conditons. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING : In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit. Nalco Company 1601 W. Diehl Road•Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 2/10 PdSAFETY DATA SHEET N ALCO PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS : Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Keep people away from and upwind of spill/leak. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment(for fires,spills, leaks,etc.)readily available. Notify appropriate government, occupational health and safety and environmental authorities. METHODS FOR CLEANING UP: SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable,covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Wash site of spillage thoroughly with water. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13(Disposal Considerations). ENVIRONMENTAL PRECAUTIONS : Do not contaminate surface water. 7. HANDLING AND STORAGE HANDLING : • Do not get in eyes,on skin,on clothing. Do not take internally. Use with adequate ventilation. Avoid generating aerosols and mists. Do not mix with acids. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. STORAGE CONDITIONS: Store the containers tightly closed. Store separately from acids. Store in suitable labeled containers. SUITABLE CONSTRUCTION MATERIAL: Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that compatibility is tested prior to use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS : Exposure guidelines have not been established for this product. Available exposure limits for the substance(s)are shown below. Substance(s) Category: ppm mg/m3 Non-Standard Unit Sodium Hydroxide ACGIH/Ceiling 2 OSHA Z1/PEL 2 ENGINEERING MEASURES : General ventilation is recommended. Use local exhaust ventilation if necessary to control airborne mist and vapor. Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 3/10 PdSAFETY DATA SHEET N A LC 0 PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC RESPIRATORY PROTECTION : Where concentrations in air may exceed the limits given in this section or when significant mists,vapors,aerosols,or dusts are generated,an approved air purifying respirator equipped with suitable filter cartridges is recommended. Consult the respirator/cartridge manufacturer data to verify the suitability of specific devices. In event of emergency or planned entry into unknown concentrations a positive pressure,full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection,fit testing,training, maintenance and inspection. HAND PROTECTION : When handling this product,the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled. Please contact the PPE manufacturer for advice on what type of glove material may be suitable. Gloves should be replaced immediately if signs of degradation are observed. SKIN PROTECTION : Wear chemical resistant apron,chemical splash goggles, impervious gloves and boots. A full slicker suit is recommended if gross exposure is possible. EYE PROTECTION : Wear a face shield with chemical splash goggles. HYGIENE RECOMMENDATIONS : Use good work and personal hygiene practices to avoid exposure. Eye wash station and safety shower are necessary. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals.When handling this product never eat, drink or smoke. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE Liquid APPEARANCE Clear ODOR None SPECIFIC GRAVITY 1.19 DENSITY 9.91 lb/gal SOLUBILITY IN WATER Complete pH (7.5%) 14.0 FREEZING POINT 12- 14°F/-10°C VAPOR PRESSURE 13 mm Hg @ 140°F/60 °C Note:These physical properties are typical values for this product and are subject to change. 10. STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. Nalco Company 1601 W. Diehl Road •Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 4/10 P4d SAFETY DATA SHEET N ALCO PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC HAZARDOUS POLYMERIZATION : Hazardous polymerization will not occur. CONDITIONS TO AVOID: Freezing temperatures. MATERIALS TO AVOID : Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric,chromic,sulfonic) may generate heat, splattering or boiling and toxic vapors. HAZARDOUS DECOMPOSITION PRODUCTS : Under fire conditions: Oxides of sodium 11. TOXICOLOGICAL INFORMATION No toxicity studies have been conducted on this product. SENSITIZATION : This product is not expected to be a sensitizer. CARCINOGENICITY: None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC),the National Toxicology Program (NTP)or the American Conference of Governmental Industrial Hygienists (ACGIH). HUMAN HAZARD CHARACTERIZATION : Based on our hazard characterization,the potential human hazard is: High 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL EFFECTS: The following results are for the product, unless otherwise indicated. Acute Fish Results : Species Exposure Test Type Value Test Descriptor Fathead Minnow 96 h LC50 351 mg/I Product Fathead Minnow 96 h LC50 >7,000 mg/I pH Adjusted Product ACUTE INVERTEBRATE RESULTS: Species Exposure Test Type Value Test Descriptor Ceriodaphnia dubia 48 h LC50 334 mg/I Product Ceriodaphnia dubia 48 h LC50 >7,000 mg/I pH Adjusted Product MOBILITY: The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface)Suite TM,provided by the US EPA.The model assumes a steady state condition between the total input and output.The level III model does not require equilibrium between the defined media.The information provided is Nalco Company 1601 W. Diehl Road •Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 5/10 frfrgil SAFETY DATA SHEET N ALCO PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air,water and soil/sediment in the approximate respective percentages; Air Water Soil/Sediment <5% 30-50% 50- 70% ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization,the potential environmental hazard is: Low If released into the environment,see CERCLA/SUPERFUND in Section 15. 13. DISPOSAL CONSIDERATIONS If this product becomes a waste,it could meet the criteria of a hazardous waste as defined by the Resource Conservation and Recovery Act(RCRA)40 CFR 261. Before disposal,it should be determined if the waste meets the criteria of a hazardous waste. Hazardous Waste: D002 Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in a properly licensed hazardous waste treatment, storage,disposal or recycling facility. Consult local, state, and federal regulations for specific requirements. 14. TRANSPORT INFORMATION The information in this section is for reference only and should not take the place of a shipping paper(bill of lading) specific to an order. Please note that the proper Shipping Name/Hazard Class may vary by packaging, properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows. The presence of an RQ component(Reportable Quantity for U.S. EPA and DOT) in this product causes it to be regulated with an additional description of RQ for road,or as a class 9 for road and air, ONLY when the net weight in the package exceeds the calculated RQ for the product. LAND TRANSPORT: Proper Shipping Name: SODIUM HYDROXIDE SOLUTION Technical Name(s) : UN/ID No: UN 1824 Hazard Class- Primary: 8 Packing Group : II Flash Point: None Reportable Quantity(per package) : 4,000 lbs RQ Component: SODIUM HYDROXIDE AIR TRANSPORT(ICAO/IATA) : Nalco Company 1601 W. Diehl Road• Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 6/10 PdSAFETY DATA SHEET N ALCO PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC The presence of an RQ component(Reportable Quantity for U.S. EPA and DOT) in this product causes it to be regulated with an additional description of RQ for road,or as a class 9 for road and air,ONLY when the net weight in the package exceeds the calculated RQ for the product. Proper Shipping Name: SODIUM HYDROXIDE SOLUTION Technical Name(s) : UN/ID No: UN 1824 Hazard Class-Primary: 8 Packing Group: II Reportable Quantity(per package) : 4,000 lbs RQ Component: SODIUM HYDROXIDE MARINE TRANSPORT(IMDG/IMO) : Proper Shipping Name : SODIUM HYDROXIDE SOLUTION Technical Name(s) : UN/ID No: UN 1824 Hazard Class- Primary: 8 Packing Group : II 15. REGULATORY INFORMATION This section contains additional information that may have relevance to regulatory compliance. The information in this section is for reference only. It is not exhaustive, and should not be relied upon to take the place of an individualized compliance or hazard assessment. Nalco accepts no liability for the use of this information. NATIONAL REGULATIONS, USA: OSHA HAZARD COMMUNICATION RULE, 29 CFR 1910.1200 : Based on our hazard evaluation,the following substance(s) in this product is/are hazardous and the reason(s) is/are shown below. Sodium Hydroxide : Corrosive CERCLA/SUPERFUND, 40 CFR 302 : This product contains the following Reportable Quantity(RQ) Substance.Also listed is the RQ for the product. If a reportable quantity of product is released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D.C. (1-800-424-8802). RQ Substance RQ Sodium Hydroxide 4,000 lbs SARA/SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (TITLE III) -SECTIONS 302,311, 312,AND 313 : SECTION 302- EXTREMELY HAZARDOUS SUBSTANCES(40 CFR 355) : This product does not contain substances listed in Appendix A and B as an Extremely Hazardous Substance. Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 7/10 PSAFETY DATA SHEET N ALC 0 PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC SECTIONS 311 AND 312-MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370) : Our hazard evaluation has found this product to be hazardous. The product should be reported under the following indicated EPA hazard categories: X Immediate(Acute) Health Hazard Delayed (Chronic) Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Under SARA 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are: 500 pounds or the threshold planning quantity(TPQ),whichever is lower,for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. SECTION 313- LIST OF TOXIC CHEMICALS (40 CFR 372) : This product does not contain substances on the List of Toxic Chemicals. TOXIC SUBSTANCES CONTROL ACT(TSCA) : The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory(40 CFR 710) FEDERAL WATER POLLUTION CONTROL ACT,CLEAN WATER ACT,40 CFR 401.15/formerly Sec.307,40 CFR 116.4/formerly Sec.311 : This product contains the following substances listed in the regulation.Additional components may be unintentionally present at trace levels. Substance(s) Citations • Sodium Hydroxide Sec.311 CLEAN AIR ACT, Sec. 112 (Hazardous Air Pollutants, as amended by 40 CFR 63),Sec.602(40 CFR 82,Class I and II Ozone Depleting Substances) : Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels. CALIFORNIA PROPOSITION 65: Substances listed under California Proposition 65 are not intentionally added or expected to be present in this product. MICHIGAN CRITICAL MATERIALS : Substances listed under this regulation are not intentionally added or expected to be present in this product. Listed components may be present at trace levels. STATE RIGHT TO KNOW LAWS: The following substances are disclosed for compliance with State Right to Know Laws: Sodium Hydroxide 1310-73-2 Nalco Company 1601 W. Diehl Road• Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 8/10. PSAFETY DATA SHEET N A LC 0 PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC INTERNATIONAL CHEMICAL CONTROL LAWS : CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) : The substance(s) in this preparation are included in or exempted from the Domestic Substance List(DSL). 16. OTHER INFORMATION This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to insure safe workplace operations. Please consult your local sales representative for any further information. REFERENCES Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices,American Conference of Governmental Industrial Hygienists, OH., (Ariel InsightTM CD-ROM Version),Ariel Research Corp., Bethesda, MD. Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland(TOMES CPSTM" CD-ROM Version), Micromedex, Inc., Englewood, CO. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, international Agency for Research on Cancer. Integrated Risk Information System, U.S. Environmental Protection Agency,Washington, D.C. (TOMES CPST"' CD-ROM Version), Micromedex, Inc., Englewood, CO. Annual Report on Carcinogens,National Toxicology Program,U.S.Department of Health and Human Services, Public Health Service. Title 29 Code of Federal Regulations, Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration(OSHA), (Ariel InsightTM CD-ROM Version), Ariel Research Corp., Bethesda, MD. Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPSTM CD-ROM Version), Micromedex, Inc., Englewood, CO. Ariel InsightTM (An integrated guide to industrial chemicals covered under major regulatory and advisory programs), North American Module,Western European Module, Chemical Inventories Module and the Generics Module(Ariel InsightTM' CD-ROM Version),Ariel Research Corp., Bethesda, MD. The Teratogen Information System, University of Washington, Seattle,WA(TOMES CPST'" CD-ROM Version), Micromedex, Inc., Englewood, CO. Nalco Company 1601 W. Diehl Road • Naperville, Illinois 60563-1198• (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 9/10 P1SAFETY DATA SHEET N ALCO PRODUCT Caustic 25 EMERGENCY TELEPHONE NUMBER(S) (800)424-9300(24 Hours) CHEMTREC Prepared By: Product Safety Department Date issued : 09/19/2011 Version Number: 1.8 Nalco Company 1601 W. Diehl Road •Naperville, Illinois 60563-1198 • (630)305-1000 For additional copies of an MSDS visit www.nalco.com and request access. 10/ 10 DUKE Allen Steam Station 253 Plant Allen Raw ENERGY. Belmont, NC28012 RECEIVED/NCDENR/DWR No t, 2 1. ?_018 WORDS November 16, 2018 MOORESVILLE REGIONAL OFFICE North Carolina Dept. of Environmental Quality Division of Water Resources -Wastewater Complex Permitting Section Attn: Ms. Julie Grzyb 1612 Mail Service Center Raleigh, North Carolina 27699-1617 Subject: NPDES Stormwater Permit Minor Revision Allen Steam Station Permit No. NCS000546 Gaston County Dear Ms. Grzyb: Duke Energy respectfully requests the inclusion of previously permitted stormwater outfall SW015 to the Allen Steam Station industrial stormwater permit NCS000546. The following narrative provides a timeline of SW015 and a justification for this request. • On August 31, 2016, an update to the NPDES wastewater permit application was submitted requesting that NC DEQ Division of Water Resources include the historically permitted stormwater outfall SW015 and associated drainage area in the NC0004979 wastewater permit. This was requested because, at the time, this flow contained both industrial stormwater and potentially, a wastewater contribution from ash basin seepage, if any. • In a July 2016 letter, Duke Energy requested the removal of SW015 from the Allen industrial stormwater permit for future inclusion in the wastewater permit. NC DEMLR approved this request on September 9, 2016. • Subsequently, the contributing ash basin seepage flow to the SW015 drainage was reconfigured to more permanently collect, pump, and return flow to the ash basin. The potential ash basin seepage flow is not included in NPDES wastewater permit NC0004979 and is currently being returned to the ash basin through a collection and pumping system • NPDES Wastewater Permit No. NC0004979 was received July 13, 2018 without the inclusion of SW015. • Stormwater outfall SW015 is a 36-inch reinforced concrete pipe (RCP) which discharges to the Catawba River (Lake Wylie) and drains an approximately 163.6-acre area. The drainage area runoff is from a large soil borrow area, as well as two ash structural fill areas, and approximately one mile of gravel and dirt road. The coordinates of SW015 are 35° 10' 52" N by 81° 00' 21"W. The Active Ash Basin Emergency Spillway, WW007, drains to the SW015 RCP, as demonstrated in the attached drainage area map. Page 2 Due to the reconfiguration of the contributing wastewater source and the unaltered state of the original SW015 drainage area, Duke Energy requests to reestablish the previously permitted outfall SW015 in the subject permit. Copies of the illustration of the new configuration and a drainage area map is included as attachments with this submittal. If you have any questions, please contact Ms. Elizabeth Glenn (980) 373-0530. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerely, It.,,., 1 w , Terry W. Tuck General Manager II Allen Steam Station Fossil/Hydro Operations - Carolinas Coal Generation Cc: Mooresville Regional Office, DWR Wastewater Program Sergei Chernikov - NCDEQ Elizabeth Glenn Randy Gantt Tina Woodward 3 • S 6 7 e .- _. 2 SHEET 1 - 02 15 Woell PS .x+:i- dl vv fl h ,rh n. r i.x Rr. ,R1fi - _ A hN -r' stre vicaso7Y MAP ■ uKAVLL © sr_ %' 16 • �I ;•A • CATAWBA RIVER ... „� i STORAGE AREA—�� `A I LAKE WYLIE) in II ^v i ACCESS ROAD �w• © • • • • OUTFACE SW013-015 G / ■ 2 u • 1O ff CMP TYP OF OUTFALL Q f i s sf f t0 COAL YARD SUMP DRAINAGE AREA GROUP 13� _ _ ] ■ SOIL BORROW AREA wa v • *a, • F Z • *Arear OUTFALL SWO1,3-014 • ssss�sssssss ++Et■1ss1■Tslrss I OUTFALL SW01J-01.J v ' 15 • , OUTFALL SWO1J-012 I OUTFALL SW014 OUTFALL SWO1J-011 E o I OUTFACE SW01J-010 _ 0 _i OUTFALL SWO1.3-009 - KEY NOTE: Q O DRAINAGE AREA I ASH LANDFILL SUMP • = DRAINAGE AREA OUTFALL SWO13-008 ASH STRUCTURAL FILL < LEGEND: ° OUTFACE SWO1J-007 PUMP TO ASH BASIN lill==="7 0 ■•• DRAINAGE AREA BOUNDARY OUTFALL SWO15 (SEE SHEET 2 FOR SPILLWAY DETAIL) — PROPERTY LINE — �' ',,''is♦ .a•* R ....r • ♦ ' /r//////////// /////////////////////// I STRUCTURE LEGEND: ....... r r �� II 0WATER TOWER ♦ I • ■ ♦ .r r ■ 2 MR COMPRESSOR C • ■ O3 GENERATOR d I • ■ r r r r r r r r r r r r r r r r■....■..• • ■ • •••,r r/r r r r r r a. r r r r r r r r r ■ ■ f ■ D ■ ■ ASH BASIN STORMWATER/SEDIMENT "' _. WATERSHED DETENTION BASINS RECEIVED/NCDENR/DWR NOV 21 2018 PLAN I e WQROS MOORESVILLE REGIONAL OFFICE - DRAWN BY: CML DUKE ENERGY CAROLINAS, LLC , I-01 _ _ — ALLEN STEAM STATION DESIGNED BY: •MECHANICAL STORMWATER POLLUTION A CHECKED BY: ELECTRICAL PREVENTION PLAN SITE PLAN APPROVED BY: DATE: SGYL: M..CMT^.O. !v. R Eng{nesrin9,I^�•of the Cerollnaa License Number:F-0116 PE SEAL NO._ DATE REVISION DRN DSGN Cues APPR CML ELEC NEON PROJECT NUA CA:OD00000002341 W I -400. _ SHEET 1 • 440 S Church Street,SuIe 1000 Charlotte,NC 21202.2075 2 I I 4 I S I ■ I 7 I a 1 1 2 3 4 5 6 7 e SW013 07 FOR FULL DETAIL, REFER to ALLEN STEAM STATION RETIRED ASH SHEET 2 • N BASIN DAM PRINCIPLE SPILLWAY REPLACEMENT(ALL-201) 'f-- E%ISn INLET/RISER ,�Y M DRAWINGS: ALN C901.002 H -EAST HOPE PIPES MAINTAINED 0D DURING i :• CONSTRUCTION ' rI C - /Y . _ _ _ NOTES: - - - 'M'. --EXISTMOITORINGWELLS 1 AREA SHOWN IS THE SOUTH EAST PORTION OF THE P"� RETIRED ASH BASIN WHERE THE EXISTING RISER AND 4 D�"P DISCHARGING 36" PIPE ARE TO BE REPLACED AND Ey5 5 OP♦' 1 —tXXRING.Tva __EUNLITY 1MMNW44 ER PARTIALLY ABANDONED IN—PLACE EXIST RISERTOWER B R II TURE TRUCT - EXIST VALVES 6UGVAULT 2. ALL ELEVATIONS SHOWN ARE IN FEET GRATE ERS TOP E GR URF ISEE HISTORICAL dGWING ALN C901002 01 A FOR KISER EXIST SyORM DRAIN w Iw: MAILS i. . • G $ A 1 C v I • rP J - I • ? 7/TOST.INLET6- - .. ORM DIMIN ,. APPROXLOCATION OF EXIST36-FORCE MAINS -_�, o jIPING TVP ISEE HISTORICAL ORANANGS ALN COO1002 EIS 016 FOR INFO ON THE ' FORCE MAINS I ER po {,O,TT POLE T pR -- EXIST FENCE TYP p f _..-6'5X E/., - -EXIST TOE TRAIN rc �Sr I��pC, - , ABANDONED DURING, i - ,ISEE OS�ORICALEDRACWING AW C90�002LOAsm f QP.1L' i'/W# - CONSTRUCTION - FORGO aBOLLARCI DETAILS T I'r �' ` - _-EXIST RAIL ROAD TRACKS . p I _ { Q I 1 - E isr' EXIST TREE-- ."-CA STUMP"VP EXIST MANHOLE- I SW015 TOP.602 0 .. 4 NV•569A E = E%is• E SW015 DETAIL WITH SPILLWAY SW015 PLAN VIEW EXIST RISER TOWER 4 -EMERGENCY SPILLWAY BY OTHERS I - w 4 2 �`55 N 522120 y // I Y 6 1 -�� az9 Q, h� i--SEE NOTE e 6•• DKL0 e\ 44' THIS DRAWING D D "HEADWALL_ _ I GRADING y� R` - • /p 25 Vn��� .�LYN`ly,* OR�o1 ls, ti4* `/BOLLARD. .1 /YL ?tiP qM :.. �. Typ.-1")4_ IR CLASS 1 RIPRAP 0 R Cy aZ 414''W 4: a"'--"`---����:: J 2 DEEP WITH -. ,1, y� a I IR • - GEOTEXTILE - EXIST 36 RCP OUTFAL ' PROPOSED HEADWALL \`1\�XJ—'VR oN ' PIPE TO BE ABANDONED ISEE PROFILE, 4 y,♦R" SEE ABANDONMENT,PLAN APPROX LOCATION OF / DRAWING NO / EXIST 36 FORCE MAIN To 20'OF NEW 54'HOPE OUTFACE - /a AL\_C901 002 009/ ACTIVE BASIN PIPE TO REPLACE EXIST 36'RCP 4 = IppO}�;�/ 7 OF EXIST 36 RCP OUTFACE C 4,- 4'Ac/� PIPE TO REMAIN C Nr r 'CONCRETE ENCASEMENT FROM -�/ , O/A, BACK OF HEADWALL TO THRUST "/N :-,,BLOCK - W} uR i _____-- ---SEE ENLARGED - 84'OF NEW 42HOPE---- __--- ---- PLAN VIEW _4-_ e H OUTFACE PIPE 70 _ -. --- 4 AY REPLACE EXIST 36 RCP p yr' h aOp.O P' ^ �''� N —102'OF EXIST 36'RCP -_ / A - ,R WTFALL PIPE TO REMAIN �55 \PLOWABLE FILL FROM THRUST- •\ 2.� _PUG N526990 _ BLOCK TO PROP MANHOLE R O ♦ / O�JE\. --- AROUND NEW 42'HOPE PIPE y,T• II11 t y O i Ly Y, '9SF. y�,`. Hm�:ti 1 -PLOWABLE FILL It _. Nsx69T0 e Gy/r ''O� \ DOWNSTREAM-B, _.��L-1 B aLU., RQ Qs EXIST OUTLET INV 5664 l 'G 1? --- STA 2071 32 B 8__I 8' 1 U,2+ — DRAWN BY' CML DUKE ENERGY CAROLINAS, LLC ALLEN STEAM STATION FYZ DESIGNED BY: MECHANICAL A _ _ STORMWATER POLLUTION A CHECKED BY: ELECTRICAL PREVENTION PLAN _ SITE PLAN -- APPROVED BY: DATE: HOR Engineering,Inc.of the Carolinas License Number:F-0116 _ scue: pe.-.Nc/s.Irn ea AT•. 440 S Church Street,Suite 1000 Charlotte,NC 28202 2075 PE SEAL NO._ DATE REVISION DRN OWN CNKD APPR CML ELEC DITTO PROJECT NUMBER:0000000002341M t•-ao0' SHEET 2 -I 1 1 2 I 3 I 4 I 5 I 6 I 7 I e DUKE Laserfiche Allen Steam Station 253 Plant Allen Roaa ENERGY® Belmont, NC 28012 CAROLINAS RECEIVED/NcDENRNVvr' 2G ?flt September 20, 2018 WQROSMOORESV!LL.F REGIONAL OFFICE Mr. Ori Tuvia North Carolina Dept. of Environmental Quality 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Subject: Allen Steam Station NPDES Permit #:NC0004979 Gaston County Dear Mr. Tuvia: Duke Energy submits this written notification and status update of the Flue Gas Desulfurization area Stormwater Basin (hereinafter"Stormwater Basin") overtopping that occurred at Allen Steam Station on September 16, 2018 during tropical storm Florence, and as verbally reported to the Agency on September 17, 2018. Overtopping of the Stormwater Basin occurred during intense rainfall from tropical storm Florence. Due to the intensity of rainfall, the two stormwater basin pumps could not displace stormwater as quickly as in-flow arrived. Subsequently, stormwater from the event exited the basin and crossed a vegetated swale to an inlet surrounded by silt fencing and rock checks. The inlet discharges to a vegetated landing, surrounded by an earthen berm, rip-rapped slope, silt-fencing, and multiple rock checks. Due to the precipitation intensity and saturated landscape, an accurate volume of the stormwater exceeding the basin rim cannot be determined. The overflow occurred for approximately 2 hours. Station personnel and environmental staff surveyed the areas, post storm event. Included in this survey was a review of the nearest perennial stream that empties into the plants cooling water discharge canal and is approximately 70 yards from the rock checks. No indication of environmental impacts from the overtopping were observed. Station personnel conducted testing of the Stormwater basin pumps and performed a visual survey of inlet structures for damage or blockage. While it is believed this was an anomalous event caused by a short duration intense rainfall associated with the tropical system, a stormwater drainage assessment is being re-validated to assure current site construction activities have not modified expected inflows beyond the design capacity of the Stormwater Basin. If you have any questions, please contact Ms. Elizabeth Glenn (980) 373-0530 or Elizabeth.glenn@duke-energv.com. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerely, 0, :✓ Terry W. uck General Manager II Allen Steam Station Fossil/Hydro Operations - Carolinas Coal Generation CC: Elizabeth Werner— NCDEQ Waste Management BC: Terry W. Tuck Randy Gantt Richard Baker via email Liz Glenn Courtney Murphy via email Shannon Langley via email 4.N Laserfiche Duke Energy ENERGY. steam „ 235 Ptant Men Road Belmont,NC 28102 RECEIVED!NCDENR/DWR November 08, 2018 NOV - 9 2018 WOROS MOORESVILLE REGIONAL OFFICE Mr. Jeff Poupart, Section Chief NC DWR Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Notification of system component startup Allen Steam Station Permit #NC0004979 Gaston County Dear Mr. Poupart: In accordance with requirements found in Section A.(9.) of subject NPDES permit, Duke Energy hereby provides notification of intent to commence discharges of wastewater from outfall 006 on or after December 12, 2018. As required, Duke Energy will obtain and submit EPA Form 2C analysis within 180 days of the commencement of the discharge. If there are any questions about this notification,please contact Elizabeth Glenn at(704) 373-0530 or elizabeth.glenn@duke-energy.com. l certif v finder penalty of lcnr mar!hi;document and all attachments.were prepared under HIP direction or smperl iliou in arc ordance with a 1YSteu!desi,tined to aVW/re that qualified personnel properly gather and erulume the inhumation 31hntitted. Baud on my inquire of the pers,up in'pel:con;a ho rmarpa;e the;18tein, or those persons dirertlr respon.iihle ter gathering the information, the inhumation submitted is. tO the hest of mil know/edge and belief true. accurate. and complete. lam aware that there are Sty niflrant penalties for 1(1)I14t6li false ttlfal7meltuin, including the possibility of fine and imprisonment/or knowing i ioiations. Sincerely, • ICJ Terry Tuck, Station Manager Allen Steam Station cc: Cory Basinger- DEQ Mooresville Regional Office Liz Glenn/Filenet - via email Randy Gantt UPS Tracking: Raleigh: 1Z X67 601 24 9627 8276 Mooresville: 1Z X67 601 24 9682 6085 RECEIVED/NCDENR/DWR Response with Plan of Action to Compliance Evaluation Inspection NOV-2017-PC-0723. JAN 1 9 gut WQROS 1.The facility has no source of standby power. MOORESVILLE REGIONAL OFFICE Presently we have a contract with the City of Kings Mountain to process our wastewater in the event of an extended outage at our plant. We also have 2 waste hauling companies that can haul our waste to Kings Mountain in the event of an extended outage. We are awaiting results from a study being conducted by the NC School of Government under a grant we received for a regionalization/merger study with the City of Kings Mountain. We also have a contact with W.K.Dickson for engineering services to eliminate our WWTP and tie into Kings Mountain Sewer System. The engineering is substantially completed, and we are awaiting results of the study being conducted by the NC School of Government before applying for a loan/grant to begin the construction phase of eliminating our plant and contracting with the City of Kings Mountain to process our wastewater. Our present plans are to continue to operate as described above until we eliminate our WWTP and connect to the City of Kings Mountain. This is because it would be extremely expensive to install backup generators at the existing plant,which will be eliminated as soon as study is completed and construction can be completed. The new system includes backup generators at all lift stations. 2.The facility had no safe way to collect grab samples from the effluent pipe. We have started installing a set of steps to provide access to effluent discharge. This will include a small platform,steps,handrails and toe boards. Work should be completed by 23 March 2018. 3.The effluent sampler lacks proper heating and insulation to maintain temperature above 0 degrees in the sampler and to prevent tubing from freezing. We have installed a heater in the cabinet and are in the process of insulating the tubing. Work should be completed by 31 January 2018. 4.The skimmer needs to be fixed in the clarifier.Floating sludge was evident. We are in the process of obtaining contractor to pull and repair skimmer.Work should be completed by 30 March 2018. 5.The bar screen needs to be either fixed or replaced. Parts of the bar screen are missing allowing debris to bypass the bar screen. Bar screen will be pulled and repaired/replaced where bar is loose at one end. Whatever method is used,the integrity of the bar screen will be insured before replacing. This should be completed by 23 March 2018. 6.The flow meter does not chart the flow. The flow meter which was recently repaired and calibrated at a cost of$ 1,365.96 provides a printout of(1)24 hour total flow(2)average gpm(3)min and max gpm with time of day. This meter is not designed for charting. If a Chart is required,it will require replacing flowmeter. Our intent was to continue use of present meter which furnishes required information in digital form until the WWTP is eliminated as explained in item#1. Please advise. 7. The facility Chain of Custody forms fail to indicate the start and finish time and the date of the composite sampler. Our testing facility(Water Tech Labs)are aware of this deficiency. Until they modify their process we are entering the start and finish times with date. • r', - 2_. Bill Willis Mayor • AiA NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Ire Coleen H. Sullins Dee Freeman Governor Director Secretary ri!.'}:_. . i r\fit •r` July 12, 2011 Mr. Allen Stowe Duke Energy Corporation - 'q.LE -;_r N EC13K/ PO Box 1006 ^1:., r 1..L� REGIONAL. OF-:'"I-._ Charlotte, NC 28201-1006 Subject: Permit Correction NPDES Permit No.NC0004979 Duke Energy Carolinas Allen Steam Station Gaston County Dear Mr. Stowe: Division of Water Quality (Division) personnel have discovered an error in Condition A (7) of the subject permit issued on January 18, 2011. Regarding COD sampling, the permit incorrectly specifies this as carbonaceous oxygen demand. This should be chemical oxygen demand. Attached is a corrected page, which you should place in your permit file. All other terms and conditions of this permit remain unchanged. It is our understanding that you have been monitoring the correct parameter, chemical oxygen demand. Therefore, you have not been deficient in monitoring, despite this error. If you have questions, please contact Gil Vinzani at [gil.vinzani@ncdenr.gov] or at (919) 807-6395. Sincerely, q/Z ergei Chernikov S iCc: /Mooresville Regional Office, Surface Water Protection Section NPDES Unit Files Central Files 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 • Location:512 N.Salisbury St.Raleigh,North Carolina 27604 One Phone:919-807-6300\FAX:919-807-6495\Customer Service:1-877-623-6748 North Carolina Internet:http:11 h2o.state.nc.us/ • �aturall� An Equal Opportunity\Affirmative Action Employer • • Permit NC A(7) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Internal Outfall 005)' During the period beginning on the effective date of this permit and lasting until permit expiration, the Permittee is authorized to discharge from internal outfall 005-treated FGD wet scrubber wastewater to ash settling basin. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Sample Average Maximum Frequency Type Location Pump logs or Flow Monitor& Report Monthly similar Effluent readings Total Suspended Solids Monitor&Report Weekly Grab Effluent Chemical Oxygen Demand Monitor& Report Weekly Grab Effluent (COD) (co: o) Total Arsenic Monitor& Report Weekly Grab Effluent Total Cadmium Monitor& Report Weekly Grab Effluent Total Chromium Monitor&Report Weekly Grab Effluent Chloride Monitor&Report Weekly Grab Effluent Total Mercury Monitor&Report Weekly Grab Effluent Total Nickel Monitor& Report Weekly Grab Effluent Total Selenium Monitor&Report Monthly Grab Effluent Total Silver Monitor&Report Weekly Grab Effluent Total Zinc Monitor& Report Weekly Grab Effluent Total Beryllium Monitor& Report Weekly Grab Effluent Footnotes: 1. "Effluent" shall be defined as the discharge from the FGD wastewater treatment system prior to discharge to the ash settling basin. All flows shall be reported on monthly DMRs. If no flow occurs during a given month, the words "no flow" shall be clearly written on the front of the DMR. All samples shall be of a representative discharge. DMRs for this outfall shall be submitted only after discharge commences from the FGD system. Sampling is only required when this outfall is discharging. A(8) SPECIAL CONDITION FOR THE DISCHARGE OF ASIATIC CLAM/DEBRIS FILTER BACKWASH The permittee may backwash the intake filter for Unit 5 condenser cooling water on an as-needed basis. It is understood that this wash water will contain materials indigenous to the Catawba River such as Asiatic clams and light debris. As these are naturally occurring in the river environment, they may be discharged with no adverse affects to the receiving stream. The Permittee may not add any detergent, chemicals or other non-indigenous material to the wash water without explicit permission from the Division of Water Quality. 8 14:44• ffir a pr. D NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H.Sullins Dee Freeman Governor Director Secretary RECEIVED DIVISION OF WATER QUALITY JAN 2 4 2011 January 18, 2011 MOORESVtLLE REGIONAL OFFICE Mr. Allen Stowe Duke Energy Corporation EC13K/ PO Box 1006 Charlotte, NC 28201-1006 Subject: Issuance of NPDES Permit No.NC0004979 • Duke Energy CaroHnas Allen Steam Station Gaston County Dear Mr. Stowe: Division of Water Quality (Division) personnel have reviewed and approved your application for renewal of the subject permit. Accordingly, we are forwarding the attached NPDES discharge permit. It is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 15, 2007. A public hearing was held on October 19, 2010 in Mooresville seeking comments on the Draft permit and proposed continuation of the Clean Water Act Section 316(a) temperature variance. This final permit incorporates recommendations of the DWQ Hearing Officer as well as other changes. Listed below are all changes from the previous permit: • Structural integrity inspection of ash pond dam This condition requires the facility to inspect for dam integrity on a weekly basis and after any one-inch or greater rainfall event. Dam safety and design requirements per 15A NCAC 2K are required. • CWA Section 316(a) Thermal Variance This condition requires the facility to submit a Balanced and Indigenous Population (BIP) study plan that conforms to EPA study guidelines, and receives DWQ and EPA concurrence prior to study implementation. A BIP report must be submitted no later than 180 days prior to permit expiration, should the permittee request continuation of the CWA Section 316(a)thermal variance. 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 Location:512 N.Salisbury St.Raleigh,North Carolina 27604 One Phone:919-807.6300\FAX:919-807.64951 Customer Service:1-877-623-6748 NorthCarolina Internet:http: I h2o.state.nc.us 1 Naturally An Equal Opportunity\Affirmativealive Action Employer A •• Fish Tissue' Monitoring Near Ash Pond Discharge The facility shall conduct fish tissue monitoring near the ash pond discharge, once during the permit term, and analyze for arsenic, selenium, and mercury. The fish tissue monitoring shall be in accordance with the sampling plan approved by the Division. • Instream Monitoring The facility shall conduct semiannual instream monitoring at two BIP monitoring stations (located upstream and downstream of the ash pond discharge). Samples shall be analyzed for arsenic, selenium, mercury, chromium, lead, cadmium, copper, zinc, and total dissolved solids (TDS). Other changes from the previous permit remain. They include changing the WET testing requirement to reflect an instream waste concentration of 20%, and the addition of a permit condition for groundwater monitoring-well construction and sampling. If any parts, measurement frequencies, or sampling requirements contained in this permit are unacceptable, you have the right to an adjudicatory hearing upon written request within thirty (30) days after receiving this letter. Your request must take the form of a written petition conforming to Chapter 150E of the North Carolina General Statutes, and must be filed with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina 27699-6714. Unless such demand is made, this permit remains final and binding. This permit is not transferable except after notifying the Division of Water Quality. The Division may modify and re-issue, or revoke this permit. Please notice that this permit does not affect your legal obligation to obtain other permits required by the Division of Water Quality, the Division of Land Resources, the Coastal Area Management Act, or other federal or local governments. If you have questions, or if we can be of further assistance, please contact Gil Vinzani at [gil.vinzani@ncdenr.gov] or at (919) 807-6395. n erely, V 1 oleen . Sullins Enclosure: NPDES Permit FINAL NC0004979 Cc: US EPA Region IV, Pamela Myers Mooresville RegionaltOffice, St1 c it ter-Protection'Sectio1 Environmental Services Section, Aquatic Toxicology Unit, Susan Meadows* Kay Bond, Southern Environmental Law Center* David Merryman, Catawba Riverkeeper* Hope Taylor, CWFNC* IMPfklmatmislMeteke Central Files *E-mail copy Permit NC0004979 • STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Duke Energy Carolinas, LLC • is hereby authorized to discharge wastewater from a facility located at the Plant Allen Steam Station 253 Plant Allen Road (NCSR 2525) Belmont Gaston County to receiving waters designated as the Catawba and South Fork Catawba Rivers in the Catawba River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV hereof. This permit shall become effective March 1, 2011. This permit and authorization to discharge shall expire at midnight on May 31, 2015. Signed this day January 18, 2011: ri • Coleen H. Sullins, Di•ector Division of Water Quality By Authority of the Environmental Management Commission Permit NC0004979 ,• SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. Duke Energy Carolinas, LLC is hereby authorized to: 1. Continue to discharge: • Once through cooling water(outfall 001) • Operate a septic tank and ash pond with pH adjustment and discharge domestic wastewater, stormwater runoff, ash sluice, water treatment system wastewaters, FGD system blowdown, landfill leachate, and miscellaneous cleaning and maintenance wash waters (002). • Coal yard sump overflow (002A) and power house sump overflow (002B) • Miscellaneous equipment non-contact cooling and sealing water (003) • Miscellaneous non-contact cooling water, vehicle washwater, and intake screen backwash (004) From a facility located at the Plant Allen Steam Station on Plant Allen Road (NCSIR 2525), south of Belmont in Gaston County, and 2. Without adding detergents or chemicals of any kind, discharge Asiatic clam/debris filter backwash from the intake filter screen, in accordance with condition A (8), and 3. Continue to operate a Flue Gas Desulfurization (FGD) wet scrubber wastewater treatment system discharging to the ash settling basin through internal outfall 005; consisting of: • A flow equalization tank and a maintenance tank • Feed systems for lime, sulfide, ferric chloride, polymer, hydrochloric acid, and molasses-based nutrient • Two clarifiers • Dual heat exchangers • A selenium reduction bioreactor • A sludge treatment system including three filter presses; and 4. Discharge from said treatment works at the location specified on the attached map into the Catawba River(outfalls 002, 002A, 002E and 004) and the South Fork Catawba River (outfalls 001 and 003) which are classified Class WS-IV B and Class WS-V waters, respectively, in the Catawba River Basin. 2 • - Stint!F9int ',� s.` `•{ Ji • _ 1 , • , • 1 3 001 .r t .,t ne:1 • . } L. i , .ram 1 s( ti n r f `- .t.., Fig y//i' ti �I" r,l jj. �+ � - , „ .-" sue,• .' .1, ',,,, - 1, .., „: • 5 , c 003\i 004 vt . ` /,. 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A , HI t � rit r, k; fx ' t J . , J a ( ' t i w - + 5 ,!a ,,.., ✓- # v am ,• -�s ,�V � 1 4 ih ' 4 :�I ) rsr `�. 3' •Ji ' 1 t/ / ': x» r{' -' p - i i ,fI t: • '' , , ',/ �I � i )i:3 /'`"i\i'. .tit : ..�` ;'; ' �1� �' G.� ` i .4 �' s3Ft�,ifaif "r .+�%fit f !( ,t ,. z �.4Z Duke Energy Corporation Allen Steam Station Map not to scale State Grid/Quad: G14NE/Belmont Permitted Flow: Not limited Receiving Streams: Catawba and South Fork Catawba Rivers Stream Class: WS-V B 8-Digit IIUC 03050102 Drainage Basin: Catawba River Basin Sub-Basin: 03-08-34 Facility} . + k _ Latitude(011l): 35°11'23" N Longitude(001): 81°00'45" W Latitude(002): 35°10'30" N Longitude(002): 81°00'23" W Location latitude(002A): 35°11'34" N Longitude(002A): 81°00'22" W Latitude(0028): 35°11'36" N Longitude(00211): 81°00'30" W latitude(004): 35°11'35" N Longitude(004): 81°00'22" W NPDES Permit No. NC0004979 ' Not-th- Gaston County • • Permit NC0004979 • A (1) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 001) During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 001- Condenser Cooling Water (CCW). Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Max. Frequency _Flow Daily Pump Logs Effluent Temperature 38.9°C Daily Grab or Effluent (June 1 -September 30)1 (102 2F) Instantaneous Temperature 35°C Daily Grab or Effluent (October 1 -May 31)1 (95°F) Instantaneous Notes: 1. The Regional Administrator has determined pursuant to Section 316(a) of the Act that the thermal component of the discharge assures the protection and propagation of a balanced, indigenous population of shellfish, fish, and wildlife in and on the receiving body of water. Chlorination of the once through condenser cooling water, discharged through outfall 001, is not allowed under this permit. Should Duke Energy Carolinas, LLC wish to chlorinate its condenser cooling water, a permit modification must be obtained beforehand. • Permit NC0004979 • •, A(2) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002) During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 002— ash pond effluent. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow _ Weekly Instantaneous Influent or Effluent or Estimate Oil and Grease 15.0 mg/I 20.0 mg/I Quarterly Grab Effluent Total Suspended Solids 30.0 mg/I 100.0 mg/I Monthly Grab Effluent Total Copper 1.0 mg/I 2/Month Grab Effluent Total Iron ' 1.58 mg/I Monthly Grab Effluent Total Selenium Monthly Grab Effluent Total Arsenic 1 Quarterly Grab Effluent Total Cadmium ' Quarterly Grab Effluent Total Chromium Quarterly Grab Effluent Chloride Quarterly Grab Effluent Total Zinc' Quarterly Grab Effluent Total Nickel 1 Quarterly Grab Effluent Total Silver' Quarterly Grab Effluent Total Mercury 2 Quarterly Grab Effluent Total Beryllium Quarterly Grab Effluent Total Nitrogen Semi-annually Grab Effluent (NO2+ NO3+TKN) Chronic Toxicity 3 Quarterly Grab Effluent pH Between 6.0 and 9.0 Monthly Grab Effluent standard units Footnotes: 1. Total metals are defined by 40 CFR 136. Any method specified by 40 CFR 136 is considered acceptable for analysis. 2. Mercury shall be measured using EPA Method 245 or Method 1631 E. 3. Whole Effluent Toxicity shall be monitored by chronic toxicity(Ceriodaphnia) P/F at 20%. Tests shall be conducted in January, April, July and October, see Condition A (9). There shall be no discharge of floating solids or foam. • 4 • Permit NC0004979 A(3) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002A) During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 002A—Coal Yard Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Sample Average Maximum Frequency Type Location - Flow Episodic Estimate Effluent' pH Episodic Grab Effluent Oil and Grease 2 15.0 mg/I 20.0 mg/I Episodic Grab Effluent Total Suspended 30.0 mg/I 100.0 mg/I Episodic Grab Effluent Solids Fecal Coliform Episodic Grab Effluent Total Iron 3 1.0 mg/I Episodic Grab Effluent Footnotes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. Sampling for iron is required only when TSS is reported as greater than 100 mg/L. There shall be no discharge of floating solids or foam. All flows shall be reported on monthly DMRs. If no flow occurs during a given month, the words "no flow" should be clearly written on the front of the DMR. Episodic sampling is required per occurrence when sump overflows occur for longer than one hour. All samples shall be of a representative discharge. 5 • Permit NC0004979 A (4) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002B) During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 002B —Power House Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Average Maximum Frequency Location Flow Episodic .Estimate -Effluent' pH Episodic Grab Effluent Oil and Grease2 15.0 mg/I 20.0 mg/I Episodic Grab Effluent Total Suspended 30.0 mg/I 100.0 mg/I Episodic Grab Effluent Solids Total Copper3 1.0 mg/I Episodic Grab Effluent Totallrop3 1.0mg/I Episodic. Grab Effluent Footnotes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. The limits for total copper and total iron only apply during a chemical metals cleaning. There shall be no discharge of floating solids or foam. All flows shall be reported on monthly DMRs. If no flow occurs during a given month, the words "no flow" should be clearly written on the front of the DMR. Episodic sampling is required per occurrence when sump overflows occur for longer than one hour. All samples shall be of a representative discharge. 6 Permit NC0004979 A(5) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 003) During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 003— miscellaneous equipment non-contact water and sealing water. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Sample Average Maximum Frequency Type Location Flow Weekly Estimate Effluent Chlorination of the once through cooling water, discharged through outfall 003, is not allowed under this permit. If Duke Energy Carolinas, LLC wishes to chlorinate this once through cooling water, a permit modification must be obtained beforehand. • A(6) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 004) During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 004- miscellaneous non-contact cooling water, vehicle washwater, and intake screen backwash. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Average Maximum Frequency Location Flow Weekly Estimate Effluent Oil and Grease 15.0 mg/I 20.0 mg/I Quarterly Grab Effluent Chlorination of the once through cooling water, discharged through outfall 004, is not allowed under this permit. If Duke Energy Carolinas, LLC wishes to chlorinate this once through cooling water, a permit modification must be obtained beforehand. 7 Permit NC0004979 A(7) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS(Internal Outfall 005) • During the period beginning on the effective date of this permit and lasting until permit expiration, the Permittee is authorized to discharge from internal outfall 005-treated FGD wet scrubber wastewater to ash settling basin. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Sample Average _ Maximum Frequency Type Location Pump logs or Flow Monitor& Report Monthly similar Effluent 1 readings Total Suspended Solids Monitor& Report Weekly Grab Effluent Carbonaceous Oxygen Demand Monitor& Report Weekly Grab Effluent (COD) Total Arsenic Monitor& Report Weekly Grab Effluent Total Cadmium Monitor& Report Weekly Grab Effluent Total Chromium Monitor& Report Weekly • Grab Effluent Chloride Monitor & Report Weekly Grab Effluent Total Mercury Monitor& Report Weekly Grab Effluent Total Nickel Monitor& Report Weekly Grab Effluent Total Selenium Monitor& Report Monthly Grab Effluent Total Silver Monitor& Report Weekly Grab Effluent Total Zinc Monitor& Report Weekly Grab Effluent Total Beryllium Monitor& Report Weekly Grab Effluent Footnotes: 1. "Effluent" shall be defined as the discharge from the FGD wastewater treatment system prior to discharge to the ash settling basin. All flows shall be reported on monthly DMRs. If no flow occurs during a given month, the words "no flow" shall be clearly written on the front of the DMR. All samples shall be of a representative discharge. DMRs for this outfall shall be submitted only after discharge commences from the FGD system. Sampling is only required when this outfall is discharging. A(8) SPECIAL CONDITION FOR THE DISCHARGE OF ASIATIC CLAM/DEBRIS FILTER BACKWASH The permittee may backwash the intake filter for Unit 5 condenser cooling water on an as-needed basis. It is understood that this wash water will contain materials indigenous to the Catawba River such as Asiatic clams and light debris. As these are naturally occurring in the river environment, they may be discharged with no adverse affects to the receiving stream. The Permittee may not add any detergent, chemicals or other non-indigenous material to the wash water without explicit permission from the Division of Water Quality. 8 • Permit NC0004979 •A(9) CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT(QUARTERLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 20%. The permit holder shall perform at a minimum, quarterly monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, or subsequent versions, or"North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised-February 1998) or subsequent versions. The tests will be performed during the months of January, April, July and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below - ' the permit limit, then multiple-concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised-February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised- February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1)for the months in which tests were performed. If reporting pass/fail results using the parameter code TGP3B, DWQ Form AT-1 (original) is sent to the below address. If reporting Chronic Value results using the parameter code THP3B, DWQ Form AT-3 (original) is to be sent to the following address: Attention: North Carolina Division of Water Quality Environmental Sciences Section 1621 Mail Service Center Raleigh, North Carolina 27699-1621 • Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Section no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Section at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re- opened and modified to include alternate monitoring requirements or limits.' • Permit NC0004979 If the Permittee monitors any pollutant more frequently than required by this permit, the results of such monitoring shall be included in the calculation & reporting of the data submitted on the DMR & all AT Forms submitted. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. A(10) BIOCIDE CONDITION The permittee shall not use any biocides except those approved in conjunction with the permit application. The permittee shall notify the Director in writing not later than ninety (90) days prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life other than those previously reported to the Division of Water Quality. Such notification shall include completion of Biocide Worksheet Form 101 and a map locating the discharge point and receiving stream. Completion of Biocide Worksheet Form 101 is not necessary for those outfalls containing toxicity testing. Division approval is not necessary for the introduction of a new biocide into an outfall currently being tested for toxicity. A(11) SPECIAL CONDITIONS The following special conditions are applicable to all outfalls regulated by this permit: • There shall be no discharge of polychlorinated biphenyl compounds. • The plans and procedures in place at Allen Steam Station shall be equivalent to that of BMPs (best management practices). • The permittee shall report the presence of cenospheres observed in any samples. • The applicant is permitted to discharge chemical metal cleaning wastes to the ash basin under the conditions outlined in the 1976 Riverbend Ash Basin Equivalency Demonstration and the 1994 Allen Steam Station permit application. • The permittee shall periodically check the diked areas for leaks by a visual inspection and shall report any leakage detected. • If the permittee, after monitoring for at least six months, determines that effluent limits are consistently being met, the permittee may request of the Director that the monitoring requirement be reduced to a lesser frequency. • Nothing contained in this permit shall be construed as a waiver by the permittee of any right to a hearing it may have pursuant to State or Federal laws and regulations. • Low volume waste is defined as follows, as per 40 CFR 423.11(b): "Low volume wastes sources include, but are not limited to: wastewaters from wet scrubber air pollution control systems, ion exchange water treatment system, water treatment evaporator blowdown, laboratory and sampling streams, boiler blowdown, floor drains, cooling tower basin cleaning wastes, and recirculating house service water systems. Sanitary and air conditioning wastes are not included." A(12) SECTION 316 (B) OF THE CLEAN WATER ACT The permittee shall comply with the Cooling Water Intake Structure Rule per 40 CFR 125.95. 10 Permit NC0004979 A(13) GROUNDWATER MONITORING WELL CONSTRUCTION AND SAMPLING The permittee shall conduct groundwater monitoring to determine the compliance of this NPDES permitted facility with the current groundwater standards found under 15A NCAC 2L .0200. The monitoring shall be conducted in accordance with the sampling plan approved by the Division. A(14) STRUCTURAL INTEGRITY INSPECTIONS OF ASH DAMS The facility shall meet the dam design and dam safety requirements per 15A NCAC 2K. A(15) SECTION 316 (A)THERMAL VARIANCE The thermal variance granted under Section 316(a) terminates on expiration of this NPDES permit. Should the permittee wish a continuation of its 316(a) thermal variance beyond the term of this permit, reapplication for such continuation shall be submitted in accordance with 40 CFR Part 125, Subpart H and Section 122.21(1) (6) not later than 180 days prior to permit expiration. Reapplication shall include a basis for continuation such as a) plant operating conditions and load factors are • unchanged and are expected to remain so for the term of the reissued permit; b) there are no changes to plant discharges or other discharges in the plant site area which could interact with the thermal discharges; and c) there are no changes to the biotic community of the receiving water body which would impact the previous variance determination. The next 316(a) studies shall be performed in accordance with the Division of Water Quality approved plan. The temperature analysis and the balanced and indigenous study plan shall conform to the specifications outlined in 40 CFR 125 Subpart H and the EPA's Draft 316(a) Guidance Manual, dated 1977. EPA shall be provided an opportunity to review the plan prior to the commencement of the study. A(16) FISH TISSUE MONITORING NEAR ASH POND DISCHARGE The facility shall conduct fish tissue monitoring once during the permit term and submit the results with the NPDES permit renewal application. The objective of this monitoring is to evaluate potential uptake of pollutants by fish tissue near the ash pond discharge. The parameters analyzed in fish tissue shall be arsenic, selenium, and mercury. The monitoring shall be conducted in accordance with the sampling plan approved by the Division. A(17) MONITORING OF THE RECEIVING WATER The facility shall conduct semiannual in-stream monitoring (one upstream and one downstream of the ash pond discharge) for arsenic, selenium, mercury, chromium, lead, cadmium, copper, zinc, and total dissolved solids (TDS). In-stream monitoring should be conducted at the stations that have already been established through the BIP monitoring program. The monitoring results shall be submitted with the NPDES permit renewal application. A(18) PRIORITY POLLUTANT ANALYSIS The permittee shall conduct a priority pollutant analysis (in accordance with 40 CFR Part 136) once per permit cycle at outfall 002 and submit the results with the application for permit renewal. • 11 • NPDES Permit Standard Conditions Page 1 of 18 PART II STANDARD CONDITIONS FOR NPDES PERMITS Section A. Definitions 2/Month Samples are collected twice per month with at least ten calendar days between sampling events. These samples shall be representative of the wastewater discharged during the sample period. 3/Week Samples are collected three times per week on three separate calendar days.These samples shall be representative of the wastewater discharged during the sample period. Act or"the Act" The Federal Water Pollution Control Act,also known as the Clean Water Act(CWA),as amended,33 USC 1251,et. seq. Annual Average The arithmetic mean of all"daily discharges"of a pollutant measured during the calendar year. In the case of fecal coliform,the geometric mean of such discharges. Arithmetic Mean The summation of the individual values divided by the number of individual values. Bypass The known diversion of waste streams from any portion of a treatment facility including the collection system, which is not a designed or established or operating mode for the facility. Calendar Day The period from midnight of one day until midnight of the next day. However, for purposes of this permit, any consecutive 24-hour period that reasonably represents the calendar day may be used for sampling. Calendar Week The period from Sunday through the following Saturday. Calendar Quarter One of the following distinct periods: January through March, April through June,July through September, and October through December. Composite Sample A sample collected over a 24-hour period by continuous sampling or combining grab samples of at least 100 ml in such a manner as to result in a total sample representative of the wastewater discharge during the sample period. The Director may designate the most appropriate method (specific number and size of aliquots necessary,the time interval between grab samples,etc.) on a case-by-case basis. Samples may be collected manually or automatically. Composite samples may be obtained by the following methods: (1) Continuous:a single,continuous sample collected over a 24-hour period proportional to the rate of flow. (2) Constant time/variable volume: a series of grab samples collected at equal time intervals over a 24 hour period of discharge and combined proportional to the rate of flow measured at the time of individual sample collection,or (3) Variable time/constant volume: a series of grab samples of equal volume collected over a 24 hour period with the time intervals between samples determined by a preset number of gallons passing the sampling point. Flow measurement between sample intervals shall be determined by use of a flow recorder and totalizer, and the preset gallon interval between sample collection fixed at no greater than 1/24 of the expected total daily flow at the treatment system,or (4) Constant time/constant volume: a series of grab samples of equal volume collected over a 24-hour period at a constant time interval. Use of this method requires prior approval by the Director. This method may Version 10/29/2010 NPDES Permit Standard Conditions ' Page 2 of 18 only be used in situations where effluent flow rates vary less than 15 percent. The following restrictions also apply: ➢ Influent and effluent grab samples shall be of equal size and of no less than 100 milliliters > Influent samples shall not be collected more than once per hour. ➢ Permittees with wastewater treatment systems whose detention time<24 hours shall collect effluent grab samples at intervals of no greater than 20 minutes apart during any 24-hour period. ➢ Permittees with wastewater treatment systems whose detention time exceeds 24 hours shall collect effluent grab samples at least every six hours;there must be a minimum of four samples during a 24- hour sampling period. Continuous flow measurement Flow monitoring that occurs without interruption throughout the operating hours of the facility. Flow shall be monitored continually except for the infrequent times when there may be no flow or for infrequent maintenance activities on the flow device. Daily Discharge The discharge of a pollutant measured during a calendar day or any 24-hour period that reasonably represents the calendar day for purposes of sampling. For pollutants measured in units of mass, the "daily discharge" is calculated as the total mass of the pollutant discharged over the day. The "daily discharge" concentration comprises the mean concentration for a 24-hour sampling period as either a composite sample concentration or the arithmetic mean of all grab samples collected during that period. (40 CFR 122.2) Daily Maximum The highest"daily discharge"during the calendar month. Daily Sampling Parameters requiring daily sampling shall be sampled 5 out of every 7 days per week unless otherwise specified in the permit. Sampling shall be conducted on weekdays except where holidays or other disruptions of normal operations prevent weekday sampling. If sampling is required for all seven days of the week for any permit parameter(s),that requirement will be so noted on the Effluent Limitations and Monitoring Page(s). DWQ or"the Division" The Division of Water Quality,Department of Environment and Natural Resources. EMC The North Carolina Environmental Management Commission EPA The United States Environmental Protection Agency Facility Closure Cessation of all activities that require coverage under this NPDES permit.Completion of facility closure will allow this permit to be rescinded. Geometric Mean The Nth root of the product of the individual values where N= the number of individual values. For purposes of calculating the geometric mean,values of"0" (or"< [detection level]")shall be considered=1. Grab Sample Individual samples of at least 100 ml collected over a period of time not exceeding 15 minutes.Grab samples can be collected manually. Grab samples must be representative of the discharge (or the receiving stream, for instream samples). Hazardous Substance Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the CWA. Instantaneous flow measurement A measure of flow taken at the time of sampling,when both the sample and flow will be representative of the total discharge. Version 10/29/2010 NPDES Permit Standard Conditions Page 3 of 18 • • Monthly Average(concentration limit) The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar month. In the case of fecal coliform,the geometric mean of such discharges. Permit Issuing Authority The Director of the Division of Water Quality. Quarterly Average(concentration limit) The average of all samples taken over a calendar quarter. Severe property damage Substantial physical damage to property, damage to the treatment facilities which causes them to become inoperable, or substantial and permanent loss of natural resources which can reasonably be expected to occur in the absence of a bypass.Severe property damage excludes economic loss caused by delays in production. Toxic Pollutant: Any pollutant listed as toxic under Section 307(a)(1)of the CWA. Upset An incident beyond the reasonable control of the Permittee causing unintentional and temporary noncompliance with permit effluent limitations and/or monitoring requirements. An upset does not include noncompliance caused by operational error, improperly designed treatment facilities, inadequate treatment facilities, lack of preventive maintenance,or careless or improper operation. Weekly Average(concentration limit) The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar week. In the case of fecal coliform,the geometric mean of such discharges. Section B. General Conditions 1. Duty to Comply The Permittee must comply with all conditions of this permit. Any permit noncompliance constitutes a violation of the CWA and is grounds for enforcement action; for permit termination, revocation and reissuance,or modification;or denial of a permit renewal application[40 CFR 122.41]. a. The Permittee shall comply with effluent standards or prohibitions established under section 307(a)of the CWA for toxic pollutants and with standards for sewage sludge use or disposal established under section 405(d) of the CWA within the time provided in the regulations that establish these standards or prohibitions or standards for sewage sludge use or disposal,even if the permit has not yet been modified to incorporate the requirement. b. The CWA provides that any person who violates section[s] 301,302,306,307,308,318 or 405 of the Act,or any permit condition or limitation implementing any such sections in a permit issued under section 402, or any requirement imposed in a pretreatment program approved under sections 402 (a) (3) or 402 (b) (8) of the Act, is subject to a civil penalty not to exceed $37,500 per day for each violation. [33 USC 1319 (d) and 40 CFR 122.41 (a) (2)] c. The CWA provides that any person who negligently violates sections 301,302,306,307,308,318,or 405 of the Act,or any condition or limitation implementing any of such sections in a permit issued under section 402 of the Act, or any requirement imposed in a pretreatment program approved under section 402(a)(3) or 402(b)(8) of the Act, is subject to criminal penalties of $2,500 to $25,000 per day of violation, or imprisonment of not more than 1 year, or both. In the case of a second or subsequent conviction for a negligent violation, a person shall be subject to criminal penalties of not more than $50,000 per day of violation,or by imprisonment of not more than 2 years,or both. [33 USC 1319(c) (1)and 40 CFR 122.41 (a) (2)] d. Any person who knowingly violates such sections,or such conditions or limitations is subject to criminal penalties of$5,000 to$50,000 per day of violation,or imprisonment for not more than 3 years, or both. In the case of a second or subsequent conviction for a knowing violation,a person shall be subject to criminal Version 10/29/2010 NPDES Permit Standard Conditions . Page 4 of 18 penalties of not more than $100,000 per day of violation, or imprisonment of not more than 6 years, or both. [33 USC 1319(c) (2)and 40 CFR 122.41 (a)(2)] e. Any person who knowingly violates section 301,302,303,306,307,308,318 or 405 of the Act,or any permit condition or limitation implementing any of such sections in a permit issued under section 402 of the Act, and who knows at that time that he thereby places another person in imminent danger of death or serious bodily injury,shall,upon conviction,be subject to a fine of not more than$250,000 or imprisonment of not more than 15 years,or both. In the case of a second or subsequent conviction for a knowing endangerment violation, a person shall be subject to a fine of not more than $500,000 or by imprisonment of not more than 30 years, or both. An organization, as defined in section 309(c)(3)(B)(iii) of the CWA, shall, upon conviction of violating the imminent danger provision,be subject to a fine of not more than$1,000,000 and can be fined up to$2,000,000 for second or subsequent convictions. [40 CFR 122.41 (a)(2)] f. Under state law,a civil penalty of not more than$25,000 per violation may be assessed against any person who violates or fails to act in accordance with the terms, conditions, or requirements of a permit. [North Carolina General Statutes§143-215.6A] g. Any person may be assessed an administrative penalty by the Administrator for violating section 301,302, 306, 307, 308, 318 or 405 of this Act, or any permit condition or limitation implementing any of such sections in a permit issued under section 402 of this Act.Administrative penalties for Class I violations are not to exceed $16,000 per violation, with the maximum amount of any Class I penalty assessed not to exceed $37,500. Penalties for Class II violations are not to exceed $16,000 per day for each day during which the violation continues, with the maximum amount of any Class II penalty not to exceed $177,500. [33 USC 1319 (g) (2)and 40 CFR 122.41 (a) (3)] 2. Duty to Mitigate The Permittee shall take all reasonable steps to minimize or prevent any discharge or sludge use or disposal in violation of this permit with a reasonable likelihood of adversely affecting human health or the environment [40 CFR 122.41 (d)]. 3. Civil and Criminal Liability Except as provided in permit conditions on "Bypassing" (Part II. C. 4), "Upsets" (Part II. C. 5) and "Power Failures" (Part II. C. 7), nothing in this permit shall be construed to relieve the Permittee from any responsibilities, liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3, 143-215.6 or Section 309 of the Federal Act,33 USC 1319. Furthermore,the Permittee is responsible for consequential damages,such as fish kills,even though the responsibility for effective compliance may be temporarily suspended. 4. Oil and Hazardous Substance Liability Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the Permittee from any responsibilities, liabilities, or penalties to which the Permittee is or may be subject to under NCGS 143-215.75 et seq. or Section 311 of the Federal Act, 33 USG 1321. Furthermore, the Permittee is responsible for consequential damages, such as fish kills, even though the responsibility for effective compliance may be temporarily suspended. 5. Property Rights The issuance of this permit does not convey any property rights in either real or personal property, or any exclusive privileges,nor does it authorize any injury to private property or any invasion of personal rights,nor any infringement of Federal,State or local laws or regulations[40 CFR 122.41 (g)]. 6. Onshore or Offshore Construction This permit does not authorize or approve the construction of any onshore or offshore physical structures or facilities or the undertaking of any work in any navigable waters. 7. Severability The provisions of this permit are severable. If any provision of this permit,or the application of any provision of this permit to any circumstances, is held invalid, the application of such provision to other circumstances, and the remainder of this permit,shall not be affected thereby[NCGS 150B-23]. Version 10/29/2010 NPDES Permit Standard Conditions • Page 5 of 18 • 8. Duty to Provide Information The Permittee shall furnish to the Permit Issuing Authority,within a reasonable time, any information which the Permit Issuing Authority may request to determine whether cause exists for modifying, revoking and reissuing, or terminating this permit or to determine compliance with this permit. The Permittee shall also furnish to the Permit Issuing Authority upon request,copies of records required by this permit [40 CFR 122.41 (h)]. 9. Duty to Reapply If the Permittee wishes to continue an activity regulated by this permit after the expiration date of this permit, the Permittee must apply for and obtain a new permit[40 CFR 122.41 (b)]. 10. Expiration of Permit The Permittee is not authorized to discharge after the expiration date. In order to receive automatic authorization to discharge beyond the expiration date,the Permittee shall submit such information,forms,and fees as are required by the agency authorized to issue permits no later than 180 days prior to the expiration date. Any Permittee that has not requested renewal at least 180 days prior to expiration, or any Permittee that does not have a permit after the expiration and has not requested renewal at least 180 days prior to expiration, will subject the Permittee to enforcement procedures as provided in NCGS 143-215.6 and 33 USC 1251 et.seq. 11. Signatory Requirements All applications, reports, or information submitted to the Permit Issuing Authority shall be signed and certified [40 CFR 122.41 (k)]. a. All permit applications shall be signed as follows: (1) For a corporation: by a responsible corporate officer. For the purpose of this Section, a responsible corporate officer means: (a) a president, secretary, treasurer or vice president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the corporation, or (b) the manager of one or more manufacturing, production, or operating facilities, provided, the manager is authorized to make management decisions which govern the operation of the regulated facility including having the explicit or implicit duty of making major capital investment recommendations, and initiating and directing other comprehensive measures to assure long term environmental compliance with environmental laws and regulations; the manager can ensure that the necessary systems are established or actions taken to gather complete and accurate information for permit application requirements;and where authority to sign documents has been assigned or delegated to the manager in accordance with corporate procedures. (2) For a partnership or sole proprietorship: by a general partner or the proprietor,respectively;or (3) For a municipality, State, Federal, or other public agency: by either a principal executive officer or ranking elected official[40 CFR 122.22]. b. All reports required by the permit and other information requested by the Permit Issuing Authority shall be signed by a person described in paragraph a. above or by a duly authorized representative of that person.A person is a duly authorized representative only if: (1) The authorization is made in writing by a person described above; (2) The authorization specified either an individual or a position having responsibility for the overall operation of the regulated facility or activity,such as the position of plant manager,operator of a well or well field, superintendent, a position of equivalent responsibility, or an individual or position having overall responsibility for environmental matters for the company. (A duly authorized representative may thus be either a named individual or any individual occupying a named position.); and (3) The written authorization is submitted to the Permit Issuing Authority[40 CFR 122.22] c. Changes to authorization: If an authorization under paragraph (b) of this section is no longer accurate because a different individual or position has responsibility for the overall operation of the facility,a new authorization satisfying the requirements of paragraph (b) of this section must be submitted to the Director prior to or together with any reports, information, or applications to be signed by an authorized representative[40 CFR 122.22] Version 10/29/2010 NPDES Permit Standard Conditions Page 6 of 18 d. Certification. Any person signing a document under paragraphs a. or b. of this section shall make the following certification [40 CFR 122.22]. NO OTHER STATEMENTS OF CERTIFICATION WILL BE ACCEPTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 12. Permit Actions This permit may be modified, revoked and reissued, or terminated for cause. The filing of a request by the Permittee for a permit modification, revocation and reissuance, or termination, or a notification of planned changes or anticipated noncompliance does not stay any permit condition[40 CFR 122.41 (f)]. 13. Permit Modification,Revocation and Reissuance,or Termination The issuance of this permit does not prohibit the permit issuing authority from reopening and modifying the permit, revoking and reissuing the permit, or terminating the permit as allowed by the laws, rules, and regulations contained in Title 40, Code of Federal Regulations, Parts 122 and 123; Title 15A of the North Carolina Administrative Code,Subchapter 2H.0100;and North Carolina General Statute 143-215.1 et.al. 14. Annual Administering and Compliance Monitoring Fee Requirements The Permittee must pay the annual administering and compliance monitoring fee within thirty days after being billed by the Division. Failure to pay the fee in a timely manner in accordance with 15A NCAC 2H.0105 (b) (2)may cause this Division to initiate action to revoke the permit. Section C. Operation and Maintenance of Pollution Controls 1. Certified Operator Upon classification of the permitted facility by the Certification Commission, the Permittee shall employ a certified water pollution control treatment system operator in responsible charge(ORC) of the water pollution control treatment system.Such operator must hold a certification of the grade equivalent to or greater than the classification assigned to the water pollution control treatment system by the Certification Commission. The Permittee must also employ one or more certified Back-up ORCs who possess a currently valid certificate of the type of the system. Back-up ORCs must possess a grade equal to(or no more than one grade less than) the grade of the system[15A NCAC 8G.02011. The ORC of each Class I facility must: > Visit the facility as often as is necessary to insure proper operation of the treatment system;the treatment facility must be visited at least weekly > Comply with all other conditions of 15A NCAC 8G.0204. The ORC of each Class II,III and IV facility must: > Visit the facility as often as is necessary to insure proper operation of the treatment system;the treatment facility must be visited at least five days per week,excluding holidays > Properly manage and document daily operation and maintenance of the facility > Comply with all other conditions of 15A NCAC 8G.0204. Once the facility is classified, the Permittee shall submit a letter to the Certification Commission designating the operator in responsible charge: a. Within 60 calendar days prior to wastewater being introduced into a new system b. Within 120 calendar days of: > Receiving notification of a change in the classification of the system requiring the designation of a new ORC and back-up ORC > A vacancy in the position of ORC or back-up ORC. Version 10/29/2010 NPDES Permit Standard Conditions • Page 7 of 18 2. Proper Operation and Maintenance The Permittee shall at all times provide the operation and maintenance resources necessary to operate the existing facilities at optimum efficiency. The Permittee shall at all times properly operate and maintain all facilities and systems of treatment and control (and related appurtenances) which are installed or used by the Permittee to achieve compliance with the conditions of this permit. Proper operation and maintenance also includes adequate laboratory controls and appropriate quality assurance procedures. This provision requires the Permittee to install and operate backup or auxiliary facilities only when necessary to achieve compliance with the conditions of the permit[40 CFR 122.41 (e)]. NOTE: Properly and officially designated operators are fully responsible for all proper operation and maintenance of the facility, and all documentation required thereof, whether acting as a contract operator [subcontractor] or a member of the Permittee's staff. 3. Need to Halt or Reduce not a Defense It shall not be a defense for a Permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the condition of this permit [40 CFR 122.41 (c)]. 4. Bypassing of Treatment Facilities a. Bypass not exceeding limitations [40 CFR 122.41 (m) (2)] The Permittee may allow any bypass to occur which does not cause effluent limitations to be exceeded, but only if it also is for essential maintenance to assure efficient operation. These bypasses are not subject to the provisions of Paragraphs b.and c.of this section. b. Notice [40 CFR 122.41 (m)(3)] (1) Anticipated bypass. If the Permittee knows in advance of the need for a bypass, it shall submit prior notice, if possible at least ten days before the date of the bypass; including an evaluation of the anticipated quality and effect of the bypass. (2) Unanticipated bypass. The Permittee shall submit notice of an unanticipated bypass as required in Part II.E.6. (24-hour notice). c. Prohibition of Bypass (1) Bypass from the treatment facility is prohibited and the Permit Issuing Authority may take enforcement action against a Permittee for bypass,unless: (A) Bypass was unavoidable to prevent loss of life,personal injury or severe property damage; (B) There were no feasible alternatives to the bypass, such as the use of auxiliary treatment facilities, retention of untreated wastes or maintenance during normal periods of equipment downtime. This condition is not satisfied if adequate backup equipment should have been installed in the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal periods of equipment downtime or preventive maintenance;and (C) The Permittee submitted notices as required under Paragraph b.of this section. (2) Bypass from the collection system is prohibited and the Permit Issuing Authority may take enforcement action against a Permittee for a bypass as provided in any current or future system-wide collection system permit associated with the treatment facility. (3) The Permit Issuing Authority may approve an anticipated bypass,after considering its adverse effects, if the Permit Issuing Authority determines that it will meet the three conditions listed above in Paragraph c. (1)of this section. 5. Upsets a. Effect of an upset[40 CFR 122.41 (n)(2)]:An upset constitutes an affirmative defense to an action brought for noncompliance with such technology based permit effluent limitations if the requirements of paragraph b. of this condition are met. No determination made during administrative review of claims that noncompliance was caused by upset, and before an action for noncompliance,is final administrative action subject to judicial review. Version 10/29/2010 NPDES Permit Standard Conditions Page8of18 b. Conditions necessary for a demonstration of upset: Any Permittee who wishes to establish the affirmative defense of upset shall demonstrate,through properly signed,contemporaneous operating logs, or other relevant evidence that: (1)An upset occurred and that the Permittee can identify the cause(s)of the upset; (2)The Permittee facility was at the time being properly operated;and (3)The Permittee submitted notice of the upset as required in Part II. E.6. (b)of this permit. (4)The Permittee complied with any remedial measures required under Part II. B.2.of this permit. c. Burden of proof[40 CFR 122.41 (n) (4)]: The Permittee seeking to establish the occurrence of an upset has the burden of proof in any enforcement proceeding. 6. Removed Substances Solids, sludges, filter backwash, or other pollutants removed in the course of treatment or control of wastewaters shall be utilized/disposed of in accordance with NCGS 143-215.1 and in a manner such as to prevent any pollutant from such materials from entering waters of the State or navigable waters of the United States. The Permittee shall comply with all existing Federal regulations governing the disposal of sewage sludge. Upon promulgation of 40 CFR Part 503, any permit issued by the Permit Issuing Authority for the utilization/disposal of sludge may be reopened and modified, or revoked and reissued, to incorporate applicable requirements at 40 CFR 503. The Permittee shall comply with applicable 40 CFR 503 Standards for the Use and Disposal of Sewage Sludge (when promulgated) within the time provided in the regulation,even if the permit is not modified to incorporate the requirement. The Permittee shall notify the Permit Issuing Authority of any significant change in its sludge use or disposal practices. 7. Power Failures The Permittee is responsible for maintaining adequate safeguards (as required by 15A NCAC 2H.0124) to prevent the discharge of untreated or inadequately treated wastes during electrical power failures either by means of alternate power sources,standby generators or retention of inadequately treated effluent. Section D. Monitoring and Records 1. Representative Sampling Samples collected and measurements taken, as required herein, shall be characteristic of the volume and nature of the permitted discharge. Samples collected at a frequency less than daily shall be taken on a day and time that is characteristic of the discharge over the entire period the sample represents. All samples shall be taken at the monitoring points specified in this permit and,unless otherwise specified,before the effluent joins or is diluted by any other wastestream, body of water, or substance. Monitoring points shall not be changed without notification to and the approval of the Permit Issuing Authority[40 CFR 122.41 (j)]. 2. Reporting Monitoring results obtained during the previous month(s) shall be summarized for each month and reported on a monthly Discharge Monitoring Report (DMR) Form (MR 1, 1.1,2, 3) or alternative forms approved by the Director, postmarked no later than the last calendar day of the month following the completed reporting period. The first DMR is due on the last day of the month following the issuance of the permit or in the case of a new facility, on the last day of the month following the commencement of discharge. Duplicate signed copies of these,and all other reports required herein,shall be submitted to the following address: NC DENR/ Division of Water Quality / Surface Water Protection Section ATTENTION:Central Files 1617 Mail Service Center Raleigh,North Carolina 27699-1617 3. Flow Measurements Appropriate flow measurement devices and methods consistent with accepted scientific practices shall be selected and used to ensure the accuracy and reliability of measurements of the volume of monitored discharges. The devices shall be installed, calibrated and maintained to ensure that the accuracy of the Version 10/29/2010 • • NPDES Permit Standard Conditions • Page 9 of 18 measurements is consistent with the accepted capability of that type of device. Devices selected shall be capable of measuring flows with a maximum deviation of less than 10% from the true discharge rates throughout the range of expected discharge volumes. Flow measurement devices shall be accurately calibrated at a minimum of once per year and maintained to ensure that the accuracy of the measurements is consistent with the accepted capability of that type of device. The Director shall approve the flow measurement device and monitoring location prior to installation. Once-through condenser cooling water flow monitored by pump logs, or pump hour meters as specified in Part I of this permit and based on the manufacturer's pump curves shall not be subject to this requirement. 4. Test Procedures Laboratories used for sample analysis must be certified by the Division. Permittees should contact the Division's Laboratory Certification Section (919 733-3908 or http://portal.ncdenr.org/web/wq/lab/cert) for information regarding laboratory certifications. Facilities whose personnel are conducting testing of field-certified parameters only must hold the appropriate field parameter laboratory certifications. Test procedures for the analysis of pollutants shall conform to the EMC regulations (published pursuant to NCGS 143-215.63 et. seq.),the Water and Air Quality Reporting Acts,and to regulations published pursuant to Section 304(g), 33 USC 1314, of the CWA (as amended), and 40 CFR 136; or in the case of sludge use or disposal, approved under 40 CFR 136, unless otherwise specified in 40 CFR 503, unless other test procedures have been specified in this permit[40 CFR 122.411. To meet the intent of the monitoring required by this permit, all test procedures must produce minimum detection and reporting levels that are below the permit discharge requirements and all data generated must be reported down to the minimum detection or lower reporting level of the procedure. If no approved methods are determined capable of achieving minimum detection and reporting levels below permit discharge requirements, then the most sensitive (method with the lowest possible detection and reporting level) approved method must be used. 5. Penalties for Tampering The CWA provides that any person who falsifies, tampers with, or knowingly renders inaccurate, any monitoring device or method required to be maintained under this permit shall,upon conviction,be punished by a fine of not more than$10,000 per violation,or by imprisonment for not more than two years per violation, or by both.If a conviction of a person is for a violation committed after a first conviction of such person under this paragraph,punishment is a fine of not more than$20,000 per day of violation,or by imprisonment of not more than 4 years,or both[40 CFR 122.41]. 6. Records Retention Except for records of monitoring information required by this permit related to the Permittee's sewage sludge use and disposal activities, which shall be retained for a period of at least five years (or longer as required by 40 CFR 503),the Permittee shall retain records of all monitoring information,including: ➢ all calibration and maintenance records > all original strip chart recordings for continuous monitoring instrumentation > copies of all reports required by this permit > copies of all data used to complete the application for this permit These records or copies shall be maintained for a period of at least 3 years from the date of the sample, measurement, report or application. This period may be extended by request of the Director at any time [40 CFR 122.41]. 7. Recording Results For each measurement or sample taken pursuant to the requirements of this permit,the Permittee shall record the following information[40 CFR 122.41]: a. The date,exact place,and time of sampling or measurements; b. The individual(s)who performed the sampling or measurements; Version 10/29/2010 NPDES Permit Standard Condifons Page l0 of 18 c. The date(s)analyses were performed; d. The individual(s)who performed the analyses; e. The analytical techniques or methods used;and f. The results of such analyses. 8. Inspection and Entry The Permittee shall allow the Director, or an authorized representative (including an authorized contractor acting as a representative of the Director),upon the presentation of credentials and other documents as may be required by law,to; a. Enter upon the Permittee's premises where a regulated facility or activity is located or conducted, or where records must be kept under the conditions of this permit; b. Have access to and copy, at reasonable times, any records that must be kept under the conditions of this permit; c. Inspect at reasonable times any facilities, equipment (including monitoring and control equipment), practices,or operations regulated or required under this permit;and d. Sample or monitor at reasonable times, for the purposes of assuring permit compliance or as otherwise authorized by the CWA,any substances or parameters at any location[40 CFR 122.41 (i)]. Section E Reporting Requirements 1. Change in Discharge All discharges authorized herein shall be consistent with the terms and conditions of this permit. The discharge of any pollutant identified in this permit more frequently than or at a level in excess of that authorized shall constitute a violation of the permit. 2. Planned Changes The Permittee shall give notice to the Director as soon as possible of any planned physical alterations or additions to the permitted facility[40 CFR 122.41 (1)].Notice is required only when: a. The alteration or addition to a permitted facility may meet one of the criteria for new sources at 40 CFR 122.29(b);or b. The alteration or addition could significantly change the nature or increase the quantity of pollutants discharged. This notification applies to pollutants subject neither to effluent limitations in the permit,nor to notification requirements under 40 CFR 122.42(a) (1). c. The alteration or addition results in a significant change in the Permittee's sludge use or disposal practices,and such alteration,addition or change may justify the application of permit conditions that are different from or absent in the existing permit,including notification of additional use or disposal sites not reported during the permit application process or not reported pursuant to an approved land application plan. 3. Anticipated Noncompliance The Permittee shall give advance notice to the Director of any planned changes to the permitted facility or other activities that might result in noncompliance with the permit[40 CFR 122.41 (1) (2)]. 4. Transfers This permit is not transferable to any person without approval from the Director. The Director may require modification or revocation and reissuance of the permit to document the change of ownership. Any such action may incorporate other requirements as may be necessary under the CWA[40 CFR 122.41 (1)(3)]. 5. Monitoring Reports Monitoring results shall be reported at the intervals specified elsewhere in this permit[40 CFR 122.41 (1) (4)]. a. Monitoring results must be reported on a Discharge Monitoring Report (DMR) (See Part II. D. 2) or forms provided by the Director for reporting results of monitoring of sludge use or disposal practices. Version 10/29/2010 . NPDES Permit Standard Conditions Page 11 of 18 • b. If the Permittee monitors any pollutant more frequently than required by this permit, the results of such monitoring shall be included in the calculation and reporting of the data submitted on the DMR. 6. Twenty-four Hour Reporting a. The Permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment.Any information shall be provided orally within 24 hours from the time the Permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the Permittee becomes aware of the circumstances. The written submission shall contain a description of the noncompliance,and its cause; the period of noncompliance, including exact dates and times,and if the noncompliance has not been corrected,the anticipated time it is expected to continue; and steps taken or planned to reduce, eliminate, and prevent reoccurrence of the noncompliance [40 CFR 122.41 (1) (6)]. b. The Director may waive the written report on a case-by-case basis for reports under this section if the oral report has been received within 24 hours. c. Occurrences outside normal business hours may also be reported to the Division's Emergency Response personnel at(800)662-7956,(800)858-0368 or(919)733-3300. 7. Other Noncompliance The Permittee shall report all instances of noncompliance not reported under Part II. E. 5 and 6. of this permit at the time monitoring reports are submitted.The reports shall contain the information listed in Part II. E. 6. of this permit[40 CFR 122.41 (1)(7)]. 8. Other Information Where the Permittee becomes aware that it failed to submit any relevant facts in a permit application, or submitted incorrect information in a permit application or in any report to the Director, it shall promptly submit such facts or information[40 CFR 122.41 (1)(8)]. 9. Noncompliance Notification The Permittee shall report by telephone to either the central office or the appropriate regional office of the Division as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: a. Any occurrence at the water pollution control facility which results in the discharge of significant amounts of wastes which are abnormal in quantity or characteristic, such as the dumping of the contents of a sludge digester; the known passage of a slug of hazardous substance through the facility; or any other unusual circumstances. b. Any process unit failure,due to known or unknown reasons,that render the facility incapable of adequate wastewater treatment such as mechanical or electrical failures of pumps,aerators,compressors,etc. c. Any failure of a pumping station,sewer line,or treatment facility resulting in a by-pass without treatment of all or any portion of the influent to such station or facility. Persons reporting such occurrences by telephone shall also file a written report within 5 days following first knowledge of the occurrence. 10. Availability of Reports Except for data determined to be confidential under NCGS 143-215.3 (a)(2)or Section 308 of the Federal Act,33 USC 1318, all reports prepared in accordance with the terms shall be available for public inspection at the offices of the Division. As required by the Act, effluent data shall not be considered confidential. Knowingly making any false statement on any such report may result in the imposition of criminal penalties as provided for in NCGS 143-215.1(b)(2)or in Section 309 of the Federal Act. 11. Penalties for Falsification of Reports The CWA provides that any person who knowingly makes any false statement,representation,or certification in any record or other document submitted or required to be maintained under this permit, including monitoring reports or reports of compliance or noncompliance shall,upon conviction,be punished by a fine of not more than$25,000 per violation,or by imprisonment for not more than two years per violation,or by both [40 CFR 122.41]. Version 10/29/2010 NPDES Permit Standard Conditions" Page 12 of 18 12. Annual Performance Reports Permittees who own or operate facilities that collect or treat municipal or domestic waste shall provide an annual report to the Permit Issuing Authority and to the users/customers served by the Permittee(NCGS 143- 215.1C). The report shall summarize the performance of the collection or treatment system, as well as the extent to which the facility was compliant with applicable Federal or State laws, regulations and rules pertaining to water quality. The report shall be provided no later than sixty days after the end of the calendar or fiscal year,depending upon which annual period is used for evaluation. The report shall be sent to: NC DENR/ Division of Water Quality / Surface Water Protection Section ATTENTION:Central Files 1617 Mail Service Center Raleigh,North Carolina 27699-1617 • Version 10/29/2010 • • NPDES Permit Standard Conditions Page 13 of 18 PART III OTHER REQUIREMENTS Section A. Construction The Permittee shall not commence construction of wastewater treatment facilities,nor add to the plant's treatment capacity, nor change the treatment process(es) utilized at the treatment plant unless the Division has issued an Authorization to Construct (AtC)permit. Issuance of an AtC will not occur until Final Plans and Specifications for the proposed construction have been submitted by the Permittee and approved by the Division. Section B. Groundwater Monitoring The Permittee shall, upon written notice from the Director,conduct groundwater monitoring as may be required to determine the compliance of this NPDES permitted facility with the current groundwater standards. Section C. Changes in Discharges of Toxic Substances The Permittee shall notify the Permit Issuing Authority as soon as it knows or has reason to believe (40 CFR 122.42): a. That any activity has occurred or will occur which would result in the discharge, on a routine or frequent basis, of any toxic pollutant which is not limited in the permit, if that discharge will exceed the highest of the following "notification levels"; (1) One hundred micrograms per liter(100 pg/L); (2) Two hundred micrograms per liter(200 pg/L)for acrolein and acrylonitrile;five hundred micrograms per liter (500 pg/L) for 2.4-dinitrophenol and for 2-methyl-4.6-dinitrophenol; and one milligram per liter (1 mg/L)for antimony; (3) Five times the maximum concentration value reported for that pollutant in the permit application. b. That any activity has occurred or will occur which would result in any discharge, on a non-routine or infrequent basis,of a toxic pollutant which is not limited in the permit,if that discharge will exceed the highest of the following"notification levels"; (1) Five hundred micrograms per liter(500 pg/L); (2) One milligram per liter(1 mg/L)for antimony; (3) Ten times the maximum concentration value reported for that pollutant in the permit application. Section D. Evaluation of Wastewater Discharge Alternatives The Permittee shall evaluate all wastewater disposal alternatives and pursue the most environmentally sound alternative of the reasonably cost effective alternatives. If the facility is in substantial non-compliance with the terms and conditions of the NPDES permit or governing rules, regulations or laws, the Permittee shall submit a report in such form and detail as required by the Division evaluating these alternatives and a plan of action within 60 days of notification by the Division. Section E. Facility Closure Requirements The Permittee must notify the Division at least 90 days prior to the closure of any wastewater treatment system covered by this permit. The Division may require specific measures during deactivation of the system to prevent adverse impacts to waters of the State. This permit cannot be rescinded while any activities requiring this permit continue at the permitted facility. Version 10/29/2010 NPDES Permit Standard Conditions} • Page14of18 PART IV SPECIAL CONDITIONS FOR MUNICIPAL FACILITIES Section A. Definitions In addition to the definitions in Part II of this permit,the following definitions apply to municipal facilities: Indirect Discharge or Industrial User Any non-domestic source that discharges wastewater containing pollutants into a POTW regulated under section 307(b),(c)or(d)of the CWA. [40 CFR 403.3(i)and(j)] Interference Inhibition or disruption of the POTW treatment processes;operations;or its sludge process,use,or disposal which causes or contributes to a violation of any requirement of the POTW's NPDES Permit or prevents sewage sludge use or disposal in compliance with specified applicable State and Federal statutes, regulations, or permits. [15A NCAC 2H.0903(b) (13)] Pass Through A discharge which exits the POTW into waters of the State in quantities or concentrations which, alone or with discharges from other sources, causes a violation, including an increase in the magnitude or duration of a violation,of the POTW's NPDES permit,or of an instream water quality standard. [15A NCAC 2H.0903(b)(23)] Publicly Owned Treatment Works(POTW) A treatment works as defined by Section 212 of the CWA, owned by a State or local government entity. This definition includes any devices and systems used in the storage,treatment,recycling and reclamation of municipal sewage or industrial wastes of a liquid nature. It also includes sewers, pipes, and other conveyances only if they convey wastewater to a POTW. The term also means the local government entity, or municipality, as defined in section 502(4) of the CWA, which has jurisdiction over indirect discharges to and the discharges from such a treatment works. [15A NCAC 2H.0903(b)(27)] "Significant Industrial User"or"SIU" An industrial user that discharges wastewater into a publicly owned treatment works and that [15A NCAC 2H.0903(b) (34)]: (a) discharges an average of 25,000 gallons or more per day of process wastewater to the POTW (excluding sanitary,noncontact cooling and boiler blowdown wastewaters)or; (b) contributes more than 5 percent of the design flow of the POTW treatment plant or more than 5 percent of the maximum allowable headworks loading of the POTW treatment plant for any pollutant of concern,or; (c) is required to meet a national categorical pretreatment standard,or; (d) is, regardless of Parts (a), (b), and (c) of this definition, otherwise determined by the POTW, the Division, or the EPA to have a reasonable potential for adversely affecting the POTW's operation or for violating any pretreatment standard or requirement or POTW's receiving stream standard, or to limit the POTW's sludge disposal options. Section B. Publicly Owned Treatment Works(POTWs) All POTWs are required to prevent the introduction of pollutants into the POTW which will interfere with the operation of the POTW, including interference with its use or disposal of municipal sludge, or pass through the treatment works or otherwise be incompatible with such treatment works. [40 CFR 403.2] All POTWs must provide adequate notice to the Director of the following[40 CFR 122.42(b)]: 1. Any new introduction of pollutants into the POTW from an indirect discharger, regardless of the means of transport, which would be subject to section 301 or 306 of CWA if it were directly discharging those pollutants;and 2. Any substantial change in the volume or character of pollutants being introduced by an indirect discharger as influent to that POTW at the time of issuance of the permit. Version 10/29/2010 • NPDES Permit Standard Conditions • Page 15 of 18 3. For purposes of this paragraph, adequate notice shall include information on (1) the quality and quantity of effluent introduced into the POTW, and (2) any anticipated impact that may result from the change of the quantity or quality of effluent to be discharged from the POTW. Section C. Municipal Control of Pollutants from Industrial Users. 1. Effluent limitations are listed in Part I of this permit. Other pollutants attributable to inputs from industries using the municipal system may be present in the Permittee's discharge.At such time as sufficient information becomes available to establish limitations for such pollutants, this permit may be revised to specify effluent limitations for any or all of such other pollutants in accordance with best practicable technology or water quality standards. 2. Prohibited Discharges a. Under no circumstances shall the Permittee allow introduction of pollutants or discharges into the waste treatment system or waste collection system which cause or contribute to Pass Through or Interference as defined in 15A NCAC 2H.0900 and 40 CFR 403. [40 CFR 403.5(a) (1)] b. Under no circumstances shall the Permittee allow introduction of the following wastes in the waste treatment or waste collection system[40 CFR 403.5(b)]: (1) Pollutants which create a fire or explosion hazard in the POTW, including, but not limited to, wastestreams with a closed cup flashpoint of less than 140 degrees Fahrenheit or 60 degrees Centigrade using the test methods specified in 40 CFR 261.21; (2) Pollutants which cause corrosive structural damage to the POTW,but in no case discharges with pH lower than 5.0,unless the works is specifically designed to accommodate such discharges; (3) Solid or viscous pollutants in amounts which cause obstruction to the flow in the POTW resulting in Interference; (4) Any pollutant, including oxygen demanding pollutants (BOD, etc.) released in a Discharge at a flow rate and/or pollutant concentration which will cause Interference with the POTW; (5) Heat in amounts which will inhibit biological activity in the POTW resulting in Interference,but in no case heat in such quantities that the temperature at the POTW Treatment Plant exceeds 40°C (104°F) unless the Division,upon request of the POTW,approves alternate temperature limits; (6) Petroleum oil, non-biodegradable cutting oil, or products of mineral oil origin in amounts that will cause Interference or Pass Through; (7) Pollutants which result in the presence of toxic gases,vapors,or fumes within the POTW in a quantity that may cause acute worker health and safety problems; (8) Any trucked or hauled pollutants,except at discharge points designated by the POTW. c. The Permittee shall investigate the source of all discharges into the POTW,including slug loads and other unusual discharges, which have the potential to adversely impact the permittee's Pretreatment Program and/or the operation of the POTW. The Permittee shall report such discharges into the POTW to the Director or the appropriate Regional Office. Any information shall be provided orally within 24 hours from the time the Permittee became aware of the circumstances. A written submission shall also be provided within 5 days of the time the Permittee becomes aware of the circumstances. The written submission shall contain a description of the discharge, the investigation into possible sources; the period of the discharge, including exact dates and times; and if the discharge has not ceased, the anticipated time it is expected to continue; and steps taken or planned to reduce,eliminate,and prevent reoccurrence of the noncompliance, 3. With regard to the effluent requirements listed in Part I of this permit,it may be necessary for the Permittee to supplement the requirements of the Federal Pretreatment Standards (40 CFR, Part 403) to ensure compliance by the Permittee with all applicable effluent limitations. Such actions by the Permittee may be necessary regarding some or all of the industries discharging to the municipal system. 4. The Permittee shall require any Industrial User discharging to the POTW to meet Federal Pretreatment Standards developed under Section 307(b) of the Act as amended (which includes categorical standards and Version 10/29/2010 NPDES Permit Standard Condiarts' Page 16 of 18 specific local limits, best management practices and narrative requirements). Prior to accepting wastewater from any Significant Industrial User, the Permittee shall either develop and submit to the Division a new Pretreatment Program or a modification of an existing Pretreatment Program, for approval as required under section D below as well as 15A NCAC 2H.0907(a)and(b). [40 CFR 122.44(j) (2)] 5. This permit shall be modified, or alternatively, revoked and reissued, to incorporate or modify an approved POTW Pretreatment Program or to include a compliance schedule for the development of a POTW Pretreatment Program as required under Section 402 (b) (8) of the CWA and implementing regulations or by the requirements of the approved State pretreatment program,as appropriate. Section D. Pretreatment Programs Under authority of sections 307 (b) and (c) and 402 (b) (8) of the CWA and implementing regulations 40 CFR 403, North Carolina General Statute 143-215.3 (14) and implementing regulations 15A NCAC 2H.0900, and in accordance with the approved pretreatment program, all provisions and regulations contained and referenced in the Pretreatment Program Submittal are an enforceable part of this permit. [40 CFR 122.44(j) (2)] The Permittee shall operate its approved pretreatment program in accordance with Section 402 (b) (8)of the CWA, 40 CFR 403,15A NCAC 2H.0900,and the legal authorities,policies,procedures,and financial provisions contained in its pretreatment program submission and Division approved modifications thereof. Such operation shall include but is not limited to the implementation of the following conditions and requirements. Terms not defined in Part II or Part IV of this permit are as defined in 15A NCAC 2H.0903 and 40 CFR 403.3. 1. Sewer Use Ordinance(SUO) The Permittee shall maintain adequate legal authority to implement its approved pretreatment program. [15A NCAC 2H.0905 and.0906;40 CFR 403.8(f)(1)and 403.9(b)(1),(2)] 2. Industrial Waste Survey(IWS) The permittee shall implement an IWS consisting of the survey of users of the POTW, as required by 40 CFR 403.8 (f) (2) (i-iii) and 15A NCAC 2H.0905 [also 40 CFR 122.44 (j) (1)], including identification of all industrial users that may have an impact on the POTW and the character and amount of pollutants contributed to the POTW by these industrial users and identification of those industrial users meeting the definition of SIU. The Permittee shall submit a summary of its IWS activities to the Division at least once every five years, and as required by the Division.The IWS submission shall include a summary of any investigations conducted under paragraph C.2.c.of this Part. 3. Monitoring Plan The Permittee shall implement a Division-approved Monitoring Plan for the collection of facility specific data to be used in a wastewater treatment plant Headworks Analysis (HWA) for the development of specific pretreatment local limits. Effluent data from the Plan shall be reported on the DMRs (as required by Part II, Section D,and Section E.5.). [15A NCAC 2H.0906(b)(2)and.0905] 4. Headworks Analysis(HWA)and Local Limits The Permittee shall obtain Division approval of a HWA at least once every five years, and as required by the Division. Within 180 days of the effective date of this permit (or any subsequent permit modification) the Permittee shall submit to the Division a written technical evaluation of the need to revise local limits (i.e., an updated HWA or documentation of why one is not needed) [40 CFR 122.44]. The Permittee shall develop, in accordance with 40 CFR 403.5 (c)and 15A NCAC 2H.0909,specific Local Limits to implement the prohibitions listed in 40 CFR 403.5 (a) and (b) and 15A NCAC 2H.0909. Pursuant to 40 CFR 403.5, local limits are enforceable Pretreatment Standards as defined by 40 CFR 403.3(1). 5. Industrial User Pretreatment Permits(IUP)&Allocation Tables In accordance with NCGS 143-215.1, the Permittee shall issue to all significant industrial users, permits for operation of pretreatment equipment and discharge to the Permittee's treatment works. These permits shall contain limitations, sampling protocols, reporting requirements, appropriate standard and special conditions, and compliance schedules as necessary for the installation of treatment and control technologies to assure that their wastewater discharge will meet all applicable pretreatment standards and requirements. The Permittee shall maintain a current Allocation Table (AT) which summarizes the results of the HWA and the limits from Version 10/29/2010 1 NPDES Permit Standard Conditions Page 17 of 18 all IUPs. Permitted IUP loadings for each parameter cannot exceed the treatment capacity of the POTW as determined by the HWA. [15A NCAC 2H.0909, .0916, and .0917; 40 CFR 403.5, 403.8 (f) (1) (iii); NCGS 143- 215.67(a)] 6. Authorization to Construct(AtC) The Permittee shall ensure that an Authorization to Construct permit (AtC) is issued to all applicable industrial users for the construction or modification of any pretreatment facility. Prior to the issuance of an AtC, the proposed pretreatment facility and treatment process must be evaluated for its capacity to comply with all Industrial User Pretreatment Permit (IUP) limitations. [15A NCAC 2H.0906 (b) (6) and .0905; NCGS 143-215.1 (a) (8)] 7. POTW Inspection&Monitoring of their IUs The Permittee shall conduct inspection, surveillance, and monitoring activities as described in its Division approved pretreatment program in order to determine, independent of information supplied by industrial users, compliance with applicable pretreatment standards. [15A NCAC 2H .0908(d); 40 CFR 403.8(f)(2)(v)] The Permittee must: a. Inspect all Significant Industrial Users(SIUs)at least once per calendar year;and b. Sample all Significant Industrial Users (SIUs) at least twice per calendar year for all permit-limited pollutants,once during the period from January 1 through June 30 and once during the period from July 1 through December 31, except for organic compounds which shall be sampled at least once per calendar year; For the purposes of this paragraph, "organic compounds" means the types of compounds listed in 40 CFR 136.3(a),Tables IC,ID,and IF,as amended. 8. IU Self Monitoring and Reporting The Permittee shall require all industrial users to comply with the applicable monitoring and reporting requirements outlined in the Division-approved pretreatment program, the industry's pretreatment permit, or in 15A NCAC 2H .0908. [15A NCAC 2H .0906(b)(4) and .0905; 40 CFR 403.8(f)(1)(v) and (2)(iii); 40 CFR 122.44(j)(2)and 40 CFR 403.12] 9. Enforcement Response Plan(ERP) The Permittee shall enforce and obtain appropriate remedies for violations of all pretreatment standards promulgated pursuant to section 307(b) and (c) of the Clean Water Act (40 CFR 405 et. seq.), prohibitive discharge standards as set forth in 40 CFR 403.5 and 15A NCAC 2H .0909, and specific local limitations. All remedies, enforcement actions and other, shall be consistent with the Enforcement Response Plan (ERP) approved by the Division. [15A NCAC 2H.0906(b)(7)and .0905; 40 CFR 403.8(0(5)] 10. Pretreatment Annual Reports(PAR) The Permittee shall report to the Division in accordance with 15A NCAC 2H .0908. In lieu of submitting annual reports,Modified Pretreatment Programs developed under 15A NCAC 2H.0904(b)may be required to submit a partial annual report or to meet with Division personnel periodically to discuss enforcement of pretreatment requirements and other pretreatment implementation issues. For all other active pretreatment programs, the Permittee shall submit two copies of a Pretreatment Annual Report (PAR) describing its pretreatment activities over the previous twelve months to the Division at the following address: NC DENR/Division of Water Quality/Surface Water Protection Section Pretreatment,Emergency Response,and Collection Systems(PERCS)Unit • 1617 Mail Service Center Raleigh,North Carolina 27699-1617 These reports shall be submitted according to a schedule established by the Director and shall contain the following: a.) Narrative A brief discussion of reasons for, status of, and actions taken for all Significant Industrial Users (SIUs) in Significant Non-Compliance(SNC); Version 10/29/2010 • NPDES Permit Standard Conditions Page18of18 - b.) Pretreatment Program Summary(PPS) A pretreatment program summary(PPS)on specific forms approved by the Division; c.) Significant Non-Compliance Report(SNCR) The nature of the violations and the actions taken or proposed to correct the violations on specific forms approved by the Division; d.) Industrial Data Summary Forms(IDSF) Monitoring data from samples collected by both the POTW and the Significant Industrial User (SIU) in SNC.These analytical results must be reported on Industrial Data Summary Forms(IDSF)or other specific format approved by the Division; e.) Other Information Copies of the POTW's allocation table, new or modified enforcement compliance schedules, public notice of SIUs in SNC,and any other information,upon request,which in the opinion of the Director is needed to determine compliance with the pretreatment implementation requirements of this permit; 11. Public Notice The Permittee shall publish annually a list of Significant Industrial Users (SIUs) that were in Significant Non- Compliance (SNC) as defined in the Permittee's Division-approved Sewer Use Ordinance with applicable pretreatment requirements and standards during the previous twelve month period. This list shall be published within four months of the applicable twelve-month period. [15A NCAC 2H .0903(b)(35), .0908(b)(5) and .0905 and 40 CFR 403.8(f)(2)(viii)] 12. Record Keeping The Permittee shall retain for a minimum of three years records of monitoring activities and results, along with support information including general records,water quality records,and records of industrial impact on the POTW. [15A NCAC 2H.0908(f); 40 CFR 403.12(o)] 13. Funding and Financial Report The Permittee shall maintain adequate funding and staffing levels to accomplish the objectives of its approved pretreatment program. [15A NCAC 2H.0906(a)and.0905;40 CFR 403.8(f)(3),403.9(b)(3)] 14. Modification to Pretreatment Programs Modifications to the approved pretreatment program including but not limited to local limits modifications, POTW monitoring of their Significant Industrial Users (SIUs), and Monitoring Plan modifications, shall be considered a permit modification and shall be governed by 40 CFR 403.18, 15 NCAC 2H .0114 and 15A NCAC 2H .0907. • Version 10/29/2010 SOC PRIORITY PROJECT: No To: Western NPDES Unit Surface Water Protection Section Attention: Gil Vinzani Date: January 19, 2010 NPDES STAFF REPORT AND RECOMMENDATIONS County: Gaston NPDES Permit No.: NC0004979 PART I - GENERAL INFORMATION Physical Location 1. Facility and address: Allen Steam Station c/o Duke Energy EC13K/Post Office Box 1006 253 Plant Allen Road Charlotte,N.C. 28201-1006 Belmont,NC 28102 2. Date of investigation: January 14, 2010 3. Report prepared by: Michael L. Parker, Environmental Engineer II 4. Person contacted and telephone number: Allen Stowe, (704) 382-1681, Don Scruggs. 5. Directions to site: From the jct. of Hwy. 7 and SR 2525 (South Point Rd.) in the Town of Belmont, travel south on SR 2525 z 2.5 miles. The entrance to the Allen Steam Plant is on the left (east) side of SR 2525. 6. Discharge point(s), list for all discharge points: - outfall 001 outfall 002 outfall 002A outfall 002B Latitude: 35° 11' 23" 35° 10' 30" 35° 11' 17" 35° 11' 15" Longitude: 81° 00' 45" 81° 00' 23" 81° 00' 46" 81° 00' 22" outfall 003 outfall 004 outfall 005 Latitude: 35° 11' 24" 35° 11' 15" 35° 11'24" Longitude: 81° 00' 46" 81° 00' 22"81° 00' 45" USGS Quad No.: G 14 NE Page Two 7. Receiving stream or affected surface waters: Catawba River(Lake Wylie)-outfalls 002, 002A, 002B, 004 & 005. South Fork Catawba River(Lake Wylie)-outfalls 001 &003. a. Classification: Catawba River, WS-IV & B; South Fork Catawba River, WS-V. b. River Basin and Subbasin No.: Catawba, 030834 c. Describe receiving stream features and pertinent downstream uses: Outfalls 002, 002A, 002B, & 004 enter the main segment of the Catawba River (Lake Wylie), which is used for primary and secondary recreation and as a receiving stream for point source (NPDES) discharges both upstream and downstream of the steam plant. There are no known municipal water intakes located immediately above or below these outfalls. Outfalls 001 & 003 enter a manmade discharge canal located west of the steam plant. This canal travels for a distance of z 1.2 miles where it enters the South Fork Catawba River(an arm of Lake Wylie). This area is also used for primary and secondary recreation and there are no known water intakes from the point of discharge to the mouth of the South Fork of the Catawba River. PART II-DESCRIPTION OF DISCHARGE AND TREATMENT WORKS Outfall 001 002 002A 002B 003 004 005 1. a. Volume of wastewater(MGD): 649.4 18.6 N/A N/A 4.5 6.5 0.5 b. What is the current permitted capacity: No flow limit for any outfall in Permit. c. Actual treatment capacity of current facility(current design capacity): N/A d. Description of existing or substantially constructed WWT facilities: outfall 001- no existing WWT facilities. Waste stream consists of Condenser Cooling Water(CCW). Outfall 002 - Ash Basin. The only existing treatment facility discharging into the Ash Basin is a septic tank that receives all the plant's domestic wastewater. This domestic wastewater enters the existing ash basin where additional treatment occurs. pH adjustment(carbon dioxide, sulfuric acid, and sodium hydroxide) is available at the effluent, if needed. Other wastewater sources entering the ash basin and discharge at outfall 002 include: stormwater runoff from the coal pile area, ash sluice,re-circulating water system, turbine non-destructive testing,heat exchanger cleaning, condensate polishers, condensate leakage testing, yard drain sump, water treatment system, pre-heater washes, laboratory wastes, and the power house sump (unit 5), Outfall 002A - Coal yard sump overflow. No existing WWT facilities. An overflow pipe directs flow directly to the Catawba River in the event that all pumps in the coal yard sump failed or redundant power supply could not be restored in a timely manner. This overflow pipe was approved by the Division in a letter dated May 15, 2000. Only one discharge has occurred from this outfall in the past five years. Page Three Outfall 002B - Power House Sump Overflow. No existing WWT facilities. An overflow pipe directs flow directly to the Catawba River in the event that all pumps in the yard sump failed or redundant power supply could not be restored in a timely manner. This overflow pipe was approved by the Division in a letter dated May 15, 2000. Only two (2) discharges have occurred from this outfall in the past five years. Outfall 003 - Miscellaneous Equipment Cooling and Seal Water. There is approximately 10,000 gpd of bearing cooling water(non-contact) discharged at this outlet. No existing WWT facilities. Discharge is to the CCW discharge canal adjacent to outfall 001. Outfall 004 -Equipment Cooling and Intake Screen Backwash and Car Wash rinse water. There is an oil/water separator installed on the car wash rinse water effluent line. Outfall 005 -This outfall is the Flue Gas Discharge (FGD)purge water from the chemical/physical WWT system constructed under the authorization of ATC No. 004979A01 issued June 21, 2004. This is an internal outfall that discharges directly into the ash basin. The WWT treatment facilities at this outfall consist of equalization followed by lime (pH) stabilization, sulfide and ferric chloride addition for chemical precipitation, clarification, gravity filtration, biological selenium removal, a final effluent holding tank, aerated sludge holding, and a plate sludge filter press. e. Description of proposed WWT facilities: There are no additional WWT facilities proposed at this time. f. Possible toxic impacts to surface waters: This facility has consistently passed toxicity tests required at outfall 002. Various chemicals are used during the cleaning and maintenance of equipment (see list provided with the application package). PART III - OTHER PERTINENT INFORMATION 1. Special monitoring or limitations (including toxicity) requests: a. Permittee requests a reduction in copper monitoring from twice per month to monthly based on historical monitoring date. Concurrence with the reduction in monitoring for copper is recommended based on a review of available analytical data. Page Four PART IV-EVALUATION AND RECOMMENDATIONS The permittee is requesting renewal of the subject permit. There have been changes to the facility since the last renewal (see Part II above). Changes to the current permit as requested by Duke for this renewal are discussed in Part III, No. 1 above. Pending a final review and approval of this renewal request and approval of the draft permit, it is recommended that the Permit be renewed as requested. )7l / ) .j� /-/9--/2 S. ture of Report Preparer Date 5 1 ----- //20/2a,/v Water Quality Regional Supervisor Date h:\ds r\dsr 10\allen.doc . . A.. .A .44 .............or NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary 4 y t' ` ._may .'. r:; December 4, 2009 - ,`.�.. 42,. ,44 -___1 ALLEN STOWE DEC — 9 2009 { WATER MANAGEMENT DUKE ENERGY EC13K/ PO BOX 1006 . CHARLOTTE NC 28201-1006 . Subject: Receipt of permit renewal application NPDES Permit NC0004979 Plant Allen Steam Station Gaston County Dear Mr. Stowe: h The NPDES Unit received your permit renewal application on November 2, 2009. A member of the NPDES Unit will review your application. They will contact you if additional information is required to complete E47-- your permit renewal. You should expect to receive a draft permit approximately 30-45 days before your existing permit expires. If you have any additional questions concerning renewal of the subject permit,please contact Gil Vinzani at (919) 807-6395. Sincerely, ZOL:it 4v24:Aititz, Dina Sprinkle '.,-'s�te Point Source Branch cc: CENTRAL FILES lial Office/Surface Water Protection NPDES Unit il + x 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 :aye Location:5f2 N.Salisbury St.Raleigh,North Carolina 27604 One Phone:919-807-63001 FAX:919-807-64921 Customer Service:1-877-623-6748 North Carol l n a �� Internet:www.ncwaterquality.org Naturally //� An Equal Opportunity i Affirmative Action Employer �/ `al 1 1 iiim Duke CORPORATE ENS SERVICES r "Energy® Duke Energy Corporation 526 South Church St. Charlotte, NC 28202 Mailing Address: EC13K/PO Box 1006 December 2, 2009 Charlotte, NC 28201-1006 Mr. Charles H. Weaver, Jr. RECEIVED State of North Carolina Department of Environment and Natural Resources - Division of Water Quality DEC NPDES Unit 1617 Mail Service Center DENR , WAITR OUALITY Raleigh, North Carolina 27699-1617 POINT SOURCE_ BRANCH Subject: Duke Energy Carolinas LLC — NPDES Permit Application Allen Steam Station - #NC0004979 Dear Mr. Weaver: Duke Energy Carolinas, LLC requests the subject permit be renewed and reissued. The above referenced permit expires May 31, 2010. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105 (e), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the renewal application, which includes the following items: EPA Form 1 EPA Form 2C EPA Form 2F Site Maps Water Flow Diagram Supplemental Information Duke Energy Carolinas, LLC requests notification that this application is complete. Additionally, the attached report, "Assessment of Balanced and Indigenous Populations in Lake Wylie," continues to indicate the maintenance of balanced indegnious populations. Therefore, this report supports renewal of the current thermal monitoring requirements of outfall #001. www.duke-energy.corn The following monitoring reductions at outfall #002 are requested based on historical monitoring data. • Reduce copper sampling from twice per month to monthly Thank you in advance for your assistance on this matter. Should you have questions regarding this application, please contact me at (704) 382-4309. 7077-57 k SYM Sincerely, Allen Stowe Water Management Attachments cc w/: Mr. Robert Krebs - NCDENR Mooresville R.O. Mr. Jay Sauber— NCDENR, Raleigh, N.C. (BIP Report 3 copies) • y, �l • / ,� `�— ,•, 1 ,t f. Ill if y��: % .. �..tt• F I ; ''� 7• ''ff} \--4_t," ..0.....,r� ms.'•J ;*.e`+Y. `o -. 1(/ • ``1 t1, ... ' , iyi•( • j i r/j.i J 111. , 1,• F= • `��a -J�,�r, ` -.1•11 '.I i,. .},J, ' '-y ,IF. f▪7�`u,} r I., -, - f•..,. -• -4,".• .; (''.. •-:: ' . , --1_ 'i "- • I�(( LL ff' -sue f• 1 •', , t 11 le J '• ,M" t.- • v.,%-%.,'/t 444444% �.i•4 A(t a '1 !l I k '1' 4 i {:. ' I,/3.1 �,rr i 011 �, 1 i4 Ifr. /• f'L .-, /t " • l • ,,'•, t1�`, '•-''Nit 11• �1, •1 `Allen �, • .1 •• t i t�"'"'• , - fi �~.--=,a�'^ /_, i`� • - ,� ' _ Steam Station ..�� • 'Ak I �.�• 1 =%..--\AN., .uF I• �, _I �y..- i��z r Qt.. - �Ik7 ,'e•r 0028 • r:1(:-, f.• .4.4.4).1,!•),ll• ,s 1` fir'.-\l•t i a a '''. ti1 3'„p.. , ±a,,),-..„ . .•. .• _`` - .•-• •"., _`iv,• ``i j fJ _�;�, ,I ,............, .. r ,.v „,_ rilc "(IT1j)1 ., , ,. i , ,_ " ' l �d� _---- 7 t -Rwrr:.,i;_••:. . enlQ s+' :t� r,!..„ ..,_.., ``� y•,.. ),:k`rL,,, ```h ,14, • , I -n^Yf� .. / ♦. . 1 / ✓ry , A. 002AI� hhp •'4. '• ,A,}`I ;l. (•. • �� .i ;- � • u1 � ter/ fir^ c; ,r:�,•y� ) „j• _ !d,� �I' / ~,fb#� •', , 7, •J _,• .' �� Till“11 •1!P1d : • ••; : I -%' /�"/'„• I 1 V!(` N( - .6 '�\ +�. `�Ara K_ti�� r \ S 'r ibb- , r' •h - -ter '� *,.,. .11 , i. it i ,- ,t t 7-7 r�Y 4, _ • ' ,,.. • I• t `�. ..� • 2/ _ ,1 .'• r/s J r" � � a , 1 per` r + ;K, l'` Vrer: ' 'I r - .--- 0,4 • ,i• '�'. 1 V t 1. *- ti" r- •? t V t I c. 6sti r -J r r ,-..� „4 r- r tt'r.. {,w i , '• f' • / " r ?••ItL l'" .! - , 4`e. jj • t ./i N„,- h:,y l —:1 , i I ` .+I 7t/. W�l�._ I� f i� i I •.\c ./ - ./ ) •- ♦� •s 1;): ... • • - - {: / , ;L ; „ t,r • 'ti E`, iii � , °' ,. ``, "7 ' ^ . ,,., ,, ! 1 ` /r,': - ". h..'{,p` ''>- L �`J � r (' `~ -.`mil••) ^:•• ! 1 f1 ,` 1 .1 i 1(1' n • '• si - •. 44,1" t: J�` troe� ' 1.;,h ' , ' :ram 11'` ?: .sue • i' 1'N, ,� f "`ri .1{tt/ k '' -- -,r ( • ! la t 44 ,., I -,t,/ (f •>i Legend �•'tatiii• v ' . •_._�— r,' ;i • ", .{ e - ,i • NPDES Outfall Location /�;t: r� t 4y, .� t -:' l`x � �;�+� C `h�{;.I� , •1' t' I001 NPDES Outfall Number -�1 i ��\ li. `- Fj ! e t ) '.s d•'j' , " ',It :: c`d '�,i �' ` �� it " t r Yf Sri - ' 1\yt Duke Energy Property Boundary r. p"�^ �i�I+,,� - ��� 7/ .. 4.�,} �i. ..�' it y( • ri ty ►� •t•om - j-�+ +� -v .4 _� 1, i REFERENCE: I 0 0.5 1 BACKGROUND DATA:1:24000 USGS TOPOGRAPHIC QUAD(BELMONT),WAS OBTAINED Kilometers _, FROM NCDOT GEOGRAPHICAL INFORMATION(GIS)WEBSITE.THE PROPERTY DATA 0 0.55 1 WAS OBTAINED FROM THE GASTON COUNTY NORTH CAROLINA GIS DEPARTMENT. PLEASE NOTE THIS DATA IS FOR INFORMATIONAL PURPOSES ONLY. Miles SCALE: AS SHOWN FIGURE Duke LOCATION MAP DUKE ENERGY NO DATE: 10-26-2009Milk ALLEN STEAM STATION DRAWN BY: NPDES # NC0004979 RDP Eiiergy®PROJECT NO: ALLEN STEAM STATION 1411-08-140 GASTON COUNTY,NORTH CAROLINA Plant Allen 2009 Water Schematic Condenser Outfa11001 South Fork Cooling Water 649 MGD ► River Sanitary Outfall002A ► Catawba Intermittent River Waste Coal Handling 0 Coal Yard Stormwater Sumps Sump Atm Ash Sluice ► T ,... Water Internal ? r FGD —► FGD WWTS Outfall 005 — 0 0.5 MGD Outran002 Catawba Ash Basin 18.6 MGD—� River A ► Water f FGD Treatment Stormwater Sump I ♦ Landfill Turbine Rm Catawba ► -- 0 Boer n ► Sumps — Leachate River V Ash Silo Sump •Boiler 4 0 Sumps Rm " 04 Stormwater YardSum'n�e Sump 4 1 1-- --♦ ,, Misc Equip ,� Outfall 003 ►South Fork 0Cooling&Seals 4.5 MGD River ► Powerhouse ^ Sump A Outfall 002B Catawba (Intermittent) River Intake Screen Backwash Outfall 004 II' ♦ ►Catawba 6.5 MGD River Limestone Stormwater Sump Asiatic Clam/ Debris Filter ► Catawba Backwash River Please print or type in the unshaded areas only. Form Approved.OMB No.2040-0086. FORM U.S.ENVIRONMENTAL PROTECTION AGENCY I.EPA I.D.NUMBE111.111111111. 1 /EPA GENERAL INFORMATION s TIA Consolidated Permits Program F NC 0 0 04 9 7 9 D GENERAL (Read the"General Instructions"before starting.) 1 - Z 13 14 15 LABEL ITEMS GENERAL INSTRUCTIONS If a prepnnted label has been provided, affix it in the designated space.Review the information carefully;if any of it I. EPA I.D.NUMBER « is incorrect,cross through it and enter the correct data in the appropriate fill-in area below.Also,if any of the preprinted data is absent (the area to the left of the label space lists the III. FACILITY NAME PLEASE PLACE LABEL IN THIS SPACE information that should appear),please provide it in the proper fill-in area(s)below.It the label is complete and correct,you V. FACILITY MAILING need not complete Items I,Ill,V,and VI(except Vl-B which ADDRESS must be completed regardless).Complete all items if no label has been provided.Refer to the instructions for detailed item descriptions and for the legal authorizations under which this VI. FACILITY LOCATION data is collected. II.POLLUTANT CHARACTERISTICS INSTRUCTIONS:Complete A through J to determine whether you need to submit any permit application forms to the EPA.If you answer"yes"to any questions,you must submit this form and the supplemental form listed in the parenthesis following the question.Mark"X"in the box in the third column if the supplemental form is attached.If you answer"no"to each question,you need not submit any of these forms.You may answer"no"if your activity is excluded from permit requirements;see Section C of the instructions.See also,Section D of the instructions for definitions of bold-faced terms. Mark'X" Mark'X' SPECIFIC QUESTIONS YES NO FORMSPECIFIC QUESTIONS YES NO FORM ATTACHED ATTACHED A. Is this facility a publicly owned treatment works which B.Does or will this facility (either existing or proposed) results in a discharge to waters of the U.S.?(FORM 2A) X include a concentrated animal feeding operation or X aquatic animal production facility which results in a 16 17 15 discharge to waters of the U.S?(FORM 26) 19 20 21 C.Is this a facility which currently results in discharges to �/ X D.Is this a proposed facility(other than those described in A X waters of the U.S.other than those described in A or B /� or B above)which will result in a discharge to waters of above?(FORM 2C) n 23 24 the U.S.?(FORM 2D) zs z6 2 E. Does or will this facility treat, store, or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes?(FORM 3) X municipal effluent below the lowermost stratum X containing, within one quarter mile of the well bore, 28 29 30 underground sources of drinking water?(FORM 4) 31 32 33 G.Do you or will you inject at this facility any produced water H.Do you or will you inject at this facility fluids for special or other fluids which are brought to the surface in processes such as mining of sulfur by the Frasch process, connection with conventional oil or natural gas production, X solution mining of minerals, in situ combustion of fossil X inject fluids used for enhanced recovery of oil or natural fuel,or recovery of geothermal energy?(FORM 4) gas, or inject fluids for storage of liquid hydrocarbons? (FORM 4) 34 J5 36 37 36 39 I. Is this facility a proposed stationary source which is one J. Is this facility a proposed stationary source which is of the 28 industrial categories listed in the instructions and X NOT one of the 28 industrial categories listed in the `� which will potentially emit 100 tons per year of any air /� instructions and which will potentially emit 250 tons per X pollutant regulated under the Clean Air Act and may affect year of any air pollutant regulated under the Clean Air Act or be located in an attainment area?(FORM 5) 40 41 02 and may affect or be located in an attainment area? U ^° 45 (FORM 5) III. NAME OF FACILITY c SKIP A len Steam Station 1 15 16-29 30 IV. FACILITY CONTACT A.NAME&TITLE(last,first,it tide) B.PHONE(area code it,no.) jsLorie111 ,1111 1 1 1 1 1 1 1 1 1 I I 1 I I I I1II3I9 I, Allen/Env. S c. III (70 ) 3 2-4 0 15 45 46 4a 1. 61 155 55 V.FACILTY MAILING ADDRESS A.STREET OR P.O.BOX 1c 1 1 1 1 1 1 1 1 I, 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 f 3IP.O. Box 1006, Mail Co e EC13K 15 16 45 B.CITY OR TOWN C.STATE D.ZIP CODE 4 Charlotte 1 1 1 I I l l 1 1 I 1 I l l l l 1 1 1 1 IIQC 282011 1 1 40 16 . l2 d] - 15 VI. FACILITY LOCATION ff A.STREET,ROUTE NO.OR OTHER SPECIFIC IDENTIFIER 15 2531 Plantl AlllIIenl Road 1 I I I I I I 1 I I I I I I I I I 1 I + 15 16 45 B.COUNTY NAME Gaston I I I 1 I I I I 1 I I 1 I I I I 1 I I I I I 46 70 C.CITY OR TOWN D.STATE E.ZIP CODE F.COUNTY CODE(iifknown) s Bolrikotit IIIIIIIIIIIIIIIIIIIII roc 21oi2 11 1 I 15 16 40 41 42 _47 51 52 -54 EPA Form 3510-1(8-90) CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII.SIC CODES 4-di.it,in order of.riorit A.FIRST B.SECOND c I I I mac,.fy) ,L I I I (specify)7 4 9 1 1 Electric Services 7 15 16 - 19 15 16 - 19 - C.THIRD D.FOURTH c I I I (specify) I I I (specify) 7 7 15 16 - 19' 15 16 - 19 VIII.OPERATOR INFORMATION A.NAME B.Is the name listed in Item 1c III I I I I I I I 1 1 I 1 1 I 1 1 I I I 1 1 1 1 I 1 1 I I I I I I I 1 I I I VIII-A also the owner'? Duke Energy Carolinas, LLC (Attention: Allen Stowe) O YES ❑NO 15 16 55 e6 C.STATUS OF OPERATOR(Enter the appropriate letter into the answer box:if"Other,"specify.) D.PHONE(area code&no.) F=FEDERAL (specify) I I I I I I I I I S=STATE M=PUBLIC(other than federalorstate) p Electric Utility A (704) 382-4309 P=PRIVATE O=OTHER(specify) 56 _ 15 6 - 18 119 • 21122 • 26 E.STREET OR P.O.BOX I I I 11 4 I I I I I J. 1 I I 1 1 1 1 1 1 1 1 1 1 P.O. ox 100 , Mai Code C13 26 56 F.CITY OR TOWN G.STATE H.ZIP CODE IX.INDIAN LAND I I IIIIIIII IIIIIIIIIII III 1 1 1 1 1 Is the facility located on Indian lands? B Charlotte NC 28201 ❑YES ©NO 15 16 .o 41 42 n - 51 52 X.EXISTING ENVIRONMENTAL PERMITS A.NPDES(Discharges to Surface Water) D.PSD(Air Emissions from Proposed Sources) C T I 1 I I 1 r I r 1 I I I 1 C T I if 9 N NC0004979 9 P 15 16 17 18 30 15 16 17 18 30 B.UIC(Underground Injection of Fluids) E.OTHER(specify) C T I III 1 1 1 1 1 1 1 1 CITI ( II II 1 1 1 1 1 I I 1 f) 9 U 9 03757T33/I�CG010000 (AaraVermit/General Stormwater 15 16 17 18 30 15 16 17 16 30 C.RCRA(Hazardous Wastes) E.OTHER s c!fy CTI 1 1 1 1 1 1 1 1 1 1 1 1 C T I 1 1 1 1 1 1 1 1 1 1 1 /s 9 R NCD043678937 9 WQ0000452/36-12 b ctrcbution of Residual Solids Permit/Industrial Landfill Permit 15 16 17 18 30 15 16 17 18 30 XI.MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries.The map must show the outline of the facility,the location of each of its existing and proposed intake and discharge structures,each of its hazardous waste treatment,storage,or disposal facilities,and each well where it injects fluids underground.Include all springs,rivers,and other surface water bodies in the map area.See instructions for precise requirements. XII.NATURE OF BUSINESS(provide a brief cIescrifIIIIII)fion) IIIIIIIIIIII Coal fired electric generation XIII.CERTIFICATION(see instructions) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that,based on my inquiry of those persons immediately responsible for obtaining the information contained in the application,I believe that the information is true,accurate,and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment. A.NAME&OFFICIAL TITLE(type or print) B.SIGNATU E C.DATE SIGNED Steve Immel - General Manager II, Regulated Fossil Stations ---. 0 11/30/2009 COMMENTS FOR OFFICIAL USE ONLY c C 15 16 55 EPA Form 3510-1(8-90) EPA I.D.NUMBER(copy from Item I of Form I) Form Approved. NC0 0 04 97 9 OMB No.2040-0086. Please print or type in the unshaded areas only. Approval expires 3-31-98. FORM U.S.ENVIRONMENTAL PROTECTION AGENCY 2C 4- EPA EXISTING MANUFGE WASTEWATER ACTURINAPPLICATIONG,COMMERC AL,MINING FOR PERMIT TO RAND SILVICULTURE OPERATIONS NPDES Consolidated Permits Program I.OUTFACE LOCATION For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A.OUTFALL NUMBER B.LATITUDE C.LONGITUDE (list) 1.DEG. 2.MIN. 3.SEC. 1.DEG. 2.MIN. 3.SEC. D.RECEIVING WATER(name) 001 35 11 22 81 00 44 South Fork River 002 35 10 30 81 00 20 Catawba River 002A/002B 35/35 11/11 13/25 81/81 00/00 21/28 Catawba River (Intermittent) 003 35 11 23 81 00 45 South Fork River 004/005 35/35 11/09 13/60 81/81 00/01 21/22 Catawba River/Internal Outfall II.FLOWS,SOURCES OF POLLUTION,AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility.Indicate sources of intake water,operations contributing wastewater to the effluent,and treatment units labeled to correspond to the more detailed descriptions in Item B.Construct a water balance on the line drawing by showing average flows between intakes,operations, treatment units,and outfalls.If a water balance cannot be determined(e.g.,for certain mining activities),provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall,provide a description of:(1)All operations contributing wastewater to the effluent,including process wastewater,sanitary wastewater,cooling water, and storm water runoff; (2)The average flow contributed by each operation;and(3)The treatment received by the wastewater.Continue on additional sheets if necessary. 1.OUT- 2.OPERATION(S)CONTRIBUTING FLOW 3.TREATMENT FALL b.AVERAGE FLOW b.LIST CODES FROM NO.(list) a.OPERATION(list) (include units) a.DESCRIPTION TABLE 2C-1 Condenser Cooling Water 649.4 MOD Screen discharge to surface water IT 001 (Once through non-contact) 4A includes intake screen backwash Ash basin discharge 18.6 MGD chemical coagulation, settling, neutralization, 2D 2K 002 ion exchange, surface water discharge lU 2J 4A Emergency Overflow of yard drain surface water discharge 002A Intermittent 4A 002B sump #1 (002A) and sunp #2 (0028) See supplemental information Miscellaneous once through 4.5 MGD surface water discharge 4A 003 non-contact cooling water Miscellaneous once through surface water discharge 004 6.5 MOD 4A non-contact cooling water surface water discharge 4A Flue Gas Desulfurization 0.5 MGD Internal outfall, discharges to ash basin 1R 2L 005 Wastewater Treatment System 2C 3C 2D 5C 2K OFFICIAL USE ONLY(effluent guidelines sub-categories) EPA Form 3510-2C(8-90) PAGE 1 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT C.Except for storm runoff,leaks,or spills,are any of the discharges described in Items II-A or B intermittent or seasonal? ©YES(complete the following table) ❑NO(go to Section iii) 3.FREQUENCY 4.FLOW a.DAYS PER B.TOTAL VOLUME 2.OPERATION(s) WEEK b.MONTHS a.FLOW RATE(in mgd) (specify with units) 1.OUTFALL CONTRIBUTING FLOW (specify PER YEAR 1.LONG TERM 2.MAXIMUM 1.LONG TERM 2.MAXIMUM C.DURATION NUMBER(fist) (list) average) (specify average) AVERAGE DAILY AVERAGE DAILY On days) 002A Emergency overflow of yard drain sump See See See See #1 (see supplmental information) Supple- Supple- Supple- Supple- mental mental mental mental Informat- Informat- Informat- Informat ion ion ion -ion 002E Emergency overflow of yard drain sump See See See See #2 (see supplmental information) Supple- Supple- Supple- Supple- mental mental mental mental Informat- Informat- Informat- Informat ion ion ion -ion III.PRODUCTION A.Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? IZI YES(complete Item Ill-B) ❑NO(go to Section IV) B.Are the limitations in the applicable effluent guideline expressed in terms of production(or other measure of operation)? ❑YES(complete Item Ill-C) V]NO(go to Section IV) C.If you answered"yes"to Item III-B,list the quantity which represents an actual measurement of your level of production,expressed in the terms and units used in the applicable effluent guideline,and indicate the affected outfalls. 1.AVERAGE DAILY PRODUCTION 2.AFFECTED OUTFALLS a.QUANTITY PER DAY b.UNITS OF MEASURE c.OPERATION,PRODUCT,MATERIAL,ETC. (list outfall numbers) (specify) NA NA NA NA IV.lfNPIIIIIIIIIIIIMIMIIIIIIIIIIIMIIIIIIIIIIII A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application?This includes,but is not limited to, permit conditions,administrative or enforcement orders,enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. ❑YES(complete the following table) 2 NO(go to Item IV-B) 1.IDENTIFICATION OF CONDITION, 2.AFFECTED OUTFALLS 3.BRIEF DESCRIPTION OF PROJECT 4.FINAL COMPLIANCE DATE AGREEMENT,ETC. a.NO. b.SOURCE OF DISCHARGE a.REQUIRED b.PROJECTED B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges)you now have underway or which you plan.Indicate whether each program is now underway or planned,and indicate your actual or planned schedules for construction. ❑MARK"X"IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED EPA Form 3510-2C(8-90) PAGE 2 of 4 CONTINUE ON PAGE 3 EPA I.D.NUMBER(copy from Item l of Form I) CONTINUED FROM PAGE 2 NC0004987 V.INTAKE AND EFFLUENT CHARACTERISTICS A,B,&C: See instructions before proceeding—Complete one set of tables for each outfall—Annotate the outfall number in the space provided. NOTE:Tables V-A,V-B,and V-C are included on separate sheets numbered V-1 through V-9. D. Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions,which you know or have reason to believe is discharged or may be discharged from any outfall.For every pollutant you list,briefly describe the reasons you believe it to be present and report any analytical data in your possession. 1.POLLUTANT 2.SOURCE 1.POLLUTANT 2.SOURCE See Supplemental Information, Table 5.1 (attached) for complete list VI.POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item V-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct'? ❑YES(list all such pollutants below) NO(go to Item VI-R) EPA Form 3510-2C(8-90) PAGE 3 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII.BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ©YES(identify the test(s)and describe their purposes below) ❑NO(go to Section VIII) Quarterly analysis of Ceriodaphnia Dubia chronic testing per current permit requirements on Outfall 002 VIII.CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? YES(list the name,address,and telephone number of and pollutants analyzed by, ❑NO(go to Section IX) each such laboratory or firm below) A.NAME B.ADDRESS C.TELEPHONE D.POLLUTANTS ANALYZED (area code&no.) (list) Shealy Environmental 106 Vantage Point Drive 803-791-9700 ,All parameters except Services,Inc. West Columbia, SC 29172 dioxin and radiological SGS Environmental Services, Inc. 5500 Business Dr, 910-350-1903 Dioxin Wilmington, NC 28405 GEL Laboratories LLC 2040 Savage Road 843-556-8171 Radiological Charleston, SC 29417 IX.CERTIFICATION I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. A.NAME&OFFICIAL TITLE(type or print) B.PHONE NO.(area code&no.) Steve Immel, General Manager II, Regulated Fossil Stations (704) 829-2400 C.SIGNATURE D.DATE SIGNED 11/30/2009 EPA Form 3510-2C(8-90) PAGE 4 of 4 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS N00004979 Allen Steam Station OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 001 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES(ration a.Biochemical Oxygen < 2.0 < 14533.7 1 mg/L lbs/Day (1<Concent 2.0 wrt (2<Maas ANALYSES Demand(SOD) b.Chemical Oxygen < 10 < 72668.3 1 mg/L lbs/Day < 10 < 1 Demand(COD) c.Total Organic 1.9 13807.0 1 mg/L lbs/Day 1.7 1 Carbon(TOC) d.Total Suspended 7.0 50867.8 1 mg/L lbs/Day 9.0 1 Solids(TSS) a.Ammonia(as N) 0.13 944.7 1 mg/L lbs/Day < 0.10 < 1 f.Flow VALUE VALUE VALUE VALUE 870.8 836.1 649.4 729 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (winter) 28.9 23.9 20.4 169 DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 43.3 38.9 38.2 184 DEGREES CELSIUS i.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.99 7.23 2 STANDARD UNITS 7.18 1 PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a Concert- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES Saban (1)Concentration (2)Mass ANALYSES a.Bromide X < 0.20 < 1453.4 1 mg/L lbs/Day < 0.20 < 1 (24959-87-9) b.Chlorine, X < 0.050 < 363.3 1 mg/L lbs/Day < 0.050 < 1 Total Residual c.Color X 15 N/A N/A N/A 1 Std.Units N/A 25 N/A 1 J.Fecal X 4 N/A N/A N/A 1 Colonies N/A < 2 < N/A 1 Coliform /100 ml s.Fluoride X < 0.10 < 726.7 1 mg/L lbs/Day < 0.10 < 1 :18984.48-8) Nitrate- X 0.17 1235.4 1 mg/L lbs/Day 0.22 1 ,Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if avafable) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES'ration (1)Concentration (2)Mass ANALYSES b.Nitrogen, Total Organic X 0.37 2688.7 1 mg/L lbs/Day 0.28 1 (as N) h.ON and Grease X < 5.0 < 36334.1 1 mg/L lbs/Day < 5.0 < 1 i.Phosphorous (as P),Total X 0.061 443.3 1 mg/L lbs/Day 0.021 1 (7723-14-0) j.Radioactivity (1)Alpha, Total X < 5.0 < N/A N/A N/A 1 PatN/A < 5.0 < N/A 1 (2)Beta, Total X 2.5 N/A N/A N/A 1 pCi/L N/A < 5.0 < N/A 1 3)Radium. Total X 0.40 N/A N/A N/A 1 pCi/L N/A < 1.0 < N/A 1 (4)Radium 226,Total X 0.76 N/A N/A N/A 1 pCitl N/A < 1.0 < N/A 1 it.Sulfate (as SO4) X 5.4 39240.9 1 mg/L lbs/Day 5.1 1 14808-79-8) I.Sulfide (as S) X 9.6 69761.5 1 mg/L lbs/Day < 1.0 < 1 m.Sulfite (as 603) X 3.0 21800.5 1 mg/L lbs/Day < 1.0 < 1 A14265.453) n.Surfactants A 0.089 646.7 1 mg/L lbs/Day < 0.0050 < 1 o.Aluminum, Total X 0.170 1235.4 1 mg/L lbs/Day 0.210 1 (7429-90-5) . b.Barium, Taal X < 0.050 < 363.3 1 mg/L lbs/Day < 0.050 < 1 (7440-39-3) p Boron, Taal X 0.065 472.3 1 mg/L lbs/Day 0.068 1 (7440.42-8) r.Cobalt, Total X < 0.020 < 145.3 1 mg/L lbs/Day < 0.020 < 1 (7440-48-4) s.Iron,Total (7439-89-6) X 0.56 4084.0 1 mg/L lbs/Day 0.60 1 -Magnesium, Taal X 1.8 13080.3 1 mg/L lbs/Day 1.9 1 (7439-95-4) u.Molybdenum, Total X < 0.020 < 145.3 1 mg/L lbs/Day < 0.020 < 1 (7439-98-7) v.Manganese, Total X 0.033 239.8 1 mg/L lbs/Day 0.040 1 (7439-96-5) w.Tin,Total (7440-31-5) X < 0.010 < 72.7 1 mg/L lbs/Day < 0.010 < 1 it.Titanium, Total X < 0.050 < 363.3 1 mg/L lbs/Day < 0.050 < 1 (7440-32-6) _ EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 001 Allen Steam Station 'PART C-If you are a primary industry and this outfafl contains process wastewater,refer to-Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF lid sent sem (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES METALS,CYANIDE,AND T TAL HENOLS 111.Antimony, X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 Total(7440-38-0) 2M.Arsenic,Total X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 (7440-38-2) 3M.Beryllium, X < 1.0 < 7.27 1 ug/L lbs/Day < 1.0 < 1 Total(7440.41-7) 4M.Cadmium, X < 0.10 < 0.73 1 uglL lbs/Day < 0.10 < 1 Total(7440-43-9) 5M.Chromium, X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 Total(7440-47-3) BM.Copper,Total X 0.015 107.55 1 mg/L lbs/Day < 0.0050 < 1 (744a50-8) 7M.Lead,Total X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (7439-92.1) 8M.Mercury,Taal X 0.0011 0.01 1 ugh lbs/Day 0.0012 1 /7439-97 6) 9M.Nickel,Total X < 10 < 72.67 1 ug/L lbs/Day < 10 < 1 ' (7440-02-0) 10M.Selenium, X < 1.0 < 7.27 1 ug/L bs/Day < 1.0 < 1 Total(7782-49-2) 11M.Silver,Taal X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 (7440-22-4) 12M.Thallium, X < 0.00050 < 3.6 1 mg/L lbs/Day < 0.00050 < 1 Total(7440.28-0) 13M.Zinc,Total X < 0.010 < 72.67 1 mg/L lbs/Day < 0.010 < 1 (7440.88.8) 14M.Cyanide, X < 0.010 < 72.67 1 mg/L bs/Day < 0.010 < 1 Total(57.12-5) 15M.Phenols, X < 0.0050 < 36.3 1 mg/L lbs/Day < 0.0050 < 1 Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X < 0.0100 1 < 0.0001 1 1 I NA- 1 IDS/Day 1 < 0.0100 I I 1 Dioxin(1784-01-0) - EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration I(2)Mass (1)Concentration 1(2)Mass ANALYSES(ration (1)Concentration 11(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS 1V.Acrolein X < 5.0 < 36.33 1 ughIbs/Day < 5.0 < 1 (107-02-8) 2V.Acrylonilrile X < 5.0 < 36.33 1 ugh lbs/Day < 5.0 < 1 (107-13.1) 3V.Benzene X < 2.0 < 14.53 1 ugh Ibs/Day < 2.0 < 1 (71-43-2) 4V.Bis(Chloro- methyl)Ether X (542-88-1) 5V.Bromoform X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (75-25-2) BV.Carbon Tetrachloride X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (56-23-5) 7V.Chlorobenzene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (108-90-7) BV.Chlorodi- bromomethane X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (124-48-1) 9V.Chloroethane X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (75-00-3) , 10V.2-Chloro- ethylvinyl Ether X < 5.0 < 36.33 1 tg/L lbs/Day < 5.0 < 1 /(110-75-8) 11V.Chloroform X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (67-66-3) 12V.Dichloro- bromomethane X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (75-27-4) 13V.Dichloro- difuorethane X < ran 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (75-51-8) - 14V.1,1-Dichloro- X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 ethane(75-34-3) 15V.1,2-Dichloro- X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 ethane(107-06-2) 18V.1,1-Dichlero- X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 ethylene(75-35-4) 17V.1,2-Dichloro- X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 propane(78-87-5) 18V.1,3-Dichloro- X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 propylene(542-75-6) . 19V.Ethylbenzene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (100-41-4) 20V.Methyl X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 Bromide(74-83-9) _ 21 V.Methyl X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed 'a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration GC/MS FRACTION-VOLATILE COMPOUNDS(continued) (1)Concentration 1(2)Mass ANALYSES 22V.Methylene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 Chloride(75-09-2) 23V.1,1,2,2-Tetra- chloroethane X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (79-34-5) 24V.Tetrachloro- X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 ethylene(127-18-4) 25V.Toluene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (108.88-3) 26V.1,2-Trans- Dichloroethylene X < 2.0 < 14.53 1 lbs/Day < 2.0 < 1 (156.60-5) 27V.1,1,1-Tri- chloroethane X < 2.0 < 14.53 1 ug/L Ibs/Day < 2.0 < 1 (71-55-6) 28V.1,1,2-Tri- chloroethane X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (79-00-5) 29V.Trichloro- X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 ethylene(79-01-6) 30V.Trichloro- Buoromethane X < 2.0 < 14.53 1 ag/L lbs/Day < 2.0 < 1 (75-694) 31V.Vinyl X < 2.0 < 14.53 1 ugh Ibs/Day < 2.0 < 1 Chloride(75-01-4) GC/MS FRACTION-ACID COMPOUNDS 1A.2-Chlorophenol X < 5.3 < 38.51 1 WA- lbs/Day < 5.0 < 1 (95-57-8) 2A.2,4-Dichloro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 phenol(120.83-2) 3A.2,4-Dimethyl- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 phenol(105-67-9) 4A.4,8-Dinitro-O- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Cresol(534-52-1) 5A.2,4-Dinfro- X < 26 < 188.94 1 ug/L lbs/Day < 25 < 1 phenol(51-28-5) BA.2-Nitrophenol X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (88-75-5) 7A.4-Nitrophenol X < 5.3 < 38.51 1 ag/L lbs/Day < 5.0 < 1 (100-02-7) BA.P-Chloro-M- X < 5.3 . < 38.51 1 ug/L lbs/Day < 5.0 < 1 Cresol(59-50-7) 9A.Pentachloro- X < 5.3 < 38.51 1 ag/L lbs/Day < 5.0 < 1 phenol(87-86-5) 10A.Phenol X < 5.3 < 38.51 1 ug/L . lbs/Day < 5.0 < 1 (108-95-2) 11A.2,4,6-Tri- chlorophenol X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (88-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 001 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed 'a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration _(1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 18.Acenaphthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (83-32-9) 28.Acenaphtylene X < 5.3 < 38.51 1 ug/L bs/Day < 5.0 < 1 (208-96-8) 3B.AMhracene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (120-12-7) 48.Benzidine X < 53 < 385.14 1 ugh lbs/Day < 50 < 1 (92-87-5) 58.Benzo(a) Anthracene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (56-55-3) BB.Benzo(a) X < 5.3 < 38.51 1 ugh bs/Day < 5.0 < 1 Pyrene(50-32-8) 78.3,4-Benzo- fluoranthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (205-99-2) BB.Benzo(ghi) X < 5.3 < 38.51 1 WA- lbs/Day < 5.0 < 1 Perylene(191-24-2) 9B.Benzo(k) Fluoranthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (207-08-9) 108.Bis(2-Chloro- ethoxyt)Methane X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 )(111-91-1) 118.Bis(2-Chloro- ethyl)Ether X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (111-44-4) 128.Bis(2-Chloroiso- propyl)Ether X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (108-60-1) 138.Bis(2-Ethyl- hexyl)Phehalate X < 5.3 < 38.51 1 ugh lbs/Day < 5.0 < 1 (117-81-7) 148.4-Bromo- phenyl Phenyl X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Ether(101-55-3) j 15B.Butyl Benzyl X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Phthalate(85.88-7) 168.2-Chloro- - naphthalene X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (91-58-7) 178.4-Chtoro- phenyl Phenyl X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Ether(7005-72-3) 188.Chrysene X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (218-01-9) _ 198.Oibenzo(a,h) Anthracene X < 5.3 < 38.51 1 ugh Ibs/Day < 5.0 < 1 (53-70-3) 208.1,2-Dichloro- X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 benzene(95-50-1) 218.1,3-Dichloro- X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 22B.1,4-Dichloro- X < 2.0 < 14.53 1 tg/L lbs/Day < 2.0 < 1 benzene(106-46-7) 238.3,3-Dichloro- benzidine X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (91-94-1) '24B.Diethyl Phthalate X < 5.3 < 38.51 1 tg/L lbs/Day < 5.0 < 1 (84-66-2) 258.Dimethyl Phthalate X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (131-11-3) 288.Di-N-Butyl Phthalate X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (84-74-2) 27B.2,4-Dinitro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 toluene(121-14-2) 28B.2,6-Dinitro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 toluene(606-20-2) 29B.Di-N-Octyl Phthalate X < 5.3 < 38.51 1 ugh lbs/Day < 5.0 < 1 (117-84-0) 30B.1,2-Diphenyl- hydrazine(as Azo- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 /benzene)(122.66-7) 318.Ftuoranthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (206-44-0) 328.Fluorene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (86-73-7) 33B.Hexachloro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 benzene(118-74-1) 34B.Hase- chlorobutadiene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (87-68-3) 35B.Hexachloro- cyclopentadiene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (77-47-4) 36B.Hexachloro- X < 5.3 < 38.51 1 Mil- lbs/Day < 5.0 < 1 ethane(67-72-1) 378.Indeno (1,2,3-cd)Pyrene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (193-39-5) 388.Isophorone X < 5.3 ' < 38.51 1 ug/L lbs/Day < 5.0 < 1 (78-59-1) 39B.Naphthalene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (91-20-3) 408.Nitrobenzene X < 5.3 < 38.51 - 1 ug/L lbs/Day < 5.0 < 1 (98-95-3) 41B.N-Nitro- sodimethylamine X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (62-75-9) 42B.N-Nitrosodi- N-Propylamine X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (621-64-7) , EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 001 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-'c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES ration to Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 43B.N-Nitro- sodiphenylamine X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (86.30.6) 448.Phenanthrene X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (85-01-8) 45B.Pyrene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (129-00-0) 46B.1,2,4-Tri- chbrobenzene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (120-82-1) GC/MS FRACTION-PESTICIDES 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-8HC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.deha-BHC X (319-86-8) BP.Chlordane X (57-74-9) 7P.4,4'-DDT X (50-29-3) BP.4,4'-DDE X (72-55-9) 9P.4,4'-DDO X (72-54-8) 10P.Dieldrin X (60-57-1) 11P.alpha-Endosulfan X (115-29-7) t2P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X (76 44-8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 001 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. cm- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- e.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-PESTI IDE (continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.26 < 1.89 1 ughL lbs/day < 0.25 1 (53469-21-9) 19P.PCB-1254 X < 0.26 < 1.89 1 ugh Ibs/day < 0.25 1 (11097-69-1) 20P.PCB-1221 X < 0.26 < 1.89 1 ug/L Ibs/day < 0.25 1 (11104-28-2) 21P.PCB-1232 X < 0.26 < 1.89 1 (11141-16-5) 1t9/L lbs/day < 0.25 1 22P.PCB-1248 X < 0.26 < 1.89 1 ug/L lbs/day < 0.25 1 (12672-29-6) 23P.PCB-1260 X < 0.26 < 1.89 1 daY < 0.25 1 (11096-82-5) 24P.PCB-1016 X < 0.26 < 1.89 1 lbs/day < 0.25 1 (12874.11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS NC0004979 Alien Steam Station OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 002 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE :c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass �(1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen < 2.0 < 392.2 1 mg/L lbs/Day Demand(BOD) b.Chemical Oxygen < 10 < 1961.1 1 mg/L lbs/Day Demand(COD) c.Total Organic 1 196.1 1 mg/L lbs/Day Carbon(TOC) d.Total Suspended 23.0 4510.5 23 4261.0 6.8 1055.5 24 mg/L lbs/Day Solids(TSS) e.Ammonia(as N) 0.310 60.8 1 mg/L lbs/Day F.Flow VALUE VALUE VALUE VALUE 23.5 22.2 18.6 105 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 28.57 1 DEGREES CELSIUS pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.2 7.4 24 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X• 3.EFFLUENT 4.UNITS 5.INTAKE optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES (ration (1)Concentration (2)Mass ANALYSES a.Bromide X 0.75 147.1 1 mg/L lbs/Day (24959.87-9) b.Chlorine, X < 0.050 < 9.8 1 mg/L lbs/Day Total Residual c.Color X 15 N/A N/A N/A 1 Std.Units N/A N/A d.Fecal X < 2 < N/A N/A N/A 1 Colonies N/A N/A Coliform /100 ml e.Fluoride X 0.27 52.9 1 mg/L lbs/Day (18984.48.8) f.Nitrate- X 0.21 41.2 1 mg/L lbs/Day Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 002 Alien Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(option) AND CAS NO. Behaved a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Comm- b.Mass b.NO.OF Sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen, Total Organic X 1.70 333.4 1.7 314.9 1.2 186.3 4 mg/L lbs/Day (as N) h.Oh and Grease X < 5.0 < 980.5 < 5 < 926.3 < 5 < 776.1 8 mg/L lbs/Day i.Phosphorous (as P),Total X 0.027 5.3 1 mg/L lbs/Day (7723-14-0) I.Radioactivity (1)Alpha, Total A < 5.0 < N/A N/A N/A 1 pCJL N/A N/A (2)Beta, Total A 3.2 N/A N/A N/A 1 pCilI N/A N/A (3)Radium, Total X 0.64 WA N/A N/A 1 pCi/L N/A N/A (4)Radium 228,Total A 0.58 N/A N/A N/A 1 pan_ N/A N/A k.Sulfate (as SO4) X 56 10982.0 1 mg/L lbs/Day (14808.79.8) I.Sulfide (as S) X < 1.0 < 196.1 1 mg/L lbs/Day m.Sulfite (as SO3) X < 1.0 < 196.1 1 mg/L lbs/Day /(14265.45-3) n.Surfactants X 0.055 10.8 1 mg/L lbs/Day o.Aluminum, Total X 0.11 21.6 1 mg/L lbs/Day (7429-90-5) p.Barium, Total X 0.078 15.3 1 mg/L lbs/Day (7440-39-3) q.Boron, Total X 0.75 147.1 1 mg/L lbs/Day (7440-42-8) r.Cobalt, Total X < 0.020 < 3.9 1 mg/L lbs/Day (7440-48-4) s.Iron,Total (7439-89-6) X 0.72 141.2 0.72 133.4 0.24 37.3 24 mg/L lbs/Day I.Magnesium, Total X 8.0 1568.9 1 mg/L lbs/Day (7439-95-4) u.Molybdenum, Total X 0.022 4.3 1 mg/L lbs/Day (7439-98-7) v.Manganese, Total X 0.10 19.6 1 mg/L lbs/Day (7439-96-5) w.Tin,Total (7440-31-5) X < 0.010 < 2.0 1 mg/L lbs/Day aTitanium, - Total X < 0.050 < 9.a 1 mg/L lbs/Day (7440-32-6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 002 Allen Steam Station PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre-'cast (if available) (if available) d.NO.OF a.Conan- b.Mass d.NO.OF ed sent sent (1)Concentration J(2)Mass (1)Concentration 1(2)Mass (1)Concentration1(2)Mass ANALYSES(ration (1)Concentration 1(2)Mass ANALYSES METALS,CYANI E,AND TOTAL PHENOLS 1M.Antimony, X I < 5.0 < 0.98 1 ugh lbs/Day Total(7440-36-0) 2M.Arsenic,Total X < 5.0 < 0.98 1 ug/L lbs/Day (7440-38-2) 3M.Beryllium, X < 1.0 < 0.20 1 ugh lbs/Day Total(7440-41-7) 4M.Cadmium, X 0.19 0.04 1 ug/L lbs/Day Total(7440-43-9) 5M.Chromium, X < 5.0 < 0.98 1 ug/t, lbs/Day Total(7440-473) BM.Copper,Total X 0.0500 9.81 0.04 7.41 0.02 3.10 48 mg/L lbs/Day i 7M.Lead,Total X < 2.0 < 0.39 1 Ig/L lbs/Day 4�11 l r L ,_c.� (7439-92-1) BM.Mercury,Total X < 0.00050 < 0.00 1 ug/L lbs/Day /7439-97-6) 9M.Nickel,Total X < 10 < 1.96 1 ug/L lbs/Day (7440-02-0) 10M.Selenium, X 12.1 2.37 10.6 1.96 4.46 0.69 48 - ' Total(7782.49-2) L lbs/Day 11M.Silver,Total X < 5.0 < 0.98 1 ug/L lbs/Day (7440-22-4) 12M.Thallium, X 0.00080 0.2 1 mg/L lbs/Day ) i' 1 Total(7440-28-0) �/ r C 13M.Zinc,Total X 0.013 2.55 1 mg/L lbs/Day (7440-66-6) 14M.Cyanide, X < 0.010 < 1.96 1 mg/L Ibs/Day Total(57-12-5) a 15M.Phenols, X 0.0050 1.0 1 mg/L lbs/Day Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X , < 0.0100 l < 0.0001 1 1 ] ng/L l lbs/Day l Dioxin(1764-01-6) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 002 Alien Steam Station 1.POLLUTANT 2.MARK•X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-!cob- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ad sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES(ration (1)Concentration J(2)Mass ANALYSES GC/MS FRACTION-VOLATILE C MPOUNDS 1V.Acrolein X < 5.0 < 0.98 1 tg/L lbs/Day (107-02-8) 2V.Acrylonirile X < 5.0 < 0.98 1 ug/L lbs/Day (107-13-1) 3V.Benzene X < 2.0 < 0.39 1 t1g/L lbs/Day (71-43-2) 4V.Bis(Chimp- methyl)Ether X (542-88-1) 5V.Bromofonn X < 2.0 < 0.39 1 u9/L lbs/Day (75-25-2) BV.Carbon Tetrachloride X < 2.0 < 0.39 1 tg/L Ibs/Day (56-23-5) 7V.Chbrobenzene X < 2.0 < 0.39 1 ugh Nts/Day (108.90.7) 8V.Chlorodi- bromomethane X < 2.0 < 0.39 1 1g/L lbs/Day (124-48-1) 9V.Chloroethane X < 2.0 < 0.39 1 ugh Ibs/Day (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 5.0 < 0.98 1 ug/L lbs/Day /110-75-8) 11V.Chloroform X < 2.0 < 0.39 1 WA- lbs/Day (67-66-3) 12V.Dichloro- bromomethane X < 2.0 < 0.39 1 ug/L lbs/Day (75-27-4) 13V.Dichloro- difluoromethane X < 2.0 < 0.39 1 ug/L lbs/Day (75.51-8) 14V.1,1-Dichloro- X < 2.0 < 0.39 1 MA- lbs/Day ethane(75-34-3) 15V.1,2-Dichbro- X < 2.0 < 0.39 1 ugh lbs/Day ethane(107-06-2) _ 16V.1,1-Dichbro- X < 2.0 < 0.39 1 tg/L lbs/Day ethylene(75-35-4) _ 17V.1,2-Dichloro- X < 2.0 < 0.39 1 tglL ' Ibs/Day propane(78-87-5) 18V.1,3-Dichloro- X < 2.0 < 0.39 1 lg/L Ibs/Day propylene(542-75-6) 19V.Ethylbenzene X < 2.0 < 0.39 1 ug/L lbs/Day (100-41-4) 20V.Methyl X < 2.0 < 0.39 1 ug/L R1s/Day Bromide(74-83-9) 21V.Methyl X < 2.0 < 0.39 1 ug/L lbs/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 002 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. ere- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab• (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ad sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration GC/MS FRACTION-V LATILE C MPOUNDS(continued) �(2)Mass ANALYSES(ration (1)Concentration 1(2)Mass ANALYSES 22V.Methylene X < 2.0 < 0.39 1 ug/L lbs/Day Chloride(75-09-2) 23V.1,1,2,2-Tetra- chloroethane X < 2.0 < 0.39 1 ugh lbs/Day (79-34-5) 24V.Tetrachloro- X < 2.0 < 0.39 1 ugh lbs/Day ethylene(127-18-4) 25V.Toluene X < 2.0 < 0.39 1 uglL bs/Day (108-88-3) 26V.1.2-Trans- Dichloroethylene X < 2.0 < 0.39 1 ug/L bs/Day (156-60-5) 27V.1,1,1-Tri- chloroethane X < 2.0 < 0.39 1 tg/L lbs/Day (71-55-6) 28V.1,1,2-Tr- chloroethane X < 2.0 < 0.39 1 ugh lbs/Day (79-00-5) 29V.Trichloro- X < 2.0 < 0.39 1 uglL bs/Day ethylene(79-01-6) 30V.Trichloro- Iluoromethane X < 2.0 < 0.39 1 ug/L bs/Day (75-69-4) - 31V.Vinyl X < 2.0 < 0.39 1 ugh lbs/Day Chloride(75-01-4) 1 GC/MS FRACTION-AOID COMPOUNDS 1A.2-Chlorophenol X < 5.4 < 1.06 1 1gIL bs/Day (95-57-8) 2A.2,4-Dichloro- X < 5.4 < 1.06 1 tglL bs/Day phenol(120-83-2) 3A.2.4-Dimethy4 X < 5.4 < 1.06 1 ugh lbs/Day Phenol(105-67-9) 4A.4.8 Din tro O X < 5.4 < 1.06 1 ugh lbs/Day Cresol(534-52-1) 5A.2,4-Dinitro- X < 27 < 5.29 1 ug/L bs/Day phenol(51-28-5) 6A.2-Nilrophanol X < 5.4 < 1.06 1 eglL lbs/Day (88-75-5) 7A.4-Nitrophenol X < 5.4 < 1.06 1 eglL lbs/Day (100-02-7) BA.P-Chloro-M- X < 5.4 < 1.06 1 tg/L lbs/Day Cresol(59-50-7) 9A.Pentaehloro- X < 5.4 < 1.06 1 ug/L bs/Day phenol(87-86-5) 10A.Phenol X < 5.4 < 1.06 1 ugh lbs/Day (108-95-2) 11A.2,4,6-Tri- chiorophenol X < 5.4 < 1.06 1 (88-06-2) ug/L lbs/Day EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 002 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Behaved a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.Acenaphthene X < 5.4 < 1.06 1 ug/L lbs/Day (83-32-9) 2B.Acenaphtytene X < 5.4 < 1.06 1 ug/L lbs/Day (208-98-b) 3B.Anthracene X < 5.4 < 1.06 1 WA- lbs/Day (120-12-7) 4B.Benzidine X < 54 < 10.59 1 ug/L lbs/Day (92-87-5) 58.Benzo(a) Anthracene X < 5.4 < 1.06 1 ug/L lbs/Day (56-55-3) 68.Benzo(a) X < 5.4 < 1.06 1 ugh Ibs/Day Pyrene(50-32-8) 7B.3,4-Benzo- Buoranthene X < 5.4 < 1.06 1 ug/L lbs/Day (205-99-2) Be.Benzo(phi) X < 5.4 < 1.06 1 ug/L Ibs/Day Perylene(191-24-2) 9B.Benzo(k) Fluoranthene X < 5.4 < 1.06 1 ug/L lbs/Day (207-08-9) 108.Bin(2-Chloro- ethozyi)Methane X < 5.4 < 1.06 1 ugh lbs/Day 1111-91-1) 11B.Bis(2-Chloro- ethyl)Ether X < 5.4 < 1.06 1 ug/L lbs/Day (111.44.4) 12B.Bis(2-Chkxoiso- propyl)Ether X < 5.4 < 1.06 1 ug/L lbs/Day (108-60-1) 13B.Bin(2-Ethyl hexyl)Phehalate X < 5.4 < 1.06 1 ug/L lbs/Day (117-81-7) 148.4-Bromo- phenyl Phenyl X < 5.4 < 1.06 1 WA. lbs/Day Ether(101-55-3) 158.Butyl Benzyl X < 5.4 < 1.06 1 ug/L lbs/Day Phthalate(85-68-7) 168.2-Chloro- naphthalene X < 5.4 < 1.06 1 Ig/L lbs/Day (91-58-7) 17B.4-Chtoro- phenyl Phenyl X < 5.4 < 1.06 1 ug/L lbs/Day Ether(7005-72-3) 18B.Chrysene X < 5.4 < 1.06 1 AA lbs/Day (218-01-9) 19B.Dibenzo(a,h) Anthracene X < 5.4 < 1.06 1 t1g/L Ibs/Day (53-70-3) 208.1,2-Dichtoro- X < 2.0 < 0.39 1 tg/L lbs/Day benzene(95.50.1) 21B.1,3-Dichloro- X < 2.0 < 0.39 1 ugA- Ibs/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 002 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre- crab- (if available) (if available) d.NO.OF a.Cancan- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tratlon (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION- SE/NEUT2AL COMPOUNDS(continued) 228.1,4-Dichloro- X < 2.0 < 0.39 1 ug/L lbs/Day benzene(108-48-7) 238.3,3-Dichloro- benzidine X < 5.4 < 1.06 1 ug/L lbs/Day (91-94-1) 248.Diethyl Phthalate X < 5.4 < 1.06 1 u9/L lbs/Day (84-66-2) 25B.Dimethyl Phthalate X < 5.4 < 1.06 1 tg/L lbs/Day (131-11-3) 268.Di-N-Butyl Phthalate X < 5.4 < 1.06 1 ug/L lbs/Day (84-74-2) 278.2,4-Dmitro- X < 5.4 < 1.06 1 ug/L lbs/Day toluene(121-14-2) 268.2,6-Dinitro- X < 5.4 < 1.06 1 ug/L lbs/Day toluene(606-20-2) 298.Di-N-Oetyl Phthalate X < 5.4 < 1.06 1 ug/L lbs/Day (117-84-0) 308.1,2-Diphenyl- hydrazine(as Azo- X < 5.4 < 1.06 1 ug/L lbs/Day penzene)(122-66-7) 318.Fluoranthene X < 5.4 < 1.06 1 ug/L lbs/Day (206-44-0) 328.Fluorene X < 5.4 < 1.06 1 ug/L lbs/Day (86-73-7) 338.Hexachloro- X < 5.4 < 1.06 1 ug/L lbs/Day benzene(118.74-1) 348.Hexa- chlorobutadiene X < 5.4 < 1.06 1 ug/L lbs/Day (87-68-3) 358.Hexachlero- cyclopentadiene X < 5.4 < 1.06 1 ug/L lbs/Day (77-474) 388.Hexachloro- X < 5.4 < 1.06 1 ug/L lbs/Day ethane(67-72-1) 378.Indeno (1.2,3-cd)Pyrene X < 5.4 < 1.06 1 ug/L lbs/Day (193-39-5) 38B.Isophorone X < 5.4 < 1.06 1 ug/L lbs/Day (78-59-1) _ _ 39B.Naphthalene X < 5.4 < 1.06 1 ug/L lbs/Day (91-20-3) _ 408.Nitrobenzene X < 5.4 < 1.06 1 ugh lbs/Day (98-95-3) 41B.N-Nitro- sodimethyamine X < 5.4 < 1.06 1 ug/L lbs/Day (62-75-9) 428.N-Nitrosodi- N-Propylamine X < 5.4 < 1.06 1 KO- lbs/Day (621-64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 002 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES!ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 438.N-Nitro- sodiphenylamine X < 5.4 < 1.06 1 / ugh lbs/Day (88-30-8) 44B.Phenanthrene X < 5.4 < 1.06 1 ug/L lbs/Day (85-01-8) • 45B.Pyrene X < 5.4 < 1.06 1 u94- lbs/Day (129-00-0) 46B.1,2,4-Td- chlorobenzene X < 2.0 < 0.39 1 ug/L lbs/Day (120.82.1) GC/MS FRACTION-P`STICIDES< 1 P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84.8) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) SP.della-BHC X (319-88-8) 8P.Chlordane X (57.74-9) 7P.4,4'-DOT X (50-29-3) BP.4,4'-DDE X (72-55-9) 9P.4,4'-ODD X (72-54-8) 10P.Dielddn X (60-57-1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endesulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) J � 18P.Heptachlor X (78-44-8) EPA Form 3510-2C(Rev.2.85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 002 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (d available) d.NO.OF a.Concern b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 2 GC/MS FRACTION-PESTI IDES(continued) �()Mass (1)Concentration 1(2)Mass ANALYSES tration (1)coneeMratlon _1(2)Mass ANALYSES 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.25 < 0.05 1 uglL lbs/day (53469-21.9) 19P.PCB-1254 X < 0.25 < 0.05 ' (11097.89.1) 1 • ug/L Ib5/day 20P.PCB-1221 X < 0.25 < 0.05 1 ug/L lbs/day (11104-28-2) 21P.PCB-1232 X < 0.25 < 0.05 (11141-16-5) 1 Ilg/L lbs/day 22P.PCB-1248 X < 0.25 < 0.05 (12672-29-6) 1 tlg/L lbs/day 23P.PCB-1260 X < 0.25 < 0.05 ' (11096-82-5) 1 IbS/day 24P.PCB-1016 X < 0.25 < 0.05 1 ug/L lbs/day (12674-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS NC0004979 Allen Steam Station OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 003 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES ration (1)Concentration (2)Mass ANALYSES e.Biochemical Oxygen < 2.0 < 75.1 1 mg/L lbs/Day Demand 0300) b.Chemical Oxygen < 10 < 375.5 1 mg/L lbs/Day Demand(COD) c.Total Organic 1.4 52.6 1 mg/L lbs/Day Carbon(TOC) d.Total Suspended 10 375.5 1 mg/L Ibs/Day Solids(TSS) e.Ammonia(as N) < 0.10 < 3.8 1 mg/L lbs/Day f.Flow VALUE VALUE VALUE VALUE 4.5 4.5 4.5 101 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (wider) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 28.57 1 DEGREES CELSIUS .pH MINIMUM MAXIMUM MINIMUM MAXIMUM 7.13 1 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. " 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass _b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES ration (1)Concentration (2)Mass ANALYSES a.Bromide X < 0.20 < 7.5 1 mg/L lbs/Day (24959-87-9) b.Chlorine, X < 0.050 < 1.9 1 mg/L lbs/Day Total Residual _ e.Color X 20 N/A N/A N/A 1 Std.Units N/A N/A 1.Fein X < 2 < N/A N/A N/A 1 Colonies N/A N/A ;otifonn /100 ml e.Fluoride X < 0.10 < 3.8 1 ' mg/L lbs/Day (18984-48-8) _ _ F.Nitrate- X 0.18 6.8 1 mg/L Ibs/Day Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 003 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen, Total Organic X 0.33 12.4 1 mg/L lbs/Day (as N) k.Oil and Grease X < 5.0 < 187.8 1 mg/L lbs/Day i.Phosphorous (as P),Total X 0.020 0.8 1 mg/L lbs/Day (7723-14-0) j.Radioactivity (1)Alpha, Total X < 5.0 < N/A N/A N/A 1 pCilL N/A N/A (2)Beta, Total X < 5.0 < N/A N/A N/A 1 pCi/L N/A N/A (3)Radium, Total X < 1.0 < N/A N/A N/A 1 pCi/L N/A N/A (4)Radium 226,Total X < 1.0 < N/A N/A N/A 1 pCi/L N/A N/A k.Sulfate (as SO4) X 5.3 199.0 1 mg/L lbs/Day (14808-79-8) I.Sulfide (as S) X < 1.0 < 37.6 1 mg/L lbs/Day m.Sulfite (as So3) X < 1.0 < 37.6 1 mg/L lbs/Day /14265-45-3) , n.Surfactants X < 0.050 < 1.9 1 mg/L lbs/Day o.Aluminum, Total X 0.34 12.8 1 mg/L lbs/Day (7429.90.5) , p.Barium, Total X < 0.050 < 1.9 1 mg/L lbs/Day (7440-39-3) q.Boron, Total X 0.066 2.5 1 mg/L lbs/Day (7440-42-8) r.Cobalt, Total X < 0.020 < 0.8 1 mg/L lbs/Day (7440-48-4) s.Iron,Total (7439-89-6) X 0.84 31.4 1 mg/L lbs/Day I.Magnesium, Total X 2.0 75.1 1 mg/L lbs/Day (7439-95-4) u.Molybdenum, Total X < 0.020 < 0.8 1 mg/L lbs/Day (7439-98-7) v.Manganese. Total X 0.055 2.1 1 mg/L lbs/Day (7439-96-5) w.Tin.Total (7440-31-5) X < 0.010 < 0.4 1 mg/L lbs/Day v.Titanium, Total X < 0.050 < 1.9 1 mg/L lbs/Day (744032-6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 003 Alien Steam Station PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. ass- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration ass tration METALS,CYANI E,AND TOTAL PHENOLS 1(2)M ANALYSES (1)Concentration 1(2)Mass ANALYSES 1 M.Antimony, X < 5.0 < 0.19 1 uglL Ibs/Day Total(7440-36-0) 2M.Arsenic,Total X < 5.0 < 0.19 1 tg/L lbs/Day (7440-38-2) 3M.Beryllium, X < 1.0 < 0.04 1 ug/L lbs/Day Total(7440-41-7) 4M.Cadmium, X < 0.10 < 0.00 1 ug/L lbs/Day Total(7440-43-9) SM.Chromium, X < 5.0 < 0.19 1 ug/L lbs/Day Total(7440-47-3) BM.Copper.Total X 0.0099 0.37 1 mg/L lbs/Day (7440-50-8) 7M.Lead,Total X < 2.0 < 0.08 1 ug/L lbs/Day (7439.92.1) 8M.Mercury,Total X 0.0016 0.00 1 tg/L lbs/Day ,(7439-97-6) 9M.Nickel,Total X < 10 < 0.38 1 ug/L lbs/Day (7440-02-0) 10M.Selenium, X < 1.00 < 0.04 1 tg/L lbs/Day Total(7782-49-2) 11M.Sever,Total X < 5.0 < 0.19 1 ug/1- lbs/Day (7440-22-4) 12M.Thallium, X < 0.00050 < 0.0 1 mg/L lbs/Day Total(7440-28-0) 13M.Zinc,Total X < 0.010 < 0.38 1 mg/L lbs/Day (7440-8(3.6) 14M.Cyanide, X < 0.010 < 0.38 1 mg/L lbs/Day Total(57-12-5) 15M.Phenols, X < 0.0050 < 0.2 1 mg/L lbs/Day Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X < 0.0100 1 < 0.0001 I 1 I ng/L I lbs/Day Dioxin(1764-01-6) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 003 Allen Steam Station 1.POLLUTANT 2.MARK•X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- cab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration J(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS 1V.Acroletn X < 5.0 < 0.19 1 uglL lbs/Day (107-02-8) 2V.Acrylonarile X < 5.0 < 0.19 1 uglL lbs/Day (107-13-1) 3V.Benzene X < 2.0 < 0.08 1 ug/L lbs/Day (71-43-2) 4V.Bis(Chloro- methyl)Ether X (542-88-1) 5V.Bromoform X < 2.0 < 0.08 1 ug&L lbs/Day (75-25-2) 6V.Carbon Tetrachloride X < 2.0 < 0.08 1 ug/L lbs/Day (56-23-5) 7V.Chlorobenzene X < 2.0 < 0.08 1 ug/L bs/Day (108-90-7) BV.Chlorodi- bromomethane X < 2.0 < 0.08 1 ug/L lbs/Day (124-48-1) 9V.Chloroethane X < 2.0 < 0.08 1 ug/L lbs/Day (75-00-3) 10V.2-Chloro- sthylvinyl Ether X < 5.0 < 0.19 1 ug/L lbs/Day /(110-75-8) 11v.Chloroform X < 2.0 < 0.08 1 ug/L lbs/Day (67-68-3) 12V.Dichloro- bromomethane X < 2.0 < 0.08 1 ug/L lbs/Day (75-27-4) 13V.Dichloro- dilluoromethane X < 2.0 < 0.08 1 ug/L lbs/Day (75-51-8) 14V.1,1-Dichloro- X < 2.0 < 0.08 1 ug/L bs/Day ethane(75-34-3) 15V.1,2-Dichloro- X < 2.0 < 0.08 1 ug/L lbs/Day ethane(107-06-2) 16V.1,1-Dichloro- X < 2.0 < 0.08 1 ugA. lbs/Day ethylene(75.35.4) . 17V.1,2-Dichloro- X < 2.0 < 0.08 1 ug/L bs/Day propane(78-87-5) . 18V.1,3-Dichloro- X < 2.0 < 0.08 1 ug/L bs/Day Propylene(542-75-6) 19V.Ethylbenzene X < 2.0 < 0.08 1 ugh lbs/Day (100-41-4) _ _ 20V.Methyl X < 2.0 < 0.08 1 ug/L lbs/Day Bromide(74-83-9) 21V.Methyl X < 2.0 < 0.08 1 ug/L lbs/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 N00004979 003 Allen Steam Station ,1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. ..re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Icab- (if available) (if available) d.NO.OF a.Cotten- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tratlon (1)Concentration I(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS(continued) 22V.Methylene X < 2.0 < 0.08 1 ugh lbs/Day Chloride(75-09-2) 23V.1,1,2,2-Tetra- chloroethane X < 2.0 < 0.08 1 ug/L lbs/Day (79-34-5) 24V.Tetrachloro- X < 2.0 < 0.08 1 ug/L lbs/Day ethylene(127-18-4) 25V.Toluene X < 2.0 < 0.08 1 ug/L. lbs/Day (108-88-3) 26V.1,2-Trans- Dichloroethylene X < 2.0 < 0.08 1 ugh lbs/Day (156-60-5) 27V.1,1,1-Tri- chloroethane X < 2.0 < 0.08 1 ugh lbs/Day (71-55-6) 28V.1,1,2-T6- chloroethane X < 2.0 < 0.08 1 ugh lbs/Day (79-00-5) 29V.Trichloro- X < 2.0 < 0.08 1 ugh lbs/Day ethylene(79-01-6) 30V.Trichloro- Buoromethane X < 2.0 < 0.08 1 ugh lbs/Day (75-69-4) 31V.Vinyl X < 2.0 < 0.08 1 ugh lbs/Day Chloride(75-01-4) GC/MS FRACTION-AeID COMPOUNDS 1A.2-Chlorophenol X < 5.5 < 0.21 1 ug/L lbs/Day (95-57-8) 2A.2,4-Dichloro- X < 5.5 < 0.21 1 ug/L lbs/Day phenol(120-83-2) 3A.2,4-Dimethyl- X < 5.5 < 0.21 1 ug/L lbs/Day phenol(105.67.9) 4A.4,6-Dinitro-0- X < 5.5 < 0.21 1 ug/L lbs/Day Cresol(534-52-1) 5A.2,4-Dinitro- X < 27 < 1.01 1 ug/L lbs/Day phenol(51-28-5) 3A.2-Nitrophanol X < 5.5 < 0.21 1 ug/L lbs/Day (88-75-5) 7A.4-Nilrophenol X < 5.5 < 0.21 1 uaJL lbs/Day (100-02-7) BA.P-Chloro-M- X < 5.5 < 0.21 1 ug/L lbs/Day Cresol(59-50-7) _ 9A.Pentachloro- X < 5.5 < 0.21 1 ug/L lbs/Day phenol(87-88-5) 10A.Phenol X < 5.5 < 0.21 1 tg/L lbs/Day (108-95-2) _ 11 A.2,4,8-Tri- Chlorophenol X < 5.5 < 0.21 1 ug/L lbs/Day "88-08.2) - EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 003 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 18.Acenaphthene X < 5.5 < 0.21 1 ug/L Ibs/Day (83-32-9) 28.AcenapMylene X < 5.5 < 0.21 1 ug/L lbs/Day (208-96-8) 3B.Anthracene X < 5.5 < 0.21 1 Ig/L lbs/Day (120-12-7) 4B.Benzidine X < 55 < 2.07 1 ug/L lbs/Day (92-87-5) 58.Benzo(a) Anthracene X < 5.5 < 0.21 1 Ug/L lbs/Day (56-55-3) 6B.Benzo(a) X < 5.5 < 0.21 1 tg/L lbs/Day Pyrene(50-32-8) 7B.3,4-Benzo- tluoranthene X < 5.5 < 0.21 1 ug/L lbs/Day (205-99-2) BB.Benzo(ph) X < 5.5 < 0.21 1 ug/L lbs/Day Perylene(191-24-2) 98.Benzo(k) Fluoranthene X < 5.5 < 0.21 1 Ig/L lbs/Day (207-08-9) 10B.Bis(2-Chbro- ethoxy)Methane X < 5.5 < 0.21 1 ug/L lbs/Day /(11 t-91-1) , 11B.Bis(2-Chloro- ethy)Ether X < 5.5 < 0.21 1 ug/L lbs/Day (111-44-4) 128.Bis(2-Chlomiso- propy)Ether X < 5.5 < 0.21 1 ug/L lbs/Day (108-60-1) 138.Bis(2-Ethyl- hazy)Phehalate X < 5.5 < 0.21 1 ug/L lbs/Day (117-81-7) 148.4-Bromo- phenyl Phenyl X < 5.5 < 0.21 1 ug/L lbs/Day Ether(101-55-3) 158.Butyl Benzyl X < 5.5 < 0.21 1 ugh lbs/Day Phthalate(85-68-7) 168.2-Chloro- naphthalene X < 5.5 < 0.21 1 ug/L lbs/Day (91-58-7) 17B.4-Chkxo- phenyl Phenyl X < 5.5 < 0.21 1 ug/L lbs/Day Ether(7005-72-3) _ 168.Chrysene X < 5.5 < 0.21 1 ug/L lbs/Day (218-01-9) 198.Dibenzo(a.h) Anthracene X < 5.5 < 0.21 1 ug/L lbs/Day (53-70-3) 20B.12-Diehioro- X < 2.0 < 0.08 1 ug/L lbs/Day benzene(95-50-1) 21B.1,3-Dichtoro- X < 2.0 < 0.08 1 ug/L lbs/Day benzene(541.73.1) _ EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 N00004979 003 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT - 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre-'c.ab- (if available) (if available) d.NO.OF a.Canon- b.Mass d.NO.OF ed sent sent (1)Concentration (2)Mass (1)Concentration 1(2)Mass (1)Concentration l(2)Mass ANALYSES tration (1)Concentration l(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUND (continued) 228.1,4-Dichloro- X < 2.0 < 0.08 1 ugh lbs/Day benzene(106.46.7) 238.3,3-Dichloro- benzidine X < 5.5 < 0.21 1 ug/L lbs/Day (91-94-1) 248.Diethyl Phthalate X c 5.5 < 0.21 1 ugh lbs/Day (84-66-2) 258.Dimethyl Phthalate X < 5.5 < 0.21 1 ugh lbs/Day (131-11-3) 26B.Di-N-Butyl Phthalate X < 5.5 < 0.21 1 ugh lbs/Day (84-74-2) 2713.2,4-Dinitro- X < 5.5 < 0.21 1 ug/L lbs/Day toluene(121-14-2) 28B.2,6-Dinitro- X < 5.5 < 0.21 1 ugh - lbs/Day toluene(606-20-2) 298.DI-N-Octyl _ Phthalate X < 5.5 < 0.21 1 u9/L lbs/Day (117-84-0) 3013 i 2 Dphenyl- hydrazine(as Azo- X < 5.5 < 0.21 1 ug/L lbs/Day /benzene)(122-66-7) 318.Fluoranthene X < 5.5 < 0.21 1 ug/L lbs/Day (206-44-0) 328.Fluorene X < 5.5 < 0.21 1 ug/L lbs/Day (86-73-7) 338.Hezachloro- X < 5.5 < 0.21 1 ug/L lbs/Day benzene(116-74-1) 348.Heza- chiorobutadiene X < 5.5 < 0.21 1 ugh lbs/Day (87-68-3) 358.Hezachloro- cyclopentediene X < 5.5 < 0.21 1 ugh lbs/Day (77.47-4) 366.Hexadrloro- X < 5.5 < 0.21 1 ugh lbs/Day ethane(87-72-1) 378.Indeno (1,2.3-cd)Pyrene X < 5.5 < 0.21 1 ug/L lbs/Day (193-39-5) 3813.Isophorone X < 5.5 < 0.21 1 ugh lbs/Day (78.59-1) 398.Naphthalene X < 5.5 < 0.21 1 ug/L lbs/Day (91-20-3) 408.Nitrobenzene X < 5.5 < 0.21 1 ug/L lbs/Day (98-95-3) 418.N-Nitro- . sodimethylamine X < 5.5 < 0.21 1 ug/L lbs/Day (62-75-9) 428.N-Nitrosodi- N-Propylamine X < 5.5 < 0.21 1 ug/L lbs/Day (621-64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 003 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT _ 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION- SE/NEUTRAL COMPOUNDS(continued) 43B.N-Nitro- sodiphenylamine X < 5.5 < 0.21 1 ug/L lbs/Day (86-30-6) 448.Phenanthrene X < 5.5 < 0.21 1 ug/L lbs/Day (85-01-8) 45B.Pyrene X < 5.5 < 0.21 1 ug/L lbs/Day (129-00-0) • 466.1,2,4-Tri- chlorobenzene X < 2.0 < 0.08 1 ug/L lbs/Day (120-82-1) GC/MS FRACTION-PkSTICIDES` 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.delta-BHC X (319-86-8) BP.Chlordane X (57-74-9) 7P.4,4'-DDT X (50-29-3) BP.IA.-DOE X (72-55-9) 9P.4,4'-DOD X (72-54-8) 10P.Dieldrin X (60.57-1) 11P.alpha-Endosulfan X :115.29.7) 12P.beta-Endosulfan X :115-29-7) 13P.Endosulfan Sulfate X 1031-07-8) 4P.Endrin X 72-20-8) it SP.Endrin 1Aldehyde X 7421-93-4) (IP.Heptachlor X • 76.44.8) 1 EPA Form 3510-2C(Rev.2.85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 003 Men Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-PESTI IDE (continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.26 < 0.01 1 ugh lbs/day (53489.21-9) 19P.PCB-1254 X < 0.26 < 0.01 1 ugh lbs/day (11097.69-1) - 20P.PCB-1221 X < 0.26 < 0.01 1 ugh lbs/day (11104-28-2) 21P.PCB-1232 X < 0.26 < 0.01 1 t1g/L lbs/day (11141-16-5) 22P.PCB-1248 X < 0.26 < 0.01 1 ugh lbs/day (12672-29-6) 23P.PCB-1260 X < 0.26 < 0.01 1 ` ugh lbs/day (11096-82-5) - 24P.PCB-1016 X < 0.26 < 0.01 1 11g/L It1s/day (12674-11-2) 25P.Toxapbane X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS NC0004979 Allen Steam Station OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 004 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE 'a.LONG TERM AVG.VALUE (d available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass �(1)Concentration (2)Mass ANALYSES(ration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen < 2.0 < 108.5 1 mg/L lbs/Day Demand(BOD) b.Chemical Oxygen < 10 < 542.4 1 mg/L lbs/Day Demand(COD) c.Total Organic 1.8 97.6 g 1 mg/L lbs/Day Carbon(IOC) d.Total Suspended 6.0 g 325.5 1 mg/L lbs/Day Solids(TSS) e.Ammonia(as N) < 0.10 < 5.4 1 mg/L lbs/Day f.Flow VALUE VALUE VALUE VALUE 6.5 6.5 6.5 101 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (winter) _ DEGREES CELSIUS _ i.Temperature VALUE VALUE VALUE VALUE (summer) 25.81 _ 1 DEGREES CELSIUS '.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 7.1 7.2 2 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X < 0.20 < 10.8 1 mg/L lbs/Day '24959-67-9) '.Chlorine, X < 0.050 < 2.7 1 mg/L lbs/Day Total Residual Color X 20 N/A N/A N/A 1 Std.Units N/A N/A Fecal X 4 N/A N/A N/A 1 Colonies N/A N/A otform /100 ml �Fluoride X < 0.10 < 5.4 1 mg/L lbs/Day 16984-48.8) [.Nitrate- X 0.18 9.8 1 mg/L lbs/Day ,Nitrite(as N) ' EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT N00004979 004 Alien Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES taboo (1)Concentration (2)Mass - ANALYSES g.Nitrogen, Total Organic X 0.28 15.2 0.53 28.7 0.31 16.8 6 mg/L lbs/Day (as N) h.Oil and Grease X < 5.0 < 271.2 < 5 < 271.2 < 5 < 271.2 6 mg/L lbs/Day .Phosphorous (as P),Total X 0.021 1.1 0.11 6.0 0.043 2.3 6 mg/L lbs/Day m23-14-0) I.Radioactivity (1)Alpha. Total X < 5.0 < N/A N/A N/A 1 pC/L N/A WA (2)Beta, Total X < 5.0 < N/A N/A N/A 1 pCilL N/A N/A (3)Radium, Total X < 1.0 < N/A N/A N/A 1 pCi/L N/A N/A (4)Radium 228,Total X 0.80 N/A N/A N/A 1 pCi/L N/A N/A k.Sulfate (as SO4) X 6.9 374.3 1 mg/L lbs/Day (14808-79-8) .Sulfide (as S) X < 1.0 < 54.2 1 mg/L lbs/Day m.Sulfite (as SO3) X < 1.0 < 54.2 1 mg/L lbs/Day /(14265-45-3) n.Surfactants X < 0.050 < 2.7 1 mg/L lbs/Day o.Aluminum, Total X 0.18 9.8 1 mg/L lbs/Day (7429-90-5) p.Barium, Total X < 0.050 < 2.7 1 mg/L lbs/Day (7440-39-3) q.Boron, Total X 0.062 3.4 1 mg/L lbs/Day (7440-42-8) Cobalt. f Tal X < 0.020 < 1.1 1 mg/L lbs/Day ,7a440.48.4) o.Iron,Total '7439.89.6) X 0.56 30.3 1 mg/L lbs/Day .Magnesium, Total X 2.1 113.9 1 mg/L lbs/Day l,'7439.95-4) . AI.Molybdenum, Yaal X < 0.020 < 1.1 1 r439-98-7) mg/L lbs/Day .Manganese, oral X 0.078 4.2 1 mg/L lbs/Day 7439.96.5) iff.Tin,Total " ,7440-31.5) X < 0.010 < 0.5 1 mg/L lbs/Day `r.Titanium, Total X < 0.050 < 2.7 1 mg/L lbs/Day 7440.32.6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 004 Allen Steam Station PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) - AND CAS NO. axe- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ad sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration METALS,CYANIDE,AND T TAL PHENOLS 1(z)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES 1M.Antimony, X < 5.0 < 0.27 1 ug/L lbs/Day Total(7440.38-0) 2M.Arsenic,Total X < 5.0 < 0.27 1 ug/L lbs/Day (7440.38-2) 3M.Beryllium, X < 1.0 < 0.05 1 41- lbs/Day Total(7440.41-7) 4M.Cadmium, X < 0.10 < 0.01 1 ug/L lbs/Day Total(7440-43-9) 5M.Chromium, X < 5.0 < 0.27 Total(7440-47-3) 1 lbs/Day BM.Copper,Total X < 0.0050 < 0.27 1 mg/L lbs/Day (7440-50-8) 7M.Lead,Taal X < 2.0 < 0.11 1 ug/L lbs/Day (7439-92-1) BM.Mercury,Total X 0.00502 0.00 /(7439-97-6) 1 11g/L lbs/Day 9M.Nickel,Total X < 10 < 0.54 1 ug/L lbs/Day (7440-02-0) 10M.Selenium, X < 1.0 < 0.05 Total(7782.49-2) 1 lbs/Day 11M.Silver,Total X < 5.0 < 0.27 1 ug/L lbs/Day (7440-22-4) 12M.Thallium, X < 0.00050 < 0.0 1 mg/L lbs/Day Total(7440-28-0) 13M.Zinc,Taal X < 0.010 < 0.54 1 mg/L lbs/Day (7440-66-6) 14M.Cyanide, X < 0.010 < 0.54 1 mg/L lbs/Day Total(57-12-5) 15M.Phenols, X 0.0076 0.4 1 mg/L lbs/Day Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenso P X < 0.0100 1 < 0.0001 1 1 1 ng/L I lbs/Day I Dioxin(1764-01-6) EPA Form 3510.2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 004 Alien Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed 'a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1 V.Acrolein X < 5.0 < 0.27 1 ug/L lbs/Day (107.02-8) 2V.Acrylonitrite X < 5.0 < 0.27 1 ug/L lbs/Day (107-13-1) 3V.Benzene X < 2.0 < 0.11 1 ug/L lbs/Day (71-43-2) 4V.Bis(Chloro- methyl)Ether X (542-88-1) 5V.Bromoform X < 2.0 < 0.11 1 ug/L lbs/Day (75-25-2) BV.Carbon Tetrachloride X < 2.0 < 0.11 1 ug/L lbs/Day (56-23-5) - 7V.Chlorobenzene X < 2.0 < 0.11 1 ug/L Ibs/Day (toe-90-7) BV.Chlorodi- bromomethane X < 2.0 < 0.11 1 ug/L lbs/Day (124-8-1) 9V.Chloroethane X < 2.0 < 0.11 1 ug/L lbs/Day (75-00-3) 10V.2-Chtoro- ethylvinyl Ether X < 5.0 < 0.27 1 ug/L lbs/Day /110-75-8) 11V.Chloroform X < 2.0 < 0.11 1 ug/L Ibs/Day (87-66-3) 12V.Dichoro- bromomethane X < 2.0 < 0.11 1 ug/L lbs/Day (75-27-4) 13V.Dichloro- difluoromethane X < 2.0 < 0.11 1 ug/L lbs/Day (75-51-8) 14V.1,1-Dichroro- X < 2.0 < 0.11 1 uglL lbs/Day ethane(75-34-3) 15V.1,2-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day ethane(107-06-2) 18V.1,1-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day ethylene(75-35-4) 17V.1,2-Dichoro- X < 2.0 < 0.11 1 ug/L lbs/Day propane(78-87-5) 18V.1,3-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day propylene(542-75-6) 19V.Ethylbenzene X < 2.0 < 0.11 1 ug/L lbs/Day (100-41-4) 20V.Methyl X < 2.0 < 0.11 1 ug/L lbs/Day Bromide(74-83-9) 21V.Methyl X < 2.0 < 0.11 1 tglL lbs/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 004 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Behoved a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (8 available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES(ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS(continued) 22V.Methylene X < 2.0 < 0.11 1 ug/L lbs/Day Chloride(75-09-2) 23V.1,1,2,2-Tetra- chioroethane X < 2.0 < 0.11 1 ug/L lbs/Day (79.34-5) 24V.Tetrachloro- X < 2.0 < 0.11 1 ug/L lbs/Day ethylene(127-18-4) 25V.Toluene X < 2.0 < 0.11 1 ug/L lbs/Day (108.88-3) 26V.1,2-Trans- Dichloroethylene X < 2.0 < 0.11 1 ug/L lbs/Day (156-60-5) 27V.1,1,1-Tri- chloroethane X < 2.0 < 0.11 1 ugh lbs/Day (71-55-6) -28V.1,1,2-Tri- chloroethane X < 2.0 < 0.11 1 ug/L lbs/Day (79-00-5) 29V.Trichloro- X < 2.0 < 0.11 1 ug/L lbs/Day ethylene(79.01.6) 30V.Trichloro- 1luoromethane X < 2.0 < 0.11 1 ug/L lbs/Day (75-69-4) _31V.Vinyl X < 2.0 < 0.11 - 1 u - ---ug/L • lbs/Day - -_ - Chloride(75-01-4) GC/MS FRACTION-ACID COMPOUNDS 1A.2-Chlorophenol X < 5.3 < 0.29 1 tg/L lbs/Day (95-57-8) 2A.2,4-Dichloro- X < 5.3 < 0.29 1 ug/L lbs/Day phenol(120-83-2) 3A.2,4-Dimethy$- X < 5.3 < 0.29 1 tg/L lbs/Day Phenol(105-67-9) 4A.4,6-Dinitro-O- X < 5.3 < 0.29 1 ug/L (bs/Day Cresol(534-52-1) 5A.2,4-Dinitro- X < 26 < 1.41 1 tg/L lbs/Day phenol(51-28-5) BA.2-Nitrophenol X < 5.3 < 0.29 1 ug/L lbs/Day (88-75-5) - 7A.4-Nitrophenol X < 5.3 < 0.29 1 tg/L lbs/Day (100-02-7) . 8A.P-Chloro-M- X < 5.3 < 0.29 1 ug/L lbs/Day Cresol(59-50-7) - 9A.Pentachloro- X < 5.3 < 0.29 1 ug/L lbs/Day phenol(87-86-5) 10A.Phenol X < 5.3 < 0.29 1 ug/L lbs/Day (108-95-2) 11A.2,4,6-Tri- chlorophenol X < 5.3 < 0.29 1 ug/L lbs/Day I(88-06-2) _ EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 004 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if evadable) quir- b.pre- cab- (1 available) (it available) d.NO.OF a Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES(ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.AcenapMhene X < 5.3 < 0.29 1 ug/L lbs/Day (8332.9) 28.Acenaphtylene X < 5.3 < 0.29 1 tg/L lbs/Day (208-98-8) 38.Anthracene X < 5.3 < 0.29 1 ug/L lbs/Day (120-12-7) 4B.Benzidtne X < 53 < 2.87 1 ug/L lbs/Day (92-87-5) SB.Benzo(a) Anthracene X < 5.3 < 0.29 1 ug/L lbs/Day (56-55-3) 58.Benzo(a) X < 5.3 < 0.29 1 ug/L lbs/Day Pyrene(50-32-8) 7B.3,4-Benzo- Iluoranthene X < 5.3 < 0.29 1 ug/L lbs/Day (205-99-2) 88.Benzo(ph) X < 5.3 < 0.29 1 ug/L bs/Day Perylene(191-24-2) 98.Benzo(k) FluoraMhene X < 5.3 < 0.29 1 ug/L lbs/Day (207-08.9) 10B.Bis(2-Chioro- ethoxy)Methane X < 5.3 < 0.29 1 ug/L lbs/Day /(111-91-1) 11B.Bis(2-Chloro- ethy)Ether X < 5.3 < 0.29 1 ug/L lbs/Day (111-4/-4) 128.Bis(2-Chioroiso- propyl)Ether X < 5.3 < 0.29 1 ug/L lbs/Day (108-80-1) 13B.Bin(2-Ethyl- hexy)Phenolate X < 5.3 < 0.29 1 ug/L bs/Day (117-81-7) 148.4-Bromo- phenyl Phenyl X < 5.3 < 0.29 1 u9/L lbs/Day Ether(101-55-3) 158.Butyl Benzyl X < 5.3 < 0.29 1 ugh lbs/Day Phthalate(85-88-7) 18B.2-Chloro- naphthalene X < 5.3 < 0.29 1 ug/L lbs/Day (91-58-7) 17B.4-Chbm- phenyl Phenyl X < 5.3 < 0.29 1 ug/L lbs/Day Ether(7005-72-3) 188.Chrysene X < 5.3 < 0.29 1 ug/L lbs/Day (218-01-9) 19B.Dibenzo(air) Anthracene X < 5.3 < 0.29 1 ugh lbs/Day (53-70-3) 20B.1,2-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day benzene(95-50-1) 21B.1,3-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day benzene(541-73-1) _ EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 004 Men Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a Goner- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration GC/MS FRACTION-BASE/NEUT ALS COMPOUNDS(continued) 1(z)Mass ANALYSES taboo (1)Concentration 1(2)Mass ANALYSES 228.1,4-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day benzene(106-46-7) 238.3,3-Dichloro- benzidine X < 5.3 < 0.29 1 ug/L lbs/Day (91-94-1) 248.Diethyl Phthalate X < 5.3 < 0.29 1 ug/L rosroay (84-66-2) 258.Dimethyl Phthalate X < 5.3 < 0.29 1 ug/L lbs/Day (131-11.3) 288.Di-N-Butyl Phthalate X < 5.3 < 0.29 1 t1g/L lbs/Day (84-74-2) 278.2,4-Dinitro- X < 5.3 < 0.29 1 ug/L lbs/Day toluene(121-14-2) 288.2,6-Dinitro- X < 5.3 < 0.29 1 11g/L lbs/Day toluene(606-20-2) 298.Di-N-Octyl Phthalate X < 5.3 < 0.29 1 ug/L lbs/Day (117.84-0) 308.1,2-Dipheny$- hydrazine(as Azo- X < 5.3 < 0.29 1 ug/L lbs/Day penzene)(122-66-7) 31B.Fluoranthene X < 5.3 < 0.29 1 11g/L lbs/Day (206-44-0) 328.Fluorene X < 5.3 < 0.29 1 WA- lbs/Day (86.73.7) 338.Hexachloro- X < 5.3 < 0.29 1 ug/L lbs/Day benzene(118-74-1) 34B.Hexa- chlorobutadiene X < 5.3 < 0.29 1 ugh lbs/Day (87-68-3) 358.Hexachloro- cyclopentadiene X < 5.3 < 0.29 1 tg/L lbs/Day (77-47-4) _ 368.Hexachloro- X < 5.3 < 0.29 1 ug/L lbs/Day ethane(67-72-1) 378.Indeno (1,2,3-cd)Pyrene X < 5.3 < 0.29 1 ug/L lbs/Day (193-39-5) 388.Isophorone X < 5.3 < 0.29 1 ug/L lbs/Day (78-59-1) 398.Naphthalene X < 5.3 < 0.29 1 ug/L lbs/Day (91-20-3) 408.Nitrobenzene X < 5.3 < 0.29 1 ug/L lbs/Day (98-95-3) 418.N-Nitro- sodimethylamine X < 5.3 < 0.29 1 ug/L lbs/Day (62-75-9) 428.N-Nitrosodi N-Propytamine X < 5.3 < 0.29 1 ug/L lbs/Day (621-64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 004 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) quit- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ad sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration (1)Concentration I(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 43B.N-Nitro- sodiphenylamine X < 5.3 < 0.29 1 ug/L lbs/Day (86-30-6) 44B.Phenanthrena X < 5.3 < 0.29 1 ugh Ibs/Day (a5-o1-8) 458.Pyrene X < 5.3 < 0.29 1 ughL lbs/Day (129-00-0) 48B.1,2,4.Tri- chlerobenzene X < 2.0 < 0.11 1 ug/L lbs/Day (120-82-1) GC/MS FRACTION-PESTICIDE§ 1 P.Aldrtn X (309-00-2) 2P.alpha-BHC X (319-84-8) 3P.beta-BHC X (315.85-7) 4P.gamma-BHC X (58-89-9) 5P.delta-BHC X (319-88-8) BP.Chlordane X (57-74-9) 7P.4,4'-DDT X (50-29-3) BP.4,4'-DDE X (72-55-9) 9P.4,4'-DDD X (72-54-8) 10P.Dieldrin X (80.57-1) 11P.atpha-Endosulfan X • (115-29-7) 12P.beta-Endosulfan X (115.29.7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 18P.Heptachlor X (76-44-8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 004 Men Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (it available) quir- b.pre- c.ab- (if available) (it available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES(ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-PESTI IDE (continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.25 < 0.01 1 ug/L lbs/day (53469-21-9) 19P.PCB-1254 X < 0.25 < 0.01 1 ug/L lbs/day (11097-69-1) 20P.PCB-1221 X < 0.25 < 0.01 1 ug/L lbs/day (11104-28-2) 21P.PCB-1232 X < 0.25 < 0.01 1 ug/L lbs/day (11141-16-5) 22P.PCB-1248 X < 0.25 < 0.01 1 ug/L lbs/day (12672-29-6) 23P.PCB-1260 X < 0.25 < 0.01 1 ug/L lbs/day (11096-82-5) 24P.PCB-1016 X < 0.25 < 0.01 1 ug/L lbs/day (12674-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 EPA ID Number(copy from item I of Form 1) Form Approved.OMB No.2040-0086 Please print or type in the unshaded areas NC0004979 Approval expires 5-31-92 United States Environmental Protection Agency Form Washington,DC 20460 2F I EP4 Application for Permit to Discharge Storm Water NPDES Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application,including time for roAedving instructions,searching ex sting data soul. ,gathering and maintaining the data needed,and completing and revievving the collection of information. Send comments regarding the burden estimate, any other aspect of this oollecton of information or suggestions for improving this form,including suggestions which may increase or reduce this burden to:Chief, Information Policy Branch,PM-223,U.S.Environmental Protection Agency,401 M St,SW,Washington,DC 20460,or Director,Office of Information and Regulatory Affairs,Office of Ma ent and Budget,Wash on,DC 20503. I Outfall Location For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number D. Receiving Water (list) B. Latitude C. Longitude (name) SW 008 35 11 25 81 00 28 Catawba River SW 015 35 10 55 81 00 22 Catawba River Note: For monitoring purposes, the above outfalls representative of the remaining 15 outfalls. II. Im•rovements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. 4. Final 1. Identification of Conditions, 2.Affected Outfalls Compliance Date Agreements,Etc. number source of discharge _ 3. Brief Description of Project a.req. b. proj. B. You may attach additional sheets describing any additional water pollution(or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. III. Site Draina•e Ma. Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a topographic map Is unavailable)depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment,storage or disposal units(including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34);each well where fluids from the facility are injected underground;springs,and other surface water bodies which receive storm water discharges from the facility. EPA Form 3510-2F(Rev. 1-92) Page 1 of 3 Continued on Page 2 Continued from the Front IV. Narrative Description of Pollutant Sources A. For each outfall,provide an estimate of the area(include units)of impervious surfaces(including paved areas and building roofs)drained to the outfall,and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) (provide units) Number (provide units) (provide units) SW001 See attached supplemental SW017 information. B. Provide a narrative description of significant materials that are currently or in the past three years have been treated,stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff;materials loading and access areas;and the location, manner,and frequency in which pesticides,herbicides,soil conditioners,and fertilizers are applied. See attached supplemental information. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outfall List Codes from Number Treatment Table 2F-1 SW001 See attached supplemental information. SW017 V. Non Stormwater Discharges A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges,and that all nonstormwater discharges from these outfall(s)are identified in either an accompanying Form 2C or Form 2E application for the outfall. Name of Official Title(type or print) Signature Date Signed Steve Immel, General Manager ll 11/30/2009 Regulated Fossil Stations B. provide a description of the method used,the date of any testing, d the onsite drainage points that were directly observed during a test. Visual inspection was performed on November 29, 2009. Besides the outfall permitted under the NPDES permit for the discharge of process water, there were no non-storm water flows observed from the storm water outfalls. VI. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years,including the approximate date and location of the spill or leak,and the type and amount of material released. Within the past three years, there have not been any significant spills of hazardous substances in excess of reportable quantities set forth by Section 311 of the Clean Water Act or Section 102 of CERCLA. EPA Form 3510-2F(Rev. 1-92) Page 2 of 3 Continued on Page 3 EPA ID Number(copy from Item I of Form 1) Continued from Page 2 NC0004979 VII. Dischar.e Information A,B,C,&D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii-A,VII-B,and VII-C are included on separate sheets numbered VII-1 and VII-2. E. Potential discharges not covered by analysis- is any toxic pollutant listed in table 2F-2, 2F-3, or 2F-4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ri Yes(list all such pollutants below) X No(go to Section IX) VIII. Biolo•ical Toxicit Testin• Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ❑ Yes(list all such pollutants below) X No(go to Section IX) IX. Contact analysis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes(list the name, address, and telephone number of,and pollutants ❑ No(go to Section X) analyzed by, each such laboratory or firm below) A.Name B.Address C.Area Code&Phone No. D.Pollutants Analyzed Shealy Environmental Services 106 Vantage Point Drive 803-791-9111 Wet chemistry& West Columbia, SC 29172 metals GEL Laboratories LLC 2040 Savage Road 843-556-8171 Radiologicals Charleston, SC 29407 X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. Name&Official Title(type or print) B.Area Code and Phone No. Steve lmmel, General Manager II (704) 829-2400 Regulated Fossil Stations C.Signature D.Date Signed 11/30/2009 EPA Form 3510-2F(Rev. 1-92) Page 3 of 3 EPA ID Number(copy from Item l of Form 1) Form Approved. OMB No.2040-0086 SW008 NCO0O4979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2F) Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <4.8 mg/L I See Supplemental Information Biological Oxygen <2.0 mg/L 1 is Demand(BOD5) Chemical Oxygen 80 mg/L 1 M Demand(COD) Total Suspended 1500 mg/L 1 " Solids(TSS) Total 0.52 mg/L 1 " Nitrogen Total 0.98 mg/L 1 M Phosphorus pH Minimum Maximum Minimum Maximum 1 " 7.78 SU Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Chlorine,Total <0.1 mg/L 1 See Supplemental residual Information Chloride <1.0 mg/L 1 u Color 20 units 1 n Fluoride(16984-48-8) 0.30 mg/L 1 N Nitrate-Nitrite(as N) <0.020 mg/L 1 '• Radioactivity,alpha 21.4 13.78 1 ff total pCi/L Radioactivity,beta 42.8±3.84 1 ff total pCilL _ Radioactivity,radium 3.86±0.877 1 ff total pCi/L Radioactivity,radium 1.02 t 0.349 1 ff 226 total pCi/L Sulfate(as SO4) 26 mg/L 1 N (14808-79-8) Aluminum,Total 27.0 mg/L 1 (7429-90-5) Barium,Total 0.470 mg/L 1 (7440-39-3) Boron,Total(7440- <0.050 mg/L 1 I' 42-8) Cobalt,Total(7440- 0.026 mg/L 1 ff 48-4) Iron,Total(7439-89-6) 36.0 mg/L 1 p Magnesium,Total 17.0 mg/L 1 . (7439-95-4) Manganese,Total 1.00 mg/L 1 N (7439-96-5) Tin,Total <0.005 mg/L 1 . (7440-31-5) Titanium,Total 2.20 mg/L 1 n (7440-32-6) EPA Form 3510-2F(Rev. 1-92) Page VII-I Continue on Reverse Arsenic,Total <0.050 mg/L 1 See Supplemental (7440-38-2) _ information Beryllium,Total <0.001 mg/L 1 " (7440-41-7) Cadmium,Total <0.000/0 1 " (7440-43-9) mg/L . Chromium,Total 0.020 mg/L 1 " (7440-47-3) _ Copper,Total 0.058 mg/L 1 " (7440-50-8) _ i Mercury,Total 0.00014 mg/L 1 " (7439-97-6) _ . Nickel,Total 0.019 mg/L 1 " (7440-02-0) Selenium,Total <0.050 mg/L i " (7782-49-2) _ Silver,Total <0.005 mg/L 1 " (7440-22-4) Zinc,Total 0.320 mg/L 1 " (7440-66-6) EPA Form 3510-2F(Rev. 1-92) Page VII-I Continue on Reverse Continued from the Front Part C- list each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present.See the instructions for additional details and requirements.Complete one table for each outfall. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Fecal Coliform CHT' 546*co1/100 1 See Supplemental mL Information 'analyzed outside holding time • Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Number of hours between Date of Storm Event Duration Total rainfall beginning of storm measured and Total flow from of Storm during storm rain event end of previous measurable rain Event event event (gallons or specify units) (in minutes) (in inches) 6/412009 960 2.82 81 hours 188374 gallons 7. Provide a description of the method of flow measurement or estimate Flows estimated using run-off coefficients for the drainage area based on rainfall data EPA Form 3510-2F(Rev. 1-92) Page VII-2 EPA ID Number(copy from Item I of Form 1) Form Approved. OMB No.2040-0086 SW 015 NC0004979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2F) Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <4.4 mg/L 1 See Supplemental Information Biological Oxygen 2.0 mg/L 1 Demand(BODS) Chemical Oxygen 16 mg/L 1 Demand(COD) Total Suspended 25 mg/L 1 Solids(TSS) Total 0.099 mg/L 1 « Nitrogen Total 0.059 mg/L 1 Phosphorus pH Minimum Maximum Minimum Maximum 1 " 7.26 SU Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Chlorine,Total 0.11 mg/L 1 « residual Chloride 5.4 mg/L 1 's Color 100 units 1 « Fluoride(16984-48-8) 0.12 mg/L 1 Nitrate-Nitrite(as N) 0.099 mg/L 1 « Radioactivity,alpha <5.0 pCi/L 1 « total Radioactivity,beta 7.10 pCUL 1 « total Radioactivity,radium <1.0 pCUL 1 « total Radioactivity,radium <1.0 pCl/L 1 « 226 total Sulfate(as SO4) 38 mg/L 1 « (14808-79-8) Aluminum,Total 0.35 mg/L 1 (7429-90-5) Barium,Total 0.080 mg/L 1 (7440-39-3) Boron,Total(7440- 0.33 mg/L 1 42-8) Cobalt,Total(7440- <0.005 mg/L 1 « 48-4) Iron,Total(7439-89-6) 1.8 mg/L 1 Magnesium,Total 5.3 mg/L 1 « (7439-95-4) Manganese,Total 0.60 mg/L 1 « (7439-96-5) Tin,Total <0.005 mg/L 1 (7440-31-5) Titanium,Total 18 ug/L 1 ft (7440-32-6) EPA Form 3510-2F(Rev. 1-92) Page VII-2 Arsenic,Total 20 ug/L 1 See Supplemental (7440-38-2) Information Beryllium,Total <1.0 ug/L 1 u (7440-41-7) Cadmium,Total <0.10 ug/L 1 " (7440-43-9) _ Chromium,Total <5.0 ug/L 1 " (7440-47-3) . Copper,Total <10 ug/L 1 " (7440-50-8) Mercury,Total <0.0001 mg/L 1 " (7439-97-6) Nickel,Total <10 ug/L 1 " (7440-02-0) . Selenium,Total <5 ug/L 1 " (7782-49-2) Silver,Total <5 ugh. 1 " (7440-22-4) Zinc,Total 35 ug/L 1 " (7440-66-6) - EPA Form 3510-2F(Rev. 1-92) Page VII-2 Continued from the Front Part C- List each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present.See the instructions for additional details and requirements.Complete one table for each outran. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Fecal Coliform CHT 410•col/100 1 See Supplemental mL Information "analyzed outside holding time Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Date of Storm Event Duration Total rainfall Number of hours between Total flow from rain event of Storm during storm beginning of storm measured and Event event end of previous measurable rain (gallons or specdy units) (in minutes) (in inches) event 4/20/2009 240 .59 >72 hours 1424263 gallons 7. Provide a description of the method of flow measurement or estimate. Flows estimated using run-off coefficient with drainage area and rainfall data EPA Form 3510-2F(Rev. 1-92) Page VII-2 NPDES Supplemental Information Allen Steam Station NPDES Permit # NC0004979 November 2009 Men Steam Station,Gaston County NPDES Permit No.NC0004979 Page 2 of 26 TABLE OF CONTENTS Page No. 1.0 GENERAL INFORMATION 3 2.0 OUTFALL INFORMATION 2.1 Outfall 001 — Condenser Cooling Water 3 2.2 Outfall 002 —Ash Basin 4 2.3 Outfall 002A— Coal Yard Sump Emergency Overflow 11 2.4 Outfall 002B — Powerhouse Sump Overflow 11 2.5 Outfall 003— Miscellaneous Equipment Cooling and Seal Water 11 2.6 Outfall 004— Equipment Cooling and Intake Screen Backwash 12 2.7 Outfall 005—WWTS Effluent Discharge 12 3.0 STORMWATER 13 4.0 HAZARDOUS AND TOXIC SUBSTANCES 25 5.0 ALLEN STEAM STATION 316 DETERMINATION 26 5.1 316(a) 26 5.2 316(b) 26 Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 3 of 26 1.0 GENERAL INFORMATION Plant Allen utilizes waters from the Catawba River for condenser cooling and service water requirements. A brief discussion of each discharge follows. All flows are based on historical data where possible or pump design capacities and normal run-times. 2.0 OUTFALL INFORMATION 2.1 Outfall 001 - Condenser Cooling Water (CCW) The CCW system is a once-through, non-contact cooling water system that removes heat rejected from the condensers and other selected heat exchangers and then discharges into the South Fork River. Each of the 5 units at Plant Allen has two condenser cooling pumps. The number of pumps used is dependent on unit load and intake temperatures with more pumps running with higher loads and intake temperatures. Units 1 and 2 share a common cooling water supply tunnel served by a total of 4 CCW pumps. Units 3 and 4 also share a tunnel and 4 CCW pumps. Unit 5 has a separate tunnel and 2 CCW pumps. The common tunnel design enables three pumps to give Units 1 and 2 or 3 and 4 the equivalent of 1 '/2 pump operation. The 1 '/2 pumps operation adds an economical range or flexibility when units are on partial load and when intake water temperatures are minimal. Condense" ot lit a stater Pum• Ca•acities Unit No. I 1-Pump GPM 1.5-Pump GPM 2-Pump GPM 1 55,500 74,800 83,500 2 55,500 74,800 83,500 3 83,000 111,200 126,000 4 83,000 111,200 126,000 5 83,000 126,000 All condenser tubes at Plant Allen are cleaned manually with metal or rubber plugs. Mechanical cleaning is required once a year for most units. A leak test is performed periodically on the condenser tubes. (See section 2.2.6.4.) If leaks are detected, then one method used to temporarily stop small leaks is to add sawdust to the CCW system, as previously approved by NCDENR. The sawdust is added at amounts that will plug the leaks and not result in an environmental impact. This is a temporary measure until the unit can come off-line so the leaks can be permanently repaired. Use of the supplemental pumping system that was approved for operation from July through September 2008 is proposed on an as-needed basis between July and September of each year. During operation of the supplemental pumping system, calculation of Allen Steam Station's CCW discharge temperature for Outfall 001 will be modified to include the temperature of the supplemental Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 4 of 26 cooling water pumping system based on the system flow and Allen Steam Station's CCW intake temperatures, as was done in 2008. The supplemental pumping system will enable Allen Steam Station to extend power production in compliance with current thermal limits that assure protection of the aquatic community and downstream users. 2.1.1 Asiatic Clam/Debris Filter Backwash Water for the Unit 5 CCW water is filtered for any twigs, leaves and other light debris, which passed through the intake screens. Asiatic clams, which are common in Lake Wylie and can clog the condenser tubes, are also captured in this filter. This filter is backwashed once a week for 15 minutes. A maximum flow of 3000 GPD is realized. No additives are in the backwash water. The twigs, leaves, clams and other light debris collected in the debris filter are indigenous to the river and are therefore flushed back with no harmful environmental consequences. 2.2 Duffel! 002 - Ash Basin 2.2.1 Boiler Cleaning All five boilers at Plant Allen are chemically cleaned with the next cleaning as needed. The volume of the boilers determines the quantity of chemicals required for a cleaning. Boilers #1 and #2 each have a waterside volume of 26,700 gallons. The volume of boilers #3, #4, and #5 is 40,100 gallons each. The volume of dilute waste chemical discharged from unit#1 or#2 during a cleaning is 294,000 gallons. The volume of diluted waste chemicals drained from #3, #4 and #5 totals 450,000 gallons each. These wastes are drained through temporary piping to the permanent ash removal lines, which flow to the ash basin. Immediately prior to the beginning of a boiler chemical cleaning procedure, additional stop logs are added to the ash basin discharge structure. This action assures longer retention time of the chemical wastes for proper treatment through dilution, neutralization, precipitation, and ion-exchange as documented in the Ash Basin Equivalency Demonstration (October 1976). Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 5 of 26 A list of the chemicals and amounts required to clean the boilers at Plant Allen follows: CLEANING CHEMICALS AMOUNT USED PER UNIT Boiler#1 and #2 Boiler#3, #4 & #5 Sodium bromate 550 lbs 550 lbs Ammonium carbonate 1000 lbs 1000 lbs Ammonium hydroxide* 850 gal 950 gal Hydrochloric acid* 3700 gal 5500 gal Thiourea* 1680 lbs 2010 lbs Citric acid 300 lbs 400 lbs Sodium Sulfite 100 lbs 100 lbs Ammonium bifluoride 1100 lbs 1700 lbs Detergent (Triton—X) 20 gal 20 gal Antifoam agent 10 gal 10 gal During a chemical metals cleaning these chemicals are present in amounts greater than the reportable quantity as identified under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). If a spill of any these chemicals were to occur, in most cases, it would be routed to the ash basin for treatment. Alternately, the boiler may be cleaned using ethylenediaminetetraacetic acid (EDTA). If EDTA is used for cleaning, no waste water will be discharged to the ash basin, rather all cleaning waste waters will either be evaporated in the boiler or collected and transported off-site for proper treatment and disposal. 2.2.2 Stormwater run-off Storm water run-off enters the ash basin from the from the ash basin's drainage area, the yard drainage sump, the coal yard sump, the FGD storm water basin and the landfill leachate sump. The powerhouse sump and the limestone storm water sump discharges its rainfall run-off into the yard drainage sump. A more detailed description of the sump systems and stormwater run-off is included in section 3.0. 2.2.3 Sanitary Wastes Sanitary waste at Plant Allen is treated in a septic tank with the effluent from the septic tank being discharged to the Ash Basin via the Coal Yard sump. Approximately 150 people are responsible for the load on this system. An average flow of 4850 GPD is treated by the system. The drinking water is supplied by City of Belmont Utilities Department. 2.2.4 Ash Sluice Plant Allen has converted to a dry ash handling system. Ash collected in the electrostatic precipitators is transported by compressed air to two silos where ash is transferred to trucks for ultimate disposal in the newly constructed on-site Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 6 of 26 landfill. Wet sluicing is still utilized during times of start up and dry system upset. Bottom ash sluicing to the basin requires approximately 6.0. Plant Allen presently has additional air pollution control systems installed on three units. Use of these systems entails the use of low concentrations of ammonia and sulfur compounds. These systems aid in the collection of the ash in the electrostatic precipitators. 2.2.5 Recirculating Water System (RCW) Plant Allen has 2 RCW systems: a chiller system and a pump cooling water system. Both systems use the biocide Nalco H-550 or similar products. In addition, the corrosion inhibitor Nalco CS-4710 or similar product is used. Generally, these systems are closed loop, but may need to be drained occasionally. All such water would enter the floor drains and then be discharged to the ash basin. 2.2.6 Miscellaneous Waste Streams 2.2.6.1 Turbine Non-destructive Testing Approximately once per year, one turbine is tested for cracks in the generator shaft using an ultrasonic nondestructive test. During the process a maximum of 400 gallons of demineralized water mixed with 4 gallons of corrosion inhibitor is used and discharged to the ash basin. 2.2.6.2 Heat Exchanger Cleaning From time to time, it may be necessary to clean the small heat exchangers with polyacrylamide, polyacrylate, sodium laurylsulfate and tri-sodium phosphate. All wastewater would be routed to the ash basin. 2.2.6.3 Condensate Polishers: Plant Allen utilizes condensate polishers which divert a portion of the normal condensate (closed system)flow through one of two cells per unit. The polishers provide filtration as well as ion exchange functions to remove or substantially reduce dissolved solids and suspended matter present in the condensate stream. The polishers require precoating with a combination of anion and cation resin. To facilitate precoating, 125-150 ml of a solution of polyacrylic acid (25%) is added to the precoat slurry. Upon exhaustion, the precoat is removed from the filters by water/ air blasting and flushed to the ash basin via sumps. Condensate water is used to remove the exhausted precoat at the rate of: • Unit 1 & 2 - 1558 gal/precoat • Units 3, 4, & 5 - 2090 gal/precoat. A total average waste flow of approximately 980 GPD to the ash basin is realized. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 7 of 26 2.2.6.4 Condenser Leakage Testing: Fluorescing Dye Method - Approximately 1 lb. of a disodium fluorescing dye added to 280,000 gals of demineralized water is used occasionally to test the condensers for leakage. All wastewater from the testing would be routed to the ash basin. Sulfur Hexafluoride Method - Periodically, sulfur hexafluoride is injected into the condenser tubes to locate condenser tube leaks. Sulfur hexafluoride is a chemically inert, nonflammable, nontoxic gas with an extremely low water solubility. It is estimated that 150 grams of sulfur hexafluoride would be used during the leak detection process. Most of the sulfur hexafluoride would be volatilized during the process. 2.2.6.5 FGD Stormwater Sump Stormwater collected at FGD site including: the dry ash handling facility, gypsum pile, WWTS area (not process water), stack, absorbers, switchgear building, dewatering building, reagent prep building, and the control room area is routed to a large stormwater collection basin prior to being pumped to the ash basin (See Section 3.4 for a more detailed description of FGD stormwater sump) 2.2.6.5 Landfill Leachate collection discharge: Industrial Solid Waste landfill (Permit No. 36-12) permitted to accept coal combustion byproducts (fly ash, bottom ash, gypsum, WWTS filter press sludge cake) consists of a double liner with leachate collection system. Collected leachate will be pumped to ash basin. 2.2.7 Ash Basin Treatment Sulfuric Acid System- An acid injection system utilizing 93 % sulfuric acid is operated as needed to maintain pH level below 9.0 standard units. Sodium Hydroxide System -A sodium hydroxide injection system utilizing 25% or 50% sodium hydroxide operated as needed to maintain pH level above 6.0 standard units. 2.2.8 Yard Drain Sump The yard drain sump is a large concrete structure that has three level controlled pumps, which pump wastewater from Plant Allen to the ash basin. These pumps are operated on a rotating basis. The combined average flow from all sources tied to the yard drain sump is approximately 4.0 MGD. (See Section 3.4 for a more detail description of rainfall run-off entering the yard drain sump.) Below is a description of waste streams going to the yard drain sump: 2.2.8.1 Boiler Room Sumps (Units 1-4) The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 8 of 26 leakage (refer to the attached schematic of water flow for individual flows). The effluent from the units 1 through 4 boiler room sumps is flushed to the yard drain sump. The effluent from the unit 5 boiler room sump is flushed to the power house sump, which is then flushed to the yard drain sump. 2.2.8.2 Turbine Room Sumps The turbine room sumps accommodate flows from floor washing, leakage, and occasional condenser water box drainage. Effluent from units 1 through 5 turbine room sumps is flushed to the yard drain sump. 2.2.8.3 Limestone Unloading/Storage Area Sump Limestone sump collects stormwater from limestone unloading and storage area and routes to YD sump via PH sump dischage line. (See Section 3.4 for a more detail description of limestone sump) 2.2.9 Water Treatment System The water treatment wastes consist of sedimentation, filter backwash, reverse osmosis (RO) concentrate, demineralizer regeneration wastes and boiler blowdown. The make-up water treatment system is comprised of a clarifier, two pressure filters, two activated carbon filters, pre RO filters, a reverse osmosis machine and one set of demineralizers. Make-up water is used in the boilers and closed cooling systems. Clarifier: The clarifier has an average production of 0.252 MGD. Caustic or ferric sulfate/ferric chloride are used to affect precipitation and thus remove suspended solids from the raw river water. Desludging of the clarifier takes place approximately 8% of the unit run-time with an average volume of 2300 GPD going to the ash basin. Pressure Filters: There are two pressure filters which follow the clarifier in the water treatment process. These filters are backwashed once per week with a waste flow of 11,000 gallons per backwash. Each pressure vessel will contain 84 ft3 of anthracite, 50 ft3 of quartz, 25 ft3 of garnet and 41 ft3 of garnet/quartz support media. Each vessel will use product water to backwash at a rate of 750 gpm. On average, both vessels is backwashed once per week. The contents of the pressure filters will be changed out, as internal maintenance requires, and the used filter medium will be sluiced to the ash basin. Activated Carbon Filters: In addition to the pressure filters, there are two activated carbon filters. These filters are backwashed twice per month. Approximately 30,000 gallons of water are required to backwash each of these filters. The activated carbon filters are composed of approximately 250 ft3 of granular activated carbon (coal). The spent filter medium is changed out yearly and sluiced to the ash basin. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 9 of 26 Reverse Osmosis (RO) Unit: A RO unit is used to decrease the conductivity in the filtered water, thereby increasing the efficiency of the demineralizers and reducing the amount of chemical needed for demineralizer regeneration. During operation, the unit has a continual blowdown of 60 gal/min, which is discharged, to the ash basin. The RO unit is cleaned on a quarterly basis with the waste going to the yard drains and eventually the ash basin. During a cleaning, approximately 30 lbs of a sulfamic acid cleaner along with 5 gallons of biocide, 2 liters of sodium hydroxide, and 0.5 gallons of sodium lauryl sulfate is used. Demineralizer: The demineralizer consists of two mixed-bed cells. Only one of these cells is operated at any one time. The cell which is in operation is regenerated approximately once every 7- 14 days of operation. A regeneration requires 42 gallons of sulfuric acid (78-80%) and 150 gallons of 50% sodium hydroxide. An average dilute waste chemical and rinse flow of 20,000 gal is realized. The dilute acid and caustic are discharged to the floor drains simultaneously through the same header for neutralization purposes. All regeneration wastes are flushed to the ash basin. The demineralizer resin is changed out approximately once every 10 years and the spent resin is sluiced to the ash basin. Approximately 1 milliliter of the surfactant Triton CF-54 or similar product is added to the new resin to improve separation. Boiler Blowdown: Each of the five boilers at Plant Allen blowdown at an average rate of approximately 500 lbs. of steam per hour. The blowdown is allowed to flash in a blowdown tank. Most of the blowdown is vented to the atmosphere with a minimal amount of condensate discharged to the boiler room sump. The average condensate flow to this sump is 0.004 MGD. Hydrazine is maintained at a concentration of 25 ppb in the condensate system for deoxygenation. A minute amount of hydrazine (<10 ppb) may be present in the condensate flow to the boiler room sump. 2.2.10 Preheater Washes Preheaters are backwashed with raw water approximately 2 times per year to remove ash and corrosion products. There are 12 preheaters at Allen that would require approximately 100,000 gallons of backwash water each. The backwash water is routed to the ash basin through the yard drain sump. 2.2.11 Laboratory Wastes The plant chemistry and the FGD chemistry laboratories on site perform a variety of water analyses and routine sample collections. Therefore several chemicals are used in the lab in small quantities for sample preservation, bottle rinsing, equipment calibration, conductivity analyses, etc. The wastes are flushed down the sink and discharged into the yard drain sump and then pumped to the ash basin. Some of the laboratory chemicals are as follows: Ammonia molybdate, Acetic acid, Ferric sulfate, Hydrochloric acid, Monoethylamine, Nitric acid and Potassium hydroxide. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 10 of 26 2.2.12 Power House Sump (Unit 5) The wastes, which enter the floor drains at Plant Allen, accumulate in the boiler room sumps and turbine room sumps. The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous leakage. Effluent from the unit 5 boiler room sump is flushed to the powerhouse sump, which is then flushed to the yard drain sump. This sump also receives stormwater from various drains located on the north end of the powerhouse. (See Section 3.4 for a more detail description of rainfall run-off entering the powerhouse sump.) 2.2.13 Physical Chemical Treatment System The purpose of this system is to provide a chemical injection system for treatment of dissolved pollutants that would not settle out of the wastestream through purely physical means. The system treats 4-6 MGD sluice water to reduce the Total Suspended Solids (TSS) and selenium to below permit limits. The three primary settling cells are used to settle the solids (one at a time, while the inactive cells are being cleaned). The treatment channel conveys settled sluice wastewater to the secondary settling or flocculation cell. Approximately 25-50 gpm of the settled waste stream from the treatment channel is pumped into the chemical treatment building. This wastewater stream provides the opportunity to take samples before and after treatment and serves as the chemical injection point. The chemicals that are presently utilized for treatment in this system are: sulfuric acid, ferric sulfate, ferric chloride and sodium hydroxide. After chemical addition and mixing in the treatment channel, the treated waste stream is discharged into a floc settling basin to allow sufficient settling time for any precipitated compounds to settle prior to discharge. Overflow from the final settling cell flows through a vegetated ash delta prior to discharge to the main pond. 2.2.14 Selective Non-Catalytic Reduction (SNCR) As part of the compliance with the North Carolina Clean Air Initiative (NCCAIR), Allen has installed a urea based "trim" Selective Non-Catalytic Reduction (SNCR) systems on all five units. The trim SNCR systems are expected to reduce NOx emissions by approximately 30%. SNCR systems operate by injecting urea into the upper section of the boiler where a chemical reaction occurs to reduce the NOx to water and nitrogen. Some residual ammonia will be collected on the fly ash in the electrostatic precipitators and a small amount will be carried to the ash basin. However, the operation of the SNCR system is not expected to require additional treatment capabilities to ensure compliance with NPDES permit limits. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 11 of 26 2.2.15 Flue Gas Desulfurization (FGD) A Wet Flue Gas Desulfurization (FGD) system has been installed at Allen for the reduction of SO2 from the stack gas. The following provides a description of the FGD system at Allen. In a Wet Scrubber system, the SO2 component of the flue gas produced from the coal combustion process is removed by reaction with limestone-water slurry. The particular system used at Allen collects the flue gas after it passes through the electrostatic precipitator and routes the gas into the absorber tank. As the gas rises through the tank to the outlet at the top, the gas passes through a spray header. A slurry of water and limestone droplets is continually sprayed through this header into the stream of flue gas. The SO2 in the flue gas reacts with the calcium in the limestone and produces SO3. The SO3 slurry falls to the bottom of the tank where a stream of air is injected to oxidize the slurry to form gypsum (CaSO4.2H2O). The gypsum slurry is drawn off the absorber tank and subsequently pumped to a vacuum belt filter. Part of the process water from the FGD system is blown down in order to maintain the FGD water chemistry within the FGD system specifications. This water is treated in a wastewater treatment system that discharges to the ash basin via internal Outfall 005. The FGD system has a material handling system that supplies limestone to the scrubber and a gypsum storage area for the gypsum removed from the process. The limestone comes onto the site by rail and is then transferred to the FGD site via a covered conveyor. Runoff from the storage area is routed to the ash basin. The gypsum is routed from the FGD tank to a dewatering belt and then to a covered conveyor belt that will carry it to a storage pile. The runoff from this area is also routed to the ash basin. 2.3 Outfall 002A— Coal Yard Sump Overflow An overflow pipe that directs flow from the sump to the Catawba River was included in the construction of the coal yard sump. This modification was implemented to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. 2.4 Outfall 002B — Powerhouse Sump Overflow An overflow pipe that directs flow from the sump to the ground was included in the construction of the powerhouse sump. This modification was implemented to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. If enough water overflows, the waste water could potentially get to the Catawba River. Overflow has not occurred during the last permit cycle. 2.5 Outfall 003— Misc Equipment Cooling & Seal Water Outfall 003 discharges into the CCW discharge canal. The discharge consists of cooling water from units 4 and 5 boiler feedpump hydraulic coupling coolers and other miscellaneous equipment cooling. This water is once-through, non-contact cooling water withdrawn from the service water system. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 12 of 26 Approximately 10,000 gpd of bearing cooling water for the ash line booster pump is routed back to the discharge canal via a stormwater outfall in the vicinity of outfall 003. The water is once through, non-contact cooling water withdrawn from the service water system. 2.6 Outfall 004— Equip. Cooling & Intake Screen Backwash 2.6.1 Equipment Cooling Water Cooling water for units 1,2 & 3 boiler feed pump hydraulic coupling coolers and other miscellaneous equipment is discharged through outfall 004. This water is once-through, non-contact water drawn from the service water system. In addition, water from a vehicle rinse-down area is directed to this outfall. The rinse water contains no soaps or other additives. Allen has also added a new chiller system for comfort cooling that is a once through non contact cooling water system and discharges back to the river via outfall 004. 2.6.2 Intake Screen Backwash The intake screens at Plant Allen are flushed on an "as needed" basis. Backwash usually averages 2 hours per shift. The average volume required is 0.053 MGD. The large debris floating on the river is caught on the parallel bar screens. This trash is collected and disposed of in a landfill. The silt, twigs, leaves and other light debris collected on the rotating screens are indigenous to the river and are therefore flushed back into the river with no harmful environmental consequences. 2.8 (Internal) Outfall 005 —WWTS Effluent Discharge FGD purge water is routed to a WWTS consisting of a physical-chemical process designed to precipitate heavy metals and remove suspended solids. The clarified product water is routed to a series of bioreactors designed for selenium and nitrate removal. The bioreactor product water is discharged to the ash basin via Outfall 005 in the vicinity of the floc settling basin (as noted in Section 2.2.13 above) 3.0 STORMWATER GENERAL INFORMATION 3.1 Site Description Allen Steam Station property covers approximately 953 acres. The powerhouse, the plant yard, the coal pile, the switchyards, and associated material and equipment storage areas cover about 65 acres. These developed areas are generally flat. There are approximately 5 miles of rail access and 1.67 miles of paved roadways on-site. Coal and limestone is shipped to the site by rail lines. There is a 64 acre retired ash basin currently being converted to a double lined with leachate collection landfill for disposal of coal combustion byproducts . The active ash basin has a surface area of about 176 acres, and it receives runoff from another 112 acres. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 13 of 26 Based on information from the Soil Survey of Gaston County, North Carolina, the original site soils at Allen Steam Station were from the Gaston series. These soils are classified as sandy clay loam with red clay in the subsoils. In developed areas, the soil profile has been altered by grading and filling. The site topography is generally flat with rolling hills in outlying, undeveloped areas. 3.2 Storm Water Drainage System In developed areas, runoff flows overland to ditches and catch basins, which are connected to a buried network of corrugated metal pipes (CMP). Rainfall runoff from the coal pile and coal handling areas and portions of the plant yard goes to the yard sumps that discharge to the ash basin. Storm water runoff from other areas of the site is discharged to the Catawba River and the South Fork River. Rainfall runoff from the transformer yard area and the 115 KV switchyard is routed through oil trap tanks prior to being discharged. 3.3 Characterization of Drainage Basins A description of the drainage area, significant materials, and material control measures is presented for each drainage basin. Herbicides are spot applied where required in parking areas, switchyards, parts laydown areas, along walkways, and around various fixtures and buildings. 3.4 Storm Water Outfalls Characteristics for 16 individual outfalls and one group of outfalls are presented. Stormwater Outfall 1 Discharge Structure: 10 inch (") diameter ( ) CMP Location: North of station on railroad tracks Drainage Area: 5.4 acres Area Description This outfall conveys runoff from undeveloped, wooded area upland of the railroad tracks, and from the tracks themselves. Approximately 345 feet of an unpaved road passes through the drainage area and 2000 feet of railway lines. There are no paved or roofed areas in this drainage area. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 2 Discharge Structure: 24" CMP Location: North of station on railroad tracks Drainage Area: 12.7 acres Area Description This area conveys overflow runoff from the construction laydown area, Boat Club road, and parking areas. This area also conveys flow from wooded areas upland of the railroad tracks. A permanent stormwater basin collects, retains, and Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 14 of 26 impedes most of the water from impermeable areas. There is approximately 4.6 acres of a gravel laydown area. Impermeable areas include 1000 feet of paved road (Boat Club) and approximately 3,000 square feet of roof surface from temporary trailers. Significant Materials/Controls Construction Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large, flat, gravel laydown area north and upland of the powerhouse. The equipment and supplies generally do not contain liquids. Parking: There is approximately 3,000 square feet of gravel parking within this drainage basin. Stormwater Outfall 3 Discharge Structure: 36" Reinforced Concrete Pipe Location: North of station on railroad tracks Drainage Area: 1.6 acres Area Description This outfall conveys runoff from the railroad tracks. There are about 1500 feet of railway lines. There are no paved or roofed areas in this drainage area. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 4 Discharge Structure: 10" Cast Iron Pipe Location: North of station at Catawba River Drainage Area: 0.4 acres Area Description This small area is southeast of the limestone unloading area. There is a bermed area with trees that separates this drainage area and the limestone unloading area. None of the drainage area is paved or roofed. Significant Materials/ Controls Significant materials are not stored within this drainage basin. Stormwater Outfall 5 Discharge Structure: 18" CMP Location: North of station at Catawba River Drainage Area: 7.3 acres Area Description This outfall conveys overflow runoff from the catchment basins upland of the railroad tracks and from the tracks themselves. There are also a few temporary Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 15 of 26 construction buildings in this area. About 450 feet of a paved road passes through the drainage area, and there are about 2,580 feet of railway lines. Significant Materials/Controls Parking: There are about 3.2 acres of gravel parking areas within this drainage basin. Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large, flat, gravel laydown area north of the powerhouse. The equipment and supplies generally do not contain liquids. Limestone/ Coal: Potential for a spill or leak from railroad activities. Stormwater Outfall 6 Discharge Structure: 10" Cast Iron Pipe Location: North of station at Catawba River Drainage Area: 0.4 acres Area Description This small area is southeast of the limestone unloading area. There is a bermed area with trees that separates this drainage area and the limestone unloading area. None of the drainage area is paved or roofed. Significant Materials/ Controls Significant materials are not stored within this drainage basin. Stormwater Outfall 7 Discharge Structure: 18" CMP Location: North of station at Catawba River Drainage Area: 1.5 acres Area Description This area collects stormwater from part of the grassy embankment of the FGD site, but not from the FGD site itself. It also collects runoff from approximately 250 feet of road and 1500 feet of railway. This outfall previously drained part of the area now known as the limestone sump drainage area, but has been capped off at that location. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 8 Discharge Structure: 24" CMP Location: North of Station at Catawba River Drainage Area: 4.1 acres Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 16 of 26 Area Description This outfall conveys runoff from the hill north of the powerhouse. This outfall also conveys runoff from a segment of railroad tracks and from the laydown area adjacent to the north warehouse. There are approximately 1,000 feet of paved roadways and 2,400 of railroad tracks in this drainage basin. Significant Materials/ Controls Parking: There is a gravel parking area at the outage trailers. This lot is used occasionally during outages. Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large flat, gravel laydown area adjacent to the north field warehouse. The equipment and supplies generally do not contain liquids. Limestone/ Coal: Potential for a spill or leak from railroad activities. Stormwater Outfall 9 Discharge Structure: 3 feet (') Concrete Ditch Location: North of Intake Structure at Catawba River Drainage Area: 0.4 acres Area Description This outfall conveys drainage from a segment of railroad tracks in front of the powerhouse and from the grassy embankment between the tracks and the intake structure. About 920 feet of railroad tracks pass through this area. There are no paved or roofed areas in this basin. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 10 Discharge Structure: 24" CMP Location: South of Intake Structure at Catawba River Drainage Area: 0.9 acres Area Description This outfall conveys runoff from a segment of the railroad tracks in front of the powerhouse and from the grassy embankment between the tracks and the intake structure. About 1,280 feet of railroad tracks pass through this area. There is less than 50 square feet of paved or roofed areas in this basin. Drainage from the CCW clam filter pit is discharged through this outfall. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 17 of 26 Stormwater Outfall 11/ NPDES 004 Discharge Structure: 72" CMP Location: East of Coal Pile at Catawba River Control Structure: 65,300 gallon oil trap tank Drainage Area: 15.3 acres Area Description This drainage area comprises most of the southern end of the station yard, and most of this area is developed. This outfall conveys roof drainage from a portion of the powerhouse roof, the machine shop roof, the service building roof, the warehouse roof, and some of the coal handling buildings. These roofed areas cover about 1.3 acres. Two large paved parking lots cover 3 acres. Other parking and paved areas cover about 1 acre. About 3,100 feet of rail lines pass through this drainage area, but only half of them are used regularly. Runoff from a portion of the transformer yard area and from the entire 115 kV switchyard is routed to a 65,300 gallon oil trap tank prior to being discharged to this outfall. The switchyard is covered with gravel. Other portions of the drainage area include the powerhouse yard, grassy, and undeveloped areas. About 50 percent of this drainage area is roofed or paved. NPDES discharges including miscellaneous non-contact cooling water from plant equipment, vehicle wash water, and intake screen backwash water are conveyed through this outfall. Significant Materials/ Controls Coal: Coal dust may be present around coal handling areas. Parking: There are about 3.2 acres of paved parking areas within this drainage basin. Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a flat, concrete laydown yard adjacent to the warehouse. The equipment and supplies generally do not contain liquids. Gasoline: There is a 500-gallon aboveground, carbon steel gasoline tent tank across from the warehouse. The tank is completely enclosed within a steel tent enclosure, and any leaks would be self contained. The enclosure can be drained by opening a valve, and that valve remains closed at any other time. Any fluid drained from the tent is captured and not released to Stormwater Outfall 11. The tank is filled by a 1,500 gallon tanker truck. Clean up supplies are located nearby. Oil: Stormwater runoff from the 115 kV switchyard and from a portion of the station's main transformer yard is routed to the south oil trap tank which has a capacity of 65,300 gallons before being discharged. Transformers 1A, 1T1, CT1, 2T1, 2A, and 3T1 contain a total of 34,533 gallons of mineral oil. The largest volume contained by a single transformer is 9,715 gallons. The oil circuit breakers in the 115 kV switchyard contain a total of 73,229 gallons of mineral oil. Each circuit breaker has three tanks, and each tank contains either 933 or 1,070 Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 18 of 26 gallons of mineral oil, depending on the model. Two transformers at the switchgear house each contain 196 gallons of mineral oil. Stormwater Outfall 12/ NPDES 003 Discharge Structure: 36" CMP Location: Discharge Canal Control Structure: 100,000 gallon oil trap tank Drainage Area: 11.6 Area Description This drainage area includes portions of the powerhouse yard north and west of the station and part of the hill to the north of the station. This drainage basin includes a portion of the station main transformer yard and the 230 kV switchyard. Within the powerhouse yard, the drainage basin is flat and generally covered with gravel or grass. Approximately 1,400 feet of rail lines have been removed or are not in service. Less than 5 percent of this drainage area is roofed or paved. Runoff from the powerhouse yard immediately north and west of the station is routed to a 100,000 gallon oil trap tank prior to being discharged to this outfall. Runoff from the transformer yard goes to the oil trap tank. Runoff from the 230 kV switchyard is not routed to the north oil trap tank because the switchgear in the 230 kV switchyard is gas cooled and does not contain oil. NPDES discharges of miscellaneous non-contact cooling water are routed through the north oil trap tank and then discharged by this outfall. Significant Materials/ Controls Ash: Above ground ash pipelines run through this area carrying ash from the plant to the ash basins. North of the powerhouse, the ash sluice pipeline is located in a trench; spills would be contained with the trench. Oil: Stormwater runoff from a portion of the station's main transformer yard is routed to the north oil trap tank which has a capacity of 100,000 gallons before being discharged. Transformers 3T2, 3A, 4T1, 4A, 4T2, 5T1, 5T2, 5A, CT2, 6A, and a spare transformer contain a total of 73,158 gallons of mineral oil. The largest volume contained by a single transformer is 13,790 gallons. The largest volume contained by a single transformer is 9,715 gallons. The switchgear in the 230 kV switchyard does not contain oil. Stormwater Outfall Group 13 Discharge Structure: Fourteen 10" CMPs Location: Every 200 feet along the retired railroad tracks Drainage Area: 13.6 acres Area Description These outfalls are located every 200 feet along the railroad tracks in front of the coal composition products (CCP) landfill. These outfalls convey runoff from the railroad tracks and from the CCP landfill embankment. About 7,500 feet of railroad tracks pass through this drainage area. None of this drainage area is paved or roofed. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 19 of 26 Significant Materials/ Controls Limestone/ Coal: Potential for a spill or leak from railroad activities. Stormwater Outfall 14 Discharge Structure: 21" CMP Location: Catawba River between the coal pile and CCP landfill. Drainage Area: 2.0 acres Area Description This outfall conveys surface drainage from the area between the embankment at the coal composition products (CCP) landfill and the coal pile. None of the drainage area is paved or roofed. Significant Materials/ Controls Significant materials are not stored within this drainage basin. Stormwater Outfall 15 Discharge Structure: 36" Reinforced Concrete Pipe Location: Catawba River at retired ash basin Drainage Area: 177.8 acres Area Description This is the discharge structure from the structural fills east of the landfill. None of this drainage area is paved or roofed at this time. This area includes a soil borrow area that is approximately 9.1 acres. Stormwater runoff from the soil borrow area is collected into a temporary sedimentation pond that contains a sedimentation basin skimmer. Stormwater Outfall 15 also includes the new coal composition products (CCP) landfill. Contact water from the CCP landfill is not located in this drainage area because it is pumped to the ash basin (see section 2.4 for more information). Only noncontact water on the CCP landfill will fall into this drainage area. Two sedimentation basin skimmers are located in the drainage ditch, and the discharge tower for the outfall is surrounded by riprap and washed stones. Significant Materials/ Controls Ash: An old ash structural fill and noncontact water from the new ash landfill are located in this drainage area. Stormwater Outfall 16 Discharge Structure: 36" CMP Location: Discharge Canal Drainage Area: 37.2 acres Area Description This discharge area drains the approximately 1,678 feet of paved road coming into the Allen site. Ash Boulevard will be paved in the future. This modification will allow a paved route from the dry ash handling facility to the CCP landfill in order for trucks to carry dry ash to the CCP landfill from the FGD site. Drains by Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 20 of 26 the intersection of the main road and the road going to the dry ash handling site are surrounded with washed stones and silt fences. Significant Materials/Controls Ash: Above ground ash sluice lines pass through this drainage area. Trucks carrying ash will pass through this drainage area. Stormwater Outfall Group 17 Discharge Structure: Numerous, 12" CMP Location: Every 170 feet along both sides of the discharge canal Drainage Area: 50 acres Area Description This discharge area drains runoff from the access roads on either side of the discharge canal. None of this area is paved or roofed. Also there is a perennial stream north of the FGD site that drains into the discharge canal through a 36" pipe. A temporary stormwater basin currently receives runoff from most of the permeable surface of the FGD site. When construction ends the temporary stormwater basin will be removed, and most of the permeable surface at the site will once again drain to the stream. Significant Materials/ Controls Significant materials are not stored within this drainage basin. 3.4.1 Sump System At Allen Steam Station, there are six main sumps that use pumps to discharge into the ash basin. They are referred to as the following: landfill (leachate) sump, FGD stormwater sump, powerhouse yard sump, yard drainage sump, limestone drainage area sump, and the coal yard sump. The landfill sump is located south of the coal pile in the CCP landfill. The FGD stormwater sump is located north of the plant and west of the FGD absorber building. The powerhouse yard sump is located east of the powerhouse, at the north end. The powerhouse yard sump discharges to the yard drainage sump. The yard drainage sump is located east of the coal pile and adjacent to the coal yard sump. FGD Stormwater Sump Drainage Area Location: North of powerhouse Drainage Area: 25.6 acres Area Description This drainage area includes the dry ash handling facility, gypsum pile, WWTS area (not process water), stack, absorbers, switchgear building, dewatering building, reagent prep building, and the control room. Most of the FGD site drainage area is routed to a permanent stormwater basin (that has a 30 foot spillway) and pumped to the ash basin through the FGD stormwater sump. Most of the dry ash handling area is surrounded with a concrete curb. Stormwater Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 21 of 26 from this area is routed to the permanent stormwater detention basin. There is an oil water separator (OWS) tank buried into the ground outside of the dewatering building that receives runoff from two transformers (T1 and T2) in the FGD area. The OWS separates the oil from the water before it is enters the permanent stormwater basin Significant Materials/ Controls Gypsum: Gypsum is stockpiled here. A contractor hauls off the gypsum and uses it to make wallboard. A paved area outlines the gypsum pile, and a concrete stormwater trench is located on the farthest edge of the gypsum area and drains to the permanent stormwater basin, and then to the FGD sump. Ash: Ash is transported via pressureized lines to a collection silo. The ash is then gravity fed into trucks which transport the material in the CCP landfill. The floor drains and stormwater runoff are pumped to the permanent stormwater basin. Oil: Runoff from two new auxiliary transformers contains 2,908 gallons of mineral oil a piece. Stormwater runoff is routed to an oil trap tank before entering into the permanent stormwater basin. Runoff from two other new transformers (T1 from the 230 kV and T2 from the 115 kV) is routed to the permanent stormwater basin. Transformers T1 and T2 contain 5,850 and 8,670 gallons of mineral oil, respectfully. All transformers are surrounded by gravel in a concrete containment area and the valves to drain the containment area remain closed most of the time. Also, there are diesel tanks located in the diesel fire pump enclosure. Chemicals: Organic acid is unloaded and stored in this drainage area. There is a 21,500 gallon tank of organic acid located in a secondary containment area inside the reagent prep building. There are various tanks of varying concentration of limestone slurry. 2,255 pounds (approximately 260 gallons) of dibasic acid will be located inside the reagent prep building in a secondary containment area. Limestone Sump Drainage Area Location: Northeast of powerhouse Drainage Area: 6.0 acres Area Description This area is an extremely flat area where limestone is unloaded, piled, and conveyed to the FGD site. Approximately 10,000 square feet is roofed. 100 feet of railroad tracks pass through this drainage area. A new bermed area with trees outlines the northeastern edge of the area. A 350 foot permanent stormwater collection trench (with a 10 foot spillway) is located at the eastern edge of the area and conveys most of the stormwater runoff from the site into the ash basin. Significant Materials/ Controls Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 22 of 26 Limestone: Limestone is stockpiled here. A limestone unloading building and limestone convey belts and hoppers operate in this area. Powerhouse Yard Sump Drainage Area Location: East of the powerhouse, at the north end Drainage Area: 3.6 acres Area Description Industrial wastewater from unit five flows into the powerhouse yard sump. Stormwater runoff from a portion of the powerhouse roof, the plant yard, the fuel oil unloading area, and the bulk fuel oil tank area drains to the powerhouse yard sump. The portion of the powerhouse roof that drains to the powerhouse sump is about 2.2 acres. About 85 percent of this drainage basin is paved or roofed. Overflow from the powerhouse yard sump would spill to the ground and then flow overland and could eventually reach the Catawba River. Overflow from the powerhouse yard sump is permitted as NPDES Outfall 2(b). Overflow from the powerhouse yard sump is not a normal occurrence. Significant Materials/ Controls Oil: The fuel oil bulk storage tank is an aboveground, galvanized steel cylinder surrounded by a concrete containment sufficient in height to contain a total spill plus rainfall. The total tank capacity is 100,000 gallons. There is a catch basin inside the berm. This outlet has a valve which is normally closed. The stormwater is inspected for the presence of oil, and if it is clean, it can be drained if there is significant standing water. In the fuel oil unloading area, fuel is transferred from an 8,000 gallon tanker truck to the bulk storage tank via pipelines. DOT unloading procedures are followed. The fuel oil unloading area is paved and surrounded by a one foot concrete curb and ramps to contain any spills. There is a small sump to drain rainfall; the sump has a valve which is normally closed. Spill clean-up supplies are located nearby. Piping from the unloading area to the bulk fuel oil tank is aboveground or enclosed in a concrete trench. The 48 transformers for the Units 1-5 precipitators contain a total of 7,560 gallons of mineral oil. About 60% of the precipitator transformers are located within this drainage area. The maximum oil content of any single component is 205 gallons. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to the powerhouse yard sump. This wastewater may include oil, chemical, and hazardous waste spills. Yard Sump Drainage Area Location: East of the coal pile Drainage Area: 5.2 acres Area Description The powerhouse yard sump discharges to the yard drainage sump. The yard drainage sump discharges to the ash basin. In addition to the discharge from the powerhouse yard sump, the yard drainage sump receives industrial wastewater Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 23 of 26 from some of the powerhouse sumps. Industrial wastewater includes effluent from the turbine room sumps and boiler room sumps. Stormwater runoff from a portion of the plant yard and parts of coal handling drains to the yard drainage sump. The total roofed area in this basin is about 1.5 acres including the warehouse roof, the maintenance garage roof, and a portion of the powerhouse roof. About half of this drainage basin is paved or roofed. Approximately 1,300 feet of railroad tracks pass through this drainage area. Overflow from the yard drainage sump would discharge to the coal yard sump. Overflow from the sump is not a normal occurrence. Significant Materials/ Controls (See description for powerhouse yard sump for additional information) Kerosene: There is a 200-gallon aboveground, carbon steel kerosene tank above the ash sluice trench. Oil: Used oil is stored in a 4,500 gallon steel tank. The tank is surrounded by a steel containment dike about five feet tall, and the piping is surrounded by a 6- inch concrete curb. Rainfall that accumulates inside the dike can be drained by opening a valve that drains to the ash trench which leads to the yard drainage sump. When the used oil tank is full, the product is removed from site by tanker truck. Small quantities of used oil are initially poured into 55-gallons drums. The drums are stored in the used oil staging area under cover, adjacent to the warehouse, for temporary storage. When the drums are full, they are emptied into the used oil tank. Empty oil drums are stored outside, adjacent to the boat shed. Approximately 250 gallons of oil are stored inside the maintenance garage where floor drains flow to the yard drainage sump. The 48 transformers for the Units 1-5 precipitators contain a total of 7,560 gallons of mineral oil. About 40% of the precipitator transformers are located within this drainage area. The maximum oil content of any single component is 205 gallons. Two transformers associated with the wastewater and coal yard sumps each contain 270 gallons of mineral oil. Fuel oil dispensers for the locomotives and bulldozers are located adjacent to the maintenance garage. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to the yard drainage sump. This wastewater may include oil, chemical, and hazardous waste spills. Coal: Coal dust is present along the railroad tracks and coal handling areas. Ash: Ash pipelines run through this drainage area. Chemicals: There is a 5,000 gallon tank of sulfuric acid located adjacent to the warehouse. The tank is surrounded by a concrete dike with an outlet to the ash line trench which leads to the yard drainage sump. Drums of various chemicals are stored inside a covered, locked shed adjacent to the warehouse. Hazardous Waste / Satellite Accumulation Areas: There is a satellite accumulation area for waste paint, chemicals, solvents, cleaners, etc. adjacent to Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 24 of 26 the paint warehouse. Hazardous wastes are stored in a covered area adjacent to the maintenance garage. Laydown Area: There is a large laydown area adjacent to the warehouse. The area is paved and fenced. Spare equipment and parts are stored in the laydown area. Coal Yard Sump Drainage Area Location: East of the coal pile Drainage Area: 24.1 acres Area Description The coal yard sump receives stormwater runoff from the coal pile and from parts of coal handling area. Less than one percent of this drainage basin is paved or roofed. Approximately 800 feet of railroad tracks pass through this drainage area. Overflow from the coal yard sump would be conveyed to the Catawba River. Overflow from the coal yard sump is permitted as NPDES Outfall 002a. Overflow from the sump is not a normal occurrence. Significant Materials/ Controls Oil: Two transformers associated with the wastewater and coal yard sumps each contain 270 gallons of mineral oil. A fuel oil dispenser for the bulldozers is located in the northwest corner of the smaller coal pile. Coal: Runoff from the coal pile and some coal handling areas is routed to the coal yard sump. Wastewater: Effluent from the septic system goes to coal yard sump. CCP Landfill Sump Drainage Area Location: South of the coal pile Drainage Area: 64.0 acres Area Description The coal combustion products (CCP) landfill is double lined with a leak detection system and leachate collection system. The contact water from the leachate collection system will be pumped from the CCP landfill into the ash basin. There is a 30 foot dike around the landfill. A stormwater drainage trench runs along the south side of the landfill currently and is part of outfall 15. In the future, there will be drainage ditches east and west of the landfill that will collect stormwater runoff and pipe it to the ash basin. Significant Materials/ Controls Ash: Leachate from the CCP Landfill Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 25 of 26 3.5 Similarity of Storm Water Outfalls at Allen Steam Station Monitoring all of the storm water outfalls at Allen Steam Station should not be necessary since many of the outfalls convey storm water from areas of substantially identical activities and materials. Storm water outfalls 8 and 15 are representative for the entire site. 4.0 Hazardous and Toxic Substances 4.1 Hazardous and Toxic Substances Table 2c- 3 At Plant Allen, the potential for toxic and hazardous substances being discharged is very low. In reference to Item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are as follows: Acetaldehyde, Asbestos, Butyl Acetate, Cyclohexane, Diuron, Epichlorohydrin, Formaldehyde, Monoethyl Amine, Propylene Oxide, Pyrethrins, Vinyl Acetate, and Xylene. Other- During the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. It is not anticipated that these products will impact the ash basin's capacity to comply with its toxicity limits, since their concentrations are extremely low. 4.2 40 CFR 117 and CERCLA Hazardous Substances The following table identifies hazardous substances located on-site that may be released to the ash basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). These values below represent the maximum quantities on-site that could be released at one time and sent to the ash basin. They do not reflect quantities that are discharged through typical use. Allen Steam Station Hazardous Substances in Excess of RQ Table 4.2 SUBSTANCE QUANTITY SOURCE Benzene 83 lbs Gasoline Tank Ethylbenzene 2,737 lbs Diesel Fuel Tanks Hydrazine 499 lbs Warehouse Naphthalene 41,700 lbs Fuel Oil Tanks Sodium Hydroxide 1,181 lbs Ash basin/Warehouse/#3 Fan Room Sodium Nitrite 800 lbs Warehouse/Powerhouse Sulfuric acid 44,277 lbs Powerhouse Xylene (Mixed Isomers) 419 lbs Gas Tank Men Steam Station,Gaston County NPDES Permit No.NC0004979 Page 26 of 26 5.0 Allen Steam Station 316 Determination 5.1 Allen Steam Station 316(a) determination Duke Energy's 316(a) demonstration (March 1976) concluded that the "heated discharge from Plant Allen is such that the protection and propagation of a balanced indigenous aquatic community in and on Lake Wylie is assured." Duke's operation experience during the past five years under the thermal limitations imposed in NPDES Permit No. NC0004979 substantiates the above conclusion and further supports Duke's belief that the operating characteristics of the station have a minimal effect of the aquatic environment of Lake Wylie. Surveys of the aquatic community in Lake Wylie demonstrate that a Balanced Indigenous Population exists in Lake Wylie. Accordingly, Duke requests a 316(a) variance and further requests that the thermal limitations imposed in the permit be continued. 5.2 Allen Steam Station 316(b) Determination In conjunction with the rulemaking process for the new Phase II 316(b) rule pertaining to fish impingement and entrainment, historical data and permitting records were reviewed. Initial 316(a) and 316(b) studies associated with enactment of the Clean Water Act concluded that the location, construction capacity, and design of the cooling water intake of Allen and other Duke Power steam stations were not detrimental to the aquatic ecosystem and minimize adverse environmental impacts. Both North Carolina and EPA regulators concurred in 1976 that 316(b) fish impingement and entrainment studies were no longer needed at that time. Although the new Phase II 316(b) rule for existing facilities is currently being litigated, plans for information collection (PICs) are being developed to conduct a Comprehensive Demonstration Study (CDS) to determine required measures to be implemented per approval of NCDENR NPDES Supplemental Information For Marshall Steam Station NPDES Permit No. NC0004987 October 2009 TABLE OF CONTENTS Page No. 1.0 GENERAL INFORMATION 3 2.0 OUTFALL INFORMATION 2.1 Outfall 001 Condenser Cooling Water (CCW) Units 1-4 3 2.2 Outfall 002 —Ash Basin 4 2.3 Outfall 002a and b —Yard Drain Sump Emergency Overflow 11 2.4 Outfall 003 — Unit 4 ID Fan Control House Cooling Water 11 2.5 Internal Outfall 004—Treated FGD (Wet Scrubber) Wastewater 12 3.0 ADDITIONAL INFORMATION 12 4.0 STORMWATER 4.1 Site Description 13 4.2 Facility Drainage and Inventory of Significant Materials and Controls 14 5.0 HAZARDOUS AND TOXIC SUBSTANCES 26 6.0 MARSHALL STEAM STATION 316 DETERMINATION 6.1 316(a) Determination 27 6.2 316(b) Determination 27 7.0 ASH BASIN CAPACITY 28 Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 3 of 30 1.0 General Information Marshall Steam Station (MSS) is located on NC Highway 150, six miles west of 1-77 in Catawba County on Lake Norman near Terrell, North Carolina. MSS consists of four coal-fired steam electric generating units. Units 1 and 2 can generate 380,000 kilowatts (net) of electricity each and units 3 and 4 have the capacity to generate 660,000 kilowatts (net) of electricity each. A brief discussion of the individual waste streams follows. 2.0 Outfall Information 2.1 Outfall 001 - Condenser Cooling Water (CCW) Units 1-4 The CCW system is a once through non-contact cooling water system, which condenses steam from the condensers and other selected heat exchangers. When MSS is operating at full power, it has a design capacity to pump 1463 MGD (1,016,000 GPM) of cooling water through a network of tubes that runs through the condenser and selected heat exchangers. The raw cooling water is returned to the lake. No biocides or other chemicals are used in the condenser cooling water. Units 1 and 2 have two CCW pumps per unit and Units 3 and 4 have three CCW pumps per unit with the following maximum flow capacities: Unit No. 1-Pump 2-Pump 3-Pump GPM GPM GPM 1 126,000 190,000 - 2 126,000 190,000 - 3 150,000 253,000 318,000 4 150,000 253,000 318,000 The operational schedule for these pumps is dependent on the intake water temperature and on the unit loads. Depending on the electrical demand, pumps are operated to maximize MSS efficiency and to assure balanced and indigenous populations are maintained in Lake Norman. Each unit is on an independent system to avoid a system trip that would suddenly reduce the discharge flow at outfall 001. This practice leads to a higher reliability factor for the units and protection of aquatic life taking refuge in the discharge canal during cold weather. Flow recorded on the monthly Discharge Monitoring Reports is based on CCW pump run times. The condensers are mechanically cleaned. Normally, amertap balls are cleaning the tubes on a continuous basis while the plant is operating. Periodically, after the condenser is drained, metal scrapers, plastic scrapers or rubber plugs are forced through the tubes to rid them of scale or other deposits. The condenser tubes may also be tested for leaks, as needed. A leak test can be conducted in approximately two to three hours per unit with usually no more than six injections of tracer gas (i.e., sulfur hexaflouride, helium, etc) each within approximately a 30 second period and/or checked with fluorescent dye. The dye is added to the condensate water and put on the outside of the condenser tubes. During the test, if fluorescent water does leak into the tubes, this discharge indicates a leak does exist in the condenser tubing. The levels of gas or dye that might be discharged would be well below any levels of aquatic biological toxicity concerns. If leaks are detected, then one method used to temporarily stop small leaks is to add sawdust to the CCW system, as previously approved by NCDENR. The sawdust is Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 4 of 30 added at amounts that will plug the leaks and not result in an environmental impact. This is a temporary measure until the unit can come off-line so the leaks can be permanently repaired. 2.1.1 Intake Screen Washing Manually by Removing Screens The intake screens (32 total) are washed on an as needed basis. Normally, the screens require washing once a month for a period of approximately 5 minutes per screen. The screens (10 ft x 20 ft) are stationary type and are removed for cleaning. A low-pressure pump supplies the raw water required for washing with a design capacity of 300 gpm. Therefore, the average flow of water used to backwash the screens is 0.002 MGD. Should it become necessary to backwash the screens on a continuous basis the maximum flow would be 0.43 MGD per screen. The debris collected on the screens consists of twigs, leaves, and other material indigenous to Lake Norman and is removed and properly disposed. The intake screen backwash water drains back to the station intake cove without any adverse environmental impact. 2.2 Outfall 002 - Ash Basin The ash basin at MSS accommodates flows from two yard-drain sumps, an ash removal system, low volume wastes and non-point source storm water. Low volume waste sources include, but are not limited to: wastewater from wet scrubber air pollution control systems, ion exchange water treatment system, water treatment evaporator blowdown, laboratory and sampling streams, boiler blowdown, floor drains, and recirculating house service water systems. Total average influent from these sources combined is approximately 8.3 MGD. At times, due to unit loads, rainfall, evaporation and seepage of ash basin ponds, the amount of effluent may be different than influent volumes. 2.2.1 Yard-Drain Sumps The yard-drain sumps are concrete structures having four level controlled pumps each that direct wastewater from the powerhouse area to the ash basin. These pumps are operated on a rotating basis. Usually two pumps are set so that one pump is primary and the other is backup. After a selected period the controls are changed so that different pumps are utilized. The yard-drain sumps collect wastewater from many sources, such as, the filtered water system, turbine and boiler room sumps, miscellaneous equipment cooling water, foundation drainage, low volume wastes, and tunnel unwatering. The yard-drain sumps also collect some storm water runoff from the coal pile, rail access, and powerhouse roofs and pavement. Ground water from a foundation drainage system under the track hopper is also intermittently discharged to the yard-drain sumps. The combined average flow from all sources tied to the yard-drain sumps is approximately 2.43 MGD, which is pumped to the ash basin for physical and biological treatment. 2.2.2 Turbine Room Sumps The turbine room sumps collect approximately 0.35 MGD of wastewater. This wastewater comes from non-contact cooling water (from Units 1 & 2 boiler feedpump turbine lube oil coolers) and floor drains. Floor drains contain boiler blowdown, leakage from seals, equipment cooling water, condensate from the feedwater system, low volume wastewater, boiler room sump overflow, emergency fire fighting water, general mechanical maintenance activities, miscellaneous plant wastes and area washdown water. Marshall Steam Station.Catawba County NPDES Permit No. NC0004987 Page 5 of 30 2.2.3 Boiler Room Sumps The average flow pumped from the boiler room sumps directly to the ash basin is approximately 4-.-3 1_55_MGD. The sources of input to the boiler room sumps include the following: 2.2.3.1 Water Treatment System The MSS make-up water treatment system is comprised of a clarifier, three gravity filters, two sets of activated carbon filters, a reverse osmosis system and two sets of demineralizers. The water treatment wastes consist of floc and sedimentation, filter backwash, reverse osmosis concentrate reject and cleaning wastes, and demineralizer regeneration wastes. Water processed through this system is supplied to the boilers to generate steam to turn the turbines. On occasion a vendor may be used with a mobile water treatment unit to augment the facility water treatment capacity. Any vendor will use traditional water treatment methods, chemicals, and disposal methods generally described below. This wastewater is drained to the boiler room sump, which ultimately discharges to the ash basin. Clarifier: The clarifier utilizes typical water treatment chemicals such as, aluminum sulfate (alum), sodium hydroxide, and calcium hypochlorite for the primary treatment of raw water. The sedimentation wastes collected in the clarifier consists of solids that were suspended in the service water plus aluminum hydroxide precipitate formed as a result of adding aluminum sulfate (alum) and sodium hydroxide. The quantity of alum used per year is approximately 14,000 gallons. The total amount of caustic is roughly one quarter the amount of alum. The average volume of water required for desludging the clarifier is approximately 0.008 MGD. These sedimentation wastes along with dilute water treatment chemicals and by- products are piped to a floor drain which flows to the boiler room sumps where they are pumped to the ash basin via the yard-drain sump. Gravity Filters: There are three gravity filters composed of anthracite (coal) which follow the clarifier in the water treatment process. They are used for removal of colloidal material and are backwashed as necessary, dependent upon the level of solids in the water. Normally, one of these filters is backwashed each day. Approximately 0.007 MGD of backwash water is required for each filter. This flow is discharged to the floor drains to the boiler room sump, which pumps to the yard-drain sump. The gravity filter medium is changed out on an as-needed basis with the spent filter media being landfilled. Activated Carbon Filters: Two activated carbon filters remove organics and the chlorine that is injected into the clarifier. These filters are typically backwashed approximately once a week. The flow of water required to backwash one of these filters is 20,000 gallons per day. The wash water flows to the boiler room sump and is pumped to the yard- drain sump. Activated carbon is replaced on an as needed basis with the spent carbon sluiced to the pyrite system. Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 6 of 30 Reverse Osmosis System There is a two stage Reverse Osmosis (RO) system which processes approximately 535 gallons per minute of filtered water. Approximately 400 gpm of permeate water is produced and flows to the permeate water storage tank. Approximately 135 gpm of concentrate water is produced which flows to the boiler room sump and ultimately the ash basin via the yard drain sump. Water from the permeate tank is pumped to the demineralizers as supply water. The RO system is cleaned approximately twice per year using a dilute low pH cleaner(sulfonic acid/citric acid), biocide (Trisep Tristat 110), and a high pH cleaner(sodium hydroxide/sodium lauryl sulfate). Demineralizers: Demineralizers at MSS consist of two sets of mixed-bed cells which supply make-up water to the boilers and other closed systems. Normal plant operation requires that only one cell of each demineralizer set operate at any one time. Each cell has a capacity of 225 gpm. Each cell is regenerated approximately every four weeks. Each year MSS will use an estimated 8,000 gallons of 50% caustic and 2,500 gallons 93% sulfuric acid for demineralizer regenerations. The dilute acid and caustic are discharged from the cell simultaneously through the same header for neutralization purposes. The regeneration wastes flow to the boiler room sumps where it is pumped to the ash basin via the yard-drain sump. The useful life of the resin varies and when replaced spent resin is sluiced to the ash basin. 2.2.3.2 Miscellaneous Waste Streams • Closed system drainage, cleanings, testing containing corrosion inhibitors (Calgon CS), biocides (Calgon H-550 and H 7330), cleanings) (small heat exchangers), dispersant (polyacrylamide), wetting agent (sodium lauryl sulfate), detergent (tri-sodium phosphate), and leak testing (disodium fluorescing dye). • Turbine room sump overflow • Boiler seal water(trace oil and grease) • Miscellaneous system leakages (small leaks from pump packings and seals, valve seals, pipe connections) • Moisture separators on air compressor precipitators • Floor wash water • Emergency fire fighting water • Pyrite (ash) removal system overflow • Low Volume Wastewater. 2.2.3.3 Chemical makeup tanks and drums rinsate Intermittent rinse water containing small amounts of aluminum sulfate, sodium hydroxide, hydrazine, ammonium hydroxide. 1 To date small closed system cleanings (e.g. heat exchangers) have not used these chemicals, reserved for future use. Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 7 of 30 2.2.3.4 Boiler blowdown Primarily when units 1 & 2 startup and until water chemistry stabilizes the blowdown from these boilers is allowed to flash in a blowdown tank. During startup a significant portion of this blowdown steam is vented to the atmosphere. After water chemistry has stabilized, blowdown venting is minimal and condensate flow is small. Trace amounts of hydrazine, ammonia, and silica oxide may be present in the condensate. The combined condensate flow from blowdown amounts to an average of approximately 0.002 MGD. This flow is routed to the boiler room sump and then to the ash basin. 2.2.3.5 Boiler Cleaning Boilers #1, #2, #3 and #4 at MSS are chemically cleaned on an as needed basis. Tube inspections are performed during outages, which indicate when cleaning needs scheduling. Boilers #1 and #2 are controlled circulation boilers and boilers #3 and #4 are supercritical boilers. The wastes produced from a boiler chemical cleaning are pumped to the ash basin. Boilers #1 and #2 each have a water-side volume of 51,600 gallons. The volume of #3 and #4 boilers is 35,300 gallons each. The total volume of dilute waste chemicals, including rinses, discharged from #1 or #2 boilers during a chemical cleaning is 580,000 gallons. The total volume of dilute waste chemicals drained from #3 or #4 amounts to 320,000 gallons. This dilute wastewater is drained through temporary piping to permanent ash removal piping where flow goes to the ash basin. The chemicals and approximate amounts for each cleaning are listed below. CLEANING CHEMICALS AMOUNT USED PER UNIT 1st Step (Alkaline Boilouts - only after major boiler tube work) Boiler#1 or#2 Boiler#3 or#4 Soda Ash 4400 lb NA Trisodium Phosphate NA 3000 lb Triton X-100 Detergent (0.05%) 25 gal 18 gal Antifoam Agent (0.025%) 13 gal 9 gal 2"d Step (Copper Removal Solution) Boiler#1 or#2 Boiler#3 or#4 Sodium Bromate 550 lb NA Ammonium Bicarbonate 1000 lb NA Ammonium Hydroxide 1000 gal NA (26°Be') Sodium Sulfite 100 lb NA 3rd Step (Iron Removal Solution) Boiler#1 or#2 Boiler#3 or#4 Hydrochloric Acid (31.5%) (20°Be') 7100 gal 4800 gal Ammonium Bifluoride (0.5%) 2150 lb 1500 lb Copper Complexer (0.75%) 2300 lb NA Thiourea or equivalent Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 8 of 30 Rodine 213 (acid inhibitor) 142 lb 96 lb Citric Acid 400 lb 300 lb 4th Step (Neutralization Solution) Boiler#1 or#2 Boiler#3 or#4 Soda Ash 4400 lb NA Trisodium Phosphate NA 3000 lb Prior to a boiler cleaning the ash basin water level is lowered and additional stop logs are added to the ash basin discharge structure. This process assures longer retention time of the chemical wastes for proper treatment through dilution, neutralization, precipitation, and ion-exchange as documented in the Ash Basin Equivalency Demonstration (October 1976). Alternately, the boiler may be cleaned using ethylenediaminetetraacetic acid (EDTA). If EDTA is used for cleaning, no waste water will be discharged to the ash basin, rather all cleaning waste waters will either be evaporated in the boiler or collected and transported off-site for proper treatment and disposal. 2.2.4 Stormwater Runoff The ash basin collects/receives flows from the yard drainage basin, ash removal lines and rainfall run-off from the basin watershed area. Details of storm water the runoff that flows into the ash basin is described in section 4.3. 2.2.5 Induced Draft Fan Motor Bearing Cooling Water Once through non-contact cooling water is supplied to eight induced draft (ID) fan motor bearings to remove excess heat. No chemicals are added to the once through raw lake water. The rate of flow through the ID fan heat exchangers that discharges to the yard- drain sumps is approximately 0.08 MGD, which is pumped to the ash basin. 2.2.6 Track Hopper Sump The track hopper sump collects ground water from a foundation drain system underneath the track hopper. The flow is usually intermittent; however, the pump capacity is 100 gpm. On a daily basis it is estimated that the run time is only 50°Ao which would correspond to a flow of 0.07 MGD to the yard-drain sumps, which is pumped to the ash basin. 2.2.7 CCW Tunnel-Unwatering Sump In the event that maintenance activities are needed in the intake or discharge tunnels an unwatering sump is provided to remove water from the tunnels. Raw water in the tunnels can be pumped to the yard-drain sumps that ultimately discharge to the ash basin. 2.2.8 Turbine Non-Destructive Testing Bore sonic testing of turbine rotors is infrequent, once every 5 years. Demineralized water is mixed with a corrosion inhibitor, e.g. Immunol 1228, at a ratio of 100 parts water to 1 part inhibitor. The mixture is applied to the turbine rotors. The excess is drained and mixed with low volume wastewater and discharged to the ash basin via the yard-drain sumps. Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 9 of 30 2.2.9 Ash Sluice MSS utilizes electrostatic precipitators as its air pollution control devices. Under normal plant operations, the dry fly ash captured in these precipitators is collected in temporary storage silos for subsequent disposal in a permitted on-site structural fill or for recycling in off-site ash utilization projects. If the system that collects the dry fly ash is not operating, the fly ash can be sluiced to the ash basin. Bottom ash from the boilers is usually sluiced with water to a holding cell for recycling activities. Pyrites from the mills are sluiced with water to an ash basin settling-cell. Approximately 3.21 MGD of fly/bottom ash and pyrite sluice is pumped through large steel pipes (ash lines) directly to the ash basin settling-cell. Once through non-contact cooling water from the coal pulverizing mill is discharged to the bottom ash hopper and pumped to the ash basin. Electrostatic precipitators at MSS are normally cleaned by mechanically vibrating the wires and rapping the plates inside the precipitator. Before major precipitator work is performed they are cleaned by a wash down. The wash water is pumped to the ash basin from the yard-drain sump. 2.2.10 Sanitary Waste A sanitary waste treatment system is operational and consists of an aerated basin that provides treatment with a 30-day retention time and has a total volume of 587,000 gallons. Effluent from the aerated basin is polished further through additional residence time in the ash basin. The new system is designed for 6100 gpd (normal) and 13,500 gpd (outage). The powerhouse lift station was installed as a central collection point to receive all the sanitary waste from MSS and pump it to the aerated basin. The present lift stations serving the vendor facilities and Units 3 and 4 have been upgraded. The sanitary system accommodates wastewater flow from the following sources: • General plant sanitary wastewater • Vendor facilities sanitary wastewater • Laboratory drains (Small amounts of laboratory chemicals used to test wastewater effluents and high purity boiler water, see the following table for non-hazardous substance). Substance I Quantity I Location 2-Propanol 4 gal. Lab/Warehouse Glycerin 4 gal. Lab/Warehouse Indigo carmine 0.3 lb Lab Dimethylaminobenzaldehyde 0.22 lbs Lab Table values represents typical quantities on-site at any given time and do not necessarily reflect quantities discharged. 2.2.11 Ash Silo Storm Water Sump A new ash silo system has been constructed for dry handling of the ash. This system includes a sump for collection of rainfall runoff and washdown of the silo area, which is Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 10 of 30 pumped to the ash basin. This sump's drainage area is approximately 1 acre. Overall, this will be a minimal input to the ash basin. 2.2.12 Wastewater from Recent Plant Additions 2.2.12.1 Selective Non-Catalytic Reduction (SNCR) As part of the compliance with the North Carolina Clean Air Initiative (NCCAIR), Marshall installed urea based "trim" Selective Non-Catalytic Reduction (SNCR) systems on units 1, 2, and 4. The trim SNCR systems are expected to reduce NOx emissions by approximately 20%. SNCR systems operate by injecting urea liquor into the upper section of the boiler where a chemical reaction occurs to reduce the NOx to water and nitrogen. Some residual ammonia will be collected in the fly ash from the electrostatic precipitators. The majority of this ammonia will stay with the ash as it is handled dry but a small amount may be carried to the ash basin. However, the operation of the SNCR system is not expected to require additional treatment capabilities to ensure compliance with NPDES permit limits. Marshall units 1, 2, and 4 currently are using this technology to reduce NOx whereas unit 3 operates a Selective Catalytic Reduction (SCR) system. 2.2.12.2 Selective Catalytic Reduction (SCR) As part of the compliance with the North Carolina Clean Air Initiative (NCCAIR), Marshall has replaced unit 3's SNCR with a more efficient Selective Catalytic Reduction (SCR) system, capable of reducing NOx by approximately 90%. This SCR utilizes a urea to ammonia (U2A)which converts the urea liquor into an ammonia gas, external to the boiler in a hydrolyzer. The hydrolyzer contains approximately 1000 gallons of urea while in operation and periodic blowdowns occur to flush out sediment in the bottom of each hydrolzer. Small quantities of urea will be discharged into the ash basin from the blowdown process. Roughly, 10 gallons a week is discarded during the blowdown process and is collected in the ash basin. Similar to the SNCR, the SCR will also result in small traces of ammonia in the fly ash that is collected from the electrostatic precipitators. The majority of this ammonia will remain with the ash as it is handled dry but a small amount may be carried to the ash basin. However, the operation of the SCR system is not expected to require additional treatment capabilities to ensure compliance with NPDES permit limits. 2.2.12.3 Flue Gas Desulfurization (FGD) The installation of a Wet Flue Gas Desulfurization (FGD) system was completed in 2006 at Marshall for Unit 4. The remaining units FGD systems were completed in 2007. The FGD is an air pollution control system that removes SO2 from the flue gas system. In a Wet Scrubber system the SO2 component of the flue gas produced from the coal combustion process is removed by reaction with limestone-water slurry. The particular system used at Marshall will collect the flue gas after it passes through the electrostatic precipitator and route the gas into the lower end of a vertical tank. As the gas rises through the tank to the outlet at the top, the gas passes through a spray header. An atomized slurry of Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 11 of 30 water and limestone droplets is continually sprayed through this header into the stream of flue gas. The SO2 in the flue gas reacts with the calcium in the limestone and produces SO3. The SO3 slurry falls to the bottom of the tank where a stream of air is injected to oxidize the slurry to form gypsum (CaSO4•H2O). The gypsum slurry is drawn off the tank to a hydrocyclone and subsequently routed to a vacuum belt filter. The liquid waste from this process will be treated as wastewater in the constructed treatment wetlands. The effluent from the CTW discharges to the ash basin (via NPDES Internal Outfall 004). The FGD system requires a material handling system that supplies limestone to the scrubber and a gypsum storage area for the gypsum removed from the process. The limestone comes into the site by rail and is stored in an area near the coal pile. It is then transferred to the FGD site via a covered conveyor. Runoff from the storage area is routed to the ash basin. The gypsum is routed from the FGD tank via a covered conveyor belt that carries it to a storage pile. The runoff from this area is also routed to the ash basin. The FGD system also requires a gypsum landfill. The FGD landfill is located west of the Marshall Ash Basin. The runoff and leachate from this landfill is routed to the ash basin. FGD residue material that is not suitable for beneficial use as wallboard will be placed in the landfill. In addition to this material, material is periodically removed from the clarifier stage of the wastewater treatment system and placed in the landfill. The landfill footprint contains approximately 20.64 acres. The FGD residue is conveyed to the landfill site by truck, where the material is spread and compacted. The landfill began receiving FGD residue in the fall of 2006. The volumetric capacity of the landfill is 2.19 million yd3' Duke Energy is exploring other beneficial uses for the FGD residue (gypsum). If these options are determined to be viable, the FGD residue meeting the material requirements for the beneficial uses will not be disposed in the landfill. 2.2.13 Wastewater from Future Plant Additions Construction of an industrial waste landfill is scheduled to begin in early 2010. Landfill operation is slated for late 2010. Fly ash, FGD gypsum and clarifier sludge will be disposed in this landfill. Landfill runoff and leachate will be routed to the ash basin for treatment. 2.3 Outfalls 002A and 002B - Yard-Drain Sump Emergency Overflow An overflow pipe that could direct flow from the sump to Lake Norman was included in the construction of the two yard sumps. This modification was performed to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. Outfall 002A has overflowed five times between April 2007 and March 2009. Outfall 002B has overflowed two times between April 2007 and March 2009. Observations and monitoring of effluent during these events have indicated no noticeable impact to water quality. No sanitary waste is routed through the yard-drain sumps. 2.4 Outfall 003 - Unit 4 ID Fan Control House Cooling Water Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 12 of 30 Once through non-contact cooling water is supplied to the Unit 4 induced draft (ID) fan motor control-house equipment to remove excess heat. No chemicals are added to the once through raw lake water. The flow rate through the control equipment that discharges to Lake Norman is approximately 0.2 MGD. 2.5 Internal Outfall 004—Treated FGD Wet Scrubber Wastewater The wastewater from the FGD system is conveyed to the wastewater solids removal system, which discharges into the mixed equalization tank. The wastewater contained in the equalization tank is conveyed to the flocculating clarifier which is utilized as the liquid/solids separation device. Polymer may be injected to aid in the settling process. Clarified effluent is conveyed to the Constructed Treatment Wetlands (CTW) supply tank. Settled solids are removed from the clarifier by the operating sludge transfer pump and conveyed to the mixed sludge holding tank and dewatered by the filter presses. Dewatered cake from the filter presses is ultimately landfilled. Filtrate from the dewatering process is conveyed to the equalization tank for reprocessing. The CTW system receives wastewater from the clarifier unit where it enters two equalization basins, each with a 24-hour hydraulic retention time (HRT) for cooling, mixing, concentration equalization, and settling of solids. Water from the equalization basins is normally split into three equal flows, each entering a treatment train consisting of two 1.28 acre wetland cells (36 hour HRT), a 0.24 acre rock filter and a 1.67 acre final wetland cell (64 hour HRT). Total area of treatment is approximately 15 acres with a normal HRT of 8 days based on average projected flows. The CTW system will treat an average flow of 1.2 and a peak flow of 1.4 MGD. 3.0 Additional Information FUEL AND OIL STORAGE TANKS The following above ground fuel and oil storage tanks are located at MSS: • two 500 gallon, • three 1,000 gallon, • 2,000 gallon, • 5,000 gallon • two 500,000 gallon fuel-oil tanks; • 1000 gallon gasoline tank; • four 750 gallon lubricating-oil tanks; • 500 gallon hydraulic-oil tank; • 900 gallon used-oil tank; • 8000 gallon used-oil tank (inside the powerhouse). At the time of this application, only one of the 500,000 gallon fuel-oil tanks is in service. All above ground tanks at MSS have secondary containment provided that is capable of containing the entire contents of the tank. Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 13 of 30 All oil storage facilities and oil filled equipment are presently covered under Spill Prevention Control and Countermeasure Plans (SPCC)2. 4.0 STORMWATER 4.1 Site Description The site covers 2,043 acres. The station includes a plant yard of 28 acres, a six acre switching station, and a coal storage yard of 36 acres. A 450-acre portion of the headwaters of Holdsclaw Creek serves as an ash-settling basin with regulated outflow to Lake Norman. Marshall Steam Station has recently undergone a large amount of construction. The site has added a Flue Gas Desulfurization (FGD) system, a Selective Catalytic Reduction (SCR) system, a wetlands wastewater treatment plant, a limestone unloading/stacker system, a gypsum stacker, a FGD landfill and various storage and maintenance buildings. Approximately 80 acres northeast of the FGD landfill are being used to place flyash in a structural fill. A 58 acre retired ash landfill is located east of the ash basin. A new ash landfill is currently under construction. The site has a sanitary wastewater treatment lagoon and several construction spoil areas. There are approximately six miles of rail access and three miles of paved roadways on-site. Soils at Marshall Steam Station are typical of the region and are predominantly micaceous sandy silts and silty sands with some clayey sands in flatter areas. The topography is generally flat with rolling hills in outlying, undeveloped areas. In developed areas, runoff is collected by catch basins and conveyed through a buried network of corrugated metal pipes (CMP). The network was originally designed to route flow to several primary trunk lines, which discharged directly to Lake Norman. In 1976 runoff from most areas with significant materials and activities was routed through either the yard holding sumps or the oil trap tank. Effluent from the yard holding sumps is pumped to the ash basin. Storm water processed through the oil trap tank is discharged to Lake Norman. Storm water runoff from the FGD area enters yard drains and is then routed via gravity flow through subsurface piping to a storm water detention pond. This pond then discharges to the station transfer sump and then to Yard Sump No. 2. Yard sump No. 2 eventually discharges via the ash basin. Runoff from the FGD Landfill, the Beneficial Structural Fill Area, the Closed Ash Landfill, the Gypsum Stacker, the Limestone Stacker, the FGD Constructed Wetlands and the Bottom Ash Operations all eventually drain into the ash basin. Marshall Steam Station has 11 storm water discharges and six NPDES process water outfalls. Four of the NPDES outfalls also contain storm water. The storm water discharges are described in Section 4.3. The six NPDES discharges are described as follows: • NPDES Outfall #001 — Once-Through Cooling Water 2 SPCC Plan required by 40 CFR 112. Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 14 of 30 This discharge contains non-contact cooling water from plant equipment. • NPDES Outfall #002 - Ash Settlings Basin Discharge This discharge is the outflow from the ash-settling basin. Plant wastewater including ash sluicing, treated sewage, equipment discharge, and chemical waste goes to the ash basin. Runoff from the coal pile, bottom ash operations, beneficial structural fill area and the closed ash landfill is routed to the ash basin via surface ditches. Runoff from the plant yard is routed to the ash basin via the yard sumps. Additionally, drainage from the newly constructed areas of the site such as FGD storm water, FGD process water treated via the constructed wetlands system, treated water from the WWTP, the FGD landfill and drainage from the gypsum and limestone radial stackers go to the ash basin. • NPDES Outfall 002A—Yard Sump #1 Overflows If the yard sump were inundated during a large storm event or spill, or if the power failed, the overflow would be conveyed to Lake Norman through Outfall SW007. Overflow from the yard sump is not a normal occurrence. • NPDES Outfall 002B —Yard Sump #2 Overflows This outfall is the emergency overflow for yard sump #2. • NPDES Outfall #003 — Non-contact Cooling Water from the Induced Draft Fan Control House This is air conditioning condensate from the heat exchanger for the Unit 4 ID Fans electronics. This outfall also conveys yard drainage and is dually listed as Outfall SW009 in Section 2.2. • NPDES Internal Outfall #004 — Treated FGD Wet Scrubber Wastewater to Ash Settling Basin 4.2 Facility Drainage and Inventory of Significant Materials and Controls Based on pipe networks and site topography, the Marshall Steam Station site was divided into individual drainage basins as shown on the attached site drawings. This section details eleven storm water outfalls to Lake Norman. To provide a complete description of the storm water drainage system, the yard sump system is also characterized. Additional outfalls have been excluded because either they have been abandoned or because runoff is from a small area, which does not contain significant materials. A description of the drainage area, significant materials, and material control measures is presented for each drainage basin. In addition to the significant materials particular to each drainage basin, herbicides are applied to selected areas throughout Marshall Steam Station to eliminate undesirable vegetation along railways, ash pipelines, and the perimeter fence. Herbicides are also applied, as needed, in the gravel parking lots, switchyard, and laydown areas. Herbicides are sprayed around the fuel oil bulk storage tanks, yard sumps, transformers, trailers, and the intake structure. All herbicides used at Marshall Steam Station are approved by the company and considered safe to the environment when used according to directions. Records are retained at the site which document information such as: the areas treated, the herbicide used and the amounts of herbicide used Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 15 of 30 Flyash is loaded and transported daily through the site. New ash storage silos have been built to the west side of the intake canal, north of the plant. Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 16 of 30 4.3 Stormwater Outfall Drainage Areas • Outfalls SW001 through SW005, "Drainage Areas 1-5"- Miscellaneous Material Storage Area Discharge Structure Outfall SW001: 24 inch (") diameter(4)) CMP Discharge Structure Outfall SW002: 2-18" 4) CMP's Discharge Structure Outfall SW003: 2-18" 4) CMP's Discharge Structure Outfall SW004: 2-18" 4) CMP's Discharge Structure Outfall SW005: This outfall was abandoned in 2001 Location: Intake Cove Drainage Area: 8.9 acres Area Description These four outfalls are located along the road adjacent to the rail lines, northeast of the ash silos. These outfalls are grouped together because they perform similar functions. This drainage area includes the slopes of the ash basin dike and the adjacent road. The embankment of the ash basin dike is sloped at a ratio of two horizontal to one vertical (2H:1 V) and covers approximately 30 percent of the drainage area. The road is 0.6 miles long. About five percent of the drainage area is paved. These outfalls do not discharge directly into Lake Norman. Runoff from the slopes of the ash basin dike is conveyed under the haul road through these pipes. Then, discharge from these pipes plus surface runoff from the area east of the road flows to the intake canal. Including the area east of the haul road, the drainage area is 22 acres. Any rainfall run-off and/or truck washing operations are collected in a local sump and pumped to the ash basin. The flyash loading area, flyash silos and truck washing areas are located within this drainage area. Additionally, ash haul trucks are washed down in this area to remove excess ash and prevent scattering ash on site roads. Significant Materials/ Controls Ash: None. Storage: Miscellaneous supplies such as steel and cable are stored outdoors in a lay-down area within this basin. • Outfall SW006, "Drainage Area 6" Discharge Structure: 18" 4) CMP Location: Intake Canal Drainage Area: 1.4 acres Area Description This drainage area includes a portion of the plant yard and approximately 9,000 square feet (ft2) of the roof of the warehouse. A storage shed east of the warehouse with roof area of about 3,300 ft2 is also included. A concrete pad of approximately 12,500 ft2 was poured between the warehouse and storage shed; the pad is covered but not enclosed. Railway lines pass through the area. The embankment leading to the coal pile is sloped at a 2H:1V ratio and Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 17 of 30 covers 35 percent of the drainage area. Approximately 40 percent of the drainage basin is roofed or paved. Significant Materials / Controls Oil: A two inch diameter, above grade, pipeline passes through this area and carries fuel oil from the 500,000 gallon bulk storage tank to the tractor shed Ash: Piping and discharge from the ash silo area flow through this drainage area. Drainage from the ash silos flows through the area and ends up in yard sump # 2. • Outfall SW007 / NPDES Outfall 002A, "Drainage Area 7" Discharge Structure: 60" 4) CMP Location: Intake Canal Drainage Area: 55 acres Area Description This drainage area includes a portion of the plant yard, the switchyard, the limestone stacking area, the limestone unloading area and some vegetated land. The plant yard contains a two acre parking lot and 1/2 mile of paved roadway. Roof area from the office annex, service building, and warehouse totals 35,000 ft2. Four miles of railway access cross the area. Railway and other embankments cover about 13 acres with maximum slope being 1.5H:1 V. Approximately four percent of the drainage area is surfaced or roofed. Emergency overflow from yard sump #1 would be discharged at this outfall. It should be noted that while the newly constructed limestone stacking area is located within this drainage area, drainage from this area is designed to flow into a detention pond which discharges into Yard Sump #1. Significant Materials/ Controls Gas:A 1,000 gallon, above-grade, gasoline tank is located in the yard area west of yard sump #1. The tank has integral spill containment. Oil: Transformers containing a total of 340 gallons of oil are located in the switchyard. Gypsum and Limestone: The Limestone Unloading area is located within this drainage area. Additionally, conveyors which transport limestone and gypsum are located within this drainage area. See details of yard sump #1 for emergency overflow discharge characteristics. Overflow from the yard sump is an NPDES permitted discharge. Sump overflow is not a normal occurrence. • Outfall SW008, "Drainage Area 8" Discharge Structure: 8" 4) CMP Location: Intake Canal Drainage Area: 0.1 acres Area Description This drainage area includes portions of the plant yard access road. Approximately 70 percent of this area is paved. Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 18 of 30 Significant Materials / Controls Significant materials are not typically stored in this drainage area. • Outfall SW009 / NPDES Outfall 003, "Drainage Area 9" Discharge Structure: 36" 4 CMP Location: Intake Canal Drainage Area: 3.6 acres Area Description This drainage area includes a portion of the plant yard and about one acre of grassy, undeveloped land. The powerhouse roof for Unit 4 covers 63,800 ft2. The roofs of various other structures such as the ID fan electronics building cover approximately 4000 ft2. In this area, the plant yard covers about 2.2 acres and contains 600 feet of railways and 600 feet of paved roadways. About 50 percent of the total drainage area is either paved or roofed. On the south and east sides of this basin, the plant yard is surrounded by embankments which slope towards the plant yard at 1.5H:1V. Office trailers, equipment, and materials are stored temporarily in this area during outages. The building, which houses the electronic equipment that controls the Unit 4 variable speed, ID fans is located in this drainage area. The electronics must be air conditioned, and the non- contact drain water from the air conditioner heat exchanger is discharged at this outfall as NPDES permitted discharge #003. There are four transformers associated with the variable speed ID fans. These transformers are located within this drainage basin, but the containment pits beneath them drain to yard sump #2. Units 3 and 4 precipitators are located in this drainage area. A transfer sump is located within this drainage area. This sump accepts drainage from a storm water detention pond located south of this area and transfers this drainage into yard sump # 2. In the unlikely event of an overflow from this transfer sump, this storm water could enter drainage area 9 and be discharged via Outfall SW009. However, this sump has engineered controls in place (e.g. high level alarms, float valves, etc.) which should minimize this threat. Significant Materials/ Controls Significant materials are not typically stored in this drainage area. Storage: This area is used temporarily as a laydown area during outages. • Outfall SW010, "Drainage Area 10" Discharge Structure: 30" 4 CMP Control Structure: 22,000 gallon oil trap tank Location: Discharge Canal Drainage Area: 11.7 acres Area Description This drainage basin includes a portion of the plant yard and the fuel oil unloading area. The plant yard contains the Unit 4 transformers, hydrogen and nitrogen tanks, three 46,000 gallon urea tanks and two 500,000 gallon oil tanks. One of the oil tanks is closed and locked out. Embankments with maximum slope of 1.5H:1 V cover about 2.4 acres. There are Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 19 of 30 approximately 0.3 miles of paved roadway and 0.2 miles of railways. Ten percent of the area is paved. All yard drainage in this basin is processed through a 22,000-gallon oil trap tank. Storm water passes through the tank and discharges to Lake Norman, and oil is contained within the trap tank. The oil trap tank is inspected periodically and cleaned out as needed. Significant Materials / Controls Oil: Two 500,000 gallon bulk storage fuel oil tanks are located in the southwest corner of the plant yard. Currently, only one of the tanks is in service; the other is closed and locked out. The tanks are aboveground, galvanized steel cylinders and are surrounded by an earthen berm sufficient in height to contain a total spill of both tanks plus rainfall. Rainfall collected within the containment berm is inspected for the presence of oil before being drained through a manually operated siphon to the oil trap tank. In the fuel oil unloading area, fuel oil is transferred from an 8,000 gallon tanker truck by aboveground pipeline to the 500,000 gallon oil tank. DOT unloading procedures are followed. The unloading area encompasses about 0.9 acres and is surrounded by a four inch berm. Catch basins drain to a 12 inch CMP that is routed to the oil trap tank. The Unit 4 main transformer and three smaller transformers located within this drainage area contain a total of 30,536 gallons of oil with 14,120 gallons in the Unit 4 transformer, 10,398 gallons for CT1, and 3,009 gallons each for 4T1 and 4T2 and 6,671 gallons for each SCR T3 and T4. The containment pits beneath the transformers drain to the oil trap tank. The transformer yard is surrounded by a 4 inch concrete curb. Urea: Three 46,000 gallon urea ASTs have recently been installed within this drainage area and are located adjacent to the bulk fuel ASTs within the earthen berm. • Outfall SW011, "Drainage Area 11" Discharge Structure: 24" 4 CMP Location: Discharge Canal Drainage Area: 0.6 acres Area Description This outfall conveys overflow from the raw water tank, which is used to store fire protection water. The basin is a small grassy area. There are no significant materials stored within this basin. • Outfall SW012, "Drainage Area 12" Discharge Structure: 24" 4 CMP Location: Discharge Canal Drainage Area: 2.5 acres Area Description This outfall conveys sheet flow runoff from areas immediately north and west of the FGD. This drainage area includes a gravel parking area located north of the FGD. There are no significant materials stored within this basin. Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 20 of 30 4.4 Yard Sump Systems There are two yard holding sumps at Marshall Steam Station. • Yard Sump #1 Yard sump #1 is located west of the coal transfer house, and effluent is pumped to the ash basin. This yard sump collects runoff from two drainage basins, and the total drainage area is 8.8 acres. Emergency overflow for yard sump #1 would go to NPDES Outfall 002A, which is also Outfall SW007. The drainage basins which discharge into this sump are defined as 1A and 1 B and are discussed below: Yard Sump Drainage Area 1A: Drainage Area: 3.4 acres Area Description Drainage area 1A consists of the Drainage collected from a portion of the plant yard west of the powerhouse which contains the Units 1, 2, and 3 transformers. From inside the powerhouse, the turbine room sumps and all equipment located in the western half of the building discharge effluent to this sump. Approximately 0.5 miles of railways and 0.25 miles of paved roadways cross the area. Approximately 21 percent of the drainage area is paved or roofed. Significant Materials / Controls Oil: The Units 1, 2, and 3 transformer yards are located in this drainage area and contain a total of 82,011 gallons of oil. Oil contents are as follows: Unit 1: 18,270 gallons 1T: 3,043 gallons CT 1 and 2: 10,395 gallons Unit 2: 18,270 gallons 2T: 3,362 gallons Unit 3: 22,920 gallons 3T1: 2,810 gallons 3T2: 2,941 gallons FGD T1: 8,490 gallons FGD T2: 9,088 gallons The transformers have containment pits beneath them, which vary in depth up to 24 inches. The transformer yard is surrounded by a 4 inch concrete curb. Yard Sump Drainage Area 1 B: Drainage Area: 5.4 acres Area Description Drainage Area 1 B is collected from a portion of the plant yard, which includes coal handling facilities, chemical storage, and compressible gas storage. The roofs of the coal handling facilities, storage sheds, and tractor shed cover approximately 20,000 ft2. The newly constructed limestone stacker discharges into a storm water detention pond which is engineered to discharge into Yard Sump 1. Embankments cover about 1.3 acres and are sloped 2H:1 V or less. Approximately 0.5 miles of railways and 0.25 miles of paved roadways cross the area. Approximately 35 percent of the drainage area is paved or roofed. Significant Materials / Controls Oil: A 1,000 gallon fuel oil tank is located beside the tractor shed. The tank sits on a concrete • pad and is surrounded by a concrete berm; a drain valve controls discharge from the enclosure. Both a tractor and a bulldozer refueling station are located beside the tractor Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 21 of 30 shed. 2,000 gallons of oil and torque fluid are stored inside the tractor shed within a bermed area. A 500 gallon tank of hydraulic fluid is located beside the coal dumper/crusher building. Two small transformers, each containing 188 gallons of oil, are located near the switchgear house. A transformer located at the sump #1 control system contains 270 gallons of oil. Chemicals: The chemical storage building contains sodium nitrate, ammonia, and hydrazine and has approximately 500 ft2 of floor space. The concrete floor is sloped to floor drains which are routed to yard sump #1. Hazardous Waste: A 55 gallon drum is used to temporarily store paint waste in a satellite accumulation area. The drum is covered inside a cage. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to yard sump #1. This wastewater may include oil, chemicals, and hazardous material spills. • Yard Sump #2 Yard sump #2 is located east of the service building and north of Stack #1. The drainage area for this sump covers 39.2 acres. This yard sump collects runoff from two drainage basins. The drainage basins which discharge into this sump are defined as 2A and 26 and are discussed below: Drainage Area 2A Drainage Area: 9.2 acres Area Description Drainage is collected from the plant yard east of the powerhouse and 161,000 ft2 of the powerhouse roof at Units 1, 2, and 3. From inside the powerhouse, boiler room sumps and all equipment located in the eastern half of the building discharge effluent to this sump. The plant yard includes the precipitators, smoke stacks, and ID fans. Cooling water from the ID fans bearings for all four units is processed through this sump. There are approximately 800 linear feet of paved roadway and 1,200 linear feet of railways in this area. The paved and roofed areas represent approximately 90 percent of the drainage area. Effluent from yard sumps is pumped to the ash-settling basin. Emergency overflow would discharge at NPDES 0026. Significant Materials / Controls Oil: Transformers located atop the precipitators contain a total of 10,848 gallons of oil. The maximum reservoir size in any one transformer is 176 gallons. There are four transformers associated with the Unit 4 variable speed ID fans. These transformers are located within the drainage basin of outfall #SW009, but the containment pits beneath them drain to yard sump #2. The basins beneath the transformers are sufficiently deep to contain a total spill. Two of the transformers each contain 401 gallons of oil, and the other two hold 364 gallons each. The total amount of oil in these transformers is 1,530 gallons. Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 22 of 30 A transformer located at the yard sump #2 control system contains 270 gallons of oil. There is a 900-gallon used oil tank located between Units 2 and 3 for Marshall Steam Station generated used oil. Sulfuric Acid: A 5,000 gallon tank of sulfuric acid is located near the southeast corner of Unit 2. The tank has a concrete pit with drain valve, which is capable of complete containment. Ash: Waste ash is sluiced across the area to the ash basin. Within the plant yard, the pipelines are contained in concrete trenches; storm water that collects in the trenches drains to yard sump #2. Beyond the plant yard, ash lines pass overland. There is a small berm between the ash lines and the ash haul road to direct spills back to the concrete trench. Flyash is transferred from the plant to the ash silos now located on ash haul road through above grade pipelines. The two ash silos can each store 2861 tons of ash. The ash is transferred from the silos to trucks for transport to either off-site facilities or the on-site structural fill project. Other facilities within the area, which collect, handle, or store ash include: baghouses, pumps, blowers, hoppers, and precipitators. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to yard sump #2. This wastewater may include oil, chemical, and hazardous material spills. Cooling water from Units 1, 2, 3, and 4 ID fan bearings is discharged to this sump. Drainage Area 2B Drainage Area: 30 acres Area Description Drainage area 2B includes the newly constructed FGD, the Wastewater Treatment Plant and ancillary parking areas that serve these areas. Catch basins located along the additional 2000 ft2 of roadway and parking lots within these areas route storm water into a detention pond located at the southeastern corner of the drainage area. Discharge from this pond is pumped into the transfer sump (located in the adjacent Drainage Area 9). The storm water is then pumped from the transfer sump into Yard Sump 2. Effluent from yard sumps is pumped to the ash-settling basin. Significant Materials/ Controls Oil: Transformers located north of the switchgear building contain a total of 5,300-gallons of oil. The maximum reservoir size in each of the four transformers is 1,325-gallons. A containment pad is located at the base of these transformers. An emergency quench pump fuel oil tank is located on the north end of the absorber building. This tank has a capacity of 100 gallons. This AST is located within containment. The fill station for this AST is located at the tank. Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 23 of 30 Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to the WWTP located within this drainage area. After treatment, this waste water is pumped via underground piping to the constructed wetlands treatment system and is eventually discharged via the ash basin. This wastewater may include process water from the FGD as well as oils, chemicals, and hazardous material spills. Gypsum and Limestone: Overhead conveyors which transport limestone and gypsum are located within this drainage area. However, these conveyors are covered and should not represent a significant threat to storm water. Additionally, areas where these conveyors cross roads or ponds are completely encapsulated to further minimize the threat of a release. 4.5 Other Drainage Areas • "Drainage Area 13"- Gypsum Radial Stacker Discharge Structure: Two 24" 4 CMP Location: Detention Pond Drainage Area: 6 acres Area Description This drainage area consists of sheet flow and piped runoff from the gypsum stacking area and soil borrow area. Gypsum is a byproduct of the FGD area. It is transported by covered conveyors from the FGD site to the gypsum stacker area, where it is stacked in a radial fashion. The soil borrow area adjacent to the radial stacker also contributes to this drainage area. The drainage from the soil borrow area consists of the portion closest to the road. Drainage from these areas is engineered to flow into a storm water detention pond, which discharges into a finger of the ash basin. Discharge from this finger eventually reaches the ash basin. Significant Materials/ Controls Oil: A 500-gallon AST and a 5,000-gallon AST containing fuel oil are located within this drainage area. These ASTs are situated within a plastic-lined containment basin with no drain. These ASTs are owned and operated by Southeastern Fly Ash (SEFA). Gypsum: Gypsum is stacked in the area until it is shipped off by trucks to the wallboard facility. The gypsum piles are contained on three sides by a berm to prevent storm water runoff to these areas. The north side of the area is open to convey the storm water through roadside ditches into two pipes which drain into a detention pond. • "Drainage Area 14"- Soil Borrow Area Discharge Structure: 24" 4 CMP Location: Detention Pond Drainage Area: 6 acres Area Description This drainage area consists of sheet flow from the soil borrow area. The drainage from the soil borrow area is limited to the half farthest from the road. Drainage from this area is engineered Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 24 of 30 to flow into a storm water detention pond which discharges into a small creek. No significant materials are located within this drainage area. • "Drainage Area 15"- FGD Landfill Discharge Structure: 24" 4) CMP Location: Finger of the Ash Basin Drainage Area: 20 acres Area Description This drainage area is composed of the entire FGD landfill. Significant Materials/ Controls Gypsum: Gypsum is one of the significant materials associated with the drainage area. Gypsum that cannot be sold and is not of quality is disposed of in this area. The surface water flow from the landfill will typically collect at the lower end of the cell and discharge into the storm water collection pond located at the southern end of the landfill. From the storm water basin, the runoff is piped into a finger of the ash basin that eventually discharges into the ash basin. FGD Wastewater Treatment Sludge: The sludge scrapped from the bottom of the wastewater treatment facility is brought to the gypsum landfill. This process is performed because the wastewater sludge is mixed with the gypsum to form a more dense substance that will not be carried by the wind. Other Materials in Landfill Include: asbestos, flyash, bottom ash, construction and demolition debris. • "Drainage Area 16" — Coal Pile Discharge Structure: Surface Ditches Location: Discharges into Ash Basin Drainage Area: 40 acres Area Description This drainage area is composed of the entire Coal Pile. Significant Materials / Controls The coal pile is the only significant material associated with the drainage area. The surface water flow from the coal pile accumulates into ditches which surround the coal pile area. These ditches channel storm water runoff into the ash basin. A berm, which surrounds the coal pile, ensures that drainage from this area remains confined. • "Drainage Area 17" — Sanitary Wastewater Lagoon Discharge Structure: 6 " line to surface trench. Location: Discharges into Ash Basin Drainage Area: 4.5 acres Marshall Steam Station.Catawba County NPDES Permit No.NC0004987 Page 25 of 30 Area Description This drainage area is composed of the sanitary wastewater treatment lagoon and surrounding land. Significant Materials / Controls This lagoon accepts sanitary wastes from the entire plant and performs aeration treatment on this waste before it is discharged into the ash basin. Significant Materials/ Controls Sanitary wastewater would be the only significant material associated with the drainage area. • "Drainage Area 18" — FGD Constructed Wetland Treatment System Discharge Structure: 18" HDPE Location: Discharges into Ash Basin Drainage Area: 40 acres Area Description: The constructed wetland treatment system (CWTS) is designed to treat wastewater from the Flue Gas Desulfurization solid removal wastewater treatment system (WWTP). The wastewater is initially treated by the WWTP and pumped to the wetland system. All the rainfall runoff from the CWTS area flows into the ash basin. Significant Materials/ Controls There are no significant materials. The wastewater is contained in the treatment system. • "Drainage Area 19" — Bottom Ash Operation and Pyrite Operation Discharge Structure: Surface Ditches Location: Discharges into Ash Basin Drainage Area: 35 acres Area Description: This area encompasses operations which involve the bottom ash operation and recovery of coal from pyrites. All storm water discharge from this area is routed via ditches into the ash basin. Significant Materials / Controls Coal and the numerous entities recovered from the coal are processed and/or staged within this area. Oil: Charah (vendor) has a 550 gallon oil storage tank located in this drainage area. BKF has a 500 gallon oil storage tank located in this drainage area. • "Drainage Area 20" - Closed Ash Landfill Discharge Structure: Surface Ditches Location: Discharges into Ash Basin Drainage Area: 58 acres Area Description: This landfill is capped and is no longer in use. Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 26 of 30 Significant Materials / Controls: There are no significant materials.. • "Drainage Area 21"- Beneficial Structural Fill Discharge Structure: Surface Ditches Location: Discharges into Ash Basin Drainage Area: 84 Acres Area Description: This area is presently being used as a beneficial structural fill area. Significant Materials/Controls: Fly ash: Fly ash is a significant material located within this area. 5.0 Hazardous and Toxic Substances 5.1 Hazardous and Toxic Substances Table 2c-3 At MSS, the potential for toxic and hazardous substances being discharged is very low. In reference to item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are as follows: Marshall Steam Station Hazardous and Toxic Substances Table 5.1 Acetaldehyde Dodecylbenzenesulfonic Nitric Acid Sodium Hydroxide Acid Acetic Acid Ethylbenzene Phenol Sodium Hypochlorite Adipic Acid Ferrous Sulfate Phosphoric Acid Sodium Phosphate Diabasic Aluminum sulfate Formaldehyde Phosphorus Sodium Phosphate Tribasic Ammonia Hydrochloric Acid Potassium Bichromate Styrene Ammonium Hydrofluoric Acid Potassium Hydroxide Sulfuric acid Chloride Ammonium Hydrogen Sulfide Potassium Permanganate Toluene Hydroxide Antimony Trioxide Maleic Acid Propionic Acid Vanadium Pentoxide Asbestos Mercuric Nitrate Pyrethrins Vinyl Acetate Benzene Monoethylamine Sodium Xylene (Mixed Isomers) Dodecylbenzenesulfonate Chlorine Naphthenic Acidalene Sodium Fluoride Zinc Chloride Cupric Nitrate Cyclohexane Nickel Hydroxide During the course of the year products such as commercial cleaners and laboratory reagents may be purchased that can contain very low levels of a substance found in Table 2C-3. It is not anticipated that these products will impact the ash basin's capacity to comply with its toxicity limits, since their concentrations are extremely low. Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 27 of 30 5.2 40 CFR 117 and CERCLA Hazardous Substances The table below identifies hazardous substances located on-site that may be released to the ash basin during a spill. Substances listed are present in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption provided in 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). Marshall Steam Station Hazardous Substances in Excess of RQ Table 5.2 SUBSTANCE QUANTITY SOURCE Aluminum sulfate 40,987 lbs Powerhouse/Water Treatment Ammonium hydroxide 3,317 lbs Powerhouse Benzene 167 lbs Gasoline Tank Hydrazine* 2,145 lbs Powerhouse/Warehouse Methyl Tert-Butyl Ether 1,334 lbs Gasoline Tank Naphthalene 41,700 lbs Fuel Oil Tanks Sodium hydroxide 50,040 lbs Powerhouse Sulfuric acid 6,738 lbs Powerhouse Xylene (Mixed Isomers) 42,992 lbs Fuel Oil Tanks Values in Table 5.2 represent maximum quantities usually on-site at any given time and do not necessarily reflect quantities discharged. Various amounts of these substances may go to the ash basin for treatment due to use in site laboratories, small leaks, spills, or drainage from closed loop systems. Treatment of these substances and their by- products is achieved by physical and biological activity in the ash basin. *Listed in 40 CFR 302.4-Table 302.4 List of Hazardous Substances and Reportable Quantities. 6.0 Marshall Steam Station 316 Determination 6.1 316(a) Determination Duke Energy's operating experience during the past five years under the thermal limitations imposed in NPDES Permit No. NC0004987 substantiates EPA's 316(a) determination for Marshall (May 1975) that the "thermal component of the discharge assures the protection and propagation of shellfish, fish and wildlife in and on the receiving body of water." This is supported by the enclosed report entitled, "Assessment of Balanced and Indigenous Populations in Lake Norman near Marshall Steam Station". In Duke's judgment the operating characteristics of the station have a minimal effect on the aquatic environment of Lake Norman. The character of the thermal discharge has not changed since the original 316(a) determination. Accordingly, Duke Energy requests that the thermal limitations in the present permit be continued. 6.2 Marshall Steam Station 316(b) Determination In conjunction with the rulemaking process for the new Phase II 316(b) rule pertaining to fish impingement and entrainment, historical data and permitting records were reviewed. Initial 316(a) and 316(b) studies associated with enactment of the Clean Water Act concluded that the location, construction capacity, and design of the cooling water intake of Marshall and other Duke 1 Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 28 of 30 Energy steam stations were not detrimental to the aquatic ecosystem and minimize adverse environmental impacts. Both North Carolina and EPA regulators concurred in 1976 that 316(b) fish impingement and entrainment studies were no longer needed at that time. When the new Phase II 316(b) Rule (Rule) was issued, Duke Energy developed Proposals for Information Collection (PICs) and initiated approved 316(b) field studies at its applicable steam stations for the eventual development of Comprehension Demonstration Studies (CDSs) to be used to determine Rule compliance. When the Rule was remanded back to EPA for revision, CDSs were no longer applicable and state agencies were instructed to use Best Professional Judgment (BPJ) in the interim to determine 316(b) impacts or the lack thereof. Currently, Duke Energy is summarizing the results of the 316(b) study at Marshall Steam Station and will be submitting an Impingement Characterization and Adverse Environmental Impact Report, BPJ Report, and 40 CFR §122.21(r)(2), (3), and (5) Source Waterbody Physical Data, Cooling Water Intake Structure Data, and Cooling Water System Data. These reports should be ready for submittal to the NCDENR in early 2010. Ash Basin Capacity Part I Section 15 of the existing NPDES permit for Marshall Steam Station requires the permittee to provide and maintain at all times a minimum free water volume (between the top of the sediment level and the minimum discharge elevation) equivalent to the sum of the maximum 24 hour plant discharges plus all direct rainfall and all runoff flows to the pond resulting from a 10 year, 24 hour rainfall event, when using a runoff coefficient of 1.0. Determination of Wet Weather Detention Volume: Wet Weather Detention Volume is the sum of the runoff accumulated in the ash basin which results from a 10-yr 24-hr storm (assuming 100% runoff) plus the maximum 24-hr dry weather waste stream which discharges to the Ash Basin (refer to NPDES Permit NC0004961) Estimate Runoff to the Ash Basin from a 10- I. yr 24-hr storm: 1 Natural Drainage Area of Ash . Basin = 1180.0 Acres Station Yard Drainage Area Pumped to Ash Basin = 14.7 Acres Total = 1194.7 Acres 2 Precipitation from 10-yr 24-hr . storm = 5.0 Inches 3 Total Stormwater Runoff to Ash . Basin = 497.79 Acre-feet (Assuming 100% runoff) Estimated Maximum 24-hr Dry Weather Waste Stream Discharging to Ash II. Basin: 1 Maximum recorded Ash Basin . Discharge = 12,400,000 Gallons/day 1 Marshall Steam Station,Catawba County NPDES Permit No. NC0004987 Page 29 of 30 2 Increase maximum daily . disharge by 10% for conservatism and convert units to acre-feet = 41.86 Acre-feet Wet Weather Detention III. Volume: Sum of Parts I. and II. = 539.65 Acre-feet Estimated Quantity of Solids (Ash)to be discharged to Ash Basin through IV. December 31, 2015. Note: NPDES Permit expiration date is 2/28/10. Time Actual or % Ash Estimated Estimated Estimated Period Estimated Total Ash Ash Sent to Ash Coal Production Structural Fill Discharged Consumpti (1000's or Re-Used to Ash on (1000's tons) (1000's tons) basin tons) (1000's tons)** 2009 5013.00 11.10% 555.40 500.10 -31.70 2010 5012.40 11.20% 561.90 505.60 -35.70 2011 5088.80 11.80% 600.00 538.00 -5.00 2012 5083.40 11.10% 566.30 509.30 -10.10 2013 4954.40 10.60% 522.70 472.30 -16.60 2014 4929.00 10.60% 520.00 470.00 -17.00 2015 5231.20 10.60% 551.90 249.10 -12.20 Total 35312.20 77.00% ; 3878.20 3244.40 -128.30 * Calculation assumes an in-place ash density of 55 lbs. per cubic foot. ** Approximately 30,000 tons of ash are transferred from the ash basin to the on-site structural fill annually until 2011 Estimated Total Storage Volume Required V. through 2015: Wet Weather Detention Volume 539.6 Acre-feet Required Storage Volume Through 12/31/2015 = 539.6 Acre-feet Marshall Steam Station,Catawba County NPDES Permit No.NC0004987 Page 30 of 30 VI. Results: Ash Basin @ Pond Elevation 790'+0" 672.5 Acre-feet 2006 Ash Removal Project (200,000 Tons) 103.0 Acre-feet Estimated Solids to Basin Oct. 2005 - Dec. 2008 35.1 Acre-feet Total 740.4 Acre-feet Note: Available Storage based on basin survey dated 8/25/2005 Available Storage> Required Storage Based on these calculations, there is sufficient capacity in the ash basin to provide the retention volume specified in the permit through the year 2015. r,. Duke CORPORATE EHS SERVICES - Energy® Duke Energy Corporation 526 South Church St. Charlotte, NC 28202 Mailing Address: EC13K/PO Box 1006 December 2, 2009 Charlotte, NC 28201-1006 • Mr. Charles H. Weaver, Jr. State of North Carolina Department of Environment and Natural Resources DEC - 3 Division of Water Quality NPDES Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Subject: Duke Energy Carolinas LLC — NPDES Permit Application Allen Steam Station - #NC0004979 Dear Mr. Weaver: Duke Energy Carolinas, LLC requests the subject permit be renewed and reissued. The above referenced permit expires May 31, 2010. As mandated by North Carolina Administrative Code 15A NCAC 2H.0105 (e), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the renewal application, which includes the following items: EPA Form 1 EPA Form 2C EPA Form 2F Site Maps Water Flow Diagram Supplemental Information Duke Energy Carolinas, LLC requests notification that this application is complete. Additionally, the attached report, "Assessment of Balanced and Indigenous Populations in Lake Wylie," continues to indicate the maintenance of balanced indegnious populations. Therefore, this report supports renewal of the current thermal monitoring requirements of outfall #001. www.duke-energy.corn The following monitoring reductions at outfall #002 are requested based on historical monitoring data. • Reduce copper sampling from twice per month to monthly Thank you in advance for your assistance on this matter. Should you have questions regarding this application, please contact me at (704) 382-4309. Sincerely, Allen Stowe Water Management Attachments cc wiallIMINIIIIINIENNIFNCDENR Mooresville R.O. Mr. Jay Sauber— NCDENR, Raleigh, N.C. (BIP Report 3 copies) Please print or type in the unshaded areas only. Form Approved.OMB No.2040-0086. FORM U.S.ENVIRONMENTAL PROTECTION AGENCY I.EPA I.D.NUMBER 1 '+ EPA GENERAL INFORMATION �� Consolidated Permits Program F NC0004979 D GENERAL (Read the General Ins truclions"before starting.) 1 2 u 14 n GENERAL INSTRUCTIONS LABEL ITEMS If a prepnnted label has been provided, affix it in the designated space.Review the information carefully,if any of it I. EPA I.D.NUMBER is incorrect,cross through it and enter the correct data in the appropriate fill-in area below.Also,if any of the preprinted data is absent (the area to the left of the label space lists the III. FACILITY NAME PLEASE PLACE LABEL IN THIS SPACE information that should appear),please provide it in the proper fill-in area(s)below. If the label is complete and correct,you V. FACILITY MAILING need not complete Items I,III,V,and VI (except VI-B which ADDRESS must be completed regardless).Complete all items if no label • has been provided.Refer to the instructions for detailed item descriptions and for the legal authorizations under which this VI. FACILITY LOCATION data is collected II.POLLUTANT CHARACTERISTICS ' INSTRUCTIONS:Complete A through J to determine whether you need to submit any permit application forms to the EPA.If you answer'yes"to any questions,you must submit this form and the supplemental form listed in the parenthesis following the question.Mark"X"in the box in the third column if the supplemental form is attached.If you answer"no"to each question,you need not submit any of these forms.You may answer"no"if your activity is excluded from permit requirements;see Section C of the instructions.See also,Section D of the instructions for definitions of bold-faced terms. Mark'X' Mark SPECIFIC QUESTIONS YES NO FORM SPECIFIC QUESTIONS YES NO FORM ATTACHED ATTACHED A.Is this facility a publicly owned treatment works which B.Does or will this facility (either existing or proposed) results in a discharge to waters of the U.S.?(FORM 2A) X include a concentrated animal feeding operation or X aquatic animal production facility which results in a _ 16 17 16 discharge to waters of the U.S.?(FORM 2B) 19 20 21 C.Is this a facility which currently results in discharges to ‘/ �/ D.Is this a proposed facility(other than those described in A waters of the U.S.other than those described in A or B X or B above)which will result in a discharge to waters of X above?(FORM 2C) 22 23 2 the U.S.?(FORM 2D) 25 26 Zr E. Does or will this facility treat, store, or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes?(FORM 3) X municipal effluent below the lowermost stratum X containing, within one quarter mile of the well bore, 26 29 3o underground sources of drinking water?(FORM 4) 31 32 33 G.Do you or will you inject at this facility any produced water H.Do you or will you inject at this facility fluids for special or other fluids which are brought to the surface in processes such as mining of sulfur by the Frasch process, connection with conventional oil or natural gas production, X solution mining of minerals, in situ combustion of fossil X inject fluids used for enhanced recovery of oil or natural fuel,or recovery of geothermal energy?(FORM 4) gas, or inject fluids for storage of liquid hydrocarbons? (FORM 4) 34 35 36 31 39 3 I. Is this facility a proposed stationary source which is one J. Is this facility a proposed stationary source which is of the 28 industrial categories listed in the instructions and X NOT one of the 28 industrial categories listed in the X which will potentially emit 100 tons per year of any air /� instructions and which will potentially emit 250 tons per pollutant regulated under the Clean Air Act and may affect year of any air pollutant regulated under the Clean Air Act or be located in an attainment area?(FORM 5) a '1 42 and may affect or be located in an attainment area? o M 45 (FORM 5) III. NAME OF FACILITY 0 1 SKIP A len Steam Station 15 16-29 30 ea IV. FACILITY CONTACT A.NAME&TITLE(last,first,&title) B.PHONE(area code&no.) l211 1 I I I J 1 1 Il 1 } 1 1 1 1 1 1 1 1 I i 1 1 I 1 I I ( ) I32 14 0 6 l I Stowe, Allen/Env. Sp c- III 0 16 45 46 <8 Si1l9 152- 55 V.FACILTY MAILING ADDRESS A.STREET OR P.O.BOX 1=I I I 1 1 I I 1 I I, 1 I j l I I 1 1 I I 1 I I I I 1 1 I 1 l 31P.O. Box 1006, Mail Co e EC13K 15 16 45 B.CITY OR TOWN C.STATE D.ZIP CODE a Charlotte I l I l l ( I I I I I I l l l i l l l l NC 2b20I1 1 1 15 16 40 n Q Il VI. FACILITY LOCATION A.STREET,ROUTE NO.OR OTHER SPECIFIC IDENTIFIER cI 2 3 1P Iant IAten 1 1 R1 oa 1d 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 I 1 �1 5 ifi 45 B.COUNTY NAME Gaston 1 I I I I I I I I 1 I 1 I I I I I 1 I I I 46 ,0 C.CITY OR TOWN D.STATE E.ZIP CODE F.COUNTY CODE(if known) e B�1r>iorit 1 l I 1 I I I l I I l l I l I l l l l l 1 r1/C 2a 012 11 I I 15 16 40 41 42 42 51 52 d1 EPA Form 3510-1(8-90) CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII.SIC CODES 4-di.it,in order of.riorit A.FIRST B.SECOND c I I I (Fsec1/)) c 1 I I (specify) 1574 911 Electric services 7 16 � 19 15 16 - 19 C.THIRD D.FOURTH 1 l I (specify) I l l (specify) 7 ., 1 15 16 • 19 VIII.OPERATOR INFORMATION A.NAME B.Is the name listed in Item c I I I I I I I I I I I I T 1 I I I 1 I I I I I I I I I - r l i f I i T l I I VIII-A also the owner? 8 Duke Energy Carolinas, LLC (Attention: Allen Stowe) 0 YES ❑NO ,5 16 56 66 C.STATUS OF OPERATOR(Enter the appropriate letter into the answer box:if"Other."specify.) D.PHONE(area code&no.) F=FEDERAL (specify) ,_ I I I I I 1 1 1 1 S=STATE M=PUBLIC(other than federal or state) p Electric Utility A (7 D4) 3 82 4 3 0 9 P=PRIVATE O=OTHER(specify) 56 15 6 - 18 11s - 21 122 26 E.STREET OR P.O.BOX II I I I I I I ,11 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 I 1 1 P.O. BOX 1006, Mai Code EC13K 26 55 F.CITY OR TOWN G.STATE H.ZIP CODE IX.INDIAN LAND c I I I I I I I I I I I I I I I I I I I I I I I I I IIII Is the facility located on Indian lands? g Charlotte NC 28201 ❑YES 0 NO W 15 16 40 41 42 47 • 51 X.EXISTING ENVIRONMENTAL PERMITS A.NPDES((Discharges to Surface Water)) D.PSD(Air Emissions from Proposed Sources) i c T 1 I I 1 1 1 1 ( I I ( I 1 c' T I I I I I 1 1 I 1 I 1 1 1 9 N NC0004979 9 P 15 16 17 18 30 15 16 17 18 30 B.UIC(((/nderground/njection of fluids) E.OTHER((specify') c T I I 1 1 1 1 1 1 I I -1 I 1 c, T i I II I II I I I I l I l (cm im 03757T33/NCG010000 WirCfermit/General Stormwater 91U 9 5 16 1 17 18 30 15 16 17 18 30 C.RCRA(Hazardous Wastes) E.OTHER(specify)C T i 1 1 I ( 1 1 1 1 1 1 1 1 CTI IIIIIIIITIII (3pe 9 R NCD043678937 g WQ0000452/36-12 ris[tfi) _ bution of Residual Solids Permit/Industrial Landfill Permit 15 16 17 18 30 15 16 1J 18 30 XI.MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries.The map must show the outline of the facility,the location of each of its existing and proposed intake and discharge structures,each of its hazardous waste treatment,storage,or disposal facilities,and each well where it injects fluids underground.Include all springs,rivers,and other surface water bodies in the map area.See instructions for precise requirements. XII.NATURE OF BUSINESS(provide a brief description) Coal fired electric generation XIII.CERTIFICATION(see instructions) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that,based on my inquiry of those persons immediately responsible for obtaining the information contained in the application,I believe that the information is true,accurate,and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment. A.NAME&OFFICIAL TITLE(type or print) B.SIGNATU E C.DATE SIGNED Steve Immel - General Manager II, Regulated Fossil Stations 11/30/2009 COMMENTS FOR OFFICIAL USE ONLY c i C 15 16 55 EPA Form 3510-1(8-90) I. • • . rr •! ' . t• I F > c- _r .4i -1 f j ,i e •� :f- 1, - / ��... tti � / 1 � i ' • `. < pi •� F\ '"C 1: 1!Xi ��' >'- �r �Am J„Lk,`, ' •_r. a;•! 1u) +"I 't� �,ti{':_ .. ...� 1 • �, ti. • .`2, C11, /,,, �( a,` Ids r ti4. 11t} 1 L --- }'...�+V1 r l�• `I'1,� . 5`.. F \ ";'�Y . 1 1 ,1 lS' I �f1 d,‘ Z a ,;f�� ,! ..1tr I $_;t I L-S\ r .'•" .�: �� % _- 1, 111, ii 1 t `-J- ��+ • ` L- / t •, , ( ,11 1 r J !�� i ifyi+ A�4` ry =e \pil i r, -. z....� _J '1 ``ri—J ! k! s.1;>E ,,y J .r. .1 ysY�3 _t d -A, (..- 111 r— > - :eS r -- i . r . -� C i �i"�f rat j t` l:• J ' r : (l _ I ' • ?fs. P. \.\`�a17:- . y .'.T' J"f�j'j; _ • '.. 1`i ,r - � .� ,'+r _ A.�I l,�`• �, J 1:`."\J` 'AA? ;71 r>/`0+,C y k‹/'ri il •` • .1411en 1, N l,l: Li .1:• .. • `• �/- y' 1'.-:r• ?• ry arr;j •,.'_:�. of r i : Steam Station' 1 kV+ -� l i t ,_.(t • st i �I� 1! 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S. aJ r�f 11 .`4.jSi' _l..\l.'� - .�c ^�� .1 .1 �1�rr '^ / r • J,"f. �na'�I ly >y�,v��f�/ .'-,'_tl.� 'r•� /- `'� • J �', .. `'f+ �I �,,+'�/. ,�� Legend -.ai:\ ti r .� 1 E r �ti \, ,r•$gI , >>jJ • NPDESOutfall Location / • ;I._iY?ti`a'y f''� 1 � ,I, .e•7y.1•+ , 11 '-• r . `` 4.1/ .:. _ _ 1't 4f ] C y ``:j 1' i 001 1 NPDES Outfall Number ~ .4,. h r n ▪ .1 �\` • 'y Duke EnergyProperty Boundary `L ){j(�ayt.., n ? /r q .31� k } .• ��({ "t !rY 7A • �y } I ^ti o� i 5[:(t s:•�•1, .4C•:•�;-- �� f/1+• �._tS a1 w! �,`� i.f,l7,t'l t! .tr �i�1 ,1+.�r�� 'J VC'1� �- ���, r t REFERENCE: 0 0,5 1 BACKGROUND DATA:1:24000 USGS TOPOGRAPHIC QUAD(BELMONT),WAS OBTAINED KI IOmeters FROM NCDOT GEOGRAPHICAL INFORMATION(GIS)WEBSITE.THE PROPERTY DATA 0 0.5 1 • WAS OBTAINED FROM THE GASTON COUNTY NORTH CAROLINA GIS DEPARTMENT. • PLEASE NOTE THIS DATA IS FOR INFORMATIONAL PURPOSES ONLY. Miles SCALE: AS SHOWN FIGURE ���� LOCATION MAP DUKE ENERGY NO. DATE:• 10-26-2009 ALLEN STEAM STATION DRAWN BY: RDP NPDES # NC0004979 PROJECT NO: .Energy® ALLEN STEAM STATION 1411-08-140 GASTON COUNTY,NORTH CAROLINA 1 EPA I.D.NUMBER(copyfromItem l of Form l) Form Approved. NC 0 0 0 4 979 OMB No.2040-0086. Please print or type in the unshaded areas only. Approval expires 3-31-98. FORM U.S.ENVIRONMENTAL PROTECTION AGENCY GE WASTEWATER 2C -iEPA APPLICATIOEXISTING MANUFACTURING,JCOMMERC AL,MINING FOR PERMIT TO RAND SILVICULTURE OPERATIONS NPDES Consolidated Permits Program I.OUTFALL LOCATION For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A.OUTFALL NUMBER B.LATITUDE C.LONGITUDE (list) 1.DEG. 2.MIN. 3.SEC. 1 DEG. 2.MIN. 3.SEC. D.RECEIVING WATER(name) 001 35 11 22 81 00 44 South Fork River 002 35 10 30 81 00 20 Catawba River 002A/002B 35/35 11/11 13/25 81/81 00/00 21/28 Catawba River (Intermittent) 003 35 11 23 81 00 45 South Fork River 004/005 35/35 11/09 13/60 81/81 00/01 21/22 Catawba River/Internal Outfall Il.FLOWS,SOURCES OF POLLUTION,AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility.Indicate sources of intake water,operations contributing wastewater to the effluent,and treatment units labeled to correspond to the more detailed descriptions in Item B.Construct a water balance on the line drawing by showing average flows between intakes,operations, treatment units,and outfalls.If a water balance cannot be determined(e.g.,for certain mining activities),provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall,provide a description of:(1)All operations contributing wastewater to the effluent,including process wastewater,sanitary wastewater,cooling water, and storm water runoff; (2)The average flow contributed by each operation; and (3) The treatment received by the wastewater. Continue on additional sheets if necessary. 1 OUT- 2.OPERATION(S)CONTRIBUTING FLOW 3.TREATMENT FALL b.AVERAGE FLOW b.LIST CODES FROM NO.(Ito) a.OPERATION(list) (include units) a.DESCRIPTION TABLE 2C-1 Condenser Cooling Water , 649.4 MGD 'Screen discharge to surface water 1T 001 (Once through non-contact) 4A includes intake screen backwash Ash basin discharge chemical coagulation, settling, neutralization,- 0 02 18.6 MGD 2D 26. ion exchange, surface water discharge 1D 2J 4A Emergency Overflow of yard drain surface water discharge 002A Intermittent 4A 002B sump #1 (002A) and sunp #2 (002B) See supplemental information Miscellaneous once through 4.5 MGD surface water discharge qA 003 non-contact cooling water Miscellaneous once through 6.5 MGD surface water discharge 4A 004 non-contact cooling water surface water discharge 4A Flue Gas Desulfurization 0.5 MGD Internal outfall, discharges to ash basin 1R 2L 005 Wastewater Treatment System 2C 3C 2D 5C 2K OFFICIAL USE ONLY(effluent guidelines sub-categories) EPA Form 3510-2C(8-90) PAGE 1 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT C.Except for storm runoff.leaks,or spills,are any of the discharges described in Items II-A or B intermittent or seasonal? ©YES(complete the following table) ❑NO(go to Section III) 3.FREQUENCY 4.FLOW a DAYS PER B.TOTAL VOLUME 2.OPERATION(s) WEEK b.MONTHS a.FLOW RATE(in mgd) (speciiywith units) 1.OUTFALL CONTRIBUTING FLOW (specify PER YEAR 1.LONG TERM 2.MAXIMUM 1.LONG TERM 2.MAXIMUM C.DURATION NUMBER(list) (list) average) (specify average) AVERAGE DAILY AVERAGE DAILY (in days) 002A Emergency overflow of yard drain sump See See See See #1 (see aupplmental information) Supple- Supple- Supple- Supple- mental mental mental mental Informat- Informat- Informat- Informat ion ion ion -ion 002B Emergency overflow of yard drain sump See See See See #2 (see aupplmental information) Supple- Supple- Supple- Supple- mental mental mental mental Informat- Informat- Informat- Informat ion ion ion -ion III PRODUCTION A.Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? ®YES(complete Item III-B) ❑NO(go to Section IV) B.Are the limitations in the applicable effluent guideline expressed in terms of production(or other measure of operation)? ❑YES(complete Item III-C) ®NO(go to Section IV) C.If you answered"yes"to Item III-B,list the quantity which represents an actual measurement of your level of production,expressed in the terms and units used in the applicable effluent guideline,and indicate the affected outfalls. 1.AVERAGE DAILY PRODUCTION 2.AFFECTED OUTFALLS a.QUANTITY PER DAY b.UNITS OF MEASURE c.OPERATION,PRODUCT,MATERIAL,ETC. (list outfall numbers) (specify) NA NA NA NA IV IMPROVEMENTS A. Are you now required by any Federal, State or local authority to meet any implementation schedule for the construction, upgrading or operations of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application?This includes,but is not limited to, permit conditions,administrative or enforcement orders,enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. 0 YES(complete the following table) IZ NO(go to Item IV-B) 1.IDENTIFICATION OF CONDITION, 2.AFFECTED OUTFALLS 4.FINAL COMPLIANCE DATE 3.BRIEF DESCRIPTION OF PROJECT AGREEMENT,ETC. a.NO. b.SOURCE OF DISCHARGE a.REQUIRED b.PROJECTED B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges)you now have underway or which you plan.Indicate whether each program is now underway or planned,and indicate your actual or planned schedules for construction. ❑MARK"X"IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED EPA Form 3510-2C(8-90) PAGE 2 of 4 CONTINUE ON PAGE 3 EPA I.D.NUMBER(copy from Item I of Form I) CONTINUED FROM PAGE 2 NC0004987 V.INTAKE AND EFFLUENT CHARACTERISTICS A,B,&C: See instructions before proceeding—Complete one set of tables for each outfall—Annotate the outfall number in the space provided. NOTE:Tables V-A,V-B,and V-C are included on separate sheets numbered V-1 through V-9. D. Use the space below to list any of the pollutants listed in Table 2c-3 of the instructions,which you know or have reason to believe is discharged or may be discharged from any outfall.For every pollutant you list,briefly describe the reasons you believe it to be present and report any analytical data in your possession. 1.POLLUTANT 2.SOURCE 1.POLLUTANT 2.SOURCE See Supplemental Information, Table 5.1 (attached) for complete list VI.POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item V-C a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? ❑YES(list all such pollutants below) NO(go to Item VI-B) EPA Form 3510-2C(8-90) PAGE 3 of 4 CONTINUE ON REVERSE CONTINUED FROM THE FRONT VII.BIOLOGICAL TOXICITY111111111111.111.TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ©YES(identify the tests)and describe their purposes below) ❑NO(go to Section VIII) Quarterly analysis of Ceriodaphnia Dubia chronic testing per current permit requirements on Outfall 002 VIII.CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? ®YES(list the name,address,and telephone number of and pollutants analyzed by, ❑NO(go to Section IX) each such laboratory or firm below) A.NAME B.ADDRESS C.TELEPHONE D.POLLUTANTS ANALYZED (area code&no.) (list) Shealy Environmental 106 Vantage Point Drive 803-791-9700 All parameters except Services,Inc. West Columbia, SC 29172 dioxin and radiological SGS Environmental Services, Inc. 5500 Business Dr. 910-350-1903 Dioxin Wilmington, NC 28405 GEL Laboratories LLC 2040 Savage Road 843-556-8171 Radiological Charleston, SC 29417 IX.CERTIFICATION 1 certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. A.NAME&OFFICIAL TITLE(type or print) B.PHONE NO.(area code&no.) Steve Immel, General Manager II, Regulated Fossil Stations (704) 829-2400 C.SIGNATURE D.DATE SIGNED 11/30/2009 EPA Form 3510-2C(8-90) PAGE 4 of 4 Plant Allen 2009 Water Schematic Condenser Outfall 001 South Fork Cooling Water 649 MGD ► River Outfall 002A Catawba Sanitary Intermittent River Waste Coal Handling ► Coal Yard .4 Stormwater Sumps Sump Atm ► Ash SluiceT , Water Internal 1 FGD —0, FGD WWTS "--Outfall 005 —► 0.5 MGD Outfall 002 Catawba Ash Basin 18.6 MGD—� River A n ► Water f FGD A • Treatment Stormwater Sump • �._ Landfill Catawba Boiler Turbine Rm Leachate Sumps River ► Ash Silo Sump A Boiler Rm ,� 10 Yard Drainage 4 Stormwater Sumps Sump 4 I I-- —♦ " ► Misc Equip ,, Outfall 003 South Fork Cooling&Seals 4.5 MGD River ► Powerhouse ^ Sump • Outfall002B Catawba (Intermittent) River Intake Screen _ol • Backwash ,� Outfall 004 Catawba 6.5 MGD River Limestone Stormwater Sump Asiatic Clam/ Debris Filter Catawba Backwash River PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS NC0004979 Allen Steam Station OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 001 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALU (if available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES e.Biochemical Oxygen < 2.0 < 14533.7 1 mg/L lbs/Day < 2.0 < 1 Demand(BOD) b.Chemical Oxygen < 10 < 72668.3 1 mg/L lbs/Day < 10 < 1 Demand(COD) c.Taal Organic 1.9 13807.0 1 mg/L lbs/Day 1.7 1 Carbon(TOC) d.Total Suspended 7.0 50867.8 1 mg/L lbs/Day 9.0 1 Solids(TSS) e.Ammonia(as N) 0.13 944.7 1 mg/L lbs/Day < 0.10 < 1 (.Flow VALUE VALUE VALUE VALUE 870.8 836.1 649.4 729 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (winter) 28.9 23.9 20.4 169 DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 43.3 38.9 38.2 184 _ DEGREES CELSIUS I.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.99 7.23 2 STANDARD UNITS 7.18 1 PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional AND CAS NO. Behaved a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (d available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass _ANALYSES (ration (1)Concentration (2)Mass ANALYSES a.Bromide X < 0.20 < 1453.4 1 mg/L lbs/Day < 0.20 < 1 (24959-87-9) b.Chlorine. X < 0.050 < 363.3 1 mg/L lbs/Day < 0.050 < 1 Total Residual a.Color X 15 N/A N/A N/A 1 Std.Units - N/A 25 N/A 1 I Fecal X 4 N/A N/A N/A 1 Colonies N/A < 2 < N/A 1 tlolifonn /100 ml e.Fluoride X < 0.10 < 726.7 1 mg/L lbs/Day < 0.10 < 1 :18984-484) I.Nitrate- X 0.17 1235.4 1 mg/L lbs/Day 0.22 1 Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if avallable) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass b. (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES YSSEE S g.Nitrogen. Total Organic X 0.37 2688.7 1 mg/L Ibs/Day 0.28 1 (as N) h.Oil end ' Grease X < 5.0 < 36334.1 1 mg/L lbs/Day < 5.0 < 1 I.Phosphorous - (as P),Total X 0.061 443.3 1 mg/L lbs/Day 0.021 1 (7723-14-0) 1.Radioactivity -CO Alpha, Total X < 5.0 < N/A N/A N/A 1 pCi/L N/A < 5.0 < N/A 1 (2)Beta. Total X 2.5 N/A N/A N/A 1 pCi/L N/A < 5.0 < N/A 1 (3)Radium, Total X 0.40 N/A N/A N/A 1 pCi/L N/A < 1.0 < N/A 1 (4)Radium 228,Total X 0.76 N/A N/A N/A 1 pCi/L N/A < 1.0 < N/A 1 k Sulfate (as SO4) X 5.4 39240.9 1 mg/L lbs/Day 5.1 1 (14808.79-8) I.Sulfide (as S) X 9.6 69761.5 1 mg/L lbs/Day < 1.0 < 1 m.Sulfite (as S03) X 3.0 21800.5 1 mg/L lbs/Day < 1.0 < 1 /(14285-453) n.Surfactants X 0.089 646.7 1 mg/L lbs/Day < 0.0050 < 1 o.Aluminum, Total X 0.170 1235.4 1 mg/L lbs/Day 0.210 1 (7429-90-5) p.Barium, Total X < 0.050 < 363.3 1 mg/L lbs/Day < 0.050 < 1 (7440-39-3) q.Boron. Total X 0.065 472.3 1 mg/L lbs/Day 0.068 1 (7440-42-8) r.Cobalt, Total X < 0.020 < 145.3 1 mg/L lbs/Day < 0.020 < 1 (7440-48-4) s.Iron,Total (7439-89-8) X 0.56 4084.0 1 mg/L lbs/Day 0.60 1 I.Magnesium. Total X 1.8 13080.3 1 mg/L Ibs/Day 1.9 1 (7439-95-4) u.Molybdenum, Total X < 0.020 < 145.3 1 mg/L lbs/Day < 0.020 < 1 (7439.98-7) v.Manganese, Total X 0.033 239.8 1 mg/L lbs/Day 0.040 1 (7439-98-5) w.Tin,Total (7440-31-5) A < 0.010 < 72.7 1 mg/L lbs/Day < 0.010 < 1 v.Titanium. Total X < 0.050 < 363.3 1 mg/L lbs/Day < 0.050 < 1 (7440.32.8) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 001 Allen Steam Station PART C-If you are a primary industry and this outfall contains process wastewater,refer to Tab%2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre- cab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES taboo (1)Concentration METALS,CYANIDE,ACID TOTAL PHENOLS 1(2)Maas ANALYSES 1M.Antimony, X < 5.0 < 36.33 1 ug/L Ibs/Day < 5.0 < 1 Total(7440-36-0) 2M.Arsenic,Total X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 (7440-38-2) 3M.Beryllium, X < 1.0 < 7.27 1 ugh lbs/Day < 1.0 < 1 Total(7440-41-7) 4M.Cadmium, X < 0.10 < 0.73 1 ug/L lbs/Day < 0.10 < 1 Taal(7440-43-9) SM.Chromium, X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 Total(7440-47-3) BM.Copper,Total X 0.015 107.55 1 mg/L Ibs/Day < 0.0050 < 1 (7440-50-8) 7M.Lead.Total X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (7439-92-1)W.Mercury,Taal X 0.0011 0.01 1 ug/L lbs/Day 0.0012 1 /(7439-9746) 9M.Nickel,Total X < 10 < 72.67 1 ug/L lbs/Day < 10 < 1 (7440-02-0) 10M.Selenium, X < 1.0 < 7.27 1 ug/L lbs/Day < 1.0 < 1 Total(7762-49-2) 11M.Silver.Total X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 (7440-22.4) 12M.Thallium, X < 0.00050 < 3.6 1 mg/L lbs/Day < 0.00050 < 1 Total(7440.28.0) 13M.Zinc,Total X < 0.010 < 72.67 1 mg/L lbs/Day < 0.010 < 1 (7440.66-6) 14M.Cyanide, X < 0.010 < 72.67 1 mg/L lbs/Day < 0.010 < 1 Total(57-12-5) _ 15M.Phenols, X < 0.0050 < 36.3 1 mg/L lbs/Day < 0.0050 < 1 Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X < 0.0100 I < 0.0001 I 1 I ng/L I Ibs/Day I < 0.0100 I I 1 Dioxin(1784-01-8) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK'X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed seM sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE COMPOUNDS 1 V.Acrolein X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 (107.02-8) _ 2V.Acrylonitnle X < 5.0 < 36.33 1 ug/L lbs/Day < 5.0 < 1 (107-13-1) 3V.Benzene X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (71-43-2) 4V.Bis(Chloro- methyl)Ether X (542-88-1) 5V.Bromoform X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (75-25-2) BV.Carbon Tetrachloride X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (56-23-5) 7V.Chlorobenzene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (108-90-7) 8V.Chtorodi- bromomethane X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (124-48-1) 9V.Chtoroethane X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (75-00-3) 10V.2-Chloro- - ---- .,,. - --- ' ' ethylvinyl Ether X < 5.0 < 36.33 1 tg/L lbs/Day < 5.0 < 1 (110-75-8) _ 11V.Chloroform X < 2.0 < 14.53 1 ag/L lbs/Day < 2.0 < I - (67-66-3) 12V.Dichloro- bromomethane X < 2.0 < 14.53 1 u Ibs/Day < 2.0 <MA 1 (75-27-4) 13V.Dichloro- difluoromethane X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (75-51-8) 14V.1,1-Dichloro- X < 2.0 < 14.53 1 ug/L bs/Day < 2.0 < 1 ethane(75-34-3) 15V.1,2-Dichioro- X ' < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 ethane(107-06-2) 16V.1,1-Dichlero- X < 2.0 < 14.53 1 MA- lbs/Day < 2.0 < 1 ethylene(75-35-4) 17V.1,2-Dichtoro- X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 propane(78-87-5) 18V.1,3-Dicharo- X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 propylene(542-75-8) 19V.Ethylbenzene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (100-41-4) 20V.Methyl X < 2.0 < 14.53 1 ug/L Ibs/Day < 2.0 < 1 Bromide(74-83-9) 21V.Methyl X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 001 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(oOional) AND CAS NO. ore- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE Of available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS(continued) 22V.Methylene X < 2.0 < 14.53 1 ugh Ibs/Day < 2.0 < 1 Chloride(75-09-2) 23V.1,1,2,2-Tetra- chloroethane X < 2.0 < 14.53 1 ug/L Ibs/Day < 2.0 < 1 (79-34-5) 24V.Tetrachloro- X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 ethylene(127-18-4) 25V.Toluene X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 (108-88-3) 26V.1,2-Trans- Dichloroethylene X < 2.0 < 14.53 1 tg/L lbs/Day < 2.0 < 1 (156-60-5) 27V.1,1,1-Tri- chloroethane X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (71-55-8) 28V.1,1,2-Tri- chloroethane X < 2.0 < 14.53 1 ugh Ibs/Day < 2.0 < 1 (79-00-5) 29V.Trichloro- X < 2.0 < 14.53 1 ug/L Ibs/Day < 2.0 < 1 ethylene(79-01-6) 30V.Trichloro- Iluoromethane X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (75-69-4) 31V.Vinyl X < 2.0 < 14.53 1 ug/L Ibs/Day < 2.0 < 1 Chloride(75.01.4) GC/MS FRACTION-ACID COMPOUNDS 1A.2-Chlomphenol X < 5.3 < 38.51 1 tg/L lbs/Day < 5.0 < 1 (95-57-8) 2A.2,4-Dichloro- X < 5.3 < 38.51 1 ug/L tbs/Day < 5.0 < 1 phenol(120-83-2) 3A.2,4-Dimethyl- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 phenol(105-67-9) 4A.4,6-Din#ro-O- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Cresol(534-52-1) SA.2,4-Dinitro- X < 28 < 188.94 1 tg/L lbs/Day < 25 < 1 phenol(51-28-5) - BA.2-Nitrophenol X < 5.3 < 38.51 1 ugh Ibs/Day < 5.0 < 1 (88-75-5) 7A.4-Nitrophenol X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (100-02-7) - BA.P-Chloro-M- X < 5.3 < 38.51 1 ughL lbs/Day < 5.0 < 1 Cresol(59-50-7) 9A.Pentachloro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 phenol(87-88-5) _ 10A.Phenol X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (106-95-2) 11A.2,4,8-Tri- chlorophenol X < 5.3 < 38.51 1 ugh Ibs/Day < 5.0 < 1 (68-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 001 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-tab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ad sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration (1)Concentration 112)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.Acenaphthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (83-32-9) 213.Acenaphtylene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (208-96-8) 38.Anthracene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (120-12-7) 48.Benzidine X < 53 < 385.14 1 ugh lbs/Day < 50 < 1 (92-87-5) 513.Benno(a) Anthracene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (58.553) BB.Benzo(a) X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Pyrene(50-32-8) 7B.3,4-Benno- Iluoranthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (205-99-2) 8B.Benzo(gh) X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Perylene(191-24-2) 98.Benzo(k) Fluoranthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (207-08-9) 108.Bis(2-Chloro- ethonyl)Methane X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 /(111-91-1) 11B.Bis(2-Chloro- etry)Ether X < 5.3 < 38.51 1 tg/L lbs/Day < 5.0 < 1 (111-44-4) 1213.Bis(2-Chloroiso- props)Ether X < 5.3 < 38.51 1 ugh lbs/Day < 5.0 < 1 (108-60-1) 138.Bis(2-Ethyl- hazy)Phehalete X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (117-81-7) 14B.4-Bromo- phenyl Phenyl X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Ether(101-55-3) 15B.Butyl Benzyl X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Phthalate(85-68-7) 168.2-Chloro- naphthalene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (91-58-7) 17B.4-Chloro- phenyl Phenyl X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 Ether(7005-72-3) 1813.Chrysene X < 5.3 < 38.51 1 tg/L lbs/Day < 5.0 < 1 (218-01-9) 198.Dibenzo(a,h) Anthracene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (53-70-3) 20B.1,2-Dichloro- X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 benzene(95-50-1) 218.1,3-Diehloro- X < 2.0 < 14.53 1 ug/L < 2.0 < lbs/Day1 benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Forth 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG. ALOE (if available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration (2)Mass (1)Concentration 1(2)Mass (1)Concentration1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASEI UTRAL COMPOUND (continued) 226.1,4-Dichloro- X < 2.0 < 14.53 1 ug/L lbs/Day < 2.0 < 1 benzene(106-46-7) 238.3,3-Dichloro- benzidine X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (91-94-1) 24B.Diethyl Phthalate X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (84.86-2) 25B.Dimethyl Phthalate X < 5.3 < 38.51 1 Ugh lbs/Day < 5.0 < 1 (131-11-3) 286.Di-N-Butyl Phthalate X < 5.3 < 38.51 1 ugh lbs/Day < 5.0 < 1 (84-74-2) 276.2,4-Dinitro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 toluene(12t-14-2) 286.2,8-Dinitro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 toluene(606-20-2) 298.Di-N-Octy1 Phthalate X < 5.3 < 38.51 1 uggl Ibs7D-a-y- ' < -_ 5.0 ----k 1 (117-84-0) 308.12-Dphenyl- hydrazine(as Azo- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 penzene)(122-66-7) 31B.Fluoranthene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (206-44-0) 32B.Fluorene X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (88-73-7) 33B.Hexachloro- X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 benzene(118-74-1) 34B.Hexa- chlerobutadiene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (87-68-3) 35B.Hexechloro- cyclopentadiene X < 5.3 < 38.51 1 WA lbs/Day < 5.0 < 1 (77-47-4) 36B.Hexachloro- X < 5.3 < 38.51 1 MA- lbs/Day < 5.0 < 1 ethane(67-72-1) 376.Indeno (1,2,3-cd)Pyrene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (193-39-5) 386.Isophorone X < 5.3 < 38.51 1 ugh lbs/Day < 5.0 < 1 (78-59-1) 398.Naphthalene X < 5.3 < 38.51 1 ugh lbs/Day < 5.0 < 1 (91-20-3) 408.Nitroberu:ene X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (98-95-3) 418.N-Nilro- sodimethylamine X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (62-75-9) 428.N-Nilrosodi- N-Propylamins X < 5.3 < 38.51 1 ug/L Ibs/Day < 5.0 < 1 (821-64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 001 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE Of available) quir- b.pre- c.ab- (d available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration (2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tratlon (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUND(continued) 43B.N-Nitro- sodiphenytamine X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (88-30.8) 448.Phenanthrene X < 5.3 < 38.51 1 ugh lbs/Day < 5.0 < 1 (85-01-8) 45B.Pyrene X < 5.3 < 38.51 1 ug/L lbs/Day < 5.0 < 1 (129-00-0) 48B.1,2,4-Tri- chlorobenzene X < 2.0 < 14.53 1 ugh lbs/Day < 2.0 < 1 (120.82-1) GC/MS FRACTION-PESTICIDES 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.delta-BHC X (319-88-8) 8P.Chlordane X (57-74-9) 7P.4,4'-DDT X (50-29-3) BP.4,4'-DDE X (72-55-9) 9P.4,4'-ODD X (72-54-8) 10P.Dietdrin X (80-57-1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 18P.Heptachlor X (713 44-8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 001 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- cab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass `(1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration I(2)Mass ANALYSES GC/MS FRACTION-PESTI IDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.26. < 1.89 1 ug/L lbs/day < 0.25 1 (53489-21.9) 19P.PCB-1254 X < 0.26' < 1.89 1 ug/L lbs/day < 0.25 1 (11097-89-1) 20P.PCB-1221 X < 0.26. < 1.89 1 ug/L lbs/day < 0.25 1 (11104-28-2) 21P.PCB-1232 X < 0.26 < 1.89 1 ug/L lbs/day < 0.25 1 (11141-18-5) 22P.PCB-1248 X < 0.26. < 1.89 1 ug/L lbs/day < 0.25 1 (12872-29-8) ` 23P.PCB-12e0 X < 0.28' < 1.89 1 ug/L lbs/day < 0.25 1 (11098.82-5) 24P.PCB-1018 X < 0.26. < 1.89 1 ug/L lbs/day < 0.25 1 (12874-11-2) 25P.Toxaphene X (8001-35-2) EPA Fonn 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS NC0004979 Allen Steam Station OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 002 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen < 2.0 < 392.2 1 mg/L lbs/Day Demand(BOO) b.Chemical Oxygen < 10 < 1961.1 1 mg/L Ibs/Day Demand(COD) c.Total Organic 1 196.1 1 mg/L lbs/Day Carbon(TOC) d.Total Suspended 23.0 4510.5 23 4261.0 6.8 1055.5 24 mg/L lbs/Day Solids(TSS) e.Ammonia(as N) 0.310 60.8 1 mg/L lbs/Day I.Flow VALUE VALUE VALUE VALUE 23.5 22.2 18.6 105 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (winter) _ DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 28.57 1 DEGREES CELSIUS I.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.2 7.4 24 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass _b.NO.OF sent sent (t)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration a.Bromide ' X 0.75 147.1 1 mg/L lbs/Day (2>Mass ANALYSES (24959-67-g) b.Chlorine, X < 0.050 < 9.8 1 mg/L lbs/Day Total Residual c.Color X 15 N/A WA N/A 1 Std.Units N/A N/A d.Fecal X < 2 < WA N/A N/A 1 Coforlies N/A N/A Coliform /100 ml e.Fluoride X 0.27 52.9 1 mg/L lbs/Day (18984-48-8) f.Nitrate- X 0.21 41.2 1 mg/L. lbs/Day Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 002 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES(ration (1)Concentration p.Nitrogen, (2)Mass ANALYSES Total Organic X 1.70 333.4 1.7 314.9 1.2 188.3 4 mg/L lbs/Day (as N) h.Oil and - - Grease X < 5.0 < 980.5 < 5 < 926.3 < 5 < 776.1 8 mg/L lbs/Day i.Phosphorous (as P),Total X 0.027 5.3 1 mg/L lbs/Day (7723-14-0) j.Radioactivity (t)Alpha, Total X < 5.0 < N/A N/A N/A 1 pCVL N/A N/A (2)Beta, Total X 3.2 N/A N/A N/A 1 pCi/L N/A N/A (3)Radium, Total X 0.64 N/A N/A N/A 1 pCVL N/A N/A (4)Radium 226,Total X 0.58 N/A N/A N/A 1 pCi/L N/A N/A k Sulfate (as SO4) X 56 10982.0 1 mg/L lbs/Day (14808-79-8) I.Sulfide (as s) X < 1.0 < 196.1 1 mg/L lbs/Day m.Sulfite (as SO3) X < 1.0 < 196.1 1 mg/L lbs/Day 1(14265.45-3) n.Surfactants X 0.055 10.8 1 mg/L lbs/Day o.Aluminum, Total X 0.11 21.6 1 mg/L lbs/Day (7429-90-5) p.Barium, Total X 0.078 15.3 1 mg/L lbs/Day (7440-39-3) q.Boron, Total X 0.75 147.1 1 mg/L lbs/Day (7440-42-8) r.Cobalt, Total X < 0.020 < 3.9 1 mg/L lbs/Day (7440-48-4) s.Iron,Total (7439.89.6) X 0.72 141.2 0.72 133.4 0.24 37.3 24 mg/L lbs/Day t.Magnesium, Total X 8.0 1568.9 1 mg/L lbs/Day (7439.95.4) u.Molybdenum, Total X 0.022 4.3 1 mg/L lbs/Day (7439-98-7) v.Manganese, Total X 0.10 19.6 1 mg/L lbs/Day (7439-96-5) w.Tin,Total (7440-31-5) X < 0.010 < 2.0 1 mg/L lbs/Day a.Titanium. Total X < 0.050 < 9.8 1 mg/L lbs/Day (7440.32.6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 002 Allen Steam Station PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quv- b.pre- c.ab- (if available) _ (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 2 Mass ANALYSES tration I() (1)Concentration 1(2)Mass ANALYSES METALS,CYANI E,AND T TAL PHENOLS 1M.Antimony, X < 5.0 < 0.98 1 ug/L lbs/Day (7440-36-0) 2M.Arsenic,Total X < 5.0 < 0.98 1 ug/L lbs/Day (7440-38-2) 3M.Beryllium, X < 1.0 < 0.20 1 ug/L lbs/Day Total(7440-41-7) 4M.Cadmium, X 0.19 0.04 1 ug/L lbs/Day Total(7440.43.9) 5M.Chromium, X < 5.0 < 0.98 1 ug/L lbs/Day Total(7440-47-3) BM.Copper.Total X 0.0500 9.81 0.04 7.41 0.02 3.10 48 mg/L lbs/Day (7440-50-8) 7M.Lead,Total X < 2.0 < 0.39 1 ug/L lbs/Day (7439-92-1) BM.Mercury,Total X < 0.00050 < 0.00 1 ug/L lbs/Day /7439-97-6) 9M.Nickel,Total X < 10 < 1.96 1 ug/L lbs/Day (7440-02-0) 10M.Selenium, X 12.1 2.37 10.6 1.96 4.46 0.69 48 ug/L lbs/Day Total(7782-49-2) 11M.SBver,Total X < 5.0 < 0.98 1 ug/L lbs/Day (7440-22-4) 12M.Thallium, X 0.00080 0.2 1 mg/L lbs/Day Total(7440-28-0) 13M.Zinc,Total X 0.013 2.55 1 mg/L lbs/Day (7440-66-6) 14M.Cyanide, X < 0.010 < 1.96 1 mg/L lbs/Day Total(57-12-5) 15M.Phenols, X 0.0050 1.0 1 mg/L lbs/Day Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibermo P X < 0.0100 I < 0.0001 I 1 I n9/L I DaY I Dioxin(1764-01.6) EPA Form 3510.2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 002 Alien Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Duncan- b.Mass d.NO.OF (1)Concentration 1(2)Mass (1)Con centration sent sent 1(2)Mass (1)Concentration1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE COMPOUNDS 1V.Acrolein X < 5.0 < 0.98 1 ug/L lbs/Day (107-02-8) 2V.Acrylonitrile X < 5.0 < 0.98 1 tg/L lbs/Day (107-13-1) 3V.Benzene X < 2.0 < 0.39 1 ug/L lbs/Day (71-43-2) 4V.Bis(Chloro- methyl)Ether X (542-88.1) 5V.Bromoform X < 2.0 < 0.39 1 ug/t. lbs/Day (75-25-2) 8V.Carbon Tetrachloride X < 2.0 < 0.39 1 ug/L lbs/Day (56-23-5) N.Chlorobenzene X < 2.0 < 0.39 1 ug/L lbs/Day (108.90-7) BV.Chlorodi- bromomethene X < 2.0 < 0.39 1 ughL lbs/Day (124-48-1) 9V.Chloroethane X < 2.0 < 0.39 1 ug/L lbs/Day (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 5.0 < 0.98 1 ug/L lbs/Day /(110.75-8) 11V.Chloroform X < 2.0 < 0.39 1 ug/L Ibs/Day (67.86-3) 12V.Dichloro- bromomethane X < 2.0 < 0.39 1 ug/L lbs/Day (75-27-4) 13V.Dichloro- d'dworomethane X < 2.0 < 0.39 1 tg/L lbs/Day (75-51-8) 14V.1,1-Dichloro- X < 2.0 < 0.39 1 ug/L lbs/Day e thane(75-34-3) 15V.12-Dichloro- X < 2.0 < 0.39 1 ug/L lbs/Day e thane(107-08-2) 18V.1,1-Dichloro- X < 2.0 < 0.39 1 ug/L lbs/Day ethylene(75-35-4) 17V.1,2-Dichloro- X < 2.0 < 0.39 1 ug/L lbs/Day propane(78-87-5) 18V.1,3-Dichloro- X < 2.0 < 0.39 1 ug/L lbs/Day propylene(542-75-6) 19V.Ethylbenzene X < 2.0 < 0.39 1 ug/L lbs/Day (100-41-4) 20V.Methyl X < 2.0 < 0.39 1 ug/L lbs/Day Bromide(74-83-9) 21V.Methyl X < 2.0 < 0.39 1 ug/L lbs/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 002 Men Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS _ 5.INTAKE(optional AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (It available) qua- b.pre-tat' (it available) (it available) d.NO.OF a.Concen- b.Mass d.NO.OF(1)Concentration 1(2)Mass (1) ed sent sent Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE OMPOUNDS(continued) 22V.Methylene X < 2.0 < 0.39 Chloride(75-09-2) 1 lbs/Day 23V.1.1,2,2-Tetra- chloroethane X < 2.0 < 0.39 1 ug/L lbs/Day (79-34-5) 24V.Tetrachloro- X < 2.0 < 0.39 1 ugh lbs/Dayethylene(127-18-4) 25V.Toluene X < 2.0 < 0.39 lbs/Day (108-88-3) 1 ugh 28V.1,2-Trans- Dichloroethylene X < 2.0 < 0.39 1 ug/L, lbs/Day (156-60-5) 27V.1,1,1-Tri- chloroethane X < 2.0 < 0.39 1 ugh lbs/Day (71 5541) 28V.1,1,2-Tri- chloroethane X < 2.0 < 0.39 1 ugh lbs/Day (79-00-5) 29V.Trichloro- X < 2.0 < 0.39 1 ugh lbs/Day ethylene(79-01-6) 30V.Trichloro- Ituoromethane X < 2.0 < 0.39 1 ugh lbs/Day (75.89-4) 31V.Vinyl X < 2.0 < 0.39 1 ugh lbs/Day Chloride(75-01-4) GC/MS FRACTION-Atli)C,<OMPOUNDS 1A.2-Chlorophenol X < 5.4 < 1.06 1 ug/L lbs/Day (95-57-8) 2A.2.4-Dichloro- X < 5.4 < 1.06 1 ugh lbs/Day phenol(120-83-2) 3A.2.4-Dimethyl- X < 5.4 < 1.06 1 ug/L lbs/Day phenol(105-67-9) 4A.4,8-Dinilro-O- X < 5.4 < 1.06 1 ugh lbs/Day Cresol(534-52-1) 6A.2,4-Dinfro- X < 27 < 5.29 1 ugh lbs/Day phenol(51-28-5) BA.2-Nitrophenol X < 5.4 < 1.06 1 ug/L lbs/Day (88-75-5) 7A.4-Nitrophenol X < 5.4 < 1.06 1 ug/L lbs/Day (100-02-7) BA.P-Chloro-M- X < 5.4 < 1.06 1 t1g/L tbs/Day Cresol(59-50-7) 9A.Pemaehloro- X < 5.4 < 1.06 1 ugh lbs/Day phenol(87-86-5) 10A.Phenol X < 5.4 < 1.06 1 ugh lbs/Day (108-95-2) 11A.2,4,8-Tri- chlorophenol X < 5.4 < 1.06 1 Ug/L lbs/Day (88-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 002 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration GC/MS FRACTION-BASE NEUTRAL COMPOUNDS (1)Concentration 1(2)Mass ANALYSES 18.AcenapMhene X < 5.4 < 1.06 1 ug/L lbs/Day (83-32-9) 28.AcenapMylene X < 5.4 < 1.06 1 ug/L lbs/Day (208-96-8) 3B.Anthracene X < 5.4 < 1.06 1 tg/L lbs/Day (120-12-7) 4B.Benzldine X < 54 < 10.59 1 ug/L lbs/Day (92-87-5) 5B.Benzo(a) Anthracene X < 5.4 < 1.06 1 ug/L lbs/Day (56-55-3) 88.Benzo(a) X < 5.4 < 1.06 1 ug/L lbs/Day Pyrene(50-32-8) 7B.3,4-Benzo- euoranthene X < 5.4 < 1.06 1 ug/L lbs/Day (205-99-2) 8B.Benzo(ghi) X < 5.4 < 1.06 1 ug/L lbs/Day Perylene(191-24-2) 98.Benzo(k) FkwraMhene X < 5.4 < 1.06 1 ug/L Ibs/Day (207-08-9) 10B.Bis(2-Chloro- ethoxy0 Methane X < 5.4 < 1.06 1 ug/L lbs/Day 1111-91.1) 118.Bis(2-Chlero- ethyl)Ether X < 5.4 < 1.06 1 ug/L lbs/Day (111-44-4) 128.Bis(2-Chleroiso- propy)Ether X < 5.4 < 1.06 1 ugh lbs/Day (108-60-1) 13B.Bis(2-Ethyl- hazy!)PhahalMs X < 5.4 < 1.06 1 WA- lbs/Day (117-81-7) 148.4-Bromo- phenyl Phenyl X < 5.4 < 1.06 1 ug/L lbs/Day Ether(101-55-3) 158.Butyl Benzyl X < 5.4 < 1.06 1 uglL Ibs/Day Phthalate(85.68-7) 168.2-Chkxo- naphthalene X < 5.4 < 1.06 1 ug/L lbs/Day (91-58-7) 178.4-Chloro- phenyl Phenyl X < 5.4 < 1.06 1 ug/L lbs/Day Ether(7005-72-3) 188.Chrysene X < 5.4 < 1.06 1 ugJL lbs/Day (218-01-9) .198.Dibenzo(a,h) Anthracene X < 5.4 < 1.06 1 ug/L lbs/Day (53-70-3) Zoe.1.2 Dichtoro- X < 2.0 < 0.39 1 u9/L lbs/Day benzene(95-50-1) 218.1,3-Diehlero- X < 2.0 < 0.39 1 WA- lbs/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 002 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Behaved a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE - (if available) quir- b.pre-'c.ab- (if available) (if available) d.NO.OF a.Conan- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDif(continued) 228.1,4-Dichloro- X < 2.0 < 0.39 1 ug/L lbs/Day benzene(106.48-7) 23B.3,3-Dichloro- benzidine X < 5.4 < 1.06 1 VI- lbs/Day (91-94-1) 24B.Diethyl Phthalate X < 5.4 < 1.06 1 ug/L lbs/Day (84-66-2) 25B.Dimethyl Phthalate X < 5.4 < 1.06 1 ug/L lbs/Day (131-11-3) 26B.DIN-Butyl Phthalate X < 5.4 < 1.06 1 ug/L lbs/Day (84-74-2) 278.2,4-Dinitro- X < 5.4 < 1.06 1 WI- lbs/Day toluene(121-14-2) 28B.2,6-Dinitro- X < 5.4 < 1.06 1 uglL tbS/Day toluene(608.20-2) 29B.Di-N-Octyl Phthalate X < 5.4 < 1.06 1 ug/L lbs/Day (117-84-0) 308.I,2-Diphenyt- hydrazine(as Azo- X < 5.4 < 1.06 1 ug/L lbs/Day benzene)(122-68-7) 31B.Fluoranthene X < 5.4 < 1.06 1 ug/L lbs/Day (206-44-0) 328.Fluorene X < 5.4 < 1.06 1 ug/L lbs/Day (86-73-7) 33B.Hexachloro- X < 5.4 < 1.06 1 ugh lbs/Day benzene(118-74-1) 34B.Hexa- chlorobutadiene X < 5.4 < 1.06 1 ugll lbs/Day (87-66-3) 358.Hexachloro- cycropentadiene X < 5.4 < 1.06 1 ugh lbs/Day (77-47-4) 36B.Hexachloro- X < 5.4 < 1.06 1 ug/L lbs/Day ethane(67-72-1) 37B.Indeno (1,2,3-cd)Pyrene X < 5.4 < 1.06 1 ug/L Ibs/Day (193-39-5) 38B.Isophorone X < 5.4 < 1.06 1 ug1L lbs/Day (78-59-1) 39B.Naphthalene X < 5.4 < 1.06 1 uglL lbs/Day (91-20-3) 40B.Nitrobenzene X < 5.4 < 1.06 1 ug/L lbs/Day (98-95-3) 41B.N-Nitro- sodimethyumine X < 5.4 < 1.06 1 WI- Ibs/Day (62.75.9) 428.N-Nitrosodi- N-Propytamine X < 5.4 < 1.06 1 ug/L lbs/Day (621-4-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 002 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) quir- b.pre-'cab- (if available) (if available) d.NO.OF a.Cancan- b.Mass d.NO.OF ed sent sent (1)Concentration (2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration GC/MS FRACTION-BASE/NEUT SAL COMPOUND (continued) (1)Concentration 1(2)Mass ANALYSES 438.N-Nitro- sodiphenylamine X < 5.4 ' < 1.06 1 ugll lbs/Day (88.30.6) 44B.Phananthrene X < 5.4 < 1.06 1 ugh lbs/Day (85-01-8) 458.Pyrene X < 5.4 < 1.06 1 - ugh lbs/Day (129-00-0) 468.1,2,4-Tn- - - chlorobenzene X < 2.0 < 0.39 1 ug/I- Ibs/Day (120-82-1) GC/MS FRACTION-PESTICIDES 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC - X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.della-BHC X (319.88.8) BP.Chlordane X (57-74-9) 7P.4,4'-DDT X (50-29-3) BP.4,4'-DDE X (72-55-9) 9P.4,4'-DDD 1 X - (72-54-8) • 10P.Dieldnn X (60-57-1) i 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X . (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X - (78-44-8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 N00004979 002 Men Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d evadable) quir- b.pre- c.ab- (if available) (it available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)M ANALYSES (ration GC/MS FRACTION-PESTICIDES(continued) ass (1)Concentration 1(2)Mass ANALYSES 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.25 < 0.05 1 (53469-21-9) ugh lbs/day 19P.PCB-1254 X < 0.25 < 0.05 1 - up/L Ibs/day (11097-69-1) 20P.PCB-1221 X < 0.25 < 0.05 1 up/L lbs/day (11104-28-2) 21P.PCB-1232 X < 0.25 < 0.05 1 ugh lbs/day (11141-16-5) 22P.PCB-1248 X < 0.25 < 0.05 1 ug/L lbs/day (12672-29-6) 23P.PCB-1260 X < 0.25 < 0.05 1 ttglL lbs/day (11098-82-5) 24P.PCB-1016 X < 0.25 < 0.05 1 tg/L lbs/day (12674-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS NC0004979 Allen Steam Station OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 003 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES (ration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen < 2.0 < 75.1 1 mg/L lbs/Day Demand(BOO) _ b.Chemical Oxygen < 10 < 375.5 1 mg/L lbs/Day Demand(COD) e.Total Organic 1.4 52.6 1 mg/L lbs/Day Carbon(TOC) d.Total suspended 10 375.5 1 mg/L lbs/Day Solids(TSS) e.Ammonia(as N) < 0.10 < 3.8 1 mg/L lbs/Day f.Flow VALUE VALUE VALUE VALUE 4.5 4.5 4.5 101 MGD N/A 9.Temperature VALUE VALUE VALUE VALUE ;winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 28.57 1 DEGREES CELSIUS p11 MINIMUM MAXIMUM MINIMUM MAXIMUM 7.13 1 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES(ration (1)Concentration (2)Mass ANALYSES a.Bromide X < 0.20 < 7.5 1 mg/L lbs/Day (24959.87-9) D.Chlorine. X < 0.050 < 1.9 1 mg/L lbs/Day Total Residual :.Color X 20 N/A N/A N/A 1 Std.Units N/A N/A i.Fecal X < 2 < N/A N/A N/A 1 Colonies N/A N/A :1oliform /100 ml a.Fluoride X < 0.10 < 3.8 1 mg/L lbs/Day (18984-48-8) r.Nitrate X 0.18 6.8 1 mg/L lbs/Day Vitrhe(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 003 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (d available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen Total Organic X 0.33 12.4 1 mg/L lbs/Day (as N) h.O9 and Grease X < 5.0 < 187.8 1 mg/L lbs/Day i.Phosphorous (as P),Total X 0.020 0.8 1 mg/L lbs/Day (7723-14-0) I.Radioactivity (1)Alpha, Total X < 5.0 < N/A N/A N/A 1 pCilL N/A N/A (2)Beta, Total X < 5.0 < N/A N/A N/A 1 pCVL N/A N/A (3)Radium, Total X < 1.0 < N/A N/A N/A 1 pCt/L N/A N/A (4)Radium 228,Total X < 1.0 < N/A N/A N/A 1 pCi/L N/A N/A k Sulfate (as 804) X 5.3 199.0 1 mg/L lbs/Day (14808-79-8) I.Sulfide (as S) X < 1.0 < 37.6 1 mg/L Ibs/Day m.Sulfite (as S03) X < 1.0 < 37.6 1 mg/L lbs/Day (14285-45-3) , n.Surfactants X < 0.050 < 1.9 1 mg/L lbs/Day o.Aluminum, Total X 0.34 12.8 1 mg/L lbs/Day (7429-90-5) p.Barium, Total X < 0.050 < 1.9 1 mg/L lbs/Day (7440-39-3) b.Boron, Total X 0.068 2.5 1 mg/L lbs/Day (7440-42-8) r.Cobalt, Total X < 0.020 < 0.8 1 mg/L lbs/Day (7440-48-4) - s.Iron,Total (7439-89-8) X 0.84 31.4 1 mg/L lbs/Day I.Magnesium, Total X 2.0 75.1 1 mg/L lbs/Day (7439-95-4) u.Molybdenum, Total X < 0.020 < 0.8 1 mg/L lbs/Day (7439.98.7) v.Manganese, Total X 0.055 2.1 1 mg/L Ibs/Day (7439-98-5) w.Tin,Total (7440-31-5) X < 0.010 < 0.4 1 mg/L lbs/Day x.Titanium, Total X < 0.050 < 1.9 1 mg/L lbs/Day (7440.32.8) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 003 Allen Steam Station PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"Xin column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre- cab- (if available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ad sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES taboo (1)Concentration 1(2)Mass ANALYSES METALS,CYANI E,AND T TAL PHENOLS 1M.Antimony, X < 5.0 < 0.19 1 ug/L lbs/Day Total(7440-36-0) 2M.Arsenic,Total X < 5.0 < 0.19 1 ug/L lbs/Day (7440-38-2) 3M.Beryllium, X < 1.0 < 0.04 1 41- lbs/Day Total(7440-41-7) 4M.Cadmium, X < 0.10 < 0.00 1 ug/L lbs/Day Total(7440-43-9) SM.Chromium, X < 5.0 < 0.19 1 ug/L lbs/Day Total(7440-47-3) , BM.Copper,Total X 0.0099 0.37 1 mg/L lbs/Day (7440-50-8) 7M.Lead,Total X < 2.0 < 0.08 1 ug/L lbs/Day (7439.92.1) BM.Mercury,Total X 0.0016 0.00 1 tig/L lbs/Day A7439-97-6) -9M.Nickel,Total X < 10 < 0.38 1 ughL lbs/Day (7440-02-0) 10M.Selenium. X < 1.00 < 0.04 1 ug/L lbs/Day Total(7782-49-2) 1tM.Silver,Total X < 5.0 < 0.19 1 ug/L lbs/Day (7440-22-4) 12M.Thallium, X < 0.00050 < 0.0 1 mg/L lbs/Day Total(7440-28-0) 13M.Zinc,Total X < 0.010 < 0.38 1 mg/L lbs/Day (7440-66-6) 14M.Cyanide, X < 0.010 < 0.38 1 mg/L Ibs/Day Total(57.12-5) 15M.Phenols, X < 0.0050 < 0.2 1 mg/L lbs/Day Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodiben:o P X < 0.0100 I < 0.0001 I 1 I n9/1- I may I Dioxin(1764-01.8) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 003 Alien Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- b.pre- c.ab- (if available) (if available) d.NO.OF a.Conan- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration I(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS 1V.Acrolein X < 5.0 < 0.19 1 tg/L lbs/Day (107-02-8) 2V.Acrytonitrile X < 5.0 < 0.19 1 ug/L lbs/Day (107-13-1) 3V.Benzene X < 2.0 < 0.08 1 ug/L lbs/Day (71-43-2) 4V.Bis(Chloro- methyl)Ether X (542-88-1) 5V.Bromoform X < 2.0 < 0.08 1 ug/L Ibs/Day (75-25-2) 6V.Carbon Tetrachloride X < 2.0 < 0.08 1 ug/L lbs/Day (56-23-5) 7V.Chlorobenzene X < 2.0 < 0.08 1 ug/L lbs/Day (108.90.7) BV.CMorodi- bromomethane X < 2.0 < 0.08 1 ug/L lbs/Day (124-48-1) 9V.Chloroethane X < 2.0 < 0.08 1 ug/L lbs/Day (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 5.0 < 0.19 1 ug/L lbs/Day /110-75-8) 11V.Chloroform X < 2.0 < 0.08 1 ug/L lbs/Day (67-66-3) 12V.Dichloro- bromomethane X < 2.0 < 0.08 1 ug/L lbs/Day (75-27-4) 13V.Dichloro- difuoromethane X < 2.0 < 0.08 1 ug/L lbs/Day (75-51-8) 14V.1,1-Dichloro- X < 2.0 < 0.08 1 ug/L lbs/Day ethane(75-34-3) 15V.1,2-Dichtoro- X < 2.0 < 0.08 1 ug/L lbs/Day ethane(107-06-2) 16V.1,1-Dichloro- X < 2.0 < 0.08 1 ug/L Ibs/Day ethylene(75-35-4) 17V.1,2-Dictiloro- X < 2.0 < 0.08 1 ug/L lbs/Day propane(78-87-5) 18V.1,3-Dichloro- X < 2.0 < 0.08 1 ug/L lbs/Day Propylene(542-75-6) 19V.Ethylbenzene X < 2.0 < 0.08 1 tg/L lbs/Day (100-41-4) 20V.Methyl X < 2.0 < 0.08 1 u9/1- lbs/Day Bromide(74-83-9) 21V.Methyl X < 2.0 < 0.08 1 ug/L lbs/Day Chloride(74.87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 003 Men Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AV .VALUE (if available) quit- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS(continued) 22V.Methylene X < 2.0 < 0.08 1 ug/L lbs/Day Chloride(75-09-2) 23V.1,1,2,2-Tetra- chloroethane X < 2.0 < 0.08 1 ug/L lbs/Day (79-34-5) 24V.Tetrachloro- X < 2.0 < 0.08 1 ug/L lbs/Day ethylene(127-18-4) 25V.Toluene X < 2.0 < 0.08 1 ug/L lbs/Day (108-88-3) 26V.1,2-Trans- Dichloroethylene X < 2.0 < 0.08 1 ug/L lbs/Day (156-60-5) 27V.1,1,1-Tri- chioroethene X < 2.0 < 0.08 1 tg/L lbs/Day (71-55-6) +28V.1,1,2-Tri- chloroethane X < 2.0 < 0.08 1 ug/L lbs/Day (79-00-5) 29V.Trichloro- X < 2.0 < 0.08 1 ugh bs/Day ethylene(79-01-6) 30V.Trichloro- Iluoromethane X < 2.0 < 0.08 1 ug/L Ibs/Day (75-69-4) 31V.Vinyl X < 2.0 < 0.08 1 ug/L lbs/Day Chloride(75-01-4) GC/MS FRACTION-ACID COMPOUNDS 1A.2-Chlorophenol X < 5.5 < 0.21 1 ugh lbs/Day (95-57-8) 2A.2,4-Dichloro- X < 5.5 < 0.21 1 ug/L lbs/Day phenol(120-83-2) 3A.2,4-Dimethy- X < 5.5 < 0.21 1 ug/L bs/Day phenol(105-67-9) 4A.4,6-Dindro-O- X < 5.5 < 0.21 1 tg/L lbs/Day Cresol(534-52-1) 5A.2,4-Dinitro- X < 27 < 1.01 1 MA- lbs/Day phenol(51-28-5) BA.2-Nitrophenol X < 5.5 < 0.21 1 ug/L bs/Day (88-75-5) 7A.4-Nilrophenol X < 5.5 < 0.21 1 ug/L bs/Day (100-02-7) BA.P-Chloro - X < 5.5 <-M 0.21 1 ug/L lbs/Day Cresol(59-50-7) 9A.Pentachioro- X < 5.5 < 0.21 1 ug/L lbs/Day phenol(87-86-5) 10A.Phenol X < 5.5 < 0.21 1 ug/L lbs/Day (108-95-2) 11A.2,4,6-Tri- chlorophenol X < 5.5 < 0.21 1 ug/L lbs/Day (88-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-S CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 003 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE 'a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Comm- b.Mass d.NO.OF ed sent sent (1)Concentration 1t)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUND 18.Acenaphthene X < 5.5 < 0.21 1 ug/L lbs/Day (83-32-9) 28.Acenaphtylene X < 5.5 < 0.21 1 ug/L lbs/Day (208-96-8) 3B.Anthracene X < 5.5 < 0.21 1 ug/L lbs/Day (120-12-7) 48.Benzidine X < 55 < 2.07 1 ug/L lbs/Day (92-87-5) 58.Benzo(a) Anthracene X < 5.5 < 0.21 1 ug/L lbs/Day (56-55-3) BB.Benno(a) X < 5.5 < 0.21 1 ug/L lbs/Day Pyrene(50-32-8) 78.3,4-Benzo- lluoranthene X < 5.5 < 0.21 1 ug/L lbs/Day (205-99-2) 88.Benzo(ghi) X < 5.5 < 0.21 1 ug/L lbs/Day Perylene(191-24-2) 98.Benzo(k) Fluoranthene X < 5.5 < 0.21 1 ug/I- lbs/Day (207-08-9) 108.Bis(2-Chloro- atltozyl)Methane X < 5.5 < 0.21 1 ug/L lbs/Day (111-91-1) 118.Bis(2-Chloro- ethyl)Ether X < 5.5 < 0.21 1 ug/L lbs/Day (111-44-4) 128.Bis(2-Chloroiso- propyq Ether X < 5.5 < 0.21 1 ug/L lbs/Day (108-60-1) - 13B.Bis(2-Ethyl- heuyl)Phehalate X < 5.5 < 0.21 1 ug/L lbs/Day (117-81-7) 148.4-Bromo- phenyl Phenyl X < 5.5 < 0.21 1 ugh lbs/Day Ether(101-55-3) 158.Butyl Benzyl X < 5.5 < 0.21 1 ug/L lbs/Day Phthalate(85.68.7) 18B.2-Chloro- naphthalene X < 5.5 < 0.21 1 ug/L lbs/Day (91-58-7) 178.4-Chloro- phenyl Phenyl X < 5.5 < 0.21 1 ug/L lbs/Day Ether(7005-72-3) 18B.Chrysene X < 5.5 < 0.21 1 ug/L lbs/Day (218-01-9) - 198.Dibenzo(a,h) Anthracene X < 5.5 < 0.21 1 ug/L Ibs/Day (53-70-3) 208.1,2-Dichloro- X < 2.0 < 0.08 1 ug/L lbs/Day benzene(95-50-1) 21B.1,3-Dlchloro- X < 2.0 < 0.08 1 u98- lbs/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 003 Men Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT - 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-'c.ab- (if available) (if available) d.NO.OF a.Conceal- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass _(1)Concentration 1(2)Mass (1)Concentration 2 Mass ANALYSES tration GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) iO (1)Concentration l(2)Mass ANALYSES 22B.1,4-Dichloro- X < 2.0 < 0.08 1 ug/L lbs/Day benzene(106-46-7) 238.3,3-Dichloro- - benzidine X < 5.5 < 0.21 1 ug/L lbs/Day (91-94-1) 248.Diethyl Phthalate X < 5.5 < 0.21 1 ug/L lbs/Day (84-66-2) 258.Dimethyl Phthalate X < 5.5 < 0.21 1 ug/L Ibs/Day (131-11-3) 268.DiN-Butyl Phthalate X < 5.5 < 0.21 1 ug/L lbs/Day (84-74-2) 278.2,4-Dinitro- X < 5.5 < 0.21 1 ug/L lbs/Day toluene(121-14-2) 288.2,8-Dinitro- X < 5.5 < 0.21 1 ug/L lbs/Day toluene(606-20-2) .298.Di-N-0Uyl Phthalate X < 5.5 < 0.21 1 ug/L lbs/Day (117-84-0) 308.12-Dipheny4 hydrazine(as Azo- X < 5.5 < 0.21 1 1g/L lbs/Day penzene)(122-66-7) 31B.Fluoranthene X < 5.5 < 0.21 1 tg/L lbs/Day (206-44-0) 328.Fhrorene X < 5.5 < 0.21 1 ug/L lbs/Day (86-73-7) 33B.Hexachloro- X < 5.5 < 0.21 1 ugh lbs/Day benzene(118.74-1) 348.Hexa- chlorobutadiene X < 5.5 < 0.21 1 ug/L Ibs/Day (87-68-3) 358.Hexachloro- cyclopemadiene X < 5.5 < 0.21 1 ug/L lbs/Day (77-47-4) 36B.Hexachloro- X < 5.5 < 0.21 1 ug/L lbs/Day ethane(67-72-1) 37B.Indeno (12,3-cd)Pyrene X < 5.5 < 0.21 1 ug/L Ibs/Day (193-39-5) 388.Isoplarone X < 5.5 < 0.21 1 tg/L lbs/Day (78.59-1) 398.Naphthalene X < 5.5 < 0.21 1 ug/L lbs/Day (91-20-3) 406.Nitrobenzene X < 5.5 < 0.21 1 ug/L lbs/Day (98-95-3) 41B.N-Nkro- sodimethylamine X < 5.5 < 0.21 1 ug/L lbs/Day (62-75-9) 428.N-Nkrosodf N-Propylamine X < 5.5 < 0.21 1 tg/L lbs/Day (621.64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 003 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) quir- b.pre- e.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed sent sent (1)Concentration (2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/ UT L COMPOUN S(continued) 43B.N-Nitro- sodiphenylamine X < 5.5 < 0.21 1 ug/L lbs/Day (88.30-8) 44B.Phenanthrene X < 5.5 < 0.21 - 1 ug/L lbs/Day (85-01-8) 45B.Pyrene X < 5.5 < 0.21 1 t,g/L lbs/Day (129-00-0) 488.1,2,4.Tri- chlorobenzene X < 2.0 < 0.08 1 ug/L lbs/Day (120.82-1) GC/MS FRACTION-PESTICIDES 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.desa-BHC X (319-86-8) BP.Chlordane X (57-74-9) 7P.4,4'-DOT X (50-29-3) BP.4,4'-DDE X (72-55-9) BP.4,4'-DOD X (72-54-8) 10P.Dieldrin X (60-57-1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 18P.Heptachlor X (76-44-8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 N00004979 003 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed •a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (t)ConcentrationConcentration1(2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor - -- - Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.26 < 0.01 1 11gIL lbs/day (53489.21-9) 19P.PCB-1254 X < 0.26 < 0.01 1 t1gIL lbs/day (1109749-1) • 20P.PCB-1221 X < 0.26 < 0.01 1 tg/L lbs/day (11104-28-2) 21P.PCB-1232 X < 0.26 < 0.01 1 t1gl1- lbs/day (11141-18.5) _ 22P.PCB-1248 X < 0.26 < 0.01 1 tglL lbs/day (12672-29-8) . 23P.PCB-1260 X < 0.26 < 0.01 1 1411- lbs/day (11096.82-5) 24P.PCB-1018 X < 0.26s < 0.01 1 ug/L lbs/day (12674-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. EPA Facility Name: SEE INSTRUCTIONS NC0004979 Allen Steam Station V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) OUTFACE NO. 004 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen < 2.0 c 108.5 1 mg/L lbs/Day Demand(BOO) b.Chemical Oxygen < 10 • < 542.4 1 mg/L lbs/Day Demand(COD) c.Total Organic 1.8 ▪ 97.6 1 mg/L lbs/Day Carbon(TOC) d.Total Suspended 6.0 325.5 1 mg/L lbs/Day Solids(TSS) e.Ammonia(as N) < 0.10 • < 5.4 1 mg/L lbs/Day I.Flow VALUE VALUE VALUE VALUE 6.5 6.5 6.5 101 MGD N/A g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 25.81 1 DEGREES CELSIUS I.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 7.1 7.2 2 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional AND CAS NO. Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (t available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass .(1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (I)Concentration (2)Mass 'ANALYSES a.Bromide X < 0.20 < 10.8 1 mg/L lbs/Day (24959-7-9) b.Chlorine, X < 0.050 < 2.7 1 mg/L lbs/Day Total Residual c.Color X 20 N/A N/A N/A 1 Std.Units N/A N/A d.Fecal X 4 N/A N/A N/A 1 Colonies N/A N/A Coliform /100 ml a.Fluoride X < 0.10 < 5.4 1 mg/L lbs/Day (16984-48-8) f.Nitrate- X 0.18 9.8 1 mg/L lbs/Day Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 004 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional AND CAS NO. eelbved a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE _ a.LONG TERM AVG.VALUE (H available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tratlon (1)Concentration (2)Mass ANALYSES • g.Nitrogen, Total Organic X 0.28 15.2 0.53 28.7 0.31 16.8 6 mg/L lbs/Day as N) .Og and .. Grease X < 5.0 < 271.2 < 5 < 271.2 < 5 < 271.2 6 mg/L lbs/Day I.Phosphorous ' (as P),Total X 0.021 1.1 0.11 6.0 0.043 2.3 6 mg/L lbs/Day (7723.14-0) I.Radioactivity (1)Alpha, - - Total X < 5.0 < N/A N/A N/A 1 pCi/L N/A N/A (2)Beta, Total X < 5.0 < N/A N/A N/A 1 pCYI N/A N/A (3)Radium, Total X < 1.0 < N/A N/A N/A 1 pCVL N/A N/A (4)Radium 228,Total X 0.80 N/A N/A N/A 1 pCi/L N/A WA k.Sulfate (as SO4) A 6.9 374.3 1 mg/L lbs/Day (14808-79-8) I.Sulfide (as S) X < 1.0 < 54.2 1 mg/L lbs/Day m.Sulfite (as S03) X < 1.0 < 54.2 1 mg/L lbs/Day /14285.45.3) n.Surfactants A < 0.050 < 2.7 1 mg/L lbs/Day o.Aluminum, Total X 0.18 9.8 1 mg/L lbs/Day (7429-90-5) p.Barium, Total X < 0.050 < 2.7 1 mg/L lbs/Day (7440-39-3) q.Boron, Total X 0.062 3.4 1 mg/L lbs/Day (7440-42-8) r.Cobalt, Total X < 0.020 < 1.1 1 mg/L lbs/Day (7440-48-4) s.Iron,Total (7439-89-8) X 0.58 30.3 1 mg/L lbs/Day I.Magnesium, Total X 2.1 113.9 1 mg/L lbs/Day (7439-95-4) u.Molybdenum, Total X < 0.020 < 1.1 1 mg/L lbs/Day (7439-98-7) v.Manganese, Total X 0.078 4.2 1 mg/L lbs/Day (7439-96-5) w.Tin,Total (7440-31-5) A < 0.010 < 0.5 1 mg/L lbs/Day s.Titanium, Total X < 0.050 < 2.7 1 mg/L lbs/Day (7440-32-8) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 004 Allen Steam Station PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine whit±of the GC/MS-fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" _ 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AV .VALUE (if avaiable) quir- b.pre- c.ab- (d available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES(ration (1)Concentration 1(2)Mass ANALYSES METALS,CYANIDE,AND T TAL •HENOLS 1M.Antimony, X < 5.0 < 0.27 1 tg/L lbs/Day Total(7440-36-0) _ 2M.Arsenic,Total X < 5.0 < 0.27 1 ugh lbs/Day (7440.38-2) 3M.Beryllium, X < 1.0 < 0.05 1 ug/L lbs/Day Total(7440-41-7) 4M.Cadmium, X < 0.10 < 0.01 1 ugh Ibs/Day Total(7440-43-9) 5M.Chromium, X < 5.0 < 0.27 1 MA- lbs/Day Total(7440-47-3) M.Copper,Total X < 0.0050 < 0.27 1 mg/L lbs/Day (7440-50-8) 7M.Lead,Total X < 2.0 < 0.11 1 tg/L lbs/Day (7439-92-1) BM.Mercury,Total X 0.00502 0.00 1 mg/L lbs/Day /7439-97-8) 9M.Nickel,Total X < 10 < 0.54 1 ug/L lbs/Day (7440-02-0) 10M.Selenium, X < 1.0 < 0.05 1 ug/L lbs/Day Total(7782-49-2) 11M.Silver,Total X < 5.0 < 0.27 1 tg/L lbs/Day (7440-22-4) 12M.Thallium, X < 0.00050 < 0.0 1 mg/L lbs/Day Total(7440-28-0) 13M.Zinc,Total X < 0.010 < 0.54 1 mg/L lbs/Day (7440-86-8) • 14M.Cyanide, X < 0.010 < 0.54 1 mg/L lbs/Day Total(57-12-5) 15M.Phenols, X 0.0076 0.4 1 mg/L lbs/Day Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X < 0.0100 1 < 0.0001 1 I I ng/L I /Day I Dioxin(1784-01-6) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 004 Alien Steam Station 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-'cab- (d available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE COMPOUNDS 1 V.Acrolein X < 5.0 < 0.27 1 ugh lbs/Day (107-02-8) 2V.Acrylonitrile X < 5.0 < 0.27 1 ugh lbs/Day (107-13-1) 3V.Benzene X < 2.0 < 0.11 1 ug/L Ibs/Day (71-43-2) 4V.Bis(Chloro- methyl Ether X (542-88-1) 5V.Bromoform X < 2.0 < 0.11 1 ugh lbs/Day (75-25-2) 5V.Carbon Tetrachloride X < 2.0 < 0.11 1 1g/L lbs/Day (56-23-5) 7V.Chlorobenzene X < 2.0 < 0.11 1 ugh. lbs/Day (108-90-7) By.Chlorodi- bromome0ane X < 2.0 < 0.11 1 ugh bs/Day (124-48-1) 9V.Chloroethane X < 2.0 < 0.11 1 ug/L Ibs/Day (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 5.0 < 0.27 1 ug/L lbs/Day /(110-75-8) , 11V.Chloroform X < 2.0 < 0.11 1 ug/L lbs/Day (67.88-3) 12V.Dichloro- bromomethane X < 2.0 < 0.11 1 ug/L lbs/Day (75-27-4) 13V.Dichlero- dieuoromethane X < 2.0 < 0.11 1 ug/L lbs/Day (75-51-8) 14V.1,1-Dichtoro- X < 2.0 < 0.11 1 ug/L lbs/Day ethane(75-34-3) 1SV.1,2-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day ethane(107-05-2) 16V.1,1-Dichloro- X < 2.0 < 0.11 1 ugh lbs/Day ethylene(75-35-4) 17V.t,2-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day propane(78-87-5) 18V.1,3-Oichloro- X < 2.0 < 0.11 1 tg/L lbs/Day propylene(542-75-8) 19V.Ethylt enzene X < 2.0 < 0.11 1 ug/L lbs/Day (100.41-4) 20V.Methyl X < 2.0 < 0.11 1 ug/L lbs/Day Bromide(74-83-9) 21V.Methyl X < 2.0 < 0.11 1 ug/L lbs/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 004 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES tration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-V LATILE C MPOUNDS(continued) 22V.Methylene X < 2.0 < 0.11 1 ug/L lbs/Day Chloride(75-09-2) 23V.1,1,2.2-Tetra- chleroethane X < 2.0 < 0.11 1 ug/L lbs/Day (79-34-5) 24V.Tetrachtoro- X < 2.0 < 0.11 1 uglL lbs/Day ethylene(127-18-4) 25V.Toluene X < 2.0 < 0.11 1 ug/L lbs/Day (108-88-3) 26V.1,2-Trans- Dichtoroethylene X < 2.0 < 0.11 1 ug/L lbs/Day (156-60-5) 27V.1,1,1-Tri- chleroethane X < 2.0 < 0.11 1 ug/L lbs/Day (71-55-6) 28V.1,1,2-Tri- chloroethane X < 2.0 < 0.11 1 ug/L lbs/Day (79-00-5) 29V.Trichloro- X < 2.0 < 0.11 1 ug/L lbs/Day ethylene(79-01-6) 30V.Trichioro- Iluoromethane X < 2.0 < 0.11 1 ug/L lbs/Day (75-69-4) 31V.Vinyl X < 2.0 < 0.11 1 ug/L lbs/Day Chloride(75-014) GC/MS FRACTION-ACID COMPOUNDS 1A.2-Chlorophsnot X < 5.3 < 0.29 1 ug/L lbs/Day (95-57-8) 2A.2,4-Dichloro- X < 5.3 < 0.29 1 ug/L lbs/Day phenol(120-83-2) 3A.2,4-Dimethyl- X < 5.3 < 0.29 1 ug/L lbs/Day phenol(105-67-9) 4A.4,6-Dinitro-0- X < 5.3 < 0.29 1 ug/L Ibs/Day Cresol(534-52-1) 5A.2.4-Dinibo- X < 26 < 1.41 1 ug/L lbs/Day phenol(51-28-5) BA.2-Nerophenol X < 5.3 < 0.29 1 ug/L lbs/Day (88-75-5) 7A.4-Nitrophenol X < 5.3 < 0.29 1 ugh lbs/Day (100-02-7) BA.P-Chloro-M- X < 5.3 < 0.29 1 ug/L lbs/Day Cresol(59-50-7) 9A.Pentachloro- X < 5.3 < 0.29 1 ug/L lbs/Day phenol(87-86-5) 10A.Phenol X < 5.3 < 0.29 1 ug/L lbs/Day (108.95.2) 11A.2,4,6-Tn- chlorophenol X < 5.3 < 0.29 1 ug/L lbs/Day (88-06-2) EPA Fonn 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 004 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (4 available) quir- b.pre- c.ab- (it available) _ (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.Acenaphthene X < 5.3 < 0.29 1 ug/L lbs/Day (83-32-9) 2B.Acenaphtylene X < 5.3 < 0.29 1 ug/L lbs/Day (208-96-8) 3B.Anthracena X < 5.3 < 0.29 1 ug/L lbs/Day (120.12-7) 48.Benzidine X < 53 < 2.87 1 ug/L lbs/Day (92-87-5) 58.Benzo(a) Anthracene X < 5.3 < 0.29 1 ug/L lbs/Day (56-55-3) 68.Benzo(a) X < 5.3 < 0.29 1 ug/L lbs/Day Pyrene(50-32-8) 78.3,4-Banzo- Iluoranthene X < 5.3 < 0.29 1 ug/L Ibs/Day (205-99-2) _ .. .• ...- -"88.Benzo(php X < 5.3 < 0.29 1 MAMAlbs/Day - Pery$ene(191-24-2) 98.Benzo(k) Fluoranthene X < 5.3 < 0.29 1 ug/L lbs/Day (207-08-9) 108.Bis(2-Chloro- ethonyl)Methane X < 5.3 < 0.29 1 ug/L Ibs/Day /(111-91-1) 11B.Bis(2-Chloro- ethyl)Ether X < 5.3 < 0.29 1 ug/L lbs/Day (111-44-4) 12B.Bis(2-Chloroiso- propyl)Ether X < 5.3 < 0.29 1 ug/L lbs/Day (108-80-1) 13B.Bis(2-Ethyl- hezy)Phthalate X < 5.3 < 0.29 1 ug/L lbs/Day (117-81-7) , 14B.4-Bromo- phenyl Phenyl X < 5.3 < 0.29 1 ug/L lbs/Day Ether(101-55-3) 158.Butyl Benzyl X < 5.3 < 0.29 1 ug/L lbs/Day Phthalate(85418.7) 168.2-Chloro- naphthalene X < 5.3 < 0.29 1 ug/L lbs/Day (91-58-7) 178.4-Chbro- phenyl Phenyl X < 5.3 < 0.29 1 Ug/L lbs/Day Ether(7005-72-3) 188.Chrysene X < 5.3 < 0.29 1 ug/L lbs/Day (218-01-9) 198.Dlbenzo(a,h) Anthracene X < 5.3 < 0.29 1 ug/L lbs/Day (53-70-3) 208.1,2-Dichloro- X < 2.0 < 0.11 1 ug/L Ibs/Day benzene(95-50-1) 21B.1.3-Dichloro• X < 2.0 < 0.11 1 ug/L lbs/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 004 Alien Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- b.pre-Ic.ab- (if available) (if available) d.NO.OF a.Conan- b.Mass d.NO.OF ed sent sent (1)Concentration (2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTAL COMPOUND (continued) 22B.1,4-Dichloro- X < 2.0 < 0.11 1 ug/L lbs/Day benzene(106-46-7) 23B.3,3-Dichloro- benzidine X < 5.3 < 0.29 1 ug/L lbs/Day (91-94-1) 24B.Diethyl Phthalate X < 5.3 < 0.29 1 ugfL lbs/Day (84-66-2) 258.Dimethyt Phthalate X < 5.3 < 0.29 1 ugfL lbs/Day (131-11-3) 268.Di-N-Butyl Phthalate X < 5.3 < 0.29 1 ug/L lbs/Day (84-74-2) 278.2,4-Dinero- X < 5.3 < 0.29 1 ug/L lbs/Day toluene(121-14-2) 288.2,6-D nitro- X < 5.3 < 0.29 1 Ig/L lbs/Day toluene(606-20-2) 298.Di-N-Octyl Phthalate X < 5.3 < 0.29 1 ugh lbs/Day (117-84-0) 308.1,2-Diphenyl- hydrazine(as Azo- X < 5.3 < 0.29 1 ug/L lbs/Day penzene)(122-66-7) 318.Fluoranthene X < 5.3 < 0.29 1 ug/L lbs/Day (206-44.0) 328.Fluorene X < 5.3 < 0.29 1 ug/L lbs/Day (86-73-7) 338.Hexichloro- X < 5.3 < 0.29 1 ug/L lbs/Day benzene(118-74.1) 34B.Hexa- chlorobutadiene X < 5.3 < 0.29 1 tg/L lbs/Day (87-68-3) 358.Hexachtoro- cyclopentadiene X < 5.3 < 0.29 1 ugh lbs/Day (7747-4) 368.Hexachloro- X < 5.3 < 0.29 1 ug&L lbs/Day ethane(87-72-1) 378.Indeno (1,2,3-cd)Pyrene X < 5.3 < 0.29 1 ugh lbs/Day (193-39-5) 388.Isophorone X < 5.3 < 0.29 1 ug/L lbs/Day (76.59-1) 398.Naphthalene X < 5.3 < 0.29 1 tg/L lbs/Day (91-20-3) 408.Nitrobenzene X < 5.3 < 0.29 1 ug/L Ibs/Day (98-95-3) 418.N-Nitro- sodimethylamine X < 5.3 < 0.29 1 ug/L lbs/Day (62-75-9) 428.N-Nitrosodi- N-Propylemine X < 5.3 < 0.29 1 ugh lbs/Day (621-64-7) -EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 004 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. ail- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) qur- b.pre- c.ab- (if available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed sent sent (1)Concentration l(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES (ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION-BASE/NEUT AL3 COMPOUNDS(continued) 438.N-Nitro- sodiphenylamine X < 5.3 < 0.29 1 ug/L IbslDay (88.30.6) 448.Phenanthrene X < 5.3 < 0.29 1 ugh lbs/Day (85-01-8) 45B.Pyrene X < 5.3 < 0.29 1 ugft. lbs/Day (129-00-0) 468.1,2.4-Tri- chlorobenzene X < 2.0 < 0.11 1 ug/L Ibs/Day (120-82-1) GC/MS FRACTION-PESTICIDE$ 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319.84.8) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.deka-BHC X (319-86-8) BP.Chlordane X (57-74-9) 7P.4,4'-DDT X (50-29-3) BP.4,4'-DOE X (72-55-9) 9P.4,4'-DDD X (72-54-8) 10P.Dieldrin X (60-57-1) 11P.alpha-Endosulhn X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X (76-44-8) EPA Form 3510.2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1 OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 004 Allen Steam Station 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- Believed a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (ifavaaabte) quir- b.pre- c.ab- (if available) (if available) d.NO.OF a.Conan- b.Mass d.NO.OF ed sent sent (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass (1)Concentration 1(2)Mass ANALYSES ration (1)Concentration 1(2)Mass ANALYSES GC/MS FRACTION- ESTI IDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X < 0.25 < 0.01 1 ug/L lbs/day (53489-21-9) 19P.PCB-1254 X < 0.25 < 0.01 1 ug/L lbs/day (11097439-1) 20P.PCB-1221 X < 0.25 < 0.01 1 ug/L lbs/day (11104-28-2) 21P.PCB-1232 X < 0.25 < 0.01 1 ug/L lbs/day (11141-18-5) 22P.PCB-1248 X < 0.25 < 0.01 1 ug/L lbs/day (12872-29.8) 23P.PCB-1280 X < 0.25 < 0.01 1 ug/L lbs/day (11098-82-5) 24P.PCB-1018 X < 0.25 < 0.01 1 lg/L lbs/day (12874.11.2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 EPA ID Number(copy from item I of Form 1) Form Approved.OMB No.2040-0086 Please print or type in the unshaded areas NC0004979 Approval expires 5-31-92 United States Environmental Protection Agency Form Washington,DC 20460 2F 1 0EP! Application for Permit to Discharge Storm Water NPDES Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions,searching existing data sound,,gathering and maintaining the data needed,and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions for improving this form,including suggestions which may increase or reduce this burden to:Chief, Information Policy Branch,PM-223,U.S.Environmental Protection Agency,401 M St.,SW,Washington,DC 20460,or Diredor,Office of Information and Regulatory Affairs,Office of Ma ent and B t,Washington,DC 20503. I. Outfall Location For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number D. Receiving Water (list) B. Latitude C. Longitude (name) SW 008 35 11 I 25 81 _ 00 28 Catawba River SW 015 35 10 55 81 00 22 Catawba River Note: For monitoring purposes, the above outfalls representative of the remaining 15 outfalls. 11. Im•rovements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. 4. Final 1.Identification of Conditions, 2.Affected Outfalls Compliance Date Agreements, Etc. number source of discharge 3. Brief Description of Project a.req. b.proj. B. You may attach additional sheets describing any additional water pollution(or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and indicate your actual or planned schedules for construction. III. Site Draina•e Ma. Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a topographic map Is unavailable)depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment, storage or disposal units(including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34);each well where fluids from the facility are injected underground;springs,and other surface water bodies which receive storm water discharges from the facility. EPA Form 3510-2F (Rev. 1-92) Page 1 of 3 Continued on Page 2 Continued from the Front IV. Narrative Description of Pollutant Sources A. For each outfall,provide an estimate of the area(include units)of impervious surfaces(including paved areas and building roofs)drained to the outfall,and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) (provide units) Number (provide units) (provide units) SW001 See attached - supplemental SW017 information. B. Provide a narrative description of significant materials that are currently or in the past three years have been treated, stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff;materials loading and access areas;and the location, manner,and frequency in which pesticides,herbicides,soil conditioners,and fertilizers are applied. See attached supplemental information. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outfall List Codes from Number Treatment Table 2F-1 SW001 See attached supplemental information. SW017 V. Non Stormwater Discharges A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges,and that all nonstormwater discharges from these outfall(s)are identified in either an accompanying Form 2C or Form 2E application for the outfall. Name of Official Title(type or print) Signature Date Signed Steve lmmel, General Manager 11 11/30/2009 Regulated Fossil Stations B. provide a description of the method used,the date of any testing, d the onsite drainage points that were directly observed during a test. Visual inspection was performed on November 29, 2009. Besides the outfall permitted under the NPDES permit for the discharge of process water, there were no non-storm water flows observed from the storm water outfalls. VI. Significant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years,including the approximate date and location of the spill or leak,and the type and amount of material released. Within the past three years, there have not been any significant spills of hazardous substances in excess of reportable quantities set forth by Section 311 of the Clean Water Act or Section 102 of CERCLA. EPA Form 3510-2F(Rev. 1-92) Page 2 of 3 Continued on Page 3 EPA ID Number(copy from Item I of Form 1) Continued from Page 2 NC0004979 VII. Discharge Information A,B,C,&D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii-A,VII-B,and VII-C are included on separate sheets numbered VII-1 and VII-2. E. Potential discharges not covered by analysis - is any toxic pollutant listed in table 2F-2, 2F-3, or 2F-4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? n Yes(list all such pollutants below) X No(go to Section IX) VIII. Biolo•ical Toxicit Testing Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? n Yes(list all such pollutants below) X No(go to Section IX) IX. Contact anal sis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? ® Yes(list the name, address, and telephone number of,and pollutants I I No(go to Section X) analyzed by, each such laboratory or firm below) A.Name B.Address C.Area Code&Phone No. D. Pollutants Analyzed Shealy Environmental Services 106 Vantage Point Drive 803-791-9111 Wet chemistry& West Columbia, SC 29172 metals GEL Laboratories LLC 2040 Savage Road 843-556-8171 Radiologicals Charleston, SC 29407 X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. Name&Official Title(type or print) B.Area Code and Phone No. Steve Immel, General Manager II (704) 829-2400 Regulated Fossil Stations C.Signature D. Date Signed 11/30/2009 EPA Form 3510-2F (Rev. 1-92) Page 3 of 3 EPA ID Number(copy from Item/of Form 1) Form Approved. OMB No.2040-0086 SW008 NC0004979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2F) Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <4.8 mg/L I See Supplemental Information Biological Oxygen <2.0 mg/L 1 ii Demand(BOD5) Chemical Oxygen 80 mg/L I " Demand(COD) Total Suspended 1500 mg/L I " Solids(TSS) Total 0.52 mg/L I " Nitrogen Total 0.98 mg/L 1 " Phosphorus pH Minimum Maximum Minimum Maximum 1 " 7.78 SU Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Chlorine,Total <0.1 mg/L I See Supplemental residual Information Chloride <1.0 mg/L 1 Color 20 units 1 " Fluoride(16984-48-8) 0.30 mg/L 1 " Nitrate-Nitrite(as N) <0.020 mg/L 1 " Radioactivity,alpha 21.4 t 3.78 1 " total pCi/L Radioactivity,beta 42.8 t 3.84 1 " total pCUL Radioactivity,radium 3.86±0.877 1 " total pCi/L Radioactivity,radium 1.02 t 0.349 1 " 226 total pCUL Sulfate(as SO4) 26 mg/L 1 " (14808-79-8) Aluminum,Total 27.0 mg/L 1 " (7429-90-5) Barium,Total 0.470 mg/L q " (7440-39-3) Boron,Total(7440- <0.050 mg/L I " 42-8) Cobalt,Total(7440- 0.026 mg/L 1 " 48-4) _ Iron,Total(7439-89-6) 36.0 mg/L 1 " Magnesium,Total 17.0 mg/L I " (7439-95-4) Manganese,Total 1.00 mg/L 1 " (7439-96-5) Tin,Total <0.005 mg/L 1 " (7440-31-5) Titanium,Total 2.20 mg/L 1 ff (7440-32-6) EPA Form 3510-2F(Rev. 1-92) Page VII-1 Continue on Reverse Arsenic,Total <0.050 mg/L 1 See Supplemental (7440-38-2) information Beryllium,Total <0.001 mg/L 1 )I (7440-41-7) . Cadmium,Total <0.000/0 1 (7440-43-9) mg/L Chromium,Total 0.020 mg/L 1 " (7440-47-3) Copper,Total 0.058 mg/L 1 " (7440-50-8) Mercury,Total 0.00014 mg/L 1 " (7439-97-6) Nickel,Total 0.019 mg/L 1 " (7440-02-0) Selenium,Total <0.050 mg/L 1 " (7782-49-2) Silver,Total <0.005 mg/L 1 " (7440-22-4) Zinc,Total 0.320 mg/L 1 " (7440-66-6) EPA Form 3510-2F(Rev. 1-92) Page WI-1 Continue on Reverse Continued from the Front Part C- List each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present.See the instructions for additional details and requirements.Complete one table for each outfall. Maximum Values Average Values Number Pollutant (Include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Fecal Coliform CHI* 546*co1/100 1 See Supplemental mL Information *analyzed outside holding time Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Number of hours between Date of Storm Event Duration Total rainfall beginning of storm measured and Total flow from of Storm during storm end of previous measurable rain rain event Event event event (gallons or specify units) (in minutes) (in inches) 6/4/2009 960 2.82 81 hours 188374 gallons 7. Provide a description of the method of flow measurement or estimate Flows estimated using run-off coefficients for the drainage area based on rainfall data EPA Form 3510-2F(Rev. 1-92) Page VII-2 EPA ID Number(copy from Item l of Form 1) Form Approved. OMB No.2040-0086 SW 015 NC0004979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2F) Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <4.4 mg/L 1 See Supplemental Information Biological Oxygen 2.0 mg/L 1 " Demand(BOD5) Chemical Oxygen 16 mg/L 1 - Demand(COD) Total Suspended 25 mg/L 1 - Solids(TSS) _ _ Total 0.099 mg/L 1 - Nitrogen Total 0.059 mg/L 1 - Phosphorus pH Minimum Maximum Minimum Maximum 1 " 7.26 SU Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Chlorine,Total 0.11 mg/L 1 " residual Chloride 5.4 mg/L 1 is Color 100 units 1 - Fluoride(16984-48-8) 0.12 mg/L 1 - Nitrate-Nitrite(as N) 0.099 mg/L 1 - Radioactivity,alpha <5.0 pCi/L 1 " total Radioactivity,beta 7.10 pCi/L 1 - total Radioactivity,radium <1.0 pCl/L 1 " total Radioactivity,radium <1.0 pCl/L 1 - 226 total , Sulfate(as SO4) 38 mg/L 1 - (14808-79-8) _ _ Aluminum,Total 0.35 mg/L 1 - (7429-90-5) _ Barium,Total 0.080 mg/L 1 - (7440-39-3) _ Boron,Total(7440- 0.33 mg/L 1 Si 42-8) Cobalt,Total(7440- <0.005 mg/L 1 " 48-4) Iron,Total(7439-89-6) 1.8 mg/L 1 - Magnesium,Total 5.3 mg/L 1 " (7439-95-4) , Manganese,Total 0.60 mg/L 1 - (7439-96-5) , Tin,Total <0.005 mg/L 1 - (7440-31-5) _ Titanium,Total 18 ug/L 1 - (7440-32-6) EPA Form 3510-2F(Rev. 1-92) Page VII-2 Arsenic,Total 20 ug/L 1 See Supplemental (7440-38-2) Information Beryllium,Total <1.0 ug/L 1 se (7440-41-7) _ Cadmium,Total <0.10 ug/L 1 « (7440-43-9) Chromium,Total <5.0 ug/L 1 .. (7440-47-3) Copper,Total <10 ug/L 1 « (7440-50-8) _ _ Mercury,Total <0.0001 mg/L 1 « (7439-97-6) Nickel,Total <10 ug/L 1 « (7440-02-0) Selenium,Total <5 ug/L 1 « (7782-49-2) Silver,Total <5 ug/L 1 « (7440-22-4) , Zinc,Total 35 ug/L 1 « (7440-66-6) EPA Form 3510-2F(Rev. 1-92) Page VII-2 Continued from the Front Part C- List each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present.See the instructions for additional details and requirements.Complete one table for each outfall. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of PoHutants Fecal Coliform CHT 410•co1h00 1 See Supplemental mL information *analyzed outside holding time Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Date of Storm Event Duration Total rainfall Number of hours between Totalr flow from of Storm duringstorm beginning of storm measured and rain event e9 9 (gallons or specify units) Event event end of previous measurable rain (in minutes) (in inches) event 4/20/2009 240 .59 >72 hours 1424263 gallons 7. Provide a description of the method of flow measurement or estimate. Flows estimated using run-off coefficient with drainage area and rainfall data EPA Form 3510-2F(Rev. 1-92) Page VII-2 NPDES Supplemental Information Allen Steam Station NPDES Permit # NC0004979 November 2009 Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 2 of 26 TABLE OF CONTENTS Page No. 1.0 GENERAL INFORMATION 3 2.0 OUTFALL INFORMATION 2.1 Outfall 001 — Condenser Cooling Water 3 2.2 Outfall 002 —Ash Basin 4 2.3 Outfall 002A— Coal Yard Sump Emergency Overflow 11 2.4 Outfall 002B — Powerhouse Sump Overflow 11 2.5 Outfall 003— Miscellaneous Equipment Cooling and Seal Water 11 2.6 Outfall 004— Equipment Cooling and Intake Screen Backwash 12 2.7 Outfall 005—WWTS Effluent Discharge 12 3.0 STORMWATER 13 4.0 HAZARDOUS AND TOXIC SUBSTANCES 25 5.0 ALLEN STEAM STATION 316 DETERMINATION 26 5.1 316(a) 26 5.2 316(b) 26 Allen Steam Station,Gaston County NPDES Permit No. NC0004979 Page 3 of 26 1.0 GENERAL INFORMATION Plant Allen utilizes waters from the Catawba River for condenser cooling and service water requirements. A brief discussion of each discharge follows. All flows are based on historical data where possible or pump design capacities and normal run-times. 2.0 OUTFALL INFORMATION 2.1 Outfall 001 - Condenser Cooling Water (CCW) The CCW system is a once-through, non-contact cooling water system that removes heat rejected from the condensers and other selected heat exchangers and then discharges into the South Fork River. Each of the 5 units at Plant Allen has two condenser cooling pumps. The number of pumps used is dependent on unit load and intake temperatures with more pumps running with higher loads and intake temperatures. Units 1 and 2 share a common cooling water supply tunnel served by a total of 4 CCW pumps. Units 3 and 4 also share a tunnel and 4 CCW pumps. Unit 5 has a separate tunnel and 2 CCW pumps. The common tunnel design enables three pumps to give Units 1 and 2 or 3 and 4 the equivalent of 1 '/2 pump operation. The 1 '/2 pumps operation adds an economical range or flexibility when units are on partial load and when intake water temperatures are minimal. Condenser Coolin• Water Pum• Ca*acities Unit No. 1-Pump GPM 1.5-Pump GPM 2-Pump GPM 1 55,500 74,800 83,500 2 55,500 74,800 83,500 3 83,000 111,200 126,000 4 83,000 111,200 126,000 5 83,000 126,000 All condenser tubes at Plant Allen are cleaned manually with metal or rubber plugs. Mechanical cleaning is required once a year for most units. A leak test is performed periodically on the condenser tubes. (See section 2.2.6.4.) If leaks are detected, then one method used to temporarily stop small leaks is to add sawdust to the CCW system, as previously approved by NCDENR. The sawdust is added at amounts that will plug the leaks and not result in an environmental impact. This is a temporary measure until the unit can come off-line so the leaks can be permanently repaired. Use of the supplemental pumping system that was approved for operation from July through September 2008 is proposed on an as-needed basis between July and September of each year. During operation of the supplemental pumping system, calculation of Allen Steam Station's CCW discharge temperature for Outfall 001 will be modified to include the temperature of the supplemental Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 4 of 26 cooling water pumping system based on the system flow and Allen Steam Station's CCW intake temperatures, as was done in 2008. The supplemental pumping system will enable Allen Steam Station to extend power production in compliance with current thermal limits that assure protection of the aquatic community and downstream users. 2.1.1 Asiatic Clam/Debris Filter Backwash Water for the Unit 5 CCW water is filtered for any twigs, leaves and other light debris, which passed through the intake screens. Asiatic clams, which are common in Lake Wylie and can clog the condenser tubes, are also captured in this filter. This filter is backwashed once a week for 15 minutes. A maximum flow of 3000 GPD is realized. No additives are in the backwash water. The twigs, leaves, clams and other light debris collected in the debris filter are indigenous to the river and are therefore flushed back with no harmful environmental consequences. 2.2 Outfall 002 - Ash Basin 2.2.1 Boiler Cleaning All five boilers at Plant Allen are chemically cleaned with the next cleaning as needed. The volume of the boilers determines the quantity of chemicals required for a cleaning. Boilers#1 and #2 each have a waterside volume of 26,700 gallons. The volume of boilers #3, #4, and #5 is 40,100 gallons each. The volume of dilute waste chemical discharged from unit#1 or#2 during a cleaning is 294,000 gallons. The volume of diluted waste chemicals drained from #3, #4 and #5 totals 450,000 gallons each. These wastes are drained through temporary piping to the permanent ash removal lines, which flow to the ash basin. Immediately prior to the beginning of a boiler chemical cleaning procedure, additional stop logs are added to the ash basin discharge structure. This action assures longer retention time of the chemical wastes for proper treatment through dilution, neutralization, precipitation, and ion-exchange as documented in the Ash Basin Equivalency Demonstration (October 1976). Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 5 of 26 A list of the chemicals and amounts required to clean the boilers at Plant Allen follows: CLEANING CHEMICALS AMOUNT USED PER UNIT Boiler#1 and #2 Boiler#3, #4 & #5 Sodium bromate 550 lbs 550 lbs Ammonium carbonate 1000 lbs 1000 lbs Ammonium hydroxide* 850 gal 950 gal Hydrochloric acid* 3700 gal 5500 gal Thiourea* 1680 lbs 2010 lbs Citric acid 300 lbs 400 lbs Sodium Sulfite 100 lbs 100 lbs Ammonium bifluoride 1100 lbs 1700 lbs Detergent (Triton —X) 20 gal 20 gal Antifoam agent 10 gal 10 gal During a chemical metals cleaning these chemicals are present in amounts greater than the reportable quantity as identified under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). If a spill of any these chemicals were to occur, in most cases, it would be routed to the ash basin for treatment. Alternately, the boiler may be cleaned using ethylenediaminetetraacetic acid (EDTA). If EDTA is used for cleaning, no waste water will be discharged to the ash basin, rather all cleaning waste waters will either be evaporated in the boiler or collected and transported off-site for proper treatment and disposal. 2.2.2 Stormwater run-off Storm water run-off enters the ash basin from the from the ash basin's drainage area, the yard drainage sump, the coal yard sump, the FGD storm water basin and the landfill leachate sump. The powerhouse sump and the limestone storm water sump discharges its rainfall run-off into the yard drainage sump. A more detailed description of the sump systems and stormwater run-off is included in section 3.0. 2.2.3 Sanitary Wastes Sanitary waste at Plant Allen is treated in a septic tank with the effluent from the septic tank being discharged to the Ash Basin via the Coal Yard sump. Approximately 150 people are responsible for the load on this system. An average flow of 4850 GPD is treated by the system. The drinking water is supplied by City of Belmont Utilities Department. 2.2.4 Ash Sluice Plant Allen has converted to a dry ash handling system. Ash collected in the electrostatic precipitators is transported by compressed air to two silos where ash is transferred to trucks for ultimate disposal in the newly constructed on-site Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 6 of 26 landfill. Wet sluicing is still utilized during times of start up and dry system upset. Bottom ash sluicing to the basin requires approximately 6.0. Plant Allen presently has additional air pollution control systems installed on three units. Use of these systems entails the use of low concentrations of ammonia and sulfur compounds. These systems aid in the collection of the ash in the electrostatic precipitators. 2.2.5 Recirculating Water System (RCW) Plant Allen has 2 RCW systems: a chiller system and a pump cooling water system. Both systems use the biocide Nalco H-550 or similar products. In addition, the corrosion inhibitor Nalco CS-4710 or similar product is used. Generally, these systems are closed loop, but may need to be drained occasionally. All such water would enter the floor drains and then be discharged to the ash basin. 2.2.6 Miscellaneous Waste Streams 2.2.6.1 Turbine Non-destructive Testing Approximately once per year, one turbine is tested for cracks in the generator shaft using an ultrasonic nondestructive test. During the process a maximum of 400 gallons of demineralized water mixed with 4 gallons of corrosion inhibitor is used and discharged to the ash basin. 2.2.6.2 Heat Exchanger Cleaning From time to time, it may be necessary to clean the small heat exchangers with polyacrylamide, polyacrylate, sodium laurylsulfate and tri-sodium phosphate. All wastewater would be routed to the ash basin. 2.2.6.3 Condensate Polishers: Plant Allen utilizes condensate polishers which divert a portion of the normal condensate (closed system)flow through one of two cells per unit. The polishers provide filtration as well as ion exchange functions to remove or substantially reduce dissolved solids and suspended matter present in the condensate stream. The polishers require precoating with a combination of anion and cation resin. To facilitate precoating, 125-150 ml of a solution of polyacrylic acid (25%) is added to the precoat slurry. Upon exhaustion, the precoat is removed from the filters by water/ air blasting and flushed to the ash basin via sumps. Condensate water is used to remove the exhausted precoat at the rate of: • Unit 1 & 2 - 1558 gal/precoat • Units 3, 4, & 5 - 2090 gal/precoat. A total average waste flow of approximately 980 GPD to the ash basin is realized. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 7 of 26 2.2.6.4 Condenser Leakage Testing: Fluorescing Dye Method -Approximately 1 lb. of a disodium fluorescing dye added to 280,000 gals of demineralized water is used occasionally to test the condensers for leakage. All wastewater from the testing would be routed to the ash basin. Sulfur Hexafluoride Method - Periodically, sulfur hexafluoride is injected into the condenser tubes to locate condenser tube leaks. Sulfur hexafluoride is a chemically inert, nonflammable, nontoxic gas with an extremely low water solubility. It is estimated that 150 grams of sulfur hexafluoride would be used during the leak detection process. Most of the sulfur hexafluoride would be volatilized during the process. 2.2.6.5 FGD Stormwater Sump Stormwater collected at FGD site including: the dry ash handling facility, gypsum pile, WWTS area (not process water), stack, absorbers, switchgear building, dewatering building, reagent prep building, and the control room area is routed to a large stormwater collection basin prior to being pumped to the ash basin (See Section 3.4 for a more detailed description of FGD stormwater sump) 2.2.6.5 Landfill Leachate collection discharge: Industrial Solid Waste landfill (Permit No. 36-12) permitted to accept coal combustion byproducts (fly ash, bottom ash, gypsum, WWTS filter press sludge cake) consists of a double liner with leachate collection system. Collected leachate will be pumped to ash basin. 2.2.7 Ash Basin Treatment Sulfuric Acid System- An acid injection system utilizing 93 % sulfuric acid is operated as needed to maintain pH level below 9.0 standard units. Sodium Hydroxide System -A sodium hydroxide injection system utilizing 25% or 50% sodium hydroxide operated as needed to maintain pH level above 6.0 standard units. 2.2.8 Yard Drain Sump The yard drain sump is a large concrete structure that has three level controlled pumps, which pump wastewater from Plant Allen to the ash basin. These pumps are operated on a rotating basis. The combined average flow from all sources tied to the yard drain sump is approximately 4.0 MGD. (See Section 3.4 for a more detail description of rainfall run-off entering the yard drain sump.) Below is a description of waste streams going to the yard drain sump: 2.2.8.1 Boiler Room Sumps (Units 1-4) The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous Men Steam Station,Gaston County NPDES Permit No.NC0004979 Page 8 of 26 leakage (refer to the attached schematic of water flow for individual flows). The effluent from the units 1 through 4 boiler room sumps is flushed to the yard drain sump. The effluent from the unit 5 boiler room sump is flushed to the power house sump, which is then flushed to the yard drain sump. 2.2.8.2 Turbine Room Sumps The turbine room sumps accommodate flows from floor washing, leakage, and occasional condenser water box drainage. Effluent from units 1 through 5 turbine room sumps is flushed to the yard drain sump. 2.2.8.3 Limestone Unloading/Storage Area Sump Limestone sump collects stormwater from limestone unloading and storage area and routes to YD sump via PH sump dischage line. (See Section 3.4 for a more detail description of limestone sump) 2.2.9 Water Treatment System The water treatment wastes consist of sedimentation, filter backwash, reverse osmosis (RO) concentrate, demineralizer regeneration wastes and boiler blowdown. The make-up water treatment system is comprised of a clarifier, two pressure filters, two activated carbon filters, pre RO filters, a reverse osmosis machine and one set of demineralizers. Make-up water is used in the boilers and closed cooling systems. Clarifier: The clarifier has an average production of 0.252 MGD. Caustic or ferric sulfate/ferric chloride are used to affect precipitation and thus remove suspended solids from the raw river water. Desludging of the clarifier takes place approximately 8% of the unit run-time with an average volume of 2300 GPD going to the ash basin. Pressure Filters: There are two pressure filters which follow the clarifier in the water treatment process. These filters are backwashed once per week with a waste flow of 11,000 gallons per backwash. Each pressure vessel will contain 84 ft3 of anthracite, 50 ft3 of quartz, 25 ft3 of garnet and 41 ft3 of garnet/quartz support media. Each vessel will use product water to backwash at a rate of 750 gpm. On average, both vessels is backwashed once per week. The contents of the pressure filters will be changed out, as internal maintenance requires, and the used filter medium will be sluiced to the ash basin. Activated Carbon Filters: In addition to the pressure filters, there are two activated carbon filters. These filters are backwashed twice per month. Approximately 30,000 gallons of water are required to backwash each of these filters. The activated carbon filters are composed of approximately 250 ft3 of granular activated carbon (coal). The spent filter medium is changed out yearly and sluiced to the ash basin. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 9 of 26 Reverse Osmosis (RO) Unit: A RO unit is used to decrease the conductivity in the filtered water, thereby increasing the efficiency of the demineralizers and reducing the amount of chemical needed for demineralizer regeneration. During operation, the unit has a continual blowdown of 60 gal/min, which is discharged, to the ash basin. The RO unit is cleaned on a quarterly basis with the waste going to the yard drains and eventually the ash basin. During a cleaning, approximately 30 lbs of a sulfamic acid cleaner along with 5 gallons of biocide, 2 liters of sodium hydroxide, and 0.5 gallons of sodium lauryl sulfate is used. Demineralizer: The demineralizer consists of two mixed-bed cells. Only one of these cells is operated at any one time. The cell which is in operation is regenerated approximately once every 7- 14 days of operation. A regeneration requires 42 gallons of sulfuric acid (78-80%) and 150 gallons of 50% sodium hydroxide. An average dilute waste chemical and rinse flow of 20,000 gal is realized. The dilute acid and caustic are discharged to the floor drains simultaneously through the same header for neutralization purposes. All regeneration wastes are flushed to the ash basin. The demineralizer resin is changed out approximately once every 10 years and the spent resin is sluiced to the ash basin. Approximately 1 milliliter of the surfactant Triton CF-54 or similar product is added to the new resin to improve separation. Boiler Blowdown: Each of the five boilers at Plant Allen blowdown at an average rate of approximately 500 lbs. of steam per hour. The blowdown is allowed to flash in a blowdown tank. Most of the blowdown is vented to the atmosphere with a minimal amount of condensate discharged to the boiler room sump. The average condensate flow to this sump is 0.004 MGD. Hydrazine is maintained at a concentration of 25 ppb in the condensate system for deoxygenation. A minute amount of hydrazine (<10 ppb) may be present in the condensate flow to the boiler room sump. 2.2.10 Preheater Washes Preheaters are backwashed with raw water approximately 2 times per year to remove ash and corrosion products. There are 12 preheaters at Allen that would require approximately 100,000 gallons of backwash water each. The backwash water is routed to the ash basin through the yard drain sump. 2.2.11 Laboratory Wastes The plant chemistry and the FGD chemistry laboratories on site perform a variety of water analyses and routine sample collections. Therefore several chemicals are used in the lab in small quantities for sample preservation, bottle rinsing, equipment calibration, conductivity analyses, etc. The wastes are flushed down the sink and discharged into the yard drain sump and then pumped to the ash basin. Some of the laboratory chemicals are as follows: Ammonia molybdate, Acetic acid, Ferric sulfate, Hydrochloric acid, Monoethylamine, Nitric acid and Potassium hydroxide. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 10 of 26 2.2.12 Power House Sump (Unit 5) The wastes, which enter the floor drains at Plant Allen, accumulate in the boiler room sumps and turbine room sumps. The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous leakage. Effluent from the unit 5 boiler room sump is flushed to the powerhouse sump, which is then flushed to the yard drain sump. This sump also receives stormwater from various drains located on the north end of the powerhouse. (See Section 3.4 for a more detail description of rainfall run-off entering the powerhouse sump.) 2.2.13 Physical Chemical Treatment System The purpose of this system is to provide a chemical injection system for treatment of dissolved pollutants that would not settle out of the wastestream through purely physical means. The system treats 4-6 MGD sluice water to reduce the Total Suspended Solids (TSS) and selenium to below permit limits. The three primary settling cells are used to settle the solids (one at a time, while the inactive cells are being cleaned). The treatment channel conveys settled sluice wastewater to the secondary settling or flocculation cell. Approximately 25-50 gpm of the settled waste stream from the treatment channel is pumped into the chemical treatment building. This wastewater stream provides the opportunity to take samples before and after treatment and serves as the chemical injection point. The chemicals that are presently utilized for treatment in this system are: sulfuric acid, ferric sulfate, ferric chloride and sodium hydroxide. After chemical addition and mixing in the treatment channel, the treated waste stream is discharged into a floc settling basin to allow sufficient settling time for any precipitated compounds to settle prior to discharge. Overflow from the final settling cell flows through a vegetated ash delta prior to discharge to the main pond. 2.2.14 Selective Non-Catalytic Reduction (SNCR) As part of the compliance with the North Carolina Clean Air Initiative (NCCAIR), Allen has installed a urea based "trim" Selective Non-Catalytic Reduction (SNCR) systems on all five units. The trim SNCR systems are expected to reduce NOx emissions by approximately 30%. SNCR systems operate by injecting urea into the upper section of the boiler where a chemical reaction occurs to reduce the NOx to water and nitrogen. Some residual ammonia will be collected on the fly ash in the electrostatic precipitators and a small amount will be carried to the ash basin. However, the operation of the SNCR system is not expected to require additional treatment capabilities to ensure compliance with NPDES permit limits. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 11 of 26 2.2.15 Flue Gas Desulfurization (FGD) A Wet Flue Gas Desulfurization (FGD) system has been installed at Allen for the reduction of SO2 from the stack gas. The following provides a description of the FGD system at Allen. In a Wet Scrubber system, the SO2 component of the flue gas produced from the coal combustion process is removed by reaction with limestone-water slurry. The particular system used at Allen collects the flue gas after it passes through the electrostatic precipitator and routes the gas into the absorber tank. As the gas rises through the tank to the outlet at the top, the gas passes through a spray header. A slurry of water and limestone droplets is continually sprayed through this header into the stream of flue gas. The SO2 in the flue gas reacts with the calcium in the limestone and produces SO3. The SO3 slurry falls to the bottom of the tank where a stream of air is injected to oxidize the slurry to form gypsum (CaSO4.2H2O). The gypsum slurry is drawn off the absorber tank and subsequently pumped to a vacuum belt filter. Part of the process water from the FGD system is blown down in order to maintain the FGD water chemistry within the FGD system specifications. This water is treated in a wastewater treatment system that discharges to the ash basin via internal Outfall 005. The FGD system has a material handling system that supplies limestone to the scrubber and a gypsum storage area for the gypsum removed from the process. The limestone comes onto the site by rail and is then transferred to the FGD site via a covered conveyor. Runoff from the storage area is routed to the ash basin. The gypsum is routed from the FGD tank to a dewatering belt and then to a covered conveyor belt that will carry it to a storage pile. The runoff from this area is also routed to the ash basin. 2.3 Outfall 002A— Coal Yard Sump Overflow An overflow pipe that directs flow from the sump to the Catawba River was included in the construction of the coal yard sump. This modification was implemented to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. 2.4 Outfall 002B — Powerhouse Sump Overflow An overflow pipe that directs flow from the sump to the ground was included in the construction of the powerhouse sump. This modification was implemented to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. If enough water overflows, the waste water could potentially get to the Catawba River. Overflow has not occurred during the last permit cycle. 2.5 Outfall 003 — Misc Equipment Cooling & Seal Water Outfall 003 discharges into the CCW discharge canal. The discharge consists of cooling water from units 4 and 5 boiler feedpump hydraulic coupling coolers and other miscellaneous equipment cooling. This water is once-through, non-contact cooling water withdrawn from the service water system. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 12 of 26 Approximately 10,000 gpd of bearing cooling water for the ash line booster pump is routed back to the discharge canal via a stormwater outfall in the vicinity of outfall 003. The water is once through, non-contact cooling water withdrawn from the service water system. 2.6 Outfall 004— Equip. Cooling & Intake Screen Backwash 2.6.1 Equipment Cooling Water Cooling water for units 1,2 & 3 boiler feed pump hydraulic coupling coolers and other miscellaneous equipment is discharged through outfall 004. This water is once-through, non-contact water drawn from the service water system. In addition, water from a vehicle rinse-down area is directed to this outfall. The rinse water contains no soaps or other additives. Allen has also added a new chiller system for comfort cooling that is a once through non contact cooling water system and discharges back to the river via outfall 004. 2.6.2 Intake Screen Backwash The intake screens at Plant Allen are flushed on an "as needed" basis. Backwash usually averages 2 hours per shift. The average volume required is 0.053 MGD. The large debris floating on the river is caught on the parallel bar screens. This trash is collected and disposed of in a landfill. The silt, twigs, leaves and other light debris collected on the rotating screens are indigenous to the river and are therefore flushed back into the river with no harmful environmental consequences. 2.8 (Internal) Outfall 005 —VWNTS Effluent Discharge FGD purge water is routed to a WWTS consisting of a physical-chemical process designed to precipitate heavy metals and remove suspended solids. The clarified product water is routed to a series of bioreactors designed for selenium and nitrate removal. The bioreactor product water is discharged to the ash basin via Outfall 005 in the vicinity of the floc settling basin (as noted in Section 2.2.13 above) 3.0 STORMWATER GENERAL INFORMATION 3.1 Site Description Allen Steam Station property covers approximately 953 acres. The powerhouse, the plant yard, the coal pile, the switchyards, and associated material and equipment storage areas cover about 65 acres. These developed areas are generally flat. There are approximately 5 miles of rail access and 1.67 miles of paved roadways on-site. Coal and limestone is shipped to the site by rail lines. There is a 64 acre retired ash basin currently being converted to a double lined with leachate collection landfill for disposal of coal combustion byproducts . The active ash basin has a surface area of about 176 acres, and it receives runoff from another 112 acres. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 13 of 26 Based on information from the Soil Survey of Gaston County, North Carolina, the original site soils at Allen Steam Station were from the Gaston series. These soils are classified as sandy clay loam with red clay in the subsoils. In developed areas, the soil profile has been altered by grading and filling. The site topography is generally flat with rolling hills in outlying, undeveloped areas. 3.2 Storm Water Drainage System In developed areas, runoff flows overland to ditches and catch basins, which are connected to a buried network of corrugated metal pipes (CMP). Rainfall runoff from the coal pile and coal handling areas and portions of the plant yard goes to the yard sumps that discharge to the ash basin. Storm water runoff from other areas of the site is discharged to the Catawba River and the South Fork River. Rainfall runoff from the transformer yard area and the 115 KV switchyard is routed through oil trap tanks prior to being discharged. 3.3 Characterization of Drainage Basins A description of the drainage area, significant materials, and material control measures is presented for each drainage basin. Herbicides are spot applied where required in parking areas, switchyards, parts laydown areas, along walkways, and around various fixtures and buildings. 3.4 Storm Water Ouffalls Characteristics for 16 individual outfalls and one group of outfalls are presented. Stormwater Outfall 1 Discharge Structure: 10 inch (") diameter( ) CMP Location: North of station on railroad tracks Drainage Area: 5.4 acres Area Description This outran conveys runoff from undeveloped, wooded area upland of the railroad tracks, and from the tracks themselves. Approximately 345 feet of an unpaved road passes through the drainage area and 2000 feet of railway lines. There are no paved or roofed areas in this drainage area. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 2 Discharge Structure: 24" CMP Location: North of station on railroad tracks Drainage Area: 12.7 acres Area Description This area conveys overflow runoff from the construction laydown area, Boat Club road, and parking areas. This area also conveys flow from wooded areas upland of the railroad tracks. A permanent stormwater basin collects, retains, and Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 14 of 26 impedes most of the water from impermeable areas. There is approximately 4.6 acres of a gravel laydown area. Impermeable areas include 1000 feet of paved road (Boat Club) and approximately 3,000 square feet of roof surface from temporary trailers. Significant Materials/ Controls Construction Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large, flat, gravel laydown area north and upland of the powerhouse. The equipment and supplies generally do not contain liquids. Parking: There is approximately 3,000 square feet of gravel parking within this drainage basin. Stormwater Outfall 3 Discharge Structure: 36" Reinforced Concrete Pipe Location: North of station on railroad tracks Drainage Area: 1.6 acres Area Description This outfall conveys runoff from the railroad tracks. There are about 1500 feet of railway lines. There are no paved or roofed areas in this drainage area. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 4 Discharge Structure: 10" Cast Iron Pipe Location: North of station at Catawba River Drainage Area: 0.4 acres Area Description This small area is southeast of the limestone unloading area. There is a bermed area with trees that separates this drainage area and the limestone unloading area. None of the drainage area is paved or roofed. Significant Materials/ Controls Significant materials are not stored within this drainage basin. Stormwater Outfall 5 Discharge Structure: 18" CMP Location: North of station at Catawba River Drainage Area: 7.3 acres Area Description This outfall conveys overflow runoff from the catchment basins upland of the railroad tracks and from the tracks themselves. There are also a few temporary Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 15 of 26 construction buildings in this area. About 450 feet of a paved road passes through the drainage area, and there are about 2,580 feet of railway lines. Significant Materials/ Controls Parking: There are about 3.2 acres of gravel parking areas within this drainage basin. Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large, flat, gravel laydown area north of the powerhouse. The equipment and supplies generally do not contain liquids. Limestone/ Coal: Potential for a spill or leak from railroad activities. Stormwater Outfall 6 Discharge Structure: 10" Cast Iron Pipe Location: North of station at Catawba River Drainage Area: 0.4 acres Area Description This small area is southeast of the limestone unloading area. There is a bermed area with trees that separates this drainage area and the limestone unloading area. None of the drainage area is paved or roofed. Significant Materials/ Controls Significant materials are not stored within this drainage basin. Stormwater Outfall 7 Discharge Structure: 18" CMP Location: North of station at Catawba River Drainage Area: 1.5 acres Area Description This area collects stormwater from part of the grassy embankment of the FGD site, but not from the FGD site itself. It also collects runoff from approximately 250 feet of road and 1500 feet of railway. This outfall previously drained part of the area now known as the limestone sump drainage area, but has been capped off at that location. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 8 Discharge Structure: 24" CMP Location: North of Station at Catawba River Drainage Area: 4.1 acres Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 16 of 26 Area Description This outfall conveys runoff from the hill north of the powerhouse. This outfall also conveys runoff from a segment of railroad tracks and from the laydown area adjacent to the north warehouse. There are approximately 1,000 feet of paved roadways and 2,400 of railroad tracks in this drainage basin. Significant Materials/ Controls Parking: There is a gravel parking area at the outage trailers. This lot is used occasionally during outages. Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large flat, gravel laydown area adjacent to the north field warehouse. The equipment and supplies generally do not contain liquids. Limestone/ Coal: Potential for a spill or leak from railroad activities. Stormwater Outfall 9 Discharge Structure: 3 feet (') Concrete Ditch Location: North of Intake Structure at Catawba River Drainage Area: 0.4 acres Area Description This outfall conveys drainage from a segment of railroad tracks in front of the powerhouse and from the grassy embankment between the tracks and the intake structure. About 920 feet of railroad tracks pass through this area. There are no paved or roofed areas in this basin. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Stormwater Outfall 10 Discharge Structure: 24" CMP Location: South of Intake Structure at Catawba River Drainage Area: 0.9 acres Area Description This outfall conveys runoff from a segment of the railroad tracks in front of the powerhouse and from the grassy embankment between the tracks and the intake structure. About 1,280 feet of railroad tracks pass through this area. There is less than 50 square feet of paved or roofed areas in this basin. Drainage from the CCW clam filter pit is discharged through this outfall. Significant Materials/ Controls Significant materials are not stored within this drainage basin, but there is a potential for a spill or leak from railroad activities. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 17 of 26 Stormwater Duffel! 11/ NPDES 004 Discharge Structure: 72" CMP Location: East of Coal Pile at Catawba River Control Structure: 65,300 gallon oil trap tank Drainage Area: 15.3 acres Area Description This drainage area comprises most of the southern end of the station yard, and most of this area is developed. This outfall conveys roof drainage from a portion of the powerhouse roof, the machine shop roof, the service building roof, the warehouse roof, and some of the coal handling buildings. These roofed areas cover about 1.3 acres. Two large paved parking lots cover 3 acres. Other parking and paved areas cover about 1 acre. About 3,100 feet of rail lines pass through this drainage area, but only half of them are used regularly. Runoff from a portion of the transformer yard area and from the entire 115 kV switchyard is routed to a 65,300 gallon oil trap tank prior to being discharged to this outfall. The switchyard is covered with gravel. Other portions of the drainage area include the powerhouse yard, grassy, and undeveloped areas. About 50 percent of this drainage area is roofed or paved. NPDES discharges including miscellaneous non-contact cooling water from plant equipment, vehicle wash water, and intake screen backwash water are conveyed through this outfall. Significant Materials/ Controls Coal: Coal dust may be present around coal handling areas. Parking: There are about 3.2 acres of paved parking areas within this drainage basin. Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a flat, concrete laydown yard adjacent to the warehouse. The equipment and supplies generally do not contain liquids. Gasoline: There is a 500-gallon aboveground, carbon steel gasoline tent tank across from the warehouse. The tank is completely enclosed within a steel tent enclosure, and any leaks would be self contained. The enclosure can be drained by opening a valve, and that valve remains closed at any other time. Any fluid drained from the tent is captured and not released to Stormwater Outfall 11. The tank is filled by a 1,500 gallon tanker truck. Clean up supplies are located nearby. Oil: Stormwater runoff from the 115 kV switchyard and from a portion of the station's main transformer yard is routed to the south oil trap tank which has a capacity of 65,300 gallons before being discharged. Transformers 1 A, 1 T1, CT1, 2T1, 2A, and 3T1 contain a total of 34,533 gallons of mineral oil. The largest volume contained by a single transformer is 9,715 gallons. The oil circuit breakers in the 115 kV switchyard contain a total of 73,229 gallons of mineral oil. Each circuit breaker has three tanks, and each tank contains either 933 or 1,070 Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 18 of 26 gallons of mineral oil, depending on the model. Two transformers at the switchgear house each contain 196 gallons of mineral oil. Stormwater Duffel! 12/ NPDES 003 Discharge Structure: 36" CMP Location: Discharge Canal Control Structure: 100,000 gallon oil trap tank Drainage Area: 11.6 Area Description This drainage area includes portions of the powerhouse yard north and west of the station and part of the hill to the north of the station. This drainage basin includes a portion of the station main transformer yard and the 230 kV switchyard. Within the powerhouse yard, the drainage basin is flat and generally covered with gravel or grass. Approximately 1,400 feet of rail lines have been removed or are not in service. Less than 5 percent of this drainage area is roofed or paved. Runoff from the powerhouse yard immediately north and west of the station is routed to a 100,000 gallon oil trap tank prior to being discharged to this outfall. Runoff from the transformer yard goes to the oil trap tank. Runoff from the 230 kV switchyard is not routed to the north oil trap tank because the switchgear in the 230 kV switchyard is gas cooled and does not contain oil. NPDES discharges of miscellaneous non-contact cooling water are routed through the north oil trap tank and then discharged by this outfall. Significant Materials/ Controls Ash: Above ground ash pipelines run through this area carrying ash from the plant to the ash basins. North of the powerhouse, the ash sluice pipeline is located in a trench; spills would be contained with the trench. Oil: Stormwater runoff from a portion of the station's main transformer yard is routed to the north oil trap tank which has a capacity of 100,000 gallons before being discharged. Transformers 3T2, 3A, 4T1, 4A, 4T2, 5T1, 5T2, 5A, CT2, 6A, and a spare transformer contain a total of 73,158 gallons of mineral oil. The largest volume contained by a single transformer is 13,790 gallons. The largest volume contained by a single transformer is 9,715 gallons. The switchgear in the 230 kV switchyard does not contain oil. Stormwater Outfall Group 13 Discharge Structure: Fourteen 10" CMPs Location: Every 200 feet along the retired railroad tracks Drainage Area: 13.6 acres Area Description These outfalls are located every 200 feet along the railroad tracks in front of the coal composition products (CCP) landfill. These outfalls convey runoff from the railroad tracks and from the CCP landfill embankment. About 7,500 feet of railroad tracks pass through this drainage area. None of this drainage area is paved or roofed. Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 19 of 26 Significant Materials/ Controls Limestone/ Coal: Potential for a spill or leak from railroad activities. Stormwater Outfall 14 Discharge Structure: 21" CMP Location: Catawba River between the coal pile and CCP landfill. Drainage Area: 2.0 acres Area Description This outfall conveys surface drainage from the area between the embankment at the coal composition products (CCP) landfill and the coal pile. None of the drainage area is paved or roofed. Significant Materials/ Controls Significant materials are not stored within this drainage basin. Stormwater Outfall 15 Discharge Structure: 36" Reinforced Concrete Pipe Location: Catawba River at retired ash basin Drainage Area: 177.8 acres Area Description This is the discharge structure from the structural fills east of the landfill. None of this drainage area is paved or roofed at this time. This area includes a soil borrow area that is approximately 9.1 acres. Stormwater runoff from the soil borrow area is collected into a temporary sedimentation pond that contains a sedimentation basin skimmer. Stormwater Outfall 15 also includes the new coal composition products (CCP) landfill. Contact water from the CCP landfill is not located in this drainage area because it is pumped to the ash basin (see section 2.4 for more information). Only noncontact water on the CCP landfill will fall into this drainage area. Two sedimentation basin skimmers are located in the drainage ditch, and the discharge tower for the outfall is surrounded by riprap and washed stones. Significant Materials/ Controls Ash: An old ash structural fill and noncontact water from the new ash landfill are located in this drainage area. Stormwater Outfall 16 Discharge Structure: 36" CMP Location: Discharge Canal Drainage Area: 37.2 acres Area Description This discharge area drains the approximately 1,678 feet of paved road coming into the Allen site. Ash Boulevard will be paved in the future. This modification will allow a paved route from the dry ash handling facility to the CCP landfill in order for trucks to carry dry ash to the CCP landfill from the FGD site. Drains by Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 20 of 26 the intersection of the main road and the road going to the dry ash handling site are surrounded with washed stones and silt fences. Significant Materials/ Controls Ash: Above ground ash sluice lines pass through this drainage area. Trucks carrying ash will pass through this drainage area. Stormwater Outfall Group 17 Discharge Structure: Numerous, 12" CMP Location: Every 170 feet along both sides of the discharge canal Drainage Area: 50 acres Area Description This discharge area drains runoff from the access roads on either side of the discharge canal. None of this area is paved or roofed. Also there is a perennial stream north of the FGD site that drains into the discharge canal through a 36" pipe. A temporary stormwater basin currently receives runoff from most of the permeable surface of the FGD site. When construction ends the temporary stormwater basin will be removed, and most of the permeable surface at the site will once again drain to the stream. Significant Materials/ Controls Significant materials are not stored within this drainage basin. 3.4.1 Sump System At Allen Steam Station, there are six main sumps that use pumps to discharge into the ash basin. They are referred to as the following: landfill (leachate) sump, FGD stormwater sump, powerhouse yard sump, yard drainage sump, limestone drainage area sump, and the coal yard sump. The landfill sump is located south of the coal pile in the CCP landfill. The FGD stomiwater sump is located north of the plant and west of the FGD absorber building. The powerhouse yard sump is located east of the powerhouse, at the north end. The powerhouse yard sump discharges to the yard drainage sump. The yard drainage sump is located east of the coal pile and adjacent to the coal yard sump. FGD Stormwater Sump Drainage Area Location: North of powerhouse Drainage Area: 25.6 acres Area Description This drainage area includes the dry ash handling facility, gypsum pile, WWTS area (not process water), stack, absorbers, switchgear building, dewatering building, reagent prep building, and the control room. Most of the FGD site drainage area is routed to a permanent stormwater basin (that has a 30 foot spillway) and pumped to the ash basin through the FGD stormwater sump. Most of the dry ash handling area is surrounded with a concrete curb. Stormwater Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 21 of 26 from this area is routed to the permanent stormwater detention basin. There is an oil water separator (OWS) tank buried into the ground outside of the dewatering building that receives runoff from two transformers (T1 and T2) in the FGD area. The OWS separates the oil from the water before it is enters the permanent stormwater basin Significant Materials/ Controls Gypsum: Gypsum is stockpiled here. A contractor hauls off the gypsum and uses it to make wallboard. A paved area outlines the gypsum pile, and a concrete stormwater trench is located on the farthest edge of the gypsum area and drains to the permanent stormwater basin, and then to the FGD sump. Ash: Ash is transported via pressureized lines to a collection silo. The ash is then gravity fed into trucks which transport the material in the CCP landfill. The floor drains and stormwater runoff are pumped to the permanent stormwater basin. Oil: Runoff from two new auxiliary transformers contains 2,908 gallons of mineral oil a piece. Stormwater runoff is routed to an oil trap tank before entering into the permanent stormwater basin. Runoff from two other new transformers (T1 from the 230 kV and T2 from the 115 kV) is routed to the permanent stormwater basin. Transformers T1 and T2 contain 5,850 and 8,670 gallons of mineral oil, respectfully. All transformers are surrounded by gravel in a concrete containment area and the valves to drain the containment area remain closed most of the time. Also, there are diesel tanks located in the diesel fire pump enclosure. Chemicals: Organic acid is unloaded and stored in this drainage area. There is a 21,500 gallon tank of organic acid located in a secondary containment area inside the reagent prep building. There are various tanks of varying concentration of limestone slurry. 2,255 pounds (approximately 260 gallons) of dibasic acid will be located inside the reagent prep building in a secondary containment area. Limestone Sump Drainage Area Location: Northeast of powerhouse Drainage Area: 6.0 acres Area Description This area is an extremely flat area where limestone is unloaded, piled, and conveyed to the FGD site. Approximately 10,000 square feet is roofed. 100 feet of railroad tracks pass through this drainage area. A new bermed area with trees outlines the northeastern edge of the area. A 350 foot permanent stormwater collection trench (with a 10 foot spillway) is located at the eastern edge of the area and conveys most of the stormwater runoff from the site into the ash basin. Significant Materials/ Controls Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 22 of 26 Limestone: Limestone is stockpiled here. A limestone unloading building and limestone convey belts and hoppers operate in this area. Powerhouse Yard Sump Drainage Area Location: East of the powerhouse, at the north end Drainage Area: 3.6 acres Area Description Industrial wastewater from unit five flows into the powerhouse yard sump. Stormwater runoff from a portion of the powerhouse roof, the plant yard, the fuel oil unloading area, and the bulk fuel oil tank area drains to the powerhouse yard sump. The portion of the powerhouse roof that drains to the powerhouse sump is about 2.2 acres. About 85 percent of this drainage basin is paved or roofed. Overflow from the powerhouse yard sump would spill to the ground and then flow overland and could eventually reach the Catawba River. Overflow from the powerhouse yard sump is permitted as NPDES Outfall 2(b). Overflow from the powerhouse yard sump is not a normal occurrence. Significant Materials/ Controls Oil: The fuel oil bulk storage tank is an aboveground, galvanized steel cylinder surrounded by a concrete containment sufficient in height to contain a total spill plus rainfall. The total tank capacity is 100,000 gallons. There is a catch basin inside the berm. This outlet has a valve which is normally closed. The stormwater is inspected for the presence of oil, and if it is clean, it can be drained if there is significant standing water. In the fuel oil unloading area, fuel is transferred from an 8,000 gallon tanker truck to the bulk storage tank via pipelines. DOT unloading procedures are followed. The fuel oil unloading area is paved and surrounded by a one foot concrete curb and ramps to contain any spills. There is a small sump to drain rainfall; the sump has a valve which is normally closed. Spill clean-up supplies are located nearby. Piping from the unloading area to the bulk fuel oil tank is aboveground or enclosed in a concrete trench. The 48 transformers for the Units 1-5 precipitators contain a total of 7,560 gallons of mineral oil. About 60% of the precipitator transformers are located within this drainage area. The maximum oil content of any single component is 205 gallons. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to the powerhouse yard sump. This wastewater may include oil, chemical, and hazardous waste spills. Yard Sump Drainage Area Location: East of the coal pile Drainage Area: 5.2 acres Area Description The powerhouse yard sump discharges to the yard drainage sump. The yard drainage sump discharges to the ash basin. In addition to the discharge from the powerhouse yard sump, the yard drainage sump receives industrial wastewater Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 23 of 26 from some of the powerhouse sumps. Industrial wastewater includes effluent from the turbine room sumps and boiler room sumps. Stormwater runoff from a portion of the plant yard and parts of coal handling drains to the yard drainage sump. The total roofed area in this basin is about 1.5 acres including the warehouse roof, the maintenance garage roof, and a portion of the powerhouse roof. About half of this drainage basin is paved or roofed. Approximately 1,300 feet of railroad tracks pass through this drainage area. Overflow from the yard drainage sump would discharge to the coal yard sump. Overflow from the sump is not a normal occurrence. Significant Materials/ Controls (See description for powerhouse yard sump for additional information) Kerosene: There is a 200-gallon aboveground, carbon steel kerosene tank above the ash sluice trench. Oil: Used oil is stored in a 4,500 gallon steel tank. The tank is surrounded by a steel containment dike about five feet tall, and the piping is surrounded by a 6- inch concrete curb. Rainfall that accumulates inside the dike can be drained by opening a valve that drains to the ash trench which leads to the yard drainage sump. When the used oil tank is full, the product is removed from site by tanker truck. Small quantities of used oil are initially poured into 55-gallons drums. The drums are stored in the used oil staging area under cover, adjacent to the warehouse, for temporary storage. When the drums are full, they are emptied into the used oil tank. Empty oil drums are stored outside, adjacent to the boat shed. Approximately 250 gallons of oil are stored inside the maintenance garage where floor drains flow to the yard drainage sump. The 48 transformers for the Units 1-5 precipitators contain a total of 7,560 gallons of mineral oil. About 40% of the precipitator transformers are located within this drainage area. The maximum oil content of any single component is 205 gallons. Two transformers associated with the wastewater and coal yard sumps each contain 270 gallons of mineral oil. Fuel oil dispensers for the locomotives and bulldozers are located adjacent to the maintenance garage. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to the yard drainage sump. This wastewater may include oil, chemical, and hazardous waste spills. Coal: Coal dust is present along the railroad tracks and coal handling areas. Ash: Ash pipelines run through this drainage area. Chemicals: There is a 5,000 gallon tank of sulfuric acid located adjacent to the warehouse. The tank is surrounded by a concrete dike with an outlet to the ash line trench which leads to the yard drainage sump. Drums of various chemicals are stored inside a covered, locked shed adjacent to the warehouse. Hazardous Waste / Satellite Accumulation Areas: There is a satellite accumulation area for waste paint, chemicals, solvents, cleaners, etc. adjacent to Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 24 of 26 the paint warehouse. Hazardous wastes are stored in a covered area adjacent to the maintenance garage. Laydown Area: There is a large laydown area adjacent to the warehouse. The area is paved and fenced. Spare equipment and parts are stored in the laydown area. Coal Yard Sump Drainage Area Location: East of the coal pile Drainage Area: 24.1 acres Area Description The coal yard sump receives stormwater runoff from the coal pile and from parts of coal handling area. Less than one percent of this drainage basin is paved or roofed. Approximately 800 feet of railroad tracks pass through this drainage area. Overflow from the coal yard sump would be conveyed to the Catawba River. Overflow from the coal yard sump is permitted as NPDES Outfall 002a. Overflow from the sump is not a normal occurrence. Significant Materials/ Controls Oil: Two transformers associated with the wastewater and coal yard sumps each contain 270 gallons of mineral oil. A fuel oil dispenser for the bulldozers is located in the northwest corner of the smaller coal pile. Coal: Runoff from the coal pile and some coal handling areas is routed to the coal yard sump. Wastewater: Effluent from the septic system goes to coal yard sump. CCP Landfill Sump Drainage Area Location: South of the coal pile Drainage Area: 64.0 acres Area Description The coal combustion products (CCP) landfill is double lined with a leak detection system and leachate collection system. The contact water from the leachate collection system will be pumped from the CCP landfill into the ash basin. There is a 30 foot dike around the landfill. A stormwater drainage trench runs along the south side of the landfill currently and is part of outfall 15. In the future, there will be drainage ditches east and west of the landfill that will collect stormwater runoff and pipe it to the ash basin. Significant Materials/ Controls Ash: Leachate from the CCP Landfill Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 25 of 26 3.5 Similarity of Storm Water Outfalls at Allen Steam Station Monitoring all of the storm water outfalls at Allen Steam Station should not be necessary since many of the outfalls convey storm water from areas of substantially identical activities and materials. Storm water outfalls 8 and 15 are representative for the entire site. 4.0 Hazardous and Toxic Substances 4.1 Hazardous and Toxic Substances Table 2c- 3 At Plant Allen, the potential for toxic and hazardous substances being discharged is very low. In reference to Item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are as follows: Acetaldehyde, Asbestos, Butyl Acetate, Cyclohexane, Diuron, Epichlorohydrin, Formaldehyde, Monoethyl Amine, Propylene Oxide, Pyrethrins, Vinyl Acetate, and Xylene. Other- During the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. It is not anticipated that these products will impact the ash basin's capacity to comply with its toxicity limits, since their concentrations are extremely low. 4.2 40 CFR 117 and CERCLA Hazardous Substances The following table identifies hazardous substances located on-site that may be released to the ash basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). These values below represent the maximum quantities on-site that could be released at one time and sent to the ash basin. They do not reflect quantities that are discharged through typical use. Allen Steam Station Hazardous Substances in Excess of RQ Table 4.2 SUBSTANCE QUANTITY SOURCE Benzene 83 lbs Gasoline Tank Ethylbenzene 2,737 lbs Diesel Fuel Tanks Hydrazine 499 lbs Warehouse Naphthalene 41,700 lbs Fuel Oil Tanks Sodium Hydroxide 1,181 lbs Ash basin/Warehouse/#3 Fan Room Sodium Nitrite 800 lbs Warehouse/Powerhouse Sulfuric acid 44,277 lbs Powerhouse Xylene (Mixed Isomers) 419 lbs Gas Tank Allen Steam Station,Gaston County NPDES Permit No.NC0004979 Page 26 of 26 5.0 Allen Steam Station 316 Determination 5.1 Allen Steam Station 316(a) determination Duke Energy's 316(a) demonstration (March 1976) concluded that the "heated discharge from Plant Allen is such that the protection and propagation of a balanced indigenous aquatic community in and on Lake Wylie is assured." Duke's operation experience during the past five years under the thermal limitations imposed in NPDES Permit No. NC0004979 substantiates the above conclusion and further supports Duke's belief that the operating characteristics of the station have a minimal effect of the aquatic environment of Lake Wylie. Surveys of the aquatic community in Lake Wylie demonstrate that a Balanced Indigenous Population exists in Lake Wylie. Accordingly, Duke requests a 316(a) variance and further requests that the thermal limitations imposed in the permit be continued. 5.2 Allen Steam Station 316(b) Determination In conjunction with the rulemaking process for the new Phase II 316(b) rule pertaining to fish impingement and entrainment, historical data and permitting records were reviewed. Initial 316(a) and 316(b) studies associated with enactment of the Clean Water Act concluded that the location, construction capacity, and design of the cooling water intake of Allen and other Duke Power steam stations were not detrimental to the aquatic ecosystem and minimize adverse environmental impacts. Both North Carolina and EPA regulators concurred in 1976 that 316(b) fish impingement and entrainment studies were no longer needed at that time. Although the new Phase II 316(b) rule for existing facilities is currently being litigated, plans for information collection (PICs) are being developed to conduct a Comprehensive Demonstration Study (CDS) to determine required measures to be implemented per approval of NCDENR i • Tir,vA Ai, /141( 0. • NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quali 7 -7 Beverly Eaves Perdue Coleen H.Sullins DO,, Freeman Governor Director Secretary J U L 7 2009 July 6, 2009 Mr. Steven Immel, General Manager II Duke Energy Carolinas, LLC- Allen Steam Station f ram. 253 Plant Allen Road. Belmont, North Carolina 28012 Subject: NPDES Permit major modification Permit No. NC0004979 Allen Steam Station Gaston County Dear Mr. Immel: Division personnel have reviewed and approved your request for major modification. Accordingly, we are forwarding the attached NPDES discharge permit. This permit is modified pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 17, 2007 (or as subsequently amended.) This permit modification addresses the request for a major modification regarding the elimination of the selenium limit at Outfall 002. The permit authorizes Duke Energy Carolinas, LLC to discharge treated industrial wastewater from the Allen Steam Station Wastewater Treatment Plant to the Catawba River and the South Fork Catawba River, class WS-IV and B waters in the Catawba River Basin. The final permit includes discharge limitations/or monitoring for flow, oil and grease, total suspended solids, arsenic, chloride, copper, iron, mercury, nickel, selenium, zinc, total nitrogen, total phosphorus, pH, and chronic toxicity. The following modifications included in the May 6thdraft permit remain in the final permit: • The weekly average effluent limit for selenium at Outfall 002 has been deleted. Data analysis indicated that there was no reasonable potential for this parameter to exceed the water quality standard in the receiving stream. There will be monthly monitoring of total selenium at both Outfall 002 and internal outfall 005. 1617 Mail Service Center,Raleigh,North Carolina 27699.1617 Location:512 N.Salisbury St.Raleigh,North Carolina 27604 One Phone:919-807-6300\FAX:919-807-6492\Customer Service:1-877-623-6748 NorthCarolina Internet:www.ncwaterquality.org a'���1'/��"//� - An Equal opportunity\Affirmative Action Employer Naturally Letter to Mr. Immel Page 2 • Due to the new wastestream from the Flue Gas Desulfurization WWTP that will be discharged into the ash settling basin above Outfall 002, quarterly monitoring for the following parameters will now be required at Outfall 002: total arsenic, total cadmium, total chromium, chloride, total mercury, total nickel, total silver, total zinc, and total beryllium. Quarterly monitoring for these parameters is the minimum requirement for a major industrial discharger to North Carolina streams. i?ik 9\ ' 2 aPlease note that there have been minor language changes an the addition of a new paragraph regarding data submittal in un 1 lit I N. - _ _ . _ . _ - - -- - - - - . -uiuuluUTi w If any parts, measurement frequencies or sampling requirements contained in this permit modification are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina 27699- 6714. Unless such a demand is made, this permit shall be final and binding. Please take notice that this permit is not transferable. The Division may require modification revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, Coastal Area Management Act, or any other Federal or Local governmental permits may be required. If you have any questions or need additional information, please contact Ms. Jacquelyn Nowell at telephone number (919) 807-6386 or email jackie.nowell@ncdenr.gov. Sincerely, F tcoieen H. Sullins cc: EPA Re•ion IV (! CO'' 1 Pr(� ) VI't4 A r 4,1d't; niPi✓ *. PII,aILj 44,'I ' ell© -f 4-') .'Itr DEH/ Public Water Supply Section/Mooresville Re• • -'i 11 ice Aquatic Toxicology Unit NPDES File/NC0004979 • STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1,other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission,and the Federal Water Pollution Control Act,as amended, Duke Energy Corporation is hereby authorized to discharge wastewater from a facility located at the Plant Allen Steam Station 253 Plant Allen Road (NCSR 2525) Belmont Gaston County to receiving waters designated as the Catawba and South Fork Catawba Rivers in the Catawba River Basin in accordance with effluent limitations,monitoring requirements, and other conditions set forth in Parts I, II,III and IV hereof. This permit shall become effective August 1,2009. This permit and authorization to discharge shall expire at midnight on May 31, 2010. Signed this day July 6, 2009. f/1 oleen H.Sullins, Director ivision of Water Quality By Authority of the Environmental Management Commission • Permit NC0004979 SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility,whether for operation or discharge are hereby revoked.As of this permit issuance,any previously issued permit bearing this number is no longer effective.Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions,requirements, terms,and provisions included herein. Duke Energy Corporation is hereby authorized to: 1. Continue to discharge: • Once through cooling water(outfall 001) • Operate a septic tank and ash pond with pH adjustment and discharge domestic wastewater,stormwater runoff,ash sluice,water treatment system wastewaters,FGD system blowdown,landfill leachate,and miscellaneous cleaning and maintenance wash waters (002). • Coal yard sump overflow (002A) and power house sump overflow (002B) • Miscellaneous equipment non-contact cooling and sealing water(003) • Miscellaneous non-contact cooling water,vehicle washwater,and intake screen backwash(004) From a facility located at the Plant Allen Steam Station on Plant Allen Road (NCSR 2525), south of Belmont in Gaston County,and 2. Without adding detergents or chemicals of any kind, discharge Asiatic clam/debris filter backwash(of the intake filter screen) (see Part A.7);and 3. Continue to operate a Flue Gas Desulfurization(FGD)wet scrubber wastewater treatment system discharging to the ash settling basin through internal outfall 005;and 4. Discharge from said treatment works at the location specified on the attached map into the Catawba River (outfalls 002,002A,002B and 004) and the South Fork Catawba River(outfalls 001 and 003)which are classified Class WS-V B waters,respectively,in the Catawba River Basin. .2 �L \L<<_-, l . / it ; Asiatic Clam/Debris r 1. /. f • , �* I \� s ,,,,,,,,,,,..4, '� 7 GJ G .' �5 i ; _�-;�'{�%' Filter Backwash ��. ` t L� ',_ 1. x - • t �' > . ��. (7 ��` 001ji ) , ,, , ,i, ,may. 4- �rl��) `., ( \_, l 'ice ( 4y e l I { 4 f'� i } � ` , s v I / ! o!1 ID'o /{44\,tl, r4 .,\C .cam,, / i('�•1 ( j�// r y \� - '� �.-�� ,W -v ,ircs . ;,(.2.‘-'..,.., , ,----- ,:n\:„/juileir c c V, ...- )) }.c.2,4L-,1 (s----C\-, .•''v• fk, ,, .... c)_,i,, i ,,,. ..,-„N, ) , , , ,;. ,.. i +j)' I N •.- (N____^ , -.7 -.1;" Nir 5------C- . -s) IN '-- • Q I \ or N‘k•N 1% '�':`} �r . , l f ,,/ ---.. el e, q� ' >Ea e f1 �c so.i Y: / iA ` / �� II:: i• / vt �` _ t 1, 1� *. lJ / r r 111111 •/ �j/ � i� it/`\CC 003 ( 9 ',i �.ro -- \rid ,�)) , l _ i " , \- -.0 /+\i .. e \ J4, ,,` (_-:A:.. \ ?\ o t,-- '0° 002A k. , ` li �. ,,,,--... \\s„.\±;:.....--_ .4,,,`\i \II:'i Allf.- ,}...;--y'l',' I•ii ..":„:„.04,1°. A :.'',,x 5 pi it, _ f,f�.,r�i N_,l�\ �• ,,y t� .1 \ ♦i,r,.:: :'yam/-•-� '3„...w.R �� t2 ile9 ))) /'fil ,,-•. :fir' A''', 4 ::::':01 1-1 .:: 1 / -\l R !/\/i,,, \ t: ; it / tom , c1. C� l„ , _ AV 1 \ r _ r e \ ''• • '''''''\ ty if I 777777000000������J) / ( (/_ l // / :c:5,„•-)„," � 11:0:‘ /�/" f.'.\) 4d L fI-T"-,-7ir �1Lific N i` --/ ICI J \L, 1/ 1 j _, 46 , 4' ,[ . rt_''',."----,'• _ \ ' )\ " `\ • /*', • o."'11 I J ,),,,_ /- -''',, ..-. i f ^ , J..:� : J '.` �-c��/ � t' ' Lr's Duke Energy Corporation Map not to scale Allen Steam Station State Grid/Ouad: Gl4NEIBelmont Permitted Flow: Not limited Receiving Streams: Catawba and South Fork Catawba Rivers Stream Class: WS-V&B Drainage Basin: Catawba River Basin Sub-Basin: 03-08-34 Facility Latitude(001): 35°11'23" N Longitude(001): 81°00'45" W x Latitude(002): 35°10'30" N Longitude(002): 81°00'23" w Location Latitude(002A): 35°11'34" N Longitude(002A): 81°00'22" W Latitude(1102B): 35°11'36" N LongitudeJ002B): 81°00'30" W _ Latitude(110-1): 35°11'35" N Longitude(004): 81°00'22" W North NPDES Permit No. NC0004979 Latitude(A.Clam): 35°11'36" N Longitude(A.Clam):81°00'30" W 1 . 0 rth Gaston County • Permit NC0004979 A. (1.) EFFLUENT LIMITATIONS.AND MONITORING REQUIREMENTS (Outfall 001) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 001-Condenser Cooling Water(CCW). Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Daily Pump Logs Effluent Temperature 38.9°C Grab or (June 1-September 30)1 (102°F) DailyInstantaneous Effluent Temperature 35°C Daily Grab or Effluent (October 1 -May 31)1 (95°F) Instantaneous Notes: 1. The Regional Administrator has determined pursuant to Section 316(a)of the Act that the thermal component of the discharge assures the protection and propagation of a balanced,indigenous population of shellfish, fish,and wildlife in and on the receiving body of water. Chlorination of the once through condenser cooling water,discharged through outfall 001,is not allowed under this permit. Should Duke Power wish to chlorinate its condenser cooling water,a permit modification must be requested and received prior to commencing chlorination. 3 . Permit NC0004979 A. (2.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002) - During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 002—ash pond effluent. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Weekly Daily Measurement Sample Type Sample Location Average Average Maximum Frequency Flow Weekly Instantaneous Influent or or Estimate Effluent Oil and Grease 15.0 mg/1 20.0 mg/1 Quarterly Grab Effluent Total Suspended Solids 30.0 mg/1 100.0 mg/1 Monthly Grab Effluent Total Copper2 1.0 mg/1 2/Month Grab Effluent Total Iron 1.58 mg/1 Monthly Grab Effluent Total Selenium2 Monthly Grab Effluent Total Arsenic2 Quarterly Grab Effluent Total Cadmium2 Quarterly Grab Effluent Total Chromium2 Quarterly Grab Effluent Chloride Quarterly Grab Effluent Total Mercury2 Quarterly Grab Effluent Total Nickell Quarterly Grab Effluent Total Silver2 Quarterly Grab Effluent Total Zinc2 Quarterly Grab Effluent Total Beryllium Quarterly Grab Effluent Total Nitrogen (NO2+NO3+TKN) Semi-annually Grab Effluent Chronic Toxicityl Quarterly Grab Effluent pH3 Monthly Grab Effluent Notes: 1. Whole Effluent Toxicity shall be monitored by chronic toxicity(Ceriodaphnia)P/F at 24%. Tests shall be conducted in January,April,July and October(see Part A.(9.)for details) 2. Total metals are defined by 40 CFR 136. Any method specified by 40 CFR 136 is considered acceptable for analysis. 3. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. There shall be no discharge of floating solids or foam visible in other than trace amounts. 4 Permit NC0004979 • A. (3.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002A) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 002A—Coal Yard Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum_, Frequency Flow Episodic Estimate Effluents pH Episodic Grab Effluent Oil and Grease2 15.0 mg/1 20.0 mg/1. Episodic Grab Effluent Total Suspended Solids2 30.0 mg/1 100.0 mg/1 Episodic Grab Effluent Fecal Coliform Episodic Grab Effluent Total Iron3 1.0 mg/1 Episodic Grab Effluent Notes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. Sampling for iron is required only when TSS is reported as greater than 100 mg/L. There shall be no discharge of floating solids or foam visible in other than trace amounts All flows shall be reported on monthly DMRs. Should no flow occur during a given month,the words"no flow"should be clearly written on the front of the DMR. Episodic sampling is required per occurrance when sump overflows occur for longer than one hour. All samples shall be of a representative discharge. 5 Permit NC0004979 A. (4.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002B) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 002B-Power House Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Episodic Estimate Effluents pH Episodic Grab Effluent Oil and Grease2 15.0 mg/1 20.0 mg/1 Episodic Grab Effluent Total Suspended Solids2 30.0 mg/1 100.0 mg/1 Episodic Grab Effluent Total Copper3 1.0 mg/1 Episodic Grab Effluent Total Iron3 1.0mg/1 Episodic Grab Effluent Notes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. The limits for total copper and total iron only apply during a chemical metals cleaning. There shall be no discharge of floating solids or visible foam in other than trace amounts All flows shall be reported on monthly DMRs. Should no flow occur during a given month,the words"no flow"should be clearly written on the front of the DMR. Episodic sampling is required per occurrence when sump overflows occur for longer than one hour. All samples shall be of a representative discharge. 6 • Permit NC0004979 A. (5.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 003) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 003—miscellaneous equipment non-contact water and sealing water. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Weekly Estimate Effluent Chlorination of the once through cooling water,discharged through outfall 003,is not allowed under this permit. Should Duke Power wish to chlorinate its once through cooling water,a permit modification must be requested and received prior to commencing chlorination. A. (6.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 004) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 004-miscellaneous non-contact cooling water,vehicle washwater,and intake screen backwash. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum m Frequency Flow Weekly Estimate Effluent Oil and Grease 15.0 mg/1 20.0 mg/1 Quarterly Grab Effluent Chlorination of the once through cooling water,discharged through outfall 004,is not allowed under this permit. Should Duke Power wish to chlorinate its condenser cooling water,a permit modification must be requested and received prior to commencing chlorination. Permit NC0004979 A. (7.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Internal Outfall 005) During the period beginning on the effective date of this permit and lasting until permit expiration,the Permittee is authorized to discharge from internal outfall 005-treated FGD wet scrubber wastewater to ash settling basin. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Sample Average Maximum Frequency Type Locations Pump logs or Flow Monitor&Report Monthly similar Effluent readings Total Suspended Solids Monitor&Report Weekly Grab Effluent Carbonaceous Oxygen Demand Monitor&Report Weekly Grab Effluent (COD) Total Arsenic Monitor&Report Weekly Grab Effluent Total Cadmium Monitor&Report Weekly Grab Effluent Total Chromium Monitor&Report Weekly Grab Effluent Chloride Monitor&Report Weekly Grab Effluent Total Mercury Monitor&Report Weekly Grab Effluent Total Nickel Monitor&Report Weekly Grab Effluent Total Selenium Monitor&Report Monthly Grab Effluent Total Silver Monitor&Report Weekly Grab Effluent Total Zinc Monitor&Report Weekly Grab Effluent Total Beryllium Monitor&Report Weekly Grab Effluent Notes: 1. "Effluent"shall be defined as the discharge from the FGD wastewater treatment system prior to discharge to the ash settling basin. All flows shall be reported on monthly DMRs. Should no flow occur during a given month,the words"no flow"shall be clearly written on the front of the DMR. All samples shall be of a representative discharge. DMRs for this outfall shall be submitted only after discharge commences from the FGD system. Sampling is only required when this outfall is discharging. A. (8.) SPECIAL CONDITION FOR THE DISCHARGE OF ASIATIC CLAM/DEBRIS FILTER BACKWASH The permittee may backwash the intake filter for Unit 5 condenser cooling water on an as-needed basis. It is understood that this wash water will contain materials indigenous to the Catawba River such as Asiatic clams and light debris. As these are naturally occurring in the river environment,they may be discharged with no adverse affects to the receiving stream. The Permittee may not add any detergent,chemicals or other non- indigenous material to the wash water without explicit permission of the Division of Water Quality. 8 Permit NC0004979 A. (9.) CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 24%. The permit holder shall perform at a minimum,quarterhi monitoring using test procedures outlined in the"North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure,"Revised February 1998,or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised-February 1998)or subsequent versions.The tests will be performed during the months of January,April,July and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit,then multiple-concentration testing shall be performed at a minimum,in each of the two following months as described in"North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure"(Revised-February 1998)or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival.The definition of"detectable impairment,"collection methods,exposure regimes,and further statistical methods are specified in the"North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure"(Revised-February 1998)or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed. If reporting pass/fail results using the parameter code TGP3B, DWQ Form AT-1 (original) is sent to the below address. If reporting Chronic Value results using the parameter code THP3B, DWQ Form AT-3 (original)is to be sent to the following address: Attention: North Carolina Division of Water Quality Environmental Sciences Section 1621 Mail Service Center Raleigh,North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Branch no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete,accurate,indude all supporting chemical/physical measurements and all concentration/response data,and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required,the permittee will complete the information located at the top of the aquatic toxicity(AT)test form indicating the facility name,permit number,pipe number,county,and the month/year of the report with the notation of"No Flow"in the comment area of the form.The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required,monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream,this permit may be re-opened and modified to include alternate monitoring requirements or limits. If the Permittee monitors any pollutant more frequently n required by this permit,the results of such monitoring shall be included in the calculation&repo hg-of the data submitted on the DMR&all AT Forms submitted. NOTE: Failure to achieve test conditions as specified in the cited document,such as minimum control organism survival,minimum control organism reproduction,and appropriate environmental controls,shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. 9 • • Permit NC000497.9 A. (10.) BIOCIDE CONDITION The permittee shall not use any biocides except those approved in conjunction with the permit application. The permittee shall notify the Director in writing not later than ninety(90)days prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life other than those previously reported to the Division of Water Quality. Such notification shall include completion of Biocide Worksheet Form 101 and a map locating the discharge point and receiving stream. Completion of Biocide Worksheet Form 101 is not necessary for those outfalls containing toxicity testing. Division approval is not necessary for the introduction of a new biocide into an outfall currently being tested for toxicity. A. (11.) SPECIAL CONDITIONS The following special conditions are applicable to all outfalls regulated by NC0004979: • There shall be no discharge of polychlorinated biphenyl compounds. • It has been determined from information submitted that the plans and procedures in place at Allen Steam Station are equivalent to that of a BMP. • The permittee shall report the presence of cenospheres observed in any samples. • The applicant is permitted to discharge chemical metal cleaning wastes to the ash basin under the conditions outlined in the 1976 Riverbend Ash Basin Equivalency Demonstration and the 1994 Allen Steam Station permit application • The permittee shall check the diked areas for leaks by a visual inspection and shall report any leakage detected • If the permittee,after monitoring for at least six months,determines that he/she is consistently meeting the effluent limits contained herein,the permittee may request of the Director that the monitoring requirement be reduced to a lesser frequency. • Nothing contained in this permit shall be construed as a waiver by the permittee or any right to a hearing it may have pursuant to State or Federal laws or regulations. • Low volume waste is defined as follows (as per 40 CFR 423.11(b): "Low volume wastes sources include,but are not limited to:wastewaters from wet scrubber air pollution control systems,ion exchange water treatment system,water treatment evaporator blowdown,laboratory and sampling streams,boiler blowdown,floor drains,cooling tower basin cleaning wastes,and recirculating house service water systems. Sanitary and air conditioning wastes are not included." A. (12.) SECTION 316 (B) OF CWA The permittee shall comply with the Cooling Water Intake Structure Rule per 40 CFR 125.95. 10 { NPDES Permit Standard Conditions Page 1of16 • PART II STANDARD CONDITIONS FOR NPDES PERMITS Section A. Definitions 2/Month Samples are collected twice per month with at least ten calendar days between sampling events. 3/Week Samples are collected three times per week on three separate calendar days. Act or"the Act" The Federal Water Pollution Control Act,also known as the Clean Water Act,as amended,33 USC 1251,et. seq. Annual Average The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar year. In the case of fecal coliform,the geometric mean of such discharges. Arithmetic Mean The summation of the individual values divided by the number of individual values. Bypass The known diversion of waste streams from any portion of a treatment facility including the collection system,which is not a designed or established or operating mode for the facility. Calendar Day The period from midnight of one day until midnight of the next day. However, for purposes of this permit, any consecutive 24-hour period that reasonably represents the calendar day may be used for sampling. Calendar Quarter One of the following distinct periods: January through March, April through June,July through September, and October through December. Composite Sample A sample collected over a 24-hour period by continuous sampling or combining grab samples of at least 100 ml in such a manner as to result in a total sample representative of the wastewater discharge during the sample period. The Director may designate the most appropriate method (specific number and size of aliquots necessary, the time interval between grab samples, etc.) on a case-by-case basis. Samples may be collected manually or automatically. Composite samples may be obtained by the following methods: (1) Continuous: a single,continuous sample collected over a 24-hour period proportional to the rate of flow. (2) Constant time/variable volume: a series of grab samples collected at equal time intervals over a 24 hour period of discharge and combined proportional to the rate of flow measured at the time of individual sample collection,or (3) Variable time/constant volume: a series of grab samples of equal volume collected over a 24 hour period with the time intervals between samples determined by a preset number of gallons passing the sampling point. Flow measurement between sample intervals shall be determined by use of a flow recorder and totalizer, and the preset gallon interval between sample collection fixed at no greater than 1/24 of the expected total daily flow at the treatment system,or (4) Constant time/constant volume: a series of grab samples of equal volume collected over a 24-hour period at a constant time interval. Use of this method requires prior approval by the Director. This method may only be used in situations where effluent flow rates vary less than 15 percent. The following restrictions also apply: > Influent and effluent grab samples shall be of equal size and of no less than 100 milliliters Version 10/10/2007 • NPDES Permit Standard Conditions I . Page 2of16 > Influent samples shall not be collected more than once per hour. ➢ Permittees with wastewater treatment systems whose detention time < 24 hours shall collect effluent grab samples at intervals of no greater than 20 minutes apart during any 24-hour period. ➢ Permittees with wastewater treatment systems whose detention time exceeds 24 hours shall collect effluent grab samples at least every X hours [X = days detention time] over a 24-hour period. Effluent samples shall be collected at least every six hours; there must be a minimum of four samples during a 24- hour sampling period. Continuous flow measurement Flow monitoring that occurs without interruption throughout the operating hours of the facility. Flow shall be monitored continually except for the infrequent times when there may be no flow or for infrequent maintenance activities on the flow device. Daily Discharge The discharge of a pollutant measured during a calendar day or any 24-hour period that reasonably represents the calendar day for purposes of sampling. For pollutants measured in units of mass,the "daily discharge"is calculated as the total mass of the pollutant discharged over the day. The "daily discharge" concentration comprises the mean concentration for a 24-hour sampling period as either a composite sample concentration or the arithmetic mean of all grab samples collected during that period. (40 CFR 122.2) Daily Maximum The highest "daily discharge" for conventional and other non-toxicant parameters. NOTE: Permittees may not submit a "daily average" calculation [for determining compliance with permit limits] for toxicants. See the relevant Federal effluent guideline[s] for the appropriate calculation interval. Daily Sampling Parameters requiring daily sampling shall be sampled 5 out of every 7 days per week unless otherwise specified in the permit. The Division expects that sampling shall be conducted on weekdays except where holidays or other disruptions of normal operations prevent weekday sampling. If sampling is required for all seven days of the week for any permit parameter(s),that requirement will be so noted on the Effluent Limitations and Monitoring Page(s). DWQ or"the Division" The Division of Water Quality,Department of Environment and Natural Resources. EMC The North Carolina Environmental Management Commission. Facility Closure The cessation of wastewater treatment at a permitted facility,or the cessation of all activities that require coverage under the NPDES. Completion of facility closure will allow this permit to be rescinded. Geometric Mean The Nth root of the product of the individual values where N = the number of individual values. For purposes of calculating the geometric mean,values of"0" (or"< [detection level]' shall be considered =1. Grab Sample Individual samples of at least 100 ml collected over a period of time not exceeding 15 minutes. Grab samples can be collected manually. Grab samples must be representative of the discharge (or the receiving stream, for instream samples). Hazardous Substance Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Water Act. Version 10/10/2007 • NPDES Permit Standard Conditions Page 3 of 16 Instantaneous flow measurement A measure of flow taken at the time of sampling,when both the sample and flow will be representative of the total discharge. Monthly Average (concentration limit) The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar month. In the case of fecal coliform,the geometric mean of such discharges. Permit Issuing Authority The Director of the Division of Water Quality. Quarterly Average(concentration limit) The average of all samples taken over a calendar quarter. Severe property damage Substantial physical damage to property,damage to the treatment facilities which causes them to become inoperable, or substantial and permanent loss of natural resources which can reasonably be expected to occur in the absence of a bypass. Severe property damage excludes economic loss caused by delays in production. Toxic Pollutant: Any pollutant listed as toxic under Section 307(a)(1)of the Clean Water Act. Upset An incident beyond the reasonable control of the Permittee causing unintentional and temporary noncompliance with permit effluent limitations and/or monitoring requirements. An upset does not include noncompliance caused by operational error, improperly designed treatment facilities, inadequate treatment facilities, lack of preventive maintenance,or careless or improper operation. Weekly Average (concentration limit) The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar week. In the case of fecal coliform,the geometric mean of such discharges. Section B. General Conditions 1. Duty to Comply The Permittee must comply with all conditions of this permit. Any permit noncompliance constitutes a violation of the Clean Water Act and is grounds for enforcement action;for permit termination,revocation and reissuance, or modification;or denial of a permit renewal application [40 CFR 122.41]. a. The Permittee shall comply with effluent standards or prohibitions established under section 307(a) of the Clean Water Act for toxic pollutants and with standards for sewage sludge use or disposal established under section 405(d) of the Clean Water Act within the time provided in the regulations that establish these standards or prohibitions or standards for sewage sludge use or disposal, even if the permit has not yet been modified to incorporate the requirement. b. The Clean Water Act provides that any person who violates section 301, 302,306,307,308,318 or 405 of the Act, or any permit condition or limitation implementing any such sections in a permit issued under section 402, or any requirement imposed in a pretreatment program approved under sections 402(a)(3) or 402(b)(8) of the Act, is subject to a civil penalty not to exceed $25,000 per day for each violation. [40 CFR 122.41 (a) (2)] c. The Clean Water Act provides that any person who negligently violates sections 301,302,306,307,308,318,or 405 of the Act, or any condition or limitation implementing any of such sections in a permit issued under Version 10/10/2007 NPDES Permit Standard Conditions NPDES Permit Standard Conditions• Page 14 of 16 f. Petroleum oil, nonbiodegradable cutting oil, or products of mineral oil origin in amounts that will cause interference or pass through; g. Pollutants which result in the presence of toxic gases, vapors, or fumes within the POTW in a quantity that may cause acute worker health and safety problems; h. Any trucked or hauled pollutants,except at discharge points designated by the POTW. 3. With regard to the effluent requirements listed in Part I of this permit, it may be necessary for the Permittee to supplement the requirements of the Federal Pretreatment Standards (40 CFR, Part 403) to ensure compliance by the Permittee with all applicable effluent limitations. Such actions by the Permittee may be necessary regarding some or all of the industries discharging to the municipal system. 4. The Permittee shall require any industrial discharges sending influent to the permitted system to meet Federal Pretreatment Standards promulgated in response to Section 307(b) of the Act. Prior to accepting wastewater from any significant industrial user, the Permittee shall either develop and submit to the Division a Pretreatment Program for approval per 15A NCAC 2H .0907(a) or modify an existing Pretreatment Program per 15A NCAC 2H .0907(b). 5. This permit shall be modified,or alternatively,revoked and reissued, to incorporate or modify an approved POTW Pretreatment Program or to include a compliance schedule for the development of a POTW Pretreatment Program as required under Section 402(b)(8) of the Clean Water Act and implementing regulations or by the requirements of the approved State pretreatment program,as appropriate. Section C. Pretreatment Programs Under authority of sections 307(b) and (c) and 402(b)(8) of the Clean Water-Act and implementing regulations 40 CFR Part 403, North Carolina General Statute 143-215.3 (14) and implementing regulations 15A NCAC 2H .0900, and in accordance with the approved pretreatment program, all provisions and regulations contained and referenced in the Pretreatment Program Submittal are an enforceable part of this permit. The Permittee shall operate its approved pretreatment program in accordance with Section 402(b)(8) of the Clean Water Act, the Federal Pretreatment Regulations 40 CFR Part 403, the State Pretreatment Regulations 15A NCAC 2H .0900, and the legal authorities, policies, procedures, and financial provisions contained in its pretreatment program submission and Division approved modifications there of. Such operation shall include but is not limited to the implementation of the following conditions and requirements: 1. Sewer Use Ordinance(SUO) The Permittee shall maintain adequate legal authority to implement its approved pretreatment program. 2. Industrial Waste Survey(IWS) The Permittee shall update its Industrial Waste Survey (IWS) to include all users of the sewer collection system at least once every five years. 3. Monitoring Plan The Permittee shall implement a Division-approved Monitoring Plan for the collection of facility specific data to be used in a wastewater treatment plant Headworks Analysis (HWA) for the development of specific pretreatment local limits. Effluent data from the Plan shall be reported on the DMRs (as required by Part II,Section D,and Section E.5.). 4. Headworks Analysis (HWA) and Local Limits The Permittee shall obtain Division approval of a Headworks Analysis (HWA) at least once every five years, and as required by the Division. Within 180 days of the effective date of this permit (or any subsequent permit modification) the Permittee shall submit to the Division a written technical evaluation of the need to revise local limits (i.e., an updated HWA or documentation of why one is not needed) [40 CFR 122.44]. The Permittee shall develop,in accordance with 40 CFR 403.5(c)and 15A NCAC 2H .0909, specific Local Limits to implement the prohibitions listed in 40 CFR 403.5(a) and (b) and 15A NCAC 2H .0909. Version 10/10/2007 r '+ • NPDES Permit Standard Conditions ti Page 15of16 5. Industrial User Pretreatment Permits (IUP)&Allocation Tables In accordance with NCGS 143-215.1,the Permittee shall issue to all significant industrial users,permits for operation of pretreatment equipment and discharge to the Permittee's treatment works. These permits shall contain limitations, sampling protocols, reporting requirements, appropriate standard and special conditions, and compliance schedules as necessary for the installation of treatment and control technologies to assure that their wastewater discharge will meet all applicable pretreatment standards and requirements. The Permittee shall maintain a current Allocation Table (AT)which summarizes the results of the Headworks Analysis (HWA) and the limits from all Industrial User Pretreatment Permits (IUP). Permitted IUP loadings for each parameter cannot exceed the treatment capacity of the POTW as determined by the HWA. 6. Authorization to Construct(AtC) The Permittee shall ensure that an Authorization to Construct permit (AtC) is issued to all applicable industrial users for the construction or modification of any pretreatment facility. Prior to the issuance of an AtC, the proposed pretreatment facility and treatment process must be evaluated for its capacity to comply with all Industrial User Pretreatment Permit(IUP) limitations. 7. POTW Inspection&Monitoring of their SIUs The Permittee shall conduct inspection, surveillance, and monitoring activities as described in its Division approved pretreatment program in order to determine, independent of information supplied by industrial users,compliance with applicable pretreatment standards. The Permittee must: a. Inspect all Significant Industrial Users (SIUs) at least once per calendar year;and b. Sample all Significant Industrial Users (SIUs) at least twice per calendar year for all permit- limited pollutants, once during the period from January 1 through June 30 and once during the period from July 1 through December 31,except for organic compounds which shall be sampled once per calendar year; 8. SIU Self Monitoring and Reporting The Permittee shall require all industrial users to comply with the applicable monitoring and reporting requirements outlined in the Division-approved pretreatment program,the industry's pretreatment permit, or in 15A NCAC 2H.0908. 9. Enforcement Response Plan (ERP) The Permittee shall enforce and obtain appropriate remedies for violations of all pretreatment standards promulgated pursuant to section 307(b) and (c) of the Clean Water Act (40 CFR 405 et. seq.),prohibitive discharge standards as set forth in 40 CFR 403.5 and 15A NCAC 2H .0909, and specific local limitations. All enforcement actions shall be consistent with the Enforcement Response Plan (ERP) approved by the Division. 10. Pretreatment Annual Reports (PAR) The Permittee shall report to the Division in accordance with 15A NCAC 2H.0908. In lieu of submitting annual reports, Modified Pretreatment Programs developed under 15A NCAC 2H .0904 (b) may be required to meet with Division personnel periodically to discuss enforcement of pretreatment requirements and other pretreatment implementation issues. For all other active pretreatment programs, the Permittee shall submit two copies of a Pretreatment Annual Report (PAR) describing its pretreatment activities over the previous twelve months to the Division at the following address: NC DENR/DWQ /Pretreatment Unit 1617 Mail Service Center Raleigh,NC 27699-1617 Version 10/10/2007 NPDES Permit Standard Conditions•' Page 16of16 These reports shall be submitted according to a schedule established by the Director and shall contain the following: a.) Narrative A brief discussion of reasons for, status of, and actions taken for all Significant Industrial Users (SIUs)in Significant Non-Compliance (SNC); b.) Pretreatment Program Summary(PPS) A pretreatment program summary(PPS) on specific forms approved by the Division; c.) Significant Non-Compliance Report(SNCR) The nature of the violations and the actions taken or proposed to correct the violations on specific forms approved by the Division; d.) Industrial Data Summary Forms (IDSF) Monitoring data from samples collected by both the POTW and the Significant Industrial User (SIU). These analytical results must be reported on Industrial Data Summary Forms (1DSF) or other specific format approved by the Division; e.) Other Information Copies of the POTW's allocation table,new or modified enforcement compliance schedules, public notice of SIUs in SNC, and any other information, upon request, which in the opinion of the Director is needed to determine compliance with the pretreatment implementation requirements of this permit; 11. Public Notice The Permittee shall publish annually a list of Significant Industrial Users (SIUs) that were in Significant Non-Compliance (SNC) as defined in the Permittee's Division-approved Sewer Use Ordinance with applicable pretreatment requirements and standards during the previous twelve month period. This list shall be published within four months of the applicable twelve-month period. 12. Record Keeping The Permittee shall retain for a minimum of three years records of monitoring activities and results, along with support information including general records,water quality records, and records of industrial impact on the POTW. 13. Funding and Financial Report The Permittee shall maintain adequate funding and staffing levels to accomplish the objectives of its approved pretreatment program. 14. Modification to Pretreatment Programs Modifications to the approved pretreatment program including but not limited to local limits modifications, POTW monitoring of their Significant Industrial Users (SIUs), and Monitoring Plan modifications, shall be considered a permit modification and shall be governed by 15 NCAC 2H .0114 and 15A NCAC 2H.0907. • Version 10/10/2007 000 WA7- Michael F. Easley,Governor • State of North Carolina William G. Ross,Jr.,Secretary net N.k. Ee isi 1 of • September 8,2008 S E P j 0 2cQB Mr.Michael Ruhe tVL U*NR MRO Duke Energy Corporation P.O. Box 1006 DWQ-Surface Water Protection Mail Code EC11E Charlotte,North Carolina 28201 Subject: NPDES Minor Modification Permit No.NC0004979 Allen Steam Station Gaston County Dear Mr.Ruhe: The subject individual NPDES permit issued on September 11,2006 has been modified as per your request. Please find attached the modified,sections of this permit,and replace the old pages with the modified pages. This permit modification is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated December 6, 1983(and as subsequently amended). The following permit modification is authorized by this letter: • Duke Energy is authorized to route landfill leachate to the existing ash basin wastewater treatment system. This minor modification is necessary so that Duke may change from its current ash sluicing operation to a dry ash handling system,which is expected to reduce overall pollutant loading to the ash pond. If any parts,measurement frequencies or sampling requirements contained in this permit modification are unacceptable to you,you have the right to an adjudicatory hearing upon written request within thirty (30)days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes,and filed with the office of Administrative Hearings,Post Office Drawer 27447,Raleigh,North Carolina 27611-7447. Unless such a demand is made,this permit shall be final and binding. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources,Coastal Area Management Act,or any other Federal or Local governmental permits may be required. If you have any questions or need additional information,please contact Toya Fields,telephone number (919)807-6385. Sincere 0)( o el en'Sullins cc: NPDES File Central Files 'Mooresville Regional Office,WaterQuaI tyr 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 Telephone(919)733-7015 FAX(919)733-0719 NoZhCarolina 512 N.Salisbury Street,Raleigh,North Carolina 27604 On the Internet at http://www.ncwaterquality.org jvaturally An Equal Opportunity/Affirmative Action Employer Permit NC0004979 SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility,whether for operation or discharge are hereby revoked.As of this permit issuance,any previously issued permit bearing this number is no longer effective.Therefore,the exclusive authority to operate and discharge from this facility arises under the permit conditions,requirements, terms, and provisions included herein. Duke Energy Corporation is hereby authorized to: 1. Continue to discharge: • Once through cooling water (outfall 001) • Operate a septic tank and ash pond with pH adjustment and discharge domestic wastewater,stormwater runoff,ash sluice,water treatment system wastewaters,FGD system blowdown,landfill leachate,and miscellaneous cleaning and maintenance wash waters(002). • Coal yard sump overflow (002A) and power house sump overflow(002B) • Miscellaneous equipment non-contact cooling and sealing water(003) • Miscellaneous non-contact cooling water,vehicle washwater,and intake screen backwash(004) From a facility located at the Plant Allen Steam Station on Plant Allen Road(NCSR 2525), south of Belmont in Gaston County,and • 2. Without adding detergents or chemicals of any kind,discharge Asiatic clam/debris filter backwash(of the intake filter screen) (see Part A.7);and 3. After receiving an Authorization to Construct from the Construction Grants and Loans Section,construct and operate a FGD wet scrubber wastewater treatment system discharging to the ash settling basin through internal outfall 005; and 4. Discharge from said treatment works at the location specified on the attached map into the Catawba River (outfalls 002, 002A, 002B and 004) and the South Fork Catawba River(outfalls 001 and 003) which are classified Class WS-V B waters, respectively,in the Catawba River Basin. 2 VV n 1 -.9 Michael F.Easley,Governor QG William G.Ross Jr.,Secretary r North Carolina Department of Environment and Natural Resources -;4): —i G1 `'C Alan W.Klimek,P.E.Director Division of Water Quality DIVISION OF WATER QUALITY September 27, 2006 Mr. Michael Ruhe Duke Energy Corporation P.O. Box 1006 • Mail Code EC 11 E Charlotte,North Carolina 28201 Subject: NPDES Permit NC0004979 • Allen Steam Station Gaston County • Dear Mr. Ruhe: Our records indicate that NPDES Permit No. NC0004979 was issued on September 1 1, 2006 for the discharge of wastewater to the surface waters of the State from your facility. The purpose of this letter is to advise you of the importance of the Permit and the liabilities in the event of failure to comply with the terms and conditions of the Permit. If you have not already done so,it is suggested that you thoroughly read the Permit. Of particular importance are Pages 3, 4, 5, 6, 7and8. Pages 3, 4, 5, 6, 7 and 8 set forth the effluent limitations and monitoring requirements for your discharge. Your discharge must not exceed any of the limitations set forth. The section headed "Monitoring Requirements" describes the measurement frequencies, sample types and sampling locations. Upon commencement of your discharge (or operation), you must initiate the required monitoring. The monitoring results must be entered on reporting forms furnished or approved by this Agency. For new permits/facilities, the Division may supply an initial small stock of these forms; however, if you fail to receive the forms, please contact this Office as quickly as possible. The forms, including directions for their completion, and other important information are.also available at http://h2o.enr.state.nc.us/NPDES/documents.html. It is imperative that all applicable parts be completed, and the original and one copy be submitted as required. Please be advised that an annual fee may be required for your facility; if so, you will receive a statement from our Raleigh Office. It is imperative that the fee be paid in a timely manner so as to prevent enforcement action or possible revocation of your permit. `„ +VA NonOn°thCarohna NCDENR dvaturally Mooresville Regional Office Division of Water Quality Phone 704-663-1699 Customer Service Internet: www.ncwaterqualitv.org 610 East Center Ave,Suite 301 Mooresville,NC 28115 Fax 704-663-6040 1-877-623-6748 An Equal Opportunity/Affirmative Action Employer—50%Recycled/10%Post Consumer Paper The remaining parts of the Permit set forth definitions, general conditions and special conditions applicable to the operation of wastewater treatment facilities and/or discharge(s). The conditions include special reporting requirements in the event of noncompliance, bypasses. treatment unit/process failures, etc. Also addressed are requirements for a certified wastewater treatment plant operator if you are operating wastewater treatment facilities. Any changes in operation of wastewater treatment facilities, quantity and type of wastewater being treated or discharged, expansions and/or upgrading of wastewater treatment facilities must be permitted or approved by this Agency. To maintain compliance with discharge limitations, proper operation and maintenance of a wastewater treatment facility and the development of a process control program are essential. For those facilities having chlorine tablet disinfection, please be advised that chlorine tablets approved for wastewater treatment use must be used; swimming pool tablets are not approved. Also,be advised that DWQ staff need to have access to the facility's discharge point into the receiving stream; please maintain a path along the outfall line to facilitate that access. Failure to comply with the terms and conditions of an NPDES Permit subjects the Permittee to enforcement action pursuant to Section 143-215.6 of the North Carolina General Statutes.. A civil penalty of up to $25,000 per violation(and/or criminal penalties) may, be: assessed;for such violations. If you find at any time that you are unable to comply with the terms and conditions of the Permit, you should contact this Office immediately. A Special Order by Consent.,(SOC) may be necessary while pursuing action to obtain compliance. As a final note, an NPDES Permit is normally issued for a five-year period. Permits are not automatically,renewed. Renewal requests must be submitted to this Agency no later. than 180 days prior:to expiration. Please make note of the expiration date of your Permit. This date is set forth on.Page'l of the Permit. Also note that NPDES Permits are not automatically transferable. gyau,.as;the,Permittee, cease to need this Permit, then you should request that.the Division of Water Quality rescind the Permit or request that DWQ reissue the Permit to another party; i,f necessary..., As mentioned previously, the purpose of this letter is to advise you of the importance of your NPDES Permit. Please read the Permit and contact this Office at 704/663-1699 in.. . Mooresville,if you have any questions or need clarification. We look forward to providing any assistance... .. . , Sincerely, D. Rex Gleason, P.E. 1 Surface Water Protection Regional Supervisor O� WA7 Michael F.Easley,Governor State of North Carolina . William G. Ross,Jr.,Secretary Dep Iii nt6I`'EedIrchnekirtitotWatural Resources 0 Alan.1W Klirfek\P.E.,Director • J� ti .. t�ivu`�ifnl6EWater Quality /y September 11,2006 1 Mr.Michael Ruhe S E P 1 8 200o Duke Energy Corporation P.O.Box 1006 Mail Code EC11E Charlotte,North Carolina 28201 WATER QUALITY SECTION Subject:Issuance of NPDES Permit NC0004979 Allen Steam Station Gaston County Dear Mr.Ruhe: Division personnel have reviewed and approved your application for renewal of the subject permit. Accordingly,we are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S.Environmental Protection Agency dated May 9,1994(or as subsequently amended). This final permit contains no'significant changes from the draft you were sent on July 5,2006. If any parts,measurement frequencies or sampling requirements contained in this permit are unacceptable to you,you have the right to an adjudicatory hearing upon written request within thirty (30)days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes,and filed with the Office of Administrative Hearings(6714 Mail Service Center,Raleigh,North Carolina 27699-6714). Unless such demand is made,this decision shall be final and binding. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources,the Coastal Area Management Act or any other Federal or Local governmental permit that may be required. If you have any questions concerning this permit,please contact Toya Fields at telephone number(919)733-5083,extension 551. Sincerely, /441) 6-11"1---d (* Alan W.Klimek,P.E. cc: Central Files Mooresville Regional Office/Surface Water Protection NPDES Unit Aquatic Toxicology Marshall Hyatt,EPA Region IV 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 Telephone(919)733-7015 FAX(919)733-0719 Noe Carolina 512 N.Salisbury Street,Raleigh,North Carolina 27604 On the Internet at http://h2o.enr.state.nc.us/ turn/lf An Equal Opportunity/Affirmative Action Employer STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1,other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission,and the Federal Water Pollution Control Act,as amended, Duke Energy Corporation is hereby authorized to discharge wastewater from a facility located at the Plant Allen Steam Station 253 Plant Allen Road (NCSR 2525) Belmont Gaston County to receiving waters designated as the Catawba and South Fork Catawba Rivers in the Catawba River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I,II,III and IV hereof. This permit shall become effective October 1, 2006. This permit and authorization to discharge shall expire at midnight on May 31,2010. Signed this day September 11, 2006. • ¢P" Alan W.Klimek,P.E. Director Division of Water Quality By Authority of the Environmental Management Commission Permit NC0004979 SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility,whether for operation or discharge are hereby revoked.As of this permit issuance,any previously issued permit bearing this number is no longer effective.Therefore,the exclusive authority to operate and discharge from this facility arises under the permit conditions,requirements, terms,and provisions included herein. Duke Energy Corporation is hereby authorized to: 1. Continue to discharge: • Once through cooling water (outfall 001) • Operate a septic tank and ash pond with pH adjustment and discharge domestic wastewater,stormwater runoff, ash sluice,water treatment system wastewaters,FGD system blowdown,and miscellaneous cleaning and maintenance wash waters (002). • Coal yard sump overflow(002A) and power house sump overflow(002B) • Miscellaneous equipment non-contact cooling and sealing water(003) • Miscellaneous non-contact cooling water,vehicle washwater, and intake screen backwash(004) From a facility located at the Plant Allen Steam Station on Plant Allen Road(NCSR 2525), south of Belmont in Gaston County, and 2. Without adding detergents or chemicals of any kind,discharge Asiatic clam/debris filter backwash(of the intake filter screen) (see Part A.7);and 3. After receiving an Authorization to Construct from the Construction Grants and Loans Section,construct and operate a FGD wet scrubber wastewater treatment system discharging to the ash settling basin through internal outfall 005;and 4. Discharge from said treatment works at the location specified on the attached map into the Catawba River(outfalls 002,002A,002B and 004)and the South Fork Catawba River(outfalls 001 and 003)which are classified Class WS-V B waters,respectively,in the Catawba River Basin. • .z . • • • •_t �•'.;� .It.Jx"r , , - i y• 4C . (( (�"� •ti s 1- _ y 3 vy • r a xt !� r t 3i nt -' .it c �r titTl .o�F - .4 \ tp.,...yr,s-F-t,r,- ?3^ �i J�' �' t •• ,.. 1 r r'Ac $�t r 6 �� .i ‹yram,, v rr ` i, ...7u si _!t ,�7 f.,� • iS1 \ vr7 /� y � �1 i y �f �� •� ti i I�q; \-f �7 - %rJ 2 / �� It -TY . , // `W /' • x 0 1� rj} \4 t t v: '/ /r r.)r j i .ti � - `t t�Vvt t�/-G �: ,J Y � r ,��� ^♦ r fl�J A ��t ytT :` ,y t� '1', � �'t !!! T■mil tl ,. 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( 7 ♦ N`'e 11 F C` \\ * r /�� ':\,.� ;1 /♦ In S• i t r/(r� 9 ) A\v��n \.�. r�r ti�� �J�(.; � ��� 4�' i`, �t i �l,�V:,5 !( ♦ -- 1 ate.+- -�\((,f y,.—; V'V`�r .� y • �:. f( ` 4 1 1 ' ,rf .„` � " j. __ , ._llj ©�}♦"'r t%J'`� `; f ir/i>' -�~-J -!'r`ry s�___,�..� j l�y '� \ � 4/M ,�'Tl 1 ti.':t ` },f':- �i+ Jt �\ 5* i( / .. t 4� ✓ x 1•- - 4•/ r r^ S: yi �i: l ' \c r / t ' ;,' i'� _.'. �'-� fit, / t , � < � t \6,J a J�� / t}S J�\�_ \\ I .%i , � 3 � =�'� jy � J/%r Xr • .�\ M-\ �� r- �/ r� t' ;���-- \ � f� ��.! }! r J \�•\ j( -`' 'E V :, //}t 4- /r`j Ja4 % • \ tirtl�,Y 5i f i %� 9;. � C t �. y e C .i! �, .3 • u� j • 4 �_ itp. „/iJ//•N'I i2 •,I�C :••c-,. \ `: f 11r�d. i.PY 1 '-A ✓!-�f ",,,gfi 1�,y^n-Lf='•'- [\r' yy�� Y �"s•" / v,,,, _`3 "./ ; l i r` •S ^' . f ° \` 4, � `\ ,F' ( 4 / :t ;;jl 1.� A,k 1 � > . . �/ \.� C: n� ��._./t:Z - \ ��y\, i- � i/f/` l �' , �I�;�a `f� te .,.,.. c'" k t f ¢ Z ./ \DOOM ti �* -, 'r E;.r\ - \ {\\, 11., ( 1 r � y �/i t,f. \` .._..i '� S „} T •, �;•,,,M rrl•'w ' '�'t+,. ,( , p �J 1 t } I 1- l tt'' j\ .-rl f.ki,\.<kh. d '\....:-� .."�-•�.^„ .,Y r i [.-�.�rtti. i I 1<Y�l�/n� �y/n-�_�:<.�,.-:1.'.\....� -�.n�.-a\\.:�t:E�<,. ..!�l��'�f! �i� � ti t, 't I fi f:y r i r Duke Energy Corporation Map not to scale Allen Steam Station State Grid/Quad: G14NE/Belmont Permitted Flow: Not limited Receiving Streams: Catawba and South Fork Catawba Rivers Stream Class: WS-V&B Drainage Basin: Catawba River Basin Sub-Basin: 03-08-34 Facility Latitude(001): 35°I I'23" N Longitude(001): 81°00'45" W x, y ",, Latitude(002): 35° 10'30" N Longitude(002): 81°00'23" W Location Latitude(002A): 35°I l'34" N Longitude(002A): 81°00'22" W Latitude(002B): 35° 11'36" N Longitude(002B): 81°00'30" W Latitude(004): 35°11'35" N Longitude(004): 81°00'22" W NPDES Permit No. NC0004979 Latitude(A.Clam): 35° f I'36" N Loneitude(A.Clam):81°00'30" W North Gaston County Permit NC0004979 A. (1.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 001) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 001-Condenser Cooling Water(CCW). Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT ' �� • LIMITS MONITORING REQUIREMENTS rt° CHARACTERISTICS Monthly" Daily Measurement Sample Type ,:Sample Location= Average:, Maximum: :Frequency ,..: ..,A ... , .; Flow Daily Pump Logs Effluent Temperature 38.9°C Grab or (June 1—September 30)1 (102°F) Daily Instantaneous Effluent Temperature 35°C Daily Grab or Effluent (October 1—May 31)1 (95°F) Instantaneous Notes: 1. The Regional Administrator has determined pursuant to Section 316(a)of the Act that the thermal component of the discharge assures the protection and propagation of a balanced,indigenous population of shellfish,fish,and wildlife in and on the receiving body of water. Chlorination of the once through condenser cooling water,discharged through outfall 001,is not allowed under this permit. Should Duke Power wish to chlorinate its condenser cooling water,a permit modification must be requested and received prior to commencing chlorination. 3 • Permit NC0004979 A. (2.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 002—ash pond effluent. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS ; CHARACTERISTICS Monthly Weekly Daily Measurement Sample Type Sample Location Average Average Maximum Frequency Flow Weekly Instantaneous Influent or or Estimate Effluent Oil and Grease 15.0 mg/1 20.0 mg/1 Quarterly Grab Effluent Total Suspended Solids 30.0 mg/1 100.0 mg/1 Monthly Grab Effluent Total Copper2 1.0 mg/1 2/Month Grab Effluent Total Iron2 1.58 mg/1 Monthly Grab Effluent Total Seleniumz3 . 31.0 pg/L 2/Month Grab Effluent. Total Seleniumz4 21.0 pg/L 2/Month Grab Effluent Total Nitrogen (NO2+NO3+TKN) Semi-annually Grab Effluent Chronic Toxicityl Quarterly Grab Effluent pH5 Monthly Grab Effluent Notes: 1. Whole Effluent Toxicity shall be monitored by chronic toxicity(Ceriodaphnia)P/F at 24%. Tests shall be conducted in January,April,July and October(see Part A.(9.)for details) 2. Total metals are defined by 40 CFR 136. Any method specified by 40 CFR 136 is considered acceptable for analysis. 3. 31 pg/L selenium limit shall be in effect October 1,2006 through September 30,2009. 4. 21 pg/L selenium limit shall take effect October 1,2009. 5. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. • There shall be no discharge of floating solids or foam visible in other than trace amounts. 4 Permit NC0004979 • A. (3.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002A) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 002A—Coal Yard Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT -LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type ;' Sample Location Average Maximum Frequency Flow Episodic Estimate Effluents pH Episodic Grab Effluent Oil and Grease2 15.0 mg/1 20.0 mg/1 Episodic Grab Effluent Total Suspended Solids2 30.0 mg/1 100.0 mg/1 Episodic Grab Effluent Fecal Colifonn Episodic Grab Effluent Total Iron3 1.0 mg/1 Episodic Grab Effluent Notes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. Sampling for iron is required only when TSS is reported as greater than 100 mg/L. There shall be no discharge of floating solids or foam visible in other than trace amounts All flows shall be reported on monthly DMRs. Should no flow occur during a given month,the words"no flow"should be clearly written on the front of the DMR. Episodic sampling is required per occurrance when sump overflows occur for longer than one hour. All samples shall be of a representative discharge. 5 Permit NC0004979 A. (4.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 002B) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 002B—Power House Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency ... Flow Episodic Estimate Effluent' pH Episodic Grab Effluent Oil and Grease2 15.0 mg/1 20.0 mg/1 Episodic Grab Effluent Total Suspended Solids2 30.0 mg/1 100.0 mg/1 Episodic Grab Effluent Total Copper3 1.0 mg/1 Episodic Grab Effluent Total Iron3 1.0mg/1 Episodic Grab Effluent Notes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. The limits for total copper and total iron only apply during a chemical metals cleaning. There shall be no discharge of floating solids or visible foam in other than trace amounts All flows shall be reported on monthly DMRs. Should no flow occur during a given month,the words"no flow"should be clearly written on the front of the DMR. Episodic sampling is required per occurrance when sump overflows occur for longer than one hour. All samples shall be of a representative discharge. 6 Permit NC0004979 A. (5.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 003) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 003—miscellaneous equipment non-contact water and sealing water. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type " Sample Location Average Maximum Frequency -. Flow Weekly Estimate Effluent Chlorination of the once through cooling water, discharged through outfall 003,is not allowed under this permit. Should Duke Power wish to chlorinate its once through cooling water,a permit modification must be requested and received prior to commencing chlorination. A. (6.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Outfall 004) During the period beginning on the effective date of this permit and lasting until expiration,the Permittee is authorized to discharge from outfall 004-miscellaneous non-contact cooling water,vehicle washwater,and intake screen backwash. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING'REQUIREMENTS' CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Weekly Estimate Effluent Oil and Grease 15.0 mg/1 20.0 mg/1 Quarterly Grab Effluent Chlorination of the once through cooling water,discharged through outfall 004,is not allowed under this permit. Should Duke Power wish to chlorinate its condenser cooling water,a permit modification must be requested and received prior to commencing chlorination. 7 Permit NC0004979 A. (7.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS (Internal Outfall 005) During the period beginning upon submittal of an engineer's certification and lasting until permit expiration, the Permittee is authorized to discharge from internal outfall 005-treated FGD wet scrubber wastewater to ash settling basin. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Sample Average Maximum Frequency Type Location Pump logs or Flow Monitor&Report Monthly similar Effluent readings Total Suspended Solids Monitor&Report Weekly Grab Effluent Carbonaceous Oxygen Demand Monitor&Report Weekly Grab Effluent (COD) Total Arsenic Monitor&Report Weekly Grab Effluent Total Cadmium Monitor&Report Weekly Grab Effluent Total Chromium Monitor&Report Weekly Grab Effluent Chloride Monitor&Report Weekly Grab Effluent Total Mercury Monitor&Report Weekly Grab Effluent Total Nickel Monitor&Report Weekly Grab Effluent Total Selenium Monitor&Report Weekly Grab Effluent Total Silver Monitor&Report Weekly Grab Effluent Total Zinc Monitor&Report Weekly Grab Effluent Total Beryllium Monitor&Report Weekly Grab Effluent Notes: 1. "Effluent"shall be defined as the discharge from the FGD wastewater treatment system prior to discharge to the ash settling basin. All flows shall be reported on monthly DMRs. Should no flow occur during a given month,the words"no flow"shall be clearly written on the front of the DMR. All samples shall be of a representative discharge. DMRs for this outfall shall be submitted only after discharge commences from the FGD system. Sampling is only required when this outfall is discharging. A. (8.) SPECIAL CONDITION FOR THE DISCHARGE OF ASIATIC CLAM/DEBRIS FILTER BACKWASH The permittee may backwash the intake filter for Unit 5 condenser cooling water on an as-needed basis. It is understood that this wash water will contain materials indigenous to the Catawba River such as Asiatic clams and light debris. As these are naturally occurring in the river environment,they may be discharged with no adverse affects to the receiving stream. The Permittee may not add any detergent,chemicals or other non- indigenous material to the wash water without explicit permission of the Division of Water Quality. 8 Permit NC0004979 A. (9.) CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QUARTERLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 24%. The permit holder shall perform at a minimum,quarterly monitoring using test procedures outlined in the"North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure,"Revised February 1998,or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure"(Revised-February 1998)or subsequent versions.The tests will be performed during the months of January,April,July and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit,then multiple-concentration testing shall be performed at a minimum,in each of the two following months as described in"North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure"(Revised-February 1998)or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival.The definition of"detectable impairment,"collection methods,exposure regimes,and further statistical methods are specified in the"North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure"(Revised-February 1998)or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form(MR-1)for the months in which tests were performed,using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value.Additionally,DWQ Form AT-3(original)is to be sent to the following address: Attention: North Carolina Division of Water Quality Environmental Sciences Section 1621 Mail Service Center Raleigh,North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Branch no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete,accurate,include all supporting chemical/physical measurements and all concentration/response data,and be certified by laboratory supervisor and ORC or approved designate signature. • Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required,the permittee will complete the information located at the top of the aquatic toxicity(AT)test form indicating the facility name,permit number,pipe number,county,and the month/year of the report with the notation of"No Flow"in the comment area of the form.The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required,monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream,this permit may be re-opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document,such as minimum control organism survival,minimum control organism reproduction,and appropriate environmental controls,shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. 9 Permit NC0004979 A. (10.) BIOCIDE CONDITION ' The permittee shall not use any biocides except those approved in conjunction with the permit application. The permittee shall notify the Director in writing not later than ninety(90)days prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life other than those previously reported to the Division of Water Quality. Such notification shall include completion of Biocide Worksheet Form 101 and a map locating the discharge point and receiving stream. Completion of Biocide Worksheet Form 101 is not necessary for those outfalls containing toxicity testing. Division approval is not necessary for the introduction of a new biocide into an outfall currently being tested for toxicity. A. (11.) SPECIAL CONDITIONS The following special conditions are applicable to all outfalls regulated by NC0004979: • There shall be no discharge of polychlorinated biphenyl compounds. • It has been determined from information submitted that the plans and procedures in place at Allen Steam Station are equivalent to that of a BMP. • The permittee shall report the presence of cenospheres observed in any samples. • The applicant is permitted to discharge chemical metal cleaning wastes to the ash basin under the conditions outlined in the 1976 Riverbend Ash Basin Equivalency Demonstration and the 1994 Allen Steam Station permit application • The permittee shall check the diked areas for leaks by a visual inspection and shall report any leakage detected • If the permittee,after monitoring for at least six months,determines that he/she is consistently meeting the effluent limits contained herein,the permittee may request of the Director that the monitoring requirement be reduced to a lesser frequency. • Nothing contained in this permit shall be construed as a waiver by the permittee or any right to a hearing it may have pursuant to State or Federal laws or regulations. • Low volume waste is defined as follows(as per 40 CFR 423.11(b): "Low volume wastes sources include,but are not limited to:wastewaters from wet scrubber air pollution control systems,ion exchange water treatment system,water treatment evaporator blowdown,laboratory and sampling streams,boiler blowdown,floor drains,cooling tower basin cleaning wastes,and recirculating house service water systems. Sanitary and air conditioning wastes are not included." A. (12.) SECTION 316 (B) OF CWA The permittee shall comply with the Cooling Water Intake Structure Rule per 40 CFR 125.95. 10 NPDES Permit Requirements Page 1 of 16 PART II STANDARD CONDITIONS FOR NPDES PERMITS Section A. Definitions 2/Month Samples are collected twice per month with at least ten calendar days between sampling events. 3/Week Samples are collected three times per week on three separate calendar days. Act or"the Act" The Federal Water Pollution Control Act,also known as the Clean Water Act,as amended,33 USC 1251,et. seq. Annual Average The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar year. In the case of fecal coliform,the geometric mean of such discharges. Arithmetic Mean The summation of the individual values divided by the number of individual values. Bypass The known diversion of waste streams from any portion of a treatment facility induding the collection system,which is not a designed or established or operating mode for the facility. Calendar Day The period from midnight of one day until midnight of the next day. However, for purposes of this permit, any consecutive 24-hour period that reasonably represents the calendar day may be used for sampling. Calendar Quarter One of the following distinct periods: January through March, April through June, July through September, and October through December. Composite Sample A sample collected over a 24-hour period by continuous sampling or combining grab samples of at least 100 ml in such a manner as to result in a total sample representative of the wastewater discharge during the sample period. The Director may designate the most appropriate method (specific number and size of aliquots necessary, the time interval between grab samples, etc.) on a case-by-case basis. Samples may be collected manually or automatically. Composite samples may be obtained by the following methods: (1) Continuous:a single,continuous sample collected over a 24-hour period proportional to the rate of flow. (2) Constant time/variable volume: a series of grab samples collected at equal time intervals over a 24.hour period of discharge and combined proportional to the rate of flow measured at the time of individual sample collection,or (3) Variable time/constant volume: a series of grab samples of equal volume collected over a 24 hour period with the time intervals between samples determined by a preset number of gallons passing the sampling point. Flow measurement between sample intervals shall be determined by use of a flow recorder and totalizer, and the preset gallon interval between sample collection fixed at no greater than 1/24 of the expected total daily flow at the treatment system,or (4) Constant time/constant volume: a series of grab samples of equal volume collected over a 24-hour period at a constant time intervaL This method may only be used in situations where effluent flow rates vary less than 15 percent. The grab samples shall be taken at intervals of no greater than 20 minutes apart during any 24-hour period and must be of equal size and of no less than 100 milliliters. Use of this method requires prior approval by the Director. Version 6J20/2003 • NPDES Permit Requirements Page 2 of 16 In accordance with(4) above,influent grab samples shall not be collected more than once per hour. Effluent grab samples shall not be collected more than once per hour except at wastewater treatment systems having a detention time of greater than 24 hours. In such cases, effluent grab samples may be collected at intervals evenly spaced over the 24-hour period that are equal in number of hours to the detention time of the system in number of days. However, the interval between effluent grab samples may not exceed six hours nor the number of samples less than four during a 24-hour sampling period. Continuous flow measurement Flow monitoring that occurs without interruption throughout the operating hours of the facility. Flow shall be monitored continually except for the infrequent times when there may be no flow or for infrequent maintenance activities on the flow device. Daily Discharge The discharge of a pollutant measured during a calendar day or any 24-hour period that reasonably represents the calendar day for purposes of sampling. For pollutants measured in units of mass,the "daily discharge"is calculated as the total mass of the pollutant discharged over the day. The "daily discharge" concentration comprises the mean concentration for a 24-hour sampling period as either a composite sample concentration or the arithmetic mean of all grab samples collected during that period. (40 CFR 122.3) Daily Maximum The highest"daily discharge"during the calendar month. Daily Sampling Parameters requiring daily sampling shall be sampled 5 out of every 7 days per week unless otherwise specified in the permit. The Division expects that sampling shall be conducted on weekdays except where holidays or other disruptions of normal operations prevent weekday sampling. If sampling is required for all seven days of the week for any permit parameter(s), that requirement will be so noted on the Effluent Limitations and Monitoring Page(s). DWQ or"the Division" The Division of Water Quality,Department of Environment and Natural Resources. EMC The North Carolina Environmental Management Commission. Facility Closure The cessation of wastewater treatment at a permitted facility,or the cessation of all activities that require coverage under the NPDES. Completion of facility closure will allow this permit to be rescinded. eometric Mean The Nth root of the product of the individual values where N = the number of individual values. For purposes of calculating the geometric mean,values of"0" (or"< [detection level]") shall be considered=1. Grab Sample Individual samples of at least 100 ml collected over a period of time not exceeding 15 minutes. Grab samples can be collected manually. Grab samples must be representative of the discharge (or the receiving stream, for instream samples). Hazardous Substance Any substance designated under 40 CFR Part 116 pursuant to Section 311 of the Clean Water Act. Instantaneous flow measurement A measure of flow taken at the time of sampling,when both the sample and flow will be representative of the total discharge. • Version 6/20/2003 NPDES Permit Requirements Page 3 of 16 Monthly Average(concentration limit) The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar month. In the case of fecal coliform, the geometric mean of such discharges. Permit Issuing Authority The Director of the Division of Water Quality. Quarterly Average (concentration limit) The average of all samples taken over a calendar quarter. Severe property damage Substantial physical damage to property, damage to the treatment facilities which causes them to become inoperable, or substantial and permanent loss of natural resources which can reasonably be expected to occur in the absence of a bypass. Severe property damage excludes economic loss caused by delays in production. Toxic Pollutant Any pollutant listed as toxic under Section 307(a)(1)of the Clean Water Act. Upset An incident beyond the reasonable control of the Permittee causing unintentional and temporary noncompliance with permit effluent limitations and/or monitoring requirements. An upset does not include noncompliance caused by operational error, improperly designed treatment facilities, inadequate treatment facilities, lack of preventive maintenance,or careless or improper operation. Weekly Average(concentration limit) The arithmetic mean of all "daily discharges" of a pollutant measured during the calendar week. In the case of fecal coliform, the geometric mean of such-discharges. Section B. General Conditions 1. Duty to Comply The Permittee must comply with all conditions of this permit. Any permit noncompliance constitutes a violation of the Clean Water Act and is grounds for enforcement action;for permit termination,revocation and reissuance, or modification;or denial of a permit renewal application [40 CFR 122.411 a. The Permittee shall comply with effluent standards or prohibitions established under section 307(a) of the Clean Water Act for toxic pollutants and with standards for sewage sludge use or disposal established under section 405(d) of the Clean Water Act within the time provided in the regulations that establish these standards or prohibitions or standards for sewage sludge use or disposal, even if the permit has not yet been modified to incorporate the requirement b. The Clean Water Act provides that any person who violates section 301,302,306,307,308,318 or 405 of the Act, or any permit condition or limitation implementing any such sections in a permit issued under section 402, or any requirement imposed in a pretreatment program approved under sections 402(a)(3) or 402(b)(8) of the Act,is subject to a civil penalty not to exceed $25,000 per day for each violation. [40 CFR 122.41 (a) (2)] c. The Clean Water Act provides that any person who negligently violates sections 301,302,306,307,308, 318, or 405 of the Act, or any condition or limitation implementing any of such sections in a permit issued under section 402 of the Act, or any requirement imposed in a pretreatment program approved under section 402(a)(3) or 402(b)(8) of the Act,is subject.to criminal penalties of$2,500 to $25,000 per day of violation, or imprisonment of not more than 1 year, or both. In the case of a second or subsequent conviction for a negligent violation, a person shall be subject to criminal penalties of not more than $50,000 per day of violation,or by imprisonment of not more than 2 years,or both. [40 CFR 122.41 (a)(2)] Version 6/20,2003 NPDES Permit Requirements Page 4 of 16 d. Any person who knowingly violates such sections, or such conditions or limitations is subject to criminal penalties of$5,000 to $50,000 per day of violation, or imprisonment for not more than 3 years, or both. In the case of a second or subsequent conviction for a knowing violation, a person shall be subject to criminal penalties of not more than $100,000 per day of violation,or imprisonment of not more than 6 years, or both. [40 CFR 122.41 (a) (2)] e. Any person who knowingly violates section 301,302,303,306,307,308,318 or 405 of the Act,or any permit condition or limitation implementing any of such sections in a permit issued under section 402 of the Act, and who knows at that time that he thereby places another person in imminent danger of death or serious bodily injury, shall,upon conviction, be subject to a fine of not more than $250,000 or imprisonment of not more than 15 years,or both. In the case of a second or subsequent conviction for a knowing endangerment violation,a person shall be subject to a fine of not more than$500,000 or by imprisonment of not more than 30 years, or both. An organization, as defined in section 309(c)(3)(B)(iu) of the CWA, shall, upon conviction of violating the imminent danger provision,be subject to a fine of not more than$1,000,000 and can be fined up to$2,000,000 for second or subsequent convictions. [40 CFR 122.41 (a) (2)] f. Under state law, a civil penalty of not more than $25,000 per violation may be assessed against any person who violates or fails to act in accordance with the terms, conditions, or requirements of a permit. [North Carolina General Statutes § 143-215.6A] g. Any person may be assessed an administrative penalty by the Administrator for violating section 301, 302, 306, 307, 308, 318 or 405 of this Act, or any permit condition or limitation implementing any of such sections in a permit issued under section 402 of this Act. Administrative penalties for Class I violations are not to exceed$10,000 per violation,with the maximum amount of any Class I penalty assessed not to exceed $25,000. Penalties for Class II violations are not to exceed $10,000 per day for each•day during which the violation continues, with the maximum amount of any Class II penalty not to exceed $125,000. [40 CFR 122.41 (a) (3)] 2 Duty to Mitigate The Permittee shall take all reasonable steps to minimize or prevent any discharge or sludge use or disposal in violation of this permit which has a reasonable likelihood of adversely affecting human health or the environment [40 CFR 122.41 (d)]. 3. Civil and Criminal Liability Except as provided in permit conditions on "Bypassing" (Part II. C. 4), "Upsets" (Part II. C. 5) and "Power Failures" (Part II. C. 7), nothing in this permit shall be construed to relieve the Permittee from any responsibilities, liabilities, or penalties for noncompliance pursuant to NCGS 143-215.3, 143-215.6 or Section 309 of the Federal Act, 33 USC 1319. Furthermore, the Permittee is responsible for consequential damages, such as fish kills,even though the responsibility for effective compliance may be temporarily suspended. 4. Oil and Hazardous Substance Liability Nothing in this permit shall be construed to preclude the institution of any legal action or relieve the Permittee from any responsibilities,liabilities, or penalties to which the Permittee is or may be subject to under NCGS 143- 215.75 et seq. or Section 311 of the Federal Act, 33 USG 1321. Furthermore, the Permittee is responsible for consequential damages; such as fish kills, even though the responsibility for effective compliance may be temporarily suspended. 5. Property Rights The issuance of this permit does not convey any property rights in either real or personal property, or any exclusive privileges, nor does it authorize any injury to private property or any invasion of personal rights, nor any infringement of Federal,State or local laws or regulations [40 CFR 122.41 (g)]. 6. Onshore or Offshore Construction This permit does not authorize or approve the construction of any onshore or offshore physical structures or facilities or the undertaking of any work in any navigable waters. Version 6/20P2003 NPDES Permit Requirements Page 5 of 16 7. Severability The provisions of this permit are severable. If any provision of this permit, or the application of any provision of thi permit to any circumstances,is held invalid, the application of such provision to other circumstances, and the remainde of this permit,shall not be affected thereby[NCGS 150B-23]. 8. Duty to Provide Information The Permittee shall furnish to the Permit Issuing Authority,within a reasonable time, any information which the Permit Issuing Authority may request to determine whether cause exists for modifying,revoking and reissuing,or terminating this permit or to determine compliance with this permit. The Permittee shall also furnish to the Permit Issuing Authority upon request,copies of records required by this permit [40 CFR 122.41 (h)]. 9. Duty to Reapply If the Permittee wishes to continue an activity regulated by this permit after the expiration date of this permit, the Permittee must apply for and obtain a new permit [40 CFR 122.41 (b)]. 10. Expiration of Permit The Permittee is not authorized to discharge after the expiration date. In order, to receive automatic authorization to discharge beyond the expiration date, the Permittee shall submit such information, forms, and fees as are required by the agency authorized to issue permits no later than 180 days prior to the expiration date. Any Permittee that has not requested renewal at least 180 days prior to expiration, or any Permittee that does not have a permit after the expiration and has not requested renewal at least 180 days prior to expiration,will subject the Permittee to enforcement procedures as provided in NCGS 143-215.6 and 33 USC 1251 et. seq. 11. Signatory Requirements All applications, reports, or information submitted to the Permit Issuing Authority shall be signed and certified [40 CFR 12241 (k)]. a. All permit applications shall be signed as follows: (1) For a corporation: by a responsible corporate officer. For the purpose of this Section, a responsible corporate officer means: (a) a president, secretary, treasurer or vice president of the corporation in charge of a principal business function, or any other person who performs similar policy or decision making functions for the corporation,or (b) the manager of one or more manufacturing,production, or operating facilities,provided, the manager is authorized to make management decisions which govern the operation of the regulated facility including having the explicit or implicit duty of making major capital investment recommendations, and initiating and directing other comprehensive measures to assure long term environmental compliance with environmental laws and regulations; the manager can ensure that the necessary systems are established or actions taken to gather complete and accurate information for permit application requirements; and where authority to sign documents has been assigned or delegated to the manager in accordance with corporate procedures (2) For a partnership or sole proprietorship: by a general partner or the proprietor,respectively;or (3) For a municipality; State, Federal, or other public agency: by either a principal executive officer or ranking elected official [40 CFR 12222]. b. All reports required by the permit and other information requested by the Permit Issuing Authority shall be signed by a person described in paragraph a. above or by a duly authorized representative of that person. A person is a duly authorized representative only if: 1. The authorization is made in writing by a person described above; 2. The authorization specified either an individual or a position having responsibility for the overall operation of the regulated facility or activity,such as the position of plant manager, operator of a well or well field, superintendent, a position of equivalent responsibility, or an individual or position having overall responsibility for environmental matters for the company. (A duly authorized representative may thus be either a named individual or any individual occupying a named position.);and 3. The written authorization is submitted to the Permit Issuing Authority [40 CFR 12222] Version 620/2003 NPDES Permit Requirements ' Page 6 of 16 c. Changes to authorization: If an authorization under paragraph (b) of this section is no longer accurate because a different individual or position has responsibility for the overall operation of the facility, a new authorization satisfying the requirements of paragraph (b) of this section must be submitted to the Director prior to or together with any reports, information, or applications to be signed by an authorized representative [40 CFR 122.22] d. Certification. Any person signing a document under paragraphs a. or b. of this section shall make the following certification [40 CFR 122.22]: I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.' 12. Permit Actions This permit may be modified, revoked and reissued, or terminated for cause. The filing of a request by the Permittee for a permit modification, revocation and reissuance, or termination, or a notification of planned changes or anticipated noncompliance does not stay any permit condition [40 CFR 122.41 (f)]. 13: Permit Modification.Revocation and Reissuance.or Termination The issuance of this permit does not prohibit the permit issuing authority from reopening and modifying the permit,revoking and reissuing the permit,or terminating the permit as allowed by the laws,rules, and regulations contained in Title 40, Code of Federal Regulations, Parts 122 and 123; Title 15A of the North Carolina Administrative Code,Subchapter 2H .0100;and North Carolina General Statute 143-215.1 et al. 14. Annual Administering and Compliance Monitoring Fee Requirements The Permittee must pay the annual administering and compliance monitoring fee within thirty days after being billed by the Division. Failure to pay the fee in a timely manner in accordance with 15A NCAC 2H.0105 (b) (4) may cause this Division to initiate action to revoke the permit Section C. •Operation and Maintenance of Pollution Controls 1. Certified Operator Upon classification of the permitted facility by the Certification Commission, the Permittee shall employ a certified water pollution control treatment system operator in responsible charge (ORC) of the water pollution control treatment system. Such operator must hold a certification of the grade equivalent to or greater than the classification assigned to the water pollution control treatment system by the Certification Commission. The Permittee must also employ one or more certified Back-up.ORCs who possess a currently valid certificate of the type of the system. Back-up ORCs must possess a grade equal to(or no more than one grade less than) the grade of the system [15A NCAC 8G.0201]. The ORC of each Class I facility must > Visit the facility at least weekly > Comply with all other conditions of 15A NCAC 8G.0204. The ORC of each Class II,III and IV facility must > Visit the facility at least daily,excluding weekends and holidays > Properly manage and document daily operation and maintenance of the facility > Comply with all other conditions of 15A NCAC 8G.0204. Once the facility is classified, the Permittee shall submit a letter to the Certification Commission designating the operator in responsible charge: a. Within 60 calendar days prior to wastewater being introduced into a new system Version 6i20/2003 NPDES Permit Requirements Page 7 of 16 b. Within 120 calendar days of: ➢ Receiving notification of a change in the classification of the system requiring the designation of a new ORC and back-up ORC ➢ A vacancy in the position of ORC or back-up ORC. 2. Proper Operation and Maintenance The Permittee shall at all times provide the operation and maintenance resources necessary to operate the existing facilities at optimum efficiency. The Permittee shall at all times properly operate and maintain all facilities and systems of treatment and control (and related appurtenances) which are installed or used by the Permittee to achieve compliance with the conditions of this permit. Proper operation and maintenance also includes adequate laboratory controls and appropriate quality assurance procedures. This provision requires the Permittee to install and operate backup or auxiliary facilities only when necessary to achieve compliance with the conditions of the permit[40 CFR 122.41 (e)]. 3. Need to Halt or Reduce not a Defense It shall not be a defense for a Permittee in an enforcement action that it would have been necessary to halt or reduce the permitted activity in order to maintain compliance with the condition of this permit [40 CFR 122.41 (c)]. 4. Bypassing of Treatment Facilities a. Bypass not exceeding limitations [40 CFR 122.41 (m) (2)] The Permittee may allow any bypass to occur which does not cause effluent limitations to be exceeded,but only if it also is for essential maintenance to assure efficient operation. These bypasses are not subject to the provisions of Paragraphs b.and c.of this section. b. Notice [40 CFR 122.41 (m) (3)] (1) Anticipated bypass. If the Permittee knows in advance of the need for a bypass, it shall submit prior notice, if possible at least ten days before the date of the bypass; including an evaluation of the anticipated quality and effect of the bypass. (2) Unanticipated bypass. The Permittee shall submit notice of an unanticipated bypass as required in Part II.E. 6. (24-hour notice). c. Prohibition of Bypass (I) Bypass from the treatment facility is prohibited and the Permit Issuing Authority may take enforcement action against a Permittee for bypass,unless: (A) Bypass was unavoidable to prevent loss of life,personal injury or severe property damage; (B) There were no feasible alternatives to the bypass, such as the use of auxiliary treatment facilities, retention of untreated wastes or maintenance during normal periods of equipment downtime. This condition is not satisfied if adequate backup equipment should have been installed in the exercise of reasonable engineering judgment to prevent a bypass which occurred during normal periods of equipment downtime or preventive maintenance;and (C) The Permittee submitted notices as required under Paragraph b. of this section. (2) Bypass from the collection system is prohibited and the Permit Issuing Authority may take enforcement action against a Permittee for a bypass as provided in any current or future system-wide collection system permit associated with the treatment facility. (3) The Permit Issuing Authority may approve an anticipated bypass,after considering its adverse effects,if the Permit Issuing Authority determines that it will meet the three conditions listed above in Paragraph c. (1) of this section. 5. Upsets a. Effect of an upset [40 CFR 122.41 (n) (2)]: An upset constitutes an affirmative defense to an action brought for noncompliance with such technology based permit effluent limitations if the requirements of paragraph b. of this condition are met. No determination made during administrative review of claims that Version 6/20/2003 NPDES Permit Requirements Page 14 of 16 Division a Pretreatment Program for approval per 15A NCAC 2H .0907(a) or modify an existing Pretreatment Program per LSA NCAC 2H.0907(b). 5. ' This permit shall be modified,or alternatively,revoked and reissued,to incorporate or modify an approved POTW Pretreatment Program or to include a compliance schedule for the development of a POTW Pretreatment Program as required under Section 402(b)(8) of the Clean Water Act and implementing regulations or by the requirements of the approved State pretreatment program,as appropriate. Section C. Pretreatment Programs Under authority of sections 307(b) and(c)and 402(b)(8) of the Clean Water Act and implementing regulations 40 CFR Part 403, North Carolina General Statute 143-215.3 (14) and implementing regulations 15A NCAC 2H .0900, and in accordance with the approved pretreatment program, all provisions and regulations contained and referenced in the Pretreatment Program Submittal are an enforceable part of this permit. The Permittee shall operate its approved pretreatment program in accordance with Section 402(b)(8) of the Clean Water Act, the Federal Pretreatment Regulations 40 CFR Part 403, the State Pretreatment Regulations 15A NCAC 2H .0900, and the legal authorities, policies, procedures, and financial provisions contained in its pretreatment program submission and Division approved modifications there of. Such operation shall include but is not limited to the implementation of the following conditions and requirements: 1. Sewer Use Ordinance(SUOl The Permittee shall maintain adequate legal authority to implement its approved pretreatment program. 2. Industrial Waste Survey(IWS) The Permittee shall update its Industrial Waste Survey (IWS) to include all users of the sewer collection system at least once every five years. 3. Monitoring Plan The Permittee shall implement a Division approved Monitoring Plan for the collection of facility specific data to be used in a wastewater treatment plant Headworks Analysis (HWA) for the development of specific pretreatment local limits. Effluent data from the Plan shall be reported on the DMRs (as required by Part II,Section D,and Section E.5.). 4. Headworks Analysis (HWA) and Local Limits The Permittee shall obtain Division approval of a Headworks Analysis (HWA) at least once every five years, and as required by the Division. Within 180 days of the effective date of this permit (or any subsequent permit modification) the Permittee shall submit to the Division a written technical evaluation of the need to revise local limits (ie., an updated HWA or documentation of why one is not needed) [40 CFR 12242]. The Permittee shall develop,in accordance with 40 CFR 403.5(c) and 15A NCAC 2H-.0909, specific Local Limits to implement the prohibitions listed in 40 CFR 403.5(a) and (b) and 15A NCAC 2H .0909. 5. Industrial User Pretreatment Permits (IUP) &Allocation Tables In accordance with NCGS 143-215.1,the Permittee shall issue to all significant industrial users,permits for operation of pretreatment equipment and discharge to the Permittee's treatment works. These permits shall contain limitations, sampling protocols, reporting requirements, appropriate standard and special conditions, and compliance schedules as necessary for the installation of treatment and control technologies to assure that their wastewater discharge will meet all applicable pretreatment standards and requirements. The Permittee shall maintain a current Allocation Table (Al) which snmmarives the results of the Headworks Analysis (HWA) and the limits from all Industrial User Pretreatment Permits (IUP). Permitted IUP loadings for each parameter cannot exceed the treatment capacity of the POTW as determined by the HWA. Version 6,20/2003 NPDES Permit Requirements Page 15 of 16 6. Authorization to Construct(A to C) The Permittee shall ensure that an Authorization to Construct permit (AtC) is issued to all applicable industrial users for the construction or modification of any pretreatment facility. Prior to the issuance of an AtC, the proposed pretreatment facility and treatment process must be evaluated for its capacity to comply with all Industrial User Pretreatment Permit(IUP)limitations. 7. POTW Inspection&Monitoring of their SIUs The Permittee shall conduct inspection, surveillance,and monitoring activities as described in its Division approved pretreatment program in order to determine,independent of information supplied by industrial users,compliance with applicable pretreatment standards. The Permittee must a. Inspect all Significant Industrial Users (SIUs)at least once per calendar year;and b. Sample all Significant Industrial Users (SIUs) at least twice per calendar year for all permit- limited pollutants, once during the period from January 1 through June 30 and once during the period from July 1 through December 31,except for organic compounds which shall be sampled once per calendar year; 8. SIU Self Monitoring and Reporting The Permittee shall require all industrial users to comply with the applicable monitoring and reporting requirements outlined in the Division approved pretreatment program,the industry's pretreatment permit, or in 15A NCAC 2H.0908. 9. Enforcement Response Plan(ERP) The Permittee shall enforce and obtain appropriate remedies for violations of all pretreatment standards promulgated pursuant to section 307(b) and (c) of the Clean Water Act (40 CFR 405 et. seq.),prohibitive discharge standards as set forth in 40 CFR 403.5 and 15A NCAC 2H .0909, and specific local limitations. All enforcement actions shall be consistent with the Enforcement Response Plan (ERP) approved by the Division. 10. Pretreatment Annual Reports (PAR) The Permittee shall report to the Division in accordance with 15A NCAC 2H .0908. In lieu of submitting annual reports, Modified Pretreatment Programs developed under 15A NCAC 2H .0904 (b) may be required to meet with Division personnel periodically to discuss enforcement of pretreatment requirements and other pretreatment implementation issues. For all other active pretreatment programs,the Permittee shall submit two copies of a Pretreatment Annual Report(PAR) describing its pretreatment activities over the previous twelve months to the Division at the following address: NC DENR/DWQ /Pretreatment Unit 1617 Mail Service Center Raleigh,NC 27699-1617 These reports shall be submitted according to a schedule established by the Director and shall contain the following a.) Narrative A brief discussion of reasons for, status of, and actions taken for all Significant Industrial Users (SIUs)in Significant Non-Compliance(SNC); b.) treatment Program Summary(PPS) A pretreatment program.summary(PPS)on specific forms approved by the Division; c.) Significant Non-Compliance Report(SNCR) The nature of the violations and the actions taken or proposed to correct the violations on specific forms approved by.the Division; d) Industrial Data Summary Forms (IDSF) Version 6202003 NPDES Permit Requirements' -' Page 16 of 16 Monitoring data from samples collected by both the POTW and the Significant Industrial User (SIU). These analytical results must be reported on Industrial Data Summary Forms (IDSF) or other specific format approved by the Division; e.) Other Information Copies of the POTW's allocation table,new or modified enforcement compliance schedules, public notice of SIUs in SNC, and any other information, upon request, which in the opinion of the Director is needed to determine compliance with the pretreatment implementation requirements of this permit; 11. Public Notice The Permittee shall publish annually a list of Significant Industrial Users (SIUs) that were in Significant Non-Compliance (SNC) as defined in the Penmittee's Division approved Sewer Use Ordinance with applicable pretreatment requirements and standards during the previous twelve month period. This list shall be published within four months of the applicable twelve-month period. 12. Record Keeping The Permittee shall retain for a minimum of three years records of monitoring activities and results,along with support information including general records,water quality records, and records of industrial impact on the POTW. 13. Funding and Financial Report The Permittee shall maintain adequate funding and staffing levels to accomplish the objectives of its approved pretreatment program. 14. Modification to Pretreatment Programs Modifications to the approved pretreatment program including but not limited to local limits modifications, POTW monitoring of their Significant Industrial Users (SIUs), and Monitoring Plan modifications,shall be considered a permit modification and shall be governed by 15 NCAC 2H.0114 and 15A NCAC 2H.0907.. Version 6/20/2003 O�QF W AT F9oG Michael F.Easley,Governor William G.Ross Jr.,Secretary c No cre t .•me 'a sources " i" *i. O `C '^ree�ivi ins, irector Quality MAR 1 J 2008 March 7, 2008 RON LEWIS WATER MANAGEMENT NC DENR IRO DUKE ENERGY CORPORATION DWQ-Surface Water Protection EC13K PO BOX 1006 CHARLOTTE NC 28202-1006 Subject: Acknowledgement of Permit Modification Request Allen Steam Station NPDES Permit NC0004979 Gaston County Dear Mr. Lewis: The Division of Water Quality, Point Source Branch,acknowledges receipt of your permit modification request with supporting information on February 26, 2008 with payment of check#0002157920, in the amount of$1030.00,dated February 22,2008. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications,the Division requests your assistance in providing a timely and complete response to any additional information requests. Please note at this time,processing permit applications can take al long as 60—90 days after receipt of a complete application. If you have any questions, please contact Jackie Nowell at 919-733-5083 ext. 512 or via email at jackie.nowell@ncrnail.net . If the reviewer is unavailable, you may leave a message,and they will respond promptly. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRES ON THIS PROJECT. Sincerely, curie Singleton Point Source Branch Cc: Central File urface Water Protection Section Permit application file NC0004979 o ee N hCarolina Naturally North Carolina Division of Water Quality 1617 Mail Service Center Raleigh,NC 27699-1617 Phone(919)733-7015 Customer Service Internet: www.ncwaterquality.org Location: 512 N.Salisbury St. Raleigh,NC 27604 Fax (919)733-2496 1-877-623-6748 An Equal Opportunity/Affirmative Action Employer—50%Recycled/10%Post Consumer Paper SOC PRIORITY PROJECT: No To: Permits and Engineering Unit Water Quality Section Attention: Carolyn Bryant Date: January 26, 2005 NPDES STAFF REPORT AND RECOMMENDATIONS County: Gaston NPDES Permit No.: NC0004979 MRO No.: 04-135 PART I- GENERAL INFORMATION 1. Facility and address: Allen Steam Station do Duke Power Company 13339 Hagers Ferry Road Huntersville,N.C. 28078 2. Date of investigation: January 12, 2005 3. Report prepared by: Samar Bou-Ghazale, Environmental Engineer I 4. Person contacted and telephone number: Robert Wylie, (704) 382-4669. 5. Directions to site: From the jct. of Hwy. 7 and SR 2525 (South Point Rd.) in the Town of Belmont,travel south on SR 2525 = 2.5 miles. The entrance to the Allen Steam Plant is on the left(east) side of SR 2525. 6. Discharge point(s), List for all discharge points: - outfall001 outfall002 outfall 002A outfall 002B Latitude: 35° 11' 23" 35° 10' 30" 35° 11' 17" 35° 11' 15" Longitude: 81° 00' 45" 81° 00' 23" 81° 00' 46" 81° 00' 22" outfall 003 outfall 004 outfall 005 Latitude: 35° 11' 24" 35° 11' 15" 35° 11' 24" Longitude: 81° 00' 46" 81° 00' 22" 81° 00' 45" Attach a USGS Map Extract and indicate treatment plant site and discharge point on map. USGS Quad No.: G 14 NE USGS Name: Belmont, NC 7. Site size and expansion area consistent with application: Yes. There is additional area available for expansion, if necessary. Page Two 8. Topography(relationship to flood plain included): The site was graded considerably when built,which removed existing contours. The steam plant is constructed above the high water elevation of Lake Wylie(the receiving stream). The surrounding area has gently rolling topography(slopes<10%). 9. Location of nearest dwelling: Approx. 1000+feet from the steam plant site. 10. Receiving stream or affected surface waters: Catawba River(Lake Wylie)-outfalls 002, 002A, 002B, 004&005. South Fork Catawba River(Lake Wylie)-outfalls 001 & 003. a. Classification: Catawba River, 14443M13,, South Fork Catawba River, WS-VB � I g b. River Basin and Subbasin No.: Catawba 030834 c. Describe receiving stream features and pertinent downstream uses: Outfalls 002, 002A, 002B, 004&005 enter the main segment of the Catawba River(Take Wylie), which is used for primary and secondary recreation and as a receiving stream for point source (NPDES) discharges both upstream and downstream of the steam plant. There are no known municipal water intakes located above or below these outfalls. Outfalls 001 & 003 enter a manmade discharge canal located west of the steam plant. This canal travels for a distance of 1.2 miles where it enters the South Fork Catawba River(an arm of Lake Wylie). This area is also used for primary and secondary recreation and there are no known water intakes from the point of discharge to the mouth of the South Fork of the Catawba River. PART IT-DESCRIPTION OF DISCHARGE AND TREATMENT WORKS Outfall 001 002 002A 002B 003 004 005 L a. Volume of wastewater(MGD): 626.3 20.7 N/A N/A 4.5 6.5 0.003 b. What is the current permitted capacity: No flow limit for any outfall in Permit. c. Actual treatment capacity of current facility(current design capacity): N/A d. Date(s)and construction activities allowed by previous ATCs issued in the previous two years: An Authorization to Construct for the construction of a physical chemical treatment system was issued on June 21, 2004 for the following: 1. Three primary settling cells 2. A Treatment channel 3. A Chemical injection system, and 4. A Final settling/flocculation cell The purpose of this system is to provide chemical injection for treatment of dissolved pollutants that will not settle out of the waste stream through purely Page Three Physical means. The system will treat 18-24 MGD sluice water to reduce the TSS and Selenium to below permit limits. The three primary settling cells will be used to settle the solids(only one operating at a time, while the inactive cells are being cleaned). e. Description of existing or substantially constructed WWT facilities: Outfall 001-Waste stream consists of non-contact cooling water from a system that removes heat from the condensers and other heat exchangers. Each of the 5 units at Plant Allen has two condenser cooling pumps. Outfall 002-Ash Basin. Waste stream consist of chemicals from boiler cleaning procedure and sanitary waste from a septic tank(serving approximately 150 employee). pH adjustment(carbon dioxide, sulfuric acid, and sodium hydroxide) is available at the effluent, if needed. Other sources for wastewater entering the ash basin and discharging at outfall 002 include stormwater runoff from the coal pile area, ash sluice recirculating water system,turbine non-destructive testing, heat exchanger cleaning, condensate polishers, condensate leakage testing, yard drain sump, water treatment system,preheater washes, laboratory wastes, the power house sump (unit 5), and physical chemical treatment system(see d above). Future sources include the waste stream from a selective non-catalytic reduction system(to reduce NO emissions by approximately 30%) and a flue gas desulfurization(FGD) system(for the reduction of SO2 from the stack gas). Outfall 002A-Coal yard sump overflow. An overflow pipe directs flow directly to the Catawba River in the event that all pumps in the coal yard sump failed or redundant power supply could not be activated in a timely manner Outfall 002B -Power house sump overflow. An overflow pipe directs flow directly to the Catawba River in the event that all pumps in the yard sump failed or redundant power supply could not be activated in a timely manner. Outfall 003 -Miscellaneous equipment cooling and seal water. Discharge is to the CCW discharge canal. Outfall 004 - Equipment cooling and intake screen backwash. e)f1 R A2,'t'f - Outfall 005 - f. Description of proposed WWT facilities: See part II, d above. g. Possible toxic impacts to surface waters: This facility has consistently passed toxicity tests required at outfall 002. Various chemicals are used during the cleaning and maintenance of equipment (see list provided with the application package). Page Four h. Pretreatment Program(POTWs only): Not Needed. 2. Residual handling and utilization/disposal scheme: Septage from the septic tank is removed as needed by Stanley Septic Tank Services (permit# SDF-36-04). With the exception of fly ash, no other residuals generation is expected. Duke Power Company has a non-discharge Permit (WQ0003255) for the disposal of fly ash. 3. Treatment plant classification: Class I for outfall 002. Outfalls 001, 003 and 004 do not meet the minimum criteria for a class I rating. 4. SIC Code(s): 4911 Wastewater Code(s): 68, 66 MTU Code(s): 50002 PART III-OTHER PERTINENT INFORMATION 1 Is this facility being constructed with Construction Grant Funds or are any public monies involved(municipals only)? No 2. Special monitoring or limitations(including toxicity)requests: a. Permittee has requested that monitoring be either eliminated or reduced for the following parameters at outfall 002: Barium, BOD, Cadmium, Chromium, Copper, Cyanide,Fecal Coliform,Naphthalene,Nickel, Phenol, Phosphorus, Sulfate and Zinc. MRO staff can support a reduction in the monitoring frequency,however, eliminating all monitoring may not be prudent. Defer to the NPDES Unit for review and comment. b. Permittee has requested continuation of the thermal limitations that are presently in the NPDES permit. (An assessment report of balanced and indigenous populations in Lake Wylie has been submitted by Duke Power with the permit renewal). According to the submitted report, the results of data analyses for fish populations and macroinvertebrates support continuation of the existing permitted thermal limits c. Permittee requests that the current selenium limit be changed from a daily maximum limit to a monthly average limit for the following reason: 40 CFR 131.36 list the Criterion Maximum Cocentration(CMC) and the Criterion Continuous Concentration (CCC) for selenium at 20 ug/1 and 5ug/l, respectively. Since the current selenium limit of 31 ug/1 is based on the CCC value of 5 ug/1,the limit should be expressed as a monthly average value. The Environmental Protection Agency's"Ambient Water Quality Criteria for Selenium-198T'document page 34 and 40 CFR 131.36 also supports this request. Defer to the NPDES Unit for review and comment. 3. Important SOC/JOC or Compliance Schedule dates: N/A 4. Alternative Analysis Evaluation: There are no practicable alternatives for the elimination of any of the existing waste streams. Page Five PART IV-EVALUATION AND RECOMMENDATIONS The permittee is requesting renewal of the subject permit. Changes requested by Duke for this renewal are discussed in Part III,No. 2 (a, b,c) above. Review and approval of these monitoring changes will be necessary by the NPDES Unit. According to Mr. Wylie, The construction of the physical chemical treatment system will be completed by the end of February 2005. Pending review and approval of the WLA and review and approval by P&E, it is recommended that the Permit be renewed as requested. r� /-z-os Signature of Report Date /D• 7).e. 7/-2_ 0-1- Water Quality Regioal Supervisor Date / 401111111111k. d - - _ ' . . , 0 . . ______ _______ I Id • • C`\ 4tSe• 4C11•1122,:I) • 1 `\ \` I` �. w. `\ ``\ ` \ ` \ v� \1\ I,\‘\ l IP.......„... ..,....,...,C•)s\s) • ...... ---‘• , ‘. r . • \,..I s. .A \d\r, .'k • `\`� _. ...\,C.7 1-.1\111 4 1 \ , .- . , \ 1 • L" '1 ---,II:4: ; -... • 1 - \ • • 1 .�,1 f 11...••• I ill 1 • 6), 40 if, a 114 o 1 \ \ • • .o'''''''."- ' ... 1 L• • i CI- \ . 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''''.."-'.-''''. 06. • • eij se 1 ca . se • a • ,.. - - 1146 / II • 0 III , i i •a .1 _ :•. 4ECmig) - 0ZtZ:::1 \4.7,..!._.(.....„..,........„,, ( :i• kç • .-.. i ,. ;11114.1.r6 15,1,1...2-4"..I it 1 _ tt��00 CP • i 1002 -" O • • ... t,,: a % NJ • ''' ''.. ......' I t/(7 .."....".'"' ' .,......;‹7 �;' / • i y 151 ci, ID 1 .:4c ft as i Lira/ /2 4 ? ki t *ss 1111.1 i .... • .., \ ....._/ f ..- 7 • 7:::: , 7.1e I / .ae.+''''", :;"-- _.,/ow,' I F eri, ` il s r.• 401 / // 1, i i • --...... , liggillif % \.1 • r• 1 D i fis , i . ,‘ . . • r �� -� 0/ • /• ; • } `�� N \ LJ� , • e' •• • ' h ♦ : r /� 11 \D 3 • , a i • 1 DUB PraA iSR C' VAHY �__._ j �.� •'� ,J ,--' • ' 7 A! I FN ST=. M STATION 1 f1. / /.A., `�--�1o. �� .., f t USES TOPO MAP OF THE AREA r ! 6's L • i �` 6� \ r. AROUND ALLEN STEAM STATION �'�! % 0 ` �� NPDES PERM ED O UTrALLS • \ %% ) \ \ \ % • t ' 1 \• _...--- \ , i;\ • 4 ' � j \ \ . / i • \ , i \ FIGURE: 11 C'1DGN\ALLENTOPNPDES. DGN 11 /18/2004 03.07:08 PM 1;iiir7'. w a rF9 Michael F.Easley,Governor 64 Q(� A (d North Carolina Department of Environment and Natural Resources p4/S i 1r11; t�f�tr' � ,FAIT c -Dit �� . 1 <�r4 i �� OFFICE II I d November 23,2004 t{• NOV 2 4 2004 -�' Albert Smith,III I Allen Steam Station r, P.O. Box 1006,Mail Code EC11E r SECTIONCharlotte,North Carolina 28201 '; Subject Receipt of permit renewal application NPDES Permit NC0004979 Allen Steam Station Gaston County Dear Mr. Smith: The NPDES Unit received your permit renewal application on November 23,2004. A member of the NPDES Unit will review your application. They will contact you if additional information is required to complete your permit renewal. You should expect to receive a draft permit approximately 30-45 days before your existing permit expires. The requirements in your existing permit will remain in effect until the permit is renewed(or the Division takes other action). If you have any additional questions concerning renewal of the subject permit,please contact me at (919) 733-5083, extension 520. Sincerely, 0...)oulki biu jc-..7r Carolyn Bryant Point Source Branch cc: CENTRAL FILES f rt7o esville r u;t<,4r i i7Yt ., , ,,- NPDES Unit NamNa` Carolina turally North Carolina Division of Water Quality 1617 Mail Service Center Raleigh,NC 27699-1617 Phone(919)733-7015 Customer Service Intemet: h2o.enr.state.nc.us 512 N.Salisbury St Raleigh,NC 27604 FAX (919)733-2496 1-877-623-6748 pliKke PROCUREMENT, CONSTRUCTION AND (Power® REcEIvED VMS A Duke Energy Company Duke Power S Duke P.O Box 1006 November 22, 2004 NOV 2 3 2004 Charlotte, NC 28201-1006 NC DEPT Of E,MRON NIENT Mr. David Goodrich AND NATURAL RESOURCES In Care of: Ms. Carolyn Bryant SOCEREVILLE REGIONAL OFFICE NC DENR/Water Quality/NPDES Unit 512 N. Salisbury Street l� Raleigh, North Carolina 27604 Subject: NPDES Permit Renewal, NC0004979 Allen Steam Station, Gaston County Dear Mr. Goodrich, The subject NPDES permit is scheduled to expire on May 31, 2005. As required by North Carolina Administrative Code (15A NCAC 2H.0105(e)), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the application for renewal, which includes the following items: • EPA Form 1 • EPA Form 2C • EPA Form 2F • Site maps • Supplemental Information to the NPDES Application • The Balanced Indigenous Population(BIP)Report In review of historical monitoring data for outfall 002 many parameters have been continuously measured at very low concentrations or below detection levels. It is therefore requested that these parameters be either eliminated from monitoring requirements or reduced in monitoring frequency. These parameters are as follows: Barium, BOD, Cadmium, Chromium, Copper, Cyanide, Fecal Coliform, Naphthalene, Nickel, Phenol, Phosphorus, Sulfate and Zinc. It is also requested that the current selenium limit is changed from a daily maximum limit to a monthly average limit for the following reason: 40 CFR 131.36 list the Criterion Maximum Concentration (CMC) and the Criterion Continuous Concentration (CCC) for selenium at 20 ug/1 and 5 ug/1, respectively. Since the current selenium limit of 31 ug/1 is based on the CCC value of 5 ug/l, the limit should be expressed as a monthly average value. The Environmental Protection Agency's"Ambient Water Quality Criteria for Selenium— 1987" document.page 34 and 40 CFR 131.36 also supports this request. The attached BIP report shows that the balanced indigenous aquatic community in Lake Wylie is being maintained under the current limits. Accordingly, Duke Energy Corporation requests a continuation of the thermal limitations that are presently in the NPDES permit. www.dukepowet.corn Duke Energy is willing to meet and discuss any of the above items at your earliest convenience. If additional information is needed please contact Robert Wylie at (704) 382-4669. Your cooperation in renewing this NPDES permit is appreciated. Sincerely, Michael A. Ruhe Manager, Environmental Support cc: Mr. Rex Gleason—NCDENR, Moorseville,N.C. 7 Ms. Trish MacPherson—NCDENR, Raleigh, N.C. (BIP Report 3 copies) Attachments Duke PROCUREMENT, CONSTRUCTION AND Power® EH&S A Duke Energy Company Duke Power EC11 E/P.O. Box 1006 Charlotte, NC 28201-1006 November 22, 2004 Mr. David Goodrich In Care of: Ms. Carolyn Bryant NC DENR/Water Quality/NPDES Unit 512 N. Salisbury Street Raleigh, North Carolina 27604 Subject: NPDES Permit Renewal, NC0004979 Allen Steam Station, Gaston County Dear Mr. Goodrich, The subject NPDES permit is scheduled to expire on May 31, 2005. As required by North Carolina Administrative Code (15A NCAC 2H.0105(e)), this permit application for renewal is being submitted at least 180 days prior to expiration of the current permit. Please find enclosed in triplicate, the application for renewal, which includes the following items: • • EPA Form 1 • EPA Form 2C • EPA Form 2F • Site maps • Supplemental Information to the NPDES Application • The Balanced Indigenous Population (BIP) Report In review of historical monitoring data for outfall 002 many parameters have been continuously measured at very low concentrations or below detection levels. It is therefore requested that these parameters be either eliminated from monitoring requirements or reduced in monitoring frequency. These parameters are as follows: Barium, BOD, Cadmium, Chromium, Copper, Cyanide, Fecal Coliform, Naphthalene, Nickel, Phenol, Phosphorus, Sulfate and Zinc. It is also requested that the current selenium limit is changed from a daily maximum limit to a monthly average limit for the following reason: 40 CFR 131.36 list the Criterion Maximum Concentration (CMC) and the Criterion Continuous Concentration (CCC) for selenium at 20 ug/I and 5 ug/1, respectively. Since the current selenium limit of 31 ug/1 is based on the CCC value of 5 ug/1, the limit should be expressed as a monthly average value. The Environmental Protection Agency's "Ambient Water Quality Criteria for Selenium— 1987"document.page 34 and 40 CFR 131.36 also supports this request. The attached BIP report shows that the balanced indigenous aquatic community in Lake Wylie is being maintained under the current limits. Accordingly, Duke Energy Corporation requests a continuation of the thermal limitations that are presently in the NPDES permit. www duke power.corn Duke Energy is willing to meet and discuss any of the above items at your earliest convenience. If additional information is needed please contact Robert Wylie at(704) 382-4669. Your cooperation in renewing this NPDES permit is appreciated. Sincerely, Michael A. Ruhe Manager, Environmental Support cc: Mr. Rex Gleason—NCDENR, Moorseville, N.C. Ms. Trish MacPherson—NCDENR, Raleigh, N.C. (BIP Report 3 copies) Attachments Please print or type in the unshaded areas only (fill-in areas are spaced for elite type,i.e., 12 characters/inch). For Approved.OMB No.2040-0086. Approval expires 5-31-92 U.S.ENVIRONMENTAL PROTECTION AGENCY FORM I. EPA 1.D NUMBER .a � GENERAL INFORMATION S NC0004979 T/A p: Consolidated Permits Program GENERAL + (Read the "General Instructions'before starting.) 1- 2 =" .Y�- • .7.4t13 14 15., LABEL ITEMS - GENERAL INSTRUCTIONS If a preprinted label has been provided,' I. EPA I.D. NUMBER affix it in the designated space.Review the information carefully; if any of it is incorrect;cross through it and enter the III. FACILITY NAME correct data in the appropriate fill-in area below.Also,if any of the preprinted data is �� absent•(the area to the left of the label V. FACILITY PLEASE PLACE LABEL IN THIS SPACE space lists the information that should appear) please provide it in the proper fill-. MAILING LIST in areas) below.If the label is complete and correct you need not complete Items I, Ill,V,and VI(except Vl-B which must be -_ completed regardless). Complete all items VI. FACILITY ' � ' if no label has been proved. Refer to the LOCATION instructions for detaied item descriptions and for the legal authorization under which this data is collected. - II. POLLUTANT CHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the EPA. If you answer"yes"to any questions,you must submit this form and the supplemental from listed in the parenthesis following the question.Mark"X"in the box in the third column if the supplemental form is attached. If you answer"no"to each question,you need not submit any of these forms. You may answer"no"if your activity is excluded from permit requirements;see Section C of the instructions.See also,Section D of the instructions for definitions of bold-faced terms. SPECIFIC QUESTIONS MARK"X" MARK"X" - YES NO FORM SPECIFIC QUESTIONS YES FORM ATTACHED - No ATTACHED A. Is this facility a publicly owned treatment works, B. Does or will- this facility (either existing or+ which results in a discharge to waters of the ❑ ® ❑ proposed) include a concentrated animal ❑ ® ❑ U.S.?(FORM 2A) feeding operation or aquatic animal production facility which results in a discharge 16 r 17 18 to waters of the U.S.?(FORM 28) 19 20 21,. C. Is this facility which currently results in ® ❑ ® D. Is this proposal facility(other than those described ❑ ® ❑ discharges to waters of the U.S. other than in A or B above)which will result in a discharge;„ those described in A or B above?(FORM 2C) 22 23 24 to waters of the U.S.?(FORM 2D? 25 26 27 E. Does or will this facility treat,store,or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes?(FORM 3) ❑ ® ❑ municipal effluent below the lowermost stratum ❑ ® ❑ containing, within one quarter mile of the well bore, underground sources of drinking water? 28 29 30 (FORM 4) 31 32 33 G. Do you or will you inject at this facility any H. Do you or will you inject at this facility fluids for produced water other fluids which are brought to special processes such as mining of sulfer by the the surface in connection with conventional oil or ❑ ® ❑ Frasch process,solution mining of minerals,in ❑ ® ❑ natural gas production, inject fluids used for situ combustion of fossil fuel,or recovery of enhanced recovery of oil or natural gas, or inject geothermal energy?(FORM 4) fluids for storage of liquid hydrocarbons? (FORM 4) 34 35 36 37 38 39 .- I. Is this facility a proposed stationary source J. Is this facility a proposed stationary source which is one of the 28 industrial categories listed which is NOT one of the 28 industrial categories in the instructions and which will potentially emit ❑ ® ❑ listed in the instructions and which will potentially' ❑ ® ❑ 100 tons per year of any air pollutant regulated emit 250 tons per year of any air pollutant under the Clean Air Act and may affect or be regulated under the Clean Air Act and may affect located in an attainment area? FORM 5 40 41 42 or be located in an attainment are? FORM 5 43 44 45 III. NAME OF FACILITY SKIP Allen Steam Station 1 15 16-29 30 69 IV. FACILITY CONTACT A.NAME&TITLE(last,first,&title) B.PHONE(area code&no.) 2 Ruhe, Michael, Manager, Environmental Support (980) 373 3231 15 16 45 46 48 49 51 52 55 V. FACILITY MAILING ADDRESS A.STREET OR P.O.BOX c P.O. Box 1006, Mail Code EC11E 15 16 45 B.CITY OR TOWN C.STATE D.ZIP CODE c Charlotte NC 28201 4 15 16 40 41 42 47 51 VI. FACILITY LOCATION A.STREET, ROUTE NO.OR OTHER SPECIFIC IDENTIFIER c 253 Plant Allen Road 15 16 45 B.COUNTY NAME Gaston 46 70 C.CITY OR TOWN D.STATE E.ZIP CODE F.COUNTY CODE s Belmont NC 28012 15 16 40 I 41 42 47 51 52 54 EPA FORM 3510-1 (8-90) CONTINUED ON REVERSE CONTINUED FROM THE FRONT VII. SIC CODES 4-di•it,in order of•riorit A.FIRST ern`' 'rt��. °'iB.SECOND , c 4911 (specify) 7 (specify) s ,s-- 17 Electric Services s 16 19, C.THIRD :FOURTH (" grot " C (specify) 7 (specify) 7 7 15 16 17 15'= 16 -.19 VIII. OPERATOR INFORMATION A.NAME B.Is the name listed in Item c Duke Energy Corporation (Attention Michael A. Ruhe) VIII-A also the owner? s 18 1s 55 ® YES ❑NO C.STATUS OF OPERATOR(Enter the appropriate letter into the answer box;if"Other,"specify.) D.PHONE_(area code&no.) F=FEDERAL M=PUBLIC(other than federal or state) p (specify) C (980) 373 3231 S=STATE 0=OTHER(specify) Electric Utility A P=PRIVATE 56 15 16 : 18 19 21 22 25 E.STREET OR PO BOX " P.O. Box 1006, Mail Code EC11E 26 55 F.CITY OR TOWN G.STATE H.ZIP CODE IX. INDIAN LAND c Charlotte NC 28201 Is the facility located on Indian lands? 1516 as 42 42 47 51 ID YES NO X. EXISTING ENVIRONMENTAL PERMITS A.NPDES(Discharges to Surface Water) D.PSD(Air Emissions from Proposed Sources) C N ' NC0004979 9 P 8 15 16 17 18 30 15 16 17 18 30 B. UIC(Underground Injection of Fluids E.OTHER(specify) (Specify) C T I c T 8 03757T26 Air Permit 9 U 9 15 16 17 18 30 15 16 17 18 30 C. RCRA(Hazardous Wastes) E.OTHER(specify) (Specify) 9 R I NCD043678937 s T 8 WQ0003255 Ash Reuse Permit 15 16 17 18 30 15 16 17 18 30 XI. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include all springs, rivers and other surface water bodies in the ma. area. See instructions for .recise re.uirements. XII. NATURE OF BUSINESS provide a brief descri•tion Coal fired steam electric generation XIII. CERTIFICATION see instructions I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment. B.SIGNATURE C. DATE SIGNED A. NAME&OFFICIAL TITLE(type or print) B. Albert J. Smith, Ill, Manager, Allen C 7-- ;I/ I0 4 Steam Station / ti�/ � — COMMENTS FOR OFFICIAL USE ONLY C C 15 16 55 EI'A FORM 3510-1 (8-90) C-5? „\\ V ,\/-) Lii i ) V \\..) ,, X.\ .,• LriO ` Aso :.\ pp� < n. j z ,,, , . • . . __, ,., 0 „. ., ,k. \ .,, • ''_.,._.„."• , ,, , _o ,, • •• 4_ ,, ....... , __. ' 1 . , . (_,, z > __. = _ , , ..„,. ....„. \ .0 ..•• • ... , _____ _/, .., „.% 0 _ f __ _;,_. ,, ___._ ... _..„.___._.. • , . .,,,,,_,„,,,._. . .. _. rri. e eq %......... ,,, / \ —..\ \izi__,y): 4104_ o 411t.-1 /LN ....'... ... 600 -4-. f ( § ) \'' e ` ' ' - 8 I/, .. Of gl 4 iiii r 8 --4-1*-:Willi\V/7 2,Ililliglit x°14 44, . ,..,.., ,. ,,,,„ ,......„.,,... . 7. • . ......... \aitd --- — ----:„.. \ I 0 1 .4, livt040 ,,..„ v.- _. 600,J\ .. , , ,,. Im.....„ ... . ''' A ip. J ok„,,,..„---- ::_..1wLw-.---- teams soles ♦♦ •so•••4 - ° GASTO N •'''•�� . . �• ...�-•, COO ,•41111=1111 MI Mt •L. , , 41�� __ OKLENBURC ��� o 1#:/ 44 �k II'V-n (/____:-_--_•-__.(------.\--_----_-_--_.---"-- I I. 7 ../ %I I ___.„IN._,i t\ C34`. -....-•—...s0.i% L°P . ' rn 6/, . uy mil) \ (+� ,I "i d ' c� > % �, 0 z �0O m7 •��0� I a 6•s \A m r y. Z�+ 11JJ o a �� t �(n� ca �� M 11 ��� �a� 1 O v m 0 cn )N..)_..---------- „\ t • T1�D O tl \ a ri. r s�O� z I \----) ' .-- �. � ■ Z /^` l ` -v 7) •� = ` EPA ID Number(Cop}yfrorrr item 1.of Form 1) Forrtr ,ppicrVeti a'. h . . :ty Please type or print in the unshaded areas only' NC0004979 OMB o expires 5-31 �' � �_ �Approval expires 5-3 i-92 ' Form U.S., ENVIRONMENTAL PROTECTION AGENCY APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER (� �� EXISTING MANUFACTURING,COMMERCIAL,MINING AND SILVICUTLRAL OPERATIONS NPDES Consolidated Permits Program I.Outfalll Location 41%, , ,,,rw ..tv,,..,.;,.,.. . ... . ,.,;:... .: .,.......0r4 +. .,F._." . For this outfall,list the latitude and longitude,and name of the receiving water(s) Outfall Latitude Longitude Receiving Water(name) Number,(list) Deg Min Sec Deg Min Sec 001 35 11 22 81 00 44 South Fork River 002 35 10 30 81 00 20 Catawba River 002A 35 11 13 81 00 21 Catawba River 002E 35 11 25 81 ' 00 28 Catawba River 003 35 11 23 81 00 45 South Fork River 004 35 11 13 81 00 21 Catawba River II. Flows,Sources of Pollution,and Treatment Technolo a ies viltf..•F:k ;, •: .k.,AM ,,0,,Au;r- :x;,;,y.,..,,•„k,A x ;,.• A. Attach a line drawing showing the water flow through the facility. Indicate sources of intaKe water,operations contributing wastewater to the effluent and treatment units labeled to correspond to the more detailed descriptions in item B.Construct a water balance on the line drawing by showing average flows between intakes, operations,treatment units,and outfalls.If a water balance cannot be determined(e.g.,for certain mining activities),provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall,provide a description of(1)all operations contributing wastewater to the effluent,including process wastewater,sanitary wastewater,cooling water, and stormwater runoff; (2)the average flow contributed by each operation;and(3)the treatment received by the wastewater. Continue on additional sheets if necessary. 1.Outfall 2.Operations Contributing Flow 3.Treatment Number a.OPERATION (list) b.AVERAGE FLOW a.DESCRIPTION b.LIST CODES FROM TABLE 'r- 2C-1 001 Condenser Cooling 626.3 MGD discharge to 4A Water(Once through surface water non-contact) 002 Ash basin discharge 20.7MGD chemical 2D, 1 U 2K coagulation, 2J, 4A settling, neutralization,ion exchange, surface water discharge 002A Emergency overflow coal Intermittent surface water 4A yard sump discharge 002E Emergency overflow of Intermittent surface water 4A power house sump discharge 003 Miscellaneous once 4.5 MGD surface water 4A through non-contact - discharge cooling water 004 Miscellaneous once 6.5 MGD surface water 4A through non-contact discharge cooling water EPA FORM 3510-2C (Rev. 2-85) Page 1 of 4 CONTINUED ON REVERSE CONTINUED FROM THE FRONT C.Except for storm runoff,leaks,or spills,are any of the discharges described in Items!I-A or B intermittent or seasonal? YES(complete the following table) ❑ NO(go to Section III) 3.FREQUENCY _4. 9A.� •� .x P. 1.OUTFALL 2.OPERATION(s) a.DAYS PER b. a.FLOW RATE, b.TOTAL VOLUME NUMBER CONTRIBUTING FLOW WEEK MONTHS (in mgd) (specify with units '' DUR - PER YEAR - TION (list) (list) (specify1.LONG TERM 2 b 1 LONG TERM 2 MAXIMUM In Ia s ' ER average) (specify AVERAGE _ MAXIMUM YAGE DAILf` �� average) DAILY av,> a .,.v 002A Emergency See See See See supplemental supplemental supplemental supplemental Overflow of coal Information Information Information Information yard sump 002E Emergency See See See See supplemental supplemental supplemental supplemental overflow of power Information Information Information Information house sump III. PRODUCTION A. Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? ® YES(complete Item Ill-B) ❑ NO(go to Section IV) B.Are the limitations in the applicable effluent guideline expressed in terms of production(or other measure of operation)? ❑ YES(complete Item 111-C) ® NO(go to Section IV) C. If you answered"yes"to Item III-B,list the quantity which represents an actual measurement of your level of production,expressed in the terms and units used in the applicable effluent guideline,and indicate the affected outfalls. 1.AVERAGE DAILY PRODUCTION 2.AFFECTED OUTFALLS a.QUANTITY PER DAY b.UNITS OF MEASURE c.OPERATION,PRODUCT,MATERIAL,ETC 1 (list OUtfall numbers) (P fy) NA NA NA NA IV. IMPROVEMENTS A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading, or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. ❑ YES(complete the following table) ® NO (go to Item IV-B) 1.IDENTIFICATION OF CONDITION, 2.AFFECTED OUTFALLS 4.FINAL 3.BRIEF DESCRIPTION OF PROJECT COMPLIANCE DATE AGREEMENT,ETC. a.No b.SOURCE OF DISCHARGE a.REQ- b.PRO- UIRED JECTED B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges)you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate your actual or planned schedules for construction. ❑ MARK"X"IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAM IS ATTACHED EPA FORM 3510-2C (Rev. 2-85) Page 2 of 4 CONTINUED ON PAGE 3 EPA ID Number(Copy from Item 1 of Form 1) CONTINUED FROM PAGE 2 NC0004979 V. INTAKE AND EFFLUENT CHARACTERISTICS A,B,&C: See instructions before proceeding-Complete one set of tables or each outfall-Annotate the outfall number in the space provided. NOTE: Tables V-A,V-B,and V-C are included on separate sheets number V-1 through V-9. D: Use the space below to list any of the pollutants listed in Tables 2c-3 of the instructions,which you know or have reason to believe is discharged or may be discharged from any outfall. For every pollutant you list,briefly describe the reasons you believe it to be present and report any analytical data in your possession. � >.. � � 4 4 1.POLLUTANT 2.�SOURCE ��°1.POLLUTANT• ISOURCE See supplemental information page 23 for a complete list. VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS Is any pollutant listed in Item V-C a substance or a component of a substance,which you currently use or manufacture as an intermediate or final product or byproduct? ❑ YES(list all such pollutants below) ® NO(go to Item VI-B) EPA FORM 3510-2C (Rev. 2-85) Page 3 of 4 CONTINUED ON REVERSE CONTINUED FROM THE FRONT VII. BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? � � ® YES(identify the test(s)and describe their purpose below) ❑ NO(go to Section VIII) Quarterly analysis of Ceriodaphnia Dubia(chronic P/F @ 16%) testing per current permit requirements on outfall 002. VIII. CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? ® YES(list the name,address,and telephone number of,and pollutants ❑ NO(go to Section IX) analyzed by,each such laboratory or firm below) C.TELEPHONE D.POLLUTANTS ANALYZED _A.NAME B.ADDRESS (area code&no.) (list) Prism Laboratories, Springbrook Rd, Charlotte, NC (704) 529-6364 oil and grease, TSS, (NC certification #402) 28224 BOD, VOC, SVOC, total phenolics, sulfide, sulfite, bromide, color MBAS, COD, Florida Radiochemistry 5456 Hoffner Ave, Orlando, FL (407) 382-7733 Total radium/radium Services, Fl 32812 226 certification # 12709 ENO River Labs, (LLC South Alston Ave, Durham, NC (919)-281-4040 dioxin screen 2445) 27713 IX. CERTIFICATION I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. NAME&OFFICIAL TITLE(type or print) B.PHONE NO. (area code&no.) Albert J. Smith, Ill, Manager,Allen:.Steam Station - (704) 829-2500 C.SIGNATURE i D.DATE SIGNED EPA FORM 3510-2C (Rev. 2-85) Page 4 of 4 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 001 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) (if available) d.NO.OF a.Conceit- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen 15 98237.3 1 mg/I lb/Day 3.55 2 Demand(BOO) b.Chemical Oxygen < 50 < 327457.8 1 mg/I lb/Day < 50 2 Demand(COD) c.Total Organic 2.83 18534.1 1 mg/I lb/Day 2.59 2 Carbon(TOC) d.Total Suspended 6 39294.9 1 mg/I lb/Day 9 2 Solids(TSS) e.Ammonia(as N) 0.14 918.9 1 mg/I lb/Day 0.095 2 f.Flow VALUE VALUE VALUE MGD X VALUE 784.8 784.8 626.3 365 g.Temperature VALUE VALUE VALUE VALUE (winter) 40 35 25.3 243 DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 41.7 38.3 37.4 122 DEGREES CELSIUS 25.4 2 .pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.92 ' 1 STANDARD UNITS 7.44 2 PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Conceit- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X < 0.1 < 654.9 1 mg/1 lb/Day 0.11 2 (24959-67-9) b.Chlorine. X 0.07 458.4 1 mg/I lb/Day 0.05 2 Total Residual c.Color X 40 X 1 Std.Units X 30 2 d.Fecal X 1600 X 60.2 X 3 Colonies X 7.5 4 Coliform /100 ml e.Floudde X 0.12 785.9 1 mg/ lb/Day 0.17 2 (16984.48.8) f.Nitrate- X 0.11 720.4 1 mg/I lb/Day 0.13 2 Nitrite(as N) EPA Fore 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 001 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (it available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass +(1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen, Total Organic A 0.18 1047.9 1 mg/I lb/Day 0.32 2 (as N) h.Oil and ' Grease X < 5 < 32745.8 1 mg/ lb/Day < 5 2 1.Phosphorous (as P),Total X 0.02 131.0 1 mg/ lb/Day 0.04 2 (7723-14-0) .Radioactivity (1)Alpha, Total A < 7.80E-02 X 1 pCill X < 2.90E-01 2 (2)Beta, Total X 1.86E+00 X 1 pCi/I X 2.79E+00 2 13.83E-01 (3)Radium, Total X < 0.9 X 1 pCVI X 0.4 2 *0.8 (4)Radium 226,Total X < 0.1 X 1 pCi/I X 0.1 2 S.Sulfate (as SO4) X 7.88 51607.3 1 mg/I lb/Day 7.59 2 (14808-79-8) I.Sulfide (as S) A < 2 < 13098.3 1 mg/I lb/Day < 2 2 71.Sulfite 'as 603) A 1 6549.2 1 mg/I Ib/Day < 2 2 )14265-45.3) Li.Surfactants X < 0.1 < 654.9 1 mg/I lb/Day < 0.1 2 o.Aluminum, Total X 0.39 2554.2 1 mg/I lb/Day 0.387 2 (7429-90-5) p.Barium, otal A 0.024 157.2 1 mg/ lb/Day 0.021 2 440-39-3) Boron, oral A < 0.1 < 654.9 1 mg/I lb/Day < 0.1 2 ,7440.42.8) L.Cobalt, otal A < 0.001 < 6.5 1 mg/I lb/Day < 1 2 7440-48-4) i Iron.Total 7439-89.8) X 0.63 4126.0 1 mg/I lb/Day 0.663 2 .Magnesium, Total X 1.8 11788.5 1 mg/I lb/Day 1.811 2 7439.95.4) .Molybdenum, Dial X 0.002 13.1 1 mg/I lb/Day 0.002 2 ,7439.98.7) .Manganese, Dial A 0.058 379.9 1 mg/I Ib/Day 0.054 2 ,7439-96-5) .Th,Total ,7440-31-5) X < 0.05 < 327.5 1 mg/I lb/Day < 0.05 2 IS.Titanium, Total X 0.031 203.0 1 mg/I lb/Day 0.024 2 r744O-32-13) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 001 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, ' nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony, X < 3 < 19.65 1 ug/I lb/Day < 3 2 Total(7440-36-0) 2M.Arsenic,Total X < 2 < 13.10 1 ugh lb/Day < 2 2 (7440-38-2) 3M.Beryllium, X < 0.5 < 327 1 ugh' lb/Day < 5 2 Total(7440-41-7) 4M.Cadmium, X < 0.5 < 3.27 1 ug/I lb/Day < 5 2 Total(7440-43-9) 5M.Chromium, X < 1 < 6.55 1 ug)I lb/Day 0.685 2 Total(7440-47-3) 6M.Copper,Total X 0.022 144.08 1 mg/I lb/Day 0.011 2 (7440-50-8) 7M.Lead,Total X < 2 < 13.10 1 ugA lb/Day 2.43 2 (7439.92-1) SM.Mercury,Total X < 0.1 < • 0.65 1 ug/I lb/Day < 0.1 2 (7439-97-6) 9M.Nickel,Taal X < 2 < 13.10 1 ugA lb/Day < 2 2 (7440-02-0) 10M.selenium, X < 2 < 13.10 1 ugA lb/Day < 2 2 Total(7782-49-2) 11M.Silver,Total X < 0.5 < 3.27 1 ugA lb/Day < 0.5 2 (7440-22-4) 12M.Thallium, X < 0.002 < 13.1 1 mg/I lb/Day < 0.002 2 Total(7440-28-0) 13M.Zinc,Total X < 0.02 < 130.98 1 mgA lb/Day < 0.02 2 (7440.68.6) 14M.Cyanide, X < 0.002 < 13.10 1 mgA lb/Day < 0.002 2 Total(57-12-5) 15M.Phenols, X < 0.05 < 327.5 1 mgA lb/Day 0.019 - 2 Total UIUXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X NOT DETECTED Dioxin(1764-01-6) EPA Form 3510.2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre-cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration GC/MS FRACTION-VOLATILE COMPOUNDS (2)Mass ANALYSES 1V.Aaolein X < 10Q < 654.92 1 ugh lb/Day < 100 2 (107-02-8) 2V.Aaylon8i8e X < 100 < 654.92 1 ugh lb/Day < 100 2 (107-13-1) 3V.Benzene X < 1 < 6.55 1 ugh lb/Day < 2 2 (71-43-2) 4V.Bia(Chloro- methyl)Ether X (542-88-1) 5V.Bromoform X < 1 < 8.55 1 ugh lb/Day < 2 2 (75-25-2) 6V.Carbon Tetrachloride X < 1 < 8.55 1 ugh lb/Day < 2 2 (58-2335) 7V.Chlorobenzene X - ' < 1 < 6755 I - ugh lb/Day < 2 2 (108-90-7) 8V.Chlorodl- bromomethane X < 1 < 6.55 1 ugh lb/Day < 2 2 (124-48-1) 9V.Chloroe0wne ' X < 2 < 13.10 1 ugh lb/Day < 2 2 (75-00-3) 10V.2-Chloro- ethylviny1 Ether X < 2 < 13.10 1 ug/I lb/Day < 2 2 (110-75-8) 11V.Chloroform X < 1 < 6.55 1 ugh lb/Day < 2 2 (67.68-3) 12V.Dlchloro- branomethane X < 1 < ' 6.55 1 ugh lb/Day < 2 2 (75-27-4) 13V.Dlchloro- difluoremethane X < 2 < 13.10 1 ugh lb/Day < 2 2 (75-51-8) 14V.1,1-Dlchloro• X < 1 < 6.55 1 ugh lb/Day < 2 2 ethane(75-34-3) 15V.1,2-Dchloro- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethane(107.08.2) 18v.1,1-Dichloro- X ' < 1 < 6.55 1 ugh lb/Day < 2 2 ethylene(75-35-4) • 17V.1,2-Dlchlaro- X < 1 < 8.55 1 ugh lb/Day < 2 2 propane(78-87-5) 18V.1,3-Dichloro- X < 1 < 6.55 1 ug/l lb/Day < 2 2 propylene(542-75-8) 19V.Ethytbenzene X < 1 < 6.55 1 ugh lb/Day < 2 2 (100-41-4) 20v.Methyl X < 2 < 13.10 1 ugh lb/Day < 5 2 Bromide(74-83-9) 21V.Methyl X < 2 < 13.10 1 ugh lb/Day < 2 2 Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 001 • 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration 1(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES (ration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X < 2 < 13.1-0 1 ug/I lb/Day < 2 2 Chloride(75.09.2) 23V.1,12,2-Tetra- dloroe9wne X < 1 < 6.55 1 ugh lb/Day < 2 2 (79-34-5) 24V.Tetracbbro- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethylene(127-18-4) 25V.Toluene X < 1 < 6.55 1 ug/I lb/Day < 2 2 (108-88-3) 26V.1,2-Trans- -. Dichloroeth14ene X < 1 < 6.55 1 ugh lb/Day < 2 2 (156-60-5) 27V.1,1,1-Trl- chtoroethane X < 1 < 6.55 1 ugh lb/Day < 2 2 (71-55-6) 28V.1,1.2-Tri- c laroethane X < 1 < 6.55 1 ugh lb/Day < 2 2 (79-00-5) 29V.Trfchlaro- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethylene(79-01-6) 30V.Trichloro- fuorome6wne X < 2 < 13.10 1 ugA lb/Day < 2 2 (75-69-4) 31V.Vinyl X < 2. < 13.10 1 ugh lb/Day < 2 2 Chloride(75014) (ae/MS 1-KAG I ION-ALL)CU(AI'OUNUS 1A.2-ChlorophenoI X < 10 < 65.49 1 ugh lb/Day < 10 2 (95-57-8) 2A.2,4-Dkriloro- X < 10 < 65.49 1 ugh lb/Day < 10 2 phenol(120-83-2) 3A.2,4-Dknethyl- X < 10 ' < 65.49 1 ugh lb/Day < 10 2 phenol(10567.9) 4A.4,6-Dlnitro-0- X < 10 < 65.49 1 ugh lb/Day < 25 2 Cresol(534-52-1) 5A.2,4-Dinitro- X < 10 < 65.49 1 ugh lb/Day < 25 2 phenol(51-28-5) 6k 2-Nitropllend X < 10 < 65.49 1 ugh lb/Day < 10 2 (88.75-5) 7k 4-Nltrophenol X < 10 < 65.49 1 ugh lb/Day < 25 2 (100-02-7) 8A.P-Chloro-M- X < 10 < 65.49 1 ugh lb/Day < 10 2 Cresol(59-50-7) 9A.Pentachioro- X < 10 < 65.49 1 ugh Ib/Day < 25 2 phenol(87-88-5) 10A.Phenol X < 10 < 65.49 1 ugh lb/Day < 10 2 (108-95-2) 11k 2,4,6Tri- - ddorophenol X < 10 < 65.49 1 ugh lb/Day < 10 2 (88-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) Quk- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ad (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 18.Acenaphthene X - < 10 < 65.49 1 ugh lb/Day < 10 2 (83-32-9) 213.Acenaphtytene X < 10, < 65.49 - 1 ugh Ib/Day < 10 2 (208-96-6) 38.Anthracene X < 10 < 65.49 1 ugh lb/Day < 10 2 (120-12-7) 48.Benaalne X < 100 < 654.92 1 ugh lb/Day < 100 2 (92-87.5) 58.Benzy(a) Anthracene X < 10 < 65.49 1 ugh lb/Day < 10 2 (56-55-3) 68.Benzy(a) X < 10 < 65.49 1 (19/1 Ib/Day < 10 2 Pyrene(50-32-8) 78.3,4-3enzo- fluoranthene X < 10 < 86.49 1 ugh lb/Day < 10 2 (205-99-2) 88.Benzy(phi) X < 10 < 65.49 1 ugh) lb/Day < 10 2 Perylene(191.24-2) 9B.Benzy(k) Fluoranthene X < 10 < 65.49 1 KOlb/Day < 10 2 (207-08-9) 108.Bie(2-Chlaro- ethoxyl Methane X < 10 < 65.49 1 ugh lb/Day < 10 2 (111-91-1) 118.BM(2-Chloro- ethyl)Ether X < 10 < 65.49 1 ugh) lb/Day < 10 ' 2 (111-44-4) 12B.Bis(2-Ch loroiso- propyl)Ether X < 10 < 65.49 1 ugh lb/Day < 10 2 (108-60-1) 13B.Ble(2-Ethyl- hexyl)Phehaka X < 10 < 65.49 1 ugA lb/Day 19 2 (117-81.7) 148.4-Bronxr phenyl Phenyl X < 10 < 65.49 1 ugh lb/Day < 10 2 Ether(101-5543) 158.Butyl Benzyl X < 10 < 65.49 1 ugA lb/Day < 10 2 Phthalate(85.68-7) 168.2-Chloro- naphthalene X < 10 < 65.49 1 ugh lb/Day < 10 2 (91-58.7) 178.4-Chloro- phenyl Phenyl X < 10 < 65.49 1 ugh lb/Day < 10 2 Ether(7005-72-3) 188.Chrysene X < 10 < 65.49 i ugh Ib/Day < 10 2 (218-01-9) 198.Dibenzo(a.h) Anthracene X < 10 < 65.49 1 ugh lb/Day < 10 2 (53-70-3) 20B.1,2-Dlchlono- X < 10 < 65.49 1 ugA lb/Day < 10 2 benzene(95-50-1) 218.1,3-Dkhloro- X < 10 < 65.49 1 ugh lb/Day < 10 2 benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 22B.1,4-Dichioro. X < 10 < 65.49 1 ugh lb/Day < 10 2 benzene(106-46-7) 238.3,3-Dlchlaro• benzidine X < id < 65.49 1 ugh lb/Day < 25 2 (91-94-1) 24B.Diethyl - Phthalate X < 10 < 65.49 1 ugh lb/Day < 10 2 (84-66-2) 258.Oimethyl Phthalate X < 10 < 65.49 1 ugh lb/Day < 10 2 (131-11-3) 268.Di1-Butyl Phthalate X < 10 < 65.49 1 ugh lb/Day < 10 2 (84.74.2) 278.2,4-Dtnitro- X < 10-- < 8549 1 ugh Ib7Day < 10 2 toluene(121-14-2) 288.2.6-Dinitro- X < 10 < 65.49 1 ugh lb/Day < 10 2 toluene(606-20-2) 298.Di-N-Octyl Phthalate X < 10 < 65.49 1 ugA lb/Day < 10 2 (117-84-0) 308.1.2-Diphenyl- hydrazine(as Azo- X < 10 < 85.49 1 ugh lb/Day < 10 2 benzene)(122.68-7) 318.Fluoranthene X < 10 < 65.49 1 ugh lb/Day < 10 2 (206-44-0) . 328.Fluorene X < 10 < 65.49 1 ugh lb/Day < 10 2 (86-73-7) 338.Hexachtoro. X < 10 < 65.49 1 ugh lb/Day < 10 2 benzene(118.74-1) - 348.Hesa- chiorobutadieno X < 10 < 65.49 1 ugh lb/Day < 10 2 (87-68-3) 358.Hexachloro- cyciopentadiene X < 10 < 65.49 1 ugh lb/Day < 25 2 (77-47-4) 36B.Hexachloro X < 10 < 65.49 1 ugh lb/Day < 10 2 ethane(67-72-1) 37B.Indeno (1.2,3-cd)Pyrene X < 10 < 65.49 1 ugh lb/Day < 10 2 (193-39-5) 388.Isophorone X < 10 < 65.49 1 ugh lb/Day < 10 2 (78-59-1) 398.Naphthalene X < 10 < 65.49 - 1 ugh lb/Day < 10 2 (91-20-3) 408.Nitrobenzene X < 10 < 65.49 - 1 ugh lb/Day ' < 10 2 (98-95-3) 418.N-Nitro sodimeth 4arnine X < 10 < 65.49 1 ugA lb/Day < 10 2 (62-75-9) 428.N-Nitrosadi- - N-Propylamine X < 10 < 65.49 1 ugh lb/Day < 10 2 (621.64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre• cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quit- sent sent (if available) (If available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (t)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) • 4313.N-NBro- sodiphenytamine X < 10 < 65.49 1 ug/I lb/Day < 10 2 (88-30-6) 448.Phenanthrene X < 10 < 65.49 1 ug/I tb/Day < 10 2 (85-01-8) 458.Pyrene X - < 10 < 65.49 1 ug/l lb/Day < 10 2 (129-00-0) 488.1.2,4-Tr- - - - cNorobeozene X < 10 < 65.49 1 ug/I lb/Day < 10 2 (120.82.1) Cic/M$1-FHAL I KK-rES1!WWUES 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319.84-8) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.delta-BHC X (319-86-8) 8P.Chlordane X (57-74-9) 7P.4.4'-DDT X (50-29-3) 8P.4,4'-DOE X (72-55-9) 9P.4,4'-DDD X (72-54-8) 10P.Dieldrin X (60-57-1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X (76-44-8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5. INTAKE(optional) AND CAS NO. a.re- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) mar- sent sent (if available) (if available) (If available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration ' (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X (53469-21-9) 19P.PC8-1254 X (11097-69-1) 20P.PCB-1221 X (11104-28-2) 21P.PCB-1232 X (11141-16-5) 22P.PCB-1248 X • (12672-29-6) 23P.PCB-1260 X (11096-82-5) 24P.PCB-1016 X (12674-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 002 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen < 3.2 < 715.7 < 3.2 < 715.7 < 2 < 345.5 5 mg/1 lb/Day 3.55 2 Demand(BOO) b.Chemical Oxygen < 20 < 4472.9 1 mg/I lb/Day < 50 2 Demand(COD) c.Total Organic 0.79 176.7 1 mg/I lb/Day 2.59 2 Carbon(TOC) d.Total Suspended 24 5367.5 24 5367.5 8.6 1485.6 13 mg/I lb/Day 9 2 Solids(TSS) a.Ammonia(as N) 0.03 6.7 1 mg/I lb/Day 0.095 2 f.Flow VALUE VALUE VALUE MGD X VALUE 26.8 28.8 20.7 52 g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 20.8 1 DEGREES CELSIUS 25.4 2 I.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.1 . 7.1 6.1 7.1 13 STANDARD UNITS 7.44 2 PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK X 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (d available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X 0.255 57.0 1 mg/I lb/Day 0.11 2 (24959.67-9) b.Chlorine. X < 0.2 < 44.7 1 mg/I lb/Day 0.05 2 Total Residual c.Color X 5 X 1 Std.Units X 30 2 d.Fecal X 2 X 2 1.1 5 Colonies X 7.5 4 Co iform /1tX)ml e.Flourde X 0.37 82.7 1 mg/ lb/Day 0.17 2 (16984.48-8) f.Nitrate- X 0.1 22.4 1 mg/I lb/Day 0.13 2 Nitrite(as N) EPA Form 3510-2C(Rev.2485) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 002 1.POLLUTANT 2.MARK"X* 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g Nitrogen, Total Organic X 0.65 145.4 0.65 145.4 0.17 29.4 3 mg/I lb/Day 0.32 2 (as N) h.OII and Grease A < 5 < 1118.2 < 5 < 1118.2 < 5 < 863.7 5 mg/I lb/Day < 5 2 I.Phosphorous (as P),Total X < 0.01 ' < 2.2 < 0.01 < 2.2 < 0.01 < 1.7 3 mg/I lb/Day 0.04 2 (7723-14-0) I.Radbactivity (1)Alpha, Total X 1.630E+00 X 1 pCUI X < 2.90E-01 2 (2)Beta. Total X 1.620+01 X 1 pCi/I X 2.79E+00 2 (3)Radium. Total X X 1 pCi/I X 0.4 2 (4)Radium 226,Total X < 0.2 < X 1 pCi/I X 0.1 2 k.Sulfate (as SO4) X 71.43 15975.0 71.43 15975.0 59.17 10221.1 5 mg/I lb/Day 7.59 2 (14808.79.8) I.Sulfide (as S) X < 0.05 < 11.2 1 mg/I lb/Day < 2 2 m.Sulfite (as S03) X < 2 < 447.3 1 mg/I lb/Day < 2 2 (1426S4S3) n.Surfactants X < 0.1 < 22.4 1 mg/I lb/Day < 0.1 2 o.Aluminum, Total X 0.2684 60.0' 1 mg/I lb/Day 0.387 2 (7429-90-5) p.Barium, . Total X 0.319 71.3 0.319 71.3 0.246 42.5 5 mg/I lb/Day 0.021 2 (7440-39-3) q.Boron, Total X 0.387 86.6 1 mg/I lb/Day < 0.1 2 (7440-42-8) r.Cobalt, Total X 0.00616 1.4 1 mg/I lb/Day < 1 2 (7440-48-4) s.Iron,Total (7439-89-6) X 0.81 181.2 0.81 181.2 0.16 27.6 13 mg/I lb/Day 0.663 2 I Magnesium, Total X 2.652 593.1 1 mg/I lb/Day 1.811 2 (7439.954) u.Molybdenum, Total X 0.05235 11.7 1 mg/I lb/Day 0.002 2 (7439.98-7) v.Manganese, Total X 0.075 16.8 1 mg/I lb/Day 0.054 2 (7439-96-5) w.Tin,Total (7440-.31-5) X < 0.05 < 11.2 1 mg/I lb/Day < 0.05 2 x.Titanium, Total A 0.022 4.9 1 mg/I lb/Day 0.024 2 (7440-32-6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 002 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (8 available) Quin- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony, X 7.61 1.70 1 ugh lb/Day < 3 2 Total(7440-36-0) 2M.Arsenic,Total X 76.8 17.T8 76 8 17.T8 14 2.42 13 ugh Ib/Day - < 2 2 (7440-38-2) 3M.Beryllium, X < 0.5 < 031 1 ugh I67Day < 5 2 Total(7440-41-7) 4M.Cadmium, X 1.25 0.28 1.25 0.28 0.5 0.09 5 ugh lb/Day < 5 2 Total(7440.43.9) 5M.Chromium, X < 46- < 8.95 < 40 < 8.95 < 40 ' < 6.91 5 ugh 16/Day 0.685 - 2 Total(7440-47-3) 6M.Copper,Tow X -0 026 5.81 0.026 5781 0.01 1.73 25 mg/I lb/Day - 0.011 2 (7440-50-8) 7M.Lead,Total X < 2 ' < 0.45 1 ugh lb/Day 2.43 2 (7439.92.1) 8M.Mercury,Total X ' < 0.1 < - 0.02- ' 1 ugh' Ib7Day < 0.1 - 2 (7439-97-6) 9M.Nickel,Total X 26.64 596 28.64 5796 T6 2.76 ' 5 ug/l ' lb/Day < 2 2 (7440-02-0) 10M.Selenium, X 27.1 6.06 27.1 6.06 12 2.07 25 ugh lb/Day < 2 2 Total(7782-49-2) 11M.Silver.Total X < 0.5 < 0.11 1 ugh lb/Day < 0.5 2 (7440-22-4) 12M.Thallium, X < 0.002 < 0.4 1 mg/I lb/Day < 0.002 2 Total(7440-28-0) 13M.Zinc,Tow X 0.035 7.83 0.035 7.83 0.019 3.28 5 mg/I lb/Day < 0.02 2 (7440-66-6) 14M.Cyanide, X 0.002 0.45 0.002 0.45 < 0.002 < 0.35 5 mg/I lb/Day < 0.002 2 Total(57-12-5) 15M.Phenols. X 0.015 3.4 1 mg/I Ib/Day 0.019 2 Total DIOXIN 2,3,7,8 Tetra DES(.klti't NESUL I b - chlorodkbenm P X NOT DETECTED Dioxin(1764-01.6) EPA Form 3510.2c(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NCo0o4979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre-c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1V.Acroleln X < ' 2U < 4.47 1 ugh lb/Day < 100 2 (107-02-8) 2V.Acrytontbile X < 20' < 4.47 1 ugh lb/Day < 100 2 (107.13-1) 3V.Benzene X __ 0.45 1 ugh lb/Day < 2 2 (71-43-2) 4V.Ma(Chlaa methyl)Ether X (542-88-1) 5V.Bromoform X < 2- < 0.45 - 1 ugh lb/Day < 2 2 (75-25-2) 8V.Carbon -- . Tetrachloride X < 2 < 0.45 1 ugh lb/Day < 2 2 (56-23-5) 7V.Chlorobenzene X < 2 < 0.45 1 ugh lb/Day < 2 2 (108-90-7) 8V.Chlcmdi- , bromomethane X < 2 < 0.45 1 ugh lb/Day < 2 2 (124-48-1) 9V.Chloroethane X < 7 < 0.45 1 ugh 1b7Day < 2 2 (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 2 < 0.45 1 ugh lb/Day < 2 2 (110-75-8) 11V.Chloroform X < 2 < 0.45 1 ugh lb/Day < 2 2 (87.66-3) 12V.Dichloro- bromomethane X < 2 < • 0.45 1 ugA lb/Day < 2 2 (75-27-4) 13V.Dichloro- dreuoromethane X < 2 < 0.45 1 ugh lb/Day < 2 2 (75-51-8) 14V.1,1-Dlchlcro- X < 2 < 0.45 1 ugh lb/Day < 2 2 ethane(75-34-3) 15V.1,2-Dichloro- X < 2 < 0.45 - ethane(107-06-2) 1 t1g/I lb/Day < 2 2 18V.1,1-Dichloro- X < 2 < 0.45 1 ugA lb/Day < 2 2 ethylene(75-35-4) 17V.12-Dichloro- X < 2 < 0.45 1 ugh lb/Day < 2 2 propane(78-87-5) 18V.1,3-Dichloro- X < 2 < 0.45 1 ugh lb/Day < 2 2 propylene(542-75-6) 19V.Ethylbenzene X < 2 < 0.45 1 ugh lb/Day < 2 2(100-41-4) 20V.Methyl X < 5 < 1.12 1 ugh lb/Day < 5 2 Bromide(74-83-9) C1V.Meyl(74-87-3) X < 2 < 0.45 1 ugh lb/Day < 2 2 orideEPA Form 3510-2C(Rev.2-85) PAGE V-a CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quit- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration 1(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES !ration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X < 2 < 0.45 1 ugh - lb/Day < 2 2 Chloride(75-09-2) 23V.1,1,2,2-Tetra- chloroethane X < 2 < 0.45 1 ugh lb/Day < 2 2 (79-34-5) 24V.Tetrachloro- X < 2 < 0.45 1 ugh lb/Day < 2 2 ethylene(127-18-4) 25V.Toluene X - < 2 < 0.45 1 - ugA lb/Day < 2 2 (108-88-3) 26V.1,2-Trans- Dic hloroe hylene X < 2 < 0.45 1 ugh lb/Day < 2 2 (156-60-5) 27V.1,1,1-Trl- adaoetane X < 2 < 0.45 1 ugh lb/Day < 2 2 (71-55-6) 28V.1,1,2-Trl- chloroethane X < 2 < 0.45 1 ugh lb/Day < 2 2 (79-00-5) 29V.Trichtoro- X - < 2 < 0.45 1 ugh ib/Day < 2 2 ethylene(79-01-6) 30V.Trichloro- fluoro nethane X < 2 < 0.45 1 ugh lb/Day < 2 2 (75-69-4) 31V.Vinyl X - < 2. < 0.45 1 ugh lb/Day < 2 2 Chloride(75-01-4) GWMS 1-RA(..I lUh1-ALL)LO NI'UUNUS 1a 2-Chlorophenol X < 10 < 2.24 1 ugh lb/Day < 10 2 (95-57-8) 2A.2,4-Dichloro- X < 10 < . 2.24 1 ugh lb/Day < 10 2 phenol(120-83-2) 3A.2,4-Dunethyl- X < 10 < 2.24 1 ugh lb/Day < 10 2 phenol(105-67-9) 4A.4,6-Dlnluo-0- X < 25 < 5.59 1 ugh lb/Day < 25 2 Cresol(534-52-1) 5A.2,4-Dwtro- X < 25 < 5.59 1 ugh lb/Day < 25 2 phenol(51-28-5) 6A.2-Niwrha phe X < 10 < 2.24 1 ugh lb/Day < 10 2 (BB-75.5) 7k 4-Niaopl,enol X < 25 ' < 5:59 1 ugh lb/Day < 25 2 (103-02-7) BA.P-Chloro-M- -X < TO < Z.24 1 ugh lb/Day < TO 2 Cresol(59-50-7) 9a Pentachloro- X < 25 < 5.59 1 ugh lb/Day < 25 2 phenol(87-86-5) 10A.Phenol X < 10 < 2.24 < 10 < 2.24 < 10 < 1.73 5 ugh lb/Day < 10 2 (108-95-2) 11a 2,4,6-Trl- - adorophend X < 10 < 2.24 1 ugh lb/Day < 10 2 (88-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (If available) Of available) (if available) d.NO.OF a.Concen- b.Mass tl.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.Acenaphthene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (83.32.9) (22B.A tylene X - < 1'� < 224 3 ug/I lb/Day < 10 2 3B.Anthracene X < 10 < 224 1 ug/I lb/Day 4 < 10 2 (120-12-7) 48.Benzldkre X < 80 < 17.89 1 ug/I lb/Day < 100 2 (92-87-5) 5B.Benzo(a) Anthracene X < 10 < 2.24 1 ug/I Ib/Day < 10 2 (56-55-3) 68.Benzo(a) X < 16- < 224 1 ug/I lb/Day < 10 2 Pyrene(50-32-8) 78.3,4-Benzo• . fltwnnthene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (205-99-2) 68.Benzo(ghi) X < 10 < 2.24 1 ug/I lb/Day < 10 2 Perylene(191-24-2) 9B.Benzo(k) ' Fluoranthene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (207-08-9) 10B.BIs(2-Chloro- ethoxyl)Methane X < 10 < 2.24 1 ug/I lb/Day < 10 2 (111-91-1) 11B.Bis(2-Chloro- ethyl)Ether X < 10 < 2.24 1 ug/I lb/Day < 10 2 (111-44-4) 126.81s(2-Chloroiao- grapyl)Ether X < 10 < 2.24 1 ugA lb/Day < 10 2 (108.80-1) 138.Bis(2-Ethy1- hexy0 Phthalate X 170 38.02 1 ug/I lb/Day 19 2 (117-81-7) 14B.4-Bromo- phenylPhenyl X < 10 < 2.24 1 ug/I lb/Day < 10 2 Ether(101-553) 158.Butyl Benzyl X < 10 < 2.24 1 ug/I Ib/Day < 10 2 Phthalate(85-68-7) 168.2-Chloro- naphthalene X < 10 < 2.24 1 ugh lb/Day < 10 2 (91-58-7) 178.4-Chloro- phenylPhenyl X < 10 < 2.24 1 ug/I lb/Day < 10 2 Ether(7005-72-3) 18B.Chrysene X < 10 < 2.24 1 ug/I Ib/Day < 10 2 (218-01-9) 19B.Dibenzo(a,h) Anthracene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (53-70-3) 208.1,2-DIchloro- X < 10 < 2.24 1 ugA lb/Day < 10 2 benzene(95-50-1) 21B.1,3-Dk1Yoro- X < 10 < 2.24 1 ugh lb/Day < 10 2 benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (If available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 228.1.4-Dichloro• X < 10 < 2.24 1 ugh lb/Day < 10 2 benzene(106.46-7) 238.3,3-Dichloro- benzidlne X < 25 < 5.59 1 ugh lb/Day < 25 2 (91-94-1) 248.Diethyl Phthalate X < 10 < 2.24 1 ugh lb/Day < 10 2 (84.66-2) 2513.Dimethyl Phthalate X < 10 < 2.24 1 ugh lb/Day < 10 2 (131-11-3) 268.Di-N-Butyl Phthalate X < 10 < 2.24 1 ugh lb/Day < 10 2 (64-7442) 278.2,4-Dinleo- X < 10 < 2.24 1 ugh lb/Day < 10 2 toluene(121-14-2) 288.2,6-Dinibo- X ' < 16- < 24 toluene(606-20-2) 1 16/Day < 10 2 2913.DIN-Octyl Phthalate X < 10 < 2.24 1 ug/I lb/Day < 10 2 (117-84-0) 308.1.2-Dlphenyl- , hydrazine(as Azo- X < 10 < 2.24 benzene)(122-66-7) 1 Ug/I lb/Day < 10 2 318.Fluoranthene X < 10 < 2.24 1 ugA Ib7Day < 10 2 (206-44-0) • 328.Fluorene X <10 < 2.24 1 ugh Ib7Day < 10 2 (86-73-7) 338.Hexachloro- X < 16-- < 2.24 1 ugh Ib/Day < 10 2 benzene(118-74-1) 34B.Hexa- chlorobutadiene X < 10 < 2.24 1 ugA lb/Day < 10 2 (67.68-3) 358.Hexachloro- cyclopentadlene X < 25 < 5.59 1 ugh lb/Day < 25 2 (77-47.4) 368.Hexadtbro- X < 10 < 2.24 1 ugh lb/Day < 10 2 ethane(67-72-1) 378.Indeno (1.2,3-cd)Pyrene X < 10 < 2.24 1 ugh lb/Day < 10 2 (193-39-5) 388.Isophorone X < 10 < 2.24 1 ugh lb/Day ' < 10 2 (78-59-1) 398.Naphthalene X < 10 < 2.24 1 ugh lb/Day < 10 2 (91-20-3) 408.Nitrobenzene X < 10 < 2.24 1 ugh lb/Day < 10 2 (98-95-3) 418.N-Nitro- sodimethylamine X < 10 < 2.24 1 ugh lb/Day < 10 2 (62-75-9) 428.N-Nitrosodi- - N-Propylamine X < 10 < '2.24 1 ugh lb/Day < 10 2 (621-64-7) EPA Form 3510.2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quit- sent sent Of available) (if available) (if available) d.NO.OF a.Concen- b.Mass d NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 438.N-Nltro- sodiphenylamine X < 10 < 2.24 1 ug/I lb/Day < 10 2 (86-30-6) 44B.Pbenant11rene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (85-01-8) 458.Pyrene X < 10 < 2.24 1 ug/I Ib/Day < 10 2 (129-00-0) 488.1,2,4-Td- chlorobenzene X < 10 < 2.24 1 ugh lb/Day < 10 2 (120-82-1) CiU/MS 1-KAC,I ION'-i''tS I IUL) b 1P.AWAn X ugA lb/Day (309-00-2) 2P.alpha-BIiC X ug/l lb/Day (319.84-8) 3P.beta-BHC X ugh - Ib/Day (315-85-7) 4P.gamma-BHC X ugh lb/Day (58-89-9) 5P.delta-BHC X ugh lb/Day (319-88.8) 6P.Chlordane X (57-74-9) ug/I lb/Day 7P.4,4.-00T X ugh lb/Day (50-29-3) 8P.4,4'-DOE X ugh lb/Day (72-55-9) 9P.4,4-DDD X ugh lb/Day (72-54-8) 10P.Dieldrn X ugh Ib/Day (60-57-1) 11P.aipha-Endosulfan X ugh lb/Day (115-29-7) 12P.bela-Endosulfan ' X ugh lb/Day (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) ugh 14P.Endrin ' X ugh lb/Day (72-20-8) 15P.Endrin Aldehyde X ugh (7421-93-4) 16P.Heptachlor X ugh lb/Day (76 44-8) J EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 • EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- bps- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quit, sent sant (If available) (If available) (If available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor - Epoxide X ug/I lb/Day (1024-57-3) 18P.PCB-1242 X - r ugh - lb/Day (53489-21-9) 19P.PCB-1254 X - ugh lb/Day , (11097-89-1) 20P.PCB-1221 - X • - ug/1 - lb/Day - (11104-28-2) 21P.PCB-1232 X ugh - lb/Day (11141-18-5) 22P.PC8-1248 X - ugh lb/Day lb/Day (12872-29-8) 23P.PCB-1280 X - ugh lb/Day (11096-82-5) 24P.PCB-1018 X ugh lb/Day (12874-11-2) 25P.Toxaphene X i ugh - lb/Day - (8001-35-2) I I EPA Form 3510.2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 003 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen 2 75.1 1 mg/I lb/Day Demand(BOO) b.Chemical Oxygen < 20 < 751.1 1 mg/I lb/Day Demand(COD) c.Total Organic 2.71 101.8 1 mg/I lb/Day Carbon(TOC) d.Total Suspended 17 638.4 1 mg/I lb/Day Solids(7SS) e.Ammonia(as N) 0.07 2.6 1 mg/I lb/Day r.Flow VALUE VALUE VALUE MGD X VALUE 4.5 4.5 4.5 52 g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 20.8 1 DEGREES CELSIUS i.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.91 1 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK-X" 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (If available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X 0.293 11.0 1 mg/I lb/Day (24959-87-9) b.Chlorine. X < 0.2 < 7.5 1 mg/I lb/Day Total Residual c.Color X 15 X 1 Std.Units X X d.Fecal X 22 X 1 Colonies X X Coliform /100 ml e.Floudde X 0.2 7.5 1 mg/I lb/Day (18984-48-8) f.Nitrate- X 0.17 6.4 1 mg/I lb/Day Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V•2 .1, EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 003 • 1.POLLUTANT 2.MARK'X' 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Cancan- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen Total Organic X 0.33 12.4 1 mg/I lb/Day (as N) h.Oil and Grease X < 5 < 187.8 1 mg/I lb/Day i.Phosphorous (as P),Total X 0.03 1.1 1 mg/1 lb/Day (7723-14-0) I.Radioactivity (1)AO% Total X 1.050E+00 X 1 pCN X (2)Beta, Total X 2.220E+00 X 1 pCUI X (3)Radium, Total X < 0.3 < X 1 pCi/I X (4)Radium 226,Total X 0.2 X 1 pCi/I X k.Sulfate (as SO4) X 6.93 260.2 1 mg/I lb/Day (14808-79-8) I.Sulfide (as S) X < 0.05 < 1.9 1 mg/I lb/Day m.Sulfite (as 503) X < 2 < 75.1 1 mg/I lb/Day (14265-45-3) • n.Surfactants X < 0.1 < 3.8 1 mg/I lb/Day o.Aluminum, Total X 0.2228 8.4• 1 mg/I lb/Day (7429-90-5) p.Barium, Total X 0.022 0.8 1 mg/1 lb/Day (7440-39-3) q.Boron, Total X 0.105 3.9 1 mg/I lb/Day (7440-42-8) r.Cobalt, Total X < 1 < 37.6 1 mg/1 lb/Day (7440-48-4) s.Iron.Total (7439-89-6) X 0.503 18.9 1 mg/I lb/Day L Magnesium, Total X 1.775 66.7 1 mg/I lb/Day (7439-95-4) u.Molybdenum, Total X 0.00157 0.1 1 mg/I lb/Day (7439-98-7) v.Manganese, Total X 0.048 1.7 1 mg/1 lb/Day (7439.98-5) w.Tin,Total (7440-31-5) X < 0.05 < 1.9 1 mg/I lb/Day x.Titanium, Total X 0.024 0.9 1 mg/I lb/Day (7440-32-6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 003 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in ' column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony, X < 3 < 0.11 1 ug/I lb/Day Total(744036-0) 2M.Arsenic,Total X < 2 < 0.08 1 ugh Ib/Day ' (7440.38.2) 3M.Beryllium, X < IS5 < 0.02 1 ug/I lb/Day Total(7440-41-7) 4M.Cadmium, X < 0.5 < 0.02 1 ugh lb/Day ' Total(7440-43-9) 5M.Chromium, X - 1.03 - 0.04 1 ugh lb/Day Total(7440-47-3) BM.Copper,Total X - 0.0)6 0.60 - 1 mg/I - Ib/Day (7440.50.8) 7M.Lead,Total X < 2 < 0.08 1 ugh lb/Day (7439.92-1) BM.Mercury,Total X < 0.1 < . 0.00 1 ug/l lb/Day (7439-97-6) 9M.Nickel,Total X < 2 < 0.08 1 ug/I lb/Day (7440-02-0) 10M.Selenium, X < 2 < 0.08 1 ug/l lb/Day Total(7782-49-2) 11M.Silver,Total X < 0.5 < 0.02 1 ug/l lb/Day (7440-22-4) 12M.Thallium, X < 0.002 < 0.1 1 mg/I lb/Day Total(7440-28-0) 13M.Zinc,Total X < 0.02 < 0.75 1 mg/I lb/Day (7440.66-6) 14M.Cyanide, X 0.002 0.08 1 mg/I lb/Day Total(57-12-5) 15M.Phenols, X 0.093 3.5 1 mg/I lb/Day Total 1JIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X NOT DETECTED Dioxin(1764-01.6) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre-cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1V.Acroleln X < 20 < 0.75 1 ug/I lb/Day (107-02-8) 2V.Acrylonitrue X < 20 ' < 0.75 1 ugA lb/Day (107-13-1) 3V.Benzene X < 2 < 0.08 1 ug/I lb/Day (71-43-2) 4V.BM(Chloro- methyl)Ether X (542-88-1) 5V.Bromofonn X < 2 < 0.08 1 ugA lb/Day (75-25-2) 6V.Carbon Tetrachloride X < 2 < 0.08 1 ugA lb/Day (56-23-5) 7V.Chlorobenzene X < 2 < 0.08 1 ugA - lb/Day (108.90.7) By.Chlorodi- bromomethane X < 2 < 0.08 1 ugA lb/Day (124-48-1) 9V.Chloroethane X < 2 < 0.08 1 ug/I lb/Day (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 2. < 0.08 1 ugA lb/Day (110-75-8) 11V.Chloroform X < 2 < 0.08 1 ugA lb/Day (67-08-3) 12V.Dichloro- • bromomethane X < 2 < 0.08 1 ugA lb/Day (75-27-4) 13V.Dichloro- dieuoromethane X < 2 < 0.08 1 ugA lb/Day (75-51-8) 14V.1,1-Dlchloro. X < 2 ' < 0.08 1 ugA lb/Day ethane(75-34-3) 15V.1,2-Dichtoro- X < 2 < 0.08 1 ugA lb/Day ethane(107-06-2) 16V.1,1•Dichioro- X < 2 < 0.08 1 ugh lb/Day ethylene(75-35-4) 17V.12-Dichloro- X < 2 < 0.08 1 ugA lb/Day propane(78-87-5) 18V.1,3-Dichloro. X < 2 < 0.08 1 ugA lb/Day propylene(542-75-6) 19V.Ethylbenzene X < 2 < 0.08 1 ugh lb/Day (100-41-4) 20V.Methyl X < 5 < 0.19 1 ugA lb/Day Bromide(74-83-9) 21V.Methyl X < 2 < 0.08 1 ugA lb/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER • CONTINUED FROM PAGE V-4 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration 1(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X < 2 < 0.08 1 ugh lb/Day Chloride(75-09-2) 23V.1.1,2.2-Tetra- chloroethane X < 2 < 0.08 1 ug/I lb/Day (79-34-5) 24V.Tetrachloro- X < 2 < 0.08 1 ug/I lb/Day ethylene(127-18-4) 25V.Toluene X < 2 < 0.08 1 ug/I lb/Day (108-88-3) 26V.1.2-Trans- Dl hloroethylene X < 2 < 0.08 1 ug/I lb/Day (156-60-5) 27V.1,1,1-Trl- ' chtoroethane X < 2 < 0.08 1 ug/I lb/Day (71-55 6) 28V.1,1,2-Tri- chtoroethane X < 2 < 0.08 1 ug/1 lb/Day (79-00-5) 29V.Trichloro- X < 2 < 0.08 1 ug/I lb/Day ethylene(79-01-6) 30V.Trichloro- fluoromethane X < 2 < 0.08 1 ug/I lb/Day (75-69-4) 31V.Vinyl X < 2• < 0.08 1 ug/I lb/Day Chloride(75-01-4) Zi(./MS 1-NAL I I V IJ-ACI-)CO VI I-V UNUS 1A.2-Chlorophenol X < 10 < 0.38 1 ug/I lb/Day (95557-8) - 2A 2,4-Dichloro- X < 10 < 0.38 1 ug/I lb/Day phenol(120.83-2) 3k 2.4-Dimethy- X < 10 < 0.38 1 ug/I lb/Day phenol(105-67-9) 4A.4,6-Dlnitro-O- X < 25 < 0.94 1 ug/I lb/Day Cresol(534-52-1) 5A.2,4-Dinitro- X < 25 < 0.94 1 ug/I lb/Day phenol(51-28-5) BA.2-Nitraphenol X < 10 < 0.38 1 ug/I lb/Day (88-75-5) 7A.4-Nitrophenol X < 25 < 0.94 1 ugA lb/Day (100-02-7) 8AA P-Chtaro-M- X < 10 < 0.38 1 ug/I lb/Day Cresol(59-50-7) 9A.Pentachloro- X < 25 < 0.94 1 ug/I lb/Day phenol(87-86-5) 10A.Phenol X < 10 < 0.38 1 ug/I lb/Day (108.95-2) 11A.2.4.6-Tri- chiorophenol X < 10 < 0.38 1 ug/I lb/Day (88-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. ore- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) gull, sent sent (if available) (if available) (If available) d.NO.OF a.Concen- b.Mass O.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 18.Acenapbanene X < 10 < 0.38 1 ugh lb/Day (83-32-9) 26.Acenaphtblete X < i( < 0.38 1 ugA lb/Day (208-98-8) 38.Anthracene X -. < 10 < 0.38 1 ugh) lb/Day (120.12.7) 4B.Benzidine X < 80 < 3.00 1 ugh lb/Day (92-87-5) 58.Benzo(a) Anthracene X < 10 < 0.38 1 ugh) lb/Day (56-55-3) 68.Benzo(a) X < 10 < 0.38 1 ugh lb/Day Pyrene(50.32-8) 7B.3,4-Benzo- - - Ituoranthene X < 10 < 0.38 1 ugh lb/Day (205-99-2) 88.Bono(phi) X < 10 < 0;38 1 ugh lb/Day Perytene(191.24-2) ' 96.Benzo(k) Fluoranthene X < 10 < 0.38 1 ugh) lb/Day (207.08.9) 108.Bis(2-Chloro- ethoxy)Methane X < 10 < 0.38 1 ug/I lb/Day (111-91-1) 1113.BM(2-Chioro- ethyl)Ether X < 10 < 0.38 1 ugh lb/Day (111-44-4) 128.Bis(2-CAloroiso- propyl)Ether X < 10 < 0.38 1 ugh) lb/Day (168.60-1) • 138.BM(2-Ethyl. ' hexy)Phthalate X < 36 < 1.35 1 ug/I lb/Day (117-81-7) 148.4-Bromo- phenyl Phenyl X < 10 < 0.38 1 ugh) lb/Day Ether(101-563) 158.Butyl Benzyl X < 10 < 0.38 1 ug/l lb/Day Phthalate(85.68.7) 168.2-Chioro- naphthalene X < 10 < 0.38 1 ugA lb/Day (91-58-7) 178.4-Chloro- phenyl Phenyl X < 10 < 0.38 1 ugA lb/Day Ether(7005.72-3) 18B.Chrysene X < 10 < 0.38 1 ug/I lb/Day (218-01.9) 198.Dlbenz°(a,h) Anthracene X < 10 < 0.38 1 ug/I lb/Day (53-70-3) 208.1,2-Dichionr X < 10 < 0.38 1 ug/l lb/Day benzene(95-50-1) 218.1,3-Dichloro- X < 10 < 0.38 1 ugh) - lb/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V.6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) auk- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration ) (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 228.1,4-Dichloro• X < 10 < 0.38 1 ugh lb/Day benzene(106-46-7) 238.3,3-0Khforo- benzidine X < 10 < 0.38 1 ug/I lb/Day (91-94-1) 248.Diethyl Phthalate X < 10 < 0.38 1 ugh lb/Day (84-66-2) 25B.Dtmethyl Phthalate X < 10 < 0.38 1 ugh lb/Day (131-11-3) 268.DiI-Butyl Phthalate X < 10 < 0.38 1 ug/I lb/Day (84-74-2) 278.2,4 Dlnitro- X < 10 < 6.38 - 1 ugh lb/Day ' toluene(121-14-2) 288.2,6-Dwtro- X < 10 < 0.3r 1 ugh lb/Day toluene(606-20-2) 29B.DI-N-Octyl Phthalate X < 10 < 0.38 1 ugh lb/Day (117-84-0) 30B.1,2-Diphenyl- - hydrazine(as Azo- X < 10 < 0.38 1 ug/I lb/Day benzene)(122-66-7) 31B.Fluoranthene X < TO < 0.38- 1 ugh lb/Day (206-44-0) 328.Fluorene X < 10 ' < 0.38 1 ugh lb/Day (86-73-7) 338.Hexachloro- X < 10 < 0.38 1 ugh lb/Day benzene(118.74-1) 348.Hesa- chlorobutadlene X < 10 < 0.38 1 ugh lb/Day (87-68-3) 358.Hexaddoro- cyclopentadiene X < 25 < 0.94 1 ug/I lb/Day (77-47-4) 368.Hexachloro- X ' < 10 < 0.38 1 ugh lb/Day ethane(67.72-1) 37B.Indeno (1,2,3-cd)Pyrene X < 10 < 0.38 1 ugh lb/Day (193-39-5) 388.Isophorone X < 10 < 0.38 1 ug/I lb/Day (7fi-59-1) 398.Naphthalene X < 10 < 0.38 1 - ugh lb/Day (91-20-3) 40B.Nitrobenzene X < 10 < 0.38 1 - ugh lb/Day - (98-95-3) 41B.N-Nitro- sodimethylamine X < 10 < 0.38 1 ugh lb/Day (62-75-9) 428.N-Nitrosodl- N-P opytamine X < 10 < 0.38 1 ugh lb/Day (821.64-7) • EPA Farm 3510.2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (if available) (if available) (If available) d.NO.OF a.Concert- b.Mass d.NO.OF ea (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES !ration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 438.N-Nitro sodiphenylamine X < 10 < 0.38 1 (88-30-6) 448.Phenanthrene X < 10 < 0.38 1 (85-01-8) 458.Pyrene X < 10 < 0.38 1 (129-00-0) 488.1,2,4-Td- ctorobenzene X < 10 < 0.38 1 (120-82-1) CIL/MS I-KAL,I wrf-Fta I IuUES 1P.Alddn X (309-00-2) 2P.alpha-BHC X (319-84-8) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.delta-BHC X (319.88.8) BP.Chlordane X (57-74-9) 7P.4,4-DOT X (50-29-3) 8P.4,4-DDE X (72-55-9) 9P.4,4'-D00 - X (72-54-8) 10P.Dleldrin X (80-57-1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X(72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 18P.Heptachlor X (78.44.8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) puir• sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration GC/MS FRACTION-PESTICIDES(continued) (z)Mass ANALYSES 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X (53489.21-9) 19P.PCB-1254 - X ' (11097-89-1) 20P.PCB-1221 X (11104-28-2) 21P.PC8-1232 ' X (11141-16-5) 22P.PCB-1248 ' X • (12672-29-8) 23P.PCB-1260 X (11098.82-5) 24P.PCB-1016 ' X ' (12674-11-2) _ 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 004 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen 6 325.5 1 mg/I lb/Day Demand(BOD) b.Chemical Oxygen < 20 < 1084.9 1 mg/I lb/Day Demand(COD) c.Total Organic < 20 < 1084.9 1 mg/I lb/Day Carbon(TOC) d.Total Suspended 8 433.9 1 mg/I lb/Day Solids(TSS) a.Ammonia(as N) 0.08 4.3 1 mg/I lb/Day f.Flow VALUE VALUE VALUE MGD X VALUE 6.5 6.5 6.5 52 g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 20.3 1 DEGREES CELSIUS , I.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 7.2 1 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK•x• 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X 0.247 13.4 1 mg/I lb/Day (24959.67-9) b.Chlorine, X < 0.25 < 13.6 1 mg/I lb/Day Total Residual c.Color X 20 X 1 Std.Units X d.Fecal X 26 X 1 Colonies X Coliform /100 ml e.Floudde X 0.19 10.3 1 mg/Ilb/Day ' (16984-48-8) f.Nitrate- X 0.18 8.7 1 mg/I lb/Day Nitrite(as N) EPA Form 3510-2C(Rev.2435) PAGE V-1 CONTINUE ON PAGE V-2 k, EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 004 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen, Total Organic X 0.42 22.8 1 mgA lb/Day (as N) h.Oil and Grease X < 5 < 271.2 < 5 < 271.2 < 5 < 271.2 5 mgA lb/Day I.Phosphorous (as P),Total X 0.05 2.7 1 mgA lb/Day (7723-14-0) 1.RadloactivrCy (1)Alpha, Total X < -2.60E-01 < X 1 pCiA X (2)Bela, Total X 1.99E+00 X 1 pCi/I X (3)Radium, Total X < 0.3 < X 1 pCUI X (4)Radium 226,Total X < 0.2 < X 1 pCUI X ic Sulfate (as SO4) X 8.72 473.0 1 mgA lb/Day (14808-79-8) I.Sulfide (as S) X < 0.05 < 2.7 1 mg/I lb/Day m.Sulfite (as 803) X < 2 < 108.5 1 mg/I lb/Day (14265-45-3) • n.Surfactants X < 0.1 < 5.4 1 mg/I lb/Day o.Aluminum, Total X 0.2455 13.3- 1 mg/I lb/Day (7429-90-5) p.Barium, Total X 0.019 1.0 1 mg/I lb/Day (7440.39-3) q.Boron, Total X < 0.1 < 5.4 1 mgA lb/Day (7440-42-8) r.Cobalt, Total X < 1 < 54.2 1 mgA lb/Day (7440-48-4) s.Iron,Total (7439-89-6) X 0.527 28.8 1 mg/I lb/Day t.Magnesium, Total X 1.924 104.4 1 mgA lb/Day (7439-95-4) u.Molybdenum, Total X 0.00138 0.1 1 mg/I lb/Day (7439-98-7) v.Manganese. - Total X 0.071 3.9 1 mgA lb/Day (7439-96-5) w.Tin,Total (7440-31-5) X < 0.05 < 2.7 1 mgA lb/Day x.Titanium, Total X 0.017 0.9 1 mg/I lb/Day (7440.32.6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER • CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 004 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, , nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ea (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony, X < 3 < 0.16 1 ug/I lb/Day - Total(7440.38-0) 2M.Arsenic,Total X < 2 < 0.11 1 ugh lb/Day (7440-38-2) 3M.Beryllium, X < 0.5 < 0.03 1 ug/I lb/Day Total(7440-41-7) 4M.Cadmium, X < 0.5 < 0.03 1 ug/I lb/Day Total(7440-43-9) 5M.Chromium, X < 1 < 0.05 1 ug/I lb/Day Total(7440-47-3) 6M.Copper,Total X 0.007 0.38 1 mg/I lb/Day (7440-50-8) '7M.Lead,Total X < 2 < 0.11 1 ugh lb/Day (7439-92-1) 8M.Mercury,Total X < 0.1 < - 0.01 1 ugA lb/Day (7439-97-6) 9M.Nickel,Total X < 2 < 0.11 1 ugh lb/Day (7440-02-0) 10M.Selenium, X < 2 < 0.11 1 ugh lb/Day Total(7782-49-2) 11M.Silver,Total X < 0.5 < 0.03 1 ugA lb/Day (7440.22-4) 12M.Thallium, X < 0.002 < 0.1 1 mgA lb/Day Total(7440-28-0) 13M.Zinc,Total X < 0.02 < 1.08 1 mgA Ib/Day (7440.86.6) 14M.Cyanide, X < 0.002 < 0.11 1 mgA lb/Day Total(57-12-5) 15M.Phenols, X 0.028 1.5 1 mg/I lb/Day Total lJl VXIN 2,3,7,8 Tetra 13631,1411sl=IhWUL 18 cttlorodibenzo P X NOT DETECTED Dioxin(1764-01-6) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 004 1.POLLUTANT 2.MARK''X'' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre-cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration GC/MS FRACTION-VOLATILE COMPOUNDS (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES 1V.Acrolain X < ' 2U < 1.08 1 ug/I lb/Day (107-02-8) 2V.Acryloruvue X < 2U < 1.08 1 ug/I lb/Day (107-13-1) 3V.Benzene X < 2 < 0.11 1 ug/I lb/Day (71-43-2) 4V.BB(Chioro- ' methyl)Ether X (542-88-1) 5V.Bromolorm X <-- < 0.11 1 ug/I lb/Day (75-25.2) 6V.Carbon Tetrachloride X < 2 < 0.11 1 ug/I lb/Day (56-23-5) 7V.Chiorobenzene X < 2 < 0.11 1 ugh lb/Day (108-90-7) 8V.Chiorodl- bromomethane X < 2 < 0.11 1 ugA lb/Day (124-48-1) 9V.Chloroethane X < 2 < 0.11 1 ug/I lb/Day (75-00-3) 10V.2-Chloro- ethytvinyl Ether X < 2 < 0.11 1 ug/I lb/Day (110-75-8) 11V.Chloroform X < 2 < 0.11 1 ug/I lb/Day (67-6a8.3) 12V.Dichioro- Ixomome0wne X < 2 < 0.11 1 ug/I lb/Day (75-27-4) 13V.Dichloro- dinuoromethane X < 2 < 0.11 1 ug/I lb/Day (75-51-8) 14V.1,1-Dichloro- X < 2 < 0.11 1 ug/I lb/Day ethane(75-34-3) 15v.1,2-13khioro- X < 2 < 0.11 1 ug/I lb/Day ethane(107-06-2) 16V.1,1-Dichloro• X < 2 < 0.11 1 ug/I lb/Day ethylene(75-35-4) 17V.1,2-Dichloro- X < 2 < 0.11 1 ug/I lb/Day propane(78-87-5) 18V.1,3-Dichloro- X < 2 < 0.11 1 ug/I lb/Day propylene(542-75-6) 19V.Ethylbenzene X < 2 < 0.11 1 ugA lb/Day (100-41.4) 20V.Methyl X ' < b < 0.27 1 ug/I lb/Day Bromide(74-83-9) 21V.Methyl X < 2 < 0.11 1 ug/I lb/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (If available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration 1(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X < 2 < 0.11 1 ugh lb/Day Chloride(75A9-2) 23V.1,1,2,2-Tetra- chloroethane X < 2 < 0.11 1 ug/I lb/Day (79-34-5) 24V.Tetrachloro- X < 2 < 0.11 1 ugA lb/Day ethylene(127-18-4) 25V.Toluene X < 2 < 0.11 1 ugA lb/Day (108.88-3) 26V.1.2-Trans- Dichloroethy1ene X < 2 < 0.11 1 ugA lb/Day (156-60-5) 27V.1,1,1-Tri- chloroethane X < 2 < 0.11 1 ugA lb/Day (71-55-6) 28V.1,1,2-T1- - chloroethane X < 2 < 0.11 1 ugA lb/Day (79-00-5) 29V.Trichloro- X < 2 < 0.1 f ' 1 ugA Ib/Day ethylene(79-01-6) 30V.Trichloro- f uoromethane X < 2 < 0.11 1 ugA lb/Day (75.89-4) 31V.Vinyl X < 2, • < 0.11 1 ugA lb/Day Chloride(75-01-4) GC/MS I-NAC I Rig-AU)CO VIYUUNDS 1a 2-Chlorophenol X < 10 < 0.54 1 ugA lb/Day (95-57-8) 2A.2.4-Dichloro- X ..--<-----T0 < 1 ugA lb/Day phenol(120-83-2) 3A.2,4-Dimethyt- X < 10 < 0.54 1 ugA lb/Day phenol(105-67-9) 4A.4,6-Dinitro-0- X < 25 < 1.36 1 ugA lb/Day Cresol(534-52-1) 5a 2,4-Dinitro- X < 25 < 1.36 1 ugA lb/Day phenol(51-28-5) 6a 2-Nitrophenol X < 10 < 0.54 1 ugh) lb/Day (88-75-5) 7A.4-Nitrophenol X < 25 < 1.36 1 ugA lb/Day (100-02-7) 8a P-Chloro-M- X < 10 < 0.54 1 ugA Ib/Day ' Cresol(59-50-7) 9a Pentadtlor- X < 25 < 1.36 1 ugA Ib/Day phenol(87-86-5) 10A.Phenol X < 10 < 0.54 1 ugA lb/Day (108-95-2) 11k 2,4,6-Td- - chto ophenol X < 10 < 0.54 1 ugh lb/Day (88-06-2) EPA Fomi 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 a • EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quk- sent sent (if available) (If available) (if available) O.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1E1.Acartaphthene X < 10 < 0.54 1 ugh Ib/Day (8332-9) 28.Acenaphtytene X < 10 ' < 0.54 1 ugh lb/Day (208-96-8) 38.Anthracene X < 10 < 0.54 1 ugh lb/Day (120-12-7) 4B.Benzldine X < 80 < 4.34 1 ugh lb/Day (92-87-5) 58.Benzo(a) Anthracene X < 10 < 0.54 1 ugh lb/Day (56-55-3) 68.Benzo(a) X < 10 < 0.54 1 ugh lb/Day Pyrene(50.32-8) 78.3,4-Benzo- nuaranthene X < 10 < 0.54 1 ugh lb/Day (205-99-2) 88.Benzo(phi) X < 10 < 0.54 i ugh Lb/Day Perylene(191-24-2) 98.Benzo(k) Fluorantene X < 10 < 0.54 1 ugh lb/Day (207-08-9) 108.Ble(2-Chlaro- ethoxyl)Methane X < 10 < 0.54 1 ugh lb/Day (111-91-1) 11B.Be(2-Chloro- ethyl)Ether X < 10' < 0.54 1 ugh lb/Day (111-44-4) 12B.Bia(2-CMorolso• prom()Ether X < 10 < 0.54 1 ugh lb/Day (108-60-1) • 138.Be(2-Ethyl- hexyl)Phehalate X 18 0.98 1 ugh lb/Day (117-81-7) 148.4-Bromo- phenyl Phenyl X < 10 < 0.54 1 ugh lb/Day Ether(101-55-3) 158.Butyl Benzyl X < 10 < 0.54 4 1 ugh lb/Day Phthalate(85.88-7) 168.2-Chloro- naphthalene X < 10 < 0.54 1 ugh lb/Day (91-58-7) 178.4-Chloro- phenyl Phenyl X < 10 < 0.54 1 ugh lb/Day Ether(7005.72-3) 188.Chryeene X < 10 < 0.54 1 - ugh lb/Day (218-01-9) 198.Dibenzo(a,h) ' Anthracene X < 10 < 0.54 1 ugh lb/Day (53-70-3) 208.1,2-Dichloro- X < 10 < 0.54 - 1 ugh lb/Day benzene(95.50.1) 21B.1,3-Dichloro- X < 10 < 0.54 1 ugh lb/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (If available) (if available) (If available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 228.1,4-Dichloro- X < 10 - < 0.54 1 ugh lb/Day benzene(108-46-7) 238.3,3-Dichioro- benzidine X < 10 < 0.54 1 ugA lb/Day (91-94-1) 248.Diethyl - , Phthalate X < 10 < 0.54 1 ugA lb/Day (84-68.2) 258.Dimethyl Phthalate X < 10 < 0.54 1 ugh lb/Day (131-11-3) 288.Di•N-Butyl Phthalate X < 10 < 0.54 1 ugA lb/Day (84.74-2) 278.2,4-Dinitro- X < f0 < 0 54 1 ugA lb/Day toluene(121-14-2) 288.2,8-Dinitro- X - < 10 ' < 0.54 1 ugA lb/Day toluene(606-20-2) 298.DI-N-Octyl v Phthalate X < 10 < 0.54 1 ugA lb/Day (117-84-0) 308.1,2-Diphenyt- hydrazine(as Azo• X < 10 < 0.54 1 ugA lb/Day benzene)(122-68-7) 318.Fluoranthene X - < TO < 0.54 (206-44-0) 1 WI lb/Day 328.Fluarene X < 10 < 0.54 1 ug/1 lb/Day (86-73-7) 338.Hexachloro- X < 10 < 0.54 1 ugA lb/Day benzene(118.74-1) 348.Hexa chiorobutadlene X < 10 < 0.54 1 ugA lb/Day (87-88.3) 358.Hexachlono- cydopenladiene X < 25 < 1.36 (77.47-4) 1 ugA lb/Day 388.Hexachioro- X < 10 < 0.54 ethane(87-72.1) 1 WI lb/Day 37B.Indeno ' (1.2.3-cd)Pyrene X < 10 < 0.54 1 ugA lb/Day (193-39-5) 388.Isopnarone X ' < 10 < 0.54 1 ugA lb/Day (78-59-1) • 39B.Naphthalene X < 10 < 0.54 1 ugh lb/Day (91-20-3) 408.Nitrobenzene X < 10 < 0.54 1 ugA lb/Day (98-95-3) 418.N-Nitro- sodinrethylartwre X < 10 < 0.54 (82-75-9) 1 ug/I lb/Day 428.N-Nitrosodi- - N-Propylamlne X < 10 < 0.54 1 ugh lb/Day (621-84-7) EPA Form 3510-2C(Rev.2-85) PAGE V•7 CONTINUE ON PAGE V•8 • EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) Quit- sent sent (if available) (if available) (if available) d.NO.OF a.Concert- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 438.N-Nitro- sodiphenylamine X < 10 < 0.54 1 (86-30.8) 448.Phenanthrene X < 10 < 0.54 (85-01-8) 45B.Pyrene X < 10 < 0.54 1 (129-00-0) 468.1,2,4-Td- chiorobenzene X < 10 < 0.54 1 (120.82.1) Cie/MS KA;I Rini-I-ES I IC.IL)ts 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.delta-BHC X (319-86-8) 6P.Chlordane X (57-74-9) 7P.4.4'-DDT X- (50-293) 8P.4,4'-DDE X • (72-55-9) 9P.4,4'-DOD X (72-54-8) 10P.Dieldrin X _ (60-57-1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72.20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X (76.44-8) EPA Form 3510-2C(Rev.2-85) ' PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (If available) (if available) (if available) if.NO.OF a.Concert- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (t)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X (53469-21-9) 19P.PCB-1254 X (11097-69-1) 20P.PC8-1221 X • (11104-28-2) 21P.PC5-1232 X (11141-16-5) 22P.PCB-1248 X (12872-29-6) 23P.PCB-1260 X (11096-82-5) 24P.PCB-1016 X (12674-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510.2C(Rev.2-85) PAGE V-9 EPA ID Number(copy from item I of Form 1) Form Approved.OMB No.2040-0086 Please print or type in the unshaded areas NC0004979 Approval expires 5-31-92 FormUnited States Environmental Protection Agency Washington,DC 20460 2F EPI\ Application for Permit to Discharge Storm Water NPDES Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application, including time for reviewing instructions,searching existing data souru ,gathering and maintaining the data needed,and completing and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions for improving this form,induding suggestions which may increase or reduce this burden to:Chief, Information Pdicy Branch,PM-223,U.S.Environmental Protection Agency,401 M St,SW,Washington,DC 20460,or Director,Office of Information and Regulatory Affairs,Office of Management and Budget,Washington,DC 20503. I. Outfall Location For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number D. Receiving Water (list) B. Latitude C. Longitude (name) 008 35u 11' 27" 81u 00' 30" Catawba River 015 350 10' 46" 81u 00' 25" Catawba River Note: For monitoring purposes,the above outfalls represent the remaining outfalls. II. Im•rovements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. 4.Final 1. Identification of Conditions, 2.Affected Outfalls Compliance Date Agreements,Etc. number source of discharge 3.Brief Description of Project a.req. b.proj. NA B. You may attach additional sheets describing any additional water pollution(or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and idicate your actual or planned schedules for construction. III. Site Draina•e Ma• Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a topographic map Is unavailable)depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment,storage or disposal units(including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34);each well where fluids from the facility are injected underground;springs,and other surface water bodies which receive storm water discharges from the facility. EPA Form 3510-2F (Rev. 1-92) Page 1 of 3 Continued on Page 2 Continued from the Front IV. Narrative Descri•tion of Pollutant Sources A. For each outfall,provide an estimate of the area(include units)of impervious surfaces(including paved areas and building roofs)drained to the outfall,and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) (provide units) Number (provide units) (provide units) SW001 See attached thru supplemental SW015 information. B. Provide a narrative description of significant materials that are currently or in the past three years have been treated,stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff;materials loading and access areas;and the location, manner,and frequency in which pesticides,herbicides,soil conditioners,and fertilizers are applied. See attached supplemental information. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. Outfall List Codes from Number Treatment Table 2F-1 SW001 See attached supplemental information. thru SW015 V. Non Stormwater Dischar•es A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of nonstormwater discharges,and that all nonstormwater discharges from these outfall(s)are identified in either an accompanying Form 2C or Form 2E application for the outfall. Name of Official Title(type or print) Signature Date Signed Albert J. Smith, III, Manager, Allen Steam Station - f - I/I fit 1 /O1L B. provide a description of the method used,the dat• of any testing,and the onsite drainage points that were directly observed during a test. Visual inspections were performed during October 2001 and December 2001 and also in May 2002 of the outfalls to verify that non-stormwater discharges were not occurring. VI. Si•nificant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years,including the approximate date and location of the spill or leak,and the type and amount of material released. No reportable spills or significant leaks have occurred at this facility in the last three years. EPA Form 3510-2F (Rev. 1-92) Page 2 of 3 Continued on Page 3 EPA ID Number(copy from Item l of Form 1) Continued from Page 2 NC0004979 VII. Dischar•e Information A,B,C,&D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii-A,VII-B,and VII-C are included on separate sheets numbered VII-1 and VII-2. E. Potential discharges not covered by analysis -is any toxic pollutant listed in table 2F-2, 2F-3, or 2F-4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? n Yes(list all such pollutants below) N No(go to Section IX) VIII. Biolo•ical Toxicit Testin• Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? n Yes(list all such pollutants below) ® No(go to Section IX) IX. Contact anal sis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? NYes(list the name,address,and telephone number of,and pollutants n No(go to Section X) analyzed by, each such laboratory or firm below) A. Name B.Address C.Area Code&Phone No. D.Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave, Suite 100 (704)875-9092 Phenolics NC Lab Certification #12 Huntersville, NC 28078 Pace Analytical Services, Inc. NC 54 Ravens Croft Dr., (828) 254-7176 Naphthalene Lab Certification #40 Asheville, NC 288801 X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A.Name&Official Title(type or print) B.Area Code and Phone No. Albert J. Smith, Ill, Manager, Allen Steam Station (704)829-2500 C.Signature %l ' j D. Date Signed IMAzi EPA Form 3510-2F (Rev. 1-92) Page 3 of 3 EPA ID Number(copy from Item I of Form 1) Form Approved. OMB No.2040-0086 SW008 NC0004979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2F) Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <5.0 N/A N/A 1 See Supplemental Information (attached) Biological Oxygen N/A N/A 1 Si Demand(BOD5) 5.8 mg/L 4.1 mg/L Chemical Oxygen N/A N/A 1 Demand(COD) 73.5 mg/L 49.8 mg/L Total Suspended N/A N/A 1 'I Solids(TSS) 552.0 mg/L 263 mg/L Total Phosphorus 1.094 mg- 0.724 mg- N/A N/A 1 Si P/L P/L pH Minimum Maximum 1 CS 6.52 Maximum Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Arsenic,Total 01002 5.09 ug/L 3.83 ug/L N/A N/A 1 See Supplemental Information (attached) Copper,Total 01042 .043 mg/L .026 mg/L N/A N/A 1 Iron,Total 014045 6.734 mg/L 4.433 mg/L N/A N/A 1 Si Selenium,Total 2.78 ug/L 2.34 ug/L N/A N/A 1 Si 01147 TKN 00625 1 „ 1.8 mg-N/L 1.2 mg-N/L N/A N/A Naphthalene ND ND N/A N/A 1 Si Phenols 1 .014 mg/I .0432 N/A N/A Fecal Coliforms 5000/100 ml 1400/100 ml N/A N/A 1 IS EPA Form 3510-2F(Rev. 1-92) Page VII-2 Continued from the Front—SW008 Part C- List each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present.See the instructions for additional details and requirements.Complete one table for each outfall. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants NA O Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Number of hours between Date of Duration Total rainfall Total flow from beginning of storm meas- Storm of Storm Event during storm event ured and end of previous rain event Event (in minutes) (in inches) measurable rain event (gallons or specify units) 22- 6 hours, 21 minutes 1.08 96+hours 48010 gallons Feb-03 7. Provide a description of the method of flow measurement or estimate. Estimated from the gallons per minute flow data collected by sampling equipment. EPA Form 3510-2F(Rev. 1-92) Page VII-2 SW015 EPA ID Number(copy from Item I of Form 1) Form Approved. OMB No.2040-0086 NC0004979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2FJ Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <5.0 mg/L N/A N/A N/A 1 See Supplemental Information (attached) Biological Oxygen <2.0 mg/L <2.0 mg/L N/A N/A 1 " Demand(BOD5) Chemical Oxygen 20.3 mg/L <20.0 mg/L N/A N/A 1 id Demand(COD) Total Suspended 9.0 mg/L 10.0 mg/L ' N/A N/A 1 " Solids(TSS) Total 0.035 mg- 0.03 mg-P/L N/A N/A 1 'i Phosphorus P/L pH 6.28 N/A Minimum Maximum 1 ,, • Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Arsenic,Total 9.66 ug/L 12.26 ug/L N/A N/A 1 See Supplemental 01002 Information (attached) Copper,Total 0.005 mg/I <0.005 mg/I N/A N/A 1 " 01042 y Iron,Total 014045 0.657 mg/I 0.504 mg/I N/A N/A 1 " Selenium,Total <2.00 ug/L <2.00 ug/I N/A N/A 1 " 01147 TKN 00625 0.5 mg-N/L 0.2 mg-N/L N/A N/A 1 �� Naphthalene <2.0 ug/I <2.0 ug/I N/A N/A 1 id Phenols <0.005 mg/I .016 mg/I N/A N/A 1 �� Fecal Coliforms 240/100 ml 80/100 ml N/A N/A 1 �� EPA Form 3510-2F(Rev. 1-92) Page I-1 Continued from the Front -SW015 Part C- List each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present.See the instructions for additional details and requirements.Complete one table for each outfall. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants NA Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Number of hours between Date of Duration Total rainfall Total flow frombeginning of storm meas- Storm of Storm Event during storm event ured and end of previous rain event Event (in minutes) (in inches) measurable rain event (gallons or specify units) 22- 6 hours,21 minutes 1.08 96+ hours 48010 gallons Feb-03 7. Provide a description of the method of flow measurement or estimate. Estimated from the gallons per minute flow data collected by sampling equipment. EPA Form 3510-2F(Rev. 1-92) Pagel-2 NPDES Supplemental Information Allen Steam Station NPDES Permit # NC0004979 , November 2004 Please print or type in the unshaded areas only (fill-in areas are spaced for elite type,i.e., 12 characters�nch). For Approved. OMB No. 2040-0086. Approval expires 5-31-92 FORM U.S.ENVIRONMENTAL PROTECTION AGENCY s I. EPA I.D. NUMBER', .1 EPA GENERAL INFORMATION S , T/A ▪ F, NC0004979 D• Consolidated Permits Program . GENERAL + N: ,.` (Read the"General Instructions"before starting] , a;. - _ ' ,' ' 13 14 - 15 LABEL ITEMS `- v ,,T4GENERAL INSTRUCTIONS F,11,'-?:- ,,.,:'41,,,:.:4"--::::'..12:0,., ▪ If a preprinted label has been provided, I.EPA I.D. NUMBERS affix it in the designated space.Review the � information carefully; if any ;of it is r : _ � �° corrrrre datain thess mp props ate fillh it and -in areaarea III. FACILITY NAMEer the below.Also,if any of the pre rinted data is absent;{the area t eainfor a le that should V. FACILITY PLEASE PLACE LABEL IN THIS SPACE appear)please provide it in the proper fill- MAILING LIST in area(s) below. If the label is complete' and correct you need not complete Items I, Ill,V,and VI(except V/-B which must be ,� �� �- Completed regardless). Complete all items VI. FACILITY if tructilabel has been roved. Refer to the LOCATION instructions for detailed item descriptions and for the legal authorization under which this data is collected. II. POLLUTANT CHARACTERISTICS INSTRUCTIONS: Complete A through J to determine whether you need to submit any permit application forms to the E. If you answer"yes"to any questions,you must submit this form and the supplemental from listed in the parenthesis following the question.Mark"X"in the box in the'third column if the supplemental form is attached. If you answer"no"to each question,you need not submit any of these forms.'You may answer"no. if your activity is excluded from permit requirements;see Section C of the instructions.See also,Section D of the instructions'for definitions of bold-faced terms. MARK"X" MARK"X" SPECIFIC QUESTIONS FORM SPECIFIC QUESTIONS FORM YES NO ATTACHED YES_: NO ATTACHED A. ni Is this facility a publicly owned treatment works B. Does or will this facility (either existing or which results in a discharge to waters of the ❑ ® ❑ proposed) include ' a <concentrated animal ❑ ® ElU.S.?(FORM 2A) feeding operation or_ aquatic animal production facility which results in a discharge 16 17 18 to waters of the U.S.?(FORM 26) 19 20 21 C. Is this facility which currently results in ® ❑ ® D. Is this proposal facility(other than those described ❑ ® ❑ discharges to waters of the U.S. other than in A or B above)which will result in a discharge those described in A or B above?(FORM 2C) 22 23 24 to waters of the U.S.?(FORM 2D) 25 26 27 E. Does or will this facility treat, store,or dispose of F. Do you or will you inject at this facility industrial or hazardous wastes?(FORM 3) ❑ ® ❑ municipal effluent below the lowermost stratum ❑ ® ❑ containing, within one quarter mile of the well bore, underground sources of drinking water? 28 29 30 (FORM 4) 31 32 33 G. Do you or will you inject at this facility any H. Do you or will you inject at this facility fluids for produced water other fluids which are brought to special processes such as mining of suffer by the the surface in connection with conventional oil or ❑ ® ❑ Frasch process,solution mining of minerals,in ❑ ® ❑ natural gas production, inject fluids used for situ combustion of fossil fuel,or recovery of enhanced recovery of oil or natural gas,or inject geothermal energy?(FORM 4) fluids for storage of liquid hydrocarbons? (FORM 4) 34 35 36 37 : 38 39 _r I. Is this facility a proposed stationary source J. Is this facility a proposed stationary source which is one of the 28 industrial categories listed ® ❑ which is NOT one of the 28 industrial categories in the instructions and which will potentially emit ❑ listed in the instructions and which will potentially ❑ ® ❑ 100 tons per year of any air pollutant regulated emit 250 tons per year of any air' pollutant under the Clean Air Act and may affect or be regulated under the Clean Air Act and may affect located in an attainment area? FORM 5 40 41 42 or be located in an attainment are? FORM 5 43 44 45 III. NAME OF FACILITY c SKIP Allen Steam Station 1 15 16-29 30 69 IV. FACILITY CONTACT A.NAME&TITLE(last,first,&title) B.PHONE(area code&no.) 2 Ruhe, Michael, Manager, Environmental Support (980) 373 3231 15 16 45 46 48 49 51 52 55 V. FACILITY MAILING ADDRESS A.STREET OR P.O.BOX 3 P.O. Box 1006, Mail Code EC11E 15 16 45 B.CITY OR TOWN C.STATE D.ZIP CODE c Charlotte NC 28201 4 15 16 40 41 42 47 51 VI. FACILITY LOCATION A.STREET, ROUTE NO.OR OTHER SPECIFIC IDENTIFIER 5 253 Plant Allen Road 15 16 45 B.COUNTY NAME Gaston 46 70 C.CITY OR TOWN D.STATE ' E.ZIP CODE F.COUNTY CODE c Belmont NC 28012 6 15 16 40 I 41 42 47 51 52 54 EI':X FORM 3510-I (8-90) CONTINUED ON REVERSE CONTINUED FROM THE FRONT VII. SIC CODES 4-di•it, in order of.riorit A.FIRST B.SECOND C 4911 (specify) 7 (specify) 7 Electric Services 7 15 16 17 15 16 4=-',,19 ` C.THIRD * ., gel,: . �:• 0FOURTH 7 (specify) 7 (specify) 7 15 16 17 15 16 19 +' VIII. OPERATOR INFORMATION A.NAME B.Is the name listed in Item sDuke Energy Corporation (Attention Michael A. Ruhe) Vlll-A also the owner? 18 19 y4 1Z YES ❑NO C.STATUS OF OPERATOR(Enter the appropriate letter into the answer box;if"Other,"specify.) D.PHONE area code&no.) F=FEDERAL M=PUBLIC(other than federal or state) p (specify) C (980) 373 3231 S=STATE O=OTHER(specify) A Electric Utility P=PRIVATE 56 15 16 18 19 21 22 25 E.`STREET OR PO BOX P.O. Box 1006, Mail Code EC11E 26 F.CITY OR TOWN G.STATE H.ZIP CODE IX.INDIAN LAND c Charlotte NC 28201 Is the facility located on Indian lands? B ❑YES ® NO 15 16 40 42 42 47 51 X. EXISTING ENVIRONMENTAL PERMITS A.NPDES(Discharges to Surface Water) D.PSD(Air Emissions from Proposed Sources) 9 N f NC0004979 CC PT 8 15 16 17 18 30 15 16 17 18 30 B.UIC(Underground Injection of Fluids E.OTHER(specify) (Specify) C T I c T 8 03757T26 Air Permit 9 U 9 15 16 17 18 30 15 16 17 18 30 C.RCRA(Hazardous Wastes) E.OTHER(specify) (Specify) s R I NCD043678937 s T 8 WQ0003255 Ash Reuse Permit 15 16 17 18 30 15 16 17 18 : - 30 XI. MAP Attach to this application a topographic map of the area extending to at least one mile beyond property boundaries. The map must show the outline of the facility, the location of each of its existing and proposed intake and discharge structures, each of its hazardous waste treatment, storage, or disposal facilities, and each well where it injects fluids underground. Include all springs, rivers and other surface water bodies in the ma. area. See instructions for .recise re.uirements. XII. NATURE OF BUSINESS •rovide a brief descri•tion Coal fired steam electric generation XIII. CERTIFICATION see instructions I certify under penalty of law that I have personally examined and am familiar with the information submitted in this application and all attachments and that, based on my inquiry of those persons immediately responsible for obtaining the information contained in the application, I believe that the information is true, accurate and complete. lam aware that there are significant penalties for submitting false information,including thepossibility of fine and imprisonment. B.SIGNATURE' - C. DATE SIGNED A. NAME&OFFICIAL TITLE(type or print) , B. Albert J. Smith, Ill, Manager,Allen (1/rl lD 4 Steam Station COMMENTS FOR OFFICIAL USE ONLY C C 15 16 55 EPA FORM 3510-I (8-90) • 0 ' / "44\ ,,. \ ip\ P, • • . .• r_ Nil( 27)(.8 r‘ rn z r. . 001. . \. --- -- -- Nj \ ...—'a , U• ... -r__— j / cn '°co-'7 • .•G ..• .. �+- .,„ • .• „...0..- %,.........p.,. c . ,_,,, • . c�.e , IIP: IL , I V 413 /i AI i q ,off -11 co o _ dt , -...,...,. ,. i ,,, fort,—,_". ',, 1 Of _ ) /•, 11144/ fl 3°' I 8 vOTA‘IIII.\\ /veil, x rf• . ‘- X 0 ,..it•tiiiir.., ...:_..„11 ,000, _ ,.._ ,_,..,..„, . ,...--;7_ 6:00)\, , ,. wtiti„.....r.7.7., .. , • . I i dr. ii, ••'.ar••I �•,,.• '��__------ .._ - -- ,� •• .a�•�'• r• aa�u�ra�ra�rr�rr�•r`••+••`...•• ft -y- \ •• .. • WI I -- CKLENBU ,� 0°q - . R 7 co65, • •.. \;._,__v___ _ � n ti, \, Ititi, ff _.../...• • -----...„ , O• i , )c x m pC� D ;, • �1 N ',---- ------=,, ---- )" ••• / - �cn� �4••II . .-•0� omo cn$ I t O ��m O / / • DDD Z ( / t,,___ _____,-..,,_) \\\ �� 1 _1 rim �J • �� ZAda v.N. ! v 7 • EPA ID Number(Copy from Item 1 of Form 1) ", Form Approved Please type or print in the unshaded areas only NC0004979 ,OMB No.2040-0086 '.Approval expires 5-31-92 Form -; U.S.ENVIRONMENTAL.PROTECTION AGENCY ., 2 APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER NPDES ��� „ P1\ EXISTING MANUFACTURING,COMMERCIAL,MINING AND SILVICUTLRAL OPERATIONS Consolidated Permits Program I.Out:fall Location For this outfall,list the latitude and longitude,and name of the receiving water(s) ;' Outfall Latitude Longitude Receiving Water(name) Number(list) Deg Min Sec Deg Min Sec `: ,1 u� ',_ ' 001 35 11 22 81 00 44 South Fork River 002 35 10 30 81 00 20 Catawba River 002A 35 11 13 81 00 21 Catawba River 002E 35 11 25 81 ' 00 28 Catawba River 003 35 11 23 81 00 45 South Fork River 004 35 11 13 81 00 21 Catawba River II. Flows, Sources of Pollution,and Treatment Technologies A. Attach a line drawing showing the water flow through the facility. Indicate sources of intake water,operations contributing wastewater to the effluent and treatment units labeled to correspond to the more detailed descriptions in item B.Construct a water balance on the line drawing by showing average flows between intakes, operations,treatment units,and outfalls.If a water balance cannot be determined(e.g.,for certain mining activities),provide a pictorial description of the nature and amount of any sources of water and any collection or treatment measures. B. For each outfall,provide a description of(1)all operations contributing wastewater to the effluent,including process wastewater,sanitary wastewater,cooling water, and stormwater runoff; (2)the average flow contributed by each operation; and(3)the treatment received by the wastewater. Continue on additional sheets if necessary. 1.Outfall 2.Operations Contributing Flow 3.Treatment Number a.OPERATION(list) b.AVERAGE FLOW a.DESCRIPTION b. LIST CODES FROM TABLE -r 2C-1 001 Condenser Cooling 626.3 MGD discharge to 4A Water(Once through surface water non-contact) 002 Ash basin discharge 20.7MGD chemical 2D, 1 U 2K coagulation, 2J, 4A settling, neutralization, ion exchange, surface water discharge 002A Emergency overflow coal Intermittent surface water 4A yard sump discharge 002E Emergency overflow of Intermittent surface water 4A power house sump discharge 003 Miscellaneous once 4.5 MGD surface water 4A through non-contact discharge cooling water 004 Miscellaneous once 6.5 MGD surface water 4A through non-contact discharge cooling water EPA FORM 3510-2C (Rev. 2-85) Page 1 of 4 CONTINUED ON REVERSE CONTINUED FROM THE FRONT C.Except for storm runoff,leaks,or spills,are any of the discharges described in Items II-A or B intermittent or seasonal? ,." s ,> `°. a ® YES(complete the following table) ❑ NO(go to Section III) H,. ti 2 `.'3.FREQUENCY ' ' '- 4.FLOW . 1.OUTFALL 2.OPERATION(s) a.DAYS PER b. a.FLOW RATE b.TOTAL VOLUME _'` NUMBER CONTRIBUTING FLOW' WEEK"- MONTHS (in mgd) "�'� (specify with unitsA C.DUR (list) (list) (specION ify PER YEAR in day average) (specify 1•LONG TERM 2. 1 LONG TERM 2 MAXIMUM (in days) :, AVERAGE' MAXIMUM, AVERAGE DAILY ,< ..average) :. DAILY' ,. - 002A Emergency See See See ��See supplemental supplemental supplemental supplemental Overflow of coal Information Information information Information yard sump 002B Emergency See See See See supplemental supplemental supplemental supplemental overflow of power Information Information Information Information house sump III. PRODUCTION A.Does an effluent guideline limitation promulgated by EPA under Section 304 of the Clean Water Act apply to your facility? ® YES(complete Item Ill-B) ❑ NO(go to Section IV) B.Are the limitations in the applicable effluent guideline expressed in terms of production(or other measure of operation)? ❑ YES(complete Item Ill-C) ® NO(go to Section IV) C. If you answered"yes"to Item III-B,list the quantity which represents an actual measurement of your level of production,expressed in the terms and units used in the applicable effluent guideline,and indicate the affected outfalls. 1.AVERAGE DAILY PRODUCTION 2.AFFECTED OUTFALLS a.QUANTITY PER DAY b.UNITS OF MEASURE c.OPERATION,PRODUCT,MATERIAL,ETC. (list outfall numbers) (specify) NA NA NA NA IV. IMPROVEMENTS __ A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading, or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. ❑ YES(complete the following table) ® NO (go to Item IV-B) 1.IDENTIFICATION OF CONDITION, 2.AFFECTED OUTFALLS 4.FINAL AGREEMENT,ETC. 3.BRIEF DESCRIPTION OF PROJECT COMPLIANCE DATE a.No b.SOURCE OF DISCHARGE a.REQ- b.PRO- UIRED JECTED B. OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges)you now have underway or which you plan. Indicate whether each program is now underway or planned, and indicate your actual or planned schedules for construction. ❑ MARK"X"IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAM IS ATTACHED EPA FORM 3510-2C (Rev. 2-85) Page 2 of 4 CONTINUED ON PAGE 3 EPA ID Number(Copy from Item 1 of Form 1) CONTINUED FROM PAGE 2 NC0004979 V. INTAKE AND EFFLUENT CHARACTERISTICS A,B,&C: See instructions before proceeding-Complete one set of tables or each outfall-Annotate the outfall number in the space provided. NOTE: Tables V-A,V-B,and V-C are included on separate sheets number V-1 through V-9. D: Use the space below to list any of the pollutants listed in Tables 2c-3 of the instructions,which you know or have reason to believe is discharged or, may be discharged from any outfall. For every pollutant you list,briefly describe the reasons you believe it to be present and report any analytical data in your possession. - `,;44.� ,, 1.POLLUTANT 2.SOURCE 1.POLLUTANT r 2.SOURCE t See supplemental information page 23 for a complete list. VI. POTENTIAL DISCHARGES NOT COVERED BY ANALYSIS :;: Is any pollutant listed in Item V-C a substance or a component of a substance,which you currently use or manufacture as an intermediate or final product or byproduct? ❑ YES (list all such pollutants below) ® NO(go to Item VI-B) EPA FORM 3510-2C (Rev. 2-85) Page 3 of 4 CONTINUED ON REVERSE CONTINUED FROM THE FRONT VII. BIOLOGICAL TOXICITY TESTING DATA Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? ® YES(identify the test(s)and describetheir purpose below) ❑ NO(go to Section Quarterly analysis of Ceriodaphnia Dubia (chronic P/F @ 16%) testing per current permit requirements on outfall 002. VIII. CONTRACT ANALYSIS INFORMATION Were any of the analyses reported in Item V performed by a contract laboratory or consulting firm? ® YES(list the name,address,and telephone number of,and pollutants ❑ NO(go to Section IX) analyzed by,each such laboratory or firm below) A.NAME B.ADDRESS C.TELEPHONE D.POLLUTANTS ANALYZED , (area code&no.) (list) Prism Laboratories, Springbrook Rd, Charlotte, NC (704) 529-6364 oil and grease,TSS, (NC certification #402) 28224 BOD, VOC, SVOC,total phenolics, sulfide, sulfite, bromide, color MBAS, COD, Florida Radiochemistry 5456 Hoffner Ave, Orlando, FL (407) 382-7733 Total radium/radium Services, Fl 32812 226 certification # 12709 ENO River Labs, (LLC South Alston Ave, Durham, NC (919)-281-4040 dioxin screen 2445) 27713 IX. CERTIFICATION I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. A. NAME&OFFICIAL TITLE(type or print) B.PHONE NO.(area code&no.) Albert J. Smith, Ill, Mana er,Allen:Steam Station (704) 829-2500 C. SIGNATURE �. D. DATE SIGNED < • EPA FORM 3510-2C (Rev. 2-85) Page 4 of 4 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 001 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF • (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen 15 98237.3 1 mg/I lb/Day 3.55 2 Demand(BOD) b.Chemical Oxygen < 50 < 327457.8 1 mg/I lb/Day < 50 2 Demand(COD) c.Total Organic 2.83 18534.1 1 mg/I lb/Day 2.59 2 Carbon(TOC) d.Total Suspended 6 39294.9 1 mg/I lb/Day 9 2 Solids(TSS) e.Ammonia(as N) 0.14 918.9 1 mg/I lb/Day 0.095 2 (.Flow VALUE VALUE VALUE MGD X VALUE 784.8 784.8 626.3 365 g.Temperature VALUE VALUE VALUE VALUE (winter) 40 35 25.3 243 DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 41.7 38.3 37.4 122 DEGREES CELSIUS 25.4 2 i.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.92 ' 1 STANDARD UNITS 7.44 2 PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X- 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG-TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X < 0.1 < 654.9 1 mg/I lb/Day 0.11 2 (24959-87-9) b.Chlorine, X 0.07 458.4 1 mg/I lb/Day 0.05 2 Total Residual c.Color X 40 X 1 Std.Units X 30 2 d.Fecal X 1600 X 60.2 X 3 Colonies X 7.5 4 Coliform /100 ml e Floudde X 0.12 785.9 1 mg/I lb/Day 0.17 2 (16984-48-8) f.Nitrate. X 0.11 720.4 1 mg/I lb/Day 0.13 2 Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 ts EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen, Total Organic X 0.16 1047.9 1 mg/I Ib/Day 0.32 2 (as N) h.ou and Grease A < 5 < 32745.8 1 mg/I lb/Day < 5 2 i.Phosphorous (as P),Total X 0.02 131.0 1 mg/I lb/Day 0.04 2 (7723-14-0) I.Radioactivity (1)Alpha, Total X < 7.80E-02 X 1 pCUI X < 2.90E-01 2 (2)Beta, Total X 1.86E+00 X 1 pCi/I X 2.79E+00 2 13.83E-01 3)Radium, Total X < 0.9 X 1 pCi/I X 0.4 2 0.6 (4)Radium 226,Total X < 0.1 X 1 pCi/I X 0.1 2 k Sulfate (as SO4) X 7.88 51607.3 1 mg/I Ib/Day 7.59 2 (14808-79-8) .Sulfide (as S) X < 2 < 13098.3 1 mg/I lb/Day < 2 2 m.Sulfffe (as S03) X 1 6549.2 1 mg/I lb/Day < 2 2 (14265-45-3) n.Surfactants X < 0.1 < 654.9 1 mg/I lb/Day < 0.1 2 o.Aluminum, Total X 0.39 2554.2 1 mg/I lb/Day 0.387 2 (7429-90-5) p.Barium, Total X 0.024 157.2 1 mg/I lb/Day 0.021 2 (7440-39-3) q.Boron, Total X < 0.1 < 654.9 1 mg/I lb/Day < 0.1 2 (7440-42-8) r.Cobalt, Total X < 0.001 < 6.5 1 mg/I lb/Day < 1 2 (7440-48-4) a.Iron,Total (7439-89-6) X 0.63 4126.0 1 mg/I lb/Day 0.663 2 t.Magnesium, Total X 1.8 11788.5 1 mgA lb/Day 1.811 2 (7439-954) u.Molybdenum, Total X 0.002 13.1 1 mg/I lb/Day 0.002 2 (7439-98-7) v.Manganese, Total X 0.058 379.9 1 mg/I lb/Day 0.054 2 (7439-96-5) w.Tin,Total (7440-31-5) X < 0.05 < 327.5 1 mg/I lb/Day < 0.05 2 x.Titanium, • Total X 0.031 203.0 1 mg/I lb/Day 0.024 2 (7440-02-6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 a EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 001 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe Is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re• b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quli- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony, X < 3 < 19.65 1 up lb/Day < 3 2 Total(7440-36-0) 2M.Arsenic,Total X < 2 < 13.10- 1 up lb/Day < 2 2 (7440-38-2) 3M.Beryllium, X < O.b < 3.27 - 1 ugh lb/Day < 5 2 Total(7440-41-7) 4M.Cadmium, X < 0.5 < 3.27 1 ugh lb/Day < 5 2 Total(7440-43-9) 5M.Chromium, X < 1 < 6.55 1 Ugh Ib/Day 0.685 2 Total(7440-47-3) 6M.Copper,Total X 0.0f 144.08 1 mgA lb/Day 0.011 - 2 (7440-50-8) 7M.Lead,Total X < 2 < 1310 1 ugh lb/Day 2.43 2 (7439-92-1) 8M.Mercury,Total X < 0.1 < . 0.66- 1 ugh Ib/Day < D.1 2 (7439-97-6) 9M.Nickel,Total X < 2 < 13.10 1 ugh Ib/Day < 2 2 (7440-02-0) 10M.Selenium, X < 2 < 13.10 1 up lb/Day < 2 2 Total(7782-49-2) 11M.Silver,Total X < 0.5 < 3.27 1 ugh lb/Day < 0.5 2 (7440-22-4) 12M.Thallium, X < 0.002 ' < 13.1 1 mgA lb/Day < 0.002 2 Total(7440-28-0) 13M.Zinc,Total X < 0.02 < 130.98 1 mgA lb/Day < 0.02 2 (7440.66.6) 14M.Cyanide, X < 0.002 < 13.10 1 mgA lb/Day < 0.002 2 Total(57-12-5) 15M.Phenols, X < 0.05 < 327.5 1 mgA lb/Day 0.019 2 Total 'UIOXIN 2,3,7,8 Tetra UESZ.14T1i6 RESUL i S chlorodibenxo P X NOT DETECTED Dioxin(1764-01.6) EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 k EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre-c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1V.Aaaleln X < 100 < 654.92 1 ugh lb/Day < 100 2 (107-02-8) 2V.Acryladille X < 100 < 654.92 1 ugh lb/Day < 100 2 (107-13-1) 3V.Benzene X < 1 < 6.55 1 ugh lb/Day < 2 2 (71-43-2) 4V.Bie(Chloro- methyl)Ether X (542-88-1) 5V.Bromofonn X < 1 < 6.55 1 ugh lb/Day < 2 2 (75-25-2) eV.Carbon Tetrachloride X < 1 < 6.55 1 ug/I lb/Day < 2 2 (56-23-5) 7V.Chlorobenzene X < 1 < 6.55 1 ugh lb/Day < 2 2 (108-90-7) 8V.Chlorodl- bromomethane X < 1 < 6.55 1 ugh lb/Day < 2 2 (124-48-1) 9V.Chloroethane X < 2 < 13.10 1 ugh lb/Day < 2 2 (75-00-3) 10V.2-Chloro• ethylvinyl Ether X < 2 < 13.10 1 ugh lb/Day < 2 2 (110-768) 11V.Chloroform X < 1 < 6.55 1 ug/I lb/Day < 2 2 (67-66-3) 12V.Dichloro- bromomethane X < 1 < ' 8.55 1 ugh lb/Day < 2 2 (75-27-4) 13V.Dichlaro- dieuoromethane X < 2 < 13.10 1 ugh lb/Day < 2 2 (75-51-8) 14V.1,1-Dlchlor- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethane(75-34-3) 15V.1,2-Dlchloro- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethane(107.06-2) 16V.1,1-Diddoro- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethylene(75-35-4) 17V.1,2-Dichlonr X < 1 < 6.55 1 ugh lb/Day < 2 2 propane(78-87-5) 18V.1,3-DIchloro- X < 1 < 6.55 1 ugh Ib/Day < 2 2 propylene(542-75-6) 19V.Ethylbenzene X < 1 < 6.55 1 ugh lb/Day < 2 2 (100-41-4) 20V.Methyl X < 2 < 13.10 1 ugh lb/Day < 5 2 Bromide(74-83-9) 21V.Methyl X < 2 < 13.10 1 ugh lb/Day < 2 2 Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item I of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (If available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration 1(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X - < 2 < 13.16 1 ugh lb/Day < 2 2 Chloride(75-09-2) 23V.1.1.2,2-Tetra- , chloroethane X < 1 < 6.55 1 ugh lb/Day < 2 2 (79-34-5) 24V.Tetradtloro- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethylene(127.18-4) 25V.Toluene X - < 1 < 6 55 I ugh lb/Day < 2 2 (108-88-3) 26V.1.2-Trans- Dichlaoethylene X < 1 < 6.55 1 ugh lb/Day < 2 2 (156-60-5) 27V.1,1,1.Tri- dtbroethane X < 1 < 6.55 1 ugh lb/Day < 2 2 (71-55-6) 28V.1,12-Tn- dHoroethane X < 1 < 8.55 1 ugh lb/Day < 2 2 (79-00-5) 29V.Trichloro- X < 1 < 6.55 1 ugh lb/Day < 2 2 ethylene(79-01-6) • 30V.Trichloro- fluoromethane X < 2 < 13.10 1 ugh lb/Day < 2 2 (75.69.4) 31v.Vinyl X < 2. < 13.10 1 ugh lb/Day < 2 2 Chloride(75-01-4) liU/MSFKAL.IlO -ALL-t O4APOUNDS 1A.2-Chloropherwl X < 10 < 65.49 1 ugh Ib/Day < 10 2 (95-57-8) 2A.2,4-Dichloro- X < 10 < 65.49 1 ugh lb/Day < 10 2 phenol(120-83-2) 3A.2.4-Dimethyl- X < 10 < 65.49 1 ugh lb/Day < 10 2 phenol(105-67.9) 4k 4,6-Dt nitnr4 X < 10 < 65.49 1 ugh lb/Day < 25 2 Cresol(534-52.1) 5A.2,4-Dwtro- X < 10 < 65.49 1 ugh lb/Day < 25 2 phenol(51-28-5) 6A.2-Nitrophenol X < 10 < 65.49 1 ugh lb/Day < 10 2 (88.75-5) 7A.4-Nibophenol X < 1r' < 65.49 1 ugh lb/Day < 25 2 (100-02-7) BA.P-Chloro-M- X < 10 < 65.49 1 ugh lb/Day < 10 2 Cresol(59-50-7) 9A.Pentachloro- X < 10 < 65.49 1 ugh lb/Day < 25 2 phenol(87-86-5) 10A.Phenol X < 10 < 65.49 1 ugh lb/Day < 10 2 (108-95-2) 11A.2,4,6-Tri- chtorophenol X < 10 < 65.49 1 ugh lb/Day < 10 2 (88.06.2) - EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 001 • 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (if available) (If available) (if available) d.NO.OF a.Concen- b.Mass d NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES (ration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.Acenaphthene X < 10 < 65.49 1 ug/I lb/Day < 10 2 (83-32-9) 213.Acenaphtylene X < 10 < 65.49 1 ugh lb/Day < 10 2 (20846-8) 38.Anthracene X < 10 < 65.49 1 ugh lb/Day < 10 2 (120-12-7) 48.Benzldine X < 100 < 654.92 1 ugh lb/Day ' < 100 2 (92-87-5) 5B.Benzo(a) Anthracene X < 10 < 65.49 1 ugh lb/Day < 10 2 (56-55-3) 68.Benz°(a) X < 1(Y < 65.49 1 ugh lb/Day < 10 2 Pyrene(50-32-8) 7B.3,4-Benzo- fluoranthene X < 10 < 65.49 1 ugh lb/Day < 10 2 (205-99-2) 86.Benzo(gill) X < 10 < 65,49 1 ugh lb/Day < 10 2 Perylene(191-24-2) 98.Benzo(k) Fluoranthene X < 10 < 65.49 1 ug/I lb/Day < 10 2 (207-08-9) 106.Bis(2-Ctrloro- ethoxyl)Methane X < 10 < 65.49 1 ugh lb/Day < 10 2 (111.91-1) 1113.Big(2-Chloro- eth)4)Ether X < 10. < 65.49 1 ugh lb/Day < 10 2 (111-44-4) 128.81a(2-Chloroiso- propyl)Ether X < 10 < 65.49 1 ugh lb/Day < 10 2 (108.80-1) - 138.Bis(2-Ethyt- hexyt)Phthalate X < 10 < 65.49 1 ugh lb/Day 19 2 (117-81-7) 148.4-Bromo- phenyl Phenyl X < 10 < 65.49 1 ugh lb/Day < 10 2 Ether(101-55-3) 158.Butyl Benzyt X < 10 < 65.49 1 ugh lb/Day < 10 2 - Phthalate(85-88-7) 168.2-Chlcro- naphthalene X < 10 < 65.49 1 ugh lb/Day < 10 2 (91-58-7) 178.4-Chlo4o- phenyl Phenyl X < 10 < 65.49 1 ugh lb/Day < 10 2 Ether(7005-72-3) 188.Chryaene X < 10 < 65.49 1 ugh lb/Day < 10 2 (218-01-9) 198.Dibenzo(a,h) Anthracene X < 10 < 65.49 1 ugh lb/Day < 10 2 (53-70-3) 208.1,2-Dichloro- X < 10 < 65.49 1 ugh lb/Day < 10 2 benzene(95-50.1) 218.1,3-Dichbro- X < 10 < 65.49 1 ugh lb/Day < 10 2 benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ad (1)Concentration ) (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 228.1,4-Dichloro- X < 10 < 65.49 1 ugh lb/Day < 10 2 benzene(10648-7) 238.3,3-Did,bro- berwdine X < 1d < 65.49 1 ugh lb/Day < 25 2 (91-94-1) 248.Diethyl _ ' Phthalate X < 10 < 65.49 1 ugh lb/Day < 10 2 (84-66-2) 258.Dlmethyl - ' Phthalate X < 10 < 65.49 1 ug/I lb/Day < 10 2 (131-11-3) 26B.Di-N-Butyl Phthalate X < 10 < 65.49 1 ugh lb/Day < 10 2 (84-74-2) 27B.2,4-Dinitro- X < 10- < 65A9 1 ugh lb/Day < 10 2 toluene(121-14-2) 288.2,6-Dinitro- X < 10 <65,49 - i - ugh lb/Day < 10 2 toluene(606-20-2) 298.DiI-0ctyl Phthalate X < 10 < 65.49 1 ugh lb/Day < 10 2 (117-84-0) - 308.1,2-Diphenyi- hydrazine(as Azo- X < 10 < 65.49 1 ugh Ib/Day < 10 2 benzene)(122-66-7) 318.Fluoranthene X < 10 < 65.49 5 ugh lb/Day < 10 2 (206-44-0) 328.Fluoene X < 10 < 65.49 1 ugh Ib/Day < 10 2 (86.73.7) 338.Hexachloro- X < 1t < 65.49 1 ug/F lb/Day < 10 2 benzene(118-74-1) 348.Hexa- chlorobutadiene X < 10 < 65.49 1 ugh lb/Day < 10 2 (87.68.3) 358.Hexachloro- cyclopenladlene X < 10 < 65.49 1 ugh) lb/Day < 25 2 (77-47-4) 388.Hexachioro- X < 10 < 65.49 1 ugh lb/Day < 10 2 ethane(67-72-1) 378.Indeno (1.2.3-cd)Pyrene X < 10 < 65.49 1 ugh lb/Day < 10 2 (193-39-5) 388.Isopharne X < 10 < 65.49 1 ugh lb/Day < 10 2 (78-59.1) 398.Naphthalene X < io < 65.49 1 ugh lb/Day < 10 2 (91-20-3) 408.Nitrobenzene X < 10 < 65.49 1 ugh lb/Day < 10 2 (98-95-3) 418.N-Nitro- sodirnethytarnine X < 10 < 65.49 1 ugh lb/Day < 10 2 (62-75-9) 42B.N-Nitroeodl- N-Propylamine X < 10 < 65.49 1 ugh lb/Day < 10 2 (621-64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (if available) (If available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 438.N-Nitro sodlphenylamine X < 10 < 65.49 1 ug/I lb/Day < 10 2 (86-30-6) 448.Phenanthrene X < 10 < 65.49 1 ug/I lb/Day < 10 2 (85-01-8) 458.Pyrene X < 10 < 65.49 1 ug/I lb/Day < 10 2 (129-00-0) 468.1,2,4-Tn- chlorobenzene X < 10 < 65.49 1 ug/I lb/Day < 10 2 (120.82.1) CiU/MS t•KAC I!UK-I'tb I I(AL) S 1P.Aldrin X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58-89-9) 5P.delta-BHC X (319-86-8) 6P.Chlordane X (57.74-9) 7P.4,4'-DOT X (50-29-3) 8P.4,4'-DDE X (72-55-9) 9P.4,4'-DOD —X (72-54-8) 10P.Dieldfn X (60-57-1) 11P.alpha-E dosulfan X (115-29-7) 12P.beta-Edosulfan X (115-29-7) 13P.Endoeulfan Sulfate X (1031-07-8) 14P.Etdrin X (72-20-8) 15P.EtdM Aldehyde X (7421-93-4) 16P.Heptachlor X (76-44.8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 001 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5. INTAKE(optional) AND CAS NO. a.re- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quit, sent sent (if available) (If available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration j (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X (53469-21-9) 19P.PCB-1254 X (11097-69-1) 20P.PCB-1221 X (11104-28-2) 21P.PCB-1232 X (11141-16-5) 22P.PCB-1248 X • (12672-29-6) 23P.PCB-1260 X (11096-82-5) 24P.PCB-1016 X (12674-11.2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 002 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen < 3.2 < 715.7 < 3.2 < 715.7 < 2 < 345.5 5 mg/I lb/Day 3.55 2 Demand MOD) b.Chemical Oxygen < 20 < 4472.9 1 mgA lb/Day < 50 2 Demand(COD) c.Total Organic 0.79 176.7 1 mg/I lb/Day 2.59 2 Carbon(TOC) d.Total Suspected 24 5367.5 24 5367.5 8.6 1485.6 13 mgA lb/Day 9 2 Solids(TSS) e.Ammonia(as N) 0.03 6.7 1 mg/I lb/Day 0.095 2 f.Flow VALUE VALUE VALUE MGD X VALUE 26.8 26.8 20.7 52 g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 20.8 1 DEGREES CELSIUS 25.4 2 I.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.1 ' 7.1 6.1 7.1 13 STANDARD UNITS 7.44 2 PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any , pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK x 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (If available) (If available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tretion (1)Concentration (2)Mass ANALYSES a Bromide X 0.255 57.0 1 mg/I lb/Day 0.11 2 (24959-67-9) b.Chlorine. X < 0.2 < 44.7 1 mgA lb/Day 0.05 2 Total Residual c.Color X 5 X 1 Std.Units X 30 2 d.Fecal X 2 X 2 1.1 5 Colonies X 7.5 4 Coliform . /100 ml e.Flouride X 0.37 82.7 1 mg/I lb/Day 0.17 2 (16984-48-8) f.Nitrate- X 0.1 22.4 1 mgA lb/Day 0.13 2 Nitrite(as N) EPA Fonn 3510-2C(Rev.2465) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 002 1.POLLUTANT 2.MARK•X• 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) a.pre- b.ab• (If available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen, Taal Organic A 0.65 145.4 0.65 145.4 0.17 29.4 3 mg/I lb/Day 0.32 2 (as N) h.Oil and Grease A < 5 < 1118.2 < 5 < 1118.2 < 5 < 863.7 5 mg/I lb/Day < 5 2 I.Phosphorous (as P).Total A < 0.01 ' < 2.2 < 0.01 < 2.2 < 0.01 < 1.7 3 mg/I lb/Day 0.04 2 (7723-14-0) I.Radioactivity Z1)Alpha, Total A 1.630E+00 X 1 pCi/I X < 2.90E-01 2 (2)Befa, Total A 1.620+01 X 1 pCI I X 2.79E+00 2 (3)Radium, Total A X 1 pCi/I X 0.4 2 (4)Radium 226,Total A < 0.2 < X 1 pCUI X 0.1 2 k Sulfate (as 604) A 71.43 15975.0 71.43 15975.0 59.17 10221.1 5 mg/I lb/Day 7.59 2 (14808-79.8) .Sulfide (as S) A < 0.05 < 11.2 . 1 mg/I lb/Day < 2 2 m.Sulfite (as S03) A < 2 < 447.3 1 mg/I lb/Day < 2 2 (14265-45-3) n.Surfactants A < 0.1 < 22.4 1 mg/I lb/Day < 0.1 2 o.Aluminum, Total X 0.2684 60.0. 1 mg/I lb/Day 0.387 2 (7429-90-5) p.Barium, Total X 0.319 71.3 0.319 71.3 0.246 42.5 5 mg/I lb/Day 0.021 2 (7440-39-3) p.Boron. Total A 0.387 86.6 1 mg/I lb/Day < 0.1 2 (7440-42-8) r.Cobalt, Total A 0.00616 1.4 1 mg/I lb/Day < 1 2 (7440-48-4) s.Iron.Total (7439-89-6) A 0.81 181.2 0.81 181.2 0.16 27.6 13 mg/I lb/Day 0.663 2 I.Magnesium, Total A 2.652 593.1 1 mg/I lb/Day 1.811 2 (7439.95-4) u.Molybdenum, Total A 0.05235 11.7 1 mg/I lb/Day 0.002 2 (7439-98-7) v.Manganese, Total A 0.075 16.8 1 mg/I lb/Day 0.054 2 (7439-96-5) w.Tin,Total (7440-31-5) A < 0.05 < 11.2 1 mg/I lb/Day < 0.05 2 x.Titanium, Total A 0.022 4.9 1 mgA lb/Day 0.024 2 (744032.6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V.3 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 002 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you . must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant Is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antlmany, X 7.81 1.70 1 ugh lb/Day < 3 2 Total(7440-38-0) 2M.Arsenic,Total X 76.8 17.18 76.8 17.18 14 2.42 13 ugh lb/Day < 2 2 (7440.38-2) 3M.Beryllium. X < 0.5 < 0.11 1 ugh lb/Day < 5 2 Total(7440-41-7) , 4M.Cadmium, ' X 1.25 0.28 1.25 0.28 0.5 0.09 5 ugh lb/Day < 5 2 Total(7440-43-9) 5M.Chromium, X <40 < 8.95 < 40 < 8,95 < 4Z1 < 6.91 5 ugh Ib/Day 0.685 2 Total(7440-47-3) 8M.Copper,Total X 0.02b 581 0.026 5-.81 0.01 1773 -25 mgh lb/Day 0.011 2 (744060.8) 7M.Lead,Total X - < 2 < 0.45 1 ugh lb/Day 2.43 2 (7439-92-1) 8M.Mercury,Total X < 0.1 < - 0.02 i ugh lb/Day < 0.1 2 (7439-97-6) 9M.Nickel,Total X 26.64 - 5:96 26 64 5?6 1-6 276 5 ugh lb/Day < 2 2 (7440-02-0) 10M.Selenium, X 27.1 6.06 27.1 6.06 12 2.07 25 ugh lb/Day < 2 -2-- Total(7782-49-2) 11M.Silver,Total X < 0.5 < 0.11 1 ugh lb/Day < 0.5 2 (7440-22-4) 12M.Thallium, X < 0.002 < 0.4 1 mg/I lb/Day < 0.002 2 Total(7440-28-0) 13M.Zinc,Total X ' 0.035 7.83 0.035 7.83 0.019 3.28 5 mgh lb/Day < 0.02 2 (7440-66-6) 14M.Cyanide, X 0.002 0.45 0.002 0.45 < 0.002 < 0.35 5 mg/I lb/Day < 0.002 2 Total(57-12-5) 15M.Phenols, X 0.015 3.4 1 mg/I lb/Day 0.019 2 Total DIOXIN 2,3,7,8 Tetra 1SESU TI&A'(=b1/ I chlorodibenzo P Dioxin(1764-01-6) X NOT DETECTED EPA Fonn 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 002 1.POLLUTANT 2.MARK"X' 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre-c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE Of available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1V.Acrolein X < 20 < 4.47 1 u A lb/Day100 (107-02-8) 9 < 2 2V.Acrytonitrile X < 20 < 4.47 1 u /I lb/Day100 (107-13-1) g < 2 3V.Benzene X 2 0.45 1 ugA lb/Day < 2 2 (71-43-2) 4V.Bis(Chloro• - - methyl)Ether X (542.88.1) 5V.Bromofonn X < 2 < 0.45 1 ug/I lb/Day < 2 2 (75.25.2) 8V.Carbon Tetrachloride X < 2 < 0.45 1 u (58-23-5) 9A lb/Day < 2 2 7V.Chlorobenzene X < 2 < 0.45 1 u A (108-90.7) g lb/Day < 2 2 8V.Chlorodi- - (blr2n or4 &ethane X < 2 < 0.45 1 ugh) lb/Day < 2 2 9V.Chloroethane X < 2 < 0.45 1 J ugh - lb/Day < 2 2 (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 2 < 0.45 1 ugA lb/Day < 2 2 (110-75.8) . 11V.Chloroform X < 2 < 0.45 1 ugh lb/Day < 2 2 (67-66-3) 12V.Dichloro- bromomethane X < 2 < • 0.45 1 u A (75-27-4) g lb/Day < 2 2 13V.DIchloro- dit)uoromethane X < 2 < 0.45 1 ugA lb/Day < 2 2 (75-51-8) 14V.1,1-Dlchloro- X < 2 < 0.45 1 ugA lb/Day < 2 2 ethane(75.34-3) 15V.1,2-Dichtoro- X < 2 < 0.45 1 ugA lb/Day < 2 2 ethane(107-06-2) 1eV.1,1-Dichloro- X < 2 < 0.45 1 u A lb/Day ethylene(75-35-4) 9 Y < 2 2 17V.1,2-Dichloro- X < 2 < 0.45 1 ugA lb/Day < 2 2 propane(78.87-5) 18V.1,3-Dichloro- X < 2 < 0.45 1 ug/I lb/Day < 2 2 propylene(542-75-6) 19V.Ethylbenzene X < 2 < 0.45 1 ug/l lb/Day < 2 2 (100-41-4) 20V.Methyl X < Bromide(74-83-9) 5 < 1.12 1 u9A lb/Day < 5 2 21V.Methyl X < 2 < 0.45 Chloride(74-87.3) 1 ugA lb/Day < 2 2 EPA Form 3510.2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5. INTAKE(optional) • AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration 1(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X < 2 < 0.45 1 ugh lb/Day ' < 2 2 Chloride(75-09-2) 23V.1,1,2,2-Tetra- chloroethane X < 2 < 0.45 1 ug/I lb/Day < 2 2 (79-34-5) 24V.Tetrachloro- X - < 2 ' < 6,45 1 ugh lb/Day < 2 2 ethylene(127-18-4) 25V.Toluene X < 2 < 0.45 1 ugh lb/Day < 2 2 (108-88-3) 26V.1,2-Trans- Dichtoroethytere X < 2 < 0.45 1 ugh lb/Day < 2 2 (156-60-5) 27V.1,1,1-TA- ' chloroethane X < 2 < 0.45 1 ugh lb/Day < 2 2 (71-55-6) 28V.1,1,2-Td- chtoroethane X < 2 < 0.45 1 ugh lb/Day < 2 2 (79-00-5) 29V.Trichloro- X < 2 < 0.45 ethylene1 Ugh lb/Day < 2 2 (79-01-6) 30V.Trichloro- 6uorometane X < 2 < 0.45 1 ugh lb/Day < 2 2 (75-69-4) 31V.Vinyl X < 2, " < 0.45 1 ugh lb/Day < 2 2 Chloride(75-01-4) (iG/MS I-FKAG I ILK-AL.L)GU POUNDS 1A 2-Chiorophend X < 10 < 2.24 1 ugh lb/Day < 10 2 (95-57-8) 2A.2.4-Dlchioro- X < 10 < ' 2.24 1 ugh lb/Day < 10 2 phenol(120-83-2) 3A.2,4-Dimethy4 X < 10 < 2.24 1 ugh lb/Day < 10 2 phenol(105-67-9) 4A.4,6-Dwtro-O- X < 25 < 5.59 1 ugh lb/Day < 25 2 Cresol(534-52-1) 5A.2,4-Dwuo X < 25 < 5.59 1 ugh lb/Day < 25 2 phenol(51-28-5) 6A.2-Nitrophenol X ' < 10 < 2.24 1 ugh lb/Day < 10 2 (88-75-5) 7k4-Nltrophend X < 25 < 5.59 1 ugh lb/Day < 25 2 (100-02-7) 8A.P-ChbwM- X < 10 < 2.24 1 ugh lb/Day < 10 2 Cresol(59-50-7) 9A.Pentachioro- X < 25 < 5.59 1 ugh lb/Day < 25 2 phenol(87-86-5) 10A.Phenol X < 10 < 2.24 < 10 < 2.24 < 10 < 1.73 5 ugh lb/Day < 10 2 (108-95-2) 11A.2,4,6-Tri- ' chtorophenol X < 10 < 2.24 1 ugh lb/Day < 10 2 (8-0-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.Acenaphthene X < i0 < 2.24 1 ug/I lb/Day < 10 2 (83.32.9) 2B.Acenaphtylene X < 14 < 2.24 1 ug/I lb/Day < 10 2 (208-96-8) 38.Anthracene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (120-12-7) 4B.Benztdine X < 80 < 17.89 1 ugA lb/Day < 100 2 (92.87.5) Anthracene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (56-55-3) 68.Benzo(a) X < TO < 224 1 ug/I lb/Day < 10 2 Pyrene(50.32.8) _ 78.3,4•Benzo. ' 6uoranthene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (205-99-2) 88.Benzo(phi) X < 10 < 2.24 1 ug/I lb/Day < 10 2 Perylene(191-24-2) 9B.Benzo(k) Fluoranthene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (207-08-9) 1013.Bis(2-Chloro- ethoxyl)Methane X < 10 < 2.24 1 ug/I lb/Day < 10 2 (111-91.1) 118.Bis(2-Chloro- ethyl)Ether X < 10 < 2.24 1 ug/I lb/Day < 10 2 (111-44-4) 128.81s(2-Chlorolso- propyl)Ether X < 10 < 2.24 1 ug/I lb/Day < 10 2 (108-60-1) 138.Ws(2-Ethy1- haxyl)Phehalate X 170 38.02 1 ug/I lb/Day 19 2 (117-81-7) 148.4-Brom ` o phenyl Phenyl X < 10 < 2.24 1 ug/I lb/Day < 10 2 Ether(101.55.3) 158.Butyl Benzyl X < 10 < 2.24 1 ug/I lb/Day < 10 2 Phthalate(85.68.7) 168.2-Chloro- naphthalene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (91-58-7) 178.4-Chloro- phenyl Phenyl X < 10 < 2.24 1 ug/I lb/Day < 10 2 Ether(7005-72-3) 188.Chrysene X < 10 < 2.24 - 1 ugA lb/Day < 10 2 (218-01-9) 198.Dibenzo(a.h) Anthracene X < 10 < 2.24 1 ug/I lb/Day < 10 2 (53-70-3) 208.1,2-Dichloro- X < 10 < 2.24 - 1 ug/IIb/Day < 10 2 benzene(95-50-1) 2113.1,3-Dtchloro- X < 10 < 2.24 - 1 ug/I lb/Day < 10 2 benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re. b.pre. dale a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quip sent sent (If available) (if available) (If available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 228.1,4-Dichloro- X < 10 < 2.24 1 ugA lb/Day < 10 2 benzene(106-46-7) 238.3,3-Dichloro- benzidine X < 25 < 5.59 1 u /I (91-94-1) 9 lb/Day < 25 2 248.Dleelyt - Phthalate X < 10 < 2.24 1 u (84-66-2) tin lb/Day < 10 2 258.Dlmethyl Phthalate X < 10 < 2.24 1 ug/I lb/Day < 10 2 (131-11-3) 26B.DIN-Butyl Phthalate X < 10 < 2.24 1 ug/I lb/Day < 10 2 (84-74-2) 278.2,4-Dinitro. X < 10S- < Z.24 1 ug/I 5/Day ' < 10 2 toluene(121.14-2) 288.2,E Dirutro- X - < 10 < 2.24 1 ugn lb/Day < 10 2 toluene(606-20-2) 298.Di-N-Octyt '-' . Phthalate X < 10 < 2.24 1 u /I (117-84-0) 9 lb/Day < 10 2 308.1,2-Diphenyl- hydrazlne(as Azo- X < 10 < 2.24 1 ugA lb/Day < 10 2 benzene)(122-66-7) 318.Fluoranthene X - ' < 10 < 2.24 1 ugA lb/Day < TO 2 (206-44-0) . 32B.Fluorene X < 10 < 2.24 1 ugh lb/Day < 10 2 (86.73-7) 338.Hexachloro- X < TO ' < 2724 1 ugh lb/Day ' < 10 2 benzene(118.74-1) 34B.lieu- - . chtorobutadiene X < 10 < 2.24 1 ug/1 lb/Day < 10 2 (87.68-3) 358.Hexachloro- cydapentadiene X < 25 < 5.59 1 ug/I lb/Day < 25 2 (77-47-4) 368.Hexachtoro- X < 10 < 2.24 1 ' ugh lb/Day < 10 2 • ethane(67-72-1) 37B.Indeno , (1,2,3•cd)Plan X < 10 < 2.24 1 ugh lb/Day < 10 2 (193.39-5) 3.lsopttorone X < 10 < 2.24 A 1 Ugh Ib/Day < TO 2 398.Naphthalene X < 16- < 2.249-1) 1 ugA lb/Day < AO 2 (91-20-3) 40B.Nitrobenzene X < 16- < 2.24 (98-95-3) 1 U9A 167DaY < 10 2 418.N-Nitro- (sodimethylamine X < 10 < 2.24 1 ugh lb/Day < 10 2 428.N-Nltroaodl- N-Propylamine X < 10 < '2.24 1 ugA lb/Day < 10 2 (621-64-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 438.N•Nitro- sodlphenylamine X < 10 < 2.24 1 ugh lb/Day < 10 2 (86-30-6) 44B.Phenanthrene X < 10 < 224 1 ugh - lb/Day < 10 2 (85-01.8) 458.Pyrene X < 10 < 2.24 1 ugh lb/Day < 10 2 (129-00-0) 46B.1,2,4-Td- chtorobenzene X < 10 < 2.24 1 ugh lb/Day < 10 2 (120-82-1) GUMS P XAc I ION'-l- S I IclUEJ 1P.Aldrin X ugh lb/Day (309-00-2) 2P.alpha-BHC X ugh lb/Day (319-84-6) 3P.beta-BHC X ugh lb7Day (315-85-7) 4P.gamma-BHC X ugh lb/Day (58-89-9) 5P.delta-BHC X ugh lb/Day (319-86-8) 6P.Chlordane X ugh lb/Day (57-74-9) 7P.4,4'-DDT X ugh lb/Day (50-29-3) 8P.4,4'-DDE X ugh lb/Day (72-55-9) 9P.4,4'-DDD X ugh lb/Day (72-54-8) 10P.Dieldr+n X ugh lb/Day (60-57-1) 11P.atpha-Endosulfan X ugh lb/Day (115-29-7) 12P.beta-Endosulfan X ugh lb/Day (115-29-7) 13P.Endosulfan Sulfate X ugh (1031-07-8) 14P.Endrin X ugh lb/Day (72-20-8) 15P.Endrin Aldehyde X ugh (7421-93-4) 16P.Heptachlor X ugh lb/Day (76-44-8) EPA Fonn 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 002 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re• b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quit- sent sent (If available) Of available) (If available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration ' (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor - Epoxide X ug/I lb/Day (1024-57.3) 18P.PCB-1242 X 1 - ug/I lb/Day - (53469-21-9) 1 19P.PCB-1254 X - ugh lb/Day - (11097-69-1) 20P.PCB-1221 X ug/I lb/Day - (11104-28-2) 21P.PCB-1232 X ugA lb/Day ' (11141-16-5) 22P.PCB-1248 X ugA lb/Day (12672-29-6) 23P.PCB-1260 X ' ug/I lb/Day - (11096.82-5) 24P.PC8-1016 X ' - ugA lb/Day - (12674-11-2) 25P.Tozaphene X ugh lb/Day (8001.35-2) ' EPA EOM 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 003 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Conan- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen 2 75.1 1 mg/I lb/Day Demand(BOD) b.Chemical Oxygen < 20 < 751.1 1 mg/I lb/Day Demand(COD) c.Total Organic 2.71 101.8 1 mg/I lb/Day Carbon(TOC) d.Total Suspended 17 838.4 1 mg/I lb/Day Solids(TSS) e.Ammonia(as N) 0.07 2.6 1 mg/I lb/Day f.Row VALUE VALUE VALUE MGD X VALUE 4.5 4.5 4.5 52 g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE (summer) 20.8 1 DEGREES CELSIUS i.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 6.91 ' 1 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"x" 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.p e- b.ab- (if available) (if available) d.NO.OF a.Cancan- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X 0.293 11.0 1 mg/I lb/Day (24959-67-9) b.Chlorine. X < 0.2 < 7.5 1 mg/I lb/Day Total Residual c.Color X 15 X 1 Std.Units X X d.Fecal X 22 X 1 Colonies X X Co lform /100 ml e.Flouride X 0.2 7.5 1 mg/I lb/Day (16984-48-8) f.Nitrate- X 0.17 6.4 1 mg/I lb/Day Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 003 1.POLLUTANT 2.MARK•X' 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) a.pre- b.ab• (if available) (if available) d.NO.OF a.Concern b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES g.Nitrogen, Total Organic X 0.33 12.4 1 mg/I lb/Day (as N) h.Oil and Grease X < 5 < 187.8 1 mg/I lb/Day I.Phosphorous (as P),Total X 0.03 1.1 1 mg/I lb/Day (7723-14-0) 1.Radioactivity (1)Alpha. ' Total X 1.050E+00 X 1 pCi/I X (2)Beta, Total X 2.220E+00 X 1 pCi/I X (3)Radium, - Total X < 0.3 < X 1 pCi/I X (4)Radium 226,Total X 0.2 X 1 pCi/I X k Sulfate (aa SO4) X 6.93 260.2 1 mg/I lb/Day (14808-79-8) I.Sulfide (as S) X < 0.05 < 1.9 1 mg/I lb/Day m.Sulfite (as S03) X < 2 < 75.1 1 mg/I lb/Day (14265.45-3) n.Surfactants X < 0.1 < 3.8 1 mg/I lb/Day o.Aluminum, Total X 0.2228 8.4• 1 mg/I lb/Day (7429-90-5) p.Barium, Total X 0.022 0.8 1 mg/I lb/Day (7440-39-3) q.Boron, Total X 0.105 3.9 1 mg/I lb/Day (7440-42-8) r.Cobalt, Total X < 1 < 37.6 1 mg/I lb/Day (7440.48-4) s.Iron,Total (7439-89-6) X 0.503 18.9 1 mg/I Ib/Day t.Magnesium, Total X 1.775 66.7 1 mg/I lb/Day (7439-95-4) u.Molybdenum, Total X 0.00157 0.1 1 mg/I lb/Day (7439-98-7) v.Manganese, Total X 0.046 1.7 1 mg/I lb/Day (7439-96-5) w.Tin,Total (7440-31-5) A < 0.05 < 1.9 1 mg/ Ib/Day x.Titanium, Total X 0.024 0.9 1 mg/I lb/Day (7440.32.8) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V.3 k EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 003 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge In concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- nab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony, X - < 3 ' < 0.11 1 ugh lb/Day Total(7440.36-0) 2M.Arsenic,Total X < 2 < 0.08 1 ug/I lb/Day (7440-38-2) 3M.Beryllium, X < 575 < 0.02 1 ugA lb/Day Total(7440-41-7) 4M.Cadmium, X < 0.5 < 0.02 1 ugA lb/Day Total(7440-43-9) 5M.Chromium, X 1.03 0.04 1 ugh) lb/Day Total(7440-47-3) 6M.Copper,Total X 0.016 0.60 1 mgA lb/Day (7440-50-8) 7M.Lead,Total X - < 2 < 0.08 - 1 ugA Ib/Day (7439.92-1) 8M.Mercury,Total X < 0.1- < - 0.00 1 - ugh) lb/Day (7439.97-8) 9M.Nickel,Total X < 2 < 0.08 1 ug/I lb/Day (7440-02-0) 10M.Selenium, X < 2 < 0.08 1 ugA lb/Day Total(7782-49-2) 11M.Silver,Taal X < 0.5 < 0.02 1 ug/l lb/Day (7440-22-4) - 12M.Thallium, X < 0.002 < 0.1 1 mg/I lb/Day Total(7440-28-0) 13M.Zinc,Total X < 0.02 < 0.75 1 mgA lb/Day (7440.66.6) 14M.Cyanide, X 0.002 0.08 1 mgA Ib/6ay Total(57-12-5) 15M.Phenols, X 0.093 3.5 1 mg/ lb/Day Total UIUXIN .3,7,8 Tetra DESCRIBE RESUL I S lorodibenzo P X �bxIn(1764-01.6) NOT DETECTED EPA Form 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 . 7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre-cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1V.AerateIn X < 20 < 0.75 1 ug/I lb/Day (107-02-8) 2V.Acryloniaile X < 20 < 0.75 1 ug/I lb/Day (107.13-1) 3V.Benzene X - < 2 < 0.68 1 ug/I lb/Day (71-43-2) 4V.Bia(Chioro methyl)Ether X (542-88-1) 5V.Bromofonn X < 2 < 0.08 1 ug/I lb/Day (75-25-2) 6V.Carbon Tetrachloride X < 2 < 0.08 1 ug/I lb/Day (56.23.5) 7V.Chlorobenzene X < 2 ' < 0.08 1 ug/I lb/Day (108.90-7) 8V.Chlorodi- bromomethane X < 2 < 0.08 1 ug/I lb/Day (124-48-1) 9V.Chloroethane X <-2 ' < 0.08 1 ug/I lb/Day (75-00-3) 10V.2-Chloro- ethylvinyl Ether X < 2. < 0.08 1 ug/I lb/Day (110-75-8) 11V.Chlorofomr X < 2 < 0.08 1 ug/I lb/Day (67-66-3) 12V.Dichloro • - bromomethane X < 2 < 0.08 1 ug/I lb/Day (75.27-4) 13V.Dichloro- dinuoromethane X < 2 < 0.08 1 ug/I lb/Day (75-51-8) 14V.1,1-Dichiaro- X < 2 < 0.08 1 ug/I lb/Day ethane(75-34-3) 15V.1,2-Dlchlao X < 2 < 0.08 1 ug/I lb/Day ethane(107-08-2) 16V.1,1-Dichioro- X < 2 < 0.08 1 ug/I lb/Day ' ethylene(75-35-4) 17V.1,2-Dichioro- X < 2 < 0.08 1 ug/I lb/Day propane(78.87-5) 18V.1,3-Dlchloro- X < 2 < 0.08 1 ug/I lb/Day propylene(542-75-6) 19V.Ethylbenzene X < 2 < 0.08 1 ug/I lb/Day (100-41-4) 20V.Methyl X < 5 < 0.19 - 1 ug/I lb/Day Bromide(74-83-9) 21V.Methyl X < 2 < 0.08 1 ug/I lb/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V-5 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Goncen- b.Mass O.NO.OF ad (1)Concentration 1(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES (ration (1)Concentration i (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X < 2 - < 0.08 1 ug/I lb/Day Chloride(75-09-2) 23V.1.1,2,2-Tetra- chlorcethane X < 2 < 0.08 1 ug/I lb/Day (79-34-5) 24V.Tetrachloro- X < 2 < 0.08 1 ug/I lb/Day ethylene(127-18-4) 25V.Toluene R < 2 < 0.08 1 ug/I lb/Day (108-88-3) 28V.1,2-Trans- Dichloroethylene X < 2 < 0.08 1 ug/I lb/Day (158-605) 27V.1,1,1-Trl- chtoethane X <ro 2 < 0.08 1 ug/I lb/Day (71-55-6) 28V.1,1,2-Trl- <chloroethane X 2 < 0.08 1 ug/I lb/Day (79-00-5) 29V.Trichloro- X < 2 < 0.08 1 ug7f Ib7Day ethylene(79-01-6) 30V.Trichloro- ffuoromethane X < 2 < 0.08 1 ug/Ilb/Day (75-69-4) 31V.Vinyl X < 2. < 0.08 1 ug/I lb/Day Chloride(75-01-4) )jL/MS FNAL I IUPi-ALL)LUMI-VUNUS 1A.2-Chlorophend X < 10 < 0.38 1 ug/I lb/Day (95-57-8) • 2k 2,4-Dichloro- X < 10 < 0.38 1 ug/I lb/Day phenol(120-83-2) 3A.2.4-Dimethyl- X < 10 < 0.38 1 ugA lb/Day phenol(105-67-9) 4A 4,6-Dinitro-0- X < 25 < 0.94 1 ug/I lb/Day Cresol(534-52-1) . 5A.2,4-Dinitro- X < 25 < 0.94 1 ug/I lb/Day phenol(51-28-5) 6A.2-Nitrophenol X < 10 < 0.38 1 ug/I lb/Day (88-75-5) 7A.4-Nitrophenol X < 25 < 0.94 1 ug/I lb/Day (100-02-7) 8k P-Chloro-M- X < 10 < 0.38 1 ug/I lb/Day Cresol(59-50-7) 9A.Pentachloro- X < 25 < 0.94 1 ug/I lb/Day phenol(87-86-5) 10A.Pheno X < 10 < 0.38 1 ug/I lb/Day (108-95-2) 11A.2,4,6.Tn- chlorophend X < 10 < 0.38 1 ug/I lb/Day (88-06-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re• b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quit, sent sent (If available) (If available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 18.Acenaphthene X < 10 < 0.38 1 ug/I lb/Day (83-32.9) 28.Acenapltytene X < 10 < 0.38 1 ug/l lb/Day (208-98-8) 38.Anthracene X - - < i0 '< 0,38 1 ugh lb/Day (120-12-7) 48.Benzidine X < 80 < 3,00 1 ugh lb/Day (92-87.5) 58.Benzo(a) Anthracene X < 10 < 0.38 1 ugh lb/Day (56.55-3) 68.Benzo(a) X < 10 < 0.38 1 ugh lb/Day Pyrene(50-32-8) 7B.3,4-Benzo• fluaranthene X < 10 < 0.38 1 ugh lb/Day (205-99-2) 88.Benzo(phi) X - < 10 < 0 38 1 ugh lb/Day Perylene(191-24-2) 98.Benzo(k) - Fluoranthene X < 10 < 0.38 1 ugh lb/Day (207-08-9) 108.Bis(2-Chloro- ethoxyl)Methane X < 10 < 0.38 1 ugh lb/Day (111-91-1) 11B.Bis(2-CMoro- ethyl)Ether X < 10 < 0.38 1 ugh lb/Day (111-44-4) 128.8is(2-Clrloroiso- propy0 Ether X < 10 < 0.38 1 ugh lb/Day (108.80.1) • 13B.Bis(2-Ethyl- hexy)Phehalate X < 36 < 1.35 1 ugh lb/Day (117-81-7) 14B.4-Bromo- phenyl Phenyl X < 10 < 0.38 1 ugh lb/Day Ether(101-55-3) 158.Butyl Benzyl X < 10 < 0.38 1 ugh lb/Day Phthalate(85-68-7) 168.2-Chioro- naphthalene X < 10 < 0.38 1 ugh lb/Day (91-58-7) 178.4-Chtoro. phenyl Phenyl X < 10 < 0.38 1 ugh) lb/Day Ether(7005-72-3) 18B.Chrysene X < 10 < 0.38 1 ugh lb/Day (218-01-9) 198.Dibenzo(a.h) Anthracene X < (53.70.3) 10 < 0.38 1 ugh lb/Day 208.1,2-Dicnbro- X < 10 < 0.38 1 ugh) lb/Day benzene(95-50-1) 21B.1,3-Dichloro- X ' < 10 < 0.38 1 ug/l lb/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. axe- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 228.1,4-Dichloro- X < 10 < 0.38 1 ug/I Ib/Day benzene(106-46-7) 23B.3,3-Dichloro- benzldine X < 10 < 0.38 1 ug/I lb/Day (91.94-1) 248.Diethyl Phthalate X < 10 < 0.38 1 ug/I lb/Day (84.66-2) 258.[timothy! Phthalate X < 10 < 0.38 1 ugA lb/Day (131-11-3) 268.DI-N-Butyl Phthalate X < 10 < 0.38 1 ug/I lb/Day (84-74-2) 278.2,4-Dlnitro- X < 10 < 0 38 I ug/I lb/Day toluene(121-14-2) 288.2,6-Dinitro- X < 10 < 0.38 i - ugA Ib/Day toluene(606-20-2) 298.DI-N-Octyl Phthalate X < 10 < 0.38 1 ugA lb/Day (117-84-0) 308.1,2-Diphenyl- hydrazine(as Azo- X < 10 < 0.38 1 ug/I lb/Day benzene)(122.66-7) 318.Fluoranthene X < 10 < 0.38 1 ug/I lb/Day (206-44-0) • 32B.Fluorene X - < 1-0 ' < 0.38 1 ug/I lb/Day (86-73.7) 338.Hexachloro- X ' < 10 < 0.38 1 ug/I lb/Day benzene(118-74-1) , 348.Hexa- chlorobutadiene X < 10 < 0.38 1 ug/I lb/Day (87438-3) 358.Hexachloro- cyclopentadiene X < 25 < 0.94 1 ugA lb/Day (77-47-4) 388.Hexachloro- X < 10 < 0.38 1 ug/I lb/Day ethane(67-72-1) 378.Indeno (1,2,3-cd)Pyrene X < 10 < 0.38 1 ug/I lb/Day (193-39-5) 388.Isophorone X < 10 < 0.38 1 ugA lb/Day (78-59-1) 39B.Naphthalene X < 10 < 0.38 1 ug/I lb/Day (91-20-3) 408.Nitrobenzene X < 10 < 0.38 - 1 ug/I lb/Day (98-95-3) 418.N-Nitro- sodimethylamine X < 10 < 0.38 1 ug/I lb/Day (62-75-9) 42B.N-Nitrosodi- N-Propylamine X < 10 < 0.38 1 ugA lb/Day (621-64-7) e EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (If available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tratiOn (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 43B.N-Nitro- sodlphenylamine X < 10 < 0.38 1 (86-30-6) 44B.Phenanthrene X < 10 < 0.38 (85-01-8) 458.Pyrene X < 10 < 0.38 1(129-00-0) 488.1,2,4•Tri- chlorobenzene X < 10 < 0.38 1 (120-82-1) GC/MS FKAC.I iO 1-I'ES I IGIDI_S 1P.Aldrin - X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC - X (58-89-9) 5P.delta-BHC X (319-86-8) • 6P.Chlordane X (57-74-9) 7P.4,4'-DOT X (50-29-3) 8P.4,4'-DDE X (72-55.9) 9P.4,4'-DDD X (72-54-8) 10P.Dieldrin X (80.57-1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin - X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X (78-44-8) EPA Form 3510.2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 003 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- c.ab• a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE C.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (If available) (if available) (If available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X (53469-21-9) 19P.PCB-1264 X (11097-69-1) 20P.PCB-1221 X (11104-28-2) 21P.PCB-1232 X (11141-16-5) 22P.PCB-1248 X (12672-29-6) 23P.PCB-1260 X (11096-82-5) 24P.PCB-1016 X (12674-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I.D.NUMBER(copy from Item 1 of Form 1) this information on separate sheets(use the same format)instead of completing these pages. SEE INSTRUCTIONS NC0004979 OUTFALL NO. V.INTAKE AND EFFLUENT CHARACTERISTICS(continued from page 3 of Form 2-C) 004 PART A-You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. 2.EFFLUENT 3.UNITS 4.INTAKE(optional) 1.POLLUTANT a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Biochemical Oxygen 6 325.5 1 mg/I lb/Day Demand(BOO) b.Chemical Oxygen < 20 < 1084.9 1 mg/ lb/Day Demand(COD) c.Total Organic < 20 < 1084.9 1 mg/I lb/Day Carbon(TOC) d.Total Suspended 8 433.9 1 mg/I lb/Day Sale(TSS) s.Ammonia(as N) 0.08 4.3 1 mg/ lb/Day IS.Flow VALUE VALUE VALUE MGD X VALUE ' 6.5 6.5 6.5 52 g.Temperature VALUE VALUE VALUE VALUE (winter) DEGREES CELSIUS h.Temperature VALUE VALUE VALUE VALUE . (summer) 20.3 1 DEGREES CELSIUS i.pH MINIMUM MAXIMUM MINIMUM MAXIMUM 7.2 1 STANDARD UNITS PART B-Mark"X"in column 2a for each pollutant you know or have reason to believe is present.Mark"X"in column 2b for each pollutant you believe to be absent.If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline,you must provide the results of at least one analysis for that pollutant.For other pollutants for which you mark column 2a,you must provide quantitative data or an explanation of their presence in your discharge.Complete one table for each outfall.See the instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 2.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES a.Bromide X 0.247 13.4 1 mg/I lb/Day (24959-67-9) b.Chlorine. X < 0.25 < 13.6 1 mg/I lb/Day Total Residual c.Color X 20 X 1 Std.Units X d.Fecal X 26 X 1 Colonies X Coliform /100 ml e.Flounde X 0.19 10.3 1 mg/I lb/Day (16984-48-8) f.Nitrate- X 0.16 8.7 1 mg/I lb/Day Nitrite(as N) EPA Form 3510-2C(Rev.2-85) PAGE V-1 CONTINUE ON PAGE V-2 X EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER ITEM V-B CONTINUED FROM FRONT NC0004979 004 1.POLLUTANT 2.MARK'X" 3.EFFLUENT 3.UNITS 4.INTAKE(optional) AND CAS NO. a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) a.pre- b.ab- (if available) (if available) d.NO.OF a.Concen- b.Mass b.NO.OF sent sent (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration 9 Nitrogen (2)Mass ANALYSES Nation (1)Concentration (2)Mass ANALYSES Total Organic X 0.42 22.8 1 mg/I lb/Day (as N) h.Oil and Grease X < 5 < 271.2 < 5 < 271.2 < 5 < 271.2 5 mg/I lb/Day I.Phosphorous (as P),Total X 0.05 2.7 1 mg/I lb/Day (7723-14-0) I.Radioactivity (1)Alpha. - - Total X < -2.60E-01 < X 1 pCVI X (2)Beta, Total X 1.99E+00 X 1 pCVI X (3)Radium, Total A < 0.3 < X 1 pCi/I X (4)Radium 226,Total X < 0.2 < X 1 pCUI X K.Sulfate (as SO4) X 8.72 473.0 1 mg/I lb/Day (14808-79-8) I.Sulfide (as S) X < 0.05 < 2.7 1 mg/I lb/Day m.Sulfite (as S03) A < 2 < 108.5 1 mg/I lb/Day (14286-45-3) n.Surfactants X < 0.1 < 5.4 1 mg/I lb/Day o.Aluminum, Total A 0.2455 13.3' 1 mg/I lb/Day (7429-90-5) p.Barium, Total X 0.019 1.0 1 mg/I lb/Day (7440-39-3) q.Boron, Total X < 0.1 < 5.4 1 mg/I lb/Day (7440-42-8) r.Cobalt, Total X < 1 < 54.2 1 mg/I lb/Day (7440-48-4) s.Iron,Total (7439-89-6) X 0.527 28.6 1 mg/I lb/Day t.Magnesium, Total X 1.924 104.4 1 mg/I lb/Day (7439-95-4) u.Molybdenum, Total X 0.00138 0.1 1 mg/I lb/Day (7439-98-7) v.Manganese, Total A 0.071 3.9 (7439-98-5) 1 mg/I lb/Day w.Tin,Total (7440-31-5) X < 0.05 < 2.7 1 mg/I lb/Day x.Titanium, Total A 0.017 0.9 1 mg/I lb/Day (7440.32.6) EPA Form 3510-2C(Rev.2-85) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C NC0004979 004 PART C-If you are a primary industry and this outfall contains process wastewater,refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for.Mark"X"in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals,cyanides,and total phenols.If you are not required to mark column 2-a(secondary industries, nonprocess wastewater outfalls,and nonrequired GC/MS fractions),mark"X"in column 2-b for each pollutant you know or have reason to believe is present.Mark"X"in column 2-c for each pollutant you believe is absent.If you mark column 2a for any pollutant,you must provide the results of at least one analysis for that pollutant.If you mark column 2b for any pollutant,you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater.If you mark column 2b for acrolein,acrylonitrile,2,4 dinitrophenol,or 2-methyl-4,6 dinitrophenol,you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater.Otherwise,for pollutants for which you mark column 2b,you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged.Note that there are 7 pages to this part;please review each carefully.Complete one table(all 7 pages)for each outfall.See instructions for additional details and requirements. 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quit- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF • ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES METALS,CYANIDE,AND TOTAL PHENOLS 1M.Antimony, X < 3 < 0.16 1 ugA lb/Day Total(7440-36-0) 2M.Arsenic,Total X < 2 < 0.11 1 ug/I lb/Day (7440-38-2) 3M.Beryllium, X < 0.5 < 0.03 1 ugA lb/Day Total(7440.41-7) 4M.Cadmium, X < 0.5 < 0.03 1 ugh lb/Day Total(7440-43-9) 5M.Chromium, X < I < 0.05 1 ugh lb/Day Total(7440-47-3) 6M.Copper,Total X 0.007 0.38 1 mg/I lb/Day (7440-50-8) 7M.Lead,Total X < 2 < 0.11 1 ugA lb/Day (7439-92-1) 8M.Mercury.Total X < 0.1 < - 0.01 1 ugA lb/Day (7439-97-6) 9M.Nickel.Total X < 2 < 0.11 1 ugh lb/Day (7440-02.0) 10M.Selenium, X < 2 < 0.11 1 ugA lb/Day Total(7782.49.2) 11M.Slaver,Total X < 0.5 < 0.03 1 ugh lb/Day (7440-22-4) 12M.Thallium, X < 0.002 < 0.1 1 mg/ lb/Day Total(7440-28-0) 13M.Zinc,Total X < 0.02 < 1.08 1 mg/ lb/Day (7440-66-6) 14M.Cyanide, X < 0.002 < 0.11 1 mg/ lb/Day Total(57-12-5) 15M.Phenols. X 0.028 1.5 1 mg/I lb/Day Total DIOXIN 2,3,7,8 Tetra DESCRIBE RESULTS chlorodibenzo P X NOT DETECTED Dioxin(1764-01-6) EPA Fonn 3510-2C(Rev.2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-3 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre-c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS 1v.Acrolein X < ' 20 < 1.08 1 ugh lb/Day (107-02-8) 2V.AcrybNtrue X < 20 < 1.08 1 ugh lb/Day (107-13-1) 3V.Benzene X < 2 < 0.11 1 ugh lb/Day (71-43-2) 4V.BM(CNoro- methyl)Ether X (542-88-1) 5V.Bromoform X '< i < 0.'fi 1 ug/I lb/Day (75-25-2) 6V.Carbon Tetrachloride X < 2 < 0.11 1 ugh lb/Day (56-23-5) 7v.Chlorobenzene X < 2 < 0.11 1 ugh lb/Day (108-90-7) BV.Chlorodi- bromomethane X < 2 < 0.11 1 ug/I lb/Day (124-48-1) 9V.Chloroethane X < 2 < 0.11 1 ug/I lb/Day (75-00-3) 10V.2-Chlaro- ethytvinyl Ether X < 2 < 0.11 1 ug/I lb/Day (110-75-8) 11V.Chloroform X < 2 < 0.11 1 ug/I lb/Day (67-66-3) 12V.Dichloro- - bmmomethane X < 2 < 0.11 1 ug/I lb/Day (75-27-4) 13V.Dichloro- difluoromethane X < 2 < 0.11 1 ugh lb/Day (75-51-8) 14V.1,1-Dichioro- X < 2 < 0.11 1 ug/I lb/Day ethane(75-34-3) 15V.1,2-Dichioro- X < 2 < 0.11 1 ugh lb/Day ethane(107-06-2) 16VV.1,1-Dicnloro- X < 2 < 0.11 1 ugh lb/Day ethylene(75-35-4) 17V.1,2-Dichloro- X < 2 < 0.11 1 ugh lb/Day propane(78-87-5) 18V.1,3-Dichloro- X < 2 < 0.11 _ 1 ugh lb/Day propylene(542-75-6) 19V.Ethylbenzene X < 2 < 0.11 1 ugh lb/Day , (100-41-4) 20V.Methyl X < b < 0.27 1 ugh lb/Day Bromide(74-83-9) 21V.Methyl X < 2 < 0.11 1 ugh lb/Day Chloride(74-87-3) EPA Form 3510-2C(Rev.2-85) PAGE V-4 CONTINUE ON PAGE V•5 k EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-4 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I(2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tratiOn (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-VOLATILE COMPOUNDS(continued) 22V.Methylene X < 2 < 0.11 1 ugh lb/Day Chloride(75-09-2) 23V.1,7.2,2-Tetra- chbroethane X < 2 < 0.11 1 ugh lb/Day (79-34-5) 24V.Tetrachloro- X < 2 < 0.11 1 ugh lb/Day ethylene(127.18-4) 25V.Toluene X < 2 < 0.11 1 ugh lb/Day (108-88-3) 26V.12-Trans- Dichlaroethylene X < 2 < 0.11 1 ugh lb/Day (156.80.5) 27V.1,1,1411- chloroethane X < 2 < 0.11 1 ugh lb/Day (71-55-6) 28V.1,12-Tn- chloroethane X < 2 < 0.11 1 ugh lb/Day (79-00-5) 29V.Trichioo- X < 2 < 0.11 1 ugh lb/Day ethylene(79-01-6) 30V.Tr chlaro- fluoromethane X < 2 < 0.11 1 ugh lb/Day (75-69-4) 31V.Vinyl X < 2, < 0.11 1 ugh lb/Day Chloride(75-01.4) LiC/MS I-KAC I ION'-ACID LA)VIPOUNUS 1A.2-Chlorophenol X < 10 < 0.54 1 ugh lb/Day (95-57-8) 2A.2,4-Dichloro- X < 10 < 0.54 1 ug/I lb/Day phenol(120.83.2) 3A.2,4-Olmemyl- X < 10 < 0.54 1 ugh lb/Day phenol(105-67-9) 4A.4,6-Dinitro-0- X < 25 < 1.36 1 ugh lb/Day Cresol(534-52-1) 5A.2.4-Dinitro. X < 25 < 1.36 1 ugh lb/Day phenol(51-28-5) 8A 2-Nitrophenol X < 10 < 0.54 1 ugh lb/Day (88-75-5) 7A.4-Nitrophenol X < 25 < 1.36 1 ugh lb/Day (100-02-7) 8A.P-Chloro-M- X < 10 < 0.54 1 ugh lb/Day Cresol(59-50-7) 9A.Pentachloro- X < 25 < 1.36 1 ugh lb/Day phenol(87-86-5) 10A.Phenol X < 10 < 0.54 1 ugh lb/Day (108-95-2) 11k 2,4,6-Tri- ahbrophenol X < 10 < 0.54 1 ugA lb/Day (8-0-2) EPA Form 3510-2C(Rev.2-85) PAGE V-5 CONTINUE ON PAGE V-6 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-5 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re. b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir• sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE NEUTRAL COMPOUNDS 1B.Acenaphthene X < 10 < 0.54 1 ug/I Ib/Day (83-32.9) 28.Acenaphthene X < 10 < 0.54 1 ugh lb/Day (208-96-8) 3B.Anthracene X < TO < 0754 f ugh lb/Day (120-12-7) 4B.Benzidine X < 86 < 4.34 1 ugh lb/Day (92-87-5) 5B.Benzo(a) Anthracene X < 10 < 0.54 1 ug/I lb/Day (56-55-3) 6B.Benzo(a) X < q0 < 0.54 1 ugh lb/Day Pyrene(50-32-8) ' -7B.3,4-Benzo- fluoranthene X < 10 < 0.54 1 ugh lb/Day (205-99-2) 88.Benzo(ghl) X - < f0 < 0.54 1 ugh lb/Day Perylene(191.24-2) 9B.Benzo(k) Ftuoranthene X < 10 < 0.54 1 ugh lb/Day (207-08-9) 108.Bia(2-Chioro- - ethoxyl)Methane X < 10 < 0.54 1 ugh lb/Day (111-91-1) 11B.Bis(2-Chloro- ethyl)Ether X < 10' < 0.54 1 ugh lb/Day (111-44-4) 12B.Bis(2-Chtoroiso- propyl)Ether X < 10 < 0.54 1 WI lb/Day (108-60-1) - 13B.Bis(2-Ethyl- hazy')Phthalate X 18 0.98 1 ugh lb/Day (117-81-7) 14B.4-Bromo- phenyl Phenyl X < 10 < 0.54 1 U9fl lb/Day Ether(101-55-3) 158.Butyl Benzyl X < 10 < 0.54 1 ugh lb/Day Phthalate(85-68-7) 168.2-Chloro. naphthalene X < 10 < 0.54 1 ugh lb/Day (91-58-7) 17B.4-Chtoro- phenyl Phenyl X < 10 < 0.54 1 ugh lb/Day Ether(7005-72-3) 18B.Chrysene X < 10 < 0.54 1 ugh lb/Day (218.01-9) 19B.Dibenzo(a,h) Anthracene X < 10 < 0.54 1 ugh lb/Day (53-70-3) 208.1.2-Dichloro- X < 10 < 0.54 1 ugh lb/Day ' benzene(95-50-1) 21B.1,3-Dichloro- X < 10 < 0.54 1 ugh lb/Day benzene(541-73-1) EPA Form 3510-2C(Rev.2-85) PAGE V-6 CONTINUE ON PAGE V-7 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-6 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- c.ab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (if available) quir- sent sent (if available) (if available) (if available) d.NO.OF a.Cancan- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 226.1,4-Dichloro. X < 10 < 0.54 1 ugh Ib/Day benzene(106-48-7) 2313.3,3-Dichlao- berwdine X < 10 < 0.54 1 ug/I lb/Day (91-94-1) 246.Diethyl Phthalate X < 10 < 0.54 1 ugA lb/Day (84-66-2) 258.Dimethyl Phthalate X < 10 < 0.54 1 ug/I lb/Day (131-11-3) 288.Di-N-Butyl Phthalate X < 10 < 0.54 1 ugA lb/Day (84-74-2) 276.2,4-Dinitro- X < 10 < 0.54 1 ug/l lb/Day toluene(121-14.2) 2813.2,6-Dinitro- X < 10 ' < 0.54 1 ugA lb/Day toluene(606.20-2) 29B.DI-N-Octyl - Phthalate X < 10 < 0.54 1 ugA lb/Day (117.84-0) 30B.1,2-Diphenyl- hydrazine(as Azo- X < 10 < 0.54 1 ugh) lb/Day benzene)(122-66-7) 318.Fluoranthene X < 10 < 0.54 1 ugh Ib/Day (206-44-0) 328.Fluorene X < 10 < 0.54 1 ugh lb/Day (86-73.7) 33B.Hexachloro- X < 10 < 0.54 1 ugA lb/Day benzene(118-74-1) 348.Hexa- - chlorobutadiene X < 10 < 0.54 1 ugA lb/Day (87-68-3) 358.Hexachtoro- cyctopentadiene X < 25 < 1.36 1 ugA lb/Day (77-47-4) 368.Hexachloro- X < 10 < 0.54 1 ugA lb/Day ethane(67-72-1) 376.Indeno (1,2,3-cd)Pyrene X < 10 < 0.54 1 ugA lb/Day (193-39-5) 386.tsophorone X < 10 < 0.54 1 ugA lb/Day (78-59-1) 39B.Naphthalene X < 10 < 0.54 1 ugA lb/Day (91-20-3) 40B.Nitrobenzene X < 10 < 0.54 1 ugA lb/Day (98-95-3) 416.N-Nitro- _ , sodimethytamine X < 10 < 0.54 1 ugA lb/Day (62-75-9) 42B.N-NItrosodi- N-Propylamine X < 10 < 0.54 1 ugh lb/Day (621-644-7) EPA Form 3510-2C(Rev.2-85) PAGE V-7 CONTINUE ON PAGE V-8 • EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-7 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. are- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) qulr- sent sent (if available) (if available) (if available) d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-BASE/NEUTRAL COMPOUNDS(continued) 438.N-Nitro- sodiphenylamine X < 10 < 0.54 1 (88-30-6) 44B.Phenanthrene X < 10 < 0.54 1 (85-01-8) 458.Pyrene X < 10 < 0.54 (129-00-0) 468.1,2.4-Tn- chlorobenzene X < 10 < 0.54 1 (120.82.1) CiU iMS 1-KAC:I loaf-rhs I IuIL)Eb 1 P.Alddn X (309-00-2) 2P.alpha-BHC X (319-84-6) 3P.beta-BHC X (315-85-7) 4P.gamma-BHC X (58.89.9) 5P.delta-BHC X (319-86-8) 6P.ChloMane X (57-74.9) 7P.4,4'-DOT X (50-29-3) 8P.4,4'-DDE X (72-55-9) 9P.4,4'-DOD X (72-54-8) 10P.Dieldrin X (80-57.1) 11P.alpha-Endosulfan X (115-29-7) 12P.beta-Endosulfan X (115-29-7) 13P.Endosulfan Sulfate X (1031-07-8) 14P.Endrin X (72-20-8) 15P.Endrin Aldehyde X (7421-93-4) 16P.Heptachlor X (76-44-8) EPA Form 3510-2C(Rev.2-85) PAGE V-8 CONTINUE ON PAGE V-9 EPA I.D.NUMBER(copy from Item 1 of Form 1) OUTFALL NUMBER CONTINUED FROM PAGE V-8 NC0004979 004 1.POLLUTANT 2.MARK"X" 3.EFFLUENT 4.UNITS 5.INTAKE(optional) AND CAS NO. a.re- b.pre- cab- a.MAXIMUM DAILY VALUE b.MAXIMUM 30 DAY VALUE c.LONG TERM AVG.VALUE a.LONG TERM AVG.VALUE (If available) quir- sent sent (if available) (if available) (If available) _ d.NO.OF a.Concen- b.Mass d.NO.OF ed (1)Concentration I (2)Mass (1)Concentration (2)Mass (1)Concentration (2)Mass ANALYSES tration (1)Concentration (2)Mass ANALYSES GC/MS FRACTION-PESTICIDES(continued) 17P.Heptachlor Epoxide X (1024-57-3) 18P.PCB-1242 X (53489-21-9) 19P.PC8-1254 X (11097-89-1) 20P.PCB-1221 X • (11104-28-2) 21P.PCB-1232 X (11141-18-5) 22P.PCB-1248 X (12872-29-6) 23P.PCB-1260 X (11098.82-5) 24P.PCB-1016 (12874-11-2) 25P.Toxaphene X (8001-35-2) EPA Form 3510-2C(Rev.2-85) PAGE V-9 EPA ID Number(copy from item I of Form 1) Form Approved.OMB No.2040-0086 Please print or type in the unshaded areas NC0004979 Approval expires 5-31-92 Form Washington, States Environmental Protection Agency Washington,DC 20460 2F 1/4EPA Application for Permit to Discharge Storm Water g NPDES Discharges Associated with Industrial Activity Paperwork Reduction Act Notice Public reporting burden for this application is estimated to average 28.6 hours per application,including time for reviewing instructions,searching existing data sources,gathering and maintaining the data needed,and ccmpleting and reviewing the collection of information. Send comments regarding the burden estimate, any other aspect of this collection of information or suggestions for improving this form,inducing suggestions which may increase or reduce this burden to:Chief, Information Pdicy Branch,PM-223,U.S.Environmental Protection Agency,401 M St,SW,Washington,DC 20460,or Director,Office of Information and Regulatory Affairs,Office of Management and Budget,Washington,DC 20503. I. Outfall Location For each outfall,list the latitude and longitude of its location to the nearest 15 seconds and the name of the receiving water. A. Outfall Number D. Receiving Water (list) B. Latitude C. Longitude (name) 008 35° 11' 27" 81u 00' 30" Catawba River 015 35° 10' 46" 81u 00' 25" Catawba River Note: For monitoring purposes,the above outfalls represent the remaining outfalls. II. Im.rovements A. Are you now required by any Federal, State, or local authority to meet any implementation schedule for the construction, upgrading or operation of wastewater treatment equipment or practices or any other environmental programs which may affect the discharges described in this application? This includes, but is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters,stipulations,court orders,and grant or loan conditions. 4. Final 1. Identification of Conditions, 2.Affected Outfalls Compliance Date Agreements,Etc. number source of discharge 3.Brief Description of Project a.req. b.proj. NA B. You may attach additional sheets describing any additional water pollution(or other environmental projects which may affect your discharges) you now have under way or which you plan. Indicate whether each program is now under way or planned, and idicate your actual or planned schedules for construction. III. Site Draina.e Ma. Attach a site map showing topography (or indicating the outline of drainage areas served by the outfall(s) covered in the application if a topographic map Is unavailable)depicting the facility including: each of its intake and discharge structures; the drainage area of each storm water outfall; paved areas and buildings within the drainage area of each storm water outfall, each known past or present areas used for - outdoor storage or disposal of significant materials, each existing structure control measure to reduce pollutants in storm water runoff, materials loading and access areas, areas where pesticides, herbicides, soil conditioners and fertilizers are applied; each of its hazardous waste treatment,storage or disposal units(including each are not required to have a RCRA permit which is used for accumulating hazardous waste under 40 CFR 262.34);each well where fluids from the facility are injected underground;springs,and other surface water bodies which receive storm water discharges from the facility. EPA Form 3510-2F(Rev. 1-92) Page 1 of 3 Continued on Page 2 Continued from the Front IV. Narrative Descri•tion of Pollutant Sources A. For each outfall,provide an estimate of the area(include units)of impervious surfaces(including paved areas and building roofs)drained to the outfall,and an estimate of the total surface area drained by the outfall. Outfall Area of Impervious Surface Total Area Drained Outfall Area of Impervious Surface Total Area Drained Number (provide units) (provide units) Number (provide units) (provide units) SW001 See attached thru supplemental SW015 information. B. Provide a narrative description of significant materials that are currently or in the past three years have been treated,stored or disposed in a manner to allow exposure to storm water; method of treatment, storage, or disposal; past and present materials management practices employed to minimize contact by these materials with storm water runoff;materials loading and access areas;and the location, manner,and frequency in which pesticides,herbicides,soil conditioners,and fertilizers are applied. See attached supplemental information. C. For each outfall, provide the location and a description of existing structural and nonstructural control measures to reduce pollutants in storm water runoff; and a description of the treatment the storm water receives, including the schedule and type of maintenance for control and treatment measures and the ultimate disposal of any solid or fluid wastes other than by discharge. _ Outfall List Codes from Number Treatment Table 2F-1 SW001 See attached supplemental information. thru SW015 V. Non Stormwater Dischar•es A. I certify under penalty of law that the outfall(s) covered by this application have been tested or evaluated for the presence of '` nonstormwater discharges,and that all nonstormwater discharges from these outfall(s)are identified in either an accompanying Form 2C or Form 2E application for the outfall. Name of Official Title(type or print) Signature Date Signed Albert J. Smith, III, Manager, Allen Steam � I l/It y /�� Station B. provide a description of the method used,the dat• of any testing,and the onsite drainage points that were directly observed during a test. Visual inspections were performed during October 2001 and December 2001 and also in May 2002 of the outfalls to verify that non-stormwater discharges were not occurring. VI. Si•nificant Leaks or Spills Provide existing information regarding the history of significant leaks or spills of toxic or hazardous pollutants at the facility in the last three years,including the approximate date and location of the spill or leak,and the type and amount of material released. No reportable spills or significant leaks have occurred at this facility in the last three years. EPA Form 3510-2F (Rev. 1-92) Page 2 of 3 Continued on Page 3 EPA ID Number(copy from Item I of Form 1) Continued from Page 2 NC0004979 VII. Dischar•e Information A,B,C,&D: See instruction before proceeding. Complete one set of tables for each outfall. Annotate the outfall number in the space provided. Tables Vii-A,VII-B,and VII-C are included on separate sheets numbered VII-1 and VII-2. E. Potential discharges not covered by analysis-is any toxic pollutant listed in table 2F-2, 2F-3, or 2F-4, a substance or a component of a substance which you currently use or manufacture as an intermediate or final product or byproduct? n Yes(list all such pollutants below) ® No(go to Section IX) VIII. Biolo.ical Toxicit Testin• Data Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made on any of your discharges or on a receiving water in relation to your discharge within the last 3 years? Ti Yes(list all such pollutants below) N No(go to Section IX) IX. Contact anal sis Information Were any of the analysis reported in item VII performed by a contact laboratory or consulting firm? NYes(list the name,address,and telephone number of, and pollutants n No(go to Section X) analyzed by,each such laboratory or firm below) A. Name B.Address C.Area Code&Phone No. D.Pollutants Analyzed Pace Analytical Services, Inc 9800 Kincey Ave, Suite 100 (704)875-9092 Phenolics NC Lab Certification #12 Huntersville, NC 28078 Pace Analytical Services, Inc. NC 54 Ravens Croft Dr., (828) 254-7176 Naphthalene Lab Certification #40 Asheville, NC 288801 X. Certification I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. A. Name&Official Title(type or print) B.Area Code and Phone No. Albert J. Smith, III, Manager, Allen Steam Station (704)829-2500 C. Signature .-l ,.!' j D. Date Signed /�1 EPA Form 3510-2F (Rev. 1-92) Page 3 of 3 EPA ID Number(copy from Item I of Form 1) Form Approved. OMB No.2040-0086 SW008 NC0004979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2F) _ Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) _ Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <5.0 N/A N/A 1 See Supplemental Information (attached) Biological Oxygen N/A N/A 1 " Demand(BOD5) 5.8 mg/L 4.1 mg/L Chemical Oxygen N/A N/A 1 Si Demand(COD) 73.5 mg/L 49.8 mg/L Total Suspended N/A N/A 1 if Solids(TSS) 552.0 mg/L 263 mg/L Phosphorus 1.094 mg- 0.724 mg- N/A N/A 1 P/L P/L pH Minimum Maximum 1 if 6.52 Maximum Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Arsenic,Total 01002 5.09 ug/L 3.83 ug/L N/A N/A 1 See Supplemental Information (attached) y. Copper,Total 01042 .043 mg/L .026 mg/L N/A N/A 1 " Iron,Total 014045 6.734 mg/L 4.433 mg/L N/A N/A 1 " Selenium,Total 2.78 ug/L 2.34 ug/L N/A N/A 1 ii 01147 TKN 00625 1 " 1.8 mg-N/L 1.2 mg-N/L N/A N/A Naphthalene 1 « ND ND N/A N/A Phenols 1 « .014 mg/I .0432 N/A N/A Fecal Coliforms 5000/100 ml 1400/100 ml N/A N/A 1 CC EPA Form 3510-2F(Rev. 1-92) Page VII-2 Continued from the Front—SW008 Part C- List each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present.See the instructions for additional details and requirements.Complete one table for each outfall. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants NA 0 Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Number of hours between Date of Duration Total rainfall beginning of storm meas- Total flow from Storm of Storm Event during storm event rain event Event (in minutes) (in inches) ured and measurableene rainof previous (gallons or specify units) event � �' 22- 6 hours,21 minutes 1.08 96+hours 48010 gallons Feb-03 7. Provide a description of the method of flow measurement or estimate. Estimated from the gallons per minute flow data collected by sampling equipment. EPA Form 3510-2F(Rev. 1-92) Page VII-2 SW015 EPA ID Number(copy from Item l of Form 1) Form Approved. OMB No.2040-0086 NC0004979 Approval expires 5-31-92 VII. Discharge Information (Continued from page 3 of Form 2F) Part A- You must provide the results of at least one analysis for every pollutant in this table. Complete one table for each outfall. See instructions for additional details. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Oil&Grease <5.0 mg/L N/A N/A N/A 1 See Supplemental Information (attached) Biological Oxygen <2.0 mg/L <2.0 mg/L N/A N/A 1 Ai Demand(BOD5) Chemical Oxygen 20.3 mg/L <20.0 mg/L N/A N/A 1 id Demand(COD) Total Suspended 9.0 mg/L 10.0 mg/L ' N/A N/A 1 if Solids(TSS) Total 0.035 mg- 0.03 mg-P/L N/A N/A 1 ii Phosphorus P/L pH 6.28 N/A Minimum Maximum 1 if Part B- List each pollutant that is limited in an effluent guideline which the facility is subject to or any pollutant listed in the facility's NPDES permit for its process wastewater(if the facility is operating under an existing NPDES permit).Complete one table for each outfall. See the instructions for additional details and requirements. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants Arsenic,Total 9.66 ug/L 12.26 ug/L N/A N/A 1 See Supplemental 01002 Information (attached) Copper,Total 0.005 mg/I <0.005 mg/I N/A N/A 1 ,, 01042 Iron,Total 014045 0.657 mg/I 0.504 mg/I N/A N/A 1 " Selenium,Total <2.00 ug/L <2.00 ug/I N/A N/A 1 " 01147 TKN 00625 0.5 mg-NIL 0.2 mg-N/L N/A N/A 1 if Naphthalene <2.0 ug/I <2.0 ug/I N/A N/A 1 if Phenols <0.005 mg/I .016 mg/I N/A N/A 1 if Fecal Coliforms 240/100 ml 80/100 ml N/A N/A 1 �� EPA Form 3510-2F(Rev. 1-92) Page I-1 Continued from the Front -SW015 Part C- List each pollutant shown in Tables 2F-2,2F-3,and 2F-4 that you know or have reason to believe is present See the instructions for additional details and requirements.Complete one table for each outran. Maximum Values Average Values Number Pollutant (include units) (include units) Of And Grab Sample Grab Sample Storm CAS Number Taken During Flow-weighted Taken During Flow-weighted Events (if available) First 30 Composite First 30 Composite Sampled Minutes Minutes Sources of Pollutants NA Part D- Provide data for the storm event(s)which resulted in the maximum values for the flow weighted composite sample. 1. 2. 3. 4. 5. Date of Duration Total rainfall Number of hours between beginning of storm meas- Total flow from Storm of Storm Event during storm event ured and end of previous rain event Event (in minutes) (in inches) measurable rain event (gallons or specify units) 22- 6 hours,21 minutes 1.08 96+ hours 48010 gallons Feb-03 7. Provide a description of the method of flow measurement or estimate. Estimated from the gallons per minute flow data collected by sampling equipment. EPA Form 3510-2F (Rev. 1-92) Page I-2 NPDES Supplemental Information Allen Steam Station NPDES Permit # NC0004979 November 2004 Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 2 of 26 TABLE OF CONTENTS Page No. 1.0 GENERAL INFORMATION 3 2.0 OUTFALL INFORMATION 2.1 Outfall 001 — Condenser Cooling Water 3 2.2 Outfall 002 —Ash Basin 4 2.3 Outfall 002A— Coal Yard Sump Emergency Overflow 11 2.4 Outfall 002B — Powerhouse Sump Overflow 11 2.5 Outfall 003 — Miscellaneous Equipment Cooling and Seal Water 12 2.6 Outfall 004 — Equipment Cooling and Intake Screen Backwash 12 3.0 STORMWATER 12 4.0 HAZARDOUS AND TOXIC SUBSTANCES 23 5.0 ALLEN STEAM STATION 316 DETERMINATION 24 5.1 316(a) 24 5.2 316(b) 25 Figures Allen Steam Station Water Schematic 26 Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 3 of 26 1.0 GENERAL INFORMATION Plant Allen utilizes waters from the Catawba River for condenser cooling and service water requirements. A brief discussion of each discharge follows. A schematic flow diagram of water use, treatment, and discharges indicating typical (average) flow rates for individual waste streams at Plant Allen is attached. All flows are based on historical data where possible or pump design capacities and normal run-times. 2.0 OUTFALL INFORMATION 2.1 Outfall 001 - Condenser Cooling Water(CCW) The CCW system is a once-through, non-contact cooling water system that removes heat rejected from the condensers and other selected heat exchangers and then discharges into the South Fork River. Each of the 5 units at Plant Allen has two condenser cooling pumps. The number of pumps used is dependent on unit load and intake temperatures with more pumps running with higher loads and intake temperatures. Units 1 and 2 share a common cooling water supply tunnel served by a total of 4 CCW pumps. Units 3 and 4 also share a tunnel and 4 CCW pumps. Unit 5 has a separate tunnel and 2 CCW pumps. The common tunnel design enables three pumps to give Units 1 and 2 or 3 and 4 the equivalent of 1 '/2 pump operation. The 1 %2 pumps operation adds an economical range or flexibility when units are on partial load and when intake water temperatures are minimal. Unit No. 1-Pump GPM 1.5-Pump GPM 2-Pump GPM 1 55,500 74,800 83,500 2 55,500 74,800 83,500 3 83,000 111,200 126,000 4 83,000 111,200 126,000 5 83,000 } 126,000 at-" to y,�'5,0( 4 $ All condenser tubes at Plant Allen are cleaned manually with metal or rubber plugs. Mechanical cleaning is required once a year for most units. A leak test is performed periodically on the condenser tubes. (See section 2.2.6.4.) If leaks are detected, then one method used to temporarily stop small leaks is to add sawdust to the CCW system, as previously approved by NCDENR. The sawdust is added at amounts that will plug the leaks and not result in an environmental impact. This is a temporary measure until the unit can come off-line so the leaks can be permanently repaired. 2.1.1 Asiatic Clam/Debris Filter Backwash Water for the Unit 5 CCW water is filtered for any twigs, leaves and other light debris, which passed through the intake screens. Asiatic clams, which are Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 4 of 26 common in Lake Wylie and can clog the condenser tubes, are also captured in this filter. This filter is backwashed once a week for 15 minutes. A maximum flow of 3000 GPD is realized. No other additives are in the backwash water. The twigs, leaves, clams and other light debris collected in the debris filter are indigenous to the river and are therefore flushed back with no harmful environmental consequences. 2.2 Outfall 002 -Ash Basin 2.2.1 Boiler Cleaning All five boilers at Plant Allen are chemically cleaned with the next cleaning as needed. The volume of the boilers determines the quantity of chemicals required for a cleaning. Boilers #1 and #2 each have a waterside volume of 26,700 gallons. The volume of boilers #3, #4, and #5 is 40,100 gallons each. The volume of dilute waste chemical discharged from unit#1 or#2 during a cleaning is 294,000 gallons. The volume of diluted waste chemicals drained from #3, #4 and #5 totals 450,000 gallons each. These wastes are drained through temporary piping to the permanent ash removal lines, which flow to the ash basin. Immediately prior to the beginning of a boiler chemical cleaning procedure, additional stop logs are added to the ash basin discharge structure. This assures longer retention time of the chemical wastes for proper treatment through dilution, neutralization, precipitation, and ion-exchange as documented in the Ash Basin Equivalency Demonstration (October 1976). A list of the chemicals and amounts required to clean the boilers at Plant Allen follows: CLEANING CHEMICALS AMOUNT USED PER UNIT Boiler#1 and #2 Boiler#3, #4 & #5 Sodium bromate 550 lbs 550 lbs Ammonium carbonate 1000 lbs 1000 lbs Ammonium hydroxide* 850 gal 950 gal Hydrochloric acid* 3700 gal 5500 gal Thiourea* 1680 lbs 2010 lbs Citric acid 300 lbs 400 lbs Sodium Sulfite 100 lbs 100 lbs Ammonium bifluoride 1100 lbs 1700 lbs Detergent (Triton —X) 20 gal 20 gal Antifoam agent 10 gal 10 gal During a chemical metals cleaning these chemicals are present in amounts greater than the reportable quantity as identified under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). If a spill Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 5 of 26 of any these chemicals were to occur, in most cases, it would be routed to the ash basin for treatment. • 2.2.2 Stormwater run-off Storm water run-off enters the ash basin from the from the ash basin's drainage area, the yard drainage sump and the coal yard sump. The powerhouse sump discharges its rainfall run-off into the yard drainage sump. A more detail description of the sump systems and stormwater run-off is included in section 3.4. 2.2.3 Sanitary Wastes Sanitary waste at Plant Allen is treated in a septic tank with the effluent from the septic tank being discharged to the Ash Basin via the Coal Yard sump. Approximately 150 people are responsible for the load on this system. An average flow of 4850 GPD is treated by the system. The drinking water well supplies the drinking water requirements of Plant Allen. Plant Allen is a non- transient and non-community drinking water system. This drinking water system is listed as ID # 01-36-704 in the NCDENR database. 2.2.4 Ash Sluice Plant Allen utilizes electrostatic precipitators to remove fly ash from its stack gases. These precipitators require approximately 10.0 MGD for fly ash sluicing to the ash basin. Bottom ash sluicing to the basin requires approximately 6.0 MGD for a total average ash removal flow of 16.0 MGD. Plant Allen presently has additional air pollution control systems installed on three units. Use of these systems entails the use of low concentrations of ammonia and sulfur compounds. These systems aid in the collection of the ash in the electrostatic precipitators. A Selective Non-Catalytic Reduction (SNCR) system has been installed on unit 1 to aid in the reduction of NOx emissions. SNCR systems operate by injecting urea into the upper section of the boiler where a chemical reaction occurs to reduce the NOx to water and nitrogen. Some residual ammonia will be collected on the fly ash in the electrostatic precipitators and a small amount will be carried to the ash basin. However, the operation of the SNCR system is not expected to require additional treatment capabilities to ensure compliance with NPDES permit limits. Additional SNCR systems are to be installed on the remaining 4 units at Allen over the next several years. 2.2.5 Recirculating Water System (RCW) Plant Allen has 2 RCW systems: a chiller system and a pump cooling water system. Both systems use the biocide H-550 or similar products. In addition, the corrosion inhibitor CS or similar product is used. Generally, these systems are closed loop, but may need to be drained occasionally. All such water would enter the floor drains and then be discharged to the ash basin. Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 6 of 26 2.2.6 Miscellaneous Waste Streams 2.2.6.1 Turbine Non-destructive Testing Approximately once per year, one turbine is tested for cracks in the generator shaft using an ultrasonic nondestructive test. During the process a maximum of 400 gal of demineralized water mixed with 4 gal of corrosion inhibitor is used and discharged to the ash basin. 2.2.6.2 Heat Exchanger Cleaning From time to time, it may be necessary to clean the small heat exchangers with polyacrylamide, polyacrylate, sodium laurylsulfate and tri- sodium phosphate. All wastes would be routed to the ash basin. 2.2.6.3 Condensate Polishers: Plant Allen utilizes condensate polishers which divert a portion of the normal condensate (closed system)flow through one of two cells per unit. The polishers provide filtration as well as ion exchange functions to remove or substantially reduce dissolved solids and suspended matter present in the condensate stream. The polishers require precoating with a combination of anion and cation resin. To facilitate precoating, 125-150 ml of a solution of polyacrylic acid (25%) is added to the precoat slurry. Upon exhaustion, the precoat is removed from the filters by water/ air blasting and flushed to the ash basin via sumps. Condensate water is used to remove the exhausted precoat at the rate of: Unit 1 & 2 - 1558 gal/precoat Units 3, 4, & 5 - 2090 gal/precoat. A total average waste flow of approximately 980 GPD to the ash basin is realized. 2.2.6.4 Condenser Leakage Testing: Fluorescing Dye Method - Approximately 1 lb. of a disodium fluorescing dye added to 280,000 gals of demineralized water is used occasionally to test the condensers for leakage. All wastes from the testing would be routed to the ash basin. Sulfur Hexafluoride Method - Periodically, sulfur hexafluoride is injected into the condenser tubes to locate condenser tube leaks. Sulfur hexafluoride is a chemically inert, nonflammable, nontoxic gas with an extremely low water solubility. It is estimated that 150 grams of sulfur hexafluoride would be used during the leak detection process. Most of the sulfur hexafluoride would be volatilized during the process. Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 7 of 26 2.2.7 Ash Basin Treatment CO2 Injection System - During warmer periods of the year, algae blooms occur in the ash basin causing pH levels to rise. A CO2 system is utilized during these events to maintain the pH level below 9.0 standard units. Acid Injection System -An acid injection system utilizing 78-80 % sulfuric acid is maintained as back-up to the CO2 system for pH adjustment Sodium Hydroxide System -A sodium hydroxide injection system utilizing 25% or 50% sodium hydroxide is maintained for pH adjustment. 2.2.8 Yard Drain Sump The yard drain sump is a large concrete structure that has three level controlled pumps, which pump wastewater from Plant Allen to the ash basin. These pumps are operated on a rotating basis. The combined average flow from all sources tied to the yard drain sump is approximately 4.0 MGD. (See Section 3.4 for a more detail description of rainfall run-off entering the yard drain sump.) Below is a description of waste streams going to the yard drain sump: 2.2.8.1 Boiler Room Sumps (Units 1-4) The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous leakage (refer to the attached schematic of water flow for individual flows). The effluent from the units 1 through 4 boiler room sumps is flushed to the 'y yard drain sump. The effluent from the unit 5 boiler room sump is flushed to the power house sump, which is then flushed to the yard drain sump. 2.2.8.2 Turbine Room Sumps The turbine room sumps accommodate flows from floor washing, leakage, and occasional condenser water box drainage. Effluent from units 1 through 5 turbine room sumps is flushed to the yard drain sump. 2.2.9 Water Treatment System The water treatment wastes consist of sedimentation, filter backwash, reverse osmosis (RO) concentrate, demineralizer regeneration wastes and boiler blowdown. The make-up water treatment system is compromised of a clarifier, two pressure filters, two activated carbon filters, two garnet filters, a reverse osmosis machine and one set of demineralizers. Make-up water is used in the boilers and closed cooling systems. Clarifier: The clarifier has an average production of 0.252 MGD. Alum and caustic or ferric sulfate/ferric chloride are used to affect precipitation and thus remove suspended solids from the raw river water. Desludging of the clarifier takes Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 8 of 26 place approximately 8% of the unit run-time with an average volume of 2300 GPD going to the ash basin. Pressure Filters: There are two pressure filters which follow the clarifier in the water treatment process. These filters are backwashed once per week with a waste flow of 11,000 gallons per backwash. Each pressure vessel will contain 84 ft3 of anthracite, 50 ft3 of quartz, 25 ft3 of garnet and 41 ft3 of garnet/quartz support media. Each vessel will use product water to backwash at a rate of 750 gpm. On average, both vessels will backwash once per week. The contents of the pressure filters will be changed out, as internal maintenance requires, and the used filter medium will be disposed of in the ash basin. Activated Carbon Filters: In addition to the pressure filters, there are two activated carbon filters. These filters are backwashed twice per month. Approximately 30,000 gallons of water are required to backwash each of these filters. The activated carbon filters are composed of approximately 250 ft3 of granular activated carbon (coal). The spent filter medium is changed out yearly and is disposed of in the ash basin. RO Prefilters: There are 2 RO prefilter vessels containing garnet, which are used to filter suspended solids. Both filters are backwashed once per week with the backwashed material routed to the ash basin. Total waste for both filters is 4500 gallons per week. RO Unit: A RO unit is used to decrease the conductivity in the filtered water, thereby increasing the efficiency of the demineralizers and reducing the amount of chemical needed for demineralizer regeneration. During operation, the unit has a continual blowdown of 60 gal/min, which is discharged, to the ash basin. The RO unit is cleaned on a quarterly basis with the waste going to the yard drains and eventually the ash basin. During a cleaning, approximately 30 lbs of the cleaner OSMO AD-20 (containing sulfamic acid) along with 5 gallons of biocide, 2 liters of sodium hydroxide, and 0.5 gallons of sodium lauryl sulfate is used. Demineralizer: The demineralizer consists of two mixed-bed cells. Only one of these cells is operated at any one time. The cell which is in operation is regenerated approximately once every 7- 14 days of operation. A regeneration requires 42 gallons of sulfuric acid (78-80%) and 150 gallons of 50% sodium hydroxide. An average dilute waste chemical and rinse flow of 20,000 gal is realized. The dilute acid and caustic are discharged to the floor drains simultaneously through the same header for neutralization purposes. All regeneration wastes are flushed to the ash basin. The demineralizer resin is changed out approximately Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 9 of 26 once every 10 years with the spent resin going to the ash basin. Approximately 1 ml of the surfactant Triton CF-54 or similar product is added to the new resin to improve separation. Boiler Blowdown: Each of the five boilers at Plant Allen blowdown at an average rate of approximately 500 lbs. of steam per hour. The blowdown is allowed to flash in a blowdown tank. Most of the blowdown is vented to the atmosphere with a minimal amount of condensate discharged to the boiler room sump. The average condensate flow to this sump is 0.004 MGD. Hydrazine is maintained at a concentration of 25 ppb in the condensate system for deoxygenation. A minute amount of hydrazine (<10 ppb) may be present in the condensate flow to the boiler room sump. 2.2.10 Preheater Washes Preheaters are backwashed with raw water approximately 2 times per year to remove ash and corrosion products. There are 12 preheaters at Allen that would require approximately 100,000 gallons of backwash water each. The backwash water is routed to the ash basin through the yard drain sump. 2.2.11 Laboratory Wastes The chemistry lab on site performs a variety of water analyses and routine sample collections. Therefore several chemicals are used in the lab in small quantities for sample preservation, bottle rinsing, equipment calibration, conductivity analyses, etc. The wastes are flushed down the sink and discharged into the yard drain sump and then pumped to the ash basin. Some of the laboratory chemicals are as follows: Ammonia molybdate, Acetic acid, Ferric sulfate, Hydrochloric acid, Monoethylamine, Nitric acid and Potassium hydroxide. 2.2.12 Power House Sump (Unit 5) The wastes, which enter the floor drains at Plant Allen, accumulate in the boiler room sumps and turbine room sumps. The water which flows to the boiler room sumps originates from such sources as floor wash water, boiler blowdown, water treatment waste, condensates, equipment cooling water, sealing water and miscellaneous leakage. Effluent from the unit 5 boiler room sump is flushed to the powerhouse sump, which is then flushed to the yard drain sump. This sump also collects stormwater from various drains located on the north end of the powerhouse. (See Section 3.4 for a more detail description of rainfall run-off entering the powerhouse sump.) 2.2.13 Physical Chemical Treatment System An Authorization to Construct permit number NC0004979A01 was issued to Allen Steam Station on June 21, 2004 for a physical chemical treatment system that will allow construction of: Plant Men,Gaston County NPDES Permit No.NC0004979 Page 10 of 26 • three primary settling cells, • a treatment channel, • a chemical injection system, and • a final settling/focculation cell. The purpose of this system is to provide a chemical injection system for treatment of dissolved pollutants that will not settle out of the wastestream through purely physical means. The system will treat 18-24 MGD sluice water to reduce the TSS and selenium to below permit limits. The three primary settling cells will be used to settle the solids (one at a time, while the inactive cells are being cleaned). The treatment channel will convey settled sluice water to the secondary settling or flocculation cell. Approximately 25-50 gpm of the settled waste stream from the treatment channel will be pumped into the chemical treatment building. This pumped stream will provide the opportunity to take samples before and after treatment and serve as the waste stream's chemical injection point. The chemicals that are presently permitted for treatment in this system are: sulfuric acid, ferric sulfate and ferric chloride. After chemical addition and mixing in the treatment channel, the treated waste stream will be discharged into a floc setting basin to allow sufficient settling time for any precipitated compounds to settle prior to discharge. Overflow from the final settling cell will flow through a vegetated ash delta prior to discharge to the main pond. There will be an alternative route to discharge from the vegitated ash delta directly to the final discharge tower. 2.2.14 Wastewater from Future Plant Additions 2.2.14.1 Selective Non-Catalytic Reduction (SNCR) As part of the compliance with the North Carolina Clean Air Initiative (NCCAIR), Allen will install an urea based "trim" Selective Non-Catalytic Reduction (SNCR) systems on all five units. The installation has been completed for Unit 1. The trim SNCR systems are expected to reduce NOx emissions by approximately 30%. SNCR systems operate by injecting urea into the upper section of the boiler where a chemical reaction occurs to reduce the NOx to water and nitrogen. Some residual ammonia will be collected on the fly ash in the electrostatic precipitators and a small amount will be carried to the ash basin. However, the operation of the SNCR system is not expected to require additional treatment capabilities to ensure compliance with NPDES permit limits. Two pressure filters with polymer injection will be installed to provide make up water to the SNCR system. Each pressure filter will be backwashed once per week with a waste flow of 5000 gallons per Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 11 of 26 backwash. Each pressure filter will contain anthracite, quartz, garnet and garnet/quartz support media. 2.2.14.2 Flue Gas Desulfurization (FGD) The installation of a Wet Flue Gas Desulfurization (FGD) system is to be installed at Allen in the future for the reduction of SO2 from the stack gas. The following provides a description of the FGD system at Allen. In a Wet Scrubber system the SO2 component of the flue gas produced from the coal combustion process is removed by reaction with limestone- water slurry. The particular system to be used at Allen will collect the flue gas after it passes through the electrostatic precipitator and route the gas into the absorber tank. As the gas rises through the tank to the outlet at the top, the gas passes through a spray header. An atomized slurry of water and limestone droplets is continually sprayed through this header into the stream of flue gas. The SO2 in the flue gas reacts with the calcium in the limestone and produces SO3. The SO3 slurry falls to the bottom of the tank where a stream of air is injected to oxidize the slurry to form gypsum (CaSO4•H2O). The gypsum slurry is drawn off the absorber tank and subsequently to a vacuum belt filter. Part of the process water from the FGD system is blown down in order to maintain the FGD water chemistry within the FGD system specifications. This water will be treated in a wastewater treatment system that will discharge to the ash basin. The FGD system will require a material handling system that will supply limestone to the scrubber and a gypsum storage area for the gypsum removed from the process. The limestone will come into the site by rail. It is then transferred to the FGD site via a covered conveyor. Runoff from the storage area is routed to the ash basin. The gypsum is routed from the FGD tank via a covered conveyor belt that will carry it to a storage pile. The runoff from this area is also routed to the ash basin. 2.3 Outfall 002A— Coal Yard Sump Overflow An overflow pipe that directs flow from the sump to the Catawba River was included in the construction of the coal yard sump. This was done to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. Overflow has not occurred during the last permit cycle. 2.4 Outfall 002B — Powerhouse Sump Overflow An overflow pipe that directs flow from the sump to the ground was included in the _ construction of the powerhouse sump. This was done to prevent submergence and damage of the pump motors within the sumps in the event that all pumps failed or redundant power supply lines could not be restored in a timely manner. If enough water Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 12 of 26 overflows, the waste water could potentially get to the Catawba River. Overflow has not occurred during the last permit cycle. 2.5 Outfall 003 — Misc Equipment Cooling & Seal Water Outfall 003 discharges into the CCW discharge canal. The discharge consists of cooling water from units 4 and 5 boiler feedpump hydraulic coupling coolers and other miscellaneous equipment cooling. This water is once-through, non-contact cooling water withdrawn from the service water system. Approximately 10,000 gpd of bearing cooling water for the ash line booster pump is routed back to the discharge canal via a stormwater outfall in the vicinity of outfall 003. The water is once through, non-contact cooling water withdrawn from the service water system. 2.6 Outfall 004— Equip. Cooling & Intake Screen Backwash 2.6.1 Equipment Cooling Water Cooling water for units 1,2 & 3 boiler feed pump hydraulic coupling coolers and other miscellaneous equipment is discharged through outfall 004. This water is once-through, non-contact water drawn from the service water system. In addition, water from a vehicle rinse-down area is directed to this outfall. The rinse water contains no soaps or other additives. Allen is also adding a new chiller system for comfort cooling that will be a once through non contact cooling water system and will discharge back to the river via outfall 004. 2.6.2 Intake Screen Backwash The intake screens at Plant Allen are flushed on an "as needed" basis. Backwash usually averages 2 hours per shift. The average volume required is 0.053 MGD. The large debris floating on the river is caught on the parallel bar screens. This trash is collected and disposed of in a landfill. The silt, twigs, leaves and other light debris collected on the rotating screens are indigenous to the river and are therefore flushed back with no harmful environmental consequences. 3.0 STORMWATER GENERAL INFORMATION 3.1 Site Description Allen Steam Station property covers approximately 953 acres. The powerhouse, the plant yard, the coal pile, the switchyards, and associated material and equipment storage areas cover about 65 acres. These developed areas are generally flat. There are approximately 5 miles of rail access and 1 2/3 miles of paved roadways on-site. Coal is shipped to.the site by rail lines. There is a 64 acre retired ash basin. The active ash basin has a surface area of about 176 acres, and it receives runoff from another 112 acres. Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 13 of 26 Based on information from the Soil Survey of Gaston County, North Carolina, the original site soils at Allen Steam Station were from the Gaston series. These soils are classified as sandy clay loam with red clay in the subsoils. In developed areas, the soil profile has been altered by grading and filling. The site topography is generally flat with rolling hills in outlying, undeveloped areas. 3.2 Storm Water Drainage System In developed areas, runoff flows overland to ditches and catch basins, which are connected to a buried network of corrugated metal pipes (CMP). Rainfall runoff from the coal pile and coal handling areas and portions of the plant yard goes to the yard sumps that discharge to the ash basin. Storm water runoff from other areas of the site is discharged to the Catawba River and the South Fork River. Rainfall runoff from the transformer yard area and the 115 KV switchyard is routed through oil trap tanks prior to being discharged. 3.3 Characterization of Drainage Basins A description of the drainage area, significant materials, and material control measures is presented for each drainage basin. Herbicides are spot applied where required in parking areas, switchyards, parts laydown areas, along walkways, and around various fixtures and buildings. 3.4 Storm Water Outfalls Characteristics for 14 individual outfalls and one group of outfalls are presented. • Storm Water Outfall 1 Discharge Structure: 10 inch (") diameter ((I)) CMP Location: North of station on railroad tracks Drainage Area: 1.75 acres Area Description This outfall conveys runoff from an undeveloped, wooded area upland of the railroad tracks and from the tracks themselves. About 200 feet of an unpaved road passes through the drainage area, and there are about 1600 feet of railway lines. There are no paved or roofed areas in this drainage area. Significant Materials/ Controls Significant materials are not stored within this drainage basin. • Storm Water Outfall 2 Discharge Structure: 24" CMP Location: North of station on railroad tracks Drainage Area: 10.6 acres Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 14 of 26 Area Description This outfall conveys runoff from an undeveloped, wooded area upland of the railroad tracks and from the tracks themselves. About 600 feet of an unpaved road passes through the drainage area, and there are about 900 feet of railway lines. There are no paved or roofed areas in this drainage area. Significant Materials / Controls Significant materials are not stored within this drainage basin. - • Storm Water Outfall 3 Discharge Structure: 8" cIrCMP Location: North of station on railroad tracks Drainage Area: 1.4 acres Area Description This outfall conveys runoff from an undeveloped, wooded area upland of the railroad tracks and from the tracks themselves. About 50 feet of an unpaved road passes through the drainage area, and there are about 1500 feet of railway lines. There are no paved or roofed areas in this drainage area. Significant Materials / Controls Significant materials are not stored within this drainage basin. • Storm Water Outfall 4 Discharge Structure: 10" Cast Iron Pipe Location: North of station at Catawba River Drainage Area: 1.4 acres Area Description This area is an extremely flat area covered with gravel that is used as a material laydown area. None of the drainage area is paved or roofed. Significant Materials / Controls Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large, flat, gravel laydown area north of the powerhouse. The equipment and supplies generally do not contain liquids. • Storm Water Outfall 5 Discharge Structure: 18" CMP Location: North of station at Catawba River Drainage Area: 7.4 acres Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 15 of 26 Area Description This outfall conveys runoff from an undeveloped, wooded area upland of the railroad tracks and from the tracks themselves. About 450 feet of a paved road passes through the drainage area, and there are about 2,580 feet of railway lines. About 2 percent of this drainage area is paved. Significant Materials/ Controls Significant materials are not stored within this drainage basin. - • Storm Water Outfall 6 Discharge Structure: 10"'4) Cast Iron Pipe Location: North of station at Catawba River Drainage Area: 1.7 acres Area Description This area is an extremely flat area covered with gravel that is used as a material laydown area. None of the drainage area is paved or roofed. Significant Materials /Controls Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in large, flat, gravel laydown area north of the powerhouse. The equipment and supplies generally do not contain liquids. • Storm Water Outfall 7 Discharge Structure: 18" CMP Location: North of Station at Catawba River Drainage Area: 5.5 acres Area Description This outfall conveys runoff from an undeveloped, wooded area upland of the railroad tracks, from the tracks themselves, and from a laydown yard. About 400 feet of a paved road passes through the drainage area, and there are about 2,280 feet of rail lines. The laydown yard is extremely flat and covered in gravel. About 2.5 percent of this drainage area is paved. Significant Materials / Controls Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large, flat, gravel laydown area north of the powerhouse. The - equipment and supplies generally do not contain liquids. Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 16 of 26 • Storm Water Outfall 8 Discharge Structure: 24" 4) CMP Location: North of Station at Catawba River Drainage Area: 5.0 acres Area Description This outfall conveys runoff from the hill North of the powerhouse including undeveloped wooded areas, from the gravel parking areas at the outage trailer area, and the grassed areas around the fuel oil tank. This outfall also conveys runoff from a segment of railroad tracks and from the laydown area adjacent to the north warehouse. There are approximately 1,000 feet of paved roadways and 2,400 of railroad tracks in this drainage basin. About 2 percent of this drainage area is paved or roofed. The fuel oil tank is not located within this basin because it is surrounded by an earthen berm, and drainage from inside the berm is routed to the powerhouse yard sump. Significant Materials I Controls Parking: There is a gravel parking area at the outage trailers. This lot is used occasionally during outages. Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a large flat, gravel laydown area adjacent to the north field warehouse. The equipment and supplies generally do not contain liquids. • Storm Water Outfall 9 Discharge Structure: 3' Concrete Ditch Location: North of Intake Structure at Catawba River Drainage Area: 0.5 acres Area Description This outfall conveys drainage from a segment of railroad tracks in front of the powerhouse and from the grassy embankment between the tracks and the intake structure. About 920 feet of railroad tracks pass through this area. There are no paved or roofed areas in this basin. Significant Materials / Controls Significant materials are not stored within this drainage basin. • Storm Water Outfall 10 Discharge Structure: 24" 4) CMP Location: South of Intake Structure at Catawba River Drainage Area: 0.9 acres Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 17 of 26 Area Description This outfall conveys runoff from a segment of the railroad tracks in front of the powerhouse and from the grassy embankment between the tracks and the intake structure. About 1,280 feet of railroad tracks pass through this area. There are no paved or roofed areas in this basin. Drainage from the CCW clam filter pit is discharged through this outfall. Significant Materials / Controls . Significant materials are not stored within this drainage basin. • Storm Water Outfall 11 / NPDES Duffel' 004 Discharge Structure: 72" 4 CMP Location: East of Coal Pile at Catawba River Control Structure: 65,300 gallon oil trap tank Drainage Area: 14.2 acres Area Description This drainage area comprises most of the southern end of the station yard, and most of this area is developed. This outfall conveys roof drainage from a portion of the powerhouse roof, the machine shop roof, the service building roof, the warehouse roof, and some of the coal handling buildings. These roofed areas cover about 1.3 acres. Two large paved parking lots cover 3 acres. Other parking and paved areas cover about 1 acre. About 3,100 feet of rail lines pass through this drainage area, but only half of them are used regularly. Runoff from a portion of the transformer yard area and from the entire 115 kV switchyard is routed to a 65,300 gallon oil trap tank prior to being discharged to this outfall. The switchyard is covered with gravel. Other portions of the drainage area include the powerhouse yard, grassy, and undeveloped areas. About 50 percent of this drainage area is roofed or paved. NPDES discharges including miscellaneous non-contact cooling water from plant equipment, vehicle wash water, and intake screen backwash water are conveyed through this outfall. Significant Materials / Controls Coal: Coal dust may be present around coal handling areas. Kerosene: There is a 200-gallon aboveground, carbon steel kerosene tank in front of the service building. Parking: There are about 3.2 acres of paved parking areas within this drainage basin. Plant Allen,Gaston County • NPDES Permit No.NC0004979 Page 18 of 26 Laydown Area: Spare equipment, parts, steel, iron, cable, and miscellaneous supplies are stored in a flat, concrete laydown yard adjacent to the warehouse. The equipment and supplies generally do not contain liquids. Gasoline: There is a 500-gallon aboveground, carbon steel gasoline tent tank across from the warehouse. The tank is completely enclosed within a steel tent enclosure, and any leaks would be self contained. The enclosure can be drained by opening a valve, and that valve remains closed at any other time. Any fluid drained from the tent is captured and not released to SW Outfall 11. The tank is filled by a 1,500 gallon tanker truck. Clean up supplies are located nearby. Gasoline contaminated groundwater from recovery wells is sometimes stored in a 55-gallon drum beside the gasoline tank. Oil: Runoff from the 115 kV switchyard and from a portion of the station's main transformer yard is routed to the south oil trap tank which has a capacity of 65,300 gallons. The south oil trap tank discharges storm water to SW Outfall 11. Transformers 1A, 1T1, CT1, 2T1, 2A, and 3T1 contain a total of 34,533 gallons of mineral oil. The largest volume contained by a single transformer is 9,715 gallons. The oil circuit breakers in the 115 kV switchyard contain a total of 73,229 gallons of mineral oil. Each circuit breaker has three tanks, and each tank contains either 933 or 1,070 gallons of mineral oil, depending on the model. Two transformers at the switchgear house each contain 196 gallons of mineral oil. • Storm Water Outfall 12 / NPDES 003 Discharge Structure: 36" CMP Location: Discharge Canal Control Structure: 100,000 gallon oil trap tank Drainage Area: 11.1 Area Description This drainage area includes portions of the powerhouse yard north and west of the station and part of the hill to the north of the station where the outage trailers are located. This drainage basin includes a portion of the station main transformer yard and the 230 kV switchyard. Within the powerhouse yard, the drainage basin is flat and generally covered with gravel or grass. About 1,400 feet of rail lines pass through this drainage area, but they are not used regularly. Less than 5 percent of this drainage area is roofed or paved. Runoff from the powerhouse yard immediately north and west of the station is routed to a 100,000 gallon oil trap tank prior to being discharged to this outfall. Runoff from the transformer yard goes to the oil trap tank. Runoff from the 230 kV switchyard is not routed to the north oil trap tank because the switchgear in the 230 kV Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 19 of 26 switchyard is gas cooled and does not contain oil. NPDES discharges of miscellaneous non-contact cooling water are routed through the north oil trap tank and then discharged by this outfall. Significant Materials / Controls Ash: Ash pipelines run through this area carrying ash from the plant to the ash basins. Parking: There are gravel parking areas at the outage trailers. These lots are used occasionally during outages. Oil: Runoff from a portion of the station's main transformer yard is routed to the north oil trap tank. The trap tank discharges storm water to SW Outfall 12. Transformers 3T2, 3A, 4T1, 4A, 4T2, 5T1, 5T2, 5A, CT2, and 6A contain a total of 73,158 gallons of mineral oil. The largest volume contained by a single transformer is 13,790 gallons. The switchgear in the 230 kV switchyard does not contain oil. The north oil trap tank has a capacity of 100,000 gallons. • Storm Water Outfall Group 13 Discharge Structure: Fourteen 10" 4 CMP's Location: Every 200 feet along the railroad tracks west of retired ash basin Drainage Area: 10.2 acres Area Description These outfalls are located every 200 feet along the railroad tracks in front of the retired ash basin. These outfalls convey runoff from the railroad tracks and from the ash basin embankment. About 7,500 feet of railroad tracks pass through this drainage area. None of this drainage area is paved or roofed. Significant Materials / Controls Significant materials are not stored within this drainage basin. • Storm Water Outfall 14 Discharge Structure: 21" (I) CMP Location: Catawba River between the coal pile and retired ash basin Drainage Area: 6.0 acres Area Description This outfall conveys surface drainage from the area between the embankment at the retired ash basin and the coal pile. None of the drainage area is paved or roofed. Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 20 of 26 Significant Materials / Controls Significant materials are not stored within this drainage basin. • Storm Water Outfall 15 Discharge Structure: 36" 4) Reinforced Concrete Pipe Location: Catawba River at retired ash basin Drainage Area: 65 acres Area Description This is the discharge structure from the retired ash basin. This outfall conveys only surface drainage from the retired ash basin. None of this drainage area is paved or roofed. Significant Materials / Controls Significant materials are not stored within this drainage basin. 2.2 Sump System At Allen Steam Station, there are three yard sumps: the powerhouse yard sump, the yard drainage sump, and the coal yard sump. The powerhouse yard sump is located east of the powerhouse, at the north end. The powerhouse yard sump discharges to the yard drainage sump. The yard drainage sump is located east of the coal pile and adjacent to the coal yard sump. The yard drainage sump and coal yard sump discharge to the ash basin. • Powerhouse Yard Sump Location: East of the powerhouse, at the north end Drainage Area: 4.0 acres Area Description Industrial wastewater from some of the powerhouse sumps flows to the powerhouse yard sump. Storm water runoff from a portion of the powerhouse roof, the plant yard, the fuel oil unloading area, and the bulk fuel oil tank area drains to the powerhouse yard sump. The portion of the powerhouse roof that drains to the powerhouse sump is about 2.2 acres. About 85 percent of this drainage basin is paved or roofed. Overflow from the powerhouse yard sump would spill to the ground and then flow overland and could eventually reach the Catawba River. Overflow from the powerhouse yard sump is permitted as NPDES Outfall 002B. Overflow from the powerhouse yard sump is not a normal occurrence. Significant Materials / Controls Oil: The fuel oil bulk storage tank is an aboveground, galvanized steel cylinder - surrounded by an earthen berm sufficient in height to contain a total spill plus rainfall. The total tank capacity is 100,000 gallons. There is a catch basin inside the berm. This outlet has a valve which is normally closed. Plant Men,Gaston County NPDES Permit No.NC0004979 Page 21 of 26 The storm water is inspected for the presence of oil, and if it is clean, it can be drained if there is significant standing water. In the fuel oil unloading area, fuel is transferred from an 8,000 gallon tanker truck to the bulk storage tank via pipelines. DOT unloading procedures are followed. The fuel oil unloading area is paved and surrounded by a one foot concrete curb and ramps to contain any spills. There is a small sump to drain rainfall; the sump has a valve which is normally closed. Spill clean-up supplies are located nearby. Piping from the unloading area to the bulk fuel oil tank is aboveground or enclosed in a concrete trench. • The 48 transformers for the Units 1-5 precipitators contain a total of 7,560 gallons of mineral oil. About 3/5 of the precipitator transformers are located within this drainage area. The maximum oil content of any single component is 205 gallons. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to the powerhouse yard sump. This wastewater may include oil, chemical, and hazardous waste spills. • Yard Drainage Sump Location: East of the coal pile Drainage Area: 4.0 acres Area Description The powerhouse yard sump discharges to the yard drainage sump. The yard drainage sump discharges to the ash basin. In addition to the discharge from the powerhouse yard sump, the yard drainage sump receives industrial wastewater from some of the powerhouse sumps. Industrial wastewater includes effluent from the turbine room sumps and boiler room sumps. Storm water runoff from a portion of the plant yard and parts of coal handling drains to the yard drainage sump. The total roofed area in this basin is about 1.5 acres including the warehouse roof, the maintenance garage roof, and a portion of the powerhouse roof. About half of this drainage basin is paved or roofed. Approximately 1,300 feet of railroad tracks pass through this drainage area. Overflow from the yard drainage sump would discharge to the coal yard sump. Overflow from the sump is not a normal occurrence. Significant Materials / Controls Oil: Used oil is stored in a 4,500 gallon steel tank. The tank is surrounded by a steel containment dike about five feet tall, and the piping is surrounded by a 6-inch concrete curb. Rainfall that accumulates inside the dike can be drained by opening a valve that drains to the ash trench which leads to Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 22 of 26 the yard drainage sump. When the used oil tank is full, the product is removed from site by tanker truck. Small quantities of used oil are initially poured into 55-gallons drums. The drums are stored in the used oil staging area under cover, adjacent to the warehouse, for temporary storage. When the drums are full, they are emptied into the used oil tank. Empty oil drums are stored outside, adjacent to the boat shed. Approximately 250 gallons of oil are stored inside the maintenance garage where floor drains flow to the yard drainage sump. The 48 transformers for the Units 1-5 precipitators contain a total of 7,560 gallons of mineral oil. About 2/5 of the precipitator transformers are located within this drainage area. The maximum oil content of any single component is 205 gallons. Two transformers associated with the wastewater and coal yard sumps each contain 270 gallons of mineral oil. Fuel oil dispensers for the locomotives and bulldozers are located adjacent to the maintenance garage. Wastewater: Plant wastewater from equipment discharges, floor drains, sumps, etc. is routed to the yard drainage sump. This wastewater may include oil, chemical, and hazardous waste spills. Coal: Coal dust is present along the railroad tracks and coal handling areas. Ash: Ash pipelines run through this drainage area. Chemicals: There is a 5,000 gallon tank of sulfuric acid located adjacent to the warehouse. The tank is surrounded by a concrete dike with an outlet to the ash line trench which leads to the yard drainage sump. Drums of various chemicals are stored inside a covered, locked shed adjacent to the warehouse. Hazardous Waste / Satellite Accumulation Areas: There is a satellite accumulation area for paint, chemicals, solvents, cleaners, etc. adjacent to the paint warehouse. Hazardous wastes are stored in a covered area adjacent to the maintenance garage. Laydown Area: There is a large laydown area adjacent to the warehouse. The area is paved and fenced. Spare equipment and parts are stored in the laydown area. Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 23 of 26 See description for powerhouse yard sump for additional significant materials. • Coal Yard Sump Location: East of the coal pile Drainage Area: 25.0 acres Area Description Storm water runoff from the coal piles and from parts of coal handling drains to the coal yard sump. Less than one percent of this drainage basin is paved or roofed. Approximately 800 feet of railroad tracks pass through this drainage area. Overflow from the coal yard sump would be conveyed to the Catawba River. Overflow from the coal yard sump is permitted as NPDES Outfall 2a. Overflow from the sump is not a normal occurrence. Significant Materials / Controls Oil: Two transformers associated with the wastewater and coal yard sumps each contain 270 gallons of mineral oil. A fuel oil dispenser for the bulldozers is located in the northwest corner of the smaller coal pile. Coal: Runoff from the coal pile and some coal handling areas is routed to the coal yard sump. Wastewater: Effluent from the septic system goes to coal yard sump. 3.5 Similarity of Storm Water Outfalls at Allen Steam Station Monitoring all of the storm water outfalls at Allen Steam Station should not be necessary since many of the outfalls convey storm water from areas of substantially identical activities and materials. Storm water outfalls 8 and 15 are representative for the entire site. 4.0 Hazardous and Toxic Substances 4.1 Hazardous and Toxic Substances Table 2c- 3 At Plant Allen, the potential for toxic and hazardous substances being discharged is very low. In reference to Item V-D of Form 2-C, the substances identified under Table 2c-3 that may be in the discharge are as follows: Acetaldehyde, Asbestos, Butyl Acetate, Cyclohexane, Diuron, Epichlorohydrin, Formaldehyde, Monoethyl Amine, Propylene Oxide, Pyrethrins, Vinyl Acetate, and Xylene. Other- During the course of the year products such as commercial cleaners and laboratory reagents may be purchased which contain very low levels of a substance found in Table 2c-3. It is not anticipated that these products will Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 24 of 26 impact the ash basin's capacity to comply with its toxicity limits, since their concentrations are extremely low. 4.2 40 CFR 117 and CERCLA Hazardous Substances The following table identifies hazardous substances located on-site that may be released to the ash basin during a spill in quantities equal to or greater than the reportable quantity (RQ) levels as referenced in 40 CFR 117, 302 and 355. This list is being provided in order to qualify for the spill reportability exemption provided under 40 CFR 117 and the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). These values below represent the maximum quantities on-site that could be released at one time and sent to the ash basin. They do not reflect quantities that are discharged through typical use. Allen Steam Station Hazardous Substances in Excess of RQ Table 4.2 SUBSTANCE QUANTITY SOURCE Benzene 83 lbs Gasoline Tank Ethylbenzene 2,737 lbs Diesel Fuel Tanks Hydrazine 499 lbs Warehouse Naphthalene 41,700 lbs Fuel Oil Tanks Sodium Hydroxide 1,181 lbs Ash basin/Warehouse/#3 Fan Room Sodium Nitrite 800 lbs Warehouse/Powerhouse Sulfuric acid 44,277 lbs Powerhouse Xylene (Mixed Isomers) 419 lbs Gas Tank 5.0 Allen Steam Station 316 Determination 5.1 Allen Steam Station 316(a) determination Duke Power Company's 316(a) demonstration (March 1976) concluded that the "heated discharge from Plant Allen is such that the protection and propagation of a balanced indigenous aquatic community in and on Lake Wylie is assured." Duke's operation experience during the past five years under the thermal limitations imposed in NPDES Permit No. NC0004979 substantiates the above conclusion and further supports Duke's belief that the operating characteristics of the station have a minimal effect of the aquatic environment of Lake Wylie. Surveys of the aquatic community in Lake Wylie demonstrate that a Balanced Indigenous Population exists in Lake Wylie. Accordingly, Duke requests a 316(a) variance and further requests that the thermal limitations imposed in the permit be continued. Plant Allen,Gaston County NPDES Permit No.NC0004979 Page 25 of 26 5.2 Allen Steam Station 316(b) Determination In conjunction with the rulemaking process for the new Phase II 316(b) rule pertaining to fish impingement and entrainment, historical data and permitting records were reviewed. Initial 316(a) and 316(b) studies associated with enactment of the Clean Water Act concluded that the location, construction capacity, and design of the cooling water intake of Allen and other Duke Power steam stations were not detrimental to the aquatic ecosystem and minimize adverse environmental impacts. Both North Carolina and -EPA regulators concurred in 1976 that 316(b) fish impingement and entrainment studies were no longer needed at that time. Although the new Phase II 316(b) rule for existing facilities is currently being litigated, plans for information collection (PICs) are being developed to conduct a Comprehensive Demonstration Study (CDS) to determine required measures to be implemented per approval of NCDENR. Plant Allen,Gaston County '• NPDES Permit No.NC0004979 Page 26 of 26 Plant Allen Water Schematic Condenser Cooling ouaau 001 South Fork Water 626.3 MGD ► River Outran 002A ► Catawba 0'. .�,,� - - Sanitary • River Waste Coal Handling Coal Yard Stormwater Sumps ► Sump 4- Ash Sluice ♦ Atm Ash Basin Outfall 002 —20.7 MGD-*atawba River Water ► Treatment Boiler ► Turbine Rm �. Sumps Catawba Rivers ► Boller Rm —� Sumps ► Yard suDmpnage ,� Stormwater Misc Equip Outfall 003 ► Cooling&Seals 4.5 MGD ►Sow Fork River Powerhouse Sump Outfall 002E River s. Intake screen Backwash Outfall 004 Catawba 6.5 MGD ► River AsiatcClam!Debris ''" 5, Filter 0.003 MGD Catawba Backwash ► River PrTIAT F[� r Michael F. Easley,Governor \‘ 71 0� QG State of North Carolina flr William G.Ross,Jr.,Secretary De rime f vironment ar NaNatural Resources NIG DEFT.OF ' ; p,a 1�n .r Alan W.15limek, P.E.,Director m00 Divisigof Water Quality J►\ June 21, 2004 Mr. Michael A. Ruhe, Manager JUN 2 9 2004 Environmental Support Duke Power 526 South Church Street Charlotte, NC 28202-1802 WATER tWLI `Y SECTION Subject: Authorization to Construct Permit Issuance ATC Number 004979A01 Allen Steam Station NPDES Permit NC0004979 Gaston County Dear Mr. Ruhe: A request for an Authorization to Construct (ATC) was received by the Division and final plans and specifications for this project have been reviewed and found to be satisfactory. Authorization is hereby granted for construction of a physical chemical treatment system at Allen Steam Station. Specifically, this ATC allows: • Construction of three primary settling cells • Construction of treatment channel • Construction of chemical injection system • Construction of final settling/flocculation cell Once construction under this ATC has been completed and an Engineer's Certificate has been submitted, the permittee is authorized to operate the units listed above, with permitted limits as.specified in the NPDES permit issued May 17, 2002. The Division of Water Quality approves this project in terms of compliance with NPDES limits; we defer to Duke Energy and their consultants for approval of distribution system, adequate mechanical design, structural integrity, etc. of the entire physical chemical treatment system. This Authorization to Construct is issued in accordance with NPDES Permit No. NC0004979 issued May 17, 2002, and shall be subject to revocation unless the treatment system is constructed in accordance with the conditions and limitations specified in the permit. The sludge generated from these treatment facilities must be disposed of in accordance with G.S. 143-215.1 and in a manner approved by the North Carolina Division of Water Quality. In the event that the facilities fail to perform satisfactorily, including the creation of nuisance conditions, the Permittee shall take immediate corrective action, including those as may be required by this Division, such as the construction of additional or replacement wastewater treatment or disposal facilities. The Mooresville Regional Office, telephone number (704) 663 - 1699, shall be notified at North Carolina Division of Water Quality (919)733-7015 1617 Mail Service Center rev Allen Steam Station Permit No.NC0004979 Page 2 least forty-eight (48) hours in advance of operation of the installed facilities so that an in-place inspection can be made. Such notification to the regional supervisor shall be made during the normal office hours from 8:00 a.m. until 5:00 p.m. on Monday through Friday, excluding State Holidays. Upon classification of the facility by the Certification Commission, the Permittee shall employ a certified water pollution control treatment system operator to be in responsible charge (ORC) of the water pollution control treatment system. The operator must hold a certificate of the type and grade at least equivalent to or greater than the classification assigned to the water pollution control treatment system by the Certification Commission. The Permittee must also employ a certified back-up operator of the appropriate type and grade to comply with the conditions of Title 15A, Chapter 8G, .0202. The ORC of the facility must visit each Class I facility at least weekly and each Class II, III, and IV facility at least daily, excluding weekends and holidays, and must properly manage and document daily operation and maintenance of the facility and must comply with all other conditions outlined in Title 15A, Chapter 8G, .0204. Once the facility is classified, the Permittee must submit a letter to the Certification Commission which designates the operator in responsible charge within: (A) Sixty calendar days prior to wastewater being introduced into a new system or(B) within 120 calendar days of the following, (i) after receiving notification of a change in the classification of the system requiring the designation of a new ORC and back-up ORC or(ii) a vacancy in the position of ORC or back-up ORC. A copy of the approved plans and specifications shall be maintained on file by the Permittee for the life of the facility. The Operational Agreement between the Permittee and the Environmental Management Commission is incorporated herein by reference and is a condition of this Permit. Noncompliance with the terms of the Operational Agreement shall subject the Permittee to all sanctions provided by G.S. 143-215.6-or violation of or-failure to-act in-accordance with the of this Permit. Failure to abide by the requirements contained in this Authorization to Construct may subject the Permittee to an enforcement action by the Division of Water Quality in accordance with North Carolina General Statute 143-215.6A to 143-215.6C. The issuance of this Authorization to Construct does not preclude the Permittee from complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other government agencies (local, state, and federal) which have jurisdiction. Upon completion of construction and prior to operation of this permitted facility, a certification must be received from a professional engineer certifying that the permitted facility has been installed in accordance with the NPDES Permit, this Authorization to Construct and the approved plans and specifications. Mail the Certification to the NPDES Unit, Division of Water Quality, 1617 Mail Service Center, Raleigh, NC 27699-1617. 2 17 Allen Steam Station Permit No. NC0004979 '.j, Page 3 k ': ?T. 7 One (1) set of approved plans and specifications is being forwarded to you. If you have any _ questions or need additional information, please contact Mr. Sergei Chernikov, Ph.D., telephone ', number(919) 733-5083, extension 594. '41 14 MI ,sy E,� Sincerely o s• dz Alan W. Klimek, P.E. .-, 4. 7 V_ i{ cc: Central Files `'0 NPDES Unit, Permit File ' tom. t,M l f h 4 Jr I r._ !: /4," " II .iIiI:iI Allen Steam Station Permit No. NC0004979 Page 4 Engineer's Certification 1, , as a duly registered Professional Engineer in the State of North Carolina, having been authorized to observe (periodically, weekly, full time) the construction of the project, , for the Project Name Location Permittee hereby states that, to the best of my abilities, due care and diligence was used in the following: • Construction of three primary settling cells • Construction of treatment channel • Construction of chemical injection system • Construction of final settling/flocculation cell Once construction under this ATC has been completed and an Engineer's Certificate has been submitted, the permittee is authorized to operate the units listed above, with permitted limits as specified in the NPDES permit issued May 17, 2002. The Division of Water Quality approves this project in terms of compliance with NPDES limits; we defer to Duke Energy and their consultants for approval of distribution system, adequate mechanical design, structural integrity, etc. of the entire physical chemical treatment system. Signature Registration No. Date Mail this Certification to the NPDES Unit DENR/DWQ 1617 Mail Service Center Raleigh, NC 27699-1617 4 SOC PRIORITY PROJECT: No 6.44'4-7 To: Permits and Engineering Unit Water Quality Section Attention: Mark McIntire Date: May 5, 2004 AUTHORIZATION TO CONSTRUCT NPDES PERMIT County: Gaston MRO No.: 04-34 Permit No. NC0004979 PART I - GENERAL INFORMATION 1. Facility and address: Allen Steam Station Duke Energy, Inc. EC11E 526 South Church Street Charlotte,NC 28202-1802 2. Date of on-site investigation(if conducted): No site visit was conducted. 3. Report prepared by: Michael L. Parker, Environmental Engineer II 4. Persons contacted and telephone number: Ron Lewis, (704) 904-3275 5. Verified discharge point(s), list for all discharge points: outfall 001 outfall 002 outfall 003 outfall 004 Latitude: 35° 11' 23" 35° 10' 30" 35° 11' 24" 35° 11' 15" Longitude: 81° 00' 45" 81° 00' 23" 81° 00' 46" 81° 00' 22" Attach a USGS map extract and indicate treatment facility site and discharge point on map. USGS Quad No.: G 14 NE 6. Site size and expansion area consistent with application? Yes. There is sufficient area available for the construction of the proposed WWT facilities. 7. Topography (relationship to flood plain included): The site is not located within the 100- year flood plain of the receiving waters. 8. Location of nearest dwelling: None within 1000± feet of the site. Page Two PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. Existing treatment facility a. Current permitted capacity: Flows are intermittent in nature. b. Date(s) and construction activities allowed by previous ATCs issued in the previous two years: No ATCs issued to this facility within the past two years. c. Actual treatment capacity of the current facility (design volume in MGD): _ Outfall 001 Outfall 002 Outfall 003 Outfall 004 784.8 11.6 6.3 8.0 d. Description of existing or substantially constructed WWT facilities: outfall 001- there are no existing WWT facilities; outfall 002 - permittee operates a septic tank/sand filter WWT treatment system for treatment of all domestic wastewater. The effluent from the septic tank/sand filter then enters an earthen(ash) settling basin with pH adjustment prior to discharge; outfall 003 - There are no existing WWT facilities; outfall 004 - There are no existing WWT facilities. The permittee also operates a raw water treatment system involving sedimentation, filter back wash, and demineralization. Discharges from the various raw water treatment processes (as well as any residuals generated) are sent to the ash basin. The raw water is not used for drinking,but rather in-plant process use. 2. Type of proposed treatment facility: The applicant proposes to construct a chemical injection system for treatment of pollutants that will not settle out in the existing ash basin settling cells. This system will involve the division of a portion of the existing fly ash basin into a series of three (3)primary settling cells. During any given period of time, each cell will be alternated during plant operation with one receiving the primary sluice wastewater flow while the other two operate in a drying or excavation mode (ash removal). From the primary settling cells,the wastewater will flow through what is being referred to as a"treatment channel"where any chemical injection that may be necessary will occur. In this channel, a portion of the flow will be analyzed for pH, and if necessary, ferric sulfate and/or sulfuric acid will be added as needed for pH control and to augment precipitation of other constituents of concern(primarily selenium). From the treatment channel,the wastewater will flow into a final settling or flocculation cell. This cell will help capture any solids that may not be removed in either the primary cells or the treatment channel. Overflow from this cell will then flow across a vegetated ash delta prior to discharge to the main ash pond. Duke also plans to install the capability of bypassing the main ash pond should effluent quality not require the additional polishing that the main ash basin would provide or should conditions in the main ash pond be detrimental to effluent quality (such as an algae bloom). Page Three 3. Residuals handling and utilization/disposal scheme: Ash is removed as needed from the ash basin, stockpiled for drying, and then reused in accordance with the terms and conditions of Duke Power's Ash Reuse permit. 4. Treatment plant classification: Class I 5. SIC Code(s): 4911 Wastewater code(s): 68, 66 Main Treatment Unit code: 50002 6. Important SOC/JOC or compliance schedule dates: This facility is neither under an SOC nor is one being considered at this time. PART III - EVALUATION AND RECOMMENDATIONS The applicant, Duke Energy, Inc. (Duke), has requested the issuance of an ATC for the construction and modification of the existing ash treatment and disposal system at Duke's Allen Steam Station. These modifications are necessary in order for Duke to maintain compliance with the company's NPDES permit. Specifically, Duke has experienced difficulty in complying with pH and selenium limitations. In July 2003, Duke was.granted approval to conduct a pilot study where flow modifications to the existing ash basin allowed Duke to maintain compliance with the permit limitation for selenium while allowing Duke staff to collect operational data that will help them implement a permanent solution. In October 2003, Duke requested an extension of the pilot study in order to finalize the data they had acculmulated, and begin the process of designing a permanent solution. This Office granted an extension of the pilot study for an additional six (6) months ending April 30, 2004. Since the actual request for the ATC was not received by the Division until March 26, 2004, Duke requested and received(by email) an extension of the pilot study until such time as the Division issues the ATC. Pending a fmal technical review and approval by the NPDES Unit, it is recommended that an ATC be issued as requested. Signa e of Report Preparer at / Water Quality RegiVnal Supervisor Date h:\atc\atc04\allen.atc Y a ` �' 1) NCDENR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT Duke Energy Corporation-Allen Steam Station NC0004979 %, ` ,, �� . x�� .� `: .Facility fnfonnatinri .; : , (1.)Faciliy Name: 1 Allen Steam Station (2.)Permitted Flow(MGD): No flow limit ! (6.) County__ —_ Gaston (3.)Facility Class: I I (7.)Regional Office: Mooresville (4.)Pretreatment Pro ram: ! N/A po_ g (8.)USGS Topo Quad_— G14NE__ __ (5.) Permit Status: f Renewal 1 (9.)USGS Quad Name: I Belmont -- ^ y x 4 4 vi02, �'dss i?i^t s « f'r. at- �� $ ea � Gtf'115t1 s� ,. , ... ... tom � lam �� � ,. �'k' =' 96 ,h. (1.)Receiving Stream: i Catawba / I (7.)Drainage Area(mi2): ??/635 South Fork Catawba Rivers _(2_.)_Su_b_basin: i 03-08-36 (8.)Summer 7Q10(cfs): 195/124 —__ (3.) Stream Index Number: ; (9.)Winter 7Q10(cfs): 195/227_ — —� (4.) Stream_ Classification: i WS-IV B_ i (10.)30Q2(cfs) _ 95/309 ^_— ^ ____ (5.)303(d) Status: Not listed _ _1 (11.)Ave_age r Flow(c__fs_):__ 95/806 (6.)305(b) Status: - _ (12.)IWC%: _ 24(Outfall 002) —� 1.0 Proposed Changes Incorporated Into Permit Renewal • Change WET testing requirement from 16%effluent concentration to 24%. • Remove monitoring requirements for BOD,fecal coliform,and phosphorus. • The quarterly monitoring requirements will be removed for barium,cadmium,chromium, cyanide,naphthalene,nickel,phenols,zinc,and sulfates. None of these pollutants were presents in levels that could reasonably be expected to cause an exceedance of water quality standards. • An arsenic limit of 42 pg/L will be added to the permit. Two values measured in 2003 were above the allowable concentration of 42 pg/L. • The facility will receive a weekly average selenium limit of 21 pg/L. • 316(b)special condition will be added. 2.0 Summary Duke Energy's Allen Steam Station is a coal fired steam electric plant in Gaston County. Effluent Guidelines are provided in 40 CFR 423.12. The facility is also subject to the Cooling Water Intake Structure Rule(316(b)Rule)per 40 CFR 125.95. A special condition will be added expressing this requirement. The facility has four permitted outfalls in the current NPDES discharge permit,issued in September 1996. > Outfall 001 is comprised of once through,non-contact condenser cooling water. The average flow through this outfall,is 626 MGD(from permit application). This outfall discharges to the South Fork Catawba River. NPDES Permit Fact Sheet—09/27/05 Duke Power/ Allen Steam Station Page 2 NC0004979 > Outfall 002 is the ash basin discharge. In 1996 the average discharge from this outfall was 11.6 MGD,however current discharge rates average 19 MGD. This outfall discharges to the Catawba River. > Outfalls 002A and 002B are intermittent discharges of emergency overflows(coal yard sump overflow and power house sump overflow,respectively). Both outfalls discharge to the Catawba River. > Outfall 003 is miscellaneous once through non-contact cooling water. This outfall discharges to the South Fork Catawba River and averages 4.5 MGD(from permit application). > Outfall 004 is also miscellaneous once through non-contact cooling water. This outfall discharges to the Catawba River and averages 6.5 MGD(from permit application). > During the previous renewal,the facility received authorization to backwash an intake filter for Unit 5 condenser cooling water on an as-needed basis. The wash waters contain materials indigenous to the Catawba River such as Asiatic Clams and light debris. There is a special condition in the permit allowing for this discharge. In 1995 the facility completed construction of a Chemical Injection Facility for the ash basin. The purpose of this project was to assist with the settling of selenium and other pollutants that were not being removed from the effluent. This project consisted of the construction of three primary settling cells,a treatment channel,a chemical injection system(ferric sulfate to enhance selenium precipitation)and a final settling/flocculation cell. In the renewal application,Duke Power requested the following changes to their permit. 1. The elimination or reduction of outfall 002 monitoring requirements for the following parameters:barium,BOD,cadmium,chromium,copper,cyanide,fecal coliform, naphthalene,nickel,phenol,phosphorus,sulfate,and zinc. 2. That the selenium limit be changed from a daily maximum limit to a monthly average limit based on an interpretation of 40 CFR 131.36. The facility also requests a continuation of the thermal limitations present in the permit. The facility has a 316(a)variance for outfall 001 and submits a yearly Balanced and Indigenous Population report in compliance with the variance. Permit modifications issued in 2003 clarify the temperature limit as being a monthly average effluent limitation,as opposed to a daily maximum limitation. As part of the permit application,Duke Power submitted EPA Forms 1,2C,and 2F. Form 2F was filled out for two stormwater outfalls:008 and 015. 3.0 Compliance Summary Instream Data The facility submitted the most recent Assessment of Balanced and Indigenous Populations In Lake Wylie Near Allen Steam Station report,developed in November 2004. This annual monitoring requirement began in 1990 as the result of an agreement between the Division and Duke Power to support the facility's 316(a)thermal variance. This study appears to concur with NPDES Permit Fact Sheet—09/27/05 Duke Power/Allen Steam Station Page 3 NC0004979 past studies in that Lake Wylie has a balanced indigenous fish community. No other instream monitoring is required as part of the NPDES permit. DMR Data Review DMRs were reviewed for outfalls 001,002,002A,002B,003 and 004 for the period of January 2002 through July 2005. At 001,the average flow over the review period was 581 MGD with a maximum flow of 784 MGD. The average daily temperature at this outfall was 82°F with a maximum daily temperature of 111°F. The discharge remained in compliance with its effluent limitations. Outfalls 002A and 002B have not discharged during the last permit cycle. Only flow is required to be estimated at outfall 003. The average flow estimate during the review period was 4.5 MGD. Only flow and oil and grease are required to be monitored at 004. Flow estimates during the review period averaged 6.5 MGD. O&G values averaged<5.0 mg/L with a maximum of 5.0 mg/L. The following table summarizes DMR data for non-toxicants at outfall 002. RPAs were performed for toxicants and metals(results discussed in the following section). Parameter Average.. :. ;,Maximum Minimum Flow(MGD) 18.92 34.1 0.7 BOD(mg/L) <2.0 2.0 <2.0 pH(s.u.) 6.8 9.3 6.1 Fecal coliform(#/100mL) <2.0 22 <2.0 TSS(mg/L) 10 28 <4.0 Oil and Grease(mg/L) <5 5 <5 Total Nitrogen(mg/L) 0.52 0.99 0.26 Total Phosphorus(mg/L) <0.010 0.02 <0.010 The only violation for the above monitored parameters was for pH. In July,2003 the facility recorded a pH value of 9.3,which exceeds its permit limit of 9.0 s.u.. Based on the above data,the facility requests removal of the monitoring requirements for BOD, fecal coliform,and phosphorus. All of those parameters had quarterly or semi-annual monitoring in the previous permit. Based on the data,it appears that effluent levels of these parameters are not sufficient to cause an adverse impact to water quality. Monitoring will be removed. RPA Analysis RPAs were performed for arsenic,barium,cadmium,chromium,copper,cyanide,iron, naphthalene,nickel,phenols,selenium,zinc,and sulfates. Since the facility does not have a permitted flow,past RPAs were conducted using the monthly average flow instead of permitted flow. That methodology was retained in this renewal. In 1996 the average flow was 11.6 MGD. Current average flows at outfall 002 are 19 MGD. NPDES Permit Fact Sheet—09/27/05 Duke Power/ Allen Steam Station " Page 4 NC0004979 The quarterly monitoring requirements will be removed for barium,cadmium,chromium, cyanide,naphthalene,nickel,phenols,zinc,and sulfates. None of these pollutants were present in levels that could reasonably be expected to cause an exceedance of water quality standards. Iron monitoring will remain in the permit due to the requirements of 40 CFR423.12. The permit limit is higher than the 1.0 mg/L recommended by 40CFR due to a past agreement between Duke Power and the Division to adjust the limit based on high levels of iron in the source water. An arsenic limit of 42 pg/L will be added to the permit. Two values measured in 2003 were above the allowable concentration of 42 pg/L. The previous permit had a selenium limit of 31 pg/L. The facility violated this limit in July,2003. Based on the change in IWC during this renewal,the new permit will have a selenium limit of 21 pg/L. The facility has requested that this limit be expressed as a monthly average based on EPA guidance. Duke argues that the current limit is based on a CCC for selenium of 5 pg/L and EPA directs for CCCs to be expressed as a monthly average limit. NC also has a selenium aquatic life criterion of 5.0 .ig/L. According to Division policy,this criterion can be expressed as a weekly average limit. Therefore the facility shall receive a weekly average selenium limit of 21 pg/L during this renewal. 40 CFR 423.12 requires a copper limit of 1.0 mg/L. Therefore the copper limit will be retained in this renewal. WET Test Results The IWC used for WET testing was 16%in previous permits. That value was based on an average discharge of 11.6 MGD. Currently,the discharge at outfall 002 averages 19 MGD. Therefore the WET testing requirement will be changed to reflect the 24%IWC. The Allen Steam Plant passed 21/23 chronic WET tests administered from January 2001 through July 2005. There were two total failures: one in October 2001 and another in October 2003. The facility passed two consecutive tests administered following each failure. Correspondence File Review/Compliance History There were two daily maximum permit violations over the 2002-2005 data review period. One was for pH(reported value of 9.3 s.u.)and the other was for selenium(reported value of 40.4 pg/L). Both violations occurred during the same month(July 2003). Inspection and staff reports note that the facility is consistently well operated and maintained. 4.0 Proposed Schedule for Permit Issuance Draft Permit to Public Notice: 9/28/05 Permit Scheduled to Issue: 12/1/05 5.0 State Contact Information If you have any questions on any of the above information or on the attached permit,please contact Toya Fields at(919)733-5083,extension 551. Copies of the following are attached to provide further information on the permit development: • Draft permit 'NPDES Permit Fact Sheet-09/27/05 Duke Power/Allen Steam Station Page 5 NC0004979 NPDES Recommendation by: Signature Date Regional Office Comments: 7% P/S4-P.G - �oG,g-/la,.f, Sot/f//15e/e- ftt.-!? ell/ 7z ,r/F i4/s 3, /.v,p0' ff s Cir? -gA /A-/ /S d3__O S2 0 v 3-G Re ional Reco endation b : Signatur Date Reviewed and accepted by: Regional Supervisor: Signature '/� f�% 4 Date / NPDES Unit Supervisor: Signature Date September 15,2005 Whole Effluent Toxicity Testing Self-Monitoring Summary • lUL AUG SEP NOV DEC FACILITY REQUIREMENT YEAR JAN FEB MAR APR MAY )UN — S Pau >� >� 2001 Peas — — Pus — _ Duke Power-Allen 002 chr lim:16% — — >64 ._ — Pass — — � — NCOW4979/002 Begin:7/I/2002 Frequency:Q Jan Apr Jul Oct + NonComp:Single 2002 >92 — — — — Pus Pass �, _ _ County:Gaston Region:MRO Subbasin:CTB34 2003 Pus — — __ — •- _ — >64 Special 2004 piss Pau Pau :s — PF: :9 2005 Paw — — — - — ass 7Q10:95.0 Order: .. ---- — ._ — ® 2001 — Pass — — Pus — -- Pus — Pus — Duke Power-Belem chr lim:19•/. — - Pus ._ — >78 — Pass Feb MayAugov + NonComp.Single 2002 -- Pass — Stokes NC0024406/003 Begin:6/I/20R2 Frequency:Q g 2003 -_ Pus — -- Pass — — Peas — — Pass County Stokes Region:WSROp Subbasin:ROA01 — — Pass — — Pau — — Pass — Spocial 2004 — Pus — — Pass — 7Q:NA 2005 — Pass - 7QIU:80.0 IWC(%)NA Order: -- — Pass 2001 — — Pau — — Pau — — Pass Duke Power-Buck Steam chr lim:0.7% _ — p� — -- Pau — — Pass Mar Jun Sep Dec + NonComp:Single 2002 — — >2.8 -- _ CCOUy:Row 02 Begin:l0/112Reg Frequency:Q 2003 — — Pau — — Pus — _ Pau Pass PF:NA• y:Rowan Region:MRO Subbasin:YADO4 2004 — — Pau -- — Pass — — Pass — — Pass 1Q Special 2004 2005 — — Pus -- — Pau — 7Q1o:1030 IWC(%)0.598 Order: — — Pau 2001 — — Pau — — Pau — — Pass Duke Power-COfbide chr lim:7.14% Pau — — >22.4 — ._ Pass -- — Pass NC0005088/002 Begin:I/I/2005 Frequency:Q Mar Jun Sep Dec + NonComp:Single 2002 —_ _ — Pus — — pus — — Pass • Rutherford Region:ARO Subbasin: _ 2003 — Peu in:BRD02 2004 — -_ Pass — -- Pass — — Pass — — Pus 7Q: Special — -- — Pus — ��_ 2005 — Pass 10:287 IWC(%) -- — Pau 2001 — -- Pus -_ — Pau — — Pau Duke Power-Dan River chr lim:LU4•/. — — Pass -_ — pair — — Pass Pus CCOUy:Rockingham Begin.9/I/20R2 Frequency:Q Mar Jun Sep Dec + NonComp:Single 2002 — — Pass — — Pus — — Pau — — Pass County:Rockingham Region:WSRO Subbasin:ROA03 PF: 1.8 SD 2004 — .- Pus — — 'Pass — — Pass — — Pau Special 2005 __ — Peas -- — POS. . _ . 7010:314.0 IWC(%)1.04 Order: -- '- -- . -- 2001 — — >92 — — >92 — — >92 .- — Late Duke Power-Lincoln Turbine chr lim:23% >92 — — >92 _ 85 — pus — _ NC0080781/001 Begin:7/1/2005 Frequency:1 x/Q Jan Apr Jul Oct + NonComp.Single 2002 >92 -- 09 -_ Pass 0 Pass 65 -- — — Pass County Lincoln Region:MRO Subbasin:CTB33 2003 — Pus — — — — — - _ Special 2004 >92 >92 >92 >92 70• 10:2.1 IWC(%)23 Order: ..- - . - .- - 2001 — Pus — — Pass — -- Pau — — Pus — DukeNC0 Power-Marshall 002 chr lien:12% — — — — Pau — — Pus — Feb May Aug Nov + NonComp:Single 2002 — Pus Pau Coun y Catawba Begin:6/IR00e5 Frequency:Q -. -_ Pass — — Pau — — Pass — County:Catawba Region:MRO Subbasin:CTB32 2003 -- Pus — — — - - — — 2001 — Pass Pus Pass Pau PF:5.3 Special — — Pus — — 7QI0:60.0 IWC(%)12.0 Order:: 2005 — Peas 2001 -- Pus -- -- Pass -_ — Pass -_ — Pass — NC0024392/001 Bee 001: 24hr plf ac lien:90% — __ — -_ — — + Feb May Augov + NonCom Sin le 2002 — pass — Pau >t00.Pau Pau :Mecklenburg Begin:l0/IR000 Region:MRO Frequency:Q Y B P B — — >t00 Pau — Pau — — Pass — 2003 — Put County: MRO Subbasin:CTB32 2004 — Pus - — Pass -- — Peas — — Pass — PF: Special 2005 — Pus -. — Peas — -_ 7010: Bo IwcCi)90 Orduo 2001 — >100 — — >100 — — >100 — — >100 — Duke Power-MeGulre 002 48hr LC50 ac lien:64% - — __ >100 — ._ >100 — + Feb MayAugov + NonCom Sin le 2002 •- >100 -- >100 CC00y:Meckle Begin:l0/I/2Reg Frequency:Q B p B — — — Pus >100 -- >100 — — >100 — PF:0.3315 Mecklenburg Region:MRO Subbasin:CTB33 2003 >100 — _ — — — — — 2004 _ >100 >100 >700 >1� PF: Specialrr -- — — — Orda: 2005 -- >100 >/00 .. . 7Q1U:80.0 IWC(%)0.64 - -- - 2001 Pus — — Pau — — Late Pass — Pus — — Duke Power-McGuire 005 chr lien:1.4% Pass — — Pua __ — Pass — — NC0024392/005 Begin:10/I/2000 Frequency:Q Jan Apr Jul Oct + NonComp:Single 2002 Pass = — Pass — — Pau — ._ Pass — — County:Mecklenburg Region:MRO Subbasin:CTB33 2003 Pass — — — — — -- — — 2004 Pass Pus Pau Pau PF:0.754 Special _ — p — — Pau 7010:80.0 IWC(%)1.4 Order: _._ Pa ss _ . .._ ___. ...--. Pau chr lim:10% 6 2001 Pass — — — -- Lau Peas -- Pus — — Duke Power-River Bead 002 — — >40 — — Pass — — Jan Apr Jul Oct + NonCom Sin le 2002 Late Pus — Pau County:Gaston Begin:3/1/2 Region:05 Frequency:Q p' g -- — Pass — — Pass — -- Pus — — PF:NA MRO Subbasin:CTB33 2003 Pass — -. — _ — — — — 2004 PusPau Pass Pass P 7Q: Special — — Pau — — Pau 7Q10:80.0 IWC(%)10.36 Order 2005 Pass Y Pre 2001 Data Available LEGEND: PERM=Permit Requirement LET=Administrative Letter-Target Frequency=Monitoring frequency:Q-Quarterly;M-Monthly;BM-Bimonthly;SA-Semiannually;A-Annually;OWD-Only when discharging;D-Discontinued monitoring requirement Begin-First month required 7Q 10-Receiving stream low flow criterion(cfs) +=quarterly monitoring increases to monthly upon failure or NR Months that testing must occur-ex.Jan,Apr,Jul,Oct NonComp=Current Compliance Requirement PF=Permitted flow(MGD) IWC/.-Instream waste concentration P/F-Pass/Fail test AC-Acute CHR=Chronic Data Notation:f-Fathead Minnow;•-Ceriodaphnia sp.;my-Mysid shrimp;ChV-Chronic value;P-Mortality of stated percentage at highest concentration;at-Performed by DWQ Aquatic Tox Unit;bt-Bad test Reporting Notation:--=Data not required;NR-Not reported Facility Activity Status:I-Inactive,N-Newly luued(To construct);H-Active but not discharging;t-More data available for month in question; =ORC signature needed 16 or - REASONABLE POTENTIAL ANALYSIS Allen Steam Station Outfall 2 NC0004979 Ow=18.9 MGD Tme Period 2002-2005 Ow(MGD) 18.9 WWTP Class 7010S(as) 95 IWC(%)0 7010S 23.569 7010W(cis) 95 0 7010W 23.569 3002(cis) 95 0 3002 23.569 Avg.Stream Flow,OA(cis) 95 0 OA 23.569 Reeving Stream Catawba River Stream Class WS-IV B STANDARDS& PARAMETER TYPE CRITERIA(2) POL Units REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION (1) NC WOS/ Ii FAV/ Chronic Acuten IDK liter Red Llr AeowaN•Cw Acute: N/A Arsenic NC 10 ug/L 42 42 203.5 _ _______ Chronic: 42 Two values above the allowable in 2003. Max predicted»allowable.Add limit Acute: N/A Barium NC 1000.0 ugh. 9 9 691.2 Note:n<12 Chronic: 4,243 Max predicted«allowable Limited data set Remove monitoring Acute: 15 Cadmium NC 2 15 ug/L 13 8 3.3 •_ _ _ __ Chronic: —_8- Max predicted re allowable. — ---�— Remove monitoring Acute: 1,022 Chromium NC 50 1,022 ug/L 14 1 Chronic: 212 •Max predicted<e allowable--- _-- Remove monitoring Acute: 7 Copper NC 7 AL 7.3 ug/L 79 76 117.9 Chronic: 30 max predicted»allowable.Action level parameter -� limit required by 40 CFR 423.12 Acute: 22 Cyanide NC 5 N 22 10 ugh. 12 3 5.0 Chronic:_—•21 man predicted«allowable._•---__-- --- _-- Remove monitoring Acute: N/A Iron NC 1 AL mg/I 52 52 2.4 Chronic:•—•4-- Max predicted<allowable•_•—• limit required by 40 CFR 423.12 Acute: N/A Napthatene NC 570 ugh. 19 1 13.9 Chronic: 2.418 Max predicted«allowable---_—•— Remove monitoring Acute: N/A Nickel NC 25 ug/L 12 12 47.9183 Chronic: 106 Max predicted«allowable•- —�— - — — —•— - Remove monitoring Acute: N/A Phenols A 1 N ug/L 19 0 5.0 Chronic:_—_4• No detections.—•—_— —�— —•— --- _-- -�� Remove monitoring Acute: 56 Selenium NC 5 56 ugh. 80 80 58.6 __ __ Chronic:_ 21 Several values above the allowable in 2003 Retain limit Acute: 67 Zinc NC 50 AL 67 ug/L 13 13 79.1 Chronic: 212 Mixrpedictetl«allowable— —�_ ---•__— Remove monitoring Acute: N/A Sunates NC 250.0 mg/L 13 13 96.4 Chronic: 1,061 Max predicted«allowable_•—�--- Remove monitoring Acute: N/A 0 0 N/A Chronic:Error I Type— - —_— - — --- - — Acute: N/A 0 0 N/A Chronic:Error 0 Type --- --- —•--- - ----- — —•— I Legend: "Freshwater Discharge C=Carcinogenic NC=Non-carcinogenic A=Aesthetic 4979_rpaxts,rpa 9/27/2005 0 WA7 . Michael F. Easley,Governor i' (1 State of North Carolina �, William G.Res, r.,Secretary 7 l Department of Environment anted, S'tuur l Resources Alan it: Y.E.,Director QMsion of Water Quality � September 28,2005 � CEP 2 9 200) Mr.Michael Ruhe r" Q� Duke Energy Corporation V P.O.Box 1006 Mail Code EC11E Charlotte,North Carolina 28201 Subject: Draft NPDES Permit Permit NC0004979 Allen Steam Station Gaston County Dear Mr.Ruhe Enclosed with this letter is a copy of the draft permit for your facility.Please review the draft very carefully to ensure thorough understanding of the conditions and requirements it contains. ➢ Since your facility does not have a flow limit,the average discharge volume at outfall 002 has historically been used to calculate permit limits and WET testing requirements. In 1996 that average flow was 11.6 MGD yielding an instream waste concentration(IWC)of 16%. Currently,your flows are averaging 19 MGD. Therefore the IWC used to calculate your permit requirements(including WET testing requirements)has been changed to 24%. ➢ Monitoring requirements for BOD,fecal coliform,and phosphorus have been removed due to the low levels historically present in your discharge. ➢ Monitoring requirements for barium,cadmium,chromium,cyanide,naphthalene,nickel,phenols, zinc,and sulfates have also been removed. None of these pollutants were present in levels that could reasonably be expected to cause an exceedance of water quality standards. ➢ An arsenic limit of 42 pg/L has been added to the permit. Two values measured in 2003 were above the allowable concentration of 42 pg/L. ➢ Based on your comments and Division policy,the selenium limit has been changed to a weekly average limit. You requested that this limit be changed to a monthly average requirement based on EPA guidance for calculating CCC-based limits,however NC water quality standards have a selenium aquatic life standard of 5.0}tg/L. Our policies allow for this to be expressed as a weekly average,not monthly average. In addition,this limit has been reduced to 21 pg/L due to your facility's higher IWC. ➢ A special condition has been added regarding the requirement to comply with the Cooling Water Intake Structure Rule per 40 CFR 125.95(section 316(b)requirements) Submit any comments to me no later than thirty days following your receipt of the draft.Comments should be sent to the address listed at the bottom of this page. If no adverse comments are received from the public or from you,this permit will likely be issued in two months. 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 Telephone(919)733-7015 FAX(919)733-0719 NolthCazolina 512 N.Salisbury Street,Raleigh,North Carolina 27604 On the Internet at http://h2o.enr.state.nc.us/ ‘Naturally An Equal Opportunity/Affirmative Action Employer k' rpt ` ` !-- . t,,„. -,: , - ,", - 77 tV '''71' " eg° pr ' ; r. ( . M 5 rtsT ro i7 4, f w +� ,t++ ,M ; V '''' If you have any questions or comments concerning this draft permit,contact me at(919)733-5083 x 551 or f °,". ' : toya.fields@ncmail.net. x w art, h F 0,4- F 'k- Sincerely, ' k 4� n,7 LeToya Fields v ti, yi,r �: . ,�, ` - Western NPDES Program 4 ,x u �, be ,.•�: ' ~ ' �. 4�Y 4e ti - cc: a Re ur ace ater Protection -, _.: ' NPDES Unit .. T Aquatic Toxicology : R i � Britt Setzer,Mooresville Regional Office—DEH r. '' k. 1, , ,'' Marshall Hyatt,EPA Region IV � a,F • -., Ifi M y,i r a '' .' t to '`1* i ' w '• e } ; ¢ a SE { r s t t } 1' ,F,, a r r RE' , r YY • ''' iYY �7 7C ��Ja� • �' • �4u��+ri'z rt". �Y 'i' ''? { �'� � :$�' �3 � k yy�� '''ir J al tt w S h�, i y ,. t if"' f" - t ( '1': r :.5 4,. :7f 1 eke i.rr EF ,, t 1'.,t y , i .#_ x :`7 t,:i;+�?: > *'!n '( ': k �Y , 4 t 1 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Duke Energy Corporation is hereby authorized to discharge wastewater from a facility located at the Plant Allen Steam Station 253 Plant Allen Road (NCSR 2525) Belmont Gaston County to receiving waters designated as the Catawba and South Fork Catawba Rivers in the Catawba River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV hereof. This permit shall become effective. This permit and authorization to discharge shall expire at midnight on May 31, 2010. Signed this day. DRAFT Alan W. Klimek, P.E. Director Division of Water Quality By Authority of the Environmental Management Commission Permit NC0004979 SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked.As of this permit issuance, any previously issued permit bearing this number is no longer effective.Therefore,the exclusive authority to operate and discharge from this facility arises under the permit conditions,requirements,terms,and provisions included herein. Duke Energy Corporation is hereby authorized to: 1. Continue to discharge: • Once through cooling water (outfall 001) • Operate a septic tank and ash pond with pH adjustment and discharge domestic wastewater, stormwater runoff, ash sluice, water treatment system wastewaters, and miscellaneous cleaning and maintenance wash waters (002). • Coal yard sump overflow (002A) and power house sump overflow (002B) • Miscellaneous equipment non-contact cooling and sealing water (003) • Miscellaneous non-contact cooling water, vehicle washwater, and intake screen backwash (004) From a facility located at the Plant Allen Steam Station on Plant Allen Road (NCSR 2525), south of Belmont in Gaston County, and 2. Without adding detergents or chemicals of any kind, discharge Asiatic clam/debris filter backwash (of the intake filter screen) (see Part A.7) 3. Discharge from said treatment works at the location specified on the attached map into the Catawba River (outfalls 002, 002A, 002B and 004) and the South Fork Catawba River (outfalls 001 and 003) which are classified Class WS-IV and B CA and WS-V waters, respectively, in the Catawba River Basin. 2 j^' tit r ia • i i t,;. _ t �{. �,( j ti f, . ,,. ' � ` ,� l; • Asiatic C1amfDebris , ▪I :i ' ' _�� ! y>< i',r ,Th �� Filter Backwash �f . a 'fir t-y Ii. -< ;11 ?�� nl �,j r �a f +�? • d� • rb: / ? ! r :� t � y l 1 r �y i if i. �✓ \ '-+a. : Y `F,�' n wts ;t i/ i I�� Li""). i• v -t t ,,. � '3�0 1:;„:i\ r S _�^•�"�. 1 a 7!` r r �), o- 'i+ 'tO F ' � ��N •-• l ^ • • `� Rt r,\ w�?1 � �� i`i)a'i. 11 ` ao� ! ,-.�r)' t�\.r -� \ .!\l ✓! :!f • i' T ',: KpJ/!�4 lg .. ` ,l?i ▪ 7. i / !'t -• 11 l !, if .' t'. , .� V. 1.4 r�U! TY a,..„:\.,...-:, \ i <! ,2 r s 7�� lif'.p fp ,1. 1�: 1 f r f s -: S� y• i W t �A /J �� l 002B f b'� /� 1 e � ' �, 1 ▪ )i �l ��a�' r- - _,' d� v A� tt. vV l jlt r _ ' # ;• ilk ! 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'�� -h-�} 4,��.'• llf c:. .-J1I . ,�k .i .'� i�`\ [�J (i`'.`f 'Ifl ..i.�aJ'f;6 Duke Energy Corporation Map not to scale Allen Steam Station State Grid/Ouad: G14NF1Belmont Permitted Flow: Not limited Receiving Streams: Catawba and South Fork Catawba Rivers Stream Class: WS-IV&B CAWS-V Drainage Basin: Catawba River Basin Sub-Basin: 03-08-34 Facility Latitude(001): 35°11'23" N Longitude(001): 81°00'45" W Location• �� � ;, Latitude(002): 35°10'30" N Longitude(002): 81°00'23" W " ,; Latitude(002A): 35°11'34" N Longitude(002A): 81°00'22" W Latitude(002B): 35°11'36" N Longitude(002B): 81°00'30" W Latitude(004): 35°11'35" N Longitude(004): 81°00'22" W North] NPDES Permit No. NC0004979 Latitude(A.Clam): 35°11'36" N Longitude(A.Clam):81°00'30" W L�/0}^G/6 Gaston County • Permit NC0004979 • A. (1.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge condenser cooling water (CCW) from outfall 001. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Daily Pump Logs Effluent Temperature 38.9°C Daily Grab or Instantaneous Effluent (June 1 -September 30)1 (102°F) Temperature 35°C Daily Grab or Instantaneous Effluent (October 1 -May 31)1 (95 2F) Notes: 1. The Regional Administrator has determined pursuant to Section 316(a) of the Act that the thermal component of the discharge assures the protection and propagation of a balanced, indigenous population of shellfish, fish, and wildlife in and on the receiving body of water. Chlorination of the once through condenser cooling water, discharged through outfall 001, is not allowed under this permit. Should Duke Power wish to chlorinate its condenser cooling water, a permit modification must be requested and received prior to commencing chlorination. 3 • Permit NC0004979 A. (2.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 002. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Weekly Daily Measurement Sample Type Sample Location Average Average Maximum Frequency Flow Weekly Instantaneous or estimate Influent or Effluent Oil and Grease 15.0 mg/1 20.0 mg/I Quarterly Grab Effluent Total Suspended Solids 30.0 mg/I 100.0 mg/I Monthly Grab Effluent Total Copper2 1.0 mg/I 2/Month Grab Effluent Total Iron2 1.58 mg/I Monthly Grab Effluent Total Arsenic2 42.0 p g/L 2/Month Grab Effluent Total Selenium2 21.0 p g/L 2/Month Grab Effluent Total Nitrogen (NO2+NO3+TKN) Semi-annually Grab Effluent Chronic Toxicity' Quarterly Grab Effluent pH3 Monthly Grab Effluent Notes: 1. Whole Effluent Toxicity shall be monitored by chronic toxicity (Ceriodaphnia) P/F at 24%. Tests shall be conducted in January, April, July and October (see Part A.(8.) for details) 2. Total metals are defined by 40 CFR 136. Any method specified by 40 CFR 136 is considered acceptable for analysis. 3. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. There shall be no discharge of floating solids or visible foam in other than trace amounts. 4 Permit NC0004979 . A. (3.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 002A-Coal Yard Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Episodic Estimate Effluent1 pH Episodic Grab Effluent Oil and Grease2 15.0 mg/I 20.0 mg/I Episodic Grab Effluent Total Suspended Solids2 30.0 mg/I 100.0 mg/I Episodic Grab Effluent Fecal Coliform Episodic Grab Effluent Total Iron3 1.0mg/I Episodic Grab Effluent Notes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. Sampling for iron is required only when TSS is reported as greater than 100 mg/L. THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS OR VISIBLE FOAM IN OTHER THAN TRACE AMOUNTS ALL FLOWS SHALL BE REPORTED ON MONTHLY DMRS. SHOULD NO FLOW OCCUR DURING A GIVEN MONTH, THE WORDS "NO FLOW" SHOULD BE CLEARLY WRITTEN ON THE FRONT OF THE DMR. EPISODIC SAMPLING IS REQUIRED PER OCCURRANCE WHEN SUMP OVERFLOWS OCCUR FOR LONGER THAN ONE HOUR. ALL SAMPLES SHALL BE OF A REPRESENTATIVE DISCHARGE. 5 Permit NC0004979 • A. (4.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 002B-Power House Sump Overflows. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Episodic Estimate Effluent1 pH Episodic Grab Effluent Oil and Grease2 15.0 mg/I 20.0 mg/I Episodic Grab Effluent Total Suspended Solids2 30.0 mg/I 100.0 mg/I Episodic Grab Effluent Total Copper3 1.0 mg/I Episodic Grab Effluent Total Iron3 1.0mg/I Episodic Grab Effluent Notes: 1. Effluent sampling shall be conducted at a point upstream of discharge to the receiving stream. 2. Monthly average limits for total suspended solids and oil and grease only apply if the overflow occurs for more than 24 hours. 3. The limits for total copper and total iron only apply during a chemical metals cleaning. THERE SHALL BE NO DISCHARGE OF FLOATING SOLIDS OR VISIBLE FOAM IN OTHER THAN TRACE AMOUNTS ALL FLOWS SHALL BE REPORTED ON MONTHLY DMRS. SHOULD NO FLOW OCCUR DURING A GIVEN MONTH, THE WORDS "NO FLOW" SHOULD BE CLEARLY WRITTEN ON THE FRONT OF THE DMR. EPISODIC SAMPLING IS REQUIRED PER OCCURRANCE WHEN SUMP OVERFLOWS OCCUR FOR LONGER THAN ONE HOUR. ALL SAMPLES SHALL BE OF A REPRESENTATIVE DISCHARGE. A. (5.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge from outfall 003. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Weekly Estimate Effluent Chlorination of the once through cooling water, discharged through outfall 003, is not allowed under-this-permit—Should-Duke-Power wish-to-chlorinate its-once-through cooling water,a permit-modification-must-be-requested-and-reeeived-priorto-commencingchlorination. 6 Permit NC0004979 • A. (6.) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS During the period beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge once through cooling water from outfall 004. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Type Sample Location Average Maximum Frequency Flow Weekly Estimate Effluent Oil and Grease 15.0 mg/I 20.0 mg/I Quarterly Grab Effluent Chlorination of the once through cooling water, discharged through outfall 004, is not allowed under this permit. Should Duke Power wish to chlorinate its condenser cooling water, a permit modification must be requested and received prior to commencing chlorination. A. (7.) SPECIAL CONDITION FOR THE DISCHARGE OF ASIATIC CLAM/DEBRIS FILTER BACKWASH The permittee may backwash the intake filter for Unit 5 condenser cooling water on an as- needed basis. It is understood that this wash water will contain materials indigenous to the Catawba River such as Asiatic clams and light debris. As these are naturally occurring in the river environment, they may be discharged with no adverse affects to the receiving stream. The Permittee may not add any detergent, chemicals or other non-indigenous material to the wash water without explicit permission of the Division of Water Quality. 7 Permit NC0004979 A. (8.) CHRONIC TOXICITY PASS/FAIL PERMIT LINIIT (QUARTERLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 24%. The permit holder shall perform at a minimum, quarterlq monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, or subsequent versions or"North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised-February 1998) or subsequent versions. The tests will be performed during the months of January,April,July and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple-concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised-February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised- February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the months in which tests were performed, using the parameter code TGP3B for the pass/fail results and THP3B for the Chronic Value. Additionally, DWQ Form AT-3 (original) is to be sent to the following address: Attention:North Carolina Division of Water Quality Environmental Sciences Branch 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Branch no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of"No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re- opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. 8 Permit NC0004979 , A. (9.) BIOCIDE CONDITION The permittee shall not use any biocides except those approved in conjunction with the permit application. The permittee shall notify the Director in writing not later than ninety (90) days prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life other than those previously reported to the Division of Water Quality. Such notification shall include completion of Biocide Worksheet Form 101 and a map locating the discharge point and receiving stream. Completion of Biocide Worksheet Form 101 is not necessary for those outfalls containing toxicity testing. Division approval is not necessary for the introduction of a new biocide into an outfall currently being tested for toxicity. A. (10.) SPECIAL CONDITIONS The following special conditions are applicable to all outfalls regulated by NC0004979: • There shall be no discharge of polychlorinated biphenyl compounds. • It has been determined from information submitted that the plans and procedures in place at Allen Steam Station are equivalent to that of a BMP. • The permittee shall report the presence of cenospheres observed in any samples. • The applicant is permitted to discharge chemical metal cleaning wastes to the ash basin under the conditions outlined in the 1976 Riverbend Ash Basin Equivalency Demonstration and the 1994 Allen Steam Station permit application • The permittee shall check the diked areas for leaks by a visual inspection and shall report any leakage detected • If the permittee, after monitoring for at least six months, determines that he/she is consistently meeting the effluent limits contained herein, the permittee may request of the Director that the monitoring requirement be reduced to a lesser frequency. • Nothing contained in this permit shall be construed as a waiver by the permittee or any right to a hearing it may have pursuant to State or Federal laws or regulations. • Low volume waste is defined as follows (as per 40 CFR 423.11(b): "Low volume wastes sources include, but are not limited to: wastewaters from wet scrubber air pollution control systems, ion exchange water treatment system, water treatment evaporator blowdown, laboratory and sampling streams, boiler blowdown, floor drains, cooling tower basin cleaning wastes, and recirculating house service water systems. Sanitary and air conditioning wastes are not included." A. (11.) SECTION 316 (B) OF CWA The permittee shall comply with the Cooling Water Intake Structure Rule per 40 CFR 125.95. 9 e State of North Carolina �� Department of Environment ' • and Natural Resources • Division of Water Quality ' �dYENl�� Michael F. Easley, Governor / JRCES William G. Ross, Jr., Secretary ,� - NCDENRLOFFlde Alan W. Klimek, P.E., Director April 16, 2004 APR 3 Q 2004 Mr. Michael Ruhe, Manager `\�' Duke Power/Environmental Support 526 South Church Street Charlotte, North Carolina 28202-1802 7771. , ,ri tl Subject: ATC Request AtilandaiiIedgmenti + i•os NPDES Permit NC0004979 Allen Steam Station CULL q AD I Gaston County Dear Mr. Ruhe: The Division of Water Quality's NPDES Unit hereby acknowledges receipt of your request for Authorization to Construct in accordance with NPDES Permit Number NC0004979. This application has been assigned the number highlighted above. Please be aware that the Division's regional office, copied below, must provide recommendations from the Regional Supervisor prior to final action by the Division. The ATC review process generally takes 90 days from the date your complete submittal is received, however, due to current staff shortages that review period may take longer. Should any additional information be required, the review engineer will contact you. If you have any questions, please contact Mr. Sergei Chernikov at (919) 733-5083 ext. 594. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING ANY INQUIRIES ABOUT THIS APPLICATION. Sincerely, qvcritnci, David A. Goodrich Supervisor, NPDES Unit cc: rl r�` nal Office +''DES Unit Permit File 1617 Mail Service Center, Raleigh, North Carolina 27699-1617/Telephone 919-733-5083 FAX 919-733-0719 An Equal Opportunity Affirmative Action Employer/50% recycled/ 10%post-consumer paper